Water-Based Paint Formulations, Volume 3

WATER- BASED PAINT FORMULATIONS Volume 3 bY Ernest W. Flick NOYES PUBLICATIONS Park R W , NOW Jo-~, USA. Copyright ...

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WATER- BASED PAINT FORMULATIONS Volume 3

bY

Ernest W. Flick

NOYES PUBLICATIONS Park R W , NOW Jo-~, USA.

Copyright 8 1994 by b e s t W.Flick No part of this book may be reproduced or utilized in any fonn or by any means, electronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without permission in writing from the Publisher. Library of coOgrcss Catalog Card Number: 75-2939 ISBN: 0-8155-1345-3 Printed in the United States Published in the United States of America by Noyes Publications Mill Rmd, Park Ridge, New Jersey 07656

10 9 8 7 6 5 4 3 2 1

Library of Congress Cataloging-in-Publications Data (Revised for vol. 3)

Flick, Ernest w. Water-based paint formulations.

Vol. 3 published by Noyes Publications. Includes index. 1. Paint--Patents. I[. Title. Tp935.F62 1975 66T.63 ISBN 0-81554571-X (v. 1) ISBN 0-8155-1345-3 (v. 3)

75-2939

To Carol and Bob and Janet and Dennis; Karen and David and their families

Preface

This collection of 463 up-to-date water-based trade and industrial formulations will be of value to technical and managerial personnel in paint manufacturing companies and firmswhich supply raw materials or services to these companies, and to those interested in less hazardous, environmentally safer formulations. The book will be useful to both those with extensive experience as well as those new to the field. This book includes new and different formulations than those included in the previously published Industrial Water-Based Paint Formulatwns and Water-Based Trade Paint Formulations. The data consist of selections of manufacturers’ suggested formulations made at no cost to, nor influence from, the makers or distributors of these materials. The information given is presented as supplied; the manufacturer should be contacted if there are any questions. Only the most recent data supplied us has been included. Any solvent contained is minimal. The table of contents is organized in such a way as to serve as a subject index. The formulations described are divided into sections which cover exterior, interior, and exterior and/or interior water-based paints, enamels, and coatings, as indicated below:

I. Coatings and Topcoats 11. Coil Coatings 111. Enamels

IV. Enamels-Baking V. Exterior Paints and Related VI. Interior Paints and Related VII. Lacquers VIII. Primers IX. Sealers X. Stains XI. Texture Paints XII. Miscellaneous vii

viii

Preface

Each formula has been placed in the chapter which is most applicable. The reader, if seeking a formula for a specific end use, should check each chapter which could possibly apply.

In addition to the above, there are two other sections which will be helpful to the reader:

XIII. A chemical trade name section where trade-named raw materials are listed with a chemical description and the supplier's name. The specificationswhich the raw materials meet are included if applicable. XIV. Main office addresses of the suppliers of trade-named raw materials and/or formulations. Included in the descriptive information for each formulation, where available, the following properties may be listed: viscosity, solids content, % nonvolatiles, pigment volume concentration, density, pH, spatter, leveling, sag resistance, scrub cycles to failure, contrast ratio, ease of dispersion, fineness of grind, heat stability, freeze-thaw stability, ease of application, gloss foaming, cratering, brightness, opacity, water spotting, adhesion to chalk, brush clean-up, reflectance, and sheen. Ernest W. Flick

Notice To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequence arising from, such information. These formulations do not purport to contain detailed manufacturing nor user instruction, and by its range and scope could not possibly do so. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Author or Publisher. Water-based paint raw materials could be toxic, and therefore, due caution should always be exercised in the use of these hazardous materials. Final determination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We strongly recommend that users seek and adhere to a manufacturer's or supplier's current instructions for handling each material they use. The Author and Publisher have used their best efforts to include only the most recent data available. The reader is cautioned to consult the supplier in case of questions regarding current availability.

Contents and Subject Index SECTION I: COATINGS AND TOPCOATS .................... 1 Air Dry or Force Dry Cure Clear Coating-A . . . . . . . . . . . . . . . . . . 2 Air Dry or Force Dry Cure Clear Coating-B . . . . . . . . . . . . . . . . . . . 2 3 Air Dry or Force Dry Clear Coating-A ...................... Air Dry or Force Dry Clear Coating-B ....................... 3 Air or Force Dry Clear Coating-A .......................... 3 Air or Force Dry Clear Coating-B .......................... 4 Alkyd Topcoat Formula .................................. 5 Aqueous Thermoset Topcoat .............................. 6 Black Rust Inhibitive Coating ............................. 7 Chrome Yellow Topcoat ................................. 8 Clear Build Coat Based on Rhoplex CL-103 Emulsion for Air-Dry or Low-Force-Dry Application . . . . . . . . . . . . . . . . 9 Clear Build Coat Based on Rhoplex CL-104 Acrylic Emulsion . . . . 10 Clear Coating ........................................ 11 12 Clear Coating for Wood and Concrete ...................... Clear Satin Thermosetting Sealerflopcoat Based on Rhoplex AC-1024 ................................. 13 Coating ............................................ 14 Curtain Coatable 35 PVC Topcoat Formulation . . . . . . . . . . . . . . . . 15 Experimental Coating: Spray ............................. 18 Flat Topcoat Based on Experimental Emulsion E-2955 . . . . . . . . . . 19 Force Dry White High Gloss Top Coat DiNSpray . . . . . . . . . . . . . . 20 Gloss Black Topcoat for Brush and Roller Application . . . . . . . . . . 21 Gloss Green AcryliJEPOxy Topcoat ........................ 23 Gloss Midtone Tint Base AcryliJEPOxy Topcoat . . . . . . . . . . . . . . 24

ir

x

Contents and Subject Index

Gloss Topcoat ....................................... 25 Gloss Topcoat Based on Experimental Emulsion E-2955 . . . . . . . . . 26 Gloss White AcryliJEpoxy Topcoat ........................ 27 Gloss White Topcoat for Brush and Roller Application . . . . . . . . . . 29 High Build Gloss White Topcoat for Airless Spray Application . . . . 30 High Gloss DTM Maintenance Coating ..................... 31 33 High Performance. Flexible Coating ........................ High Performance Water-Borne Air Dry Coating Topcoat Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 High Solids Water-Borne Clear Coating-B . . . . . . . . . . . . . . . . . . 35 High Solids Water-Borne Clear Coating-C . . . . . . . . . . . . . . . . . . 35 Industrial Airdry White High Gloss Top Coat . . . . . . . . . . . . . . . . . 36 Low Solids Clear Topcoat ............................... 37 Low Solids Full Gloss Topcoat Based on Rhoplex CL-104 Emulsion for Air-Dry or Low-Force-Dry Application . . . . . . . 38 Red Oxide Maintenance Coating . . . . . . . . . . . . . . . . . . . . . . . . . . 39 Satin Thermosetting SealerRopcoat Based on Rhoplex AC-1024 Emulsion with Early Water and Stain Resistance . . . . . . . . . . . 40 Waterbased Charcoal Basecoat with Pearlescent Waterbased Clearcoat Conventional Urethane Clearcoat . . . . . . . . . . . . . . . 41 Waterbased Clearcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 Water-Borne Clear Coating-A ........................... 43 Waterborne Acrylic Conversion Coating for Wood . . . . . . . . . . . . . 44 Water-Borne Coating for Plastics ......................... 45 Water Soluble Acrylic Clear Coating-A Modified with K-Flex 46 UD-320W . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Water Soluble Acrylic Clear Coating-B ..................... 47 Water Soluble Acrylic Clear Coating-C ..................... 47 White High Gloss Railcar Coating . . . . . . . . . . . . . . . . . . . . . . . . . 48 White Roof Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 White Satin Thermosetting Topcoat ........................ 50 25 PVC Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 35 PVC Curtain Coatable Topcoat ......................... 52 35 PVC Hardboard Topcoat Formulation .................... 53

SECI'ION II: COIL COATINGS ............................ Gloss Coil Coating-Black Deeptone ....................... Gloss Coil Coating-Dark Brown Deeptone . . . . . . . . . . . . . . . . . . Phthalo Green Coil Coating Green Semi-Gloss . . . . . . . . . . . . . . . . Water-Reducible Acrylic Coil Coating ...................... White Coil Coating: All Ti02 ............................ White Coil Coatings: Low Gloss ..........................

54 55 56 57 58

59 60

Contents and Subject Index

xi

SECl'ION III: ENAMELS ................................. 61 Acrylic Semi-Gloss White Enamel ........................ 62 Air-Dry Water-Reducible Enamel ......................... 63 Black Acrylic Emulsion Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Black Air Dry Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 66 Black Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 Black Gloss Chromate Enamel ............................ 77 Black Gloss Enamel Flowcoat or Dip ....................... 78 Black Gloss Non-Chromate Enamel ........................ 79 Black High Gloss Brushing Enamel ........................ 80 Black High Gloss Enamel ............................... 81 Blue High Gloss Enamel ................................ 82 Black Low Gloss Enamel ............................... 83 Blue Acrylic Emulsion Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . 84 Blue Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Blue High Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 Blue Semi-Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87 Clear Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88 Clear Enamel (for use with predispersed colorants) . . . . . . . . . . . . . 89 Gloss White Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90 Gloss White Enamel (Maximum Acid Resistance) . . . . . . . . . . . . . . 91 Clear Enamel (Maximum Acid Resistance) . . . . . . . . . . . . . . . . . . . 92 Clear Enamel (Maximum Solvent and Abrasion Resistance) . . . . . . . 93 Economical Flat Black Air Dry Enamel ..................... 94 Gloss Black Enamel ................................... 95 Gloss Black Forced-Dry Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . 98 Gloss Green Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 Gloss Maintenance Enamel-Deep Base .................... 100 Gloss White Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 Gloss White Enamel for Electrostatic Disc Spray . . . . . . . . . . . . . 104 Gloss White Enamel for Electrostatic Spray Application . . . . . . . . 105 Gloss Yellow Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 106 Gray Deck Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 Gray Low Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108 Green Chrome Free Gloss Enamel ........................ 109 Green Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110 Green Fast Dry Gloss Enamel ........................... 111 High Gloss Ford Blue Enamel ........................... 112 High Gloss Interior Enamel ............................. 113 High-Hiding Eggshell Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 High Performance Bake White Enamels .................... 115 High Solids PolyesterMelamine Enamel .................... 116 Light Heliogen Green Enamel ........................... 117 Non-Leafing Aluminum Enamel ......................... 118

xii

Contents and Subject Index

Quality Gloss White Enamel ............................ 119 Red Acrylic Emulsion Enamel ........................... 122 123 Red Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Red Gloss Acrylic Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124 Red Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 Red High Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126 Red Rose Air Dry Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127 Satin White Air Dry Enamel ............................ 128 Semigloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129 Semigloss Maintenance Enamel-White ..................... 130 Semigloss White Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131 Semigloss White Trim Enamel ........................... 132 Steel Blue Gloss Enamel ............................... 133 Tintable Eggshell Enamel .............................. 134 Velvet Latex Enamel OptiwhiteBurgess No. 98 Approach . . . . . . . 135 Waterborne Polyester Enamel ........................... 136 Waterborne Polyesterhfelamine Enamel Clear Enamel Composition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137 Water Reducible Acrylic Enamel-IIB K-Flex UD-320W Modified . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 . . . . . . . . . . . . . . . . . . 139 Water Reducible Acrylic Enamel-II-C-I1 Water Reducible Air Dry Gloss White Enamel . . . . . . . . . . . . . . . 140 Water Reducible. Low Gloss Black Enamel . . . . . . . . . . . . . . . . . 141 Water-Reducible Polyester Enamel A ..................... 142 Water-Reducible Polyester Enamel B ..................... 143 Water Reducible White Enamel .......................... 144 145 White Acrylic Baking Enamel ........................... White Acrylic Emulsion Enamel ......................... 146 White Air Dry Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148 White Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156 White Enamel Formulation ............................. 159 White Fast Dry Enamel ................................ 160 161 White Gloss Enamel .................................. White. High Gloss. Air Dry or Force Dry Water Reducible Enamel ........................................ 164 White High Gloss Brushing Enamel ....................... 166 White Semi-Gloss Trade Sales Enamel .................... 167 W R Polyesterhfelamine Enamel K-Flex Modified . . . . . . . . . . . . 168 Yellow Gloss Enamel ................................. 169 Yellow Iron Oxide High Gloss Enamel ..................... 170 SECTION IV: ENAMELS-BAKING ....................... Black Anti-Corrosive Dip Enamel ........................ Black Baking Dip Enamel ..............................

171 172 173

Contents and Subject Index

xiii

Black Gloss Baking Enamel ............................ 174 Black Low Gloss Baking Enamel ......................... 175 Bone White Semi-Gloss Baking Enamel . . . . . . . . . . . . . . . . . . . 176 Brown High Gloss Baking Enamel ........................ 177 Clear Low VOC Baking Enamel . . . . . . . . . . . . . . . . . . . . . . . . . 178 275 Grams/Liter Gloss Black Baking Enamel . . . . . . . . . . . . . . . . 179 Gloss Black Baking Enamel ............................ 180 181 Gloss White Bakiig Enamel ............................ Green Gloss Force Cure Enamel ......................... 184 185 High Gloss Black Baking Enamel . . . . . . . . . . . . . . . . . . . . . . . . High Gloss Gray Baking Enamel ......................... 186 High Gloss Light Blue Baking Enamel ..................... 187 188 High Gloss White Baking Enamel ........................ High Gloss White Baking Finish Roller Mill Grind . . . . . . . . . . . . 190 High Gloss White Baking Finish Cowles Dissolver Grind . . . . . . . 190 High Gloss White Baking Finish Sand Mill G r i d . . . . . . . . . . . . . 191 High Gloss White Baking Finish Pebble Mill Grind . . . . . . . . . . . . 191 Low Temperature Cure Black Baking Enamel . . . . . . . . . . . . . . . . 192 Red Baking Enamel .................................. 193 Semi-Gloss Gray Baking Enamel ........................ 194 Silver Metallic Bake Enamel ............................ 195 Tan Semi-Gloss Baking Enamel ......................... 196 Very Low VOC Gloss Gray Baking Enamel . . . . . . . . . . . . . . . . . 197 Very Low VOC Gloss Rose Baking Enamel . . . . . . . . . . . . . . . . . 198 199 Very Low VOC Gray Baking Enamel ...................... Very Low VOC Semi-Gloss Blue Baking Enamel . . . . . . . . . . . . . 201 Very Low VOC Violet Baking Enamel ..................... 202 Very Low VOC White Baking Enamel ..................... 203 205 Waterborne Acrylic Bake Enamel ........................ Water Reducible. Force Cure Black Gloss Enamel . . . . . . . . . . . . 206 Water Reducible. Gloss White Baking Enamel . . . . . . . . . . . . . . . 207 Water Reducible. High Gloss White Baking Enamel . . . . . . . . . . . 208 Water Soluble Baking Enamels .......................... 209 White Baking Enamel ................................. 210 White. High Gloss. Water Reducible Baking Enamel . . . . . . . . . . . 217

SECTION V: EXTERIOR PAINTS AND RELATED . . . . . . . . . . . . Accent-Base Trim Paint ............................... Clear Wood Preservative ............................... Deep-Base Trim Paint ................................ Economy White House Paint ............................ Exterior Flat House Paint-White ......................... Exterior Flat Paint ................................... Exterior Flat White House Paint with Zinc Oxide . . . . . . . . . . . . .

221 222 223 224 225 226 227 229

xiv

Contents and Subject Index

Exterior House Paint-Tint Base . . . . . . . . . . . . . . . . . . . . . . . . . . Exterior Semi-Gloss . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Exterior Sheen House Paint-White ........................ Exterior Trim House Paint-White . . . . . . . . . . . . . . . . . . . . . . . . Exterior White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lower Cost White and Tint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Exterior White House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Flexible. Premium.Performance. High-Solids Caulk . . . . . . . . . . . General Purpose Mastic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Quality Deep-Base House Paint .......................... Quality Sheen White House Paint ........................ Quality Tint-Base House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . Quality White House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Tint-Base Trim Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . TT-P-19D Acrylic House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . White Trim Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

230 231 232 233 234 234 235 236 237 238 240 241 244 249 250 251

SECTION VI: INTERIOR PAINTS AND REJATED . . . . . . . . . . . 253 Architectural Interior Flat .............................. 254 Best Quality Flat Wall Paint ............................ 255 Better Quality Flat Wall Paint ........................... 256 Dripfree Acrylic Latex Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . 257 Economy Flat Wall Paint .............................. 258 Flat Intenor Latex Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 260 Flat Intenor Vinyl-Acrylic Latex Paint .................... 264 266 Good Quality Flat Wall Paint ........................... Good Quality Interior Flat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267 268 Green Floor Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . High-Build Interior Flat Wall Paint Based on a Vinyl Acrylic Copolymer Thickened with Acrysol RM-825 . . . . . . . 269 High Build Interior Flat Wall Paint Based on a Vinyl Acrylic Copolymer Thickened with Experimental Rheology Modifier QR-708 ......................... 270 High-Quality Flat Wall Paint ........................... 271 272 Interior Gloss White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Interior Semigloss-Acrylic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273 274 Interior Semigloss White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Latex Interior Satin ................................... 275 Latex Interior Semi-Gloss .............................. 276 Low Cost. High Hide Interior Flat ........................ 277 Low-Cost Interior Flat Tint Base . . . . . . . . . . . . . . . . . . . . . . . . . 278 Low VOC Paint 65PVC Flat . . . . . . . . . . . . . . . . . . . . . . . . . . . . 279 280 Low VOC Semi Gloss ................................. Polyvinyl Acetate Latex Paint ........................... 281

Contents and Subject Index Premium Quality Interior White Eggshell Wall Paint Based on Rhoplex AC-64 Thickened with Acrysol RM-825 . . . . . . . Quality Flat Tint Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Quality Interior White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Quality Latex Flat Optiwhite Approach .................... Quality Latex Interior Flat Optiwhite Approach . . . . . . . . . . . . . . . Quality Latex Semi-Gloss Burgess No. 98 Approach . . . . . . . . . . . Red Floor Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Semigloss Interior White Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . Semi-Gloss White Formulation .......................... Styrene-Butadiene Latex Paint .......................... White Floor Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

SECTION W:LACQUERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Air-Dry Lacquer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear. Full Gloss Waterborne Lacquer Based on Rhoplex CL-103 Emulsion for Air-Dry or Low-Force-Dry Application . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear. Full-Gloss Waterborne Lacquer Based on Rhoplex CL-104 Emulsion for Air-Dry or Low-Force-Dry Application . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Lacquer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Lacquer Based on Rhoplex WL-92 Polymer Wood Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Lacquer Formulation for Low Force-Dry Application . . . . . . Clear Waterborne Lacquer. Flatted to 40 Based on Rhoplex CL-103 Emulsion for Air-Dry or Low-Force-Dry Application . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Waterborne Lacquer. Flatted to 40 Gloss at 60 Based on Rhoplex CL-104 Emulsion for Low-Force-Dry Application . Flat Black Lacquer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lacquer Type Busan Primer .................................... Chromate-Free . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Chromate Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear for Corrosion Resistance ........................ Dark Walnut Wiping Stain . . . . . . . . . . . . . . . . . . . . . . . . . . Flat Black . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Flat Clear . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Full Gloss Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gloss Black . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gloss Black Force-Dry ............................. Gloss Green .....................................

xv

282 283 284 285 286 287 288 289 290 291 292 293 294

295

297 297 298 299

300 301 302 303 304 305 306 311 312 313 314 315 317 319 320

mi

Contents and Subject Index Gloss Pastel Yellow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gloss Yellow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Golden Oak Wiping Stain ........................... Grey Chromate Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heucophos ZBZ Red Primer ......................... High Gloss Green ................................. Medium Gloss Topcoat ............................. Oncor F-31 Pigmented . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Strontium Chromate ............................... Strontium Chromate Primer . . . . . . . . . . . . . . . . . . . . . . . . . . Tinsel Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Medium Gloss. Force Dry. Weatherborne Lacquer-White . . . . . . . Pigmented Lacquer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................. Pigmented Lacquer-White Waterborne Pigmented Lacquer White. for Air Dry or Force Dry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

321 322 323 324 325 326 327 328 329 331 332 334 335 338 339 340

SECTION VIII: PRIMERS ............................... Airdry Black Metal Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Chromate-Free Anti-Corrosive Primer ..................... Force Dry Red Oxide Metal Primer ....................... Gray Primer ........................................ Gray Rust Inhibitive Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Metal Free Water-Borne Barrier Primer . . . . . . . . . . . . . . . High Quality Stain Blocking Primer ....................... Latex Maintenance Primer .............................. Latex Stain Blocking Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . Latex Wood Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Lead-Free and Chromate-Free Primer ..................... Light Blue Anti-Corrosive Primer . . . . . . . . . . . . . . . . . . . . . . . . Light Duty Maintenance Primer Containing Busan 11M-1 . . . . . . . OFM Acrylic/Epoxy Primer ............................. Primer Formulation ................................... Red AcryliC/Epoxy Primer .............................. Red Iron Oxide Air Drymake primer ...................... Red Iron Oxide Baking Primer ........................... Red Iron Oxide Metal Primer ............................ Red Iron Oxide Primer ................................ Red Iron Oxide Primer with Heucophos ZBZ for Brush/Roller Application . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Red Iron Oxide Primer with Zinc Phosphate for Airless Spray Application .....................................

342 343 344 345 346 348 349 350 351 352 353 354 355 356 357 358 360 361 362 364 365

341

367 368

Contents and Subject Index

Red Iron Oxide Primer with Zinc Phosphate for BrusldRoller Application . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Red Iron Oxide Rust Inhibitive Primer ..................... Red Oxide Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Starting Point Formulation P-76-1 for Cementitious Metal Primers Based on Rhoplex MC-76 .................... Starting Point Formulation P-76-2 for Cementitious Metal Primers Based on Rhoplex MC-76 .................... Starting Point 45 PVC Primer Formulation . . . . . . . . . . . . . . . . . . Tannin Block Primer/Sealer Formulation . . . . . . . . . . . . . . . . . . . Tannin Stain-Blocking Exterior Primer .................... Tannin Stain Inhibiting Latex Wood Primer . . . . . . . . . . . . . . . . . Waterbase Acrylic Latex Primer ......................... Water-Reducible Automotive Primer with Strontium Chromium Gray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Water-Reducible Automotive Primer Without Strontium Chromate Gray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Water Reducible. Gray Air Dry or Force Dry Cure Primer: Lead and Chromate Free ............................ White AcrylidEpoxy Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . White Alkyd Wood Primer ............................. White House Paint Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Woodstain-ResistantKorrosion-Resistant Primer Containing A c ~ ~ s oRM-825 I ................................. 20 PVC Waterborne Pigmented Primer ..................... 31 PVC Waterborne Pigmented Primer ..................... 45 PVC Exterior Hardboard Primer ....................... 55 PVCPrimer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 PVC Primer Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . .

SECTION Ix: SEALERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clear Concrete Sealer ................................. Clear Urethane/Acrylic Wood Finish ...................... Clear Sealer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concrete Sealer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low-Solids Sanding Waterborne Sealer Based on Rhoplex CL-104 Emulsion for Air-Dry or Low-Force-Dry Application ..................................... Sanding Sealer Based on Experimental Emulsion E-2955 Sanding Waterborne Sealer Based on Rhoplex CL-104 Emulsion for Air-Dry or Low-Force-Dry Application . . . . . . Sealer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Waterproofing Sealer: White Masonry Paint . . . . . . . . . . . . . . . . .

xvii

369 370 371 373 373 374 375 376 377 379 380

381 382 384 385 386 387 388 389 390 392 394

395 396 396 397 398

399 401 402 403

xviii

Contents and Subject Index

SECIlON X STAINS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 404 Brown Pigmented Spray Stain Based on Acrysol 1-62 . . . . . . . . . . 405 Brown Pigmented Wiping Stain . . . . . . . . . . . . . . . . . . . . . . . . . . 406 Redwood Stain-Opaque . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 407 Redwood Staidemi-Transparent . . . . . . . . . . . . . . . . . . . . . . . 408 Semi-Transparent Cherry Stain . . . . . . . . . . . . . . . . . . . . . . . . . . 410 Shingle Stain Tint Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 411 Sierra Redwood Stain-Semi-Transparent . . . . . . . . . . . . . . . . . . 412 Stain Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 413 Waterborne Redwood Solid Color Stain .................... 415 Waterborne Semi-Transparent Russet Brown Stain . . . . . . . . . . . . 416 SECTION XI: TEXTURE PAINTS . . . . . . . . . . . . . . . . . . . . . . . . . Interior Texture Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . White Textured Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

417 418 421

SECTION XU: MISCELLANEOUS . . . . . . . . . . . . . . . . . . . . . . . . . 422 Ball Mill Paste-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 423 Ball Mill Paste-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 423 Ball Mill Paste-111 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 423 Ball Mill Paste-IV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 423 Clear Coating and Concrete Curing Membrane . . . . . . . . . . . . . . . 424 Concrete Sealer/CCM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 424 Corrosion Inhibitor Comparison in an Air Dry Waterborne Alkyd System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 425 Corrosion Inhibitor Comparison in a Waterborne Polyester/ Melamine Bake System ............................. 426 Gloss White Tile-Like Formulation XG-105-2 For Brush and Roller Applications ..................... 427 For Spray Applications ............................. 428 Gloss White Tile-Like Formulation XG-105-4 for Brush and Roller Applications ................................ 429 Gray EM1 Shielding Coating ............................ 430 Green. High pH Formulation ............................ 431 Green. Low pH. High Solids Formulation . . . . . . . . . . . . . . . . . . . 432 High Performance Traffic Paint .......................... 433 Red Semi-Gloss Traffic Paint ........................... 434 Rhoplex WL-81Epotuf 38-690 (Epoxy Ester) Blend System . . . . 435 Traffic Marking Paint ................................. 437 Wash Coat Based on Emulsion E-2774 .................... 438 Water-Borne Air Dry Primer and Topcoat System Primer Formulation ..................................... 439 Water-Borne Air Dry Primer and Topcoat System Topcoat 440 Formulation .....................................

Contents and Subject Index

xix

Water Reducible Alkyd . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 441 Water-Reducible Automotive Under-Hood Coating Black . . . . . . . 442 Water Reducible Epoxy: Polyol Modified-B . . . . . . . . . . . . . . . . . 443 Water Reducible Acrylic Enamel: Polyol Modified . . . . . . . . . . . . 444 White. High pH. General All-Purpose Ambient Cure System with an Optimum Balance for Key Property Development . . . . 445 White. Low pH. High Solids Formulation Based on Acryloid WR-748 Resin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 446 White. Pebble Mill Formulation .......................... 447 White. Water Grind Formulation. High pH . . . . . . . . . . . . . . . . . . 448 White. Water Grind Formulation. Low pH . . . . . . . . . . . . . . . . . . 449 White. Water Reducible Acrylic/Melamine-A . . . . . . . . . . . . . . . . 450 White. Water Reducible Acrylic/Melamine-B . . . . . . . . . . . . . . . . 451 White. Water Reducible Acrylic/Melamine-C . . . . . . . . . . . . . . . . 452 White. Water Reducible AcrylidMelamine-D . . . . . . . . . . . . . . . . 453 Wiping Stain for Media Mills . . . . . . . . . . . . . . . . . . . . . . . . . . . 454 Yellow Implement Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 455 Yellow Iron Oxide Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 456 SECTION XUU: TRADE NAMED RAW MATERIALS SECTION XIV: SUPPLIERS' ADDRESSES

. . . . . . . . . . 457

. . . . . . . . . . . . . . . . . . 495

2

Water-Based Paint Formulations

A i r D r y o r F o r c e D r y Cure C l e a r Coatina-A

I n g r e d ien t s : Chempol 10-0094 28% Ammoni um H y d r o x i d e Water 5% C o b a l t Hydrocure 5% Manganese Hydrocure A c t i v-8

P a r t s b y Weiqht

57.11 3.00 38.89 0.40 0.40 0.20

A i r D r y o r F o r c e D r y Cure C l e a r C o a t i n a - 0 Inaredi ents : Chempol 10-0094 28% Ammonium H y d r o x i d e Water Hydrocure I 1 Hydrocem C a l c i u m Hydrocem Z i r c o n i u m

P a r t s by Weight

57.40 3.00 37.42 0.40 1.20 0.50

Method 0 y i e l d s a somewhat t o u g h e r f i l m s t h a n Method A .

SOURCE: Freeman Pol ymers D i v i s i on : CHEMPOL 10-0094: Formulas A i r D r y o r F o r c e D r y Cure C l e a r C o a t i n Q - 0

I n a r e d ie n t s : Chempol 10-0097 E t h y l e n e g l y c o l monobutyl e t h e r NH40H (28% m i n . ) Water 5% C o b a l t Hydrocure 5% Manganese Hydrocure A c t iv-8 Hydrocure I 1 Hydrochem C a l c i u m Hydrochem Z i r c o n i u m

SOURCE:

P a r t s by Wei a h t

54.05 3.80 3.40 36.65 0.00 0.00 0.00 0.40 1.20 0.50

Freeman Polymers D i v i s i o n : CHEMPOL 10-0097: Formula B

Coatings and Topcoats

A i r D r v o r F o r c e D r v C l e a r Coating-A

Chempol 10-0095 E t h y l e n e g l y c o l monobutyl e t h e r NH40H (28% m i n. ) Water 5% C o b a l t H y d r o c u r e 5% Manganese H y d r o c u r e Activ-8 Hydrocure I 1 Hydrochem Cal c i um Hydrochem Z i r c o n i um

P a r t s by W t . 53.30 3.90 3.00 38.00 0.95 0.55 0.40 0.00 0.00 0.00

A i r D r y o r F o r c e D r v C1e a r C o a t i n w B Chempol 10-0095 E t h y l e n e g l y c o l monobutyl e t h e r NH4OH (28% m i n. ) Water 5% C o b a l t H y d r o c u r e 5% Manganese H y d r o c u r e A c t i v-8 Hydrocure I 1 Hydrochem C a l c i um Hydrochem Z i r c o n i um

P a r t s by W t . 53.30 3.90 3.00 37.35 0.00 0.00 0.00 0.40 1.20 0.50

SOURCE: Freeman Polymers D i v i s i o n : CHEMPOL 10-0095:

Formulas

A i r o r Force D r y C l e a r Coatinn-A Chempol 10-0097 E t h y l e n e g l y c o l monobutyl e t h e r NH40H (28% m i n . ) Water 5% C o b a l t H y d r o c u r e 5% Manganese H y d r o c u r e A c t i v-8 Hydrocure I 1 Hydrochem C a l c i um Hydrochem Z i r c o n i um

P a r t s by W t . 54.15 3.80 3.40 36.75 0.95 0.55 0.40 0.00 0.00 0.00

SOURCE: Freeman Polymers D i v i s i o n : CHEMPOL 10-0097:

Formula

3

4

Water-Based Paint Formulations

A i r o r F o r c e D r y C l e a r C o a t i nq-A

Chempol 10-1210 E t h y l e n e g l y c o l monobutyl e t h e r NH40H (28% m i n . ) Water 5% C o b a l t H y d r o c u r e 5% Manganese H y d r o c u r e A c t i v-8 Hydrocure I 1 Hydrocem Cal c i um Hydrocem Z i r c o n i u m

P a r t s b y Weiqht 54.15 3.80

3.40 36.75 0.95 0.55 0.40 0.00 0.00 0.00

A i r o r F o r c e D r y C l e a r C o a t i ng-8 Chempol 10-1210 E t h y l e n e g l y c o l monobutyl e t h e r NH40H (28% m i n. ) Water 5% C o b a l t H y d r o c u r e 5% Manganese H y d r o c u r e A c t i v-8 Hydrocure I 1 Hydrocem Cal c i um Hydrocem Z i r c o n i um

SOURCE:

P a r t s b y Weiqht 54.05 3.80 3.40 36.65 0.00 0.00 0.00 0.40 1.20 0.50

Freeman Polymers D i v i s i o n : CHEMPOL 10-1210 F o r m u l a t i o n

Coatings and Topcoats

5

A1 kvd Topcoat Formula Mater ia1 s : A c r y l a t e d a l k y d (75% NVM) Ammonium h y d r o x i d e (28%) Deionized water C o b a l t d r i e r (6%) ( 1 ) Manganese d r i e r (6%) ( 1 ) Z i r c o n i u m d r i e r (12%) ( 1 ) A n t i - s k i n agent ( 2 ) D r i e r accelerator (3) Flow agent ( 4 ) Titanium dioxide (5) Water f o r a p p l i c a t i o n v i s c o s i t y

P a r t s by w e i n h t 259.3 9.9 509.9 1.6 1.6 1.6 0.9 0.4 0.4 155.6 58.8

P r o p e r t i es: Pigment/binder r a t i o : 0.8/1 . O pH: 8 . 0 - 8 . 5 N o n - v o l a t i l e m a t e r i a l (NVM), w t %: 35 V i s c o s i t y , #4 F o r d Cup, sec: 30-40 Dry t i m e s , ASTM D1640: s e t t o t o u c h , min: 10-20 d r y t h r o u g h , h r : 6-7 Compounding Procedure: 1 . S o l u b i 1 ize t h e a1 k y d w i t h ammonium h y d r o x i d e and d i l u t e w i t h water. 2. Add d r i e r s , a n t i - s k i n agent, d r i e r a c c e l e r a t o r and f l o w a g e n t . M i x t h o r o u g h l y and a d j u s t pH. 3. S t i r i n t i t a n i u m d i o x i d e . 4. G r i n d r e s u l t i n g p a s t e i n a b a l l m i l l o v e r n i g h t t o a Hegman Grind o f 7. 5 . A d j u s t g r i n d base w i t h a d d i t i o n a l w a t e r t o a p p l i c a t i o n v i scosi t y ( 1 ) Cyclodex d r i e r s ( 2 ) E x k i n #2 (3) A c t i v - 8 ( 4 ) FC-430 ( 5 ) T i - P u r e R-900

.

A l k y d t o p c o a t performance p r o p e r t i e s ( 1 , 2 ) : A i r d r y t i m e : 1 day: 60 G l o s s , %: 88 P e n c i l hardness: F C r o s s h a t c h a d h e s i o n : 58 C o n i c a l bend, % pass: 100 Impact r e s i s t a n c e , i n - l b : d i r e c t : 60 r e v e r s e : 10 Water s p o t r e s i s t a n c e , 1 h r : pass, no s o f t e n i n g o r d u l l i n g ( 1 ) S u b s t r a t e : B o n d e r i t e 37, t r e a t e d c o l d r o l l e d s t e e l ( 2 ) F i l m t h i c k n e s s : 1 . 0 t o 1.2 m i l s

SOURCE: Amoco Chemical Co.: Water-Borne A i r D r y i n g A l k y d s Based on AMOCO I P A and TMA: Formula T a b l e 10 and 11

6

Water-Based Paint Formulations

Aaueous Thermoset Topcoat M a t e r i a1 s 1. B e e t l e 65 2. Resimene 797 3. Methanol

4. L-7605 5. B u t y l C e l l o s o l v e 6. I s o p r o p y l A l c o h o l 7. E k t a s o l v e EP 8. AC-1024 9. Tego 1488 10. Water 1 1 . Chemcor Emu1s i on AS-35-3 12. Methanol 13. Nacure 155

Weight Pounds

Volume Gal l o n s

183.23 48.79 22.44 2.24 5.21 22.44 14.03 448.88 4.49 22.44 38.47 16.83 44.89

17.79 5.08 3.40 0.25 0.69 3.43 1.85 51.60 0.54 2.69 4.62 2.55 5.50

F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w e i g h t / v o l u m e ) : 56.5/52.0 VOC, g / l i t e r : 188 1b s / g a l 1on : 1 .56 Freeze/Thaw S t a b i l i t y : P r o t e c t f r o m F r e e z i n g

SOURCE:

Rohm and Haas Co.:

F o r m u l a t i o n KC-24-1 Sealer

Material

1. E-2955 (37 n v ) 2. Water 3. 14% Ammonia

Wei Qht Pounds

Volume Gal l o n s

528.2 211.3 11.1

61.6 25.4 1.3

Premix t h e above and add t h e f o l l o w i n g w i t h a g i t a t i o n :

4. B u t y l C a r b i t o l 5 . Butyl Cellosolve 6. I s o p r o p a n o l 7. Water ( e s t f o r v i s c )

4.2 25.4 29.7 26.4

F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w e i g h t / v o l ) : 23.4/21.7 pH: 7.8 V i s c o s i t y , #2 Zahn Seconds: 19 VOC, g / l i t e r : 235 l b s / g a l l o n : 1.96 Freeze/Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat Age S t a b i l i t y : S a t i s f a c t o r y F l a s h P o i n t , Tag c l o s e d cup F: 120 SOURCE: Rohm and Haas Co.:

F o r m u l a t i o n WR-55-1

0.5

3.4 4.5 3.2

Coatings and Topcoats

B l a c k Rust I n h i b i t i v e C o a t i n q

C a r g i l l Water R e d u c i b l e Epoxy E s t e r 73-7331 Aqueous Ammonia 28% Triethylamine E t h y l e n e G l y c o l Monobutyl E t h e r sec-Butanol S t r o d e x MOK-70 Special Black 4 Z i n c Phosphate 50852 I m s i l A-10 A e r o s i l R972 Byk-020 D e i o n i z e d Water

Pounds

Gal l o n s

96.0 5.7 1. o 9.6 14.4 6.0 12.5 51.3 16.3 2.9 1.9 212.8

11.36 0.76 0.17 1.28 2.14 0.63 0.85 1.92 0.74 0.16 0.26 25.57

192.0 9.6

22.72 1.28

9.6 14.4 1.o 2.5 2.1

1.28 2.14 0.13 0.32 0.24

172.8 1.o

20.74 0.13

43.2

5.18

Pebble M i l l t o a 6 Hegman C a r g i l l Water R e d u c i b l e Epoxy E s t e r 73-7331 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

E t h y l e n e G1 y c o l Monobutyl E t h e r sec-Butanol A c t iv-8 5% C o b a l t Hydro Cure I 1 Manganese Hydro Cure I 1 D e i o n i z e d Water E x k i n No.2 D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment) Pa n t P r o p e r t i e s : % N o n v o l a t i l e (By W e i g h t ) : 33.28 (By Volume): 27.07 Pigment t o U i n d e r R a t i o : 0.40 Pigment Volume C o n c e n t r a t i o n : 13.70 Weight Per G a l l o n : 8 . 7 9 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3.08 ( G r a m s / L i t e r ) : 370 W a t e r : C o s o l v e n t Weight R a t i o : 75.00:25.00 pH: 8.2-8.7 V i s c o s i t y Krebs-Stormer (KU): 65-70 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1807-F2

7

8

Water-Based Paint Formulations

Chrome Y e l l o w Topcoat M a t e r i a1 : Kel s o l 3962-826-70 Water Ammoni urn H y d r o x i d e C o b a l t Hydrocure I 1 A c t iv-8 Manganese Hydrocure I 1 Propasol P T i - P u r e R-902 Mapico Y e l l o w 1 0 5 0 A Medium Chrome Y e l l o w X2035 S t r o n t i u m Chromate 5-1365 S t e e l b a l l m i l l t o a 7 Hegman g r i n d . Letdown : Kel s o l 3962-826-70 Water Ammonium H y d r o x i d e Butoxy E t h a n o l

Lbs. 90.29 210.50 4.41 3.40 1.53 2.87 2.42 65.27 21.26 86.77 12.64

Gals. 10.45 25.27 0.59 0.45 0.18 0.39 0.33 1.96 0.63 1.85 0.40

168.57 277.64 3.66 31.32

19.51 33.33 0.49 4.17

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 36.66 P i g m e n t / B i n d e r R a t i o : 2.24/1 P e r c e n t Sol i d s , Wei g h t : 39.63 P e r c e n t S o l i d s , Volume: 23.95 V i s c o s i t y C 25C. #4 F o r d , Secs.: 40-50 Pounds/Gallon: 10.42 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 286 Pounds/Gallon: 2.38

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2349-42A

Inc.:

Waterborne Handbook:

Coatings and Topcoats

C l e a r B u i l d Coat Based on Rhoolex CL-103 E m u l s i o n f o r A i r - D r y o r Low-Force-Dry A o o l i c a t i o n M a t e r i a1 s Rhoplex CL-103 e m u l s i o n Dee Fo 3000

Weight Pounds 704.3 1.8

Vol ume Gal 1ons 81.7 0.3

57.1 28.5 20.8

7.1 3.9

Premix and add under a g i t a t i o n : B u t y l Carbi t o 1 B u t y l Propasol Water

2.5

Add : 14% Ammonia 1.6 0.2 ( A d j u s t v i s c o s i t y w i t h w a t e r t o a r a n g e o f 20 t o 26 seconds on a #2 Zahn c u p ) Water 36.3 4.3 Formulation Constants: Approximate s o l i d s , % ( w t / v o l ) : 33.8/31.7 pH: 7.5-8.0 V i s c o s i t y , #2 Zahn cup, seconds: 20 t o 26 VOC, g / l i t e r : 240 lb/gallon: 2.0 C o a l e s c e n t , w t % on p o l y m e r s o l i d s : B u t y l P r o p a s o l : 10 B u t y l C a r b i t o l : 20 Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes Freeze/thaw s t a b i l i t y : P r o t e c t from f r e e z i n g

SOURCE:

Rohm and Haas Co.: RHOPLEX CL-103 A c r y l i c E m u l s i o n : F o r m u l a t i o n KC-53-4

9

10

Water-Based Paint Formulations

Clear,

B u i l d Coat Based on Rhoplex CL-104 A c r y l i c Emulsion

Materials: Rhoplex CL-104 e m u l s i o n Dee Fo 3000

Weight Pounds 718.1 1.7

Volume Gal l o n s 63.3 0.2

55.3 27.6 20.8

7.0 3.8 2.5

Premix and add under a g i t a t i o n : B u t y l Carbi t o 1 B u t y l Propasol Water Add : 14% Ammoni a 1.5 0.2 ( a d j u s t v i s c o s i t y w i t h w a t e r t o a r a n g e o f 20 t o 26 seconds on a #2 Zahn cup) Water 25.3 3.0 F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w t / v o l ) : 32.7/31.0 pH: 7.5-8.0 V i s c o s i t y , #2 Zahn cup, seconds: 20 t o 26 VOC, g / l i t e r : 237 l b / g a l l o n : 1.98 Coalescent, w t % on polymer s o l i d s : B u t y l C a r b i t o l : 20 B u t y l Propasol : 10 Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes

SOURCE:

Rohm and Haas Co.: RHOPLEX CL-104 A c r y l i c Emulsion: F o r m u l a t i o n WR-74-6

Coatings and Topcoats

C l e a r C o a t i ng Pounds

Gal l o n s

C a r g i 11 Water R e d u c i b l e Sel f Cross1 in k i ng R e s i n 73-7390 D i e t h y l e n e G l y c o l Monobutyl E t h e r D i m e t h y l e t h a n o l ami ne Ammonium H y d r o x i d e 28% P a t c o t e 577 Byk-301

345.9 1.5 12.3 8.2 3.6 3.7

40.61 0.18 1.67 1.10 0.53 0.45

Dei o n i zed Water

461.9

55.46

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 29.26 (By Volume): 27.11 Weight Per G a l l o n : 8 . 3 7 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 8 4 ( G r a m s / L i t e r ) : 340 W a t e r : C o s o l v e n t Weight R a t i o : 79.00:21. 00 pH: 8 . 5 0 V i s c o s i t y Krebs-Stormer ( K U ) : 66 T y p i c a l Cured F i 1m P r o p e r t i es : Cure Schedule: 10 M i n u t e s a t 325F Substrate: Cold Rolled Steel P e n c i l Hardness: Pass HB % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 160 Reverse: 160

SOURCE:

Cargill,

I n c . : CARGILL F o r m u l a r y : Formul a P1887-828

11

12

Water-Based Paint Formulations

C l e a r C o a t i n e f o r Wood and C o n c r e t e

Lbs/100 Gal 72.52 23.25 4.65 9.30 1 .86 71.59 496.51

Inqredient E k t a s o l v e EP S a n t i c i z e r 160 S u r f y n o l 104H D i e t h y l ami ne Drew L-475 Water P l i o l i t e 7104 (44% s o l i d ) M i x w e l l , t h e n add: Witcobond 234 ( P o l y u r e t h a n e )

169.22

Dry t o t o u c h : 15-20 m i n u t e s 60 degree G l o s s ( 2 c o a t s on wood): 80-85% I s o p r o p y l a l c o h o l s p o t t e s t : Pass 81 u s h i ng r e s i s t a n c e : Good V i s c o s i t y : 15-25 seconds, No. 4 F o r d Cup Age Panel 7 days b e f o r e t e s t i n g S.G.: 1.02 Lb/Gal : 8.49 VOC: 3.41 l b / g a l l o n (402 g r a m / l i t r e ) SOURCE: The Goodyear T i r e & Rubber Co.:

Formula 12084-22-90

Coatings and Topcoats

13

C l e a r S a t i n (-40 a l o s s a t 6 0 ) T h e r m o s e t t i n g Sealer/Topcoat Based on Rhoplex AC-1024 Materials: Part A: Add w h i l e m i x i n g : B e e t l e 65 Methanol S i l w e t L-77 Dehydran 1293

Pounds

Gal l o n s

179.94 17.63 2.64 3.52

17.47 2.67 0.32 0.47

Premix and add: Water S y l o i d 169

28.21 7.05

3.39 0.42

Add t o above: Rhopl ex AC-1024 Water Exxate 600

352.66 40.91 10.58

40.54 4.91 1.45

Add s l o w l y i n o r d e r : A c r y s o l RM-825 r h e o l o g y m o d i f i e r 17.63 2.03 Chemcor wax emulsion AS-35-3 30.22 3.63 ( a d j u s t v i s c o s i t y w i t h water t o a range o f 35+-5 seconds on a #2 Zahn cup) Water 99.79 11 - 9 7 P e r t B: Premix and add s l o w l y : Methanol Nacure 155

42.32 35.27

6.41 4.32

Formul a t ion Constants : PVC: 1.14 Approximate s o l i d s , % ( w t / v o l ) : 46.1/41.6 pH, p a r t A : 6.5 3 B combined: 1 . 4 pH, p a r t s A i V i s c o s i t y , p a r t A , #2 Zahn cup, seconds: 35+-5 V i s c o s i t y , p a r t s A & B combined, #2 Zahn cup, seconds:

voc :

20

g/L, t h e o r e t i c a l : 203 g/L, a c t u a l , p e r ASTM D-2369: 350 Heat-age s t a b i l i t y , 140F f o r 10 days: Passes Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g

SOURCE:

Rohm and Haas Co.: KC-24-2

RHOPLEX AC-1024 Emulsion:

Formulation

14

Water-Based Paint Formulations

C o a t i n~ M a t e r i a1 s: P a r t s by w e i g h t WB-138 d i s p e r s i o n (49% NVM) 439.5 D i m e t h y l ethanolami ne 5.7 Dei o n i zed w a t e r 284.8 Melamine ( 1 ) 53.7 Flow a d d i t i v e ( 2 ) 1.5 Titanium d i o x i d e (3) 214.8 P r o p e r t ies : Pigment/binder r a t i o : 0.8/1.0 Resin/melamine r a t i o : 80/20 W a t e r / c o s o l v e n t r a t i o : 95/5 N o n - v o l a t i l e m a t e r i a l (NVM), w t % : 4 8 . 9 V i s c o s i t y , Zahn #2, sec: 25 Weight p e r g a l l o n , l b : 10.53 VOC ( c a l c u l a t e d ) , 1b / g a l : 1 . 4 pH: 8.15 Compounding p r o c e d u r e f o r WB-138 c o a t i n g : 1 . A d j u s t pH o f t h e r e s i n d i s p e r s i o n to 7.5-8.0 w i t h a d i m e t h y l e t h a n o l a m i n e and d e i o n i z e d w a t e r m i x t u r e i n a 5:95 ratio. 2. Charge t h e r e s i n d i s p e r s on, melamine, f l o w a d d i t i v e and pigment t o a p e b b l e m i l l R o l l o v e r n i g h t t o a Hegman G r i n d o f 7+. 3. D i s c h a r g e m i l l and a d j u s pH t o 8 . 0 and Zahn #2 v i s c o s i t y to 25 seconds. ( 1 ) Cyme1 303 ( 2 ) FC-430 (33% NVM i n p r o p y l e n e g l y c o l m e t h y l e t h e r a c e t a t e ) ( 3 ) T i - P u r e R-900 Performance P r o p e r t i e s o f WB-130 c o a t i n g ( 1 ) : I n i t i a l : CRS ( 2 ) : F i l m thickness, m i l s : 1.2 60 g l o s s , %: 93 P e n c i l hardness ( n o c u t ) : 3H Impact r e s i s t a n c e , i n - l b : d i r e c t : 150 r e v e r s e : 110 C o n i c a l bend, % p a s s : 100 C r o s s h a t c h a d h e s i o n : 58 Double MEK r u b s , passed: 100+ 8-37(3) : F i l m thickness, m i l s : 1.3 60 g l o s s , %: 91 P e n c i l hardness ( n o c u t ) : 3H Impact r e s i s t a n c e , i n - l b : d i r e c t : 160 r e v e r s e : 120 C o n i c a l bend, % pass: 100 C r o s s h a t c h adhesion: 50 Double MEK r u b s , passed: 100+ ( 1 ) Cure c y c l e : 5 m i n u t e s f l a s h p l u s 20 m i n u t e s a t 177C (2) Cold r o l l e d s t e e l ( 3 ) B o n d e r i t e 37 t r e a t e d c o l d r o l l e d s t e e l SOURCE: Amoco Chemical Co.: Water-Borne Bake P o l y e s t e r s Based on AMOCO IPA and TMA: Formula T a b l e 7 and B

Coatings and Topcoats

C u r t a i n C o a t a b l e 35 PVC Topcoat F o r m u l a t i o n Pounds 30.0 6.0 91 .o 277.0 23.0 1.o 65.0

M a t e r i a1 s : A c r y s o l 1-62 (22.7%)* B a l a b 3046A T i 0 2 , T i - P u r e R-960 Minex 4 Cr203 Green Bentone LT Water G r i n d a t h i g h speed,

Gallons 3.45 0.95 2.75 12.77 0.54 0.07 7.80

t h e n l e t down as f o l l o w s :

Rhoplex AC-1822 (46%) Cyme1 373 (85%) E t h y l e n e G l y c o l Monobutyl E t h e r (60%) S u r f y n o l 104E**

563.0 33.9 48.0 0.5

63.90 3.20 6.16

----

A d j u s t pH t o 9 . 0 w i t h DMAE. Topcoat C o n s t a n t s : pvc: 35% V i s c o s i t y ( # 4 F o r d Cup): Weight S o l i d s : 60% Volume S o l i d s : 46% T i 0 2 / B i nder : 24/76

*

**

24 seconds

A c r y s o l 1-62 N e u t r a l i z a t i o n : A c r y s o l 1-62 (50%) 40.0 40.0 Water DMAE (50%) 8.0

For c u r t a i n coater application.

SOURCE: Rohm and Haas Co.:

B u i l d i n g P r o d u c t s : ACRYSOL 1-62: F o r m u l a t i o n T a b l e 11

15

16

Water-Based Paint Formulations

C u r t a i n C o a t a b l e 35 PVC Topcoat F o r n u l a t i on Materials: A c r y s o l 1-62 (50%) Water premix Dimethylaminoethanol/ Water, 1 / 1 B a l a b 3046A T i 0 2 , T i - P u r e R-960 Minex 4 Cr203 Green Bentone LT Water G r i n d a t h i g h speed,

Pounds 13.4 13.4 2.7

Gal l o n s 3.40

5.9 89.6 273.7 22.6

0.94 2.71 12.57 0.53 0.07 7.68

1.o

64.0

t h e n l e t d o w n as f o l l o w s :

Rhoplex AC-1822 (46%) Cyme1 373 (85%) E t h y l e n e G l y c o l Monobutyl E t h e r (60%) S u r f y n o l 104E*

554.2 33.4 47.2 0.5

62.90 3.15 6.06

----

A d j u s t pH t o 9 . 0 w i t h DMAE. Topcoat C o n s t a n t s : PVC: 35% V i s c o s i t y ( # 4 F o r d Cup): Weight S o l i d s : 60% Volume S o l i d s : 46% T i O P / B i n d e r : 24/76

*

24 seconds

For c u r t a i n c o a t e r a p p l i c a t i o n

SOURCE:

Rohm and Haas Co.:

B u i l d i n g P r o d u c t s : A c r y s o l 1-62: Formulation Table I1

Coatings and Topcoats

C u r t a i n C o a t a b l e 35 PVC Topcoat Formul a t i on Pounds 30.0 6.0 91 . o 277.0 23.0 1.o 65.0

M a t e r ia1 s : A c r y s o l 1-62 ( 2 2 . 7 % ) B a l a b 3046A T i 0 2 , T i - P u r e R-960 Minex 4 Cr203 Green (X-1134CP) Bentone LT Water

*

Gal 1ons 3.45 0.95 2.75 12.77 0.54 0.07 7.00

G r i n d a t h i g h speed t h e n l e t down as f o l l o w s : 563.0 33.9 40.0 0.5

Rhoplex AC-1822 (46%) Cyme1 373 (85%) B u t y l C e l l os01 ve (60%) S u r f y n o l 104E**

63.90 3.20 6.16

-----

A d j u s t pH t o 9 . 0 w i t h DMAE. Topcoat C o n s t a n t s : PVC: 35% V i s c o s i t y ( # 4 F o r d Cup): Weight S o l i d s : 60% Volume S o l i d s : 46% T i O 2 / 0 i n d e r : 24/76

*

**

24 seconds

N e u t r a l i z a t i o n o f A c r y s o l 1-62: A c r y s o l 1-62 (50%) Water DMAE (50%) For c u r t a i n c o a t e r a p p l i c a t i o n

40.0 40.0

8.0

SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s Board C o a t i n g s : RHOPLEX AC-1822: F o r m u l a t i o n T a b l e I11

17

18

Water-Based Paint Formulations

Experimental Coatina:

Spray

Materials:

Sol u b i 1 ized r e s i n ( 1 )

680.3 26.1 208.6 3.9 81.1

Melamine ( 2 ) Titanium Dioxide (3) Flow Agent ( 4 ) Water ( d i s t i l l e d ) Resin/Melamine R a t i o : 90/10 Pigment/Binder R a t i o : . 8 / 1 . 0 pH: 8.38 NVM, %: 4 7 . 1 V i s c o s i t y , #4 F o r d Cup, s e c . :

37

1. S o l u b i l i z e d R e s i n Composition: Polymer ( R e s i n BAL-389) Diethylene glycol b u t y l ether D i m e t h y l ami n o e t h a n o l Water NVM = 34.5% pH = 8 . 0 - 8 . 5

700 300 29 1000

2. Cyme1 303 3. T i - P u r e R-900 4 . FC-430 Performance P r o p e r t i e s : CRS ( 1 ) : Cure C y c l e 10 min/l8OF p l u s 20 min/350F F i l m Thickness, m i l s : 1.1 Sward Hardness: 44 P e n c i l Hardness: H C r o s s h a t c h Adhesion, % pass: 100 Impact R e s i s t a n c e , i n - l b : D i r e c t : 160 Reverse: 160 C o n i c a l Bend, % pass: 100 8-37 ( 2 ) : Cure C y c l e 10 m i n / l 8 0 F p l u s 20 min/350F F i l m Thickness, m i l s : 1.5 Sward Hardness: 54 P e n c i l Hardness: H C r o s s h a t c h Adhesion, % pass: 100 Impact R e s i s t a n c e , in-1 b . : D i r e c t : 160 Reverse: 160 C o n i c a l Bend, % pass: 100 1 . CRS: C o l d r o l l e d s t e e l B o n d e r i t e 37 t r e a t e d c o l d r o l l e d s t e e l

2. 8-37:

SOURCE: Amoco Chemical Co.: R e s i n BAL-389, Water Borne P o l y e s t e r f o r C o i l and Spray A p p l i e d F l e x i b l e C o a t i n g s : C o a t i n g No. 6265-1 24

Coatings and Topcoats

F l a t Topcoat Based on E x p e r i m e n t a l Emu1s i on E-2955 Materials: E x p e r i m e n t a l emu1 s i o n E-2955 Dow 65 Water

Weight Pounds 692.9 0.6 25.0

Volume Gallons 79.6 0.1 3.0

Mix above t h e n add s l o w l y w i t h good a g i t a t i o n : TS-100 14% ammonia t o a d j u s t pH t o 8 . 5 Premix and add s l o w l y under a g i t a t i o n : Butyl Cellosolve E k t a s o l v e EEH I s o p r o p a n o l (15%)

25.6

1.4

33.3 5.1 38.5

4.4 0.7 5.9

40.8

4.9

Add : Water 7% ammonia t o a d j u s t pH between 7.5-8.0

F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w t / v o l ) : 32.8/29.2 pH: 7.5-8.0 F l a s h p o i n t , c l o s e d cup, F: 125 VOC, g / l i t e r : 156 l b / g a l l o n : 1.3 C o a l e s c e n t , w t % on polymer s o l i d s : B u t y l C e l l o s o l v e : 13 E k t a s o l v e EEH: 2 Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes

SOURCE: Rohm and Haas Co.: E x p e r i m e n t a l Emulsion E-2955: F o r m u l a t i o n WR-55-4

19

20

Water -&sed

Point Formulations

F o r c e D r y W h i t e H i g h G l o s s TOP Coat DiD/Spray Diethylamine E k t a s o l v e EP S u r f y n o l 104H Drew L-475 DSX 1550 Water P l i o l i t e 7104

Lbs/100 Gal 14.12 56.50 5.04 4.03 10.00 76.67 66.59

M i x w e l l t h e n add: T i 0 2 R-900 H i g h Speed t o 7+ N S

238.10

Follow w i t h : P l i o l i t e 7104 E k t a s o l v e EP S a n t i c i z e r 160 Texanol 10% Ammonium Benzoate

463.08 30.27 24.21 11.10 20.18

F o r c e d r y : 20 min. a t 180 deg F N . V . V . : 35.6% T . N . V . : 48% Pigment/binder r a t i o : 1 : l W.P.G.: 10.07 Sp. G r . : 1 . 2 1 G l o s s 80-85% a t 1.5 m i l , 60 deg V i s c : 60-65 sec #4 F o r d A d j u s t v i s c . a s needed w i t h w a t e r f o r d i p a p p l i c a t i o n V . O . C . : 2.34 l b s / g a l (276 g r a m / l i t r e ) pH: 9 . 0 - 9 . 5 SOURCE: The Goodyear T i r e & Rubber Co.:

Formula #2064-30-90

Coatings and Topcoats

21

G l o s s B l a c k ToDcoat f o r Brush and R o l l e r AgplicatPounds Ingredient. 49.5 Water 50.0 Methyl Carbi t o 1 609.4 Mai n c o t e HG-54 38.0 Texanol 5.0 Foamaster AP 18.3 Chrom-Chem (896-9901) Lampblack 73.8 W a t e r / A c r y s o l RM-1020, t o a d j u s t to 85 KU

NH40H (28% NH3) Sodium N i t r i t e (15% aqueous s o l u t i o n )

3.5 6.6

Gal 1 ons

5.94 5.80 70.99 4.80 0.65 1.76 8.85 0.42 0.79

F o r m u l a t i o n Constants: Pigment Volume C o n t e n t , %: 2.6 Volume S o l i d s . %: 28.8 pH: 9.2 Stormer V i s c o s i t y , Kreb U n i t s : 85 I C 1 V i s c o s i t y , p o i s e : 1.5 VOC, g m / l i t e r : 235 G l o s s (60/20): 90/75

SOURCE: Rohm and Haas Co.: Maintenance C o a t i n g s : MAINCOTE HG-54: F o r m u l a t i o n GD-54-3

22

Water -Based Paint Formulations

G l o s s B l a c k Toocoat f o r Brush and R o l l e r A D D l i c a t i o n In n r e d ien:t s Pounds Water 49.5 Methyl Carbi t o 1 50.0 Mai n c o t e HG-54 609.4 Texanol 38.0 Foamaster AP 5.0 Chrom-Chem (896-9901) Lampblack 18.3 W a t e r / A c r y s o l RM-1020, t o a d j u s t t o 85 K U 73.8

NH40H (28% NH3) Sodium N i t r i t e (15% aqueous s o l u t i o n )

3.5 6.6

Gal l o n s

5.94 5.80 70.99 4.80 0.65 1.76 8.85 0.42 0.79

Formulation Constants: Pigment Volume C o n t e n t , %: 2.6 Volume S o l i d s , % : 28.8 pn: 9.2 Stormer V i s c o s i t y , Krebs U n i t s : 85 I C 1 V i s c o s i t y , p o i s e : 1.5 VOC, g m / l i t e r : 235 G l o s s (60/20): 90/75

SOURCE:

Rohm

and Haas Co.: Maintenance C o a t i n g s : MAINCOTE HG-54: F o r m u l a t i o n GD-54-3

Coatings and Topcoats

Gloss Green A c r v l i c / E D o x y Toocoat Pounds M a t e r i a 1s : Gallons A c r y l i c Component A : Grind Preparation: G r i n d t h e f o l l o w i n g m a t e r i a l s u s i n g a h i g h speed d i s s o l v e r f o r 20 m i n u t e s : Methyl Carbi t o 1 45.0 5.22 Tamol 165 3.9 0.44 T r i t o n CF-10 0.6 0.07 0.07 P a t c o t e 519 0.5 Chrome o x i d e green, X-1134 81.4 1.91 Letdown p r e p a r a t i o n : Add t h e f o l l o w i n g i n t h e o r d e r l i s t e d and m i x t h o r o u g h l y : Mai n c o t e AE-58 543.4 63.15 NH40H (28% NH3) 1.2 0.16 Water 64.7 7.76 G r i n d ( f r o m above) 131.4 7.71 E k t a s o l v e EEH 53.1 7.16 P a t c o t e 531 2.0 0.28 A c r y s o l RM-1020 (20%) 9.6 1.08 Sodium N i t r i t e (15%) 9.0 1.08 Epoxy Component B: Genepoxy 370-H55 (55%)

104.7

11.62

Topcoat F o r m u l a t i o n C o n s t a n t s : Pigment Volume C o n t e n t , %: 5 . 7 Volume S o l i d s , %: 33.5 VOC, g m / l : 250 G l o s s , 60/20: 70/30 Component A F o r m u l a t i o n C o n s t a n t s : pH: 8 . 5 Stormer V i s c o s i t y , Kreb U n i t s : 85 I C 1 V i s c o s i t y , p o i s e : 0.9

SOURCE: Rohm and Haas C o . : Maintenance C o a t i n g s : MAINCOTE AE-58: F o r m u l a t i o n G-58-2

23

24

Water-Based Paint Formulatiori

Gloss M i d t o n e T i n t Base A c r y l i c / E p o x y Topcoat Materials: Pounds Gal l o n s A c r y l i c Component A : G r ind P r e p a r a t ion : G r i n d t h e f o l l o w i n g m a t e r i a l s u s i n g a h i g h speed d i s s o l v e r f o r 20 m i n u t e s : Methyl Carbi t o 1 11.0 1.27 0.44 Tamol 165 3.9

NH40H (28% NH3) T r i t o n CF-10 P a t c o t e 519 T i P u r e R-900 Water

1 .o 0.4 0.4 54.8 5.2

0.12 0.05 0.06 1.60 0.63

Letdown P r e p a r a t i o n : Add t h e f o l l o w i n g i n t h e o r d e r l i s t e d and m i x t h o r o u g h l y : Mai n c o t e AE-58 462.8 53.81 Water 60.0 7.20 NH40H (28% NH3) 4.7 0.63 76.7 4.17 G r i n d ( f r o m above) 27.8 3.23 Methyl Carbi t o 1 ) 45.2 6.10 E k t a s o l v e EEH ) premix 2.0 0.28 P a t c o t e 531 ) A c r y s o l RM-1020 25.0 2.82 Water 89.8 10.77 Sodium n i t r i t e (15% aqueous s o l u t i o n ) 9.0 1.08 Epoxy Component 8 : Genepoxy 370-H55 (55%) Topcoat F o r m u l a t i o n C o n s t a n t s : Pigment Volume C o n t e n t , %: 5.6 Volume S o l i d s , %: 28.5 VOC, gm/l : 225 G l o s s , 60/20: 89/79 Component A F o r m u l a t i o n C o n s t a n t s : W i t h 8 o z / g a l o f Chroma Chem 896-5501 p h t h a l o green PH Stormer V i s c o s i t y , Krebs U n i t s IC1 V i scosi t y , p o i s e

89.5

9.91

No

Yes

8.7

8.4 78 1.2

94 1.5

SOURCE: Rohm and Haas Co.: Maintenance C o a t i n g s : MAINCOTE AE-58: F o r m u l a t i o n M-58-1

Coatings and Topcoats

25

Gloss Topcoat

M a t e r i a1 s: Propylene g l y c o l Tamol SG-1 Water T r i t o n X-100 AMP-95 Nopco NDW T i t a n i um d i o x i d e (Zopaque RCL-9) Zinc oxide

P a r t s Per Weight Hundred R a t i o * ( V o l ume Basi sl 60.0 6.98 7.9 0.87 5.1 0.62 2.5 0.28 3.2 0.42 1.o 0.13 250.0 7.30 25.0 0.54

G r i n d t h e above m a t e r i a l s i n a high-speed m i l l f o r 20 m i n u t e s and l e t d o w n . Water Rhoplex AC-507 ( 4 6 . 5 % ) Texanol Propylene g l y c o l Skane M-8 Nopco NDW W a t e r / N a t r o s o l 250 MR (2.5%)

30.0 546.7 25.0 38.0 2.0 1.o 74.2

3.60 62.38 3.16 4.42 0.23 0.13 8.94

Formulation Properties: Pigment Volume C o n t e n t , %: 2 2 . 5 Volume S o l i d s , %: 3 4 . 8 I n i t i a l v i s c o s i t y , KU: 70 t o 74 I n i t i a l pH: 9 . 0 t o 9 . 2

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t ; u s i n g k i l o g r a m s , about 833 l i t e r s w i l l result.

SOURCE: Rohm and Haas Co.: Maintenance and M a r i n e C o a t i n g s : RHOPLEX A c r y l i c Emulsions f o r L a t e x Maintenance C o a t i n g s : F o r m u l a t i o n G-07-7

26

Water-Based Paint Formulations

G l o s s Topcoat Based on E x p e r i m e n t a l Emulsion E-2955 Materials: E x p e r i m e n t a l e m u l s i o n E-2955 Water

Weight Pounds 659.9 22.0

Volume Gal l o n s 76.9 2.6

M i x above t h e n add s l o w l y w i t h good a g i t a t i o n : 14% ammonia t o a d j u s t pH t o 8 . 5 Premix and add s l o w l y under a g i t a t i o n : B u t y l C e l l os01 ve E k t a s o l v e EEH I s o p r o p a n o l (15%)

31.7 4.0 36.5

4.2 0.6 5.5

24.6 21.1 32.5

3.7 2.5 3.9

Add : Dow C o r n i n g #14 Michem Emulsion 39235 Water 7% Ammonia t o a d j u s t pH between 7 . 5 - 8 . 0

F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w t / v o l ) : 3 0 . 5 / 2 7 . 9 pH: 7.5-8.0 F l a s h p o i n t , c l o s e d cup, F: 120 VOC, g / l i t e r : 218 l b / g a l l o n : 1.85 C o a l e s c e n t , w t % on polymer s o l i d s : B u t y l C e l l o s o l v e : 13 E k t a s o l v e EEH: 2 Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes

SOURCE: Rohm and Haas Co. : E x p e r i m e n t a l Emulsion E-2955: F o r m u l a t i o n WR-55-3

Coatings and Topcoats

27

Gloss White Acrvlic/Epoxy Topcoat M a t e r ia 1 s : _ Pounds _ _ _Gal _1ons _ A c r y l i c Component A: Grind Preparation: G r i n d t h e f o l l o w i n g m a t e r i a l s u s i n g a h i g h speed d i s s o l v e r f o r 20 m i n u t e s : 38.8 4.50 Methyl Carbi t o 1 Tamol 165 13.8 1.57 NH40H (28% NH3) 1. o 0.12 T r i t o n CF-10 1.6 0.19 P a t c o t e 519 0.4 0.06 T i P u r e R-900 193.7 5.66 Add t h e f o l l o w i n g and c o n t i n u e t o g r i n d f o r 2-3 m i n u t e s a t l o w e r speed : Water 19.9 2.39 Letdown P r e p a r a t i o n : Add t h e f o l l o w i n g i n t h e o r d e r l i s t e d and mix t h o r o u g h l y : Mai n c o t e AE-58 493.0 57.25 Water 58.5 7.00 NH40H (28% NH3) 2.4 0.29 G r i n d ( f r o m above) 269.2 14.49 E k t a s o l v e EEH 48.2 6.50 P a t c o t e 531 2.0 0.28 Water 14.2 1.71 A c r y s o l RM-1020 8.0 0.90 Sodium N i t r i t e (15% aqueous s o l u t i o n ) 8.8 1.06 Epoxy Component 8 : Genepoxy 370-H55

94.0

10.52

Topcoat F o r m u l a t i o n C o n s t a n t s : Pigment Volume C o n t e n t , %: 1 6 . 5 Volume S o l i d s , %: 34.0 VOC, g m / l : 230 G l o s s , 60/20: 80/45 Component A F o r m u l a t i o n C o n s t a n t s : pH: 8 . 5 Stormer V i s c o s i t y , Krebs U n i t s : 75 I C 1 V i s c o s i t y , p o i s e : 0.8

SOURCE: Rohm and Haas Co.: Maintenance C o a t i n g s : MAINCOTE A € - 5 8 : F o r m u l a t i o n 6-58-1

28

Water-Based Paint Formulations

G l o s s W h i t e A c r y l i c / E p o x y Topcoat m t e r i a1 s : Gallons Pounds A c r v l ic Comoonent A : G r i Ad P r e p a k a t ion : G r i n d t h e f o l l o w i n g m a t e r i a l s u s i n g a h i g h speed d i s s o l v e r f o r 20 m i n u t e s : 4.50 Methyl Carbi t o 1 38.8 1.57 Tamol 165 13.8 0.12 NH40H (28% NH3) 1 .o 0.19 T r i t o n CF-10 1.6 0.06 P a t c o t e 519 0.4 5.66 T i P u r e R-900 193.7 Add t h e f o l l o w i n g and c o n t i n u e t o g r i n d f o r 2-3 m i n u t e s a t l o w e r speed: Water 19.9 2.39 Letdown P r e p a r a t i o n : Add t h e f o l l o w i n g i n t h e o r d e r l i s t e d and m i x t h o r o u g h l y : M a i n c o t e AE-58 461 .O 53.62 Water 45.8 5.50 NH40H (28%/NH3) 1.8 0.22 G r i n d ( f r o m above) 269.2 14.49 Texanol 29.4 3.91 P a t c o t e 531 2.0 0.28 Sodium N i t r i t e (15% aqueous s o l u t i o n ) 9.0 1.08 A c r y s o l RM-1020 8.8 1 .oo Epoxy Component B: Epi -Rez WJ-3520 (55%) Water A c r y s o l RM-1020

125.5 47.1 5.6

13.81 5.66 0.62

Topcoat F o r m u l a t i o n C o n s t a n t s : Pigment Volume C o n t e n t , %: 1 6 . 5 Volume S o l i d s , %: 3 4 . 3 VOC, g m / l : 196 G l o s s , 60/20: 79/37 Component A F o r m u l a t i o n C o n s t a n t s : pH: 8 . 5 Stormer V i s c o s i t y , Kreb U n i t s : 76 I C 1 Viscosity, poise: 1 . O SOURCE: Rohm and Haas Co.: F o r m u l a t i o n 6-58-4

M a i n t e n a n c e C o a t i n g s : MAINCOTE A€-58:

Coatings and Topcoats

29

G l o s s W h i t e Topcoat f o r B r u s h and R o l l e r A p p l i c a t i o n Pounds Gal 1ons Inaredients: G r i nd P r e p a r a t i o n : G r i n d i n Cowles D i s s o l v e r 15 m i n u t e s . Then l e t down a t s l o w e r speed. 300.0 34.95 Mai n c o t e HG-54 0.92 8.4 Tamol 681 0.12 1. o NH40H (28% NH3) 0.23 2.0 T r i t o n CF-10 0.14 1.o Drew L-405 5.70 195.0 T i - P u r e R-900 HG A l l o w p i g m e n t t o wet t h o r o u g h l y , t h e n add: 0.45 4.0 A c r y s o l RM-1020 Letdown P r e p a r a t i o n : Water Methyl C a r b i t o l Mai n c o t e HG-54 Texanol Drew Y-250 NH4OH (28% NH3) Sodium N i t r i t e (15% Aqueous Sol u t i on ) A c r y s o l RM-1020

38.8 59.0 332.6 39.4 2.5 4.0 9.0 14.0

4.65 6.83 38.75 4.98 0.35 0.48 1.08 1.63

F o r m u l a t i o n Constants: Pigment Volume C o n t e n t , %: 16.3 Volume S o l i d s , %: 3 4 . 5 pH: 9 . 1 S t o r m e r V i s c o s i t y , Krebs U n i t s : 90 IC1 V i s c o s i t y , p o i s e : 1 . 8 VOC, g m / l i t e r : 250 G1oss (60/20) : 75/40 To i m p r o v e f l o w , i f d e s i r a b l e , w i t h 1/2 p t . w a t e r p e r g a l l o n . SOURCE: Rohm and Haas Co.: F o r m u l a t i o n G-54-3

d i l u t e t h i s formulation

Maintenance C o a t i n g s : MAINCOTE HG-54:

30

Water-Based Paint Formulations

H i g h B u i l d G l o s s W h i t e Topcoat f o r A i r l e s s Sprav A p p l i c a t i o n Inqredients : .~ Pounds Gal l o n s Grind Preparation: G r i n d i n Cowles D i s s o l v e r 15 m i n u t e s . Then l e t down a t s l o w e r speed. Mai n c o t e HG-54 400.0 46.60 Tamol 681 9.1 1 .oo

NH40H (28% NH3) Drew L-405 T i - P u r e R-900 HG A l l o w pigment t o wet t h o r o u g h l y , t h e n add: Rheology Modi f ie r OR-708

1 .o 2.4 127.6

0.12 0.34 3.70

0.5

0.06

318.5 44.7 3.5 4.0 8.2 29.0 0.5

37.10 5.63 0.46 0.48 0.98 3.48 0.06

Letdown P r e p a r a t i o n : Mai n c o t e HG-54 Texanol Drew Y-250

NH40H (28% NH3) Sodium N i t r i t e (15% Aqueous S o l u t i o n ) Water Rheology Modi f ie r OR-708 Formulation Constants: Pigment Volume C o n t e n t , %: 10.0 Volume S o l i d s , %: 37.0 pH: 9.2 Stormer V i s c o s i t y , Kreb U n i t s : 100 IC1 V i s c o s i t y , p o i s e : 0.4 VOC, g m / l i t e r : 124 G l o s s (60/20): 79/31

SOURCE:

Rohm and Haas Co.: Maintenance C o a t i n g s : MAINCOTE HG-54: F o r m u l a t i o n HB-54-1

Coatings and Topcoats

H i q h Gloss DTM Maintenance C o a t i n g

26 l b s / 1 0 0 g a l B u t y l Carbi t o 1 13 D i e t h y l ami ne 4 S u r f y n o l 104H 5.5 Manchem APG 5.5 DSX 1514 4 S a n t i c i z e r 160 4 Butyl D i propasol 79 Water M i x w e l l ; t h e n add: 72 P l i o l i t e 7104 M i x w e l l ; t h e n add: 210 T i t a n o x 2160 9 Kadox 911 S a n d m i l l t o 7.5 NS, t h e n d r o p t o f u l l y assembled l e t d o w n w i t h m i x i ng L e t Down Phase: P l i o l i t e 7104 S a n t i c i z e r 160 Butyl D i propasol 10% Ammonium Benzoate S o l u t i o n P r o p y l e n e G1 y c o l Drew L-475

476 29 15 22 30 2

L b / g a l : 10.08 NVV: 38% NVW: 48% PVC: 18% KU V i s c o s i t y : 85-95 KU Freeze Thaw S t a b i l i t y : Pass 5 c y c l e s Oven S t a b i l i t y : Pass 4 weeks, 120 deg F Dry t o Touch @ 2 m i l DFT: 1 hour Recoat Time: 4 h o u r s G l o s s 60 deg @ 2 m i l DFT: 85% Method o f A p p l i c a t i o n : Brush o r Spray VOC: 236 g/1

SOURCE: The Goodyear T i r e & Rubber Co.:

Formula 2074-42

31

32

Water-Based Paint Formulations

H i a h G l o s s Maintenance/DTM C o a t i n g Ingredient: E k t a s o l v e EP Diethylamine S u r f y n o l 104H Manchem APG

Lbs/100 Gal 27 13 4 6 1 4 4 90

DSX 1550

Sant ic i z e r 160 Texanol Water M i x w e l l , t h e n add: P l i o l i t e 7104

74

M i x w e l l , t h e n add: T i t a n o x 2160 Kadox 911

216 9

S a n d m i l l t o 7.5 NS, t h e n d r o p t o f u l l y assembled l e t d o w n w i t h mixing: L e t Down Phase: P l i o l i t e 7104 409 Sant ic i z e r 160 30 Texanol 16 22 10% Ammonium Benzoate Drew L-475 2 Bul k densi t y : 10.07#/gal V i s c o s i t y : 95-110 KU VOC: 156 g/1 (1.30 l b / g a l l o n ) PVC: 15% NVV: 40% G l o s s 60 deg/20 deg a t 2 m i l DFT: 09%/66% Gloss r e t e n t i o n : 500 h o u r s QUV: 100%/100% 750 h o u r s QUV: 79%/61%

120 deg F oven s t a b i l i t y :

Pass one week

Freeze Thaw: P r o t e c t f r o m f r e e z i n g Age p a n e l 7 days b e f o r e t e s t i n g A l l o w 4 hours b e f o r e r e c o a t i n g

SOURCE: The Goodyear T i r e B Rubber Co.:

Formula #2065-59-21

Coatings and Topcoats

H i q h Perfornance. F l e x i b l e C o a t i n g P a r t s by w e i q h t 680.3 81.1 26.1 3.9 208.6

M a t e r ia1 s : WB-389 d i s p e r s i o n (34.5% NVM) D e i o n i zed w a t e r Melamine ( 1 ) Flow a d d i t i v e ( 2 ) Titanium d i o x i d e (3) Properties: Pigment/binder r a t i o : 0 . 8 / 1 . O Resin/melamine r a t i o : 90/10 N o n - v o l a t i l e m a t e r i a l (NVM), w t % : V i s c o s i t y , #4 F o r d Cup, s e c : 37 pH: 8.38

47.1

Compounding Procedure: 1. Charge t h e d i s p e r s i o n , melamine, f l o w a d d i t i v e , w a t e r , and pigment t o a p e b b l e m i l l . R o l l o v e r n i g h t t o a Hegman G r i n d o f 7+. 2. D i s c h a r g e m i l l and a d j u s t pH t o 8 . 0 - 8 . 5 and # 4 F o r d cup v i s c o s i t y t o 37 seconds. ( 1 ) Cyme1 303 ( 2 ) FC-430 (33% NVM i n d i e t h y l e n e g l y c o l n - b u t y l ( 3 ) T i - P u r e R-900

ether)

Performance P r o p e r t i e s ( 1 ) : CRS ( 2 ) : F i l m thickness, m i l s : 1.1 Sward hardness: 44 P e n c i l hardness: H Impact r e s i s t a n c e , i n - l b : d i r e c t : 160 r e v e r s e : 160 C o n i c a l bond, % pass: 100 C r o s s h a t c h a d h e s i o n : 5B 8-37 ( 3 ) : F i l m thickness, m i l s : 1.5 Sward hardness: 54 P e n c i l hardness: H Impact r e s i s t a n c e , i n - l b : d i r e c t : 160 r e v e r s e : 160 C o n i c a l bond, % pass: 100 C r o s s h a t c h adhesion: 5B ( 1 ) Cure C y c l e : 10 m i n u t e s a t 82C p l u s 20 m i n u t e s a t 177C ( 2 ) Cold r o l l e d s t e e l ( 3 ) B o n d e r i t e 37 t r e a t e d c o l d r o l l e d s t e e l

SOURCE: Amoco Chemical Co.: Water-Borne Bake P o l y e s t e r s Based on AMOCO IPA and TMA: Formula T a b l e 14 and 15

33

34

Water-Based Paint Formulations

H i q h Performance Water-Borne A i r D r y CoatTopcoat F o r m u l a t i o n Materials: R e s i n WB-151 175% NVM) Ammonium h y d r o x i d e , 28% Dei o n i zed w a t e r C o b a l t d r i e r , 5% ( 1 ) C a l c i u m d r i e r , 5% ( 2 ) Z i r c o n i u m d r i e r , 12% ( 3 ) A n t i - s k i n agent ( 4 ) Flow agent ( 5 ) T i t a n i um d i o x i d e ( 6 ) Secondary b u t a n o l E t h y l e n e g l y c o l monobuty e t h e r Dei o n i zed w a t e r

P a r t s by weiaht 256.1 11.5 439.7 3.8 3.8 1.6 0.9 0.3 173.1 20.8 13.9 74.5

Properties: N o n - v o l a t i l e m a t e r i a l (NVM). %: 36.5 Pigment/binder r a t i o : 0.9/1 .o pH: 8 . 5 W a t e r / c o s o l v e n t r a t i o ( v o l u m e ) : 82/18 V i s c o s i t y , #4 Zahn Cup, sec: 18 D r y t i m e s a t 20C, 50% RH: s e t t o t o u c h , m i n : 20 t a c k f r e e , min: 52 d r y hard, h r : 3.0 Compounding Procedure: 1 Sol u b i 1 ize t h e r e s i n w i t h ammoni um h y d r o x i de. 2. D i l u t e t h e m i x t u r e w i t h 75-85% o f t h e w a t e r . 3 . Add d r i e r s , a n t i - s k i n agent and f l o w agent; m i x t h o r o u g h l y . 4. Slowly s t i r i n t h e t i t a n i u m dioxide. 5 . G r i n d t h e m i x t u r e o v e r n i g h t t o a 7 Hegman G r i n d i n a p e b b l e mill. 6 . A d j u s t w i t h w a t e r , ammonia and c o s o l v e n t t o s p r a y i n g v i s c o s i t y and 8 . 0 - 8 . 5 pH.

.

(1) (2) (3) (4)

C o b a l t Hydro-Cure I 1 C a l c i u m Hydro-Cem Z i r c o n i u m Hydro-Cem E x k i n #2 ( 5 ) Byk 301 ( 6 ) T i - P u r e R-900 SOURCE: Amoco Chemical Co.: Water-Borne A i r D r y i n g A l k y d s Based on Amoco IPA and TMA: T a b l e 7

Coatings and Topcoats

H i g h S o l i d s Water-Borne C l e a r Coating-B Formulation: K-Flex 188 K-F1 ex UD-320W Cymel 303 Nacure 5225 S i 1wet L-7600 Water A r c o s o l v PM

259.5 259.5 257.7 15.0 0.7 175.2 32.4

P o l y 0 1/Urethane D i o l /HMM: 34/31 /35 c a l c . : 74.6 20 m i n / l 2 0 C : 6 7 . 8 V i s c o s i t y , 25C, cps: 275

% Solids, % Solids,

Film Properties: S u b s t r a t e : B o n d e r i t e 1000 C o l d - R o l l e d S t e e l Cure Time: 20 m i n u t e s F i l m T h i c k n e s s : 1.25 m i l DFT 120 Cure Temperature, C : F-H P e n c i l Hardness: Knoop Hardness: 4.2 Impact Rev., i n / l b : >160 Dit-., i n / l b : >160

150 H-2H 18.0 10-20 60-80

H i g h S o l i d s Water-Borne C l e a r Coatinq-C Formul a t i on : K-Flex 188 K-F1 ex UD-320W Cymel 303 Nacure 5225 S i l w e t L-7600 Water A r c o s o l v PM Polyol/Urethane Dio c a l c . : 74 20 m i n / l 2 V i s c o s i t y , 25C, cps:

% Solids, % Solids,

222.6 222.6 361.1 15.0 0.6 150.3 27.8 /HMM:

25/27/48

B C: 7 0 . 1 250

Film Properties: S u b s t r a t e : B o n d e r i t e 1000 C o l d - R o l l e d S t e e l Cure Time: 20 m i n u t e s F i l m T h i c k n e s s : 1.25 m i l DFT Cure Temperature, C : 120 Penci 1 Hardness H-2H Knoop Hardness 11 .o Impact Rev., i n / l b : >160 Dit-., i n / l b : >160 SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-10 and UDW-1C

150 H-2H 21 . o 0-10 40-60

35

36

Water-Based Paint Formulations

I n d u s t r i a l A i r d r v W h i t e H i g h G l o s s TOP Coat L b s / 1 0 0 Gal 9.71 29.26 26.21 11 .65 15.53 3.88 3.88 117.48 218.45 4.85

Inqredient: S u r f y n o l 104H B u t y l Carbi t o 1 Methyl Carbi t o 1 D i e t h y l ami ne OSX 1514 S a n t i c i z e r 160 Texanol Water R u t i l e Ti02 L-475 Defoamer H i g h speed o r S a n d m i l l t o 7 N.S., P l i o l i t e 7104 S a n t i c i z e r 160 E k t a s o l v e EP 10% Ammonium Benzoate

t h e n add: 485.44 26.21 26.21 19.42

A i rdry V i s c : 75 KU pH: 9.0-9.5 G l o s s 90% a t 60 deg Gardner Pass: 120 des F , 4 weeks Re-coat a f t e r 2 - h r s a i r d r y For f a s t d r y , B u t y l C a r b i t o . can be r e p l a c e d w i t h E k t a s o l v e EP VOC: 2.21 l b / g a l o r 260 g r a m s / l i t . W.P.G.: 9.9% Sp. G r . : 1 . 2 0 T.N.V.: 47.05 N.V.V.: 35.66

SOURCE: The Goodyear T i r e & Rubber Co.:

Formula #2064-34-Q0

Coatings and Topcoats

Low

Solids C l e a r Topcoat

Materials: Rhoplex CL-103 e m u l s i o n Dee Fo 3000

Weight Pounds

Volume Gal l o n s

484.5 1 .o

56.2 0.1

19.6 29.5 19.6 30.3

2.5 4.0 2.9 3.6

Premix and add under a g i t a t i o n : B u t y l Carbi t o 1 Hexyl C e l l os01 ve Dow C o r n i n g #14 Water Add :

16.8 2.0 M i chem Emu1 s i on 39235 15.8 1.8 A c r y s o l RM-825 modi f iet0.2 0.02 14% ammonia ( a d j u s t v i s c o s i t y w i t h w a t e r t o a range o f 20 t o 26 seconds on a #2 Zahn cup) 223.3 26.9 Water Formulation Constants: Approximate s o l i d s , % w t / v o l ) : 24.9/23.2 pn: 1 . 5 - 8 . 0 V i s c o s i t y , #2 Zahn cup seconds: 20 t o 26 VDC, g / l i t e r : 256 l b / g a l l o n : 2.1 C o a l e s c e n t . w t % on DO m e r s o l i d s : B u t y l C e l l o s o l v e : ' 15B u t y l C a r b i t o l : 10 Rheology m o d i f i e r , w t % on polymer s o l i d s : 2.0 Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g

SOURCE: Rohm and Haas Co.: RHOPLEX CL-103 A c r y l i c Emulsion: F o r m u l a t i o n KC-53-1 LS

37

38

Water-Based Paint Formulations

Low-Sol i d s F u l l -G1 oss Toocoat Based on Rhool ex CL-104 F o r A i r - D r y o r Low-Force-Dry Aool i c a t i o n Materials: Rhoplex CL-104 e m u l s i o n Dee Fo 3000

Emul s i on

Weight Pounds 513.9 0.9

Volume Gal 1ons 60.1 0.1

19.7 19.7 29.7 30.5

3.0 2.5 4.0 3.6

Premix and add under a g i t a t i o n : Dow C o r n i n g #14 B u t y l Carbi t o 1 Hexyl C e l l os01 ve Water Add : M i chem Emul s i on 39235 16.9 2.0 1.4 1.4 QR-708 Rheology Modi f ie r 14% Ammoni a 0.5 0.1 ( a d j u s t v i s c o s i t y w i t h w a t e r t o a range o f 38 t o 44 seconds on a #2 Zahn cup) Water 194.3 23.3

Formulation Constants: Approximate s o l i d s , % ( w t / v o ) : 25.2/23.7 PH: 7 . 0 - 7 . 5 V i s c o s i t y , B r o o k f i e l d LV S p i n d l e #1, CP @ 30 rpm: 175-200 V i s c o s i t y , #2 Zahn cup, seconds: 38-44 VOC, g / l i t e r : 257 l b / g a l l o n : 2.14 Coalescent, w t % on polymer s o l i d s : Hexyl C e l l o s o l v e : 15 B u t y l C a r b i t o 1 : 10 Rheology m o d i f i e r , w t % on polymer s o l i d s : 2.0 Freeze/thaw s t a b i 1 it y : P r o t e c t f r o m f r e e z i n g Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes

SOURCE:

Rohm and Haas Co.: RHOPLEX CL-104 A c r y l i c Emulsion: F o r m u l a t i o n WR-74-7LS

Coatings and Topcoats

39

Red O x i d e M a i n t e n a n c e C o a t i n g

Lb/100 G a l l o n 21 4 4 42 16 5 13 57 0.34

B u t y l Carbi t o 1 S a n t i c i z e r 160 Texanol Methyl Carbi t o 1 DSX 1514 S u r f y n o l 104H D i e t h y l ami ne Water Drew L-405 M i x we1 1 ; t h e n add: P l i o l i t e 7104

70

M i x we1 1 ; t h e n add: 100 146

Red Oxide 130M Heubach ZBZ S a n d m i l l t o 6 . 5 N.S. shown.

t h a n add t h e f o l l o w i n g t o g r i n d i n o r d e r

P l i o l i t e 7104 S a n t i c i z e r 160 Propyl C e l l osolve 10% Ammonium Benzoate S o l u t i o n

487 22 22 21

D e n s i t y : 10.30 l b / g a l VOC: 241 g/1 Pigment/binder r a t i o : 1 : l w t NVV: 39.61% NVM: 48.41% KU V i s c o s i t y : 70-80 KU Freeze Thaw S t a b i l i t y : Pass 5 c y c l e s Oven S t a b i l i t y : Pass 4 weeks 120 degrees F Dry Time @ 2 m i l DFT: 1 h o u r Recoat Time: 4 h o u r s Method o f A p p l i c a t i o n : B r u s h o r s p r a y F o r B r u s h i n g : 2 c o a t s recommended Recommended S u b s t r a t e : B l a s t e d h o t o r c o l d r o l l e d s t e e l

SOURCE: The Goodyear T i r e 8 Rubber Co.:

Formula 2074-44

40

Water-Based Paint Formulutfons

S a t i n (-40 gloss a t 6 0 ) T h e r m s e t t i n q Sealer/ToDcoat Based on RhoDlex AC-1024 Emulsion W i t h E a r l y Water and S t a i n R e s i s t a n c e Materials: P a r t A: Add w h i l e m i x i n g : B e e t l e 65 Resimene 797 Met hano 1 S i l w e t L-77 Dehydran 1293 Premix and add: Water S y l o i d 169 Add t o above: Rhopl ex AC-1024 emul s i on Water E x x a t e 600

Pounds

Gallons

143.24 30.14 17.55 2.63 3.51

13.91 3.97 2.66 0.31 0.47

20.07 7.02

3.37 0.42

350.90 40.71 10.53

40.33 4.09 1.44

Add s l o w l y i n o r d e r : A c r v s o l RM-025 r h e o l o a v modi f ie r 17.55 2.02 Chemcor wax emul s i on AS-35-3 3.61 30.07 ( a d j u s t v i s c o s i t y w i t h w a t e r t o a range o f 35+-5 seconds on a #2 Zahn cup) 99.29 11.92 Water P a r t 8: Premix and add s l o w l y : Methanol Nacure 155

42.11 35.09

6.30 4.30

Formulation Constants: PVC: 1.26 Approximate s o l i d s , % ( w t / v o l ) : 46.0/41.6 p H p a r t A : 6.5 pH, p a r t s A & B combined: 1.4 V i s c o s i t y , p a r t A, #2 Zahn cup, seconds: 35+-5 V i s c o s i t y , p a r t s A B B combined, #2 Zahn cup, seconds: voc : g / L , t h e o r e t i c a l : 207 g/L, a c t u a l , p e r ASTM D-2369: 350 Heat-age s t a b i l i t y , 14OF f o r 10 days: Passes Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g

SOURCE:

Rohm and Haas Co.:

KC-24-3

RHOPLEX AC-1024

Emulsion:

20

Formulation

Coatings and Topcoats

41

Waterbased Charcoal Basecoat w i t h P e a r l e s c e n t Waterbased C l e a r c o a t Conventional Urethane C l e a r c o a t Inaredients: Chempol 20-4301 Nopco NXZ 2-butoxyethanol T i n u v i n 1130 T i n u v i n 440 S u r f y n o l 104BC Nuocure C K - 1 0 Water

Pounds 661.18 3.00 58.43 4.17 2.09 0.80 1.39 52.50

Gal l o n s 75.13 0.39 7.78 0.43 0.23 0.11 0.17 6.30

Add defoamer t o 20-4301 s l o w l y and w i t h good a g i t a t i o n . Premix t h e c o s o l v e n t , l i g h t s t a b i l i z e r s , s u r f a c t a n t and d r i e r Add t h i s m i x t u r e t o t h e v o r t e x o f t h e e m u l s i o n under a g i t a t i o n . Add t h e w a t e r a t t h e end o r a l o n g w i t h t h e c o - s o l v e n t m i x t u r e o l o w e r t h e v i s c o s i t y . M i x w e l l , t h e n add s l o w l y w h i l e c o n t i n u ng t o agitate. Mearl in F i ne-Pearl #I 39V WD-2348 T i n t Paste-81 ack Water

46.93 7.35 26.70

1.81 0.76 3.21

Add t h e f o l l o w i n g t o i n c r e a s e t h i x o t r o p y t o l e v e l s necessary t o m a i n t a i n m e t a l o r i e n t a t i o n . Premix t h e f i r s t two i t e m s t h a t follow: Water Isopropyl alcohol Ammon ia

13.05 13.05 1 .oo

1.57 1.98 0.13

Allow p a i n t t o stand overnight before adjusting o r using. P r o p e r t i 8s : T o t a l s o l i d s , % b y w e i g h t : 33.41 T o t a l s o l i d s , % b y volume: 27.40 Wei g h t / g a l 1on : 8.92 PVC: 7 . 2 2 VOC. l b s . / g a l . : 2.10 V i s c o s i t y , a p p l i c a t i o n : 17” #4 Zahn pH: 7 . 4 S u b s t r a t e : 8-1000 Cure: 1 wk. A.D. DFT: 1 . 0 - 1 . 5 m i l

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 20-4301-H

Formulation

42

Water-Based Paint Formulaiions

Waterbased C l e a r c o a t InQredients: Chempol 20-4301 Nopco NXZ 2-butoxyethanol Dibutyl phthalate B u t y l Carbi t o 1 S u r f y n o l 104BC Nuocure CK-10 Water

Pounds 605.09 2.74 45.78 9.14 22.84 2.74 2.56 72.48

Gal 1ons 68.76 0.36 6.10 1.05 2.88 0.36 0.31 8.70

Add defoamer t o 20-4301 s l o w l y w i t h good a g i t a t i o n . Premix t h e c o - s o l v e n t s , p l a s t i c i z e r , s u r f a c t a n t and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e e m u l s i o n under a g i t a t i o n . Add t h e w a t e r a t t h e end o r a l o n g w i t h t h e c o - s o l v e n t m i x t u r e t o l o w e r the viscosity. Add t h e f o l l o w i n g t o i n s u r e t h i x o t r o p y t o l e v e l s necessary t o m a i n t a i n sag c o n t r o l . Premix t h e f i r s t two i t e m s t h a t f o l l o w . Water 2-butoxyethanol Ammon ia Byk 301 Water ( h o l d t o a d j u s t v i s c o s i t y )

11.94 11.94 0.91 0.91 68.53

1.43 1.59 0.12 0.11 8.23

A l l o w p a i n t t o s t a n d o v e r n i g h t b e f o r e a d j u s t i n g o r u s i n g . To be a p p l i e d o v e r Waterbased Charcoal Basecoat w i t h P e a r l e s c e n t . P r o p e r t i es : T o t a l s o l i d s , % by w e i g h t : 27.16 T o t a l s o l i d s , % by volume: 23.95 Weight/gal l o n : 8.58 VOC, l b s . / g a l . : 2.53 V i s c o s i t y , a p p l i c a t i o n : 38" #2 Zahn pH: 7.3 S u b s t r a t e : 8-1000 Cure: 1 wk. A . D . DFT: 1 . 5 m i l G l o s s , 60: 80 20: 46 P e n c i l hardness: F-H C r o s s h a t c h a d h e s i o n : 100%

SOURCE: Freeman Polymers D i v i son: CHEMPOL 20-430 -H

Formulat On

Coatings and Topcoats

43

Water-Borne C l e a r Coatinq-A T h i s f o r m u l a t i o n has been developed t o d e m o n s t r a t e t h e use o f K-FLEX UD-320 W p o l y 0 1 as a c o - s o l v e n t f o r a l o w m o l e c u l a r w e i g h t p o l y e s t e r r e s i n . The s o l v e n t i s w a t e r and about 15% 2-methoxyp r o p a n o l i s used as a c o - s o l v e n t . T h i s f o r m u l a t i o n does n o t c o n t a i n any amine t o s o l u b i l i z e t h e r e s i n s , t h e r e f o r e i t i s possi b l e t o c a t a l y z e t h i s f o r m u l a t i o n f o r low temperature c u r e f o r a p p l i c a t i o n s on paper o r wood. F o r extended s h e l f l i f e t h e formu l a t i o n s h o u l d be s h i p p e d w i t h o u t w a t e r . Formul a t ion : K-Flex 188 K-F1 ex UD-320W Cyme1 303 Nacure 5225 S i l w e t L-7600 Water A r c o s o l v PM

281.7 281.7 195.8 14.6 0.7 190.2 35.2

P o l y o l / U r e t h a n e Diol/HMM: 38/35/27 c a l c . : 72.7 20 min/l20C: 64.9 V i s c o s i t y , 25C, c p s : 200

% Solids, % Solids,

F i lm P r o p e r t ies : S u b s t r a t e : B o n d e r i t e 1000 C o l d - R o l l e d S t e e l Cure Time: 20 m i n u t e s F i l m T h i c k n e s s : 1.25 m i l DFT Cure Temperature, C: 120 P e n c i l Hardness: 128 Knoop Hardness: Impact Rev., i n / l b : Dir.. in/lb: Not c u r e d Cure Temperature, C: 150 P e n c i l Hardness: H-2H Knoop Hardness: 13.8 I m p a c t Rev., i n / l b : 40-60 D i r . , i n / l b : 100-120

*

*

SOURCE:

* *

K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-1A

44

Water -Based Paint Formulations

Waterborne A c r y l i c C g n v e r s i o n C o a t i n a f o r Wood Improvements i n t h e w a t e r and s t a i n r e s i s t a n c e o f a w a t e r b o r n e a c r y l i c c o n v e r s i o n c o a t i n g f o r wood can be a c h i e v e d by s e l e c t i n g t h e p r o p e r c a t a l y s t . U s i n g a more h y d r o p h o b i c c a t a l y s t , such as NACURE 155 (DNNDSA), i n s t e a d o f t h e more h y d r o p h i l i c pTSA c a t a l y s t can g r e a t l y improve t h e r e s i s t a n c e p r o p e r t i e s o f t h e c o a t i n g as shown i n t h e f o l l o w i n g f o r m u l a t i o n : Composi t i on : B e e t l e 65 Resimene 797

Weight

25.20 6.30

Premix t h e above and add: AC 1024 ASA 35.3

63.00 5.36 0.14

FC 430 Characteristics: T o t a l S o l i d s : 65.0% R e s i n S o l i d : 63.0% A c r y l ic / C r o s s l in k e r : 50/50 % Wax: 3% on R e s i n S o l i d s

C a t a l y s t L e v e l s : 6.3% K-CURE 1040 (4% pTSA on TRS) 8.7% NACURE 155 reduced t o 40% a c t i v e w i t h methanol ( 5 . 5 % DNNDSA on TRS) S u b s t r a t e : S t a i n e d and s e a l e d b i r c h plywood Cure: I R c u r i n g equipment can be oven c u r e d 10'/130F Appl ic a t i on : Spray a p p l ied t o a p p r o x i mate1y 3 m i 1s. wet I R Cure: U n i t u b e I n f r a r e d H e a t e r s Peak Emmission Wave L e n g t h : 2.95 m i c r o n s Energy O u t p u t : 25 W a t t s / i n 2 E m i t t e r Temperature: 1400F F l a s h Time: None D w e l l Time: 8" A l l

p a n e l s c u r e d t o 20 MEK r u b s ,

and aged one week.

S t a i n Test Results: C a t a l y s t : K-Cure 1040 A c i d : p-TSA 16 Hour Immersion: Water: L i g h t C o f f e e : Moderate Tea: Heavy C a t a l y s t : NACURE 155 A c i d : DNNDSA 16 Hour Immersion: Water: No E f f e c t Coffee: V. L i g h t Tea: L i g h t

SOURCE:

K i n g I n d u s t r i e s : F o r m u l a t i o n WR-21

Coatings and Topcoats

Water-Borne C o a t i n g f o r P l a s t i c s M a t e r i a1 s : R e s i n WB-151 (75% NVM) Ammonium H y d r o x i d e , 28% Dei o n i zed Water C o b a l t D r i e r , 5% ( 1 ) C a l c i u m D r i e r , 5% ( 2 ) Z i r c o n i u m D r i e r , 12% ( 3 ) A n t i - S k i n n i n g Agent ( 4 ) Flow Agent ( 5 ) Titanium Dioxide (6) Secondary B u t a n o l E t h y l e n e G l y c o l Monobutyl E t h e r Dei o n i zed Water

P a r t s bv Weiqht 256.1 11.5 439.7 3.8 3.8 1.6 0.9 0.3 173.1 20.8 13.9 74.5

Coating Properties: N o n - V o l a t i l e M a t e r i a l (NVM), w t %: 36.2 pH: 8.37 V i s c o s i t y , #4 Zahn Cup, seconds: 17 Wt/gal, l b s : 9.58 Pigment/Binder R a t i o : 0 . 9 , f i . O Water/Cosolvent R a t i o (Volume): 82/18 Dry Times a t 23C: Set-to-Touch, min: 10 Tack Free, min: 50 Dry Hard, h r : > 6 . 0 Dry Through, h r : > 6 . 0 C o a t i n g Compounding Procedure: 1 Sol u b i 1ize t h e r e s i n w i t h ammoni um h y d r o x i de. 2. D i l u t e t h e m i x t u r e w i t h w a t e r . 3. Add d r i e r s , a n t i - s k i n agent, and f l o w agent; mix t h o r o u g h l y . 4. S t i r i n t h e t i t a n i u m d i o x i d e . 5 . G r i n d t h e m i x t u r e o v e r n i g h t i n a p e b b l e m i l l t o a Hegman G r i n d o f 7+. 6 . A d j u s t w i t h ammonia, w a t e r and c o s o l v e n t t o a 8 . 0 t o 8 . 5 pH and s p r a y v i s c o s i t y . ( 1 ) C o b a l t Hydro-Cure I 1 ( 2 ) Cal c i um Hydro-Cem ( 3 ) Z i r c o n i um Hydro-Cem ( 4 ) E x k i n #2 ( 5 ) Byk 301 ( 6 ) T i - P u r e R-900 Coating Physical Properties: S u b s t r a t e : ABS 7 Day Cure: 30 Day Cure: G l o s s , 60, %: 86.5 G l o s s , 60, %: 88.9 Hardness, Sward: 50 Hardness, Sward: 54 P e n c i l , no c u t : 38 P e n c i l , no c u t : 28 C r o s s h a t c h Adhesion, % pass: 99 C r o s s h a t c h Adhesion, % pass: 100

.

SOURCE: Amoco Chemical Co. : Water-Borne C o a t i n g f o r P l a s t i c s : Formula T a b l e I1 and I11

45

46

Water-Based Paint Formulations

Water S o l u b l e A c r y l i c C l e a r C o a t i n g - A M o d i f i e d w i t h K-FLEX UD-320W T h i s f o r m u l a t i o n d e m o n s t r a t e s t h e u s e o f K-FLEX UD-320 p o l y u r e t h a n e d i o l as a m o d i f i e r f o r a w a t e r s o l u b l e a c r y l i c r e s i n . I n such a f o r m u l a t i o n t h e u r e t h a n e d i o l a c t s a s a r e a c t i v e m o d i f i e r and r a i s e s t h e a p p l i c a t i o n s o l i d s and t h e hardness o f the coating. Formulation: A c r y l o i d WR-97 K-F1 ex UD-320W Cyme1 303 Nacure-5225 D i m e t h y l e t h a n o l A m i ne Water ~~

277.5 0.0 49.6 3.0 12.4 657.5

A c r y l i c / U r e t h a n e Diol/HMM: BO/-/20 c a l c . : 24.3 % S o l i d s , 60 m i n / l l O C : 23.4 V i s c o s i t y , 25C, c p s : 351

% Solids,

F i l m Properties: S u b s t r a t e : B o n d e r i t e 1000 ( I r o n Phosphated CRS) Cure Schedule: 20 min/l5OC F i l m T h i c k n e s s , m i l DFT: . 7 Penci 1 Hardness: HB-F K i o o p Hardness: 7 . 0 I m p a c t Rev., i n / l b : >160 Dit-., i n / l b : >160 Sa t Spray, 100 h r s : Creepage: 1 0 mm C r o s s h a t c h Adhesion, %: 100 Mandrel 1 / 8 " d i a : Pass F i m T h i c k n e s s , m i l DFT: . 5 P e n c i l Hardness: H-2H KnooD Hardness: 9 . 1 I m p a c t Rev., i n / l b : >160 D i r . , i n / l b : >160 S a l t Spray, 100 h r s : Creepage: ---C r o s s h a t c h Adhesion, %: 100 Mandrel 1 / 8 " d i a : Pass

SOURCE: K i n g I n d u s t r i e s :

F o r m u l a t i o n UDW-PA

Coatings and Topcoats

Water S o l u b l e A c r y l ic C 1 e a r C o a t i nq-B Formul a t ion : A c r y l o i d WR-97 K-F1 ex UD-320W Cymel 303 Nacure-5225 D i m e t h y l e t h a n o l Amine Water

274.8 23.8 69.5 3.0 12.2 616.7

A c r y l i c / U r e t h a n e Diol/HMM: 68/7/25 c a l c . : 28.2 60 m i n / l l O C : 26.8 V i s c o s i t y , 25C, c p s : 601

% Solids, % Solids,

Film Properties: S u b s t r a t e : B o n d e r i t e 1000 ( I r o n Phosphated CRS) Cure Schedule: 20 m i n / l 5 0 C .7 F i l m T h i c k n e s s , m i l DFT: P e n c i l Hardness: H-2H Knoop Hardness: 14.0 I m p a c t Rev., i n / l b : 120-140 Dit-., i n / l b : 120-140

.5 H-2H 19.0 2160 >160

Water S o l ubl e A c r y l ic C l e a r C o a t i n q - C Formulation: A c r y l o i d WR-97 K-F1 ex UD-320W Cymel 303 Nacure-5225 D i m e t h y l e t h a n o l Amine Water

278.0 54.0 96.2 3.0 12.4 556.4

A c r y l i c / U r e t h a n e Diol/HMM: 57/15/28 % S o l i d s , c a l c . : 33.8 % S o l i d s , 60 m i n / l l O C : 3 2 . 4 V i s c o s i t y , 25C, c p s : 952 Film Properties: S u b s t r a t e : B o n d e r i t e 1000 ( I r o n Phosphated CRS) Cure Schedule: 20 m i n / l 5 0 C F i l m T h i c k n e s s , m i l DFT: .7 Penci 1 Hardness: H-2H Knoop Hardness: 15.0 I m p a c t Rev., i n / l b : 40-60 Dir., in/lb: 80-100 SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-28 and UDW-2C

.5 H-2H 17.0 >160 140-160

47

48

Water-Based Paint Formulations

White Hiah Gloss R a i l c a r C o a t i n g Propyl Carbi t o 1 Methyl Carbi t o 1 B u t y l D i propasol Water L475 Drew S u r f y n o l 104H DSX-1550

30 27 4 81 5 10 2 10

T.E.A.

M i x w e l l t h e n add: P l i o l i t e 7104 M i x w e l l t h e n add: Ti02 M i x w e l l t h e n h i g h speed o r sand m i l l t o 7+ N.S.: Follow w i t h : 7104 721 7 M i x w e l l t h e n add: Butyl Dipropasol S a n t i c i z e r 160 Ammonium Benzoate (10% s o l u t i o n ) P a n e l s sprayed and 72 h r s a i r d r i e d on 8-1000 p a n e l s Impact 80" l b : Passes a f t e r 72 h r s a i r d r y . F i l m T h i c k n e s s : 3.5 t o 4 m i l s d r y S a l t s p r a y : 300 h r s passes. No c r e e p o r b l i s t e r 600 h r s few b l i s t e r s , no c r e e p G l o s s : 3 . 5 t o 4 m i l s , 80% (60 degree) Passes: 1/4" Mendral bend 180 deg V i s c o s i t y : 75-80 KU TNV: 51.1 NVV: 41% D e n s i t y : 9.98 l b s / g a l voc: 200 g / 1

SOURCE: The Goodyear T i r e & Rubber Co.:

Formula 2064-57-91

67 225 467 107 14 27 20

Coatings and Topcoats

W h i t e Roof C o a t i n q 122 3 3 6 4 210 100 5 150 300 3 10 35 304 1

Water N a t r o s o l 250HR AMP 95 Tamol 850 Foamburst 363 Flexbond 471 T i P u r e R-902 T i t a n o x AWD N y t a l 300 Snowf 1ake Troysan Polyphase AF-1 Texan01 Water Flexbond 471 GE 60 Defoamer Y i e l d , g a l l o n s : 102.5 PVC, %: 45 S o l i d s , %: 64.7 V i s c o s i t y , KU: 93

Commercial S t y r e n e - A c r y l a t e Comparison: 45% PVC Roof C o a t i n g : F1exbond 471 : T e n s i l e , c u r e d f i l m s : 218 p s i U l t i m a t e E l o n g a t i o n : 538% Water A b s o r p t i o n , 7 days immersion: 12.9% MVTR (grams/100 square i n c h e s / 2 4 h o u r s - 20 m i l f i l m ) : 6.38 Mandrel Bend a t OF: Breaks Peel Adhesion, Urethane Foam, d r y : 6 . 0 p l i Peel Adhesion, Urethane Foam, wet: 5.0-5.5 p l i Peel Adhesion t o Aluminum, d r y : 4.5 p l i Peel Adhesion t o Aluminum, w e t : 5.0 p l i Commercial--15 Tg S t y r e n e - A c r y l a t e : T e n s i l e , c u r e d f i l m s : 243 p s i U l t i m a t e E l o n g a t i o n : 560% Water A b s o r p t i o n , 7 days immersion : 14.5% MVTR (grams/100 square i n c h e s / 2 4 h o u r s 20 m i l f i l m ) : Mandrel Bend a t OF: Breaks Peel Adhesion, Urethane Foam, d r y : 1.5-2.0 p l i Peel Adhesion, Urethane Foam, wet: 1 .O-1 .5 p l i Peel Adhesion t o Aluminum, d r y : 5 . 0 p l i Peel Adhesion t o Aluminum, w e t : 5.0 p l i

-

4.57

SOURCE: A i r P r o d u c t s and Chemicals, I n c . : FLEXBOND 471 A c r y l i c Emulsion: Suggested F o r m u l a t i o n F-471-83

49

50

Water-Based Paint Formulations

W h i t e S a t i n T h e r m o s e t a m TODCOat Materials: P a r t A: Add w h i l e m i x i n g : B e e t l e 65 Resimene 797 Methanol S i l w e t L-77 Dehydran 1293 T i - P u r e R-900 Premix and add: Water S y l o i d 169 Add t o above: Rhopl ex AC-1024 emu1 s i on Water E x x a t e 600

-__ Pounds

Gallons

140.95 37.53 17.26 2.59 3.45 64.33

13.68 3.91 2.62 0.31 0.46 1.93

27.62 6.91

3.32 0.41

345.29 70.23 10.36

39.69 8.43 1.42

Add s l o w l y i n o r d e r : A c r y s o l RM-825 r h e o l o g y m o d i f i e r Chemcor wax e m u l s i o n AS-35-3 ( a d j u s t v i s c o s i t y w i t h water t o a range a #2 Zahn cup) Water

64.76

7.77

P a r t €3: Premix and add s l o w l y : Methanol Nacure 155

41.53 34.53

6.28 4.23

1.99 17.26 3.55 29.59 o f 35+-5 seconds on

Formulation Constants: PVC: 6 . 7 5 Approximate s o l i d s , % ( w t / v o l ) : 46.9/42.9 pH, p a r t A : 6 . 5 pH, p a r t s A & B combined: 1 . 4 V i s c o s i t y , p a r t A, #2 Zahn cup, seconds: 35+-5 V i s c o s i t y , p a r t s A & B combined, #2 Zahn cup, seconds: 20 voc : g/L, t h e o r e t i c a l : 199 g/L, a c t u a l , p e r ASTM D-2369: 350 Heat-age s t a b i l i t y , 140F f o r 10 d a y s : Passes Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g SOURCE: Rohm and Haas Co.: KC-24-4

RHOPLEX AC-1024 E m u l s i o n : F o r m u l a t i o n

Coatings and Topcoats

51

25 PVC Topcoat Pounds M a t e r i a1 s : Cowles G r i n d : 25.4 A c r y s o l 1-62 (22.7%)* 4.5 B a l a b 3056A 150.0 T i P u r e R-960 138.8 Minex 4 1.o Bentone LT 39.2 Water Letdown : 625.1 Rhoplex AC-2045 (45%) Monomeric Me1ami ne (Cymel 303 o r Resimene 31 . 3 745) E t h y l e n e G l y c o l Monobutyl E t h e r (60% i n 52.0 water) 0.5 S u r f y n o l 104E

Gallons 2.93 0.61 4.56 6.40 0.07 4.70 71 .01 3.13 6.66 0.06

Formulation Constants: pH: a d j u s t t o 8 . 3 - 8 . 8 w i t h DMAE (50% i n H20) V i s c o s i t y ( # 4 F o r d Cup), s e c . : 21 % PVC: 25 % Weight S o l i d s : 57 % Volume S o l i d s : 47 A c r y l i c / M e l a m i n e ( s o l i d s r a t i o ) : 90/10 A c r y s o l 1-62 N e u t r a l i z a t i o n : A c r y s o l 1-62 (50%) 40.0 40.0 Water 8.0 DMAE (50%)

*

F o r m u l a t i o n #TC-2045-6 F l a t t e d C 1 e a r Topcoat Pounds M a t e r i a1 s : 729.1 Rhoplex AC-2045 (45.0%) Monomeric Me1ami ne (Cymel 303 o r Resimene 745) 36.5 47.4 E t h y l e n e G l y c o l Monobutyl E t h e r 25.5 E t h y l e n e G1y c o l 7.3 S u r f y n o l 104E 1.8 B a l a b 3056A 36.5 F l a t t i n g Agent ( S y l o i d 74 o r OK-41 2 ) 9.5 Water

Gal 1ons 82.83 3.65 6.30 2.74 0.90 0.25 2.21 1.14

Formulation Constants: pH: a d j u s t t o 8 . 3 - 8 . 8 w i t h DMAE (50% i n H20) V i s c o s i t y ( # 4 F o r d Cup), s e c . : 35 % Weight S o l i d s : 45 % Volume S o l i d s : 43 A c r y l ic/Mel ami ne ( s o l i d s r a t i o ) : 90/10 SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s Hardboard C o a t i n g s : RHOPLEX AC-2045: F o r m u l a t i o n #CL-2045-2

Water-Based Paint Formulations

52

35 PVC C u r t a i n C o a t a b l e Topcoat Materials: Cowl es G r i nd : A c r y s o l 1-62 ( 2 2 . 7 % ) * B a l a b 3056A T i P u r e R-960 Minex 4 Chrome O x i d e Green Bentone LT Water

Pounds

Gallons

29.2 5.8 87.8 269.4 22.6 63.3

3.36 0.92 2.67 12.42 0.53 0.07 7.59

559.8

63.59

28.0

2.80

46.8 0.5

5.99 0.06

1 .o

Letdown : Rhoplex AC-2045 (45%) Monomeric Melamine (Cyme1 303 o r Resimene 745) E t h y l e n e G l y c o l Monobutyl E t h e r (60% i n water) S u r f y n o l 104E

Formulation Constants: pH: a d j u s t t o 8 . 3 - 8 . 8 w i t h DMAE (50% i n H20) V i s c o s i t y ( # 4 F o r d Cup), s e c . : 21 % PVC: 35 % Weight S o l i d s : 52 % Volume S o l i d s : 48 A c r y l i c / M e l a m i n e ( s o l i d s r a t i o ) : 90/10

*

A c r y s o l 1-62 N e u t r a l i z a t i o n : A c r y s o l 1-62 (50%) Water DMAE (50%)

40.0 40.0 8.0

SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s Hardboard C o a t i n g s : RHOPLEX AC-2045: F o r m u l a t i o n #TC-2045-9

Coatings and Topcoats

53

35 PVC Hardboard Topcoat F o r m u l a t i o n M a t e r ia1 s : G r i n d (20 minutes) Add i n o r d e r : Water Bentone LT A c r y s o l 1-62 (50%) Water

Pounds

Gal 1ons

65.0

7.80 0.07

1. o

1

) Pr,emix

Dimethylaminoethanol/Water, 1 / 1 f Foamaster V L Foamaster TCX T i - P u r e R-960 Minex 4 Cr203 Green Letdown : Rhoplex AC-1230 (47%) E t h y l e n e g l y c o l monobutyl e t h e r (60% i n water) S u r f y n o l 104E

13.6 13.6 2.8 1.4 0.6 91 . o 277.0 23.0

0.19 0.08 2.75 12.77 0.54

612.3

71 . 5 0

48.0 0.5

6.16 0.06

3.45*

Dimethylaminoethanol/Water, 1 / 1 : A d j u s t p H t o 9 . 5 T h i c k e n e r o r w a t e r as needed: A d j u s t v i s c o s i t y t o 25 seconds, #4 F o r d Cup Formulation Constants: Pigment volume c o n t e n t : 35% T i 0 2 / B i n d e r r a t i o , b y w t . : 24/76 S o l i d s c o n t e n t : 60% ( w e i g h t ) 48% (volume)

*

3.45 g a l l o n s o f t h e premix.

SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s : RHOPLEX AC-1230: F o r m u l a t i o n Tab1 e I V

Coil Coatings

G l o s s C o i 1 C o a t i na--Black Sand M i l l G r i n d (15 m i n u t e s ) : A c r v s o l 1-62 (50.0%)

)

Premix

W _._ ater

D i m e t h y l ami n o e t h a n o l /Water, Resimene 745 Ethylene Glycol Rhopl ex AC-1822 (46.5%) B a l a b 3056A Raven 420 Water

1/ 1 )

Deeptone Pounds 1.5 1.5 0.3 36.8 27.9 195.5 7.3 27.7 10.8

A d j u s t g r i n d t o pH 8 . 7 w t h D i m e t h y l ami n o e t h a n o l / w a t e r , necessary. Rhoplex AC-1822 (46.5%) E t h y l e n e g l y c o l monobuty 80/20 S u r f y n o l 104E

55

Gal l o n s 0.17 0.18 0.03 3.68 3.00 22.21 0.98 1 .85 1 .30 1/1

, if

513.2

58.29

56.2 7.4

7.39 0.92

ether/Water,

V i s c o s i t y , #2 Zahn Cup: A d j u s t t o 30 seconds w i t h w a t e r Volume S o l i d s : 39.8% Wei g h t S o l i d s : 44.7% P.V.C.: 4.7 P/B: 7/93 A c r y l i c / M e l a m i n e : 90/10 V . O . C . : 0 . 2 2 k g / l ( 1 . 8 4 p o u n d s / g a l l o n ) minus w a t e r 0 . 2 5 k g / l ( 2 . 0 8 pounds/gal 1on) o f c o a t i ng s o l ids a p p l ied G l o s s , 60/20: 80/49 T-Bend M i c r o s c o p e : 2T Tape: OT P e n c i l Hardness: F

SOURCE: Rohm and Haas Co.: B u i l d i n g Products: ACRYSOL 1-62: Formul a t i on Tab1 e I V

56

Water -Based Paint Formulations

Gloss Coi 1 Coatinq--Dark

Brown Deeptone

Sand M i l l G r i n d (15 m i n u t e s ) : ) A c r y s o l 1-62 (50.0%) Water ) Premix Dimethylaminoethanol/Water, 1 / 1 ) Resimene 745 Ethylene Glycol Rhopl ex AC-1822 B a l a b 3056A Brown I r o n O x i d e 444 Raven 420

Pounds 8.2 8.2 1.7 35.2 27.6 187.1 7.0 178.0 9.4

Gal 1ons 0.94 0.99 0.20 3.52 2.97 21.26 0.95 4.45 0.63

A d j u s t g r i n d t o p H 8 . 7 w i t h Dimethylaminoethanol/water, 1 / 1 , if n e c e s s a r y . Letdown : Rhopl ex AC-1822 E t h y l e n e G l y c o l Monobutyl E t h e r / W a t e r , 80/20 S u r f y n o l 104E

493.9

56.12

54.0 7.0

7.10 0.87

V i s c o s i t y , #2 Zahn Cup: A d j u s t t o 30 seconds w i t h w a t e r Volume S o l i d s : 42.5% Weight S o l i d s : 54% P.V.C.: 12% P/B: 35/65 A c r y l i c / M e l a m i n e : 90/10 V.O.C.: 0 . 2 1 k g / l ( 1 . 7 5 p o u n d s / g a l l o n ) minus w a t e r 0.25 k g / l ( 2 . 0 6 p o u n d s / g a l l o n ) o f c o a t i n g s o l i d s applied G l o s s , 60/20: 77/40 T-Bend M i c r o s c o p e : 2T Tape: OT P e n c i l Hardness: F

SOURCE:

Rohm and Haas Co.: B u i l d i n g P r o d u c t s : ACRYSOL 1-62: Formulation Table 1 1 1

Coil Coatings

P h t h a l o Green C o i l C o a t i n g Green Semi -Gloss M a t e r i a1 s : Cowles G r i n d ( 1 5 m i n u t e s ) : Rhoplex AC-1230 (47%) A c r y s o l 1-62 (25% t o t a l s o l i d s , pH 9 . 2 w i t h DMAE) DMAE (50% i n w a t e r ) S y l o i d 72 T i -Pure R-960 Green P e b b l e M i l l G r n d ( f r o m b e l o w )

Pounds

Gallons

252.9

28.3

44.5 3.0 20.7 227.1 20.2

5.0 0.3 1.2 6.8 2.1

G r i n d t h e above a t h gh speed, t h e n l e t d o w n a s f o l l o w s : Letdown : Rhopl ex AC-1230 (47%) 458.3 Foamaster TCX 1.6 D i e t h y l e n e g l y c o l monomethyl e t h e r (60% i n w a t e r ) 29.4 T h i c k e n e r o r w a t e r as needed 10.0 Green P e b b l e M i l l G r i n d : GT-674 P h t h a l o Green A c r y s o l 1-62 (25% t o t a l s o l i d s , pH 9 . 2 w i t h DMAE) T r i t o n X-114 Water Foamaster TCX

51.4 0.2 3.5 1.2

242.5

14.55

48.5 9.8 654.7 3.7

5.34 1.07 78.57 0.47

Formulation Constants: S o l i d s c o n t e n t , w t %: 59 Pigment volume c o n t e n t , %: 19 T i 0 2 / B i n d e r r a t i o : 40/60 T i 0 2 / P h t h a l o g r e e n / S i l i c a r a t i o : 89/2/9 SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s : RHOPLEX AC-1230: F o r m u l a t i o n SOT-1230-1

57

58

Water-Based Paint Formulations

Water-Reducible Ingredients : Chempol 10-0509 D i m e t h y l e t h a n o l ami ne Byk P-104s 2-butoxyethanol B u t y l Carbi t o 1 Water T i -Pure R-900

A c r y l i c C o i l Coatina

Pounds

Gal 1ons

149.13 10.41 3.55 11.56 11.57 104.07 155.34

17.34 1.41 0.45 1.54 1.46 12.49 4.53

Weigh i n f i r s t f i v e i n g r e d i e n t s and mix we1 1 . Add w a t e r s l o w l y w i t h a g i t a t i o n . M i x w e l l , t h e n add pigment s l o w l y w i t h continued a g i t a t i o n . S a n d m i l l t o #7 Hegman, k e e p i n g g r i n d t e m p e r a t u r e below 120F w i t h water j a c k e t . L e t down w i t h : 74.07 8.61 Chempol 10-0509 Dimethylethanolamine 3.47 0.47 Cyme1 303 47.71 4.77 2-butoxyethanol 5.78 0.77 Water 326.78 39.23 Water ( h o l d t o a d j u s t v i s c o s i t y ) 57.73 6.93 I n t h e " l e t down," p r e m i x t h e f i r s t f o u r i n g r e d i e n t s , mix w e l l , and add t h e w a t e r w i t h c o n t i n u e d a g i t a t i o n . A f t e r t h o r o u g h l y m i x i n g t h e l e t d o w n p o r t i o n , add i t s l o w l y t o t h e g r i n d w i t h a g i t a t i o n . M i x w e l l , and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h d i m e t h y l e t h a n o l a m i n e i f necessa r y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . P r o p e r t ies : T o t a l s o l i d s , % by w e i g h t : 36.89% T o t a l s o l i d s , % by volume: 25.14% W e i g h t / g a l l o n : 9.61 l b s / g a l pvc: 18.01 P i g m e n t / b i n d e r r a t i o : 0.8 VOC: 2.97 l b s / g a l V i s c o s i t y : 36" #4 Zahn pH: 8.3 S u b s t r a t e : Aluminum DFT: 0.5-0.7 m i l Cure: 60" @ 500F PMT: 42OF-435F Gloss, 60: 91 , 20: 71 P e n c i l hardness: H-2H C r o s s h a t c h a d h e s i o n : 100% r e t e n t i o n Impact r e s i s t a n c e , r e v e r s e : Pass 24 i n c h pounds T-bend: 2T-3T

SOURCE:

Freeman Polymers D i v i s o n : CHEMPOL 10-0509-A F o r m u l a t i o n

Coil Coatings

White C o u o a t i n o :

A l l Ti02

P a r t s p e r hundred M a t e r ia1 s : Weight R a t i o * (Vol. Basis1 Rhoplex AC-658 (47%) 175.1 19.6 A c r y s o l 1-98 (25%, pH t o 9 . 2 w i t h DMAE) 28.5 3.2 0.03 Foamaster VL 0.3 Foamaster TCX 1.6 0.20 T i - P u r e R-960 267.7 8.1 G r i n d t h e above a t h i g h speed,

t h e n l e t down as f o l l o w s :

Rhoplex AC-658 (47%) D i e t h y l e n e g l y c o l monomethyl e t h e r (60% i n w a t e r ) DMAE ( 1 / 1 w i t h w a t e r ) C e l l o s i z e QP-40 (5% i n w a t e r )

524.3

58.8

55.0 6.6 22.4

0.8

6.6 2.7

Formulation Constants: Pigment volume c o n t e n t : 19 T i 0 2 / b i n d e r r a t i o , b y w e i g h t : 45/55 pn: 9 . 7 t o 10.0 V i s c o s i t y , s e c . ( # 4 F o r d Cup): 30 Sol i d s Content: by w e i g h t : 56.5 b y volume: 46

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t ; u s i n g k i l o g r a m s , a b o u t 833 l i t e r s w i l l result.

SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s : RHOPLEX AC-658: Formulation: A l l T i 0 2

59

Water-Based Paint Formulations

60

W h i t e C o i l C o a t i n g s : Low G l o s s P a r t s p e r hundred Ratio* LVol. B a s i x M a t e r i a1 s : Weight ____ Rhoplex AC-658 (47%) 220.4 24.7 A c r y s o l 1-98 (25%, pH t o 9 . 2 w i t h DMAE) 29.3 3.2 Foamaster VL 0.3 0.03 Foamaster TCX 1 .6 0.20 Water 11.1 1.3 T i -Pure R-960 223.4 6.8 S y l o i d 72 44.5 2.5 G r i n d t h e above a t h i g h speed,

t h e n l e t down a s f o l l o w s :

Rhoplex AC-658 (47%) D i e t h y l e n e g l y c o l monomethyl e t h e r (60% i n w a t e r ) DMAE ( 1 / 1 w i t h w a t e r )

481 . 2

53.9

54.6 6.6

6.6 0.8

Formulation Constants: Pigment volume c o n t e n t : 22 T i 0 2 / b i n d e r r a t i o , b y w e i g h t : 40/60 pH: 9 . 7 t o 1 0 . 0 V i s c o s i t y , sec. ( # 4 F o r d Cup): 30 Sol i d s Content: b y w e i g h t : 53 by volume: 46

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t ; u s i n g k i l o g r a m s , about 833 l i t e r s w i l l result.

SOURCE: Rohm and Haas C o . : B u i l d i n g P r o d u c t s : RHOPLEX AC-658: F o r m u l a t i o n : Low G l o s s

62

Water -Based Paint Formulations

A c r y l ic Semi -G1 oss W h i t e En@ D i s p e r s i on : D i spersant (1 )

Pounds

Defoamer (2) P r o p y l ene g l y c o l H i g h g l o s s t i t a n i u m d i o x i d e (3) Reduction: Propylene g l y c o l A c r y l i c l a t e x (4) Vancide TH Water ) C o a l e s c e n t (5) ) Premix S u r f a c t a n t (6) ) Defoamer 3% Van Gel ( W a t e r / p r o p y l e n e g l y c o l 75/25 gel 1

Gal l o n s

I1 2 63 270

1.3 .27 7.3 7.9

30 556 1 23 12 2 3

3.5 62.7 0.1 2.8 1.5 0.23

103

12.0

0.4

1 ) Tamol 731 o r e q u i v a l e n t 2) Nopco NDW o r e q u i v a l e n t 3 ) T i P u r e R-900 o r e q u i v a l e n t 4 ) Rhoplex AC-490 o r e q u i v a l e n t 5 ) Texanol o r e q u i v a l e n t 6) T r i t o n GR-7 o r e q u i v a l e n t

Pain t Properties: C o n s i s t e n c y , KU: 77 Pigment volume c o n c e n t r a t i o n , %: 23 S o l i d s by w e i g h t , %: 49 S o l i d s by volume, %: 35 60 G l o s s , 1 week: 65-70 T h i s f o r m u l a t i o n e x h i b i t s t h e s u b s t i t u t i o n o f VAN GEL f o r b a c t e r i a - s e n s i t i v e c e l l u l o s i c t h i c k e n e r i n an a c r y l i c semig l o s s enamel. Manufacturing I n s t r u c t i o n s : (Equipment - h i g h shear d i s p e r s i o n t y p e ) Paint Preparation: 1 . Charge d i s p e r s a n t , defoamer and p r o p y l e n e g l y c o l t o s u i t a b l e container. 2. M i x a t l o w speed u n t i l u n i f o r m . 3 . Add and d i s p e r s e t i t a n i u m d i o x i d e , i n c r e a s i n g t h e m i x i n g speed as n e c e s s a r y . 4 . Reduce speed and add t h e f o l l o w i n g i n g r e d i e n t s , m i x i n g u n t i l u n i f o r m a f t e r each a d d i t i o n : p r o p y l e n e g l y c o l , l a t e x , c o a l e s c e n t p r e m i x , VANCIDE TH, defoamer and VAN GEL d i s p e r s i o n . Note: The use o f VAN GEL d i s p e r s i o n p r e v e n t s a i r entrapment and o p t i m i z e s g l o s s . The c o a l e s c e n t i s e m u l s i f i e d i n p r e m i x t o m i n i m i z e e f f e c t on l a t e x upon i n c o r p o r a t i o n .

SOURCE: R . T . V a n d e r b i l t Co.,

I n c . : Development F o r m u l a t i o n SG-201

Enamels

A i r - D r y Water-Reducible

63

Enamel Weiqht %

I n q r e d ie n t s : Grind: T i t a n i u m d i o x i d e , R-900 Polymon b l u e pigment R e s i n WA-17-2T, 75% N . V . Ammonium h y d r o x i d e , 28% E k t a s o l v e EB s o l v e n t Cycloden c o b a l t , 6% Co Cyclodex manganese, 6% Mn

16.07 0.85 27.57 1 .26 4.34 0.20 0.10

L e t Down: Water

49.61

Constants: N o n v o l a t i l e s , w t %: 37.6 P i gment/bi nder w t %: 45/55 W a t e r / o r g a n i c s , w t %: 82/18 V i s c o s i t y by No. 4 F o r d Cup, sec: 60 pH: 8 . 9 D r y i n g P r o p e r t i e s (One-Mi 1 Dry F i l m ) : S e t t o t o u c h , min ( b ) : 30 Tack f r e e , min ( c ) : 45 One-hour w a t e r s p o t , a f t e r 6 h o u r s : S l i g h t e f f e c t , recovery C o a t i n g P r o p e r t i e s , A f t e r 7 Days: Penci 1 hardness: B-HB Impact r e s i s t a n c e , i n . - l b : D i r e c t : 40 Reverse: 4 60 G l o s s : 83 S a l t s p r a y r e s i s t a n c e , 100 h o u r s : No creepage, gloss

full

no l o s s o f

S t a b i l i t y A f t e r 18 Months a t Ambient Temperature: pH: 7 . 1 V i s c o s i t y by No. 4 F o r d Cup, s e c : 34 S e t - t o - t o u c h , min ( b ) : 30 Tack f r e e , min ( c ) : 45 One-hour w a t e r s p o t , a f t e r 6 h o u r s : S l i g h t e f f e c t , recovery

full

b ) ASTM D1640.5.1 c ) ASTM D1640.5.3.3.1 d ) Unprimed, z i n c p h o s p h a t i z e d , c o l d r o l l e d s t e e l p a n e l s c o a t e d w i t h a 1 - m i l f i l m were used i n t h e s e e v a l u a t i o n s .

SOURCE: Eastman Chemical P r o d u c t s , I n c . : A i r - D r y i n g WaterR e d u c i b l e A1 kyd Enamel Based on TMPD G l y c o l

64

Wafer-Based Paint Formulations

A i r - D r y Water-Reduci b l e Enamel

Grind: T i -Pure R-900 p i g m e n t WA-17-6C (75% N.V.) a l k y d Ammonium h y d r o x i d e (28%) C o b a l t Cyclodex d r i e r (6%) Manganese Cyclodex d r i e r (6%) Activ-8 additive BYK 301 a d d i t i v e n-Butanol L e t Down: Water

Wei q h t 240.1 251.5 18.6 3.8 3.8 1.2 2.3 23.8 454.9

Physical Constants: N o n v o l a t i l e s , w t %: 42.9 P i g m e n t / B i n d e r , w t %: 56/44 Water/Organi c s , w t %: 84/16 V i s c o s i t y , No. 4 F o r d Cup, seconds: 36 pH: 8 . 8 Dry1 ng P r o p e r t i es (One-Mi 1 D r y F i l m ) : S e t t o t o u c h , ( b ) m i n : 20 Tack Free, ( c ) m i n : 35 1-Hour Water Spot, A f t e r 6 H o u r s : S l i g h t e f f e c t , f u l l recovery P r o p e r t i e s A f t e r 1 Week D r y ( d ) : P e n c i l Hardness: HB I m p a c t R e s i s t a n c e , D i r e c t : 28 Reverse: <4 G l o s s , % 60: 90 20: 70 S a l t - S p r a y R e s i s t a n c e , 100 h r , creepage f r o m S c r i b e , i n . : Carbon-Arc Weather-Ometer, 500 h r : % G l o s s R e t e n t i o n , 60: 66 2 0 : 44 P r o p e r t i e s A f t e r 3 Weeks D r y : S a l t - S p r a y R e s i s t a n c e , Creepage f r o m S c r i b e , i n . : @ 100 h r : None @ 200 h r : 1 / 1 6 @ 300 h r : 9 / 1 6 Solution S t a b i l i t y : A f t e r Four Weeks a t 120F: pH: 7 . 2 V i s c o s i t y , No. 4 F o r d Cup seconds: 155 D r y Time, S e t t o Touch, in n: 30 Tack F r e e , m i n : 45 G1o s s : E x c e l 1e n t Appearance: E x c e l l e n t b ) ASTM D 1 6 4 0 . 5 . 1 c ) ASTM D 1 6 4 0 . 5 . 3 . 3 . 1 d) Untreated c o l d - r o l l e d s t e e l panels coated w i t h a 1 - m i l were used i n t h e s e e v a l u a t i o n s . SOURCE: Eastman Chemical P r o d u c t s , I n c . : P o l y e s t e r R e s i n WA-17-6C

3/16

f i l m

Enamel P r e p a r e d f r o m

Enamels

65

Black Acrylic Emulsion Enamel Pounds 47.00 7.91 8.25 1.35 31 .OS 10.26

Inaredients: Coroc A - 2 6 7 8 4 2-butoxyethanol S u r f y n o l 104BC S u r f y n o l DF-75 Water Raven #14 powder

Gal 1ons 5.34 1.05 1.10 0.16 3.73 0.70

Pre-mix f i r s t f o u r i n g r e d i e n t s , t h e n add w a t e r w i t h a g i t a t i o n . Load m i x t u r e i n t o b a l l m i l l f o l l o w e d by p i g m e n t . S t e e l b a l l g r i n d t o a #7 Hegman. A d j u s t g r i n d a n d / o r wash m i l l u s i n g w a t e r f r o m below, i f n e c e s s a r y . L e t down w i t h : Chempol 20-4301 2-butoxyethanol B u t y l Carbit o 1 Dibutyl Phthalate Nuocure CK-10 Michem 39235 Water ( h o l d t o a d j u s t v i s c o s i t y )

507.57 32.79 20.97 7.24 2.06 30.96 77.03

66.77 4.37 2.64 0.83 0.25 3.72 9.34

Add t h e g r i n d t o t h e e m u l s i o n . Add i t s l o w l y and w i t h good a g i t a t i o n . Pre-mix c o - s o l v e n t s , p l a s t i c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r s e e d i n g . Add t h e wax d i s p e r s i o n t o t h e " l e t down" w i t h a g i t a t i o n . M i x w e l l , and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7 . 6 , a s t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % b y w e i g h t : 31.20% T o t a l s o l i d s , "4 by volume: 27.60% W e i g h t / g a l l o n : 8.65 l b s . / g a l . P V C : 2.55 Pigment/binder r a t i o : 0.04 VOC: 2 . 1 7 l b s . / g a l V i s c o s i t y : 49" # 2 Zahn pH: 7 . 5 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y Set t o t o u c h : 1 0 ' Dust f r e e : 1 5 ' Tack f r e e : 4 5 ' - 5 0 '

.

SOURCE:

Freeman Polymers D i v i s i on : CHEMPOL 20-4301 - F Formula

66

Water-Based Paint Formulations

__ B l a c k A i r D r y Enamel Pounds

~~

C a r g i l l Water R e d u c i b l e Epoxy E s t e r 73-7331 Aqueous Ammonia 28% E t h y l e n e G l y c o l Monobutyl E t h e r sec-Butanol Byk-301 S p e c i a l B l a c k 4A A e r o s i l R972 D e i o n i z e d Water

____. Gal 1ons

97.8 5.9 9.8 14.7 2.0 12.2 4.9 190.8

11.58 0.78 1 .30 2.18 0.24 0.83 0.27 22.90

181 .O 10.8

21.43 1.43

14.7 9.8 1. o 2.5 2.2

2.18 1.30 0.12 0.33 0.25

273.9

32.88

Pebble M i l l t o a 7 . 5 Hegman C a r g i 11 Water R e d u c i b l e Epoxy E s t e r 73-7331 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: sec-Butanol E t h y l e n e G l y c o l Monobutyl E t h e r Activ-8 5% C o b a l t Hydro Cure I 1 Manganese Hydro Cure I 1 D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 25.97 (By Volume): 23.47 Pigment t o B i n d e r R a t i o : 0.09 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3 . 2 4 ( G r a m s / L i t e r ) : 388 W a t e r : C o s o l v e n t Weight R a t i o : 77.80:22.20 PH: 8 . 2 - 8 . 7 V i s c o s i t y Krebs-Stormer (KU): 68-73 Typi c a l Cured F i 1rn P r o p e r t i es : Cure Schedule: 7 Days A i r Dry Substrate: Cold Rolled Steel Gloss ( 6 0 ) : 83 P e n c i l Hardness: Pass B Dry Time ( M i n u t e s ) : 65 H u m i d i t y ( H o u r s ) : 120 B1 is t e r s : None S a l t Spray ( H o u r s ) : 96 S c r i b e Creep ( m m ) : 5 % Wet Tape Adhesion: 98

SOURCE: C a r g i l l ,

Inc.: CARGILL F o r m u l a r y : F o r m u l a t i o n P1897-F1

Enamels

B l a c k A i r D r y Enamel Pounds

Gal 1ons

C a r g i l l Water R e d u c i b l e S t y r e n a t e d A l k y d Copolymer 74-7422 Aqueous Ammonia 28%

90.8 3.6

10.75 0.48

P r o p y l e n e G l y c o l Monobutyl E t h e r Byk-301 Special Black 4

9.1 1.8 10.2

1.24 0.22 0.69

181.6 5.9

21.49 0.79

P r o p y l e n e G l y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 4% C a l c i u m A c t iv-8

18.2 1.9 2.9 0.9

2.48 0.25 0.38 0.11

Dei o n i zed Water P r o p y l e n e G l y c o l Monobutyl E t h e r

455.4 10.4

54.67 1.43

41 . 8

5.02

Sand M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e S t r e n a t e d A l k y d Copolymer 74-7422 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment) Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 24.51 (By Volume): 21.83 Pigment t o B i n d e r R a t i o : 0.05 P i gment V o l ume Concent r a t ion : 3.30 Weight Per G a l l o n : 8 . 3 5 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3 . 1 9 ( G r a m s / L i t e r ) : 382 W a t e r : C o s o l v e n t Weight R a t i o : 80.00:20.00 pH: 8 . 0 V i s c o s i t y #4 F o r d Cup (Seconds): 44 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y S u b s t r a t e : C o l d R o l l ed S t e e l G l o s s ( 6 0 / 2 0 ) : 91/77 P e n c i l Hardness: Pass 2 8 % C r o s s h a t c h Adhesion: 80 Impact ( I n . L b s . ) : D i r e c t : 10 Reverse: 5 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula PlB57-207A

67

68

Water-Based Paint Formulations

__.._____ Black A i r

D r y Enamel

Pounds

Gal 1 ons

125.6 13.2 2.6 7.9 17.2 330.5

14.52 1.76 0.33 1.06 1.16 39.68

244.6

28.28

E t h y l e n e G l y c o l Monobutyl E t h e r sec-Butanol 5% C o b a l t Hydro Cure I 1 8% Manganese Hydro Cure I 1 Act iv - 8

13.2 6.6 1.7 1.3 0.8

1.76 0.98 0.22 0.15 0.10

Aqueous Ammonia 28% E x k i n No. 2

11.9 1.3

1.59 0.17

2.6

0.30

66.1

7.94

C a r g i 1 1 Water R e d u c i b l e S t y r e n a t e d A 1 kyd Copolymer 74-7425 E t h y l e n e G l y c o l Monobutyl E t h e r By k - 3 0 1 Aqueous Ammonia 28% Special Black 4A D e i o n i z e d Water Pebble M i l l t o a 7 . 5 Hegman C a r g i l l Water R e d u c i b l e S t y r e n a t e d A l k y d Copolymer 74-7425 Premix t h e f o l l o w i n g , t h e n add:

Aqueous Ammonia 28% ( a d j u s t t o pH 8 . 0 - 8 . 5 ) D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment) Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 3 3 . 0 (By Volume): 2 9 . 6 Pigment t o B i n d e r R a t i o : 0 . 0 7 Weight Per G a l l o n : 8 . 4 7 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3.00 (Grams/Li t e r ) : 360 pH: 8 . 0 - 8 . 5 V i s c o s i t y Krebs-Stormer (KU): 67-72 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r Dry Substrate: Cold Rolled Steel Gloss ( 6 0 ) : 87-92 P e n c i l Hardness ( 1 Day): Pass 68 ( 7 Days): Pass 38 Dry Time 5009 Zapon ( H o u r s ) : 1 SOURCE: C a r g i l l ,

Inc.: CARGILL F o r m u l a r y : Formula P1863--D2

Enamels

____ B l a c k A i r Dry Enamel Pounds

Gallons

53.0 1.9 2.0 9.7 68.3

6.23 0.24 0.27 0.66 8.20

195.2 11.9

22.97 1.59

2.9 2.9 1. o 40.2 3.0

0.38 0.40 0.12 5.46 0.38

2.6 439.4

0.34 52.76

C a r g i 11 Water R e d u c i b l e A c r y l ic Modi f ied A1 k y d 74-7432

Byk-301 Aqueous Ammonia 28% Special Black 4 D e i o n i zed Water Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e A c r y l ic Modi f ied A1 k y d 74-7432 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

I n t e r c a r 6% C o b a l t I n t e r c a r 6% Manganese A c t iv-8 P r o p y l e n e G l y c o l Monopropyl E t h e r D i a c e t o n e A1 coho1 Exkin No. 2 De o n i zed Water

Pa n t P r o p e r t i e s : % N o n v o l a t i l e (By W e i g h t ) : 22.42 (By Volume): 19.85 Pigment t o B i n d e r R a t i o : 0 . 0 6 Pigment Volume C o n c e n t r a t i o n : 3.54 Weight Per G a l l o n : 8 . 3 4 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3 . 4 2 ( G r a m s / L i t e r ) : 410 W a t e r : C o s o l v e n t Weight R a t i o : 8 0 . 0 0 : 2 0 . 0 0 pH: 8 . 4 0 V i s c o s i t y #4 F o r d Cup (Seconds): 61 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 85/60 P e n c i l Hardness: Pass B % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 70 Reverse: ( 5

SOURCE:

Cargill,

I n c . : CARGILL F o r m u l a r y : Formula P 1 8 4 8 - l 6 l A

69

70

Water -Based Paint Formulations

_B_l a _c _k _ _A~ ~i r_ _D_ r y Enamel ~

Pounds

Gal 1ons

86.0 4.2 15.4 10.6 3.6 1.4 96.6

10.12 0.57 2.28 0.71 0.20 0.24 0.17 11.60

196.5 9.9

23.12 1.32

2.8 1.8 2.5 1.4 0.8

0.42 0.23 0.34 0.18 0.10

0.8 248.6

0.10 29.85

153.7

18.45

C a r g i 11 Water R e d u c i b l e A c r y l i c Modi f ied A1 k y d 74-7432 Aqueous Ammonia 28% sec-Butanol Special Black 4 A e r o s i l R972 Byk-020 S u r f y n o l 104E D e i o n i zed Water

1.8

B a l l M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e A c r y l ic Modi f ied A1 k y d 74-7432 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i u m I n t e r c a r 4% C a l c i u m A c t iv-8 E x k i n No. 2 Dei o n i zed Water Dei on1 zed Water Ad j ustment )

(Hold f o r V i s c o s i t y

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 25.68 (By Volume): 2 2 . 6 9 Pigment t o B i n d e r R a t i o : 0 . 0 7 Pigment Volume C o n c e n t r a t i o n : 4.19 Weight Per G a l l o n : 8 . 3 8 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 9 3 (Grams/Li t e r ) : 351 W a t e r : C o s o l v e n t Weight R a t i o : 81.72:18.28 pH: 8 . 4 V i s c o s i t y Krebs-Stormer (KU): 68 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G1o s s ( 6 0 / 2 0 ) : 79/38 P e n c i l Hardness: Pass 2 8 % C r o s s h a t c h Adhesion: 90 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1843-125A

Enamels

B l a c k A i r D r y Enamel Pounds

Gal 1ons

80.3 4.2 26.4 10.6 3.6 1.8 1.4 96.8

9.24 0.57 3.93 0.71 0.20 0.24 0.17 11.62

C a r g i 11 Water R e d u c i b l e Chain Stopped A1 k y d 74-7470 Aqueous Ammonia 28% sec-Butanol Special Black 4 A e r o s i l R972 Byk-020 S u r f y n o l 104E D e i o n i z e d Water B a l l M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e Chain Stopped A1 k y d 74-7470 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

183.6 9.9

21 .ll 1.32

t h e n add: 10.7 1.8 2.5 1.4 0.8

1.59 0.23 0.34 0.18 0.10

0.8 402.9

0.10 48.35

sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um I n t e r c a r 4% C a l c i u m A c t iv-8 E x k i n No. 2 Dei o n i zed Water

P a i n t P r o p e r t i 8s: % N o n v o l a t i l e (By W e i g h t ) : 2 5 . 6 8 (By Volume): 2 2 . 2 0 Pigment t o B i n d e r R a t i o : 0 . 0 7 Pigment Volume C o n c e n t r a t i o n : 4 . 2 9 Weight Per G a l l o n : 8 . 3 9 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 9 4 ( G r a m s / L i t e r ) : 352 W a t e r : C o s o l v e n t Weight R a t i o : 8 1 . 7 2 : 1 8 . 2 8 pH: 8 . 5 V i s c o s i t y Krebs-Stormer ( K U ) : 65 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 76/35 P e n c i l Hardness: Pass 38 % C r o s s h a t c h Adhsion: 70 Impact ( i n . l b s . ) : D i r e c t : 40 Reverse: >5

SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1843-125D

71

72

Water-Based Paint Formulations

B l a c k A i r D r y Enamel Pounds

Gal 1ons

80.1 4.2 26.3 10.5 3.6 1.8 1.4 96.4

9.31 0.56 3.91 0.71

C a r g i l l Water R e d u c i b l e F a t t y A c i d A l k y d 74-7472 Aqueous Ammonia 28% sec-Butanol Special Black 4 A e r o s i l 13972 Byk-020 S u r f y n o l 104E D e i o n i z e d Water

0.20 0.24 0.17 11.58

B a l l M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e F a t t y A c i d A l k y d 74-7472 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

183.0 9.9

21.28

10.6 1.8 1.4 0.8

1.58 0.23 0.34 0.18 0.10

0.8 401.4

0.10 48.19

1.32

t h e n add:

sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um I n t e r c a r 4% C a l c i u m A c t iv-8 E x k i n No. 2 Dei o n i zed Water

2.4

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 2 5 . 6 8 (By Volume): 2 2 . 4 8 Pigment t o B i n d e r R a t i o : 0 . 0 7 Pigment Volume C o n c e n t r a t i o n : 4 . 2 3 Weight Per G a l l o n : 8 . 3 6 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 9 1 ( G r a m s / L i t e r ) : 349 W a t e r : C o s o l v e n t Weight R a t i o : 8 1 . 7 2 : 1 8 . 2 8 pH: 8 . 3 V i s c o s i t y Krebs-Stormer (KU): 74 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 86/70 P e n c i l Hardness: Pass 28 % C r o s s h a t c h Adhesion: 90 Impact ( I n . L b s . ) : D i r e c t : 30 Reverse: <5

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y :

Formula P1843-125E

Enamels

B l a c k A i r D r y Enamel C a r g i 11 Water R e d u c i b l e Chain Stopped A1 k y d 74-7474 Aqueous Ammonia 28% sec-Butanol Special Black 4 A e r o s i l R972 Byk-020 S u r f y n o l 104 E Dei o n i zed Water

Pounds

Gal l o n s

85.5 4.5 28.1 11.3 3.8 1.9 1.5 103.0

9.71 0.60 4.18 0.76 0.21 0.26 0.18 12.36

195.4 10.5

22.20 1 .41

11.4 1.9 2.6 1.5 0.8

1.69 0.25 0.36 0.19 0.10

0.8 378.4

45.44

B a l l M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e Chain Stopped A1 k y d 74-7474 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um I n t e r c a r 4% C a l c i u m Activ-8 E x k i n No. 2 D e i o n i z e d Water

0.10

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 27.21 (By Volume): 2 3 . 3 6 Pigment t o B i n d e r R a t i o : 0 . 0 7 Pigment Volume C o n c e n t r a t i o n : 4 . 3 4 Weight Per G a l l o n : 8 . 4 3 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.97 ( G r a m s / L i t e r ) : 356 W a t e r : C o s o l v e n t Weight R a t i o : 8 0 . 2 2 : 19.78 pH: 0 . 2 V i s c o s i t y Krebs-Stormer ( K U ) : 72 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 90/71 P e n c i l Hardness: Pass 3 8 % C r o s s h a t c h Adhesion: 50 Impact ( i n . l b s . ) : D i r e c t : 20 Reverse: 15 D r y Time: S e t t o Touch ( M i n u t e s ) : 37 5009 Zapon ( H o u r s ) : 4 1/2

SOURCE: C a r g i l l , I n c . : CARGILL F o r m u l a r y : Formula P1843-125F

73

74

Water-Based Paint Formulations

Pounds

GsXws

80.1 4.2 26.3 10.5 3.6 1.8 1.4 96.4

9.31 0.56 3.91 0.71 0.20 0.24 0.17 11.58

183.0 9.9

21.28 1.32

10.6 1.8 2.4 1.4 0.8

1.58 0.23 0.34 0.18 0.10

0.8 401.4

0.10 48.19

C a r g i 11 Water R e d u c i b l e F a t t y A c i d A l k y d 74-7476 Aqueous Ammonia 28% sec-Butanol Special Black 4 A e r o s i l R972 By k - 02 0 S u r f y n o l 104 E D e i o n i z e d Water B a l l M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e F a t t y A c i d A l k y d 74-7476 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i u m I n t e r c a r 4% C a l c i u m A c t iv-8 E x k i n No. 2 D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 25.68 (By Volume): 2 2 . 3 6 Pigment t o B i n d e r R a t i o : 0 . 0 7 Pigment Volume C o n c e n t r a t i o n : 4 . 2 5 Weight Per G a l l o n : 8 . 3 6 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 9 1 (Grams/Li t e r ) : 349 W a t e r : C o s o l v e n t Weight R a t i o : 8 1 . 7 2 : 1 8 . 2 8 pH: 8 . 3 V i s c o s i t y Krebs-Stormer ( K U ) : 65 T y p i c a l Cured F i 1m P r o p e r t i es : Cure S c h e d u l e : 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 D ) : 87/72 P e n c i l Hardness: Pass 28 % C r o s s h a t c h Adhesion: 95 I m p a c t ( I n . L b s . ) : D i r e c t : 30 Reverse: <5 Dry Time: S e t t o Touch ( M i n u t e s ) : 25 500g Zapon ( H o u r s ) : 2 8

SOURCE: C a r g i l l ,

I n c . : C A R G I L L F o r m u l a r y : Formula P I 043-1 25G

Enamels

___Black A i r Dry E n m e 1

Cargi 1 1 Water Reducible Phenol i c Modi f i ed A1 kyd 74-7478 Aqueous Ammonia 28% sec-Butanol Special Black 4 Aerosil R972 Byk-020 Surfynol 1 0 4 E Deionized Water

Pounds

Gallons

84.9 4.5 27.9 11.2 3.8 1.5 102.2

9.87 0.60 4.15 0.75 0.21 0.26 0.18 12.27

193.9 10.5

22.55 1 .40

11.3 1.9 2.6 1.5 0.8

1.67 0.25 0.36 0.19 0.10

0.8 375.6

0.10 45.09

1.9

Ball Mill to a 7 Hegman Cargi 1 1 Water Reduci bl e Phenol i c Modi f i ed AI kyd 74-7478 Aqueous Ammonia 28% Premix the following, then add: sec-Butanol Intercar 6% Cobalt Intercar 6% Zi rconi urn Intercar 4% Calcium Acti v-8 Exkin No. 2 Deionized Water

Paint Properties: % Nonvolatile (By Weight): 27.21 (By Volume): 24.09 Pigment to Binder Ratio: 0 . 0 7 Pigment Volume Concentration: 4 . 1 8 Weight Per Gallon: 0 . 3 7 Theoretical VOC (Pounds/Gallon): 2 . 9 1 (Grams/Liter): 349 Water:Cosolvent Weight Ratio: 80.22:19.78 pH: 8 . 7 Viscosity Krebs-Stormer (KU): 70 Typical Cured Film Properties: Cure Schedule: 7 Days Air Dry Substrate: Cold Rolled Steel Gloss ( 6 0 / 2 0 ) : 87/75 Pencil Hardness: Pass 38 % Crosshatch Adhesion: 98 Impact ( i n . L b s . ) : Direct: 40 Reverse: < 5 Dry Time: Set to Touch (Hours): 3 / 4 5509 Zapon (Hours): >8 SOURCE: Cargill, Inc.: CARGILL Formulary: Formula P1843-125H

75

76

Water-Based Paint Formulations

B l a c k Enamel Material: Lbs. Water 100.0 Foamaster VL 2.0 C e l l o s i z e QP 4400 0.5 Methyl Carbit o 1 8.5 D i sperse-Ayd W22 4.4 A e r o s o l OT-75 2.3 A r o l on 820-W-49 105.6 AMP 95 1.9 Nalzin 2 50.0 Raven 1020 Beads 15.0 P e b b l e m i l l g r i n d t h e above t o a 7 Hegman. Letdown : A r o l on 820-W-49 572.0 Methyl Carbi t o 1 25.0 Water 20.3 R h e o l a t e 278 4.4 Ammonium H y d r o x i d e 1.9 Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 6 . 5 P i g m e n t / B i n d e r R a t i o : 0.20/1 .O P e r c e n t S o l i d s , Weight : 4 4 . 3 P e r c e n t S o l i d s , Volume: 39.0 V i s c o s i t y @ 25C, KU: 77 Pounds/Gallon: 9 . 1 4 pH: 8 . 5 - 9 . 0 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 88 Pounds/Gallon: 0 . 7

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2343-07

I n c . : Waterborne Handbook:

Gals. 12.00 0.25 0.04 1 .oo 0.50 0.25 12.00 0.25 1.52 1 .oo 65.00 3.00 2.44 0.50 0.25

Enamels

B l a c k Gloss Chromate Enamel M a t e r i a1 : K e l s o l 3918-B2G-70 Ammoni um Hydoxi de Raven 1255 S t r o n t i u m Chromate 51365 I g e p a l CTA-639 Water S t e e l b a l l m i l l t o a 7 Hegman g r i n d . Letdown : Kel s o l 3918-826-70 Ammoni um H y d r o x i d e Water Cobalt Hydrocure I 1 A c t iv-8 Butoxy Ethanol Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : P i g m e n t / B i n d e r R a t i o : .26/1 P e r c e n t S o l i d s , Weight: 26.2 P e r c e n t S o l i d s , Volume: 2 1 . 9 V i s c o s i t y @ 25C, KU: 35-45 pH: 8.2-8.5 Pounds/Gallon: 8 . 6 4 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 31 7 . 2 Pounds/Gallon: 2 . 6 4 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2403-19

Lbs. 123.60 4.30 20.60 25.75 1 .85 248.32

Gals. 14.49 0.58 1.41 0.83 0.21 29.81

128.96 7.00 283.25 5.29 1.26 13.80

15.12 0.94 34.00 0.70 0.16 1.84

10.48

I n c . : Waterborne Handbook:

77

78

Water -Based Paint Formulations

B l a c k G l o s s Enamel F l o w c o a t or D i p

Lbs.

Material : Water Ammoni um H y d r o x i de K e l s o l 3902-864-75 Premix and add t o above m i x t u r e : Cobalt Hydrocure I 1 Activ-8 Butoxy E t h a n o l

28.05 .93 13.36

4.69 2.33 4.90

.61 .29 .66

Premix d r i e r and s o l v e n t and add t o above m i x t u r e : 12% Manganese Cem-All 4.90 Butoxy E t h a n o l 5.83 Then add i n o r d e r : Cab-0-Si1 M5 S t r o n t i u m Chromate 31365 Raven 1020 F o a m k i l l FBF Sand m i l l t o 7 Hegman g r i n d . Letdown : Water Ammoni um H y d r o x i d e Kel s o l 3902-864-75 Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P i g m e n t / B i n d e r R a t i o : .16/1 P e r c e n t S o l i d s , Weight: 38.0 P e r c e n t S o l i d s , Volume: 32.6 Pounds/Gallon: 8.75 pH: 8.2-8.5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 264 Pounds/Gallon: 2.2 SOURCE: R e i c h h o l d Chemicals, Formul a t i on 1648-40

Percent:

Gals.

233.69 7.00 116.90

.66 .69

4.68 23.58 17.20 3.14

.26 .76 1.18 .44

182.43 6.26 257.16

21.90 .83 29.38

10.3

I n c . : Waterborne Handbook:

Enamels

B l a c k G l o s s Non-Chromate Enamel

Lbs.

M a t e r i a1 : Kel s o l 3919-826-70 Ammoni um H y d r o x i de C o b a l t Hydrocure I 1 A c t iv - 8 Butoxy Ethanol n-Butanol Heucophos ZPO A l c o p h o r 827 Raven 1255 Water S t e e l b a l l m i l l t o a 7 Hegman g r i n d .

169.11 9.64 5.79 0.96 22.91 10.33 56.55 6.99 9.76 252.23

Gals. 19.55 1.29 0.76 0.12 3.05 1.53 1.83 0.34 0.67 30.28

Letdown : Kel s o l 391 9-826-70 Ammoni um H y d r o x i de Water

106.14 1 .31 234.41

12.27 0.17 28.14

Anal y s i s: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 9 . 6 3 Pigment/Binder R a t i o : .33/1 P e r c e n t S o l i d s , W e i g h t : 30.3 P e r c e n t S o l i d s , Volume: 2 3 . 7 V i s c o s i t y @ 25C, #4 F o r d , S e c s . : 35-45 pH: 8 . 2 - 8 . 5 Pounds/Gallon: 8 . 8 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 350.0 Pounds/Gallon: 2 . 9 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2403-16

I n c . : Waterborne Handbook:

79

80

Water-Based Point Formulations

B l a c k H i s h G l o s s B r u s h i n g Enamel M a t e r i a1 : Water Triethylamine B u t y l Carbi t o 1 Kel s o l 3970-64-75 Raven 1020 Foamki 11 6390 S t e e l b a l l m i l l t o a 7 Hegman g r i n d . Letdown : Kel s o l 3970-G4-75 Ammoni um H y d r o x i d e Propasol P Premi x : Cobalt Hydrocure I 1 Activ-8 Water

Lbs. 86.0 7.0 12.0 98.0 24.0 0.5

269.0

Gals. 10.32 1.16 1.52 11 .oo 1.64 0.07

20.0

30.19 1 .13 2.72

6.0 1 .o 327.0

0.79 0.13 39.26

8.5

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 5 . 3 Pigment/Binder R a t i o : .09/1 P e r c e n t S o l i d s , Weight: 3 4 . 8 P e r c e n t S o l i d s , Volume: 3 1 . 0 V i s c o s i t y @ 25C, KU: 90-95 Pounds/Gallon: 8 . 6 0 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 326 Pounds/Gallon: 2.72 SOURCE: R e i c h h o l d Chemicals, Inc.: Waterborne Handbook: F o r m u l a t i o n 2025-73-1A

Enamels

B l a c k Hiqh G l o s s Enamel

Lbs. Material : 86.6 A r o l on 850-W-45 83.3 Water 8.5 Methyl Carbi t o 1 4.4 D i s p e r s e Ayd W22 2.3 A e r o s o l OT-75 1.8 Dapro 1181 15.0 Raven 1020 Premix t h e above, t h e n p e b b l e m i l l g r i n d t o a 7 Hegman 529.2 A r o l on 850-W-45 39.4 Butoxy Ethanol 29.7 Methyl Carbi t o 1 4.2 KP 140 1.9 S u r f y n o l 104 BC 2.1 15% S o l u t i o n FC430 4.3 Ucar SCT 200 43.7 Water 1.9 Ammonium H y d r o x i d e Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : P i g m e n t / B i n d e r R a t i o : 0.05/1 . O O P e r c e n t S o l i d s , W e i g h t : 36.5 P e r c e n t S o l i d s , Volume: 33.0 V i s c o s i t y @ 25C, #4 F o r d , S e c s . : 94 G l o s s ( 6 0 ) : 94 Pounds/Gallon: 8 . 6 pH: 8 . 0 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 233 Pounds/Gal 1on : 1 .94 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2210-1

3.0

I n c . : Waterborne Handbook:

Gals. 10.00 10.00 1 .oo 0.50 0.25 0.25 1 .oo 61.25 5.25 3.50 0.50 0.25 0.25 0.50 5.25 0.25

81

82

Water-Based Paint Formulations

B l u e H i g h G l o s s Enamel M a t e r i a1 : K e l s o l 3961 -826-75 Ammoni urn H y d r o x i de n-Butanol Butoxy Ethanol Water Heucophthal B l u e RF BT 698D Raven 1020 Y.I.Q. 2288D S t r o n t i u m Chromate 5-1365 T i -Pure R-902 P e b b l e m i l l t o 6-7 Hegman g r ii n d . Letdown : K e l s o l 3961-82G-75 sec-Butanol n-Butanol Ammoni um H y d r o x i de Water Premi x : A c t iv-8 Cobalt Hydrocure I 1 Butoxy Ethanol M e t h y l E t h y l Ketone

Lbs. 43.95 2.91 3.59 3.89 71.75 4.87 2.91 2.91 17.94 35.87

Gals. 5.13 0.38 0.53 0.52 8.61 0.36 0.19 0.08 0.56 1.04

242.15 5.84 7.71 7.71 385.65

28.29 0.87 1.14 1.02 46.30

1.17 6.62 0.98 26.91

0.14 0.86 0.13 4.01

N o t e : Water may be used t o r e p l a c e t h e MEK f o r a l o w e r CARB value. Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 8 . 1 8 Pigment/Binder R a t i o : .3/1 P e r c e n t S o l i d s , Weight: 31.87 P e r c e n t S o l i d s , Volume: 27.25 V i s c o s i t y @ 25C, KU: 75-80 Pounds/Gallon: 8 . 7 4 pH: 8.2-8.5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 351 Pounds/Gallon: 2.93 SOURCE: R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i o n 2116-51-2

Enamels

B l a c k Low G l o s s Enamel M a t e r i a1 : K e l s o l 3963-826-70 C o b a l t Hydrocure I 1 Activ-8 n-Butanol Butoxy E t h a n o l Propoxy P r o p a n o l Ammoni um H y d r o x i de Raven 1255 Beads Novaci t e L207A Atomi t e S y l o i d 83 P a t c o t e 519 Water S t e e l b a l l m i l l t o 7 Hegman g r i n d Letdown : K e l sol 3963-B2G-70 Ammoni um H y d r o x i de n B u t ano 1 P a t c o t e 519 Water N o t e : Premix t h e c o b a l t d r i e r , adding t o t h e r e s i n .

-

Activ-8,

Lbs.

Gals. 16.53

141.33 4.16 0.72 1.15 1.20 1.18 6.95 11.52 34.70 34.88 8.18 1.17 363.10

57.97 2.91 1.69 0.76 214.25 and n - b u t a n o l

0.55 0.09 0.17 0.16 0.16 0.93 0.79 1.57 1.55 0.49 0.17 43.59

6.78 0.39 0.25 0.11 25.72 before

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 22.78 P i g m e n t / B i n d e r R a t i o : 0.64/1 P e r c e n t S o l i d s , W e i g h t : 26.42 P e r c e n t S o l i d s , Volume: 19.85 V i s c o s i t y @ 25C, #4 F o r d , Secs.: 35-45 Pounds/Gallon: 8 . 8 8 pH: 8 . 3 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 271.2 Pounds/Gal 1on: 2 . 2 6

SOURCE:

R e i c h h o l d Chemicals, Formul a t i on 2344-75

I n c . : Waterborne Handbook:

83

84

Water-Bused Paint Formulations

B l u e A c r y l i c Emulsion Enamel I n q r e d ie n t s : Coroc A-2678-M 2-butoxyethanol S u r f y n o l 104BC S u r f y n o l DF-75 Water T i P u r e R-900

Pounds 22.22 7.48 7.81 1.28 7.48 99.68

Gallons 2.52 1 .oo 1.04 0.15 0.90 2.90

Pre-mix f i r s t f o u r i n g r e d i e n t s , t h e n add w a t e r w i t h a g i t a t i o n . Add pigment s l o w l y w i t h a g i t a t i o n . Cowles t o a #7 Hegman w i t h a h i g h speed d i s p e r s a t o r . A d j u s t g r i n d v i s c o s i t y w i t h w a t e r f r o m below i f n e c e s s a r y . L e t down w i t h : 66.64 Chempol 20-4301 586.40 4.13 2-butoxyethanol 31 . O O 2.50 B u t y l Carbi t o 1 19.82 0.79 Dibutyl Phthalate 6.85 0.24 Nuocure CK-10 1.95 3.51 Michem 39235 29.27 2.23 UCD 4820Q 19.94 11.45 Water ( h o l d t o a d j u s t v i s c o s i t y ) 95.38 Pre-mix c o - s o l v e n t s , p l a s t i c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r s e e d i n g . Add t h e wax d i s p e r s i o n t o t h e " l e t down" w i t h a g i t a t i o n . A f t e r m i x i n g w e l l , add t h e g r i n d t o t h e " l e t down" w i t h good a g i t a t i o n . F i n a l l y , add t h e b l u e t i n t p a s t e s l o w l y t o t h e b l e n d e d p a i n t and mix u n t i l w e l l d i s p e r s e d . A l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7.6, as t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . P r o p e r t ie s : T o t a l s o l i d s , % by w e i g h t : 37.50% T o t a l s o l i d s , % by volume: 28.85% Wei g h t / g a l 1on : 9.37 1b s / g a l PVC: 11.10 P i g m e n t / b i n d e r r a t i o : 0.42 VOC: 1.97 l b s . / g a l V i s c o s i t y : 23" #2 Zahn pH: 7 . 5 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y Set t o touch: 17' Dust f r e e : 20' Tack f r e e : 7 5 ' - 9 0 ' Dry through: 75'-90'

.

.

.

SOURCE:

Freeman Polymers D i v i s i o n : Chempol 20-4301-E F o r m u l a t i o n

Enamels

B l u e Enamel M a t e r i a1 s 255 R e s i n WB-408 (80% NVM) 18 Triethylamine 36 A m i no c r o s s l in k e r , Cymel ( 1 ) 2 Manganese n a p h t h e n a t e , 6% 443 Water 40 Phthalocyanine b l u e ( 2 ) 8 Titanium dioxide (3) Properties: Pigment/binder r a t i o : 0.2/1 . O M e l a m i n e / a l k y d r a t i o : 15/85 N o n - v o l a t i l e (NVM), w t %: 39 V i s c o s i t y , #4 F o r d cup, s e c : 35-45 pH: 7 . 5 - 8 . 0 S t a b i l i t y , 15 days a t 49C ( 4 ) : pass ( 1 ) Cymel 301 ( 2 ) M o n a s t r a l B l u e BT ( 3 ) T i - P u r e R-900 ( 4 ) Less t h a n 5 seconds v i s c o s i t y change o r 0 . 5 pH change f o r pass The pigmented enamel i s compounded u s i n g a p e b b l e m i l l . The r e s i n, ami ne s o l u b i 1 iz e r , ami no c r o s s l in k e r , pigment , and 80% o f t h e w a t e r a r e added t o t h e m i l l . The enamel i s d i s p e r s e d t o a minimum o f #7 Hegman g r i n d . The enamel i s t h e n a d j u s t e d t o t h e c o r r e c t pH and v i s c o s i t y u s i n g a d d i t i o n a l amine and w a t e r r e s p e c t iv e l y Performance p r o p e r t i e s o f b l u e e n a m e l ( 1 ) : S u b s t r a t e : B-37(3): P e n c i l hardness: H Sward h a r d n e s s : 46 C r o s s h a t c h a d h e s i o n : 5B 1 / 8 - i n c h c o n i c a l bend, % p a s s : 100 Impact r e s i s t a n c e , i n - l b : d i r e c t : 80 r e v e r s e : 80 60 g l o s s , %: 9Ot Mar r e s i s t a n c e : good S a l t s p r a y r e s i s t a n c e , 250 h r : pass S u b s t r a t e : CRS(4): P e n c i l hardness: H Sward hardness: 48 Crosshatch adhesion: 5B 1 / 8 - i n c h c o n i c a l bend, % p a s s : 100 Impact r e s i s t a n c e , i n - l b : d i r e c t : 80 r e v e r s e : 80 60 g l o s s , %: 90+ Mar r e s i s t a n c e : good ( 1 ) C u r e c y c l e 20 m i n u t e s a t 177C ( 3 ) B o n d e r i t e 37 t r e a t e d c o l d r o l l e d s t e e l ( 4 ) L e s s t h a n 5 seconds v i s c o s i t y change o r 0 . 5 pH f o r pass SOURCE: Amoco Chemical Co.: Water-Borne Bake A l k y d s Based on Amoco TMA and I P A : T a b l e 5 & 7 Formula

.

85

86

Water-Based Paint Formulations

B l u e H i g h G l o s s Enamel M a t e r i a1 : Water Ammoni um H y d r o x i d e K e l s o l 3970-64-75 Premix : A c t iv-8 C o b a l t Hydrocure I 1 Manganese Hydrocure Butoxy E t h a n o l He1 iogen B1 ue L6975F T i t a n o x 2160 S t e e l b a l l m i l l t o 6+ Hegman g r i n d . Letdown : Water Butoxy E t h a n o l Ammonium H y d r o x i d e K e l s o l 3970-G4-75

Lbs.

Gals 30.98 1.72 14.49

1.29 2.58 5.16 12.91 40.02 40.02

0.17 0.34 0.68 1.72 3.02 1.12

154.92 6.46 6.46 225.93

18.59 0.86 0.86 25.36

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 1 2 . 8 Pigment/Binder R a t i o : . 3 / 1 P e r c e n t S o l i d s , Weight: 3 8 . 7 P e r c e n t S o l i d s , Volume: 32.3 V i s c o s i t y @ 25C, #4 Ford, Secs.: 38-42 Pounds/Gallon: 8 . 9 7 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i ng w a t e r ) : G r a m s / L i t e r : 278 Pounds/Gallon: 2.32

SOURCE:

.

258.20 12.91 129.10

R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i o n 2079-42-2

Enamels

B l u e Semi-Gloss

Enamel

.

Lbs. M a t e r i a1 : 103.70 Kel s o l 3980-G4-75 2.07 S u r f y n o l 104E 2.07 Defoamer L-475 10.37 E t h y l e n e G l y c o l Monobutyl E t h e r 5.19 D i m e t h y l e t h a n o l A m i ne (DMEA) 82.96 Water 207.41 T i -Pure R-902 2.07 A-4434 Tacoma B l u e 62.22 T a l c 399 Pebble m i l l o r sand m i l l t o a 6 1/2 Hegman g r i n d . Letdown : Kel s o l 3980-G4-75 Cyme1 327 E t h y l e n e G l y c o l Monobutyl E t h e r DMEA Propoxy Propanol Water

Inc.:

Gals 11.52 0.25 0.28 1.38 0.70 9.96 6.07 0.17 2.77

17.26 7.35 1.38 1.40 2.82 36.67

155.56 72.07 10.37 10.37 20.74 305.41

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 25.28 P i g m e n t / B i n d e r R a t i o : 1.04/1 P e r c e n t S o l i d s , Weight: 5 0 . 5 5 P e r c e n t S o l i d s , Volume: 35.62 V i s c o s i t y @ 25C, KU: 70-75 Pounds/Gal 1on : 10.53 pH: 8 . 2 - 8 . 6 Resin/Melamine R a t i o : 72/75 % R e d u c t i o n t o 30 Secs., #2 Zahn, w i t h w a t e r : VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 294 Pounds/Gallon: 2.45 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2185-66

87

15

Waterborne Handbook:

88

Water-Based Paint Formulations

C l e a r Enamel M a t e r i a1 : P a r t A: Epi-Rez WD-510 Epoxy R e s i n 2-Propoxyethanol ( 2 ) Water

-__ Pounds

Gal l o n s

79.0 7.6 90.1

8.18

10.82

P a r t B: CMD 9790 A c r y l i c R e s i n 2-Propoxyethanol ( 2 ) M i x w e l l u n d e r l o w a g i t a t i o n and add: Water

653.0 22.7

75.50 3.00

12.5

1 .50

Composite B l e n d : Viscosity Part A 12 seconds #4 F o r d Cup Part B 114 KU P a r t s A and B 94 K U

176.7 688.2

20.00 80.00

( 2 ) E k t a s o l v e EP T y p i c a l C o a t i n g P r o p e r t i es : T o t a l Weight S o l i d s , p e r c e n t : 40.8 T o t a l Volume S o l i d s , p e r c e n t : 38.0 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gallon: 2.33 G r a m s / L i t e r : 280 Resin Composition ( S o l i d s ) : A c r y l i c R e s i n : 77.6% Epoxy R e s i n : 22.4%

SOURCE: S h e l l Chemical Co. : 24-258 C l e a r Enamel

1 .oo

Enamels

89

C l e a r Enamel ( f o r u s e w i t h p r e d i s p e r s e d c o l o r a n t s ) Pounds Materials: Grind Portion: 240.0 K e l s o l 3905 1.9 Aquacat 3.8 Magnacat 0.9 P a t c o t e 519 0.9 P a t c o t e 577 5.1 28% Ammonia 321.7 Water M i x w e l l ( % n e u t r a l i z a t i o n = 5 8 % , pH 5 . 8 t o 6 . 0 ) Add i n o r d e r , w i t h a g i t a t i o n : 186.7 Rhoplex WL-71 32.2 Water 20.0 B u t y l Carbit o 1 14% Ammonia ( t o pH 8 . 4 ) Water 21.4 N o t e : Reduce t o s p r a y v i s c o s i t y w i t h 87/13 w a t e r / B u t y l

----

Gallons 27.93 0.24 0.49 0.12 0.12 0.61 38.76

21.71 3.86 2.52

----

2.58 Cellosolve

Formulation Constants: Pounds/gallon: 8.4 N o n - v o l a t i l e s ( W t . ) : 31.3% ( V o l . ) : 28.2% Rhoplex WL-71/Kelsol 3905: 30/70 pH: 8 . 4 V i s c o s i t y : 300-500 c p s . VOC: 1 . 9 7 l b s . / g a l . Note: C o l o r s a r e o b t a i n e d b y a d d i n g p i g m e n t d i s p e r s i o n s ( C o l a n y l s e r i e s ) t o t h i s c l e a r enamel w i t h good m i x i n g . Code No. Description P i gment/Bi n d e r Lb./100 G a l . 16-2010 Green 8G 13/87 70 18-1004 B l a c k PR-A 5/95 40 11-1 109 Y e l l o w OT 13/87 70

SOURCE:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-71: F o r m u l a t i o n WL-71-5

90

Water-Based Paint Formulations

G l o s s W h i t e Enamel M a t e r i a1 : Part A: Epi-Rez WD-510 Epoxy R e s i n 2-Propoxyethanol ( 2 ) Water

Pounds

Gallons

68.0 22.2 83.3

7.07 2.93 10.00

P a r t B: Water 73.3 8.80 Potassium T r i p o l y p h o s p h a t e 2.0 0.12 M i x w e l l a t l o w speed, t h e n add : Defoamer ( 4 ) 2.0 0.26 Surfactant (5) 0.23 2.0 Water D i s p e r s i b l e L e c i t h i n 6 ) 0.52 4.5 R u t i l e Titanium Dioxide (7) 250.0 7.33 H i g h speed d i s p e r s e f o r 5-1 m i n u t e s a t 2000 rom. t h e n add: CMD 9790 A c r v l i c R e s i n 108'. 0. 12.50 H i g h speed d i s p e r s e t o a t e x t u r e o f 9-10 P.S.C., t h e n add: Defoamer 2.0 0.26 2-Propoxyethanol 22.7 3.00 CMD 9790 A c r y l i c R e s i n 404.0 46.98 Composite B l e n d : Part A Part B P a r t s A and B

V i scosi t y 12 seconds #4 F o r d Cup 120 KU 90 KU

173.5 870.5

20.00 80.00

2 ) E k t a s o l v e EP 4 ) C o l l o i d 640 5 ) T r i t o n X-100 6) A l c o l e c 439-C 7 ) T i t a n o x 2020 or Tronox CR800 Typical Coating Properties: T o t a l Weight S o l i d s , p e r c e n t : 5 1 . 0 T o t a l Volume S o l i d s , p e r c e n t : 3 8 . 0 PVC, p e r c e n t : 1 9 . 3 Resin Composition: Epoxy R e s i n , p e r c e n t : 24.0 A c r y l i c R e s i n , p e r c e n t : 76.0 R e d u c t i o n t o Spray V i s c o s i t y : b y Volume: P a r t s A and B Water

46 p a r t s 1 part

SOURCE: S h e l l Chemical Co. : 24-309 Gloss W h i t e Enamel U s i n g CMD 9790 A c r y l i c R e s i n

Enamels

G l o s s W h i t e Enamel _(MaximumA c i d R e s i s t a n c e 1 M a t e r i a1 : P a r t A: Epi -Rez WJ-5522 Epoxy R e s i n H i g h F l a s h A r o m a t i c Hydrocarbon ( 2 ) 2-Propoxyethanol ( 3 ) Water

Pounds

Gal l o n s

501.2 22.3 22.7 38.9

56.00 3.00 3.00 4.67

P a r t 8: CMD 560-8290 C u r i n g Agent 81 . o Defoamer ( 4 ) 4.0 R u t i l e Titanium Dioxide (5) 250.0 Water 33.3 H i g h speed d i s p e r s e t o a t e x t u r e o f 10 P . S . C . Water 96.1 Glacial Acetic Acid 2.9

9.17 0.56 7.74 4.00 11.53 0.33

2 ) H i - S o l 15 o r Enco A r o m a t i c 150 3) E k t a s o l v e EP 4) P a t c o t e 847 5 ) R-960 H i g h G l o s s , o r g a n i c t r e a t m e n t Composite B1end : Part A Part B

Viscosity 97 K . U . 75 K . U .

R e d u c t i o n f o r C o n v e n t i o n a l Spray: P a r t s A and 0 Water

585.1 467.3 by volume 25 p a r t s 1 part

Typical Coating Properties: T o t a l Weight S o l i d s , p e r c e n t : 54.6 T o t a l Volume S o l i d s , p e r c e n t : 41.1 PVC, p e r c e n t : 18.8 V o l a t i l e O r g a n i c Compounds (V.O.C.): Pounds/Gallon: 2.07 G r a m s / L i t e r : 249 I n d u c t ion T i me, m i n u t e s : 30 R e s i n C o m p o s i t i o n (based on s o l i d s ) : Epoxy Resin, p e r c e n t C u r i n g Agent, p e r c e n t SOURCE: S h e l l Chemical Co.:

85.0 15.0

24-296 G l o s s W h i t e Enamel

66.67 33.33

91

92

Water-Based Paint Formulations

C l e a r Enamel maximum A c i d R e s i s t a n c e ) M a t e r i a1 : Part A: E p i -Rez WJ-5522 Epoxy Resi n H i g h F l a s h A r o m a t i c Hydrocarbon ( 2 ) 2-Propoxyethanol ( 3 ) Water

-__ Pounds

Gal 1ons

540.8 32.5 33.2 48.6

60.42 4.37 4.37 5.84

87.6 4.0 121 . o

9.92 0.56 14.52

655.1 212.6

75.00 25.00

P a r t B: CMD 560-8290

C u r i n g Agent

Defoamer ( 4 ) Water Composite B l e n d : Part A Part 0 Parts A & 0

Viscosity 93 K.U. 61 K . U . 75 K . U .

15 o r Enco A r o m a t i c 150 3 ) E k t a s o l v e EP 4) P a t c o t e 847 Defoamer

2 ) Hi-Sol

Typical Properties: T o t a l Weight S o l i d s , p e r c e n t : 40.3 T o t a l Volume S o l i d s , p e r c e n t : 3 6 . 1 Vol a t i 1e O r g a n i c Compounds : Pounds/Gallon: 2 . 5 7 G r a m s / L i t e r : 308 I n d u c t i o n Time, m i n u t e s : 30 Resi n Composi t i on (based on s o l i d s ) : Epoxy Resi n, p e r c e n t : C u r i n g Agent, p e r c e n t

85.0 15.0

R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y volume) None R e q u i r e d SOURCE: S h e l l Chemical C o . :

24-294 C l e a r Enamel

Enamels

C l e a r Enamel (Maximum S o l v e n t and A b r a s i o n R e s i s t a n c e 1 M a t e r i a1 : Part A: €pi-Rez WJ-5522 Epoxy R e s i n H i g h F l a s h A r o m a t i c Hydrocarbon ( 2 ) 2-Propoxyethanol ( 3 ) Water P a r t B: CMD 560-0290 C u r i n g Agent Defoamer ( 4 ) Water

Pounds

Gal 1ons

477.2 32.5 33.2 107.9

53.31 4.37 4.37 12.95

145.8 4.0 66.1

16.51 0.56 7.93

650.8 215.9

75.00 25.00

2 ) H i - S o l 15 o r Enco A r o m a t i c 150 3 ) E k t a s o l v e EP 4) P a t c o t e 847 Composite B l e n d : Part A Part B Typical Coating Properties: V i s c o s i t y , P a r t A : 68 KU P a r t B: 64 KU P a r t A + B: 75 KU T o t a l Weight S o l i d s , p e r c e n t : 40.4 T o t a l Volume S o l i d s , p e r c e n t : 36.0 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gallon: 2.84 G r a m s / L i t e r : 340 I n d u c t i o n Time, m i n u t e s : 30 R e s i n C o m p o s i t i o n (based on s o l i d s ) : Epoxy R e s i n , p e r c e n t : 7 5 . 0 C u r i ng Agent, p e r c e n t : 25.0 R e d u c t i o n f o r C o n v e n t i o n a l Spray (by v o l u m e ) : None r e q u i r e d

SOURCE:

S h e l l Chemical Co.:

24-295 C l e a r Enamel

93

94

Water-Based Paint Formulations

Economical F l a t B l a c k A i r D r y Enamel Pounds

Gal l o n s

111.3 134.8 7.7 5.7 6.7 2.8 1.1 12.0 226.4

12.87 6.27 0.52 0.31 1.11 0.40 0.12 1.79 27.18

1.5 0.9 0.4 0.2

0.22 0.12 0.05 0.03

E x k i n No. 2 Byk-080 sec-Butanol

9.3 2.6 1.1 52.3

1.54 0.34 0.12 7.77

A c r y s o l ASE-60 D e i o n i zed Water

31.2 31 .2

3.42 3.75

Dei o n i zed Water

267.0

32.07

C a r g i l l Water R e d u c i b l e S t y r e n a t e d A l k y d Copolymer 74-7425 ASP 170 Aluminum S i l i c a t e Special Black 4 A e r o s i l R972 Triethylamine M-P-A

1075

Byk-080 sec-Butanol Dei o n i zed Water Sand M i l l t o a 5 Hegman Premix t h e f o l l o w i n g , t h e n add: sec-Butanol 5% C o b a l t Hydro Cure Manganese Hydro Cure I 1 A c t iv-8 T r i e t h y l ami ne

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 26.39 (By Volume): 16.76 Pigment t o B i n d e r R a t i o : 1.63 Pigment Volume C o n c e n t r a t i o n : 42 46 Weight Per G a l l o n : 9.07 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3.50 (Grams/Li t e r ) : 4 9 . Water:Cosolvent Weight R a t i o : 82.00:18.00 ~

pH: 8.0-8.5

V i s c o s i t y #4 F o r d Cup (Seconds): Anti-Sag Resistance: E x c e l l e n t T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: I 7 Days A i r D r y Substrate: Cold Rolled Steel G l o s s (60/20): 5/0 P e n c i l Hardness: Pass 4 6 % C r o s s h a t c h Adhesion: 50 Impact ( I n . L b s . ) : D i r e c t : 30 Reverse: <5

SOURCE: C a r g i l l ,

Inc.:

57

C A R G I L L F o r m u l a r y : Formula P 1 8 8 7 - 5 8 A

Enamels

Gloss B l a c k Enamel Sand M i l l ( 3 0 m i n u t e s ) : Cyme1 303 Tamol 731 (25%) Butyl Cellosolve Isopropanol Water DMAE (20% i n w a t e r ) Raven 1035 Letdown : Sand m i l l g r i n d A c r y s o l WS-68 (38%) PTSA* (10%) L-5310 (30% i n B u t y l C e l l o s o l v e ) n-Butanol

P a r t s by Weiqht 135.6 1.2 21 . o 21 . o 84.0 1.5 35.7 150.3 715.5 6.8 2.2 5.2

Enamel C o n s t a n t s : T o t a l s o l i d s , %: 40.7 P i g m e n t / b i n d e r r a t i o : 5/95 A c r y l i c / m e l a m i n e r a t i o : 80/20 % C a t a l y s t (PTSA) on b i n d e r s o l i d s : 0 . 2 % L-5310 on b i n d e r s o l i d s : 0 . 2 Water/organi c r a t i 0: By volume: 8 9 . 8 / 1 0 . 2 By w e i g h t : 9 1 . 1 / 8 . 9 pn: 7 . 6 V i s c o s i t y , s e c . (No. 4 F o r d Cup): 23 V o l a t i l e O r g a n i c Compounds (VOC): 130 g m s . / l

*

1 0 PTSA/10 DMAE/80 Water

SOURCE:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYSOL WS-68: Formul a t i on WS-68-3

95

96

Water-Based Paint Formulations

G l o s s B l a c k Enamel Materials: Grind Portion: K e l s o l 3960 Aquacat Magnacat 28% Ammonia Water P a t c o t e 519 P a t c o t e 577 Raven 420 S t r o n t i u m Chromate

Pounds

Gal 1ons

89.2 1.9 3.7 2.2 142.5 0.9 0.9 10.0 10.0

10.36 0.23 0.48 0.26 17.18 0.12 0.10 0.68 0.32

149.0 3.7 176.4

17.30 0.44 21.25

185.0 31.8 21.2 21.2

21.52 3.83 2.67 2.56

S t e e l b a l l m i l l t o 7 t o 7 1/2 N . S . K e l s o l 3960 28% Ammonia Water

1 ) Premix

1

Add i n o r d e r w i t h good a g i t a t i o n : Rhopl ex WL-71 Water B u t y l Carbi t o 1 Water 14% Ammonia ( t o pH 7 . 3 t o 7 . 5 )

----

N o t e : Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l

-----

Cellosolve

F o r m u l a t i o n Constants: Pounds/gallon: 8.56 N o n - v o l a t i l e s ( W t . ) : 33.1% ( V o l . ) : 29.1% P i g m e n t / B i n d e r R a t i o : 8/92 pvc: 3.5% Rhopl ex WL-71 /Kel s o l 3960: 30/70 pH: 7 . 3 t o 7 . 5 V i s c o s i t y : 400-600 c p s . VOC: 1 . 8 7 l b s . / g a l . SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-71: F o r m u l a t i o n WL-71-9

Enamels

G l o s s B l a c k Enamel (No Chromate) Materials: Grind Portion: K e l s o l 3960 Aq uaca t Magnacat 28% Ammonia Water P a t c o t e 519 P a t c o t e 577 Raven 420

Pounds

Gal l o n s

89.2 1.9 3.7 2.2 142.5 0.9 0.9 13.3

10.36 0.23 0.48 0.26 17.18 0.12 0.10 0.91

149.0 3.7 176.4

17.30 0.44 21.25

185.0 31.8 21.2

21.52 3.83 2.67

S t e e l b a l l m i l l t o 7 t o 7 1/2 N . S . K e l s o l 3960 28% Ammonia Water

1 ) Premix )

Add i n o r d e r w i t h good a g i t a t i o n : Rhoplex WL-71 Water B u t y l Carbi t o 1 14% Ammonia ( t o pH 7 . 3 t o 7 . 5 )

-----

-----

Note: Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l C e l l o s o l v e F o r m u l a t i o n Constants: P o u n d s / g a l l o n : 8.5 N o n - v o l a t i l e s ( W t . ) : 33.4% ( V o l . ) : 30.1% P i gment/Bi nder : 5/95 PVC: 3 . 2 % Rhopl ex WL-71 / K e l s o l 3960: 30/70 pn: 7 . 3 t o 7 . 5 V i s c o s i t y : 200-600 c p s . Grind: 7 t o 7 1/2 N . S . VOC: 1 . 8 7 l b s . / g a l .

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-71: F o r m u l a t i on WL-71-10

97

98

Water-Based Paint Formulations

Gloss Black Forced-Dry Enamel Materials: Grind Portion: Kelsol 3905 Aquaca t Magnacat 28% Ammoni a Water Patcote 519 Patcote 577 Raven 420 Steel ball mill to 7 1/2 N.S. Kelsol 3905 28% Ammoni a

1

Water

1

)

Premix

Pounds

Gallons

89.2 1.9 3.7 2.2 142.5 0.9 0.9 13.3

10.36 0.23 0.48 0.26 17.18 0.12 0.10 0.91

149.0 3.7 176.4

17.30 0.44 21 . 2 5

185.0 31 . 8 21.2

21.52 3.83 2.67

21.2

2.56

( % Neutralization = 70%, pH 6 . 0 to 6 . 3 )

Add in order with good agitation: Rhopl ex WL-71 Water Butyl Carbi to1 14% Ammonia (to pH 7 . 3 to 7 . 5 ) Water

----

-----

Note: Reduce for spray with 87/13 water/Butyl Cellolsolve Formulation Constants: Pounds/gallon: 8 . 5 Non-volatiles (Wt.): 32.3% (Vol.): 29.1% Pigment/Binder Ratio: 5/95 PVC: 3 . 2 Rhopl ex WL-71 /Kel sol 3905: 30/70 pn: 7 . 3 to 7 . 5 Viscosity: 200-400 cps. VOC: 1.87 lbs./gal.

Source: Rohm and Haas Co.: Industrial Coatings: RHOPLEX WL-71: Formu 1 at i on WL-7 1-2

Enamels

99

Gloss Green Enamel M a t e r ia1 s : Grind Portion: Chempol 10-0091 Aq uac at Magnacat 28% Ammonia Water P a t c o t e 519 P a t c o t e 577 Chrome O x i d e X-1134 I m p e r i a1 B r a z i 1 Ye1 l o w X-286C Butyl Cellosolve B u t y l Carbi t o 1

Pounds

Gal 1ons

88.2 1 .o 3.7 1.7 142.3 0.9 0.9 38.3 6.3 5.0 5.0

10.02 0.23 0.48 0.20 17.17 0.12 0.12 0.87 0.53 0.67 0.63

147.4 3.1 174.5

17.14 0.37 21.02

183.1 31.5 16.0

21 .29 3.79 2.01

21 . a

2.53

S t e e l b a l l m i l l t o 7 1 / 2 N.S. Chempol 10-0091 28% Ammonia Water

) ) Premix

1

( N e u t r a l i z a t i o n = 9 3 % , pH 6 . 1 t o 6 . 4 ) Add i n o r d e r w i t h good a g i t a t i o n : Rhoplex WL-71 Water B u t y l Carbi t o 1 14% Ammonia ( t o pH 7 . 3 t o 7 . 5 ) Water

-----

N o t e : Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l

-----

Cellosolve.

Formulation Constants: Pounds/gallon: 8.68 N o n - v o l a t i l e s ( W t . ) : 34.5% ( V o l . ) : 28.0% P i g m e n t / B i n d e r R a t i o : 15/85 p v c : 4.8% Rhopl ex WL-?l/Chempol 10-0091 : 30/70 N e u t r a l i z a t i o n ( f i n a l based on Chempol 10-0091 s o l i d s ) : pH: 7 . 3 t o 7 . 5 V i s c o s i t y : 200-400 c p s . VOC: 2 . 1 6 l b s . / g a l . SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : Formul a t ion WL-71-8

170%

RHOPLEX WL-71:

100

Water-Based Paint Formulations

Gloss Maintenance Enamel--Deep

Base

A g l o s s maintenance enamel w i t h good c o m p a t i b i l i t y w i t h H u l s

America 896 C o l o r System. Insredients: Pigment G r i nd: Water Methyl Carbi t o 1 Solvent B u t y l C a r b i t o l Solvent Dispersant ( 1 ) P r e s e r v a t i v e (2) Nonionic Surfactant (3) Antifoam ( 4 ) Urethane A s s o c i a t i v e T h i c k e n e r ( 5 ) Titanium Dioxide (6)

L e t Down: Water Ucar T h i c k e n e r SCT-275 Ucar F i l m e r IBT Antifoam ( 3 ) Mix: Sodium N i t r i t e Water Ucar L a t e x 430 (43.0%)

Pounds

Gallons

25.0 34.0 23.8 4.4 1.2 4.7 2.1 12.9 125.0

3.00 4.00 3.00 0.50 0.13 0.50 0.25 1.50 3.65

109.6 21.5 31.7 2.1

13.16 2.50 4.00 0.25

1.o 4.2 548.1

0.06 0.50 63.00

Suppl ie r s : ( 1 ) D i s p e r s a n t - "Tamol" 165 o r e q u i v a l e n t ( 2 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 3 ) N o n i o n i c S u r f a c t a n t - " B o r c h i g e n " DFN o r e q u i v a l e n t ( 4 ) A n t i f o a m - "Foamex" 1488 o r e q u i v a l e n t ( 5 ) Urethane A s s o c i a t i v e T h i c k e n e r - " A c r y s o l " RM-1020 o r e q u i Val e n t ( 6 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 12.3 T o t a l S o l i d s , %: b y Volume: 29.5 b y Weight: 39.5 V i s c o s i t y ( e q u i 1 ib r a t e d ) : Stormer, KU: 89 I C I , Poise: 1.4 pH, i n i t i a l : 9 . 2 Weight p e r G a l l o n , l b : 9.51 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 w k s a t 120F (49C): Pass Foam C o n t r o l : Good VOC, g / l : 270.7 F i 1m P r o p e r t ies : C o n t r a s t R a t i o 0.003 i n : 0.942 R e f l e c t a n c e , %: 89.3

SOURCE:

Ucar Emulsions Systems: UCAR L a t e x 430: S u g g e s t i o n M-2205

Formulation

Enamels

101

Gloss W h i t e Enamel B a l l M i l l Grind; R u t i l e t i t a n i u m d i o x i d e (RCL-9) A c r y s o l WS-68 (38%) water B u t y l Cel l o s o l v e n-Butanol DMAE

P a r t s by Weiqht 480.0 126.3 149.4 21.4 20.0 2.9

Letdown : Ball m i l l grind A c r y s o l WS-68 (38%) Water n-Butanol L-5310 (30% i n B u t y l C e l l o s o l v e ) DMAE (10% i n w a t e r ) * Cyme1 303 PTSA ( l o % ) * *

326.4 567.0 48.2 6.9

1.9 5.1 58.7 5.8

Enamel C o n s t a n t s : T o t a l s o l i d s , %: 4 8 . 0 P i g m e n t / B i n d e r r a t i o : 40/60 A c r y l ic/Mel ami ne r a t i 0 : 80/20 % C a t a l y s t (PTSA) on b i n d e r s o l i d s : 0 . 2 W a t e r / o r g a n i c r a t i o , on volume: 91/9 pH: 7 . 7 V i s c o s i t y , s e c . ( N o . 4 F o r d Cup): 23 V o l a t i l e O r g a n i c Compounds (VOC): 124 g m s . / l .

* **

Add s l o w l y w i t h good a g i t a t i o n t o a c h i e v e d e s i r e d v i s c o s i t y 10 PTSA/10 DMAE/80 Water

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYSOL WS-68: F o r m u l a t i o n WS-68-1

102

Water-Based Paint Formulations

Gloss White Enamel ~

Sand MI1 1 L30 minutes) :Cyme1 303 Tamol 731 (25%) DMAE (20% in water) Butyl Cell os01 ve Isopropanol Water Rutile titanium dioxide (RCL-9) _____._.

___ Parts by Weiaht.

Letdown : Sand mill grind Acrysol WS-68 (38%) Water DMAE (20% in water) L-5310 (30% in Butyl Cellosolve) PTSA (lo%)* n-Butanol

63.0 4.2

5.0 10.4 5.6 101.8 210.0 373.0 618.4 4.0 10.8 2.0 5.8 6.0

Enamel Constants: Total solids, %: 48.0 Pigment/binder ratio: 40/60 Acrylic/melamine ratio: 80/20 % Catalyst (PTSA) on binder solids: 0.2 % L-5310 on binder solids: 0.2 Water/organic ratio: By volume: 91.1/8.9 By weight: 92.2/7.8 pH: 7.6 Viscosity, sec. ( N o . 4 Ford Cup): 25 Volatile Organic Compounds (VOC): 121 gms./l.

*

1 0 PTSA/10 DMAE/80 Water

SOURCE: Rohm and Haas C o . : Industrial Coatings: ACRYSOL WS-68: Formulation WS-68-2

Enamek

103

G l o s s W h i t e Enamel M a t e r i a1 : P a r t A: Epi-Rez 510 Epoxy R e s i n He1oxy 8 Epoxy F u n c t io n a l Modi f ie r Isopropyl Alcohol P a r t 8: CMD WJ60-8537 C u r i n g Agent Defoamer ( 2 ) R u t i l e Titanium Dioxide (3) D i s p e r s e t o a t e x t u r e o f 9-10 P.C.S.. CMD WJ60-85 7 C u r i n g Agent Defoamer Water Composite B end : Part A Part B P a r t s A and B

Viscosity 55 KU 78 KU 93 KU

Pounds 125.8 42.0 8.4

loris 3.04 5.68 1.28

160.0 17.78 4.0 0.50 250.0 7.31 t h e n add a t reduced sDeed: 79.0 8'. 78 4.0 0.50 375.9 45.13 176.2 872.9

2 ) C o l l o i d 640 3) T i t a n o x 2020 o r Tronox CR-800 Typical Coating Properties: T o t a l Weight S o l i d s , P e r c e n t : 53.5 T o t a l Volume S o l i d s , P e r c e n t : 40.7 PVC, P e r c e n t : 1 7 . 9 R e s i n C o m p o s i t i o n (based on s o l i d s ) : Epoxy R e s i n , P e r c e n t : 54.0 C u r i n g Agent, P e r c e n t : 46.0 SOURCE: S h e l l Chemical Co.:

@

24-315 G l o s s White Enamel

20.00 80.00

Water-Based Paint Formulations

104

G l o s s W h i t e E n a m e l f o r E l e c t r o s t a t i c D i s c Spray Sand M i l l (30 m i n u t e s l l Cyme1 303 Tamol 731 (25%) Butyl Cellosolve Isopropanol Water DMAE (10% i n w a t e r ) R u t i l e t i t a n i u m d i o x i d e (RCL-9)

P a r t s b y Weight 94.5 6.0 12.0 7.5 130.0 15.0 315.0

Letdown : Sand m i l l g r i n d A c r y s o l WS-68 (38%) Water D i p r o p y l ene g l y c o l L-5310 (30% i n B u t y l C e l l o s o l v e ) DMAE (10% i n w a t e r ) PTSA* (10%) n-Butanol Enamel Con s t a n t s : T o t a l s o l i d s , %: 35.0 Pigment/binder r a t i o : 40/60 A c r y l ic/mel ami ne r a t i0 : 80/20 % C a t a l y s t (PTSA) on b i n d e r s o l i d s : 0 . 2 % L-5310 on b i n d e r s o l i d s : 0 . 2 Water/organic r a t i o : By volume: 8 0 . 4 / 1 9 . 6 by w e i g h t : 8 1 . 1 / 1 8 . 9 pH: 8 . 4 V i s c o s i t y , sec. (No. 4 F o r d Cup): 45 (Use more OMAE t o i n c r e a s e s p r a y v i s c o s i t y ; t o decrease s p r a y v i s c o s i t y . ) V o l a t i l e O r g a n i c Compounds (VOC): 372 g m s . / l .

*

250.1 428.9 68.6 75.0 1.4 132.0 4.0 10.0

use l e s s DMAE

10 PTSA/10 DMAE/80 Water

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYSOL WS-88: F o r m u l a t i o n WS-60-4

Enamels

105

G l o s s W h i t e Enamel f o r E l e c t r o s t a t i c Spray A p p l i c a t i o n P a r t s bv Weight 12.4 26.5 3.3 2.7 2.0 4.1

Cowl es G r i nd : A c r y s o l WS-68 (38%) Water DMAE (10% i n w a t e r ) Tamol 731 (25%) T r i t o n X-114 n-Butanol M i x t h e above i n g r e d i e n t s ,

t h e n add s l o w l y :

R u t i l e t i t a n i u m d i o x i d e (RCL-9) M i x t h e g r i n d f o r 20 minutes, as f o l l o w s :

134.5

t h e n l e t down under good a g i t a t i o n

Letdown : Water ) premix Butyl Cellosolve ) n-Butanol A c r y s o l WS-68 (38%) L-5310 (30% i n B u t y l C e l l o s o l v e ) Cyme1 303 D i p r o p y l ene g l y c o l DMAE (10% i n w a t e r ) PTSA* (10%)

108.1 4.7 6.3 414.0 1.4 40.4 74.7 131.0 4.0

Physical Constants: T o t a l s o l i d s , %: 35.0 P i g m e n t / b i n d e r r a t i o : 40/60 A c r y l i c / m e l a m i n e r a t i o : 80/20 % C a t a l y s t (PTSA) on b i n d e r s o l i d s : 0 . 2 W a t e r / o r g a n i c r a t i o , by volume: 81 . 4 / 1 8 . 6 pH: 8 . 4 V i s c o s i t y , sec. (No. 4 F o r d Cup): 43 V o l a t i l e O r g a n i c Compounds (VOC): 362 g m s . / l .

*

10 PTSA/10 DMAE/EO Water

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYSOL WS-68: F o r m u l a t i o n WS-68-5

106

Water-Eased Paint Formulations

Gloss Yellow Enamel Materials: Grind Portion: Chempol 10-0091 Aquacat Magnacat 28% Ammoni a Water Patcote 519 Patcote 577 Krolor Yellow KY-7810 Yellow Iron Oxide Butyl Cellosolve B u t y l Carbi to1

Pounds

Gallons

08.2 1.9 3.7 1.7 142.3 0.9 0.9 58.3 3.8 5.0 5.0

10.02 0.23 0.48 0.20 17.17 0.12 0.12 1.77 0.11 0.67 0.63

147.4 3.1 174.5

17.14 0.37 21.02

183.1 31.5 16.0

21.29 3.79 2.01

21 . o

2.53

Steel ball mill to 7 1/2 N.S. Chempol 10-0091 28% Ammonia Water

1 ) )

Premix

(Neutralization=93%, pH 6.1 to 6.4)

Add in order with good agitation: Rhoplex WL-71 Water Butyl Carbi to1 14% A m m o n i a (to pH 7.3 to 7.5) Water

----

----

Note: Reduce for spray with 07/13 water/butyl Cellosolve. Formulation Constants: Pounds/gallon: 8.82 Non-volatiles (Wt.): 35.7% (Vol.1: 32.0% Pigment/Binder -Ratio: 20/00 PVC: 6.3% Rhoplex WL-71/Chempol 10-0091: 30/70 Neutralization (final based on Chempol 10-0091 solids): 170% pH: 7.3 to 7.5 Viscosity: 200-400 cps. VOC: 2.14 lbs./gal,

SOURCE: Rohm and Haas Co.: Industrial Coatings: Formulation WL-71-3

RHOPLEX WL-71:

Enamels

107

Gray Deck Enamel

Lbs/100 Gal 27.2 27.2 8.2 1.4 5.4 20.4 36.7

I n a r e d ie n t : Propyl Carbi t o 1 Methyl Propasol D i e t h y l ami ne Drew L-475 S a n t i c i z e r 160 DSX 1514 Water M i x we1 1, t h e n add : P l i o l i t e 7104

91.1

M i x w e l l , t h e n add : T i t a n o x 2160 Minusil 5 Aquasperse Brown Oxide P a s t e L i q u a k o t e Y e l l o w Oxide L i quakote B l a c k HSD t o 5 N.S.

197.2 204.0 16.3 16.3 4.1

t h e n d r o p t o f u l l y assembled l e t d o w n w i t h m i x i n g :

L e t Down Phase: P l i o l i t e 7104 B u t y l Dipropasol Sant ic i z e r 160

360.4 20.4 15.0

P r e p a r e t h e f o l l o w i n g p r e m i x ; t h e n add t o l e t d o w n : 74.8 2.7

Water A-107

VOC: 221 g/1 o r 1 . 8 4 l b / g a l D e n s i t y : 11.3 l b / g a l l o n Oven S t a b i l i t y : Pass 4 weeks a t 120 degrees F Freeze Thaw: Pass 5 c y c l e s KU V i s c o s i t y : 100-110 NVV: 42% PVC: 43%

SOURCE: The Goodyear T i r e & Rubber Co.:

Formula #2065-106

108

Water-Based Paint Formulations

Gray Low G l o s s Enamel M a t e r i a1 : Bentone EW S o l u t i o n 2% K e l s o l 3961 -B2G-75 Ammoni um H y d r o x i d e Butoxy Ethanol n-0utanol T i t a n o x 2101 106 Lo M i c r o n B a r y t e s OK 412 S i l i c a Z i n c Phosphate 50852 A1 cophor 827 Raven 1255 Water S t e e l b a l l m i l l t o 6-7 Hegman g r i n d . Letdown : Kel s o l 3961 -826-75 Ammoni um H y d r o x i de Premix t h e f o l l o w i n g and add t o above: C o b a l t Hydrocure I 1 Manganese H y d r o c u r e I 1 Butoxy Ethanol n-Butanol Water

Lbs.

Gals 13.02 17.51 1.86 2.29 2.55 3.50 5.13 0.54 3.42 0.49 0.30 24.60

50.60 6.20

5.75 0.83

3.10 6.38 8.79 6.55 123.37

0.41 0.85 1.17 0.97 14.81

Analysis: p i g m e n t VOI ume C o n c e n t r a t i o n , P e r c e n t : 4 5 . 4 P i g m e n t / B i n d e r R a t i o : 2.74/1 P e r c e n t S o l i d s , W e i g h t : 49.7 P e r c e n t S o l i d s , Volume: 24.4 V i s c o s i t y @ 25C, #4 F o r d , S e c s . : 35-45 Pounds/Gallon: 1 1 . 4 4 pH: 8 . 3 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 275 Pounds/Gallon: 2.29

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2419-22

.

110.67 154.09 13.89 17.20 17.21 116.55 187.25 9.81 92.58 10.19 4.37 204.92

I n c . : Waterborne Handbook:

Enamels

Green Chrome F r e e G l o s s Enamel M a t e r i a1 : Lbs. A r o l on 557-8-70 119.73 E t h y l e n e G l y c o l Monobutyl E t h e r 9.21 T r i t o n X-405 1.84 8yk 301 1.84 9.21 D i m e t h y l e t h a n o l Ami ne (DMEA) Water 92.10 Y-5775 F a s t Y e l l o w 27.63 A-4434 Tacoma B l u e 1.84 T i t a n o x 2020 92.10 P e b b l e m i l l o r sand m i l l t o 7 Hegman g r i n d . Letdown : A r o l o n 557-8-70 Cyme1 350 T r i b u t y l Phosphate E t h y l e n e G l y c o l Monobutyl E t h e r DMEA Water

122.49 73.68 9.21 27.63 7.37 352.10

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 15.56 P i g m e n t / B i n d e r R a t i o : .5/1 P e r c e n t S o l i d s , W e i g h t : 39.71 P e r c e n t S o l i d s , Volume: 30.61 V i s c o s i t y C 25C, KU: 80-85 Pounds/Gallon: 9 . 2 1 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 328.9 Pounds/Gallon: 2 . 7 4 Resin/Melamine R a t i o : 70/30 % R e d u c t i o n t o 30 S e c s . , #2 Zahn, w i t h w a t e r : 30

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2185-63

Inc.:

Waterborne Handbook:

.

Gals 14.42 1.23 .20 .23 1.24 11.06 1.92 .15 2.70

14.76 7.37 1.02 3.68 1 .oo 39.02

109

110

Water -Based Paint Formulations

Green Enamel M a t e r i a1 : Water 2-Butoxy E t h a n o l n-Butyl Alcohol Ammoni um H y d r o x i de Kel s o l 3990-826-70 Byk P104S T i t a n o x 2101 Y IO-2288D S u n f a s t Green 264-8142 Dalamar Ye1 l o w YT820D S t e e l b a l l m i l l t o a 7 Hegman g r ind Letdown : Water E k t a s o l v e EP Ammoni um H y d r o x i d e Kel s o l 3990-02G-70 Premi x : Cobalt Hydrocure I 1 A c t i v-8 E k t a s o l v e EP

Lbs.

.

Gals 22.10 2.80 3.12 0.93 15.05 0.16 0.88 0.87 0.74 1.01

313.16 18.06 5.64 84.79

37.59 2.38 0.76 10.03

7.29 1.71 3.00

0.21 0.39

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 17.08 P i g m e n t / B i n d e r R a t i o : 0.55/1 P e r c e n t S o l i d s , Weight: 26.83 P e r c e n t S o l i d s , Volume: 20.53 V i s c o s i t y @ 25C, #4 Ford, Secs.: 35-45 Pounds/Gal 1on : 8 . 7 8 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 401 Pounds/Gal 1on : 3 . 3 4

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2578-50

.

184.11 21.05 21.06 6.98 127.15 1.27 29.30 29.30 12.94 11.86

I n c . : Waterborne Handbook:

0.95

Enamels

111

Green F a s t D r y G l o s s Enamel

Lbs.

M a t e r i a1 : K e l s o l 3960-826-75 C o b a l t Hydrocure 11 Manganese H y d r o c u r e I 1 Butoxy Ethanol Ammoni um H y d r o x i d e

76.71 3.02 3.78 13.69 3.35

Gals. 8.88 0.39 0.50 1.82 0.45

76.60 14.36 15.71 168.03

2.29 1.22 0.67 20.17

Add above m a t e r i a l s under a g i t a t i o n Y e l l o w I r o n O x i d e 2288D Dal amar Ye1 1ow YT820D Palomar Green G5406 Water Pebble m i l l t o 7 Hegman g r i n d .

Letdown : K e l s o l 3960-826-75 324.31 37.54 Ammoni um H y d r o x i d e 7.14 0.96 Normal B u t a n o l 23.52 3.48 Secondary B u t a n o l 25.19 3.74 Butoxy Ethanol 42.01 5.59 Water 78.97 9.48 Premix above m a t e r i a l s and add t o m i l l base under a g i t a t i o n . A r o l on Water Butoxy Premix pH t

840-W-39

108.89 12.52 16.79 2.02 Ethanol 4.19 0.56 above m a t e r i a l s and add t o b a t c h under a g i t a t i o n . A d j u s t o 8 . 0 - 8 . 5 w i t h ammonium h y d r o x i d e .

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : Pigment/Binder R a t i o : .35/1 P e r c e n t S o l i d s . Weight: 40.8 P e r c e n t S o l i d s , Volume: 3 6 . 8 Pounds/Gallon: 8 . 9 pH: 8 . 0 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 355 Pounds/Gallon: 2 . 9 6 SOURCE: R e i c h h o l d Chemicals, I n c . : F o r m u l a t i o n 2175-76C

10.2

Waterborne Handbook:

II2

Water-Based Paint Formulations

Hiclh G l o s s Ford B l u e Enamel I n a r e d ie n t s : Chempol 10-0091 Butyl Cellosolve 28% NH3 6% C a l c i u m D r i e r Coroc A2678M U v i n u l N539 Byk 035 T i ona RCL-628 Phthalo Blue D e i o n i z e d Water

Pounds 297.94 22.35 8.94 4.47 4.47 4.47 1.12 49.62 24.81 44.70

Gal 1ons 33.86 2.98 1.20 0.55 0.51 0.51 0.15 1.49 1.78 5.37

Pebble o r s a n d m i l l t o Hegman 7+, t h e n l e t down w i t h : B u t y l C e l l os01 ve 11.18 5% C o b a l t Hydrocure I 1 2.46 12% Z i r c o n i urn Hydrocem 3.69 A c t iv-8 0.45 E x k i n #2 1.12

1.49 0.32 0.44 0.05 0.15

M i x w e l l and c o n t i n u e l e t down w i t h : Butyl Cellosolve D e i o n i z e d Water

1.49 6.72

11.18 55.88

Premix t h e f o l l o w i n g and add s l o w l y w i t h r a p i d m i x i n g : A c r y s o l ASEGO 1.12 D e i o n i z e d Water 55.08 A d j u s t pH t o 8.0-8.5 D e i o n i z e d Water

and c o n t i n u e l e t down w i t h : 279.04

0.13 6.72 33.47

P r o p e r t i es : % Weight S o l i d s : 35.06 % Volume S o l i d s : 28.38 P/B Weight R a t i o : 0.33 % PVC: 11.5 VOC, # / g a l l o n , c a l c u l a t e d : 2.78 minus w a t e r V i s c o s i t y , # 4 F o r d Cup*: 33-36 seconds Volume r e d u c t i o n 100 p a r t s 10-0091-H w i t h 18-20 p a r t s o f d e i o n i zed w a t e r .

*

F i l m Properties: Spray a p p l i e d o v e r 61000 CRS and a i r d r i e d two weeks b e f o r e t e s t i ng. Dry f i l m t h i c k n e s s , m i l s : 1 . 3 P e n c i l hardness: 26 C r o s s h a t c h a d h e s i o n : e x c e l l e n t - no t a p e o f f 60/20 g l o s s : 09/76 MEK d o u b l e r u b s t o m e t a l : 45 D i r e c t i m p a c t , inch-1 b s . : >80

SOURCE: Freeman Polymers D i v i s i o n : CHEMPOL 10-0091-H: Suggested S t a r t i n g F o r m u l a t i o n

EnameLF

Hiah G l o s s I n t e r i o r Enamel M a t e r i a1 : Water Texanol C o l l o i d 261 I g e p a l GO-630 Foamaster R Nuosept 95 AMP 95 Tronox C R - 8 0 0 H i g h speed d i s p e r s e r Water Synthemul 40-424 Texanol n-Butyl Propionate

Lbs.

46.8 600.0 10.0 50.5 0.3 4.5

5.62 69.77 1.27 6.93 0.03 0.53

10.5 9.6 1.6

0.5

,

15 m i n u t e s maxi mum.

FC-120 RM-825,

0.8 1.o 219.0

Gals. 6.66 1.33 1 .oo 0.18 0.07 0.08 0.13 6.40

55.5

10%

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t S o l i d s , Weight: 45.4 P e r c e n t S o l i d s , Volume: 33.0 I n i t i a l V i s c o s i t y , KU: 9 6 . 0 Pounds/Gal l o n : 10.11 pH: 6 . 8 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 197 I C I , Poise: 1.6 G l o s s @ 60/20: 83/65 Flow and L e v e l i n g : Exc. V i s c o s i t y , 7 Days @ 135F: 91

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 424-01

Percent: 19.4

I n c . : Waterborne Handbook:

113

114

Water-Based Paint Formulations

H i a h - h i d i na Eqashel 1 Enamel Inaredients : Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-4400 P r e s e r v a t ive ( 1 ) Dispersant (2) T r i t o n N o n i o n i c S u r f a c t a n t N-57 2-Amino-2-methyl-1-propanol (3) P r o p y l e n e G1 y c o l Antifoam ( 4 ) Titanium Dioxide (5) Thermo-optic Clay (6) Hydrous C l a y ( 7 ) Letdown : Ucar F i l m e r I B T Butyl C a r b i t o l Solvent Ucar T h i c k e n e r SCT-275 Ucar L a t e x 379 Antifoam ( 4 )

Pounds

Gal l o n s

226.7 2.0 2.3 9.2 2.3 1.o 51.8 1.9 225.0 100.0 25.0

27.21 0.18 0.25 1.oo 0.25 0.13 6.00 0.25 6.54 5.46 1.15

11.9 11.9 17.2 418.2 2.8

1.50 1.50 2.00 46.21 0.37

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 145 o r e q u i Val e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r equ v a l e n t ( 3 ) 2-Amino-2-methyl-1-propanol A P-95 o r e q u i v a l e n t " C o l l o i d " 643 o r equ v a l e n t ( 4 ) Antifoam ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t ( 6 ) Thermo-opti c C1 ay - " O p t i whi t e " o r equi Val e n t ( 7 ) Hydrous C l a y - Burgess No. 98 o r e q u i v a l e n t

-

-

Comparat ive P r o p e r t ies : Pigment Volume C o n c e n t r a t i o n , %: 3 5 . 6 S o l i d s , %: by Volume: 3 7 . 6 by Weight: 53.4 Weight p e r G a l l o n , l b : 11.09 Pai n t P r o p e r t i8s : V i s c o s i t y , in i t i a1 : Stormer, KU: 104 I C I , poise: 1.4 pH, i n i t i a l : 8 . 2 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks at 120F: Pass F i 1m P r o p e r t i es : C o n t r a s t R a t i o , 6 - m i l b a r ( 1 ) : 0.968 R e f l e c t a n c e , %: 91.9 G l o s s , 60, 6 - m i l b a r : 8 Sheen, 85, 6 - m i l b a r : 22 Flow and L e v e l i n g : Brushed: Good ( 1 ) Opacity increased w i t h t o n i n g SOURCE: Ucar Emulsion Systems: UCAR L a t e x 379: F o r m u l a t i o n S u g g e s t i o n 1-1998

Enamels

115

H i g h Performance Bake W h i t e Enamels P a r t s by w e i g h t PELA TOFA ~ _

Materials: R e s i n WB-3823, 75% NVM D i m e t h y l e t h a n o l ami ne A m i no C r o s s l in k e r A ( 1 ) A m i no C r o s s l in k e r B (2) . . T i t a n i u m d i o x i d e 3) Water P r o p e r t i es : P i gment/bi nder r a t i o Me1ami n e / a l kyd r a t io N o n - v o l a t i l e m a t e r i a l (NVM), V i s c o s i t y , #4 F o r d cup, sec PH

257.0 10.0 48.0

----

245.0 440.0

wt %

0.98/1.0 20/80 50 53 7.5

_

290.4 11.2

----

39.4 258.4 400.6 0.98/1.0 15/85 52.5 55 7.65

( 1 ) U f o r m i t e MM 83 (2) Cyme1 301 (3) T i - P u r e R-900 Compounding p r o c e d u r e f o r t h e enamels: 1. S o l u b i l i r e r e s i n i n a m i x i n g v e s s e l c o n t a i n i n g a s o l u t i o n o f d i m e t h y l e t h a n o l a m i n e and d e i o n i z e d w a t e r . 2. Charge r e s i n s o l u t i o n , pigment and amino c r o s s l i n k e r a p e b b l e m i 11. G r i n d o v e r n i g h t t o a Hegman G r i n d o f 7+. 3 . A f t e r m i l l i n g , a d j u s t t o c o r r e c t pH and v i s c o s i t y . Mechanical P r o p e r t i e s o f WB-3823 enamel s : PELA( 1 ) Properties P e n c i l hardness C r o s s h a t c h adhesion 1 / 8 - i n c h c o n i c a l bend, % pass Impact r e s i s t a n c e , i n - l b : direct reverse

8-37( 3) H 5B 100

CRS(4) F 5B

100 100 60

140 80 TOFA(2)

Penci 1 hardness Crosshatch adhesion 1 / 8 - i n c h c o n i c a l bend, % pass Impact r e s i s t a n c e , i n - l b : direct reverse

(1) (2) (3) (4)

B-37( 3) 2H

CRS(4) 3H

5B

58

100

100

120 80

140 60

1.0 t o 1.2 m i l f i l m t h i c k n e s s , c u r e d 2 0 m i n u t e s a t 121C 1.0 t o 1.2 m i l f i l m t h i c k n e s s , c u r e d 30 m i n u t e s a t 177C S u b s t r a t e : B o n d e r i t e 37 t r e a t e d c o l d r o l l e d s t e e l S u b s t r a t e : Cold r o l l e d s t e e l

SOURCE: Amoco Chemical Co.: Water-Borne Bake A l k y d s Based on AMOCO TMA and I P A : Formula T a b l e 8 and T a b l e 9

116

Water-Based Paint Formulations

H i qh S o l i d s P o l v e s t e r / M e l ami ne Enamel Grind: R e s i n WS-3-2C (85% NV) T i t a n i u m D i o x i d e Pigment Hexamethoxymethyl Me1 ami ne D i m e t h y l e t h a n o l a m i n e (DMEA) Flow C o n t r o l A d d i t i v e

Wei q h t

Sol i d s

258.0 256.3 94.0 18.1 3.1

219.3 256.3 94.0

-----

0.3

L e t Down: Demi n e r a l ized Water n-Butyl Alcohol P h y s i c a l C o n s t a n t s o f Enamel: R e s i n / C r o s s l i n k e r R a t i o : 70/30 B i n d e r / P i gment , w t %: 55/45 N o n v o l a t i l e s , w t %: 57 Water/Organic, W t %: 82/18 pH: 8.0-8.5 V i s c o s i t y , No. 4 F o r d Cup, sec:

55-60

P h y s i c a l P r o p e r t i e s o f Enamel C o a t i n g ( b , c ) : Cure Temperature/Time, C/min: 177/20 I n i t i a l Gloss, Gardner, %:

60: 98 20: 83 Impact R e s i s t a n c e , i n . - l b (cm-kg): D i r e c t : 140 (161) Reverse: 90 (104) P e n c i l Hardness: 4H S o l v e n t R e s i s t a n c e , M E K d o u b l e r u b s : 200+ S c r i b e d Adhesion, % pass: 100 C o n i c a l Mandrel F l e x i b i l i t y , ASTM D-522, 1/8 i n . , % pass: 100 S t a i n R e s i s t a n c e : 5-10 D e t e r g e n t R e s i s t a n c e ( d ) , 1 1/2% s t a n d a r d d e t e r g e n t s o l u t i o n , 240 h r , 165F (74C): 60 g l o s s r e t e n t i o n , %: 100 b l i s t e r s , f r e q u e n c y / s i z e : None S a l t Spray, 500 h r : 60 g l o s s r e t e n t i o n , %: 100 S c r i b e creepage, i n . ( m m ) : 11/32 b l is t e r s : None Storage S t a b i l i t y : I n i t i a l : p H / V i s c o s i t y , cP: 8.3/320 A f t e r 500 h o u r s a t 120F; p H / V i s c o s i t y , cP: 7.0/400 b ) Unprimed, z i n c p h o s p h a t i z e d , c o l d - r o l l e d s t e e l p a n e l s c o a t e d w i t h a 1 - 1 1/2 m i l f i l m were used i n t h e s e e v a l u a t i o n s c ) T e s t methods a r e t h o s e commonly used i n t h e p o l y m e r s and coatings industry. d ) C o a t i n g s were a p p l i e d o v e r an epoxy p r i m e r f o r d e t e r g e n t resistance tests.

SOURCE:

Eastman Chemical P r o d u c t s , P o l y e s t e r Resi n WS-3-2C

Inc.:

Enamel P r e p a r e d f r o m

Enamels

L i g h t He1 iogen Green Enamel C a r g i l l Water R e d u c i b l e S i l i c o n e M o d i f i e d A1 kyd 74-7435 Aqueous Ammonia 28% E t h y l e n e G l y c o l Monobutyl E t h e r

Byk-301 He1 i o g e n Green L8690 T i t a n i um D i o x i d e T i -Pure R-900 Dei o n i zed Water

Pounds

Gal 1ons

155.2 6.7 13.2 3.3 6.7 194.0 118.7

17.25 0.89 1.76 0.41 0.36 5.54 14.27

110.9 6.5

12.32 0.87

15.9 4.0 5.0 1.3

2.11 0.52 0.69 0.17

288.3

34.58

68.8

8.26

Sand M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e S i l i c o n e M o d i f i e d A1 kyd 74-7435 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: E t h y l e n e G l y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um A c t iv-8 D e i o n i z e d Water D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Ad j ustment )

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 40.63 (By Volume) : 27.14 Pigment t o B i n d e r R a t i o : 0.98 P i gment Vol ume Concent r a t i on : 22.00 Weight p e r G a l l o n : 9.98 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.58 ( G r a m s / L i t e r ) : 309 W a t e r : C o s o l v e n t Weight R a t i o : 82.80:18.20 pH: 8.0-8.5 V i s c o s i t y Krebs-Stormer (KU): 70t-5 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold Rolled Steel G l o s s (60/20): 86/60 P e n c i l Hardness: Pass F % C r o s s h a t c h Adhesion: 100 Impact ( I n . Lbs.): D i r e c t : 30 Reverse: < 5 D r y Time L i n e a r D r y i n g Recorder ( H o u r s ) : 2 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1843-227

I

117

118

Water-Based Paint Formulations

Non-Leaf ina A1 umi num Enamel Material : Add, mix i n o r d e r l i s t e d : Water Ammoni um H y d r o x i de K e l s o l 3906-826-75 Premix, add t o above: Letdown : C o b a l t Hydrocure I 1 Activ-8 Butoxy E t h a n o l Manganese H y d r o c u r e F i n a l Letdown: Butoxy Ethanol Hydro-Paste 82255

Lbs. 463.40 11.20 241 .OO

55.63 1.49 27.54

5.55 2.21 11.27 3.04

0.72 0.28 1 .so 0.40

26.59 111.25

3.54 8.90

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 15.0 Pigment/Binder R a t i o : .3?/1 Percent S o l i d s , Weight: 30.6 P e r c e n t S o l i d s , Volume: 2 4 . 6 Pounds/Gallon: 8 . 7 6 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i ng w a t e r ) : G r a m s / L i t e r : 389 Pounds/Gallon: 3 . 2 4

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 1652-40

Gals.

I n c . : Waterborne Handbook:

Enamels

Quality

Gloss W h i t e Enamel

A q u a l it y h i g h - h i d i ng g l o s s enamel

Inpredients: Pigment G r i n d : Water P r o p y l ene G1y c o l D i spersant (1 ) Nonionic Surfactant (2) Preservative (3) Antifoam (4) Titanium Dioxide (5)

Pounds

Gallons

50.10 43.30 9.20 2.20 1.20 0.25 250.00

6.02 5.00 1.oo 0.25 0.13 0.03 7.31

L e t Down: Anionic Surfactant (6) Butyl C a r b i t o l Solvent Ucar F i l m e r IBT Antifoam (7) Ucar L a t e x 430 (43.0%) Ucar T h i c k e n e r SCT-275

3.10 19.80 39.60 5.60 604.70 6.50

0.37 2.50 5.00 0.75 69.51 0.75

Premi x : A n i o n i c Thickener (8) 3.30 Water 8.30 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 0 . 1 0

0.37 1 .oo 0.01

Suppliers: ( 1 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t ( 2 ) N o n i o n i c S u r f a c t a n t - " T r i t o n " CF-10 o r e q u i v a l e n t ( 3 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t "Nalco" 2300 o r e q u i v a l e n t (4) Antifoam ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t ( 6 ) A n i o n i c S u r f a c t a n t - " T r i t o n " GR-7M o r e q u i v a l e n t ( 7 ) A n t i f o a m - "Byk" 035 o r e q u i v a l e n t ( 8 ) A n i o n i c T h i c k e n e r - " A c r y s o l " RM-5 o r e q u i v a l e n t

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 20.3 T o t a l S o l i d s , %: by Volume: 35.9 by W e i g h t : 49.8 V i s c o s i t y ( e q u i 1ib r a t e d ) : Stormer, KU: 86 I C I , Poise: 1.2 pH, i n i t i a l : 9 . 4 Weight p e r G a l l o n , l b : 10.47 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 w k s a t 120F (49C): Pass Flow and L e v e l i n g , b r u s h e d : Good Sag R e s i s t a n c e , brushed: E x c e l l e n t Foam C o n t r o l : Good VQC, g / 1 : 248

SOURCE:

Ucar Emulsion Systems: UCAR L a t e x 430: S u g g e s t i o n E-2201

Formulation

119

120

Water-Based Paint Formulations

Q u a l i t y G l o s s W h i t e Enamel A q u a l i t y g l o s s enamel w i t h an o u t s t a n d i n g b a l a n c e o f D r o o e r t i e s

Inaredients: Pigment G r i n d : Water Propylene G l y c o l C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-15M D i spersant ( 1) 2-Ami no-2-methyl -1 - p r o p a n o l ( 2 ) Antifoam ( 3 ) Preservative (4) Nonionic Surfactant ( 5 ) Nonionic Surfactant (6) Titanium Dioxide (7) L e t Down: Butyl C a r b i t o l Solvent Mix: Butyl C a r b i t o l Solvent Ucar T h i c k e n e r SCT-275 Ucar L a t e x 430 (43%) Ucar F i l m e r I B T Antifoam (3)

Pounds

'

Gai 1ons

82.90 34.60 0.75 9.60 3.00 2.10 1.20 2.10 7.10 225.00

9.95 4.00 0.07 1 .oo 0.37 0.25 0.13 0.25 0.75 6.58

15.80

2.00

5.90 6.50 590.70 39.60 2.10

0.75 0.75 67.90 5.00 0.25

Suppl ie r s : ( 1 ) D i s p e r s a n t - " C o l l o i d " 261 o r e q u i v a l e n t ( 2 ) 2-Ami no-2-methyl -1 - p r o p a n o l - AMP-95 o r e q u i Val e n t ( 3 ) A n t i f o a m - "Foamex" 1488 o r e q u i v a l e n t ( 4 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 5 ) N o n i o n i c S u r f a c t a n t - " S u r f y n o l " 104E o r e q u i v a l e n t ( 6 ) N o n i o n i c S u r f a c t a n t - " E o r c h i g e n " DFN o r e q u i v a l e n t ( 7 ) T i t a n i u m Oxide - "Tronox" CR-800 o r e q u i v a l e n t

P a i n t P r o p e r t ies : Pigment Volume C o n c e n t r a t i o n (PVC), %: 19.0 T o t a l S o l i d s , %: by Volume: 3 4 . 5 by Weight: 48.3 V i s c o s i t y ( e q u i 1 ib r a t e d ) : Stormer, KU: 97 I C I , Poise: 1 . 8 pH, i n i t i a l : 9 . 4 Weight p e r G a l l o n , l b : 10.29 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 wks a t 120F (49C): Pass Flow and L e v e l i n g , brushed: Good Sag R e s i s t a n c e , brushed: Excel l e n t Foam C o n t r o l : Excel 1e n t VOC, g / l : 245.6 F i 1m P r o p e r t ies : C o n t r a s t R a t i o 0.003 i n : 0.973 R e f l e c t a n c e %: 92.0

SOURCE: Ucar Emulsion Systems: UCAR L a t e x 430: S u g g e s t i o n E-2202

Formulation

Enamels

Q u a l i t y G l o s s W h i t e Enamel A q u a l i t y enamel w i t h e x c e p t i o n a l a p p l i c a t i o n p r o p e r t i e s .

Ingredients: Pigment G r i n d : Water Butyl C a r b i t o l Solvent P r o p y l e n e G1y c o l C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-15M D i spersant ( 1) Nonionic Surfactant (2) Nonionic Surfactant ( 3 ) Antifoam (4) P r e s e r v a t i v e (5) Titanium Dioxide (6)

Pounds

Gallons

42.00 47.50 43.20 0.75 6.10 2.20 2.10 0.70 1.20 225.00

5.04 6.00 0.07 0.62 0.25 0.25 0.09 0.13 6.58

L e t Down: Mix: Ucar T h i c k e n e r SCT-270 B u t y l C a r b i t o l Solvent Ucar L a t e x 430 (43.0%) P l a s t i c i z e r (7) Antifoam (8)

13.00 11.90 600.00 23.60 7.50

1.50 1.50 68.97 3.00 1 .oo

5.00

Suppliers: ( 1 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 2 ) N o n i o n i c S u r f a c t a n t - " T r i t o n " N-57 o r e q u i v a l e n t (3) Nonionic Surfactant " S u r f y n o l " 104E o r e q u i v a l e n t ( 4 ) A n t i f o a m - " C o l l o i d " X-0137-MC-33 o r e q u i v a l e n t ( 5 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 6 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t (7) P l a s t i c i z e r - "Kodaflex" T X I B o r equivalent ( 8 ) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 18.8 T o t a l S o l i d s , %: b y Volume: 34.9 by Weight: 48.2 Viscosity (equilibrated): Stormer, KU: 86 I C I , Poise: 1.2 pH, i n i t i a l : 8 . 7 Weight p e r G a l l o n , l b : 10.27 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 wks a t 120F (49C): Pass Flow and L e v e l i n g , brushed: Good Sag R e s i s t a n c e , brushed: E x c e l l e n t Foam C o n t r o l : Excel l e n t VOC, g / 1 - p l a s t i c i z e r : 226.4 SOURCE: Ucar Emulsion Systems: UCAR L a t e x 430: S u g g e s t i o n E-2203

Formulation

121

122

Water-Based Paint Formulations

Red A c r v l ic Emu1s i on Enamel Ingredients: Coroc A-2678-M 2-butoxyethanol S u r f y n o l 104BC S u r f y n o l DF-75 Water Mapico Red #347 I r o n Oxide 13-3060 Novoperm A20 Red

Pounds 45.81 7.71 8.05 1.32 30.27 20.55 30.83

Gal 1ons 5.21 1.03 1.07 0.16 3.63 0.48 2.73

Pre-mix f i r s t f o u r i n g r e d i e n t s , t h e n add w a t e r w i t h a g i t a t i o n . Load m i x t u r e i n t o b a l l m i l l f o l l o w e d b y pigments. P o r c e l a i n b a l l g r i n d t o a #7 Hegman. A d j u s t g r i n d a n d / o r wash m i l l w i t h w a t e r f r o m below i f n e c e s s a r y . L e t down w i t h : Chempol 20-4301 2-butoxyethanol B u t y l Carbi t o 1 Dibutyl Phthalate Nuocure CK-10 Michem 39235 Water ( h o l d t o a d j u s t v i s c o s i t y )

572.76 31.96 20,44 7.06 2.01 30.18 75.72

65.09 4.26 2.57 0.81 0.25 3.62 9.09

Pre-mix c o - s o l v e n t s , p l a s t i c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r seeding. Add t h e wax d i s p e r s i o n t o t h e " l e t down" w i t h a g i t a t i o n . A f t e r m i x i n g w e l l , add t h e g r i n d t o t h e " l e t down" w i t h good a g i t a t i o n . M i x w e l l and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7 . 6 , as t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % by w e i g h t : 34.42% T o t a l s o l i d s , % by volume: 29.42% Wei g h t / g a l 1 on : 8.85 1b s . / g a l PVC: 10.90 P i g m e n t / b i n d e r r a t i o : 0.20 VOC: 2 . 0 4 l b s . / g a l . V i s c o s i t y : 38" #2 Zahn pH: 7 . 6 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y Set t o t o u c h : 1 7 ' Dust f r e e : 2 0 ' Tack f r e e : 7 5 ' - 9 0 ' Dry t h r o u g h : 7 5 ' - 9 0 '

.

SOURCE : Freeman Polymers D i v i s i on : CHEMPOL 20-4301 -D F o r m u l a t i o n

123

Enamels

Red Enamel M a t e r i a1 : Water 2-Butoxy E t h a n o l n-Butyl Alcohol E k t a s o l v e EP Ammonium H y d r o x i d e K e l s o l 3990-826-70 Byk P104S Novaperm Red F3RK-70 Copperas Red R-7098 S t e e l b a l l m i l l t o a 7 Hegman g r i n d . Letdown : Water Ammonium H y d r o x i d e Kel s o l 3990-B2G-70 Premi x : Cobalt Hydrocure I 1 A c t i v-8 2-Butoxy E t h a n o l

Lbs.

Gals 36.31 0.71 1.23 1.10 1.12 16.57 0.17 3.79 0.20

212.52 3.49 93.38

25.51 0.47 l? .05

8.97 1.51 3.00

1.17 0.19 0.40

Anal v s i s : P;gment Volume C o n c e n t r a t i o n , P e r c e n t : 17.51 P i g m e n t / B i n d e r R a t i o : 0.29/1 P e r c e n t S o l i d s , W e i g h t : 25.67 P e r c e n t S o l i d s , Volume: 22.78 V i s c o s i t y @ 25C, #4 F o r d , Secs. : 35-45 pH: 8 . 2 - 8 . 5 Pounds/Gallon: 8 . 4 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 335 Pounds/Gallon: 2 . 7 9

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2578-49

.

302.47 5.33 8.33 8.33 8.36 140.04 1.37 40.76 8.43

I n c . : Waterborne Handbook:

124

Water-Based Paint Formulations

Red G l o s s A c r v l i c Enamel M a t e r i a1 : A r o l o n 559-64-70 Butoxy E t h a n o l D i m e t h y l e t h a n o l A m i ne (DMEA) Water D i sperbyk X-1843 Madras Orange 13-3690 Novoperm Bordeaux HF3R Pebble o r sand m i l l t o 7+ Hegman G r i n d . Letdown : A r o l o n 559-G4-70 Resimene 740 Butoxy E t h a n o l n-Butanol DMEA Water

Lbs. 73.42 18.38 5.48 73.39 1.44 4.10 22.00

Gals. 8.41 2.45 .74 8.81 .16 3.98 1.90

109.93 100.16 14.25 17.62 9.92 296.63

21.87 10.22 1.90 2.61 1.34 35.61

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 1 7 . 3 P i g m e n t / B i n d e r R a t i o : .24/1 P e r c e n t S o l i d s , W e i g h t : 39.10 P e r c e n t S o l i d s , Volume: 34.02 V i s c o s i t y @ 25C, KU: 70-75 Pounds/Gallon: 8.68 % R e d u c t i o n t o 30 Secs., #2 Zahn, w i t h w a t e r : 30 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 338 Pounds/Gallon: 2 . 8 2

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2185-83

I n c . : Waterborne Handbook:

Enamels

Red G l o s s Enamel

Lbs.

Material : Water Ammoni um H y d r o x i d e K e l s o l 391 0-826-75 Butoxy Ethanol Cobalt Hydrocure I 1 A c t iv - 8 Novaperm F5RK Novaperm F3RK70 Oswego Orange X-2065 T i P u r e R-902 B a l l m i l l t o 6-7 Hegman g r i n d .

157.82 10.52 134.67 21.04 6.24 1.04 14.03 15.43 56.81 47.70

Gals. 18.95 1.40 15.37 2.81 0.83 0.13 1.24 1.44 4.77 1.43

Letdown : Kel s o l 391 0-B2G-75 n-Butanol Ammoni um H y d r o x i d e Water V e r s a f l o w 102 Butoxy Ethanol Water

142.38 22.44 11.22 56.81 2.10 34.37 163.43

16.25 3.32 1.49 6.82 0.25 4.57 19.62

Anal y s i s: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 28.9 P i g m e n t / B i n d e r R a t i o : .65/1 . O P e r c e n t S o l i ds, Wei g h t : 3 8 . 3 P e r c e n t Sol i d s , Vol ume: 3 0 . 7 V i s c o s i t y @ 25C, #4 F o r d , Secs. : 75-80 Pounds/Gallon: 8 . 9 3 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 334 Pounds/Gal 1on : 2 . 7 9

SOURCE:

R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i o n 21 1 6 - 7 l A

125

126

Water -Based Paint Formulations

Red H i g h Gloss Enamel

Lbs.

Material : Water Ammoni um H y d r o x i de Kel s o l 3906-626-75 Premix d r i e r s and s o l v e n t : C o b a l t Hydrocure A c t i v-8 Butoxy E t h a n o l Rex Orange X-2806 Garnet Toner X-2433 Sand m i l l t o 6 Hegman g r i n d . Letdown : Water Ammonium H y d r o x i d e Kel s o l 3906-B2G-75 10% DC-29 i n B u t y l C e l l Anal y s i s : Pigment Volume C o n c e n t r a t i o n , Pigment/Binder R a t i o : . 5 / 1 P e r c e n t S o l i d s , Weight: 36.9 P e r c e n t Sol ids, Vol ume: 28.4 Pounds/Gallon: 9 . 1 9 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 265 Pounds/Gal 1on : 2 . 2 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 174-1

Percent:

142.35 6.57 82.13

Gals. 17.10 0.88 9.50

2.30 1.10 5.48 84.32 26.28

0.30 0.14 0.73 1.82 2.05

328.50 8.76 219.00 5.04

39.42 8.17 25.36 0.61

13.6

I n c . : Waterborne Handbook:

Enamels

127

Red Rose A i r D r v Enamel C a r g i l l Water R e d u c i b l e Chain Stopped A1 kyd 74-7495 Aqueous Ammonia 28% Byk-301 Byk-020 sec-Butanol E t h y l e n e G l y c o l Monobutyl E t h e r Quindo Magenta RV-6803 S y n t h e t i c Red I r o n Oxide R0-3097 T i t a n i u m D i o x i d e T i - P u r e R-900 D e i o n i z e d Water

Pounds

Gal 1ons

134.6 4.4 1.o 1.9 4.5 6.4 20.7 7.4 9.4 70.6

15.65 0.58 0.13 0.26 0.67 0.85 1.72 0.18 0.27 8.47

137.8 7.0

16.02 0.94

5.6 4.0 3.6 2.6 0.9

0.83 0.53 0.46 0.37 0.12

432.7

51.95

S a n d m i l l t o a 7 . 5 Hegman C a r g i l l Water R e d u c i b l e Chain Stopped A1 kyd 74-7495 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: sec-Butanol E t h y l e n e G l y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i u m A c t iv-8 Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 27.09 (By Volume): 22.80 Pigment t o B i n d e r R a t i o : 0 . 0 8 Pigment Volume C o n c e n t r a t i o n : 2.19 Weight Per G a l l o n : 8 . 5 5 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.90 ( G r a m s / L i t e r ) : 348 W a t e r : C o s o l v e n t Weight R a t i o : 82.04:17.96 pH: 8 . 7 V i s c o s i t y Krebs-Stormer (KU): 65-75 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold Rolled Steel G l o s s ( 6 0 / 2 0 ) : 95/85 D r y Time L i n e a r D r y i n g Recorder ( M i n u t e s ) : 64

SOURCE:

Cargill,

Inc.:

CARGILL F o r m u l a r y : Formula PI 843-2578

128

Water-Based Paint Formulations

S a t i n White A i r Dry E n a a ~Pounds

C a r g i 11 Water R e d u c i b l e A c r y l ic Modi f ied A1 kyd 74-7432 Aqueous Ammonia 28% T r i e t h y l ami ne T i t a n i um D i o x i d e T i -Pure R-900 I m s i l A-8 Byk-301 D e i o n i z e d Water

Gallons

174.0 10.1 1 .o 174.0 98.6 1.5 149.0

20.47 1.34 0.17 4.97 4.47 0.18 17.89

74.6 4.3 0.4

8.77 0.58 0.07

2.9 2.9 0.8

0.38 0.40 0.10

335.0

40.21

Sand M i l l t o a 7 Hegman C a r g i 1 1 Water R e d u c i b l e A c r y l ic Modi f ied A1 kyd 74-7432 Aqueous Ammonia 28% T r i e t h y l ami ne Premix t h e f o l l o w i n g , t h e n add: I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um A c t iv-8 Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 43.71 (By Volume): 28.62 Pigment t o B i n d e r R a t i o : 1.54 Pigment Volume C o n c e n t r a t i o n : 33.14 Weight Per G a l l o n : 10.29 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.09 ( G r a m s / L i t e r ) : 250 Water:Cosolvent Weight R a t i o : 85.34:14.66 pH: 8.80 V i s c o s i t y #4 F o r d Cup (Seconds): 45 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r Dry Substrate: Cold Rolled Steel G l o s s ( 6 0 ) : 29 P e n c i l Hardness: Pass B % C r o s s h a t c h Adhesion: 100 Impact ( i n . L b s . ) : D i r e c t : 20 Reverse: (5

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P1887-32-1

Enamels

Semi a1oss Enamel Inaredients: Pigment G r i n d : Water C e l l o s i z e H y d o x y e t h y l C e l l u l o s e ER- 15M Preservative (1) Dispersant ( 2 ) T r i t o n N o n i o n i c S u r f a c t a n t N-57 2-Ami no-2-methyl-1-propanol (3) P r o p y l e n e G1y c o l Antifoam (4) T i t a n i um D i o x i d e ( 5 )

Pounds

Gallons

268.2 2.0 2.4 9.2 2.1 1. o 43.2 1. o 250.0

32.20 0.18 0.25 1 .oo 0.25 0.13 5.00 0.13 7.27

29.9 428.4 20.0 1.9 0.5

3.48 47.28 2.52 0.25 0.06

Letdown : UCAR T h i c k e n e r SCT-275, p r e m i x ( a ) Ucar L a t e x 379 Ucar F i l m e r IBT Antifoam (4) T r i t o n A n i o n i c S u r f a c t a n t GR-7M

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 145 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t ( 3 ) 2-Ami no-2-methyl -1-propanol - AMP-95 o r e q u i v a l e n t ( 4 ) A n t i f o a m - "Byk" 035 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t ( a ) Premix c o n s i s t s o f 1 : l : l T h i c k e n e r SCT-275:water.

b l e n d o f p r o p y l e n e glyco1:UCAR

Comparative P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: S o l i d s , %: by Volume: 31.8 b y Weight: 46.0 Weight p e r G a l l o n , l b : 10.60

23.0

Paint Properties: Viscosity, i n i t i a l : Stormer, KU: 82 I C I , poise: 0.4 pH, i n i t i a l : 8 . 5 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Film Properties: C o n t r a s t R a t i o , 6 - m i l b a r : 0.967 Ref 1e c t a n c e , %: 8 9 . 5 Gloss, 60: Drawdown, 6-mi 1 b a r : 59 Flow and L e v e l i n g : Brushed: Very Good Drawdown, NYPC Blade:

SOURCE:

8

Ucar Emulsion Systems: UCAR L a t e x 379: F o r m u l a t i o n S u g g e s t i o n 1-1989

129

130

Water-Based Paint Formulations

S e m i a l o s s M a i n t e n a n c e Enamel-White A s e m i g l o s s maintenance enamel w i t h a n t i - c o r r o s i v e

Inaredients: Piement G r i n d : Water D i spersant (1 ) 2-Amino-2-methyl-1-propanol Antifoam (3) Nonionic Surfactant (4) Nonionic Surfactant (5) Titanium Dioxide (6) A n t i - c o r r o s i v e Pigment ( 7 )

(2)

pigment.

Pounds

Gallons

79.9 3.4 3.0 2.1 2.1 7.1 200.0 25.0

9.59 0.37 0.37 0.25 0.25 0.75 5.85 1.oo

2.1 34.6 20.8

0.25 4.00 2.62

5.4 5.0 39.6

0.62 0.62 5.00

1 .o 4.2 590.7

0.06 0.50 67.90

L e t Down: Antifoam (3) Propylene Glycol Butyl C a r b i t o l Solvent Mix: Ucar T h i c k e n e r SCT-275 Butyl C a r b i t o l Solvent Ucar F i l m e r I B T Mix: Sodium N i t r i t e Water Ucar L a t e x 430 (43.0%)

Suppl ie r s : ( 1 ) D i s p e r s a n t - " B o r c h i g e n " ND o r e q u i v a l e n t ( 2 ) 2-Amino-2-methyl-1-propanol - AMP-95 o r e q u i v a l e n t ( 3 ) A n t i f o a m - "Foamex" 1488 o r e q u i v a l e n t (4) Nonionic Surfactant - "Surfynol" lOXE o r equivalent ( 5 ) N o n i o n i c S u r f a c t a n t - " B o r c h i g e n " DFN o r e q u i v a l e n t ( 6 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t ( 7 ) A n t i - c o r r o s i v e Pigment - " M o l y - w h i t e " MZAP o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), T o t a l S o l i d s , %: b y Volume: 3 4 . 8 b y W e i g h t : 48.3 Viscosity (equilibrated): S t o r m e r , KU: 88 I C I , Poise: 0 . 5 pH1 i n i t i a l : 9 . 3 Weight p e r G a l l o n , l b : 1 0 . 2 6 VOC, g / l : 249.2

%:

19.7

Film Properties: C o n t r o l R a t i o , 0.003 i n : 0.966 R e f l e c t a n c e , %: 9 1 . 5 G l o s s , 60: 38.1 SOURCE: Ucar E m u l s i o n Systems: UCAR L a t e x 430:

Suggestion M-2204

Formulation

Enamels

131

Semi g l o s s W h i t e Enamel Pounds

Gal 1ons

Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-15M Preservative (1) Dispersant (2) T r i t o n N o n i o n i c S u r f a c t a n t N-57 (3) 2-Amino-2-methyl-1-propanol P r o p y l e n e G1y c o l Antifoam (4) T i t a n i u m D i o x i d e (5)

268.2 2.0 2.3 9.2 2.1 1. o 43.2 0.9 250.0

32.20 0.18 0.25 1 .oo 0.25 0.13 5.00 0.13 7.27

Letdown : Butyl C a r b i t o l Solvent Thickener, premix ( a ) Ucar L a t e x 367 Ucar F i l m e r I B T Antifoam ( 4 ) T r i t o n A n i o n i c S u r f a c t a n t GR-7M

15.8 21.5 428.4 11.9 1.8 0.6

2.00 2.50 47.28 1.50 0.25 0.06

I n a r e d ie n t s :

P i gment G r i nd

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t ( 3 ) 2-Ami no-2-methyl -1 - p r o p a n o l - AMP-95 o r e q u i v a l e n t ( 4 ) A n t i f o a m - "BYK" 035 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t ( a ) Premix c o n s i s t s o f 1 : l : l b l e n d o f p r o p y l e n e glyco1:Rohm and Haas' " A c r y s o l SCT-275" T h i c k e n e r : w a t e r , r e s p e c t i v e l y . Paint Properties: Pigment Volume C o n c e n t r a t i o n ( P V C ) , %: 23.0 S o l i d s , %: b y Volume: 31.6 by Weight: 46.8 Viscosity ( i n i t i a l ) : Stormer, KU: 85 I C I , poise: 1.0 pH ( i n i t i a l ) : 8.1 Weight p e r G a l l o n , l b . : 10.59 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass ( + 2 KU) Heat S t a b i l i t y , 2 weeks a t 120F: Pass ( + 5 KU) Film Properties: C o n t r a s t R a t i o , 3 m i l f i l m : 0.968 Ref 1e c t a n c e , %: 9 2 . 6 Gloss, 60: Drawdown: 61.0 B r u s h o u t : 67.0 Flow and L e v e l i n g , Brushed: Very Good

SOURCE:

Ucar Emulsion Systems: UCAR L a t e x 387/UCAR L a t e x 378: F o r m u l a t i o n S u g g e s t i o n 1-2219

132

Water-Based Paint Formulations

Semi g l o s s W h i t e T r i m Enamel Inqredients: Pigment G r i n d : Water Phenyl M e r c u r i c A c e t a t e , 100% Cel l o s i ze H y d r o x y e t h y l C e l l u l o s e QP-4400 Dispersant ( 1 ) Nonionic Surfactant (2) P r o p y l e n e G1 y c o l Antifoam (3) Titanium Dioxide (4) L e t Down: Ucar A c r y l i c 525 Ucar F i l m e r IBT Antifoam (3) Anionic Surfactant (5) Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gal l o n s

246.0 1.o 3.5 9.7 2.0 51.8 0.9 250.0

29.51 0.05 0.32 1 .oo 0.25 6.00 0.13 7.26

471.9 17.8 1.9 1.1 3.0

52.43 2.25 0.25 0.13 0.42

su001 ie r s : ( 1 j ' D i s p e r s a n t - "Pol ywet" ND-2 o r equi Val e n t ( 2 ) N o n i o n i c S u r f a c t a n t - " I g e p a l " CO-630 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 681-F o r e q u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - "Zopaque" RCL-9 o r e q u i v a l e n t (5) A n i o n i c S u r f a c t a n t - " T r i t o n " GR-7M o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 22.0 T o t a l S o l i d s , %: by Volume: 33.0 by Weight: 48.5 V i s c o s i t y , in i t i a1 : Stormer, KU: 90-95 I C I , poise: 1.1 pH, i n i t i a l : 9.4 Weight p e r G a l l o n , l b : 10.61 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 wk a t 120F: Pass F i 1m P r o p e r t y : G l o s s , 60: 45-50 SOURCE: Ucer Emulsion Systems: S u g g e s t i o n E-2077

UCAR A c r y l i c 525:

Formulation

Enameks

S t e e l B l u e G l o s s Enamel M a t e r i a1 : Kel s o l 3907-G2B-75 Ammoni um H y d r o x i d e n-Butanol Butoxy Ethanol Monarch B l u e X3367 Raven 1020 Ye1 1ow I r o n Oxi de 22881) T i - P u r e R-902 Water S t e e l b a l l m i l l t o 7 Hegman g r i n d . Letdown : K e l s o l 3907-G28-75 n-Butanol Ammoni um H y d r o x i d e Water Premix : A c t i v-8 C o b a l t Hydrocure I 1 Butoxy Ethanol

Lbs. 45.71 2.32 3.85 3.83 4.50 3.21 2.35 40.01 76.22

Gals. 5.34 0.31 0.57 0.51 0.34 0.22 0.07 1 .17 9.15

254.30 13.97 7.62 403.34

29.71 2.07 1.02 48.42

1.28 6.35 0.75

0.16 0.84 0.10

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 6.62 P i gment/Bi n d e r R a t i o : . 2 2 / 1 P e r c e n t S o l i d s , W e i g h t : 32.91 P e r c e n t S o l i d s , Volume: 27.17 V i s c o s i t y @ 25C. #4 Ford, S e c s . : 35-40 Pounds/Gallon: 8 . 7 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 294 Pounds/Gallon: 2.45

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i on 2103-71

I n c . : Waterborne Handbook:

133

134

Water-Based Paint Formulations

T i n t a b l e E q q s h e l l Enamel

lbs/100 s a l Premix on K a d y z o l v e r a t 2,000 rpm f o r 10 min: Propylene g l y c o l 51.8 Water 50.0 Thickener 1.5 Tamol 731 (25%) 7.0 Nopco NDW 2.0 Add and g r i n d a t 2,000 T i -Pure R-902 I m s i l A-25

rpm f o r 20 min:

L e t down ( l o w speed on an a i r s t i r r e r ) : Water Nopco NDW 100% a c r y l i c l a t e x , 46.5% Texanol 1 P r o p y l e n e g l y c o l ) premi x Water 1 D o w i c i l 75 ) premix T r i t o n N-57 T r i t o n X-114 T r i t o n X-207 Thickener (2.5% s o l u t i o n )

250.0 75.0

299.5 89.8

83.0 4.0 450.0 12.6 17.3 24.9 1.3 4.0 4.0 2.0 60.1

99.4 4.8 539.1 15.1 20.7 29.8 1.6 4.8 4.8 2.4 72.0

T i n t w i t h C a l / I n k 8800 s e r i e s c o l o r a n t s a t 4 o z / g a l Physical Properties: PVC, %: 33.2 Volume s o l i d s , %: 3 2 . 3 Weight s o l i d s , %: 48.50 D e n s i t y , l b s / g a l ( k g / l ) : 11.00 ( 1 . 3 2 ) I n i t i a l pH: 8 . 2 - 8 . 5 Stormer v i s c o s i t y ( o v e r n i g h t ) , KU: 92-96

SOURCE: Aqualon Co.:

sL1 62.1 59.9 1.8 8.4 2.4

NATROSOL B: Formula T a b l e I V

EnameLF

V e l v e t L a t e x Enamel m t i w h i t e / B u r a e s s No. 98 Approach Water KTPP N a t r o s o l 250 MBR N a l c o #2300 Tamol 1254 T r i t o n X-100 AMP-95 P r o t e l GXL R-900 Optiwhi t e Burgess No. 98 Ethylene Glycol Ucar 367 Ucar 522 Texanol Foamaster G Eva1 u a t ion R e s u l t s : H i d i n g 3 M i l B i r d B l a d e on O p a c i t y P a n e l : Ref 1e c t a n c e : .908 C o n t r a s t R a t i o : .974 T i n t S t r e n g t h . 5 Blue/200 grams: R e f l e c t a n c e : .702 Sheen : 85: 1 9 . 4 60: 3 . 6 V i s c o s i t y KU: 95

SOURCE:

Burgess Pigment Co. : Formula 71 OPT/98

Lbs./100 G a l . 398 1 .oo 6.50 1 .oo 3.28 2.00 3.00 1 .oo 200 75 75 28 205 109 15.84 7.60

135

136

Water-Based Paint Formulations

Waterborne P o l y e s t e r Enamel I n a r e d ie n t s : WS-17-1T P o l y e s t e r , 75% s o l i d s Cyme1 303 melamine r e s i n N, N-Dimethylami n o e t h a n o l (DMEA) p-To1 uenesul f o n i c a c i d , 40% in isopropanol F l u o r a d FC-430, 20% i n w a t e r Demi n e r a l ized w a t e r Enamel P r o p e r t i e s : pH: 8.42 V i s c o s i t y , cP: 810 T h e o r e t i c a l s o l i d s , %:

Weight 33.42 8.33 2.33 0.25 0.25 55.42

31.3

Coatings P r o p e r t i e s - I n i t i a l : S u b s t r a t e : 20 gauge CRS w i t h B o n d e r i t e 37 Cure: 30 m i n u t e s a t 177C (350F) P e n c i l hardness, c u t / s c r a t c h : 3-4H/H D i r e c t / r e v e r s e impact r e s i s t a n c e , i n . - l b : 160/160 MEK d o u b l e r u b s : 200+ 5 M i n u t e I 2 s t a i n t e s t : No s t a i n 500 Hours s a l t spray--mm creepage f r o m s c r i b e : 1 H u m i d i t y r e s i s t a n c e - - 9 6 h o u r s a t 60C (140F): No b l C o a t i n g s P r o p e r t i e s - A f t e r A g i n g S o l u t i o n 4 wks a t 49C S u b s t r a t e : 20 gauge CRS w i t h B o n d e r i t e 37 Cure: 30 m i n u t e s a t 177F (350F)

ers

20F) :

P e n c i l hardness, c u t / s c r a t c h : 4H/H D i r e c t / r e v e r s e impact r e s i s t a n c e , i n . - l b : 160/160 MEK d o u b l e r u b s : 200+ 5 M i n u t e I 2 s t a i n t e s t : No s t a i n 500 Hours s a l t spray--mm creepage f r o m s c r i b e : 1 H u m i d i t y r e s i s t a n c e - - 9 6 h o u r s a t 60C (140F): No b l i s t e r s

SOURCE:

Eastman Chemical P r o d u c t s , I n c . : f r o m P o l y e s t e r R e s i n WS-17-1T

Enamel Prepared

Waterborne P o l v e s t e r / M e l a m i n e Enamel C1 e a r Enamel Comoosi t i on Inqredients: P r e d i s p e r s i on: WB-17-1NS P o l y e s t e r R e s i n ( n e a t ) I s o p r o p y l A1 coho1 D i s t i l l e d Water Cyme1 303 o r Resimene 745 Melamine R e s i n D i s t i 1 l e d Water

Wei q h t 100.0 20.0 20.0 42.9 136.0

Enamel P r e p a r a t i o n : Enamels can be c o n v e n i e n t l y p r e p a r e d b y w e i g h i n g t h e p r e d i s p e r s i o n i n t o a s u i t a b l e s t i r r e d v e s s e l and h e a t i n g t o a temperaa t u r e s l i g h t l y b e l o w r e f l u x ( a p p r o x i m a t e l y 70-8OC). B e g i n b y adding h o t d i s t i l l e d water s l o w l y t o reduce t h e p e r c e n t s o l i d s t o 50% i f i t i s n o t a l r e a d y a t t h a t l e v e l . Reduce t h e h e a t t o a p p r o x i m a t e l y 60C and add t h e melamine r e s i n . A g i t a t e t h e m i x t u r e w e l l and add t h e r e m a i n d e r o f t h e warm d i s t i l l e d w a t e r . These n o n a l k a l i n e d i s p e r s i o n s can have s h e l f s t a b i l i t y i n excess o f one y e a r . Enamel P r o p e r t i e s : P o l y e s t e r / M e l a m i ne: 70/30 D e n s i t y , l b / g a l ( g / L ) : 8 . 8 1 (1057) C a l c u l a t e d N o n v o l a t i l e s , w t %: 44.2 C a l c u l a t e d VOC, w t VOC/vol c o a t i n g : 1 . 6 (192) (minus H20), l b / g a l ( g / L ) V i s c o s i t y b y No. 4 F o r d Cup, sec: 11 Coating Properties: F i l m T h i c k n e s s , m i l s (um): 0 . 8 - 1 . 0 (20-25) P e n c i l Hardness, m a r / c u t : F/H Impact Resistance: D i r e c t , i n . / l b : 160 Reverse, i n . / l b : 150 MEK D o u b l e - r u b S o l v e n t R e s i s t a n c e : >250 1 / 8 - i n . C o n i c a l Mandrel F l e x i b i l i t y , % pass: 100 C l e v e l a n d H u m i d i t y , 100 h a t 60C ( 1 4 0 F ) : % G l o s s R e t e n t i o n a t 20: 88 B1 is t e r i ng: None S t a i n R e s i s t a n c e ( w a t e r / a c e t o n e r i n s e , 5=nO s t a i n ) : 5 min: 4 30 min: 3 G l o s s , %: a t 20: 80 a t 60: 99 a) On 20-gauge, c o l d - r o l l e d , B o n d e r i t e 37 p r e t r e a t e d s t e e l baked 30 m i n u t e s a t 150C ( 3 0 2 F ) . SOURCE: Eastman Chemical Co.: WB- 17- INS

Waterborne P o l y e s t e r R e s i n

138

Water -Based Paint Formulations

W a a r R e d u c i b l e A c r v l i c Enamel-IIB K-FLEX UD-320W Modi f.W T h i s f o r m u l a t i o n demonstrates s e v e r a l advantages when m o d i f y i n g a w a t e r r e d u c i b l e a c r y l i c system w i t h K-FLEX UD-320W. The advantages i n c l u d e l o w e r VOC, h a r d e r f i l m s and improved s a l t s p r a y , h u m i d i t y and QUV r e s i s t a n c e . P r o p e r t i e s g e n e r a l l y improved as t h e l e v e l of UD-320W was i n c r e a s e d . Pebble M i l l G r i n d : T i t a n o x 2020 A c r y s o l WS-68 K-F1 ex UD-320W Water Butyl Cellosolve n-Butanol DMEA Letdown : Grind: A c r y s o l WS-68 Water n-Butanol Dow C o r n i n g #57 (30% i n B u t y l C e l l o s o l v e ) DMEA (10% i n Water) Cyme1 303 K-F1 ex UD-320W

480.00 63.12 26.64 144.44 43.76 40.64 1.40

1073.60 282.24 16.88 4.64 9.36 216.00 80.00

Enamel C h a r a c t e r i s t i c s : A c r y l i c / K - F l e x / M e l a m i n e : 60/10/30 T o t a l S o l i d s , %: 48.3 T o t a l R e s i n S o l i d s , %: 29.0 P i gment/Binder: 40/60 VOC, c a l c . ( l b s / g a l ) : 0.50 pH: 7.27 V i s c o s i t y , 25C, c p s : 89 Film Properties: S u b s t r a t e : B o n d e r i t e 1000 ( I r o n Phosphated CRS) Cure: 30 min/250F (121C) C a t a l y s t : 1.6% Nacure X49-110 ( o n TRS) F i l m T h i c k n e s s : 0 . 9 m i l DFT A c r y l i c / K - F l e x / M e l a m i n e : 60/10/30 Penci 1 Hardness: F-H Knoop Hardness: 6 . 4 MEK Rubs: 80 I m p a c t , Rev., i n / l b : 5-10 , D i r . , i n / l b : 40-50 C r o s s h a t c h Adhesion, %: 100 I n i t i a l Gloss, 60: 8 9 . 6 , 20: 72.1 SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-4-11-B

Enamels

Water R e d u c i b l e A c r y l i c Enamel - 1 1 - C - I 1 P e b b l e M i l l Grind: T i t a n o x 2020 A c r y s o l WS-68 K-Fl ex UD-320W Water B u t y l C e l l os01ve n-Butanol DMEA

480.00 63.12 26.64 144.44 43.76 40.64 1.40

Letdown : Grind: A c r y s o l WS-68 Water n-Butanol Dow C o r n i n g #57 (30% i n B u t y l CellOSOlVe) DMEA (10% i n Water) Cyme1 303 K - F l e x UD-320W

789.44 452.72 16.88 4.64 7.04 252.00 160.00

Enamel C h a r a c t e r i s t i c s : A c r y l ic/K-Flex/Mel ami ne: 45/20/35 T o t a l S o l i d s , %: 4 8 . 3 T o t a l R e s i n S o l i d s , %: 29.0 P i gment/Bi n d e r : 40/60 VOC, c a l c . ( l b s / g a l ) : 0.60 pn: 7.28 V i s c o s i t y , 25C., c p s : 35 F i 1m Propert% S u b s t r a t e : B o n d e r i t e 1000 ( I r o n Phosphated CRS) Cure: 30 min/250F (121C) C a t a l y s t : 1 . 6 % Nacure X49-110 ( o n TRS) F i l m T h i c k n e s s : 0 . 9 m i l DFT A c r y l i c / K - F l e x / M e l a m i ne: 45/20/35 Penci 1 Hardness: H-2H Knoop Hardness: 7 . 0 MEK Rubs: 100 I m p a c t , Rev., i n / l b : 5-10 , D i r . , i n / l b : 30-40 C r o s s h a t c h Adhesion, %: 100 I n i t i a l Gloss, 60: 87.0 , 20: 7 8 . 9 S a l t Spray, 126 h r s mm C r e e p a g e / B l i s t e r : 7-9/NA H u m i d i t y , 60C, 250 h r s : G l o s s , 60: 1 1 . 4 , 20: 2 . 4 B1 is t e r : Med-Den/Mi c QUV**, 250 h r s : G l o s s , 60: 78.9 , 20: 4 2 . 7 QUV s c h e d u l e o f 8 h o u r s UV a t 50C., 4 h o u r s h u m i d i t y a t 40C.

**

SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-4-11-C-I1

139

140

Water-Bused Paint Formufations

Water R e d u c i b l e A i r D r y G l o s s W h i t e Enamel Pounds 106.81 2.94 2.11 8.46 8.44 84.56 146.71

Ingredients: Chempol 10-01 73 Byk P-104s S u r f y n o l 704BC 2-Butoxyethanol Ammoni um h y d r o x i de (28%) Water T i -Pure R - 9 0 0

Gal l o n s 12.33 0.37 0.28 1.12 1.13 10.15 4.27

Weigh i n f i r s t f o u r i n g r e d i e n t s and m i x w e l l . Add ammonia and water s e p a r a t e l y w i t h a g i t a t i o n . Add p i g m e n t s l o w l y w i t h c o n t i n u e d a g i t a t i o n . S a n d m i l l t o #7 Hegman k e e p i n g g r i n d t e m p e r a t u r e below 120F w i t h water j a c k e t . L e t down w i t h : 149.17 12.67 11.04 7.17 0.42 333.52 73.97

Chempol 10-01 73 Ammonium h y d r o x i d e (28%) 2-Butoxyethanol Nuocure CK-10 Byk 301 Water Water ( H o l d t o a d j u s t v i s c o s i t y )

17.22 1.70 1.58

0.88 0.05 40.04 8.88

I n t h e " l e t down", p r e - b l e n d r e s i n and ammonium h y d r o x i d e w i t h a g i t a t i o n . Premix t h e 2 - b u t o x y e t h a n o l , Nuocure CK-10, and Byk 301 and add t h i s p r e m i x t o t h e resin/ammonia m i x t u r e s l o w l y w i t h good a g i t a t i o n . S l o w l y add t h e f i r s t amount o f w a t e r and m i x w e l l . Now add t h e " l e t down" p o r t i o n to t h e g r i n d w i t h good a g i t a t i o n . M i x w e l l and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonium h y d r o x i d e i f n e c e s s a r y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % by w e i g h t : 35.06 T o t a l s o l i d s , % b y volume: 23.77 Weight/gallon, l b s . : 9.49 PVC: 17.97 P i gment/bi n d e r w e i g h t r a t i 0 : 0 . 7 9 / 1 00 VOC, l e s s w a t e r : 2.79 l b s / g a l . V i s c o s i t y #2 Zahn: 30"-50" pH: 8 . 0 - 8 . 5 DFT: 0 . 9 - 1 . 0 m i l s Cure: 1 week a i r d r y G l o s s , 60: 91 20: 76 P e n c i l hardness: B C r o s s h a t c h a d h e s i o n : 100% r e t e n t i o n , t a p e d

.

SOURCE:

Freeman Polymers D i v i s i on : CHEMPOL 10-01 73-A

Formul a

Enamels

Water R e d u c i b l e ,

141

Low G l o s s B l a c k Enamel

10-0091-E i s a w a t e r r e d u c i b l e , a i r d r y enamel, based on CHEMPOL 10-0091 a l k y d r e s i n . I t was e s p e c i a l l y f o r m u l a t e d f o r d i p , f l o w o r spray a p p l i c a t i o n over h i g h p r o f i l e , p o o r l y t r e a t e d s t e e l s u b s t r a t e . 10-0091-E w i l l p r o v i d e maximum c o r r o s i o n r e s i s t a n c e by p r o v i d i n g a h i g h - b u i l d f i l m designed t o b r i d g e o v e r i r r e g u l a r s u r f a c e s . F i l m s o f 10-0091-E d r y q u i c k l y (15-30 m i n u t e s ) and "tie-down'' f o r maximum p r o t e c t i o n o f m e t a l s u b s t r a t e . F i l m s exposed t o s a l t s p r a y show no l o s s o f adhesion a f t e r 1 hour r e c o v e r y .

I n a r e d ie n t s : Chempol 10-0091 Ammonium h y d r o x i d e (28% NH3 min) DMAMP- 8 0 E k t a s o l v e EP A n t i - S a g WR 300 Carbon 81 a c k - S t e r l ing R S t r o n t i u m Chromate B a r m i t e XF Durami t e Atomi t e S u r f y n o l PC Bentone 27 ) Premix Methyl a l c o h o l ) MPA 1075 ) Premix Butyl Cellosolve) Propasol P Butyl Cellosolve Bykumen 50% G i 1s o n i t e i n Xylene

Pounds 133.67 6.84 6.56 50.55 3.15 15.18 9.61 137.83 67.95 67.95 2.48 10.37 6.90 30.15 10.14 33.71 15.62 3.07 42.83

Gal l o n s 15.19 0.94 0.83 6.66 0.42 1.04 0.31 3.85 3.02 3.02 0.31 0.73 1.04 4.37 1.35 4.58 2.08 0.42 5.20

Combine CHEMPOL 10-0091, ammonium h y d r o x i d e , DMAMP-80, and E k t a s o l v e EP. M i x i n A n t i - S a g WR 300 and t h e n add p i g m e n t s . Add t h e r e m a i n i n g i n g r e d i e n t s and mix we1 1 . G r i n d i n a s t e e l b a l l m i l l t o a 6 Hegman. L e t Down W i t h : Chempol 10-0091 117.22 13.32 1 .62 0.21 5% C o b a l t Hydrocure I 1 5% C a l c i u m Hydrochem 3.39 0.42 5% Manganese Hydrochem 1.58 0.21 E x k i n #2 3.98 0.52 Water 159.52 19.15 Texanol 20.57 2.60 Ammonium h y d r o x i d e (28% NH3 m i n ) 2.26 0.31 S y l o i d 74x3500 10.35 0.62 N e o c r y l A-640 62.61 7.28 Mix " L e t Down" i n g r e d i e n t s i n o r d e r l i s t e d . Add t h e S y l o i d 74x3500 under a g i t a t i o n , t h e n add N e o c r y l A-640 s l o w l y w h i l e c o n t i n u i n g a g i t a t i o n . A d j u s t t o a f i n a l pH o f 8 . 0 - 8 . 5 w i t h ammoni um h y d r o x i de.

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 10-0091-E

Formulation

142

Water-Based Paint Formulations

Water-Reducible

P o l y e s t e r Enamel A

Grind ( a t t r i t o r l P i gment (R-900 T i 0 2 ) Resin WS-3-1C (76.5% N . V . ) D i m e t h y l e t h a n o l ami ne Hexamethoxymethyl melami ne Cyzac 4040 c a t a l y s t Flow c o n t o l agent (L-5310, 10% i n n - b u t a n o l )

Weight % 20.57 23.00 1.53 7.54 0.12 0.24

L e t Down: D i s t i l l e d Water

47.00

P h y s i c a l Constants: V i s c o s i t y , #4 F o r d Cup, sec: 27 pH: 8 . 2 N o n v o l a t i l e , w t %: 45.7 P o l y e s t e r / C r o s s l i n k e r , w t %: 70/30 P i gment/Bi n d e r , w t %: 45/55 W a t e r / O r g a n i c , w t %: 87/13 Cure c y c l e : 350F (177C) Physical Properties: F i l m t h i c k n e s s : 1 .O-1 . 5 m i l G l o s s , 60/20: 93/79 P e n c i l hardness: 4H C o n i c a l mandrel f l e x i b i l i t y , 1 / 8 i n . , ASTM D-522, % Pass: 100 Impact r e s i s t a n c e , D i r e c t , i n . - l b (cm-kg): >160 (>185) Reverse, i n . - l b (cm-kg): 140 (162) S o l v e n t r e s i s t a n c e , Double MEK Rubs: 200+ C r o s s h a t c h adhesion, % Pass: 100 S t a i n r e s i s t a n c e , 24 h r a t room temp ( b ) : Tomato j u i c e : 10 B l a c k shoe p o l i s h : 10 Mustard: 9 Iodine (5 minutes): 7 Detergent r e s i s t a n c e ( c ) : 1-1/2% AATCC S o l u t i o n a t 165+-2F: B l i s t e r i n g : 240 h r : Very Few #8 500 h r : ---% Gloss R e t e n t i o n , 60/20: 240 h r : 100/87 500 h r :

------

( b ) V i s u a l l y r a t e d u s i n g t h e f o l l o w i n g s c a l e : 10=No s t a i n , 8 = S l i g h t , 6=Moderate, 4 = C o n s i d e r a b l e . NOTE: S u b s t r a t e used was c o l d - r o l l e d s t e e l p a n e l t r e a t e d w i t h z i nc phosphate. ( c ) Epoxy primed, z i n c phosphate t r e a t e d , c o l d - r o l l e d s t e e l p a n e l s were used i n t h i s e v a l u a t i o n .

SOURCE:

Eastman Chemical P r o d u c t s ,

I n c . : Enamels Prepared

f r o m P o l y e s t e r R e s i n WS-3-1C

Enamels

Water-Reduci b l e P o l y e s t e r Enamel Grind ( a t t r i t o r ) : P i gment (R-900 T i 0 2 ) R e s i n WS-3-1C ( 7 6 . 5 % N.V.) D i m e t h y l e t h a n o l ami ne Benzoguanamine (85% N . V . ) Cyzac 4040 c a t a l y s t Flow c o n t r o l agent (L-5310,

10% i n n - b u t a n o l )

143

B Weiqht % 19.17 21.43 1.43 8.27 0.12 0.24

L e t Down : D i s t i11ed Water

49.34

Physical Constants: V i s c o s i t y , #4 F o r d Cup, sec: 30 pH: 8 . 4 N o n v o l a t i l e , w t %: 42.6 P o l y e s t e r / C r o s s l i n k e r , w t %: 70/30 P i gment/Bi n d e r , w t %: 45/55 Water/Organic, w t %: 86/14 Cure c y c l e : 350F (177C) f o r 30 m i n u t e s P h y s i c a l P r o p e r t i es : F i l m t h i c k n e s s : 1.0-1.5 m i l G l o s s , 60/20: 92/78 P e n c i l h a r d n e s s : 4H C o n i c a l mandrel f l e x i b i l i t y , 1 / 8 i n . , ASTM D-552, % Pass: 100 I m p a c t r e s i s t a n c e , D i r e c t , i n . - l b (cm-kg): 140 ( 1 6 2 ) Reverse, i n . - l b (cm-kg): 80 ( 9 2 ) S o l v e n t r e s i s t a n c e , Double M E K Rubs: 200+ C r o s s h a t c h a d h e s i o n , % Pass: 100 S t a i n r e s i s t a n c e , 24 h r a t room temp ( b ) : Tomato j u i c e : 10 B l a c k shoe p o l i s h : 10 Mustard: 9 I o d i n e ( 5 minutes) : 7 Detergent r e s i s t a n c e ( c ) : 1-1/2% AATCC S o l u t i o n a t 1 6 5 t - 2 F : B l i s t e r i n g : 240 h r : None 500 h r : Very Few #8 % G l o s s R e t e n t i o n , 60/20: 240 h r : l 0 0 / 8 9 500 h r : 92/72 b ) V i s u a l l y r a t e d u s i n g t h e f o l l o w i n g s c a l e : 10= No s t a i n , 8 = S l i g h t , 6=Moderate, 4 = C o n s i d e r a b l e . NOTE: S u b s t r a t e used was c o l d - r o l l e d s t e e l p a n e l s t r e a t e d w i t h z i n c phosphate. c ) Epoxy p r i m e d , z i n c phosphate t r e a t e d , c o l d - r o l l e d s t e e l p a n e l s were used i n t h i s e v a l u a t i o n .

SOURCE:

Eastman Chemical P r o d u c t s , P o l y e s t e r R e s i n WS-3-1C

I n c . : Enamel P r e p a r e d f r o m

144

Water-Based Paint Formulations

Water R e d u c i b l e W h i t e Enamel F o r m u l a t i o n 10-1706-A i s a w a t e r r e d u c i b l e , t h e r m o s e t t i n g , a c r y l i c enamel w h i c h p r o v i d e s good adhesion t o b o t h m e t a l l i c and n o n m e t a l l i c s u b s t r a t e s . Ingredients: Chempol 10-1 706 D i m e t h y l ethanolami ne N a l c o 2309 Bykumen E k t a s o l v e EP Water T i t a n i u m D i o x i d e (R-900) G r i n d Pebble M i l l 7 1 / 2 Add f o r s t a b i l i t y :

-

Pounds 49.28 5.10 4.31 4.33 23.16 53.16 183.48

Gal 1ons 5.60 0.69 0.59 0.59 2.95 6.39 5.51

49.28 5.10

5.60 0.69

98.65 45.53 9.46 1.53 42.47 406.60

11.21 4.42 1.28 0.20 5.41 48.87

8 Hegman gauge.

Chempol 10-1 706 Dimethylethanolamine L e t down w i t h : Chempol 10-1706 Cyme1 385 Dimethylethanolamine E x k i n No. 2 E k t a s o l v e EP Water Properties: T o t a l s o l i d s , % b y w e i g h t : 38 T o t a l s o l i d s , % b y volume: 25 V i s c o s i t y , #2 Zahn cup, seconds: 35 P i g m e n t / b i n d e r w e i g h t r a t i o : 1.0/1 .O PVC, %: 21.6 Weight/gallon, l b s . : 9.8 VOC, l b s . / g a l . , l e s s water: 3.2

Performance Notes: Drawndown 3 m i l s wet on B o n d e r i t e 1000 c u r e d a t 15'/325F: Dry f i l m t h i c k n e s s , m i l s : 0.8 60 G l o s s : 83 P e n c i l hardness: >4H C r o s s h a t c h adhesion: 100 MEK r e s i s t a n c e : 100 Forward i m p a c t : 20 Reverse i m p a c t : t 2 0 SOURCE: Freeman Polymers D i v i s i on : CHEMPOL 10-1 706-A Formul a t 1 on

Enamels

145

W h i t e A c r v l i c B a k i n g Enamel Pounds .~

I n q r e d ie n t s : Cyme1 303 Coroc A - 2 6 7 8 4 Butyl Cellosolve N a l c o 2309 D e i o n i zed w a t e r S u r f y n o l 104BC T i P u r e R700

43.90 43.90 32.93 1.10 131.71 0.88 219.51

Pebble g r i n d t o Hegman 7-1/2+, ing pre-mi xed: Chempol 20-4301 D e i o n i z e d Water

Gal 1ons 4.39 4.99 4.38 0.15 15.83 0.12 6.80

t h e n l e t down w i t h t h e f o l l o w -

M i x t h o r o u g h l y and c o n t i n u e l e t down w i t h : Cycat 4040 D i m e t h y l e t h a n o l ami ne Dei o n i zed w a t e r A d j u s t t o d e s i r e d v i s c o s i t y u s i n g DMEA.

426.95 75.73

48.52 9.10

2.20 0.88 44.34

0.27 0.12 5.33

P r o p e r t ies : T o t a l s o l i d s , % by w e i g h t : 43.00 T o t a l s o l i d s , % b y volume: 29.40 P/B w e i g h t r a t i o : 1 . 1 1 % PVC: 23.1 VOC; l b s / g a l l o n l e s s H20 ( t h e o r y ) : 1 . 2 8 I n i t i a l V i s c o s i t y #4 F o r d Cup, secs: 16-17 pH: 7 . 6 A d j u s t e d v i s c o s i t y , #4 F o r d Cup, s e c s : 45 (pH=8.2) F i l m P r o p e r t i e s : Spray a p p l i e d o v e r B l O O O t r e a t e d CRS: Suggested bake s c h e d u l e : 20 mins/325F D r y f i l m t h i c k n e s s , m i l s : 1.0-1.2 60/20 g l o s s : 80/40 P e n c i l h a r d n e s s : 3H MEK d o u b l e r u b s , 100: no e f f e c t 100% no t a p e o f f C r o s s h a t c h a d h e s i o n : Exc. Reverse i m p a c t , i n c h - l b s . : t 5 D i r e c t i m p a c t , i n c h - l b s . : 2 0 , s l . c r a c k i n g b u t no t a p e o f f l / 8 " c o n i c a l m a n d r e l : 12 mm c r a c k - no a d h e s i o n l o s s

-

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 20-4301-6

Formulation

146

Water-Based Paint Formulations

W h i t e A c r y l i c Emulsion Enamel Ingredients : Coroc A-2678-M 2-butoxyethanol S u r f y n o l 104BC S u r f y n o l DF-75 Water T i -Pure R-900

Pounds 21.70 7.30 7.62 1.25 28.67 152.49

Gal l o n s 2.47 0.97 1.01 0.15 3.44 4.44

Pre-mi x f ir s t f o u r i n g r e d i e n t s , t h e n add w a t e r w i t h a g i ta t i o n . Add pigment s l o w l y w i t h a g i t a t i o n . Cowles t o a #7 Hegman w i t h a h i g h speed d i s p e r s a t o r . A d j u s t g r i n d v i s c o s i t y w i t h w a t e r f r o m below i f n e c e s s a r y . L e t down w i t h : Chempol 20-4301 2-butoxyethanol B u t y l Carbi t o 1 Dibutyl Phthalate Nuocure C K - I O Michem 39235 Water ( h o l d t o a d j u s t v i s c o s t Y )

572.63 30.28 19.36 6.69 1.90 28.59 96.19

65.07 4.03 2.44 0.77 0.23 3.43 11.55

Premix c o - s o l v e n t s , p l a s t c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r s e e d i n g . A d d t h e wax d i s p e r s i o n t o t h e " l e t down" w i t h a g i t a t i o n . A f t e r m i x i n g w e l l , add t h e g r i n d t o t h e " l e t down" w i t h good a g i t a t i o n . M i x w e l l and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7.6, as t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % by w e i g h t : 40.25% T o t a l s o l i d s , % by volume: 29.26% Weight/gallon: 9.75 l b s . / g a l . PVC: 15.18 Pigment/binder r a t i o : 0.64 VOC: 1 . 8 8 l b s . / g a l . V i s c o s i t y : 30" #2 Zahn pH: 7.5 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y Set t o t o u c h : 1 2 ' Dust f r e e : 1 4 ' Tack f r e e : 3 0 ' Dry t h r o u g h : 3 0 ' DFT: 1 . 2 - 1 . 5 m i l

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 20-430 -B F o r m u l a t on

Enamels

I47

W h i t e A c r v l i c E m u l s i o n Enamel Inqredients:

Pounds

Gal 1ons

A c r y s o l 1-62 Ammonia, 28% 2-butoxyethanol S u r f y n o l 104BC S u r f y n o l DF-75 Water DuPont R-960 VHG

44.20 4.83 8.03 8.03 1.32 28.71 150.76

5.08 0.65 1.07 1.07 0.16 3.45 4.64

Add ammonia t o A c r y s o l 1-62 s l o w l y and w i t h good a g i t a t i o n u n t i l t h e s o l u t i o n t u r n s c l e a r and v i s c o u s . Add r e m a i n i n g i n g r e d i e n t s one a t a t i m e w i t h c o n t i n u e d a g i t a t i o n . Cowles t o a #7 Hegman w i t h a h i g h speed d i s p e r s a t o r . A d j u s t g r i n d v i s c o s i t y w i t h w a t e r f r o m b e l o w if n e c e s s a r y . L e t down w i t h : Chempol 20-4301 603.57 68.59 2-butoxyethanol 31.91 4.25 B u t y l Carbi t o 1 20.40 2.57 7.05 0.81 Dibutyl Phthalate 2.00 0.25 Nuocure CK-10 30.13 3.62 Michem 39235 Water ( h o l d t o a d j u s t v i s c o s i t y ) 31.57 3.79 Premix c o - s o l v e n t s , p l a s t i c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r s e e d i n g . Add t h e wax d i s p e r s i o n t o t h e " l e t down" w i t h a g i t a t i o n . A f t e r m i x i n g w e l l , add t h e g r i n d t o t h e " l e t down" w i t h good a g i t a t i o n . M i x w e l l and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7 . 6 , as t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . P r o p e r t ies : T o t a l s o l i d s , % b y w e i g h t : 42.58% T o t a l s o l i d s , % by volume: 32.06% W e i g h t / g a l l o n : 9.73 l b s . / g a l PVC: 1 4 . 4 7 P i g m e n t / b i n d e r r a t i o : 0.57 VOC: 1 . 7 6 l b s . / g a l V i s c o s i t y : 31" #2 Zahn pH: 7.6 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y Set t o t o u c h : 1 0 ' - 1 2 ' Dust f r e e : 1 3 ' - 1 5 ' Tack f r e e : 2 5 ' - 3 0 ' Dry t h r o u g h : 2 5 ' - 3 0 '

.

.

SOURCE:

Freeman Polymers

Di v i s on: CHEMPOL 20-430

-C Formul a t i on

148

Water-Based Paint Formulations

W h i t e A i r D r y Enamel C a r g i 11 Water R e d u c i b l e S i 1 icone Modi f ied A1 kyd 74-7435

L-531 O* E t h y l e n e G l y c o l Monobutyl E t h e r Aqueous Ammonia 28% D e i o n i z e d Water T i t a n i um D i o x i d e T i -Pure R-900

Pounds

Gal l o n s

197.9 2.5 11.9 8.3 118.7 237.6

21.94 0.30 1.59 0.96 14.25 6.97

118.7 5.3

13.16 0.61

14.3 3.6 4.5 1.2

1.90 0.45 0.62 0.16

248.4

29.64

62.1

7.45

H i g h Speed t o a 7 Hegman C a r g i l l Water R e d u c i b l e S i l i c o n e M o d i f i e d A1 k y d 74-7435 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: E t h y l e n e G1 y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i u m A c t iv-8 Dei o n i zed Water D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment)

*50% i n E t h y l e n e G l y c o l Monobutyl E t h e r Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 4 6 . 4 (By Volume): 3 0 . 7 Pigment t o B i n d e r R a t i o : 0 . 9 8 Weight Per G a l l o n : 1 0 . 3 5 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 3 9 ( G r a m s / L i t e r ) : 286 W a t e r : C o s o l v e n t Weight R a t i o : 7 5 . 5 : 2 4 . 5 pH: 8 . 5 V i s c o s i t y Krebs-Stormer (KU) : 78 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold Rolled Steel Dry F i l m T h i c k n e s s ( M i l s ) : 1 . 5 Gloss (60/20): 94/78 H u m i d i t y ( H o u r s ) : 96 Gloss (60/20): 89/75 B l i s t e r s : Medium Dense #4 O b s e r v a t i o n s : None QUV ( H o u r s ) : 500 Gloss (60/20): 35/4

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P i 686-1 89

Enamels

White A i r Dry Enamel C a r g i l l Water R e d u c i b l e S t y r e n a t e d Copolymer A l k y d 74-7425 E t h y l e n e G l y c o l Monobutyl E t h e r

Byk-301 Aqueous Ammonia 28% Titanium Dioxide Ti-Pure R-900 D e i o n i z e d Water

Pounds

Gal l o n s

213.1 11.2 2.2 10.1 201.8 72.9

24.63 1.49 0.28 1.35 5.77 8.75

78.5

9.07

11.2 5.6 1.1 1.3 0.6

1.49 0.83 0.14 0.17 0.07

3.4 319.6 1.1

0.45 38.37 0.15

2.2

0.26

56.1

6.73

H i g h Speed D i s p e r s e t o a 7 . 5 Hegman C a r g i l l Water R e d u c i b l e S t y r e n a t e d Copolymer A l k y d 74-7425 Premix t h e f o l l o w i n g ,

t h e n add:

E t h y l e n e G l y c o l Monobutyl E t h e r sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Manganese A c t i v-8 Aqueous Ammonia 28% Dei o n i zed Water E x k i n No. 2 Aqueous Ammonia 28% ( A d j u s t t o pH 8 . 0 - 8 . 5 ) D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment) Pai n t P r o p e r t i e s % N o n v o l a t i l e (By W e i g h t ) : 41.2 (By Volume): 2 8 . 2 Pigment t o B i n d e r R a t i o : 0 . 9 8 Weight Per G a l l o n : 9 . 9 2 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 7 0 ( G r a m s / L i t e r ) : 324 pH: 8 . 0 - 8 . 5 V i s c o s i t y Krebs-Stormer ( K U ) : 70-75 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 ) : 87 P e n c i l Hardness ( 1 Day): Pass 5 8 ( 7 Days): Pass 3 8 Impact ( I n . L b s . ) : D i r e c t : 20 D r y Time ( H o u r s ) : 1 / 3 5009 Zapon: 60-65

SOURCE: C a r g i l l , I n c . : CARGILL F o r m u l a r y : Formula P1883-Dl

149

150

Water-Based Paint Formulations

W h i t e A i r D r y Enamel C a r g i l l Water R e d u c i b l e Chain Stopped A1 k y d 74-7470 Aqueous Ammonia 28% T i t a n i u m D i o x i d e T i - P u r e R-902 Dei o n i zed Water

Pounds

Gal 1ons

90.6 6.0 186.7 146.9

10.42 0.80 5.46 17.64

159.5 7.9

18.34 1.06

28.1 1.8 2.2

3.74 0.24 0.28

350.2

42.02

Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e Chain Stopped A1 k y d 74-7470 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

E t h y l e n e G l y c o l Monobutyl E t h e r 5% C o b a l t Hydro Cure I 1 Manganese Hydor Cure I 1 D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 38.41 (By Volume): 25.57 Pigment t o B i n d e r R a t i o : 0 . 9 9 Pigment Volume C o n c e n t r a t i o n : 21.47 Weight Per G a l l o n : 9 . 8 0 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 4 6 ( G r a m s / L i t e r ) : 295 Water: Cosol v e n t Weight R a t i o : 84.03: 15.97 pH: 8 . 1 3 V i s c o s i t y Krebs-Stormer (KU) : 76 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel Dry F i l m T h i c k n e s s ( M i l s ) : 1 . 5 G l o s s ( 6 0 / 2 0 ) : 91/78 H u m i d i t y ( H o u r s ) : 96 G l o s s ( 6 0 / 2 0 ) : 92/70 B l i s t e r s : Medium #4 O b s e r v a t i o n s : None S o u t h F l o r i d a Exposure ( M o n t h s ) : Gloss (60/20) : Washed: 76/39 Unwashed: 71/38 SOURCE: C a r g i l l ,

Inc.:

6

CARGILL F o r m u l a r y : Formula P1843-30E

Enamels

W h i t e A i r D r y Enamel

C a r g i 11 Water R e d u c i b l e F a t t y A c i d A 1 k y d 74-7472 Aqueous Ammonia 28% T i t a n i um D i o x i d e T i -Pure R-902 Dei o n i zed Water

Pounds

Gal 1ons

96.9 7.7 208.2 125.9

11 .27 1.03 6.09 15.11

180.6 7.3

21 .oo 0.98

21.8 2.1 3.1

2.96 0.27 0.40

340.6

40.89

Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e F a t t y A c i d A1 k y d 74-7472 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

P r o p y l e n e G l y c o l Monopropyl E t h e r 5% C o b a l t Hydro Cure I 1 Manganese H y d r o Cure I 1 Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 42.14 (By Volume): 2 8 . 8 3 Pigment t o B i n d e r R a t i o : 0.99 Pigment Volume C o n c e n t r a t i o n : 21.25 Weight Per G a l l o n : 9 . 9 4 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.29 ( G r a m s / L i t e r ) : 275 W a t e r : C o s o l v e n t Weight R a t i o : 82.98:17.02 pH: 8.52 V i s c o s i t y #4 F o r d Cup (Seconds): 33 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel Dry F i l m Thickness ( M i l s ) : 1 . 5 G l o s s ( 6 0 / 2 0 ) : 87/60 QUV ( H o u r s ) : 500 G l o s s ( 6 0 / 2 0 ) : 18/1 South F l o r i d a Exposure ( M o n t h s ) : 6 Gloss (60/20) Washed: 64/17 Unwashed: 58/16 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1843-30H

151

I52

Water-Based Paint Formulations

White A i r Dry E n a e C a r g i l l Water R e d u c i b l e F a t t y A c i d A l k y d 74-7476 Aqueous Ammonia 28% T i t a n i um D i o x i d e T i -Pure R-902 D e i o n i z e d Water

Pounds

Gal l o n s

129.2

15.02 1.10 8.70 16.14

8.2 297.4 134.4

Sand M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e F a t t y A c i d A l k y d 74-7476 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

167.6 8.5

19.49

1.14

t h e n add:

E t h y l e n e G1y c o l Monobutyl E t h e r 5% C o b a l t Hydro Cure I 1 Manganese Hydro Cure I 1 Dei o n i zed Water

23.2

3.08

2.1

0.27

3.2

0.41

288.7

34.65

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 49.20 (By Volume): 32.86 Pigment t o B i n d e r R a t i o : 1.32 Pigment Volume C o n c e n t r a t i o n : 26.58 Weight Per G a l l o n : 10.63 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.19 ( G r a m s / L i t e r ) : 262 W a t e r : C o s o l v e n t Weight R a t i o : 8 0 . 6 2 : 1 9 . 3 8 pH: 8 . 0 7 V i s c o s i t y #4 F o r d Cup (Seconds): 18 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel Dry F i l m T h i c k n e s s ( M i l s ) : 1 . 5 G l o s s ( 6 0 / 2 0 ) : 87/70 H u m i d i t y ( H o u r s ) : 96 G l o s s ( 6 0 / 2 0 ) : 90/80 B l i s t e r s : Dense #6 O b s e r v a t i o n s : None QUV ( H o u r s ) : 500 Gloss (60/20): 38/3 South F l o r i d a Exposure (Months): G l o s s (60/20): Washed: 75/26 Unwashed: 66/24 SOURCE: C a r g i l l ,

6

I n c . : CARGILL F o r m u l a r y :

Formula P1843-30L

Enamels

W h i t e A i r Dry Enamel C a r g i 11 Water R e d u c i b l e Phenol ic Modi f ied A1 k y d 74-7478 Aqueous Ammonia 28% P r o p y l e n e G l y c o l Monopropyl E t h e r sec-Butanol T i t a n i u m D i o x i d e T i - P u r e R-902 D e i o n i z e d Water

Pounds

Gallons

150.3 7.0 7.6 3.8 207.0 182.5

17.48 0.94 1.03 0.57 6.05 21.91

126.3 6.7

14.68 0.89

7.6 3.8 4.2 0.7

1 .03 0.57 0.51 0.09

285.4

34.25

Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e Phenol ic Modi f ied A1 k y d 74-7478 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

P r o p y l e n e G l y c o l Monopropyl E t h e r sec-Butanol Nuocure CK 10% E x k i n No. 2 Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 41.98 (By Volume): 2 8 . 8 9 Pigment t o B i n d e r R a t i o : 0 . 9 9 Pigment Volume C o n c e n t r a t i o n : 21.13 Weight Per G a l l o n : 9 . 9 3 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 3 0 ( G r a m s / L i t e r ) : 275 W a t e r : C o s o l v e n t Weight R a t i o : 8 3 . 0 1 : 1 6 . 9 9 pH: 8 . 1 6 V i s c o s i t y Krebs-Stormer (KU): 87 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel Dry F i l m Thickness ( M i l s ) : 1.5 G l o s s ( 6 0 / 2 0 ) : 09/90 H u m i d i t y ( H o u r s ) : 96 G l o s s ( 6 0 / 2 0 ) : 81/68 B l i s t e r s : Medium Dense #8 QUV ( H o u r s ) : 500 G l o s s ( 6 0 / 2 0 ) : 31/2 S o u t h F l o r i d a Exposure ( M o n t h s ) : 6 Gloss (60/20): Washed: 88/57 Unwashed: 75/46 SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y :

Formula P1843-30N

I53

154

Water-Based Paint Formulations

White Ai r - D r y m a m e l Pounds

Gallons

76.3 2.6 161 . 1 49.9 1.5 8.0 1.5 70.5

8.62 0.35 4.60 2.21 0.18 1.06 0.20 8.46

175.0 6.1

19.75 0.81

E t h y l e n e G l y c o l Monobutyl E t h e r 5% C o b a l t Hydro Cure I 1 Manganese Hydro Cure I 1

4.2 1.3 1.3

0.56 0.16 0.15

A c t iv - 8 E x k i n No. 2 Raybo 62-HydroFlo E t h y l e n e G l y c o l Monobutyl E t h e r D e i o n i z e d Water

0.7 1.5 4.0 8.5 2.55.7

0.09 0.19 0.48 1 .13 30.71

4.0

0.53

164.6

19.76

C a r g i 11 Water R e d u c i b l e Chai n Stopped A1 k y d 74-7487 Aqueous Ammonia 28% T i t a n i u m D i o x i d e T i - P u r e R-900 Supercoat S u r f y n o l 104 E E t h y l e n e G l y c o l Monobutyl E t h e r Byk-020 D e i o n i z e d Water H i g h Speed t o a 7 Hegman C a r g i 11 Water R e d u c i b l e C h a i n Stopped A1 k y d 74-7487 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

Aqueous Ammonia 28% ( A d j u s t t o pH o f 8 . 3 ) D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Ad] u s t m e n t )

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 41 . 5 6 (By Volume): 28.55 Pigment t o B i n d e r R a t i o : 1 . 0 4 Pigment Volume C o n c e n t r a t i o n : 2 3 . 9 4 Weight Per G a l l o n : 9.98 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 0 9 ( G r a m s / L i t e r ) : 250 W a t e r : C o s o l v e n t Weight R a t i o : 85.70:14 . 3 0 pH: 8 . 3 V i s c o s i t y #4 F o r d Cup (Seconds): 36 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 91/77 P e n c i l Hardness: Pass B % C r o s s h a t c h Adhesion: 100 SOURCE: C a r g i l l ,

Inc.: CARGILL F o r m u l a r y : Formula P1887-5181

Enamels

W h i t e A i r D r y Enamel Pounds ~ _ C a r g i 11 Water R e d u c i b l e Chain Stopped A1 kyd 74-7495 Aqueous Ammonia 28% sec-Butanol E t h y l e n e G l y c o l Monobutyl E t h e r Byk-301 T i t a n i um D i o x i d e T i -Pure R - 9 0 0 Dei o n i zed Water

_

Gallons

134.2 4.3 4.4 6.4 0.9 182.8 56.5

15.60 0.58 0.66 0.85 0.12 5.22 6.78

137.3 7.9

15.97 1.05

5.6 4.0 3.5 2.6 0.9

0.83 0.53 0.45 0.36 0.12

423.8

50.88

S a n d m i l l t o a 7 . 5 Hegman C a r g i l l Water R e d u c i b l e Chain Stopped A1 k y d 74-7495 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: sec-Butanol E t h y l e n e G l y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um A c t iv-8 D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 3 8 . 5 6 (By Volume): 25.75 Pigment t o B i n d e r R a t i o : 0.95 Pigment Volume C o n c e n t r a t i o n : 20.47 Weight Per G a l l o n : 9.75 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.66 (Grams/Li t e r ) : 319 W a t e r : C o s o l v e n t Weight R a t i o : 81.64:18.36 pH: 8 . 7 V i s c o s i t y Krebs-Stormer ( K U ) : 65-75 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold Rolled Steel Gloss ( 6 0 / 2 0 ) : 86/74 P e n c i l Hardness: Pass B % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 30 Reverse: (5 Dry Time L i n e a r D r y i n g Recorder ( H o u r s ) : 3 / 4 H u m i d i t y ( H o u r s ) : 100 O b s e r v a t i o n s : None

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P1843-25714

155

156

Water-Based Paint Formulations

W h i t e Enamel

Lbs.

M a t e r i a1 : Water Tamol 731 T i - P u r e R902 Foamaster V L

63.14 3.40 221 .ll 0.23

Gals. 7.58 0.37 6.66 0.03

602.48 60.44 48.98 7.09 11.65

69.25 8.07 5.88 0.70 1.56

Pebble m i l l t o a 7 Hegman g r i n d . Letdown : A r o l o n 845-W-45 Butoxy E t h a n o l Water 10% Sodium N i t r i t e Ammoni u m H y d r o x i de

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 17.61 P i g m e n t / B i n d e r R a t i o : 0 . 8 / 1 .OO P e r c e n t Sol ids, Wei g h t : 48.96 P e r c e n t S o l i d s , Volume: 38.45 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 35-45 Pounds/Gallon: 10.17 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 160.80 Pounds/Gallon: 1 . 3 4

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2402-24A

Inc.:

Waterborne Handbook:

Enamels

W h i t e Enamel M a t e r i a1 :

Pounds

Gallons

162.1 53.5

16.84 7.21

216.0 250.0 4.0

24.80 7.60 0.50

P a r t A: Epi-Rez 510 Epoxy R e s i n H e l o x y 8 Epoxy F u n c t i o n a l Mod f i e r Part 8 : Epi -Cure W50-8535 C u r i n g Agen R u t i l e T i t a n i u m D i o x i d e (2) Defoamer (3) H i g h speed d i s p e r s e t o t e x t u r e 7-8 NS. Glacial Acetic Acid Defoamer (3) Water

Reduce speed and add:

2.0 4.0 352.4

0.24 0.50 42.31

215.6 828.4

24.05 75.95

(2) T i t a n o x 2020 (3) C o l l o i d 640 Composite B1end: Part A Part B P a r t s A and B

Viscosity 68 KU 60 KU 100 KU

Typical Coating Properties: T o t a l Weight S o l i d s , p e r c e n t : 44.2 T o t a l Volume S o l i d s , p e r c e n t : 45.0 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gal 1on : 0.14 Grams/Li t e r : 16.8

SOURCE: She1 1 Chemical Co. : 24-212 W h i t e Enamel U s i n g EPI-CURE W50-8535 C u r i n g Agent

157

158

Water-Based Paint Formulations

W h i t e Enamel M a t e r i a1 : Pounds P a r t A: R u t i l e Titanium Dioxide 250.0 Epi-Rez 510 Epoxy R e s i n 130.0 H i g h speed d i s p e r s e t o t e x t u r e o f 10 P.C.S. Add: Epi-Rez 510 Epoxy R e s i n 32.1 H e l o x y 8 Epoxy F u n c t i o n a l M o d i f i e r 53.5

____ Gallons 7.34 13.50 3.34 5.82

P a r t 8: Epi-Cure W50-8535 C u r i n g Agent Glacial Acetic Acid Water

216.0 2.0 374.0

24.80 0.24 44.96

Composite B l e n d : Part A Part 0

465.6 592.0

30.00 70.00

Typical Coating Properties Viscosity: F r e s h : 75-85 KU 1 Hour: O f f S c a l e Pounds/Gal 1on : 10.58 A p p l i c a t i o n : B r u s h o r Spray Cure Schedule: Room Temperature P.V.C.: 17.5% V e h i c l e Non-Vol a t i 1e : 45.8% T o t a l S o l i d s : 53.2% Typical Film Properties: G l o s s (60 A n g l e ) : 98 U n i t s Penci 1 Hardness: "E" 72 Hours Cure Resin Composition: Epoxy R e s i n : 66.5% C u r i n g Agent: 33.5%

SOURCE: S h e l l Chemical Co.:

24-146 W h i t e Enamel

Enamels

159

W h i t e Enamel F o r m u l a t i o n Materials: R e s i n WE-300 (80% NVM) D i m e t h y l e t h a n o l a m i ne D e i o n i zed w a t e r Melamine ( 1 ) Flow agent ( 2 ) Titanium dioxide (3) Water f o r s p r a y v i s c o s i t y ( a p p r o x ) Solvent ( 4 ) f o r spray v i s c o s i t y (approx) Coating Properties: P i g m e n t / b i n d e r r a t i o : 0 . 9 / 1 .O Resin/melamine r a t i o : 15/85 W a t e r / c o s o l v e n t r a t i o : 82/18 N o n - v o l a t i l e m a t e r i a l (NVM), w t % : V i s c o s i t y , #4 Ford, sec: 30-35 pH: 7.5-8.0

P a r t s by w e i q h t 288.2 16.3 262.6 40.7 0.5 244.1 121.1 26.5

53-54

Compounding Procedure: 1. M i x p o l y e s t e r r e s i n and d i m e t h y l e t h a n o l a m i n e u n t i l homogeneous. S l o w l y add w a t e r u n t i l mixed t h o r o u g h l y . S t i r i n melamine and a d j u s t pH t o 7 . 5 - 8 . 0 . 2. S t i r i n f l o w agent and p i g m e n t . 3 . Charge m i x t u r e t o p e b b l e m i l l . R o l l o v e r n i g h t t o Hegman G r i n d o f 7+. 4 . D i s c h a r g e m i l l and a d j u s t t o d e s i r e d a p p l i c a t i o n v i s c o s i t y .

(1) (2) (3) (4)

Cyme1 303 FC-430 T i - P u r e R-900 B u t y l Carbi t o 1 d i e t h y l e n e g l y c o l n - b u t y l

Performance P r o p e r t i e s ( 1 ) : P r o p e r t i e s : CRS ( 4 ) : F i l m thickness, m i l s : 1.3 60 g l o s s , %: 92 Yellowness i n d e x ( 7 ) : -3.83 Sward hardness: 89 P e n c i l hardness: 2H Impact r e s i s t a n c e , i n - l b : d i r e c t : 80 r e v e r s e : 50 C o n i c a l bend, 1 / 8 - i n c h , % pass: 100 C r o s s h a t c h a d h e s i o n : 48 ( 1 ) Cure c y c l e : 20 m i n u t e s a t 177C ( 2 ) Commercial s o l v e n t - a p p l i e d , o i 1 - f r e e , ( 4 ) Cold r o l l e d s t e e l ( 7 ) Yellowness index:[(A-E)/G]xlOO

ether

f l e x i b l e polyester

SOURCE: Amoco Chemical Co.: Water-Borne Bake P o l y e s t e r s Based on AMOCO IPA and TMA: Formula T a b l e 11 and 1 2

160

Water-Based Paint Formulations

W h i t e F a s t D r v Enamel M a t e r i a1 : A r o l on 970-G4-70 Premi x : Cobalt Hydrocure A c t i v-8 T i -Pure R-902 R o l l e r m i l l t o 7 Hegman g r i n d Letdown : A r o l o n 970-G4-70 Ammoni um H y d r o x i de Propasol P Butoxy E t h a n o l sec-Butanol n - But a n 0 1 Lodyne S-107 Water Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : Pigment/Binder R a t i o : .7/1 P e r c e n t S o l i d s , W e i g h t : 26.9 P e r c e n t S o l i d s , Vol ume: ; 18.4 V i s c o s i t y @ 25C, #4 F o r d , S e c s . : 45-50 Pounds/Gallon: 9 . 0 8 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 409 Pounds/Gallon: 3 . 4 1

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2053-35

Inc.:

Lbs. 14a.93

Gals. 16.93

4.27 .72 100.93

.56 .09 3.03

55.82 7.82 7.24 17.16 16.29 17.59 1.55 528.81

6.34 1.04 .98 2.29 2.43 2.61 .16 63.48

16.5

Waterborne Handbook:

Enamels

W h i t e G l o s s Enamel Material : A r o l o n 860-W-45 S u r f y n o l 104H C o l l o i d 679 Water Ammoni um H y d r o x i d e T i t a n o x 2101 Cowles g r i n d t o a 6 Hegman. Letdown : A r o l o n 860-W-45 Butoxy Ethanol Diethylene Glycol n-Butyl Byk 301 10% Sodium N i t r i t e Water Ammoni um H y d r o x i d e

Ether

Lbs. 285.12 2.59 2.81 60.48 2.16 226.80

Gals. 32.44 0.32 0.39 7.26 0.28 6.80

341.28 28.08 28.08 1.08 4.10 43.20 4.32

38.04 3.74 3.54 0.13 0.50 5.18 0.58

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 18.2 Pigment/Binder R a t i o : .8/1 P e r c e n t S o l i d s , W e i g h t : 49.4 P e r c e n t S o l i d s , Volume: 37.5 V i s c o s i t y @ 25C, #2 Zahn, S e c s . : 35-45 Pounds/Gallon: 10.30 pH: 8.2-8.5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 155 Pounds/Gal 1on : 1 .29

SOURCE:

R e i c h h o l d Chemicals, I n c . : F o r m u l a t i o n 2402-1744

Waterborne Handbook:

161

I62

Water-Based Paint Formulations

W h i t e G l o s s Enamel

Lbs.

Material : K e l s o l 3960-B2G-75 Premi x : A c t iv-8 C o b a l t Hydrocure Add t h e n add: Butoxy E t h a n o l T i t a n o x 2101 R o l l e r m i l l t o 7 Hegman g r i n d . Letdown : K e l s o l 3960-B2G-75 n-Butanol sec-Butanol Ammoni um H y d r o x i d e Butoxy E t h a n o l Water

183.30

Gals. 21 .OB

0.92 5.68

0.12 0.75

9.17 188.80

1.22 5.67

69.65 13.44 12.83 13.44 3.67 474.14

8.01 2.00 1.92 1.80 0.50 56.93

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 22.0 Pigment/Binder R a t i o : 1/1 P e r c e n t S o l i d s , Weight: 32.2 P e r c e n t S o l i d s , Volume: 25.7 V i s c o s i t y @ 25C, #4 Ford, Secs.: 53-56 Pounds/Gallon: 11.74 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 302 Pounds/Gallon: 2.52

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2079-7

I n c . : Waterborne Handbook:

Enamels

163

W h i t e G l o s s Enamel

Lbs.

M a t e r i a1 : Kel s o l 3990-B2G-70 Ammonium H y d r o x i d e Butoxy E t h a n o l D i a c e t o n e A1 coho1 Propyl Dipropasol Premix : C o b a l t Hydrocure I 1 A c t i v-8 Butoxy E t h a n o l T i t a n o x 2101 Water Pebble m i l l t o a 7 Hegman g r i n d . Letdown : Kel s o l 3990-026-70 Ammonium H y d r o x i d e Water

Gals 14.79 0.90 2.22 1 .07 1.07

5.07 0.80 2.48 171.50 208.80

0.67 0.10 0.33 5.15 24.98

119.91 4.11 283.05

14.19

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 21.2 Pigment/Binder R a t i o : 1 / 1 P e r c e n t S o l i d s , Weight: 36.07 P e r c e n t Sol i d s , Volume: 24.66 V i s c o s i t y @ 25C, #4 Ford, Secs.: 35-45 pH: 8 . 2 - 8 . 5 Pounds/Gallon: 9.60 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 334 Pounds/Gallon: 2.79

SOURCE:

R e i c h h o l d Chemicals, Formul a t i on 2470-59

.

124.98 6.72 16.67 8.37 8.31

I n c . : Waterborne Handbook:

0.55 33.98

164

Water-Based Paint Formulations

White.

H i q h G l o s s , A i r D r y o r F o r c e D r y Water R e d u c i b l e Enamel

10-1300-A i s f o r m u l a t e d t o d e m o n s t r a t e o u t s t a n d i n g p e r f o r m ance o f CHEMPOL 10-1300 i n h i g h g l o s s , a i r d r y and f o r c e d r y a p p l i c a t i o n f o r use o v e r t r e a t e d o r u n t r e a t e d m e t a l s u r f a c e s . T h i s enamel d e v e l o p s e a r l y w a t e r r e s i s t a n c e w i t h i n 2-4 h o u r s after application. 10-1300-A i s recommended f o r e i t h e r i n t e r i o r o r e x t e r i o r a p p l i c a t i o n s . S a l t s p r a y t e s t s have demonstrated t h e s u p e r i o r c o r r o s i o n r e s i s t a n c e p r o p e r t i e s o f 10-1300-A. T h i s enamel can be p r e p a r e d w i t h o u t f i r s t h a v i n g t o s o l u b i l i z e CHEMPOL 10-1300. I t i s recommended t h a t t h e f o r m u l a t i o n p r o c e d u r e be c l o s e l y f o l l o w e d . Changes i n pigment w e t t i n g a g e n t s o r d r i e r s may cause v a r i a t i o n i n g l o s s and performance. 10-1300-A c o n t a i n s 20% o r g a n i c s o l v e n t and amine, 80% w a t e r by volume, w h i c h meets R u l e 66 r e q u i r e m e n t s f o r w a t e r r e d u c i b l e coatings containing organic solvents. I n n r e d ie n t s : Premix i n o r d e r l i s t e d : Chempol 10-1 300 T r i e t h y l ami ne Polycompound W-953 N a l c o 435-36 Water Bykumen T i t a n i u m D i o x i d e ( T i - P u r e R--900)

Pounds

Gallons

66.71 4.86 2.84 1.49 91.06 2.84 186.76

8.07 0.82 0.37 0.15 10.91 0.37 5.38

G r i n d Pebble M i l l t o 7 1/2 Hegman. Add t o m i l l t h e f o l l o w i n g and r e d i s p e r s e one h o u r : Chempol 10-1 300 T r i e t h y l ami ne

8.07 0.82

66.71 4.86

L e t down w i t h : Premix i n o r d e r l i s t e d and add w h i l e under a g i t a t i o n : Chempol 10-1300 133.41 Triethylamine 11.35 E x k i n No. 2 1.49 P a i n t A d d i t i v e #14 1.49 Hydrocure 5.60 Water 382.99 Properties: T o t a l s o l i d s , % by w e i g h t : 38.72 T o t a l s o l i d s , % by volume: 26.00 V i s c o s i t y #4 F o r d cup, seconds: 30-45 R e d u c t i o n f o r s p r a y a p p l i c a t i o n : Use as i s Pigment/binder weight r a t i o : 1.0/1 .O PVC, %: 21 pH: 8 . 5 - 9 . 5 G l o s s , 60 Gardner: 100+ Weight/gallon, l b s . : 9.64

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 10-1300-A

16.41 1.87 0.15 0.15 0.75 45.98

Formulation

Enamels

165

Sugaested S t a r t i n a F o r m u l a t i o n 10-1300-F i s a r e f o r m u l a t i o n o f 10-1300-A w h i c h uses r e c e n t developments i n w a t e r - r e d u c i b l e t e c h n o l o g y . H i g h e r s o l i d s and enhanced p a i n t s t a b i l i t y a r e t h e improved p r o p e r t i e s a c h i e v e d w i t h 10-1300-F. Inqredients: Chempol 10-1 300 Triethylamine Coroc A2678M S u r f y n o l 1048C Dei o n i zed Water A c r y s o l ASEGO T i P u r e R700

Pounds 69.81 5.02 2.93 0.42 115.12 1.05 195.50

Gal 1ons 8.46 0.79 0.33 0.06 13.84 0.12 6.05

G r i n d p e b b l e m i l l t o Hegman 7 o r b e t t e r . L e t down w i t h : Chempol 10-1 300 NH40H (28% NH3) Dei o n i zed Water Coroc A2678M

69.81 3.66 26.16 4.19

8.46 0.49 3.14 0.48

Premix t h e f o l l o w i n g and c o n t i n u e l e t down under a g i t a t i o n : Chempol 10-1 300 Triethylamine NH4OH (28% NH3) E x k i n #2 8yk 301 C o b a l t H y d r o c u r e 11 Manganese H y d r o c u r e I 1 Dei o n i zed Water

139.61 6.07 4.19 1.57 0.52 7.33 3.14 313.97

16.92 0.96 0.56 0.20 0.06 0.96 0.37 37.74

Properties: T o t a l s o l i d s , % b y w e i g h t : 41.30 T o t a l s o l i d s , % b y volume: 28.06 V i s c o s i t y #4 F o r d Cup, s e c s . : 50.00 R e d u c t i o n f o r s p r a y a p p l i c a t i o n : Use as i s P/0 w e i g h t r a t i o : 1.00 PVC, %: 21.57 pH: 8.5-9.0 VOC, # / g a l l o n minus w a t e r : 2.35 Film Properties: 3 . 0 m i l wet drawdown o v e r g l a s s ; 78F; S e t t o t o u c h : 25-30 m i n u t e s Zapon (100 grams): 60-70 m i n u t e s Dry h a r d : 4-5 h o u r s 60 g l o s s : 90

75% r e l a t i v e h u m i d i t y :

SOURCE: Freeman Polymers D i v i s i o n : CHEMPOL 10-1300-F

Formulation

166

Water-Based Paint Formulations

W h i t e H i a h G l o s s B r u s h i n a Enamel

Lbs. Material: Gals. Water 85.0 10.20 T r i e t h y l ami ne 1 .24 7.5 12.0 Propasol P 1.63 90.0 K e l s o l 3922-G-80 10.43 P a t c o t e 531 1.o 0.14 T i -Pure R-902 275.0 8.04 A d j u s t pH t o 8 . 2 - 8 . 6 . G r i n d i n h i g h speed d i s p e r s e r f o r 15-20 m i n u t e s ( 6 + Hegman)

.

Letdown : K e l s o l 3922-6-80 A r o p l a z 1272 Ammoni um H y d r o x i d e Water P r e - b l end: Water A c r y s o l ASE-60 A d j u s t pH t o 8.2-8.6 Premix : P r o p a s o l P* A c t iv-8 Cobalt Hydrocure I 1 Cal c i um Hydrocem Z i r c o n i u m Hydrocem

*

196.0 12.0 13.0 368.0

22.71 1.44 1.73 44.18

7.0 7.0

0.80

14.0 0.5 3.5 3.5 3.0

1.90 0.06 0.46 0.44 0.36

b e f o r e p r o c e e d i ng.

M e t h y l C a r b i t o l may be s u b s t i t u t e d .

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 22.7 P i g m e n t / B i n d e r R a t i o : 1.14/1 P e r c e n t Sol i d s , Weight : 47.0 P e r c e n t S o l ids, Vol ume: 33.0 V i s c o s i t y @ 25C, #4 F o r d , S e c s . : 92-96 Pounds/Gallon: 10.30 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 235 Pounds/Gallon: 1 . 9 6

SOURCE:

0.84

R e i c h h o l d Chemicals, I n c . : F o r m u l a t i o n 2003-44-2AA

Waterborne Handbook:

Enamels

I67

W h i t e Semi-Gloss Trade S a l e s Enamel M a t e r i a1 : A r o l o n 580-W-2 Butoxy E t h a n o l E t h y l e n e G1 y c o l P o t a s s i um T r i p o l y p h o s p h a t e Tamol 731 6% C o b a l t Cyclodex I g e p a l CO-630 T r i t o n GR7 T i t a n o x 2101 D i s p e r s e t o 7+ Hegman g r i n d . Then add : Letdown : A r o l on 580-W-42 T h i c k e n e r LN Water Nopco NDW Rhoplex AC 707 Water

Lbs.

.

135.0 40.0 15.0 0.5 5.0 1.o 2.0 2.0 275.0

Gals 15.17 5.33 1.60 0.01 0.63 0.12 0.25 0.25 7.88

160.0 38.0 38.0 4.0 190.0 175.0

18.00 4.00 4.00 0.50 21 .ll 21 .oo

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 21.5 Pigment/Binder R a t i o : 1.1/1 P e r c e n t S o l i d s , Weight : 48.4 P e r c e n t S o l i d s , Volume: 34.0 V i s c o s i t y @ 25C, KU: 75-85 Pounds/Gallon: 10.83 pH: 7.0-7.5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 149 Pounds/Gal 1on : 1 . 2 4

SOURCE: R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i on 31 111-42-25

168

Water-Based Paint Formulations

WR P o l v e s t e r / M e l a t n i n e Enamel K-FLEX Modi-

Cowles G r i n d : C a r g i l l 7203 D i m e t h y l e t h a n o l amine Cymel 303 Byk 301 K-Flex 188 D I Water T i t a n o x 2020

50/15/35

156.4 10.8 54.8 1.3 23.5 30.0 313.1

7+ on Hegman Letdown : C a r g i l l 7203 D i m e t h y l e t h a n o l ami ne Cymel 303 K - F l e x 188 D I Water D I Water ( H o l d f o r A d j u s t m e n t ) Enamel C h a r a c t e r i s t i c s : % S o l i d s ( b y w t ) : 50 % TRS: 25 % N e u t r a l i z a t i o n : 100 Enamel p H : 8 . 0 Film Properties: S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS C a t a l y s t : None Cure: 1 5 ' @ 325F. F i l m Thickness: 0.75-0.80 m l P e n c i l Hardness: F-H Double MEK Rubs: 100+ I m p a c t Rev. i n . l b . : 120-130 D i r . i n . l b . : 130-140 C r o s s h a t c h Adhesion % Loss: 0 G l o s s 60: 90 Water Soak 50C. 72 h r . : 65/NA 60 G l o s s / B l i s t e r 240 h r . : 60/NA 480 h r . : 45/NA S a l t Spray 240 h r . mm C r e e p / B l i s t e r : 3-5/V. L t . 9 SOURCE: K i n g I n d u s t r i e s : Water R e d u c i b l e F o r m u l a t i o n #9

52.1 3.6 54.7 23.4 285.2 242.9

Enamels

Y e l l o w Gloss Enamel

Lbs.

M a t e r i a1 : Water Ammoni um H y d r o x i de Kel s o l 3904-064-75 Add i n o r d e r l i s t e d : Aquacat 12% Manganese Cem-All Butoxy E t h a n o l T i t a n o x 2101 Mapico Y e l l o w 1050 Chrome Y e l l o w X3356 Molybdate Orange YE-637-D Sand m i l l t o 6 Hegman g r i n d . Letdown : Water Ammonium H y d r o x i d e Butoxy E t h a n o l K e l s o l 3904-0G4-75 Analysis: Pigment Volume C o n c e n t r a t i o n , Pigment/Binder R a t i o : 1/1 P e r c e n t S o l i d s , Weight: 42.7 P e r c e n t S o l i d s , Volume: 28.0 Pounds/Gal l o n : 10.1 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 259 Pounds/Gal 1on : 2.16

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 1610-22

206.40 6.19 103.20

Gals. 24.77 0.83 11.94

2.06 2.06 10.32 15.48 46.44 144.48 6.19

0.24 0.26 1.37 0.45 1.37 3.11 0.13

275.54 6.19 5.16 180.60

33.12 0.83 0.69 20.89

P e r c e n t : 18.0

Inc.:

Waterborne Handbook:

169

I70

Water -Based Paint Formulations

Y e l l o w I r o n O x i d e H i n h G l o s s Enamel M a t e r i a1 : Kel s o l 3960-026-75 Ammoni um H y d r o x i de Butoxy E t h a n o l T i t a n o x 2101 Y e l l o w I r o n O x i d e 2288D Water Pebble m i l l t o a 7+ Hegman g r i n d Letdown : K e l s o l 3960-B2G-75 Ammonium H y d r o x i d e Butoxy Ethanol n-Butanol Cobalt Hydrocure I 1 A c t i v-8 Water

Lbs.

6.48 0.54 2.13 0.15 2.87 12.48

233.02 10.98 14.94 10.97 6.50 1.12 352.27

26.97 1.47 1.99 1.63 0.86 0.14 42.29

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 11.49 P i g m e n t / B i n d e r R a t i o : 0.47/1 .O P e r c e n t S o l i d s , W e i g h t : 35.76 P e r c e n t S o l ids, Vol ume : 26.87 V i s c o s i t y C 2 5 C , #4 F o r d , Secs.: 35-45 G l o s s (60/20): 93/87 Pounds/Gallon: 9.11 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 322.80 Pounds/Gallon: 2.69

SOURCE:

ReSchhold Chemicals, F o r m u l a t i o n 2403-47

Inc.:

Gals.

55.98 4.03 15.99 4.99 96.14 103.96

Waterborne Handbook:

62

Water -Based Paint Formulations

A c r y l ic Semi -G1 oss W h i t e En@ D i s p e r s i on : D i spersant (1 )

Pounds

Defoamer (2) P r o p y l ene g l y c o l H i g h g l o s s t i t a n i u m d i o x i d e (3) Reduction: Propylene g l y c o l A c r y l i c l a t e x (4) Vancide TH Water ) C o a l e s c e n t (5) ) Premix S u r f a c t a n t (6) ) Defoamer 3% Van Gel ( W a t e r / p r o p y l e n e g l y c o l 75/25 gel 1

Gal l o n s

I1 2 63 270

1.3 .27 7.3 7.9

30 556 1 23 12 2 3

3.5 62.7 0.1 2.8 1.5 0.23

103

12.0

0.4

1 ) Tamol 731 o r e q u i v a l e n t 2) Nopco NDW o r e q u i v a l e n t 3 ) T i P u r e R-900 o r e q u i v a l e n t 4 ) Rhoplex AC-490 o r e q u i v a l e n t 5 ) Texanol o r e q u i v a l e n t 6) T r i t o n GR-7 o r e q u i v a l e n t

Pain t Properties: C o n s i s t e n c y , KU: 77 Pigment volume c o n c e n t r a t i o n , %: 23 S o l i d s by w e i g h t , %: 49 S o l i d s by volume, %: 35 60 G l o s s , 1 week: 65-70 T h i s f o r m u l a t i o n e x h i b i t s t h e s u b s t i t u t i o n o f VAN GEL f o r b a c t e r i a - s e n s i t i v e c e l l u l o s i c t h i c k e n e r i n an a c r y l i c semig l o s s enamel. Manufacturing I n s t r u c t i o n s : (Equipment - h i g h shear d i s p e r s i o n t y p e ) Paint Preparation: 1 . Charge d i s p e r s a n t , defoamer and p r o p y l e n e g l y c o l t o s u i t a b l e container. 2. M i x a t l o w speed u n t i l u n i f o r m . 3 . Add and d i s p e r s e t i t a n i u m d i o x i d e , i n c r e a s i n g t h e m i x i n g speed as n e c e s s a r y . 4 . Reduce speed and add t h e f o l l o w i n g i n g r e d i e n t s , m i x i n g u n t i l u n i f o r m a f t e r each a d d i t i o n : p r o p y l e n e g l y c o l , l a t e x , c o a l e s c e n t p r e m i x , VANCIDE TH, defoamer and VAN GEL d i s p e r s i o n . Note: The use o f VAN GEL d i s p e r s i o n p r e v e n t s a i r entrapment and o p t i m i z e s g l o s s . The c o a l e s c e n t i s e m u l s i f i e d i n p r e m i x t o m i n i m i z e e f f e c t on l a t e x upon i n c o r p o r a t i o n .

SOURCE: R . T . V a n d e r b i l t Co.,

I n c . : Development F o r m u l a t i o n SG-201

Enamels

A i r - D r y Water-Reducible

63

Enamel Weiqht %

I n q r e d ie n t s : Grind: T i t a n i u m d i o x i d e , R-900 Polymon b l u e pigment R e s i n WA-17-2T, 75% N . V . Ammonium h y d r o x i d e , 28% E k t a s o l v e EB s o l v e n t Cycloden c o b a l t , 6% Co Cyclodex manganese, 6% Mn

16.07 0.85 27.57 1 .26 4.34 0.20 0.10

L e t Down: Water

49.61

Constants: N o n v o l a t i l e s , w t %: 37.6 P i gment/bi nder w t %: 45/55 W a t e r / o r g a n i c s , w t %: 82/18 V i s c o s i t y by No. 4 F o r d Cup, sec: 60 pH: 8 . 9 D r y i n g P r o p e r t i e s (One-Mi 1 Dry F i l m ) : S e t t o t o u c h , min ( b ) : 30 Tack f r e e , min ( c ) : 45 One-hour w a t e r s p o t , a f t e r 6 h o u r s : S l i g h t e f f e c t , recovery C o a t i n g P r o p e r t i e s , A f t e r 7 Days: Penci 1 hardness: B-HB Impact r e s i s t a n c e , i n . - l b : D i r e c t : 40 Reverse: 4 60 G l o s s : 83 S a l t s p r a y r e s i s t a n c e , 100 h o u r s : No creepage, gloss

full

no l o s s o f

S t a b i l i t y A f t e r 18 Months a t Ambient Temperature: pH: 7 . 1 V i s c o s i t y by No. 4 F o r d Cup, s e c : 34 S e t - t o - t o u c h , min ( b ) : 30 Tack f r e e , min ( c ) : 45 One-hour w a t e r s p o t , a f t e r 6 h o u r s : S l i g h t e f f e c t , recovery

full

b ) ASTM D1640.5.1 c ) ASTM D1640.5.3.3.1 d ) Unprimed, z i n c p h o s p h a t i z e d , c o l d r o l l e d s t e e l p a n e l s c o a t e d w i t h a 1 - m i l f i l m were used i n t h e s e e v a l u a t i o n s .

SOURCE: Eastman Chemical P r o d u c t s , I n c . : A i r - D r y i n g WaterR e d u c i b l e A1 kyd Enamel Based on TMPD G l y c o l

64

Wafer-Based Paint Formulations

A i r - D r y Water-Reduci b l e Enamel

Grind: T i -Pure R-900 p i g m e n t WA-17-6C (75% N.V.) a l k y d Ammonium h y d r o x i d e (28%) C o b a l t Cyclodex d r i e r (6%) Manganese Cyclodex d r i e r (6%) Activ-8 additive BYK 301 a d d i t i v e n-Butanol L e t Down: Water

Wei q h t 240.1 251.5 18.6 3.8 3.8 1.2 2.3 23.8 454.9

Physical Constants: N o n v o l a t i l e s , w t %: 42.9 P i g m e n t / B i n d e r , w t %: 56/44 Water/Organi c s , w t %: 84/16 V i s c o s i t y , No. 4 F o r d Cup, seconds: 36 pH: 8 . 8 Dry1 ng P r o p e r t i es (One-Mi 1 D r y F i l m ) : S e t t o t o u c h , ( b ) m i n : 20 Tack Free, ( c ) m i n : 35 1-Hour Water Spot, A f t e r 6 H o u r s : S l i g h t e f f e c t , f u l l recovery P r o p e r t i e s A f t e r 1 Week D r y ( d ) : P e n c i l Hardness: HB I m p a c t R e s i s t a n c e , D i r e c t : 28 Reverse: <4 G l o s s , % 60: 90 20: 70 S a l t - S p r a y R e s i s t a n c e , 100 h r , creepage f r o m S c r i b e , i n . : Carbon-Arc Weather-Ometer, 500 h r : % G l o s s R e t e n t i o n , 60: 66 2 0 : 44 P r o p e r t i e s A f t e r 3 Weeks D r y : S a l t - S p r a y R e s i s t a n c e , Creepage f r o m S c r i b e , i n . : @ 100 h r : None @ 200 h r : 1 / 1 6 @ 300 h r : 9 / 1 6 Solution S t a b i l i t y : A f t e r Four Weeks a t 120F: pH: 7 . 2 V i s c o s i t y , No. 4 F o r d Cup seconds: 155 D r y Time, S e t t o Touch, in n: 30 Tack F r e e , m i n : 45 G1o s s : E x c e l 1e n t Appearance: E x c e l l e n t b ) ASTM D 1 6 4 0 . 5 . 1 c ) ASTM D 1 6 4 0 . 5 . 3 . 3 . 1 d) Untreated c o l d - r o l l e d s t e e l panels coated w i t h a 1 - m i l were used i n t h e s e e v a l u a t i o n s . SOURCE: Eastman Chemical P r o d u c t s , I n c . : P o l y e s t e r R e s i n WA-17-6C

3/16

f i l m

Enamel P r e p a r e d f r o m

Enamels

65

Black Acrylic Emulsion Enamel Pounds 47.00 7.91 8.25 1.35 31 .OS 10.26

Inaredients: Coroc A - 2 6 7 8 4 2-butoxyethanol S u r f y n o l 104BC S u r f y n o l DF-75 Water Raven #14 powder

Gal 1ons 5.34 1.05 1.10 0.16 3.73 0.70

Pre-mix f i r s t f o u r i n g r e d i e n t s , t h e n add w a t e r w i t h a g i t a t i o n . Load m i x t u r e i n t o b a l l m i l l f o l l o w e d by p i g m e n t . S t e e l b a l l g r i n d t o a #7 Hegman. A d j u s t g r i n d a n d / o r wash m i l l u s i n g w a t e r f r o m below, i f n e c e s s a r y . L e t down w i t h : Chempol 20-4301 2-butoxyethanol B u t y l Carbit o 1 Dibutyl Phthalate Nuocure CK-10 Michem 39235 Water ( h o l d t o a d j u s t v i s c o s i t y )

507.57 32.79 20.97 7.24 2.06 30.96 77.03

66.77 4.37 2.64 0.83 0.25 3.72 9.34

Add t h e g r i n d t o t h e e m u l s i o n . Add i t s l o w l y and w i t h good a g i t a t i o n . Pre-mix c o - s o l v e n t s , p l a s t i c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r s e e d i n g . Add t h e wax d i s p e r s i o n t o t h e " l e t down" w i t h a g i t a t i o n . M i x w e l l , and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7 . 6 , a s t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % b y w e i g h t : 31.20% T o t a l s o l i d s , "4 by volume: 27.60% W e i g h t / g a l l o n : 8.65 l b s . / g a l . P V C : 2.55 Pigment/binder r a t i o : 0.04 VOC: 2 . 1 7 l b s . / g a l V i s c o s i t y : 49" # 2 Zahn pH: 7 . 5 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y Set t o t o u c h : 1 0 ' Dust f r e e : 1 5 ' Tack f r e e : 4 5 ' - 5 0 '

.

SOURCE:

Freeman Polymers D i v i s i on : CHEMPOL 20-4301 - F Formula

66

Water-Based Paint Formulations

__ B l a c k A i r D r y Enamel Pounds

~~

C a r g i l l Water R e d u c i b l e Epoxy E s t e r 73-7331 Aqueous Ammonia 28% E t h y l e n e G l y c o l Monobutyl E t h e r sec-Butanol Byk-301 S p e c i a l B l a c k 4A A e r o s i l R972 D e i o n i z e d Water

____. Gal 1ons

97.8 5.9 9.8 14.7 2.0 12.2 4.9 190.8

11.58 0.78 1 .30 2.18 0.24 0.83 0.27 22.90

181 .O 10.8

21.43 1.43

14.7 9.8 1. o 2.5 2.2

2.18 1.30 0.12 0.33 0.25

273.9

32.88

Pebble M i l l t o a 7 . 5 Hegman C a r g i 11 Water R e d u c i b l e Epoxy E s t e r 73-7331 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: sec-Butanol E t h y l e n e G l y c o l Monobutyl E t h e r Activ-8 5% C o b a l t Hydro Cure I 1 Manganese Hydro Cure I 1 D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 25.97 (By Volume): 23.47 Pigment t o B i n d e r R a t i o : 0.09 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3 . 2 4 ( G r a m s / L i t e r ) : 388 W a t e r : C o s o l v e n t Weight R a t i o : 77.80:22.20 PH: 8 . 2 - 8 . 7 V i s c o s i t y Krebs-Stormer (KU): 68-73 Typi c a l Cured F i 1rn P r o p e r t i es : Cure Schedule: 7 Days A i r Dry Substrate: Cold Rolled Steel Gloss ( 6 0 ) : 83 P e n c i l Hardness: Pass B Dry Time ( M i n u t e s ) : 65 H u m i d i t y ( H o u r s ) : 120 B1 is t e r s : None S a l t Spray ( H o u r s ) : 96 S c r i b e Creep ( m m ) : 5 % Wet Tape Adhesion: 98

SOURCE: C a r g i l l ,

Inc.: CARGILL F o r m u l a r y : F o r m u l a t i o n P1897-F1

Enamels

B l a c k A i r D r y Enamel Pounds

Gal 1ons

C a r g i l l Water R e d u c i b l e S t y r e n a t e d A l k y d Copolymer 74-7422 Aqueous Ammonia 28%

90.8 3.6

10.75 0.48

P r o p y l e n e G l y c o l Monobutyl E t h e r Byk-301 Special Black 4

9.1 1.8 10.2

1.24 0.22 0.69

181.6 5.9

21.49 0.79

P r o p y l e n e G l y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 4% C a l c i u m A c t iv-8

18.2 1.9 2.9 0.9

2.48 0.25 0.38 0.11

Dei o n i zed Water P r o p y l e n e G l y c o l Monobutyl E t h e r

455.4 10.4

54.67 1.43

41 . 8

5.02

Sand M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e S t r e n a t e d A l k y d Copolymer 74-7422 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment) Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 24.51 (By Volume): 21.83 Pigment t o B i n d e r R a t i o : 0.05 P i gment V o l ume Concent r a t ion : 3.30 Weight Per G a l l o n : 8 . 3 5 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3 . 1 9 ( G r a m s / L i t e r ) : 382 W a t e r : C o s o l v e n t Weight R a t i o : 80.00:20.00 pH: 8 . 0 V i s c o s i t y #4 F o r d Cup (Seconds): 44 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y S u b s t r a t e : C o l d R o l l ed S t e e l G l o s s ( 6 0 / 2 0 ) : 91/77 P e n c i l Hardness: Pass 2 8 % C r o s s h a t c h Adhesion: 80 Impact ( I n . L b s . ) : D i r e c t : 10 Reverse: 5 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula PlB57-207A

67

68

Water-Based Paint Formulations

__.._____ Black A i r

D r y Enamel

Pounds

Gal 1 ons

125.6 13.2 2.6 7.9 17.2 330.5

14.52 1.76 0.33 1.06 1.16 39.68

244.6

28.28

E t h y l e n e G l y c o l Monobutyl E t h e r sec-Butanol 5% C o b a l t Hydro Cure I 1 8% Manganese Hydro Cure I 1 Act iv - 8

13.2 6.6 1.7 1.3 0.8

1.76 0.98 0.22 0.15 0.10

Aqueous Ammonia 28% E x k i n No. 2

11.9 1.3

1.59 0.17

2.6

0.30

66.1

7.94

C a r g i 1 1 Water R e d u c i b l e S t y r e n a t e d A 1 kyd Copolymer 74-7425 E t h y l e n e G l y c o l Monobutyl E t h e r By k - 3 0 1 Aqueous Ammonia 28% Special Black 4A D e i o n i z e d Water Pebble M i l l t o a 7 . 5 Hegman C a r g i l l Water R e d u c i b l e S t y r e n a t e d A l k y d Copolymer 74-7425 Premix t h e f o l l o w i n g , t h e n add:

Aqueous Ammonia 28% ( a d j u s t t o pH 8 . 0 - 8 . 5 ) D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment) Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 3 3 . 0 (By Volume): 2 9 . 6 Pigment t o B i n d e r R a t i o : 0 . 0 7 Weight Per G a l l o n : 8 . 4 7 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3.00 (Grams/Li t e r ) : 360 pH: 8 . 0 - 8 . 5 V i s c o s i t y Krebs-Stormer (KU): 67-72 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r Dry Substrate: Cold Rolled Steel Gloss ( 6 0 ) : 87-92 P e n c i l Hardness ( 1 Day): Pass 68 ( 7 Days): Pass 38 Dry Time 5009 Zapon ( H o u r s ) : 1 SOURCE: C a r g i l l ,

Inc.: CARGILL F o r m u l a r y : Formula P1863--D2

Enamels

____ B l a c k A i r Dry Enamel Pounds

Gallons

53.0 1.9 2.0 9.7 68.3

6.23 0.24 0.27 0.66 8.20

195.2 11.9

22.97 1.59

2.9 2.9 1. o 40.2 3.0

0.38 0.40 0.12 5.46 0.38

2.6 439.4

0.34 52.76

C a r g i 11 Water R e d u c i b l e A c r y l ic Modi f ied A1 k y d 74-7432

Byk-301 Aqueous Ammonia 28% Special Black 4 D e i o n i zed Water Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e A c r y l ic Modi f ied A1 k y d 74-7432 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

I n t e r c a r 6% C o b a l t I n t e r c a r 6% Manganese A c t iv-8 P r o p y l e n e G l y c o l Monopropyl E t h e r D i a c e t o n e A1 coho1 Exkin No. 2 De o n i zed Water

Pa n t P r o p e r t i e s : % N o n v o l a t i l e (By W e i g h t ) : 22.42 (By Volume): 19.85 Pigment t o B i n d e r R a t i o : 0 . 0 6 Pigment Volume C o n c e n t r a t i o n : 3.54 Weight Per G a l l o n : 8 . 3 4 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3 . 4 2 ( G r a m s / L i t e r ) : 410 W a t e r : C o s o l v e n t Weight R a t i o : 8 0 . 0 0 : 2 0 . 0 0 pH: 8 . 4 0 V i s c o s i t y #4 F o r d Cup (Seconds): 61 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 85/60 P e n c i l Hardness: Pass B % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 70 Reverse: ( 5

SOURCE:

Cargill,

I n c . : CARGILL F o r m u l a r y : Formula P 1 8 4 8 - l 6 l A

69

70

Water -Based Paint Formulations

_B_l a _c _k _ _A~ ~i r_ _D_ r y Enamel ~

Pounds

Gal 1ons

86.0 4.2 15.4 10.6 3.6 1.4 96.6

10.12 0.57 2.28 0.71 0.20 0.24 0.17 11.60

196.5 9.9

23.12 1.32

2.8 1.8 2.5 1.4 0.8

0.42 0.23 0.34 0.18 0.10

0.8 248.6

0.10 29.85

153.7

18.45

C a r g i 11 Water R e d u c i b l e A c r y l i c Modi f ied A1 k y d 74-7432 Aqueous Ammonia 28% sec-Butanol Special Black 4 A e r o s i l R972 Byk-020 S u r f y n o l 104E D e i o n i zed Water

1.8

B a l l M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e A c r y l ic Modi f ied A1 k y d 74-7432 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i u m I n t e r c a r 4% C a l c i u m A c t iv-8 E x k i n No. 2 Dei o n i zed Water Dei on1 zed Water Ad j ustment )

(Hold f o r V i s c o s i t y

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 25.68 (By Volume): 2 2 . 6 9 Pigment t o B i n d e r R a t i o : 0 . 0 7 Pigment Volume C o n c e n t r a t i o n : 4.19 Weight Per G a l l o n : 8 . 3 8 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 9 3 (Grams/Li t e r ) : 351 W a t e r : C o s o l v e n t Weight R a t i o : 81.72:18.28 pH: 8 . 4 V i s c o s i t y Krebs-Stormer (KU): 68 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G1o s s ( 6 0 / 2 0 ) : 79/38 P e n c i l Hardness: Pass 2 8 % C r o s s h a t c h Adhesion: 90 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1843-125A

Enamels

B l a c k A i r D r y Enamel Pounds

Gal 1ons

80.3 4.2 26.4 10.6 3.6 1.8 1.4 96.8

9.24 0.57 3.93 0.71 0.20 0.24 0.17 11.62

C a r g i 11 Water R e d u c i b l e Chain Stopped A1 k y d 74-7470 Aqueous Ammonia 28% sec-Butanol Special Black 4 A e r o s i l R972 Byk-020 S u r f y n o l 104E D e i o n i z e d Water B a l l M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e Chain Stopped A1 k y d 74-7470 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

183.6 9.9

21 .ll 1.32

t h e n add: 10.7 1.8 2.5 1.4 0.8

1.59 0.23 0.34 0.18 0.10

0.8 402.9

0.10 48.35

sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um I n t e r c a r 4% C a l c i u m A c t iv-8 E x k i n No. 2 Dei o n i zed Water

P a i n t P r o p e r t i 8s: % N o n v o l a t i l e (By W e i g h t ) : 2 5 . 6 8 (By Volume): 2 2 . 2 0 Pigment t o B i n d e r R a t i o : 0 . 0 7 Pigment Volume C o n c e n t r a t i o n : 4 . 2 9 Weight Per G a l l o n : 8 . 3 9 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 9 4 ( G r a m s / L i t e r ) : 352 W a t e r : C o s o l v e n t Weight R a t i o : 8 1 . 7 2 : 1 8 . 2 8 pH: 8 . 5 V i s c o s i t y Krebs-Stormer ( K U ) : 65 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 76/35 P e n c i l Hardness: Pass 38 % C r o s s h a t c h Adhsion: 70 Impact ( i n . l b s . ) : D i r e c t : 40 Reverse: >5

SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1843-125D

71

72

Water-Based Paint Formulations

B l a c k A i r D r y Enamel Pounds

Gal 1ons

80.1 4.2 26.3 10.5 3.6 1.8 1.4 96.4

9.31 0.56 3.91 0.71

C a r g i l l Water R e d u c i b l e F a t t y A c i d A l k y d 74-7472 Aqueous Ammonia 28% sec-Butanol Special Black 4 A e r o s i l 13972 Byk-020 S u r f y n o l 104E D e i o n i z e d Water

0.20 0.24 0.17 11.58

B a l l M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e F a t t y A c i d A l k y d 74-7472 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

183.0 9.9

21.28

10.6 1.8 1.4 0.8

1.58 0.23 0.34 0.18 0.10

0.8 401.4

0.10 48.19

1.32

t h e n add:

sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um I n t e r c a r 4% C a l c i u m A c t iv-8 E x k i n No. 2 Dei o n i zed Water

2.4

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 2 5 . 6 8 (By Volume): 2 2 . 4 8 Pigment t o B i n d e r R a t i o : 0 . 0 7 Pigment Volume C o n c e n t r a t i o n : 4 . 2 3 Weight Per G a l l o n : 8 . 3 6 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 9 1 ( G r a m s / L i t e r ) : 349 W a t e r : C o s o l v e n t Weight R a t i o : 8 1 . 7 2 : 1 8 . 2 8 pH: 8 . 3 V i s c o s i t y Krebs-Stormer (KU): 74 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 86/70 P e n c i l Hardness: Pass 28 % C r o s s h a t c h Adhesion: 90 Impact ( I n . L b s . ) : D i r e c t : 30 Reverse: <5

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y :

Formula P1843-125E

Enamels

B l a c k A i r D r y Enamel C a r g i 11 Water R e d u c i b l e Chain Stopped A1 k y d 74-7474 Aqueous Ammonia 28% sec-Butanol Special Black 4 A e r o s i l R972 Byk-020 S u r f y n o l 104 E Dei o n i zed Water

Pounds

Gal l o n s

85.5 4.5 28.1 11.3 3.8 1.9 1.5 103.0

9.71 0.60 4.18 0.76 0.21 0.26 0.18 12.36

195.4 10.5

22.20 1 .41

11.4 1.9 2.6 1.5 0.8

1.69 0.25 0.36 0.19 0.10

0.8 378.4

45.44

B a l l M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e Chain Stopped A1 k y d 74-7474 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um I n t e r c a r 4% C a l c i u m Activ-8 E x k i n No. 2 D e i o n i z e d Water

0.10

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 27.21 (By Volume): 2 3 . 3 6 Pigment t o B i n d e r R a t i o : 0 . 0 7 Pigment Volume C o n c e n t r a t i o n : 4 . 3 4 Weight Per G a l l o n : 8 . 4 3 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.97 ( G r a m s / L i t e r ) : 356 W a t e r : C o s o l v e n t Weight R a t i o : 8 0 . 2 2 : 19.78 pH: 0 . 2 V i s c o s i t y Krebs-Stormer ( K U ) : 72 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 90/71 P e n c i l Hardness: Pass 3 8 % C r o s s h a t c h Adhesion: 50 Impact ( i n . l b s . ) : D i r e c t : 20 Reverse: 15 D r y Time: S e t t o Touch ( M i n u t e s ) : 37 5009 Zapon ( H o u r s ) : 4 1/2

SOURCE: C a r g i l l , I n c . : CARGILL F o r m u l a r y : Formula P1843-125F

73

74

Water-Based Paint Formulations

Pounds

GsXws

80.1 4.2 26.3 10.5 3.6 1.8 1.4 96.4

9.31 0.56 3.91 0.71 0.20 0.24 0.17 11.58

183.0 9.9

21.28 1.32

10.6 1.8 2.4 1.4 0.8

1.58 0.23 0.34 0.18 0.10

0.8 401.4

0.10 48.19

C a r g i 11 Water R e d u c i b l e F a t t y A c i d A l k y d 74-7476 Aqueous Ammonia 28% sec-Butanol Special Black 4 A e r o s i l R972 By k - 02 0 S u r f y n o l 104 E D e i o n i z e d Water B a l l M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e F a t t y A c i d A l k y d 74-7476 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i u m I n t e r c a r 4% C a l c i u m A c t iv-8 E x k i n No. 2 D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 25.68 (By Volume): 2 2 . 3 6 Pigment t o B i n d e r R a t i o : 0 . 0 7 Pigment Volume C o n c e n t r a t i o n : 4 . 2 5 Weight Per G a l l o n : 8 . 3 6 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 9 1 (Grams/Li t e r ) : 349 W a t e r : C o s o l v e n t Weight R a t i o : 8 1 . 7 2 : 1 8 . 2 8 pH: 8 . 3 V i s c o s i t y Krebs-Stormer ( K U ) : 65 T y p i c a l Cured F i 1m P r o p e r t i es : Cure S c h e d u l e : 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 D ) : 87/72 P e n c i l Hardness: Pass 28 % C r o s s h a t c h Adhesion: 95 I m p a c t ( I n . L b s . ) : D i r e c t : 30 Reverse: <5 Dry Time: S e t t o Touch ( M i n u t e s ) : 25 500g Zapon ( H o u r s ) : 2 8

SOURCE: C a r g i l l ,

I n c . : C A R G I L L F o r m u l a r y : Formula P I 043-1 25G

Enamels

___Black A i r Dry E n m e 1

Cargi 1 1 Water Reducible Phenol i c Modi f i ed A1 kyd 74-7478 Aqueous Ammonia 28% sec-Butanol Special Black 4 Aerosil R972 Byk-020 Surfynol 1 0 4 E Deionized Water

Pounds

Gallons

84.9 4.5 27.9 11.2 3.8 1.5 102.2

9.87 0.60 4.15 0.75 0.21 0.26 0.18 12.27

193.9 10.5

22.55 1 .40

11.3 1.9 2.6 1.5 0.8

1.67 0.25 0.36 0.19 0.10

0.8 375.6

0.10 45.09

1.9

Ball Mill to a 7 Hegman Cargi 1 1 Water Reduci bl e Phenol i c Modi f i ed AI kyd 74-7478 Aqueous Ammonia 28% Premix the following, then add: sec-Butanol Intercar 6% Cobalt Intercar 6% Zi rconi urn Intercar 4% Calcium Acti v-8 Exkin No. 2 Deionized Water

Paint Properties: % Nonvolatile (By Weight): 27.21 (By Volume): 24.09 Pigment to Binder Ratio: 0 . 0 7 Pigment Volume Concentration: 4 . 1 8 Weight Per Gallon: 0 . 3 7 Theoretical VOC (Pounds/Gallon): 2 . 9 1 (Grams/Liter): 349 Water:Cosolvent Weight Ratio: 80.22:19.78 pH: 8 . 7 Viscosity Krebs-Stormer (KU): 70 Typical Cured Film Properties: Cure Schedule: 7 Days Air Dry Substrate: Cold Rolled Steel Gloss ( 6 0 / 2 0 ) : 87/75 Pencil Hardness: Pass 38 % Crosshatch Adhesion: 98 Impact ( i n . L b s . ) : Direct: 40 Reverse: < 5 Dry Time: Set to Touch (Hours): 3 / 4 5509 Zapon (Hours): >8 SOURCE: Cargill, Inc.: CARGILL Formulary: Formula P1843-125H

75

76

Water-Based Paint Formulations

B l a c k Enamel Material: Lbs. Water 100.0 Foamaster VL 2.0 C e l l o s i z e QP 4400 0.5 Methyl Carbit o 1 8.5 D i sperse-Ayd W22 4.4 A e r o s o l OT-75 2.3 A r o l on 820-W-49 105.6 AMP 95 1.9 Nalzin 2 50.0 Raven 1020 Beads 15.0 P e b b l e m i l l g r i n d t h e above t o a 7 Hegman. Letdown : A r o l on 820-W-49 572.0 Methyl Carbi t o 1 25.0 Water 20.3 R h e o l a t e 278 4.4 Ammonium H y d r o x i d e 1.9 Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 6 . 5 P i g m e n t / B i n d e r R a t i o : 0.20/1 .O P e r c e n t S o l i d s , Weight : 4 4 . 3 P e r c e n t S o l i d s , Volume: 39.0 V i s c o s i t y @ 25C, KU: 77 Pounds/Gallon: 9 . 1 4 pH: 8 . 5 - 9 . 0 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 88 Pounds/Gallon: 0 . 7

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2343-07

I n c . : Waterborne Handbook:

Gals. 12.00 0.25 0.04 1 .oo 0.50 0.25 12.00 0.25 1.52 1 .oo 65.00 3.00 2.44 0.50 0.25

Enamels

B l a c k Gloss Chromate Enamel M a t e r i a1 : K e l s o l 3918-B2G-70 Ammoni um Hydoxi de Raven 1255 S t r o n t i u m Chromate 51365 I g e p a l CTA-639 Water S t e e l b a l l m i l l t o a 7 Hegman g r i n d . Letdown : Kel s o l 3918-826-70 Ammoni um H y d r o x i d e Water Cobalt Hydrocure I 1 A c t iv-8 Butoxy Ethanol Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : P i g m e n t / B i n d e r R a t i o : .26/1 P e r c e n t S o l i d s , Weight: 26.2 P e r c e n t S o l i d s , Volume: 2 1 . 9 V i s c o s i t y @ 25C, KU: 35-45 pH: 8.2-8.5 Pounds/Gallon: 8 . 6 4 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 31 7 . 2 Pounds/Gallon: 2 . 6 4 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2403-19

Lbs. 123.60 4.30 20.60 25.75 1 .85 248.32

Gals. 14.49 0.58 1.41 0.83 0.21 29.81

128.96 7.00 283.25 5.29 1.26 13.80

15.12 0.94 34.00 0.70 0.16 1.84

10.48

I n c . : Waterborne Handbook:

77

78

Water -Based Paint Formulations

B l a c k G l o s s Enamel F l o w c o a t or D i p

Lbs.

Material : Water Ammoni um H y d r o x i de K e l s o l 3902-864-75 Premix and add t o above m i x t u r e : Cobalt Hydrocure I 1 Activ-8 Butoxy E t h a n o l

28.05 .93 13.36

4.69 2.33 4.90

.61 .29 .66

Premix d r i e r and s o l v e n t and add t o above m i x t u r e : 12% Manganese Cem-All 4.90 Butoxy E t h a n o l 5.83 Then add i n o r d e r : Cab-0-Si1 M5 S t r o n t i u m Chromate 31365 Raven 1020 F o a m k i l l FBF Sand m i l l t o 7 Hegman g r i n d . Letdown : Water Ammoni um H y d r o x i d e Kel s o l 3902-864-75 Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P i g m e n t / B i n d e r R a t i o : .16/1 P e r c e n t S o l i d s , Weight: 38.0 P e r c e n t S o l i d s , Volume: 32.6 Pounds/Gallon: 8.75 pH: 8.2-8.5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 264 Pounds/Gallon: 2.2 SOURCE: R e i c h h o l d Chemicals, Formul a t i on 1648-40

Percent:

Gals.

233.69 7.00 116.90

.66 .69

4.68 23.58 17.20 3.14

.26 .76 1.18 .44

182.43 6.26 257.16

21.90 .83 29.38

10.3

I n c . : Waterborne Handbook:

Enamels

B l a c k G l o s s Non-Chromate Enamel

Lbs.

M a t e r i a1 : Kel s o l 3919-826-70 Ammoni um H y d r o x i de C o b a l t Hydrocure I 1 A c t iv - 8 Butoxy Ethanol n-Butanol Heucophos ZPO A l c o p h o r 827 Raven 1255 Water S t e e l b a l l m i l l t o a 7 Hegman g r i n d .

169.11 9.64 5.79 0.96 22.91 10.33 56.55 6.99 9.76 252.23

Gals. 19.55 1.29 0.76 0.12 3.05 1.53 1.83 0.34 0.67 30.28

Letdown : Kel s o l 391 9-826-70 Ammoni um H y d r o x i de Water

106.14 1 .31 234.41

12.27 0.17 28.14

Anal y s i s: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 9 . 6 3 Pigment/Binder R a t i o : .33/1 P e r c e n t S o l i d s , W e i g h t : 30.3 P e r c e n t S o l i d s , Volume: 2 3 . 7 V i s c o s i t y @ 25C, #4 F o r d , S e c s . : 35-45 pH: 8 . 2 - 8 . 5 Pounds/Gallon: 8 . 8 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 350.0 Pounds/Gallon: 2 . 9 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2403-16

I n c . : Waterborne Handbook:

79

80

Water-Based Point Formulations

B l a c k H i s h G l o s s B r u s h i n g Enamel M a t e r i a1 : Water Triethylamine B u t y l Carbi t o 1 Kel s o l 3970-64-75 Raven 1020 Foamki 11 6390 S t e e l b a l l m i l l t o a 7 Hegman g r i n d . Letdown : Kel s o l 3970-G4-75 Ammoni um H y d r o x i d e Propasol P Premi x : Cobalt Hydrocure I 1 Activ-8 Water

Lbs. 86.0 7.0 12.0 98.0 24.0 0.5

269.0

Gals. 10.32 1.16 1.52 11 .oo 1.64 0.07

20.0

30.19 1 .13 2.72

6.0 1 .o 327.0

0.79 0.13 39.26

8.5

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 5 . 3 Pigment/Binder R a t i o : .09/1 P e r c e n t S o l i d s , Weight: 3 4 . 8 P e r c e n t S o l i d s , Volume: 3 1 . 0 V i s c o s i t y @ 25C, KU: 90-95 Pounds/Gallon: 8 . 6 0 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 326 Pounds/Gallon: 2.72 SOURCE: R e i c h h o l d Chemicals, Inc.: Waterborne Handbook: F o r m u l a t i o n 2025-73-1A

Enamels

B l a c k Hiqh G l o s s Enamel

Lbs. Material : 86.6 A r o l on 850-W-45 83.3 Water 8.5 Methyl Carbi t o 1 4.4 D i s p e r s e Ayd W22 2.3 A e r o s o l OT-75 1.8 Dapro 1181 15.0 Raven 1020 Premix t h e above, t h e n p e b b l e m i l l g r i n d t o a 7 Hegman 529.2 A r o l on 850-W-45 39.4 Butoxy Ethanol 29.7 Methyl Carbi t o 1 4.2 KP 140 1.9 S u r f y n o l 104 BC 2.1 15% S o l u t i o n FC430 4.3 Ucar SCT 200 43.7 Water 1.9 Ammonium H y d r o x i d e Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : P i g m e n t / B i n d e r R a t i o : 0.05/1 . O O P e r c e n t S o l i d s , W e i g h t : 36.5 P e r c e n t S o l i d s , Volume: 33.0 V i s c o s i t y @ 25C, #4 F o r d , S e c s . : 94 G l o s s ( 6 0 ) : 94 Pounds/Gallon: 8 . 6 pH: 8 . 0 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 233 Pounds/Gal 1on : 1 .94 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2210-1

3.0

I n c . : Waterborne Handbook:

Gals. 10.00 10.00 1 .oo 0.50 0.25 0.25 1 .oo 61.25 5.25 3.50 0.50 0.25 0.25 0.50 5.25 0.25

81

82

Water-Based Paint Formulations

B l u e H i g h G l o s s Enamel M a t e r i a1 : K e l s o l 3961 -826-75 Ammoni urn H y d r o x i de n-Butanol Butoxy Ethanol Water Heucophthal B l u e RF BT 698D Raven 1020 Y.I.Q. 2288D S t r o n t i u m Chromate 5-1365 T i -Pure R-902 P e b b l e m i l l t o 6-7 Hegman g r ii n d . Letdown : K e l s o l 3961-82G-75 sec-Butanol n-Butanol Ammoni um H y d r o x i de Water Premi x : A c t iv-8 Cobalt Hydrocure I 1 Butoxy Ethanol M e t h y l E t h y l Ketone

Lbs. 43.95 2.91 3.59 3.89 71.75 4.87 2.91 2.91 17.94 35.87

Gals. 5.13 0.38 0.53 0.52 8.61 0.36 0.19 0.08 0.56 1.04

242.15 5.84 7.71 7.71 385.65

28.29 0.87 1.14 1.02 46.30

1.17 6.62 0.98 26.91

0.14 0.86 0.13 4.01

N o t e : Water may be used t o r e p l a c e t h e MEK f o r a l o w e r CARB value. Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 8 . 1 8 Pigment/Binder R a t i o : .3/1 P e r c e n t S o l i d s , Weight: 31.87 P e r c e n t S o l i d s , Volume: 27.25 V i s c o s i t y @ 25C, KU: 75-80 Pounds/Gallon: 8 . 7 4 pH: 8.2-8.5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 351 Pounds/Gallon: 2.93 SOURCE: R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i o n 2116-51-2

Enamels

B l a c k Low G l o s s Enamel M a t e r i a1 : K e l s o l 3963-826-70 C o b a l t Hydrocure I 1 Activ-8 n-Butanol Butoxy E t h a n o l Propoxy P r o p a n o l Ammoni um H y d r o x i de Raven 1255 Beads Novaci t e L207A Atomi t e S y l o i d 83 P a t c o t e 519 Water S t e e l b a l l m i l l t o 7 Hegman g r i n d Letdown : K e l sol 3963-B2G-70 Ammoni um H y d r o x i de n B u t ano 1 P a t c o t e 519 Water N o t e : Premix t h e c o b a l t d r i e r , adding t o t h e r e s i n .

-

Activ-8,

Lbs.

Gals. 16.53

141.33 4.16 0.72 1.15 1.20 1.18 6.95 11.52 34.70 34.88 8.18 1.17 363.10

57.97 2.91 1.69 0.76 214.25 and n - b u t a n o l

0.55 0.09 0.17 0.16 0.16 0.93 0.79 1.57 1.55 0.49 0.17 43.59

6.78 0.39 0.25 0.11 25.72 before

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 22.78 P i g m e n t / B i n d e r R a t i o : 0.64/1 P e r c e n t S o l i d s , W e i g h t : 26.42 P e r c e n t S o l i d s , Volume: 19.85 V i s c o s i t y @ 25C, #4 F o r d , Secs.: 35-45 Pounds/Gallon: 8 . 8 8 pH: 8 . 3 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 271.2 Pounds/Gal 1on: 2 . 2 6

SOURCE:

R e i c h h o l d Chemicals, Formul a t i on 2344-75

I n c . : Waterborne Handbook:

83

84

Water-Bused Paint Formulations

B l u e A c r y l i c Emulsion Enamel I n q r e d ie n t s : Coroc A-2678-M 2-butoxyethanol S u r f y n o l 104BC S u r f y n o l DF-75 Water T i P u r e R-900

Pounds 22.22 7.48 7.81 1.28 7.48 99.68

Gallons 2.52 1 .oo 1.04 0.15 0.90 2.90

Pre-mix f i r s t f o u r i n g r e d i e n t s , t h e n add w a t e r w i t h a g i t a t i o n . Add pigment s l o w l y w i t h a g i t a t i o n . Cowles t o a #7 Hegman w i t h a h i g h speed d i s p e r s a t o r . A d j u s t g r i n d v i s c o s i t y w i t h w a t e r f r o m below i f n e c e s s a r y . L e t down w i t h : 66.64 Chempol 20-4301 586.40 4.13 2-butoxyethanol 31 . O O 2.50 B u t y l Carbi t o 1 19.82 0.79 Dibutyl Phthalate 6.85 0.24 Nuocure CK-10 1.95 3.51 Michem 39235 29.27 2.23 UCD 4820Q 19.94 11.45 Water ( h o l d t o a d j u s t v i s c o s i t y ) 95.38 Pre-mix c o - s o l v e n t s , p l a s t i c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r s e e d i n g . Add t h e wax d i s p e r s i o n t o t h e " l e t down" w i t h a g i t a t i o n . A f t e r m i x i n g w e l l , add t h e g r i n d t o t h e " l e t down" w i t h good a g i t a t i o n . F i n a l l y , add t h e b l u e t i n t p a s t e s l o w l y t o t h e b l e n d e d p a i n t and mix u n t i l w e l l d i s p e r s e d . A l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7.6, as t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . P r o p e r t ie s : T o t a l s o l i d s , % by w e i g h t : 37.50% T o t a l s o l i d s , % by volume: 28.85% Wei g h t / g a l 1on : 9.37 1b s / g a l PVC: 11.10 P i g m e n t / b i n d e r r a t i o : 0.42 VOC: 1.97 l b s . / g a l V i s c o s i t y : 23" #2 Zahn pH: 7 . 5 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y Set t o touch: 17' Dust f r e e : 20' Tack f r e e : 7 5 ' - 9 0 ' Dry through: 75'-90'

.

.

.

SOURCE:

Freeman Polymers D i v i s i o n : Chempol 20-4301-E F o r m u l a t i o n

Enamels

B l u e Enamel M a t e r i a1 s 255 R e s i n WB-408 (80% NVM) 18 Triethylamine 36 A m i no c r o s s l in k e r , Cymel ( 1 ) 2 Manganese n a p h t h e n a t e , 6% 443 Water 40 Phthalocyanine b l u e ( 2 ) 8 Titanium dioxide (3) Properties: Pigment/binder r a t i o : 0.2/1 . O M e l a m i n e / a l k y d r a t i o : 15/85 N o n - v o l a t i l e (NVM), w t %: 39 V i s c o s i t y , #4 F o r d cup, s e c : 35-45 pH: 7 . 5 - 8 . 0 S t a b i l i t y , 15 days a t 49C ( 4 ) : pass ( 1 ) Cymel 301 ( 2 ) M o n a s t r a l B l u e BT ( 3 ) T i - P u r e R-900 ( 4 ) Less t h a n 5 seconds v i s c o s i t y change o r 0 . 5 pH change f o r pass The pigmented enamel i s compounded u s i n g a p e b b l e m i l l . The r e s i n, ami ne s o l u b i 1 iz e r , ami no c r o s s l in k e r , pigment , and 80% o f t h e w a t e r a r e added t o t h e m i l l . The enamel i s d i s p e r s e d t o a minimum o f #7 Hegman g r i n d . The enamel i s t h e n a d j u s t e d t o t h e c o r r e c t pH and v i s c o s i t y u s i n g a d d i t i o n a l amine and w a t e r r e s p e c t iv e l y Performance p r o p e r t i e s o f b l u e e n a m e l ( 1 ) : S u b s t r a t e : B-37(3): P e n c i l hardness: H Sward h a r d n e s s : 46 C r o s s h a t c h a d h e s i o n : 5B 1 / 8 - i n c h c o n i c a l bend, % p a s s : 100 Impact r e s i s t a n c e , i n - l b : d i r e c t : 80 r e v e r s e : 80 60 g l o s s , %: 9Ot Mar r e s i s t a n c e : good S a l t s p r a y r e s i s t a n c e , 250 h r : pass S u b s t r a t e : CRS(4): P e n c i l hardness: H Sward hardness: 48 Crosshatch adhesion: 5B 1 / 8 - i n c h c o n i c a l bend, % p a s s : 100 Impact r e s i s t a n c e , i n - l b : d i r e c t : 80 r e v e r s e : 80 60 g l o s s , %: 90+ Mar r e s i s t a n c e : good ( 1 ) C u r e c y c l e 20 m i n u t e s a t 177C ( 3 ) B o n d e r i t e 37 t r e a t e d c o l d r o l l e d s t e e l ( 4 ) L e s s t h a n 5 seconds v i s c o s i t y change o r 0 . 5 pH f o r pass SOURCE: Amoco Chemical Co.: Water-Borne Bake A l k y d s Based on Amoco TMA and I P A : T a b l e 5 & 7 Formula

.

85

86

Water-Based Paint Formulations

B l u e H i g h G l o s s Enamel M a t e r i a1 : Water Ammoni um H y d r o x i d e K e l s o l 3970-64-75 Premix : A c t iv-8 C o b a l t Hydrocure I 1 Manganese Hydrocure Butoxy E t h a n o l He1 iogen B1 ue L6975F T i t a n o x 2160 S t e e l b a l l m i l l t o 6+ Hegman g r i n d . Letdown : Water Butoxy E t h a n o l Ammonium H y d r o x i d e K e l s o l 3970-G4-75

Lbs.

Gals 30.98 1.72 14.49

1.29 2.58 5.16 12.91 40.02 40.02

0.17 0.34 0.68 1.72 3.02 1.12

154.92 6.46 6.46 225.93

18.59 0.86 0.86 25.36

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 1 2 . 8 Pigment/Binder R a t i o : . 3 / 1 P e r c e n t S o l i d s , Weight: 3 8 . 7 P e r c e n t S o l i d s , Volume: 32.3 V i s c o s i t y @ 25C, #4 Ford, Secs.: 38-42 Pounds/Gallon: 8 . 9 7 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i ng w a t e r ) : G r a m s / L i t e r : 278 Pounds/Gallon: 2.32

SOURCE:

.

258.20 12.91 129.10

R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i o n 2079-42-2

Enamels

B l u e Semi-Gloss

Enamel

.

Lbs. M a t e r i a1 : 103.70 Kel s o l 3980-G4-75 2.07 S u r f y n o l 104E 2.07 Defoamer L-475 10.37 E t h y l e n e G l y c o l Monobutyl E t h e r 5.19 D i m e t h y l e t h a n o l A m i ne (DMEA) 82.96 Water 207.41 T i -Pure R-902 2.07 A-4434 Tacoma B l u e 62.22 T a l c 399 Pebble m i l l o r sand m i l l t o a 6 1/2 Hegman g r i n d . Letdown : Kel s o l 3980-G4-75 Cyme1 327 E t h y l e n e G l y c o l Monobutyl E t h e r DMEA Propoxy Propanol Water

Inc.:

Gals 11.52 0.25 0.28 1.38 0.70 9.96 6.07 0.17 2.77

17.26 7.35 1.38 1.40 2.82 36.67

155.56 72.07 10.37 10.37 20.74 305.41

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 25.28 P i g m e n t / B i n d e r R a t i o : 1.04/1 P e r c e n t S o l i d s , Weight: 5 0 . 5 5 P e r c e n t S o l i d s , Volume: 35.62 V i s c o s i t y @ 25C, KU: 70-75 Pounds/Gal 1on : 10.53 pH: 8 . 2 - 8 . 6 Resin/Melamine R a t i o : 72/75 % R e d u c t i o n t o 30 Secs., #2 Zahn, w i t h w a t e r : VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 294 Pounds/Gallon: 2.45 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2185-66

87

15

Waterborne Handbook:

88

Water-Based Paint Formulations

C l e a r Enamel M a t e r i a1 : P a r t A: Epi-Rez WD-510 Epoxy R e s i n 2-Propoxyethanol ( 2 ) Water

-__ Pounds

Gal l o n s

79.0 7.6 90.1

8.18

10.82

P a r t B: CMD 9790 A c r y l i c R e s i n 2-Propoxyethanol ( 2 ) M i x w e l l u n d e r l o w a g i t a t i o n and add: Water

653.0 22.7

75.50 3.00

12.5

1 .50

Composite B l e n d : Viscosity Part A 12 seconds #4 F o r d Cup Part B 114 KU P a r t s A and B 94 K U

176.7 688.2

20.00 80.00

( 2 ) E k t a s o l v e EP T y p i c a l C o a t i n g P r o p e r t i es : T o t a l Weight S o l i d s , p e r c e n t : 40.8 T o t a l Volume S o l i d s , p e r c e n t : 38.0 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gallon: 2.33 G r a m s / L i t e r : 280 Resin Composition ( S o l i d s ) : A c r y l i c R e s i n : 77.6% Epoxy R e s i n : 22.4%

SOURCE: S h e l l Chemical Co. : 24-258 C l e a r Enamel

1 .oo

Enamels

89

C l e a r Enamel ( f o r u s e w i t h p r e d i s p e r s e d c o l o r a n t s ) Pounds Materials: Grind Portion: 240.0 K e l s o l 3905 1.9 Aquacat 3.8 Magnacat 0.9 P a t c o t e 519 0.9 P a t c o t e 577 5.1 28% Ammonia 321.7 Water M i x w e l l ( % n e u t r a l i z a t i o n = 5 8 % , pH 5 . 8 t o 6 . 0 ) Add i n o r d e r , w i t h a g i t a t i o n : 186.7 Rhoplex WL-71 32.2 Water 20.0 B u t y l Carbit o 1 14% Ammonia ( t o pH 8 . 4 ) Water 21.4 N o t e : Reduce t o s p r a y v i s c o s i t y w i t h 87/13 w a t e r / B u t y l

----

Gallons 27.93 0.24 0.49 0.12 0.12 0.61 38.76

21.71 3.86 2.52

----

2.58 Cellosolve

Formulation Constants: Pounds/gallon: 8.4 N o n - v o l a t i l e s ( W t . ) : 31.3% ( V o l . ) : 28.2% Rhoplex WL-71/Kelsol 3905: 30/70 pH: 8 . 4 V i s c o s i t y : 300-500 c p s . VOC: 1 . 9 7 l b s . / g a l . Note: C o l o r s a r e o b t a i n e d b y a d d i n g p i g m e n t d i s p e r s i o n s ( C o l a n y l s e r i e s ) t o t h i s c l e a r enamel w i t h good m i x i n g . Code No. Description P i gment/Bi n d e r Lb./100 G a l . 16-2010 Green 8G 13/87 70 18-1004 B l a c k PR-A 5/95 40 11-1 109 Y e l l o w OT 13/87 70

SOURCE:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-71: F o r m u l a t i o n WL-71-5

90

Water-Based Paint Formulations

G l o s s W h i t e Enamel M a t e r i a1 : Part A: Epi-Rez WD-510 Epoxy R e s i n 2-Propoxyethanol ( 2 ) Water

Pounds

Gallons

68.0 22.2 83.3

7.07 2.93 10.00

P a r t B: Water 73.3 8.80 Potassium T r i p o l y p h o s p h a t e 2.0 0.12 M i x w e l l a t l o w speed, t h e n add : Defoamer ( 4 ) 2.0 0.26 Surfactant (5) 0.23 2.0 Water D i s p e r s i b l e L e c i t h i n 6 ) 0.52 4.5 R u t i l e Titanium Dioxide (7) 250.0 7.33 H i g h speed d i s p e r s e f o r 5-1 m i n u t e s a t 2000 rom. t h e n add: CMD 9790 A c r v l i c R e s i n 108'. 0. 12.50 H i g h speed d i s p e r s e t o a t e x t u r e o f 9-10 P.S.C., t h e n add: Defoamer 2.0 0.26 2-Propoxyethanol 22.7 3.00 CMD 9790 A c r y l i c R e s i n 404.0 46.98 Composite B l e n d : Part A Part B P a r t s A and B

V i scosi t y 12 seconds #4 F o r d Cup 120 KU 90 KU

173.5 870.5

20.00 80.00

2 ) E k t a s o l v e EP 4 ) C o l l o i d 640 5 ) T r i t o n X-100 6) A l c o l e c 439-C 7 ) T i t a n o x 2020 or Tronox CR800 Typical Coating Properties: T o t a l Weight S o l i d s , p e r c e n t : 5 1 . 0 T o t a l Volume S o l i d s , p e r c e n t : 3 8 . 0 PVC, p e r c e n t : 1 9 . 3 Resin Composition: Epoxy R e s i n , p e r c e n t : 24.0 A c r y l i c R e s i n , p e r c e n t : 76.0 R e d u c t i o n t o Spray V i s c o s i t y : b y Volume: P a r t s A and B Water

46 p a r t s 1 part

SOURCE: S h e l l Chemical Co. : 24-309 Gloss W h i t e Enamel U s i n g CMD 9790 A c r y l i c R e s i n

Enamels

G l o s s W h i t e Enamel _(MaximumA c i d R e s i s t a n c e 1 M a t e r i a1 : P a r t A: Epi -Rez WJ-5522 Epoxy R e s i n H i g h F l a s h A r o m a t i c Hydrocarbon ( 2 ) 2-Propoxyethanol ( 3 ) Water

Pounds

Gal l o n s

501.2 22.3 22.7 38.9

56.00 3.00 3.00 4.67

P a r t 8: CMD 560-8290 C u r i n g Agent 81 . o Defoamer ( 4 ) 4.0 R u t i l e Titanium Dioxide (5) 250.0 Water 33.3 H i g h speed d i s p e r s e t o a t e x t u r e o f 10 P . S . C . Water 96.1 Glacial Acetic Acid 2.9

9.17 0.56 7.74 4.00 11.53 0.33

2 ) H i - S o l 15 o r Enco A r o m a t i c 150 3) E k t a s o l v e EP 4) P a t c o t e 847 5 ) R-960 H i g h G l o s s , o r g a n i c t r e a t m e n t Composite B1end : Part A Part B

Viscosity 97 K . U . 75 K . U .

R e d u c t i o n f o r C o n v e n t i o n a l Spray: P a r t s A and 0 Water

585.1 467.3 by volume 25 p a r t s 1 part

Typical Coating Properties: T o t a l Weight S o l i d s , p e r c e n t : 54.6 T o t a l Volume S o l i d s , p e r c e n t : 41.1 PVC, p e r c e n t : 18.8 V o l a t i l e O r g a n i c Compounds (V.O.C.): Pounds/Gallon: 2.07 G r a m s / L i t e r : 249 I n d u c t ion T i me, m i n u t e s : 30 R e s i n C o m p o s i t i o n (based on s o l i d s ) : Epoxy Resin, p e r c e n t C u r i n g Agent, p e r c e n t SOURCE: S h e l l Chemical Co.:

85.0 15.0

24-296 G l o s s W h i t e Enamel

66.67 33.33

91

92

Water-Based Paint Formulations

C l e a r Enamel maximum A c i d R e s i s t a n c e ) M a t e r i a1 : Part A: E p i -Rez WJ-5522 Epoxy Resi n H i g h F l a s h A r o m a t i c Hydrocarbon ( 2 ) 2-Propoxyethanol ( 3 ) Water

-__ Pounds

Gal 1ons

540.8 32.5 33.2 48.6

60.42 4.37 4.37 5.84

87.6 4.0 121 . o

9.92 0.56 14.52

655.1 212.6

75.00 25.00

P a r t B: CMD 560-8290

C u r i n g Agent

Defoamer ( 4 ) Water Composite B l e n d : Part A Part 0 Parts A & 0

Viscosity 93 K.U. 61 K . U . 75 K . U .

15 o r Enco A r o m a t i c 150 3 ) E k t a s o l v e EP 4) P a t c o t e 847 Defoamer

2 ) Hi-Sol

Typical Properties: T o t a l Weight S o l i d s , p e r c e n t : 40.3 T o t a l Volume S o l i d s , p e r c e n t : 3 6 . 1 Vol a t i 1e O r g a n i c Compounds : Pounds/Gallon: 2 . 5 7 G r a m s / L i t e r : 308 I n d u c t i o n Time, m i n u t e s : 30 Resi n Composi t i on (based on s o l i d s ) : Epoxy Resi n, p e r c e n t : C u r i n g Agent, p e r c e n t

85.0 15.0

R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y volume) None R e q u i r e d SOURCE: S h e l l Chemical C o . :

24-294 C l e a r Enamel

Enamels

C l e a r Enamel (Maximum S o l v e n t and A b r a s i o n R e s i s t a n c e 1 M a t e r i a1 : Part A: €pi-Rez WJ-5522 Epoxy R e s i n H i g h F l a s h A r o m a t i c Hydrocarbon ( 2 ) 2-Propoxyethanol ( 3 ) Water P a r t B: CMD 560-0290 C u r i n g Agent Defoamer ( 4 ) Water

Pounds

Gal 1ons

477.2 32.5 33.2 107.9

53.31 4.37 4.37 12.95

145.8 4.0 66.1

16.51 0.56 7.93

650.8 215.9

75.00 25.00

2 ) H i - S o l 15 o r Enco A r o m a t i c 150 3 ) E k t a s o l v e EP 4) P a t c o t e 847 Composite B l e n d : Part A Part B Typical Coating Properties: V i s c o s i t y , P a r t A : 68 KU P a r t B: 64 KU P a r t A + B: 75 KU T o t a l Weight S o l i d s , p e r c e n t : 40.4 T o t a l Volume S o l i d s , p e r c e n t : 36.0 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gallon: 2.84 G r a m s / L i t e r : 340 I n d u c t i o n Time, m i n u t e s : 30 R e s i n C o m p o s i t i o n (based on s o l i d s ) : Epoxy R e s i n , p e r c e n t : 7 5 . 0 C u r i ng Agent, p e r c e n t : 25.0 R e d u c t i o n f o r C o n v e n t i o n a l Spray (by v o l u m e ) : None r e q u i r e d

SOURCE:

S h e l l Chemical Co.:

24-295 C l e a r Enamel

93

94

Water-Based Paint Formulations

Economical F l a t B l a c k A i r D r y Enamel Pounds

Gal l o n s

111.3 134.8 7.7 5.7 6.7 2.8 1.1 12.0 226.4

12.87 6.27 0.52 0.31 1.11 0.40 0.12 1.79 27.18

1.5 0.9 0.4 0.2

0.22 0.12 0.05 0.03

E x k i n No. 2 Byk-080 sec-Butanol

9.3 2.6 1.1 52.3

1.54 0.34 0.12 7.77

A c r y s o l ASE-60 D e i o n i zed Water

31.2 31 .2

3.42 3.75

Dei o n i zed Water

267.0

32.07

C a r g i l l Water R e d u c i b l e S t y r e n a t e d A l k y d Copolymer 74-7425 ASP 170 Aluminum S i l i c a t e Special Black 4 A e r o s i l R972 Triethylamine M-P-A

1075

Byk-080 sec-Butanol Dei o n i zed Water Sand M i l l t o a 5 Hegman Premix t h e f o l l o w i n g , t h e n add: sec-Butanol 5% C o b a l t Hydro Cure Manganese Hydro Cure I 1 A c t iv-8 T r i e t h y l ami ne

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 26.39 (By Volume): 16.76 Pigment t o B i n d e r R a t i o : 1.63 Pigment Volume C o n c e n t r a t i o n : 42 46 Weight Per G a l l o n : 9.07 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3.50 (Grams/Li t e r ) : 4 9 . Water:Cosolvent Weight R a t i o : 82.00:18.00 ~

pH: 8.0-8.5

V i s c o s i t y #4 F o r d Cup (Seconds): Anti-Sag Resistance: E x c e l l e n t T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: I 7 Days A i r D r y Substrate: Cold Rolled Steel G l o s s (60/20): 5/0 P e n c i l Hardness: Pass 4 6 % C r o s s h a t c h Adhesion: 50 Impact ( I n . L b s . ) : D i r e c t : 30 Reverse: <5

SOURCE: C a r g i l l ,

Inc.:

57

C A R G I L L F o r m u l a r y : Formula P 1 8 8 7 - 5 8 A

Enamels

Gloss B l a c k Enamel Sand M i l l ( 3 0 m i n u t e s ) : Cyme1 303 Tamol 731 (25%) Butyl Cellosolve Isopropanol Water DMAE (20% i n w a t e r ) Raven 1035 Letdown : Sand m i l l g r i n d A c r y s o l WS-68 (38%) PTSA* (10%) L-5310 (30% i n B u t y l C e l l o s o l v e ) n-Butanol

P a r t s by Weiqht 135.6 1.2 21 . o 21 . o 84.0 1.5 35.7 150.3 715.5 6.8 2.2 5.2

Enamel C o n s t a n t s : T o t a l s o l i d s , %: 40.7 P i g m e n t / b i n d e r r a t i o : 5/95 A c r y l i c / m e l a m i n e r a t i o : 80/20 % C a t a l y s t (PTSA) on b i n d e r s o l i d s : 0 . 2 % L-5310 on b i n d e r s o l i d s : 0 . 2 Water/organi c r a t i 0: By volume: 8 9 . 8 / 1 0 . 2 By w e i g h t : 9 1 . 1 / 8 . 9 pn: 7 . 6 V i s c o s i t y , s e c . (No. 4 F o r d Cup): 23 V o l a t i l e O r g a n i c Compounds (VOC): 130 g m s . / l

*

1 0 PTSA/10 DMAE/80 Water

SOURCE:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYSOL WS-68: Formul a t i on WS-68-3

95

96

Water-Based Paint Formulations

G l o s s B l a c k Enamel Materials: Grind Portion: K e l s o l 3960 Aquacat Magnacat 28% Ammonia Water P a t c o t e 519 P a t c o t e 577 Raven 420 S t r o n t i u m Chromate

Pounds

Gal 1ons

89.2 1.9 3.7 2.2 142.5 0.9 0.9 10.0 10.0

10.36 0.23 0.48 0.26 17.18 0.12 0.10 0.68 0.32

149.0 3.7 176.4

17.30 0.44 21.25

185.0 31.8 21.2 21.2

21.52 3.83 2.67 2.56

S t e e l b a l l m i l l t o 7 t o 7 1/2 N . S . K e l s o l 3960 28% Ammonia Water

1 ) Premix

1

Add i n o r d e r w i t h good a g i t a t i o n : Rhopl ex WL-71 Water B u t y l Carbi t o 1 Water 14% Ammonia ( t o pH 7 . 3 t o 7 . 5 )

----

N o t e : Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l

-----

Cellosolve

F o r m u l a t i o n Constants: Pounds/gallon: 8.56 N o n - v o l a t i l e s ( W t . ) : 33.1% ( V o l . ) : 29.1% P i g m e n t / B i n d e r R a t i o : 8/92 pvc: 3.5% Rhopl ex WL-71 /Kel s o l 3960: 30/70 pH: 7 . 3 t o 7 . 5 V i s c o s i t y : 400-600 c p s . VOC: 1 . 8 7 l b s . / g a l . SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-71: F o r m u l a t i o n WL-71-9

Enamels

G l o s s B l a c k Enamel (No Chromate) Materials: Grind Portion: K e l s o l 3960 Aq uaca t Magnacat 28% Ammonia Water P a t c o t e 519 P a t c o t e 577 Raven 420

Pounds

Gal l o n s

89.2 1.9 3.7 2.2 142.5 0.9 0.9 13.3

10.36 0.23 0.48 0.26 17.18 0.12 0.10 0.91

149.0 3.7 176.4

17.30 0.44 21.25

185.0 31.8 21.2

21.52 3.83 2.67

S t e e l b a l l m i l l t o 7 t o 7 1/2 N . S . K e l s o l 3960 28% Ammonia Water

1 ) Premix )

Add i n o r d e r w i t h good a g i t a t i o n : Rhoplex WL-71 Water B u t y l Carbi t o 1 14% Ammonia ( t o pH 7 . 3 t o 7 . 5 )

-----

-----

Note: Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l C e l l o s o l v e F o r m u l a t i o n Constants: P o u n d s / g a l l o n : 8.5 N o n - v o l a t i l e s ( W t . ) : 33.4% ( V o l . ) : 30.1% P i gment/Bi nder : 5/95 PVC: 3 . 2 % Rhopl ex WL-71 / K e l s o l 3960: 30/70 pn: 7 . 3 t o 7 . 5 V i s c o s i t y : 200-600 c p s . Grind: 7 t o 7 1/2 N . S . VOC: 1 . 8 7 l b s . / g a l .

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-71: F o r m u l a t i on WL-71-10

97

98

Water-Based Paint Formulations

Gloss Black Forced-Dry Enamel Materials: Grind Portion: Kelsol 3905 Aquaca t Magnacat 28% Ammoni a Water Patcote 519 Patcote 577 Raven 420 Steel ball mill to 7 1/2 N.S. Kelsol 3905 28% Ammoni a

1

Water

1

)

Premix

Pounds

Gallons

89.2 1.9 3.7 2.2 142.5 0.9 0.9 13.3

10.36 0.23 0.48 0.26 17.18 0.12 0.10 0.91

149.0 3.7 176.4

17.30 0.44 21 . 2 5

185.0 31 . 8 21.2

21.52 3.83 2.67

21.2

2.56

( % Neutralization = 70%, pH 6 . 0 to 6 . 3 )

Add in order with good agitation: Rhopl ex WL-71 Water Butyl Carbi to1 14% Ammonia (to pH 7 . 3 to 7 . 5 ) Water

----

-----

Note: Reduce for spray with 87/13 water/Butyl Cellolsolve Formulation Constants: Pounds/gallon: 8 . 5 Non-volatiles (Wt.): 32.3% (Vol.): 29.1% Pigment/Binder Ratio: 5/95 PVC: 3 . 2 Rhopl ex WL-71 /Kel sol 3905: 30/70 pn: 7 . 3 to 7 . 5 Viscosity: 200-400 cps. VOC: 1.87 lbs./gal.

Source: Rohm and Haas Co.: Industrial Coatings: RHOPLEX WL-71: Formu 1 at i on WL-7 1-2

Enamels

99

Gloss Green Enamel M a t e r ia1 s : Grind Portion: Chempol 10-0091 Aq uac at Magnacat 28% Ammonia Water P a t c o t e 519 P a t c o t e 577 Chrome O x i d e X-1134 I m p e r i a1 B r a z i 1 Ye1 l o w X-286C Butyl Cellosolve B u t y l Carbi t o 1

Pounds

Gal 1ons

88.2 1 .o 3.7 1.7 142.3 0.9 0.9 38.3 6.3 5.0 5.0

10.02 0.23 0.48 0.20 17.17 0.12 0.12 0.87 0.53 0.67 0.63

147.4 3.1 174.5

17.14 0.37 21.02

183.1 31.5 16.0

21 .29 3.79 2.01

21 . a

2.53

S t e e l b a l l m i l l t o 7 1 / 2 N.S. Chempol 10-0091 28% Ammonia Water

) ) Premix

1

( N e u t r a l i z a t i o n = 9 3 % , pH 6 . 1 t o 6 . 4 ) Add i n o r d e r w i t h good a g i t a t i o n : Rhoplex WL-71 Water B u t y l Carbi t o 1 14% Ammonia ( t o pH 7 . 3 t o 7 . 5 ) Water

-----

N o t e : Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l

-----

Cellosolve.

Formulation Constants: Pounds/gallon: 8.68 N o n - v o l a t i l e s ( W t . ) : 34.5% ( V o l . ) : 28.0% P i g m e n t / B i n d e r R a t i o : 15/85 p v c : 4.8% Rhopl ex WL-?l/Chempol 10-0091 : 30/70 N e u t r a l i z a t i o n ( f i n a l based on Chempol 10-0091 s o l i d s ) : pH: 7 . 3 t o 7 . 5 V i s c o s i t y : 200-400 c p s . VOC: 2 . 1 6 l b s . / g a l . SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : Formul a t ion WL-71-8

170%

RHOPLEX WL-71:

100

Water-Based Paint Formulations

Gloss Maintenance Enamel--Deep

Base

A g l o s s maintenance enamel w i t h good c o m p a t i b i l i t y w i t h H u l s

America 896 C o l o r System. Insredients: Pigment G r i nd: Water Methyl Carbi t o 1 Solvent B u t y l C a r b i t o l Solvent Dispersant ( 1 ) P r e s e r v a t i v e (2) Nonionic Surfactant (3) Antifoam ( 4 ) Urethane A s s o c i a t i v e T h i c k e n e r ( 5 ) Titanium Dioxide (6)

L e t Down: Water Ucar T h i c k e n e r SCT-275 Ucar F i l m e r IBT Antifoam ( 3 ) Mix: Sodium N i t r i t e Water Ucar L a t e x 430 (43.0%)

Pounds

Gallons

25.0 34.0 23.8 4.4 1.2 4.7 2.1 12.9 125.0

3.00 4.00 3.00 0.50 0.13 0.50 0.25 1.50 3.65

109.6 21.5 31.7 2.1

13.16 2.50 4.00 0.25

1.o 4.2 548.1

0.06 0.50 63.00

Suppl ie r s : ( 1 ) D i s p e r s a n t - "Tamol" 165 o r e q u i v a l e n t ( 2 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 3 ) N o n i o n i c S u r f a c t a n t - " B o r c h i g e n " DFN o r e q u i v a l e n t ( 4 ) A n t i f o a m - "Foamex" 1488 o r e q u i v a l e n t ( 5 ) Urethane A s s o c i a t i v e T h i c k e n e r - " A c r y s o l " RM-1020 o r e q u i Val e n t ( 6 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 12.3 T o t a l S o l i d s , %: b y Volume: 29.5 b y Weight: 39.5 V i s c o s i t y ( e q u i 1 ib r a t e d ) : Stormer, KU: 89 I C I , Poise: 1.4 pH, i n i t i a l : 9 . 2 Weight p e r G a l l o n , l b : 9.51 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 w k s a t 120F (49C): Pass Foam C o n t r o l : Good VOC, g / l : 270.7 F i 1m P r o p e r t ies : C o n t r a s t R a t i o 0.003 i n : 0.942 R e f l e c t a n c e , %: 89.3

SOURCE:

Ucar Emulsions Systems: UCAR L a t e x 430: S u g g e s t i o n M-2205

Formulation

Enamels

101

Gloss W h i t e Enamel B a l l M i l l Grind; R u t i l e t i t a n i u m d i o x i d e (RCL-9) A c r y s o l WS-68 (38%) water B u t y l Cel l o s o l v e n-Butanol DMAE

P a r t s by Weiqht 480.0 126.3 149.4 21.4 20.0 2.9

Letdown : Ball m i l l grind A c r y s o l WS-68 (38%) Water n-Butanol L-5310 (30% i n B u t y l C e l l o s o l v e ) DMAE (10% i n w a t e r ) * Cyme1 303 PTSA ( l o % ) * *

326.4 567.0 48.2 6.9

1.9 5.1 58.7 5.8

Enamel C o n s t a n t s : T o t a l s o l i d s , %: 4 8 . 0 P i g m e n t / B i n d e r r a t i o : 40/60 A c r y l ic/Mel ami ne r a t i 0 : 80/20 % C a t a l y s t (PTSA) on b i n d e r s o l i d s : 0 . 2 W a t e r / o r g a n i c r a t i o , on volume: 91/9 pH: 7 . 7 V i s c o s i t y , s e c . ( N o . 4 F o r d Cup): 23 V o l a t i l e O r g a n i c Compounds (VOC): 124 g m s . / l .

* **

Add s l o w l y w i t h good a g i t a t i o n t o a c h i e v e d e s i r e d v i s c o s i t y 10 PTSA/10 DMAE/80 Water

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYSOL WS-68: F o r m u l a t i o n WS-68-1

102

Water-Based Paint Formulations

Gloss White Enamel ~

Sand MI1 1 L30 minutes) :Cyme1 303 Tamol 731 (25%) DMAE (20% in water) Butyl Cell os01 ve Isopropanol Water Rutile titanium dioxide (RCL-9) _____._.

___ Parts by Weiaht.

Letdown : Sand mill grind Acrysol WS-68 (38%) Water DMAE (20% in water) L-5310 (30% in Butyl Cellosolve) PTSA (lo%)* n-Butanol

63.0 4.2

5.0 10.4 5.6 101.8 210.0 373.0 618.4 4.0 10.8 2.0 5.8 6.0

Enamel Constants: Total solids, %: 48.0 Pigment/binder ratio: 40/60 Acrylic/melamine ratio: 80/20 % Catalyst (PTSA) on binder solids: 0.2 % L-5310 on binder solids: 0.2 Water/organic ratio: By volume: 91.1/8.9 By weight: 92.2/7.8 pH: 7.6 Viscosity, sec. ( N o . 4 Ford Cup): 25 Volatile Organic Compounds (VOC): 121 gms./l.

*

1 0 PTSA/10 DMAE/80 Water

SOURCE: Rohm and Haas C o . : Industrial Coatings: ACRYSOL WS-68: Formulation WS-68-2

Enamek

103

G l o s s W h i t e Enamel M a t e r i a1 : P a r t A: Epi-Rez 510 Epoxy R e s i n He1oxy 8 Epoxy F u n c t io n a l Modi f ie r Isopropyl Alcohol P a r t 8: CMD WJ60-8537 C u r i n g Agent Defoamer ( 2 ) R u t i l e Titanium Dioxide (3) D i s p e r s e t o a t e x t u r e o f 9-10 P.C.S.. CMD WJ60-85 7 C u r i n g Agent Defoamer Water Composite B end : Part A Part B P a r t s A and B

Viscosity 55 KU 78 KU 93 KU

Pounds 125.8 42.0 8.4

loris 3.04 5.68 1.28

160.0 17.78 4.0 0.50 250.0 7.31 t h e n add a t reduced sDeed: 79.0 8'. 78 4.0 0.50 375.9 45.13 176.2 872.9

2 ) C o l l o i d 640 3) T i t a n o x 2020 o r Tronox CR-800 Typical Coating Properties: T o t a l Weight S o l i d s , P e r c e n t : 53.5 T o t a l Volume S o l i d s , P e r c e n t : 40.7 PVC, P e r c e n t : 1 7 . 9 R e s i n C o m p o s i t i o n (based on s o l i d s ) : Epoxy R e s i n , P e r c e n t : 54.0 C u r i n g Agent, P e r c e n t : 46.0 SOURCE: S h e l l Chemical Co.:

@

24-315 G l o s s White Enamel

20.00 80.00

Water-Based Paint Formulations

104

G l o s s W h i t e E n a m e l f o r E l e c t r o s t a t i c D i s c Spray Sand M i l l (30 m i n u t e s l l Cyme1 303 Tamol 731 (25%) Butyl Cellosolve Isopropanol Water DMAE (10% i n w a t e r ) R u t i l e t i t a n i u m d i o x i d e (RCL-9)

P a r t s b y Weight 94.5 6.0 12.0 7.5 130.0 15.0 315.0

Letdown : Sand m i l l g r i n d A c r y s o l WS-68 (38%) Water D i p r o p y l ene g l y c o l L-5310 (30% i n B u t y l C e l l o s o l v e ) DMAE (10% i n w a t e r ) PTSA* (10%) n-Butanol Enamel Con s t a n t s : T o t a l s o l i d s , %: 35.0 Pigment/binder r a t i o : 40/60 A c r y l ic/mel ami ne r a t i0 : 80/20 % C a t a l y s t (PTSA) on b i n d e r s o l i d s : 0 . 2 % L-5310 on b i n d e r s o l i d s : 0 . 2 Water/organic r a t i o : By volume: 8 0 . 4 / 1 9 . 6 by w e i g h t : 8 1 . 1 / 1 8 . 9 pH: 8 . 4 V i s c o s i t y , sec. (No. 4 F o r d Cup): 45 (Use more OMAE t o i n c r e a s e s p r a y v i s c o s i t y ; t o decrease s p r a y v i s c o s i t y . ) V o l a t i l e O r g a n i c Compounds (VOC): 372 g m s . / l .

*

250.1 428.9 68.6 75.0 1.4 132.0 4.0 10.0

use l e s s DMAE

10 PTSA/10 DMAE/80 Water

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYSOL WS-88: F o r m u l a t i o n WS-60-4

Enamels

105

G l o s s W h i t e Enamel f o r E l e c t r o s t a t i c Spray A p p l i c a t i o n P a r t s bv Weight 12.4 26.5 3.3 2.7 2.0 4.1

Cowl es G r i nd : A c r y s o l WS-68 (38%) Water DMAE (10% i n w a t e r ) Tamol 731 (25%) T r i t o n X-114 n-Butanol M i x t h e above i n g r e d i e n t s ,

t h e n add s l o w l y :

R u t i l e t i t a n i u m d i o x i d e (RCL-9) M i x t h e g r i n d f o r 20 minutes, as f o l l o w s :

134.5

t h e n l e t down under good a g i t a t i o n

Letdown : Water ) premix Butyl Cellosolve ) n-Butanol A c r y s o l WS-68 (38%) L-5310 (30% i n B u t y l C e l l o s o l v e ) Cyme1 303 D i p r o p y l ene g l y c o l DMAE (10% i n w a t e r ) PTSA* (10%)

108.1 4.7 6.3 414.0 1.4 40.4 74.7 131.0 4.0

Physical Constants: T o t a l s o l i d s , %: 35.0 P i g m e n t / b i n d e r r a t i o : 40/60 A c r y l i c / m e l a m i n e r a t i o : 80/20 % C a t a l y s t (PTSA) on b i n d e r s o l i d s : 0 . 2 W a t e r / o r g a n i c r a t i o , by volume: 81 . 4 / 1 8 . 6 pH: 8 . 4 V i s c o s i t y , sec. (No. 4 F o r d Cup): 43 V o l a t i l e O r g a n i c Compounds (VOC): 362 g m s . / l .

*

10 PTSA/10 DMAE/EO Water

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYSOL WS-68: F o r m u l a t i o n WS-68-5

106

Water-Eased Paint Formulations

Gloss Yellow Enamel Materials: Grind Portion: Chempol 10-0091 Aquacat Magnacat 28% Ammoni a Water Patcote 519 Patcote 577 Krolor Yellow KY-7810 Yellow Iron Oxide Butyl Cellosolve B u t y l Carbi to1

Pounds

Gallons

08.2 1.9 3.7 1.7 142.3 0.9 0.9 58.3 3.8 5.0 5.0

10.02 0.23 0.48 0.20 17.17 0.12 0.12 1.77 0.11 0.67 0.63

147.4 3.1 174.5

17.14 0.37 21.02

183.1 31.5 16.0

21.29 3.79 2.01

21 . o

2.53

Steel ball mill to 7 1/2 N.S. Chempol 10-0091 28% Ammonia Water

1 ) )

Premix

(Neutralization=93%, pH 6.1 to 6.4)

Add in order with good agitation: Rhoplex WL-71 Water Butyl Carbi to1 14% A m m o n i a (to pH 7.3 to 7.5) Water

----

----

Note: Reduce for spray with 07/13 water/butyl Cellosolve. Formulation Constants: Pounds/gallon: 8.82 Non-volatiles (Wt.): 35.7% (Vol.1: 32.0% Pigment/Binder -Ratio: 20/00 PVC: 6.3% Rhoplex WL-71/Chempol 10-0091: 30/70 Neutralization (final based on Chempol 10-0091 solids): 170% pH: 7.3 to 7.5 Viscosity: 200-400 cps. VOC: 2.14 lbs./gal,

SOURCE: Rohm and Haas Co.: Industrial Coatings: Formulation WL-71-3

RHOPLEX WL-71:

Enamels

107

Gray Deck Enamel

Lbs/100 Gal 27.2 27.2 8.2 1.4 5.4 20.4 36.7

I n a r e d ie n t : Propyl Carbi t o 1 Methyl Propasol D i e t h y l ami ne Drew L-475 S a n t i c i z e r 160 DSX 1514 Water M i x we1 1, t h e n add : P l i o l i t e 7104

91.1

M i x w e l l , t h e n add : T i t a n o x 2160 Minusil 5 Aquasperse Brown Oxide P a s t e L i q u a k o t e Y e l l o w Oxide L i quakote B l a c k HSD t o 5 N.S.

197.2 204.0 16.3 16.3 4.1

t h e n d r o p t o f u l l y assembled l e t d o w n w i t h m i x i n g :

L e t Down Phase: P l i o l i t e 7104 B u t y l Dipropasol Sant ic i z e r 160

360.4 20.4 15.0

P r e p a r e t h e f o l l o w i n g p r e m i x ; t h e n add t o l e t d o w n : 74.8 2.7

Water A-107

VOC: 221 g/1 o r 1 . 8 4 l b / g a l D e n s i t y : 11.3 l b / g a l l o n Oven S t a b i l i t y : Pass 4 weeks a t 120 degrees F Freeze Thaw: Pass 5 c y c l e s KU V i s c o s i t y : 100-110 NVV: 42% PVC: 43%

SOURCE: The Goodyear T i r e & Rubber Co.:

Formula #2065-106

108

Water-Based Paint Formulations

Gray Low G l o s s Enamel M a t e r i a1 : Bentone EW S o l u t i o n 2% K e l s o l 3961 -B2G-75 Ammoni um H y d r o x i d e Butoxy Ethanol n-0utanol T i t a n o x 2101 106 Lo M i c r o n B a r y t e s OK 412 S i l i c a Z i n c Phosphate 50852 A1 cophor 827 Raven 1255 Water S t e e l b a l l m i l l t o 6-7 Hegman g r i n d . Letdown : Kel s o l 3961 -826-75 Ammoni um H y d r o x i de Premix t h e f o l l o w i n g and add t o above: C o b a l t Hydrocure I 1 Manganese H y d r o c u r e I 1 Butoxy Ethanol n-Butanol Water

Lbs.

Gals 13.02 17.51 1.86 2.29 2.55 3.50 5.13 0.54 3.42 0.49 0.30 24.60

50.60 6.20

5.75 0.83

3.10 6.38 8.79 6.55 123.37

0.41 0.85 1.17 0.97 14.81

Analysis: p i g m e n t VOI ume C o n c e n t r a t i o n , P e r c e n t : 4 5 . 4 P i g m e n t / B i n d e r R a t i o : 2.74/1 P e r c e n t S o l i d s , W e i g h t : 49.7 P e r c e n t S o l i d s , Volume: 24.4 V i s c o s i t y @ 25C, #4 F o r d , S e c s . : 35-45 Pounds/Gallon: 1 1 . 4 4 pH: 8 . 3 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 275 Pounds/Gallon: 2.29

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2419-22

.

110.67 154.09 13.89 17.20 17.21 116.55 187.25 9.81 92.58 10.19 4.37 204.92

I n c . : Waterborne Handbook:

Enamels

Green Chrome F r e e G l o s s Enamel M a t e r i a1 : Lbs. A r o l on 557-8-70 119.73 E t h y l e n e G l y c o l Monobutyl E t h e r 9.21 T r i t o n X-405 1.84 8yk 301 1.84 9.21 D i m e t h y l e t h a n o l Ami ne (DMEA) Water 92.10 Y-5775 F a s t Y e l l o w 27.63 A-4434 Tacoma B l u e 1.84 T i t a n o x 2020 92.10 P e b b l e m i l l o r sand m i l l t o 7 Hegman g r i n d . Letdown : A r o l o n 557-8-70 Cyme1 350 T r i b u t y l Phosphate E t h y l e n e G l y c o l Monobutyl E t h e r DMEA Water

122.49 73.68 9.21 27.63 7.37 352.10

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 15.56 P i g m e n t / B i n d e r R a t i o : .5/1 P e r c e n t S o l i d s , W e i g h t : 39.71 P e r c e n t S o l i d s , Volume: 30.61 V i s c o s i t y C 25C, KU: 80-85 Pounds/Gallon: 9 . 2 1 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 328.9 Pounds/Gallon: 2 . 7 4 Resin/Melamine R a t i o : 70/30 % R e d u c t i o n t o 30 S e c s . , #2 Zahn, w i t h w a t e r : 30

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2185-63

Inc.:

Waterborne Handbook:

.

Gals 14.42 1.23 .20 .23 1.24 11.06 1.92 .15 2.70

14.76 7.37 1.02 3.68 1 .oo 39.02

109

110

Water -Based Paint Formulations

Green Enamel M a t e r i a1 : Water 2-Butoxy E t h a n o l n-Butyl Alcohol Ammoni um H y d r o x i de Kel s o l 3990-826-70 Byk P104S T i t a n o x 2101 Y IO-2288D S u n f a s t Green 264-8142 Dalamar Ye1 l o w YT820D S t e e l b a l l m i l l t o a 7 Hegman g r ind Letdown : Water E k t a s o l v e EP Ammoni um H y d r o x i d e Kel s o l 3990-02G-70 Premi x : Cobalt Hydrocure I 1 A c t i v-8 E k t a s o l v e EP

Lbs.

.

Gals 22.10 2.80 3.12 0.93 15.05 0.16 0.88 0.87 0.74 1.01

313.16 18.06 5.64 84.79

37.59 2.38 0.76 10.03

7.29 1.71 3.00

0.21 0.39

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 17.08 P i g m e n t / B i n d e r R a t i o : 0.55/1 P e r c e n t S o l i d s , Weight: 26.83 P e r c e n t S o l i d s , Volume: 20.53 V i s c o s i t y @ 25C, #4 Ford, Secs.: 35-45 Pounds/Gal 1on : 8 . 7 8 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 401 Pounds/Gal 1on : 3 . 3 4

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2578-50

.

184.11 21.05 21.06 6.98 127.15 1.27 29.30 29.30 12.94 11.86

I n c . : Waterborne Handbook:

0.95

Enamels

111

Green F a s t D r y G l o s s Enamel

Lbs.

M a t e r i a1 : K e l s o l 3960-826-75 C o b a l t Hydrocure 11 Manganese H y d r o c u r e I 1 Butoxy Ethanol Ammoni um H y d r o x i d e

76.71 3.02 3.78 13.69 3.35

Gals. 8.88 0.39 0.50 1.82 0.45

76.60 14.36 15.71 168.03

2.29 1.22 0.67 20.17

Add above m a t e r i a l s under a g i t a t i o n Y e l l o w I r o n O x i d e 2288D Dal amar Ye1 1ow YT820D Palomar Green G5406 Water Pebble m i l l t o 7 Hegman g r i n d .

Letdown : K e l s o l 3960-826-75 324.31 37.54 Ammoni um H y d r o x i d e 7.14 0.96 Normal B u t a n o l 23.52 3.48 Secondary B u t a n o l 25.19 3.74 Butoxy Ethanol 42.01 5.59 Water 78.97 9.48 Premix above m a t e r i a l s and add t o m i l l base under a g i t a t i o n . A r o l on Water Butoxy Premix pH t

840-W-39

108.89 12.52 16.79 2.02 Ethanol 4.19 0.56 above m a t e r i a l s and add t o b a t c h under a g i t a t i o n . A d j u s t o 8 . 0 - 8 . 5 w i t h ammonium h y d r o x i d e .

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : Pigment/Binder R a t i o : .35/1 P e r c e n t S o l i d s . Weight: 40.8 P e r c e n t S o l i d s , Volume: 3 6 . 8 Pounds/Gallon: 8 . 9 pH: 8 . 0 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 355 Pounds/Gallon: 2 . 9 6 SOURCE: R e i c h h o l d Chemicals, I n c . : F o r m u l a t i o n 2175-76C

10.2

Waterborne Handbook:

II2

Water-Based Paint Formulations

Hiclh G l o s s Ford B l u e Enamel I n a r e d ie n t s : Chempol 10-0091 Butyl Cellosolve 28% NH3 6% C a l c i u m D r i e r Coroc A2678M U v i n u l N539 Byk 035 T i ona RCL-628 Phthalo Blue D e i o n i z e d Water

Pounds 297.94 22.35 8.94 4.47 4.47 4.47 1.12 49.62 24.81 44.70

Gal 1ons 33.86 2.98 1.20 0.55 0.51 0.51 0.15 1.49 1.78 5.37

Pebble o r s a n d m i l l t o Hegman 7+, t h e n l e t down w i t h : B u t y l C e l l os01 ve 11.18 5% C o b a l t Hydrocure I 1 2.46 12% Z i r c o n i urn Hydrocem 3.69 A c t iv-8 0.45 E x k i n #2 1.12

1.49 0.32 0.44 0.05 0.15

M i x w e l l and c o n t i n u e l e t down w i t h : Butyl Cellosolve D e i o n i z e d Water

1.49 6.72

11.18 55.88

Premix t h e f o l l o w i n g and add s l o w l y w i t h r a p i d m i x i n g : A c r y s o l ASEGO 1.12 D e i o n i z e d Water 55.08 A d j u s t pH t o 8.0-8.5 D e i o n i z e d Water

and c o n t i n u e l e t down w i t h : 279.04

0.13 6.72 33.47

P r o p e r t i es : % Weight S o l i d s : 35.06 % Volume S o l i d s : 28.38 P/B Weight R a t i o : 0.33 % PVC: 11.5 VOC, # / g a l l o n , c a l c u l a t e d : 2.78 minus w a t e r V i s c o s i t y , # 4 F o r d Cup*: 33-36 seconds Volume r e d u c t i o n 100 p a r t s 10-0091-H w i t h 18-20 p a r t s o f d e i o n i zed w a t e r .

*

F i l m Properties: Spray a p p l i e d o v e r 61000 CRS and a i r d r i e d two weeks b e f o r e t e s t i ng. Dry f i l m t h i c k n e s s , m i l s : 1 . 3 P e n c i l hardness: 26 C r o s s h a t c h a d h e s i o n : e x c e l l e n t - no t a p e o f f 60/20 g l o s s : 09/76 MEK d o u b l e r u b s t o m e t a l : 45 D i r e c t i m p a c t , inch-1 b s . : >80

SOURCE: Freeman Polymers D i v i s i o n : CHEMPOL 10-0091-H: Suggested S t a r t i n g F o r m u l a t i o n

EnameLF

Hiah G l o s s I n t e r i o r Enamel M a t e r i a1 : Water Texanol C o l l o i d 261 I g e p a l GO-630 Foamaster R Nuosept 95 AMP 95 Tronox C R - 8 0 0 H i g h speed d i s p e r s e r Water Synthemul 40-424 Texanol n-Butyl Propionate

Lbs.

46.8 600.0 10.0 50.5 0.3 4.5

5.62 69.77 1.27 6.93 0.03 0.53

10.5 9.6 1.6

0.5

,

15 m i n u t e s maxi mum.

FC-120 RM-825,

0.8 1.o 219.0

Gals. 6.66 1.33 1 .oo 0.18 0.07 0.08 0.13 6.40

55.5

10%

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t S o l i d s , Weight: 45.4 P e r c e n t S o l i d s , Volume: 33.0 I n i t i a l V i s c o s i t y , KU: 9 6 . 0 Pounds/Gal l o n : 10.11 pH: 6 . 8 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 197 I C I , Poise: 1.6 G l o s s @ 60/20: 83/65 Flow and L e v e l i n g : Exc. V i s c o s i t y , 7 Days @ 135F: 91

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 424-01

Percent: 19.4

I n c . : Waterborne Handbook:

113

114

Water-Based Paint Formulations

H i a h - h i d i na Eqashel 1 Enamel Inaredients : Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-4400 P r e s e r v a t ive ( 1 ) Dispersant (2) T r i t o n N o n i o n i c S u r f a c t a n t N-57 2-Amino-2-methyl-1-propanol (3) P r o p y l e n e G1 y c o l Antifoam ( 4 ) Titanium Dioxide (5) Thermo-optic Clay (6) Hydrous C l a y ( 7 ) Letdown : Ucar F i l m e r I B T Butyl C a r b i t o l Solvent Ucar T h i c k e n e r SCT-275 Ucar L a t e x 379 Antifoam ( 4 )

Pounds

Gal l o n s

226.7 2.0 2.3 9.2 2.3 1.o 51.8 1.9 225.0 100.0 25.0

27.21 0.18 0.25 1.oo 0.25 0.13 6.00 0.25 6.54 5.46 1.15

11.9 11.9 17.2 418.2 2.8

1.50 1.50 2.00 46.21 0.37

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 145 o r e q u i Val e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r equ v a l e n t ( 3 ) 2-Amino-2-methyl-1-propanol A P-95 o r e q u i v a l e n t " C o l l o i d " 643 o r equ v a l e n t ( 4 ) Antifoam ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t ( 6 ) Thermo-opti c C1 ay - " O p t i whi t e " o r equi Val e n t ( 7 ) Hydrous C l a y - Burgess No. 98 o r e q u i v a l e n t

-

-

Comparat ive P r o p e r t ies : Pigment Volume C o n c e n t r a t i o n , %: 3 5 . 6 S o l i d s , %: by Volume: 3 7 . 6 by Weight: 53.4 Weight p e r G a l l o n , l b : 11.09 Pai n t P r o p e r t i8s : V i s c o s i t y , in i t i a1 : Stormer, KU: 104 I C I , poise: 1.4 pH, i n i t i a l : 8 . 2 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks at 120F: Pass F i 1m P r o p e r t i es : C o n t r a s t R a t i o , 6 - m i l b a r ( 1 ) : 0.968 R e f l e c t a n c e , %: 91.9 G l o s s , 60, 6 - m i l b a r : 8 Sheen, 85, 6 - m i l b a r : 22 Flow and L e v e l i n g : Brushed: Good ( 1 ) Opacity increased w i t h t o n i n g SOURCE: Ucar Emulsion Systems: UCAR L a t e x 379: F o r m u l a t i o n S u g g e s t i o n 1-1998

Enamels

115

H i g h Performance Bake W h i t e Enamels P a r t s by w e i g h t PELA TOFA ~ _

Materials: R e s i n WB-3823, 75% NVM D i m e t h y l e t h a n o l ami ne A m i no C r o s s l in k e r A ( 1 ) A m i no C r o s s l in k e r B (2) . . T i t a n i u m d i o x i d e 3) Water P r o p e r t i es : P i gment/bi nder r a t i o Me1ami n e / a l kyd r a t io N o n - v o l a t i l e m a t e r i a l (NVM), V i s c o s i t y , #4 F o r d cup, sec PH

257.0 10.0 48.0

----

245.0 440.0

wt %

0.98/1.0 20/80 50 53 7.5

_

290.4 11.2

----

39.4 258.4 400.6 0.98/1.0 15/85 52.5 55 7.65

( 1 ) U f o r m i t e MM 83 (2) Cyme1 301 (3) T i - P u r e R-900 Compounding p r o c e d u r e f o r t h e enamels: 1. S o l u b i l i r e r e s i n i n a m i x i n g v e s s e l c o n t a i n i n g a s o l u t i o n o f d i m e t h y l e t h a n o l a m i n e and d e i o n i z e d w a t e r . 2. Charge r e s i n s o l u t i o n , pigment and amino c r o s s l i n k e r a p e b b l e m i 11. G r i n d o v e r n i g h t t o a Hegman G r i n d o f 7+. 3 . A f t e r m i l l i n g , a d j u s t t o c o r r e c t pH and v i s c o s i t y . Mechanical P r o p e r t i e s o f WB-3823 enamel s : PELA( 1 ) Properties P e n c i l hardness C r o s s h a t c h adhesion 1 / 8 - i n c h c o n i c a l bend, % pass Impact r e s i s t a n c e , i n - l b : direct reverse

8-37( 3) H 5B 100

CRS(4) F 5B

100 100 60

140 80 TOFA(2)

Penci 1 hardness Crosshatch adhesion 1 / 8 - i n c h c o n i c a l bend, % pass Impact r e s i s t a n c e , i n - l b : direct reverse

(1) (2) (3) (4)

B-37( 3) 2H

CRS(4) 3H

5B

58

100

100

120 80

140 60

1.0 t o 1.2 m i l f i l m t h i c k n e s s , c u r e d 2 0 m i n u t e s a t 121C 1.0 t o 1.2 m i l f i l m t h i c k n e s s , c u r e d 30 m i n u t e s a t 177C S u b s t r a t e : B o n d e r i t e 37 t r e a t e d c o l d r o l l e d s t e e l S u b s t r a t e : Cold r o l l e d s t e e l

SOURCE: Amoco Chemical Co.: Water-Borne Bake A l k y d s Based on AMOCO TMA and I P A : Formula T a b l e 8 and T a b l e 9

116

Water-Based Paint Formulations

H i qh S o l i d s P o l v e s t e r / M e l ami ne Enamel Grind: R e s i n WS-3-2C (85% NV) T i t a n i u m D i o x i d e Pigment Hexamethoxymethyl Me1 ami ne D i m e t h y l e t h a n o l a m i n e (DMEA) Flow C o n t r o l A d d i t i v e

Wei q h t

Sol i d s

258.0 256.3 94.0 18.1 3.1

219.3 256.3 94.0

-----

0.3

L e t Down: Demi n e r a l ized Water n-Butyl Alcohol P h y s i c a l C o n s t a n t s o f Enamel: R e s i n / C r o s s l i n k e r R a t i o : 70/30 B i n d e r / P i gment , w t %: 55/45 N o n v o l a t i l e s , w t %: 57 Water/Organic, W t %: 82/18 pH: 8.0-8.5 V i s c o s i t y , No. 4 F o r d Cup, sec:

55-60

P h y s i c a l P r o p e r t i e s o f Enamel C o a t i n g ( b , c ) : Cure Temperature/Time, C/min: 177/20 I n i t i a l Gloss, Gardner, %:

60: 98 20: 83 Impact R e s i s t a n c e , i n . - l b (cm-kg): D i r e c t : 140 (161) Reverse: 90 (104) P e n c i l Hardness: 4H S o l v e n t R e s i s t a n c e , M E K d o u b l e r u b s : 200+ S c r i b e d Adhesion, % pass: 100 C o n i c a l Mandrel F l e x i b i l i t y , ASTM D-522, 1/8 i n . , % pass: 100 S t a i n R e s i s t a n c e : 5-10 D e t e r g e n t R e s i s t a n c e ( d ) , 1 1/2% s t a n d a r d d e t e r g e n t s o l u t i o n , 240 h r , 165F (74C): 60 g l o s s r e t e n t i o n , %: 100 b l i s t e r s , f r e q u e n c y / s i z e : None S a l t Spray, 500 h r : 60 g l o s s r e t e n t i o n , %: 100 S c r i b e creepage, i n . ( m m ) : 11/32 b l is t e r s : None Storage S t a b i l i t y : I n i t i a l : p H / V i s c o s i t y , cP: 8.3/320 A f t e r 500 h o u r s a t 120F; p H / V i s c o s i t y , cP: 7.0/400 b ) Unprimed, z i n c p h o s p h a t i z e d , c o l d - r o l l e d s t e e l p a n e l s c o a t e d w i t h a 1 - 1 1/2 m i l f i l m were used i n t h e s e e v a l u a t i o n s c ) T e s t methods a r e t h o s e commonly used i n t h e p o l y m e r s and coatings industry. d ) C o a t i n g s were a p p l i e d o v e r an epoxy p r i m e r f o r d e t e r g e n t resistance tests.

SOURCE:

Eastman Chemical P r o d u c t s , P o l y e s t e r Resi n WS-3-2C

Inc.:

Enamel P r e p a r e d f r o m

Enamels

L i g h t He1 iogen Green Enamel C a r g i l l Water R e d u c i b l e S i l i c o n e M o d i f i e d A1 kyd 74-7435 Aqueous Ammonia 28% E t h y l e n e G l y c o l Monobutyl E t h e r

Byk-301 He1 i o g e n Green L8690 T i t a n i um D i o x i d e T i -Pure R-900 Dei o n i zed Water

Pounds

Gal 1ons

155.2 6.7 13.2 3.3 6.7 194.0 118.7

17.25 0.89 1.76 0.41 0.36 5.54 14.27

110.9 6.5

12.32 0.87

15.9 4.0 5.0 1.3

2.11 0.52 0.69 0.17

288.3

34.58

68.8

8.26

Sand M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e S i l i c o n e M o d i f i e d A1 kyd 74-7435 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: E t h y l e n e G l y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um A c t iv-8 D e i o n i z e d Water D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Ad j ustment )

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 40.63 (By Volume) : 27.14 Pigment t o B i n d e r R a t i o : 0.98 P i gment Vol ume Concent r a t i on : 22.00 Weight p e r G a l l o n : 9.98 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.58 ( G r a m s / L i t e r ) : 309 W a t e r : C o s o l v e n t Weight R a t i o : 82.80:18.20 pH: 8.0-8.5 V i s c o s i t y Krebs-Stormer (KU): 70t-5 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold Rolled Steel G l o s s (60/20): 86/60 P e n c i l Hardness: Pass F % C r o s s h a t c h Adhesion: 100 Impact ( I n . Lbs.): D i r e c t : 30 Reverse: < 5 D r y Time L i n e a r D r y i n g Recorder ( H o u r s ) : 2 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1843-227

I

117

118

Water-Based Paint Formulations

Non-Leaf ina A1 umi num Enamel Material : Add, mix i n o r d e r l i s t e d : Water Ammoni um H y d r o x i de K e l s o l 3906-826-75 Premix, add t o above: Letdown : C o b a l t Hydrocure I 1 Activ-8 Butoxy E t h a n o l Manganese H y d r o c u r e F i n a l Letdown: Butoxy Ethanol Hydro-Paste 82255

Lbs. 463.40 11.20 241 .OO

55.63 1.49 27.54

5.55 2.21 11.27 3.04

0.72 0.28 1 .so 0.40

26.59 111.25

3.54 8.90

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 15.0 Pigment/Binder R a t i o : .3?/1 Percent S o l i d s , Weight: 30.6 P e r c e n t S o l i d s , Volume: 2 4 . 6 Pounds/Gallon: 8 . 7 6 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i ng w a t e r ) : G r a m s / L i t e r : 389 Pounds/Gallon: 3 . 2 4

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 1652-40

Gals.

I n c . : Waterborne Handbook:

Enamels

Quality

Gloss W h i t e Enamel

A q u a l it y h i g h - h i d i ng g l o s s enamel

Inpredients: Pigment G r i n d : Water P r o p y l ene G1y c o l D i spersant (1 ) Nonionic Surfactant (2) Preservative (3) Antifoam (4) Titanium Dioxide (5)

Pounds

Gallons

50.10 43.30 9.20 2.20 1.20 0.25 250.00

6.02 5.00 1.oo 0.25 0.13 0.03 7.31

L e t Down: Anionic Surfactant (6) Butyl C a r b i t o l Solvent Ucar F i l m e r IBT Antifoam (7) Ucar L a t e x 430 (43.0%) Ucar T h i c k e n e r SCT-275

3.10 19.80 39.60 5.60 604.70 6.50

0.37 2.50 5.00 0.75 69.51 0.75

Premi x : A n i o n i c Thickener (8) 3.30 Water 8.30 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 0 . 1 0

0.37 1 .oo 0.01

Suppliers: ( 1 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t ( 2 ) N o n i o n i c S u r f a c t a n t - " T r i t o n " CF-10 o r e q u i v a l e n t ( 3 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t "Nalco" 2300 o r e q u i v a l e n t (4) Antifoam ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t ( 6 ) A n i o n i c S u r f a c t a n t - " T r i t o n " GR-7M o r e q u i v a l e n t ( 7 ) A n t i f o a m - "Byk" 035 o r e q u i v a l e n t ( 8 ) A n i o n i c T h i c k e n e r - " A c r y s o l " RM-5 o r e q u i v a l e n t

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 20.3 T o t a l S o l i d s , %: by Volume: 35.9 by W e i g h t : 49.8 V i s c o s i t y ( e q u i 1ib r a t e d ) : Stormer, KU: 86 I C I , Poise: 1.2 pH, i n i t i a l : 9 . 4 Weight p e r G a l l o n , l b : 10.47 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 w k s a t 120F (49C): Pass Flow and L e v e l i n g , b r u s h e d : Good Sag R e s i s t a n c e , brushed: E x c e l l e n t Foam C o n t r o l : Good VQC, g / 1 : 248

SOURCE:

Ucar Emulsion Systems: UCAR L a t e x 430: S u g g e s t i o n E-2201

Formulation

119

120

Water-Based Paint Formulations

Q u a l i t y G l o s s W h i t e Enamel A q u a l i t y g l o s s enamel w i t h an o u t s t a n d i n g b a l a n c e o f D r o o e r t i e s

Inaredients: Pigment G r i n d : Water Propylene G l y c o l C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-15M D i spersant ( 1) 2-Ami no-2-methyl -1 - p r o p a n o l ( 2 ) Antifoam ( 3 ) Preservative (4) Nonionic Surfactant ( 5 ) Nonionic Surfactant (6) Titanium Dioxide (7) L e t Down: Butyl C a r b i t o l Solvent Mix: Butyl C a r b i t o l Solvent Ucar T h i c k e n e r SCT-275 Ucar L a t e x 430 (43%) Ucar F i l m e r I B T Antifoam (3)

Pounds

'

Gai 1ons

82.90 34.60 0.75 9.60 3.00 2.10 1.20 2.10 7.10 225.00

9.95 4.00 0.07 1 .oo 0.37 0.25 0.13 0.25 0.75 6.58

15.80

2.00

5.90 6.50 590.70 39.60 2.10

0.75 0.75 67.90 5.00 0.25

Suppl ie r s : ( 1 ) D i s p e r s a n t - " C o l l o i d " 261 o r e q u i v a l e n t ( 2 ) 2-Ami no-2-methyl -1 - p r o p a n o l - AMP-95 o r e q u i Val e n t ( 3 ) A n t i f o a m - "Foamex" 1488 o r e q u i v a l e n t ( 4 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 5 ) N o n i o n i c S u r f a c t a n t - " S u r f y n o l " 104E o r e q u i v a l e n t ( 6 ) N o n i o n i c S u r f a c t a n t - " E o r c h i g e n " DFN o r e q u i v a l e n t ( 7 ) T i t a n i u m Oxide - "Tronox" CR-800 o r e q u i v a l e n t

P a i n t P r o p e r t ies : Pigment Volume C o n c e n t r a t i o n (PVC), %: 19.0 T o t a l S o l i d s , %: by Volume: 3 4 . 5 by Weight: 48.3 V i s c o s i t y ( e q u i 1 ib r a t e d ) : Stormer, KU: 97 I C I , Poise: 1 . 8 pH, i n i t i a l : 9 . 4 Weight p e r G a l l o n , l b : 10.29 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 wks a t 120F (49C): Pass Flow and L e v e l i n g , brushed: Good Sag R e s i s t a n c e , brushed: Excel l e n t Foam C o n t r o l : Excel 1e n t VOC, g / l : 245.6 F i 1m P r o p e r t ies : C o n t r a s t R a t i o 0.003 i n : 0.973 R e f l e c t a n c e %: 92.0

SOURCE: Ucar Emulsion Systems: UCAR L a t e x 430: S u g g e s t i o n E-2202

Formulation

Enamels

Q u a l i t y G l o s s W h i t e Enamel A q u a l i t y enamel w i t h e x c e p t i o n a l a p p l i c a t i o n p r o p e r t i e s .

Ingredients: Pigment G r i n d : Water Butyl C a r b i t o l Solvent P r o p y l e n e G1y c o l C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-15M D i spersant ( 1) Nonionic Surfactant (2) Nonionic Surfactant ( 3 ) Antifoam (4) P r e s e r v a t i v e (5) Titanium Dioxide (6)

Pounds

Gallons

42.00 47.50 43.20 0.75 6.10 2.20 2.10 0.70 1.20 225.00

5.04 6.00 0.07 0.62 0.25 0.25 0.09 0.13 6.58

L e t Down: Mix: Ucar T h i c k e n e r SCT-270 B u t y l C a r b i t o l Solvent Ucar L a t e x 430 (43.0%) P l a s t i c i z e r (7) Antifoam (8)

13.00 11.90 600.00 23.60 7.50

1.50 1.50 68.97 3.00 1 .oo

5.00

Suppliers: ( 1 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 2 ) N o n i o n i c S u r f a c t a n t - " T r i t o n " N-57 o r e q u i v a l e n t (3) Nonionic Surfactant " S u r f y n o l " 104E o r e q u i v a l e n t ( 4 ) A n t i f o a m - " C o l l o i d " X-0137-MC-33 o r e q u i v a l e n t ( 5 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 6 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t (7) P l a s t i c i z e r - "Kodaflex" T X I B o r equivalent ( 8 ) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 18.8 T o t a l S o l i d s , %: b y Volume: 34.9 by Weight: 48.2 Viscosity (equilibrated): Stormer, KU: 86 I C I , Poise: 1.2 pH, i n i t i a l : 8 . 7 Weight p e r G a l l o n , l b : 10.27 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 wks a t 120F (49C): Pass Flow and L e v e l i n g , brushed: Good Sag R e s i s t a n c e , brushed: E x c e l l e n t Foam C o n t r o l : Excel l e n t VOC, g / 1 - p l a s t i c i z e r : 226.4 SOURCE: Ucar Emulsion Systems: UCAR L a t e x 430: S u g g e s t i o n E-2203

Formulation

121

122

Water-Based Paint Formulations

Red A c r v l ic Emu1s i on Enamel Ingredients: Coroc A-2678-M 2-butoxyethanol S u r f y n o l 104BC S u r f y n o l DF-75 Water Mapico Red #347 I r o n Oxide 13-3060 Novoperm A20 Red

Pounds 45.81 7.71 8.05 1.32 30.27 20.55 30.83

Gal 1ons 5.21 1.03 1.07 0.16 3.63 0.48 2.73

Pre-mix f i r s t f o u r i n g r e d i e n t s , t h e n add w a t e r w i t h a g i t a t i o n . Load m i x t u r e i n t o b a l l m i l l f o l l o w e d b y pigments. P o r c e l a i n b a l l g r i n d t o a #7 Hegman. A d j u s t g r i n d a n d / o r wash m i l l w i t h w a t e r f r o m below i f n e c e s s a r y . L e t down w i t h : Chempol 20-4301 2-butoxyethanol B u t y l Carbi t o 1 Dibutyl Phthalate Nuocure CK-10 Michem 39235 Water ( h o l d t o a d j u s t v i s c o s i t y )

572.76 31.96 20,44 7.06 2.01 30.18 75.72

65.09 4.26 2.57 0.81 0.25 3.62 9.09

Pre-mix c o - s o l v e n t s , p l a s t i c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r seeding. Add t h e wax d i s p e r s i o n t o t h e " l e t down" w i t h a g i t a t i o n . A f t e r m i x i n g w e l l , add t h e g r i n d t o t h e " l e t down" w i t h good a g i t a t i o n . M i x w e l l and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7 . 6 , as t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % by w e i g h t : 34.42% T o t a l s o l i d s , % by volume: 29.42% Wei g h t / g a l 1 on : 8.85 1b s . / g a l PVC: 10.90 P i g m e n t / b i n d e r r a t i o : 0.20 VOC: 2 . 0 4 l b s . / g a l . V i s c o s i t y : 38" #2 Zahn pH: 7 . 6 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y Set t o t o u c h : 1 7 ' Dust f r e e : 2 0 ' Tack f r e e : 7 5 ' - 9 0 ' Dry t h r o u g h : 7 5 ' - 9 0 '

.

SOURCE : Freeman Polymers D i v i s i on : CHEMPOL 20-4301 -D F o r m u l a t i o n

123

Enamels

Red Enamel M a t e r i a1 : Water 2-Butoxy E t h a n o l n-Butyl Alcohol E k t a s o l v e EP Ammonium H y d r o x i d e K e l s o l 3990-826-70 Byk P104S Novaperm Red F3RK-70 Copperas Red R-7098 S t e e l b a l l m i l l t o a 7 Hegman g r i n d . Letdown : Water Ammonium H y d r o x i d e Kel s o l 3990-B2G-70 Premi x : Cobalt Hydrocure I 1 A c t i v-8 2-Butoxy E t h a n o l

Lbs.

Gals 36.31 0.71 1.23 1.10 1.12 16.57 0.17 3.79 0.20

212.52 3.49 93.38

25.51 0.47 l? .05

8.97 1.51 3.00

1.17 0.19 0.40

Anal v s i s : P;gment Volume C o n c e n t r a t i o n , P e r c e n t : 17.51 P i g m e n t / B i n d e r R a t i o : 0.29/1 P e r c e n t S o l i d s , W e i g h t : 25.67 P e r c e n t S o l i d s , Volume: 22.78 V i s c o s i t y @ 25C, #4 F o r d , Secs. : 35-45 pH: 8 . 2 - 8 . 5 Pounds/Gallon: 8 . 4 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 335 Pounds/Gallon: 2 . 7 9

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2578-49

.

302.47 5.33 8.33 8.33 8.36 140.04 1.37 40.76 8.43

I n c . : Waterborne Handbook:

124

Water-Based Paint Formulations

Red G l o s s A c r v l i c Enamel M a t e r i a1 : A r o l o n 559-64-70 Butoxy E t h a n o l D i m e t h y l e t h a n o l A m i ne (DMEA) Water D i sperbyk X-1843 Madras Orange 13-3690 Novoperm Bordeaux HF3R Pebble o r sand m i l l t o 7+ Hegman G r i n d . Letdown : A r o l o n 559-G4-70 Resimene 740 Butoxy E t h a n o l n-Butanol DMEA Water

Lbs. 73.42 18.38 5.48 73.39 1.44 4.10 22.00

Gals. 8.41 2.45 .74 8.81 .16 3.98 1.90

109.93 100.16 14.25 17.62 9.92 296.63

21.87 10.22 1.90 2.61 1.34 35.61

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 1 7 . 3 P i g m e n t / B i n d e r R a t i o : .24/1 P e r c e n t S o l i d s , W e i g h t : 39.10 P e r c e n t S o l i d s , Volume: 34.02 V i s c o s i t y @ 25C, KU: 70-75 Pounds/Gallon: 8.68 % R e d u c t i o n t o 30 Secs., #2 Zahn, w i t h w a t e r : 30 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 338 Pounds/Gallon: 2 . 8 2

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2185-83

I n c . : Waterborne Handbook:

Enamels

Red G l o s s Enamel

Lbs.

Material : Water Ammoni um H y d r o x i d e K e l s o l 391 0-826-75 Butoxy Ethanol Cobalt Hydrocure I 1 A c t iv - 8 Novaperm F5RK Novaperm F3RK70 Oswego Orange X-2065 T i P u r e R-902 B a l l m i l l t o 6-7 Hegman g r i n d .

157.82 10.52 134.67 21.04 6.24 1.04 14.03 15.43 56.81 47.70

Gals. 18.95 1.40 15.37 2.81 0.83 0.13 1.24 1.44 4.77 1.43

Letdown : Kel s o l 391 0-B2G-75 n-Butanol Ammoni um H y d r o x i d e Water V e r s a f l o w 102 Butoxy Ethanol Water

142.38 22.44 11.22 56.81 2.10 34.37 163.43

16.25 3.32 1.49 6.82 0.25 4.57 19.62

Anal y s i s: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 28.9 P i g m e n t / B i n d e r R a t i o : .65/1 . O P e r c e n t S o l i ds, Wei g h t : 3 8 . 3 P e r c e n t Sol i d s , Vol ume: 3 0 . 7 V i s c o s i t y @ 25C, #4 F o r d , Secs. : 75-80 Pounds/Gallon: 8 . 9 3 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 334 Pounds/Gal 1on : 2 . 7 9

SOURCE:

R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i o n 21 1 6 - 7 l A

125

126

Water -Based Paint Formulations

Red H i g h Gloss Enamel

Lbs.

Material : Water Ammoni um H y d r o x i de Kel s o l 3906-626-75 Premix d r i e r s and s o l v e n t : C o b a l t Hydrocure A c t i v-8 Butoxy E t h a n o l Rex Orange X-2806 Garnet Toner X-2433 Sand m i l l t o 6 Hegman g r i n d . Letdown : Water Ammonium H y d r o x i d e Kel s o l 3906-B2G-75 10% DC-29 i n B u t y l C e l l Anal y s i s : Pigment Volume C o n c e n t r a t i o n , Pigment/Binder R a t i o : . 5 / 1 P e r c e n t S o l i d s , Weight: 36.9 P e r c e n t Sol ids, Vol ume: 28.4 Pounds/Gallon: 9 . 1 9 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 265 Pounds/Gal 1on : 2 . 2 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 174-1

Percent:

142.35 6.57 82.13

Gals. 17.10 0.88 9.50

2.30 1.10 5.48 84.32 26.28

0.30 0.14 0.73 1.82 2.05

328.50 8.76 219.00 5.04

39.42 8.17 25.36 0.61

13.6

I n c . : Waterborne Handbook:

Enamels

127

Red Rose A i r D r v Enamel C a r g i l l Water R e d u c i b l e Chain Stopped A1 kyd 74-7495 Aqueous Ammonia 28% Byk-301 Byk-020 sec-Butanol E t h y l e n e G l y c o l Monobutyl E t h e r Quindo Magenta RV-6803 S y n t h e t i c Red I r o n Oxide R0-3097 T i t a n i u m D i o x i d e T i - P u r e R-900 D e i o n i z e d Water

Pounds

Gal 1ons

134.6 4.4 1.o 1.9 4.5 6.4 20.7 7.4 9.4 70.6

15.65 0.58 0.13 0.26 0.67 0.85 1.72 0.18 0.27 8.47

137.8 7.0

16.02 0.94

5.6 4.0 3.6 2.6 0.9

0.83 0.53 0.46 0.37 0.12

432.7

51.95

S a n d m i l l t o a 7 . 5 Hegman C a r g i l l Water R e d u c i b l e Chain Stopped A1 kyd 74-7495 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: sec-Butanol E t h y l e n e G l y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i u m A c t iv-8 Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 27.09 (By Volume): 22.80 Pigment t o B i n d e r R a t i o : 0 . 0 8 Pigment Volume C o n c e n t r a t i o n : 2.19 Weight Per G a l l o n : 8 . 5 5 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.90 ( G r a m s / L i t e r ) : 348 W a t e r : C o s o l v e n t Weight R a t i o : 82.04:17.96 pH: 8 . 7 V i s c o s i t y Krebs-Stormer (KU): 65-75 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold Rolled Steel G l o s s ( 6 0 / 2 0 ) : 95/85 D r y Time L i n e a r D r y i n g Recorder ( M i n u t e s ) : 64

SOURCE:

Cargill,

Inc.:

CARGILL F o r m u l a r y : Formula PI 843-2578

128

Water-Based Paint Formulations

S a t i n White A i r Dry E n a a ~Pounds

C a r g i 11 Water R e d u c i b l e A c r y l ic Modi f ied A1 kyd 74-7432 Aqueous Ammonia 28% T r i e t h y l ami ne T i t a n i um D i o x i d e T i -Pure R-900 I m s i l A-8 Byk-301 D e i o n i z e d Water

Gallons

174.0 10.1 1 .o 174.0 98.6 1.5 149.0

20.47 1.34 0.17 4.97 4.47 0.18 17.89

74.6 4.3 0.4

8.77 0.58 0.07

2.9 2.9 0.8

0.38 0.40 0.10

335.0

40.21

Sand M i l l t o a 7 Hegman C a r g i 1 1 Water R e d u c i b l e A c r y l ic Modi f ied A1 kyd 74-7432 Aqueous Ammonia 28% T r i e t h y l ami ne Premix t h e f o l l o w i n g , t h e n add: I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um A c t iv-8 Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 43.71 (By Volume): 28.62 Pigment t o B i n d e r R a t i o : 1.54 Pigment Volume C o n c e n t r a t i o n : 33.14 Weight Per G a l l o n : 10.29 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.09 ( G r a m s / L i t e r ) : 250 Water:Cosolvent Weight R a t i o : 85.34:14.66 pH: 8.80 V i s c o s i t y #4 F o r d Cup (Seconds): 45 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r Dry Substrate: Cold Rolled Steel G l o s s ( 6 0 ) : 29 P e n c i l Hardness: Pass B % C r o s s h a t c h Adhesion: 100 Impact ( i n . L b s . ) : D i r e c t : 20 Reverse: (5

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P1887-32-1

Enamels

Semi a1oss Enamel Inaredients: Pigment G r i n d : Water C e l l o s i z e H y d o x y e t h y l C e l l u l o s e ER- 15M Preservative (1) Dispersant ( 2 ) T r i t o n N o n i o n i c S u r f a c t a n t N-57 2-Ami no-2-methyl-1-propanol (3) P r o p y l e n e G1y c o l Antifoam (4) T i t a n i um D i o x i d e ( 5 )

Pounds

Gallons

268.2 2.0 2.4 9.2 2.1 1. o 43.2 1. o 250.0

32.20 0.18 0.25 1 .oo 0.25 0.13 5.00 0.13 7.27

29.9 428.4 20.0 1.9 0.5

3.48 47.28 2.52 0.25 0.06

Letdown : UCAR T h i c k e n e r SCT-275, p r e m i x ( a ) Ucar L a t e x 379 Ucar F i l m e r IBT Antifoam (4) T r i t o n A n i o n i c S u r f a c t a n t GR-7M

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 145 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t ( 3 ) 2-Ami no-2-methyl -1-propanol - AMP-95 o r e q u i v a l e n t ( 4 ) A n t i f o a m - "Byk" 035 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t ( a ) Premix c o n s i s t s o f 1 : l : l T h i c k e n e r SCT-275:water.

b l e n d o f p r o p y l e n e glyco1:UCAR

Comparative P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: S o l i d s , %: by Volume: 31.8 b y Weight: 46.0 Weight p e r G a l l o n , l b : 10.60

23.0

Paint Properties: Viscosity, i n i t i a l : Stormer, KU: 82 I C I , poise: 0.4 pH, i n i t i a l : 8 . 5 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Film Properties: C o n t r a s t R a t i o , 6 - m i l b a r : 0.967 Ref 1e c t a n c e , %: 8 9 . 5 Gloss, 60: Drawdown, 6-mi 1 b a r : 59 Flow and L e v e l i n g : Brushed: Very Good Drawdown, NYPC Blade:

SOURCE:

8

Ucar Emulsion Systems: UCAR L a t e x 379: F o r m u l a t i o n S u g g e s t i o n 1-1989

129

130

Water-Based Paint Formulations

S e m i a l o s s M a i n t e n a n c e Enamel-White A s e m i g l o s s maintenance enamel w i t h a n t i - c o r r o s i v e

Inaredients: Piement G r i n d : Water D i spersant (1 ) 2-Amino-2-methyl-1-propanol Antifoam (3) Nonionic Surfactant (4) Nonionic Surfactant (5) Titanium Dioxide (6) A n t i - c o r r o s i v e Pigment ( 7 )

(2)

pigment.

Pounds

Gallons

79.9 3.4 3.0 2.1 2.1 7.1 200.0 25.0

9.59 0.37 0.37 0.25 0.25 0.75 5.85 1.oo

2.1 34.6 20.8

0.25 4.00 2.62

5.4 5.0 39.6

0.62 0.62 5.00

1 .o 4.2 590.7

0.06 0.50 67.90

L e t Down: Antifoam (3) Propylene Glycol Butyl C a r b i t o l Solvent Mix: Ucar T h i c k e n e r SCT-275 Butyl C a r b i t o l Solvent Ucar F i l m e r I B T Mix: Sodium N i t r i t e Water Ucar L a t e x 430 (43.0%)

Suppl ie r s : ( 1 ) D i s p e r s a n t - " B o r c h i g e n " ND o r e q u i v a l e n t ( 2 ) 2-Amino-2-methyl-1-propanol - AMP-95 o r e q u i v a l e n t ( 3 ) A n t i f o a m - "Foamex" 1488 o r e q u i v a l e n t (4) Nonionic Surfactant - "Surfynol" lOXE o r equivalent ( 5 ) N o n i o n i c S u r f a c t a n t - " B o r c h i g e n " DFN o r e q u i v a l e n t ( 6 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t ( 7 ) A n t i - c o r r o s i v e Pigment - " M o l y - w h i t e " MZAP o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), T o t a l S o l i d s , %: b y Volume: 3 4 . 8 b y W e i g h t : 48.3 Viscosity (equilibrated): S t o r m e r , KU: 88 I C I , Poise: 0 . 5 pH1 i n i t i a l : 9 . 3 Weight p e r G a l l o n , l b : 1 0 . 2 6 VOC, g / l : 249.2

%:

19.7

Film Properties: C o n t r o l R a t i o , 0.003 i n : 0.966 R e f l e c t a n c e , %: 9 1 . 5 G l o s s , 60: 38.1 SOURCE: Ucar E m u l s i o n Systems: UCAR L a t e x 430:

Suggestion M-2204

Formulation

Enamels

131

Semi g l o s s W h i t e Enamel Pounds

Gal 1ons

Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-15M Preservative (1) Dispersant (2) T r i t o n N o n i o n i c S u r f a c t a n t N-57 (3) 2-Amino-2-methyl-1-propanol P r o p y l e n e G1y c o l Antifoam (4) T i t a n i u m D i o x i d e (5)

268.2 2.0 2.3 9.2 2.1 1. o 43.2 0.9 250.0

32.20 0.18 0.25 1 .oo 0.25 0.13 5.00 0.13 7.27

Letdown : Butyl C a r b i t o l Solvent Thickener, premix ( a ) Ucar L a t e x 367 Ucar F i l m e r I B T Antifoam ( 4 ) T r i t o n A n i o n i c S u r f a c t a n t GR-7M

15.8 21.5 428.4 11.9 1.8 0.6

2.00 2.50 47.28 1.50 0.25 0.06

I n a r e d ie n t s :

P i gment G r i nd

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t ( 3 ) 2-Ami no-2-methyl -1 - p r o p a n o l - AMP-95 o r e q u i v a l e n t ( 4 ) A n t i f o a m - "BYK" 035 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-800 o r e q u i v a l e n t ( a ) Premix c o n s i s t s o f 1 : l : l b l e n d o f p r o p y l e n e glyco1:Rohm and Haas' " A c r y s o l SCT-275" T h i c k e n e r : w a t e r , r e s p e c t i v e l y . Paint Properties: Pigment Volume C o n c e n t r a t i o n ( P V C ) , %: 23.0 S o l i d s , %: b y Volume: 31.6 by Weight: 46.8 Viscosity ( i n i t i a l ) : Stormer, KU: 85 I C I , poise: 1.0 pH ( i n i t i a l ) : 8.1 Weight p e r G a l l o n , l b . : 10.59 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass ( + 2 KU) Heat S t a b i l i t y , 2 weeks a t 120F: Pass ( + 5 KU) Film Properties: C o n t r a s t R a t i o , 3 m i l f i l m : 0.968 Ref 1e c t a n c e , %: 9 2 . 6 Gloss, 60: Drawdown: 61.0 B r u s h o u t : 67.0 Flow and L e v e l i n g , Brushed: Very Good

SOURCE:

Ucar Emulsion Systems: UCAR L a t e x 387/UCAR L a t e x 378: F o r m u l a t i o n S u g g e s t i o n 1-2219

132

Water-Based Paint Formulations

Semi g l o s s W h i t e T r i m Enamel Inqredients: Pigment G r i n d : Water Phenyl M e r c u r i c A c e t a t e , 100% Cel l o s i ze H y d r o x y e t h y l C e l l u l o s e QP-4400 Dispersant ( 1 ) Nonionic Surfactant (2) P r o p y l e n e G1 y c o l Antifoam (3) Titanium Dioxide (4) L e t Down: Ucar A c r y l i c 525 Ucar F i l m e r IBT Antifoam (3) Anionic Surfactant (5) Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gal l o n s

246.0 1.o 3.5 9.7 2.0 51.8 0.9 250.0

29.51 0.05 0.32 1 .oo 0.25 6.00 0.13 7.26

471.9 17.8 1.9 1.1 3.0

52.43 2.25 0.25 0.13 0.42

su001 ie r s : ( 1 j ' D i s p e r s a n t - "Pol ywet" ND-2 o r equi Val e n t ( 2 ) N o n i o n i c S u r f a c t a n t - " I g e p a l " CO-630 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 681-F o r e q u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - "Zopaque" RCL-9 o r e q u i v a l e n t (5) A n i o n i c S u r f a c t a n t - " T r i t o n " GR-7M o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 22.0 T o t a l S o l i d s , %: by Volume: 33.0 by Weight: 48.5 V i s c o s i t y , in i t i a1 : Stormer, KU: 90-95 I C I , poise: 1.1 pH, i n i t i a l : 9.4 Weight p e r G a l l o n , l b : 10.61 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 wk a t 120F: Pass F i 1m P r o p e r t y : G l o s s , 60: 45-50 SOURCE: Ucer Emulsion Systems: S u g g e s t i o n E-2077

UCAR A c r y l i c 525:

Formulation

Enameks

S t e e l B l u e G l o s s Enamel M a t e r i a1 : Kel s o l 3907-G2B-75 Ammoni um H y d r o x i d e n-Butanol Butoxy Ethanol Monarch B l u e X3367 Raven 1020 Ye1 1ow I r o n Oxi de 22881) T i - P u r e R-902 Water S t e e l b a l l m i l l t o 7 Hegman g r i n d . Letdown : K e l s o l 3907-G28-75 n-Butanol Ammoni um H y d r o x i d e Water Premix : A c t i v-8 C o b a l t Hydrocure I 1 Butoxy Ethanol

Lbs. 45.71 2.32 3.85 3.83 4.50 3.21 2.35 40.01 76.22

Gals. 5.34 0.31 0.57 0.51 0.34 0.22 0.07 1 .17 9.15

254.30 13.97 7.62 403.34

29.71 2.07 1.02 48.42

1.28 6.35 0.75

0.16 0.84 0.10

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 6.62 P i gment/Bi n d e r R a t i o : . 2 2 / 1 P e r c e n t S o l i d s , W e i g h t : 32.91 P e r c e n t S o l i d s , Volume: 27.17 V i s c o s i t y @ 25C. #4 Ford, S e c s . : 35-40 Pounds/Gallon: 8 . 7 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 294 Pounds/Gallon: 2.45

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i on 2103-71

I n c . : Waterborne Handbook:

133

134

Water-Based Paint Formulations

T i n t a b l e E q q s h e l l Enamel

lbs/100 s a l Premix on K a d y z o l v e r a t 2,000 rpm f o r 10 min: Propylene g l y c o l 51.8 Water 50.0 Thickener 1.5 Tamol 731 (25%) 7.0 Nopco NDW 2.0 Add and g r i n d a t 2,000 T i -Pure R-902 I m s i l A-25

rpm f o r 20 min:

L e t down ( l o w speed on an a i r s t i r r e r ) : Water Nopco NDW 100% a c r y l i c l a t e x , 46.5% Texanol 1 P r o p y l e n e g l y c o l ) premi x Water 1 D o w i c i l 75 ) premix T r i t o n N-57 T r i t o n X-114 T r i t o n X-207 Thickener (2.5% s o l u t i o n )

250.0 75.0

299.5 89.8

83.0 4.0 450.0 12.6 17.3 24.9 1.3 4.0 4.0 2.0 60.1

99.4 4.8 539.1 15.1 20.7 29.8 1.6 4.8 4.8 2.4 72.0

T i n t w i t h C a l / I n k 8800 s e r i e s c o l o r a n t s a t 4 o z / g a l Physical Properties: PVC, %: 33.2 Volume s o l i d s , %: 3 2 . 3 Weight s o l i d s , %: 48.50 D e n s i t y , l b s / g a l ( k g / l ) : 11.00 ( 1 . 3 2 ) I n i t i a l pH: 8 . 2 - 8 . 5 Stormer v i s c o s i t y ( o v e r n i g h t ) , KU: 92-96

SOURCE: Aqualon Co.:

sL1 62.1 59.9 1.8 8.4 2.4

NATROSOL B: Formula T a b l e I V

EnameLF

V e l v e t L a t e x Enamel m t i w h i t e / B u r a e s s No. 98 Approach Water KTPP N a t r o s o l 250 MBR N a l c o #2300 Tamol 1254 T r i t o n X-100 AMP-95 P r o t e l GXL R-900 Optiwhi t e Burgess No. 98 Ethylene Glycol Ucar 367 Ucar 522 Texanol Foamaster G Eva1 u a t ion R e s u l t s : H i d i n g 3 M i l B i r d B l a d e on O p a c i t y P a n e l : Ref 1e c t a n c e : .908 C o n t r a s t R a t i o : .974 T i n t S t r e n g t h . 5 Blue/200 grams: R e f l e c t a n c e : .702 Sheen : 85: 1 9 . 4 60: 3 . 6 V i s c o s i t y KU: 95

SOURCE:

Burgess Pigment Co. : Formula 71 OPT/98

Lbs./100 G a l . 398 1 .oo 6.50 1 .oo 3.28 2.00 3.00 1 .oo 200 75 75 28 205 109 15.84 7.60

135

136

Water-Based Paint Formulations

Waterborne P o l y e s t e r Enamel I n a r e d ie n t s : WS-17-1T P o l y e s t e r , 75% s o l i d s Cyme1 303 melamine r e s i n N, N-Dimethylami n o e t h a n o l (DMEA) p-To1 uenesul f o n i c a c i d , 40% in isopropanol F l u o r a d FC-430, 20% i n w a t e r Demi n e r a l ized w a t e r Enamel P r o p e r t i e s : pH: 8.42 V i s c o s i t y , cP: 810 T h e o r e t i c a l s o l i d s , %:

Weight 33.42 8.33 2.33 0.25 0.25 55.42

31.3

Coatings P r o p e r t i e s - I n i t i a l : S u b s t r a t e : 20 gauge CRS w i t h B o n d e r i t e 37 Cure: 30 m i n u t e s a t 177C (350F) P e n c i l hardness, c u t / s c r a t c h : 3-4H/H D i r e c t / r e v e r s e impact r e s i s t a n c e , i n . - l b : 160/160 MEK d o u b l e r u b s : 200+ 5 M i n u t e I 2 s t a i n t e s t : No s t a i n 500 Hours s a l t spray--mm creepage f r o m s c r i b e : 1 H u m i d i t y r e s i s t a n c e - - 9 6 h o u r s a t 60C (140F): No b l C o a t i n g s P r o p e r t i e s - A f t e r A g i n g S o l u t i o n 4 wks a t 49C S u b s t r a t e : 20 gauge CRS w i t h B o n d e r i t e 37 Cure: 30 m i n u t e s a t 177F (350F)

ers

20F) :

P e n c i l hardness, c u t / s c r a t c h : 4H/H D i r e c t / r e v e r s e impact r e s i s t a n c e , i n . - l b : 160/160 MEK d o u b l e r u b s : 200+ 5 M i n u t e I 2 s t a i n t e s t : No s t a i n 500 Hours s a l t spray--mm creepage f r o m s c r i b e : 1 H u m i d i t y r e s i s t a n c e - - 9 6 h o u r s a t 60C (140F): No b l i s t e r s

SOURCE:

Eastman Chemical P r o d u c t s , I n c . : f r o m P o l y e s t e r R e s i n WS-17-1T

Enamel Prepared

Waterborne P o l v e s t e r / M e l a m i n e Enamel C1 e a r Enamel Comoosi t i on Inqredients: P r e d i s p e r s i on: WB-17-1NS P o l y e s t e r R e s i n ( n e a t ) I s o p r o p y l A1 coho1 D i s t i l l e d Water Cyme1 303 o r Resimene 745 Melamine R e s i n D i s t i 1 l e d Water

Wei q h t 100.0 20.0 20.0 42.9 136.0

Enamel P r e p a r a t i o n : Enamels can be c o n v e n i e n t l y p r e p a r e d b y w e i g h i n g t h e p r e d i s p e r s i o n i n t o a s u i t a b l e s t i r r e d v e s s e l and h e a t i n g t o a temperaa t u r e s l i g h t l y b e l o w r e f l u x ( a p p r o x i m a t e l y 70-8OC). B e g i n b y adding h o t d i s t i l l e d water s l o w l y t o reduce t h e p e r c e n t s o l i d s t o 50% i f i t i s n o t a l r e a d y a t t h a t l e v e l . Reduce t h e h e a t t o a p p r o x i m a t e l y 60C and add t h e melamine r e s i n . A g i t a t e t h e m i x t u r e w e l l and add t h e r e m a i n d e r o f t h e warm d i s t i l l e d w a t e r . These n o n a l k a l i n e d i s p e r s i o n s can have s h e l f s t a b i l i t y i n excess o f one y e a r . Enamel P r o p e r t i e s : P o l y e s t e r / M e l a m i ne: 70/30 D e n s i t y , l b / g a l ( g / L ) : 8 . 8 1 (1057) C a l c u l a t e d N o n v o l a t i l e s , w t %: 44.2 C a l c u l a t e d VOC, w t VOC/vol c o a t i n g : 1 . 6 (192) (minus H20), l b / g a l ( g / L ) V i s c o s i t y b y No. 4 F o r d Cup, sec: 11 Coating Properties: F i l m T h i c k n e s s , m i l s (um): 0 . 8 - 1 . 0 (20-25) P e n c i l Hardness, m a r / c u t : F/H Impact Resistance: D i r e c t , i n . / l b : 160 Reverse, i n . / l b : 150 MEK D o u b l e - r u b S o l v e n t R e s i s t a n c e : >250 1 / 8 - i n . C o n i c a l Mandrel F l e x i b i l i t y , % pass: 100 C l e v e l a n d H u m i d i t y , 100 h a t 60C ( 1 4 0 F ) : % G l o s s R e t e n t i o n a t 20: 88 B1 is t e r i ng: None S t a i n R e s i s t a n c e ( w a t e r / a c e t o n e r i n s e , 5=nO s t a i n ) : 5 min: 4 30 min: 3 G l o s s , %: a t 20: 80 a t 60: 99 a) On 20-gauge, c o l d - r o l l e d , B o n d e r i t e 37 p r e t r e a t e d s t e e l baked 30 m i n u t e s a t 150C ( 3 0 2 F ) . SOURCE: Eastman Chemical Co.: WB- 17- INS

Waterborne P o l y e s t e r R e s i n

138

Water -Based Paint Formulations

W a a r R e d u c i b l e A c r v l i c Enamel-IIB K-FLEX UD-320W Modi f.W T h i s f o r m u l a t i o n demonstrates s e v e r a l advantages when m o d i f y i n g a w a t e r r e d u c i b l e a c r y l i c system w i t h K-FLEX UD-320W. The advantages i n c l u d e l o w e r VOC, h a r d e r f i l m s and improved s a l t s p r a y , h u m i d i t y and QUV r e s i s t a n c e . P r o p e r t i e s g e n e r a l l y improved as t h e l e v e l of UD-320W was i n c r e a s e d . Pebble M i l l G r i n d : T i t a n o x 2020 A c r y s o l WS-68 K-F1 ex UD-320W Water Butyl Cellosolve n-Butanol DMEA Letdown : Grind: A c r y s o l WS-68 Water n-Butanol Dow C o r n i n g #57 (30% i n B u t y l C e l l o s o l v e ) DMEA (10% i n Water) Cyme1 303 K-F1 ex UD-320W

480.00 63.12 26.64 144.44 43.76 40.64 1.40

1073.60 282.24 16.88 4.64 9.36 216.00 80.00

Enamel C h a r a c t e r i s t i c s : A c r y l i c / K - F l e x / M e l a m i n e : 60/10/30 T o t a l S o l i d s , %: 48.3 T o t a l R e s i n S o l i d s , %: 29.0 P i gment/Binder: 40/60 VOC, c a l c . ( l b s / g a l ) : 0.50 pH: 7.27 V i s c o s i t y , 25C, c p s : 89 Film Properties: S u b s t r a t e : B o n d e r i t e 1000 ( I r o n Phosphated CRS) Cure: 30 min/250F (121C) C a t a l y s t : 1.6% Nacure X49-110 ( o n TRS) F i l m T h i c k n e s s : 0 . 9 m i l DFT A c r y l i c / K - F l e x / M e l a m i n e : 60/10/30 Penci 1 Hardness: F-H Knoop Hardness: 6 . 4 MEK Rubs: 80 I m p a c t , Rev., i n / l b : 5-10 , D i r . , i n / l b : 40-50 C r o s s h a t c h Adhesion, %: 100 I n i t i a l Gloss, 60: 8 9 . 6 , 20: 72.1 SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-4-11-B

Enamels

Water R e d u c i b l e A c r y l i c Enamel - 1 1 - C - I 1 P e b b l e M i l l Grind: T i t a n o x 2020 A c r y s o l WS-68 K-Fl ex UD-320W Water B u t y l C e l l os01ve n-Butanol DMEA

480.00 63.12 26.64 144.44 43.76 40.64 1.40

Letdown : Grind: A c r y s o l WS-68 Water n-Butanol Dow C o r n i n g #57 (30% i n B u t y l CellOSOlVe) DMEA (10% i n Water) Cyme1 303 K - F l e x UD-320W

789.44 452.72 16.88 4.64 7.04 252.00 160.00

Enamel C h a r a c t e r i s t i c s : A c r y l ic/K-Flex/Mel ami ne: 45/20/35 T o t a l S o l i d s , %: 4 8 . 3 T o t a l R e s i n S o l i d s , %: 29.0 P i gment/Bi n d e r : 40/60 VOC, c a l c . ( l b s / g a l ) : 0.60 pn: 7.28 V i s c o s i t y , 25C., c p s : 35 F i 1m Propert% S u b s t r a t e : B o n d e r i t e 1000 ( I r o n Phosphated CRS) Cure: 30 min/250F (121C) C a t a l y s t : 1 . 6 % Nacure X49-110 ( o n TRS) F i l m T h i c k n e s s : 0 . 9 m i l DFT A c r y l i c / K - F l e x / M e l a m i ne: 45/20/35 Penci 1 Hardness: H-2H Knoop Hardness: 7 . 0 MEK Rubs: 100 I m p a c t , Rev., i n / l b : 5-10 , D i r . , i n / l b : 30-40 C r o s s h a t c h Adhesion, %: 100 I n i t i a l Gloss, 60: 87.0 , 20: 7 8 . 9 S a l t Spray, 126 h r s mm C r e e p a g e / B l i s t e r : 7-9/NA H u m i d i t y , 60C, 250 h r s : G l o s s , 60: 1 1 . 4 , 20: 2 . 4 B1 is t e r : Med-Den/Mi c QUV**, 250 h r s : G l o s s , 60: 78.9 , 20: 4 2 . 7 QUV s c h e d u l e o f 8 h o u r s UV a t 50C., 4 h o u r s h u m i d i t y a t 40C.

**

SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-4-11-C-I1

139

140

Water-Bused Paint Formufations

Water R e d u c i b l e A i r D r y G l o s s W h i t e Enamel Pounds 106.81 2.94 2.11 8.46 8.44 84.56 146.71

Ingredients: Chempol 10-01 73 Byk P-104s S u r f y n o l 704BC 2-Butoxyethanol Ammoni um h y d r o x i de (28%) Water T i -Pure R - 9 0 0

Gal l o n s 12.33 0.37 0.28 1.12 1.13 10.15 4.27

Weigh i n f i r s t f o u r i n g r e d i e n t s and m i x w e l l . Add ammonia and water s e p a r a t e l y w i t h a g i t a t i o n . Add p i g m e n t s l o w l y w i t h c o n t i n u e d a g i t a t i o n . S a n d m i l l t o #7 Hegman k e e p i n g g r i n d t e m p e r a t u r e below 120F w i t h water j a c k e t . L e t down w i t h : 149.17 12.67 11.04 7.17 0.42 333.52 73.97

Chempol 10-01 73 Ammonium h y d r o x i d e (28%) 2-Butoxyethanol Nuocure CK-10 Byk 301 Water Water ( H o l d t o a d j u s t v i s c o s i t y )

17.22 1.70 1.58

0.88 0.05 40.04 8.88

I n t h e " l e t down", p r e - b l e n d r e s i n and ammonium h y d r o x i d e w i t h a g i t a t i o n . Premix t h e 2 - b u t o x y e t h a n o l , Nuocure CK-10, and Byk 301 and add t h i s p r e m i x t o t h e resin/ammonia m i x t u r e s l o w l y w i t h good a g i t a t i o n . S l o w l y add t h e f i r s t amount o f w a t e r and m i x w e l l . Now add t h e " l e t down" p o r t i o n to t h e g r i n d w i t h good a g i t a t i o n . M i x w e l l and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonium h y d r o x i d e i f n e c e s s a r y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % by w e i g h t : 35.06 T o t a l s o l i d s , % b y volume: 23.77 Weight/gallon, l b s . : 9.49 PVC: 17.97 P i gment/bi n d e r w e i g h t r a t i 0 : 0 . 7 9 / 1 00 VOC, l e s s w a t e r : 2.79 l b s / g a l . V i s c o s i t y #2 Zahn: 30"-50" pH: 8 . 0 - 8 . 5 DFT: 0 . 9 - 1 . 0 m i l s Cure: 1 week a i r d r y G l o s s , 60: 91 20: 76 P e n c i l hardness: B C r o s s h a t c h a d h e s i o n : 100% r e t e n t i o n , t a p e d

.

SOURCE:

Freeman Polymers D i v i s i on : CHEMPOL 10-01 73-A

Formul a

Enamels

Water R e d u c i b l e ,

141

Low G l o s s B l a c k Enamel

10-0091-E i s a w a t e r r e d u c i b l e , a i r d r y enamel, based on CHEMPOL 10-0091 a l k y d r e s i n . I t was e s p e c i a l l y f o r m u l a t e d f o r d i p , f l o w o r spray a p p l i c a t i o n over h i g h p r o f i l e , p o o r l y t r e a t e d s t e e l s u b s t r a t e . 10-0091-E w i l l p r o v i d e maximum c o r r o s i o n r e s i s t a n c e by p r o v i d i n g a h i g h - b u i l d f i l m designed t o b r i d g e o v e r i r r e g u l a r s u r f a c e s . F i l m s o f 10-0091-E d r y q u i c k l y (15-30 m i n u t e s ) and "tie-down'' f o r maximum p r o t e c t i o n o f m e t a l s u b s t r a t e . F i l m s exposed t o s a l t s p r a y show no l o s s o f adhesion a f t e r 1 hour r e c o v e r y .

I n a r e d ie n t s : Chempol 10-0091 Ammonium h y d r o x i d e (28% NH3 min) DMAMP- 8 0 E k t a s o l v e EP A n t i - S a g WR 300 Carbon 81 a c k - S t e r l ing R S t r o n t i u m Chromate B a r m i t e XF Durami t e Atomi t e S u r f y n o l PC Bentone 27 ) Premix Methyl a l c o h o l ) MPA 1075 ) Premix Butyl Cellosolve) Propasol P Butyl Cellosolve Bykumen 50% G i 1s o n i t e i n Xylene

Pounds 133.67 6.84 6.56 50.55 3.15 15.18 9.61 137.83 67.95 67.95 2.48 10.37 6.90 30.15 10.14 33.71 15.62 3.07 42.83

Gal l o n s 15.19 0.94 0.83 6.66 0.42 1.04 0.31 3.85 3.02 3.02 0.31 0.73 1.04 4.37 1.35 4.58 2.08 0.42 5.20

Combine CHEMPOL 10-0091, ammonium h y d r o x i d e , DMAMP-80, and E k t a s o l v e EP. M i x i n A n t i - S a g WR 300 and t h e n add p i g m e n t s . Add t h e r e m a i n i n g i n g r e d i e n t s and mix we1 1 . G r i n d i n a s t e e l b a l l m i l l t o a 6 Hegman. L e t Down W i t h : Chempol 10-0091 117.22 13.32 1 .62 0.21 5% C o b a l t Hydrocure I 1 5% C a l c i u m Hydrochem 3.39 0.42 5% Manganese Hydrochem 1.58 0.21 E x k i n #2 3.98 0.52 Water 159.52 19.15 Texanol 20.57 2.60 Ammonium h y d r o x i d e (28% NH3 m i n ) 2.26 0.31 S y l o i d 74x3500 10.35 0.62 N e o c r y l A-640 62.61 7.28 Mix " L e t Down" i n g r e d i e n t s i n o r d e r l i s t e d . Add t h e S y l o i d 74x3500 under a g i t a t i o n , t h e n add N e o c r y l A-640 s l o w l y w h i l e c o n t i n u i n g a g i t a t i o n . A d j u s t t o a f i n a l pH o f 8 . 0 - 8 . 5 w i t h ammoni um h y d r o x i de.

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 10-0091-E

Formulation

142

Water-Based Paint Formulations

Water-Reducible

P o l y e s t e r Enamel A

Grind ( a t t r i t o r l P i gment (R-900 T i 0 2 ) Resin WS-3-1C (76.5% N . V . ) D i m e t h y l e t h a n o l ami ne Hexamethoxymethyl melami ne Cyzac 4040 c a t a l y s t Flow c o n t o l agent (L-5310, 10% i n n - b u t a n o l )

Weight % 20.57 23.00 1.53 7.54 0.12 0.24

L e t Down: D i s t i l l e d Water

47.00

P h y s i c a l Constants: V i s c o s i t y , #4 F o r d Cup, sec: 27 pH: 8 . 2 N o n v o l a t i l e , w t %: 45.7 P o l y e s t e r / C r o s s l i n k e r , w t %: 70/30 P i gment/Bi n d e r , w t %: 45/55 W a t e r / O r g a n i c , w t %: 87/13 Cure c y c l e : 350F (177C) Physical Properties: F i l m t h i c k n e s s : 1 .O-1 . 5 m i l G l o s s , 60/20: 93/79 P e n c i l hardness: 4H C o n i c a l mandrel f l e x i b i l i t y , 1 / 8 i n . , ASTM D-522, % Pass: 100 Impact r e s i s t a n c e , D i r e c t , i n . - l b (cm-kg): >160 (>185) Reverse, i n . - l b (cm-kg): 140 (162) S o l v e n t r e s i s t a n c e , Double MEK Rubs: 200+ C r o s s h a t c h adhesion, % Pass: 100 S t a i n r e s i s t a n c e , 24 h r a t room temp ( b ) : Tomato j u i c e : 10 B l a c k shoe p o l i s h : 10 Mustard: 9 Iodine (5 minutes): 7 Detergent r e s i s t a n c e ( c ) : 1-1/2% AATCC S o l u t i o n a t 165+-2F: B l i s t e r i n g : 240 h r : Very Few #8 500 h r : ---% Gloss R e t e n t i o n , 60/20: 240 h r : 100/87 500 h r :

------

( b ) V i s u a l l y r a t e d u s i n g t h e f o l l o w i n g s c a l e : 10=No s t a i n , 8 = S l i g h t , 6=Moderate, 4 = C o n s i d e r a b l e . NOTE: S u b s t r a t e used was c o l d - r o l l e d s t e e l p a n e l t r e a t e d w i t h z i nc phosphate. ( c ) Epoxy primed, z i n c phosphate t r e a t e d , c o l d - r o l l e d s t e e l p a n e l s were used i n t h i s e v a l u a t i o n .

SOURCE:

Eastman Chemical P r o d u c t s ,

I n c . : Enamels Prepared

f r o m P o l y e s t e r R e s i n WS-3-1C

Enamels

Water-Reduci b l e P o l y e s t e r Enamel Grind ( a t t r i t o r ) : P i gment (R-900 T i 0 2 ) R e s i n WS-3-1C ( 7 6 . 5 % N.V.) D i m e t h y l e t h a n o l ami ne Benzoguanamine (85% N . V . ) Cyzac 4040 c a t a l y s t Flow c o n t r o l agent (L-5310,

10% i n n - b u t a n o l )

143

B Weiqht % 19.17 21.43 1.43 8.27 0.12 0.24

L e t Down : D i s t i11ed Water

49.34

Physical Constants: V i s c o s i t y , #4 F o r d Cup, sec: 30 pH: 8 . 4 N o n v o l a t i l e , w t %: 42.6 P o l y e s t e r / C r o s s l i n k e r , w t %: 70/30 P i gment/Bi n d e r , w t %: 45/55 Water/Organic, w t %: 86/14 Cure c y c l e : 350F (177C) f o r 30 m i n u t e s P h y s i c a l P r o p e r t i es : F i l m t h i c k n e s s : 1.0-1.5 m i l G l o s s , 60/20: 92/78 P e n c i l h a r d n e s s : 4H C o n i c a l mandrel f l e x i b i l i t y , 1 / 8 i n . , ASTM D-552, % Pass: 100 I m p a c t r e s i s t a n c e , D i r e c t , i n . - l b (cm-kg): 140 ( 1 6 2 ) Reverse, i n . - l b (cm-kg): 80 ( 9 2 ) S o l v e n t r e s i s t a n c e , Double M E K Rubs: 200+ C r o s s h a t c h a d h e s i o n , % Pass: 100 S t a i n r e s i s t a n c e , 24 h r a t room temp ( b ) : Tomato j u i c e : 10 B l a c k shoe p o l i s h : 10 Mustard: 9 I o d i n e ( 5 minutes) : 7 Detergent r e s i s t a n c e ( c ) : 1-1/2% AATCC S o l u t i o n a t 1 6 5 t - 2 F : B l i s t e r i n g : 240 h r : None 500 h r : Very Few #8 % G l o s s R e t e n t i o n , 60/20: 240 h r : l 0 0 / 8 9 500 h r : 92/72 b ) V i s u a l l y r a t e d u s i n g t h e f o l l o w i n g s c a l e : 10= No s t a i n , 8 = S l i g h t , 6=Moderate, 4 = C o n s i d e r a b l e . NOTE: S u b s t r a t e used was c o l d - r o l l e d s t e e l p a n e l s t r e a t e d w i t h z i n c phosphate. c ) Epoxy p r i m e d , z i n c phosphate t r e a t e d , c o l d - r o l l e d s t e e l p a n e l s were used i n t h i s e v a l u a t i o n .

SOURCE:

Eastman Chemical P r o d u c t s , P o l y e s t e r R e s i n WS-3-1C

I n c . : Enamel P r e p a r e d f r o m

144

Water-Based Paint Formulations

Water R e d u c i b l e W h i t e Enamel F o r m u l a t i o n 10-1706-A i s a w a t e r r e d u c i b l e , t h e r m o s e t t i n g , a c r y l i c enamel w h i c h p r o v i d e s good adhesion t o b o t h m e t a l l i c and n o n m e t a l l i c s u b s t r a t e s . Ingredients: Chempol 10-1 706 D i m e t h y l ethanolami ne N a l c o 2309 Bykumen E k t a s o l v e EP Water T i t a n i u m D i o x i d e (R-900) G r i n d Pebble M i l l 7 1 / 2 Add f o r s t a b i l i t y :

-

Pounds 49.28 5.10 4.31 4.33 23.16 53.16 183.48

Gal 1ons 5.60 0.69 0.59 0.59 2.95 6.39 5.51

49.28 5.10

5.60 0.69

98.65 45.53 9.46 1.53 42.47 406.60

11.21 4.42 1.28 0.20 5.41 48.87

8 Hegman gauge.

Chempol 10-1 706 Dimethylethanolamine L e t down w i t h : Chempol 10-1706 Cyme1 385 Dimethylethanolamine E x k i n No. 2 E k t a s o l v e EP Water Properties: T o t a l s o l i d s , % b y w e i g h t : 38 T o t a l s o l i d s , % b y volume: 25 V i s c o s i t y , #2 Zahn cup, seconds: 35 P i g m e n t / b i n d e r w e i g h t r a t i o : 1.0/1 .O PVC, %: 21.6 Weight/gallon, l b s . : 9.8 VOC, l b s . / g a l . , l e s s water: 3.2

Performance Notes: Drawndown 3 m i l s wet on B o n d e r i t e 1000 c u r e d a t 15'/325F: Dry f i l m t h i c k n e s s , m i l s : 0.8 60 G l o s s : 83 P e n c i l hardness: >4H C r o s s h a t c h adhesion: 100 MEK r e s i s t a n c e : 100 Forward i m p a c t : 20 Reverse i m p a c t : t 2 0 SOURCE: Freeman Polymers D i v i s i on : CHEMPOL 10-1 706-A Formul a t 1 on

Enamels

145

W h i t e A c r v l i c B a k i n g Enamel Pounds .~

I n q r e d ie n t s : Cyme1 303 Coroc A - 2 6 7 8 4 Butyl Cellosolve N a l c o 2309 D e i o n i zed w a t e r S u r f y n o l 104BC T i P u r e R700

43.90 43.90 32.93 1.10 131.71 0.88 219.51

Pebble g r i n d t o Hegman 7-1/2+, ing pre-mi xed: Chempol 20-4301 D e i o n i z e d Water

Gal 1ons 4.39 4.99 4.38 0.15 15.83 0.12 6.80

t h e n l e t down w i t h t h e f o l l o w -

M i x t h o r o u g h l y and c o n t i n u e l e t down w i t h : Cycat 4040 D i m e t h y l e t h a n o l ami ne Dei o n i zed w a t e r A d j u s t t o d e s i r e d v i s c o s i t y u s i n g DMEA.

426.95 75.73

48.52 9.10

2.20 0.88 44.34

0.27 0.12 5.33

P r o p e r t ies : T o t a l s o l i d s , % by w e i g h t : 43.00 T o t a l s o l i d s , % b y volume: 29.40 P/B w e i g h t r a t i o : 1 . 1 1 % PVC: 23.1 VOC; l b s / g a l l o n l e s s H20 ( t h e o r y ) : 1 . 2 8 I n i t i a l V i s c o s i t y #4 F o r d Cup, secs: 16-17 pH: 7 . 6 A d j u s t e d v i s c o s i t y , #4 F o r d Cup, s e c s : 45 (pH=8.2) F i l m P r o p e r t i e s : Spray a p p l i e d o v e r B l O O O t r e a t e d CRS: Suggested bake s c h e d u l e : 20 mins/325F D r y f i l m t h i c k n e s s , m i l s : 1.0-1.2 60/20 g l o s s : 80/40 P e n c i l h a r d n e s s : 3H MEK d o u b l e r u b s , 100: no e f f e c t 100% no t a p e o f f C r o s s h a t c h a d h e s i o n : Exc. Reverse i m p a c t , i n c h - l b s . : t 5 D i r e c t i m p a c t , i n c h - l b s . : 2 0 , s l . c r a c k i n g b u t no t a p e o f f l / 8 " c o n i c a l m a n d r e l : 12 mm c r a c k - no a d h e s i o n l o s s

-

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 20-4301-6

Formulation

146

Water-Based Paint Formulations

W h i t e A c r y l i c Emulsion Enamel Ingredients : Coroc A-2678-M 2-butoxyethanol S u r f y n o l 104BC S u r f y n o l DF-75 Water T i -Pure R-900

Pounds 21.70 7.30 7.62 1.25 28.67 152.49

Gal l o n s 2.47 0.97 1.01 0.15 3.44 4.44

Pre-mi x f ir s t f o u r i n g r e d i e n t s , t h e n add w a t e r w i t h a g i ta t i o n . Add pigment s l o w l y w i t h a g i t a t i o n . Cowles t o a #7 Hegman w i t h a h i g h speed d i s p e r s a t o r . A d j u s t g r i n d v i s c o s i t y w i t h w a t e r f r o m below i f n e c e s s a r y . L e t down w i t h : Chempol 20-4301 2-butoxyethanol B u t y l Carbi t o 1 Dibutyl Phthalate Nuocure C K - I O Michem 39235 Water ( h o l d t o a d j u s t v i s c o s t Y )

572.63 30.28 19.36 6.69 1.90 28.59 96.19

65.07 4.03 2.44 0.77 0.23 3.43 11.55

Premix c o - s o l v e n t s , p l a s t c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r s e e d i n g . A d d t h e wax d i s p e r s i o n t o t h e " l e t down" w i t h a g i t a t i o n . A f t e r m i x i n g w e l l , add t h e g r i n d t o t h e " l e t down" w i t h good a g i t a t i o n . M i x w e l l and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7.6, as t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % by w e i g h t : 40.25% T o t a l s o l i d s , % by volume: 29.26% Weight/gallon: 9.75 l b s . / g a l . PVC: 15.18 Pigment/binder r a t i o : 0.64 VOC: 1 . 8 8 l b s . / g a l . V i s c o s i t y : 30" #2 Zahn pH: 7.5 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y Set t o t o u c h : 1 2 ' Dust f r e e : 1 4 ' Tack f r e e : 3 0 ' Dry t h r o u g h : 3 0 ' DFT: 1 . 2 - 1 . 5 m i l

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 20-430 -B F o r m u l a t on

Enamels

I47

W h i t e A c r v l i c E m u l s i o n Enamel Inqredients:

Pounds

Gal 1ons

A c r y s o l 1-62 Ammonia, 28% 2-butoxyethanol S u r f y n o l 104BC S u r f y n o l DF-75 Water DuPont R-960 VHG

44.20 4.83 8.03 8.03 1.32 28.71 150.76

5.08 0.65 1.07 1.07 0.16 3.45 4.64

Add ammonia t o A c r y s o l 1-62 s l o w l y and w i t h good a g i t a t i o n u n t i l t h e s o l u t i o n t u r n s c l e a r and v i s c o u s . Add r e m a i n i n g i n g r e d i e n t s one a t a t i m e w i t h c o n t i n u e d a g i t a t i o n . Cowles t o a #7 Hegman w i t h a h i g h speed d i s p e r s a t o r . A d j u s t g r i n d v i s c o s i t y w i t h w a t e r f r o m b e l o w if n e c e s s a r y . L e t down w i t h : Chempol 20-4301 603.57 68.59 2-butoxyethanol 31.91 4.25 B u t y l Carbi t o 1 20.40 2.57 7.05 0.81 Dibutyl Phthalate 2.00 0.25 Nuocure CK-10 30.13 3.62 Michem 39235 Water ( h o l d t o a d j u s t v i s c o s i t y ) 31.57 3.79 Premix c o - s o l v e n t s , p l a s t i c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r s e e d i n g . Add t h e wax d i s p e r s i o n t o t h e " l e t down" w i t h a g i t a t i o n . A f t e r m i x i n g w e l l , add t h e g r i n d t o t h e " l e t down" w i t h good a g i t a t i o n . M i x w e l l and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7 . 6 , as t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . P r o p e r t ies : T o t a l s o l i d s , % b y w e i g h t : 42.58% T o t a l s o l i d s , % by volume: 32.06% W e i g h t / g a l l o n : 9.73 l b s . / g a l PVC: 1 4 . 4 7 P i g m e n t / b i n d e r r a t i o : 0.57 VOC: 1 . 7 6 l b s . / g a l V i s c o s i t y : 31" #2 Zahn pH: 7.6 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y Set t o t o u c h : 1 0 ' - 1 2 ' Dust f r e e : 1 3 ' - 1 5 ' Tack f r e e : 2 5 ' - 3 0 ' Dry t h r o u g h : 2 5 ' - 3 0 '

.

.

SOURCE:

Freeman Polymers

Di v i s on: CHEMPOL 20-430

-C Formul a t i on

148

Water-Based Paint Formulations

W h i t e A i r D r y Enamel C a r g i 11 Water R e d u c i b l e S i 1 icone Modi f ied A1 kyd 74-7435

L-531 O* E t h y l e n e G l y c o l Monobutyl E t h e r Aqueous Ammonia 28% D e i o n i z e d Water T i t a n i um D i o x i d e T i -Pure R-900

Pounds

Gal l o n s

197.9 2.5 11.9 8.3 118.7 237.6

21.94 0.30 1.59 0.96 14.25 6.97

118.7 5.3

13.16 0.61

14.3 3.6 4.5 1.2

1.90 0.45 0.62 0.16

248.4

29.64

62.1

7.45

H i g h Speed t o a 7 Hegman C a r g i l l Water R e d u c i b l e S i l i c o n e M o d i f i e d A1 k y d 74-7435 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: E t h y l e n e G1 y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i u m A c t iv-8 Dei o n i zed Water D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment)

*50% i n E t h y l e n e G l y c o l Monobutyl E t h e r Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 4 6 . 4 (By Volume): 3 0 . 7 Pigment t o B i n d e r R a t i o : 0 . 9 8 Weight Per G a l l o n : 1 0 . 3 5 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 3 9 ( G r a m s / L i t e r ) : 286 W a t e r : C o s o l v e n t Weight R a t i o : 7 5 . 5 : 2 4 . 5 pH: 8 . 5 V i s c o s i t y Krebs-Stormer (KU) : 78 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold Rolled Steel Dry F i l m T h i c k n e s s ( M i l s ) : 1 . 5 Gloss (60/20): 94/78 H u m i d i t y ( H o u r s ) : 96 Gloss (60/20): 89/75 B l i s t e r s : Medium Dense #4 O b s e r v a t i o n s : None QUV ( H o u r s ) : 500 Gloss (60/20): 35/4

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P i 686-1 89

Enamels

White A i r Dry Enamel C a r g i l l Water R e d u c i b l e S t y r e n a t e d Copolymer A l k y d 74-7425 E t h y l e n e G l y c o l Monobutyl E t h e r

Byk-301 Aqueous Ammonia 28% Titanium Dioxide Ti-Pure R-900 D e i o n i z e d Water

Pounds

Gal l o n s

213.1 11.2 2.2 10.1 201.8 72.9

24.63 1.49 0.28 1.35 5.77 8.75

78.5

9.07

11.2 5.6 1.1 1.3 0.6

1.49 0.83 0.14 0.17 0.07

3.4 319.6 1.1

0.45 38.37 0.15

2.2

0.26

56.1

6.73

H i g h Speed D i s p e r s e t o a 7 . 5 Hegman C a r g i l l Water R e d u c i b l e S t y r e n a t e d Copolymer A l k y d 74-7425 Premix t h e f o l l o w i n g ,

t h e n add:

E t h y l e n e G l y c o l Monobutyl E t h e r sec-Butanol I n t e r c a r 6% C o b a l t I n t e r c a r 6% Manganese A c t i v-8 Aqueous Ammonia 28% Dei o n i zed Water E x k i n No. 2 Aqueous Ammonia 28% ( A d j u s t t o pH 8 . 0 - 8 . 5 ) D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment) Pai n t P r o p e r t i e s % N o n v o l a t i l e (By W e i g h t ) : 41.2 (By Volume): 2 8 . 2 Pigment t o B i n d e r R a t i o : 0 . 9 8 Weight Per G a l l o n : 9 . 9 2 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 7 0 ( G r a m s / L i t e r ) : 324 pH: 8 . 0 - 8 . 5 V i s c o s i t y Krebs-Stormer ( K U ) : 70-75 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 ) : 87 P e n c i l Hardness ( 1 Day): Pass 5 8 ( 7 Days): Pass 3 8 Impact ( I n . L b s . ) : D i r e c t : 20 D r y Time ( H o u r s ) : 1 / 3 5009 Zapon: 60-65

SOURCE: C a r g i l l , I n c . : CARGILL F o r m u l a r y : Formula P1883-Dl

149

150

Water-Based Paint Formulations

W h i t e A i r D r y Enamel C a r g i l l Water R e d u c i b l e Chain Stopped A1 k y d 74-7470 Aqueous Ammonia 28% T i t a n i u m D i o x i d e T i - P u r e R-902 Dei o n i zed Water

Pounds

Gal 1ons

90.6 6.0 186.7 146.9

10.42 0.80 5.46 17.64

159.5 7.9

18.34 1.06

28.1 1.8 2.2

3.74 0.24 0.28

350.2

42.02

Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e Chain Stopped A1 k y d 74-7470 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

E t h y l e n e G l y c o l Monobutyl E t h e r 5% C o b a l t Hydro Cure I 1 Manganese Hydor Cure I 1 D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 38.41 (By Volume): 25.57 Pigment t o B i n d e r R a t i o : 0 . 9 9 Pigment Volume C o n c e n t r a t i o n : 21.47 Weight Per G a l l o n : 9 . 8 0 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 4 6 ( G r a m s / L i t e r ) : 295 Water: Cosol v e n t Weight R a t i o : 84.03: 15.97 pH: 8 . 1 3 V i s c o s i t y Krebs-Stormer (KU) : 76 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel Dry F i l m T h i c k n e s s ( M i l s ) : 1 . 5 G l o s s ( 6 0 / 2 0 ) : 91/78 H u m i d i t y ( H o u r s ) : 96 G l o s s ( 6 0 / 2 0 ) : 92/70 B l i s t e r s : Medium #4 O b s e r v a t i o n s : None S o u t h F l o r i d a Exposure ( M o n t h s ) : Gloss (60/20) : Washed: 76/39 Unwashed: 71/38 SOURCE: C a r g i l l ,

Inc.:

6

CARGILL F o r m u l a r y : Formula P1843-30E

Enamels

W h i t e A i r D r y Enamel

C a r g i 11 Water R e d u c i b l e F a t t y A c i d A 1 k y d 74-7472 Aqueous Ammonia 28% T i t a n i um D i o x i d e T i -Pure R-902 Dei o n i zed Water

Pounds

Gal 1ons

96.9 7.7 208.2 125.9

11 .27 1.03 6.09 15.11

180.6 7.3

21 .oo 0.98

21.8 2.1 3.1

2.96 0.27 0.40

340.6

40.89

Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e F a t t y A c i d A1 k y d 74-7472 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

P r o p y l e n e G l y c o l Monopropyl E t h e r 5% C o b a l t Hydro Cure I 1 Manganese H y d r o Cure I 1 Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 42.14 (By Volume): 2 8 . 8 3 Pigment t o B i n d e r R a t i o : 0.99 Pigment Volume C o n c e n t r a t i o n : 21.25 Weight Per G a l l o n : 9 . 9 4 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.29 ( G r a m s / L i t e r ) : 275 W a t e r : C o s o l v e n t Weight R a t i o : 82.98:17.02 pH: 8.52 V i s c o s i t y #4 F o r d Cup (Seconds): 33 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel Dry F i l m Thickness ( M i l s ) : 1 . 5 G l o s s ( 6 0 / 2 0 ) : 87/60 QUV ( H o u r s ) : 500 G l o s s ( 6 0 / 2 0 ) : 18/1 South F l o r i d a Exposure ( M o n t h s ) : 6 Gloss (60/20) Washed: 64/17 Unwashed: 58/16 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1843-30H

151

I52

Water-Based Paint Formulations

White A i r Dry E n a e C a r g i l l Water R e d u c i b l e F a t t y A c i d A l k y d 74-7476 Aqueous Ammonia 28% T i t a n i um D i o x i d e T i -Pure R-902 D e i o n i z e d Water

Pounds

Gal l o n s

129.2

15.02 1.10 8.70 16.14

8.2 297.4 134.4

Sand M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e F a t t y A c i d A l k y d 74-7476 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

167.6 8.5

19.49

1.14

t h e n add:

E t h y l e n e G1y c o l Monobutyl E t h e r 5% C o b a l t Hydro Cure I 1 Manganese Hydro Cure I 1 Dei o n i zed Water

23.2

3.08

2.1

0.27

3.2

0.41

288.7

34.65

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 49.20 (By Volume): 32.86 Pigment t o B i n d e r R a t i o : 1.32 Pigment Volume C o n c e n t r a t i o n : 26.58 Weight Per G a l l o n : 10.63 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.19 ( G r a m s / L i t e r ) : 262 W a t e r : C o s o l v e n t Weight R a t i o : 8 0 . 6 2 : 1 9 . 3 8 pH: 8 . 0 7 V i s c o s i t y #4 F o r d Cup (Seconds): 18 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel Dry F i l m T h i c k n e s s ( M i l s ) : 1 . 5 G l o s s ( 6 0 / 2 0 ) : 87/70 H u m i d i t y ( H o u r s ) : 96 G l o s s ( 6 0 / 2 0 ) : 90/80 B l i s t e r s : Dense #6 O b s e r v a t i o n s : None QUV ( H o u r s ) : 500 Gloss (60/20): 38/3 South F l o r i d a Exposure (Months): G l o s s (60/20): Washed: 75/26 Unwashed: 66/24 SOURCE: C a r g i l l ,

6

I n c . : CARGILL F o r m u l a r y :

Formula P1843-30L

Enamels

W h i t e A i r Dry Enamel C a r g i 11 Water R e d u c i b l e Phenol ic Modi f ied A1 k y d 74-7478 Aqueous Ammonia 28% P r o p y l e n e G l y c o l Monopropyl E t h e r sec-Butanol T i t a n i u m D i o x i d e T i - P u r e R-902 D e i o n i z e d Water

Pounds

Gallons

150.3 7.0 7.6 3.8 207.0 182.5

17.48 0.94 1.03 0.57 6.05 21.91

126.3 6.7

14.68 0.89

7.6 3.8 4.2 0.7

1 .03 0.57 0.51 0.09

285.4

34.25

Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e Phenol ic Modi f ied A1 k y d 74-7478 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

P r o p y l e n e G l y c o l Monopropyl E t h e r sec-Butanol Nuocure CK 10% E x k i n No. 2 Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 41.98 (By Volume): 2 8 . 8 9 Pigment t o B i n d e r R a t i o : 0 . 9 9 Pigment Volume C o n c e n t r a t i o n : 21.13 Weight Per G a l l o n : 9 . 9 3 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 3 0 ( G r a m s / L i t e r ) : 275 W a t e r : C o s o l v e n t Weight R a t i o : 8 3 . 0 1 : 1 6 . 9 9 pH: 8 . 1 6 V i s c o s i t y Krebs-Stormer (KU): 87 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel Dry F i l m Thickness ( M i l s ) : 1.5 G l o s s ( 6 0 / 2 0 ) : 09/90 H u m i d i t y ( H o u r s ) : 96 G l o s s ( 6 0 / 2 0 ) : 81/68 B l i s t e r s : Medium Dense #8 QUV ( H o u r s ) : 500 G l o s s ( 6 0 / 2 0 ) : 31/2 S o u t h F l o r i d a Exposure ( M o n t h s ) : 6 Gloss (60/20): Washed: 88/57 Unwashed: 75/46 SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y :

Formula P1843-30N

I53

154

Water-Based Paint Formulations

White Ai r - D r y m a m e l Pounds

Gallons

76.3 2.6 161 . 1 49.9 1.5 8.0 1.5 70.5

8.62 0.35 4.60 2.21 0.18 1.06 0.20 8.46

175.0 6.1

19.75 0.81

E t h y l e n e G l y c o l Monobutyl E t h e r 5% C o b a l t Hydro Cure I 1 Manganese Hydro Cure I 1

4.2 1.3 1.3

0.56 0.16 0.15

A c t iv - 8 E x k i n No. 2 Raybo 62-HydroFlo E t h y l e n e G l y c o l Monobutyl E t h e r D e i o n i z e d Water

0.7 1.5 4.0 8.5 2.55.7

0.09 0.19 0.48 1 .13 30.71

4.0

0.53

164.6

19.76

C a r g i 11 Water R e d u c i b l e Chai n Stopped A1 k y d 74-7487 Aqueous Ammonia 28% T i t a n i u m D i o x i d e T i - P u r e R-900 Supercoat S u r f y n o l 104 E E t h y l e n e G l y c o l Monobutyl E t h e r Byk-020 D e i o n i z e d Water H i g h Speed t o a 7 Hegman C a r g i 11 Water R e d u c i b l e C h a i n Stopped A1 k y d 74-7487 Aqueous Ammonia 28% Premix t h e f o l l o w i n g ,

t h e n add:

Aqueous Ammonia 28% ( A d j u s t t o pH o f 8 . 3 ) D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Ad] u s t m e n t )

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 41 . 5 6 (By Volume): 28.55 Pigment t o B i n d e r R a t i o : 1 . 0 4 Pigment Volume C o n c e n t r a t i o n : 2 3 . 9 4 Weight Per G a l l o n : 9.98 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 0 9 ( G r a m s / L i t e r ) : 250 W a t e r : C o s o l v e n t Weight R a t i o : 85.70:14 . 3 0 pH: 8 . 3 V i s c o s i t y #4 F o r d Cup (Seconds): 36 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 91/77 P e n c i l Hardness: Pass B % C r o s s h a t c h Adhesion: 100 SOURCE: C a r g i l l ,

Inc.: CARGILL F o r m u l a r y : Formula P1887-5181

Enamels

W h i t e A i r D r y Enamel Pounds ~ _ C a r g i 11 Water R e d u c i b l e Chain Stopped A1 kyd 74-7495 Aqueous Ammonia 28% sec-Butanol E t h y l e n e G l y c o l Monobutyl E t h e r Byk-301 T i t a n i um D i o x i d e T i -Pure R - 9 0 0 Dei o n i zed Water

_

Gallons

134.2 4.3 4.4 6.4 0.9 182.8 56.5

15.60 0.58 0.66 0.85 0.12 5.22 6.78

137.3 7.9

15.97 1.05

5.6 4.0 3.5 2.6 0.9

0.83 0.53 0.45 0.36 0.12

423.8

50.88

S a n d m i l l t o a 7 . 5 Hegman C a r g i l l Water R e d u c i b l e Chain Stopped A1 k y d 74-7495 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: sec-Butanol E t h y l e n e G l y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um A c t iv-8 D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 3 8 . 5 6 (By Volume): 25.75 Pigment t o B i n d e r R a t i o : 0.95 Pigment Volume C o n c e n t r a t i o n : 20.47 Weight Per G a l l o n : 9.75 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.66 (Grams/Li t e r ) : 319 W a t e r : C o s o l v e n t Weight R a t i o : 81.64:18.36 pH: 8 . 7 V i s c o s i t y Krebs-Stormer ( K U ) : 65-75 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold Rolled Steel Gloss ( 6 0 / 2 0 ) : 86/74 P e n c i l Hardness: Pass B % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 30 Reverse: (5 Dry Time L i n e a r D r y i n g Recorder ( H o u r s ) : 3 / 4 H u m i d i t y ( H o u r s ) : 100 O b s e r v a t i o n s : None

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P1843-25714

155

156

Water-Based Paint Formulations

W h i t e Enamel

Lbs.

M a t e r i a1 : Water Tamol 731 T i - P u r e R902 Foamaster V L

63.14 3.40 221 .ll 0.23

Gals. 7.58 0.37 6.66 0.03

602.48 60.44 48.98 7.09 11.65

69.25 8.07 5.88 0.70 1.56

Pebble m i l l t o a 7 Hegman g r i n d . Letdown : A r o l o n 845-W-45 Butoxy E t h a n o l Water 10% Sodium N i t r i t e Ammoni u m H y d r o x i de

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 17.61 P i g m e n t / B i n d e r R a t i o : 0 . 8 / 1 .OO P e r c e n t Sol ids, Wei g h t : 48.96 P e r c e n t S o l i d s , Volume: 38.45 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 35-45 Pounds/Gallon: 10.17 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 160.80 Pounds/Gallon: 1 . 3 4

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2402-24A

Inc.:

Waterborne Handbook:

Enamels

W h i t e Enamel M a t e r i a1 :

Pounds

Gallons

162.1 53.5

16.84 7.21

216.0 250.0 4.0

24.80 7.60 0.50

P a r t A: Epi-Rez 510 Epoxy R e s i n H e l o x y 8 Epoxy F u n c t i o n a l Mod f i e r Part 8 : Epi -Cure W50-8535 C u r i n g Agen R u t i l e T i t a n i u m D i o x i d e (2) Defoamer (3) H i g h speed d i s p e r s e t o t e x t u r e 7-8 NS. Glacial Acetic Acid Defoamer (3) Water

Reduce speed and add:

2.0 4.0 352.4

0.24 0.50 42.31

215.6 828.4

24.05 75.95

(2) T i t a n o x 2020 (3) C o l l o i d 640 Composite B1end: Part A Part B P a r t s A and B

Viscosity 68 KU 60 KU 100 KU

Typical Coating Properties: T o t a l Weight S o l i d s , p e r c e n t : 44.2 T o t a l Volume S o l i d s , p e r c e n t : 45.0 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gal 1on : 0.14 Grams/Li t e r : 16.8

SOURCE: She1 1 Chemical Co. : 24-212 W h i t e Enamel U s i n g EPI-CURE W50-8535 C u r i n g Agent

157

158

Water-Based Paint Formulations

W h i t e Enamel M a t e r i a1 : Pounds P a r t A: R u t i l e Titanium Dioxide 250.0 Epi-Rez 510 Epoxy R e s i n 130.0 H i g h speed d i s p e r s e t o t e x t u r e o f 10 P.C.S. Add: Epi-Rez 510 Epoxy R e s i n 32.1 H e l o x y 8 Epoxy F u n c t i o n a l M o d i f i e r 53.5

____ Gallons 7.34 13.50 3.34 5.82

P a r t 8: Epi-Cure W50-8535 C u r i n g Agent Glacial Acetic Acid Water

216.0 2.0 374.0

24.80 0.24 44.96

Composite B l e n d : Part A Part 0

465.6 592.0

30.00 70.00

Typical Coating Properties Viscosity: F r e s h : 75-85 KU 1 Hour: O f f S c a l e Pounds/Gal 1on : 10.58 A p p l i c a t i o n : B r u s h o r Spray Cure Schedule: Room Temperature P.V.C.: 17.5% V e h i c l e Non-Vol a t i 1e : 45.8% T o t a l S o l i d s : 53.2% Typical Film Properties: G l o s s (60 A n g l e ) : 98 U n i t s Penci 1 Hardness: "E" 72 Hours Cure Resin Composition: Epoxy R e s i n : 66.5% C u r i n g Agent: 33.5%

SOURCE: S h e l l Chemical Co.:

24-146 W h i t e Enamel

Enamels

159

W h i t e Enamel F o r m u l a t i o n Materials: R e s i n WE-300 (80% NVM) D i m e t h y l e t h a n o l a m i ne D e i o n i zed w a t e r Melamine ( 1 ) Flow agent ( 2 ) Titanium dioxide (3) Water f o r s p r a y v i s c o s i t y ( a p p r o x ) Solvent ( 4 ) f o r spray v i s c o s i t y (approx) Coating Properties: P i g m e n t / b i n d e r r a t i o : 0 . 9 / 1 .O Resin/melamine r a t i o : 15/85 W a t e r / c o s o l v e n t r a t i o : 82/18 N o n - v o l a t i l e m a t e r i a l (NVM), w t % : V i s c o s i t y , #4 Ford, sec: 30-35 pH: 7.5-8.0

P a r t s by w e i q h t 288.2 16.3 262.6 40.7 0.5 244.1 121.1 26.5

53-54

Compounding Procedure: 1. M i x p o l y e s t e r r e s i n and d i m e t h y l e t h a n o l a m i n e u n t i l homogeneous. S l o w l y add w a t e r u n t i l mixed t h o r o u g h l y . S t i r i n melamine and a d j u s t pH t o 7 . 5 - 8 . 0 . 2. S t i r i n f l o w agent and p i g m e n t . 3 . Charge m i x t u r e t o p e b b l e m i l l . R o l l o v e r n i g h t t o Hegman G r i n d o f 7+. 4 . D i s c h a r g e m i l l and a d j u s t t o d e s i r e d a p p l i c a t i o n v i s c o s i t y .

(1) (2) (3) (4)

Cyme1 303 FC-430 T i - P u r e R-900 B u t y l Carbi t o 1 d i e t h y l e n e g l y c o l n - b u t y l

Performance P r o p e r t i e s ( 1 ) : P r o p e r t i e s : CRS ( 4 ) : F i l m thickness, m i l s : 1.3 60 g l o s s , %: 92 Yellowness i n d e x ( 7 ) : -3.83 Sward hardness: 89 P e n c i l hardness: 2H Impact r e s i s t a n c e , i n - l b : d i r e c t : 80 r e v e r s e : 50 C o n i c a l bend, 1 / 8 - i n c h , % pass: 100 C r o s s h a t c h a d h e s i o n : 48 ( 1 ) Cure c y c l e : 20 m i n u t e s a t 177C ( 2 ) Commercial s o l v e n t - a p p l i e d , o i 1 - f r e e , ( 4 ) Cold r o l l e d s t e e l ( 7 ) Yellowness index:[(A-E)/G]xlOO

ether

f l e x i b l e polyester

SOURCE: Amoco Chemical Co.: Water-Borne Bake P o l y e s t e r s Based on AMOCO IPA and TMA: Formula T a b l e 11 and 1 2

160

Water-Based Paint Formulations

W h i t e F a s t D r v Enamel M a t e r i a1 : A r o l on 970-G4-70 Premi x : Cobalt Hydrocure A c t i v-8 T i -Pure R-902 R o l l e r m i l l t o 7 Hegman g r i n d Letdown : A r o l o n 970-G4-70 Ammoni um H y d r o x i de Propasol P Butoxy E t h a n o l sec-Butanol n - But a n 0 1 Lodyne S-107 Water Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : Pigment/Binder R a t i o : .7/1 P e r c e n t S o l i d s , W e i g h t : 26.9 P e r c e n t S o l i d s , Vol ume: ; 18.4 V i s c o s i t y @ 25C, #4 F o r d , S e c s . : 45-50 Pounds/Gallon: 9 . 0 8 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 409 Pounds/Gallon: 3 . 4 1

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2053-35

Inc.:

Lbs. 14a.93

Gals. 16.93

4.27 .72 100.93

.56 .09 3.03

55.82 7.82 7.24 17.16 16.29 17.59 1.55 528.81

6.34 1.04 .98 2.29 2.43 2.61 .16 63.48

16.5

Waterborne Handbook:

Enamels

W h i t e G l o s s Enamel Material : A r o l o n 860-W-45 S u r f y n o l 104H C o l l o i d 679 Water Ammoni um H y d r o x i d e T i t a n o x 2101 Cowles g r i n d t o a 6 Hegman. Letdown : A r o l o n 860-W-45 Butoxy Ethanol Diethylene Glycol n-Butyl Byk 301 10% Sodium N i t r i t e Water Ammoni um H y d r o x i d e

Ether

Lbs. 285.12 2.59 2.81 60.48 2.16 226.80

Gals. 32.44 0.32 0.39 7.26 0.28 6.80

341.28 28.08 28.08 1.08 4.10 43.20 4.32

38.04 3.74 3.54 0.13 0.50 5.18 0.58

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 18.2 Pigment/Binder R a t i o : .8/1 P e r c e n t S o l i d s , W e i g h t : 49.4 P e r c e n t S o l i d s , Volume: 37.5 V i s c o s i t y @ 25C, #2 Zahn, S e c s . : 35-45 Pounds/Gallon: 10.30 pH: 8.2-8.5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 155 Pounds/Gal 1on : 1 .29

SOURCE:

R e i c h h o l d Chemicals, I n c . : F o r m u l a t i o n 2402-1744

Waterborne Handbook:

161

I62

Water-Based Paint Formulations

W h i t e G l o s s Enamel

Lbs.

Material : K e l s o l 3960-B2G-75 Premi x : A c t iv-8 C o b a l t Hydrocure Add t h e n add: Butoxy E t h a n o l T i t a n o x 2101 R o l l e r m i l l t o 7 Hegman g r i n d . Letdown : K e l s o l 3960-B2G-75 n-Butanol sec-Butanol Ammoni um H y d r o x i d e Butoxy E t h a n o l Water

183.30

Gals. 21 .OB

0.92 5.68

0.12 0.75

9.17 188.80

1.22 5.67

69.65 13.44 12.83 13.44 3.67 474.14

8.01 2.00 1.92 1.80 0.50 56.93

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 22.0 Pigment/Binder R a t i o : 1/1 P e r c e n t S o l i d s , Weight: 32.2 P e r c e n t S o l i d s , Volume: 25.7 V i s c o s i t y @ 25C, #4 Ford, Secs.: 53-56 Pounds/Gallon: 11.74 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 302 Pounds/Gallon: 2.52

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2079-7

I n c . : Waterborne Handbook:

Enamels

163

W h i t e G l o s s Enamel

Lbs.

M a t e r i a1 : Kel s o l 3990-B2G-70 Ammonium H y d r o x i d e Butoxy E t h a n o l D i a c e t o n e A1 coho1 Propyl Dipropasol Premix : C o b a l t Hydrocure I 1 A c t i v-8 Butoxy E t h a n o l T i t a n o x 2101 Water Pebble m i l l t o a 7 Hegman g r i n d . Letdown : Kel s o l 3990-026-70 Ammonium H y d r o x i d e Water

Gals 14.79 0.90 2.22 1 .07 1.07

5.07 0.80 2.48 171.50 208.80

0.67 0.10 0.33 5.15 24.98

119.91 4.11 283.05

14.19

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 21.2 Pigment/Binder R a t i o : 1 / 1 P e r c e n t S o l i d s , Weight: 36.07 P e r c e n t Sol i d s , Volume: 24.66 V i s c o s i t y @ 25C, #4 Ford, Secs.: 35-45 pH: 8 . 2 - 8 . 5 Pounds/Gallon: 9.60 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 334 Pounds/Gallon: 2.79

SOURCE:

R e i c h h o l d Chemicals, Formul a t i on 2470-59

.

124.98 6.72 16.67 8.37 8.31

I n c . : Waterborne Handbook:

0.55 33.98

164

Water-Based Paint Formulations

White.

H i q h G l o s s , A i r D r y o r F o r c e D r y Water R e d u c i b l e Enamel

10-1300-A i s f o r m u l a t e d t o d e m o n s t r a t e o u t s t a n d i n g p e r f o r m ance o f CHEMPOL 10-1300 i n h i g h g l o s s , a i r d r y and f o r c e d r y a p p l i c a t i o n f o r use o v e r t r e a t e d o r u n t r e a t e d m e t a l s u r f a c e s . T h i s enamel d e v e l o p s e a r l y w a t e r r e s i s t a n c e w i t h i n 2-4 h o u r s after application. 10-1300-A i s recommended f o r e i t h e r i n t e r i o r o r e x t e r i o r a p p l i c a t i o n s . S a l t s p r a y t e s t s have demonstrated t h e s u p e r i o r c o r r o s i o n r e s i s t a n c e p r o p e r t i e s o f 10-1300-A. T h i s enamel can be p r e p a r e d w i t h o u t f i r s t h a v i n g t o s o l u b i l i z e CHEMPOL 10-1300. I t i s recommended t h a t t h e f o r m u l a t i o n p r o c e d u r e be c l o s e l y f o l l o w e d . Changes i n pigment w e t t i n g a g e n t s o r d r i e r s may cause v a r i a t i o n i n g l o s s and performance. 10-1300-A c o n t a i n s 20% o r g a n i c s o l v e n t and amine, 80% w a t e r by volume, w h i c h meets R u l e 66 r e q u i r e m e n t s f o r w a t e r r e d u c i b l e coatings containing organic solvents. I n n r e d ie n t s : Premix i n o r d e r l i s t e d : Chempol 10-1 300 T r i e t h y l ami ne Polycompound W-953 N a l c o 435-36 Water Bykumen T i t a n i u m D i o x i d e ( T i - P u r e R--900)

Pounds

Gallons

66.71 4.86 2.84 1.49 91.06 2.84 186.76

8.07 0.82 0.37 0.15 10.91 0.37 5.38

G r i n d Pebble M i l l t o 7 1/2 Hegman. Add t o m i l l t h e f o l l o w i n g and r e d i s p e r s e one h o u r : Chempol 10-1 300 T r i e t h y l ami ne

8.07 0.82

66.71 4.86

L e t down w i t h : Premix i n o r d e r l i s t e d and add w h i l e under a g i t a t i o n : Chempol 10-1300 133.41 Triethylamine 11.35 E x k i n No. 2 1.49 P a i n t A d d i t i v e #14 1.49 Hydrocure 5.60 Water 382.99 Properties: T o t a l s o l i d s , % by w e i g h t : 38.72 T o t a l s o l i d s , % by volume: 26.00 V i s c o s i t y #4 F o r d cup, seconds: 30-45 R e d u c t i o n f o r s p r a y a p p l i c a t i o n : Use as i s Pigment/binder weight r a t i o : 1.0/1 .O PVC, %: 21 pH: 8 . 5 - 9 . 5 G l o s s , 60 Gardner: 100+ Weight/gallon, l b s . : 9.64

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 10-1300-A

16.41 1.87 0.15 0.15 0.75 45.98

Formulation

Enamels

165

Sugaested S t a r t i n a F o r m u l a t i o n 10-1300-F i s a r e f o r m u l a t i o n o f 10-1300-A w h i c h uses r e c e n t developments i n w a t e r - r e d u c i b l e t e c h n o l o g y . H i g h e r s o l i d s and enhanced p a i n t s t a b i l i t y a r e t h e improved p r o p e r t i e s a c h i e v e d w i t h 10-1300-F. Inqredients: Chempol 10-1 300 Triethylamine Coroc A2678M S u r f y n o l 1048C Dei o n i zed Water A c r y s o l ASEGO T i P u r e R700

Pounds 69.81 5.02 2.93 0.42 115.12 1.05 195.50

Gal 1ons 8.46 0.79 0.33 0.06 13.84 0.12 6.05

G r i n d p e b b l e m i l l t o Hegman 7 o r b e t t e r . L e t down w i t h : Chempol 10-1 300 NH40H (28% NH3) Dei o n i zed Water Coroc A2678M

69.81 3.66 26.16 4.19

8.46 0.49 3.14 0.48

Premix t h e f o l l o w i n g and c o n t i n u e l e t down under a g i t a t i o n : Chempol 10-1 300 Triethylamine NH4OH (28% NH3) E x k i n #2 8yk 301 C o b a l t H y d r o c u r e 11 Manganese H y d r o c u r e I 1 Dei o n i zed Water

139.61 6.07 4.19 1.57 0.52 7.33 3.14 313.97

16.92 0.96 0.56 0.20 0.06 0.96 0.37 37.74

Properties: T o t a l s o l i d s , % b y w e i g h t : 41.30 T o t a l s o l i d s , % b y volume: 28.06 V i s c o s i t y #4 F o r d Cup, s e c s . : 50.00 R e d u c t i o n f o r s p r a y a p p l i c a t i o n : Use as i s P/0 w e i g h t r a t i o : 1.00 PVC, %: 21.57 pH: 8.5-9.0 VOC, # / g a l l o n minus w a t e r : 2.35 Film Properties: 3 . 0 m i l wet drawdown o v e r g l a s s ; 78F; S e t t o t o u c h : 25-30 m i n u t e s Zapon (100 grams): 60-70 m i n u t e s Dry h a r d : 4-5 h o u r s 60 g l o s s : 90

75% r e l a t i v e h u m i d i t y :

SOURCE: Freeman Polymers D i v i s i o n : CHEMPOL 10-1300-F

Formulation

166

Water-Based Paint Formulations

W h i t e H i a h G l o s s B r u s h i n a Enamel

Lbs. Material: Gals. Water 85.0 10.20 T r i e t h y l ami ne 1 .24 7.5 12.0 Propasol P 1.63 90.0 K e l s o l 3922-G-80 10.43 P a t c o t e 531 1.o 0.14 T i -Pure R-902 275.0 8.04 A d j u s t pH t o 8 . 2 - 8 . 6 . G r i n d i n h i g h speed d i s p e r s e r f o r 15-20 m i n u t e s ( 6 + Hegman)

.

Letdown : K e l s o l 3922-6-80 A r o p l a z 1272 Ammoni um H y d r o x i d e Water P r e - b l end: Water A c r y s o l ASE-60 A d j u s t pH t o 8.2-8.6 Premix : P r o p a s o l P* A c t iv-8 Cobalt Hydrocure I 1 Cal c i um Hydrocem Z i r c o n i u m Hydrocem

*

196.0 12.0 13.0 368.0

22.71 1.44 1.73 44.18

7.0 7.0

0.80

14.0 0.5 3.5 3.5 3.0

1.90 0.06 0.46 0.44 0.36

b e f o r e p r o c e e d i ng.

M e t h y l C a r b i t o l may be s u b s t i t u t e d .

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 22.7 P i g m e n t / B i n d e r R a t i o : 1.14/1 P e r c e n t Sol i d s , Weight : 47.0 P e r c e n t S o l ids, Vol ume: 33.0 V i s c o s i t y @ 25C, #4 F o r d , S e c s . : 92-96 Pounds/Gallon: 10.30 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 235 Pounds/Gallon: 1 . 9 6

SOURCE:

0.84

R e i c h h o l d Chemicals, I n c . : F o r m u l a t i o n 2003-44-2AA

Waterborne Handbook:

Enamels

I67

W h i t e Semi-Gloss Trade S a l e s Enamel M a t e r i a1 : A r o l o n 580-W-2 Butoxy E t h a n o l E t h y l e n e G1 y c o l P o t a s s i um T r i p o l y p h o s p h a t e Tamol 731 6% C o b a l t Cyclodex I g e p a l CO-630 T r i t o n GR7 T i t a n o x 2101 D i s p e r s e t o 7+ Hegman g r i n d . Then add : Letdown : A r o l on 580-W-42 T h i c k e n e r LN Water Nopco NDW Rhoplex AC 707 Water

Lbs.

.

135.0 40.0 15.0 0.5 5.0 1.o 2.0 2.0 275.0

Gals 15.17 5.33 1.60 0.01 0.63 0.12 0.25 0.25 7.88

160.0 38.0 38.0 4.0 190.0 175.0

18.00 4.00 4.00 0.50 21 .ll 21 .oo

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 21.5 Pigment/Binder R a t i o : 1.1/1 P e r c e n t S o l i d s , Weight : 48.4 P e r c e n t S o l i d s , Volume: 34.0 V i s c o s i t y @ 25C, KU: 75-85 Pounds/Gallon: 10.83 pH: 7.0-7.5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 149 Pounds/Gal 1on : 1 . 2 4

SOURCE: R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i on 31 111-42-25

168

Water-Based Paint Formulations

WR P o l v e s t e r / M e l a t n i n e Enamel K-FLEX Modi-

Cowles G r i n d : C a r g i l l 7203 D i m e t h y l e t h a n o l amine Cymel 303 Byk 301 K-Flex 188 D I Water T i t a n o x 2020

50/15/35

156.4 10.8 54.8 1.3 23.5 30.0 313.1

7+ on Hegman Letdown : C a r g i l l 7203 D i m e t h y l e t h a n o l ami ne Cymel 303 K - F l e x 188 D I Water D I Water ( H o l d f o r A d j u s t m e n t ) Enamel C h a r a c t e r i s t i c s : % S o l i d s ( b y w t ) : 50 % TRS: 25 % N e u t r a l i z a t i o n : 100 Enamel p H : 8 . 0 Film Properties: S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS C a t a l y s t : None Cure: 1 5 ' @ 325F. F i l m Thickness: 0.75-0.80 m l P e n c i l Hardness: F-H Double MEK Rubs: 100+ I m p a c t Rev. i n . l b . : 120-130 D i r . i n . l b . : 130-140 C r o s s h a t c h Adhesion % Loss: 0 G l o s s 60: 90 Water Soak 50C. 72 h r . : 65/NA 60 G l o s s / B l i s t e r 240 h r . : 60/NA 480 h r . : 45/NA S a l t Spray 240 h r . mm C r e e p / B l i s t e r : 3-5/V. L t . 9 SOURCE: K i n g I n d u s t r i e s : Water R e d u c i b l e F o r m u l a t i o n #9

52.1 3.6 54.7 23.4 285.2 242.9

Enamels

Y e l l o w Gloss Enamel

Lbs.

M a t e r i a1 : Water Ammoni um H y d r o x i de Kel s o l 3904-064-75 Add i n o r d e r l i s t e d : Aquacat 12% Manganese Cem-All Butoxy E t h a n o l T i t a n o x 2101 Mapico Y e l l o w 1050 Chrome Y e l l o w X3356 Molybdate Orange YE-637-D Sand m i l l t o 6 Hegman g r i n d . Letdown : Water Ammonium H y d r o x i d e Butoxy E t h a n o l K e l s o l 3904-0G4-75 Analysis: Pigment Volume C o n c e n t r a t i o n , Pigment/Binder R a t i o : 1/1 P e r c e n t S o l i d s , Weight: 42.7 P e r c e n t S o l i d s , Volume: 28.0 Pounds/Gal l o n : 10.1 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 259 Pounds/Gal 1on : 2.16

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 1610-22

206.40 6.19 103.20

Gals. 24.77 0.83 11.94

2.06 2.06 10.32 15.48 46.44 144.48 6.19

0.24 0.26 1.37 0.45 1.37 3.11 0.13

275.54 6.19 5.16 180.60

33.12 0.83 0.69 20.89

P e r c e n t : 18.0

Inc.:

Waterborne Handbook:

169

I70

Water -Based Paint Formulations

Y e l l o w I r o n O x i d e H i n h G l o s s Enamel M a t e r i a1 : Kel s o l 3960-026-75 Ammoni um H y d r o x i de Butoxy E t h a n o l T i t a n o x 2101 Y e l l o w I r o n O x i d e 2288D Water Pebble m i l l t o a 7+ Hegman g r i n d Letdown : K e l s o l 3960-B2G-75 Ammonium H y d r o x i d e Butoxy Ethanol n-Butanol Cobalt Hydrocure I 1 A c t i v-8 Water

Lbs.

6.48 0.54 2.13 0.15 2.87 12.48

233.02 10.98 14.94 10.97 6.50 1.12 352.27

26.97 1.47 1.99 1.63 0.86 0.14 42.29

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 11.49 P i g m e n t / B i n d e r R a t i o : 0.47/1 .O P e r c e n t S o l i d s , W e i g h t : 35.76 P e r c e n t S o l ids, Vol ume : 26.87 V i s c o s i t y C 2 5 C , #4 F o r d , Secs.: 35-45 G l o s s (60/20): 93/87 Pounds/Gallon: 9.11 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 322.80 Pounds/Gallon: 2.69

SOURCE:

ReSchhold Chemicals, F o r m u l a t i o n 2403-47

Inc.:

Gals.

55.98 4.03 15.99 4.99 96.14 103.96

Waterborne Handbook:

172

Water-Based Paint Formulations

Black Anti-Corrosive C a r g i 11 Water R e d u c i b l e Chain Stopped A1 k y d 74-7474 E t h y l e n e G l y c o l Monobutyl E t h e r A e r o s i l R972 Special Black 4 S t r o n t i u m Chromate 30-AC-3008 Byk-020 By k-30 1 Aqueous Ammonia 28% Triethylamine D e i o n i z e d Water

D i p Enamel

Pounds

Gal i o n s

68.1 7.5 2.6 11.3 28.3 1.6 1.3 1.9 1.5 121.5

7.74 1 .oo 0.14 0.76 1 .oo 0.22 0.16 0.25 0.25 14.58

181.5 39.0

20.63 5.15

5.0 1.4 2.3 1.6

0.63 0.17 0.30 0.20

1.9 2.4 8.0 376.2

0.27 0.31 1.06 45.18

Sand M i l l t o a 7 Hegman C a r g i 7 1 Water R e d u c i b l e Chain Stopped A1 k y d 74-7474 E t h y l e n e G l y c o l Monopropyl E t h e r Premix t h e f o l l o w i n g , t h e n add: B u t y l Carbi t o 1 Manganese Hydro Cure I1 5% C o b a l t Hydro Cure I1 Activ-8 S u r f y n o l 104A E x k i n No. 2 Aqueous Ammonia 28% D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 27.06 (By Volume): 22.03 Pigment t o B i n d e r R a t i o : 0 . 2 2 Pigment Volume C o n c e n t r a t i o n : 8.80 Weight Per G a l l o n : 8.65 T h e o r e t i c a l VOC (Pounds/Gallon): 3 . 2 0 ( G r a a s / L i t e r ) : 384 W a t e r : C o s o l v e n t Weight R a t i o : 80.00:20.00 V i s c o s i t y # 4 f o r d C u p (Seconds): 51

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P1848-1628

Enamels -Baking

173

B l a c k B a k i n g DiD Enamel Pounds

Gallons

106.8 3.9 6.9 1.5 19.5 6.7 2.4 181 . o

12.64 0.51 0.93 0.19 1.32 0.37 0.34 21.73

147.5 2.4 6.5 8.6 5.7 10.1

17.45 0.34 0.85 1.28 0.72 1.37

24.5 1.9 310.7

2.42 0.23 37.31

C a r g i 11 Water R e d u c i b l e Epoxy E s t e r

73-7331 E t h y l e n e G l y c o l Monopropyl E t h e r D i m e t h y l e t h a n o l ami ne By k-301 Special Black 4 A e r o s i l R972 P a t c o t e 577 D e i o n i z e d Water Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e Epoxy E s t e r

73-7331 P a t c o t e 577 E t h y l e n e G l y c o l Monopropyl E t h e r Isobutanol D i e t h y l e n e G l y c o l Monobutyl E t h e r D i m e t h y l e t h a n o l a m i ne C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Me1 ami ne 23-2347 Nacure 155 D e i o n i z e d Water

Paint Properties: ?6 N o n v o l a t i l e (By W e i g h t ) : 27.38 (By Volume): 24.43 Pigment t o B i n d e r R a t i o : 0.13 Pigment Volume C o n c e n t r a t i o n : 6.89 Weiaht Per G a l l o n : 8.46 T h e o r e t ic a l VOC (Pounds/Gal 1on) : 3.00 ( G r a m s / L i t e r ) : 360 W a t e r : C o s o l v e n t Weight R a t i o : 80.00:20.00 pH: 8.37 V i s c o s i t y #4 F o r d Cup (Sesonds): 25

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula Pl848-180

174

Water -Based Paint Formulations

B l a c k G l o s s B a k i n a Enamel Material : A r o l o n 970-G4-70 E t h y l e n e G l y c o l Monobutyl E t h e r D i m e t h y l e t h a n o l A m i ne (DMEA) S u r f y n o l 104E Water Raven 1250 S t e e l b a l l m i l l t o a 7 Hegman g r i n d . Letdown : A r o l o n 970-64-70 Cyme1 303 n-Butanol DMEA Water Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t P i g m e n t / B i n d e r R a t i o : .07/1 P e r c e n t S o l i d s , W e i g h t : 35.90 P e r c e n t S o l i d s , Volume: 31.68 V i s c o s i t y @ 25C, KU: 95-100 pH: 8.2-8.6 Pounds/Gallon: 8 . 5 9 Resin/Melamine R a t i o : 76/24 % R e d u c t i o n t o 30 Secs., #2 Zahn: 80 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 335.7 Pounds/Gallon: 2 . 8

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2185-67

Inc.:

Lbs. 79.06 15.47 4.30 3.44 137.50 21.48

Gals. 9.07 2.06 0.58 0.41 16.51 1.47

230.32 68.75 21.48 6.88 270.71

26.41 6.88 3.18 0.93 32.50

4.65

Waterborne Handbook:

Enamels-Baking

Black

Low G l o s s B a k i n q Enamel

M a t e r i a1 : K e l s o l 3910-826-75 T r i e t h y l ami ne Water Butoxy E t h a n o l S t r o n t i u m Chromate 5-1365 106 Lo M i c r o n W h i t e B a r y t e s T a l c 399 N o v a c i t e L207A Raven 1020 S t e e l b a l l m i l l t o a 7 Hegman g r i n d . Letdown : Kel s o l 391 0-B2G-75 Triethylamine Cyme1 327 Water Butoxy E t h a n o l

Lbs. 71 . O 4.3 248.5 10.65 17.75 35.5 35.5 35.5 7.1

Gals. 8.20 0.71 29.87 1 .42 0.57 0.96 1.55 1.61 0.49

124.30 5.68 39.76 275.48 16.33

14.35 0.94 4.06 33.10 2.17

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 21.33 Pigment/Binder R a t i o : .72/1 P e r c e n t S o l i d s , Weight: 33.77 P e r c e n t S o l i d s , Volume: 24.42 V i s c o s i t y @ 25C, #4 Ford, Secs.: 30-40 Pounds/Gallon: 9 . 2 8 pH: 8.2-8.5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 235 Pounds/Gallon: 1 . 9 6

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i on 2106-30

I n c . : Waterborne Handbook:

175

176

Water-Based Paint Formulations

Bone W h i t e Semi-Gloss B a k i n a Enamel Pounds

Gal 1ons

181.9 12.3 16.5 2.3 153.2 6.9 15.3 2.5 1.3

20.67 2.02 2.19 0.31 4.38 0.20 0.84 0.14 0.16

C a r g i 11 Water R e d u c i b l e S h o r t T o f a A1 k y d 74-7451 T r i e t h y l ami ne E t h y l e n e G l y c o l Monobutyl E t h e r Byk-020 T i t a n i u m D i o x i d e T i - P u r e R-900 S y n t h e t i c I r o n O x i d e Y e l l o w 1103 F l a t t i n g Agent TS-100 A e r o s i l R972 Raybo 62-HydroF1 o Sand M i l l t o a 6-6 1 / 2 Hegman C a r g i 11 Water R e d u c i b l e S h o r t T o f a A1 k y d 74-7451 E t h y l e n e G l y c o l Monobutyl E t h e r Triethylamine C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Me1ami ne 23-2347 B u t y l Carbi t o 1 Byk-020 Byk-Catalyst-451 Sec-Butanol D e i o n i z e d Water

116.9 16.2 6.9

13.28 2.15 1 .14

33.9 4.6 1.5 6.6 16.1 216.4

3.35 0.58 0.21 0.87 2.39 25.97

D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Ad j u stmen t )

159.5

19.15

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 43.58 (By Volume): 31 - 0 8 Pigment t o B i n d e r R a t i o : 0 . 7 3 Pigment Volume C o n c e n t r a t i o n : 17.88 Weight Per G a l l o n : 9 . 7 1 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3 . 1 3 ( G r a m s / L i t e r ) : 375 W a t e r : C o s o l v e n t Weight R a t i o : 68.65:31.35 PH: 8 . 0 - 8 . 5 V i s c o s i t y #4 F o r d Cup: 78 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 350F Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 75/25 P e n c i l Hardness: Pass 2H % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 150 Reverse: 10 SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y :

F o r m u l a t i o n P1887-102C

Enamels -Baking

I77

Brown H i g h Gloss B a k i n a Enamel

Lbs.

M a t e r i a1 : Cyme1 303 n-Butanol 2-Butoxy E t h a n o l Hoover Brown 7148 Byk 104s

Gals.

67,20 13.10 13.05 86.40 2.00

6.75 1.93 1.74 2.68 0.25

335.05 30.04 399.17 1.54

34.05 4.51 47.92 0.19

Sand o r p e b b l e m i l l t o 7+ Hegman g r i n d . Letdown : A r o l on 465-64-80 T r i e t h y l ami ne Water Byk 301

Anal y s i s: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 7.6 P i g m e n t / B i n d e r R a t i o : 0.26/1 P e r c e n t S o l i d s , Weight: 44.49 P e r c e n t S o l i d s , Volume: 35.04 V i s c o s i t y @ 2 5 C , KU: 62-65 pH: 8.2-8.6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 288 Pounds/Gallon: 2.4 Resin/Melamine R a t i o : 80/20 P e r c e n t R e d u c t i o n t o 30", #2 Zahn Cup w i t h w a t e r : 25 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2552-1A

I n c . : Waterborne Handbook:

178

Water-Based Paint Formulations

C l e a r L o w VOC B a k i n g Enamel

Lbs. M a t e r i a1 : 486.6 Kel s o l 4069-WG4-55 Cymel 303 90.0 2.1 Byk 301 Water 304.1 Add t h e above m a t e r i a l s i n o r d e r under good a g i t a t i o n . Cure Schedule: 30 m i n u t e s a t 325F.

Gals. 54.25 9.00 0.25 36.50

Anal y s i s : P e r c e n t S o l i d s , Weight: 40.4 P e r c e n t S o l i d s , Volume: 36.0 V i s c o s i t y C 25C, #4 Ford, Secs. : 110 Pounds/Gallon: 8.8 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 168 Pounds/Gal l o n : 1 . 4 F o r m u l a t i o n 2316-73 W h i t e H i g h G l o s s B a k i n Q Enamel

Lbs.

Material : Kel s o l 4069-WG4-55 Water T i -Pure R-960 Premix t h e above m a t e r i a l s , 7+ Hegman.

119.0 149.4 261.9

t h e n sandmi 1 o r Debb e m i l l g r i n d t o

Letdown : K e l s o l 4069-WG4-55 Cymel 303 Byk 301 Water

327.4 81.9 2.7 132.5

Cure Schedule: 30 m i n u t e s a t 325F. Note: Reduce t o s p r a y v i s c o s i t y 20-30 Secs., Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : P i g m e n t / B i n d e r R a t i o : 0.8/1 .O P e r c e n t Sol i d s , Wei g h t : 5 4 . 8 P e r c e n t S o l i d s , Volume: 40.7 V i s c o s i t y h 25C, KU: 110 Pounds/Gal 1on : 1 0 . 7 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 146 Pounds/Gal l o n : 1 . 2

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2316-880

Gals. 13.27 17.94 7.86

Inc.:

36.50 8.19 0.33 15.91

#2 Zahn w i t h w a t e r .

19.3

Waterborne Handbook:

Enamels-Baking

275 G r a m s / L i t e r Gloss B l a c k B a k i n a Enamel Pounds

Gallons

116.4 4.2 7.5 1.6 12.8 155.3

13.14 0.56 1.23 0.20 0.87 18.64

C a r g i l l Water R e d u c i b l e Chain Stopped A l k y d 74-7407 160.7 18.14 E t h y l e n e G l y c o l Monobutyl E t h e r 9.1 Triethylamine 11 .o C a r g i l l High S o l i d s Polymeric Methylated Me1ami ne 23-2347 36.1 D e i o n i zed Water 336.9

1.21 1.81

C a r g i l l Water R e d u c i b l e C h a i n Stopped A 1 k y d 74-7487 E t h y l e n e G l y c o l Monobutyl E t h e r Triethylamine Byk-301 Special Black 4 Dei o n i zed Water Sand M i l l t o a 7 Hegman

3.76 40.44

P a i n t P r o p e r t ies : % N o n v o l a t i l e (By W e i g h t ) : 31.20 (By Volume): 27.48 Pigment t o B i n d e r R a t i o : 0.05 Pigment Volume C o n c e n t r a t i o n : 3 . 1 6 Weight Per G a l l o n : 8 . 5 2 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.29 ( G r a m s / L i t e r ) : 275 W a t e r : C o s o l v e n t Weight R a t i o : 84.00:16.00 V i s c o s i t y #4 F o r d Cup (Seconds) : 61 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 20 M i n u t e s a t 275F Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 97/89 P e n c i l Hardness: Pass B % C r o s s h a t c h Adhesion: 100 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y :

F o r m u l a t i o n P1848-L3

179

180

Water-Based Paint Formulations

Gloss B l a c k B a k i n a Enamel Pounds C a r g i 11 Water R e d u c i b l e Chain Stopped A1 kyd 74-7487 E t h y l e n e G l y c o l Monobutyl E t h e r Triethylamine By k - 30 1 Special Black 4 D e i o n i z e d Water

Gal l o n s

116.4 4.2 7.5 1.6 12.8 155.3

13.14 0.56 1 .23 0.20 0.87 18.64

160.7 9.1 1 1 .o

18.14 1.21 1.81

36.1 336.9

3.76 40.44

Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e Chain Stopped A 1 kyd 74-7487 E t h y l e n e G l y c o l Monobutyl E t h e r Triethylamine C a r g i l t High S o l i d s Polymeric Methylated Me1 ami ne 23-2347 D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 31.20 (By Volume): 27.48 Pigment t o B i n d e r R a t i o : 0.05 Pigment Volume C o n c e n t r a t i o n : 3.16 Weight Per G a l l o n : 8.52 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.29 (Grams/Li t e r ) : . 275 Water:Cosolvent Weight R a t i o : 84.00:16.00 V i s c o s i t y #4 Ford Cup (Seconds): 61 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 20 M i n u t e s a t 275F S u b s t r a t e : Cold R o l l e d S t e e l G l o s s (60/20): 97/89 P e n c i l Hardness: Pass B % C r o s s h a t c h Adhesion: 100

SOURCE:

Cargill,

Inc.:

CARGILL F o r m u l a r y : Formula P1848-L3

Enamels-Baking

181

Gloss W h i t e B a k i n a Enamel Pounds C a r g i 11 Water R e d u c i b l e O i 1 F r e e P o l y e s t e r 72-7289 141 .l D i m e t h y l e t h a n o l a m ine 8.7 C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d 49.2 Me1ami n e 23-2347 Dow C o r n i n g 1 4 A d d i t i v e 3.0 28.1 D e i o n i z e d Water T i t a n i u m D i o x i d e T i - P u r e R-902 246.0

Gallons 15.34 1.18 4.87 0.45 3.37 7.19

H i g h Speed t o a 7 Hegman C a r g i l l Water R e d u c i b l e O i l F r e e P o l y e s t e r 72-7289 121 . o Dimethylethanolamine 12.9 Dei o n i zed Water 439.0

13.15 1.75 52.70

Pai n t P r o p e r t i e s : % N o n v o l a t i l e (By W e i g h t ) : 46.91 (By Volume): 31.65 Pigment t o B i n d e r R a t i o : 1.00 P i gment V o l ume Concent r a t ion : 22.72 Weight Per G a l l o n : 1 0 . 4 9 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 0 4 ( G r a m s / L i t e r ) : 245 W a t e r : C o s o l v e n t Weight R a t i o : 83.87:16.13 PH: 8 . 0 - 8 . 5 V i s c o s i t y #2 Zahn Cup (Seconds): 50-60 T y p i c a l Cured F i l m P r o p e r t i e s : Cure S c h e d u l e : 10 M i n u t e s a t 350F Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 88/66 P e n c i l Hardness: Pass 3H % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 150 Reverse: 20 H u m i d i t y ( H o u r s ) : 166 G l o s s ( 6 0 / 2 0 ) : 86/62 P e n c i l Hardness: Pass 2H % C r o s s h a t c h Adhesion: 100 OUV ( H o u r s ) : 150 G l o s s ( 6 0 / 2 0 ) : 65/21 S a l t Spray ( H o u r s ) : 166 S c r i b e Creep ( m m ) : 2 S c r i b e B l i s t e r s : Medium Dense #4 S c r i b e C o r r o s i o n (mrn): 1 S u r f a c e B l i s t e r s : None Tape P u l l Removal ( m m ) : 4 SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y :

F o r m u l a t i o n P1877-49D

182

Water-Based Paint Formulations

G l o s s W h i t e Bakinq Enamel C a r g i l l Water R e d u c i b l e S h o r t Soya A l k y d 74-7450 C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Me1ami ne 23-2347 E t h y l e n e G l y c o l Monobutyl E t h e r Byk-301 T i t a n i u m D i o x i d e T i - P u r e R-900

Pounds

Gallons

150.2

17.78

35.8 10.0 3.0 282.4

3.54 1.33 0.37 8.07

217.3 22.0 18.0 309.5

25.72 3.64 2.40 37.15

H i g h Speed t o a 7 Hegman C a r g i l l Water R e d u c i b l e S h o r t Soya A l k y d 74-7450 T r i e t h y l amine E t h y l e n e G l y c o l Monobutyl E t h e r D e i o n i z e d Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 5 5 . 0 4 (By Volume): 3 8 . 9 7 Pigment t o B i n d e r R a t i o : 0 . 9 6 Pigment Volume C o n c e n t r a t i o n : 20.71 Weight Per G a l l o n : 10.48 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 5 8 ( G r a m s / L i t e r ) : 309 W a t e r : C o s o l v e n t Weight R a t i o : 6 5 . 6 6 : 3 4 . 3 4 V i s c o s i t y Krebs-Stormer (KU): 65 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 350F Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 95/82 P e n c i l Hardness: Pass 2H % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 120 Reverse: 20 S a l t Spray ( H o u r s ) : 96 S c r i b e Creep ( m m ) : 8

SOURCE:

Cargill,

I n c . : CARGILL F o r m u l a r y :

Formula P1883A-7450

Enamels-Baking

G l o s s W h i t e B a k i n g Enamel C a r g i l l Water R e d u c i b l e C h a i n Stopped A 1 k y d 74-7474 Dimethylethanolamine E t h y l e n e G l y c o l Monobutyl E t h e r T i t a n i u m D i o x i d e T i -Pure R-900 Byk-020 Byk-301 Dei o n i zed Water

Pounds

Gallons

104.4 6.4 14.4 215.2 1.7 1.1 196.0

11 .87 0.86 1.92 6.15 0.23 0.14 23.54

148.5 9.0 13.7

16.87 1.22 1 .82

25.9 1.7 271.5

2.57 0.21 32.60

H i g h Speed t o a 7 Hegman C a r g i 11 Water R e d u c i b l e C h a i n Stopped A1 k y d 74-7474 Dimethylethanolamine E t h y l e n e G l y c o l Monobutyl E t h e r C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Melami ne 23-2347 S u r f y n o l 104 E Dei o n i zed Water

Pai n t P r o p e r t ie s : % N o n v o l a t i l e (By W e i g h t ) : 42.83 (By Volume): 28.74 Pigment t o B i n d e r R a t i o : 0 . 9 9 Pigment Volume C o n c e n t r a t i o n : 2 1 . 4 0 Weiaht Per G a l l o n : 10.10 T h e o r e t i c a l VOC (Pounds/Gal l o n ) : 2.50 ( G r a m s / L i t e r ) : 300 W a t e r : C o s o l v e n t Weight R a t i o : 81.OO:lQ.OO V i s c o s i t y #4 F o r d Cup (Seconds): 47 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 20 M i n u t e s a t 275F Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 91/75 P e n c i l Hardness: Pass HB Impact ( I n . L b s . ) : D i r e c t : 150 Reverse: 35 SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P1848-157

183

184

Water-Based Paint Formulations

Green Gloss ~ _ _ F o r c e Cure E n a m e l

Lbs.

M a t e r i a l :. _____. Water Triethylamine K e l s o l 3902-864-75 Add i n o r d e r l i s t e d : Propasol P C o b a l t Hydrocure 12% Manganese Cem-All Medi um Chrome Ye1 low X-3356 Heucophthal B l u e R F BT-627-D Lactimon WS Foamki 11 6390 Sand m i l l t o 7 Hegman g r i n d . Letdown : Water T r i e t h y l ami ne K e l s o l 3902-864-75 sec-Butanol Propasol P

Gals. 13.40 1.11 19.15

5.60 2.24 2.56 94.82 39.09 4.14 4.47

0.76 0.29 0.29 2.04 2.97 0.49 0.63

334.95 6.74 139.65 5.58 5.59

Analysis: P i gment V o l ume C o n c e n t r a t i o n , Pigment/Binder R a t i o : . 4 8 / 1 P e r c e n t S o l i d s , Weight: 39.9 P e r c e n t S o l i d s , Volume: 28.0 Pounds/Gallon: 9 . 3 1 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 293 Pounds/Gallon: 2 . 4 6

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 1701-3

111.62 6.74 167.56

P e r c e n t : 11 . 5

I n c . : Waterborne Handbook:

40.21 1 .ll 15.96 0.83 0.76

Enamels -Baking

H i q h G l o s s B l a c k B a k i n a Enamel C a r g i l l Water R e d u c i b l e Epoxy E s t e r 73-7331 E t h y l e n e G l y c o l Monobutyl E t h e r Dimethylethanolamine By k-30 1 Special Black 4 D e i o n i z e d Water

Pounds

Gallons

113.4 4.1 7.3 1.6 12.5 166.9

13.42 0.55 0.99 0.19 0.85 20.03

156.6 17.8 10.7

18.53 2.37 1.45

26.0 2.0 323.2

2.57 0.25 38.80

Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e Epoxy E s t e r 73-7331 E t h y l e n e G l y c o l Monobutyl E t h e r Dimethylethanolamine C a r g i 11 H i gh S o l i d s Monomeric M e t h y l a t e d Melami ne 23-2347 Nacure 155 Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 27.24 (By Volume): 24.80 Pigment t o B i n d e r R a t i o : 0 . 0 6 P i gment Vol ume Concent r a t ion : 3.40 Weight Per G a l l o n : 8.42 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 9 8 ( G r a m s / L i t e r ) : 357 W a t e r : C o s o l v e n t Weight R a t i o : 80.00:20.D0 pH: 8 . 4 6 V i s c o s i t y #4 F o r d Cup (Seconds): 41 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 300F Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 95/75 P e n c i l Hardness: Pass HB Impact ( I n . L b s . ) : D i r e c t : 160 Reverse: 140 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1848-170

185

186

Water-Based Paint Formulations

H i g h Gloss

G r a y Bakina E n a m e l

C a r g i l l Water R e d u c i b l e S h o r t T o f a A l k y d 74-7461 D i m e t h y l e t h a n o l ami ne T i t a n i u m D i o x i d e T i - P u r e R-900 Special Black 4 P a t c o t e 577 Byk-301 E t h y l e n e G l y c o l Monobutyl E t h e r D e i o n i z e d Water

Pounds

Gal l o n s

78.4 4.9 113.0 5.6 2.4 2.1 1.3 97.0

9.23 0.66 3.23 0.38 0.34 0.27 0.18 11.64

202.4

23.81

27.3 15.0 2.1 7.2 368.9

2.71 2.04 0.26 0.96 44.29

Sand M i l l t o a 7-8 Hegman C a r g i l l Water R e d u c i b l e S h o r t T o f a A l k y d 74-7461 C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Me1ami ne 23-2347 D i m e t h y l e t h a n o l a m i ne Nacure 155 E t h y l e n e G l y c o l Monobutyl E t h e r D e i o n i zed Water

Pai n t P r o p e r t i e s : % N o n v o l a t i l e (By W e i g h t ) :

37.23 (By Volume): 27.39 Pigment t o B i n d e r R a t i o : 0 . 5 2 Pigment Volume C o n c e n t r a t i o n : 13.18 Weight Per G a l l o n : 9.28 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 6 4 (Grams/Li t e r ) : 31 7 Water: Cosol v e n t Weight R a t i 0 ; 8 0 . 0 0 : 20.00 pu: 8.7 V i s c o s i t y #4 F o r d Cup (Seconds): 44

T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 325F S u b s t r a t e : Cold R o l l e d S t e e l G l o s s ( 6 0 / 2 0 ) : 93/76 P e n c i l Hardness: Pass HB Impact ( I n . L b s . ) : D i r e c t : 160 Reverse: 60

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P1848-169A

Enamels-Baking

H i g h Gloss L i Q h t B l u e B a k i n a Enamel

Cargill Water Reducible Short Soya Alkyd 74-7450 Dimethylethanolamine Heliogen Blue L 6875 F Patcote 577 Ti tani um Dioxide Ti -Pure R-900 Deionized Water

Pounds

Gal 1 ons

124.6 9.9 0.9 1.3 154.4 151 . E

14.74 1.34 0.06 0.18 4.41 18.22

117.6

13.92

23.3 7.0 1.8 29.4 330.9

2.31 0.96 0.22 3.91 39.73

Sand Mill to a 7 Hegman Cargill Water Reducible Short Soya Alkyd 74-7450 Cargill High Solids Monomeric Methylated Me1 ami ne 23-2347 Dimethylethanolamine Nacure 1 5 5 Ethylene Glycol Monobutyl Ether Deionized Water

Pa n t P r o p e r t i es : % Nonvolatile (By Weight): 3 6 . 6 8 (By Volume): 2 4 . 8 4 Pigment to Binder Ratio: 0.80 Pigment Volume Concentration: 1 8 . 0 2 Weight Per Gallon: 9 . 5 3 Theoretical VOC (Pounds/Gallon): 2 . 8 7 (Grams/Literl: 344 Water:Cosolvent Weight’Ratio: 8 0 . 0 0 : 2 0 . 0 0 pH: 8 . 8 2 Viscosity #4 Ford Cup (Seconds): 4 8 Typical Cured Film P r o p e r t i e s : Cure Schedule: 1 0 Minutes at 325F Substrate: Cold Rolled Steel Dry Film Thickness (Mils): 1 1 . 5 Gloss ( 6 0 / 2 0 ) : 9 0 / 7 0 Pencil Hardness: Pass 2H % Crosshatch Pdhesion: 100 Impact (1n.Lbs.): Direct: 130 Reverse: 5 MEK Double Rubs: Pass 100 SOURCE: Cargill, Inc.: CARGILL Formulary: Formula P1900-4B

187

I88

Water-Based Paint Formulations

H i a h G l o s s W h i t e B a k i n a Enamel Pounds

Gallons

84.7 5.4

9.41 0.73

24.6 174.3 1.5 126.7

2.44 4.98 0.19 15.13

189.7 10.8 3.5 16.5 349.2

21 .08 1.47 0.48 2.18 41.91

C a r g i 11 Water R e d u c i b l e Coconut O i 1 A1 kyd

74-7455 Dimethylethanolamine C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Me1ami ne 23-2347 T i t a n i u m D i o x i d e T i - P u r e R-900 Byk P 104 S Dei o n i zed Water H i g h Speed t o a 7 Hegman C a r g i l l Water R e d u c i b l e Coconut O i l A l k y d

74-7455 Dimethylethanolamine Byk-020 E t h y l e n e G l y c o l Monopropyl E t h e r Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 39.76 (By Volume): 27.06 Pigment t o B i n d e r R a t i o : 0 . 8 0 Pigment Volume C o n c e n t r a t i o n : 18.41 Weight Per G a l l o n : 9.86 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.77 ( G r a m s / L i t e r ) : 332 Water:Cosolvent Weight R a t i o : 80.00:20.00 pH:

8.35

V i s c o s i t y #4 F o r d Cup (Seconds): 52 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 325F S u b s t r a t e : Cold R o l l e d S t e e l G l o s s (60/20): 91/70 P e n c i l Hardness: Pass HB % C r o s s h a t c h Adhesion: 100 Impact ( I n . Lbs.): D i r e c t : 40 Reverse: <.5 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1848-1826

Enamels-Baking

189

H i a h G l o s s W h i t e B a k i n q Enamel C a r g i l l Water R e d u c i b l e A c r y l i c 17-7240 Dimethylethanolamine Dei o n i zed Water CT- 136 T i t a n 1 um D i o x i d e T i -Pure R-902

Pounds 43.88 4.43 109.70 9.62 134.72

Gallons 5.07 0.60 13.17 1.14 3.94

148.57 14.82

17.17 2.01

33.68 429.16 13.47 1.93

3.34 51.52 1.79 0.25

Sand M i l l t o a 7 Hegman C a r g i l l Water R e d u c i b l e A c r y l i c 17-7240 Dimethylethanolamine C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Me1ami ne 23-2347 D e i o n i z e d Water E t h y l e n e G l y c o l Monobutyl E t h e r Byk 306

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 32.64 (By Volume): 22.26 Pigment t o B i n d e r R a t i o : 0 . 7 8 Pigment Volume C o n c e n t r a t i o n : 17.70 Weight Per G a l l o n : 9 . 4 4 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 7 5 ( G r a m s / L i t e r ) : 329.06 W a t e r : C o s o l v e n t Weight R a t i o : 88.60:11 .40 pH: 8 . 4 0 V i s c o s i t y #4 F o r d Cup (Seconds): 36 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s @ 350F S u b s t r a t e : BlOOO Dry F i l m Thickness: 1.0 G l o s s ( 6 0 / 2 0 ) : 91/71 P e n c i l Hardness: 2H % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 90 Reverse: 5 H u m i d i t y ( H o u r s ) : 250 B1 is t e r s : none % C r o s s h a t c h Adhesion: 100 S a l t Spray ( H o u r s ) : 250 S c r i b e Creep ( m m ) : 2 . 5 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula 1855-91

190

Water-Based Paint Formulations

High-Gloss W h i t e B a k i n g F i n i s h Roller M i l l Grind R o l l e r m i l l grind: (3 passes): A c r y l o i d WR-97 ( a s s u p p l i e d ) D i m e t h y l ami n o e t h a n o l Rutile titanium dioxide

300.0 7.8 300.0

Letdown : R o l l e r m i l l g r i n d above A c r y l o i d WR-97 ( a s s u p p l i e d ) U f o r m i t e MM-83 ( a s s u p p l i e d ) Dimethylami n o e t h a n o l Water

607.8 127.5 93.6 3.3 782.4

Formulation Constants: Pigment/binder r a t i o : 44.5/55.5 A c r y l ic/mel ami ne r a t i 0 : 8 0 / 2 0 Sol i d s c o n t e n t : 41 .7% W a t e r / s o l v e n t r a t i o , b y volume: 80/20 Spray v i s c o s i t y , No. 4 F o r d cup: 30 seconds VOC, l b s / g a l ( c a l c u l a t e d ) : 2 . 2 E x p e r i m e n t a l F o r m u l a t i o n CTS-197-1 H i gh-Gloss W h i t e B a k i n g F i n i sh Cowl es D i ssol v e r G r i nd

Charge t o t h e t a n k and m i x a t l o w speed: A c r y l o i d WR-97 (50% s o l i d s reduced w i t h w a t e r ) 150.0 Water 110.0 Add g r a d u a l l y w h i l e i n c r e a s i n g speed: Rutile titanium dioxide 340.0 G r i n d a t h i g h speed f o r 12 t o 15 m i n u t e s t h e n reduce speed and letdown w i t h t h e f o l l o w i n g : Water 734.1 D i m e t h y l a m i n o e t h a n o l (OMAE) 9.8 A c r y l o i d WR-97 ( a s s u p p l i e d ) 377.6 U f o r m i t e MM-83 ( a s s u p p l i e d ) 106.1 F o r m u l a t i o n Constants: Pigment/binder r a t i o : 44.5/55.5 A c r y l i c / m e l ami ne r a t i0 : 80/20 Sol i d s c o n t e n t : 41.7% W a t e r / s o l v e n t r a t i o , by volume: 80/20 Spray v i s c o s i t y , No. 4 F o r d cup: 30 seconds VOC, l b s / g a l ( c a l c u l a t e d ) : 2 . 2

SOURCE:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYLOID WR-97: E x p e r i m e n t a l F o r m u l a t i o n CTS-197-2

Enamels -Baking

191

H i ah-Gloss W h i t e B a k i nQ F i n i s h Sand M i 11 G r i n d Charge t o sand m i l l and g r i n d ( 1 5 m i n u t e s ) : A c r y l o i d WR-97 (50% s o l i d s reduced w i t h w a t e r ) R u t i l e t i t a n i um d i o x i d e Water Sand F i l t e r t h e n l e t d o w n as f o l l o w s : F i 1t e r e d g r i n d above A c r y l o i d WR-97 ( a s s u p p l i e d ) U f o r m i t e MM-83 ( a s s u p p l i e d ) Dimethylami n o e t h a n o l (DMAE) Water

20 50 30 100 89.00 50.71 13.88 1.32 84.62

F o r m u l a t i o n Constants: P i g m e n t / b i nder r a t i o : 44.5/55.5 A c r y l i c / m e l a m i n e r a t i o : 80/20 Sol i d s c o n t e n t : 41 .7% W a t e r / s o l v e n t r a t i o , b y volume: 80/20 V i s c o s i t y , No. 4 F o r d cup: 30 seconds VOC, l b s / g a l ( c a l c u l a t e d ) : 2.2 Hiah-Gloss W h i t e B a k i n g F i n i s h Pebble M i l l G r i n d Pebble m i l l g r i n d : ( 1 6 h o u r s ) A c r y l o i d WR-97 (50% s o l i d s reduced w i t h w a t e r ) Rut i 1e t i t a n ium d i o x i de Water Letdown : Pebble m i l l g r i n d above A c r y l o i d WR-97 ( a s s u p p l ied) U f o r m i t e MM-83 ( a s s u p p l i e d ) D i m e t h y l ami n o e t h a n o l Water

20.0 50.0

30.0 100.0 57.0 15.6 1.5 95.0

Formulation constants: P i g m e n t / b i n d e r r a t i o : 44.5/55.5 A c r y l i c / m e l a m i n e r a t i o : 80/20 Sol i d s c o n t e n t : 41 .7% W a t e r / s o l v e n t r a t i o , by volume: 80/20 Spray v i s c o s i t y , No. 4 F o r d cup: 30 seconds VOC, l b s / g a l ( c a l c u l a t e d ) : 2.2

SOURCE:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYLOID WR-97: E x p e r i m e n t a l F o r m u l a t i o n CTS-197-4

192

Water -Based Paint Formulations

Low TemDerature Cure Black Bakina Enamel Pounds Cargi 1 1 Water Reducible Short Tofa A1 kyd 74-7451 Triethylamine By k-30 1

Special Black 4 Deionized Water

Gallons

62.4 4.1 1 .o 12.1 91.4

7.09 0.68 0.12 0.82 10.97

180.1 13.2

20.47 2.17

86.6 8.8 8.4 386.3

9.02 1.17 1 .ll 46.38

Sand Mill to a 7 Hegman Cargill Water Reducible Short Tofa Alkyd 74-7451 Triethylamine Cargill High Solids Polymeric Methylated Me1 ami ne 23-2317 Ethylene Glycol Monobutyl Ether Bvk-Catalvst-451 O k oni zed-Water

Pa nt Properties: % Nonvolatile (By Weight): 30.11 (By Volume): 25.84 Pigment to Binder Ratio: 0.05 Pigment Volume Concentration: 3.17 Weight Per Gallon: 8.54 Theoretical VOC (Pounds/Gallon): 2.80 (Grams/Liter): 336 Water:Cosolvent Weight Ratio: 80.00:20.00 pH: 8.30 Viscosity #4 Ford Cup (Seconds): 31 Typical Cured Film Properties: Cure Schedule: 20 Minutes at 250F Substrate: Cold Rolled Steel Gloss (60/20): 97/72 Pencil Hardness: Pass H % Crosshatch Adhesion: 65 Impact (In. Lbs.): Direct: 80 Reverse: (5 SOURCE: Cargill, Inc.: CARGILL Formulary: Formula P1887-308

Enamels -Baking

I93

Red Baking Enamel

C a r g i l l Water R e d u c i b l e Chain Stopped A1 kyd 74-7487 Triethylamine C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Melami ne 23-2347 E t h y l e n e G l y c o l Monobutyl E t h e r By k-30 1 13-3061 Novo Perm Red F5RK X-2806 Red Orange D e i o n i z e d Water

Pounds

Gallons

115.5 6.0

13.04 0.99

27.8 22.2 2.0 40.2 30.2 277.8

2.75 2.96 0.25 3.55 0.65 33.34

145.5 6.0 7.8 200.0

16.43 0.99 1.04 24.01

Pebble M i l l t o a 7.5 Hegman C a r g i l l Water R e d u c i b l e Chain Stopped A1 kyd 74-7407 T r i e t h y l ami ne E t h y l e n e G l y c o l Monobutyl E t h e r D e i o n i zed Water

Pai n t P r o p e r t i es : % N o n v o l a t i l e (By W e i g h t ) : 34.97 (By Volume): 29.32 Pigment t o B i n d e r R a t i o : 0 . 3 0 Pigment Volume C o n c e n t r a t i o n : 14.34 Weight Per G a l l o n : 8 . 8 1 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.23 ( G r a m s / L i t e r ) : 268 Water:Cosolvent Weight R a t i o : 8 3 . 3 8 : 1 8 . 6 2 R e s i n / C r o s s l i n k e r R a t i o : 88/12 pH: 8 . 1 - 8 . 5 V i s c o s i t y Krebs-Stormer ( K U ) : 60-65 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 12 M i n u t e s a t 350F Substrate: Cold Rolled Steel G l o s s ( 6 0 / 2 0 ) : 86/61 P e n c i l Hardness: Pass F Impact ( I n . L b s . ) : D i r e c t : 120 H u m i d i t y ( H o u r s ) : 120 81 is t e r s : None % C r o s s h a t c h Adhesion: 99 S a l t Spray ( H o u r s ) : 96 S c r i b e Creep (mm): 8 S u r f a c e B l i s t e r s : None S u r f a c e C o r r o s i o n : None SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : F o r m u l a t i o n P1883-85

I94

Water-Based Paint Formulations

Semi -Gloss Gray Baki nn Enamel Pounds Cargi 1 1 Water Reduci bl e Polyester 72-7203 156.9 Triethylamine 7.7 Cargill High Solids Monomeric Methylated Me1 ami ne 23-2347 46.3 Dei oni zed Water 55.2 Dow Corning 14 2.7 Titanium Dioxide Ti-Pure R-902 145.9 Imsil A-10 97.3 Special Black 4 2.9

-~ Gal 1 ons

17.63 1.27 4.59 6.62 0.41 4.27 4.41 0.20

Sand Mill to a 7 Hegman Cargill Water Reducible Polyester 72-7203 91.8 OK 500 9.7 Triethylami ne 13.0 Deionized Water 336.1 Deionized Water (Hold f o r Viscos Ad] ustmen t )

59.7

10.32 0.62

2.15 40.34 7.17

Paint Prooerties: % Nonvolatile (By Weight): 47 69 (By Volume): 33.12 Pigment to Binder Ratio: 1.10 Pi gment Vol ume Concent rat i on : 28.65 Weight Per Gallon: 10.25 Theortical VOC (Pounds/Gallon): 1.86 (Grams/Liter): 223 Water:Cosolvent Weight Ratio: 84.09:15.91 pH: 8.0-8.5 Viscosity # 2 Zahn Cup (Seconds): 80 Typical Cured Film Properties: Cure Schedule: 15 Minutes at 350F Substrate: Cold Rolled Steel Gloss (60/20): 58/9 Pencil Hardness: Pass 2H % Crosshatch Adhesion: 100 Impact (In. Lbs.): Direct: 160 Reverse: 30 Humi di ty (G1oss 60/20) : Initial: 58/9 170 Hours: 65/15 Observations: Swelling Salt Spray (Hours): 150 Scribe Creep (mm): 6 Scribe Blisters: Dense #4 Scribe Corrosion (mm): 1 SOURCE: Cargill, Inc.: CARGILL Formulary: Formula P1877-56D

Enamels -Baking

S i l v e r M e t a l l i c Bake Enamel M a t e r i a1 : Lbs. Hydro-Paste 8726 9.87 Butoxy Ethanol 16.17 Reduce p a s t e w i t h s o l v e n t s l o w l y w i t h a g i t a t i o n .

Gals. 0.77 2.16

A r o l o n 557 ( 5 0 NV) See n e u t r a l i z a t i o n below

319.52

38.22

Cyme1 373 T r i - n - b u t y l Phosphate 10% DC-29 i n B u C e l l Water

81.06 9.70 5.40 413.99

7.72 .82 .54 49.77

Resin N e u t r a l i z a t i o n : A r o l o n 557-8-70 D i m e t h y l e t h a n o l ami ne Water

Lbs. 714.2 50.0 235.8

Percent N o n v o l a t i l e : 50.0 pH: 8.5 Pounds Per G a l l o n : 8 . 3 Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 2 . 0 P i gment/Bi n d e r R a t i 0 : .03/1 P e r c e n t S o l i d s , W e i g h t : 27.5 P e r c e n t S o l i d s , Volume: 2 3 . 8 V i s c o s i t y @ 25C, #4 F o r d , Secs.: 65-75 Pounds/Gallon: 8 . 5 5 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i ng w a t e r ) : G r a m s / L i t e r : 349.0 Pounds/Gallon: 2.91

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 1961-65

Inc.:

Waterborne Handbook:

195

1%

Water-Based Paint Formulations

Tan Semi -Gloss B a k i nq Enamel M a t e r i a1 : Kel s o l 3961 -82G-75 Butoxy Ethanol Triethylamine Water T r i t o n X-405 Raven 1020 R . I .O. R-4098 Y.I.O. Y-2288 T i t a n o x 2020

Lbs.

Gals.

103.32 10.33 8.27 103.32 2.07 1.03 1.03 10.33 123.98 151.87 1.03

12.15 1.38 1.36 12.40 0.26 0.07 0.02 0.31 3.64 6.75 0.06

103.32 70.25 10.33 20.66 8.27 303.75

12.15 7.17 1.38 3.06 1.36 36.48

Atomi t e Cab-0-Si 1 M-5 Pebble m i l l o r sand m i l l t o 6 + Hegman g r i n d . Letdown : Kel s o l 3961 -826-75 Cyme1 370 Butoxy Ethanol n-Butanol T r i e t h y l ami ne Water

Analysis: 33.06 Pigment Volume C o n c e n t r a t i o n , P e r c e n t P i g m e n t / B i n d e r R a t i o : 1.4/1 P e r c e n t S o l i d s , W e i g h t : 47.98 P e r c e n t S o l i d s , Vol ume: 32.80 V i s c o s i t y @ 25C. KU: 65-70 Pounds/Gallon: 10.33 pH: 8.2-8.6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 284 Pounds/Gallon: 2.37 Resin/Melamine R a t i o : 70/30 % R e d u c t i o n t o 30", #2 Zahn cup, w i t h w a t e r : 10

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2185-45

I n c . : Waterborne Handbook:

Enamels-Baking

197

V e r v Low VOC G l o s s Gray B a k i n q Enamel C a r g i 11 Waterborne P o l y e s t e r D i s p e r s i o n 108-1 775 C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Melami ne 23-2347 T i t a n i um D i o x i d e T i -Pure R-902 S p e c i a l B l a c k 4A Aerosil R972

Pounds

Gal 1ons

175.1

19.38

56.8 164.0 3.3 2.1

5.62 4.79 0.22 0.12

595.6 3.0 8.0 2.0

67.68 0.45 0.96 0.27

Sand M i l l t o a 7 Hegman C a r g i 11 Waterborne P o l y e s t e r D i s p e r s i on 108-1775 Dow C o r n i n g 14 D e i o n i z e d Water D i m e t h y l e t h a n o l a m i n e ( N o t e #1 and #2)

F o r m u l a t i n g Notes: 1 . The amount o f d i m e t h y l e t h a n o l a m i n e n e c e s s a r y t o o b t a i n t h e f i n a l p a i n t pH o f 8 . 0 - 8 . 3 w i l l v a r y more t h a n t y p i c a l w a t e r r e d u c i b l e systems. 2 . A d j u s t t h e p a i n t t o i t s f i n a l pH i m m e d i a t e l y a f t e r p r o c e s s i n g t o prevent s e t t l i n g . Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 45.33 ( B y Volume): 33.92 Pigment t o B i n d e r R a t i o : 0 . 5 9 Pigment Volume C o n c e n t r a t i o n : 1 5 . 1 3 Weight Per G a l l o n : 10.10 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 0.70 ( G r a m s / L i t e r ) : 84 pH: 8 . 0 - 8 . 3 V i s c o s i t y #2 Zahn (Seconds): 50-60 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 350F Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 87/71 P e n c i l Hardness: 3H % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 160 Reverse: 120 QCT H u m i d i t y (672 h o u r s ) : B1 is t e r s : None P e r c e n t G l o s s R e t e n t i o n : 93/82 S a l t Spray (168 h o u r s ) : S c r i b e Creep (mm): 3-6 S c r i b e B l i s t e r s : #8 Medium S u r f a c e B l i s t e r s : None S u r f a c e C o r r o s i o n : None SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y :

Formula P1877-680

198

Wafer-Based Paint Formulations

V e r y L o w VOC Gloss Rose B a k i n q Enamel C a r g i 11 Waterborne P o l y e s t e r D i s p e r s i o n 108-1 775 C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Melami ne 23-2347 T i t a n i um D i o x i d e T i -Pure R-902 M o n a s t r a l Red Y RT-759-D A e r o s i l R972

Pounds

Gallons

200.6

22.80

56.1 34.9 35.1 2.0

5.55 1.02 2.91 0.11

560.6 3.3 2.2

63.70 0.50 0.30

25.9

3.11

Sand M i l l t o a 7 Hegman C a r g i l l Waterborne P o l y e s t e r D i s p e r s i o n 108-1 775 Dow C o r n i n g 14 Dimethylethanolamine D e i o n i z e d Water ( H o l d f o r v i s c o s i t y adjustment ) Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 3 8 . 7 6 (By Volume): 32.48 Pigment t o B i n d e r R a t i o : 0 . 2 5 Figment Volume C o n c e n t r a t i o n : 12.45 Weight Per G a l l o n : 9 . 2 1 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 0 . 7 3 ( G r a m s / L i t e r ) : 88 pH: 8 . 0 - 8 . 3 V i s c o s i t y #2 Zahn (Seconds): 50-60 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 350F Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 87/59 P e n c i l Hardness: 2H % C r o s s h a t c h Adhesion: 100 Impact Resistance ( I n L b s . ) : D i r e c t : 160 Reverse: 60 H u m i d i t y (188 h o u r s ) : 81 is t e r s : None % C r o s s h a t c h Adhesion: 99 S a l t Spray (188 h o u r s ) : S c r i b e Creep ( m m ) : 1-9 S c r i b e B l i s t e r s : #2-#4 Medium Dense S u r f a c e B l i s t e r s : None S u r f a c e C o r r o s i o n : None

SOURCE: C a r g i l l , I n c . : CARGILL F o r m u l a r y : Formula P1977-745

Enamels -Baking

I99

Very Low VOC Gray B a k i n q Enamel Pounds

-~ Gal 1 ons

C a r g i l l Waterborne P o l y e s t e r D i s p e r s i o n

72-7231 172.3 19.80 72-7231 must be a t a minimum pH o f 6.7 f o r d i s p e r s i n g C a r g i 11 H i gh Sol i d s Monomeric M e t h y l a t e d Me1 ami ne 23-2347 T i t a n i u m D i o x i d e T i - P u r e R-902 S p e c i a l B l a c k 4A A e r o s i l R972

55.9 161.4 3.2 2.1

5.53 4.72 0.22 0.11

586.1 2.9

67.37 0.44

4.9 4.9 3.9

0.57 0.59 0.65

Sand M i l l t o a 7 Hegman C a r g i l l Waterborne P o l y e s t e r D i s p e r s i o n

72-7231 Dow C o r n i n g 14 A d d i t i v e Premix t h e f o l l o w i n g , t h e n add: A d d i t o l XW 395 D e i o n i zed Water T r i e t h y l a m i n e ( N o t e #2 and # 3 )

Formul a t i ng Notes : 1 . 72-7231 must be a t a minimum pH o f 6.7 f o r d i s p e r s i n g . 2. The amount o f t r i e t h y l a m i n e necessary t o o b t a i n t h e f i n a l pH o f 8 . 0 t o 8.3 w i l l v a r y . 3. A d j u s t t h e p a i n t t o i t s f i n a l pH i m m e d i a t e l y a f t e r p r o c e s s i n g t o prevent s e t t l i n g . Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 45.39 (By Volume): 34.41 Pigment t o B i n d e r R a t i o : 0.58 Pigment Volume C o n c e n t r a t i o n : 14.68 Weight Per G a l l o n : 9.98 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 0 . 7 6 ( G r a m s / L i t e r ) : 91 pH: 8.0-8.3

V i s c o s i t y # 2 Zahn (Seconds) : 35-45 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 m i n u t e s a t 350F Substrate: Cold Rolled Steel G l o s s (60/20): 86/70 P e n c i l Hardness: Pass H % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 160 Reverse: 120

SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P1877-688

200

Water-Based Paint Formulations

V e r y Low VOC Gray Baking Enamel -~ Pounds Gal l o n s C a r g i l l Waterborne P o l y e s t e r D i s p e r s i o n 72-7232 135.0 16.71 72-7232 must be a t a minimum pH o f 6 . 7 f o r d i s p e r s i n g O e i o n i zed Water 22.5 2.71 C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Melami ne 23-2347 51.1 5.06 T i t a n i u m D i o x i d e T i - P u r e R-902 147.6 4.32 S p e c i a l B l a c k 4A 3.0 0.20 A e r o s i l R972 1.9 0.10

Sand M i l l t o a 7 Hegman C a r g i 11 Waterborne P o l y e s t e r D i s p e r s i o n 72-7232 O e i o n i zed Water Byk 301 Premix t h e f o l l o w i n g ,

459.5 76.6 2.7

56.86 9.19 0.33

4.5 4.5 3.6

0.52 0.54 0.59

23.9

2.87

t h e n add:

A d d i t o l XW 395 D e i o n i z e d Water T r i e t h y l a m i n e ( N o t e #2 and #3) D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Ad] u stmen t )

Formulating Notes: 1 . 72-7232 must be a t a minimum pH o f 6 . 7 f o r d i s p e r s i n g . 2 . The amount o f t r i e t h y l a m i n e n e c e s s a r y t o o b t a i n t h e f i n a l pH o f 8 . 0 t o 8 . 3 w i l l v a r y . 3 . A d j u s t t h e p a i n t t o i t s f i n a l pH i m m e d i a t e l y a f t e r p r o c e s s i n g t o prevent s e t t l i n g . Pai n t P r o p e r t i e s : % N o n v o l a t i l e (By W e i g h t ) : 44.34 (By Volume): 32.72 Pigment t o B i n d e r R a t i o : 0 . 5 8 P i gment Vol ume Concent r a t ion : 1 4 . 1 2 Weight Per G a l l o n : 9 . 3 6 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 0 . 6 3 ( G r a m s / L i t e r ) : 76 p y : 8.0-8.3 V i s c o s i t y #2 Zahn (Seconds): 50-60 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 350F Substrate: Cold Rolled Steel G l o s s ( 6 0 / 2 0 ) : 91/74 P e n c i l Hardness: Pass H SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y : Formula P1877-68J

Enamels-Baking

V e r y Low VOC Semi -G1 oss B1ue_ B a k i ng Enamel C a r g i l l Waterborne P o l y e s t e r D i s p e r s i o n 72-7230 C a r g i 11 H i g h S o l i d s Monomeric M e t h y l a t e d Melamine 23-2347 H e l i o g e n B l u e L 7071F T i t a n i u m D i o x i d e T i - P u r e R-902 I m s i l A-10 A e r o s i l R972

___ Pounds

___. Gal l o n s

142.6

16.39

53.0 10.0 79.9 93.9 1.9

5.25 0.75 2.34 4.26 0.10

567.3 9.4 3.0 7.2 6.3

65.20 0.59 0.45 0.83 1.04

23.3

2.80

Sand M i l l t o a 7 Hegman C a r g i l l Waterborne P o l y e s t e r D i s p e r s i o n 72-7230 OK 500 Dow C o r n i n g 1 4 A d d i t i v e A d d i t o l XW 395 Triethylamine D e i o n i z e d Water (Hold f o r V i s c o s i t y Adjustment) P a i nt P r o p e r t ies : % N o n v o l a t i l e (By W e i g h t ) : 46.60 (By Volume): 3 5 . 7 3 Pigment t o B i n d e r R a t i o : 0 . 7 2 P i gment Vol ume Concent r a t ion : 22.50 Weight Per G a l l o n : 9.98 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 0 . 7 7 ( G r a m s / L i t e r ) : 92 PH: 8 . 0 - 8 . 3 V i s c o s i t y #2 Zahn Cup (Seconds): 35-45 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 15 M i n u t e s a t 350F S u b s t r a t e : Sheet M o l d i n g Compound Dry F i l m Thickness ( M i l s ) : 1 . 0 Gloss (60/20): 50/6 C r o s s h a t c h Adhesion ( % R e m a i n i n g ) : 24 H o u r s : 100 Water Soak ( 4 Days, 24 Hour R e c o v e r y ) : 100 H u m i d i t y ( 1 4 Days, 24 Hour R e c o v e r y ) : 100 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y :

Formula P1877-21E

201

202

Water-Based Paint Formulations

V e r y L o w VOC V i o l e t B a k i n a Enamel Pounds C a r g i l l Waterborne P o l y e s t e r D i s p e r s i o n 72-7232 124.3 72-7232 must be a t a minimum o f 6 . 7 f o r d i s p e r s i n g Dei o n i zed Water 24.8 C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Me1ami ne 23-2347 53.5 T i t a n i u m D i o x i d e T i - P u r e R-902 99.0 M o n a s t r a l V i o l e t R RT-201-0 9.9

Gal t o n s 15.38 2.97 5.30 2.90 0.79

Sand M i l l t o a 7 Hegman C a r g i 11 Waterborne P o l y e s t e r D i s p e r s i o n 72-7232 Byk 301 D i e t h y l e n e G l y c o l Monobutyl E t h e r D e i o n i z e d Water Premix t h e f o l l o w i n g ,

492.5 3.1 0.9 79.2

60.96 0.39 0.11 9.50

5.0 5.0 3.1

0.58 0.60 0.52

t h e n add:

A d d i t o l XW 395 Dei o n i zed Water T r i e t h y l a m i n e ( N o t e #2 and #3)

F o r m u l a t i n g Notes: 1 . 72-7232 must b e a t a minimum pH o f 6 . 7 f o r d i s p e r s i n g . 2 . The amount of t r i e t h y l a m i n e n e c e s s a r y t o o b t a i n t h e f i n a l pH o f 8.0 t o 8 . 3 w i l l v a r y . 3. A d j u s t t h e p a i n t t o i t s f i n a l pH i m m e d i a t e l y a f t e r p r o c e s s i n g t o prevent s e t t l i n g . Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 4 2 . 4 6 (By Volume): 32.93 Pigment t o B i n d e r R a t i o : 0.40 Pigment Volume C o n c e n t r a t i o n : 11.19 Weight Per G a l l o n : 9 . 0 0 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 0 . 6 6 ( G r a m s / L i t e r ) : 79 pH: 8 . 0 - 8 . 3 V i s c o s i t y #2 Zahn (Seconds): 50-60 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 350F S u b s t r a t e : Sheet M o l d i n g Compound Dry F i l m Thickness ( M i l s ) : 1 . 0 G l o s s ( 6 0 / 2 0 ) : 86/70 C r o s s h a t c h Adhesion (% Remaining) : 24 Hours: 100 Water Soak (120 Hours, 24 Hour R e c o v e r y ) : 99 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y :

Formula P1917-8

Enamels -Baking

203

Very Low VOC White Bakinq Enamel ___ Pounds Gallons Cargill Waterborne Polyester Dispersion 18.39 72-7230 160.0 72-7230 must be at a minimum pH of 6.7 for dispersing Cargill High Solids Monomeric Methylated Me1 ami ne 23-2347 51.9 5.14 Ti tani um Dioxide Ti -Pure R-902 220.1 6.44

Sand Mill to a 7 Hegman Cargi 11 Waterborne Polyester Dispersion 72-7230 Dow Corning 14 Additive Triethylamine (Note #2 and #3) Deionized Water (Hold for Viscosity Adjustment)

544.6 3.0 3.6

62.59 0.45 0.60

53.3

6.39

Formulating Notes: 1. 72-7230 must be at a minimum pH of 6 . 7 for dispersing. 2. The amount of triethylamine necessary to obtain the final paint pH of 8.0 to 8.3 will vary. 3. Adjust the paint to its final pH immediately after processing to prevent settling. Pa nt Properties: % Nonvolatile (By Weight): 46.67 (By Volume): 33.49 Pigment to Binder Ratio: 0.84 Pigment Volume Concentration: 19.22 Weight Per Gal lon: 10.36 Theoretical VOC (Pounds/Gallon): 0.70 (Grams/Liter): 84 pH: 8.0-8.3 Viscosity #2 Zahn Cup (Seconds): 35-45 Typical Cured Film Properties: Cure Schedule: 15 Minutes at 350F Substrate: Cold Rolled Steel Gloss (60/20): 93/73 Pencil Hardness: Pass 2H % Crosshatch Adhesion: 100 Impact (In. Lbs.) : Direct: 160 Reverse: 140 Humidity (Hours): 150 81 i sters: None % Crosshatch Adhesion: 100 Salt Spray (Hours): 150 Scribe Creep ( m m ) : 4 Scribe Blisters: Few # 2 SOURCE: Cargill, Inc.: CARGILL Formulary: Formulation P1877-32C

204

Water-Based Paint Formulations

V e r y Low VOC W h i t e Bakinq Enamel Pounds Gallons C a r g i l l Waterborne P o l y e s t e r D i s p e r s i o n 72-7231 203.6 19.15 72-7231 must be a t a minimum pH o f 6 . 7 f o r d i s p e r s i n g C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Me1ami ne 23-2347 54.0 5.35 T i t a n i u m D i o x i d e T i - P u r e R-902 277.1 8.10 Sand M i l l t o a 7 Hegman C a r g i l l Waterborne P o l y e s t e r D i s p e r s i o n 72-7231 Dow C o r n i n g 14 A d d i t i v e Premix t h e f o l l o w i n g ,

530.2 3.2

65.20 0.47

5.1 5.1 3.2

0.59 0.62 0.52

t h e n add:

A d d i t o l XW 395 D e i o n i z e d Water T r i e t h y l a m i n e ( N o t e #2 and #3)

F o r m u l a t i n g Notes: 1 . 72-7231 must b e a t a minimum p X o f 6 . 7 f o r d i s p e r s i n g . 2 . The amount o f t r i e t h y l a m i n e n e c e s s a r y t o o b t a i n t h e f i n a l pH o f 8 . 0 t o 8 . 3 w i l l v a r y . 3. A d j u s t t h e p a i n t t o i t s f i n a l pH i m m e d i a t e l y a f t e r p r o c e s s i n g t o prevent s e t t l i n g . Pai n t P r o p e r t i e s : % N o n v o l a t i l e (By W e i g h t ) : 51 . 2 4 (By Volume): 36.53 Pigment t o B i n d e r R a t i o : 1 . 0 0 Pigment Volume C o n c e n t r a t i o n : 2 2 . 1 8 Weight Per G a l l o n : 10.82 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 0 . 6 9 ( G r a m s / L i t e r ) : 83 pH: 8 . 0 - 8 . 3 V i s c o s i t y #2 Zahn (Seconds): 35-45 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 350F Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 94/70 P e n c i l Hardness: Pass H % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 160 Reverse: 80 H u m i d i t y ( H o u r s ) : 344 81 is t e r s : None % C r o s s h a t c h Adhesion: 100

SOURCE: C a r g i l l ,

Inc.:

C A R G I L L Formulary: Formula 1877-98

Enamels -Baking

205

Waterborne Acrvl i c Bake Enamel The WR-17 s t u d y was conducted t o d e m o n s t r a t e t h e improved c o r r o s i o n r e s i s t a n c e a f f o r d e d a w a t e r b o r n e system by c h o o s i n g a more h y d r o p h o b i c c a t a l y s t , NACURE 155 (DNNDSA), o v e r a more h y d r o p h i l i c c a t a l y s t , K-CURE 1040 (p-TSA). Free a c i d c a t a l y s t , r a t h e r t h a n t h e b l o c k e d v e r s i o n s , were used i n t h i s s t u d y , s i n c e t h e f o r m u l a a l r e a d y c o n t a i n e d a n e u t r a l i z i n g amine. A summary o f t h e f o r m u l a t i o n , i t ' s p h y s i c a l p r o p e r t i e s and t e s t r e s u l t s a r e l i s t e d below: Grind: T i 0 2 2020 A c r y s o l WS-68 2-Butoxyethanol n-Butanol

150.7 39.7 6.7 6.3 0.9 46.9

DMEA D . I . Water

Pebble m i l l g r i n d t o 7+ on Hegman L e t Down: A c r y s o l WS-68 n-Butanol Cyme1 303LF 2-Butoxyethanol *DMEA (10% i n w a t e r ) * D . I . Water

436.3 5.4 45.1

39.0 22.0 201 . o

P i gment/Bi nder : 40/60 A c r y l i c / M e l a m i n e : 80/20 T o t a l S o l i d s , %: 3 7 . 7 S o l i d s 1 h r / l l O C : 37.4 T o t a l R e s i n S o l i d s : 21.1 Wt/gal I3 25C ( l b / g a l ) : 9 . 6 5 V.O.C.: 1.04

*

Used t o a d j u s t pH and v i s c o s i t y . Film Properties: S u b s t r a t e : E31000 Cure: 15 min /149C Thickness: 0 7-0.8 m i l

P e n c i l Hardness Tukon KNH25 MEK Rub ( 2 X ) Impact Reverse, in / l bs D i r e c t , in / i b s Crosshatch, % Adhesion S a l t Spray, 150 h o u r s 0 . 5 % on TRS

*

SOURCE:

Control H-2H 13.2 24 90-1 00 40-50 100 10/6-7mm

K i n g I n d u s t r i e s : F o r m u l a t i o n WR-17

*K-1040 p-TSA H-2H 13.2 42 120-1 30 30-40 100 10/6-7mm

*N-l55 DNNDSA H-ZH 13.0 50 90-1 00 30-40 100 10/3-4mm

206

Water-Based Paint Formulations

Water R e d u c i b l e , F o r c e Cure B l a c k G l o s s Enamel F o r m u l a t i o n 10-0091-G shows how CHEMPOL 10-0091 may be used w i t h a t h e r m o p l a s t i c a c r y l i c l a t e x t o g a i n e x c e p t i o n a l adhesion t o untreated s t e e l surfaces. This blend provides cured f i l m s w i t h o u t s t a n d i n g adhesion, hardness, and c o r r o s i o n r e s i s t a n c e , e s p e c i a l l y when c o a t i n g u n t r e a t e d s t e e l s u b s t r a t e . F o r m u l a t i o n 10-0091-G was d e s i g n e d p r i m a r i l y f o r c u r i n g i n f o r c e d r y a p p l i c a t i o n , b u t i t may a l s o b e used i n a i r d r y situations. 10-0091-G i s f o r m u l a t e d t o be sprayed "as i s " . When used i n t h i s manner, t h e v o l a t i l e o r g a n i c compounds a t p o i n t o f a p p l i c a t i o n a r e 2 . 9 3 pounds p e r g a l l o n , e x c l u d i n g w a t e r . These "VOC" e m i s s i o n s conform t o most e x i s t i n g and p e n d i n g s t a t e and f e d e r a l Clean A i r r e g u l a t i o n s . I t i s s t r o n g l y recommended t h a t t h e m i x i n g p r o c e d u r e be f o l l o w e d p r e c i s e l y . Changes i n t h e raw m a t e r i a l o r m i x i n g p r o c e d u r e may cause wide v a r i a t i o n s i n t h e f i n i s h e d p r o d u c t . The pH o f t h e f i n i s h s h o u l d be m o n i t o r e d d u r i n g m a n u f a c t u r e and m a i n t a i n e d a t a v a l u e o f 7 . 5 - 8 . 0 . I f t h e pH i s a l l o w e d t o go beyond 8 . 5 " s e e d i n g " o f t h e a c r y l i c l a t e x may o c c u r . Gal 1ons Pounds 6.12 53.83 0.40 3.23 0.24 2.42 0.16 1.61 0.16 EA-1075 1 .61 11.62 Water 96.85 0.24 Bykumen 2.02 1 .05 Carbon b l a c k ( S t e r l i n g R ) 16.14 Charge t o s t e e l b a l l m i l l and g r i n d 7-1/2 t o 8 Hegman gage. Add t h e f o l l o w i n g t o m i l l and g r i n d 30 m i n u t e s . 6.12 Chempol 10-0091 53.83 0.32 DMAMP-80 2.66 6.86 Water 57.39 L e t Down W i t h : 17.12 Chempol 10-0091 50.69 0.16 C o b a l t H y d r o c u r e 5% 1.94 0.16 Manganese Hydrocure 5% 1.94 0.08 VP-321 0.81 3.35 Texanol 28.25 0.16 A n t i - s k i n n i n g agent 1.61 0.08 N a l c o 2309 0.56 0.08 N a l c o 2302 0.24 1.29 DMAMP-80 10.33 30.75 Water 250.12 13.48 Ucar 4431X 117.84 P r o p e r t ies : T o t a l s o l i d s , % b y w e i g h t : 30.17 T o t a l s o l i d s , % b y volume: 21.31 V i s c o s i t y , #4 F o r d Cup, seconds: 45-55 Inaredients: Chempol 10-0091 DMAMP- 8 0 Nal c o 955-81 5 Polycompound W-953

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 1 0 - 0 0 9 1 - G

Formulation

Enamels -Baking

207

Water R e d u c i b l e , Gloss W h i t e B a k i n g Enamel I n a r e d ie n t s : Grind paste. Chempol 10-0503 B u t y l C e l l os01 ve Byk P-104s D i m e t h y l e t h a n o l a m i ne T i t a n i u m D i o x i d e (R-902) Water

Pounds

Gal 1ons

152.73 61.12 4.11 8.92 405.24 48.64

16.97 8.15 0.52 1.05 12.28 5.86

B l e n d r e s i n and e t h y l e n e g l y c o l monobutyl e t h e r . Add Byk

P-104s and m i x . Add DMEA and m i x . Add T i 0 2 f o l l o w e d by w a t e r . G r i n d t o 7 1/2 Hegman. S t a b i 1ize: Chempol 10-0503 Cyme1 303 DMEA Water

31 .I4 118.20 8.67 13.03

3.46 11.82 1.02 1.57

B l e n d s t a b i l i z i n g s o l u t i o n and m i x i n t o g r i n d . L e t down w i t h : Chempol 10-0503 DMEA Cycat 4040 D i p r o p y l ene g l y c o l monomethyl e t h e r Byk 020 Water Properties: V i s c o s i t y : 43 sec. #4 F o r d CUP pH: 8.7 N o n v o l a t i l e , %: 66.3 P o l v e s t e r / M e l a m i n e : 68/32 P i gment/bi n d e r w e i g h t r a t i 0 : 1 . 0 0 / 1 Cure c y c l e : 15 min. @ 300F Gloss, 60: 88

SOURCE:

154.35 16.83 2.77 26.39 7.27 12.54

17.15 1.98 0.37 3.32 0.92 13.56

.OO

Freeman Polymers D i v i s i o n : CHEMPOL 10-0503-A

Formulation

208

Water-Based Paint Formulations

Water R e d u c i b l e , H i g h G l o s s W h i t e B a k i n a Enamel Suggested S t a r t i n g F o r m u l a t i o n 10-0503-8 i s f o r m u l a t e d t o i l l u s t r a t e t h e o u t s t a n d i n g performance o f CHEMPOL 10-0503 s a t u r a t e d p o l y e s t e r . E x c e l l e n t p a i n t s t a b i l i t y and o u t s t a n d i n g f i l m hardness, g l o s s , f l e x i b i l i t y , and a d h e s i o n a r e t h e h a l l m a r k s o f t h i s water r e d u c i b l e p o l y e s t e r . Ingredients: Chempol 10-0503 B u t y l C e l l os01 ve DMEA Hypermer PS2 Coroc A2678M Dei o n i zed Water

Pounds 148.21 55.61 13.07 2.78 8.34 185.47

Gal 1ons 15.12 7.41 1.77 0.33 0.95 22.29

Mix u n t i l c l e a r , t h e n add u s i n g a Cowles d i s s o l v e r T i ona RCL-535

B a l l o r p e b b l e g r i n d t o Hegman 7-1/2+ f o l l o w i n g pre-mixed r e s i n s o l u t i o n : Chempol 10-0503 Butyl Cellosolve Cyme1 303 DMEA Dei o n i zed Water

333.69

9.56

and l e t down w i t h t h e 111.23 27.81 83.42 7.23 48.38

11.35 3.70 8.34 0.98 5.82

Premix and s l o w l y add under s t i r r i n g t h e f o l l o w i n g : A c r y s o l ASEGO 1.11 Dei o n i zed Water 82.31

0.13 9.89

And, f i n a l l y , p r e m i x and add: Cycat 4040 DMEA Dei o n i zed Water

0.35 0.08 1.94

2.78 0.56 16.13

P r o p e r t i es : % Weight S o l i d s : 54.96 % Volume S o l i d s : 36.32 VOC, # / g a l l o n : 5.08 VOC, # / g a l l o n - w a t e r : 2.92 P/B r a t i o : 1 . 2 % PVC: 26.3 Binder/Melamine r a t i o : 70/30 V i s c o s i t y , #4 F o r d Cup: 26 seconds

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 10-0503-6

Formulation

Enamels -Baking

Water

Soluble B a k i n a Enamels

C u r i n g I n f o r m a t i on: Suggested Water Reduction Schedule: Ingredients: Chempol 10-0501 Butoxyethanol T r i e t h y l ami ne Water Resimene 745

P a r t s by Weight 44.4

Inaredients: Chempol 10-0501 Butoxyethanol Triethanolamine Water Resimene 745

P a r t s by Weiaht 44.4

Suggested Baking Schedule: T i me 10 minutes 20 minutes

14.8 4.6 29.6 6.6

14.8 4.1 30.1 6.6 Temperature

350F 325F

SOURCE: Freeman Polymers D i v i s i o n : CHEMPOL 10-0501 F o r m u l a t i o n

209

210

Water-Based Paint Formulations

W h i t e B a k i n q Enamel C a r g i l l Water R e d u c i b l e O i l F r e e P o l y e s t e r 72-7203 Triethylamine C a r g i l l H i g h S o l i d s Monomeric M e t h y l a t e d Melami ne 23-2347 D e i o n i z e d Water Dow C o r n i n g 14 A d d i t i v e T i t a n i u m D i o x i d e T i - P u r e R-902

Pounds

Gal 1ons

161.3 7.9

18.13 1.31

47.6 56.7 2.8 237.9

4.71 6.80 0.43 6.96

94.4 13.4 345.5

10.60 2.21 41.48

61.4

7.37

H i g h Speed t o a 7 Hegman C a r g i l l Water R e d u c i b l e O i l F r e e P o l y e s t e r 72-7203 T r i e t h y l ami ne D e i o n i zed Water D e i o n i z e d Water Ad j ustment )

Hold f o r Viscosity

Paint Properties % N o n v o l a t i l e ( B y W e i g h t ) : 46.42 (By Volume): 31.25 Pigment t o B i n d e r R a t i o : 0 . 9 9 Pigment Volume C o n c e n t r a t i o n : 22.26 Weight Per G a l l o n : 10.29 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 1 . 9 8 ( G r a m s / L i t e r ) : 237 W a t e r : C o s o l v e n t Weight R a t i o : 8 4 . 0 9 : 1 5 . 9 1 pH: 8 . 0 - 8 . 5 V i s c o s i t y #2 Zahn Cup (Seconds): 60-70 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 350F Substrate: Cold R o l l e d Steel G l o s s ( 6 0 / 2 0 ) : 94/82 P e n c i l Hardness: Pass H % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 160 Reverse: 60 H u m i d i t y ( H o u r s ) : 150 B1 is t e r s : None 96 C r o s s h a t c h Adhesion: 100 S a l t Spray ( H o u r s ) : 150 S c r i b e Creep (mm): 3 S c r i b e B l i s t e r s : Medium Dense #4 S u r f a c e B l i s t e r s : None S u r f a c e C o r r o s i o n : None

SOURCE: C a r g i l l , Inc.: CARGILL F o r m u l a r y : Formula P1877-308

Enamels -Baking

W h i t e B a k i n a Enamel Pounds C a r g i 11 Water R e d u c i b l e S e l f C r o s s l in k i ng R e s i n 73-7390 D i m e t h y l e t h a n o l ami ne T i t a n i um D i o x i d e T i -Pure R-900 P a t c o t e 577 Bvk-301 D; e t h y l ene G1 y c o l Monobutyl E t h e r Dei o n i zed Water

73.0 4.5 224.9 3.0 3.0 1.5 90.0

8.57 0.61 6.43 0.44 0.37 0.19 10.80

215.4 14.0 5.0 4.0 368.9

25.29 1.90 0.59 0.53 44.28

H i g h Speed t o a 7 Hegman C a r g i 11 Water R e d u c i b l e S e l f C r o s s l i n k i n g R e s i n 73-7390 D i m e t h y l e t h a n o l ami ne Raybo 62-HydroFlo E t h y l e n e G l y c o l Monobutyl E t h e r D e i o n i z e d Water Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 42.62 (By Volume): 29.04 Pigment t o B i n d e r R a t i o : 1.10 Pigment Volume C o n c e n t r a t i o n : 22 Weight Per G a l l o n : 10.07 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : (Grams/Liter): 3 Water:Cosolvent Weight R a t i o : 79 pH: 8.6 V i s c o s i t y #2 Zahn Cup (Seconds):

13 2.65 8 40: 20.60 30

T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 15 M i n u t e s a t 350F Substrate: Cold Rolled Steel G l o s s ( 6 0 ) : 85 P e n c i l Hardness: Pass 3H Impact ( I n . L b s . ) : D i r e c t : 130 Reverse: 40 S a l t Spray ( H o u r s ) : 150 S c r i b e Creep (mm): 1 S c r i b e B l i s t e r s : Few, #4 S c r i b e C o r r o s i o n (mm): 1 S u r f a c e B l i s t e r s : None S u r f a c e C o r r o s i o n : None

SOURCE:

Cargill,

I n c . : CARGILL F o r m u l a r y : Formula P1396-77

211

212

Water-Based Paint Formulations

W h i t e B a k i n g Enamel

Lbs.

M a t e r i a1 : T i t a n o x 2101 A r o l o n 580-W-42 Butoxy E t h a n o l Water O d o r l e s s M i n e r a l Spi r i t s Pebble m i l l 18-24 h o u r s . Letdown : A r o l o n 580-W-2 Cyme1 373 n-Butanol Water Sodium N i t r i t e Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : P i gment/8i nder R a t i o : .75/1 P e r c e n t S o l i d s , Weight: 5 2 . 8 P e r c e n t S o l i d s , Volume: 37.5 V i s c o s i t y @ 25C, #4 Ford, Secs.: 40-60 Pounds/Gallon: 10.39 pH: 7.0-7.5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 21 2 Pounds/Gallon: 1 . 7 7

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i on P-233A

226.0 113.0 45.0 22.0 5.4

Gals. 6.78 12.71 5.99 2.64 0.86

526.0 38.6 30.0 31 . O 1 .o

59.17 3.68 4.44 3.73 .06

18.1

I n c . : Waterborne Handbook:

Enamels-Baking

W h i t e B a k i n a Enamel M a t e r i a1 : Lbs. A r o l on 860-W-45 271.39 S u r f y n o l 104H 2.45 C o l l o i d 679 2.69 Water 57.56 T r i e t h y l ami ne 2.98 T i - P u r e R-902 215.80 G r i n d t o a 7 Hegman on Cowles o r p e b b l e m i 11. Letdown : A r o l on 860-W-45 Cyme1 303 Premix and add under a g i t a t i o n : Butoxy Ethanol B u t y l Carbi t o 1 Byk 301 Water Triethylamine

Gals. 30.84 0.31 0.29 6.91 0.33 6.50

324.90 53.30

36.92 5.33

26.70 26.80 1.03 41.15 5.14

3.56 3.37 0.13 4.94 0.57

Anal v s i s : P i gment Vol ume C o n c e n t r a t i o n , P e r c e n t : 17.57 P i g m e n t / B i n d e r R a t i o : 0.80/1 P e r c e n t S o l i d s , W e i g h t : 52.59 P e r c e n t S o l i d s , Volume: 42.66 V i s c o s i t y I3 25C, #4 F o r d , S e c s . : 35-45 Pounds/Gallon: 10.32 pH: 8.2-8.5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 152.4 Pounds/Gal 1on : 1 .27

SOURCE: R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i o n 2402-1 7 D

213

214

Water-Based Paint Formulations

W h i t e B a k i n q Enamel M a t e r i a1 : Lbs. K e l s o l 4097-164-55 119.8 Butoxy E t h a n o l 9.9 Water 140.4 T i t a n o x 2101 263.6 Pebble o r s a n d m i l l g r i n d t o 7 Hegman. Letdown : K e l sol 4097-WG4-55 329.4 Cymel 303 82.3 Byk 301 2.7 Water 130.0 A d j u s t f i n a l pH t o 8.2-8.8, i f necessary, w i t h DMEA Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 1 9 . 5 Pigment/Binder R a t i o : 0.8/1 . O P e r c e n t S o l i d s , Weight: 55.1 P e r c e n t S o l i d s , Volume: 4 0 . 7 V i s c o s i t y @ 25C, KU: 70-80 Pounds/Gallon: 10.8 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 186 Pounds/Gal 1 on : 1 . 6 F o r m u l a t i o n 2293-86

.

Gals 13.27 1.32 16.85 7.91 36.48 8.23 0.33 15.61

W h i t e G l o s s B a k i n g Enamel M a t e r i a1 : Lbs. Water 261.5 11.6 Triethylamine K e l s o l 5293-0-75 129.9 T i t a n o x 2101 303.9 Pebble m i l l t o a 7 Hegman g r i n d . Letdown : 216.2 K e l sol 5293-8-75 78.1 Cymel 303 30.4 T r i e t h y l ami ne 20.6 Butoxy E t h a n o l 22.2 Water 3.3 DC29 Anal y s i s: P i gment Volume C o n c e n t r a t i o n , P e r c e n t : 2 0 . 8 Pigment/Binder R a t i o : 0.9/1 P e r c e n t S o l i d s , Weight: 5 9 . 6 P e r c e n t S o l i d s , Volume: 43.8 V i s c o s i t y @ 25C, #4 Ford, Secs.: 60-70 Pounds/Gallon: 10.8 pH: 8.2-8.6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 271 Pounds/Gallon: 2 . 2 6 SOURCE: R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i o n 2425-22

Gals. 31.40 1.90 14.62 9.12 24.35 7.81 5.02 2.74 2.66 0.38

Enamels -Baking

215

W h i t e B a k i n q Enamel

Lbs. M a t e r i a1 : 86.0 Water 4.0 DMEA 46.0 Synthemul 40-427 1.o Foamaster R 30.0 D i e t h y l e n e G1y c o l 300.0 T i t a n o x 2020 H i g h speed d i s p e r s e r , Hegman g r i n d o f 7 1 / 2 . 66.7 Super Beckami ne 27-568 35.3 Water 428.0 Synthemul 40-431 3.0 DMEA Anal y s i s : P i gment Vol ume Concent r a t i o n , P e r c e n t : 1 8 . 8 Pigment/Binder R a t i o : 1/1 P e r c e n t S o l i d s , Weight: 6 0 . 4 P e r c e n t S o l i d s , Volume: 46.7 V i s c o s i t y @ 25C, #4 For&, Secs.: 25-30 Pounds/Gal 1on : 1 1 . 2 pH: 8.3-8.8 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 145.0 Melamine, P e r c e n t : 1 9 . 8 B o n d e r i t e 37, 0 . 7 - 0 . 9 m i l s , 20 min. @ 300F c u r e . 60 G l o s s : 87 20 G l o s s : 68 Mek, 30 Double Rubs: Exc. Impact R e s i s t a n c e : Forward: F8 Reverse: F120 150 Hours S a l t Fog: Appearance: No r u s t , no b l i s t e r s 60 G l o s s : 90 20 G l o s s : 72 4-Hour Spot T e s t : Toluene: Exc., no b l i s t e r s V a r s o l : Exc., no b l i s t e r s Gasol ine: Exc., no b l i s t e r s 5% NaOH S o l u t i o n : E x c . , no b l i s t e r s 5% H2S04: Exc., no b l i s t e r s SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 431-01

Inc.:

Waterborne Handbook:

.

Gals 10.32 0.54 5.41 0.14 3.22 8.77 6.74 4.24 49.77 0.41

216

Water-Based Paint Formulations

W h i t e B a k i n q Enamel M a t e r i a1 : ___ Pounds R u t i l e Titanium Dioxide 250.0 CMD 9012 A c r y l i c Resin 114.0 Hexamethoxymethylmelami ne R e s i n (2) 45.8 P o l y e s t e r Poly01 R e s i n (3) 21.4 n-Butyl Alcohol 18.7 H i g h Speed D i s p e r s e t o 7-8 NS. Add CMD 9012 A c r y l i c R e s i n 91.3 Hexamethoxymethylmel ami ne Resin (2) 36.7 P o l y e s t e r P o l y o l Resin (3) 17.1 n-Butyl Alcohol 15.0 Mix t h o r o u g h l y and add SLOWLY under a g i t a t i o n : D i m e t h y l e t h a n o l ami ne 17.5 M i x w e l l and add s l o w l y : D e i o n i z e d Water 415.6 A d j u s t pH t o 8.0-8.7 u s i n g D i m e t h y l e t h a n o l a m i n e

Gal 1ons

7.50 2.67 4.58 2.40 2.78 0.14 3.67 1.91 2.22 2.24 49.89

(2) Cyme1 303 (3) N i a x PCP-0301 T y p i c a l C o a t i ng P r o p e r t i e s : T o t a l Weight S o l i d s : 50.4% T o t a l Volume S o l i d s : 36.5% P . V . C . : 20.5% V i s c o s i t y : 115-120 Krebs U n i t s pH: 8.0-9.7 ( A d j u s t e d ) Reduced V i s c o s i t y : 40-50" (3:l i n D I Water) # 4 F o r d Cup Resin Composition ( S o l i d s ) : A c r y l i c Resin: 56% P o l y e s t e r P o l y o l R e s i n : 14% Hexamethoxymethylmelamine R e s i n : 30% V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gallon: 2.21 G r a m s / L i t e r : 265 T y p i c a l F i l m P r o p e r t i e s : Uncatalyzed: P e n c i l Hardness: 4 H 60 G l o s s : 86 Reverse I m p a c t : Cracks 40 i n / l b s . D i r e c t I m p a c t : Pass 100 i n / l b s . 1/4" C o n i c a l M a n d r e l : F a i l s 1/2" MEK Rubs: 1 0 0 - 8 ( P . H . ) Catalyzed ( 5 ) : P e n c i l Hardness: 6-7H 60 G l o s s : 97 Reverse I m p a c t : 10 i n / l b s . D i r e c t Impact: Pass 40, F a i l s 60 i n / l b s . (5) C a t a l y s t i s 0 . 2 5 % - - ( T o t a l R e s i n S o l i d s ) Syntex 3981

SOURCE:

S h e l l Chemical Co.:

25-200 W h i t e B a k i n g Enamel

Enamels-Baking

White,

217

H i q h G l o s s , Water R e d u c i b l e B a k i n a Enamel

F o r m u l a t i o n 10-1105-A i s a h i g h g l o s s w h i t e b a k i n g enamel based on a w a t e r r e d u c i b l e c o c o n u t a l k y d , CHEMPOL 10-1105. C o a t i n g s based on CHEMPOL 10-1105 d e m o n s t r a t e good hardness, h u m i d i t y and overbake r e s i s t a n c e . The p r o d u c t s h o u l d be used f o r g e n e r a l p u r p o s e b a k i n g enamels o v e r t r e a t e d o r u n t r e a t e d m e t a l s u b s t r a t e where c o l o r r e t e n t i o n i s r e q u i r e d . Inaredients: T i t a n i u m D i o x i d e ( T i - P u r e R-902) Chempol 10-1105 Byk P-104s Byk 020 D i m e t h y l e t h a n o l ami ne E t h y l e n e g l y c o l monobutyl e t h e r Water

Pounds 304.78 123.08 3.07 2.76 36.74 37.78 36.55

Gal 1ons 9.15 13.47 0.39 0.38 0.91 5.03 4.39

G r i n d i n P e b b l e M i l l t o 7 1 / 2 Hegman gauge. Add t h e f o l l o w i n g and r e d i s p e r s e f o r 30 m i n u t e s : Chempol 10-1 105 25.21 Cyme1 303 121.77 D i m e t h y l e t h a n o l ami ne 6.51 Water 8.05

2.76 12.18 0.88 0.97

L e t down w i t h : Chempol 10-1 105 D i m e t h y l e t h a n o l ami ne Cycat 4040 Ucar S o l v e n t 2LM E t h y l e n e g l y c o l monobutyl e t h e r Water

14.40 1.79 0.28 2.59 1.37 29.07

131.58 13.26 2.22 20.61 10.27 241.86

Properties: T o t a l s o l i d s , % by w e i g h t : 57.03 T o t a l s o l i d s , % b y volume: 41.07 R e d u c t i o n f o r s p r a y a p p l i c a t i o n (pbw):

150 p a r t s p a i n t / 7 p a r t s water R e d u c t i o n v i s c o s i t y , #4 F o r d cup, seconds: 55-65 Pigment/binder weight r a t i o : 0.96/1 . O VOC, l b s / g a l s , ( c a l c u l a t e d ) : 2.81 PVC, %: 22.29 G l o s s (60 Gardner G l o s s m e t e r ) : 94 W e i g h t / g a l l o n , l b s . : 10.58 pH: 8 . 0 - 9 . 0 F l a s h - o f f t i m e , ( 3 m i l wet f i l m ) : 5-10 m i n u t e s Suggested c u r e s c h e d u l e : 10 m i n u t e s 13 325F % C a t a l y s t (based on v e h i c l e s o l i d s ) : 0.55 A c r y l i c / M e l a a i n e (based on v e h i c l e s o l i d s ) : 62/38

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 10-1105-A

Formulation

218

Water-Based Paint Formulations

White,

H i g h Gloss,

Water R e d u c i b l e B a k i n a Enamel

F o r m u l a t i o n 10-1706-8 i s a h i g h g l o s s w h i t e b a k i n g enamel based on a w a t e r r e d u c i b l e a c r y l i c copolymer, CHEMPOL 10-1706. CHEMPOL 10-1706-8 demonstrates e x c e l l e n t h u m i d i t y r e s i s t a n c e , g l o s s r e t e n t i o n i n QUV exposure t e s t i n g and good c o r r o s i o n r e s i s t a n c e . CHEMPOL 10-1706-8 s h o u l d be used f o r h i g h p e r f o r m ance i n d u s t r i a l b a k i n g f i n i s h e s where e x t e r i o r d u r a b i l i t y i s extremely important. Inaredients: T i t a n i u m D i o x i d e ( T i - P u r e R-902) Chempol 10-1 706 Byk P-104s Byk 020 Dimethylethanolamine E t h y l e n e g l y c o l monobutyl e t h e r Water

Pounds

Gal l o n s

300.60 113.30 3.02 2.72 6.65 45.35 36.05

9.03 12.88 0.38 0.37 0.90 6.04 4.33

G r i n d i n Pebble M i l l t o 7 1 / 2 Hegman gauge. Add t h e f o l l o w i n g and r e d i s p e r s e f o r 10 m i n u t e s : Chempol 10-1 706 Cyme1 303 Dimethylethanolamine Water

23.13 120.10 6.42 9.67

2.63 12.01 0.87 1.16

L e t down w i t h : Chempol 10-1 706 D i m e t h y l ethanolami ne Cycat 4040 Ucar S o l v e n t 2LM E t h y l e n e g l y c o l monobutyl e t h e r Water

120.33 13.30 2.19 20.48 18.90 237.64

13.67 1.80 0.27 2.58 2.58 28.56

Properties: T o t a l s o l i d s , % by w e i g h t : 5 7 . 0 4 T o t a l s o l i d s , % by volume: 4 1 . 9 6 R e d u c t i o n f o r s p r a y a p p l i c a t i o n (pbw):

150 p a r t s p a i n t / 7 p a r t s water R e d u c t i o n v i s c o s i t y , # 4 F o r d cup, seconds: 55-60 Pigment/binder weight r a t i o : 0 . 9 6 / 1 .OO VOC, l b s / g a l ( c a l c u l a t e d ) , l e s s w a t e r : 2 . 7 7 PVC, %: 2 1 . 5 2 G l o s s ( 6 0 Gardner G l o s s m e t e r ) : 90 Weight/gallon, l b s . : 10.86 pH: 8 . 0 - 9 . 0 F l a s h - o f f t i m e , ( 3 . 0 m i l wet f i l m ) : 5-10 m i n u t e s Suggested c u r e s c h e d u l e : 10 m i n u t e s @ 325F % C a t a l y s t (based on v e h i c l e s o l i d s ) : 0 . 7 A c r y l i c / M e l a m i n e (based on v e h i c l e s o l i d s ) : 6 2 / 3 8

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 10-1708-8

Formulation

Enamels -Baking

21 9

W h i t e , H i q h Gloss, Water R e d u c i b l e B a k i n g Enamel 10-1300-8 w h i t e , h i g h g l o s s , w a t e r r e d u c i b l e b a k i n g enamel was f o r m u l a t e d t o demonstrate t h e performance o f CHEMPOL 10-1300 i n a g e n e r a l purpose h i g h g l o s s b a k i n g enamel o v e r t r e a t e d ( B o n d e r i t e ) and u n t r e a t e d m e t a l s u r f a c e s . 10-1300-8 i s i n t e n d e d f o r spray a p p l i c a t i o n s . 10-1300-8 can be p r e p a r e d w i t h o u t f i r s t h a v i n g t o s o l u b i l i z e CHEMPOL 10-1300. I t i s i m p o r t a n t t h a t t h e p r o c e d u r e f o r p r e p a r i n g t h i s enamel be c l o s e l y f o l l o w e d . Changes i n pigment w e t t i n g agents o r melamine r e s i n may cause v a r i a t i o n i n g l o s s and p e r formance. When reduced as d i r e c t e d , 10-1300-8 c o n t a i n s 19.5% o r g a n i c s o l v e n t and amine, 80.5% w a t e r by volume w h i c h meets Rule 66 r e q u i rements f o r w a t e r r e d u c i b l e c o a t i n g s c o n t a i n i n g o r g a n i c solvents. I n a r e d ie n t s : Premix i n o r d e r l i s t e d : Chempol 10-1300 T r i e t h y l ami ne Polycompound W-953 N a l c o 655-769 Water Bykumen T i t a n i u m D i o x i d e ( T i - P u r e R-900)

Pounds

Gallons

~~

75.19 5.47 3.20 1 .68 102.64 3.20 210.50

9.09 0.93 0.42 0.17 12.29 0.42 6.06

G r i n d Pebble M i l l to 7 1 / 2 Hegman gauge. Add t o m i l l t h e f o l l o w i n g and d i s p e r s e one h o u r : Chempol 10-1300 Triethylamine

75.19 5.47

0.09 0.93

L e t down w i t h : Premix i n o r d e r l i s t e d and add w h i l e under a g i t a t i o n : Chempol 10-1300 Resi mene 1-720 T r i e t h y l ami ne E x k i n No. 2 P a i n t A d d i t i v e #14 C a t a l y s t 600 Water

105.25 35.11 12.80 1 .68 2.11 1.09 347.66

12.71 3.54 2.11 0.17 0.25 0.08 41 .74

Properties: T o t a l s o l i d s , % by w e i g h t : 42.60 T o t a l s o l i d s , % b y volume: 28.87 V i s c o s i t y #4 F o r d cup, seconds: 75-90 R e d u c t i o n f o r s p r a y a p p l i c a t i o n : 10 p a r t s 10-1300-8/ b y volume 1 p a r t water Pigment/binder weight r a t i o : 1.0/1 .O PVC, %: 21 pH: 8.5-9.5

SOURCE: Freeman Polymers D i v i s i o n : CHEMPOL 10-1300-8 F o r m u l a t i o n

220

Water -Based Paint Formulations

Water R e d u c i b l e G l o s s W h i t e B a k i n q Enamel Inaredients: ChemDol 10-01 73 D i m e t h y l ami n o e t h a n o l Byk VP020 Byk P-104s B u t y l Carbi t o 1 Water T i -Pure R-900

Pounds 126.75 8.58 2.47 4.17 19.80 69.43 207.31

Gal l o n s 14.64 1 .16 0.33 0.53 2.49 8.33 6.04

Weigh i n f i r s t f o u r i n g r e d i e n t s and m i x we1 1 . Add w a t e r s e p a r a t e l y w i t h a g i t a t i o n . Add pigment s l o w l y w i t h c o n t i n u e d agitation. S a n d m i l l t o #7 Hegman k e e p i n g g r i n d t e m p e r a t u r e below 120F w i t h water j a c k e t . L e t down w i t h : Chempol 10-01 73 Dimethylami n o e t h a n o l Butyl Cellosolve Byk 301 Cyme1 303 Water Water ( h o l d t o a d j u s t v i s c o s i t y )

118.86 6.17 20.75 2.95 57.30 262.02 96.67

13.72 0.84 2.76 0.35 5.72 31.45 11.64

I n t h e " l e t down", p r e b l e n d t h e f i r s t f o u r i n g r e d i e n t s and m i x w e l l . Add w a t e r t o t h e m i x t u r e w i t h c o n t i n u e d a g i t a t i o n . Then add t h e " l e t down" p o r t i o n t o t h e g r i n d s l o w l y w i t h good a g i t a t ion. Check t h e pH and a d j u s t w i t h more D i m e t h y l a m i n o e t h a n o l i f n e c e s s a r y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % b y w e i g h t : 43-44 T o t a l s o l i d s , % by volume: 30-31 W e i g h t / g a l l o n , l b s . : 10.0-10.5 VOC ( l b s / g a l ) , l e s s w a t e r : 2.7-2.8 PVC, %: 20.003 V i s c o s i t y , #2 Zahn: 30"-40" pH: 8.5-9.0 S u b s t r a t e ; B o n d e r i t e 1000 CRS Bake: 1 0 ' @ 325F DFT: 1 . 0 - 1 . 2 m i l s G l o s s : 60: 80 20: 40 P e n c i l hardness: F-2H MEK: Passed 50 Double Rubs Impact r e s i s t a n c e : Passed 60 i n c h pounds C r o s s h a t c h : 100% r e t e n t i o n

SOURCE: Freeman Polymers D i v i s i on : CHEMPOL 10-01 73-8 Formula

222

Water -Based Paint Formulations

Accent-Base

Trim Paint

I n a r e d ie n t s : Piament G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-4400 Propylene G l y c o l 2-Ami no-2-methyl-1 -propanol ( 1 ) Dispersant ( 2 ) Antifoam (3) Preservative (4) T r i t o n N o n i o n i c S u r f a c t a n t N-101 Clay ( 5 ) Nephel ine S y e n i t e ( 6 ) Letdown : Ucar L a t e x 624 Ucar F i l m e r IBT Antifoam (3) Mildewcide ( 7 ) T r i t o n N o n i o n i c S u r f a c t a n t CA T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gallons

302.5 51.8 2.0 2.5 1.9 2.3 2.2 50.0 25.0

36.32 0.45 6.00 0.25 0.25 0.25 0.25 0.25 2.07 1.13

438.9 11 .o 1.9 7.3 2.1 1. I 0.9

49.88 1.39 0.25 0.75 0.25 0.13 0.13

5.0

Suppl ie r s : ( 1 ) 2-Ami no-2-methyl -1-propanol - AMP-95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 653 o r e q u i v a l e n t ( 4 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t (5) Clay " P o l y g l o s s " 90 o r e q u i v a l e n t ( 6 ) N e p h e l i n e S y e n i t e - "Minex" 10 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r e q u i v a l e n t

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 1 2 . 0 Volume S o l i d s , %: 26.7 V i s c o s i t y , e q u i 1 ib r a t e d : Stormer, KU: 86 I C I , p o i s e : 0.8 Weight p e r G a l l o n , l b : 9.08 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Film Properties: G l o s s , 60: 50 Gloss, 20: 13 Flow and L e v e l i n g , b r u s h e d : F a i r Wet Adhesion: E x c e l l e n t C o l o r Acceptance : H u l s C o l o r 64A-1A Nuance System: E x c e l l e n t H u l s C o l o r 73A-1A Nuance System: E x c e l l e n t

SOURCE:

Ucar Emulsion Systems: S u g g e s t i o n E-2421

UCAR L a t e x 624:

Formulation

Exterior Paints and Related

223

C l e a r Wood P r e s e r v a t i v e Gals. Lbs. Material: 166.0 20.00 K e l s o l 3931 -WG4 45 7.5 1 .oo Butoxy Ethanol 25.0 1.50 S y l o i d 234 G r i n d t h e above t o a 6 Hegman g r i n d , t h e n add t h e f o l l o w i n g and d i s p e r s e 10- 5 m i n u t e s : 28.7 3.50 M i cheml ube 743 Letdown : K e l sol 3931 -WG4-45 207.5 25.00 Premix t h e n e x t two m a t e r i a l s , t h e n add under good a g i t a t i o n : Manganese H y d r o c u r e I 1 6.4 0.75 Butoxy Ethanol 7.5 1 .oo Premix t h e n e x t f o u r m a t e r i a l s , t h e n add under good a g i t a t i o n : A e r o s o l OT-75 2.3 0.25 I n t e r c i d e T-0 7.3 0.75 Polyphase AF-1 9.8 1 .oo Butoxy E t h a n o l 15.0 2.00 Add t h e f o l l o w i n g under good a g i t a t i o n : Ammoni um H y d r o x i de Water

1.9 358.2

Anal y s i s : P i gment Volume C o n c e n t r a t i o n , P e r c e n t : 6 . 2 P i gment/Bi n d e r R a t i o : . 2 / 1 P e r c e n t S o l i d s , W e i g h t : 26.0 P e r c e n t S o l i d s , Volume: 24.1 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 32 Pounds/Gal 1on : 8 . 4 pH: 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 272 Pounds/Gallon: 2.3

SOURCE:

R e i c h h o l d Chemicals, I n c . : F o r m u l a t i o n 2262-12C

Waterborne Handbook:

0.25 43.00

224

Water-Based Point Formulations

Deep-Base T r i m P a i n t Inaredients: Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-4400 Propylene G l y c o l 2-Amino-2-methyl-1-propanol (1) Dispersant (2) Antifoam ( 3 ) Preservative (4) T r i t o n N o n i o n i c S u r f a c t a n t N-101 Titanium Dioxide ( 5 ) Nepheline S y e n i t e ( 6 )

Pounds

Gal l o n s

257.5 4.5 51 .8 2.0 50.0 1.9 2.3 2.2 75.0 75.0

30.91 0.41 6.00 0.25 0.50 0.25 0.25 0.25 2.15 3.30

464.3 11.6 1.9 7.3 2.1 1.1 0.9

52.76 1 .46 0.25 0.75 0.25 0.13 0.13

Letdown : Ucar L a t e x 624 Ucar F i l m e r IBT Antifoam (3) Mildewcide ( 7 ) T r i t o n N o n i o n i c S u r f a c t a n t CA T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Suppl ie r s : - AMP-95 o r e q u i v a l e n t ( 1 ) 2-Amino-2-methyl-1-propanol ( 2 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 653 o r e q u i v a l e n t ( 4 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - " T i o n a " RCL-535 o r e q u i v a l e n t ( 6 ) N e p h e l i n e S y e n i t e - "Minex" 10 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 1 8 . 0 Volume S o l i d s , %: 30.3 Viscosity, equilibrated: Stormer, KU: 90 I C I , p o i s e : 0.95 Weight p e r G a l l o n , l b : 9 . 6 6 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Film Properties: G l o s s , 60: 33 Gloss, 20: 6 Flow and L e v e l i n g , brushed: F a i r Wet Adhesion: Very Good C o l o r Acceptance: H u l s 236-30 Nuance System: E x c e l l e n t H u l s 73C-30 Nuance System: Very Good

SOURCE:

Ucar Emulsion Systems: UCAR L a t e x 624: F o r m u l a t i o n S u g g e s t i o n E-2420

Exterior Paints and Related

Econonv W h i t e House P a i n t I n a r e d ie n t s : Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-3OM P r e s e r v a t ive ( 1 ) Dispersant (2) T r i t o n Nonionic Surfactant N - 1 0 1 Antifoam (3) Propylene G l y c o l Titanium Dioxide (4) Clay ( 5 ) Talc (6) Letdown : Ucar L a t e x 624 Ucar F i l m e r IBT Antifoam (3) Mildewcide ( 7 ) T r i t o n N o n i o n i c S u r f a c t a n t CA Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gal l o n s

492.7 4.5 2.3 7.4 2.1 1.9 13.0 150.0 50.0 150.0

59.15 0.41 0.25 0.75 0.25 0.25 1.50 4.31 2.31 6.32

199.0 6.0 1.9 4.9 2.1 0.9

22.61 0.76 0.25 0.50 0.25 0.13

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 650 o r e q u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - " T i o n a " RCL-535 o r e q u i v a e n t ( 5 ) C l a y - "Kaopaque" 105 o r e q u i v a l e n t ( 6 ) T a l c - " N y t a l " 300 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r equ v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 55.0 Volume S o l i d s , %: 23.7 V i s c o s i t y , equ 1 ib r a t e d : Stormer, KU 86 I C I , poise: 0.4 Weight p e r Gal on, l b : 10.89 Freeze-thaw S t a b i 1 i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m P r o p e r t i es : C o n t r a s t R a t i o , 6 - m i l wet drawdown ( 1 ) : R e f l e c t a n c e , %: 8 8 . 6 Sheen, 85: 3 . 9 Flow and L e v e l i n g , brushed: Good Wet Adhesion: Excel 1e n t

0.927

( 1 ) O p a c i t y c o u l d be i n c r e a s e d by t o n i n g .

SOURCE: UCAR Emulsion Systems: UCAR L a t e x 624: F o r m u l a t i o n S u g g e s t i o n E-2414

225

226

Water-Based Paint Formulations

E x t e r i o r F l a t House P a i n t - W h i t e Pounds

Gal 1ons

Water Cel l o s i ze H y d r o x y e t h y l C e l l u l ose ER- .30m P r e s e r v a t ive ( 1 ) D i s p e r s a n t (2) A n t i f o a m (3) T r i t o n N o n i o n i c S u r f a c t a n t N-101 P r o p y l e n e G1 y c o l T i t a n i u m D i o x i d e (4) Nephel ine S y e n i t e (5) Talc (6)

301.2 4.0 2.3 7.7 1.9 2.1 25.9 225.0 100.0 100.0

36.16 0.36 0.25 0.75 0.25 0.25 3.00 6.59 4.61 4.21

Letdown : Ucar L a t e x 625 Ucar F i l m e r IBT A n t i f o a m (3) M i l d e w c i d e (7) T r i t o n N o n i o n i c S u r f a c t a n t CA Ammoni um H y d r o x i de, 28% Aqueous Sol u t i on

357.2 8.9 1.9 15.0 2.1

40.36 1.12 0.25 1.46 0.25 0.13

Ingredients:

P i gment G r i nd :

0.9

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t (2) D i s p e r s a n t - " C o l l o i d " 270 o r e q u i v a l e n t (3) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t (4) T i t a n i u m D i o x i d e - "Tronox" CR-828 o r e q u i v a l e n t (5) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t (6) T a l c - " N y t a l " 300 o r e q u i v a l e n t (7) M i 1dewci de - "NuoCi de" 404-D o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 44.7 Volume S o l i d s , %: 34.5 V i s c o s i t y , equ 1 ib r a t e d : Stormer, KU 93 I C I , p o i s e : 0.5 Weight p e r Gal on, l b : 11.56 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass

F i l m Properties: Contrast Ratio: 6 - m i l wet drawdown: 0.981 Ref 1e c t a n c e , %: 89.8 Sheen, 85: 4.0 Wet Adhesion, g l o s s a l k y d : 4-hour d r y : E x c e l l e n t 24-hour d r y : E x c e l l e n t SOURCE:

Ucar Emulsion Systems: Suggestion € 4 4 3 7

UCAR L a t e x 625: F o r m u l a t i o n

Exterior Paints and Related

227

Exterior Flat Paint N a t r o s o l 250HR, 2 1/2% E t h y l e n e G1y c o l P r o p y l ene G l y c o l Texanol D i s p e r s a n t ( 4 . 5 1b s . a c t i v e ) KTPP T r i t o n CF-10 Drew L-475 Horsehead RF-30 S t . Joe #40 ZnO A s b e s t i n e 3X Nopcoci de N-96

110 25 34 11 18 1.5 2.5 1 .o 250 50 179 5

N a t r a s o l 250HR 2-1/2% Water Drew L-475 NH40H (28%) Rhopl ex AC-388

30 34 3 2 464

Weight p e r G a l l o n : 12.08 Weight S o l i d s : 58.3%

Volume S o l i d s : PVC: 39

40.2%

F o r m u l a t i o n 1203-7 Exterior Flat Paint N a t r o s o l 250HR 2-1/2% E t h y l e n e G1 y c o l P r o p y l ene G1y c o l Texanol Dispersant (4.5 l b s . a c t i v e ) KTPP T r i t o n CF-10 Drew L-475 Zopaque RCL-9 S t . Joe #40 ZnO A s b e s t i n e 3X Skane M8

110 25 34 11 12.6 1.5 2.5 1.o 250 50 179 2

N a t r o s o l 250HR 2-1/2% Water Drew L-475 NH4OH (28%) Rhopl ex AC-388

30 34 3 2 464

Weight p e r G a l l o n : 12 08 Weight S o l i d s : 58.7%

Volume Sol i d s : PVC: 39

40.5%

F o r m u l a t i o n 1203-8

SOURCE: Uni r o y a l Chemica

Co.,

I n c . : POLYWET RC-54

228

Water-Based Paint Formulations

Exterior Flat Paint

__ E 13998, F e d e s l S p e c i f _ i c a t i o n TT-P-19C. M a t e r i a1 s : Water Tamol 8 5 0 P o t a s s i um t r i p o l y p h o s p h a t e D o w i c i l 75 I g e p a l CO-610 Ethylene g l y c o l Skane M-8 H e r c u l e s 501 defoamer Texanol T i -Pure R-900 Horsehead XX503 N y t a l 300 Rhopl ex AC-829 Ammonium h y d r o x i d e , 28% 3% Natr-osol P l u s s o l u t i o n / w a t e r P a i n t P r o p e r t ies : Pigment volume c o n c e n t r a t i o n , %: S o l i d s , w t %: 56 S o l i d s , volume %: 39 Pigment, w t %: 35.7 W t / g a l , l b s : 11.9

Amendment 1

!=& 100.0 6.0 1.o 0.5 3.0 20.0 2.0 3.0 12.0 250.0 50.0 125.0 401 .O 2.0 208.0

Gal 12.0 0.5 0.3 2.2 0.2 0.3 1.5

1.5 1.1 5.3 43.6 0.2 25.3

37.2

P r o p e r t i e s e x h i b i t e d when p a i n t i s t h i c k e n e d w i t h N a t r o s o l P l u s : V i s c o s i t y , KU: 98 Brushing v i s c o s i t y , poises: 1.5 Spatter: 8 Leveling: 2 Sag r e s i s t a n c e : 21.75 Scrub c y c l e s t o f a i l u r e : 283 C o n t r a s t r a t i o : 0.92

SOURCE: Aqualon Co.:

NATROSOL PLUS: F o r m u l a t i o n 2

Exterior Paints and Related

E x t e r i o r F l a t W h i t e House P a i n t w i t h Zinc O x i d e Innredients : Pigment G r i nd : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30M Preservative (1) D i spersant (2) A n t i f o a m (3) T r i t o n N o n i o n i c S u r f a c t a n t N-101 P r o p y l e n e G1y c o l P o t a s s i u m T r i p o l y p h o s p h a t e (KTPP) Titanium Dioxide (4) Z i n c Oxide ( 5 ) Nepheline Syenite (6) Talc (7) Letdown : Ucar L a t e x 625 Ucar F i l m e r I B T Antifoam ( 3 ) Mildewcide (8) T r i t o n N o n i o n i c S u r f a c t a n t CA Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gallons

307.1 3.5 2.3 10.3 1.9 2.1 25.9 1.o 225.0 25.0 100.0 75.0

36.87 0.32 0.25 1 .oo 0.25 0.25 3.00 0.05 6.59 0.54 4.61 3.16

357.2 8.9 1.9 10.2 2.1 0.9

40.36 1.12 0.25 1 .oo 0.25 0.13

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - " C o l l o i d " 270 o r e q u i v a l e n t (3) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - "Tronox" CR-828 o r e q u i v a l e n t ( 5 ) Z i n c Oxide - "XX-503R" o r e q u i v a l e n t ( 6 ) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t ( 7 ) T a l c - " N y t a l " 300 o r e q u i v a l e n t ( 8 ) M i l d e w c i d e - "Nuocide" 404-D o r e q u i v a l e n t

Pai n t P r o p e r t ie s : Pigment Volume C o n c e n t r a t i o n , %: 4 3 . 8 Volume S o l i d s , %: 34.0 V i s c o s i t y , e q u i 1 ib r a t e d : S t o r m e r , KU: 87 I C I , poise: 0.4 Weight p e r G a l l o n , l b : 1 1 . 6 0 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass F i 1m P r o p e r t ies : C o n t r a s t R a t i o : 6 - m i l wet drawdown: 0 . 9 8 1 R e f l e c t a n c e , %: 8 9 . 9 Sheen, 8 5 : 5 . 7 Wet Adhesion, g l o s s a l k y d : 4-hour d r y : E x c e l l e n t 24-hour d r y : E x c e l l e n t C h a l k Adhesion, ASTM #5: E x c e l l e n t SOURCE: Ucar E m u l s i o n Systems: S u g g e s t i o n E-2441

UCAR L a t e x 625: F o r m u l a t i o n

229

230

Water-Based Paint Formulations

E x t e r i o r House P a i n t - T i n t

Base Pounds

Gallons

Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30M P r e s e r v a t ive ( 1 ) Dispersant (2) Antifoam (3) T r i t o n N o n i o n i c S u r f a c t a n t N-101 2-Amino-2-methyl-I-p opanol ( 4 ) P r o p y l e n e G1 y c o l Titanium Dioxide (5) Nepheline S y e n i t e ( 6

267.0 3.5 2.3 5.2 1.9 2.1 2.0 25.9 150.0 200.0

32.05 0.32 0.25 0.50 0.25 0.25 0.25 3.00 4.39 9.23

Letdown : Ucar L a t e x 625 Ucar F i l m e r I B T Antifoam ( 3 ) Mildewcide (7) T r i t o n N o n i o n i c S u r f a c t a n t CA

415.5 10.4 1.9 7.3 2.1

46.95 1.31 0.25 0.75 0.25

In a r e d i e n t s :

Suppl i e r s : (1) Preservative "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - " C o l l o i d " 270 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t ( 4 ) 2-Amino-2-methyl-1-propanol - AMP-95 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-808 o r e q u i v a l e n t ( 6 ) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Troysan Polyphase" AF-1 o r e q u i v a l e n t

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 38.0 Volume S o l i d s , %: 35.8 V i s c o s i t y , equi 1 ib r a t e d : Stormer, KU: 94 I C I , p o i s e : 0.55 Weight p e r G a l l o n , l b : 10.97 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Fi m Properties: C o n t r a s t R a t i o : 6 - m i l wet drawdown: 0.955 R e f l e c t a n c e , %: 8 9 . 7 Sheen, 85: 4.5 Wet Adhesion, g l o s s a l k y d : 4-hour d r y : E x c e l l e n t 24-hour d r y : Excel l e n t oz./gal: C o l o r Acceptance, 4 f l H u l s 888-7214E: E x c e l l e n t H u l s 888-1045F: E x c e l l e n t

.

SOURCE:

Ucar Emulsion Systems: S u g g e s t i o n E-2438

UCAR L a t e x 625:

Formulation

Exterior Paints and Related

E x t e r i o r Semi -Gloss

Lbs.

M a t e r i a1 : Water T r i t o n X-102 C o l l o i d 226 C o l l o i d 643 B u t y l Carbi t o 1 AMP 95 Nopcocide N-40D

116.6 2.0 8.0 2.0 9.6 1.6 12.0

Gals. 14.00 0.26 0.78 0.26 1.21 0.18 1.31

Premix t h e f o l l o w i n g , t h e n add: P r o p y l e n e G1 y c o l N a t r o s o l 250MR T i t a n o x 2101 ASP 170 H i g h speed d i s p e r s e r , 15 m i n u t e s maxi mum. Water C o l l o i d 643 Synthemul 40-412 T r i t o n N-57

25.1 1.5 250.0 40.0

2.90 0.13 7.31 1.86

10.6 2.0 439.0 1.5

1.27 0.26 50.46 0.16

Premix t h e f o l l o w i n g b e f o r e a d d i n g : P r o p y l e n e G1 y c o l SCT 270 Water

25.1 24.0 100.0

2.90 2.75 12.00

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 27.5 P e r c e n t S o l i d s , Weight: 4 7 . 6 P e r c e n t S o l i d s , Volume: 3 3 . 3 I n i t i a l V i s c o s i t y , KU: 80-85 Pounds/Gallon: 10.70 pH: 8.5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 175.0 81 is t e r Resi s t a n c e : Exc. Wet Adhesion ( A l k y d ) : Exc. C o n t r a s t R a t i o ( 3 m i l s w e t ) : 0.975 G l o s s @ 60: 25

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 412-01

I n c . : Waterborne Handbook:

231

232

Water-Based Paint Formulations

E x t e r i o r Sheen House P a i nt-Whi t e Pounds Gal 1ons I n n r e d ie n t s : Pigment G r i n d : Water 199.9 24.00 Ucar Polyphobe 104 Rheology M o d i f i e r 3.3 0.37 2-Amino-2-methyl-1-propanol (1) 3.0 0.37 Preservative (2) 2.3 0.25 D i spersant (3) 7.7 0.75 Antifoam (4) 1.9 0.25 T r i t o n N o n i o n i c S u r f a c t a n t N-101 2.1 0.25 Propylene G l y c o l 34.6 4.00 Titanium Dioxide (5) 225.0 6.67 Nepheline S y e n i t e ( 6 ) 75.0 3.46 China C l a y ( 7 ) 25.0 1.14 Letdown : Water 65.7 7.89 Water )Premix 16.7 2.00 Ucar Polyphobe 102 Rheology M o d i f i e r ) 17.4 2.00 Ucar L a t e x 625 391.4 44.23 Ucar F i l m e r I B T 9.8 1.24 Antifoam (4) 1.9 0.25 M i 1dewci de ( 8 ) 7.3 0.75 Surfactant (9) 1.1 0.13 Suppl ie r s : ( 1 ) 2-Ami no-2-methyl -1 - p r o p a n o l - AMP-95 o r e q u i Val e n t ( 2 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 3 ) D i s p e r s a n t - " C o l l o i d " 270 o r e q u i v a l e n t ( 4 ) A n t i f o a m - " C o l l o i d " 643 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - " T i o x i d e " TR92 o r e q u i v a l e n t ( 6 ) N e p h e l i n e S y e n i t e - "Minex" 10 o r e q u i v a l e n t ( 7 ) China C l a y - "Burgess" No. 98 o r e q i u i v a l e n t ( 8 ) Mildewcide "Troysan Polyphase" AF-1 o r e q u i v a l e n t ( 9 ) S u r f a c t a n t - "Pentex" 99 A n i o n i c S u r f a c t a n t o r e q u i v a l e n t

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 35.0 Volume S o l i d s , %: 32.2 V i s c o s i t y , equi 1 ib r a t e d : Stormer, KU: 90 I C I , poise: 1.1 Weight p e r G a l l o n , l b : 10.91 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m P r o p e r t i es : C o n t r a s t R a t i o : 6 - m i l wet drawdown: 0.971 Ref 1e c t a n c e , %: 9 0 . 9 Sheen, 85: 53.3 Gloss, 60: 11.7 Flow and L e v e l i n g , brushed: Good Wet Adhesion, g l o s s a l k y d : 4-hour d r y : E x c e l l e n t 24-hour d r y : E x c e l l e n t SOURCE: Ucar Emulsion Systems: S u g g e s t i o n E-2439

UCAR L a t e x 625:

Formulation

Exterior Paints and Related

E x t e r i o r T r i m House P a i nt-Whi t e Pounds

Gallons

166.6 8.8 3.0 2.3 60.5 7.4 1.9 2.1 250.0 2.0

20.00 1 .oo 0.37 0.25 7.00 0.62 0.25 0.25 7.50 0.10

Letdown : Water 79.4 Water )Premix 12.5 Ucar Polyphobe 102 Rheology M o d i f i e r ) 13.2 Ucar L a t e x 625 420.8 Ucar F i l m e r IBT 10.5 Antifoam (4) 2.8 M i 1dewci de ( 7 ) 7.3 T r i t o n A n i o n i c S u r f a c t a n t GR-7M 1.1

9.53 1.50 1.50 47.55 1.33 0.37 0.75 0.13

Ingredients: Pigment G r i nd: Water Ucar Polyphobe 102 Rheology M o d i f i e r 2-Ami no-2-methyl -1 - p r o p a n o l ( 1 ) Preservative (2) P r o p y l e n e G1y c o l Dispersant (3) Antifoam (4) T r i t o n N o n i o n i c S u r f a c t a n t N-57 Titanium Dioxide (5) A t t a p u l g i t e Clay (6)

Suppl ie r s : ( 1 ) 2-Amino-2-methyl-1-propanol - AMP-95 o r e q u i v a l e n t ( 2 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 3 ) D i s p e r s a n t - " C o l l o i d " 286 o r e q u i v a l e n t ( 4 ) A n t i f o a m - " C o l l o i d " 653 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - " T i - P u r e " R-702 o r e q u i v a l e n t ( 6 ) A t t a p u l g i t e C l a y - " A t t a g e l " 50 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - Troysan Polyphase" AF-1 o r e q u i v a l e n t Paint Properties: P i gment Volume C o n c e n t r a t i o n , %: 25.2 Vol ume Sol ids, %: 30.1 V i s c o s i t y , equ 1 ib r a t e d : Stormer, KU 90 I C I . ooise: 1.1 W e i g h t - p e r G a l l o n , l b : 10.52 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass F i m Properties: C o n t r a s t R a t i o : 6 - m i l wet drawdown: 0.967 R e f l e c t a n c e , %: 9 2 . 3 G l o s s , 60: 7 4 . 1 G l o s s , 20: 2 6 . 4 Flow and L e v e l i n g . brushed: Very Good Wet Adhesion, g l o s s a l k y d : 4-hour d r y : E x c e l l e n t 24-hour d r y : E x c e l l e n t SOURCE: Ucar Emulsion Systems: S u g g e s t i o n E-2440

UCAR L a t e x 625: F o r m u l a t i o n

233

234

Water-Based Paint Formulations

E x t e r i o r White Pounds N a t r o s o l 250 HR, 2% Tamol 731 I g e p a l CO-610 C o l l o i d 677 Ethylene Glycol Texanol Troysan Polyphase AF-1 Tronox CR 820 N y t a l 300 Water N a t r o s o l 250 HR, 2% Flexbond 325

100 7 3 3 25 8 5 2 50 100 150 175 300

Y i e l d , g a l l o n s : 101 S o l i d s , %: 46 PVC, %: 40 V i s c o s i t y , KU: 90 VOC, gm/l - w a t e r : 125 F o r m u l a t i o n No. 32514 Lower C o s t W h i t e and T i n t Pounds Methocel J-12-HS, 3% Tamol 731 AMP-95 W i t c o 3056-A I g e p a l CO-610 Ethylene Glycol Texanol Tronox CR-812 S a t i n t o n e #1 Camel -Carb C e l i t e 499 Water W i t c o 3056-A Merbac 35 Methocel J-12-HS, 3% Flexbond 325 Yield, gallons: S o l i d s , %: 48 PVC, %:

100 6

2 2 3 20 8 175 100 125 50 276 1 1 100 180

100

63

VOC, gm/l - w a t e r : 117 F o r m u l a t i o n No. 32513

SOURCE: A i r P r o d u c t s and Chemicals,

I n c . : FLEXBOND 325 V i n y l A c r y l i c Emulsion: T y p i c a l S t a r t i n g F o r m u l a t i o n s

235

Exterior Paints and Related

E x t e r i o r W h i t e House P a i n t N a t r o s o l P l u s , Grade 330, 3% Tamol 731 AMP 95 S u r f y n o l TG Drew L-475 Propylene G l y c o l Texanol T i -Pure R-902 N y t a l 300 Troysan Polyphase AF-1 Nuosept 95

100 7 2 2

Water N a t r o s o l P l u s , Grade 330, Drew L-475 A e r o s o l OT, 75% Flexbond 380 DEV

165 150 2 1 300

2

25 10 250 100 5 1

3%

Y i e l d , g a l l o n s : 101 S o l i d s , %: 46 PVC, %: 40 V i s c o s i t y , KU: 100 VOC, gm/l - w a t e r : 139

SOURCE: A i r P r o d u c t s and Chemicals, I n c . : F o r m u l a t i o n 38014

FLEXBOND 380 DEV:

Wood Panel F i l l e r Water Tamol 850 T r i t o n CF-10 Foamaster R T i -Pure R-901 ASP-400 N o v a c i t e S-325 D i s p e r s e on h i g h shear d i s p e r s e r Merbac 35 V i n a c 885

Pounds 247 14 3 2 95 61 6 327 0.35 236

V i s c o s i t y : 73 KU Y i e l d : 100 g a l l o n s S o l i d s b v Weiaht: 73.2% Sol i d s by Vol &e: 53.7% PVC: 79% W e i g h t / G a l l o n : 14.5 pounds

SOURCE: A i r P r o d u c t s and Chemicals, I n c . : V I N A C 885 Emulsion: F o r m u l a t i o n No. 2794-78-1

236

Water-Based Paint Formulations

F l e x i b l e . Premium-Performance,

Hiqh-Solids Caulk P a r t s by Weiaht 54.3 38.0 0.8 0.7 0.5 0.8 12.5 9.0 2.9 1.5 1.4 1.0 27.2 48.0 0.4 1.0

_ Pounds_ G a l l o_ ns UCAR L a t e x 154 (60% N.V.) Surfactant (1) Dispersant ( 2 ) P l a s t i c i z e r (3) T o o l i n g Agent ( 4 ) E t h y l e n e G1 y c o l F i l l e r (5) Titanium Dioxide (6)

488.0 9.0 10.0 115.5 19.5 13.0 616.0 12.5

~

Suppl ie r s : ( 1 ) S u r f a c t a n t - " T r i t o n " X-405 o r e q u i v a l e n t (2) Dispersant - Composition T o r e q u i v a l e n t ( 3 ) P l a s t i c i z e r - " S a n t i c i z e r " 160 o r e q u i v a l e n t ( 4 ) T o o l i n g Agent - " V a r s o l " No. 1 o r e q u i v a l e n t ( 5 ) F i l l e r - "Atomite" o r e q u i v a l e n t ( 6 ) T i t a n i u m D i o x i d e - "Ti-Pure'' R-901 o r e q u i v a l e n t P r o p e r t ies : T o t a l S o l i d s : 83.3% b y w t Weight p e r G a l l o n , T h e o r e t i c a l : 1 2 . 8 l b F i l l e r / L a t e x S o l i d s R a t i o : 2 . 2 / 1 .O P l a s t i c i z e r (on t o t a l b i n d e r s o l i d s ) : 28.5% by w t Shore " A " Hardness ( 4 weeks 73F, 50% RH): 26 T e n s i l e ( 2 weeks, 73F, 50% R H ) : 9 p s i E l o n g a t i o n ( 2 weeks, 73F, 50% R H ) : 185% 180 Peel Adhesion ( p e r i n c h ) : P i newood : 1 1 1b ( c o h e s i ve/adhesi ve) Aluminum: 23 l b ( c o h e s i v e ) G l a s s : 20 l b ( c o h e s i v e / a d h e s i v e ) E x t r u s i o n : Good gunnabi l i t y ASTM S h r i n k a g e ( 2 8 days, 73F, 50% R H ) : 25% o r l e s s Slump a t Room Temperature: None Recovery (25% E x t e n s i o n RT f o r 1 / 2 h r . ) : 70% or g r e a t e r XW A c c e l e r a t e d Weathering, Wood Channel, 1500t h o u r s : E x c e l lent

SOURCE: Union C a r b i d e Corp.:

UCAR L a t e x 154: Table 8

Exterior Paints and Related

General Purpose M a s t i c Ingredients: UCAR L a t e x 154 Antifoam (1) P o t a s s i um T r i p o l y p h o s p h a t e (KTPP) Dispersant ( 2 ) TERGITOL N o n i o n i c S u r f a c t a n t NP-40, Aqueous Sol u t i on Plasticizer (3) Odorless Mineral S p i r i t s Preservative (4) Z i n c Oxide T i t a n i um D i o x i d e Mica Talc C a l c i um Carbonate

Pounds 685.8 7.4 1 .o 4.9

Gal 1ons 76.2 1.o 0.1 0.5

0.7 23.3 13.2 2.0 25.0 25.0 150.0 100.0 100.0

1.o 2.5 2.0 0.3 0.5 0.7 6.4 4.4 4.4

70%

Suppl i e r s : ( 1 ) A n t i f o a m - " C o l l o i d " 679 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 850 or e q u i v a l e n t ( 3 ) P l a s t i c i z e r - " S a n t i c i z e r " 160 o r e q u i v a l e n t ( 4 ) P r e s e r v a t i v e - "Troysan" 364 o r e q u i v a l e n t Properties: Weight p e r G a l l o n : 1 1 . 4 l b P i gment/Bi n d e r : 1/1 Total Solids: b y Volume: 60.6% by Weight: 70.7% Pigment Volume C o n c e n t r a t i o n (PVC): 27% C o n s i s t e n c y : Paste-1 ike

SOURCE:

UCAR L a t e x 154: T a b l e 6

237

238

Water-Based Paint Formulations

Q u a l i t y Deep-Base House P a i n t Ingredients: Pigment G r i n d : Water Cel l o s i ze H y d r o x y e t h y l Cel u l o s e ER-30M P r e s e r v a t ive ( 1 ) Antifoam (2) Dispersant ( 3 ) T r i t o n N o n i o n i c S u r f a c t a n t N-101 2-Amino-2-methyl-I-propano (4) P r o p y l e n e G1 y c o l T i t a n i um D i o x i d e ( 5 ) Nepheline S y e n i t e (6) Letdown: Ucar L a t e x 624 Ucar F i l m e r IBT Antifoam (2) M i l d e w c i d e (71 T r i t o n N o n i o n i c S u r f a c t a n t CA Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gal 1ons

277.0 4.0 2.3 1.9 5.0 2.2 2.0 17.3 75.0 250.0

33.25 0.36 0.25 0.25 0.50 0.25 0.25 2.00 2.15 11.33

411.2 10.3 1.9 7.3 2.1 0.9

46.73 1.30 0.25 0.75 0.25 0.13

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) A n t i f o a m - " C o l l o i d " 650 o r e q u i v a l e n t ( 3 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 4 ) 2-Amino-2-methyl -1 - p r o p a n o l - AMP-95 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - " T i o n a " RCL-535 o r e q u i v e l e n t ( 6 ) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 38.0 Volume S o l i d s , %: 35.5 V i s c o s i t y , e q u i 1 ib r a t e d : Stormer, KU: 92 I C I , poise: 1.0 Weight p e r G a l l o n , l b : 10.70 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass

F i l m Properties: Sheen, 85: 2.2 Flow and L e v e l i n g , brushed: Good Wet Adhesion : Excel l e n t C o l o r Acceptance: H u l s 238-3D Nuance System: E x c e l l e n t H u l s 73C-3D Nuance System: Very Good C o l o r Match t o Chip: H u l s 236-30 Nuance System: E x c e l l e n t H u l s 73C-3D Nuance System: Very Good

SOURCE: Ucar Emulsion Systems: UCAR L a t e x 8 2 4 : F o r m u l a t i o n S u g g e s t i on E-241 8

Exterior Paints and Related

Q u a l i t y Deep-Base House P a i n t Inqredients: Pigment G r i n d : Water Cel l o s i ze H y d r o x y e t h y l C e l l u l o s e ER-30M Preservative (1) Antifoam (2) Dispersant (3) T r i t o n N o n i o n i c S u r f a c t a n t N-101 2-Ami no-2-methyl -1 - p r o p a n o l ( 4 ) P r o p y l ene G1y c o l T i t a n i um D i o x i d e ( 5 ) Nephel ine S y e n i t e ( 6 ) Letdown : Ucar L a t e x 624 Ucar F i l m e r IBT Antifoam ( 2 ) Mildewcide (7) T r i t o n N o n i o n i c S u r f a c t a n t CA Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gallons

277.0 4.0 2.3 1.9 5.0 2.2 2.0 17.3 75.0 250.0

33.25 0.36 0.25 0.25 0.50 0.25 0.25 2.00 2.15 11.33

411 . 2 10.3 1.9 7.3 2.1 0.9

46.73 1.30 0.25 0.75 0.25 0.13

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) Antifoam " C o l l o i d " 650 o r e q u i v a l e n t ( 3 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 4 ) 2-Amino-2-methyl-1-propanol - AMP-95 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - " T i o n a " RCL-535 o r e q u i v e l e n t ( 6 ) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r e q u i v a l e n t

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 38.0 Volume S o l i d s , %: 3 5 . 5 V i s c o s i t y , e q u i 1 ib r a t e d : Stormer, KU: 92 I C I , poise: 1.0 Weight p e r G a l l o n , l b : 10.70 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m P r o p e r t i es : Sheen, 85: 2.2 Flow and L e v e l i n g , brushed: Good Wet Adhesion : Excel 1e n t C o l o r Acceptance: H u l s 23B-3D Nuance System: E x c e l l e n t H u l s 73C-3D Nuance System: Very Good C o l o r Match t o C h i p : H u l s 238-3D Nuance System: E x c e l l e n t H u l s 73C-3D Nuance System: Very Good

SOURCE: Ucar Emulsion Systems: UCAR L a t e x 624: S u g g e s t i o n E-2416

Formulation

239

240

Water-Based Paint Formulations

Q u a l i t y Sheen W h i t e House P a i n t I n q r e d ie n t s : Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-3OM P r e s e r v a t ive ( 1 ) P r o p y l ene G1y c o l D i spersant (2) T r i t o n N o n i o n i c S u r f a c t a n t N-101 Antifoam (3) Titanium Dioxide (4) Nephel ine S y e n i t e ( 5 ) Letdown : Ucar L a t e x 624 Ucar F i l m e r I B T M i 1dewci de ( 6 ) Antifoam (3) Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gallons

295.5 3.5 2.3 34.6 7.4 2.2 1.9 225.0 100.0

35.48 0.32 0.25 4.00 0.75 0.25 0.25 6.75 4.61

394.6 9.9 7.3 1.9 2.0

44.84 1 .25 0.75 0.25 0.25

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 3 ) Antifoam " C o l l o i d " 653 o r e q u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - "Ti-Pure" R-902 o r e q u i v a l e n t ( 5 ) N e p h e l i n e S y e n i t e - "Minex" 10 o r e q u i v a l e n t ( 6 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r e q u i v a l e n t

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 35.0 Volume S o l i d s , %: 3 2 . 5 V i s c o s i t y , e q u i 1 ib r a t e d : S t o r m e r , KU: 92 I C I , poise: 0.8 Weight p e r G a l l o n , l b : 10.88 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass

F i l m Properties: C o n t r a s t R a t i o , 6 - m i l wet drawdown: R e f l e c t a n c e , %: 9 1 . 4 Gloss, 60: 8 . 2 Gloss, 85: 45.0 Flow and L e v e l i n g , b r u s h e d : Good Wet Adhesion: E x c e l l e n t

SOURCE:

Ucar Emulsion Systems: S u g g e s t i o n E-2422

0.962

UCAR L a t e x 6 2 4 : F o r m u l a t i o n

Exterior Paints and Related

Qual it y T i nt-Base House P a i n t I n s r e d ie n t s : Water Cel l o s i ze H v d r o x-y e t h y .l C e l l u l o s e ER- .30M Preservative (1) Antifoam (2) Dispersant (3) T r i t o n N o n i o n i c S u r f a c t a n t N-101 2-Amino-2-methyl-l-propano1 ( 4 ) P r o p y l ene G1y c o l Titanium Dioxide (5) Nepheline Syenite (6) Letdown : Ucar L a t e x 624 Ucar F i l m e r I B T Antifoam (2) Mildewcide (7) T r i t o n N o n i o n i c S u r f a c t a n t CA Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds 267.6 3.0 2.3 1.9 7.4 2.2 2.0 21.6 150.0 225.0

Gal 1ons 32.13 0.27 0.25 0.25 0.75 0.25 0.25 2.50 4.30 10.19

406.5 10.2 1.9 7.3 2.1 0.9

46.19 1.29 0.25 0.75

0.25 0.13

Suppliers: ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) A n t i f o a m - " C o l l o i d " 650 o r e q u i v a l e n t ( 3 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 4 ) 2-Ami no-2-methyl -1 - p r o p a n o l - AMP-95 o r e q u i v a l e n t (5) Titanium Dioxide " T i o n a " RCL-535 o r e q u i v a l e n t "Minex" 4 o r e q u i v a l e n t (6) Nepheline S y e n i t e ( 7 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r e q u i v a l e n t

-

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 4 0 . 0 Volume S o l i d s , %: 36.2 V i s c o s i t y , e q u i 1 ib r a t e d : Stormer, KU: 94 I C I , poise: 1.2 Weight p e r G a l l o n , l b : 11.12 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m P r o p e r t i es : C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.946 R e f l e c t a n c e , %: 8 8 . 9 Sheen, 85: 3 . 5 Flow and L e v e l i n g , brushed: Good Wet Adhesion: E x c e l l e n t C o l o r Acceptance: H u l s 328-3T Nuance System: Excel 1e n t H u l s 73C-2T Nuance System: E x c e l l e n t SOURCE: Ucar Emulsion Systems: S u g g e s t i o n E-241 5

UCAR L a t e x 624: F o r m u l a t i o n

241

242

Water-Based Paint Formulations

Qual it y T i n t

Base House P a i n t ( C o n v e n t i o n a l 1

Inqredients: Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-3OM Preservative (1 ) Dispersant (2) T r i t o n N o n i o n i c S u r f a c t a n t N-101 Propylene G l y c o l Antifoam (3) Titanium Dioxide (4) Nephel ine S y e n i t e ( 5 ) Letdown : Opaque Polymer ( 6 ) Ucar L a t e x 376 Butyl C a r b i t o l Solvent Antifoam (3) M i 1dewci de ( 7 ) Nonionic Surfactant (8) Ammonium H y d r o x i d e 28% Aqueous S o l u t i o n

Pounds

Gallons

237.2 4.0 2.3 10.2 2.2 25.9 1.9 175.0 225.0

28.47 0.36 0.25 1.oo 0.25 3.00 0.25 5.09 10.37

-----

-----

435.1 11.9 1.9 7.3 2.1 1.o

48.08 1.50 0.25 0.75 0.25 0.13

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - " C o l l o i d " 226/35 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - " T i - P u r e R-902" o r e q u i v a l e n t ( 5 ) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t ( 6 ) Opaque Polymer - "Ropaque" OP-62 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Troysan Polyphase" AF-1 o r e q u i v a l e n t ( 8 ) N o n i o n i c S u r f a c t a n t - "Color-Sperse" 188-A o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 38.5 S o l i d s , %: by Volume: 40.2 by Weight: 56.9 Viscosity ( i n i t i a l ) : Stormer, KU: 85 I C I , poise: 1.0 pH ( i n i t i a l ) : 8 . 2 Weight p e r G a l l o n , l b . : 1 1 . 4 3 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass ( + 4 KU) Heat S t a b i l i t y , 2 weeks a t 120F: Pass ( + 2 KU) Film Properties: C o n t r a s t R a t i o , 3 m i l f i l m : 0.966 Ref 1 e c t a n c e , %: 90. 5 Sheen, 85: 5 . 5 C o l o r Acceptance ( 1 ) : Excel l e n t ( 1 ) 4 f l . o z . / g a l l o n H u l s 888-1045°F"

Colorant

SOURCE: Ucar Emulsion Systems: UCAR L a t e x 36?/UCAR L a t e x 376: F o r m u l a t i o n S u g g e s t i o n E-2211 ( C o n v e n t i o n a l )

Exterior Paints and Related

Q u a l i t v T i n t Base House P a i n t IReduced T i 0 2 1

I n g r e d ie n t s :

Pounds

Gal 1ons

Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-.30M P r e s e r v a t i v e (1 ) Dispersant (2) T r i t o n N o n i o n i c S u r f a c t a n t N-101 P r o p y l e n e G1y c o l Antifoam (3) Titanium Dioxide (4) Nephel ine S y e n i t e (5)

203.6 4.2 2.3 7.7 2.2 25.9 1.9 125.0 150.0

24.44 0.39 0.25 0.75 0.25 3.00 0.25 3.63 6.91

Letdown : Opaque Polymer ( 6 ) Ucar L a t e x 376 B u t y l C a r b i t o l Solvent Antifoam (3) Mildewcide (7) Nonionic Surfactant (8) Ammonium H y d r o x i d e 28% Aqueous S o l u t i o n

105.8 406.6 13.9 1.9 7.3 2.1 1.o

12.27 44.93 1.75 0.25 0.75 0.25 0.13

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - " C o l l o i d " 226/35 o r e q u i v a l e n t (3) Antifoam " C o l l o i d " 640 o r e q u i v a l e n t (4) Titanium Dioxide " T i - P u r e " R-902 o r e q u i v a l e n t ( 5 ) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t ( 6 ) Opaque Polymer - "Ropaque" OP-62 o r e q u i v a l e n t ( 7 ) Mildewcide "Troysan Polyphase" AF-1 o r e q u i v a l e n t ( 8 ) N o n i o n i c S u r f a c t a n t - "Color-Sperse" 188-A or e q u i v a l e n t

-

-

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 42.4 S o l i d s , %: by Volume: 42.4 b y Weight: 51.7 V i s c o s i t y ( i n i t i a1 ) : S t o r m e r , KU: 85 I C I , poise: 0.9 pH ( i n i t i a l ) : 8 . 1 Weight p e r G a l l o n , l b . : 10.61 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass ( + 3 KU) Heat S t a b i l i t y , 2 weeks a t 120F: Pass ( + 2 KU) Film Properties: C o n t r a s t R a t i o , 3 m i l f i l m : 0.952 R e f l e c t a n c e , %: 91.6 Sheen, 85: 14.0 C o l o r Acceptance ( 1 ) : E x c e l l e n t ( 1 ) 4 f l .o z . / g a l l o n H u l s 888-1045F C o l o r a n t SOURCE: Ucar Emulsion Systems: UCAR L a t e x 367/UCAR L a t e x 378: F o r m u l a t i o n S u g g e s t i o n E-2211-A (Reduced T i 0 2 )

243

244

Water-Based Paint Formulations

Qual it y W h i t e House P a i n t I n s r e d ients : Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-3OM P r e s e r v a t ive ( 1 ) Dispersant ( 2 ) Potassium T r i p o l y p h o s p h a t e (KTPP) T r i t o n N o n i o n i c S u r f a c t a n t N-101 2-Amino-2-methyl-1-propanol (3) P r o p y l e n e G1 y c o l Antifoam (4) Titanium Dioxide (5) Z i n c Oxide ( 6 ) Mica ( 7 ) Talc (8) Letdown: Ucar L a t e x 379 Ucar F i l m e r IBT Mildewcide (9) Antifoam (4)

Pounds

Gal l o n s

252.1 4.0 2.3 10.5 2.0 2.2 1.o 34.5 1.9 225.0 25.0 25.0 175.0

30.27 0.36 0.25 1 .oo 0.10 0.25 0.13 4.00 0.25 6.54 0.54 1.07 7.37

408.3 17.8 2.2 1.9

45.12 2.25 0.25 0.25

Suppliers: ( 1 ) P r e s e r v a t ive - "Nuosept" 145 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 960 o r e q u i v a l e n t - AMP-95 o r e q u i v a l e n t ( 3 ) 2-Amino-2-methyl-1-propanol ( 4 ) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - " T i - P u r e " R-900 o r e q u i v a l e n t ( 6 ) Z i n c Oxide - "Pasco'' 311 o r e q u i v a l e n t ( 7 ) M i c a - M i c a 325WG or e q u i v a l e n t ( 8 ) T a l c - IT-325 o r e q u i v a l e n t ( 9 ) M i l d e w c i d e - Skane M-8 o r e q u i v a l e n t Comparative P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 40.1 S o l i d s , %: b y Volume: 39.3 by Weight: 57.7 Weight p e r G a l l o n , l b : 11.9 Paint Properties: Viscosity, i n i t i a l : Stormer, KU: 100 I C I , poise: 0.9 pH, i n i t i a l : 8 . 9 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Film Properties: C o n t r a s t R a t i o , 6 - m i l b a r : 0.966 Ref 1e c t a n c e , %: 9 0 . 5 Sheen, 85: 5 . 1

SOURCE:

Ucar Emulsion Systems: UCAR L a t e x 379: S u g g e s t i o n E-1 992

Formulation

Exterior Paints and Related

Q u a l i t y W h i t e House P a i n t Pounds I n a r e d ie n t s : Pigment G r i n d : 224.0 Water 3.5 C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e QP-15,000 9.1 D i spersant ( 1) 2.0 Nonionic Surfactant (2) 0.9 Antifoam (3) 1.o Potassium T r i p o l y p h o s p h a t e (KTPP 25.9 P r o p y l ene G1 y c o l 250.0 Titanium Dioxide (4) 150.0 Nepheline S y e n i t e (5) 50.0 Clay (6) L e t Down: Ucar A c r y l i c 525 Ucar F i l m e r I B T Antifoam (3) M i 1dewci de ( 7 ) Ammonium H y d r o x i d e ,

28% Aqueous S o l u t i o n

427.9 16.9 2.6 9.0 1.8

Gal l o n s 26.89 0.32 1 .oo 0.25 0.13 0.05 3.00 7.26 6.91 2.73 47.54 2.13 0.37 1.17 0.25

Suppl ie r s : ( 1 ) D i s p e r s a n t - "Byk" VP-155 o r e q u i v a l e n t . ( 2 ) N o n i o n i c S u r f a c t a n t - " T r i t o n " N-101 o r e q u i v a l e n t (3) Antifoam " C o l l o i d " 643 o r e q u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - "Zopaque" RCL-9 o r e q u i v a l e n t ( 5 ) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t (6) Clay - "Optiwhite" o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Super-Ad-It" o r equivalent

-

Pai n t P r o p e r t ies : Pigment Volume C o n c e n t r a t i o n , %: 42.0 T o t a l S o l i d s , %: by Volume: 40.2 by Weight: 58.0 Viscosity, i n i t i a l : S t o r m e r , KU: 95-100 I C I , poise: 1.7 pH, i n i t i a l : 9 . 1 Weight p e r G a l l o n , I b : 11.75 Freeze-Thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 wk a t 120F: Pass SOURCE: U n i o n C a r b i d e C o r p . : S u g g e s t i o n E-2076

UCAR A c r y l i c 525: F o r m u l a t i o n

245

246

Water-Based Point Formulations

Qual it y W h i t e House P a i n t Inqredients: Pigment G r i n d : Water Cel l o s i ze H y d r o x y e t h y C e l l u l o s e ER-3OM P r e s e r v a t ive ( 1 ) Propylene Glycol Dispersant (2) T r i t o n N o n i o n i c S u r f a t a n t N-101 Antifoam (3) Titanium Dioxide (4) C l a y (5) Nepheline Syenite (6) Letdown : Ucar L a t e x 624 Ucar F i l m e r I B T M i 1dewci de ( 7 ) Antifoam (3) Ammonium H y d r o x i d e ,

28% Aqueous S o l u t i o n

Pounds

Gallons

294.7 3.0 2.3 25.9 7.4 2.2 1.9 225.0 50.0 150.0

35.38 0.27 0.25 3.00 0.75 0.25 0.25 6.75 2.28 6.91

364.2 9.1 7.3 2.8 2.0

41.39 1.15 0.75 0.37 0.25

Suppl ie r s : (1) Preservative "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 653 o r e q u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - " T i - P u r e " R-902 o r e q u i v a l e n t ( 5 ) Clay - "Iceberg" o r equivalent ( 6 ) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r e q u i v a l e n t

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 45.0 Volume S o l i d s , %: 3 5 . 4 V i s c o s i t y , e q u i 1 ib r a t e d : S t o r m e r , KU: 92 I C I , poise: 1.2 Weight p e r G a l l o n , l b : 11.48 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Film Properties: C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0 . 9 5 6 Ref 1e c t a n c e , %: 9 0 . 6 Sheen, 85: 3.0 Flow and L e v e l i n g , b r u s h e d : Good Wet Adhesion : E x c e l 1e n t SOURCE: Ucar E m u l s i o n Systems: UCAR L a t e x 624: S u g g e s t i o n E-2413

Formulation

Exterior Paints and Related

Q u a l i t y W h i t e House P a i n t ( C o n v e n t i o n a l ) Inaredients: Pigment G r i n d : Water C e l l o s i z e H v d r o x-v e t h-v l C e l l u l o s e ER-30M D i spersant ) P o t a s s i um T r i p o l y p h o s p h a t e (KTPP) T r i t o n N o n i o n i c S u r f a c t a n t N-101 2-Ami no-2-methyl -1 - p r o p a n o l ( 2 ) P r o p y l ene G1y c o l Antifoam ( 3 ) Titanium Dioxide (4) Z i n c Oxide (5) Mica (6) Talc (7)

il

Letdown : Opaque Polymer ( 8 ) Ucar L a t e x 367 Ucar F i l m e r IBT Mildewcide ( 9 ) Antifoam (3)

Pounds

Gal 1ons

271.9 4.0 10.5 2.0 2.2 1.o 25.9 1.9 225.0 25.0 25.0 175.0

32.64 0.36 1 .oo 0.10 0.25 0.13

3.00 0.25 6.54 0.54 1.07 7.37

-----

----

408.3 8.9 2.2 1.9

45.12 1.13 0.25 0.25

S ~ D i De ~ rs: (1)' Dispersant "Tamol" 960 o r e q u i v a l e n t AMP-95 o r e q u i v a l e n t ( 2 ) 2-Amino-2-methyl-1-propanol (3) Antifoam " C o l l o i d " 640 o r e q u i v a l e n t " T i - P u r e " R-900 o r e q u i v a l e n t (4) Titanium Dioxide ( 5 ) Z i n c Oxide "Pasco" 311 o r e q u i v a l e n t ( 6 ) Mica "Mica" 325WG o r e q u i v a l e n t (7) Talc "IT-325" o r e q u i v a l e n t ( 8 ) Opaque Polymer "Ropaque" OP-62 o r e q u i v a l e n t ( 9 ) Mildewcide "Skane" ME o r e q u i v a l e n t

-

-

-

-

-

-

-

-

Pai n t P r o p e r t ies : Pigment Volume C o n c e n t r a t i o n (PVC), %: 40.1 S o l i d s , %: b y Volume: 3 8 . 7 by Weight: 5 7 . 7 Viscosity ( i n i t i a l ) : Stormer, KU: 85 I C I , poise: 0.8 pH ( i n i t i a l ) : 8 . 5 Weight p e r G a l l o n , l b . : 11.91 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass ( + 4 KU) Heat S t a b i l i t y , 2 weeks a t 120F: Pass ( + 3 KU) Film Properties: C o n t r a s t R a t i o , 3 m i l f i l m : 0.964 R e f l e c t a n c e , %: 91.9 Sheen 85: 5 . 9

SOURCE: Ucar Emulsion Systems: UCAR L a t e x 367/UCAR L a t e x 376: F o r m u l a t i o n S u g g e s t i o n E-2210 ( C o n v e n t i o n a l )

247

248

Water-Based Paint Formulations

Q u a l i t y W h i t e House P a i n t (Reduced T i 0 2 1 Ingredients:. P i gment G r i nd : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30M Dispersant ( 1) P o t a s s i um T r i p o l y p h o s p h a t e (KTPP) T r i t o n N o n i o n i c S u r f a c t a n t N-101 2-Amino-2-methyl-1-propanol (2) P r o p y l e n e G l y 01 Antifoam (3) T i t a n i um D i o x de ( 4 ) Z i n c Oxide ( 5 Mica ( 6 ) Talc ( 7 ) Letdown : Opaque Polymer ( 8 ) Ucar L a t e x 367 Ucar F i l m e r IBT Mildewcide (9) Antifoam ( 3 )

Pounds

Gal 1ons

234.2 4.2 10.5 2.0 2.2 1. o 25.9 1.9 175.0 25.0 25.0 100.0

28.12 0.39 1 .oo 0.10 0.25 0.13 3.00 0.25 5.09 0.54 1.07 4.21

101.9 382.4 9.9 2.2 1.9

11.85 42.25 1.25 0.25 0.25

Suppl ie r s : ( 1 ) D i s p e r s a n t - "Tamol" 960 o r e q u i v a l e n t ( 2 j 2-Ami no-2-methyl -1 - p r o p a n o l - -AMP-95 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - " T i - P u r e " R-900 o r e q u i v a l e n t ( 5 ) Z i n c Oxide - "Pasco" 311 o r e q u i v a l e n t ( 6 ) M i c a - "Mica" 325WG o r e q u i v a l e n t ( 7 ) T a l c - IT-325 o r e q u i v a l e n t ( 8 ) Opaque Polymer - "Ropaque" OP-62 o r e q u i v a l e n t ( 9 ) M i l d e w c i d e - "likane" M8 o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 44.0 S o l i d s , %: b y Volume: 38.8 b y Weight: 53.0 Viscosity ( i n i t i a l ) : Stormer, KU: 83 I C I . p o i s e : 0.8 pH ( i n i t i a l ) : 8 . 7 Weight p e r G a l l o n , l b : 11.05 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass ( + 4 KU) Heat S t a b i l i t y , 2 weeks a t 120F: Pass ( + 4 KU) Film Properties: C o n t r a s t R a t i o , 3 m i l f i l m : 0.962 R e f l e c t a n c e , %I 92.6 Sheen, 85: 16.2 Reduced T i 0 2 f o r m u l a t i o n n o t " f i n e - t u n e d " f o r o p t i c a l p r o p e r t i e s

SOURCE:

Ucar Emulsion Systems: UCAR L a t e x 367/UCAR L a t e x 376: F o r m u l a t i o n S u g g e s t i o n E-2210-A (Reduced T i 0 2 1

Exterior Paints and Related

249

Tint-Base T r i m P a i n t I n q r e d ie n t s : P i gment G r i nd : Water Cel l o s i ze H y d r o x y e t h y l C e l l u l o s e ER-4400 P r o p y l e n e G1y c o l 2-Amino-2-methyl-1-propanol (1) Dispersant (2) Antifoam (3) Preservative (4) T r i t o n N o n i o n i c S u r f a c t a n t N-101 Titanium Dioxide (5) Nephel i n e S y e n i t e ( 6 ) Letdown : Ucar L a t e x 624 Ucar F i l m e r IBT Antifoam (3) Mildewcide (7) T r i t o n N o n i o n i c S u r f a c t a n t CA T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammoni um H y d r o x i de, 28% Aqueous Sol u t i on

Pounds

Gal 1ons

219.2 3.0 60.5 2.0 6.1 1.9 2.3 2.2 150.0 50.0

26.31 0.27 7.00 0.25 0.62 0.25 0.25 0.25 4.30 2.20

486.2 12.2 1.9 7.3 2.1 1.1 0.9

55.25 1.54 0.25 0.75 0.25 0.13 0.13

Suppl ie r s : ( 1 ) . 2-Ami no-2-methyl-1 - p r o p a n o l - AMP-95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - Tamol 1124 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 653 o r e q u i v a l e n t ( 4 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t (5) Titanium Dioxide " T i o n a " RCL-535 o r e q u i v a l e n t ( 6 ) N e p h e l i n e S y e n i t e - "Minex" 10 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r e q u i v a l e n t

-

P a i n t P r o p e r t i 8s: P i qment Volume C o n c e n t r a t i o n , %: 20.0 Vol ume Sol ids, %: 32.5 V i s c o s i t y , equ 1 ib r a t e d : Stormer, KU 92 I C I , p o i s e : 1.05 Weight p e r Gal on, l b : 10.09 Freeze-thaw S t b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m P r o p e r t i es : C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.942 R e f l e c t a n c e , %: 8 9 . 5 G l o s s , 60: 45 G l o s s , 20: 10 Flow and L e v e l i n g , b r u s h e d : Good Wet Adhesion : Excel 1e n t C o l o r Acceptance: H u l s 328-3T Nuance System: E x c e l l e n t H u l s 73C-2T Nuance System: E x c e l l e n t

SOURCE: Ucar Emulsion Systems: UCAR L a t e x 624: F o r m u l a t i o n E-2419

250

Water -Based Paint Formulations

TT-P-19D

A c r y l i c House P a i n t

Innredients: Pounds Gal 1ons Pigment G r i nd: Water 203.7 24.45 C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-3OM 3.5 0.32 P r e s e r v a t i v e (1 ) 2.3 0.25 Dispersant ( 2 ) 12.8 1.25 T r i t o n N o n i o n i c S u r f a c t a n t N-101 2.2 0.25 0.25 Antifoam ( 3 ) 1.9 P o t a s s i um T r i p o l yphosphate (KTPP) 0.05 1.o P r o p y l e n e G1 y c o l 25.9 3.00 Titanium Dioxide (4) 260.0 7.59 8.86 C a l c i u m Carbonate ( 5 ) 200.0 Letdown : Ucar L a t e x 624 448.4 50.95 Ucar F i 1 mer I 8T 11.2 1 .41 0.37 Antifoam (3) 2.8 M i 1dewci de ( 6 ) 7.3 0.75 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 2.0 0.25 Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - " C o l l o i d " 226/35 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 653 o r e a u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - " T i - P u r e " R-902 o r e q u i v a l e n t ( 5 ) C a l c i u m Carbonate - "Snowflake" o r e q u i v a l e n t ( 6 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r e q u i v a l e n t Specifications: TT-P-19D E-2423 R e s u l t s 50 (minimum) 58.8 T o t a l NV, % b y w e i g h t 40 (minimum) 40.4 T o t a l NV, % by volume N o n v o l a t i l e Organic Content 19.2 ( % by w e i g h t ) 19 (minimum) Stormer V i s c o s i t y , KU 96 80-100 Fineness o f D i s p e r s i o n 4 4 (minimum) Reflectance, % 91.4 90 (minimum) 5.8 Gloss, 60 20 (maximum) D r y i n g Time, s e t t o t o u c h , minutes 10 10 (minimum) t2 D r y i n g Through, h o u r s 2 (maximum) VOC, grams p e r l i t e r 96 250 (maxi mum) C o n t r a s t R a t i o , 6 - m i l wet drawdown 0 . 9 5 (minimum) 0.96 Lead, % by w e i g h t 0 . 0 6 (maxi mum) 0 30 days a t 125F Pass Accelerated Storage 3 c y c l e s , no c o a g u l a t i o n , Pass Freeze-thaw S t a b i l i t y KU change 8 max -3 No c r a c k i n g o r f l a k i n g Pass F l e x i b i 1 it y A1 k a l i R e s i s t a n c e No b l i s t e r i n g o r remul s i f i c a t i o n Pass U n i f o r m c o l o r and g l o s s Pass Compati b i 1 it y 8+ s u r f a c e d i s f igurement 10 B i o l o g i c a l Growth No c h a l k i n g : t r a c e c h a l k i n g Accelerated Weathering L i g h t n e s s d i f f e r e n c e i n d e x 1 . 5 : -1.32

SOURCE: Ucar Emulsion Systems: UCAR L a t e x 624: F o r m u l a t i o n E-2423

Exterior Paints and Related

White Trim P a i n t (Conventionall Ingredients: Pigment G r i n d : Water Cel l o s i ze H y d r o x y e t h y l C e l l u l o s e ER-4400 Preservative (1) P r o p y l e n e G1y c o l Dispersant (2) 2-Amino-2-methyl-1-propanol (3) T r i t o n N o n i o n i c S u r f a c t a n t N-57 Antifoam (4) Titanium Dioxide (5) Letdown : Ucar Polyphobe T h i c k e n e r 102 Ucar L a t e x 624 Opaque Polymer ( 6 ) Ucar F i l m e r IBT Antifoam (4) Mildewcide ( 7 ) T r i t o n A n i o n i c S u r f a c t a n t GR-7M

Pounds

Gallons

241.2 1.o 2.3 60.5 7.4 2.0 2.1 1.9 250.0

28.96 0.09 0.25 7.00 0.75 0.25 0.25 0.25 7.16

13.1 447.7

1.50 50.88

11.2 2.8 7.3 1.1

1.41 0.37 0.75 0.13

-----

-----

Suppliers: ( 1 ) . P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 3 ) 2-Amino-2-methyl-1-propanol - AMP-95 o r e q u i v a l e n t ( 4 ) A n t i f o a m - " C o l l o i d " 653 o r e q u i v a l e n t (5) T i t a n i u m D i o x i d e - " T i o n a " RCL-535 o r e q u i v a l e n t ( 6 ) Opaque Polymer - "Ropaque" OP-62 o r e q u i v a l e n t ( 7 ) M i l d e w c i d e - "Troysan" Polyphase AF-1 o r e q u i v a l e n t Pai n t P r o p e r t ies : Pigment Volume C o n c e n t r a t i o n , %: 23.0 Volume S o l i d s , %: 31.1 V i s c o s i t y , e q u i 1 ib r a t e d : Stormer, KU: 100 I C I , p o i s e : 0.95 Weight p e r G a l l o n , l b : 10.52 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Fi m Properties: C o n t r a s t R a t i o , 6 - m i l wet drawdown: Ref 1e c t a n c e , %: 9 0 . 6 Gloss, 60: 65 G l o s s , 20: 20 Flow and L e v e l i n g , brushed: Good Wet Adhesi on : Excel 1e n t

SOURCE:

0.957

Ucar Emulsion Systems: UCAR L a t e x 624: F o r m u l a t i o n S u g g e s t i o n E-2416A ( C o n v e n t i o n a l )

251

252

Water-Based Paint Formulations

W h i t e T r i m P a i n t (Opaque-Polymer M o d i f i e d 1 I n n r e d ie n t s : Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-4400 Preservative (1) Propylene G l y c o l D i spersant (2) 2-Amino-2-methyl-1-propanol (3) T r i t o n N o n i o n i c S u r f a c t a n t N-57 Antifoam ( 4 ) T i t a n i um D i o x i d e ( 5 ) Letdown : Ucar Polyphobe T h i c k e n e r 102 Ucar L a t e x 624 Opaque Polymer ( 6 ) Ucar F i l m e r I 6 T Antifoam ( 4 ) M i 1dewci de ( 7 ) T r i t o n A n i o n i c S u r f a c t a n t GR-7M

Pounds

Gal 1ons

239.6 2.3 60.5 6.9 2.0 2.1 1.9 231.7

28.76 0.09 0.25 7.00 0.70 0.25 0.25 0.25 6.64

13.1 420.4 25.6 11.2 2.8 7.3 1.1

1.50 40.67 2.98 1 .41 0.37 0.75 0.13

1 .o

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 1124 o r e q u i v a l e n t ( 3 ) 2-Amino-2-methyl-1-propanol - AMP-95 o r e q u i v a l e n t ( 4 ) A n t i f o a m - " C o l l o i d " 653 o r e q u i v a l e n t " T i o n a " RCL-535 o r e q u i v a l e n t (5) Titanium Dioxide ( 6 ) Opaque Polymer - "Ropaque" OP-62 o r e q u i v a l e n t (7) Mildewcide "Troysan" Polyphase AF-1 o r e q u i v a l e n t

-

-

Paint Properties: Pigment Volume C o n c e n t r a t i o n , %: 2 6 . 4 Volume S o l i d s , %: 31.1 V i s c o s i t y , e q u i 1ib r a t e d : Stormer, KU: 100 I C I , p o i s e : 0.95 Weight p e r G a l l o n , l b : 1 0 . 3 6 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Film Properties: C o n t r a s t R a t i o , 6 - m i l wet drawdown: Ref 1e c t a n c e , %: 9 0 . 6 Gloss, 60: 50 Gloss, 20: 11 Flow and L e v e l i n g , b r u s h e d : Good Wet Adhesion: Very Good

0.956

SOURCE: Ucar Emulsion Systems: UCAR L a t e x 624: F o r m u l a t i o n S u g g e s t i o n E-24188 (Opaque-Polymer M o d i f i e d )

254

Water-Based Paint Formulations

Architectural Interior Flat Lbs/100 G a l . 591.4 6.9

Water C e l l o s i z e QP-15,000 Add C e l l o s i z e under a g i t a t i o n ;

mix 5 m i n u t e s 1.o

KTPP Add and m i x 2 m i n u t e s T r i t o n N101 Tamol 731 DrewPl us L475 E t h y l e n e G1y c o l

5.2 5.0 0.3 23.4

Add and mix 2 m i n u t e s Ti02 Snow*Tex 45 Min-U-Si1 40 Add s l o w l y ;

130.7 112.7 56.4

d i s p e r s e t o a 4+ Hegman

W a l l p o l 40-1 36 E x x a t e 1300 DrewPl u s L475 D o w i c i l 75

104.5

8.3 0.7 1.4

Add s l o w l y under a g i t a t i o n , m i x 1 0 m i n u t e s V i s c o s i t y : 90 KU a t 25C Wt/gal: 10.48 l b s . N.V.W.: 35.6% N.V.V.: 19.2% PVC: 0.612 Pigment : 28.6% Contrast Ratio: 0.95 R e f l e c t a n c e ( H u n t e r Green): 90.5 Gloss 60: 1 . 9 G l o s s 2 0 : 1.3

SOURCE: U.S. S i l i c a Co.:

Formula AC-106

Interior Paints and Related

255

Best Q u a l i t v F l a t Wall P a i n t Inaredients: Pounds Gal 1ons Pigment G r i nd: Water 348.2 41.80 C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-3OM 4.5 0.41 Preservative (1) 2.3 0.25 Dispersant (2) 5.7 0.62 Potassium T r i p o l y p h o s p h a t e (KTPP) 1 .o 0.05 T r i t o n N o n i o n i c S u r f a c t a n t N-101 2.2 0.25 2-Amino-2-methyl-1-propanol (3) 1. o 0.13 P r o p y l ene G1y c o l 21.6 2.50 Antifoam (4) 1.9 0.25 175.0 5.47 T i t a n i u m D i o x i d e (5) 175.0 7.99 Clay (6) 100.0 4.43 Cal c i um Carbonate ( 7 ) 75.0 3.40 Nephel ine S y e n i t e ( 8 ) Letdown : Ucar L a t e x 376 282.7 31.20 B u t y l C a r b i t o l Solvent 7.9 1 .oo Antifoam (4) 1.9 0.25 Suppl ie r s : (1) Preservative "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t ( 3 ) 2-Amino-2-methyl-1-propanol AMP-95 o r e q u i v a l e n t ( 4 ) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-813 o r e q u i v a l e n t ( 6 ) Clay - "Satintone" W o r equivalent ( 7 ) C a l c i u m Carbonate - "#I White" o r e q u i v a l e n t ( 8 ) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 5 7 . 0 S o l i d s , %: b y Volume: 37.4 b y Weight: 5 7 . 2 V i s c o s i t y ( i n i t i a l ) : Stormer, KU: 90 I C I , poise: 1.4 pH ( i n i t i a l ) : 8.2 Weight p e r G a l l o n , l b . : 12.06 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass ( + 8 KU) Heat S t a b i l i t y , 2 weeks a t 120F: Pass ( + 5 KU) F i l m Properties: C o n t r a s t R a t i o , 3 m i l f i l m : 0.980 Ref 1e c t a n c e , %: 9 3 . 6 Sheen, 85: 4 . 2 ASTM Scrub C y c l e s , w i t h shim: I n i t i a l Break: 335 F a i l u r e , 100%: 1100 P o r o s i t y , ASTM D-3258: 23.8 C o l o r ( 1 ) : ( 1 ) T i n t e d 1% by w e i g h t w i t h H u l s 888-7214E C o l o r Acceptance: E x c e l l e n t R . T . Drawdown, R.T. Touchup ( 2 ) : E x c e l l e n t R.T. Drawdown, C.T. Touchup ( 2 ) : Very Good ( 2 ) R.T.=72F/50% r e l a t i v e h u m i d i t y C.T.=40F/50% r e l a t i v e hum. SOURCE: UCAR Emulsion Systems: UCAR L a t e x 367/UCAR L a t e x 376: F o r m u l a t i o n S u g g e s t i o n 1-2215

-

-

256

Water-Based Paint Formulations

B e t t e r Q u a l i t y F l a t Wall P a i n t

I ngredi ents : Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-15M P r e s e r v a t iv e ( 1 ) Dispersant (2) Potassium T r i p o l y p h o s p h a t e (KTPP) T r i t o n N o n i o n i c S u r f a c t a n t N-101 2-Amino-2-methyl-I-propanol (3) P r o p y l e n e G1y c o l Antifoam (4) Titanium Dioxide ( 5 ) Clay (6) C a l c i u m Carbonate ( 7 ) Letdown : Ucar L a t e x 367 Ucar F i l m e r I 8 T Antifoam (4)

Pounds

Gallons

419.4 5.5 2.3 4.6

17.3 1.9 150.0 125.0 200.0

50.35 0.50 0.25 0.50 0.05 0.25 0.13 2.00 0.25 4.80 5.81 8.86

226.3 7.9 1.9

25.00 1 .oo 0.25

1.o

2.2

1.o

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t - AMP-95 o r e q u i v a l e n t ( 3 ) 2-Amino-2-methyl-1-propanol ( 4 ) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t (5) T i t a n i u m D i o x i d e - " T i - P u r e " R-931 o r e q u i v a l e n t (6) Clay - "Satintone" W o r equivalent ( 7 ) C a l c i u m Carbonate - "#I W h i t e " o r e q u i v a l e n t Pai n t P r o p e r t ies : Pigment Volume C o n c e n t r a t i o n (PVC), %: 60.2 S o l i d s , %: b y Volume: 3 2 . 3 by Weight: 52.3 V i s c o s i t y ( i n i t i a1 ) : S t o r m e r , KU: 95 I C I , poise: 1.1 pH ( i n i t i a l ) : 8.0 Weight p e r G a l l o n , l b . : 1 1 . 6 6 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass ( t 6 KU) Heat S t a b i l i t y , 2 weeks a t 120F: Pass ( t 4 KU) F i 1m P r o p e r t ies : C o n t r a s t R a t i o , 3 m i l f i l m : 0.969 Reflectance, %: 92.3 Sheen, 8 5 : 1 . 9 ASTM Scrub C y c l e s , w i t h shim: I n i t i a l Break: 190 F a i l u r e , 100%: 575 P o r o s i t y , ASTM D-3258: 22.9

SOURCE: Ucar E m u l s i o n Systems: UCAR L a t e x 367/UCAR F o r m u l a t i o n Suggestion 1 - 2 2 1 6

L a t e x 376:

Interior Paints and Related

257

D r i D f r e e A c r y l i c Latex P a i n t Pigment d i s p e r s i o n , Cowles D i s s o l v e r Pounds

Gal l o n s

Vancide TH Ethylene g l y c o l Darvan No. 7 A n t i foamer Ammoni um h y d r o x i de 28% Titanium dioxide N y t a l 300

200 1 25 10 4 2 200 225

23.9 0.1 3.0 1 .o 0.4 0.2 5.8 9.5

Reduction: Rhoplex AC-33 o r e q u i v a l e n t 4% Veegum T w a t e r g e l W e t t i n g agent

327 136 20

37.7 16.0 2.4

1.5% Sodium CMC* w a t e r

*

H e r c u l e s 7H3SF o r e q u i v a l e n t

C o n s i s t e n c y , one day KU: 94 C o n s i s t e n c y , immediate KU: 90 C o n s i s t e n c y , one week KU: 94 C o n s i s t e n c y , one month KU: 95 Pigment volume c o n c e n t r a t i o n : 49 P e r c e n t s o l i d s by w e i g h t : 51 Formula No. 1246 D r i p f r e e A c r y l i c Latex P a i n t Pigment d i s p e r s i o n , Cowles D i s s o l v e r Pounds

Gallons

23.9

Vancide TH Ethylene g l y c o l Darvan N o . 7 A n t i foamer Ammonium h y d r o x i d e 28% Titanium dioxide N y t a l 300

200 1 25 10 4 2 200 225

Reduct ion : Rhoplex AC-33 o r e q u i v a l e n t 4% Veegum T w a t e r g e l W e t t i n g agent

260 202 20

30.0 23.7 2.4

1.5% Sodium CMC* w a t e r g e l

*

0.1

3.0 1 .o 0.4 0.2 5.8 9.5

H e r c u l e s 7H3SF o r e q u i v a l e n t

C o n s i s t e n c y , one day KU: 96 C o n s i s t e n c y , immediate KU: 93 C o n s i s t e n c y , one week KU: 96 C o n s i s t e n c y , one month KU: 96 Pigment volume c o n c e n t r a t i o n : 55 P e r c e n t s o l i d s by w e i g h t : 49 Formula No. 1247

SOURCE: R . T .

V a n d e r b i l t Co.,

Inc.:

VEEGUM T i n L a t e x P a i n t s

258

Water -Based Paint Formulations

Economy F l a t W a l l P a i n t Inaredients: Pigment G r i n d : Water Cel l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-3OM P r e s e r v a t iv e ( 1 ) Dispersant (2) P o t a s s i u m T r i p o l y p h o s p h a t e (KTPP) T r i t o n N o n i o n i c S u r f a c t a n t N-101 2-Amino-2-methyl-1-propanol (3) Propylene Glycol Antifoam (4) Titanium Dioxide (5) Clay (6) Calcium Carbonate (7) S i l i c a (8) Letdown : Ucar L a t e x 376 Butyl C a r b i t o l Solvent Antifoam (4)

Pounds

Gal l o n s

496.0 5.5 2.3 4.6 1.o 2.2 1.o 13.0 1. o 75.0 200.0 150.0 25.0

59.54 0.50 0.25 0.50 0.05 0.25 0.13 1.50 0.13 2.34 9.30 6.65 1.30

147.8 7.9 1.9

16.31 1.oo 0.25

Suppliers: ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t ( 3 ) 2-Amino-2-methyl-1-propanol - AMP-95 o r e q u i v a l e n t ( 4 ) A n t i f o a m - "PA-454" o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-813 or e q u i v a l e n t ( 6 ) C l a y - "ASP-NC2" o r e q u i v a l e n t ( 7 ) Calcium Carbonate - " # l White" o r e q u i v a l e n t ( 8 ) S i l i c a - " C e l i t e " 281 o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n (PVC), %: 70.0 S o l i d s , %: b y Volume: 28.0 b y Weight: 47.7 Viscosity ( i n i t i a l ) : S t o r m e r , KU: 95 I C I , poise: 0.6 pH ( i n i t i a l ) : 8 . 5 Weight p e r G a l l o n , l b . : 1 1 . 3 4 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass ( + 3 KU) Heat S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m P r o p e r t i es : C o n t r a s t R a t i o , 3 m i l f i l m : 0.974 R e f l e c t a n c e , %: 9 1 . 5 Sheen, 85: 2 . 4 ASTM S c r u b C y c l e s , w i t h shim: I n i t i a l Break: 25 F a i l u r e , 700%: 40 P o r o s i t y , ASTM D-3258: 27.3 SOURCE: Ucar E m u l s i o n Systems: UCAR L a t e x 367/UCAR L a t e x 376: F o r m u l a t i o n S u g g e s t i o n 1-2218

Interior Paints and Related

259

Economy F l a t W a l l P a i n t I n g r ed ient s : P i gment G r i nd : Water Cel l o s i ze H y d r o x y e t h y l C e l l u l o s e ER-3OM Preservative (1) Dispersant (2) T r i t o n N o n i o n i c S u r f a c t a n t N-101 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40 2-Amino-2-methyl-1-propanol (3) Propylene Glycol Antifoam (4) Titanium Dioxide (5) Clay (6) Calcium Carbonate ( 7 ) S i l i c a (8) Letdown : Ucar L a t e x 379 Butyl C a r b i t o l Solvent Antifoam (4) P r o p y l e n e G1y c o l

Pounds

Gallons

484.6 5.5 2.3 4.6 2.2 2.2 1. o 13.0 1.o 75.0 200.0 150.0 25.0

58.18 0.50 0.25 0.50 0.25 0.25 0.13 1.50 0.13 2.34 9.30 6.65 1.30

147.8 7.9 1.9 10.0

16.31 1.oo

0.25 1.16

Suppl ie r s : (1) Preservative "Nuosept" 145 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t ( 3 ) 2-Amino-2-methyl-1-propanol - AMP-95 o r e q u i v a l e n t ( 4 ) A n t i f o a m - "PA-454" o r e q u i v a l e n t (5) Titanium Dioxide "Tronox" CR-813 o r e q u i v a l e n t ( 6 ) C l a y - ASP-NC2 o r e q u i v a l e n t ( 7 ) C a l c i u m Carbonate - "#1 W h i t e " o r e q u i v a l e n t ( 8 ) S i l i c a - " C e l i t e " 281 o r e q u i v a l e n t

-

-

Comparat iv e P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 70.0 S o l i d s , %: b y Volume: 2 8 . 5 b y Weight: 47.4 Weight p e r G a l l o n , l b : 11.34 Paint Properties: Viscosity, i n i t i a l : S t o r m e r , KU: 89 I C I , poise: 0.6 pH, i n i t i a l : 8 . 7 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Film Properties: C o n t r a s t R a t i o , 6 - m i l b a r : 0.966 R e f l e c t a n c e , %: 8 9 . 5 Sheen, 85: 2.1 ASTM S c r u b C y c l e s , w i t h shim: I n i t i a l Break: 153 F a i l u r e , 10%: 189 SOURCE: Ucar E m u l s i o n Systems: UCAR L a t e x 379: F o r m u l a t i o n 1-1988

260

Water-Based Paint Formulations

F l a t I n t e r i o r Latex P a i n t Pounds

Gal 1ons

Dispersion: Water Van Gel B H y d r o x y e t h y l C e l l u l ose ( 1 ) Vancide TH Darvan No. 7 Surfactant (3) Ethylene G l ycol Coalescent ( 4 ) Defoamer ( 5 ) Titanium Dioxide (6) N y t a l 300

250 3 5 1 15 2 25 12 1 150 310

30.0 0.2 0.3 0.1 1.5 0.2 2.7 1.5 0.1 4.7 13.1

Reduct ion : Water Defoamer V i n y l - a c r y l ic L a t e x ( 7 )

185 1 21 0

22.2 0.1 23.3

Pigment Volume C o n c e n t r a t i o n , %: 60 S o l i d s by Weight, %: 50 C o n s i s t e n c y , KU: 07 B r o o k f i e l d V i s c o s i t y , Poises: A t 10 RPM: 68 A t 100 RPM: 15 T h i x o t r o p i c I n d e x : 4.5 Raw m a t e r i a l s o r e q u i v a l e n t s : 1 ) Cel l o s i ze QP-4400 3 ) T r i t o n CF-10 4 ) Texanol 5 ) Nopco NDW 6 ) T i - P u r e R-931 7) E v e r f l e x E

SOURCE: R.T.

V a n d e r b i l t Co.,

I n c . : Van G e l 9: Formula No. F-103

Interior Paints and Related

F l a t I n t e r i o r Latex P a i n t Pounds D i s p e r s i on : Water Van Gel B H y d r o x y e t h y l C e l l u l o s e (2) Vancide TH Darvan No. 7 S u r f a c t a n t (3) E t h y l e n e G1 y c o l Coalescent (4) Defoamer ( 5 ) Titanium Dioxide (6) N y t a l 300

350 4.5 4.5 1 15 L

25 12 1 150 31 0

Reduction: Water Defoamer V i n y l - a c r y l i c Latex ( 7 )

85 1 210

Pigment Volume C o n c e n t r a t i o n , %: S o l i d s b y Weight, %: 50 C o n s i s t e n c y , KU: 94 B r o o k f i e l d V i s c o s i t y , Poises: A t 10 RPM: 102 A t 100 RPM: 20 T h i x o t r o p i c I n d e x : 5.1

Gallons

42.0 0.2 0.3 0.1 1.5 0.2 2.7 1.5 0.1 4.7 13.1 10.2 0.1 23.3

60

(2) (3) (4) (5)

C e l l o s i z e QP-15,000 T r i t o n CF-10 Texanol Nopco NDW (6) T i - P u r e R-931

SOURCE: R.T.

V a n d e r b i l t Co.,

Inc.:

VAN GEL

B: Formula No. F-104

261

262

Water-Based Paint Formulations

F l a t I n t e r i o r Latex P a i n t Dispersion: Water Van Gel B Hydroxyethyl Cellulose (1) Vancide TH Darvan No. 7 Surfactant (3) Ethylene Glycol Coalescent ( 4 ) Defoamer (5) Titanium Dioxide (6) N y t a l 300

Pounds

Gallons

250 3

30.0 0.2 0.3

5 1 15 2

25 12

Reduct ion : Water Defoamer A c r y l i c Latex ( 8 )

1.5 0.2 2.7

1

1.5 0.1

150 310

13.1

170 1

20.4 0.1 25.1

221

Pigment Volume C o n c e n t r a t i o n , %: S o l i d s b y Weight, %: 50 C o n s i s t e n c y , KU: 78 B r o o k f i e l d V i s c o s i t y , Poises: A t 10 RPM: 64 A t 100 RPM: 1 1 T h i x o t r o p i c Index: 5.8

0.1

4.7

60

Raw M a t e r i a l s o r e q u i v a l e n t s : 1 ) Cel l o s i ze QP-4400 3 ) T r i t o n CF-10 4 ) Texanol 5) Nopco NDW 6 ) T i P u r e R-931 8 ) Rhoplex AC-388

SOURCE:

R.T.

V a n d e r b i l t Co.,

Inc.:

VAN GEL 8 : Formula No, F-105

Interior Paints and Related

263

F l a t I n t e r i o r Latex P a i n t Pounds

Gal 1ons

Dispersion: Water Van Gel B Hydroxyethyl Cellulose (2) Vancide TH Darvan No. 7 Surfactant (3) E t h y l e n e G1y c o l Coalescent (4) Defoamer ( 5 ) Titanium Dioxide (6) N y t a l 300

350 4.5 4.5 1 15 2 25 12 1 150 31 0

42.0 0.2 0.3 0.1 1.5 0.2 2.7 1.5 0.1 4.7 13.1

Reduct ion : Water Defoamer A c r y l i c Latex (8)

70 1 221

8.4 0.1 25.1

Pigment Volume C o n c e n t r a t i o n , %: S o l i d s b y Weight, %: 50 C o n s i s t e n c y , KU: 85 B r o o k f i e l d V i s c o s i t y , Poises: A t 10 RPM: 124 A t 100 RPM: 16 T h i x o t r o p i c Index: 7.8

60

Raw M a t e r i a l s o r E q u i v a l e n t s : 2 ) C e l l o s i z e QP-15,000 3 ) T r i t o n CF-10 4 ) Texanol 5 ) Nopco NDW 6 ) T i - P u r e R-931 8 ) Rhoplex AC-388

SOURCE: R.T. V a n d e r b i l t Co.,

Inc.:

VAN GEL 8 : Formula NO. F-108

264

Water -Based Paint Formulations

Flat Interior Vinyl-Acrylic D i s p e r s i on : Water Van -Ge 1 Hydroxyethyl c e l l u l o s e ( 1 ) Vancide TH Darvan No. 7 Ethylene g l y c o l Coalescent ( 2 ) Defoamer (3) T i t a n i um d i o x i d e (4) N y t a l 300

Latex Paint Pounds

350 4.5 4.5 1 15 25

Reduction: Water S u r f a c t a n t - 5% s o l u t i o n (5) Vinyl-acrylic latex (6)

Gal l o n s

42.0 .2 .3 .1 1.5 2.7

12

1.5

2 150 31 0

.2 4.7

67

20 210

13.1 8.0 2.4 23.3

( 1 ) QP15,000 o r e q u i v a l e n t Texanol o r e q u i v a l e n t Nopco NDW o r e q u i v a l e n t R-931 o r e q u i v a l e n t A e r o s o l OT-8 o r e q u i v a l e n t (6) Everflex E o r equivalent

(2) (3) (4) (5)

Paint Properties: C o n s i s t e n c y , KU: 98 Pigment volume c o n c e n t r a t i o n , %: S o l i d s by w e i g h t , %: 50

60

T h i s f o r m u l a t i o n e x h i b i t s g r e a t e r body and b r u s h p i c k - u p w h i l e m a i n t a i n i n g t h e smooth and even f l o w o f Development F o r m u l a t i o n No. F-101. Paint Preparation: VAN-GEL i s added t o i n i t i a l w a t e r charge a t s l o w a g i t a t i o n and t h e n d i s p e r s e d a t h i g h speed u n t i l a 7 Hegman i s o b t a i n e d (5-10 m i n u t e s ) . H y d r o x y e t h y l c e l l u l o s e and o t h e r i n g r e d i e n t s f o r pigment d i s p e r s i o n a r e t h e n added i n t h e u s u a l manner. A f t e r d i s p e r s i o n s t e p , t h e p a i n t i s reduced a t s l o w a g i t a t i o n w i t h remaining ingredients. SOURCE: R . T .

F-102

V a n d e r b i l t G o . , I n c . : Development F o r m u l a t i o n No.

Interior Paints and Related

Flat Interior Vinyl-Acrylic D i s D e r s i on : Water Van gel Hydroxyethyl c e l l u l o s e ( 1 ) Vancide TH Darvan No. 7 Ethylene g l y c o l Coalescent (2) Defoamer ( 3 ) T i t a n i um d i o x i d e ( 4 ) N y t a l 300

Latex P a i n t Pounds

Gal l o n s

250 5 1 15 25 12 2 150 31 0

30.0 0.2 0.3 0.1 1.5 2.7 1.5 0.2 4.7 13.1

167 20 210

20.0 2.4 23.3

3

Reduct ion : Water S u r f a c t a n t - 5% s o l u t i o n ( 5 ) V i n y l - a c r y l i c l a t e x (6)

265

( 1 ) QP4400 o r e q u i v a l e n t ( 2 ) Texanol o r e q u i v a l e n t ( 3 ) Nopco NDW o r e q u i v a l e n t ( 4 ) R-931 o r e q u i v a l e n t (5) A e r o s o l OT-B o r e q u i v a l e n t (6) E v e r f l e x E o r e q u i v a l e n t Paint Properties: C o n s i s t e n c y , KU: 87 Pigment volume c o n c e n t r a t i o n , %: S o l i d s by w e i g h t , %: 50

60

This formulation i s the f i r s t i n a series intended t o provide a range o f t h i x o t r o p i c p r o p e r t i e s f o r t h e p a i n t f o r m u l a t o r . Paint Preparation: VAN GEL i s added t o i n i t i a l w a t e r charge a t s l o w a g i t a t i o n and t h e n d i s p e r s e d a t h i g h speed u n t i l a 7 Hegman i s o b t a i n e d (5 10 m i n u t e s ) . H y d r o x y e t h y l c e l l u l o s e and o t h e r i n g r e d i e n t s f o r pigment d i s p e r s i o n a r e t h e n added i n t h e u s u a l manner. A f t e r d i s p e r s i o n s t e p , t h e p a i n t i s reduced a t s l o w a g i t a t i o n w i t h remaining i n g r e d i e n t s .

-

SOURCE:

R . T . V a n d e r b i l t Co., NO. F-101

Inc.:

Developmental F o r m u l a t i o n

266

Water-Based Paint Formulations

Good O u a l i t v F l a t W a l l P a i n t Ingredients: Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l o s i z e €it-30M P r e s e r v a t ive ( 1 ) Dispersant (2) P o t a s s i um T r i p o l y p h o s p h a t e (KTPP) T r i t o n N o n i o n i c S u r f a c t a n t N-101 P r o p y l e n e G1 y c o l Antifoam ( 3 ) Titanium Dioxide (4) Clay ( 5 ) C a l c i um Carbonate ( 6 ) Letdown : Ucar L a t e x 367 Ucar F i l m e r I 8 T Antifoam (3) Ammonium H y d r o x i d e 28% Aqueous S o l u t i o n

Pounds

Gallons

427.7 5.0 2.3 5.7 1.o 2.2 17.3 1.9 125.0 175.0 175.0

51.35 0.45 0.25 0.62 0.05 0.25 2.00 0.25 3.91 9.55 7.75

201 . o 7.9 1.9 1.o

22.19 1 .oo 0.25 0.13

Suppl ie r s : ( 1 ) P r e s e r v a t i v e - "Nuosept" 95 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t ( 3 ) A n t i f o a m - " C o l l o i d " 643 o r e q u i v a l e n t ( 4 ) T i t a n i u m D i o x i d e - "Tronox" CR-813 o r e q u i v a l e n t ( 5 ) Clay - " O p t i w h i t e " o r e q u i v a l e n t ( 6 ) C a l c i u m Carbonate - "#1 W h i t e " o r e q u i v a l e n t Pai n t P r o p e r t i 8s: Pigment Volume C o n c e n t r a t i o n (PVC), %: 65.0 S o l i d s , %: by Volume: 32.6 by Weight: 51.8 Viscosity ( i n i t i a l ) : Stormer, KU: 92 I C I , p o i s e : 1.2 pH ( i n i t i a l ) : 8 . 0 Weight Der G a l l o n . l b : 1.5 Freeze-Thaw S t a b i i i t y , 3 c y c l e s : Pass ( + 8 KU) Heat S t a b i l i t y , 2 weeks a t 120F: Pass ( + 3 KU) F i 1rn P r o p e r t ies : C o n t r a s t R a t i o , 3 m i l f i l m : 0.979 Ref 1e c t a n c e , %: 9 3 . 1 Sheen, 85: 2.3 ASTM Scrub C y c l e s , w i t h shim: I n i t i a l Break: 115 F a i l u r e , 100%: 350 P o r o s i t y , ASTM D-3258: 28.0

SOURCE:

Ucar Emulsion Systems: UCAR L a t e x 367/UCAR L a t e x 376: F o r m u l a t i o n S u g g e s t i o n 1-2217

267

Interior Paints and Related

Good Q u a l i t y I n t e r i o r F l a t N a t r o s o l P l u s , Grade 330, P r o p y l e n e G1y c o l Col 1o i d 226/35 Texanol S u r f y n o l TG C o l l o i d 643 T i -Pure R-901 S a t i ntone W Durami t e C e l i t e 499 Tektamer 38

100 24

3%

5 8 3 2 150 150 150 25

0.5 193 2 120 1 240

Water C o l l o i d 643 N a t r o s o l P l u s , Grade 330, 3% A e r o s o l OT, 75% Flexbond 380 DEV Y i e l d , g a l l o n s : 100 S o l i d s , %: 5 1 . 8 PVC, %: 58.5 V i s c o s i t y , KU: 98 VOC, gm/l - w a t e r : 121 R e f l e c t a n c e : 91.8 C o n t r a s t R a t i o : 0.96 85 Sheen: 1 . 5 F o r m u l a t i o n 3801 2

68% PVC I n t e r i o r F l a t N a t r o s o l 250 HR, 2% Col l o i d 226/35 AMP-95 S u r f y n o l TG P r o p y l e n e G1 y c o l Texanol Drew L-475 T i -Pure R-900 Samhide 583 Sati ntone W Snowf 1ake C e l i t e 499 Tektamer 38 Water N a t r o s o l 250 HR, 2% Flexbond 380 DEV Y i e l d , g a l l o n s : 102 S o l i d s , %: 4 7 . 6 PVC, %: 68 V i s c o s i t y , KU: 90 F o r m u l a t i o n 38013

100 5 2 2 24 8 3 125 12 150 150 25

0.5 200 190 160 VOC, g m / l - w a t e r : 124 Ref 1e c t a n c e : 92.8 C o n t r a s t R a t i o : 0.97 85 Sheen: 2

SOURCE: A i r P r o d u c t s and Chemicals,

Inc.:

FLEXBOND 380 DEV

268

Water -Based Paint Formulations

~Green

F l-______ oor Paint

M_ a t_ e_ r i a1 _ . ~:. Water Methyl Carbi t o 1 Exp. Di s p e r s a n t QR-681 M (35%) NH40H (28%) T r i t o n CF-10 Drew L-405 Chrome Oxide Green X-1134 Letdown : Mai n c o t e HG-54 B u t y l Propasol E k t a s o l v e EEH Sodi um N i t r i t e ( 1 5%) Drew Y-250 NH40H (28%) Rheology M o d i f i e r QR-1001 Water

(20.8%)

F o r m u l a t i o n Constants: Pigment Volume C o n t e n t , %: Volume S o l i d s , %: 34.9 V i s c o s i t y , KU: I n i t i a l : 72 E q u i l i b r a t e d : 74 V i scosi t y , I C I , poise: I n i t i a l : 1.5 Equi 1 ib r a t e d : 1 . 5 pH : I n i t i a l : 9.2 E q u i l i b r a t e d : 9.2

Weight ( L b s .) 14.0 50.0 10.4 1 .o 2.0 1.o 242.1

Volume lGals ) 1.68 5.80 1 .14 0.13 0.23 0.14 5.69

632.6 31.5 5.3 9.0 2.5 5.0 25.0 13.3

73.70 4.25 0.71 1.08 0.35 0.68 2.82 1.60

.

16.3

SOURCE: Rohm and Haas Co.: Maintenance C o a t i n g s : MAINCOTE HG-54: F o r m u l a t i o n FP-54-2

Interior Paints and Related

High-Build

269

I n t e r i o r F l a t W a l l P a i n t Based on a V i n y l A c r y l i c Copolymer Thickened w i t h A c r v s o l RM-825

Weiqht/RatioVolume/Gal l o n s 120.0 14.40 10.0 0.94 25.0 2.69 1.o 0.08 2.0 0.25

Materials: Water Tamol 960 (40%) E t h y l ene G l y c o l D o w i c i l 75 PAG- 188 Add t h e f o l l o w i n g a t low speed:

0.25 5.84 5.45 3.40

5.0 200.0 100.0 75.0

A t t a g e l 50 T i -Pure R-900 Optiwhi t e I m s i l A-15

G r i n d t h e above on a high-speed i m p e l l e r m i l l a t 3800-4500 f o r 20 m i n u t e s . A t a s l o w e r speed l e t down as f o l l o w s : 140.0 33.6 14.0 350.0 4.0 1.5 40.2 0.7

Water A c r y s o l RM-825 B u t y l Carbi t o 1 V i n y l A c r y l i c Copolymer (55%) PAG- 188 Ammonium H y d r o x i d e (28%) Water Toners* Formulation Constants: PVC: 43% Volume Sol i d s : 35% I n i t i a l V i s c o s i t y : 80-90 KU Equi 1 ib r a t e d V i s c o s i t y : 75-1 1 0 KU I C 1 V i s c o s i t y : 1.9-2.7 P CARE ( O r g a n i c V o l a t i l e L e v e l ) g / L : PH: 7.8-8.2

**

FPM

16.80 3.86 1.75 38.68 0.50 0.20 4.83 0.08

167

Tenneco 8800 L i n e Lampblack 0 . 5 Tenneco 8800 L i n e Raw Umber 0 . 2

SOURCE:

Rohm and Haas Co.: Formul a t ion F-VA-2

Trade S a l e s C o a t i n g s : ACRYSOL RM-825:

Water-Based Paint Formulations

270

HiQh B u i l d I n t e r i o r F l a t W a l l P a i n t Based on a V i n y l A c r y l & Copolymer T h i c k e n e d w i t h E x p e r i m e n t a l Rheoloqv M o d i f i e r QR-708 Materials: Water Tamol 960 (40%) Ethylene Glycol D o w i c i l 75 PAG-188

P a r t s Per Hundred Wei q h t R a t i o*(Vol ume 8 a s i s) 120.0 14.40 10.0 0.94 25.0 2.69 1. o

0.08

2.0

0.25

5.0 200.0 100.0 75.0

0.25 5.84 5.45 3.40

Add t h e f o l l o w i n g a t l o w speed: A t t a g e l 50 T i -Pure R-900 Optiwhi t e I m s i l A-15

G r i n d t h e above o n a h i g h speed i m p e l l e r a t 3800-4500 m i n u t e s . A t a s l o w e r speed l e t down as f o l l o w s : Water E x p e r i m e n t a l Rheology M o d i f i e r QR-708 B u t y l Carbit o 1 V i n y l A c r y l i c Copolymer (55%) PAG- 188 Ammonium H y d r o x i d e (28%) Water Toners**

140.0 (35%) 24.0 20.0 350.0 4.0 1.5 43.9 0.7

FPM f o r 20 16.80 2.67 2.50 38.68 0.50 0.20 5.27 0.08

Formulation Constants: p v c : 43% Volume S o l i d s : 35% I n i t i a l S t o r m e r V i s c o s i t y : 80-90 K . U . E q u i l i b r a t e d Stormer V i s c o s i t y : 75-110 K.U. I C 1 V i s c o s i t y : 1.9-2.7 P CARB ( O r g a n i c V o l a t i l e L e v e l ) g / L : 167 p n : 7.8-8.2

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result

.

** **

Tenneco 8800 L i n e Lampblack 0 . 5 Tenneco 8800 L i n e Raw Umber 0 . 2

SOURCE: Rohm and Haas C o . : E x p e r i m e n t a l Rheology M o d i f i e r QR-708: F o r m u l a t i o n XF-VA-1

Interior Paints and Related

H i Qh-Qualit y F l a t W a l l P a i n t Ingredients: Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30M P r e s e r v a t ive ( 1 ) Dispersant (2) T r i t o n N o n i o n i c S u r f a c t a n t N-101 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40 2-Amino-2-methyl-1-propanol (3) Propylene G l y c o l Antifoam (4) Titanium Dioxide (5) Clay (6) C a l c i u m Carbonate ( 7 ) Nepheline S y e n i t e ( 8 ) Letdown : Ucar L a t e x 379 B u t y l C a r b i t o l Solvent Antifoam ( 4 ) Propylene G l y c o l

Pounds

Gallons

330.6 4.5 2.3 5.7 2.2 2.2 1.o 21.6 1.9 175.0 175.0 100.0 75.0

39.69 0.41 0.25 0.62 0.25 0.25 0.13 2.50 0.25 5.47 7.99 4.43 3.40

282.7 13.8 1.9 10.0

31.20 1.75 0.25 1.16

Suppliers: ( 1 ) P r e s e r v a t i v e - "Nuosept" 145 o r e q u i v a l e n t ( 2 ) D i s p e r s a n t - "Tamol" 731 o r e q u i v a l e n t - AMP-95 o r e q u i v a l e n t ( 3 ) 2-Amino-2-methyl-1-propanol ( 4 ) A n t i f o a m - " C o l l o i d " 640 o r e q u i v a l e n t ( 5 ) T i t a n i u m D i o x i d e - "Tronox" CR-813 o r e q u i v a l e n t (6) Clay Satintone W or equivalent ( 7 ) C a l c i u m Carbonate - "#l White" o r e q u i v a l e n t ( 8 ) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t Comparative P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 57.0 S o l i d s , %: by Volume: 37.8 by Weight: 56.9 Weight p e r G a l l o n , l b : 12.05 Paint Properties: V i s c o s i t y , in i t i a1 : Stormer, KU: 92 I C I , poise: 1. O pH, i n i t i a l : 8 . 4 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass Film Properties: C o n t r a s t R a t i o , 6 - m i l b a r : 0.979 R e f l e c t a n c e , %: 90.5 Sheen, 85: 3 . 8 ASTM Scrub C y c l e s , w i t h shim: I n i t i a l Break: 881 F a i l u r e , 10%: 1053

-

SOURCE: U c a r Emulsion Systems: UCAR L a t e x 379: S u g g e s t i o n 1-1985

Formulation

271

272

Water-Based Paint Formulations

I n t e r i o r Gloss White

Lbs.

M a t e r i a1 Water P r o p y l e n e G1y c o l C o l l o i d 226 Col l o i d 643 AMP 95

P r o x e l GXL Premix t h e f o l l o w i n g , t h e n add: P r o p y l ene G1y c o l N a t r o s o l 250MR Tiona RCL-9 H i g h speed d i s p e r s e r , 15 m i n u t e s maximum. Synthemul 40-430 Water I g e p a l CO-610 B u t y l Carbi t o 1 C o l l o i d 643 Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t S o l i d s , Weight: 46.9 P e r c e n t S o l i d s , Volume: 38.2 I n i t i a l V i s c o s i t y , KU: 85-95 Pounds/Gal l o n : 10.49 pH: 8.3-8.8 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 238.0 60 G l o s s : 65-75 20 G l o s s : 20-25

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 430-04

Gals.

100.0 40.0 8.0 1 .o 1.5 1.5

12.00 4.63 0.78 0.13 0.18 0.17

48.8 3.0 250.0

5.65 0.26 7.31

525.0 56.0 3.0 10.0 1 .o

60.34 6.72 0.34 1.35 0.13

P e r c e n t : 20.2

I n c . : Waterborne F o r m u l a t i o n s :

Interior Paints and Related

I n t e r o r Semi qloss

-

273

A c r v l ic

Pounds Water C e l l o s i z e QP4400, T h i c k e n e r ( 2 . 5 % ) Pol ywet ND-2, D i s p e r s a n t ( 2 5 % ) Propylene G l y c o l C o l l o i d s 6 0 0 , Defoamer T i P u r e R-900, R u t i l e T i t a n i u m D i o x i d e

30.0 92.0 7.2 20.0 2.0 170.0

D i s p e r s e a t h i g h speed. Add Rhopl ex AC-490, A c r y l ic Emu1 s i on Texanol , C o a l e s c i n g S o l v e n t T r i t o n CF-10, W e t t i n g Agent Super A d - I t , P r e s e r v a t i v e Water Ethylene Glycol Water C e l l o s i z e QP4400, T h i c k e n e r ( 2 . 5 % ) C o l l o i d 6 0 0 , Defoamer T r i t o n N-57, W e t t i n g Agent

382.0 10.0 2.0

0.5 20.0 20.0 101 . o 112.5 1 .o 8.0

Weight p e r G a l l o n : 9 . 5 8 pounds Solids: 36.1% PVC:

20.9%

V i s c o s i t y : 80 KU Gloss, 6 0 : 68 Pai n t D i s p e r s i o n s : POLYWET ND-2 and ND-35 e x h i b i t t h e f o l l o w i n g o u t s t a n d i n g p r o p e r t i e s i n l a t e x p a i n t s : s u p e r i o r r e s i s t a n c e t o foaming i n package and a p p l i e d , absence o f c r a t e r i n g , improved s c r u b r e s i s t ance and s u p e r i o r adhesion t o c h a l k e d p a i n t and enamel s u r f a c e s . POLYWET ND-2 i s t h e l o w e r s o l i d s v e r s i o n o f ND-35 (25% v s . 3 5 % ) .

SOURCE:

U n i r o y a l Chemical Co., Formul a t ion

Inc.:

POLYWET ND-2 and ND-35:

274

Water-Based Paint Formulations

I n t e r i o r Semigloss

White

Propylene G l y c o l Tamol 731 Texanol AMP 9 5 T r i t o n CF10 Drew L-484 T i - P u r e R-900 A t t a g e l 50 Tektamer 3 8 Water A e r o s o l OT-75% N a t r o s o l P l u s , Grade 3 3 0 , 2% Drew L-484 Flexbond 380 DEV A c r y s o l RM-825 Y i e l d , gallons: 100.7 S o l i d s , %: 4 5 . 5 PVC, %: 2 2 . 3 V i s c o s i t y , KU: 9 5 IC1 V i s c o s i t y , p o i s e : 1 . 5 5 VOC, gm/l - w a t e r : 222 60 g l o s s : 68 20 g l o s s : 24

SOURCE: A i r Products and Chemicals, I n c . : FLEXBOND 3 8 0 DEV: F o r m u l a t i o n 38018

50 12 10 2 2 1 240 3 0.5 182 1 100 3 430 22

Interior Paints and Related

275

Latex I n t e r i o r S a t i n Lbs./100 -

Gal. 200.00 1.60 0.40

Water Tamol 731 KTPP T r i t o n N-101 QP-15,000

0.80 1.40

Add a l l t o w a t e r u n d e r a g i t a t i o n , m i x 5 m i n u t e s 120.00 46.60 30.00

R-900 Min-U-Si1 15 Snow*Tex 45 D o w i c i l 75 Drew P l u s L-475 E x x a t e 1300 Add a l l u n d e r a g i t a t i o n ,

0.80

1 .oo 10.20 d i s p e r s e t o 6+ Hegman

108.40 18.40

Water Ucar SCT-275 Mix 5 minutes 28% Ammonia W a l l p o l 40-1 36

0.80 464.00

60 G l o s s : 2 8 . 5 20 G l o s s : 6.0 V i s c o s i t y : 88 KU a t 25C PVC: 20.8% P i gment : 19.6% C o n t r a s t R a t i o : 98.0 R e f l e c t a n c e ( Y ) : 90.8% L b s . / g a l : 10.0 N . V . V . : 34.1% N.V.W.: 47.5% Gloss, c o n t r a s t r a t i o , f il m t h i c k n e s s .

SOURCE: U . S .

and r e f l e c t a n c e measured a t 2 m i l d r y

S i l i c a C o . : Formula AC-108

276

Water-Based Painr Formulations

_ L a_ tex ~ I_ n t_ e r_ i o_ r _____ Semi-Gloss ~

.

Lbs. / l o 0 Gal 200.00 1.60 0.40 0.80 1.40

Water Tamol 731 KTPP T r i t o n N-101 QP-15,000 Add a l l t o w a t e r u n d e r a g i t a t i o n ,

mix 5 minutes 110.00 28.00 0.80 1 .oo 10.20

R-900 Min-U-Si1 10 D o w i c i l 75 Drew P l u s L-475 E x x a t e 1300

Add a l l u n d e r a g i t a t i o n ,

d i s p e r s e t o 7+ Hegman 106.40 18.00

Water Ucar SCT-275 Mix 5 minutes

0.80 490.20

28% Ammonia W a l l p o l 40-136 60 G l o s s : 58.0 20 G l o s s : 2 0 . 3 V i s c o s i t y : 87 KU a t 25C PVC: 13.8% P i gment : 14.2% C o n t r a s t R a t i o : 97.3 R e f l e c t a n c e ( Y ) : 90.9% Lbs./gal.: 9.7 N . V . V . : 33.0% N.V.W.: 42.8%

G l o s s , c o n t r a s t r a t i o , and r e f l e c t a n c e measured a t 2 m i l d r y f i l m thickness. SOURCE: U . S .

S i l i c a Co.:

Formula AC-105

277

Interior Painrs and Relared

Low Cost,

High Hide I n t e r i o r F l a t

Lbs./100 G a l . 566.8 7.0

Water C e l l o s i z e QP 15,000 Add C e l l o s i z e under a g i t a t i o n ,

mix 5 m i n u t e s

KTPP

1

.o

Add and mix 2 m i n u t e s

5.2 5.0 0.4 23.7

T r i t o n NlOl Tamol 731 Drewpl us L475 Ethylene Glycol Add and m i x 2 m i n u t e s

100.0 250.0

R900 Snow*Tex 45 Add s l o w l y ;

d i s p e r s e t o a 4t Hegman

104.4 8.2 0.7 1.5

W a l l p o l 40-136 Exxate 1300 Drewpl us L475 Dowcil 75 Add s l o w l y under a g i t a t i o n ,

m i x 10 m i n u t e s

V i s c o s i t y : 92 KU a t 25C W t / g a l : 10.74 lbs. N.V.W.:

39.4%

N . V . V . : 22.1% PVC: .704 Pigment : 32.59% P/0: 4.79 C o n t r a s t R a t i o : 0.97 R e f l e c t a n c e ( H u n t e r Green): 92.5 Gloss 60: 2.0 Gloss 20: 1.3

SOURCE:

U.S.

Silica Co.: Formula AC-110

278

Water-Based Paint Formulations

Low-Cast

I n t e r i s r F l a t T i n t Base

lbs/99.7 gal Premix on K a d y z o l v e r a t 2,000 rpm f o r 10 min: Water 200.0 KTPP

Ross & Rowe 551 Tamol 731 (25%) Nopco NXZ Ethylene g l y c o l Carbi t o 1 a c e t a t e T h i c k e n e r (2.5% s o l u t i o n )

SLL

2.0 20.0 10.0 101 . o

240.4 2.4 2.4 6.0 2.4 24.0 12.0 121.4

175.0 150.0 125.0 25.0

210.3 180.3 150.3 30.0

3.0 200.0 0.5 40.0 110.0 1 .o

3.6 240.4 0.6 48.1 132.2 1.2

2.0 2.0 5.0

Add and g r i n d a t 3,500 rpm f o r 15 min: Ti-Pure R-901 Camel Carb Iceburg c l a y 1160 s i l i c a L e t down ( l o w speed on an a i r s t i r r e r ) : Makon 10 P o l y c o 2161 (55%) Merbac 35 Water T h i c k e n e r (2.5% s o l u t i o n ) N H 4 0 H , 28% ammonium h y d r o x i d e

T i n t w i t h C a l / I n k 8800 s e r i e s c o l o r a n t s a t 2 o z / g a l Physical Properties: PVC, % : 62.7 Volume s o l i d s , % : 30.3 Weight s o l i d s , %: 49.9 D e n s i t y , 1b s / g a l ( k g / l ) : 11.75 (1.41 ) Stormer v i s c o s i t y ( o v e r n i g h t ) , KU: 88t-3 pH: 8.0-8.5

SOURCE: Aqualon Ca.: NATROSOL B H y d r o x y e t h y l c e l l u l o s e : Formula Table I1

Interior Paints and Related

279

Low VOC P a i n t 65PVC F l a t

Pounds 100 2 1 2 3 7 3 125 150 175 3 193 200 190

Water N a t r o s o l 250HR Kathon L X S u r f y n o l TG P o t a s s i um Carbonate C o l l o i d 226 C o l l o i d 640 T i P u r e R-900 Huber 70C Hubercarb Q-6 C o l l o i d 640 Water N a t r o s o l 250HR 2% A i r f l e x 738 Y i e l d , g a l l o n s : 100.9 S o l i d s : 48% PVC: 65% V i s c o s i t y : 90 KU Contrast Ratio, 3 m i l : Ref 1e c t a n c e : 90.76 85 Sheen: 1 . 9 F o r m u l a t i o n 12776-16

0.9714

Low VOC 60 PVC F l a t

Water N a t r o s o l P l u s , Grade 330 S u r f y n o l TG Kathon LX C o l l o i d 226 Col l o i d 640 T i P u r e R-901 Huber 70C Hubercarb Q-325 Col l o i d 643 Water A i r f l e x 738 Y i e l d , g a l l o n s : 100.8 S o l i d s : 51.10% PVC: 60% F o r m u l a t i o n 12061-76

SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Low VOC P a i n t F o r m u l a t i o n s Based on AIRFLEX 738 Emulsion

Pounds 300 6.7 2 1 7 2 125 150 200 3 136 250

280

Water-Based Paint Formulations

L o w VOC Semi G l o s s

Pounds 75 8 2 1 1 3 250

Water Tamol 731 AMP 95 S u r f y n o l TG Kathon LX Col l o i d 640 T i - P u r e R-900 Water A i r f l e x 738 Rhoplex SGlO C o l l o i d 640 A c r y s o l RM-5 Water AMP95 A c r y s o l TT-935

too

220 140 2 50 184 6 5

Yield, gallons: 99.5 Sol i d s : 43% PVC: 27.50% V i s c o s i t y : 91 KU I C 1 V i s c o s i t y : 1.35 Poise 60 G l o s s : 61 F o r m u l a t i o n 11975-30A

Low VOC E a a s h e l l Enamel Pounds 200 10 2 1 3 5 225 20 110 2 170 20 350

Water Tamol 731 S u r f y n o l TG Kathon LX C o l l o i d 640 P o t a s s i um Carbonate T i -Pure R-900 S p a c e r i t e S-11 Atomi t e C o l l o i d 640 Water Pol yphobe 11 1 A i r f l e x 738 Y i e l d , g a l l o n s : 100 S o l i d s : 48.50% PVC: 41.20% V i s c o s i t y : 100 KU 60 G l o s s : 13 85 Sheen: 29 Ref 1e c t a n c e : 91 . 8 9 Contrast Ratio, 3 m i l : F o r m u l a t i o n 12776-39

0.971

SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Low VOC P a i n t Formulas

Interior Paints and Related

281

P o l y v i n y l Acetate Latex P a i n t Pigment d i s p e r s i o n , Cowles D i s s o l v e r 1.5% Sodium CMC* w a t e r g e l Vancide TH Water Ethylene g l y c o l Darvan No. 7 A n t i foamer Titanium dioxide N y t a l 300 Reduct ion : Water E v e r f l e x BG o r e q u i v a l e n t 4% Veegum T w a t e r g e l W e t t i n g agent

Pounds 134 1 116 25 10 4 200 150

Gal 1ons 16.0 0.1 13.9 3.0 1.o 0.4 5.8 6.3

130 264 50 20

15.6 29.6 5.9 2.4

*

H e r c u l e s 7H3SF o r e q u i v a l e n t C o n s i s t e n c y , immediate KU: 67 C o n s i s t e n c y , one day KU: 75 C o n s i s t e n c y , one month KU: 81 C o n s i s t e n c y , one week KU: 79 Pigment volume c o n c e n t r a t i o n : 46 P e r c e n t s o l i d s by w e i g h t : 45 Formula No. 1242 S t i p p l e F i n i s h PVA L a t e x P a i n t Pigment d i s p e r s i o n , Cowles D i s s o l v e r 1.5% Sodium CMC* w a t e r g e l Vancide TH Water Ethylene g l y c o l Darvan No. 7 A n t i foamer Titanium dioxide N y t a l 300 Reduct ion : Water E v e r f l e x BG o r e q u i v a l e n t 4% Veegum T w a t e r g e l W e t t i n g agent

Pounds 134 1 116 25 10 4 200 300

Gallons 16.0 0.1 13.9 3.0 1 .o

78 264

9.3 29.6 5.9 2.4

50 20

0.4 5.8 12.6

*

H e r c u l e s 7H3SF o r e q u i v a l e n t C o n s i s t e n c y , immediate KU: 93 C o n s i s t e n c y , one day KU: 97 C o n s i s t e n c y , one week KU: 97 C o n s i s t c n c y , one month KU: 97 Pigment volume c o n c e n t r a t i o n : 57 P e r c e n t s o l i d s b y w e i g h t : 54 Formula No. 1243

SOURCE:

R.T.

V a n d e r b i l t Co.,

Inc.:

VEEGUM T i n L a t e x P a i n t s

282

Water-Based Paint Formulations

Premium O u a l i t v I n t e r i o r W h i t e E g a s h e l l W a l l P a i n t Based on Rhoplex AC-64 Thickened w i t h A c r y s o l RM-825 Mater ia1 s : Water D o w i c i l 75 Tamol 731 (25%) P r o p y l e n e G1 y c o l P a t c o t e 888 T i -Pure R-900 Optiwhite A t t a g e l 50

Wei qht/Pounds Volume/Gal l o n s 83.2 10.00 1. o 0.09 11.5 1.25 25.0 2.91 2.0 0.25 250.0 7.30 100.0 5.45 5.0 0.26

G r i n d t h e above on a high-speed i m p e l l e r m i l l a t 3800-4500 FPM f o r 20 m i n u t e s . A t a s l o w e r speed l e t down as f o l l o w s : Water Rhopl ex AC-64 Texanol P a t c o t e 888 Water B u t y l Carbi t o 1 ) Premix A c r y s o l RM-825 ) N a t r o s o l MR (2.5%) Ammoni um H y d r o x i de (28%) Water Formulation Constants: PVC: 36% Volume S o l i d s : 35.4% I n i t i a l Viscosity: KU: 85+-5 KU I C 1 : 1 .6+-0.2P Equilibrated Viscosity: KU: 95+-5KU I C 1 : 1.7+-0.2P Gloss 85: 20 60: 6 CARB ( O r g a n i c V o l a t i l e L e v e l ) g / L : SOURCE: Rohm and Haas Co.: F o r m u l a t i o n F-64-7

83.2 350.0 10.6 4.0

83.2 31 . O 26.6 12.0 1.5 20.9

10.00 39.55 1.33 0.50 10.00 3.88 3.06 1.45 0.21 2.51

188

Trade S a l e s C o a t i n g s : ACRYSOL RM-825:

Interior Paints and Related

283

Q u a l i t y F l a t T i n t Base Inqredients:

P i gment G r i nd : Water C e l l o s i z e Hydroxyethyl C e l l u l o s e QP-15, OOOH P r e s e r v a t ive ( 1 ) D i s p e r s a n t (2) N o n i o n i c S u r f a c t a n t (3) P r o p y l e n e G1y c o l A n t i f o a m (4) T i t a n i u m D i o x i d e (5) Nephel ine S y e n i t e (6) Letdown : Ucar L a t e x 376 (7) Ucar A c r y l i c 522 (7) Ucar F i l m e r IBT A n t i f o a m (4) Mildewcide ( 8 ) W e t t i n g A i d (9) Ammoni um H y d r o x i de 28% Aqueous Sol u t i on

Pounds

Gal l o n s

175.0

20.98

4.5 2.3 10.2 3.0 25.9 0.9 175.0 200.0

0.39 0.26 1.02 0.34 2.99 0.13 5.24 9.20

183.2 199.5 14.2 2.6 5.0

20.24 22.42 1.79 0.37 0.33 0.20 0.24

2.3

1.8

Sunn1 ie r s : (lj' P r e s e r v a t i v e - "Cosan" 145 o r e q u i v a l e n t (2) D i s p e r s a n t - " C o l l o i d " 226/35 o r e q u i v a l e n t ( 3 ) N o n i o n i c S u r f a c t a n t - " I g e p a l " CO-630 o r e q u i v a l e n t (4) A n t i f o a m - " C o l l o i d " 643 o r e q u i v a l e n t (5) T i t a n i u m D i o x i d e - "Tronox" CR-822 o r e q u i v a l e n t (6) N e p h e l i n e S y e n i t e - "Minex" 4 o r e q u i v a l e n t (7) Ucar L a t e x 376: Ucar Acr l i c 522 i n 50:50 volume s o l i d s b l end, r e s p e c t iv e l y ( 8 ) M i 1dewci de - "Nopcoci de" N-96 o r e q u i v a l e n t (9) W e t t i n g Agent - " D e x t r o 1 OC-50" o r equi Val e n t

.

Paint Properties: P i gment Volume C o n c e n t r a t on (PVC), S o l i d s , %: by Volume: 37.2 by Weight: 53.3 V i s c o s i t y ( i n i t i a1 ) : Stormer, KU: 104 I C I . n o i s e : 1.3 PH ( i n i t i a l ) : 8.4 Weight p e r G a l l o n , l b : 11.24 Film Properties: Contrast Ratio, 3 m i l f i l m : R e f l e c t a n c e , %: 90.5

SOURCE:

%:

40.9

0.962

Ucar Emulsion Systems: UCAR L a t e x 367/UCAR L a t e x 376: F o r m u l a t i o n S u g g e s t i o n E-2212

284

Water-Based Paint Formulations

Quality I n t e r i o r White Methocel J-12-HS, 3% Tamol 731 AMP-95 I g e p a l CO-610 E t h y l e n e G1 y c o l Texanol W i t c o 3056-A Tronox CR-812 S a t i n t o n e #5 Zeolex 80 Gold Bond R Water Merbac 35 W i t c o 3056-A Methocel J-12-HS, 3% Flexbond 325 Y i e l d , g a l l o n s : 103 S o l i d s , %: 51 PVC, %: 4 9 VOC, gm/l - w a t e r : 130 F o r m u l a t i o n No. 32511

Pounds 75 6 3 4 25 8 2 250 100 20 75 215 1 1 110 300

I n t e r i o r Semigloss W h i t e P r o p y l e n e G1 y c o l Texanol Tamol 731 Drew L-404 AMP-95 Water T i - P u r e R-900 Drew L-404 Merbac 35 A e r o s o l OT Flexbond 325 N a t r o s o l P l u s , Grade 330, 2% R h e o l a t e 278 Water Y i e l d , g a l l o n s : 99.7 S o l i d s , %: 45 PVC, %: 24 VOC, g m / l - w a t e r : 195 V i s c o s i t y , KU: 82 I C 1 V i s c o s i t y , p o i s e : 1.24 60 G l o s s : 64 20 G l o s s : 21 Leneta L e v e l i n g : 7 F o r m u l a t i o n No. 32528

Pounds 40 13 12 2 3 25 250 3 1 1 400 100 18 185

SOURCE: A i r P r o d u c t s and Chemicals, I n c . : F l e x b o n d 325 V i n y l A c r y l i c Emulsion: T y p i c a l S t a r t i n g F o r m u l a t i o n s

Interior Paints and Related

Q u a l i t y Latex F l a t O p t i w h i t e Approach Lbs. / l o 0 G a l . 340 3.00 2.00 18.60 1 .oo 6.90 4.50 9.30 4.00 1 .oo 120 200 150 35 265 11.88 3.00

Water PA-328 Nuosept 95 Ethylene Glycol KTPP Tamol 731 T r i t o n X-100 P r o p y l e n e G1y c o l Cel l o s i ze QP-4400 Ammon ia CR-813 Optiwhi t e # l W h i t e (CaC03) C e l i t e 281 301 1 Texanol PA-328 Evaluation Results: H i d i n g 3 M i l B i r d B l a d e on O p a c i t y P a n e l : R e f l e c t a n c e : .903 C o n t r a s t R a t i o : .972 T i n t S t r e n g t h . 5 Blue/200 grams: Ref 1e c t a n c e : .727 Sheen: 85: 1 . 9 60: 2 . 3 V i s c o s i t y KU: 95 SOURCE: Burgess Pigment Co.:

Formula 95 ICE/OPT

285

286

Water -Based Paint Formulations

Q u a l i t y Latex I n t e r i o r F l ~ t O p t i w h i t e Approach

Lbs./lOO G a l . Water Troysan 174 N a t r o s o l P l u s 330 KTPP Propylene G l y c o l AMP-95 Tamol 1124 I g e p a l CO-630 Col l o i d 697 RCL-9 #10 W h i t e Opt iwhi t e Unocal 3084 C o l l o i d 697 Texanol T r i t o n GR-7 RM-825

261 2.25 3.50 1 .68 61 3.00 8.00 3.95 4.00 160 200 200 268 4.00 13.00 3.90 9.75

Eva1u a t i o n R e s u l t s : H i d i n g 3 M i 1 B i r d B l a d e on O p a c i t y Panel : Ref 1e c t a n c e : .901 C o n t r a s t R a t i o : .970 T i n t S t r e n g t h . 5 Blue/200 grams: Ref 1e c t a n c e : ,715 Sheen : 85: 1 . 7 60: 2.7 V i s c o s i t y KU: 95 SOURCE: Burgess Pigment

Co.: Formula 1 4 0 OP-62/OPT

Interior Paints and Related

Q u a l i t y L a t e x Semi -Gloss Burgess No. 98 Appro& Lbs./100 Water Tamol 731 ~ ~ p - 9 5 T e r g i t o 1 NP-10 Drew L-464 T r o y s a n 186 CR-800 Burgess N o . 98 A t t a g e l 50 Texan01 Ucar 379 Ucar 525 Propylene Glycol T r i t o n GR-7M Drew L-464 Ucar SCT-275

294 5.00 3.00 2.00 2.00 2.00 250 75 4.00 16.00 280 180 40 1 .oo 4.00 18

Eva1 u a t i on R e s u l t s : H i d i n g 3 M i l B i r d B l a d e on O p a c i t y P a n e l : R e f l e c t a n c e : .920 C o n t r a s t R a t i o : .981 T i n t S t r e n g t h . 5 B l u e / 2 0 0 grams: R e f l e c t a n c e : .737 Sheen : 85: 8 2 . 8 60: 3 3 . 4 20: 3.8 V i s c o s i t y KU: 96

SOURCE:

Burgess Pigment Co.:

Gal.

Formula 100 OP-62/98

287

288

Water-Based Paint Formulations

Red Floor P a i n t Weight ILbs. 1 14.0 50.0 10.4 1.o 2.0 1. o 41.6 201.3

M a t e r i a1 : Water Methyl Carbi t o 1 Exp. D i s p e r s a n t QR-681M (35%) NH4OH (28%) T r i t o n CF-10 Drew L-405 Chrome O x i d e Green X-1134 Red I r o n O x i d e R-2899

Volume (Gals.) 1.68 5.80 1.14 0.13 0.23 0.14 0.98 4.71

G r i n d on t h e h i g h - s p e e d c o w l e s f o r t w e n t y m i n u t e s ; t h e n , f o l l o w i n g letdown: 632.6 Mai n c o t e HG-54 31.5 B u t y l Propasol 5.3 E k t a s o l v e EEH 9.0 Sodium N i t r i t e (15%) 2.5 Drew Y-250 5.0 NH40H (28%) 21 .o Rheology M o d i f i e r QR-1001 (20.8%) 7.2 Water F o r m u l a t i o n Constants: Pigment Volume C o n t e n t , %: Volume S o l i d s , %: 3 4 . 9 V i s c o s i t y , KU: I n i t i a l : 82 E q u i l i b r a t e d : 85 Viscosity, I C I , poise: I n i t i a l : 1.5 E q u i l i b r a t e d : 1 .5 pH : I n i t i a l : 9.2 E q u i l i b r a t e d : 9.2

add t h e 73.70 4.25 0.71 1.08 0.35 0.68 2.36 2.06

16.3

SOURCE: Rohm and Haas Co.: M a i n t e n a n c e C o a t i n g s : MAINCOTE HG-54: F o r m u l a t i o n FP-54-1

Interior Paints and Related

289

Semialoss I n t e r i o r W h i t e P a i n t M a t e r ia1 s : Propylene g l y c o l Tamol SG-1, 35% H e r c u l e s SGL defoamer Rutile titanium dioxide S i l i c a ( s m a l l - p a r t i c l e , amorphous) Water

&j

80.0 8.5 2.0 240.0 25.0 25.0

Gal 9.30 0.89 0.26 7.03 1.13 3.00

M i l l t h e above i n a h i g h - s p e e d m i l l

l e t down a t a s l o w e r speed,

(Cowles) f o r 20 m i n u t e s and as f o l l o w s :

Rhoplex AC-417, 48.0% H e r c u l e s SGL defoamer Propylene g l y c o l Texanol Super A d - I t ) Premix ) T r i t o n GR-7M Water a n d / o r 3% N a t r o s o l P l u s Formulation Constants: W t / g a l , l b s : 10.65 Pigment volume c o n c e n t r a t i o n , %: Volume s o l i d s , %: 3 2 . 9

500.0 2.7 10.0 21.6 1.o 0.5 169.0

56.00 0.37 1.16 2.73 0.12 0.06 20.20

24.8

P r o p e r t i e s e x h i b i t e d when p a i n t i s t h i c k e n e d w i t h N a t r o s o l P l u s : Wt%polymer: 0 . 3 3 V i s c o s i t y , KU: 92 Brushing v i s c o s i t y , poises: 1.2 Spatter: 8 Leveling: 5 Sag r e s i s t a n c e , m i l s : 1 9 . 5 S c r u b c y c l e s t o f a i l u r e : 600 60 g l o s s : 42.9 SOURCE: Aqualon Co.:

NATROSOL PLUS: Formula SG-41-3

Water-Based Paint Formulations

290

Semi-Gloss W h i t e F o r m u l a t i o n P a r t s Per Hundred M a t e r ia 1s : Weiqht R a t i o * (Volume B a s i s ) Charge t o a Cowles t a n k and m i x f o r 5 m i n u t e s a t a l o w speed o f a b o u t 1,500 f e e t p e r m i n u t e . Rhoplex AC-604 (46%) 160.0 17.73 Tamol 731 (25%) 14.0 1 .70 T r i t o n CF-10 2.0 0.24 Nopco NXZ 0.5 0.06 Dimethylami noethanol )Premix 1.1 0.13 2.2 0.27 ) Water S l o w l y add t h e t i t a n i u m d i o x i d e and s i l i c a s w h i l e i n c r e a s i n g m i x e r speed t o 4,200 f e e t p e r m i n u t e . G r i n d f o r 20 m i n u t e s : T i -Pure R-960 200.2 6.06 S y l o i d 978 13.3 0.80 S y l o i d 308 6.7 0.40 G r a d u a l l y add t h e f o l l o w i n g and b l e n d a t a l o w speed o f about 1,500 f e e t p e r m i n u t e : Rhoplex AC-604 (46%) 490.0 54.30 Water 10.0 1.21 B u t y l C e l l o s o l v e (60% i n w a t e r ) 50.0 6.00 Cel l o s i ze QP-40 (5%) 8.4 1 .40 I f a l o w e r t e m p e r a t u r e c u r i n g i s r e q u i r e d , r e p l a c e some o f t h e water i n t h e formulation w i t h c a t a l y s t .

F o r m u l a t i o n Constants: Pigment volume c o n t e n t , %: T i O Z / b i n d e r r a t i o : 40/60 A p p r o x i m a t e s o l i d s , %: W e i g h t : 54 Volume: 45

*

19

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result.

SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s : RHOPLEX AC-604: F o r m u l a t i o n Based on RHOPLEX AC-604 E m u l s i o n

Interior Paints and Related

291

S t y r e n e - B u t a d i ene L a t e x P a i n t Pigment d i s p e r s i o n , Cowles D i s s o l v e r 1.5% Sodium CMC* w a t e r g e l Vancide TH Ethylene g l y c o l Darvan No. 7 A n t i foamer Ammoni um h y d r o x i de, 28% Titanium dioxide N y t a l 300 Reduction: Dow 762-W o r e q u i v a l e n t 4% Veegum T w a t e r g e l W e t t i n g agent

*

Pounds 200

Gal 1ons 23.9

1

0 - .. 1.

25 10 4 2 200 225

3.0 1.o 0.4 0.2 5.8 9.5

308 146 20

36.6 17.1 2.4

H e r c u l e s 7H3SF o r e q u i v a l e n t

C o n s i s t e n c y , one day KU: 85 C o n s i s t e n c y , immediate KU: 80 C o n s i s t e n c y , one month KU: 88 C o n s i s t e n c y , one week KU: 86 Pigment volume c o n c e n t r a t i o n : 47 P e r c e n t s o l i d s b y w e i g h t : 52 Formula No. 1244 A c r y l i c Latex P a i n t P i gment d i s p e r s i on, Cowles D i s s o l ver

322 100 20

37.2 11.8 2.4

1

Reduct ion : Rhoplex AC-33 o r e q u i Val e n t 4% Veegum T w a t e r g e l W e t t i n g Agent

*

105 25 10 4 2 200 225

Gal l o n s 16.0 0.1 12.6 3.0 1.o 0.4 0.2 5.8 9.5

Pounds 134

1.5% Sodium CMC* w a t e r g e l Vancide TH Water Ethylene g l y c o l Darvan No. 7 A n t i foamer Ammonium h y d r o x i d e 28% Titanium dioxide N y t a l 300

H e r c u l e s 7H3SF o r e q u i v a l e n t

C o n s i s t e n c y , immediate KU 79 C o n s i s t e n c y , one day KU: 82 C o n s i s t e n c y , one month KU: 84 C o n s i s t e n c y , one week KU: 83 Pigment volume c o n c e n t r a t on: 50 P e r c e n t s o l i d s b y w e i g h t : 51 Formula No. 1245

SOURCE:

R.T.

V a n d e r b i l t Co.,

Inc.:

VEEGUM T i n L a t e x P a i n t s

292

Water-Based Paint Formulations

White F l o o r P a i n t Weight (Lbs. 1 4.0 50.0 8.4

M a t e r i a1 Water Methyl Carbi t o 1 Exp. D i s p e r s a n t QR-681 M NH40H (28%) T r i t o n CF-10 Drew L-405 T i P u r e R-900 t i t a n i u m d i o x i d e

632.6 31.5 5.3 6.6 2.5 5.0 50.9

73.70 4.25 0.72 0.79 0.35 0.68 6.11

1. o

Letdown : Mai n c o t e HG-54 B u t y l Propasol E k t a s o l v e EEH Sodium N i t r i t e (15%) Drew Y-250 NH4OH (28%) Rheology Modi f ie r QR-1001 /Water F o r m u l a t i o n Constants: Pigment Volume C o n t e n t , %: Volume S o l i d s , %: 3 4 . 9 V i s c o s i t y , KU: I n i t i a l : 75 Equi 1 ib r a t e d : 77 Viscosity, I C I , poise: I n i t i a l : 1.1 Equilibrated: 1.2 pH : I n i t i a l : 9.2 Equi 1 ib r a t e d : 9 . 1

2.0 1.o 195.0

Volume (Gals. 1 0.48 5.80 0.92 0.13 0.23 0.14 5.70

16.3

SOURCE: Rohm and Haas Co.: M a i n t e n a n c e C o a t i n g s : MAINCOTE HG-54: F o r m u l a t i o n FP-54-3

294

Water-Based Paint Formulations

C l e a r A i r - D r y Lacquer Material : Water Methyl Carbi t o 1 AMP 95 Dimethyl Phthalate Aerosol TR-70 Foamaster G P r o x e l GXL B l e n d above i n o r d e r ; Synthemul 97-603

Lbs. ~. Gals. 205.0 24.61 58.0 6.82 1 .o 0.11 18.2 1 .85 2.0 0.25 1 .o 0.15 1.o 0.10 add t o b e l o w s l o w l y , under a g i t a t i o n . 581.8 66.11

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 0 . 0 Percent S o l i d s , Weight: 30.2 P e r c e n t S o l i d s , Volume: 2 7 . 7 V i s c o s i t y @ 25C, #4 Ford, S e c s . : 25-30 pH: 8 . 5 - 9 . 0 Pounds/Gallon: 8 . 6 8 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 191 . O 60 G l o s s : 80-85 MFFT, C : 0 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n T603-01

Inc.:

Waterborne Handbook:

Lacquers

Clear,

F u l l G l o s s Waterborne Lacquer Based On Rhoplex CL-103 Emulsion f o r A i r - D r v o r Low-Force-Dry A p p l i c a t i o n

Mater ia1 s : Rhopl ex CL-103 emu1s i on Dee Fo 3000

Weight Pounds 668.0 1.4

Volume Gal l o n s 77.5 0.2

26.7 40.1 33.4

3.4 5.4 4.0

Premix and add under a g i t a t i o n : B u t y l Carbi t o 1 Butyl Cellosolve Water Add : 26.7 4.0 22.9 2.8 14% ammonia 2.4 0.3 ( a d j u s t v i s c o s i t y w i t h w a t e r t o a range o f 20 t o 26 seconds on a #2 Zahn cup) Water 20.3 2.4 Dow C o r n i n g #14

M i chem Emu1s i on 39235

F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w t / v o l ) : 33.6/31.4 pH: 7 . 5 - 8 . 0 V i s c o s i t y , #2 Zahn cup, seconds: 20 t o 26 VOC, g / l i t e r : 249 l b / g a l l o n : 2.08 C o a l e s c e n t , w t % on polymer s o l i d s : B u t y l C e l l o s o l v e : 15 B u t y l C a r b i t o l : 10 Heat/age S t a b i l i t y : Passes Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g

SOURCE: Rohm and Haas Co.: F o r m u l a t i o n KC-53-1

RHOPLEX CL-103 A c r y l i c Emulsion:

295

2%

Water-Based Paint Formulations

Clear,

F u l l -Gloss Waterborne Lacouer Based on RhoDlex CL-104 Emulsion f o r A i r - D r y o r Low-Force-Dry A p p l i c a t i o n

Materials: Rhoplex CL-104 e m u l s i o n Dee Fo 3000

Weight Pounds 642.8 1.3

Volume Gal 1ons 75.2 0.2

24.7 24.7 37.6 29.2

3.7 3.1 5.1 3.5

Premix and add under a g i t a t i o n : Dow C o r n i n g #14 B u t y l Carbi t o 1 Hexyl C e l l os01 ve Water Add : M i chem Emu1s i on 39235 21.8 2.6 14% Ammoni a 3.0 0.4 ( a d j u s t v i s c o s i t y w i t h w a t e r t o a range o f 20 t o 26 seconds on a #2 Zahn cup) 51.5 6.2 F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w t / v o l ) : 30.7/29.1 pH: 7.5-8.0 V i s c o s i t y , #2 Zahn cup, seconds: 20 t o 26 VOC, g / l i t e r : 249 l b / g a l l o n : 2.07 C o a l e s c e n t , w t % on polymer s o l i d s : B u t y l C e l l o s o l v e : 15 B u t y l C a r b i t o 1 : 10 Rheology m o d i f i e r , w t % on polymer s o l i d s : 1 . 0 Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes SOURCE: Rohm and Haas Co.: RHOPLEX CL-104 A c r y l i c Emulsion: F o r m u l a t i o n WR-74-7

Lacquers

297

C1 e a r Lacquer P a r t s p e r Hundred Weiqht R a t i o * ( V o l u m e B a s i s ) 650.0 75.6 13.2 110.0

M a t e r i a1 s : Rhoplex WL-81 Water Premix and add under a g i t a t i o n : E t h y l e n e g l y c o l monobutyl e t h e r D i e t h y l e n e g l y c o l monobutyl e t h e r

BYK-301 P a t c o t e 519

103.8 10.8 1.3 0.9

13.8 1.4 0.2 0.1

To i n c r e a s e t h e l a c q u e r v i s c o s i t y add d l u t e ammonia s o l u t i o n c o n s i s t i n g o f 1 p a r t c o n c e n t r a t e d ammonia 28%) and 1 p a r t w a t e r . To decrease t h e l a c q u e r v i s c o s i t y t h i n w i t w a t e r . F o r m u l a t i on C o n s t a n t s : PH: 7 . 5 + - 0 . 3 V i s c o s i t y , c p s . : 100 t o 400 Approximate S o l i d s , % ( w t . , v o l . ) : 31, 2 9 Density, l b s . / g a l . : 8 . 4 Freeze/Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Mechanical S t a b i l i t y ( 5 ' Waring B l e n d e r ) : S a t i s f a c t o r y Heat S t a b i l i t y (10 d a y s / l 4 0 F ) : S a t i s f a c t o r y VOC, g / l i t e r : 304 lbs./gal.: 2.53 % on Polymer S o l i d s : E t h y l e n e g l y c o l monobutyl e t h e r : 38.5 D i e t h y l e n e g l y c o l monobutyl e t h e r : 4 . 0

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f l a c q u e r w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result.

T h i s c l e a r f o r m u l a t i o n can be used w i t h C o l a n y l p r e d i s p e r s e d c o l o r a n t s t o achieve v a r i o u s c o l o r s .

SOURCE: Rohm and Haas Co.: F o r m u l a t i o n WL-81-3

I n d u s t r i a l C o a t i n g s : RHOPLEX WL-81:

Water-Based Paint Formulations

298

C l e a r Lacauer Based on Rhoplex WL-92 Wood F o r m u l a t i o n M a t e r i a1 s Rhoplex WL-92 (42 w t . % s o l i d s ) P a t c o t e 519 B u t y l Carbi t o 1 Dowanol PNB MichemLUBE 110 (25 w t . % s o l i d s ) Ammonia (14%) t o pH o f 7 . 9 - 8 . 1 Water t o Reduce V i s c o s i t y Formulation Constants: PH: 7 . 9 - 8 . 1 V i s c o s i t y , cps: 400-600 Approximate S o l i d s , % ( w t . / v o l . ) : Density, l b s . / g a l . : 8.5 VOC, g / l i t e r : 234 l b s . / g a l l o n : 1 .95 Weight % on Polymer S o l i d s : B u t y l C a r b i t o l : 20 Dowanol PNB: 10

*

Polymer

Weight* (Pounds 1 705.9 1.7 59.3 29.6

28.0

Vol ume lGallons) 82.19 0.24 7.41 4.05 3.38

22.7

2.72

__-_

__-_

36/34

U s i n g w e i g h t i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f l a c q u e r . W i t h k i l o g r a m s , 833 l i t e r s w i l l r e s u l t

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-92: F o r m u l a t i o n WL-92-1

Lacquers

C l e a r Lacquer F o r m u l a t i o n for Low Force-Dry Applicat.1P a r t s Per Hundred Materials: Rhoplex WL-96 ( 4 2 % ) P a t c o t e 519 B u t y l Cel l o s o l v e MichemLUBE 110 ( 2 5 % s o l i d s ) Water

*

W e i q h t ( Vo 1ume Ba s is )

630.8 1.7 93.0 27.7 86.3

73.18 0.24 12.37 3.34 10.36

Formulation Constants: PH:

8.0

V i s c o s i t y , c p s : 600 Approximate S o l i d s , % ( w t . , v o l . ) : 3 3 , 3 0 Density, l b s . / g a l . : 8 . 4 Freeze/Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat/Age S t a b i l i t y (140F/10 d a y s ) : S a t i s f a c t o r y VOC, g / l i t e r : 261 lbs./gal.: 2.18 % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 35

*

U s i n g w e i g h t i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f l a c q u e r . Weight u n i t s o f k i l o g r a m s y i e l d 8 3 3 1 it e r s .

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-96: F o r m u l a t i o n WL-96-1

299

300

Water-Based Paint Formulatiom

C l e a r Waterborne Lacquer, F l a t t e d to 40 Based on RhoDlex CL-103 Emu1s i on f o r A i r - D r y o r Low-Force-Dry ApD1 ic a t i o n Materials: Rhopl ex CL-103 emu1 s i on Dee Fo 3000

Weight Pounds 655.0 1.3

Volume Gal 1ons 75.9 0.2

52.4 26.2 10.5 29.6

6.6 3.6 0.6 3.6

Premix and add under a g i t a t i o n : B u t y l Carbi t o 1 B u t y l Propasol Degussa T S - 1 0 0 Water Add : 26.2 3.9 Dow C o r n i n g # I 4 Michem Emulsion 39235 22.4 2.7 2.0 0.2 14% Ammon ia ( a d j u s t v i s c o s i t y w i t h w a t e r t o a range o f 20 t o 26 seconds on a #2 Zahn cup) Water 22.5 2.7 Formulation Constants: Approximate s o l i d s , % ( w t / v o l ) : 34.0131.4 pH: 7 . 5 - 8 . 0 V i s c o s i t y , #2 Zahn cup, seconds: 20 t o 26 VOC, g / l i t e r : 272 l b / g a l l o n : 2.27 C o a l e s c e n t , w t % on polymer s o l i d s : B u t y l P r o p a s o l : 10 B u t y l C a r b i t o l : 20 Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g

SOURCE: Rohm and Haas Co.: F o r m u l a t i o n KC-53-2

RHOPLEX CL-103 A c r y l i c Emulsion:

Lacquers

C l e a r Waterborne Lacquer. F l a t t e d t o 40 Gloss a t 60 Based o n RhoDl ex CL-104 E m u l s i o n f o r Low-Force-Dry ADD1 ic a t i o n M a t e r i a1 s : Rhoplex CL-104 e m u l s i o n Dee Fo 3000

Weight Pounds 638.8 1.2

Volume Gal 1ons 74.7 0.2

Premix and add under a g i t a t i o n : B u t y l Carbi t o 1 B u t y l Propasol Degussa TS-100 Water

49.2 24.6 9.8 26.1

6.2 3.3 0.5 3.1

Add : Dow C o r n i n g #14

24.6 3.7 21 .o 2.5 14% Ammoni a 1.9 0.2 ( a d j u s t v i s c o s i t y w i t h w a t e r t o a range o f 20 t o 26 seconds on a #2 Zahn cup) Water 46.3 5.6 M i chem Emul s i on 39235

F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w t / v o l ) : 31.5/29.5 pH: 7.5-8.0 V i s c o s i t y , #2 Zahn cup, seconds: 20 t o 26 VOC, g / l i t e r : 271 l b / g a l l o n : 2.25 C o a l e s c e n t , w t % on polymer s o l i d s : B u t y l C e l l o s o l v e : 10 B u t y l C a r b i t o l : 20 Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes

SOURCE: Rohm and Haas C o . : RHOPLEX CL-104 A c r y l i c Emulsion: F o r m u l a t i o n WR-74-8

301

302

Water-Based Paint Formulations

F l a t B l a c k Lacquer P a r t s p e r Hundred M a t e r ia1 s : Weight R a t i o * ( V o l u m e B a s i s ) Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 612.1 71 . 1 9 Rhoplex WL-81 ( 4 1 . 5 w t % s o l i d s ) Water 65.9 7.91 C o l a n y l B l a c k PR-A 24.5 2.35 Mix w e l l ,

then s i f t i n :

S y l o i d 166

18.8

1.13

Add t h e f o l l o w i n g w i t h good a g i t a t i o n : E t h y l e n e g l y c o l monobutyl e t h e r Texanol Ammonium Benzoate, 10 w t % i n w a t e r Deefo 806-102 (or P a t c o t e 519)

97.9 10.4 23.5 1.4

13.09 1 .32 2.82 0.19

N o t e : I f v i s c o s i t y i s t o o low, a d j u s t up w i t h 14% Ammonia. I f v i s c o s i t y i s t o o h i g h , a d j u s t down w i t h w a t e r . Formulation Constants: PH: 7 . 9 - 8 . 4 V i s c o s i t y , cps: 400-1000 A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 31 . 0 / 2 8 . 7 Density, l b s / g a l l o n : 8.5 Freeze/Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g VOC, g / l i t e r : 330 l b s / g a l l o n : 2.66 Weight % on Polymer S o l i d s : E t h y l e n e g l y c o l monobutyl e t h e r : 3 8 . 6 Texanol: 4.1

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f l a c q u e r w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result.

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-81: F o r m u l a t i o n WL-81-8

Lacquers

Lacquer Type: Busan P r i m e r Substrate: Ferrous Metal Weight R a t i o * Volume R a t i o * M a t e r i a1 s : Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 46.0 6.12 Butyl Cellosolve 137.0 16.44 Water 1.o 0.14 P a t c o t e 519 3.4 0.39 I g e p a l CTA-639 14.8 1 .68 Tamol 165 82.5 1.93 Red I r o n Oxide 68.4 2.49 Busan 11M-1 84.8 3.77 499 T a l c 119.0 3.17 290 Lo-Micron B a r y t e s Pebble m i l l g r i n d t o 7 t o 7 . 5 N . S . Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : Rhoplex WL-91 ( 4 1 . 5 w t %) 420.0 48.72 T r i t o n X-405 ( r e d u c e d t o 35 w t % s o l i d s ) 9.9 1.08 26.2 3.27 B u t y l Carbi t o 1 17.4 1.99 Di b u t y l p h t h a l a t e 41.5 5.52 Butyl Cellosolve 6.8 0.85 14% Ammonia t o pH 9 . 0 - 9 . 3 20.9 2.51 Ammonium Benzoate ( 1 0 w t % i n w a t e r ) A d j u s t v i s c o s i t y w i t h w a t e r (200-600 c p s ) Formulation Constants: Approximate S o l i d s , % ( w t / v o l ) : 51/34 P i gment/Bi n d e r Rat i0 : 65/35 Pigment Volume C o n t e n t , %: 3 4 . 8 pH: 9 . 0 - 9 . 3 V i s c o s i t y , c p s : 200-600 D e n s i t y , l b s / g a l : 11 . O VOC, g / l i t e r : 276 , l b s / g a l l n n : 2.30 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 50 B u t y l C a r b i t o l : 15 D i b u t y l p h t h a l a t e : 10 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be o b t a i ned.

SOURCE: Rohm and Haas Co.: F o r m u l a t i o n WL-91-2

RHOPLEX WL f o r A c r y l i c Lacquers:

303

Water-Based Paint Formulatiom

304

Lacquer Type: Chromate-Free S u b s t r a t e : M e t a l and O t h e r S u b s t r a t e s Materials: Weight R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : E p o t u f 38-690 27.5 3.27 Triethylamine 2.4 0.40 Aq ua c a t 1. o 0.12 Magnacat 1 .o 0.13 Butyl Cellosolve 13.9 1 .85 Add i n o r d e r and m i x w e l l : Water 129.2 15.50 Tamol 165 2.7 0.31 P a t c o t e 550 0.5 0.07 Raven 2000 33.8 2.32 P e b b l e m i l l g r i n d t o 7 t o 7 . 5 N . S . Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 148.1 17.63 1 E p o t u f 38-690 Triethylamine ) Premix 12.1 2.00 15.50 129.2 Water ) Mix w e l l (recheck g r i n d ) , good a g i t a t i o n :

t h e n add t h e f o l l o w i n g i n o r d e r w i t h

Rhoplex WL-81 ( 4 1 . 5 w t %) T r i t o n X-405 ( r e d u c e d t o 35 w t %) S a n t i c i z e r 160 Ammonium Benzoate ( 1 0 w t % i n w a t e r ) Water

287.4 4.8 23.7 24.0 8.3

33.26 0.55 2.53 2.88 1 .oo

Formulation Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 36/33 pH: 8 . 9 V i s c o s i t y , c p s : 300 E p o t u f 38-690/Rhoplex WL-81 ( w t ) : 51/49 Density, lbs/gal: 8.6 VOC, g / l i t e r : 224 , l b s / g a l l o n : 1.87 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e o b t a i ned.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: Formul a t i on WL-81-5

Lacquers

305

Lacauer Type: Chromate P r i m e r Substrate: Ferrous Metal WeiQht R a t i o * Volume R a t i o * Materials: Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 50.6 6.73 Butyl Cellosolve 148.7 17.84 Water 1.2 0.17 P a t c o t e 519 3.7 0.42 I g e p a l CTA-639 16.1 1.89 Tamol 165 89.5 2.09 Red I r o n Oxide 10.9 0.35 S t r o n t i u m Chromate 3.3 0.12 Zinc Yellow 32.5 1.45 499 T a l c 44.7 1.19 290 Lo-Micron B a r y t e s Pebble m i l l g r i n d t o 7 t o 7.5 N . S . Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 455.8 52.88 Rhoplex WL-91 ( 4 1 . 5 w t %) 21.5 2.46 T r i t o n X-405 ( r e d u c e d t o 35 w t % s o l i d s ) B u t y l Carbi t o 1 28.4 3.55 D i b u t y lp h t h a l a t e 19.0 2.17 Butyl Cellosolve 22.2 2.95 14% Ammonia t o pH 9 . 0 - 9 . 3 7.4 0.92 Ammonium Benzoate, ( 1 0 w t % i n w a t e r ) 22.7 2.72 A d j u s t v i s c o s i t y w i t h w a t e r (200-600 c p s ) F o r m u l a t i o n Constants: Approximate S o l i d s , % ( w t / v o l ) : 42/30 pH: 9 . 0 - 9 . 3 Pigment Volume C o n t e n t , %: 1 8 . 4 D e n s i t y , 1b s / g a l : 9 . 8 VOC, g / l i t e r : 279 , l b s / g a l l o n : 2.33 Coalescent, W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 38.5 B u t y l C a r b i t o l : 15 D i b u t y l p h t h a l a t e : 10 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be obtained.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-gl-5

306

Water -Based Paint Formulations

Lac u e r T S u b s t r a t e - ! M-ubstrates

e: Clear

_ M a t e r i a1_ s: ~ Weight R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Rhoplex WL-91 ( 4 1 . 5 w t %) 637.6 73.97 Water 107.9 12.95 P a t c o t e 519 1.5 0.21 Premix and add under a g i t a t i o n : Butyl C e l losolve B u t y l Carbi t o 1 Dibutyl phthala t e BYK-301

79.5 13.2 13.2 1.3

10.57 1 .65 1.51 0.16

F o r m u l a t i o n Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 33/31 pn: 7.2-7.4 V i s c o s i t y , c p s : 200-450 Density, lbs/gal: 8.5 VOC, g / l i t e r : 258 , l b s / g a l l o n : 2.15 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 30 Butyl Carbitol: 5 Dibutylphthalate: 5 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat S t a b i 1 it y (10 d a y s / l 4 0 F ) : S a t i s f a c t o r y Mechanical S t a b i l i t y ( 5 minutes Waring B l e n d e r ) : S a t i s f a c t o r y N o t e : T h i s c l e a r f o r m u l a t i o n can b e used w i t h C o l a n y l p r e d i s persed' c o l o r a n t s t o o b t a i n v a r i o u s c o l o r s .

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e obtained

.

SOURCE: Rohrn and Haas C o . : RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-91-6

Lacquers

Lacquer Type: C l e a r Substrate: P l a s t i c s Wei n h t J b t j o * Vol ume R a t i o * Materials: Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Rhoplex WL-51 ( 4 1 . 5 w t %) 531.4 62.48 138.1 16.57 Water 111.5 14.83 Butyl Cellosolve 22.3 2.79 Butyl Carbit o 1 17.8 2.03 Dibutylphthalate 4.8 0.60 Ammonia ( 1 4%) F o r m u l a t i o n Constants: Approximate S o l i d s , % ( w t / v o l ) : 29/27 pH: 9 . 0 V i s c o s i t y , c p s : 1000 Density, l b s / g a l : 8.4 VOC, g / l i t e r : 361 , l b s / g a l l o n : 3.1 C o a l e s c e n t , W t % on Polymer Sol id s : B u t y l C e l l o s o l v e : 50 B u t y l C a r b i t o l : 10 Dibutylphthalate: 8 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be o b t a i ned.

Red Lacquer f o r P l a s t i c s Based on Rhoplex WL-51: Materials: C l e a r f o r P l a s t i c s (above) C o l a n y l Red FRLL-A

SOURCE: Rohm and Haas Co.: F o r m u l a t i o n WL-51-9

Weight R a t i o 783.3 105.0 RHOPLEX WL f o r A c r y l i c Lacquers:

307

308

Water-Based Paint Formulations

Lacauer Type: C l e a r Subst r a t e : Wood M a t e r i a1 s : Weight R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Rhoplex WL-92 ( 4 2 . 0 w t %) 705.9 82.19 1.7 0.24 P a t c o t e 519 59.3 7.41 B u t y l Carbi t o 1 29.6 4.05 Dowanol PNB M i chemLUBE 110 (25.0% s o l i d s ) 28.0 3.38 ------Ammonia (14%) t o pH o f 7.9-8.1 22.7 2.72 Water t o Reduce V i s c o s i t y F o r m u l a t i o n Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 36/34 PH: 7.9-8.1 V i s c o s i t y , c p s : 400-600 Density, lbs/gal: 8.5 VOC. g / l i t e r : 234 , l b s / g a l l o n : 1.95 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C a r b i t o l : 20 Dowanol PNB: 10 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be o b t a i ned.

SOURCE:

Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-92-1

Lacquers

309

Lacquer Type: C l e a r S u b s t r a t e : Wood Weiciht R a t i o * Volume R a t i o * M a t e r i a1 s: Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Rhoplex WL-96 ( 4 2 . 0 w t %) 624.0 72.39 0.21 1.5 P a t c o t e 519 6.55 52.4 B u t y l Carbi t o 1 3.58 26.2 B u t y l Propasol 2.98 24.7 MichemLUBE 110 ( 2 5 w t % s o l i d s ) 3.86 15.5 Water 0.06 14% Ammonia t o pH approx. 8 . 0 0.5 F o r m u l a t i o n Constants: Approximate S o l i d s , % ( w t / v o l ) : 32/30 pH: 8 . 0 V i s c o s i t y , c p s : 600 D e n s i t y , 1b s / g a l : 8 . 5 VOC, g / l i t e r : 235 , l b s / g a l l o n : 1.96 Coalescent, W t % on Polymer S o l i d s : B u t y l C a r b i t o l : 20 B u t y l P r o p a s o l : 10 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be o b t a i n e d .

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-96-7

Water-Based Paint Formulations

310

Lacquer Type: C l e a r ( a n d f o r u s e w i t h p r e d i s p e r s e d c o l o r a n t s ) Substrate: Metal M a t e r i a1 s : WeiAht R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : K e l s o l 3905 240.0 28.07 Aquacat 1.9 0.23 Magnacat 3.8 0.47 P a t c o t e 519 0.9 0.13 P a t c o t e 577 0.9 0.13 28% Ammonia 5.1 0.66 Water 321 . 7 38.60 M i x w e l l ( % n e u t r a l i z a t i o n = 5 8 % , pH=5.8-6.0) Add i n o r d e r , w i t h a g i t a t i o n : 186.7 21.68 Rhoplex WL-71 ( 4 1 . 5 w t %) Water 32.2 3.86 B u t y l Carbit o 1 20.0 2.50 14% Ammonia ( t o pH=8.4) ------_ Water 21.4 2.57 Formulation Constants: Approximate S o l i d s , % ( w t / v o l ) : 31.3/28.2 pH: 8 . 4 V i s c o s i t y , c p s : 300-500 D e n s i t y , 1b s / g a l : 8 . 4 VOC, g / l i t e r : 246 , lbs/gallon: 2.05 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m F r e e z i n g Note

Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l

Cellosolve.

The f o l owi ng Col any1 s e r i e s p i gment d i s p e r s i ons a r e c o m p a t i b l e with t h i s formulation: D e s c r i p t ion Code No P i gment/Bi n d e r Add x Lbs/100 G a l l o n s 16-2010 Green 8G 13/87 70 18-1004 B l a c k PR-A 5/95 40 11-1 109 Y e l l o w OT 13/87 70

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e o b t a i ned.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-71-5

Lacquers

Lacquer Type: C l e a r f o r C o r r o s i o n R e s i s t a n c e S u b s t r a t e : C o m e r and B r a s s Mater ia1 s : Weiqht R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 59.03 508.9 Rhoplex WL-51 ( 4 1 . 5 w t %) 19.78 164.9 Water B u t y l C e l l os01 ve B u t y l Carbi to1 Benzotriazole Dibutylphthalate P a t c o t e 519 Byk-301 Ammonia ( 1 4%)

1 ) Premix

1

105.6 21.2 1.6

14.04 2.65

16.9 0.5 4.1 15.2

1.94 0.15 0.50 1.92

----

F o r m u l a t i o n Constants: Approximate S o l i d s , ?6 ( w t / v o l ) : 29/27 pH: 9 . 0 V i s c o s i t y , c p s : 1000** Density, l b s / g a l : 8.4 VOC, g / l i t e r : 347 , 1bs.gallon: 2.9 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l os01 ve: 50 B u t y l C a r b i t o l : 10 Dibutvlohthalate: 8 Freeze-Thaw S t a b i 1 it y : P r o t e c t f r o m f r e e z i n g Heat S t a b i l i t y (10 days/l40F): S a t i s f a c t o r y

* **

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l 1ons W i t h k i lograms, a p p r o x i mate1y 833 1 it e r s w i 11 be o b t a i ned. V i s c o s i t y may be a d j u s t e d w i t h w a t e r p r i o r t o a p p l i c a t i o n

.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-51-4

311

312

Water-Based Paint Formulations

Lacquer TYDO: Dark Walnut Wining S t a i n Subst r a t e : Wood M a t e r i a1 s : Weisht R a t i o * Vol ume Rat io* Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Rhoplex WL-93 ( 3 4 w t %) Butyl Cellosolve S a n t i c i z e r 160 Deefo 806-102 Water

342.6 70.0 8.8 1.o 69.5

39.84 9.33 0.94 0.12 8.34

Water Calco Calco Calco Calco

330.6 21.8 7.5 3.4 3.4

39.69 1.03 0.37 0.17 0.17

N i g r o s i n e 02P PDR C I D Orange Y Ex. Conc. C I D C r o c e i n S c a r l e t MOS Conc. C I D T a r t a z i n e DE1 Conc.

Formulation Constants: Approximate S o l i d s , % ( w t / v o l ) : 18.6/16.2 pH: 7 . 3 V i s c o s i t y , cps: 20 Density, lbs/gal: 8.6 VOC, g / l i t e r : 338 , l b s / g a l l o n : 2.82 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 60.1 S a n t i c i z e r 160: 7 . 6 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat S t a b i l i t y ( 8 days/140F): S a t i s f a c t o r y

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be o b t a i ned.

Procedure: Wipe d i r e c t l y o n t o wood, o r s p r a y ( a s i s ) o n t o wood; i m m e d i a t e l y wipe o f f excess.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: Formul a t ion WL-93-1 DW

Lacquers

313

Lacquer Type: F l a t B l a c k S u b s t r a t e : M e t a l and O t h e r S u b s t r a t e s Weiqht R a t i o * Volume R a t i o * Materials: Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 612.1 70.84 Rhoplex WL-81 ( 4 1 . 5 w t %) 65.9 7.91 Water 24.5 2.31 C o l a n y l B l a c k PR-A Mix w e l l ,

then s i f t i n :

S y l o i d 166

18.8

1.14

97.9 10.4 23.5 1.4

13.02 1.31 2.82 0.19

Add t h e f o l l o w i n g w i t h good a g i t a t i o n : B u t y l C e l l os01 ve Texanol Ammonium Benzoate, (10 w t % i n w a t e r ) Deefo 806-102 ( o r P a t c o t e 519) Note:

I f v i s c o s i t y i s t o o low, a d j u s t up w i t h 14% ammonia. I f v i s c o s i t y i s t o o h i g h , a d j u s t down w i t h w a t e r .

F o r m u l a t i o n Constants: Approximate S o l i d s , % ( w t / v o l ) : 34/30 7.9-8.4 V i s c o s i t y , c p s : 400-1000 Density, l b s / g a l : 8.6 VOC, g / l i t e r : 292 , l b s / g a l l o n : 2.44 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 38.6 Texanol : 4.1 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

PH:

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be o b t a i ned.

SOURCE:

Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-81-8

Water-Based Paint Formulations

314

Lacquer Type: F l a t C l e a r S u b s t r a t e : Wood Materials: Weight R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Rhopl ex WL-81 591 . O 68.40 Water 77.9 9.35 Butyl Cellosolve 94.4 12.56 Texanol 1 .24 9.8 BY K - 30 1 1.2 0.15 P a t c o t e 519 0.37 2.6 S y l o i d 166 F l a t t i n g P a s t e FP-2 7.28 65.4 14% Ammonia t o pH 8 . 4 4.2 0.52 F l a t t i n g P a s t e FP-2: Water T r i t o n X-100 Deefo 806-102 S y l o i d 166

749.1 2.0 9.0 135.4

89.89 0.30 1.08 8.21

Formulation Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 31/28 S y l o i d 166, % ( w t ) : 15 pH: 8 . 4 V i s c o s i t y , c p s : 240 Density, l b s / g a l : 8.5 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l Cellosolve: 38.5 Texanol : 4 . 0 VOC, g / l i t e r : 299 , l b s / g a l l o n : 2.50 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m e t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e o b t a i ned.

SOURCE:

Rohm and Haas C o . : RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-81-6

Lacquers

Lacauer T w e : F u l l Gloss Topcoat S u b s t r a t e : M e t a l and O t h e r S u b s t r a t e s M a t e r i a1 s: Weight R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Water 68.8 8.26 Rhoplex WL-93 ( 3 4 w t %) 552.8 64.20 Butyl Cellosolve 112.8 15.00 14.1 1.51 S a n t i c i z e r 160 BYK-301 0.5 0.06 Dow C o r n i n g A d d i t i v e #14 0.5 0.08 Water 90.6 10.87 Formulation Constants: Approximate S o l i d s , % ( w t / v o l ) : 24/22 pH: 8 . 2 - 8 . 6 V i s c o s i t y , c p : 200 D e n s i t y , 1b s / g a l : 8 . 4 VOC, g / l i t e r : 360 , l b s / g a l l o n : 3.00 Coalescent, W t % on Polymer S o l i d s : B u t y l C e l l s o l v e : 60 S a n t i c i z e r 160: 7 . 5 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be o b t a i ned.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-93-2

315

316

Water-Based Paint Formulations

Lacquer T w e : F u l l G l o s s TODCOat S u b s t r a t e : M e t a l and O t h e r S u b s t r a t e s M a t e r ia1 s : Wei g h t R a t i o * Vol ume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Water 75.7 9.08 Rhoplex WL-93 ( 3 4 w t %) 601.9 69.91 Butyl Cellosolve 81.8 10.88 Butyl Carbi t o 1 5.11 40.9 15.4 S a n t i c i z e r 160 1.65 BYK-301 0.06 0.5 Dow C o r n i n g A d d i t i v e #14 0.5 0.08 27.1 Water 3.25 F o r m u l a t i o n Constants: 27/25 Approximate S o l i d s , % (wt/vo!): pH: 8 . 2 - 8 . 6 V i s c o s i t y , c p s : 200 Density, l b s / g a l : 8.4 VOC, g / l i t e r : 363 , l b s / g a l l o n : 3.03 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 40 B u t y l C a r b i t o l : 20 S a n t i c i z e r 160: 7 . 5 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , 833 l i t e r s w i l l be o b t a i n e d .

SOURCE: Rohrn and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-93-4

Lacquers

317

Lacsuer Type: G l o s s B l a c k Substrate: Metal Weiaht R a t i o * Volume Rat Mater ia1 s : Add t h e f o l l o w i n g w i t h good a g i t a t i o n : K e l s o l 3960 92.3 10 73 2.0 0 24 Aquacat Magnacat 3.8 0 47 0.30 28% Ammoni a 2.3 147.4 17.69 Water 0.13 P a t c o t e 519 0.9 0.13 P a t c o t e 577 0.9 0.95 Raven 420 13.8 Pebble m i l l g r i n d t o 7 t o 7 . 5 N.S. Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 17.93 154.2 K e l s o l 3960 ) 0.49 3.8 28% Ammonia ) Premix 21.90 182.5 Water 1 22.23 191.4 Rhoplex WL-71 ( 4 1 . 5 w t %) 3.95 32.9 Water 2.74 21.9 Butyl Carbi t o 1 _ _ _ _-_-14% Ammonia t o pH 7 . 3 - 7 . 5 F o r m u l a t i o n Constants: Approximate S o l i d s , % ( w t / v o l ) : 33/32 P i g m e n t / B i n d e r R a t i o : 5/95 Pigment Volume C o n t e n t , %: 3 . 2 pH: 7 . 3 - 7 . 5 V i s c o s i t y , c p s : 200-400 D e n s i t y , 1b s / g a l : 8 . 5 VOC, g / l i t e r : 244 , l b s / g a l l o n : 2.04 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g N o t e : Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l C e l l o s o l v e .

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be o b t a i ned.

SOURCE: Rohm and Haas C o . : RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-71-10

Water-Based Paint Formulations

31 8

Lacquer Type: G l o s s B l a c k l c o n t a i n s S t r o n t i u m Chromate1 Substrate: Ferrous Metal M a t e r ia1 s : Weight R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 89.2 10.37 K e l s o l 3960 Aquacat 1.9 0.23 3.7 0.46 Magnacat 28% Ammonia 2.2 0.29 142.5 17.10 Water P a t c o t e 519 0.9 0.13 P a t c o t e 577 0.9 0.13 Raven 420 10.0 0.69 S t r o n t i u m Chromate 10.0 0.32 P e b b l e m i l l g r i n d t o 7 t o 7 . 5 N.S. Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 149.0 17.33 ) K e l s o l 3960 28% Ammonia ) Premix 3.7 0.48 176.4 21 .17 f Water Add i n o r d e r w i t h good a g i t a t i o n : Rhopl ex WL-71 Water B u t y l Carbi t o 1 Water 14% Ammonia ( t o pH=7.3-7.5)

185.0 31.8 21.2 21.2

----

21.49 3.82 2.65 2.54

--_-

F o r m u l a t i o n Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 33/31 P i gment/Bi n d e r R a t i o : 8/92 Pigment Volume C o n t e n t , %: 3 . 3 pH: 7 . 3 - 7 . 5 V i s c o s i t y , c p s : 400-600 Density, lbs/gal: 8.6 VOC, g / l i t e r : 244 , l b s / g a l l o n : 2.04 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g N o t e : Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l

*

Cellosolve.

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e o b t a i ned.

SOURCE: Rohm and Haas Co.: F o r m u l a t i o n WL-71-Q

RHOPLEX WL f o r A c r y l i c Lacquers:

Lacquers

Lacquer Type: G l o s s B l a c k Force-Dry Substrate: Metal M a t e r i a1 s : Weiqht R a t i o * Volume R a t Add t h e f o l owing w i t h good a g i t a t i o n : K e l s o l 3905 89.2 10 43 Aquacat 1.9 0 23 0 46 Magnacat 3.7 28% Ammonia 2.2 0.29 Water 142.5 17.10 P a t c o t e 519 0.9 0.13 P a t c o t e 577 0.9 0.13 Raven 420 13.3 0.91 P e b b l e m i l l g r i n d 7 t o 7 . 5 N.S. Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 149.0 17.43 K e l s o l 3905 ) 3.7 0.48 28% Ammonia ) Premix 176.4 21.17 1 Water N o t e : % N e u t r a l i z a t i o n = 7 0 % , pH=6.0-6.3 Rhoplex WL-71 (41 . 5 w t %) 185.0 21.49 53.0 6.36 Water 21.2 2.66 B u t y l Carbi t o 1 --------14% Ammonia t o pH 7 . 3 - 7 . 5 Formulation Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 32/31 P i g m e n t / B i n d e r R a t i o : 5/95 Pigment Volume C o n t e n t , %: 3 . 0 pH: 7 . 3 - 7 . 5 V i s c o s i t y , cps: 200-400 D e n s i t y , 1b s / g a l : 8 . 5 VOC, g / l i t e r : 243 , l b s / g a l l o n : 2.02 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g N o t e : Reduce f o r s p r a y w i t h 07/13 w a t e r / B u t y l

*

Cellosolve.

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e o b t a i ned.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-71-2

319

320

Water-Bused Paint Formulations

Lacquer Tvpe: G l o s s Green Substrate: Metal Materials: Weight R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Chempol 10-0091 88.2 10.02 Aquacat 1. o 0.12 Magnacat 3.7 0.46 28% Ammonia 1.7 0.22 Water 42.3 17.08 P a t c o t e 519 0.9 0.13 P a t c o t e 577 0.9 0.13 Chrome O x i d e X-1134 38.3 0.87 I m p e r i a1 B r a z i 1 Ye1 l o w X-286C 6.3 0.54 Butyl Cellosolve 5.0 0.66 B u t y l Carbi t o 1 5.0 0.62 P e b b l e m i l l g r i n d t o 7 t o 7.5 N . S . Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : Chempol 10-0091 ) 147.4 16.75 28% Ammonia ) Premix 3.1 0.40 ) 174.5 20.94 Water ( N e u t r a l i z a t i o n = 9 3 % , pH=6.1-6.4) Add i n o r d e r w i t h good a g i t a t i o n : Rhoplex WL-71 ( 4 1 . 5 w t %) 183.1 21.27 Water 52.5 6.30 B u t y l Carbit o 1 16.0 2.00 14% Ammonia ( t o pH 7 . 3 - 7 . 5 ) ------F o r m u l a t i o n Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 34/30 P i g m e n t / B i n d e r R a t i o : 15/83 Pigment Volume C o n t e n t , %: 4 . 8 pH: 7 . 3 - 7 . 5 V i s c o s i t y , c p s : 200-400 D e n s i t y , 1b s / g a l : 8 . 8 VOC, g / l i t e r : 257 , l b s / g a l l o n : 2.14 Freeze-Thaw S t a b i 1i t y : P r o t e c t f r o m f r e e z i n g N o t e : Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l

*

Cellosolve.

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e o b t a i ned.

SOURCE: Rohm and Haas Co.: RHOPLEX WL F o r m u l a t i o n WL-71-8

for

A c r y l i c Lacquers:

Locquers

Lacauer Type: G l o s s P a s t e l Y e l l o w Substrate: Metal Mater ia1 s : Weinht RaVolume Rat Add t h e f o l l o w i n g w i t h good a g i t a t i o n : K e l s o l 3909 88.2 10 20 Aqu ac at 1.9 0 23 3.7 0.46 Magnacat 1.7 0.22 28% Ammoni a 172.3 20.68 Water 0.9 0.13 P a t c o t e 519 0.6 0.09 P a t c o t e 577 40.0 3.23 Hansa Y e l l o w T i -Pure R-900 31 .O 0.93 5.0 0.66 Butyl Cellosolve 5.0 0.62 B u t y l Carbi t o 1 Pebble m i l l g r i n d t o 7 t o 7 . 5 N.S. Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 147.4 17.04 K e l s o l 3909 ) 28% Ammonia ) Premix 3.1 0.40 174.5 20.94 Water 1 Rhopl ex WL-71 B u t y l Carbi t o 1 14% Ammonia ( t o pH 7 . 3 - 7 . 5 )

183.1 16.0 3.8

21.27 2.00 0.47

F o r m u l a t i o n Constants: Approximate S o l i d s , % ( w t / v o l ) : 37/34 P i g m e n t / B i n d e r R a t i o : 22/78 Pigment Volume C o n t e n t , %: 1 3 . 4 pn: 7 . 3 - 7 . 5 V i s c o s i t y , c p s : 200-400 Density, l b s / g a l : 8.8 VOC, g / l i t e r : 237 , l b s / g a l l o n : 1.98 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Note: Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l

*

Cellosolve.

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be obtained.

SOURCE:

Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-71-11

321

Water-Eased Paint Formulations

322

Lacquer Type: Gloss Y e l l o w Substrate: Metal Materials: WeiRht R a t i o * Volume R a t i o * Chempol 10-0091 88.2 10.02 0.12 Aquacat 1 .o Magnacat 3.7 0.46 28% Ammonia 1.7 0.22 Water 142.3 17.08 P a t c o t e 519 0.9 0.13 P a t c o t e 577 0.9 0.13 K r o l o r Y e l l o w KY-7810 58.3 1.77 Y e l l o w I r o n Oxide 3.8 0.11 Butyl Cellosolve 5.0 0.66 B u t y l Carbit o 1 5.0 0.62 Pebble m i l l g r i n d t o 7 t o 7 . 5 N . S . Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : Chempol 10-0091 ) 147.4 16.75 28% Ammonia ) Premix 3.1 0.40 Water ) 174.5 20.94 N o t e : N e u t r a l i z a t i o n = 9 3 % ; pH=6.1-6.4 183.1 21 .27 Rhoplex WL-71 ( 4 1 . 5 w t %) Water 52.5 6.31 B u t y l Carbi t o 1 16.0 2.00 14% Ammonia ( t o pH 7 . 3 - 7 . 5 ) ------F o r m u l a t i o n Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 36/31 P i g m e n t / B i n d e r R a t i o : 20/80 Pigment Volume C o n t e n t , %: 6 . 2 pH: 7 . 3 - 7 . 5 V i s c o s i t y , c p s : 200-400 Density, l b s / g a l : 9.0 VOC, g / l i t e r : 253 , lbs/gallon: 2.11 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g N o t e : Reduce f o r s p r a y w i t h 87/13 w a t e r / B u t y l

*

Cellosolve.

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e o b t a i ned.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-71-3

Lacquers

Lacquer TYDe: Golden Oak Wipina S t a i n S u b s t r a t e : Wood Materials: Wei g h t R a t i o * Vol ume Rat io* Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Rhoplex WL-93 ( 3 4 w t %) 342.6 39.79 70.0 9.31 Butyl Cellosolve 8.8 0.94 S a n t i c i z e r 160 0.13 Deefo 806-102 1 .o 69.5 8.34 Water Water C a l c o N i g r o s i n e 02P PDR Calco C I D Orange Y E x . Conc. C a l c o C I D T a r t a z i n e DB1 Conc.

330.6 3.4 6.9 24.1

39.67 0.17 0.34 1.20

Formulation Constants: Approximate S o l i d s , % ( w t / v o l ) : 18.6/16.2 pH: 7 . 3 V i s c o s i t y , cps: 20 Density, lbs/gal: 8.6 VOC, g / l i t e r : 333 , l b s / g a l l o n : 2.78 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 60.1 S a n t i c i z e r 160: 7 . 6 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat S t a b i l i t y ( 8 d a y s / l 4 0 F ) : S a t i s f a c t o r y

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be obtained.

Procedure: Wipe d i r e c t l y o n t o wood, o r s p r a y ( a s i s ) o n t o wood; i m m e d i a t e l y , wipe o f f excess.

SOURCE:

Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-93-100

323

Water-Based Paint Formulations

324

Lacauer Type: Grey Chromate P r i m e r Substrate: Ferrous Metal Materials: Weight R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t ion : Butyl Cellosolve 50.6 6.73 Water 148.7 17.84 P a t c o t e 519 1.2 0.17 I g e p a l CTA-639 3.7 0.42 16.1 Tamol 165 1.82 T i - P u r e R-900 69.3 2.08 S t r o n t i u m Chromate 10.9 0.35 Zinc Yellow 3.3 0.12 499 T a l c 1.45 32.5 290 Lo-Micron B a r y t e s 44.7 1.19 Pebble m i l l g r i n d t o 7 t o 7 . 5 N.S. Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : Rhoplex WL-91 ( 4 1 . 5 w t %) 52.88 455.8 T r i t o n X-405 ( 3 5 w t %) 2.46 21.5 3.55 28.4 B u t y l Carbi t o 1 2.17 19.0 Dibutylphthalate 2.95 22.2 B u t y l C e l l os01 ve 0.12 1.3 C o l a n y l B l a c k PR-A (35%) 2.72 22.7 10% Ammoni um Benzoate 0.92 7.4 14% Ammonia t o pH=9.0-9.3 A d j u s t v i s c o s i t y w i t h w a t e r (200-600 c p s ) Formulation Constants: Approximate S o l i d s , % ( w t / v o l ) : 40/30 Pigment/Binder R a t i o : 35/65 pH: 9 . 0 - 9 . 3 Density, lbs/gal: 9 . 6 VOC, g / l i t e r : 279 , l b s / g a l l o n : 2.33 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 35 B u t y l C a r b i t o l : 15 D i b u t y l p h t h a l a t e : 10 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be obtained.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-01-8

Lacquers

325

Lacquer Type: Heucophos 202 Red P r i m e 1 ~Substrate: Ferrous Metal M a t e r i a1 s : Weiqht R a t i o ? Volume Rat Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Water 120.2 14 42 0 14 P a t c o t e 519 1. o 0.30 3.2 I g e p a l CTA-639 1.72 15.2 Tamol 165 81 . o 1.89 Red I r o n Oxide 76.2 2.54 Heucophos ZBZ 82.2 3.65 Atomi t e 115.4 3.08 290 Lo-Micron B a r y t e s Pebble m i l l g r i n d t o 7-7.5 N . S . Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g - o r d e r w i t h good a g i t a t i o n : 52.32 451 . O Rhoplex WL-91 ( 4 1 . 5 w t %) 1.09 9.7 Concofoc 690 3.46 27.7 B u t y l Carbi t o 1 1.70 14.9 Dibutylphthalate 8.83 65.5 E k t a s o l v e EEH 1.21 9.7 14% Ammonia t o pH 9 . 0 - 9 . 3 3.18 26.5 Ammonium Benzoate ( 1 0 w t % i n w a t e r ) 0.41 2.7 Dow C o r n i n g A d d i t i v e #14 F o r m u l a t i o n Constants: Approximate S o l i d s , % ( w t / v o l ) : 52/35 P i g m e n t / B i n d e r R a t i o : 65/35 Pigment Volume C o n t e n t , %: 35 pH: 9.0-9.3 V i s c o s i t y , cps : 200-600 D e n s i t y , 1b s / g a l : 11 . O VOC, g / l i t e r : 240 , lbs/gallon: 2.0 C o a l e s c e n t , W t % on Polymer S o l i d s : E k t a s o l v e EEH: 35 B u t y l C a r b i t o l : 15 D i b u t v l o h t h a la t e : 8 Freeze-Thaw S t a b i 1 it y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be obtained.

SOURCE:

Rohm and Haas Co.: RHOPLEX WL Formul a t ion WL-91-9

for

A c r y l i c Lacquers:

Water-Based Paint Formulations

326

Lacquer W o e : H i g h G l o s s Green S u b s t r a t e : M e t a l and O t h e r S u b s t r a t e s Mater ia1 s : WeiQht R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Tamol 165 1 .8 0.20 T r i t o n CF-10 0.3 0.03 P a t c o t e 519 0.3 0.04 Water 23.5 2.82 Butyl Cellosolve 16.5 2.19 Chrome Oxide X-1134 32.9 0.75 Hansa Y e l l o w G-1230 5.4 0.44 Phthalo Blue 0.3 0.02 Pebble m i l l g r i n d t o 7 t o 7.5 N.S. Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : Water 55.6 6.67 Rhoplex WL-91 ( 4 1 . 5 w t %) 615.1 71.36 B u t y l Carbi t o 1 25.7 3.21 51.3 6.82 Butyl Cellosolve Dibutylphthalate 12.8 1.46 BY K - 30 1 1.1 0.14 1.1 0.16 P a t c o t e 519 Dow P a i n t A d d i t i v e #14 1.1 0.17 10% HEI-SCORE-XAB 25.7 3.10 14% Ammonia t o pH=8.8 3.8 0.47 F o r m u l a t i o n Constants: Approximate Sol i d s , % ( w t / v o l ) : 36/32 P i gment/Bi nder R a t i 0 : 12.6/87.4 Pigment Volume C o n t e n t , %: 3.9 pH: 8.8 Density, l b s / g a l : 8.7 VOC, g / l i t e r : 259 , l b s / g a l l o n : 2.16 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 26.6 B u t y l C a r b i t o l : 10.0 D i b u t y l p h t h a l a t e : 5.0 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat S t a b i l i t y (10 d a y s / l 4 0 F ) : S a t i s f a c t o r y G l o s s (20-degree/60-degree): 70/85 Mechanical S t a b i l i t y ( 5 m i n u t e s Waring B l e n d e r ) : S a t i s f a c t o r y

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be obtained.

SOURCE: Rohm and Haas Co.: RHOPLEX W L f o r A c r y l i c Lacquers: F o r m u l a t i o n : WL-91-7

Lncquers

Lacquer Type: Medium G l o s s Toocoat S u b s t r a t e : M e t a l and O t h e r S u b s t r a t e s Materials: Wei q h t R a t i o * Volume Rat1o* Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 8.28 68.8 Water 64.22 552.8 Rhoplex WL-93 ( 3 4 w t %) 15.00 112.8 Butyl Cellosolve 1 .51 14.1 S a n t i c i z e r 160 0.06 0.5 BY K - 30 1 0.06 Dow C o r n i n g A d d i t i v e #14 0.5 90.6 10.87 Water 26.9 2.99 F l a t t i n g P a s t e FP-2 F l a t t i n g P a s t e FP-2: Water T r i t o n X-100 Deefo 806-102 S y l o i d 166

749.1 2.0 9.0 135.4

89.89 0.30 1.08 8.21

Formulation Constants: Approximate S o l i d s , % ( w t / v o l ) : 24/22 P i gment/Bi nder R a t i 0 : 2/98 pH: 8.2-8.6 V i s c o s i t y , cps: 200 Density, l b s / g a l : 9.0 VOC, g / l i t e r : 3.04 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t v l C e l l o s o l v e : 60 S a n i i c i z e r 160: 7 . 5 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be o b t a i ned.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-93-2MG

327

328

Water-Based Paint Formulations

Lacquer Type: Oncor F-31 Pigmented Substrate: Ferrous Metal M a t e r i a1 s : Weisht R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : E p o t u f 38-690 27.5 3.27 Aquacat 1. o 0.12 0.13 Magnacat 1.o Butyl Cellosolve 13.9 1.85 Add i n o r d e r : Triethylamine Water Tamol 165 P a t c o t e 550 Raven 2000 Oncor F-31** Pebble m i l l g r i n d t o 7 t o 7 . 5 N.S. Hegman, f o l l o w i n g o r d e r w i t h good a g i t a t i o n : E p o t u f 38-690 T r i e t h y l ami ne Water

0.40 2.4 15.50 129.2 2.7 0.31 0.07 0.5 2.32 33.8 0.30 10.0 t h e n letdown i n t h e 148.8 12.1 129.2

17.71 2.00 15.50

M i x w e l l ( r e c h e c k g r i n d ) , t h e n add t h e f o l l o w i n g i n o r d e r w i t h good a g i t a t i o n : Rhoplex WL-81 ( 4 1 . 5 w t %) 287.4 33.26 T r i t o n X-405 ( r e d u c e d t o 35 w t %) 4.8 0.55 S a n t i c i z e r 160 23.7 2.53 Ammonium Benzoate ( I O w t % i n w a t e r ) 24.0 2.88 Water 8.3 1 .oo F o r m u l a t i o n Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 37/34 pH: 8 . 9 V i s c o s i t y , c p s : 300 E p o t u f 38-690/Rhoplex WL-81 ( w t ) : 51/49 D e n s i t y , 1b s / g a l : 8 . 6 VOC, g / l i t e r : 223 , l b s / g a l l o n : 1.86 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

* **

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e o b t a i ned. S t r o n t i u m Chromate can b e used i n p l a c e of t h e Oncor F-31.

SOURCE:

Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: Formul a t ion WL-81-4

Lacquers

Lacquer Tyve:

329

P r i m e r ( c o n t a i n s S t r o n t i u m Chromate) Substrate: Ferrous Metal

Wei q h t Rat io* Vol ume Rat io* Materials: Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 15.2 1.72 Tamol 165 1.1 0.16 P a t c o t e 519 3.5 0.40 I g e p a l CTA-639 117.3 14.08 Water 85.3 1.99 Red I r o n Oxide 10.4 0.33 S t r o n t i um Chromate 3.0 0.11 Zinc Yellow 4.08 91.8 499 T a l c 128.8 3.44 290 Lo-Micron B a r y t e s Cowles g r i n d t o 7 t o 7.5 N.S. Hegman, t h e n 1etdown i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 437.3 50.91 Rhoplex WL-92 (42.0 w t % ) : 10.4 1.19 T r i t o n X-405 ( r e d u c e d t o 35 w t %) 27.5 3.66 Butyl Cellosolve 3.44 27.5 Butyl Carbi t o 1 1.15 9.2 Dowanol DPM 22.1 2.65 10% Ammonium Benzoate i n Water ---14% Ammonia t o pH=7.9-8.1 A d j u s t v i s c o s i t y w i t h A c r y s o l ASE-60 79.2 9.48 (5% i n w a t e r , pH=9.2)

_---

F o r m u l a t i o n Constants: Approximate S o l i d s , % ( w t / v o l ) : 48/33 Pigment/Binder R a t i o : 63/37 Pigment Volume C o n t e n t , %: 31 pH: 7.9-8.1 V i s c o s i t y , cps: 400-600 D e n s i t y , l b s / g a l : 10.8 VOC, g / l i t e r : 168 , l b s / g a l l o n : 1.40 C o a l e s c e n t , W t % on Polymer Sol i d s : B u t y l C e l l o s o l v e : 15 B u t y l C a r b i t o l : 15 Dowanol DPM: 5 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat S t a b i l i t y (8 d a y s / l 4 0 F ) : S a t i s f a c t o r y

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be obtained.

SOURCE: Rohm and Haas Co.: F o r m u l a t i on WL-92-4

RHOPLEX WL f o r A c r y l i c Lacquers:

Water -Based Paint Formulations

330

Lacquer Type:

P r i m e r ( c o n t a i n s S t r o n t i u m Chromate) Substrate: Ferrous Metal

M a t e r i a1 s : Weiqht R a t i o * Vol ume Rat io* Add t h e f o l l o w i n g w i t h good a g i t a t ion : Butyl Cellosolve 50.3 6.69 Water 23.8 2.86 P a t c o t e 519 1.6 0.23 I g e p a l CTA-639 0.29 2.6 Tamol 165 11.1 1 .26 Red I r o n Oxide 118.6 2.77 S t r o n t i u m Chromate 14.3 0.46 Zinc Yellow 4.2 0.15 499 T a l c 42.9 1.91 290 Lo-Micron B a r y t e s 59.3 1.58 Cowles g r i n d t o 7 t o 7 . 5 N.S. Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 596.1 69.39 Rhoplex WL-92 ( 4 2 . 0 w t %) 14.3 1.63 T r i t o n X-405 ( r e d u c e d t o 35 w t %) B u t y l Carbi t o 1 37.6 4.70 Dibutylphthalate 12.7 1.45 10% Ammonium Benzoate i n Water 33.4 4.00 14% Ammonia t o pH=7.9-0.1 5.3 0.66 A d j u s t v i s c o s i t y w i t h A c r y s o l ASE-60 (5% i n w a t e r , pH=9.2) F o r m u l a t i o n Constants: Approximate Sol i d s , % ( w t / v o l ) : 50/38 Pigment/Binder R a t i o : 49/51 Pigment Volume C o n t e n t , %: 20 PH: 7.9-8.1 V i s c o s i t y , c p s : 200-600 Density, l b s / g a l : 10.3 VOC, g / l i t e r : 214 , l b s / g a l l o n : 1.79 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 20 B u t y l C a r b i t o l : 15 Dibutylphthalate: 5 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat S t a b i l i t y ( 8 d a y s / l 4 0 F ) : S a t i s f a c t o r y

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e obtained.

SOURCE: Rohm and Haas: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-92-5

Lacquers

331

Lacquer Type: S t r o n t i u m Chromate Substrate: Ferrous Metal M a t e r i a1 s : Wei ctht Rat io*Vol ume Rat io* Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 45.0 5.40 Water 10.8 1.22 Tamol 165 1.4 0.16 T r i t o n CF-10 0.4 0.06 P a t c o t e 519 152.0 4.45 T i o n a RCL-9 8.5 0.27 S t r o n t i u m Chromate Cowles g r i n d t o 7 t o 7 . 5 N . S . Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 33.4 4.01 Water 18.0 2.01 T r i t o n X-405 ( 2 5 w t %; pH=8.5-9.0) 556.2 64.38 Rhoplex WL-81 ( 4 1 . 5 w t %) 88.6 11.78 Butyl Cellosolve 17.5 2.08 P a r a p l ex WP-1 0.8 0.11 P a t c o t e 519

**

Add s l o w l y w i t h good a g i t a t i o n : Ammonia (14%) t o p H 7 . 7 - 8 . 3 HEI-SCORE-XAB (10 w t %)

---24.7

2.98

Formulation Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 44/34 P i g m e n t / B i n d e r R a t i o : 40/60 Pigment Volume C o n t e n t , %: 1 4 . 7 pH: 7 . 7 - 8 . 3 V i s c o s i t y , c p s : 100-400 Density, l b s / g a l : 9.7 VOC, g / l i t e r : 235 , l b s / g a l l o n : 1.96 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 38.4 P a r a p l e x WP-1 : 7 . 5 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

* **

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e obtained. I f P a r a p l e x WP-1 i s n o t added a s a p r e m i x , a l l o w 1-2 days f o r t h e p l a s t i c i z e r t o b e absorbed b y t h e l a t e x .

SOURCE:

Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: Formul a t ion WL-81-2

332

Water-Based Paint Formulations

Lacquer Type: S t r o n t i u m Chromate P r i m e r Substrate: Ferrous Metal Materials: Weiqht R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Butyl Cellosolve 10.5 1 .40 Water 147.1 17.65 Tamol 165 12.8 1.45 2.9 0.33 T r i t o n CF-10 Red I r o n O x i d e 65.8 1.54 499 T a l c 129.2 5.74 290 Lo-Mi c r o n B a r y t e s 67.1 1.79 S t r o n t i u m Chromate 15.7 0.50 Cowles g r i n d t o 6 . 5 N.S Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 1 140.7 16.46 K e l s o l 3905 ) 1.3 0.16 Aquacat Magnacat 1 1.2 0.15 ) Premix 1.o 0.14 P a t c o t e 519 P a t c o t e 577 ) 1.o 0.15 28% Ammoni a ) 2.5 0.32 ) 105.0 12.60 Water N o t e : % N e u t r a l i z a t i o n o f t h e p r e m i x i s o n l y 52%, pH 5 . 8 t o 6 . 0 Rhopl ex WL-71 253.5 29.44 T r i t o n X-405 ( r e d u c e d t o 35 w t % s o l i d s ) 9.0 0.98 B u t y l C e l l os01 ve 10.4 1.39 B u t y l Carbit o 1 15.9 1.99 Dibutylphthalate 10.7 1.22 14% Ammonia t o pH 7 . 3 - 7 . 5 3.4 0.42 87/13 W a t e r / B u t y l C e l l o s o l v e 27.8 2.73 Formulation Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 50/37 P i g m e n t / B i n d e r R a t i o : 56/44 Pigment Volume C o n t e n t , %: 27.5 pH: 7 . 3 - 7 . 5 V i s c o s i t y , c p s : 400-600 Density, l b s / g a l : 10.5 VOC, g / l i t e r : 192 , lbs/gallon: 1.80 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g N o t e : Reduce for s p r a y w i t h 87/13 w a t e r / B u t y l

*

Cellosolve.

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e obtained.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-71-1

Lacquers

Lacauer TyPe: S t r o n t i u m Chromate P r i m e r Substrate: Ferrous Metal Weiqht R a t i o * Volume R a t i o * M a t e r i a1 s : Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 46.0 6.12 Butyl Cellosolve 137.0 16.44 Water 0.14 1.o P a t c o t e 519 3.4 0.39 I g e p a l CTA-639 14.8 1.68 Tamol 165 82.5 1.93 Red I r o n Oxide S t r o n t i u m Chromate 15.0 0.48 109.1 4.85 499 T a l c 152.6 4.07 290 Lo-Micron B a r y t e s Pebble m i l l g r i n d t o 7 t o 7.5 N . S . Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : 420.0 48.72 Rhoplex WL-91 (41 .5 w t %) 9.9 1 .13 T r i t o n X-405 ( r e d u c e d t o 35 w t % s o l i d s ) B u t y l Carbi t o 1 26.2 3.27 D i b u t y lp h t h a l a t e 17.4 1.99 Butyl Cellosolve 41 . 5 5.52 14% Ammonia t o pH 9 . 0 - 9 . 3 6.8 0.85 Ammonium Benzoate (10 w t % i n w a t e r ) 20.9 2.51 A d j u s t v i s c o s i t y w i t h w a t e r (200-600 c p s ) F o r m u l a t i o n Constants: Approximate S o l i d s , % ( w t / v o l ) : 51/34 P i g m e n t / B i n d e r R a t i o : 67/33 Pigment Volume C o n t e n t , %: 34.7 pH: 9.0-9.3 V i s c o s i t y , c p s : 200-600 D e n s i t y , 1b s / g a l : 11 .O VOC, g / l i t e r : 279 , l b s / g a l l o n : 2.33 Coalescent, W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 50 B u t y l C a r b i t o l : 15 D i b u t y l p h t h a l a t e : 10 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be o b t a i ned.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: Formul a t i on WL-91-3

333

334

Water-Based Paint Formulations

Lacquer Type: T i n s e l C o a t i n q Substrate: P l a s m M a t e r i a1 s : Weight R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : Rhoplex WL-51 ( 4 1 . 5 w t %) 612.9 71 .18 Water 35.0 4.20 Butyl Cellosolve 109.3 14.54 Dibutylphthalate P a t c o t e 519 BYK-301

12.7 0.4 2.5

1.45 0.06 0.31

Premix t h e f o l l o w i n g and add t o t h e above b l e n d : Stapa H y d r o l a c W 60 n . 1 Butyl Cellosolve B u t y l Carbi t o 1

35.9 17.8 25.3

2.98 2.37 3.16

Formulation Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 34/32 pH: 6 . 8 V i s c o s i t y , c p s : 210 , #4 F o r d Cup, seconds: 29 Density, l b s / g a l : 8.5 VOC, g / l i t e r : 359 , l b s / g a l l o n : 2.9 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 50 B u t y l C a r b i t o l : 10 Oibutylpthalate: 5

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e o b t a i ned. N o t e : T h i s recommended f o r m u l a t i o n c o n t a i n s an aluminum pigment t h a t t h e manufacturer c l a i m s i s s t a b i l i z e d a g a i n s t hydrogen g a s s i n g i n aqueous media. The m a n u f a c t u r e r o f t h i s p i g m e n t has suggested g e n e r a l g u i d e l i n e s t o f o r m u l a t e aqueous one-pack c o a t i n g s , and t h i s f o r m u l a t i o n f o l l o w s t h o s e g u i d e l i n e s . However, as c o n d i t i o n s and methods o f use o f t h e s e p r o d u c t s a r e beyond Rohm and Haas' c o n t r o l , t h e y u r g e you t o c o n t a c t t h e aluminum p i g m e n t m a n u f a c t u r e r o r t h e d i s t r i b u t o r f o r f u r t h e r i n f o r m a t i o n and t o adeq u a t e l y t e s t t h i s o r any f o r m u l a t i o n you may d e v e l o p based on t h i s t e c h n o l o g y t o e n s u r e t h a t i t i s s t a b l e f o r i t s i n t e n d e d u s e b e f o r e a d a p t i n g i t f o r commercial purposes.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-51-10

Lacquers

335

Lacquer Type: W h i t e S u b s t r a t e : M e t a l and O t h e r S u b s t r a t e s Weight R a t i o * Volume R a t i o * M a t e r i a1 s : Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 40.0 4.80 Water 10.8 1.22 Tamol 165 1.4 0.16 T r i t o n CF-10 2.0 0.29 P a t c o t e 519 160.0 4.69 T i o n a RCL-9 Cowles g r i n d t o 7 t o 7 . 5 N.S. Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : Water 54.0 6.48 Rhoplex WL-81 ( 4 1 . 5 w t %) 575.0 66.55 91 . o 12.10 Butyl Cellosolve 9.5 1.19 B u t y l Carbit o 1 P a t c o t e 519 1. o 0.14 1.2 0.15 BYK-301 Dow C o r n i n g A d d i t i v e #14 1.2 0.18 Add s l o w l y w i t h good a g i t a t i o n : Ammonia (14%) t o pH 7 . 7 - 8 . 3 HEI-SCORE-XAB (10 w t %)

--24.0

__-2.89

Formulation Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 42/32 P i g m e n t / B i n d e r R a t i o : 40/60 Pigment Volume C o n t e n t , %: 1 5 . 2 pn: 7 . 7 - 8 . 3 V i s c o s i t y , c p s : 300-500 Density, l b s / g a l : 9 . 6 VOC, g / l i t e r : 269 , l b s / g a l l o n : 2.24 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 38 Butyl Carbitol: 4 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t a l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e obtained.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i on: WL-81-1

336

Water-Based Paint Formulations

Lacquer Type: W h i t e S u b s t r a t e : M e t a l and O t h e r S u b s t r a t e s Materials: Weight R a t i o * Volume R a t i o * Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 77.4 8.98 Rhoplex WL-91 ( 4 1 . 5 w t %) Tamol 165 10.0 1 .13 T r i t o n CF-10 1.2 0.14 1 .o 0.14 P a t c o t e 519 T i o n a RCL-9 148.7 4.36 Cowles g r i n d t o 7 t o 7 . 5 N . S . Hegman, t h e n l e t d o w n i n t h e f o l l o w i n g o r d e r w i t h good a g i t a t i o n : Rhoplex WL-91 ( 4 1 . 5 w t %) 459.2 53.27 Water 130.5 15.66 Butyl Cellosolve 78.5 10.44 B u t y l Carbi t o 1 11.2 1.40 Dibutylphthalate 11.2 1.28 Add s l o w l y w i t h good a g i t a t i o n : Ammonia, 14% Ammonium Benzoate,

(10 w t % i n w a t e r )

2.4 22.6

0.30 2.71

Formulation Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 41/31 P i gment/Bi n d e r R a t i o : 39/61 Pigment Volume C o n t e n t , %: 1 4 . 4 pH: 7 . 8 - 8 . 0 V i s c o s i t y , c p s : 300-500 VOC, g / l i t e r : 251 , l b s / g a l l o n : 2.09 Densi t y , 1b s / g a l : 9 . 6 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 41.2 B u t v l Carbit o 1 : 5.9 D i b;tyl p h t h a l a t e : 5 . 9 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l b e o b t a i ned.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c L a c q u e r s : F o r m u l a t i o n WL-91-1

Lacquers

337

Lacauer Type: W h i t e Substrate: P l a s t i c s M a t e r ia1 s : Add t h e f o l l o w i n g Water Tamol 165 T r i t o n CF-10 P a t c o t e 519 T i o n a RCL-9 Cowles g r i n d t o 7 i n g order w i t h Rhoplex WL-96 ( 4 2 B u t y l Cel l o s o l v e Butyl Carbitol Water

Wei g h t R a t i o* Vol ume R a t i o * w i t h good a g i t a t i o n : 29.2 3.50 9.8 1 .ll 1.2 0.14 0.9 0.13 142.7 4.18 t o 7 . 5 N.S. Hegman, t h e n l e t d o w n i n t h e f o l l o w good a g i t a t i o n : w t %) 509.6 59.12 74.9 9.76 21.4 2.67 162.2 19.46

Add s l o w l y w i t h good a g i t a t i o n : Ammonia (14%) t o pH a p p r o x . 8 . 0

-----

-----

F o r m u l a t i o n Constants: A p p r o x i m a t e S o l i d s , % ( w t / v o l ) : 38/28 P i g m e n t / B i n d e r R a t i o : 40/60 Pigment Volume Content, %: 1 5 . 0 pH: 8 . 0 V i s c o s i t y , c p s : 365 D e n s i t y , l b s / g a l : 9.5 VOC, g / l i t e r : 282 , l b s / g a l l o n : 2.35 C o a l e s c e n t , W t % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 35 B u t y l C a r b i t o l : 10 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g

*

U s i n g w e i g h t r a t i o i n pounds w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s . W i t h k i l o g r a m s , a p p r o x i m a t e l y 833 l i t e r s w i l l be obtained.

SOURCE: Rohm and Haas Co.: RHOPLEX WL f o r A c r y l i c Lacquers: F o r m u l a t i o n WL-90-3

338

Wuter-Bused Paint Formulations

Medium Gloss,

F o r c e Dry, Weatherborne Lacquer

Inqredients: Chempol 20-4301 Tamol 165 T r i t o n CF-10 S u r f y n o l 104BC Water T i -Pure R-900

Pounds 75.85 10.11 1 .51 6.07 47.18 131.48

-

White Gal 1ons 8.62 1.15 0.17 0.81 5.66 3.84

Add each i n g r e d i e n t s e p a r a t e l y t o t h e e m u l s i o n u s i n g good a g i t a t i o n . Check f o r s i g n s o f k i c k - o u t o r s e e d i n g b e f o r e a d d i n g t h e pigment. Cowles t o a #7 Hegman w i t h a h i g h speed d i s p e r s a t o r . A d j u s t g r i n d v i s c o s i t y w i t h w a t e r f r o m below i f n e c e s s a r y . L e t down w i t h : Chempol 20-4301 2-butoxyethanol B u t y l Carbi t o 1 Dibutyl phthalate Nuocure CK-10 Water ( h o l d t o a d j u s t v i s c o s i t y )

510.24 41.06 26.20 5.66 1.62 101.21

57.98 5.47 3.30 0.65 0.20 12.15

Premix c o - s o l v e n t s , p l a s t i c i z e r s and d r i e r . Add t h i s m i x t u r e t o t h e v o r t e x o f t h e a g i t a t i n g e m u l s i o n VERY SLOWLY. I f t h e m i x t u r e becomes heavy, add a s m a l l amount o f w a t e r f r o m t h e " a d j u s t v i s c o s i t y . " Check m i x t u r e f o r k i c k - o u t o r s e e d i n g , t h e n add t h e g r i n d t o t h e " l e t down" w i t h good a g i t a t i o n . M i x w e l l and a l l o w t h e p a i n t t o s e t o v e r n i g h t . Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . A v o i d pH v a l u e s above 7 . 6 , as t h i s w i l l cause t h e v i s c o s i t y o f t h e p a i n t t o i n c r e a s e s i g n i f i c a n t l y . Use t h e " a d j u s t v i s c o s i t y " w a t e r t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % b y w e i g h t : 37.11% T o t a l s o l i d s , % by volume: 26.81% W e i g h t / g a l l o n : 9.58 l b s . / g a l . PVC: 1 4 . 3 VOC: 2.01 l b s . / g a l . V i s c o s i t y : 28" #3 Zahn pH: 7 . 3 S u b s t r a t e : 8-1000 CRS Cure: 1 5 ' @ 150F DFT: 1 . 0 - 1 . 2 m i l Gloss, 60: 71 20: 29 Penci 1 Hardness : B-F Impact R e s i s t a n c e , r e v e r s e : Less t h a n 20 i n c h C r o s s h a t c h a d h e s i o n : 100% r e t e n t i o n SOURCE: Freeman Polymers D i v i s i o n : CHEMPOL 20-4301-A

Formulation

Lacquers

339

P i geented Lacauer P a r t s p e r Hundred Wei p h t Rat io* ( V o l ume B a s i s) M a t e r i a1 s : Add t h e f o l l o w i n g w i t h good a g i t a t i o n : 45.0 5.6 Water 1.3 10.8 Tamol 165 1.4 0.2 T r i t o n CF-10 0.1 0.4 P a t c o t e 519 4.6 152.0 Ti02 0.3 8.5 S t r o n t i u m Chromate Letdown as f o l l o w s : Water S u r f a c t a n t XQS-20** Rhopl ex WL-81 E t h y l e n e g l y c o l monobutyl e t h e r P a r a p l e x WP-1*** P a t c o t e 519

33.4 18.0 556.2 88.6 17.5 0.8

4.0 2.2 64.7 11.8 2.1 0.2

24.7

3.0

Add s l o w l y under good a g i t a t i o n : HEI-SCORE-XAB ( l o % ) * * * *

Formulation Constants: pH: 8 . 0 + - 0 . 3 V i s c o s i t y , c p s . : 100 t o 400 A p p r o x i m a t e S o l i d s , % ( w t . , v o l ) : 43, 32.5 Density, l b s / g a l . : 9.6 PVC, %: 15 T i O 2 / B i n d e r R a t i o : 40/60 Freeze/Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Mechanical S t a b i l i t y ( 5 ' Waring B l e n d e r ) : S a t i s f a c t o r y Heat S t a b i l i t y ( 1 0 d a y s / l 4 0 F ) : S a t i s f a c t o r y VOC, g / l i t e r : 220 l b s . / g a l . : 1.83 % on Polymer S o l i d s : E t h y l e n e g l y c o l monobutyl e t h e r : 3 8 . 4 P a r a p l e x WP-1: 7 . 5

*

** *** ****

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f l a c q u e r w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result. Reduced t o 25% s o l i d s ; pH a d j u s t e d t o 8 . 5 - 9 . 0 . I f P a r a p l e x WP-1 i s n o t added a s a p r e m i x , a l l o w 1 t o 2 days f o r t h e p l a s t i c i z e r t o be absorbed b y t h e l a t e x . 10% s o l u t i o n i n w a t e r .

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-81: F o r m u l a t i o n WL-81-2

Water -Based Paint Formulations

340

Pigmented Lacquer--Whi te

Parts Per Hundred Materials: yeeight Ratio* LVolume Basis1 Add the following with good agitation: Water 4.8 40.0 Tamol 165 10.8 1.3 Triton CF-10 1.4 0.2 Patcote 519 2.0 0.2 Ti 02 4.7 160.0 Cowles grind to 7-7 1/2 N.S. Hegman. Then, add the following in order under agitation: Water 6.5 54.0 Rhopl ex WL-81 66.9 575.0 Ethylene glycol monobutyl ether 12.1 91 . o Diethylene glycol monobutyl ether 1.2 9.5 Patcote 519 0.1 1 .o BY K - 301 1.2 0.1 Dow Corning Additive #14 1.2 0.1 Finally, add slowly under agitation: HEI-SCORE-XAB

(lo%)**

24.0

2.9

Formulation Constants: pH: 8 . 0 + - 0 . 3 Viscosity, No. 4 Ford Cup, sec.: 20 to 30 Approximate Solids, % (wt.,vol.): 41,31 Density, lbs./gal.: 9.6 Ti02/Binder Ratio: 40/60 PVC, %: 15 Freeze/Thaw Stability: Protect from freezing Mechanical Stability (5' Waring Blender): Satisfactory Heat Stability (10 days/l40F): Satisfactory VOC, g/liter: 285 (2.4 lbs./gal.) % on Polymer Solids: Ethylene glycol monobutyl ether: 38 Diethylene glycol monobutyl ether: 4

* **

Using weight ratio in pound units will yield approximately 100 gallons of lacquer while with kilograms, 833 liters will result. 10% solution in water. Adjust pH with 14% ammonia.

SOURCE: Rohm and Haas Co.: Industrial Coatings: RHOPLEX WL-81: Formulation WL-81-1

Lacquers

341

Waterborne Pigmented Lacquer White. f o r A i r D r y o r Force Dry Materialsr Water Tamol 165 T r i t o n CF-10 P a t c o t e 519 Zopaque RCL-9 Cowles g r i n d ( 7

-

Weight* (Pounds) 26.6 9.3 1.1 1.o 140.2

Volume (Gallons) 3.19 1.05 0.12 0.14 4.11

499.2 141.2 75.3 21.2 21.3

58.11 16.94 10.29 2.65 2.55

7 1 / 2 N.S.)

Letdown as f o l l o w s : Rhoplex WL-92 (42 w t . % s o l i d s ) Water B u t y l Propasol B u t y l Carbit o 1 10% Ammonium Benzoate i n Water 14% Ammonia t o pH o f 7 . 9 - 8 . 1

----

-____

Formulation Constants: PH: 7 . 9 - 8 . 1 V i s c o s i t y , c p s : 300-500 A p p r o x i m a t e S o l i d s , % ( w t . / v o l . ) : 38/28 Density, l b s . / g a l . : 9.4 P i g m e n t / B i n d e r R a t i o : 39/61 PVC, %: 1 4 . 5 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat S t a b i l i t y ( 8 d a y s / l 4 0 F ) : S a t i s f a c t o r y Mechanical S t a b i l i t y : S a t i s f a c t o r y VOC, g / l i t e r : 281 1b s . / g a l l o n : 2.34 % on Polymer S o l i d s : B u t y l P r o p a s o l : 35 B u t y l C a r b i t o l : 10

*

U s i n g w e i g h t i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f l a c q u e r . W i t h k i l o g r a m s , 833 l i t e r s w i l l r e s u l t .

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-92: F o r m u l a t i o n WL-92-3

Primers

A i r d r v Black Metal Primer Lbs/100 Gal

Inqredient: E k t a s o l v e EP S a n t i c i z e r 160 S u r f y n o l 104H D i e t h y l a m i ne Drew L-475 DSX 1550 Manchem APG Water

56.01 3.93 4.91 14.24 1.96 9.82 9.82 75.67

M i x w e l l t h e n add: P l i o l i t e 7104 (44% s o l i d )

65.84

M i x w e l l t h e n add: Degussa B l a c k #4 ZBZ Z i n c Phosphate

9.82 235.85

G r i n d t o 7 N.S. t h e n add: P l i o l i t e 7104 (44% s o l i d ) S a n t i c i z e r 160 E k t a s o l v e EP Texanol

450.92 20.64 9.82 10.81

Then add: 10% Ammonium Benzoate

19.65

A i r D r y : 20-30 m i n u t e s t o h a n d l e W.P.G.: 10.08

V i s c o s i t y : 40-50 seconds, No. 4 F o r d Cup S o l i d s W t % : 51.54 S o l i d s Vol%: 37.40 VOC: 2.00 l b s / g a l (235 g m / l i t r e ) Pigment B i n d e r 60 degree g l o s s : 10-15% a t 1.2 m i l Age p a n e l 3 t o 7 days b e f o r e t e s t i n g

SOURCE: The Goodyear T i r e 8 Rubber Co.:

Formula #2064-24-90

343

344

Water-Based Paint Formulations

Chromate-Free A n t i - C o r r o s i v e M a t e r i a1 : Water Butyl Cellosolve B u t y l Carbi t o 1 C o l l o i d 226 AMP 95 Nuosept 95 Z i n c Phosphate Busan 11M-1 Tronox CR-800 #4098-D Red Oxide H i g h speed d i s p e r s e r ,

Primer

Lbs. 25.0 15.0 31 . O 5.0 5.0 1. o 40.0 10.0 6.0 13.0

Gals. 3.00 2.00 3.89 0.50 0.50 0.09 1.50 0.36 0.18 0.30

15 m i n u t e s maxi mum.

C o l l o i d 694 Synthemul 40-422 OR-708 (10% s o l u t i o n ) N a t r o s o l 250MR (3% s o l n ) Water

5.0 688.0

5.0 34.0 19.4

10% OR-708 S o l u t i o n : QR-708 (35%) P r o p y l ene G1y c o l Water

0.70 80.00 0.57 4.08 2.32

288 424

288

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 5.8 P e r c e n t S o l i d s , Weight: 45.2 P e r c e n t Sol i d s . Vol m e : 40.7 I n i t i a l V i s c o s i t y , KU: 63-68 Pounds/Gal 1on : 9.02 pH: 8 . 0 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 133.0 S a l t s p r a y r e s i s t a n c e , c o l d r o l l e d s t e e l , 1 . 2 m i l s DFT, 64 h o u r s : B l i s t e r i n g : M i n i m a l (some a t s c r i b e ) Creepage a t S c r i b e : None ( < 1 / 8 i n c h ) O v e r a l l Rust: None SOURCE: R e i c h h o l d Chemica F o r m u l a t i o n 422-0

s,

Inc.:

Waterborne Handbook:

Primers

345

Force Dry Red O x i d e M e t a l Primer Lbs/100 Gal

Inqredient: E k t a s o l v e EP S a n t i c i z e r 160 DSX 1550 S u r f y n o l 104H D i e t h y l a m i ne Water

91.2 6.4 8.0 6.4 8.0 123.2

Mix w e l l , t h e n add t o f o l l o w i n g l a t e x s l o w l y , P l i o l i t e 7104 (44% s o l i d ) Then under a g i t a t i o n , Red Oxide Heubac k 2 02 A t t a g e l 50 M i c a 3000 M i c r o f ine B a r y t e s G r i n d t o 6+

under a g i t a t i o n :

107.2

add:

32.0 112.0 3.2 32.0 88.0

N.S. by sand m i l l :

Premix below, t h e n add t o g r i n P l i o l i t e 7104 (44% s o l i d ) S a n t i c i z e r 160 E k t a s o l v e EP

s Jwly w i t h a g i a t i o n :

462.4 20.8 20.8

M i x w e l l t h e n add: 10% ammonium benzoate

32.0

D r y t i m e : 4 m i n u t e s a t 200 deg F ( a f t e r f l a s h d r y 10 m i n u t e s ) Hardness: I n i t i a l F; A f t e r 24 h o u r s , F t o H 60 degree g l o s s : 20% VOC: 263 l b / g a l l o n (310 g r a m / l i t r e ) W.P.G.: 11.51 V i s c o s i t y : 30-35 seconds, No. 4 F o r d Cup S o l i d s W t % : 48.8 S o l i d s Vol%: 38.2 P i g m e n t / B i n d e r r a t i o : 1.04:l Age p a n e l 3 days b e f o r e t e s t i n g

SOURCE: The Goodyear T i r e & Rubber Co.:

Formula #2064-4-90

346

Water -Bused Paint Formulations

Gray P r i m e r M a t e r i a1 : Kel s o l 3950-826-70 Butoxy E t h a n o l Ammoni um H y d r o x i d e I g e p a l CTA-639 Busperse-39 T i t a n o x 2101 Atomi t e 106 Lo M i c r o n B a r y t e s Raven 1020 B u t r o l 22 Water S t e e l b a l l m i l l t o a 6 Hegman g r i n d .

Gals. 13.61 4.33 0.87 0.55 0.47 1.71 2.46 1.25 0.23 1.82 19.52

199.96 47.16 6.65

23.58 6.28 0.89

t h e n add t o above: 6.73 1.12 3.30 175.05

0.89 0.14 0.44 21 .oo

Letdown : K e l s o l 3950-8G-70 Butoxy E t h a n o l Ammonium H y d r o x i d e Premix under m i l d a g i t a t i o n , Cobalt Hydrocure I 1 Activ-8 Butoxy E t h a n o l Water

Lbs. 115.41 32.52 6.49 4.79 4.84 56.94 55.35 45.30 3.28 60.24 162.61

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 22.0 Pigment/Binder R a t i o : 1 / 1 P e r c e n t Sol i d s , Weight : 49.6 P e r c e n t S o l i d s , Volume: 3 5 . 6 V i s c o s i t y @ 25C, #4 Ford, Secs.: 40-60 Pounds/Gallon: 9 . 8 7 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 365 Pounds/Gallon: 3 . 0 3

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2327-2A

Inc.:

Waterborne Handbook:

Primers

Gray P r i m e r M a t e r i a1 : Kel s o l 3962-B2G-70 Ammoni um H y d r o x i d e Butoxy Ethanol Secondary B u t a n o l T i t a n o x 2101 Lo M i c r o n B a r y t e s 106 OK 412 S i l i c a Raven B l a c k 1020 S t r o n t i u m Chromate 5-1365 Water S t e e l b a l l m i l l t o a 6 Hegman g r i n d . Letdown : Kel s o l 3962-B2G-70 Ammoni um H y d r o x i de C o b a l t Hydrocure I 1 Manganese H y d r o c u r e I 1 Water Butoxy E t h a n o l Secondary B u t a n o l Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : Pigment/Binder R a t i o : 1.03/1 P e r c e n t S o l i d s , Weight: 38.04 P e r c e n t S o l i d s , Volume: 22.48 V i s c o s i t y I3 25C, #4 F o r d , S e c s . : 40-60 Pounds/Gallon: 9.82 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 322.8 Pounds/Gal 1on : 2 . 6 9

SOURCE:

Lbs. 124.94 8.92 8.03 8.03 94.59 151.72 8.03 3.56 22.31 224.89

Gals. 14.53 1.19 1.07 1.19 2.84 4.16 0.44 0.25 0.72 27.00

53.54 5.35 2.49 5.18 307.96 7.13 5.35

6.23 0.72 0.33 0.61 36.97 0.95 0.80

19.9

R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i o n 2340-60-A

347

348

Wafer-Based Paint Formulations

Gray Rust I n h i b i t i v e P r i m e r M a t e r i a1 : Lbs. Water 127.9 Tamol 731 14.1 I g e p a l CTA-639 2.8 Foamaster VL 1.4 Methyl Carbi t o 1 24.0 D o w i c i l 75 0.5 M i x t h e above a t slow speed, t h e n add t h e f o l l o w i n g : T i t a n o x 2101 188.1 Z i n c Y e l l o w Y539-D 9.4 Z i n c Phosphate 50852 28.1 M i c a 325 30.9 Snowf 1ake 117.5 HEC QP4400 0.8 B l a c k T i n t 888-9907 3.8 Cowles g r i n d t h e above 15-20 m i n u t e s t o a 4-5 Hegman. Letdown : A r o l o n 850-W-45 512.0 Butoxy E t h a n o l 44.7 10% S o l u t i o n o f Sodium N i t r i t e 4.0 Ammoni um H y d r o x i de 1 .a Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 3 5 . 2 Pigment/Binder R a t i o : 1 . 8 / 1 . 0 P e r c e n t S o l i d s , Weight: 53.0 P e r c e n t S o l i d s , Volume: 38.2 V i s c o s i t y @ 25C, #4 Ford, Secs.: 18-25 Pounds/Gallon: 1 1 . 1 pH: 8 . 0 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 162 Pounds/Gal 1on : 1 .35

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2154-61A

Inc.:

Waterborne Handbook:

Gals. 15.35 1.53 0.34 0.18 2.89 0.04 5.50 0.34 1.06 1.32 5.22 0.08 0.38 59.12 5.95 0.48 0.24

Primers

Heavy Metal Free Water-Borne Barrier Primer Lbs./100 aal. Beckosol 13-402 Triethylami ne Surfynol 104 B.C. Butyl Cellosolve Secondary Butyl Alcohol

194.0 11.9 8.5 36.6 36.6

Mix 10 minutes Min-U-Si1 10 Vicron 1515 YLO 3288D Talcron MP40-27

Black Tint Base (See Below)

50.2 51 . 3 149.8 12.0 76.9

High Speed Disperse to a 5 N.S. Nuocure 10% Cobalt Nuocure 6% Manganese Exkin #2

0.5 1.8 2.6

Add slowly Deionized Water

Black T i n t Base: Beckosol 13-402 Dimethyl Ethanolamine Surfynol 104 B . C . Butyl Cellosolve Special Black #5 Ball Mill t o a 7+ N.S. Viscosity: 6 6 KU at 25C Wt./gal.: 1 0 . 2 N.V.W.: 4 4 . 6 % N.V.V.: 2 9 . 6 % P/B: 1.52/1 PVC: 0 . 3 5 pH: 8 . 4 VOC, gm/l calculated: 380 SOURCE:

U.S. S i l i c a C o . : Formula IC-104

392.2

L b s . / 1 0 0 aal. 490.8 27.9 2.8 245.4 92.2

349

350

Water-Based Paint Formulations

H i h Q u a l i t S t a i n B l o c k i n Primer IP;2;712 Modiked t o P r e v e w q ) I n r e d i en-tz:ia:er Exp. D i s p e r s a n t QR-681M (35%) C o l l o i d 643 Kadox 515 T i -Pure R-960 Atomi t e Tamol 960 (40%)**

P a r t s Per Hundred Weiqht R a t i o * ( V o l u m e B a s i s ) 48.5 5.82 9.3 1.02 2.0 0.22 12.0 0.26 151 .O 4.59 53.0 2.35 2.2 0.21

Rhoplex MV-23 (43%) B u t y l Carbi t o 1 E t h y l e n e G1y c o l Skane M-8 C o l l o i d 643 NH40H (28%) A c r y s o l TT-615 (30%) ) Premix Water 1 Exp. Rheology Modi f ie r QR-708 (25% i n p r o p y l e n e g l y c o l / H 2 0 ) * * * Water

**

667.0 10.0 28.0 2.0 4.0 4.0 2.0 10.0

76.04 1.25 3.01 0.23 0.44 0.54 0.23 1.20

11 . o 10.3

1.24 1.24

Must b e added l a s t s i n c e e a r l i e r a d d i t i o n t h i c k e n s l i q u i d phase.

PVC: 19.3% Volume s o l i d s : 37.4% I n i t i a l pH/KU/ICI: 9 . 9 / 1 0 4 / . 9 E q u i l i b r a t e d pH/KU/ICI: 9 . 9 / 1 0 5 / . 9

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result

.

Rheology M o d i f i e r QR-708 (25% S o l u t i o n ) : P a r t s Per Hundred Wei a h t Rat io* ( V o l ume E a s i s ) Exp. Rheology M o d i f i e r QR-708 71.4 7.93 P r o p y l e n e G1y c o l 17.2 2.00 Water 11.4 1.37 ***Experimental

SOURCE:

Rohm and Haas Co.: M a i n t e n a n c e C o a t i n g s : RHOPLEX MV-23: F o r m u l a t i o n P-23-18

Primers

351

L a t e x Maintenance P r i m e r

Ammonium h y d r o x i d e (28%) Tamol 850 (30%) T r i t o n CF-10 T i t a n i u m d i o x i d e ( T i - P u r e R-960) Water ground mica, 325 mesh Calcium c a r b o n a t e ( A t o m i t e ) Barium m e t a b o r a t e (Busan 11-M1)

P a r t s Per Weight Hundred R a t i o * ( V o l ume B a s i s ) 155.23 18.63 1.63 0.14 0.84 0.11 0.82 0.11 12.68 1.27 1.99 0.23 135.84 3.98 22.64 0.97 99.62 4.41 90.56 3.31

Letdown : Rhoplex MV-9 (45.5%) Texanol Ethylene g l y c o l Nopco NXZ Sodium n i t r i t e (13.8% i n Water)

541.84 11.95 21.01 0.84 5.43

Mater ia1 s : Water N a t r o s o l 250 MR (100%) NOPCO NXZ

62.31 1 .51 2.26 0.11 0.65

PVC: 32% Volume S o l i d s : 39.5% A d j u s t pH t o 9 . 3 - 9 . 5 w i t h 28% ammonium h y d r o x i d e I n i t i a l V i s c o s i t y : 65 KU

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t ; u s i n g k i l o g r a m s , about 833 l i t e r s w i l l result.

SOURCE:

Rohm and Haas Co.: Maintenance and M a r i n e C o a t i n g s : RHOPLEX A c r y l ic Emu1 s i ons f o r L a t e x Mai ntenance C o a t i n g s : F o r m u l a t i o n P-9-16

352

Water-Based Paint Formulations

L a t e x S t a i n B l o c k i n a Formula

Raw M a t e r i a l : Pounds Gal 1ons Water 102.2 12.27 Nuosept 95 1.5 0.16 Nopcoside N-96 5.2 0.50 Nopcosperse 44 10.2 1 .oo I g e p a l CO-630 2.2 0.25 T i t a n i u m D i o x i d e R-902 150.0 4.38 Z i n c Oxide 10.0 0.22 BW-100 125.0 5.16 N y t a l 300 40.0 1.68 A t t a g e l 50 0.15 3.0 0.75 AMP 95 6.0 L-475 0.26 2.0 G r i n d t o a minimum o f NS 6 . Add t o t h e l e t d o w n a f t e r g r i n d i s a c h i e v e d and t h e p r e m i x has been added. Use f o r g r i n d a d j u s t m e n t and wash: 20.48 Water 170.6 Premix n e x t 4 i t e m s and add t o t h e g r i n d . 25.8 P r o p y l e n e G1 y c o l Texanol 5.8 OR-708 4.5 N a t r o s o l P1 us 2.1 Letdown : Aquamac 430 L-475

420.8 3.8

Properties: Weight S o l i d s : 49.6% Volume S o l i d s : 34.1% Pgmt Vol Conc: 34.0% V i s c o s i t y : 85-95 KU G l o s s @ 60: 0-5 Lbs/Gals: 10.91 Application: Brush: X Roller: X Spray: X

SOURCE: McWhorter: Suggested Formula Aquamac 430

3.00 0.75 0.50 0.19 47.80 0.50

Primers

353

L a t e x Wood P r i m e r T h i s i s a h i g h performance, t a n n i n s t a i n - b l o c k i n g l a t e x wood p r i m e r based on HALOX BW-100 and Rhoplex MV-23 a c r y l i c l a t e x . The f o r m u l a has been s p e c i f ic a l l y b a l a n c e d w i t h t h e a p p r o p r i a t e w e t t i n g and d i s p e r s i n g a i d s f o r t h e u s e o f HALOX BW-100. I t i s recommended as a g e n e r a l p u r p o s e wood p r i m e r , e s p e c i a l l y o v e r t h o s e woods w h i c h e x h i b i t a t a n n i n s t a i n p r o b l e m such as redwood and c e d a r . I n i t i a l Grind: D i s o e r s e t h e f o l l o w i n a-.. i n o r d e r , m i l l t o a 5 n.s.u. g r i n d :

Water A n t i -foam agent C e l l u l o s i c Thickener NH40H E t h y l e n e G1 y c o l QR-681M D i s p e r s a n t T r i t o n CF-10 T i t a n i um D i o x i d e C a l c i um Carbonate H a l o x BW-100 Z i n c Oxide

on a h i g h speed d i s p e r s i o n Pounds p e r 100 a a l l o n s 124.95 1.70 0.70 1 .oo 30.00 18.20 2.70 150.00 200.00 50.00 10.00

Then l e t down w i t h ( a t l o w speed) Rhopl ex MV-23 Texanol * A r o p l a z 1271 & D r e r s Defoamer Preservative QR-708 T h i c k e n e r Water

440.23 4.75 48.00 1 .oo 2.00 5.50 51 . 1 5

*

Gal l o n s 15.00 0.23 0.06 0.14 3.23 2.00 0.31 4.38 8.86 2.07 0.22

50.00 0.61 5.75 0.13 0.23 0.63 6.15

Premix t h e d r i e r s w i t h t h e A r o p l a z 1271, t h e n s l o w l y add t h i s p r e m i x t u r e t o t h e l e t - d o w n phase under a g i t a t i o n . D r i e r combination: A r o p l a z 1271 93.4% Z i r c o n i u m D r i e r 6% 5.6% C o b a l t D r i e r 6% 0.5% Manganese D r i e r 6% 0.5% PVC: 36.51 Weight p e r g a l l o n : 11.40# S o l i d s b y w e i g h t : 57.83% S o l i d s by volume: 42.54% V i s c o s i t y : 110 Ku @ 75F Pigment: 35.95% b y w e i g h t N o n - v o l a t i l e v e h i c l e : 21.88% by w e i g h t V.O.C.: 161 g/1 133#/ga1

SOURCE: H a l o x Pigments: F o r m u l a t i o n A-81-08A

354

Water -Based Paint Formulations

Lead-Free and Chromate-Free

Primer

Lbs.

Material : Water Ammoni um H y d r o x i d e K e l s o l 3909-BG4-75 Premix d r i e r s and c o s o l v e n t and add t o b a t c h : C o b a l t Hydrocure I 1 A c t iv-8 Butoxy E t h a n o l Manganese Hydrocure Mapico 297 106 Lo M i c r o n B a r y t e s T a l c 399 Halox SW-111 Atomi t e G r i n d t o a 6 Hegman on sand (bead) m i l l . Letdown : Water Ammoni urn H y d r o x i de Kel s o l 3909-864-75 Butoxy E t h a n o l Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P i g m e n t / B i n d e r R a t i o : 1.4/1 P e r c e n t S o l i d s , Weight: 49.5 P e r c e n t S o l i d s , Volume: 34.5 Pounds/Gallon: 10.59 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 227 Pounds/Gallon: 1.89

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 1855-32

.

214.0 8.6 106.9

Gals 25.68 1.14 12.41

4.3 1.6 10.7 4.3 53.6 80.2 26.8 100.0 48.2

0.56 0.20 1.42 0.57 1.24 2.16 1.19 4.20 2.14

214.0 8.6 187.3 10.7

25.69 0.86 21.74 0.75

P e r c e n t : 32.6

I n c . : Waterborne Handbook:

Primers

355

L i g h t Blue Anti-Corrosive Primer C a r g i 11 Water R e d u c i b l e S e l f C r o s s l in k i n g R e s i n 73-7390 Dimethylethanolamine T i t a n i u m D i o x i d e T i - P u r e R-960 Z i n c Phosphate 50852 He1 i o g e n B1ue L 6875 F Special Black 4 A e r o s i l R972 P a t c o t e 577 Dei o n i zed Water

Pounds

Gal l o n s

140.2 10.5 210.7 38.7 0.5 0.7 4.0 2.5 225.0

16.46 1.43 6.52 1.45 0.04 0.05 0.22 0.37 27.01

115.2 5.0 2.5 4.9 25.8 231.9

13.52 0.67 0.37 0.61 3.43 27.85

Sand M i l l t o a 6 Hegman C a r g i 11 Water R e d u c i b l e S e l f C r o s s l in k i n g R e s i n 73-7390 D i m e t h y l e t h a n o l ami ne P a t c o t e 577 D i e t h y l e n e G l y c o l Monobutyl E t h e r E t h y l e n e G l y c o l Monobutyl E t h e r Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 42.71 (By Volume): 28.24 Pigment t o B i n d e r R a t i o : 1 . 4 1 Pigment Volume C o n c e n t r a t i o n : 29.33 Weight Per G a l l o n : 10.18 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.80 ( G r a m s / L i t e r ) : 336 W a t e r : C o s o l v e n t Weight R a t i o : 78.33:21 .67 pH: 8 . 4 - 8 . 5 V i s c o s i t y #4 F o r d Cup (Seconds): 23 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 10 M i n u t e s a t 325F G l o s s ( 6 0 / 2 0 ) : 33/0 P e n c i l Hardness ( D r y F i l m T h i c k n e s s - M i l s ) : 0 . 5 C o l d R o l l e d S t e e l : Pass 3H Z i n c Phosphate T r e a t e d : Pass 6H % C r o s s h a t c h Adhesion: C o l d R o l l e d S t e e l : 100 Z i n c Phosphate T r e a t e d : 100 Impact ( I n . L b s . ) : D i r e c t : 160 Reverse: 90 CRS Z i n c Phosphate T r e a t e d H u m i d i t y (750 Hours) : Unexposed % C r o s s h a t c h Adhesion 100 100 Pass 4H Penci 1 Hardness Pass 2H SOURCE: C a r g i l l ,

I n c . : CARGILL F o r m u l a r y :

Formu a P1887-68E

356

Water-Based Paint Formulations

L i a h t D u t y M a i n t e n a n c e P r i m e r C o n t a i n i n g Busan 11M-1 (P-23-llA M o d i f i e d t o Prevent S e t t l i n a P a r t s Per Hundred Ingredients: Wei a h t Rat iQ* (Vol ume B a s i s 1 Water 125.0 15.00 Methyl Carbit o 1 50.0 5.80 Exp. Rheology Modi f ie r QR-708 (35%) 5.7 0.65 AMP-95 3.0 0.38 C o l l o i d 643 0.22 2.0 T r i t o n X-405 (70%) 2.0 0.22 Exp. D i s p e r s a n t QR-681M (35%) 12.8 1.40 Kadox-515 6.0 0.13 T i -Pure R-902 125.0 3.78 Busan 11-M1 50.0 1.82 117.8 ASP-1 70 5.47 Tamol 960 (40%)** 3.0 0.28 Rhoplex MV-23 (43%) A r o p l a z 1271 t D r i e r s * * * B u t y l Carbi t o 1 C o l l o i d 643 Skane M-8 Sodium N i t r i t e (13.8%) aqueous A c r y s o l TT-615 (30%) ) Premix Water 1 Exp. Rheology Modi f ie r QR-708 (25% in p r o p y l ene g l y c o l /H20) Water

**

****

365.0 37.0 10.0 3.0 2.0 8.0 2.0 10.0

41 . 6 1 4.46 1.25 0.40 0.23 0.96 0.23 1.20

21 . o 101.2

2.37 12.14

Must be added l a s t s i n c e e a r l i e r a d d i t i o n t h i c k e n s l i q u i d phase.

PVC: 35.2% Volume s o l i d s : 31.8% I n i t i a l pH/KU/ICI: 9 . 4 / 1 0 1 / 1 . 7 € q u i 1 ib r a t e d pH/KU/ICI : 9 . 4 / 1 1 7 / 1 . 7

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result A r o p l a z 1271 t D r i e r s : A r o p l a z 1271 93.4% 6% C o b a l t Naphthenate 0.5% 6% Manganese O c t o a t e 0.5% 6% Z i r c o n i um O c t o a t e 5.6% E x p e r i m e n t a l Rheology M o d i f i e r QR-708 (25% S o l u t i o n ) : ( P a r t s Per Hundred) Wei a h t R a t i o * ( V o l ume B a s i si 71.4 7.93 Exp Rheology Modi f ie r QR-708 17.2 2.00 P r o p y l ene G1 y c o l Water 11.4 1.37

***

.

****

.

SOURCE: Rohm and Haas Co.: M a i n t e n a n c e C o a t i n g s : RHOPLEX MV-23: F o r m u l a t i o n P-23-17M

Primers

357

OEM A c r v l ic/Epoxv P r i m e r -~ Pounds Gallons M a t e r i a1 s : A c r y l i c Component A : Grind Preparation: G r i n d t h e f o l l o w i n g m a t e r i a l s u s i n g a h i g h speed d i s s o l v e r f o r 20 minutes: 3.48 30.0 Methyl Carbi t o 1 41 . 1 4.93 Water 1.57 13.8 Tamol 1 6 5 0.14 1.o Ammon ia (28%) T r i t o n CF-10 1.6 0.19 Drew L-405 2.0 0.29 T i P u r e R-900 1.46 50. 0 2.36 Heucophos ZBZ 75. 0 1 .68 Shi e l dex 25 0 131 1 290 B a r y t e s 3.50

Letdown P r e p a r a t ion : Add t h e f o l l o w i n g i n t h e o r d e r l i s t e d and mix h o r o u g h l y : M a i n c o t e A€-58 51 0 0 59.16 Water 20 0 2.40 Ammonia (28% NH3) 1 0 19.60 G r i n d ( f r o m above) 370.6 19.60 E k t a s o l v e EEH 32.3 4.36 1U.L c. IY Water Prooasol B 25 3.38 .. 0 . . -Drew L-493 0.56 4.0 Ammoni a ( 28%) 0.20 1.5 Sodium N i t r i t e (15% aqueous) 8.8 1.06 3.0 Rheology Modi f ie r QR-708 0.34 1.01 8.5 Water

-.

.-

Epoxy Component 8: Genepoxy 370-H55

-

1 , .

~~

~

50.5

5.60

Primer Formulation Constants: Pigment Volume C o n t e n t , %: 2 5 Volume S o l i d s , %: 36 VOC, gm/l: 217 Component A F o r m u l a t i o n C o n s t a n t s : pH: 8 . 5 Stormer V i s c o s i t y , Krebs U n i t s : 85 I C 1 Viscosity, poise: 0.5 Source: Rohm and Haas Co.: Maintenance C o a t i n g s : MAINCOTE AE-58: Formul a t ion P - 5 8 - 3

358

Water-Eased Paint Formulations

Primer F o r m u l a t i o n Materials: P a r t s by weiqht R e s i n WB-408 (80% NVM) 255 T r i e t h y l ami ne 18 A m i no c r o s s 1 in k e r ( 1 ) 36 2 Manganese naphthenate, 6% Dei o n i zed w a t e r 485 Carbon b l a c k ( 2 ) 6 94 C a l c i um c a r b o n a t e ( 3 ) ( 1 ) Cyme1 301 ( 2 ) Raven 150 ( 3 ) Vera B l a n c Properties: Pigment/binder r a t i o : 0.42/1 .OO M e l a m i n e / r e s i n r a t i o : 15/85 N o n - v o l a t i l e m a t e r i a l (NVM), w t % : 39 V i s c o s i t y , #4 F o r d cup, sec: 35-45 I n i t i a l pH: 7 . 5 - 8 . 0 Compounding p r o c e d u r e f o r p r i m e r : 1 . S o l u b i l i z e R e s i n WB-408 i n a m i x i n g v e s s e l c o n t a i n i n g a s o l u t i o n o f t r i e t h y l a m i n e and d e i o n i z e d w a t e r . 2 . Charge t h e r e s i n s o l u t i o n , pigments, d r i e r and amino c r o s s l i n k e r t o a p e b b l e m i l l . G r i n d o v e r n i g h t t o a Hegman G r i n d o f 7. 3. A f t e r m i l l i n g , a d j u s t pH t o 7.5-8.0 and #4 F o r d cup v i s c o s i t y t o 35-45 seconds. Performance p r o p e r t i e s o f t h e r m o s e t t i n g p r i m e r ( 1 ) : S u b s t r a t e : 8-37 ( 3 ) : P e n c i l hardness: H Sward hardness: 18 C r o s s h a t c h a d h e s i o n : 58 1 / 8 - i n c h c o n i c a l bend, % p a s s : 100 Impact r e s i s t a n c e , i n - l b : d i r e c t : 80 r e v e r s e : 50 60 g l o s s , %: 46 Mar r e s i s t a n c e : good S a l t s p r a y r e s i s t a n c e , 250 h r : pass 500 h r . : pass S u b s t r a t e : CRS ( 4 ) : P e n c i l hardness: H Sward hardness: 18 C r o s s h a t c h a d h e s i o n : 5B 1 / 8 - i n c h c o n i c a l bend, % p a s s : 100 Impact r e s i s t a n c e , i n - l b : d i r e c t : 80 r e v e r s e : 80 60 g l o s s , %: 48 Mar r e s i s t a n c e : good S a l t s p r a y r e s i s t a n c e , 250 h r : f a i l ( 1 ) Cure c y c l e 20 m i n u t e s a t 177C ( 2 ) Overbake 30 m i n u t e s a t 205C (4) Cold r o l l e d s t e e l panels SOURCE: Amoco Chemical Co.: Water-Borne Bake A l k y d s Based on AMOCO TMA and IPA: T a b l e s 3 & 4

Primers

P r i m e r F o r n u l a t ion ( C o n t a i n s S t r o n t i u m Chromate) M a t e r ia1 s :~ Grind Portion: Butyl Cellosolve Water Tamol 165 T r i t o n CF-10 Red I r o n O x i d e 499 T a l c 290 Lo M i c r o n B a r y t e s S t r o n t i u m Chromate Cowles g r i n d t o 6 1 / 2 N.S.

Pounds

Gallons

10.5 1.40 147.1 17.68 12.8 1.46 2.9 0.32 65.8 1.54 129.2 5.74 67.1 1.88 15.7 0.50 and add t o t h e f o l l o w i n g p r e m i x :

140.7 K e l s o l 3905 1 1.3 Aquacat ) 1.2 Magnacat 1 P a t c o t e 519 ) Premix 1. o 1.o 1 P a t c o t e 577 2.5 28% Ammonia 1 105.0 Water ) ( N e u t r a l i z a t i o n o f t h e p r e m i x only=52%, pH 5 . 8 t o 6 . 0 ) Add i n o r d e r w i t h good a g i t a t i o n : Rhopl ex WL-71 253.5 9.0 T r i t o n X-405 (35% n o n - v o l a t i l e s ) 7.1 Butyl Cellosolve 15.9 B u t y l Carbit o 1 10.7 Dibutyl Phthalate 3.4 28% Ammonia 26.2 W a t e r / B u t y l C e l l o s o l v e 87/13 14% Ammonia ( t o pH 8 . 5 ) 1.8

16.44 0.16 0.16 0.15 0.15 0.33 12.62 29.48 1.03 0.95 1.99 1.22 0.45 3.20 0.23

Formulation Constants: Pounds/gal 1on : 1 0 . 4 N o n - v o l a t i l e s ( W t . ) : 48.4% ( V o l . ) : 34.0% P i g m e n t / B i n d e r R a t i o : 56/44 PVC: 28.6% Rhopl ex WL-71 / K e l s o l 3905: 50/50 pH: 8 . 5 V i s c o s i t y : 400-600 c p s . VOC: 1 . 0 8 l b s . / g a l . SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-71: F o r m u l a t i o n WL-71-1

359

360

Water-Based Paint Formulations

Red Acrvlic/Epoxv

Materials: A c r y l i c Component A : Grind Preparation: Methyl C a r b i t o l Tamol 165 T r i t o n CF-10 Foamaster AP NH40H (28% NH3) Water Heucophos Z8Z M o d i f i e d Z i n c Phosphate B a y f e r r o x 120NM Red I r o n O x i d e Talc

Primer Pounds

Gallons

45.5 10.0 1.o 1.o 1.o 66.0 100.0 75.0 53.0

5.32 1.13 0.11 0.14 0.14 7.92 3.15 1.85 23.60

Letdown P r e p a r a t i o n : Add t h e f o l l o w i n g i n t h e o r d e r l i s t e d and m i x t h o r o u g h l y : Mai n c o t e AE-58 522.7 60.75 G r i n d ( f r o m above) 352.5 22.12 NH40H (28% NH3) 3.4 0.46 Dal pad-A 22.2 2.42 ) premix 11.1 1.40 Texanol ) Foamaster AP 3.0 0.42 A c r y s o l RM-1020 13.0 1.46 Water 33.1 3.97 Sodium n i t r i t e (15% aqueous s o l u t i o n ) 8.0 0.96 Epoxy Component 8 : Genepoxy 370-H55

54.9

6.04

Primer Formulation Constants: Pigment Volume C o n t e n t , %: 21.0 Volume S o l i d s , %: 3 5 . 0 VOC, g m / l : 228 Component A F o r m u l a t i o n C o n s t a n t s : pH: 8 . 5 Stormer V i s c o s i t y , Kreb U n i t s : 89 I C 1 Viscosity, poise: 1.O SOURCE: Rohm and Haas Co.: F o r m u l a t i o n P-58-1

M a i n t e n a n c e C o a t i n g s : MAINCOTE AE-58:

Primers

Red I r o n O x i d e A i r Dry/Bake P r i m e r M a t e r i a1 : Bentone 27 Isopropanol D e i o n i z e d Water D i s p e r s e i n m i l l 15 m i n u t e s : A r o l on 585-W-43 Raven 1255 Oncor M50 B a r y t e s W1430 399 Lo M i c r o n T a l c T r i t o n X405 6% C o b a l t Naphthenate 14% Lead Naphthenate Butoxy Ethanol P o t a s s i urn T r i p o l y p h o s p h a t e Drew L-475 D e i o n i z e d Water P e b b l e m i l l t o 6 Hegman g r i n d . Letdown : A r o l on 585-W-43 Dei o n i zed Water

Lbs. 7.2 7.2 34.0

Gals. 0.51 1.10 4.09

185.0 14.4 46.1 136.5 93.6 6.9 2.0 0.5 9.5 1.3 1.3 114.8

20.77 0.96 1.38 3.75 4.18 0.75 0.26 0.05 1.26 0.13 0.23 13.78

392.0 23.0

44.04 2.76

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 2 9 . 3 P i gment/Bi n d e r R a t i 0 : 1 . 2 / 1 P e r c e n t S o l i d s , Weight: 49.5 P e r c e n t S o l i d s , Volume: 3 5 . 4 V i s c o s i t y @ 25C, #2 Zahn, S e c s . : 18.25 Pounds/Gallon: 10.75 pH: 8.0-8.5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 69 Pounds/Gallon: .60

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 1014-04C

Inc.:

Waterborne Handbook:

361

362

Water-Based Paint Formulations

Red I r o n O x i d e B a k i n g P r i m e r

Lbs.

M a t e r i a1 : Water Ammoni um H y d r o x i d e Kel s o l 3902-864-75

191.51 5.78 95.81

Premix d r i e r and s o l v e n t and add t o above m i x t u r e . Butoxy E t h a n o l 5.00 12% Manganese Cem-all 2.00 Then add t h e f o l l o w i n g , i n o r d e r : 106 Lo M i c r o n B a r y t e s T i -Pure R-902 S t r o n t i u m Chromate 51365 Mapico 297 Novaci t e L-337 Sand m i l l t o 6 Hegman g r i n d . Letdown : Water Ammoni um H y d r o x i d e Kel s o l 3902-864-75 Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P i g m e n t / B i n d e r R a t i o : 1.16/1 P e r c e n t Sol i d s , Wei g h t : 42.8 P e r c e n t S o l i d s , Volume: 28.5 Pounds/Gal 1on : 10.09 pH: 8.2-8.5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 223 Pounds/Gallon: 1 . 8 6

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 1701-47

Gals. 22.99 0.77 10.95 0.66 0.25

102.43 21.98 19.21 28.53 57.58

3.09 0.66 0.62 0.66 2.61

310.46 5.78 167.65

37.27 0.77 19.16

P e r c e n t : 26.3

I n c . : Waterborne Handbook:

Primers

Red I r o n O x i d e B a k i n n P r i m e r

Lbs.

M a t e r i a1 : Water Ammoni um H y d r o x i d e Kel s o l 3909-864-75 Premix d r i e r and s o l v e n t : Manganese H y d r o c u r e Butoxy E t h a n o l 106 Lo M i c r o n B a r y t e s T a l c 399 N o v a c i t e L-337 Mapico 297 T i -Pure R-902 S t r o n t i u m Chromate 51365 Sand m i l l t o a 6 Hegman g r i n d . Letdown : Water Ammoni um H y d r o x i d e Kel s o l 3909-BG4-75 Analysis: Pigment Volume C o n c e n t r a t i o n , P i g m e n t / B i n d e r R a t i o : 1.28/1 P e r c e n t S o l i d s , Weight: 43.4 P e r c e n t S o l i d s , Volume: 29.5 Pounds/Gal 1on: 10.13 pH: 8 . 2 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 212 Pounds/Gallon: 1.76 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i on 1701-10

186.80 5.60 93.40

Gals. 22.42 0.75 10.86

3.74 4.67

0.50 0.63

56.04 56.04 56.04 28.02 28.02 23.35

1.51 2.54 2.54 0.64 0.82 0.76

302.62 5.60 163.45

36.33 0.75 19.00

P e r c e n t : 29.7

Inc.:

Waterborne Handbook:

363

364

Warer-Based Paint Formulations

Red I r o n O x i d e M e t a l P r i m e r Inaredients: Pigment G r i n d : Water M e t h y l C a r b i t o 1 Sol v e n t Dispersant ( 1 ) Nonionic Surfactant ( 2 ) Antifoam (3) Urethane A s s o c i a t i v e T h i c k e n e r ( 4 ) Red I r o n Oxide ( 5 ) C a l c i u m Carbonate ( 6 ) Z i n c Phosphate ( 7 ) L e t Down: Ucar L a t e x 430 (43.0%) Ucar F i l m e r I B T Antifoam (3) Mix: Methyl C a r b i t o l Solvent Ucar T h i c k e n e r SCT-275 Mix: Water Sodi um N i t r i t e Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n

Pounds

Gal 1 ons

133.9 51 .O 17.6 2.2 2.1 17.2 50.0 225.0 50.0

16.08 6.00 2.00 0.25 0.25 2.00 1.17 9.97 1.67

480.5 37.6 2.1

52.80 4.75 0.25

8.5 8.6

1 .oo 1 .oo

4.2

0.50 0.06 0.25

1.o

1.9

Suppl ie r s : D i s p e r s a n t - "Tamol " 165 o r equi Val e n t N o n i o n i c S u r f a c t a n t - " T r i t o n " CF-10 o r e q u i v a l e n t A n t i foam - "Foamex" 1488 o r equi Val e n t Urethane A s s o c i a t i v e T h i c k e n e r - " A c r y s o l " RM-1020 o r equi Val e n t Red I r o n Oxide - R-2899D o r e q u i v a l e n t Calcum Carbonate - "Gamasperse" 6352 o r e q u i v a l e n t Z i n c Phosphate - "Heucophos" ZBZ o r e q u i v a l e n t Paint Properties: Pigment Volume C o n c e n t r a t i o n ( P V C ) , T o t a l S o l i d s , %: by Volume: 35.5 by Weight: 49.9 Viscosity (equilibrated): S t o r m e r , KU: 105 pH, i n i t i a l : 8 . 9 Weight p e r G a l l o n , l b : 10.93 VOC, g / l : 243.2

SOURCE:

%:

36.1

Ucar Emulsion Systems: UCAR L a t e x 430: F o r m u l a t i o n S u g g e s t i o n M-2206

Primers

Red I r o n O x i d e P r i m e r M a t e r i a1 : Water N a t r o s o l 250 Ammonium H y d r o x i d e S u r f y n o l GA Texanol Foamaster R R . I . O . RO-4098 Busan 11M-1 325 M i c a I m s i l A-10 B a r y t e s #1 Cowles g r i n d t o 4-5 Hegman. Letdown : A r o l on 840-W-39 8utoxy Ethanol Water

Lbs. 166.6 2.0 1.9 6.6 2.0 1.9 50.0 50.0 25.0 50.0 175.0

Gals. 20.00 0.19 0.25 0.75 0.25 0.25 1.18 1.82 1 .07 2.27 4.72

491.6 48.8 35.4

56.50 6.50 4.25

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 34.8 Pigment/Binder R a t i o : 1.8/1 P e r c e n t S o l i d s , W e i g h t : 49.7 P e r c e n t S o l i d s , Volume: 31.8 V i s c o s i t y @ 25C, #2 F o r d , S e c s . : 37-42 Pounds/Gal 1on : 11 1 pH: 8 . 3 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 159 Pounds/Gallon: 1 . 3

.

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2124-94

I n c . : Waterborne Handboook:

365

366

Water-Based Paint Formulations

Red I r o n Oxide P r i m e r M a t e r i a1 : Water Ammoni um H y d r o x i de K e l s o l 3960-826-75 Premix : Cobalt Hydrocure I1 Manganese Hydrocure I1 Butoxy E t h a n o l S t r o n t i u m Chromate 5-1365 Mapico 297 106 Lo M i c r o n B a r y t e s T a l c 399 Novaci t e L207A S t e e l b a l l m i l l t o 6 Hegman g r i n d . Letdown : Kel s o l 3960-82G-75 Ammoni um H y d r o x i d e Water Premix and d i s s o l v e c r y s t a l s c o m p l e t e l y : Water P o t a s s i um Dichromate And t h e n add t o t h i s p r e m i x : Ammoni um H y d r o x i de Add p r e m i x s l o w l y on a g i t a t i o n .

Lbs. 165.80 4.15 82.90

Gals. 19.90 0.56 9.60

1.66 3.32 12.44 20.73 41.45 41.45 41.45 41.45

0.22 0.44 1.66 0.65 0.96 1.13 1.84 1.88

145.08 4.97 318.34

16.80 0.66 38.22

41.45 4.15

4.97 0.18

2.49

0.33

Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 26.1 Pigment/Binder R a t i o : 1 . 1 / 1 . O P e r c e n t S o l i d s , Weight: 36.7 P e r c e n t S o l i d s , Volume: 2 4 . 8 V i s c o s i t y @ 25C, #4 F o r d , Secs.: 20-25 Pounds/Gallon: 9 . 7 3 pH: 8.2-8.6 VOC ( e x c l u d i rig w a t e r ) : G r a m s / L i t e r : 240 Pounds/Gallon: 2 . 0

SOURCE:

R e i c h h o l d Chemicals, I n c . : Waterborne Handbook: F o r m u l a t i o n 21 18-74-1

Primers

Red Iron O x i d e P r i m e r w i t h Heucophos ZBZ Application

367

for B r u s h / R o l l e r

Pounds Inaredients: Gallons. Grind Preparation: G r i n d i n Cowles D i s s o l v e r 15 m i n u t e s . Then l e t down a t s l o w e r speed. 63.0 7.56 Water 6.26 52.2 Methyl Carbit o 1 12.3 1.39 Tamol 165 0.34 3.0 T r i t o n CF-10 0.14 Drew L-493 1 .o 1.39 B a y f e r r o x 120NM Red I r o n O x i d e 57.4 9.79 A t o m i t e C a l c i u m Carbonate 221 . o 1.52 Heucophos 202-Modi f i e d Z i n c Phosphate 50.0 Letdown P r e p a r a t i o n : Mai n c o t e HG-54 Texanol Dibutyl Phthalate Drew L-493 NH4OH (28% NH3) Sodium N i t r i t e (15% Aqueous S o l u t i o n ) W a t e r / A c r y s o l RM-1020

510.1 4.0 12.9 3.6 1.7 8.4 69.5

59.43 0.50 1.48 0.50 0.20 1.01 8.10

Formulation Constants: Pigment Volume C o n t e n t , %: 3 5 . 0 Volume S o l i d s , %: 3 6 . 5 pH (pH r a n g e = 8 . 3 - 8 . 7 ) : 8 . 5 Stormer V i s c o s i t y , Krebs U n i t s : 87 I C 1 V i s c o s i t y , poise: 1.7 VOC, g m / l i t e r : 150

SOURCE:

Rohm and Haas Co.: F o r m u l a t i o n P-54-5

M a i n t e n a n c e C o a t i n g s : MAINCOTE HG-54:

368

Water-Based Paint Formulations

R e d I r o n O x i d e P r i m e r w i t h Z i n c PhosDhate f o r A i r l e s s Spray 1 i c a t i on m red ient s : -__ Pounds Gal 1ons Grind Preparation: G r i n d i n Cowles D i s s o l v e r f o r 15 m i n u t e s , t h e n l e t d o w n a t s l o w e r speed. Water 67.2 8.06 Tamol 165 1.31 11.6 T r i t o n CF-10 0.11 1.o Drew L-405 2.5 0.35 NH40H (28% NH3) 1.o 0.13 Red I r o n O x i d e R-2899 1.46 62.4 Atomi t e 156.2 6.92 S i c o r ZNP-M Z i n c Phosphate 28.4 1 .oo

Letdown P r e p a r a t i on : Mai n c o t e HG-54 Texanol Dibutyl Phthalate Drew L-493 NH40H (28% NH3) Water Rheology Modi f ie r QR-708 Sodium N i t r i t e (15% Aqueous S o l u t i o n )

614.9 19.1 19.1 7.0 2.8 17.5 1.o 7.0

71.64 2.41 2.19 0.97 0.39 2.10 0.12 0.84

F o r m u l a t i o n Constants: Pigment Volume C o n t e n t , %: 2 4 . 8 Volume S o l i d s , %: 3 7 . 9 pH (pH r a n g e = 8 . 3 - 8 . 7 ) : 8 . 5 Stormer V i s c o s i t y , Krebs U n i t s : 95 I C 1 V i s c o s i t y , poise: 0.4 VOC, g m / l i t e r : 51 SOURCE:

Rohm and Haas Co.: M a i n t e n a n c e C o a t i n g s : MAINCOTE HG-54: F o r m u l a t i o n P-54-6

Primers

369

Red I r o n O x i d e P r i m e r w i t h Z i n c Phosphate f o r B r u s h / R o l l e r ADpliCatiOtI Pounds Gal l o n s Ingredients: Grind Preoaration: G r i n d i n Cowles D i s s o l v e r f o r 15 m i n u t e s . Then l e t down a t s l o w e r speed. 31.1 3.73 Water 50.0 6.00 Methyl Carbi t o 1 0.94 8.3 Tamol 165 0.11 1 .o T r i t o n CF-10 2.8 0.40 Drew L-405 2.26 20.2 A c r y s o l RM-1020 55.5 1.35 Red I r o n O x i d e R-2899 150.0 6.65 Atomi t e 27.3 0.96 S i c o r ZNP-M Z i n c Phosphate Letdown P r e p a r a t i o n : Mai n c o t e HG-54 Texanol Dibutyl phthalate Drew L-493 NH40H (28% NH3) Sodium n i t r i t e (15% Aqueous S o l u t i o n ) Water

591.5 15.0 15.0 3.4 4.0 7.4 26.9

68.90 1.89 1.72 0.49 0.48 0.89 3.23

Formulation Constants: Pigment Volume C o n t e n t , %: 2 4 . 6 Volume S o l i d s , %: 3 6 . 4 pH (pH r a n g e = 8 . 3 - 8 . 7 ) : 8 . 5 Stormer V i s c o s i t y , Kreb U n i t s : 97 I C 1 Viscosity, poise: 1.9 VOC, g m / l i t e r : 200 SOURCE:

Rohm and Haas Co.: F o r m u l a t i o n P-54-4

Maintenance C o a t i n g s : MAINCOTE HG-54:

370

Water-Based Paint Formulations

Red I r o n Oxide R u s t I n h i b i t i v e P r i m e r (Non-Lead/Non-Chromate) M a t e r i a1 : Lbs. Water 128.58 Foamaster VL 3.04 Tamol 731 23.44 I g e p a l CTA-639 4.09 AMP-95 3.06 A r o p l a z 1271 51.27 C o b a l t Hydrocure I1 1.14 C a l c i um Hydrocem 1.03 Z i r c o n i um Hydrocem .50 M i x a t l o w speed-then add: HEC QP-4400 1.96 Nalzin 2 106.89 Kadox 515 13.51 Atomi t e 190.56 Red I r o n Oxide R-4098 53.93 G r i n d under h i g h shear 15-20 m i n u t e s t o a 6 Hegman g r i n d . Letdown : A r o l o n 820-W-49 493.59 Methyl Carbi t o 1 30.64 B u t y l Carbi t o 1 3.10 B u t y l Carbi t o 1 Acetate 3.10 Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 27.0 Pigment B i n d e r R a t i o : 1.25/1 P e r c e n t S o l i d s , Weight: 59.20 P e r c e n t S o l i d s , Volume: 49.84 V i s c o s i t y @ 25C, KU: 72-76 Pounds/Gallon: 11.15 pH: 8 . 8 - 9 . 2 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 118.8 Pounds/Gal 1on : .99

SOURCE:

R e i c h h o l d Chemicals, I n c . : F o r m u l a t i o n 2130-08-F1

Waterborne Handbook:

Gal s . 15.43 .39 2.71 .47 .39 6.14 .15 .13 .06 .17 3.29 .29 8.47 1.26 56.09 3.60 .39 .38

Primers

371

Red O x i d e P r i m e r C a r g i 11 Water R e d u c i b l e S t y r e n a t e d A1 k y d Copolymer 74-7422 Aqueous Ammonia 28% E t h y l e n e G1 y c o l Monobutyl E t h e r

Byk-301 Byk-020 Atomi t e Blanc F i x I m s i l A-10 Mapico Red 516 Medium Z i n c Phosphate 30852 A e r o s i l R972 D e i o n i z e d Water

Pounds

Gal l o n s

141.3 8.9 26.4 1.3 1.3 68.5 72.7 15.4 70.7 56.5 6.6 224.2

16.72 1. I 8 3.51 0.16 0.18 3.04 1.99 0.70 1.90 2.11 0.36 26.94

70.8 5.2

8.38 0.69

17.4 1.4 1.6 0.7 0.8

2.32 0.18 0.22 0.09 0.10

171 . 2

20.55

72.3

8.68

Sand M i l l t o a 5 Hegman C a r g i l l Water R e d u c i b l e S t y r e n a t e d A l k y d Copolymer 74-7422 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: E t h y l e n e G1 y c o l Monobutyl E t h e r I n t e r c a r 6% C o b a l t I n t e r c a r 6% Z i r c o n i um A c t i v-8 E x k i n No. 2 D e i o n i z e d Water D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment) Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 42.60 (By Volume): 26.47 Pigment t o B i n d e r R a t i o : 1 . 9 3 Pigment Volume C o n c e n t r a t i o n : 3 8 . 2 3 Weight Per G a l l o n : 10.35 T h e o r e t i c a l VOC (Pounds/Gallon: 2.73 ( G r a m s / L i t e r ) : 327 pH: 8.33 V i s c o s i t y #4 F o r d Cup (Seconds): 36 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r D r y Substrate: Cold Rolled Steel P e n c i l Hardness: Pass H 8 % C r o s s h a t c h Adhesion: 80 Dry Time ( M i n u t e s ) : Set t o Touch: 15 Tack F r e e : 22

SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1857-208

372

Water-Based Paint Formulatiom

Red O x i d e P r i m e r

___ Pounds Gal 1ons M a t e r 1 a1 : Part A: €pi-Rez 510 Epoxy R e s i n 130.0 13.50 Red I r o n O x i d e 125.0 2.93 B a r i um S u l p h a t e 282.2 7.70 D i s p e r s e t o t e x t u r e o f 6-7 P . C . S . Add f o l l o w i n g a t reduced speed: Epi-Rez 510 Epoxy R e s i n 32.1 3.34 H e l o x y 8 Epoxy F u n c t i o n a l M o d i f i e r 53.5 7.22 Part 9: € p i - C u r e W50-8535 C u r i n g Agent Glacial Acetic Acid Water

216.0 2.0 334.0

24,80 0.24 40,27

Composite B l e n d : Part A Part 8

622.8 552.0

34.69 65.31

Typical Coating Properties: V i scosi t y : P a r t A : 130 Krebs U n i t s P a r t B: A ( G a r d n e r - H o l d t ) P a r t s A + B: 119 Krebs U n i t s Reduced V i s c o s i t y ( 1 O : l i n w a t e r ) : 80-90 Krebs U n i t s Useable p o t l i f e : 1-2 h o u r s P . V . C . : 23.2% T o t a l Weight S o l i d s : 61.24% T o t a l Vol ume S o l i d s : 45.07% Resi n Composi t i on : Epoxy R e s i n : 49.96% C u r i n g Agent: 50.04% Gal 1ons V o l a t i l e Composition: Pounds 54.58 Water 453.84 0.50 Organic 4.16 SOURCE: S h e l l Chemical C o . :

24-192 Red O x i d e P r i m e r

Primers

373

S t a r t i n g P o i n t F o r m u l a t i o n P-76-1 ( F o r m e r l y WH-2895-C) F o r C e m e n t i t i o u s M e t a l P r i m e r s Based on RHOPLEX MC-76 M a t e r i a1 s: S i l i c a F l o u r 120 P o r t l a n d Cement Type I** RHOPLEX MC-76 (47%) Defoamer*** Water ( f o r s i l i c a f l o u r )

Weight R a t i o *

V-olume R a t i o

200 100 63.8 0.3 90

17.85 7.58 7.25 0.04 10.79

Formulation Constants: S o l i d s c o n t e n t , %: 72.7 Lb. w t . / U . S . g a l . : 15.2 % S o l i d polymer on cement: 30 Aggregate/Cement r a t i o : 2/1

*

** ***

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 36 g a l l o n s . W h i t e o r Gray Type I P o r t l a n d Cement may be used. Recommended defoamers: Nopco NXZ (100% a c t i v e ) ; GE A n t i f o a m #60 (30% a c t i v e ) S t a r t i n g P o i n t F o r m u l a t i o n P-76-2 ( F o r m e r l y WH-2889-J) F o r C e m e n t i t i o u s M e t a l P r i m e r s Based On Rhoplex MC-76

Wei q h t R a t i o * Materials: 56.8 Water T h i c k e n e r (2.5% S o l n . ) * * ) Premix 1.2 Ammonia (28%) 1 1.5 Rhoplex MC-76 619.0 Tenneco Lamp B l a c k ( C o l o r t r e n d 888-9907) 2.0 S i l i c a F l o u r 120 270.0 P o r t l a n d Cement Type I*** 540.0 Defoamer**** 0.4

Y-oJume

Ratio

6.79 0.1 0.2 70.34 0.17 24.11 40.91 0.05

F o r m u l a t i o n Constants: S o l i d s c o n t e n t , %: 72.8 Lb. w t . / U . S . g a l . : 12.8 % Sol i d polymer on cement : 54 Aggregate/Cement r a t i o : 1/2

* ** *** ****

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 116 g a l l o n s . A c r y s o l RM-5 d i l u t e d 1:l w i t h H20 a t t h e l e v e l o f 0.5% on polymer s o l i d s may be s u b s t i t u t e d . A c r y s o l RM-5 i s an e f f i c i e n t t h i c k e n e r t h a t a l s o i m p a r t s improved r h e o l o g y c h a r a c t e r i s t i c s . W h i t e o r g r a y Type I P o r t l a n d cement may be used. Recommended defoamers: Nopco NXZ (100% a c t i v e ) ; GE A n t i f o a m #60 (30% a c t i v e )

SOURCE: Rohm and Haas Co.: Maintenance and M a r i n e C o a t i n g s : RHOPLEX MC-76: F o r m u l a t i on P-76-1 /Formu1 a t i on P-76-2

Water-Based Paint Formulaiions

374

S t a r t i n a P o i n t 45 PVC P r i m e r F o r m u l a t i o n M a t e r ia 1s : Cowles G r i n d : Water B a l a b 3056A Dispersant* A u r a s p e r s e W-7102 T i -Pure R-960 Snowf 1ake Neosil A Letdown : E x p e r i m e n t a l E m u l s i o n E-2189 (40.5%) * * S u r f y n o l 104E E t h y l e n e G l y c o l Monobutyl E t h e r (60% i n H20)

Pounds

Gallons

58.2 6.1 38.7 0.5 138.6 254.1 46.2

7.27 0.82 4.34 0.05 4.22 11 . 2 7 2.13

500.6 2.0

56.48 0.25

101.4

13.17

A d j u s t w i t h 14% NH3 t o pH 8 . 5 . Reduce v i s c o s i t y t o 30 s e c . ( # 2 Zahn Cup) w i t h w a t e r f o r DRC; t o 26 sec. (#2 Zahn Cup) f o r curtain coating. **Surfynol

104E i s r e q u i r e d o n l y f o r c u r t a i n c o a t i n g ,

E t h y l e n e G l y c o l monobutyl e t h e r a t 30% based on p o l y m e r s o l i d s i s recommended t o g i v e maximum f i l m f o r m a t i o n u n d e r m a r g i n a l conditions. F o r m u l a t i o n Constants: PVC: 45% Weight S o l i d s : 57% Volume S o l i d s : 43% pH: 8 . 5 V i s c o s i t y , #2 Zahn Cup: 26 s e c . f o r c u r t a i n c o a t i n g 30 s e c . f o r DRC

*

Dispersant A c r y s o l 1-62 (50%) H20 NH3 (14%)

Parts 30 30 4 ( 1 / 1 c o n c . NH3 (28%)/H20)

SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s Board C o a t i n g s : E x p e r i m e n t a l Emu1s i o n E-2189: F o r m u l a t i o n

Primers

T a n n i n Block P r i m e r / S e a l e r F o r m u l a t i o n T e s t i n g has been c o n d u c t e d o v e r s e v e r a l s t a i n i n g woods, i n c l u d i n g redwood and c e d a r , a s w e l l as wood-base p r o d u c t s commonly used i n b u i l d i n g m a t e r i a l s such as c e i l i n g t i l e s . I n a l l cases t h e t a n n i n b l o c k p r i m e r / s e a l e r based on RAP 213NA p e r f o r m e d e q u i v a l e n t t o t h e i n d u s t r y - l e a d i n g a c r y l i c l a t e x as w e l l as a l e a d i n g s o l v e n t - b o r n e p r i m e r / s e a l e r , b u t a t l o w e r cost. Pounds 235.00 1 .SO 1.oo

Gal 1ons 28.21 0.14 0.13

21 . 5 0 10.00 16.50

2.48 1.14 1.91

4.00 4.00 1.oo

0.48 0.51 0.08

Tronox CR-821 H a l o x BW-100 Durami t e XX-503 ZnO

150.00 50.00 200.00 25.00

4.49 2.07 8.89 0.54

Nopco NDW RAP 213NA

1.oo 425,OO

0.13 50.18

M a t e r i a1 : Water KTPP NOPCO NDW

Propylene Glycol ) Premi x Dowanol PPh g l y c o l e t h e r )And SCT-275 )Add S u r f y n o l 104E AMP-95 Dowi c i 1 75 P r e s e r v a t i v e

T y p i c a l P r o p e r t i e s , A s Formulated: W t . p e r G a l l o n , Lbs.: 11.30 V i s c o s i t y : 74 KU N . V . b y W t . : 55.7% N . V . b y Volume: 40.0% PVC: 39.5% voc : Lbs/Gal - Water: 0 . 9 0 Gm/L - Water: 108

SOURCE: Dow Chemical USA: F o r m u l a t i o n RAP 213NA

375

376

Water-Based Paint Formulations

Tannin S t a i n - B l o c k i n a E x t e r i o r Primer M a t e r i a1 : Water Ethylene Glycol Col l o i d 640 N a t r o s o l 250 MR Colloid 1 1 1 I g e p a l CO-630 Nuosept 95 Tronox CR-800 Halox BW-100 Snowf 1ake N y t a l 300 D i s p e r s e t o 3 NS

slow m i l l ,

Pounds

Gal l o n s

166.6 23.2 2.0 1 .o 18.0 3.0 2.0 100.0 100.0 150.0 50.0

20.00 2.50 0.27 0.09 1.96 0.34 0.21 2.91 4.13 6.67 2.11

7.9 504.0 2.0 1.5

1 .oo 60.00 0.28 0.17

t h e n add:

Texanol 76 RES 4076 Col l o i d 643 SCT 275 Physical Properties: V i s c o s i t y : 77-85 KU pH: 8.60 Weight p e r g a l l o n : 11.02 l b s . % Solids: By w e i g h t : 58.7% By volume: 45.3% PVC: 35.0% VOC: 71 g/1 - w a t e r

SOURCE: Unocal: Formula C-88182-8

Primers

377

T a n n i n S t a i n I n h i b i t i n g L a t e x Wood P r i m e r Weiaht

Volume

100.0 1 .o 1 .o 18.2 2.5 2.5 30.0

12.0 0.1 0.1 2.0 0.3 0.3 3.2

T i t a n i u m D i o x i d e (5) H a l o x BW-100 Snowf 1ake Minex 7

150.0 100.0 100.0 50.0

4.5 4.2 4.4 2.3

S t y r e n e / B u t a d i e n e L a t e x (8) Texanol Nopco NDW SCT 200 T h i c k e n e r Water

405.0 10.0 2.0 10.0 57.4

57.5 1 .o 0.1 1.1 6.9

Inaredient: Water C e l l u l o s i c Thickener (1) Ammoni um H y d r o x i de D i s p e r s a n t (2) I g e p a l CO-630 S u r f y n o l 104E E t h y l e n e G1 y c o l

Raw M a t e r i a l S u p p l i e r s : ( 1 ) Cel l o s i ze QP-4400 o r e q u i v a l e n t SCT 200 A s s o c i a t i v e T h i c k e n e r (2) Tamol 731 D i s p e r s a n t or e q u i v a l e n t (5) U n i t a n e OR-600 o r e q u i v a l e n t (8) Dow L a t e x RAP 213 NA F o r m u l a t i o n Constants: PVC: 35.4 Weight S o l i d s : 57.4 Pigment by W e i g h t : 35.7 VOC: 1.2 ( l b s / g a l )

Weight p e r G a l l o n : 11.2 Volume S o l i d s : 43.5 NVV by W e i g h t : 21.7

SOURCE: H a l o x Pigments: P r e l i m i n a r y F o r m u l a t i o n : AD-87-03

Water-Based Paint Formulations

378

T a n n i n S t a i n I n h i b i t i n a L a t e x Wood P r i m e r Ingredient: Water C e l l u l o s i c Thickener (1) Ammonium H y d r o x i d e O i spersant (2) I g e p a l CO-630 S u r f y n o l 104E Ethylene Glycol

Weight 100.0 1 .o 1 .o 18.2 2.5 2.5 30.0

Volume 12.0 0.1 0.1 2.0 0.3 0.3 3.2

Titanium Dioxide (5) H a l o x BW-100 Snowf 1a k e Minex 7

150.0 150.0 25.0 25.0

4.5 6.2 1.1 1.1

Styrene/Butadiene Latex (8) Texanol A1 k y d Modi f ic a t i o n * Nopco NDW SCT 200 T h i c k e n e r Water

450.0 10.0 24.0 2.0 10.0 90.0

53.3 1.o 2.8 0.1 1.1 10.8

*

A l k y d M o d i f i c a t i o n Blend: Duramac 2400 94.0% Z r Hydrocure 5.0% Co H y d r o c u r e 0.5% Mn H y d r o c u r e 0.5%

Raw M a t e r i a1 Suppl ie r s : ( 1 ) C e l l o s i ze QP-4400 o r Equi Val e n t SCT 200 A s s o c i a t i v e T h i c k e n e r ( 2 ) Tamol 731 D i s p e r s a n t o r E q u i v a l e n t ( 5 ) U n i t a n e OR-600 o r E q u i v a l e n t ( 8 ) RAP 213 S/B L a t e x Formulation Constants: PVC: 3 1 . 6 Weight p e r G a l l o n : 1 0 . 9 Weight S o l i d s : 5 4 . 2 Volume S o l i d s : 40.8 Pigment b y W e i g h t : 32.1 NVV b y W e i g h t : 2 2 . 1 VOC: 1 . 2 ( l b s / g a l ) SOURCE: H a l o x Pigments: P r e l i m i n a r y F o r m u l a t i o n : AD-87-04

Primers

379

Waterbase Acrylic L a t e x P r i m e r Grind: Water Methyl Carbi t o 1 Tamol 165 T r i t o n CF-10 Drew L-493 Red I r o n O x i d e Snowf 1a ke H a l o x SZP-391 Letdown : Mai n c o t e HG-54 Texanol Dibutyl Phthalate Drew L-493 Ammonium H y d r o x i d e 28% Sodium N i t r i t e 10% Water Ucar T h i c k e n e r SCT 200

Lbs/100 G a l s 63.00 52.00 12.00 3.00 1.oo 57.40 255.00 33.00

Grams/Li t e r 75.60 62.40 14.80 3.60 1.20 68.90 306.00 39.60

510.00 4.00 12.90 3.60 1.70 8.40 50.00 7.00

612.00 4.80 15.50 4.30 2.00 10.10 60.00 8.40

Formulation Constants: D e n s i t y l b s / g a l : 10.74 D e n s i t y g / L : 1289.20 % Weight S o l i d s : 5 3 . 2 0 % Volume S o l i d s : 40.00 % PVC: 35.00 V i s c o s i t y : 95-100 KUs @ 77F (25C) VOC: 1.25 l b s / g a l (150g/L) The l a b o r a t o r y t e s t i n g documented h e r e p r o v e s t h a t HALOX SZP-391 i s an e x c e l l e n t c h o i c e f o r u s e i n a c r y l i c l a t e x e m u l s i o n systems such as M a i n c o t e HG-54. HALOX SZP-391 c l e a r l y o u t p e r formed t h e c o m p e t i t i o n i n t e r m s o f c o r r o s i o n p r o t e c t i o n , package s t a b i l i t y and c o s t e f f e c t i v e n e s s .

SOURCE: H a l o x Pigments: S t a r t i n g P o i n t F o r m u l a t i o n

380

Water-Based Paint Formulations

Water-Reducible

A u t o m o t i v e P r i m e r w i t h S t r o n t i u m Chromate Gray

I n q r e d ie n t s : Chempol 10-0453 Byk P-104s S u r f y n o l 1048C E k t a s o l v e EP AMP-95 Water T i P u r e R-900 Raven #14 Powder 5-1365 S t r o n t i u m Chromate

Pounds 103.68 4.40 2.43 14.60 4.87 138.22 132.63 9.73 34.07

Gal l o n s 12.23 0.55 0.32 1.92 0.62 16.59 3.86 0.67 1.07

Premix f i r s t f i v e i n g r e d i e n t s and mix we1 1 . Add w a t e r s l o w l y w i t h a g i t a t i o n . Load m i x t u r e i n t o b a l l m i l l f o l l o w e d by p i g m e n t s . Run i n s t e e l b a l l m i l l t o a #7 Hegman. A d j u s t g r i n d v i s c o s i t y and/or wash m i l l w i t h w a t e r f r o m below. L e t dowm w i t h : Chempol 10-0453 206.03 24.30 Ammonia, 28% 13.63 1.83 15.49 2.04 E k t a s o l v e EP NuoCure CK-10 8.67 1.07 NuoCure Mn 7.23 0.97 8yk 301 0.50 0.06 Water 240.74 28.90 Water ( h o l d t o a d j u s t v i s c o s i t y ) 25.00 3.00 Add ammonia t o t h e r e s i n s l o w l y and w i t h good a g i t a t i o n ; m i x w e l l . Premix c o s o l v e n t , d r i e r s , and Byk 301. Add t h i s m i x t u r e t o t h e n e u t r a l i z e d r e s i n w i t h a g i t a t i o n . M i x w e l l , t h e n add t h e w a t e r s l o w l y w h i l e s t i l l m i x i n g . Add t h i s m i x t u r e t o t h e g r i n d w i t h c o n t i n u e d a g i t a t i o n . M i x w e l l , and a l l o w t h e p a i n t t o s t a n d overnight. Check t h e pH and a d j u s t w i t h ammonia i f necessary. Use t h e "adjust v i s c o s i t y " water t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Note: T h i s c o a t i n g may d i s p l a y q u e s t i o n a b l e s t a b i l i t y p r o p e r t i e s i n t h e f o r m o f phase s e p a r a t i o n , e s p e c i a l l y a t e l e v a t e d temperatures. A d d i t i o n a l c o s o l v e n t (2-butoxyethanol) o r amine (AMP-95) may be r e q u i r e d t o c o r r e c t t h i s problem; however, t h e s e a d d i t i o n s w i l l r a i s e t h e VOC c o n t e n t o f t h e c o a t i ng

.

Properties: T o t a l s o l i d s , % by w e i g h t : 42.12 T o t a l s o l i d s , % by volume: 31.11 W e i g h t / g a l l o n : 9.62 l b s / g a l PVC: 18.00% P i g m e n t / b i n d e r r a t i o : 0.77 VOC - w a t e r : 2.84 l b s / g a l V i s c o s i t y , #2 Zahn cup: 36" pH: 8 . 4 SOURCE: Freeman Polymers D i v i s i on : CHEMPOL 10-0453-A

Formul a t i on

Primers

Water-Reducible

381

A u t o m o t i v e P r i m e r W i t h o u t S t r o n t i u m Chromate Gray

Inaredients: Chempol 10-0453 Byk P-104s S u r f y n o l 104BC AMP-95 Water T i P u r e R-900 Raven #14 Powder

Pounds 104.76 4.45 2.46 14.75 139.66 134.01 9.84

Gal l o n s 12.35 0.56 0.33 1.96 16.77 3.90 0.67

Premix f i r s t f i v e i n g r e d i e n t s and m i x w e l l . Add w a t e r s l o w l y w i t h a g i t a t i o n . Add m i x t u r e i n t o b a l l m i l l f o l l o w e d by t h e pigments. Run i n s t e e l b a l l m i l l t o a #7 Hegman. A d j u s t g r i n d v i s c o s i t y a n d / o r wash m i l l w i t h w a t e r f r o m b e l o w . L e t down w i t h : Chempol 10-0453 208.17 24.55 Ammonia, 28% 13.77 1.85 2-butoxyethanol 15.65 2.08 NuoCure CK-10 0.76 1.08 NuoCure Mn 7.30 0.98 Byk 301 0.50 0.06 Water 243.49 29.23 Water ( h o l d t o a d j u s t v i s c o s i t y ) 25.00 3.00 Add ammonia t o t h e r e s i n s l o w l y and w i t h good a g i t a t i o n ; mix w e l l . Premix c o s o l v e n t , d r i e r s , and Byk 301. Add t h i s m i x t u r e t o t h e n e u t r a l i z e d r e s i n w i t h a g i t a t i o n . M i x w e l l , t h e n add t h e w a t e r s l o w l y w h i l e s t i l l m i x i n g . Add t h i s m i x t u r e t o t h e g r i n d w i t h c o n t i n u e d a g i t a t i o n . M i x w e l l , and a l l o w t h e p a i n t t o stand overnight. Check t h e pH and a d j u s t w i t h ammonia i f n e c e s s a r y . Use t h e " a d j u s t v i s c o s i t y " water t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . P r o p e r t ies : T o t a l s o l i d s , % by w e i g h t : 39.99 T o t a l s o l i d s , % by volume: 30.35 W e i g h t / g a l l o n : 9.37 l b s / g a l PVC: 15.07% P i g m e n t / b i n d e r r a t i o : 0.62 VOC - w a t e r : 2.90 l b s / g a l V i s c o s i t y , #2 Zahn cup: 38" pH: 8.5 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y S e t - t o - t o u c h , mins. : 25 Dust f r e e , m i n s . : 25 Tack f r e e , m i n s . : 60-70 D r y t h r o u g h , h o u r s : 6-8 DFT: 1 . 2 - 1 . 4 m i l G l o s s , 60: 84

SOURCE:

Freeman Polymers D i v i s i on : CHEMPOL 10-0453-8

Formul a t i on

382

Water-Based Paint Formulations

Water R e d u c i b l e , Gray A i r D r y or F o r c e D r y Cure Primer; Lead and Chromate F r e e F o r m u l a t i o n 10-0091-F i s a w a t e r r e d u c i b l e p r i m e r w h i c h may be a i r d r i e d o r f o r c e c u r e d on s t e e l s u b s t r a t e . A p p l i e d c o a t i n g s c u r e r a p i d l y t o p r o d u c e tough, f l e x i b l e and h i g h l y a d h e r e n t f i l m s which have a h i g h o r d e r o f c o r r o s i o n r e s i s t a n c e . I n a d d i t i o n , f o r m u l a t i o n 10-0091-F c o m p l i e s w i t h many proposed Clean A i r r e g u l a t i o n s , c o n t a i n i n g o n l y 2 . 3 pounds o f v o l a t i l e o r g a n i c compounds p e r g a l l o n o f p a i n t ( e x c l u s i v e o f w a t e r ) . Ingredients: Pounds Gal l o n s Chempol 10-0091 83.88 9.53 Ammonium h y d r o x i d e 6.37 0.90 Polycompound W-953 2.49 0.30 N a l c o 2309 2.49 0.30 Water 183.19 21.99 Bykumen 2.49 0.30 Z i n c phosphate 50852 49.75 1.89 T i -Pure R-900 47.75 1.39 Lampblack S u p e r j e t L B - l o l l 2.99 0.20 Atomi t e 59.70 2.69 N y t a l 400 29.85 1.69 Barmite XF 59.70 1.69 EA-1 075 9.95 1.49 Combi ne CHEMPOL 10-0091 and ammonia. Then add Pol ycompound W-953 and N a l c o 2309. Add w a t e r , s t i r w e l l and add Bykumen. Add pigments, EA-1075 and s t i r w e l l . Pebble M i 11 G r i n d 7 Hegman Chempol 10-0091 142.88 16.24 Ammoni um h y d r o x i de 10.85 1.49 Odor1 ess m i n e r a l s p i r i t s 19.90 3.09 Hydrocure c o b a l t d r i e r (5% c o b a l t ) 1.69 0.20 1.69 0.20 Hydrocure manganese d r i e r (5% manganese) A c t iv-8 1 .oo 0.10 E x k i n No. 2 1.99 0.30 Water 279.40 34.02 I n " L e t Down" combine CHEMPOL 10-0091, Ammonium H y d r o x i d e , O d o r l e s s M i n e r a l S p i r i t s , d r i e r s , A c t i v - 8 and E x k i n No. 2 i n o r d e r g i v e n b e f o r e a d d i n g t o t h e m i l l base. F i n a l water a d d i t i o s h o u l d be made s l o w l y w i t h a g i t a t i o n t o p r e v e n t p gment f l o c c u l a t i on and s h o c k i ng. Properties: T o t a l s o l i d s , % b y w e i g h t : 42.54 T o t a l s o l i d s b y volume: 27.34 V i s c o s i t y , Krebs u n i t s : 96 R e d u c t i o n f o r s p r a y a p p l i c a t i o n by volume: 4 p a r t s p a i n t / 1 p a r t water P i g m e n t / b i n d e r w e i g h t r a t i o : 1.00/0.67 PVC, %: 35.86 G1oss (60% G1o s s m e t e r ) : F1a t

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 10-0091-F

Formulation

Primers

Water R e d u c i b l e . Gray. A i r D r y o r F o r c e D r y Cure P r i m e r ; and Chromate F r e e Inqredients: Chempol 10-0095 Ammonium h y d r o x i d e (28% m i n ) P o l ycompound W-953 sec-Butanol N a l c o 2309 Water Bykumen Z i n c Phosphate 5852 T i - P u r e R-900 Lampblack S u p e r j e t L E - l o l l Atomi t e N y t a l 400 B a r m i t e XF EA-1075

Pounds 83.88 6.72 2.49 6.00 2.49 182.84 2.49 49.75 49.75 2.99 59.70 29.85 59.70 9.95

383

Lead

Gal 1ons 9.64 0.95 0.30 0.58 0.30 21.92 0.30 1.89 1.39 0.20 2.69 1.69 1.69 1.49

Combine Chempol 10-0095 and ammonium h y d r o x i d e . Then add P o l y compound W-953, s e c - B u t a n o l and N a l c o 2309. Add w a t e r , m i x w e l l and add Bykumen. Add p i g m e n t s and EA-1075. M i x w e l l . Pebble M i l l G r i n d 7 Hegman L e t down w i t h : Chempol 10-0095 Ammonium h y d r o x i d e (28% m i n ) sec-Butanol Odorless m i n e r a l s p i r it s H y d r o c u r e c o b a l t d r i e r (5% c o b a l t ) H y d r o c u r e manganese d r i e r (5% manganese) A c t i v-8 E x k i n No. 2 Water

142.88 11.45 10.20 19.90 1.69 1.69 1 .oo 1.99 268.55

16.42 1.57 0.98 3.09 0.20 0.20 0.10 0.30 32.20

I n " L e t Down" combine Chempol 10-0095, ammonium h y d r o x i d e , secB u t a n o l , o d o r l e s s m i n e r a l s p i r i t s , d r i e r s , A c t i v - 8 and E x k i n No. 2 i n o r d e r g i v e n b e f o r e a d d i n g t o t h e m i l l base. F i n a l w a t e r a d d i t i o n s h o u l d be made s l o w l y w i t h a g i t a t i o n t o p r e v e n t p i g m e n t f l o c c u l a t i o n and s h o c k i n g . Properties: T o t a l s o l i d s , % by w e i g h t : 42.3 T o t a l s o l i d s , % by volume: 2 8 . 4 Reduction f o r spray a p p l i c a t i o n : 4 p a r t s p a i n t / 1 p a r t water ( b y volume) V i s c o s i t y s p r a y a p p l i c a t i o n , seconds, Zahn #4: 20-23 seconds Pigment/binder weight r a t i o : 1.5/1 . O SOURCE: Freeman Polymers D i v i s i o n : CHEMPOL 10-0095-A

Formula

384

Water-Based Paint Formulations

White AcrylicfEpoxy Primer Materi a1 s i Pounds Gallons Acrylic Comoonent A: Gri nd Preparat i on : Grind the following materials using a high speed dissolver for 20 minutes: Methyl Carbi to1 50.0 6.00 Tamol 165 1.57 13.8 NH40H (28% NH3) 1. o 0.12 Triton CF-10 1.6 0.19 Drew L-405 2.0 0.28 TiPure R-900 50.0 1.46 Heucophos Z B Z 75.0 2.38 Shi el dex 25.0 1.68 Letdown Preparation: Add the following in the order listed and mix thoroughly: Mai ncote AE-58 492.8 57.25 Water 58.2 7.07 Ammonia (28% NH3) 1. o 0.12 Grind (from above) 218.4 13.68 Ektasolve EEH 31.5 4.25 Drew L-493 3.0 0.42 Acrysol RM-1020 14.0 1.58 33.2 3.99 Water Chroma-Chem 896-9901 (lampblack) 0.3 0.03 8.8 1.09 Sodium Nitrite (15% aqueous solution) Epoxy Component 6 : Genepoxy 370-H55 (55%)

94.8

10.52

Primer Formulation Constants: Pigment Volume Content, %: 1 6 . 5 Volume Solids, %: 3 4 . 7 VOC, gm/l: 216 Component A Formulation Constants: pH: 8 . 5 Stormer Viscosity, Krebs Units: 8 2 IC1 Viscosity, poise: 1 . 2 SOURCE: Rohm and Haas Co.: Maintenance Coatings: MAINCOTE AE-58: Formulation P-58-2

Primers

W h i t e A l k y d Wood P r i m e r Inaredient : H a l o x BW-100 Titanium Dioxide Z i n c Oxide Beaverwhi t e 325 T a l c K r a y g e l 36 C a r g i l l 5150 Raw L i n s e e d O i l Nuosperse 657 M i n e r a l Spi r it s Z r D r i e r (12%) Co D r i e r (12%) Mn D r i e r (6%) M e t h a n o l : Water ( 9 5 : 5 ) S k i n o #1

Wei q h t 25.0 150.0 25.0 325.0 6.0

Volume 1.o 4.4 0.5 14.1 0.4

362.5 27.7 3.0 169.0 3.6 1.5 0.9 2.0 1.o

48.3 3.6 0.4 26.4 0.5 0.2 0.1 0.3 0.1

Formulation Constants: S o l i d s b y Volume: 45.0% PVC: 45.3% Weight p e r g a l l o n : 1 1 . 0 Pigment by W e i g h t : 48.2% NVV by Weight: 19.2% S o l i d s by W e i g h t : 66.9% P r e l im i n a r y Formul a t i on : A-04-03 Clear Latex P r i m e r B e a l e r (Water/Smoke Damage) Inaredient : Water C e l l u l o s i c Thickener Ammoni um H y d r o x i de O i spersant I g e p a l CO-630 S u r f y n o l 104E E t h y l e n e G1 y c o l

Weight 100.0 1. o 1 .o 18.2 2.5 2.5 30.0

Vol ume 12.0 0.1 0.1 2.0 0.3 0.3 3.2

H a l o x BW-100 Snowf 1ake Minex 7

100.0 100.0 100.0

4.2 4.4 4.6

Styrene/Butadiene Latex Texanol Nopco NDW SCT 200 Water

465.0 10.0 2.0 10.0 96.5

55.0 1.o 0.1 1.1 11.6

Formulation Constants: PVC: 3 3 . 7 Weight p e r G a l l o n : 10.4 Weight S o l i d s : 5 0 . 5 Volume S o l i d s : 3 9 . 2

Pigment b y W e i g h t : 28.9 NVV b y W e i g h t : 2 1 . 6 VOC: 1.3 ( l b s / g a l )

SOURCE: H a l o x Pigments: P r e l i m i n a r y F o r m u l a t i o n :

AD-87-05

385

386

Water-Based Paint Formulations

W h i t e House P a i n t P r i m e r

Cbs.

Gals.

116.5 3.5 10.4 0.9 86.3 237.3 172.6

14.00

153.6 1.3 22.4 10.4 12.1 280.5

17.80 0.16 2.68 1.38 1.52 33.68

Premi x : A c t i v-8 C o b a l t Hydrocure I1 C a l c i u m Hydrocem Z i r c o n i um Hydrocem

0.4 3.0 3.0 2.6

0.05 0.40 0.38 0.31

Premi x : Water A c r y s o l ASE-60

3.5 3.5

0.20 0.40

M a t e r i a1 : Water Triethylamine Methyl Carbi t o 1 P a t c o t e 550 Kel sol 3922-G-80 T i - P u r e R-902 Daper N o v a c i t e Cowles t o a 5 Hegman g r i n d . Letdown : Kel s o l 3922-6-80 S u r f y n o l 104E A r o p l a z 1272 Ammonium H y d r o x i d e Butyl Carbitol Water

Analysis: Pigment Volume C o n c e n t r a t i o n , Pigment/Binder R a t i o : 1 . 9 2 / 1 P e r c e n t S o l i d s , Weight: 5 5 . 9 P e r c e n t S o l i d s , Volume: 3 9 . 6 V i s c o s i t y @ 25C, KU: 85-90 pH: 8 . 2 - 8 . 6 Pounds/Gallon: 1 1 . 2 4 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 187 Pounds/Gallon: 1 . 5 5 SOURCE: R e i c h h o l d Chemicals, I n c . : F o r m u l a t i o n 2121-53-1

Percent:

38.0

Waterborne Handbook:

0.57

1.23 0.12 10.00 7.12 7.82

Primers

387

Woodstai n-Resi stant/Corrosi on-Resi s t a n t Primer Contai n i nq Acrvsol RM-825

Weitaht/PoundsVolume/Gallons M a t e r i a1 s : 125.0 15.00 Water 50.0 5.80 Methyl Carbit o 1 8.0 0.92 A c r y s o l RM-5 (25%) 3.0 0.38 AMP-95 0.22 2.0 C o l l o i d 643 0.22 2.0 T r i t o n X-405 (70%) 12.8 1.40 E x p e r i m e n t a l D i s p e r s a n t PR-681M (35%) 6.0 0.13 Kadox 515 125.0 3.78 T i -Pure R-902 1.82 50.0 Busan 11M-1 5.47 117.8 ASP-1 70 0.28 3.0 Tamol 960 (40%)* 365.0 37.0 4.5 3.0 4.0 8.0 2.0 10.0 21 . o 102.0

Rhoplex MV-23 (43%) A r o p l a z 1271 + D r i e r s * * B u t y l Carbit o 1 C o l l o i d 643 Super-Ad-It Sodium N i t r i t e (13.8%) aqueous A c r y s o l TT-615 (30%) )Premix Water 1 A c r y s o l RM-825 (25%) Water

*

41.61 4.46 0.56 0.40 0.50 0.96 0.23 1.20 2.41 12.25

Must b e added l a s t s i n c e e a r l i e r a d d i t i o n t h i c k e n s l i q u i d phase.

Formulation Constants: PVC: 35.2% Volume S o l i d s : 31.8% pH: 9 . 4 I n i t i a l Viscosity: KU: 101 I C I : 1.7 Equi 1 ib r a t e d V i s c o s i t y : KU: 101 I C I : 1.7

**

A r o p l a z 1271 + D r i e r s : A r o p l a z 1271 6% C o b a l t Naphthenate 6% Manganese O c t o a t e 6% Z i r c o n i um O c t o a t e

93.4% 0.5% 0.5% 5.6%

SOURCE: Rohm and Haas Co.: T r a d e S a l e s C o a t i n g s : A c r y s o l RM-825: F o r m u l a t i o n P-23-22A

388

Water-Based Paint Formulations

20 PVC Waterborne Pigmented P r i m e r ( C o n t a i n s S t r o n t i urn Chromatej Materials: Butyl Cellosolve Water P a t c o t e 519 I g e p a l CTA-639 Tamol 165 Red I r o n Oxide S t r o n t i u m Chromate Z i n c Ye1 l o w 499 T a l c 290 Lo M i c r o n B a r y t e s

Weight* [Pounds) 50.3 23.8 1.6 2.6 11.1 118.6 14.3 4.2 42.9 59.3

Volume LGallons) 6.69 2.86 0.23 0.29 1.26 2.77 0.46 0.15 1.91 1.58

Cowles g r i n d ( 7 - 7 1 / 2 N . S . ) Letdown w i t h : 596.1 Rhoplex WL-92 ( 4 2 w t . % s o l i d s ) 14.3 T r i t o n X-405 ( r e d u c e d t o 35 w t . % s o l i d s ) B u t y l Carbi t o 1 37.6 Dibutyl Phthalate 12.7 10% Ammonium Benzoate i n Water 33.4 14% Ammonia t o pH o f 7 . 9 - 8 . 1 5.3 A d j u s t v i s c o s i t y w i t h ASE-60 (5% i n w a t e r , pH o f 9 . 2 ) , i f r e q u i r e d

69.39 1.63 4.70 1.45 4.00 0.66

F o r m u l a t i o n Constants: pH: 7 . 9 - 8 . 1 V i s c o s i t y , c p s : 200-600 Approximate S o l i d s , % ( w t . / v o l . ) : 50/38 D e n s i t y , l b s . / g a l . : 10.3 P i g m e n t / B i n d e r R a t i o : 49/51 PVC, %: 20 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat S t a b i l i t y ( 8 d a y s / l 4 0 F ) : S a t i s f a c t o r y VOC, g / l i t e r : 214 l b s . / g a l l o n : 1.79 Weight % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 20 B u t y l C a r b i t o 1 : 15 Dibutyl Phthalate: 5

*

U s i n g w e i g h t i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f l a c q u e r . W i t h k i l o g r a m s , 833 l i t e r s w i l l r e s u l t

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-92: F o r m u l a t i o n WL-92-5

Primers

389

_ 31 PVC _ Waterborne ~ _ _ Pigmented P r i m e r ( C o n t a i n s S t r o n t i u m Chromate) Weight* Materials:. Tamol 165 P a t c o t e 519 Igepal C T A - 6 3 9 Water Red I r o n Oxide S t r o n t i u m Chromate Zinc Yellow 499 T a l c 290 Lo M i c r o n B a r y t e s

15.2 1.1 3.5 117.3 85.3 10.4 3.0 91 . 8 128.8

Volume (Gallons) 1.72 0.16 0.40 14.08 1.99 0.33 0.11 4.08 3.44

437.3 10.4 27.5 27.5 9.2 22.1

50.91 1.19 3.66 3.44 1.15 2.65

79.2

9.48

( Pounds 1

Cowles g r i n d ( 7 - 7 1 / 2 N . S . ) Letdown w i t h : Rhoplex WL-92 ( 4 2 w t . % s o l i d s ) T r i t o n X-405 ( r e d u c e d t o 35 w t % s o l i d s ) Butyl Cellosolve B u t y l Carbi t o 1 Dowanol DPM 10% Ammonium Benzoate i n Water 14% Ammonia t o pH o f 7.9-8.1 A d j u s t v i s c o s i t y w i t h ASE-BO (5% i n w a t e r , pH o f 9 . 2 )

____

--__

Formulation Constants: pH: 7.9-8.1 V i s c o s i t y , c p s : 400-600 Approximate S o l i d s , % ( w t . / v o l . ) : 48/33 D e n s i t y , l b s . / g a l . : 10.8 P i gment/Bi nder R a t i 0 : 63/37 PVC, %: 31 Freeze-Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat S t a b i l i t y ( 8 d a y s / l 4 0 F ) : S a t i s f a c t o r y VOC, g / l i t e r : 168 l b s . / g a l l o n : 1.40 Weight % on Polymer S o l i d s : B u t y l C e l l o s o l v e : 15 B u t y l C a r b i t o l : 15 Dowanol DPM: 5

*

U s i n g w e i g h t i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f l a c q u e r . W i t h k i l o g r a m s , 833 l i t e r s w i l l result

.

SOURCE:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-92: F o r m u l a t i o n WL-92-4

390

Water-Based Paint Formulations

45 W C Exterior Hardboard Primer Grind: Water Acrysol 1-62 (25%, pH 9.5 with DMAE) Balab 3056A Aurasperse W-7012 Ti-Pure R-960 (Ti02) Snowflake (CaC03) Minex 4 (Silicate) Bentone LT Letdown : Resimene 745 Rhoplex AC-1822 (46.5%) Butyl Cellosolve (60%) Dimethyl ami noethanol (50%) Cellosize HEC, QP-4400 (2.5%)

90.2 39.2 3.6 0.8 78.5 207.8 207.8 0.7

Gallons 10.82 4.51 0.49 0.08 2.37 9.18 9.58 0.05

25.3 488.4 41 .6 1.3 8.6

2.53 55.48 5.33 0.16 1.04

_-__ Pounds

Constants: PVC: 45% pH: 9.0 Viscosity: 25 sec., #4 Ford Cup Acrylic Binder/Melamine (weight ratio): 90/10 Weight Solids: 64% Volume Solids: 47% Note: Weight in pounds will yield about 100 gallons of paint; using kilograms, the yield will be about 833 liters. SOURCE: Rohm and Haas Co.: Building Products Board Coatings: RHOPLEX AC-1822: Formulation Table I V

Primers

391

45 PVC E x t e r i o r H a r d b o a r d P r i m e r Grind: Water A c r y s o l 1-62 (25%, pH 9 . 5 w i t h DMAE) B a l a b 3056A A u r a s p e r s e W-7012 T i - P u r e R-960 ( T i 0 2 ) Snowflake (CaC03) Minex 4 Bentone LT

_ Pounds _ 90.2 39.2 3.6 0.8 78.5 207.8 207.8 0.7

Gal l o n s 10.82 4.51 0.49 0.08 2.37 9.18 9.58 0.05

25.3 488.4 41.6 1.3 8.6

2.53 55.48 5.33 0.16 1.04

Letdown : Resimene 745 Rhopl ex AC-1822 ( 4 6 . 5 % ) B u t y l C e l l o s o l v e (60%) D i m e t h y l ami n o e t h a n o l (50%) C e l l o s i z e HEC, QP-4400 (2.5%)

Constants: PVC=45% pH=9.0 V i s c o s i t y = 2 5 s e c . , #4 F o r d Cup A c r y l i c Binder/Melamine ( w e i g h t r a t i o ) = 9 0 / 1 0 Weight S o l i d s : 64% Volume S o l i d s : 47% N o t e : Weight i n pounds w i l l y i e l d a b o u t 100 g a l l o n s o f p a i n t ; u s i n g k i l o g r a m s , t h e y i e l d w i l l be about 833 l i t e r s . SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s Board C o a t i n g s : RHOPLEX AC-1822: F o r m u l a t i o n T a b l e V

392

Water -Based Paint Formulations

55 PVC P r i m e r M a t e r i a1 s: Cowles G r i n d : A c r y s o l 1-62 (22.7%)* 8 a l a b 3056A A u r a s p e r s e W-7012 T i P u r e R-960 S n o w f l a k e CaC03 Minex 4 Bentone LT Water

Pounds

Letdown : Rhoplex AC-2045 (45.0%) Cyme1 373 (85%) E t h y l e n e g l y c o l monobutyl e t h e r (60% i n water)

-~ Gallons

49.4 4.4 1 .o 98.7 261.5 261.5 1.o 125.3

5.54 0.60 0.10 3.00 11.59 12.06 0.07 15.04

400.4 25.1

45.48 2.26

33.4

4.27

F o r m u l a t i o n Constants: pH: a d j u s t t o 8 . 3 - 8 . 8 w i t h DMAE (50% i n H20) V i s c o s i t y ( # 4 F o r d Cup), s e c . : 35 % PVC: 55 % Weight S o l i d s : 66 % Volume S o l i d s : 49 A c r y l i c / M e l a m i n e ( s o l i d s r a t i o ) : 90/10

*

A c r y s o l 1-62 N e u t r a l i z a t i o n : A c r y s o l 1-62 (50%) Water DMAE (50%)

40.0 40.0

8.0

SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s Hardboard C o a t i n g s : RHOPLEX AC-2045: F o r m u l a t i o n #P-2045-1

Rimers

393

55 PVC P r i m e r

Materials: Cowles G r i n d : A c r y s o l 1-62 ( N e u t r a l i z e d a t 23.7%)* B a l a b 3056A T i P u r e R-960 Snowf 1ake Neosil A A u r a s p e r s e W-7012 Bentone LT Water Letdown : E x p e r i m e n t a l E m u l s i o n E-2573 (47.5%)) Cyme1 373 (85%) ) 1st ) T r i e t h y l a m i n e (TEA) Premix ) E t h y l e n e G l y c o l Monobutyl E t h e r (60% i water)

Pounds

54.4 4.6

102.2 270.9 270.8 1 1

.o .o

96.9 2nd 392.6 Pre24.3 mix 5.5 n

38.9

Gal 1ons

6.42 0.58 3.11 12.03 12.27 0.10 0.06 11.63 45.54 2.31 0.92 5.05

Formulation Constants: A d j u s t pH w i t h TEA t o : 9 . 0 V i s c o s i t y (#4 F o r d Cup), s e c . : 16 % Pigment Volume C o n t e n t : 55 % Weight S o l i d s : 67.5 % Volume S o l i d s : 50 B i n d e r / M e l a m i n e ( s o l i d s r a t i o ) : 90/10

*

A c r y s o l 1-62 N e u t r a l i z a t i o n : A c r y s o l 1-62 (50%) Water T r i e t h y l ami ne

40.0 40.0 4.0

SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s Hardboard C o a t i n g s : E x p e r i m e n t a l Emu1s i on E-2573 : F o r m u l a t i o n UP-2573-1

394

Water-Based Paint Formulations

55 PVC P r i m e r F o r m u l a t i o n M a t e r i a1 s : A c r y s o l 1-62 ( 2 2 . 7 % T . S . ) * B a l a b 3056A A u r a s p e r s e W-7012 R u t i l e T i 0 2 , T i - P u r e R-960 Snowf 1ake Minex 4 Bentone LT Water

Pounds 50.0 4.5 1.o 100.0 265.0 265.0 1.o 86.4

Gal 1ons 5.75 0.61 0.10 3.02 11.77 12.22 0.07 10.37

G r i n d a t h i g h speed and l e t down as f o l l o w s : Rhoplex AC-22 (46%) Cyme1 373 (85%) B u t y l C e l l os01 ve (60%)

417.0 25.1 35.5

47.40 2.40 4.55

A d j u s t pH t o 9 . 0 w i t h DMAE 50%. Primer Constants: PVC: 55.0% V i s c o s i t y ( # 4 F o r d Cup) : 24" Weight S o l i d s : 68% Volume S o l i d s : 50%

*

N e u t r a l i z a t i o n o f A c r y s o l 1-62: A c r y s o l 1-62 (50%) Water DMAE (50%)

40.0 40.0 8.0

SOURCE: Rohm and Haas Co.: B u i l d i n g P r o d u c t s Board C o a t i n g s : RHOPLEX AC-1822:

Formulation Table V

396

Water-Based Paint Formulations

C l e a r C o n c r e t e SeMaterial : A r o l o n 840-W-39 Water Premix and add: Spensol L44 Water Premix and add: E k t a s o l v e DE Water Add i n f o l l o w i n g o r d e r w i t h a g i t a t i o n : T r i b u t o x y E t h y l Phosphate Lodyne 51078 sws 211 Ammonium H y d r o x i d e

Cbs. 415.4 129.1

Gals. 47,75 15.50

163.7 70.8

18.75 8.50

33.0 36.4

4.00 4.37

6.4 1.7 0.2 1.3

0.75

0.18 0.03 0.17

Analysis: R a t i o o f AROLON 840 t o SPENSOL L44: 75/25 P e r c e n t S o l i d s , W e i g h t : 25.2 P e r c e n t S o l i d s , Volume: 2 2 . 8 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 16 pH: 8.0-8.8 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 202 Pounds/Gallon: 1 . 7 F o r m u l a t i o n 2076-70 C l e a r U r e t h a n e / A c r v l i c Wood F i n i s h

Lbs.

M a t e r i a1 : A r o l o n 840-W-39 Ammoni um H y d r o x i de Byk 301 M i chem Emu1 s i on 43040 R h e o l a t e 255 Spensol L44 Analysis: P e r c e n t Sol ids, Weight : 35.2 P e r c e n t S o l i d s , Volume: 32.2 V i s c o s i t y @ 25C, #2 Zahn, Secs.: Pounds/Gallon: 8 . 7 pH: 8 . 2 - 8 . 8 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 159 Pounds/Gal 1on : 1 . 3

SOURCE:

R e i c h h o l d Chemicals, I n c . : F o r m u l a t i o n 2384-650

378.1 2.0 3.0 24.6 2.5 460.8

25

Waterborne Handbook:

Gals. 43.46 0.26 0.37 2.96 0.29 52.66

Sealers

397

Clear Sealer A c l e a r sealer formulation f o r concrete, chalk, e t c . Ideal s t a r t i n g formulation f o r c l e a r lacquer. Pounds 158.9 0.5 0.5 47.5 25.9 23.1 1.9 596.3

Inqredients: Water F1u o r o s u r f a c t a n t ( 1 ) Antifoam (2) Butyl C a r b i t o l Solvent Propylene G l y c o l Plasticizer (3) Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n Ucar L a t e x 430 (43.0%)

Gal l o n s 19.08 0.06 0.07 6.00 3.00 3.00 0.25 68.54

Suppliers: ( 1 ) F1u o r o s u r f a c t a n t - FC-120 o r equi Val e n t ( 2 ) A n t i f o a m - SWS-211 o r e q u i v a l e n t ( 3 ) P l a s t i c i z e r - T r i b u t o x y e t h y l Phosphate KP-140 o r e q u i v a l e n t C1e a r Wet P r o p e r t i es : T o t a l S o l i d s , %: b y Volume: 28.2 by Weight: 30.1 V i s c o s i t y , #4 F o r d Cup, sec: 21 pH, i n i t i a l : 9 . 4 Weight p e r g a l l o n , l b : 8.55 Freeze-thaw, 3 c y c l e s : Pass Heat S t a b i l i t y , 2 wks a t 120F (49C): VOC, g / l : 216.8

Pass

F i m P r o p e r t ies : Gloss, 60: 86 W h i t e n i n g , w a t e r , 24-hr day: None Low-Temperature Coalescence: E x c e l l e n t Chalk Adhesion ( 1 ) : Excel 1e n t ( 1 ) ASTM #2 Chalk

SOURCE:

Ucar Emulsions Systems: UCAR L a t e x 430: S u g g e s t i o n V-2207

Formulation

398

Water-Based Paint Formulations

Concrete Sealer Pounds

Gal 1ons

278.0 16.7

32.90 2.22

15.0 1 .o 2.1 2.9 4.0

1.99 0.13 0.27 0.38 0.49

463.4

55.63

49.9

5.99

C a r g i 11 Water R e d u c i b l e Epoxy E s t e r

73-7331 Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: E t h y l e n e G1 y c o l Monobutyl E t h e r Activ-8 I n t e r c a r 6% C o b a l t I n t e r c a r 6% Manganese Byk-301 Dei o n i zed Water D e i o n i z e d Water ( H o l d f o r V i s c o s i t y Adjustment)

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 23.99 (By Volume): 22.40 Weight Per G a l l o n : 8.33 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.92 ( G r a m s / L i t e r ) : 350 W a t e r : C o s o l v e n t Weight R a t i o : 84.20:15.80 pH: 8.48 V i s c o s i t y # 4 F o r d Cup (Seconds): 30 I t s h o u l d be n o t e d t h a t t h i s c o a t i n g w i l l t e n d t o y e l l o w more t h a n c o n v e n t i o n a l s o l v e n t - b a s e d p r o d u c t s .

SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1877-lQG

Sealers

Low-Solids Sandinq Waterborne S e a l e r Based on RhoDlex CL-104 Emu1s i on f o r A i r - D r y o r Low-Force-Dry Appl ic a t i o n M a t e r i a1 s : Rhoplex CL-104 e m u l s i o n Dee Fo 3000

Weight Pounds 514.1 1.o

Volume Gallons 59.6 0.1

19.8 49.5 162.6

2.5 6.6 19.5

62.7 11.9 5.6

9.6 1.4 0.7

Premix and add under a g i t a t i o n : B u t y l Carbi t o 1 B u t y l C e l l os01 ve Water Add : Isopropanol L i q u a z i nc AQ-90 OR-708 Rheology Modi f ie r

F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w t / v o l ) : 25.0/23.1 pH: 7 . 0 - 7 . 5 V i s c o s i t y , B r o o k f i e l d LV S p i n d l e #1, CP @ 30 rpm: 25-30 V i s c o s i t y , #2 Zahn cup, seconds: 16-22 VOC, g / l i t e r : 382 l b / g a l l o n : 3.18 C o a l e s c e n t , w t % on polymer s o l i d s : B u t y l C e l l o s o l v e : 25 B u t y l C a r b i t o 1 : 10 Rheology m o d i f i e r , w t % on polymer s o l i d s : 1 . 0 Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes

SOURCE: Rohm and Haas Co.:

RHOPLEX CL-104 A c r y l i c E m l s i o n : F o r m u l a t i o n WR-74-5LS

399

400

Water-Based Paint Formulations

Sandinq S e a l e r Based on E x p e r i m e n t a l Emulsion E-2955 M a t e r i a1 s : E x p e r i m e n t a l e m u l s i o n E-2955 Water

Weight Pounds 660.0 84.0

Volume Gal 1ons 76.9 10.1

M i x above t h e n add s l o w l y w i t h good a g i t a t i o n : 14% ammonia (to a d j u s t pH t o 8.5) Premix and add under a g i t a t i o n : B u t y l Cel l o s o l v e E k t a s o l ve EEH I s o p r o p y n o l (15%)

31 . 7 4.9 36.6

4.2 0.7 5.6

Add : Water 21 . o 2.5 ( a d j u s t v i s c o s i t y w i t h w a t e r t o a range o f 20 t o 26 seconds on a #2 Zahn cup) F o r m u l a t i o n Constants: A p p r o x i m a t e s o l i d s , % ( w t / v o l ) : 29.1/26.9 pH: 7 . 5 - 8 . 0 F l a s h p o i n t , c l o s e d cup, F: 120 V i s c o s i t y , #2 Zahn cup, seconds: 2 0 t o 26 VOC, g / l i t e r : 235 l b / g a l l o n : 1.95 C o a l e s c e n t , w t % on polymer s o l i d s : B u t y l C e l l o s o l v e : 13 E k t a s o l v e EEH: 2 Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes

SOURCE: Rohm and Haas Co.: F o r m u l a t i o n WR-55-2

E x p e r i m e n t a l Emulsion E-2955:

Sealers

Sandina Waterborne S e a l e r Based on RhoDlex CL-104 Emulsion For A i r - D r y or Low-Force-Dry A p p l i c a t i o n Materials: Rhoplex CL-104 e m u l s i o n Dee Fo 3000

Weight Pounds 695.1 1.6

Volume Gal l o n s 81.3 0.2

26.7 67.0 15.9

3.3 8.9 1.9

Premix and add under a g i t a t i o n : B u t y l Carbit o 1 Butyl Cellosolve Water Add : L i quaz inc AQ-90 16.0 1.9 14% ammonia ( a d j u s t v i s c o s i t y w i t h w a t e r t o a range o f 20 t o 26 seconds on a #2 Zahn cup) Water 19.4 2.3 F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w t / v o l ) : 32.5/30.8 pH: 7.5-8.0 V i s c o s i t y , #2 Zahn cup, seconds: 20 t o 26 VOC, g / l i t e r : 259 l b s / g a l l o n : 2.15 C o a l e s c e n t , w t % on polymer s o l i d s : B u t y l C e l l o s o l v e : 25 B u t y l C a r b i t o l : 10 Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes

SOURCE: Rohm and Haas Co.: RHOPLEX CL-104 A c r y l i c Emulsion: F o r m u l a t i on WR-74-5

401

402

Water -Based Paint Formulations

Sealer Materials: 1 . E-2774 (38.5% n v ) 2 . Dehydran 1620 ( 100% a c t i v e )

Weight Pounds 694.6 2.5

Vo 1ume Gal lons 80.6 0.3

Premix 3-5 and add t o 1 and 2 w i t h a g i t a t i o n 3. B u t y l C a r b i t o l 4. B u t y l C e l l o s o l v e 5 . Water 6. L i q u a z i n c AQ-90 7. 14% Ammoni a 8 . Water

(50%)

26.7 66.9 20.1

3.4 8.9 2.4

16.0 1.4 24.5

1.3 0.2 2.9

Formulation Constants: Approximate S o l i d s , % ( w t / v o l ) : 32.3/30.0 pH: 7 . 5 V i s c o s i t y , #2 Zahn, seconds: 18 VOC,* g / l i t e r : 264 l b s / g a l l o n : 2.20 C o a l e s c e n t , w t % Polymer S o l i d s : B u t y l C e l l o s o l v e : 25 B u t y l C a r b i t o l : 10 Freeze/Thaw S t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat Age S t a b i l i t y : S a t i s f a c t o r y SOURCE: Rohm and Haas Co.:

F o r m u l a t i o n WR-74-9

Sealers

W a t e r p r o o f i n g S e a l e r : W h i t e Masonry P a i n t lb/100 nal 40 19 18 11 5

P r o p y l C e l l os01 ve M e t h y l Propasol K o d a f l e x TXIB Triethylamine Nopco NDW Mix w e l l ;

t h e n add: 400

P l i o l i t e 7104 Mix w e l l ;

t h e n add: 90 225 179 113 3

T i t a n o x 2101 Atomi t e M i n u s i l 30 M i c a C-3000 Nopcocide N-96 H i g h speed d i s p e r s e t o 3 NS. Then add t h e f o l owing shown:

n order

Water 28% NH40H S o l u t i o n

57 10

Nopco NDW 4% Cel l o s i ze QP-4400 S o l u t i o n

4 45

VOC: 1.22 l b / g a l = 1 4 7 g/1 (-H20) D e n s i t y : 12.25 l b / g a l PVC: 54% NVW: 66% NVV: 48% KU V i s c o s i t y : 100 t o 110 KU Freeze Thaw- S t a b i 1 it y : pass 5 c y c l e s Oven S t a b i l i t y : pass 4 weeks 120 degrees F D r y Time @ 2 m i l DFT: 1 h o u r Recoat Time: 4 h o u r s Method o f A p p l i c a t i o n : b r u s h o r r o l l H y d r o s t a t i c Water P r e s s u r e T e s t : pass 4 p s i no blisters

SOURCE: The Goodyear T i r e & Rubber Co.:

eaks o r

Formula 20 4-41 -1

403

Stains

405

Brown Pigmented Spray S t a i n Based on A c r y s o l 1-62 S o l u b i l i z e t h e A c r y s o l 1-62 b y c o m b i n i n g m a t e r i a l s 1, 2 and 3 . Disperse pigments 4 t h r o u g h 7 w i t h t h e B u t y l C a r b i t o l ( 8 ) i n a media m i l l t o a 7 Hegman G r i n d . Letdown w i t h 9 t h r o u g h 11. Some s e t t l i n g may o c c u r d u r i n g s t o r a g e . A g i t a t e and check t h e Hegman grind before application. This formulation i s similar t o the p i g m e n t e d w i p i n g s t a i n b u t i s l e t down w i t h w a t e r t o a c h i e v e t h e proper c o l o r concentrations a f t e r spraying. Materials: 1 . A c r y s o l 1-62 (50% n v ) 2 . Water 3 . 14% Ammoni a

Weight Pounds 11 . 6 9.4 0.9

Volume Gal l o n s 1.4 1.1 0.1

0.5 7.4 2.3 8.2 5.8

0.0 0.3 0.1 0.3

19.7 48.1 63.7

2.5 6.1 7.6

664.4

79.8

4 . Bentone LT 5 . Van Dyke Brown 6 . B u r n t Umber 7 . Raw Umber 8. B u t y l C a r b i t o l 9. Dipropylene g l y c o l 10. B u t y l C a r b i t o l 1 1 . Water 12. Water

0.7

Formulation Constants: Approximate S o l i d s , % ( w t / v o l ) : 2 . 9 / 1 . 4 pH: 6 . 7 V i s c o s i t y , #2 Zahn, seconds: 15 VOC,* g / l i t e r : 88 l b s / g a l l o n : .74 Freeze/Thaw S t a b i l i t y : P r o t e c t f r o m F r e e z i n g Heat Age S t a b i l i t y : S a t i s f a c t o r y

*

C a l i f o r n i a ' s South Coast A i r Management D i s t r i c t a l l o w s VOC's f o r s t a i n s w i t h l e s s t h a n one pound s o l i d s p e r g a l l o n t o be c a l c u l a t e d on t h e b a s i s o f pounds o f VOC p e r g a l l o n p l u s w a t e r . A c c o r d i n g l y , t h a t c o n v e n t i o n i s used h e r e .

SOURCE: Rohm and Haas Co.:

F o r m u l a t i o n PST-1

Water-Based Paint Formulations

406

Brown P i qmented W i D i ng S t a i n S o l u b i l i z e t h e A c r y s o l 1-62 b y c o m b i n i n g m a t e r i a l s 1, 2 and 3. Disperse pigments 4 t h r o u g h 7 w i t h t h e B u t y l C a r b i t o l ( 8 ) i n a media m i l l t o 7 Hegman g r i n d . L e t down w i t h 9 t h r o u g h 11. Some s e t t l i n g may o c c u r d u r i n g s t o r a g e . A g i t a t e and check t h e Hegman grind before application. M a t e r ia1 s : 1 . A c r y s o l 1-62 (50% n v ) 2 . Water 3 . 14% Ammonia 4. 5. 6. 7. 8.

Wei a h t Pounds 32.4 26.4 2.6

Volume Gal l o n s 3.8 3.2 0.3

1.4 20.8 6.4 23.0 16.2

0.1 0.9 0.2 0.9 2.0

55.4 135.0 178.5 360.1

6.9 17.0 21.4 43.2

Bentone LT Van Dyke Brown B u r n t Umber Raw Umber Butyl Carbitol

9. D i propylene g l y c o l 10. B u t y l C a r b i t o l 11. Water 12. Water

Formulation Constants: Approximate s o l i d s , % (wt, v o l ) : 7 . 9 / 4 . 0 pH: 7 . 0 V i s c o s i t y , #2 Zahn, seconds: 15 VOC*, g / l i t e r : 248 1b s / g a l 1on : 2 . 0 7 Freeze/Thaw S t a b i l i t y : P r o t e c t f r o m F r e e z i n g Heat/Age S t a b i l i t y : S a t i s f a c t o r y

*

C a l i f o r n i a ' s South Coast A i r Management D i s t r i c t a l l o w s VOC's f o r s t a i n s w i t h l e s s t h a n one pound s o l i d s p e r g a l l o n t o be c a l c u l a t e d on t h e b a s i s o f pounds o f VOC p e r g a l l o n p l u s w a t e r . A c c o r d i n g l y , t h a t c o n v e n t i o n i s used h e r e .

SOURCE: Rohm and Haas Co.:

F o r m u l a t i o n PWS-1

Stains

Redwood Stain--Opaque Material : Lbs. Gals. Kel s o l 3931 -WG4-45 166.0 20.00 Butoxy Ethanol 15.2 2.00 Mapico 347A 50.0 1 .16 Tan 10A 25.0 0.57 S y l o i d 234 25.0 1.50 G r i n d t h e above t o a 6 Hegman, t h e n add t h e f o l l o w i n g and d i s p e r s e 10-15 m i n u t e s : M i cheml ube 143 20.7 3.50 Letdown : K e l s o l 3931 -WG4-45

207.5

25.00

Premix t h e n e x t two m a t e r i a l s , t h e n add under good a g i t a t i o n : Manganese H y d r o c u r e I 1 6.4 0.75 Butoxy Ethanol 7.5 1 .oo Premix t h e n e x t f o u r m a t e r i a l s , t h e n add under good a g i t a t i o n : A e r o s o l OT-75 2.3 0.25 I n t e r c i d e T-0 4.9 0.50 Polyphase AF-1 7.3 0.75 Butoxy E t h a n o l 7.5 1 .oo Add t h e f o l l o w i n g under good a g i t a t i o n : Ammoni um H y d r o x i de Water Anal y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : Pigment/Binder R a t i o : 0.6/1 . O P e r c e n t S o l i d s , W e i g h t : 32.2 P e r c e n t S o l i d s , Volume: 25.5 V i s c o s i t y @ 25C, #2 Zahn, S e c s . : 23 Pounds/Gal 1on : 9 . 0 pH: 8 . 3 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 264 Pounds/Gallon: 2.2

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2262-12A

1.9 347.9 12.7

I n c . : Waterborne Handbook:

0.25 41.77

407

408

Water-Based Paint Formulations

Redwood S t a i n - - S e m i - T r a n s p a r e n t

Lbs. Gals. M a t e r i a1 : 166.0 20.00 Kel s o l 3931 -WG4-45 15.2 2.00 Butoxy E t h a n o l Mapico 347A 15.0 0.35 S y l o i d 234 25.0 1 .50 G r i n d t h e above t o a 6 Hegman, t h e n add t h e f o l l o w i n g and d i s perse 10-15 m i n u t e s : 28.7 3.50 M i cheml ube 743 Letdown : Kel s o l 3931 -WG4-45

207.5

25.00

Premix t h e n e x t two m a t e r i a s , t h e n add under good ag t a t i o n : 0.75 6.4 Manganese H y d r o c u r e I 1 1 .oo 7.5 Butoxy E t h a n o l Premix t h e n e x t f o u r m a t e r i I s , t h e n add under good a it a t i on : 0.25 2.3 A e r o s o l OT-75 0.50 4.9 I n t e r c i de T - 0 0.75 7.3 Polyphase AF-1 1 .oo 7.5 Butoxy Ethanol Add t h e f o l l o w i n g under good a g i t a t i o n : Ammonium H y d r o x i d e Water

1.2 359.4

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 7 . 7 Pigment/Binder R a t i o : 0.2/1 . O P e r c e n t S o l ids, Wei g h t : 26.8 P e r c e n t Solids, Volume: 2 4 . 1 V i s c o s i t y @ 25C, #2 Zahn, S e c s . : 25 Pounds/Gallon: 8 . 2 - 8 . 6 pH: 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 264 Pounds/Gallon: 2 . 2

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2282-128

I n c . : Waterborne Handbook:

0.25 43.15

Stains

Redwood S t a i n--Semi - T r a n s p a r e n t M a t e r i a1 : Lbs. K e l s o l 3937-WG4-45 166.0 Butoxy Ethanol 12.2 Mapico 347A 15.0 S y l o i d 234 25.0 G r i n d t h e above t o a 6 Hegman, t h e n add t h e f o l l o w i n p e r s e 15 m i n u t e s : M i cheml ube 743 28.7 Letdown : K e l s o l 3937-WG4-45

Gals. 19.80 1.62 0.35 1.50 and d i s -

207.5

Premix t h e n e x t t w o m a t e r i a l s , t h e n add under a g i t a t on : 6.4 Manganese H y d r o c u r e I 1 Butoxy Ethanol 7.5

3.50 24.76 0.75 1 .oo

Premix t h e n e x t f o u r m a t e r i a l s , t h e n add under a g i t a t i o n : A e r o s o l OT-75 2.3 0.25 Intercide T-0 4.9 0.50 Polyphase AF-1 7.3 0.75 Butoxy Ethanol 7.5 1 .oo Ammonium H y d r o x i d e 1.2 0.25 Water 366.3 43.97 Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 9 . 0 Pigment/Binder R a t i o : .24/1 P e r c e n t S o l i d s , W e i g h t : 24.2 P e r c e n t S o l i d s , Volume: 21.3 V i s c o s i t y @ 25C, #2 Zahn, S e c s . : 25-35 Pounds/Gallon: 8.58 pH: 8.2-8.6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 244 Pounds/Gallon: 2.04

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2402-54A

Inc.:

Waterborne Handbook:

409

Water-Based Paint Formulations

410

Semi-Transparent Material : Water 2% N a t r o s o l 250MR S o l u t i o n P r o p y l ene G1 y c o l Butyl Cellosolve AMP 95 P r o x e l GXL Synthemul 40-423 Brown I r o n O x i d e O i s p .

Cherry S t a i n

Lbs. 284.1 100.0 45.0 34.5 0.6 1.o 370.0 27.6

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 3 . 6 P e r c e n t S o l i d s , W e i g h t : 21.5 P e r c e n t S o l i d s , Volume: 1 8 . 4 I n i t i a l V i s c o s i t y , KU: 50-55 pH: 8 . 3 - 8 . 8 Pounds/Gallon: 8.63 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 338.0 60 G l o s s * (comm. a l k y d = 4 - 6 ) : 9- 0 1 .o-1.5 20 G l o s s * (comm. a l k y d = 0 . 5 - 1 . O ) 8 5 Sheen* (comm. a1 k y d = l 4 - 1 8 ) : 8-22

*

Two Coats

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 423-01

I n c . : Waterborne Handbook:

Gals. 34.10 11.93 5.21 4.59 0.06 0.10 42.05 1.95

Stains

S h i n a l e S t a i n T i n t Base

Lbs.

M a t e r i a1 : Water L i naqua K e l e c i n 1081 C o b a l t Hydrocure I 1 Manganese Hydrocure Act iv-8 Bentone 38 T i t a n o x 2101 Z i n c Oxide XX601 T a l c 399

549.00 168.00 8.20 3.00 3.00 0.74 5.10 76.00 102.00 153.00

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 3 8 . 2 P e r c e n t S o l i d s , Weight: 4 6 . 0 P e r c e n t S o l i d s , Volume: 2 9 . 3 Pounds/Gallon: 1 0 . 6 8 VOC ( e x c l u d i n g w a t e r ) : Grams/Liter: 9 8 . 4 Pounds/Gallon: 0 . 8 2 SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 1936-54

Inc.:

Waterborne Handbook:

Gals. 65.89 20.70 0.95 0.39 0.40 0.09 0.36 2.23 2.19 6.80

411

412

Water-Based Paint Formulations

S i e r r a Redwood S t a i n - - S e m i - T r a n s p a r e n t

.

M a t e r i a1 : Lbs. Gals Kel s o l 3939-WG4-45 166.0 19.80 Butoxy E t h a n o l 12.2 1 .62 Mapico 297 10.0 0.23 Mapico 1075 4.0 0.12 Mapico B l a c k 1.o 0.02 S y l o i d 234 25.0 1.50 G r i n d t h e above t o a 6 Hegman, t h e n add t h e f o l l o w i n g and d i s p e r s e 15 m i n u t e s : Michemlube 743 28.7 3.50 Letdown : K e l s o l 3939-WG4-45

207.5

Premix t h e n e x t two m a t e r i a l s , Manganese H y d r o c u r e I 1 Butoxy E t h a n o l Premix t h e n e x t f o u r m a t e r i a l s , A e r o s o l OT-75 I n t e r c i d e T-0 Polyphase AF-1 Butoxy E t h a n o l Ammoni um H y d r o x i d e Water

t h e n add under good a g i t a t i o n : 6.4 0.75 7.5 1 .oo t h e n add under good a g i t a t i o n : 2.3 0.25 4.9 0.50 7.3 0.75 7.5 1 .oo 1.2 0.25 366.3 43.96

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 9 . 0 Pigment/Binder R a t i o : .24/1 P e r c e n t S o l i d s , Weight: 24.2 P e r c e n t S o l i d s , Volume: 21.3 V i s c o s i t y @ 25C, #2 Zahn, Sees.: 25-35 Pounds/Gallon: 8 . 5 8 pH: 8 . 2 - 8 . 6 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 244 Pounds/Gallon: 2.04

SOURCE:

R e i c h h o l d Chemicals, F o r m u l a t i o n 2402-34A

24.75

Inc.:

Waterborne Handbook:

Stains

S t a i n Fortnul a t i on Materials: WB-151 R e s i n ( a t 75% NVM) Dei o n i zed Water Ammoni um H y d r o x i de E t h y l e n e g l y c o l monobutyl e t h e r Secondary b u t a n o l Cobalt d r i e r ( 1 ) Opaque s t a i n ( 2 ) Red I r o n Oxide Pigment ( 3 ) Flow Agent ( 4 ) Foam C o n t r o l Agent ( 5 ) Fungicide (6) Stain Properties: N o n - v o l a t i l e m a t e r i a l , (NVM), w t %: 23.0 P i g m e n t / b i n d e r R a t i o : 0.07 Cosolvent/Water R a t i o , w t % : 17/83 V i s c o s i t y , #2 Zahn Cup. sec: 28.0 pH: 8.02 Dry t i m e s a t 20C, 50% RH: s e t t o t o u c h , min: 13.0 t a c k f r e e , min: 20.0 d r y h a r d , min: 20.0 V o l a t i l e O r g a n i c Compound, (VOC), l b / g a l :

P a r t s by Wei q h t 205.0 450.0 11 . o 15.0 23.0 6.0

----

11 . o 1.o 2.0 2.0

2.90

1 . C o b a l t Hydrocure 2. WA-8 3 . R0-3097 4 . BYK-301 5 . Drewplus L-418 6 . Nopcocide N-40-D

Compounding Procedure: 1 . D i s p e r s e pigment i n t o r e s i n u s i n g a h i g h speed m i x e r . 2. N e u t r a l ize t h e r e s i n / p i gment d i s p e r s i on w i t h ammoni um h y d r o x i d e and d e i o n i z e d w a t e r ; mix t h o r o u g h l y . 3 . Add c o s o l v e n t , d r i e r , f l o w a g e n t , foam c o n t r o l agent and f u n g i c i d e ; mix t h o r o u g h l y .

SOURCE: Amoco Chemical Co.;

Water-borne A l k y d S t a i n / S e a l e r f o r Wood Based on Amoco IPA and TMA: Formula WE-1

413

414

Water-Based Paint Formulations

S t a i n Formulation Mater ia1 s : WB-151 R e s i n ( a t 75% NVM) Dei o n i zed Water Ammonium H y d r o x i d e E t h y l e n e g l y c o l monobutyl e t h e r Secondary b u t a n o l Cobalt d r i e r ( 1 ) Opaque s t a i n ( 2 ) Flow Agent ( 4 ) Foam C o n t r o l Agent ( 5 ) Fungicide (6) Stain Properties: N o n - v o l a t i l e m a t e r i a l , (NVM), w t % : 2 2 . 0 P i g m e n t / b i n d e r R a t i o : 0.07 Cosolvent/Water R a t i o , w t % : 15/85 V i s c o s i t y , #2 Zahn Cup, sec: 21.0 pH: 8 . 3 3 D r y t i m e s a t 20C, 50% RH: s e t t o t o u c h , min: 14.0 t a c k f r e e , min: 30.0 d r y h a r d , min: 32.0 V o l a t i l e O r g a n i c Compound, (VOC), l b / g a l : 1. 2. 4. 5. 6.

P a r t s by Weiqht 205.0 500.0 11 . o 15.0 23.0 6.0 11 . o 1.o 2.0 5.0

2.90

C o b a l t Hydrocure WA-8 BYK-301 Drewplus L-418 Nopcocide N-40-D

Compounding Procedure: 1 . D i s p e r s e pigment i n t r e s i n u s i n g a h i g h speed m i x e r . 2. N e u t r a l i z e t h e r e s i n tigment d i s p e r s i o n w i t h ammonium h y d r o x i d e and d e i o n i z e d w a t e r ; m i x t h o r o u g h l y . 3. Add c o s o l v e n t , d r i e r , f l o w a g e n t , foam c o n t r o l a g e n t and f u n g i c i d e ; mix t h o r o u g h l y . SOURCE: Amoco Chemical Co.: Water-borne A l k y d S t a i n / S e a l e r f o r Wood Based on AMOCO IPA and TMA: Formula WB-2

Stains

Waterborne Redwood S o l i d C o l o r S t a i n Pounds

Gal l o n s

70.0 50.0 2.5 2.5

9.03 1.23 0.14 0.36

Water R e d u c i b l e M o d i f i e d P o l y o l e f i n 73-7358 OK 412 E t h y l e n e G1 y c o l Monobutyl E t h e r

90.0 25.0 80.0

11.61 1.58 10.65

Manganese Hydrocure I 1 1 E t h y l e n e G l y c o l Monobutyl E t h e r )Premix Polyphase A F - 1 1

9.5 24.0 8.0

1.10 3.19 0.85

11.5 468.4

1.53 56.23

20.0

2.50

Water R e d u c i b l e M o d i f i e d P o l y o l e f i n 73-7358 S y n t h e t i c Red I r o n Oxide R0-3097 A e r o s i l R972 P a t c o t e 577 H i g h Speed t o a 6 Hegman Add under a g i t a t i o n :

Aqueous Ammonia 28% Dei o n i zed Water Michem Lube 511

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 29.54 (By Volume): 25.41 Pigment t o B i n d e r R a t i o : 0.44 Pigment Volume C o n c e n t r a t i o n : 11.92 Weight Per G a l l o n : 8 . 6 1 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2.84 (Grams/Li t e r ) : 341 W a t e r : C o s o l v e n t Weight R a t i o : 80.68:19.32 pH: 8 . 8 V i s c o s i t y #2 Zahn Cup (Seconds): 33 T y p i c a l Cured F i l m P r o p e r t i e s : D r y Time ( H o u r s ) : 2009 Zapon: 5 5009 Zapon: 6 1 / 4

SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : F o r m u l a t i o n 1396-70

415

416

Water-Based Paint Formulations

Waterborne Semi-Transparent Russet B r o w n S t a i n Pounds

Gallons

80.0 3.0 1 .o 8.0 4.0

10.32 0.09 0.10 0.20 0.22

100.0 28.0 90.0

12.91 1.77 11.98

9.5 24.0 8.0

1.10 3.20 0.85

14.7 440.1

1.96 52.80

20.0

2.50

Water R e d u c i b l e Modi f ied Pol yo1 e f i n

73-7358 T i t a n i um D i ox de T i - P u r e

R-900 Speci a1 81 ack 4 S y n t h e t i c Red I r o n Oxide R0-3097 A e r o s i l R972

H i g h Speed t o a 6 Hegman Add under a g i a t i o n : Water R e d u c i b l e M o d i f i e d P o l y o l e f i n

73-7358

OK 412 E t h y l e n e G l y c o l Monobutyl E t h e r Manganese Hydro Cure I 1 1 E t h y l e n e G l y c o l Monobutyl E t h e r ) Premix Polyphase AF-1 1 Aqueous Ammonia 28% D e i o n i z e d Water Michem Lube 511

P a i n t P r o p e r t i as: % N o n v o l a t i l e (By W e i g h t ) : 28.94 (By Volume): 27.31 Pigment t o B i n d e r R a t i o : 0.23 Pigment Volume C o n c e n t r a t i o n : 8.89 Weiaht Per G a l l o n : 8.30 T h e o r e t i c a l VOC (Pounds/Gal 1on) : 2.85 ( G r a m s / L i t e r ) : 342 Water:Cosolvent Weight R a t i o : 78.58:21.42 pH: 8.0-8.5 V i s c o s i t y #2 Zahn Cup (Seconds): 20 T y p i c a l Cured F i l m P r o p e r t i e s : Dry Time ( H o u r s ) : 2009 Zapon: 5 5009 Zapon: 6 1/4

SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula 1396-71

418

Water-Based Paint Formulations

I n t e r i o r Texture Paint A low c o s t t e x t u r e p a i n t f o r m u l a t e d w i t h PYRAX WA t o e l i m i n a t e need f o r a s b e s t o s o r mica t o p r e v e n t mudcracking. I t i s easy t o a p p l y w i t h b r u s h o r r o l l e r , y e t f i l m s r e t a i n whatever t e x t u r e p r o f i l e developed d u r i n g a p p l i c a t i o n .

Pounds 460 1 8 2 6 1 150 75 425

Material: Water Vancide TH Darvan 7 W e t t i n g Agent ( 1 ) Coalescent ( 2 ) Defoamer ( 3 ) Calcined Clay ( 4 ) Wollastonite (5) Pyrax WA Defoamer Latex ( 6 ) Rhodopol 23 ) Combined Ethylene Glycol)

Gal 1ons 55.2 0.1 0.8

0.2 0.8

0.1 6.8 3.1 18.2

1

0.1

100

11.1

10

0.8

25

2.7

1 ) T r i t o n CF-10 o r e q u i v a l e n t

2) 3) 4) 5) 6)

Texanol o r e q u i v a l e n t Nopco NDW o r e q u i v a l e n t Iceberg o r equivalent Nyad G o r e q u i v a l e n t E v e r f l e x GT o r e q u i v a l e n t

Formulation Constants: S o l i d s b y w e i g h t , %: 57 S o l i d s by volume, %: 35 Pigment volume c o n c e n t r a t i o n , %: 83 P i g m e n t / b i n d e r w e i g h t r a t i o : 12/1 Pai n t P r e p a r a t i o n : M a t e r i a l s a r e added i n t h e o r d e r l i s t e d i s u i t a b l e d i s p e r s i o n equipment. RHODOPOL 23 i e t h y l e n e g l y c o l and added a l l a t once under t o avoid the large viscosity build-up u n t i l preparation. SOURCE: R.T. V a n d e r b i l t Co., TX-305A

Inc.:

n t h e formula using s wetted w i t h t h e vigorous a g i t a t i o n t h e end o f p a i n t

Development F o r m u l a t i o n

No.

Texture Paints

419

I n t e r i o r Texture Paint M a t e r i a1 : Water Van-Gel Thickener (1) Vancide TH Dispersant (2) W e t t i n g agent ( 3 ) Coalescent ( 4 ) Ethylene g l y c o l Defoamer ( 5 ) Titanium dioxide ( 6 ) Vansi 1 W-10 Pyrax WA Defoamer Vinyl latex (7)

Pounds 363 6 6 1

15 1 4 25 1 25 500 325 1 136

Gal l o n s 43.6 0.3 0.5 0.1 1.5 0.1 0.5 2.7 0.1 0.8 20.7 13.9 0.1 15.1

1) N a t r o s o l 250HR o r e q u i v a l e n t 2 ) Tamol 731 o r e q u i v a l e n t 3) T r i t o n CF-10 o r e q u i v a l e n t 4 ) Texanol o r e q u i v a l e n t 5 ) Nopco NOW o r e q u i v a l e n t 6 ) T i - P u r e R-931 o r e q u i v a l e n t 7) E v e r f l e x GT o r e q u i v a l e n t F o r m u l a t i o n Constants: S o l i d s b y w e i g h t , %: 67 S o l i d s by volume, %: 44 Pigment volume c o n c e n t r a t i o n , %: 82 Pigment/binder weight r a t i o : 11.3/1 T h i s f o r m u l a t i o n e x h i b i t s a smooth t e x t u r e f i n i s h w i t h s h a r p p e a k i ng. Paint Preparation: M a t e r i a l s a r e added i n t h e o r d e r l i s t e d i n t h e f o r m u l a u s i n g s u i t a b l e d i s p e r s i o n equipment. VAN-GEL i s added t o w a t e r u s i n g slow a g i t a t i o n f o l l o w e d by h i g h - s h e a r m i x i n g f o r f i v e m i n u t e s . T h i c k e n e r and r e m a i n i n g i n g r e d i e n t s a r e added i n t h e u s u a l manner. A p o r t i o n o f PYRAX WA, i f necessary, may be added a f t e r t h e l a t e x t o maintain a d e s i r a b l e working v i s c o s i t y .

SOURCE:

R . T . V a n d e r b i l t Co., TX-302

Inc.:

Development F o r m u l a t i o n No.

420

Water-Based Paint Formulations

I n t e r i o r Texture Paint Material : Water Vancide TH D i s p e r s a n t ( 1) Ethylene g l y c o l Defoamer ( 2 ) Titanium dioxide (3) Vansi 1 W - 1 0 Pyrax WA Vinyl-acrylic latex (4) Defoamer H y d r o x y e t h y l c e l l u l o s e ( 5 ) ) Premix Coalescent )

Pounds 277 1 15 25 1

50 600 300 200 1 2 4

Gallons 33.3 0.1 1.5 2.7 0.1 1.6 24.8 12.9 22.2 0.1 0.2 0.5

1 ) Tamol 731 o r e q u i v a l e n t 2 ) Nopco NDW o r e q u i v a l e n t 3 ) T i - P u r e R-931 o r e q u i v a l e n t 4 ) E v e r f l e x GT o r e q u i v a l e n t 5 ) C e l l o s i z e PP-4400 o r e q u i v a l e n t 6 ) Texanol o r e q u i v a l e n t Formulation Constants: S o l i d s by w e i g h t , %: 72 S o l i d s by volume, %: 51 Pigment volume c o n c e n t r a t i o n , %: 78 Pigment/binder weight r a t i o : 8.6/1 T h i s f o r m u l a t i o n e x h i b i t s a smooth t e x t u r e f i n i s h . Sharper p e a k i n g and c o a r s e r appearance may be o b t a i n e d by a d d i n g 10 pounds M i n i F i b e r s Grade 13 038 t o 100 g a l l o n s p a i n t . Paint Preparation: M a t e r i a l s a r e added i n t h e o r d e r l i s t e d i n t h e f o r m u l a u s i n g s u i t a b l e d i s p e r s i o n equipment. PYRAX WA d i s p e r s e s e a s i l y and, i f necessary, a p o r t i o n ( e . g . , 100 pounds) may be added a f t e r t h e l a t e x t o maintain a desirable working v i s c o s i t y . A g i t a t i o n should be c o n t i n u e d f o r 10 m i n u t e s a f t e r a d d i t i o n o f t h e premixed hydroxyethyl cellulose/coalescent s l u r r y .

SOURCE: R.T. V a n d e r b i l t Co., TX-301

Inc.:

Development F o r m u l a t i o n

No.

Texture Paints

421

White Textured Coating Gals. Lbs. M a t e r i a1 : 50.00 6.00 Water 0.25 Ammonium H y d r o x i d e 1.90 0.24 Bentone EW 5.00 Cowles g r i n d t h e above t h r e e m a t e r i a l s 15-20 m i n u t e s , t h e n add t h e f o l l o w i n g under good a g i t a t i o n : 55.00 A r o l o n 850-W-45 476.30 S u r f y n o l GA 4.40 0.50 0.25 Foamaster 0 1.90 4.29 T i t a n o x 2101 150.00 Pebble m i l l o r sand m i l l g r i n d t h e above m a t e r i a l s t o a 7 Hegman. Letdown : A r o l o n 850-W-45 Butoxy Ethanol Water Texanol S u r f y n o l 104H Michemlube 155 Cab-0-Si1 M5 A c r y s o l ASE-60 Ammoni um H y d r o x i de

114.70 80.70 50.00 2.00 4.00 12.50 10.00 4.20 1.90

13.25 10.75 6.00 0.25 0.50 1.50 0.55 0.50 0.25

O p t i o n a l : A p o l y f u n c t i o n a l a z i r i d i n e c r o s s l i n k i n g a g e n t , such as XAMA-7, can b e added t o t h i s f o r m u l a a t a l e v e l o f 9 t o 10 l b s / 1 0 0 g a l l o n s t o maximize a l l p h y s i c a l p r o p e r t i e s o f t h e enamel. Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : Pigment/Binder R a t i o : 0.6/1 . O P e r c e n t S o l i d s , W e i g h t : 45.7 P e r c e n t Sol i d s , Vol m e : 3 5 . 9 V i s c o s i t y @ 25C, KU: 100-105 Pounds/Gallon: 9.7 pH: 8 . 0 - 8 . 5 VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 208 Pounds/Gallon: 1 . 7

SOURCE: R e i c h h o l d Chemicals, F o r m u l a t i o n 2154-23

11 . 9

I n c . : Waterborne Handbook:

Miscellaneous

423

B a l l M i l l Paste-I Mapi c o Ye1 1ow 1000 Polywet ND-2 ( 2 5 % ) Nopco 1907 Water ( v a r i a b l e t o 100%)

58% 8% 0.05% 33.95%

B a l l M i l l Paste-I1 Mapico Y e l l o w 3100 P o l y w e t ND-2 (25%) Nopco KFS Methocel HG-400 Water ( v a r i a b l e t o 100%)

45% 8% 0.05% 0.45% 46.50%

B a l l M i l l Paste-I11 Mapico Red 297 Polywet ND-2 (25%) Nopco KFS Water ( V a r i a b l e t o 100%)

65% 6% 0.05% 28.95%

B a l l M i l l Paste-IV Mapico Brown 422 Polywet ND-2 ( 2 5 % ) Nopco KFS Water ( v a r i ab1 e t o 100%)

5 5% 8% 0.05% 36.95%

Formulae I and I 1 a r e used t o d e v e l o p optimum pigment l o a d i n g f o r y e l l o w i r o n o x i d e s ; Formula I 1 1 i s used t o d e v e l o p maximum pigment l o a d i n g f o r r e d , r o a s t e d copperas i r o n o x i d e s : Formula I V f o r brown and b l a c k i r o n o x i e s . SOURCE: U n i r o y a l Chemical G o . , I n c . : POLYWET ND-2 for C o l o r C o n c e n t r a t e s : Formulas

424

Water-Based Paint Formulations

C1e a r C o a t i n s and C o n c r e t e C u r i n s Membrane l b s / 1 0 0 Gal 23.80 29.80 9.00 5.80 0.13 0.13 3.00

Ingredient : S a n t i c i z e r 160 B u t y l Carbi t o 1 AMP 95 S u r f y n o l 104 F1 u o r a d FC-431 F1u o r a d FC-129 Dehydran 1293

M i x t h e above i n g r e d i e n t s and add t o t h e f o l l o w i n g w i t h m i x i n g : 50.00 325.80

Water P l i o l i t e 7104 (44% S o l i d s ) A f t e r mixing well,

add t h e f o l l o w i n g i n g r e d i e n t s i n o r d e r : 385.50 9.50

Water Ethylene Glycol Sol i d s Weight P e r c e n t : 21.2 S o l i d s Volume P e r c e n t : 20.2 Pounds Per G a l l o n : 8 . 4 VOC ( g m / l ) : 226.5 pH: 1 0 . 6 Freeze/Thaw, 5 C y c l e s : Pass V i s c o s i t y S t a b i l i t y , 30 days,

12OF: Pass

Age p a n e l p e r ASTM C-309 Meets MVTR Requirements o f ASTM C-309 Formula #1910-102-6 C o n c r e t e Sealer/CCM

(ASTM C 309 C o m p l i a n t )

Propyl Cellosolve S u r f y n o l 104H FC-129 Water Butyl D i propasol S a n t i c i z e r 160 28% Ammonium H y d r o x i d e M i x w e l l , t h e n add under a g i t a t ion : P l i o l i t e 7104

4.8 l b s 2.5 0.1 478 11.6 22 3 319

1. Pass ASTM C 309 2 . Pass oven s t a b i l i t y 120 deg F, 4 weeks 3. NVV 18% 4. P r o t e c t f r o m F r e e z i n g Note: I f 5 c y c l e s f r e e z e thaw s t a b i l i t y i s needed, s u b s t i t u t e 38 l b s o f w a t e r w i t h 35 l b s o f M e t h y l P r o p a s o l .

SOURCE: The Goodyear T i r e 6 Rubber Co.:

Formula 2074-40-5

Miscellaneous

425

C o r r o s i o n I n h i b i t o r Comparison i n an A i x D r y Waterborne A l k y d System % by Wei q h t 12.67 20.00 0.50 0.54 1.20 0.28 4.30

G r i n d (Pebble M i l l ) : C a r g i l l 7474 T i - P u r e R902 Sec-Butanol N-Butanol 2-Butoxyethanol 28 Ammoni a Water Letdown : C a r g i l l 7474 28 Ammonia n-Butanol 2-Butoxyethanol C o b a l t Hydrocure Activ 8 Water Corrosion I n h i b i t o r

14.10 0.90 1.10 0.90 0.58 0.10 42.83 1 .O% a c t i v e on t o t a l w e i g h t

Characteri s t i cs: T o t a l S o l i d s : 40.0% Pigment/Binder: 1/1 % Pigment: 20.0 % Resin S o l i d s : 20.0 pH: 8 . 5 Film Properties: S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS Cure: 7 Days a t Room Temperature F i l m Thickness: 0.8-1.0 m i l s

NACORR 1151 : P e n c i l Hardness: HB MEK Rubs ( 2 X ) : 9 NACORR 1351 : P e n c i l Hardness: HB MEK Rubs ( 2 x 1 : 13 NACORR 1651 : P e n c i l Hardness: H MEK Rubs ( 2 X ) : 15 NA-SUL 412: P e n c i l Hardness: B MEK Rubs ( 2 X ) : 7 NA-SUL MPD: P e n c i l Hardness: 28 M E K Rubs (2X): 10

Tukon Hardness: 7.46 G l o s s : 90.9 Tukon Hardness: 8.88 G l o s s : 91 . 8 Tukon Hardness: 9.28 Gloss: 92.6 Tukon Hardness: 5.22 Gloss: 92.9 Tukon Hardness: 5.85 Gloss 60: 9 3 . 4

SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-22

426

Water-Based Paint Formulations

C o r r o s i o n I n h i b i t o r Comparison i n a Waterborne P o l y e s t e r / Me1 a m i ne Bake System I n t h i s s t u d y , t h e NACORR l i n e o f l i q u i d c o r r o s i o n i n h i b i t o r s were compared t o s e v e r a l c o m m e r c i a l l y a v a i l a b l e c o m p e t i t i v e p r o d u c t s . The c o a t i n g used was a pigmented w a t e r b o r n e p o l y e s t e r / melamine enamel. A l l o f t h e i n h i b i t o r s were p o s t added a t a r a t e o f 1% a c t i v e i n g r e d i e n t on t h e t o t a l w e i g h t o f t h e c o a t i n g . S a l t Spray t e s t i n g was c a r r i e d o u t o v e r b o t h i r o n phosphated p a n e l s (BlOOO) and z i n c phosphated p a n e l s (B37). %_by Weiqht 18.00 24.00 4.00 0.69 1 .31

G r i n d (Pebble M i l l ) : C a r a i l l 7203 T i - P u r e R960 2-Butoxyethanol DMEA Water Letdown : C a r g i l l 7203 DMEA Cyme1 325 10% S i l w e t 7605 i n 2 - B u t o x y e t h a n o l Water Characteristics: T o t a l S o l i d s : 48.0% P i gment/Bi nder : 1/ 1 % Pigment: 2 4 . 0 % Resin S o l i d s : 24.0 P o l y e s t e r / M e l a m i ne: 75/25 pH: 8 . 5 5 Film Properties: S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS Cure: 15 m i n u t e s a t 300F (150C) F i l m Thickness: 0.9-1.1 m i l s

NACORR 1151 : Penci 1 Hardness 2H-3H MEK Rubs ( 2 X ) : 00 NACORR 1351 : Penci 1 Hardness 2H-3H 00 MEK Rubs ( 2 X ) : NACORR 1552: P e n c i l Hardness: 2H-3H MEK Rubs ( 2 X ) : 100 NA-SUL SRC-X: P e n c i l Hardness: 2H-3H MEK Rubs (2X): 100

Tukon Hardness: 2 5 . 6 Gloss 60: 9 4 . 0 Tukon Hardness: 25.9 Gloss 60: 9 4 . 7 Tukon Hardness: 24.7 G l o s s 60: 9 2 . 9 Tukon Hardness: 1 5 . 6 Gloss 60: 8 7 . 9

SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-23

6.00 1 .oo 7.50 1 .oo 36.50

Miscellaneous

G l o s s W h i t e T i l e - L i k e F o r m u l a t i o n XG-1052 Based on MAINCOTE TL-5 Polymer F o r B r u s h and R o l l e r A p p l i c a t i o n s

...

The c h o i c e and amount o f each i n g r e d i e n t i n F o r m u l a t i o n XG-105-2 a r e s i g n i f i c a n t t o t h e performance o f t h e c o a t i n g . S u b s t i t u t i o n s s h o u l d be e v a l u a t e d c a r e f u l l y . M a t e r i a1 s: A c r y l i c Component A : Methyl Carbi t o 1 Tamol 731 T r i t o n CF-10 P a t c o t e 519 T i P u r e R-900 HG

Pounds

Gal 1ons

45.0 10.8 2.0 0.5 225.0

5.26 1.18 0.22 0.07 6.48

G r i n d t h e above u s i n g a h i g h speed Cowles d i s s o l v e r f o r 25 m i n u t e s , t h e n l e t d o w n a t a l o w e r speed as f o l l o w s : 42.0 5.04 Water 1.94 E t h y l e n e G1y c o l 18.0 60.25 M a i n c o t e TL-5 (41 .5%) 517.9 2.35 21.6 Dalpad A 1.37 10.8 Texanol 0.23 Col l o i d 643 1.8 0.79 Sodium N i t r i t e (15% i n w a t e r ) 6.6 0.59 NH40H (14% NH3) 4.5 3.65 30.4 Water ) 0.27 NH40H (28% NH3) ) Premix 2.0 2.46 21 . 6 A c r y s o l RM-5 (30%) 1 1.96 Water 16.3 Epoxy Component 8 : Genepoxy 370 H-55 F o r m u l a t i o n Constants: PVC, %: 19.4 Volume S o l i d s , %: 3 3 . 3 Weight S o l i d s , %: 46.2 CARB (grams V O M / l i t e r - w a t e r ) : pH: 8 . 3 - 8 . 5

53.1

5.89

247

Typical Viscosities, KU/ICI: Component A : I n i t i a1 : 9 3 / 1 . 1 € q u i 1 ib r a t e d : 100/1.1 Components A t B: I n i t i a l : 95/1.1 6 hours: 95/1.0

SOURCE:

Rohm and Haas C o . : Maintenance and M a r i n e C o a t i n g s : MAINCOTE TL-5: F o r m u l a t i o n XG-105-2

427

428

Water-Based Paint Formulations

Gloss W h i t e T i l e - L i k e F o r m u l a t i o n XG-1-3 Based on MAINCOTE 3JL-5 Polymer. . . F o r Spray -1 ic a t i 011s The c h o i c e and amount o f each i n g r e d i e n t i n t h i s f o r m u l a t i o n a r e s i g n i f i c a n t t o t h e performance o f t h e c o a t i n g . S u b s t i t u t i o n s s h o u l d be e v a l u a t e d c a r e f u l l y . M a t e r ia1 s i A c r y l i c Component A : Methyl Carbit o 1 Tamol 731 T r i t o n CF-10 P a t c o t e 519 T i - P u r e R-900 HG

Pounds

Gal l o n s

46.7 11.2 2.0 0.5 233.4

5.45 1.22 0.22 0.07 6.72

G r i n d t h e above u s i n g a h i g h speed Cowles d i s s o l v e r f o r 25 m i n u t e s , t h e n l e t d o w n a t a l o w e r speed as f o l l o w s : Water 84.0 10.08 M a i n c o t e TL-5 (41.5%) 537.2 62.48 Dalpad A 22.4 2.44 Texanol 11.2 1.41 E x p e r i m e n t a l Rheology M o d i f i e r OR-708 (35%) 1 . 9 0.21 Sodium N i t r i t e (15% i n w a t e r ) 6.6 0.79 NH40H (14% NH3) t o a d j u s t t o pH 8.3-8.8 5.0 0.64 Water 18.0 2.16 Epoxy Component 8 : Genepoxy 370 H-55 Formulation Constants: PVC, %: 19.4 Volume S o l i d s , %: 3 4 . 6 Weight s o l i d s , %: 4 7 . 0 CARB (grams V O M / l i t e r - w a t e r ) :

55.1

6.11

214

Spray I n f o r m a t i o n : P r e s s u r e P o t Spray Gun ( D e V i l b i s s MBC): F l u i d t i p No.: AV-15FX N o z z l e cap N o . : 704 P o t p r e s s u r e : 28 p s i Recommended f i l m t h i c k n e s s : 5 t o 7 wet m i l s (1.7 t o 2.4 d r y m i l ) Typical Viscosities, KU/ICI: Component A : I n i t i a l 82/0.4 E q u i l i b r a t e d 94/0.4 Component A + 0 : I n i t i a l : 93/0.4 6 hours: 93/0.4 SOURCE: Rohm and Haas Co.: M a i n t e n a n c e and M a r i n e C o a t i n g s : MAINCOTE TL-5: F o r m u l a t i o n XG-105-3

Miscellaneous

G l o s s W h i t e T i l e - L i k e F o r m u l a t i o n XG-105-4 BaseM a i n c o t e TL-5 Polymer F o r B r u s h and R o l l e r A p p l i c a t i o n s Materials: A c r y l i c Component A: Methyl Carbi t o 1 Tamol 731 T r i t o n CF-10 P a t c o t e 519 T i - P u r e R-900 HG

___ Pounds

Gallons

44.0 10.6 2.0 0.5 220.0

5.14 1 .15 0.22 0.07 6.34

G r i n d t h e above u s i n g a h i g h speed Cowles d i s s o l v e r f o r 25 m i n u t e s , t h e n l e t d o w n a t a l o w e r speed as f o l l o w s : 84.9 10.19 Water E x p e r i m e n t a l Rheology M o d i f i e r QR-1001 23.5 2.64 (20.0%) 506.4 Mai n c o t e TL-5 ( 4 1 .5%) 58.91 1.94 18.0 Ethylene Glycol 21.1 Dalpad A 2.30 1.34 10.6 Texanol 1. a 0.23 Col l o i d 643 Sodium N i t r i t e (15% i n w a t e r ) 0.79 6.6 0.59 NH40H (14% NH3) ( t o a d j u s t t o pH 8 . 3 - 8 . 8 ) 4.5 2.40 20.0 Water Epoxy Component E : Genepoxy 370 H-55 F o r m u l a t i o n Constants: PVC, %: 1 9 . 4 Volume S o l i d s , %: 3 2 . 6 Weight S o l i d s , %: 44.7 CARE (grams V O M / l i t e r - w a t e r ) :

51.9

5.75

254

Typical Viscosities (KU/ICI): Component A : I n i t i a l 90/1 . 7 E q u i l i b r a t e d 97/1.8 Components A&E: I n i t i a1 9 6 / 1 . 7 6 Hours: 9 6 / 1 . 7

SOURCE:

Rohm and Haas Co.: Maintenance and M a r i n e C o a t i n g s : MAINCOTE T L - 5 : F o r m u l a t i o n X G - 1 0 5 - 4

429

430

Water-Based Paint Formulations

Gray EM1 Shielding Coating Materi a1 : Water Ammoni um Hydroxi de Bentone EW Cell osi ze QP-4400

Lbs. 168.7 1.9 5.0 6.2

Gals . 20.25 0.25 0.24 0.54

Cowles grind the above four materials for 20-25 minutes, then add the following in order under good agitation. Arolon 850-W-45 Foamaster 0 Butoxy Ethanol Dibutyl Phthalate Nickel HCT Surfynol 104H Ammoni um Hydroxi de

510.9 1.9 58.2 11.1 700.0 4.0 5.6

Analysis: Pigment Volume Concentration, Percent: 2 6 . 3 Pigment/Binder Ratio: 3 / 1 Percent Solids, Weight: 64.8 Percent Solids, Volume: 3 7 . 2 Viscosity @ 25C, KU: 80-90 Pounds/Gallon: 14.65 pH: 8.2-8.8

VOC (excluding water): Grams/Liter: 133 Pounds/Gallon: 1 . 1 SOURCE: Reichhold Chemicals, Inc.: Waterborne Handbook: Formulation 2154-13 Revised

59.00 0.25 7.75 1.25 9.80 0.50 0.75

Miscellaneous

431

Green. High p H F o r m u l a t i o n T h i s f o r m u l a t i o n r e p r e s e n t s an a l l - p u r p o s e f o r m u l a t i o n f o r f a r m implement o r g e n e r a l maintenance t y p e c o a t i n g s . P a r t s Per Hundred Mater ia1 s : Weight Ratio*(Volume B a s i s 1 Pebble M i l l G r i n d : t o 7-1/2 N . S . Chrome Oxide Green X-1134 37.3 0.87 I m p e r i a l 8 r a z i 1 Ye1 low X-2866 4.9 0.42 P h t h a l o B1 ue 8T-417D 0.7 0.05 A c r y l o i d WR-748 (60%) 115.1 13.83 Water 310.7 37.27 NH40H** (28%) 6.5 0.78 A d j u s t pH t o 8 . 8 + - 0 . 1 w i t h ammonim h y d r o x i d e , i f necessary. Letdown : Above G r i n d A c r y l o i d WR-748 (60%) Butyl Cellosolve Water NH40H** (28%)

475.2 99.3 34.2 240.9 7.6

53-22 11.93 4.56 28.89 0.90

M i x w e l l , t h e n add: C o b a l t Naphthenate Manganese Naphthenate Activ 8

2.1 0.4 1.5

0.26 0.05 0.19

A d j u s t pH t o 8 . 8 + - 0 . 1 w i t h 28% ammonium h y d r o x i d e * * ; i f necessary Reduce t o s p r a y v i s c o s i t y o f 55+-5" #4 F o r d Cup w i t h 80/20 b y volume w a t e r / c o s o l v e n t . Formulation Constants: P i g m e n t / B i n d e r : 25/75 W a t e r / c o s o l v e n t r a t i o ( b y volume): 80/20 D r i e r l e v e l : 0.10% Co/O.O2% Mn/1.2% A c t i v 8 % S o l i d s : 19-21 VOC: l b . / g a l . l e s s w a t e r : 3.83 g m s . / l i t e r l e s s w a t e r : 459

**

*

DMAE can be s u b s t i t u t e d f o r ammonia i f a b a k i n g f i n i s h i s d e s i r e d . S o l i d s i n such a system i n c r e a s e t o 20-22%. U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result

.

SOURCE:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYLOID WR-748: F o r m u l a t i o n WR-748-8

432

Water-Based Paint Formulations

Green,

Low pH.

H i g h Solids Formulation

T h i s f o r m u l a t i o n i s a l o w pH, h i g h e r s o l i d s v e r s i o n o f p r e v i o u s f o r m u l a t i o n . I t s h o u l d be used b y t h o s e who can e x e r c i s e r e l a t i v e l y t i g h t pH c o n t r o l . P a r t s Per Hundred Weight R a t i o * I V o l u m e B a s i s 1 Mater ia 1 s : Pebble M i 11 G r i n d t o 7-1/2 N . S . : Chrome Oxide Green X-1134 52.3 1.22 I m p e r i a1 B r a z i 1 Ye1 l o w X-2866 6.9 0.59 P h t h a l o 81 ue BT-417D 0.9 0.07 A c r y l o i d WR-748 (60%) 161.3 19.39 Water 435.4 52.22 NH40H (28%)** 9.2 1.10 A d j u s t pH t o 8 . 8 + - 0 . 1 w i t h ammonium h y d o x i d e , i f n e c e s s a r y . Letdown : Above G r i n d A c r y l o i d WR-748 Water

(60%)

Mix w e l l , t h e n add: C o b a l t Naphthenate Manganese Naphthenate Activ 8

666.0 139.2 66.6

74.59 16.72 7.99

3.0 0.7 2.2

0.37 0.07 0.27

A d j u s t pH t o 8 . 0 + - 1 . 0 w i t h 28% ammonium h y d r o x i d e * * , i f n e c e s s a r y . Reduce t o s p r a y v i s c o s i t y w i t h w a t e r t o 45+-5" #4 F o r d Cup. F o r m u l a t i o n Constants: P i g m e n t / B i n d e r : 25/75 W a t e r / c o s o l v e n t r a t i o ( b y volume): D r i e r l e v e l : 0.1% % S o l i d s : 27-28 VOC: l b . / g a l . l e s s w a t e r : 3.24 g m s . / l i t e r l e s s w a t e r : 388

** *

80/20

DMAE can be s u b s t i t u t e d f o r ammonia i f a b a k i n g f i n i s h i s d e s i r e d . S o l i d s i n such a system i n c r e a s e t o 28-30%. U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result .

SOURCE:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYLOID WR-748: F o r m u l a t i o n WR-748-7

Miscellaneous

433

H i Q h Performance T r a f f i c P a i n t Lb/100 n a l l o n s

73 21 5 6 23 24 29 4

Isopropyl Alcohol M e t h y l Propasol C o l l o i d 226 T r i e t h y l ami ne S a n t i c i z e r 160 Butyl Dipropasol Water Nopco NQW Mix w e l l ;

t h e n add:

31 2

P l i o l i t e 7103 Mix w e l l ;

t h e n add:

130 21 260 208

T i t a n o x 2160 M i c a 325 Atomi t e M i n u s i l 30 HSD t o 3 N . S .

Then add:

104

P l i o l i t e 7103 L b / g a l 1on : 12.20 VOC: 1.83 l b / g a l = 2 2 0 g/1 PVC: 52% NVV: 50% NVM: 68% No P i c k Up: Pass 5 m i n u t e s @ 75F and 58% R . H . Pass 5 m i n u t e s @ 36F and 75% R.H. C o l d Temperature Coalescence: Pass 36F and 75% R . H . Oven S t a b i l i t y : Pass 1 week 120F Freeze Thaw S t a b i l i t y : Pass 5 c y c l e s .

SOURCE: The Goodyear T i r e & Rubber Co.:

Formula 2074-55-1

434

Water -Based Paint Formulations

__ Red-. Semi _ ______ -Gloss T r a f f i c Pai n t C a r g i l l Water R e d u c i b l e S h o r t TOFA A l k y d 74-7461 M-P-A 1075 Aqueous Ammonia 28%

Byk-301 Byk-020 T o l u i d i n e Red RD-0027 X-2806 Red Orange Mapico Red 516 Medium Atomi t e D e i o n i z e d Water

_ Pounds __

Gal 1 ons

137.7 4.4 11.6 1.2 1.3 30.4 10.1 4.5 252.4 153.5

16.20 0.64 1.55 0.15 0.18 2.44 0.22 0.12 11.18 18.42

120.5 6.1 1.3 3.6

13.60 0.81 0.19 0.45

19.4 5.9 1.3

2.56 0.71 0.16

250.6 2.6

30.08 0.34

Sand M i l l t o a 6 Hegman C a r g i 11 Water R e d u c i b l e Chain Stopped A1 kyd 74-7487 Aqueous Ammonia 28% P a t c o t e 577 B u t y l Carbi t o 1 Premix t h e f o l l o w i n g , t h e n add: E t h y l e n e G l y c o l Monopropyl E t h e r 12% Z i r c o n i u m Hydro Chem A c t iv-8 D e i o n i z e d Water E x k i n No. 2

Pai n t P r o p e r t ies : % N o n v o l a t i l e (By W e i g h t ) :

48.83 (By Volume): 35.21 Pigment t o B i n d e r R a t i o : 1 . 5 0 Pigment Volume C o n c e n t r a t i o n : 39.89 Weight Per G a l l o n : 10.18 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 2 . 0 9 ( G r a m s / L i t e r ) : 250 Water:Cosolvent Weight- R a t i o ; 6 0 . 0 0 : 2 0 . 0 0 pH: 8 . 7 2 V i s c o s i t y Krebs-Stormer (KU): 75 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r Dry Substrate: Sold Rolled Steel Gloss ( 6 0 / 2 0 ) : 51/11 P e n c i l Hardness: Pass 7 6 % C r o s s h a t c h Adhesion: 100 Impact ( I n . L b s . ) : D i r e c t : 150 Reverse: 50 SOURCE: C a r g i l l ,

Inc.:

CARGILL F o r m u l a r y : Formula P1887-36E

Miscellaneous

RhoDlex WL-81/EpOtUf

435

38-690 (Epoxy E s t e r ] B l e n d Systen,

M a t e r i a1 s : E p o t u f 38-690 Aquacat Magnacat E t h y l e n e g l y c o l monobutyl e t h e r T r i e t h y l ami ne Water Tamol 165 P a t c o t e 550 Raven 2000

P a r t s Der Hundred Weight R a t i o * Volume B a s i s 26.7 3.18 0.12 1.o 0.12 1 .o 1 .80 13.5 0.39 2.3 15.05 125.4 0.30 2.6 0.07 0.5 2.25 32.8

B a l l m i l l t o 7 1 / 2 + N.S., add t h e f o l o w i n g i n o r d e r : E p o t u f 38-690 Triethylamine Water

144.5 11.7 125.4

17.21 1.93 15.05

M i x w e l l ( r e c h e c k g r i n d ) and add t h e f o l l o w i n g i n o r d e r w i t h good a g i t a t ion : Rhopl ex WL-81 279.1 32.84 T r i t o n X-405 (35% NV) 0.56 4.7 23.0 2.48 S a n t i c i z e r 160 31.4 3.78 Water 23.3 2.91 HEI-SCORE-XAB (10%) F o r m u l a t i o n Constants: Pounds/Gallon: 8 . 5 pH: 8 . 9 V i s c o s i t y , c p s . : 330 G r i n d : 7 1/2+ S o l i d s % ( w t . ) : 34.5 ( v o l . ) : 31.3 P/B: 11/89 E p o t u f 38-690/Rhoplex WL-81 : 51 /49 VOC ( l b s . / g a l . ) : 1 . 5 2 % on Polymer S o l i d s : E t h y l e n e g l y c o l monobutyl e t h e r : 27.5 S a n t i c i z e r 160: 9 . 7

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f l a c q u e r w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result.

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : RHOPLEX WL-81: F o r m u l a t i o n WL-61-5

436

Water-Based Paint Formulations

R h o D l e x WL-bl/EDotuf 38-690 (EPOXY E s t e r ) B l e n d System _(Chromate C o n t a i n i nn) Materials: E p o t u f 38-690 Aquaca t Magnacat E t h y l e n e g l y c o l monobutyl e t h e r Mix w e l l ,

P a r t s p e r Hundred Weight R a t i o * ( V o l u m e B a s i s ) 26.6 3.17 1.o 0.12 0.12 1.o 13.5 1.79

t h e n add i n o r d e r :

Triethylamine Water Tamol 165 P a t c o t e 550 Raven 2000 Oncor F-31

2.3 125.1 2.6 0.5 32.7 9.7

B a l l m i l l t o 7 1 / 2 N.S., add t h e f o l l o w i n g i n o r d e r : E p o t u f 38-690 144.1 T r i e t h y l ami ne 11.7 Water 125.1

0.39 15.01 0.30 0.07 2.25 0.29 17.16 1.93 15.01

M i x well

( r e c h e c k g r i n d ) and add t h e f o l l o w i n g i n o r d e r w i t h good a g i t a t i o n : Rhopl ex WL-81 278.2 32.74 4.6 0.56 T r i t o n X-405 (35% NV) 22.9 2.47 S a n t i c i z e r 160 31 . 3 3.77 Water HEI-SCORE-XAB (10%) 23.2 2.90 Formulation Constants: Pounds/Gal 1on : 8.6 pn: 8 . 9 V i s c o s i t y , c p s . : 290 Grind: 7 1/2 S o l i d s % ( w t . ) : 35.3 ( v o l . ) : 31.5 Epotuf 38-690/Rhoplex WL-81: 51/49 VOC ( l b s . / g a l . ) : 1 . 5 2 % on Polymer S o l i d s : E t h y l e n e g l y c o l monobutyl e t h e r : S a n t i c i z e r 160: 9 . 7

* **

27.5

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f l a c q u e r w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l result S t r o n t i u m Chromate can be used i n p l a c e o f t h e Oncor F-31.

.

SOURCE: Rohm and Haas C o . : I n d u s t r i a l C o a t i n g s : RHOPLEX WL-81: F o r m u l a t i o n WL-81-4

Miscellaneous

T r a f f i c Markina P a i n t

Lbs.

M a t e r i a1 : Svnthemul 97-799 Nbpcosperse 44 C o l l o i d 643 Premix t h e f o l l o w i n g , Methyl Carbi t o 1 N a t r o s o l 250MR T i t a n o x 2020 Durami t e S i l i c a #19 H i gh speed d i s p e r s e r , Water 28% Ammonia I g e p a l CO-830 C o l l o i d 643 Synthemul 97-799 Methanol Polyphase AF-1

46.60 0.70 0.14

22.9 1 .o 200.0 401.4 137.9

2.69 0.09 5.81 17.84 6.25

0.6 1.o 2.0 3.0 147.9 10.0 5.0

0.08 0.12 0.26 0.40 17.00 1.51 0.51

t h e n add:

1 5 m i n u t e s maxi mum.

Analysis: Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 4 9 . 5 P e r c e n t Sol ids, Weight : 7 5 . 5 P e r c e n t S o l i d s , Volume: 6 0 . 3 I n i t i a l V i s c o s i t y , KU: 8 0 . 0 Pounds/Gal l o n : 1 3 . 4 6 pH: 8 . 9 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 5 9 Dry Time, 3 m i l s Wet, M i n . : < 1 5 (77F D r y ) B1 is t e r Resi s t a n c e : Exc. Wet Adhesion ( A l k y d ) : Exc. E a r l y Glass (Wet) Adhesion: Exc. C o n t r a s t R a t i o ( 3 M i l s Wet): 0 . 9 9 0

SOURCE:

Gals.

405.42 7.0 1 .o

R e i c h h o l d Chemicals, F o r m u l a t i on 799-02

I n c . : Waterborne Handbook:

437

438

Water-Based Paint Formulations

Wash Coat Based on Emulsion E-2774 T h i s l o w s o l i d s wash c o a t i s used as a p a r t i a l s e a l e r between s t a i n s t o h o l d i n c o l o r s and p r o v i d e a more u n i f o r m s u r f a c e f o r subsequent s t a i n s t o be a p p l i e d t o . Premix 1 t h r o u g h 4 and add t o Emulsion E-2774 ( 5 ) w i t h a g i t a t i o n . Add L i q u a z i n c AQ-90 ( 6 ) with agitation. Materials: 1 . Deefo 3000 2. B u t y l C a r b i t o l 3. B u t y l C e l l o s o l v e 4. Water

Weight Pounds 0.4 6.5 16.4 10.9

Volume Gal 1ons 0.1

0.8 2.2 1.3

5. Emulsion E-2774

170.1

19.7

6. L i q u a z i n c AQ-90 (50%) 7. 14% Ammonia 8 . Water

0.5 6.0 625.9

0.0 0.7 75.1

F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w t / v o l ) : 7 . 9 / 7 , 2 pn: 7 . 0 V i s c o s i t y , #2 Zahn, seconds: 15 seconds VOC*, g / l i t e r : 27 l b s / g a l l o n : .23 C o a l e s c e n t , w t % Polymer S o l i d s : B u t y l Cel l o s o l v e : 25 B u t y l C a r b i t o l : 10 Freeze/Thaw S t a b i l i t y : P r o t e c t f r o m F r e e z i n g Heat Age S t a b i l i t y : S a t i s f a c t o r y

*

C a l i f o r n i a ' s South Coast A i r Management D i s t r i c t a l l o w s VOC's f o r wash c o a t s w i t h l e s s t h a n one pound o f s o l i d s p e r g a l l o n t o be c a l c u l a t e d on t h e b a s i s o f pounds o f VOC per g a l l o n p l u s water. Accordingly, t h a t convention i s used h e r e .

SOURCE: Rohm and Haas Co.:

F o r m u l a t i o n WR-74-3

Miscellaneous

Water-Borne A i r D r v P r i m e r and Topcoat Svstem Primer Formulation

Materials: R e s i n WB-408 (65% NVM) Ammoni um h y d r o x i de, 28% Deionized water C o b a l t n a p h t h e n a t e , 6% ( 1 ) A n t i - s k i n agent ( 2 ) Red i r o n o x i d e ( 3 ) Calcium carbonate ( 4 ) China c l a y ( 5 ) Talc (6)

P a r t s by weiqht 292.7 15.7 356.0 2.9 0.9 97.6 146.4 29.3 58.5

Properties: N o n - v o l a t i l e m a t e r i a l (NVM), w t % : 52.2 V i s c o s i t y , #4 F o r d Cup, sec: 30-35 pH: 8 . 0 D r y t i m e s a t 2 0 C , 50% RH: s e t t o t o u c h , m i n : 20-30 t a c k - f r e e , min: 60 d r y h a r d , min: 120 Compounding p r o c e d u r e : 1 . N e u t r a l i z e r e s i n w i t h ammonium h y d r o x i d e and add 260 p a r t s water. 2 . Add d r i e r and a n t i - s k i n a g e n t . 3 . Add f i l l e r s and p i g m e n t and s t i r i n t o r e s i n s o l u t i o n . 4. Charge m i x t u r e t o a p e b b l e m i l l and g r i n d o v e r n i g h t . 5. A d j u s t t o a p p l i c a t i o n v i s c o s i t y w i t h remaining water. ( 1 ) P r o d u c t o f t h e H u l s America I n c . (2) E x k i n #1 ( 3 ) R-4098 ( 4 ) Duramite ( 5 ) ASP 400 ( 6 ) N y t a l 300

SOURCE: Amoco Chemical Co.: Water-Borne A i r D r y i n g A l k y d s Based on Amoco I P A and TMA: Formula T a b l e 4

439

440

Water-Based Paint Formulations

Water-Borne A i r D r y P r i m e r and Topcoat System ToDcoat F o r m u l a t i o n Materials: R e s i n WB-408 165% N V M I Ammonium h y d r o x i d e , 28% Dei o n i zed w a t e r C o b a l t naphthenate, 6% ( 1 ) Manganese naphthenate, 6% ( 1 ) D r i e r accelerator (2) A n t i - s k i n agent ( 3 ) Flow a d d i t i v e ( 4 ) Titanium dioxide (5) P r o p e r t ies : N o n - v o l a t i l e m a t e r i a l (NVM), w t % : V i s c o s i t y , #4 F o r d Cup, sec: 44 pH: 9 . 3 Dry t i m e s a t 20C, 50% RH: s e t t o t o u c h , min: 30-45 t a c k f r e e , h r : 6.5-7.0 d r y hard: overnight

P a r t s by w e i s h t 320.6 27.4 348.9 5.4 2.7 1.4 1.4 0.7 291.5 50.0

Compounding Procedure: 1 . N e u t r a l i z e r e s i n w i t h ammonium h y d r o x i d e and add 320 p a r t s water. 2. Add d r i e r s , a n t i - s k i n agent and f l o w a d d i t i v e . 3 . Add pigment and s t i r i n t o r e s i n s o l u t i o n . 4 . Charge m i x t u r e t o a p e b b l e m i l l . G r i n d o v e r n i g h t t o a Hegman Grind o f 7+. 5. Adjust t o a p p l i c a t i o n v i s c o s i t y w i t h remaining water. (1) (2) (3) (4) (5)

P r o d u c t o f H u l s America I n c . Activ-8 E x k i n #1 FC-430 T i - P u r e R-900

SOURCE: Amoco Chemical Co.: Water-Borne A i r D r y i n g A l k y d s Based on AMOCO I P A and TMA: Formula T a b l e 5

Miscellaneous

441

Water R e d u c i b l e A1 k y d I n a r e d ie n t : Chempol 10-0091 Butyl Cellosolve Water TEA Ammoni um H y d r o x i d e Byk 301 Y e l l o w I r o n Oxide Hal ox SZP-391 Snowf 1ake Beaverwhi t e 325 K o r t h ix Chempol 10-0091 B u t y l C e l l os01 ve Water TEA Ammonium H y d r o x i d e C o b a l t Hydrocure D r i e r C a l c i um H y d r o c u r e D r i e r Zirconium Hydrocure D r i e r Activ 8 N-Butanol Water

Lbs/100 G a l s 150.0 25.0 200.0 4.5 4.0 1. o

Grams/Li t e r 180.0 30.0 240.0 5.4 4.8 I .2

75.0 33.0 75.0 75.0 1.o

90.0 40.0 90.0 90.0 1.2

100.0 30.0 150.0 3.5 4.0

120.0 36.0 180.0 4.2 4.8

1.5 3.5

1.8 4.2 2.4 1.2 30.0 39.4

2.0

1.o 25.0 32.8

PVC: 40.0% D e n s i t y : 9 . 4 l b s / g a l (1193 g / L ) Weight S o l i d s : 45.9% Volume S o l i d s : 32.0% VOC: 2.94 l b s / g a l (350 g / L )

SOURCE: H a l o x Pigments: HALOX SZP-391 i n a Water R e d u c i b l e A l k y d

442

Water-Based Paint Formulations

W a t e r - R e d u c i b l e A u t o m o t i v e Under-Hood C o a t i n g B l a c k Inqredients: Chempol 10-0453 Byk P-104s S u r f y n o l 1048C Ammonia, 28% Water Raven #I4 Powder

Pounds 71.79 1.58 2.51 5.02 100.49 15.78

Gal l o n s 8.47 0.20 0.33 0.67 2.06 2.02

Premix f i r s t t h r e e i n g r e d i e n t s and m i x w e l l . A d d ammon a s l o w l y and w i t h good a g i t a t i o n . M i x u n t i l w e l l i n c o r p o r a t e d . Add t h e w a t e r i n t h e same manner and mix w e l l . Load m i x t u r e i n t o t h e b a l l m i l l f o l l o w e d by t h e b l a c k p i g m e n t . Run i n s t e e l b a l l m i l l t o a #7 Hegman. A d j u s t g r i n d v i s c o s i t y a n d / o r wash m i l l w i t h w a t e r f r o m b e l o w . L e t down w i t h : Chempol 10-0453 262.87 31 . O O Ammonia, 28% 15.07 2.02 2-butoxyethanol 20.10 2.68 NuoCure CK-10 9.36 1.15 NuoCure Mn 7.80 1.05 Byk 301 293.97 35.29 Water 293.97 35.29 Water ( h o l d t o a d j u s t v i s c o s i t y ) 25.00 3.00 Add ammonia t o t h e r e s i n s l o w l y and w i t h good a g i t a t i o n ; m i x w e l l . Premix c o s o l v e n t s , d r i e r s , and Byk 301. Add t h i s m i x t u r e to t h e n e u t r a l i z e d r e s i n w i t h a g i t a t i o n . M i x w e l l , t h e n add t h e w a t e r s l o w l y w i t h c o n t i n u e d a g i t a t i o n . Add t h i s m i x t u r e t o t h e g r i n d w i t h a g i t a t i o n and mix w e l l . A l l o w t h e p a i n t t o s t a n d o v e r night. Check t h e pH and a d j u s t w i t h ammonia i f necessary. Use t h e “ a d j u s t v i s c o s i t y ” water t o b r i n g t h e v i s c o s i t y o f t h e c o a t i n g t o spec a t room t e m p e r a t u r e . Properties: T o t a l s o l i d s , % by w e i g h t : 31.11 T o t a l s o l i d s , % by volume: 26.46 Wei g h t / g a l l o n : 8.40 1b s / g a l PVC: 3.80% Pigment/binder r a t i o : 0.06 VOC - w a t e r : 2.91 l b s / g a l V i s c o s i t y , #2 Zahn cup: 30” pH: 8 . 5 S u b s t r a t e : 8-1000 CRS Cure: 1 week a i r d r y S e t - t o - t o u c h , mins. : 25 Dust f r e e , m i n s . : 30 Tack f r e e , m i n s . : 60-65 D r y t h r o u g h , h o u r s : 6-8 h o u r s DFT: 1 . 1 - 1 . 3 m i l

SOURCE:

Freeman Polymers D i v i s i o n : CHEMPOL 10-0453-C

Formulation

Miscellaneous

Water Reduci b l e Epoxy :

Pol yo1 Modi f ied-B

Grind: Epoxy E s t e r P-2017-S-11 T r i e t h y l ami ne K-FLEX 188 (75% i n IPA) Water T i t a n o x 2020 Byk 301 Letdown : Cyme1 303 Water Enamel C h a r a c t e r i s t i c s : Epoxy/Pol yo1 /Me1 ami ne: 60/10/30 Enamel s o l i d s , w t %: 43.2 TRS, W t %: 2 1 . 2 P i gment/Bi n d e r : 0.94/1 VOC, C a l c . ( l b s / g a l ) : 0.95 Film Properties: S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS Cure: 1 5 ' a t 300F. F i l m Thickness: 0.7-0.8 m i l E p o x y / P o l y o l / M e l a m i n e : 60/10/30 P e n c i l Hardness: 2-3H MEK Rubs: 200+ I m p a c t R e s i s t a n c e , (in-lbs): D i r e c t : 60-70 Reverse: 5-10 60 G l o s s : 87 S a l t Spray, 150 h r s . mm C r e e p / B l i s t e r : 0-3 Scat/NA 50C Water Soak, 500 h r s . 60 G l o s s / B l i s t e r : 83/VLT 9 QUV*, 60 G l o s s : 600 h r s : 55 1000 h r s : 42

*

8 h r s . UV 50C, 4 h r s . H u m i d i t y , 40C

Enamel S t a b i 1 it y , 50C: N o . 4 F o r d Cup, Seconds a t 25C: 60/10/30 : I n i t i a l : 26" 1 Week: 236" 2 Weeks: S o f t Paste, Too V i s c . t o t e s t SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-BB

97.7 7.8 14.1 75.0 99.5 3.0 31 . 8 169.0

443

444

Water-Based Paint Formulations

Water R e d u c i b l e A c r y l i c Enamel : - P o l y 0 1 M o d i f i e d WR-7 demonstrates t h e advantages o f f o r m u l a t i n g w i t h K-FLEX 188 p o l y 0 1 as a m o d i f i e r i n a w a t e r r e d u c i b l e a c r y l i c c o a t i n g . The a d d i t i o r : o f a s u i t a b l e c o s o l v e n t t o t h e p o l y 0 1 such as isopropanol w i 1 render i t water r e d u c i b l e a t t y p i c a l m o d i f i c a tion levels of 0-20% on t o t a l r e s i n s o l i d s . K-FLEX 188 improves s o l v e n t , impact QUV and s a l t s p r a y c o r r o s i o n r e s i s t a n c e p r o p e r ties. Grind: T i t a n o x 2020 A c r y s o l WS-68 Water Butyl Cellosolve n-Butanol DMEA

480 126.3 149.4 21.4 20.0 2.9

Pebble M i l l G r i n d O v e r n i g h t Letdown : Grind A c r y s o l WS-68 Water n-Butanol Dow C o r n i n g No. 57 (30% i n B u t y l C e l l s o l v e ) DMEA (10% i n Water) Cyme1 303 K-Flex 188 (50% i n IPA) Enamel C h a r a c t e r i s t i c s : T o t a l S o l i d s , %: 48.3 P i gment/Bi nder : 40/60

Acrylic/Polyol/Melamine: 60/10/30 T o t a l Resin S o l i d s , %: 29.0 VOC, C a l c . ( l b s / g a l ) : 1.38 pn: 7 . 8 V i s c o s i t y , Sec. ( N o . 4 F o r d Cup): 19 Film Properties: S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS Cure: 3 0 ' a t 275F. F i l m Thickness: 0.6-0.7 m i l A c r y l ic / P o l y o l / M e l ami n e : 60/10/30 I.No C a t a l y s t : P e n c i l Hardness: 2-3H MEK Rubs: 200+ 11. C a t a l y s t : 0.8% Nacure X49-110 P e n c i l Hardness: 2-3H MEK Rubs: 200+

on TRS:

SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-78

326.4 412.3 114.7 6.9 1.9 5.1 88.14 58.76

Miscellaneous

445

W h i t e , Hiqh pH. General A l l - P u r p o s e Ambient Cure System with an O p t i m u m B a l a n c e f o r Key P r o p e r t y Development Materials: R o l l e r M i l l G r i n d : t o >7-1/2 N . S T i t a n i u m d i o x i d e ( T i - P u r e R-902) A c r y l o i d WR-748 (60%) Butyl Cellosolve**

P a r t s p e r Hundred Weight R a t i o * ( V o l u m e B a s i s ) 101.9 98.0 3.8

2.98 11.79 0.51

Letdown : Above G r i n d A c r y l o i d WR-748 (60%) B u t y l Cel l o s o l v e * * Water NH40H (28%)

203.7 109.2 37.9 207.8 16.3

15.28 13.12 5.05 24.91 1.96

Mix w e l l t h e n add***: C o b a l t Naphthenate Manganese Naphthenate A c t i v B (as supplied)

2.1 0.4 1.5

0.26 0.05 0.19

326.5

39.15

M i x w e l l t h e n add: Water

A d j u s t pH t o 8 . 8 + - 0 . 1 w i t h NH40H f necessary. Reduce t o s p r a y v i s c o s i t y o f 55+-5" #4 F o r d Cup w i t h 80/20 by volume w a t e r / B u t y l C e l l o s o l v e ; add 0.1% Byk-301 on t o t a enamel w e i g h t , i f d e s i r e d . F o r m u l a t i o n Constants: P i Qment/Bi n d e r : 45/55 W a t e r / c o s o l v e n t r a t i o ( b y volume) : 80/20 D r i e r l e v e l : 0.10% Co/O.O2% Mn/1.2% A c t i v 8 % S o l i d s : 25+-1 VOC: l b . / g a l . l e s s Water: 3 . 7 6 g m s . / l i t e r l e s s w a t e r : 451

**

*** *

Propasol P can be s u b s t i t u t e d f o r B u t y l C e l l o s o l v e , and w i l l r e s u l t i n a system w i t h a s l i g h t l y reduced t a c k - f r e e t i m e b u t w i t h somewhat reduced g l o s s . For a system w i t h b e t t e r c o l o r and b e t t e r p r o j e c t e d e x t e r i o r d u r a b i l i t y , a d r i e r system of 0.15% C o b a l t / O . l 5 % C a l c i u m (Naphthenate) i s recommended. On t h e above f o r m u l a t i o n , i n l i e u o f l i s t e d d r i e r s , add 1 . 5 g C o b a l t Naphthenate and 2.39 Cal c i um Naphthenate. U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result

.

Source: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYLOID WR-740: F o r m u l a t i o n WR-748-1

Water-Based Paint Formulations

446

W h i t e , Low DH, H i g h S o l i d s F o r m u l a t i o n Based Qn-ACryl o i d WR-748 Resi n ( 1 1 P a r t s Per Hundred Weight R a t i o * (Volume B a s i s )

_____ Materials: R o l l e r M i l l G r i n d : 7-1/2 N . S . : T i t a n i u m d i o x i d e ( T i - P u r e R-902) A c r y l o i d WR-748 (60%) B u t y l Cel l o s o l ve**

148.8 143.3 5.6

4.35 17.22 0.75

Letdown : Above G r i nd A c r y l o i d WR-748 (60%) Water NH40H (28%)

297.7 159.6 469.8 11.9

22.32 19.17 56.33 1.43

M i x w e l l , t h e n add***: C o b a l t Naphthenate Manganese Naphthenate Activ 8

3.0 0.6 2.2

0.39 0.07 0.28

A d j u s t pH t o 8 . 0 + - 0 . 1 NH40H, i f necessary. Reduce t o s p r a y v i s c o s i t y o f 45+-5” #4 F o r d Cup w i t h w a t e r i f necessary; add 0 . 1 % Byk-301 on t o t a l enamel w e i g h t , i f d e s i r e d . Formulation Constants: P i gment/Bi nder : 45/55 Water/cosolvent r a t i o : by volume: 67/33 D r i e r l e v e l : 0.10% C0/0.02% M n / l . 2 % A c t i v 8 % S o l i d s : 35 VOC: l b . / g a l . l e s s w a t e r : 3.07 g m s . / l i t e r l e s s w a t e r : 368 ( 1 ) T h i s f o r m u l a t i o n r e p r e s e n t s Rohm and Haas’ b e s t recommenda t i o n f o r maximum s o l i d s f r o m A c r y l o i d WR-748. T h i s formu l a t i o n a l s o o f f e r s f a s t e s t d r y i n g p o t e n t i a l b u t s h o u l d be used b y t h o s e who can e x e r c i s e r e l a t i v e l y t i g h t p H c o n t r o l . Propasol P can be s u b s t i t u t e d f o r B u t y l C e l l o s o l v e , and w i l l r e s u l t i n a system w i t h a s l i g h t l y reduced t a c k - f r e e t i m e b u t w i t h somewhat reduced g l o s s . For a system w i t h b e t t e r c o l o r and b e t t e r p r o j e c t e d e x t e r i o r d u r a b i l i t y , a d r i e r system o f 0.15% C o b a l t / l . 5 % C a l c i u m (Naphthenate) i s recommended. On t h e above f o r m u l a t i o n , i n l i e u o f l i s t e d d r i e r s , add 1 . 5 9 C o b a l t Naphthenate and 2 . 3 9 C a l c i u m Naphthenate. U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result

** ***

*

.

Source:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYLOID WR-748: F o r m u l a t i o n WR-748-2

Miscellaneous

White.

Pebble M i l l F o r m u l a t i o n

F o r m u l a t i o n p r o v i d e s same p a i n t as f o r m u l a t i o n WR-748-1 i s d e s i g n e d f o r t h o s e who cannot use a r o l l e r m i l l . Materials: Pebble M i l l G r i n d : t o 7-1/2 N . S . : T i t a n i u m d i o x i d e ( T i - P u r e R-902) A c r y l o i d WR-748 (60%) Water NH40H (28%) Letdown : Above G r i n d A c y l o i d WR-748 (60%) Water NH4OH (28%) Butyl Cellosolve M i x w e l l , t h e n add: C o b a l t Naphthenate Manganese Naphthenate Activ 8

447

but

P a r t s Per Hundred Weiaht R a t i o * ( V o l u m e B a s i s ) 101.7 45.3 119.4 4.9

2.96 5.52 14.26 0.59

271.3 162.0 415.5 10.9 41 . 6

23.33 19.48 49.82 1.30 5.54

2.1 0.4 1.5

0.27 0.05 0.19

A d j u s t pH t o 8 . 8 + - 0 . 1 w i t h ammonium h y d r o x i d e , i f necessary. Reduce t o s p r a y v i s c o s i t y o f 55+-5" #4 F o r d Cup w i t h 80/20 by volume w a t e r / B u t y l C e l l o s o l v e ; add 0.1% Byk-301 on t o t a l enamel weight, i f desired. Formulation Constants: P i gment/Bi nder : 45/55 W a t e r / c o s o l v e n t r a t i o ( b y volume): 80/20 D r i e r l e v e l : 0.10% Co/O.O2% Mn/1.2% A c t i v 0 % S o l i d s : 25+-1 VOC: l b . / g a l . l e s s w a t e r : 3 . 7 6 g m s . / l i t e r l e s s w a t e r : 451

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result

.

SOURCE: Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYLOID WR-740: F o r m u l a t i o n WR-748-5

448

Water-Based Paint Formulations

White. Water G r i n d F o r m u l a t i o n . H i q h DH F o r m u l a t i o n s d e s i g n e d f o r t h o s e who need t o maximize t h e volume o f p a i n t r e s u l t i n g f r o m a u n i t g r i n d . Some a t t r i t i o n i n humi d i t y - s a l t s p r a y r e s i s t a n c e can be expected. P a r t s Per Hundred Weight R a t i o * (Volume B a s i s )

M a t e r i a1 s: M i x Thorough1 y : Water Tainol 165 T r i t o n CF-10

22.3 6.9 0.9

2.67 0.75 0.10

add i n g r a d u a l l y : 101.8

2.99

Letdown : Above G r i n d A c r y l o i d WR-748 (60%) Water NH40H (28%) Butyl Cellosolve

131.9 207.6 459.0 16.3 50.5

6.51 24.95 59.35 1.95 6.72

M i x w e l l , t h e n add: C o b a l t Naphthenate Manganese Naphthenate A c t i v 8 (as supplied)

2.1 0.4 1.5

0.26 0.05 0.19

W h i l e s t i r r i n g on a Cowles, T i t a n i u m d i o x i d e (RCL-9) G r i n d io 7 1/2 N.S.

A d j u s t pH t o 8.8+-0.1 w i t h NH40H, reduce t o s p r a y v i s c o s i t y o f 55+-5", # 4 F o r d Cup w i t h 80/20 w a t e r / c o s o l v e n t . Formulation Constants: P i gment/Bi nder : 45/55 W a t e r / c o s o l v e n t r a t i o b y volume: % S o l i d s : 26.0 VOC: l b . / g a l . l e s s w a t e r : 3 . 5 7 g m s . / l i t e r l e s s w a t e r : 428

*

80/20

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result

.

SOURCE: Rohm and Haas Co.:

I n d u s t r i a l C o a t i n g s : ACRYLOID WR-740: F o r m u l a t i o n WR-740-3

Miscellaneous

White.

Water G r i n d F o r m u l a t i o n .

449

Low pH

F o r m u l a t i o n s d e s i g n e d f o r t h o s e who need t o maximize t h e volume o f p a i n t r e s u l t i n g f r o m a u n i t g r i n d . Some a t t r i t i o n i n humi d i t y - s a l t s p r a y r e s i s t a n c e can be e x p e c t e d . M a t e r i a1 s : Mix Thorough1 y : Water Tam01 165 T r i t o n CF-10 W h i l e s t r i i r i n g on a Cowles, T i t a n i u m d i o x i d e (RCL-9) G r i n d t o 7-1/2 N . S .

P a r t s Per Hundred s i g h t Ratio*(Volume B a s i s ) 32.7 10.1 1.3

3.92 1.09 0.15

add i n g r a d u a l l y : 149.2

4.38

193.3 304.2 434.5 8.9

9.54 36.56 52.10 1.07

3.0 0.6 2.2

0.39 0.06 0.27

Above G r i n d A c r y l o i d WR-748 Water NH4OH (28%) M i x w e l l , t h e n add: C o b a l t Naphthenate Manganese Naphthenate A c t i v 8 (as supplied)

A d j u s t pH t o 8 . 0 + - 0 . 1 w i t h NH40H, reduce t o s p r a y v i s c o s i t y o f 45+-5” #4 F o r d Cup w i t h w a t e r . Formulation Constants: P i gment/Bi nder : 45/55 W a t e r / c o s o l v e n t r a t i o by volume: 71/29 % S o l i d s : 35.0 VOC: l b . / g a l . l e s s w a t e r : 3.19 g m s . / l i t e r l e s s w a t e r : 382

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result.

SOURCE:

Rohm and Haas Co.: I n d u s t r i a l C o a t i n g s : ACRYLOID WR-740: F o r m u l a t i o n WR-748-4

450

Water-Based Paint Formulations

White.

Water R e d u c i b l e A c r y l i c / M e l a m i n e - A

K-FLEX UD-320W modi f ic a t i on o f t h i s w h i t e w a t e r r e d u c i b l e a c r y l i c / m e l a m i n e system demonstrated s e v e r a l advantages i n c l u d i n g : improved f l o w / l e v e l i n g ; h i g h e r g l o s s ; improved g l o s s r e t e n t i o n on QUV exposure; h i g h e r s o l i d s ( l o w e r VOC) and l o w e r c o s t p e r pound on a s o l i d s b a s i s . Grind: J o n c r y l 540 AMP-95 S u r f y n o l 104 T i -Pure R-960 Water

Wei q h t % 41 . 8 1. o 1. o 48.6 7.6

G r i n d t o 6+ Hegman on t h e b a l l m i l l Letdown : G r i nd J o n c r y l 540 Cyme1 303LF B u t y l Cel l o s o l v e K-F1 ex UD-320W N a c o r r 1552 Water

100.0 58.3 19.9 11.4

----

1.3 43.0

Enamel C h a r a c t e r i s t i c s : A c r y l / K - F l e x / M e l : 70/0/30 % S o l i d s , 1 H r . / l l O C : 47.7 Cost/pound ( s o l i d s ) : $1.62 V i s c o s i t y , cps (25C): 205 pH: 8.70 VOC, 1b s . / g a l : 1 .604 Pigment:Binder: 0 . 7 5 : l .O E x c l u d i n g w a t e r , b u t i n c l u d i n g amines.

.

*

A p p l i c a t i o n & Cure: S u b s t r a t e : B o n d e r i t e 1000 Cure Schedule: 1 5 ' / 2 0 0 F DFT ( m i l s ) : 0 . 9 + - 0 . 0 1

F i l m Properties: P e n c i l Hardness: 4H-5H Knoop Hardness(25g): 17.2 MEK R e s i s t a n c e ( 2 X ) : 100 C r o s s h a t c h Adhesion: 100% Impact R e s i s t a n c e : D i r e c t ( i n - l b s ) : 100-110 Reverse ( i n - l b s ) : 20-30 G l o s s , 60 Degree: 8 3 . 6 20 Degree: 47.1 SOURCE:

K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-12A

Miscellaneous

White,

Water R e d u c i b l e A c r y l i c / M e l a m i n ~ ~

Grind: J o n c r y l 540 AMP-95 S u r f y n o l 104 T i -Pure R-960 Water

Wei a h t % 41.8 1. o 1.o 48.6 7.6

G r i n d t o 6+ Hegman on t h e b a l l m i l l Letdown : Grind J o n c r y l 540 Cyme1 303LF B u t y l C e l l os01 ve K-F1 ex UD-320W N a c o r r 1552 Water

100.0 50.9 19.9

----

3.6 1.3 23.0

Enamel C h a r a c t e r i s t i c s : Acryl/K-Flex/Mel: 65/5/30 % S o l i d s , 1 H r . / l l O C : 56.6 Cost/pound ( s o l i d s ) : $1.56 V i s c o s i t y , cps (25C): 200 pH: 8 . 7 5 VOC, l b s . / g a l . * : 0.551 Pigment:Binder: 0.76:l.O E x c l u d i n g w a t e r , b u t i n c l u d i n g amines

*

Appl i c a t i o n & Cure: S u b s t r a t e : B o n d e r i t e 1000 Cure Schedule: 1 5 ' / 3 0 0 F DFT ( m i l s ) : 0 . 9 + - 0 . 0 1

F i l m Properties: P e n c i l Hardness: 4H-5H Knoop Hardness(25g): 17.0 MEK R e s i s t a n c e ( 2 X ) : 100 C r o s s h a t c h Adhesion: 100% Impact R e s i s t a n c e : D i r e c t ( i n - l b s ) : 100-110 Reverse ( i n - l b s ) : 20-30 Gloss, 60 Degree: 9 1 . 1 20 Degree: 6 5 . 6 C1 eve1 and H u m i d i t y Resi s t a n c e : 500 h o u r s : 9/M 1200 h o u r s : 3/MD

SOURCE:

K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-12-8

451

452

Water-Based Paint Formulations

White,

Water R e d u c i b l e A c r y l i c / M e l a m i n e - C

__ G r i n__ d:

Weight% 41 . a

J o n c r y l 540 AMP-95 S u r f y n o l 104 T i -Pure R-960 Water

1

G r i n d t o 6 t Hegman on t h e

all mil

Letdown : G r in d J o n c r y l 540 Cyme1 303LF K-Flex UD-320W N a c o r r 1552 Water

100.0 39.1 29.1 7.2 1.3 25.0

Enamel C h a r a c t e r i s t i c s : A c r y l / K - F l e x / M e l : 57/10/33 % Solids, 1 H r . / l l O C : 57.9 Cost/pound ( s o l i d s ) : $1.57 V i s c o s i t y , c p s (25C): 200 DH: 8 . 7 4 bOC, 1b s . / g a l 0.546 Pigment:Binder: 0.76:l .O E x c l u d i n g w a t e r , b u t i n c l u d i n g amines.

. *:

*

A p p l i c a t i o n & Cure: S u b s t r a t e : B o n d e r i t e 1000 Cure Schedule: 1 5 ' / 3 0 0 F DFT ( m i l s ) : 0 . 9 t - 0 . 0 1 F i 1m P r o p e r t ies : P e n c i l Hardness: 4H-5H Knoop H a r d n e s s ( 2 5 g ) : 1 8 . 4 MEK R e s i s t a n c e ( 2 X ) : 100 C r o s s h a t c h Adhesion: 100% Impact Resistance: D i r e c t ( i n - l b s ) : 100-110 Reverse ( i n - l b s ) : 20-30 G l o s s , 60 Degree: 9 1 . 5 20 Degree: 67.0 C 1 eve1 and H u m i d i t y Resi s t a n c e : 500 h o u r s : 9/MD 1200 h o u r s : 8/MD

SOURCE:

.o

1.o 48.6 7.6

King I n d u s t r i e s : Formulation

UDW-12C

Miscellaneous

W h i t e , Water-Reduci b l e A c r y l ic/Melami ne-? Grind: J o n c r y l 540 AMP-95 S u r f y n o l 104 T i - P u r e R-960 Water

Weight% 41 . 8 1.o 1.o 48.6 7.6

G r i n d t o 6 t Hegman on t h e b a l l m i l l . Letdown : Grind J o n c r y l 540 Cyme1 303LF K-Flex UD-320W N a c o r r 1552 Water

100.0 28.7 23.3 10.9 1.3 21 . o

Enamel C h a r a c t e r i s t i c s : A c r y l /K-Flex-Me1 : 50/15/35 % S o l i d s , 1 H r . / l l O C : 59.1 Cost/pound ( s o l i d s ) : $1.59 V i s c o s i t y , cps (25C): 197 pH: 8.70 VOC, l b s . / g a l . * : 0.429 Pigment:Binder: 0.74:l.O E x c l u d i n g w a t e r , b u t i n c l u d i n g amines.

*

A p p l i c a t i o n & Cure: S u b s t r a t e : B o n d e r i t e 1000 Cure Schedule: 1 5 ’ / 3 0 0 F DFT ( m i l s ) : 0 . 9 t - 0 . 0 1 Film Properties: P e n c i l Hardness: 4H-5H Knoop Hardness ( 2 5 9 ) : 1 8 . 9 MEK R e s i s t a n c e ( 2 X ) : 100 C r o s s h a t c h Adhesion: 100% Impact R e s i s t a n c e : D i r e c t ( i n-1 b s ) : 80-90 Reverse ( i n - l b s ) : 5-10 Gloss, 60 Degree: 9 2 . 6 20 Degree: 73.0 Cleveland Humidity Resistance: 500 h o u r s : 8/M 1200 h o u r s : 6/D

SOURCE:

K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-12-D

453

454

Water-Based Paint Formulations

W i D i na S t a i n f o r Media M i 1 1 s

Materials: Premix and m i l l : Water T r i t o n CF-10 Dehydran 1620 Van Dyke Brown Bentone L T

Weight Pounds

Volume Gallons

428.2 10.1 0.6 101 . o 1.3

51 . 4 1.2 0.1 8.1 0.1

20.2

2.6

Add : Aqueous Ammonia (28%) t o a d j u s t pH>8 Add t o above u n i f o r m m i x t u r e : E x p e r i m e n t a l e m u l s i o n E-2955 227.2 26.1 ( g r i n d a l l o f above w i t h s h o t m i l l f o r a t l e a s t 30 m i n u t e s o r u n t i l pigment i s s u f f i c i e n t l y d i s p e r s e d ) Premix and add s l o w l y under a g i t a t i o n : Ethylene g l y c o l Butyl Carbi to1 Butyl Cellosolve E k t a s o l v e EEH

69.4 12.6 6.3 3.8

Add 7% ammonia ( a d j u s t pH between 7 . 5 and 8.0) F o r m u l a t i o n Constants: Approximate s o l i d s , % ( w t / v o l ) : 22.3/18.3 PH: 7 . 5 - 8 . 0 VOC, g / l i t e r : 373 lb/gallon: 3.2 C o a l e s c e n t , w t % on polymer s o l ds : B u t y l Carbi t o 1 : 5 Butyl Cellosolve 7 . 5 E k t a s o l v e EEH: 4 5 Edge c o n t r o l s o l v e n t , w t % on polymer s o l i d s e t h y l e n e g l y c o l : 82 Freeze/thaw s t a b i l i t y : P r o t e c t f r o m f r e e z i n g Heat/age s t a b i l i t y (140F/10 d a y s ) : Passes

SOURCE:

Rohm and Haas Co.: E x p e r i m e n t a l Emulsion E-2955: F o r m u l a t i o n WPS 55-1

7.5 1.6 0.8 0.5

Miscellaneous

Ye1 1ow Imp1 ernent Enamel C a r g i l l Water R e d u c i b l e Chain Stopped A1 k y d 74-7474 E t h y l e n e G1 y c o l Monobutyl E t h e r Aqueous Ammonia 28% T i t a n i um D i o x i d e T i -Pure R-902 S y n t h e t i c Y e l l o w I r o n Oxide YLO-3288-D S y n t h e t i c Red I r o n Oxide R0-3097 A e r o s i l R972 S u r f y n o l 104 E Byk-020 D e i o n i z e d Water

Pounds

Gallons

80.0 18.0 4.4 31 . O 57.1 2.1 1.7 1.5 1.5 162.6

9.10 2.40 0.58 0.91 1 .70 0.05 0.09 0.19 0.21 19.52

160.9 10.3 11.8

18.29 1.38 1.57

7.0 1.7 1.3 0.9

1.04 0.22 0.15 0.11

7.3 1.5 343.4

1.08 0.20 41.21

Sand M i l l t o a 7 Hegman C a r g i 11 Water R e d u c i b l e Chain Stopped A1 k y d 74-7474 E t h y l e n e G1 y c o l Monobutyl E t h e r Aqueous Ammonia 28% Premix t h e f o l l o w i n g , t h e n add: E t h y l e n e G l y c o l Monobutyl E t h e r 5% C o b a l t Hydro Cure I 1 Manganese Hydro Cure I 1 Activ-8 sec-Butanol E x k i n No. 2 Dei o n i zed Water

Paint Properties: % N o n v o l a t i l e (By W e i g h t ) : 30.40 (By Volume): 22.00 Pigment t o B i n d e r R a t i o : 0.50 Pigment Volume C o n c e n t r a t i o n : 12.65 Weight Per G a l l o n : 9 . 0 7 T h e o r e t i c a l VOC ( P o u n d s / G a l l o n ) : 3 . 0 0 ( G r a m s / L i t e r ) : 360 Water:Cosolvent Weight R a t i o : 82.00:18.00 V i s c o s i t y #4 F o r d Cup (Seconds): 47 T y p i c a l Cured F i l m P r o p e r t i e s : Cure Schedule: 7 Days A i r Dry Substrate: Cold Rolled Steel G l o s s ( 6 0 / 2 0 ) : 91/85 P e n c i l Hardness: Pass 28 Impact ( I n . l b s . ) : D i r e c t : 30 Reverse: 1 5 SOURCE:

Cargill, I n c . : CARGILL F o r m u l a r y : Formula P1848-135C

455

456

Water-Based Paint Formulations

Y e l l o w Iron O x i d e P a i n t Roller M i l l : Y e l l o w I r o n O x i d e YLO-1888D A c r y l o i d WR-748 (60%) Butyl Cellosolve Letdown: Above G r i n d A c r y l o i d WR-748 (60%) Water 28% N H ~ O H Butyl Cellosolve Byk 301 C o b a l t Naphthenate Manganese Naphthenate Activ 8

P a r t s Per Hundred Weiqht R a t i o * (Volume B a s i s ) 52.43 1.56 55.85 6.93 5.70 0.76 113.98 148.05 539.14 11.40 42.63 1.60 2.04 0.41 1.47

9.25 18.37 64.65 1.37 5.68 0.20 0.25 0.05 0.19

F o r m u l a t i o n Constants: Pi gment/Bi n d e r : 30/70 W a t e r / c o s o l v e n t r a t i o ( b y volume): 80/20 D r i e r l e v e l : 0.10% Co/O.O2% M n / l . 2 % A c t i v 8 S o l i d s %: 22+-1 Spray v i s c o s i t y ( # 4 F o r d Cup): 55+-5" pH: 8 . 8 + - 0 . 1 VOC: l b s . / g a l . l e s s w a t e r : 3 . 8 7 g m s . / l i t . l e s s w a t e r : 465

*

U s i n g w e i g h t r a t i o i n pound u n i t s w i l l y i e l d a p p r o x i m a t e l y 100 g a l l o n s o f p a i n t , w h i l e w i t h k i l o g r a m s , 833 l i t e r s w i l l result.

SOURCE: Rohm and Haas Co.: Formula MT-740-3Y

I n d u s t r i a l C o a t i n g s : ACRYLOID WR-748:

458

Water-Based Paint Formulations

RAW MATERIAL A-187

CHEMICAL D E S C R I P T I O N S i l a n e e s t e r adhesion promoter

SOURCE Union Carbide

A-4434

Tacoma b l u e

C i baGei gy

AC-1024

A c r y l ic emu1 s i on

Rohm & Haas

A c r y l o i d WR-97

Acryl i c r e s i n

Rohm 8, Haas

A c r y s o l ASE-60

Water-sol ubl e a c r y l i c r e s i n

Rohm & Haas

Acrysol

1-62

W a t e r - s o l u b l e a c r y l ic r e s i n

Rohm & Haas

Acrysol

1-98

W a t e r - s o l u b l e a c r y l ic r e s i n

Rohm & Haas

A c r y s o l OR708

W a t e r - s o l u b l e a c r y l ic r e s i n

Rohm & Haas

A c r y s o l RM-5

W a t e r - s o l u b l e a c r y l ic r e s i n

Rohm & Haas

A c r y s o l RM-025

W a t e r - s o l u b l e a c r y l ic r e s i n

Rohm & Haas

A c r y s o l RM-1020

W a t e r - s o l u b l e a c r y l ic r e s i n

Rohm & Haas

A c r y s o l SCT-275

W a t e r - s o l u b l e a c r y l ic r e s i n

Rohm & Haas

A c r y s o l TT-615

W a t e r - s o l u b l e a c r y l ic r e s i n

Rohm & Haas

A c r y s o l TT-935

W a t e r - s o l u b l e a c r y l ic r e s i n

Rohm & Haas

A c r y s o l WS-68

W a t e r - s o l u b l e a c r y l ic r e s i n

Rohm & Haas

Activ-8

Drier,

accel e r a t o r ,

s t a b i 1 iz e r

Vanderbilt

Trade Named Raw Materials

459

RAW MATERIAL A d d i t o l XW 395

CHEMICAL DESCRIPTION Additive

SOURCE Hoechst

A e r o s i 1 R-972

Fumed s i l i c a

Degussa

A e r o s o l OT

S u r f a c e a c t i v e agent

Am Cyan

A e r o s o l OT-B

S u r f a c e a c t i v e agent

Am Cyan

A e r o s o l OT-75

S u r f a c e a c t i v e agent

Am Cyan

A e r o s o l TR-70

S u r f a c e a c t i v e agent

Am Cyan

A i r f l e x 738

V i n y l a c e t a t e - e t h y l e n e copolymer emu1 s i on

A i r

A1 c o l ec 439-C

Water d i s p e r s i b l e l e c i t h i n

Am Lec

A l c o p h o r 827

Paint additive

Henkel

AMP-95

Dispersant

Angus

A n t i -Sag WR300 Aq uac at

Prod.

Byk Drier

Ultra McWhort

Aquamac 430 A r c o s o l v PTB

Propylene g l y c o l m o n o t e r t i a r y b u t y l ethe

A r c o s o l v DPM

D i p r o p y l ene g l y c o l monoethyl e t h e r / A r c o

A r c o s o l v PM

P r o p y l e n e g y c o l monomethyl e t h e r A r c 0

A r c o s o l v PP

Coalescent

Arc0

A r o l o n 465

P o l y e s t e r . % S o l i d s : 80

Rei ch-

A r o l o n 557

A c r y l i c polymer. % S o l i d s :

70

Rei ch-

A r o l o n 559

A c r y l i c p o l y m e r . % S o l i d s : 70

Rei ch-

A r o l o n 580

Oxidizing alkyd. % Solids:

42

Rei ch-

A r o l o n 585

O x i d i z i n g a l k y d . % S o l i d s : 43

Reich-

A r o l o n 820

A c r y l i c p o l y m e r . % S o l i d s : 49

Reich-

A r o l o n 840

A c r y l i c polymer. % S o l i d s :

Rei ch-

39

Arc0

460

Water-Based Paint Formulations

RAW MATERIAL A r o l o n 845

CHEMICAL DESCRIPTION A c r y l i c polymer. % S o l i d s :

45

SOURCE Rei ch-

A r o l o n 850

Acry i c p o l y m e r . % S o l i d s :

45

Reich-

A r o l o n 860

Ac r y i c p o l y m e r . % S o l i d s :

45

Reich-

A r o l o n 921

Oxi d z i n g a l k y d . % S o l i d s :

70

Rei ch-

A r o l o n 970

O x i d z i n g a l k y d . % S o l i d s : 70

Reich-

A r o p l a z 1271

Long-oi

A r o p l a z 1272

100% so i d s v e r s on o f A r o p l a z 1271

NLChem

ASA 35.3

Wax emu s i on

Chem. Corp.

A s b e s t i n e 3X

Talc

IntTalc

Aluminum s i l i c a t e e x t e n d e r

Engel -

ASP-1 70

A 1 umi num s i 1 ic a t e e x t e n d e r

Engel -

ASP-400

A1 umi num s i 1 ic a t e e x t e n d e r

Engel -

Atomi t e

C a l c i um c a r b o n a t e

ECC

A t t a g e l 50

A t t a p u l g i t e t h i c k e n i n g agent

Engel -

Aurasperse W-7012

Carbon b l a c k

Harshaw

B a l a b 3046A

Defoamer

Witco

B a l a b 3056A

Defoamer

Witco

Barimite XF

Natural b a r i t e s

Thomp-

B a r y t e s W1430

Barytes

P f iz e r

B a r y t e s #1

Barytes

WC&D

B a y f e r r o x 120NM

S y n t h e t i c i r o n o x i d e pigment

M i 1es-

ASP-NC2

Clay

1inseed a l k y d r e s i n

NLChem

Azo Rubine Ex Conc

Trade Named Raw Materials

461

SOURCE

RAW MATERIAL Beaverwhi t e 325

CHEMICAL DESCRIPTION Talc

Cyprus

Beckosol 13-402

Synthetic resin

Reich-

B e e t l e 65

Urea-formaldehyde r e s i n

Am Cyan

Bentone EW

Rheological a d d i t i v e

Rheox

Bentone LT

Rheological a d d i t i v e

Rheox

Bentone 27

Rheological a d d i t i v e

Rheox

Bentone 38

Rheol o g i c a l addi t i ve

Rheox

Benzotriazole

Inhibitor

Sandoz

B l a c k T i n t 888-9907

81 ack t i n t

Hul s

Blanc F i x

Sachtl-

B o r c h i gen DFN

Nonionic s u r f a c t e n t

Borch-

B o r c h i g e n ND

Dispersant

Borch-

Brown I r o n Oxide D i s p .

Pigment d i s p e r s i o n

Hul s /

Brown I r o n Oxide 444

Brown

Col umb-

Burgess No. 98

Hydrous c l a y

Burgess

Busan 1lM-1

Microbiocide

Buckman

Busperse-39

D i s p e r s i n g agent

Buckman

B u t r o l 22

C o r r o s i o n and s c a l e i n h i b i o r

Buckman

B u t y l Carbi t o 1

D i e t h y l e n e g l y c o l monobuty

Butyl C a r b i t o l Acetate

D i e t h y l e n e g l y c o l monobutyl e t h e r Union acetate Carbide

Butyl Cellosolve

E t h y l e n e g l y c o l monobutyl e t h e r acetate

Union Carbide

Butyl D i propasol

Coalescent

Union Carbide

e t h e r Union Carbide

462

Water-Based Paint Formulations

RAW MATERIAL B u t y l Propasol

CHEMICAL DESCRIPTION Coalescent

SOURCE Union Carbide

n-Butyl

Coalescent

Union Carbide

Byk 020

Defoamer

Byk-

Byk 035

Defoamer

Byk-

Byk 080

Additive

Byk-

Byk 104s

Additive

By k-

Byk 156

Addi t i ve

Byk-

Byk 301

A d d i t i ve

Byk-

Byk 306

Add t i v e

Byk-

Byk 344

Mar a i d

Byk-

B y k - C a t a l y s t 451

Add t i v e

Byk-

Byk P-104s

Add t i v e

Byk-

Bykumen

Wetting/dispersing additive

Byk-

Byk VP020

Additive

By k -

Byk VP-155

Additive

Byk-

Byk VP-321

Mar p r o o f i n g and s l i p a i d

Byk-

Fumed s i l i c a

Cabot

C a l c i um Hydro-Cem

6% C a l c i u m d r i e r c a t a l y s t

OMGr ou p

Calcium Hydrocure

Cat a 1yst

OMGroup

Calco S t a i n s

Stains

Am Cyan

C a l / I n k 8800 S e r i e s

Colorants

nu1 s

Camel-Carb

Cal c i um c a r b o n a t e

Genst a r

Propionate

Cab-0-Si1

M5

Trade Named Raw Materials

463

SOURCE

RAW MATERIAL Carbi t o 1

CHEMICAL DESCRIPTION Sol v e n t

C a r b i t o l Acetate

Sol v e n t

Union Carbide

Carg 11 17-7240

Water r e d u c i b l e a c r y l ic

Cargi 11

Carg 11 23-2317

H i g h s o l i d s p o l y m e r i c methy a t e d me1ami ne

Cargill

Carg 11 23-2347

H i g h s o l i d s monomeric methy a t e d me1 ami ne

Cargill

Carg 11 72-7203

Water r e d u c i b l e o i l f r e e p o l y ester

Cargi

Carg 11 72-7230

Waterborne p o l y e s t e r d i s p e r s i o n

Cargi

Carg 11 72-7231

Waterborne p o l y e s t e r d i s p e r s i on

Cargi

Carg 11 72-7232

Waterborne p o l y e s t e r d i s p e r s i o n

Cargill

Carg 11 72-7209

Water r e d u c i b l e o i l - f r e e p o l y ester

Cargill

Carg 11 73-7331

Water r e d u c i b l e epoxy e s t e r

C a r g i 11

Carg 11 73-7390

Water r e d u c i b l e s e l f c r o s s l i n k i n g C a r g i l l resin

Carg 11 74-7412

Water r e d u c i b l e f o r e s t p r o d u c t s resin

Cargill

Carg 11 74-7422

Water r e d u c i b l e s t y r e n a t e d a l k y d copolymer

Cargill

Carg 11 74-7425

Water r e d u c i b l e s t y r e n a t e d copolymer a1 kyd

Cargill

C a r g i 11 74-7432

Water r e d u c i b l e a c r y l ic modi f i ed a1 kyd

C a r g i 11

C a r g i 11 74-7435

Water r e d u c i b l e s i 1i c o n e modi f ied C a r g i 11 a1 kyd

C a r g i 11 74-7450

Water r e d u c i b l e s h o r t soya a l k y d

Union Carbide

Cargill

464

Water-Based Paint Formulations

RAW MATERIALS C a r g i 1 1 74-7451

CHEMICAL D E S C R I P T I O N Water r e d u c i b l e s h o r t t o f a a l k y d

SOURCE Cargill

C a r g i 11 74-7455

Water r e d u c i b l e c i o c o n u t o i l a1 k y d

Cargi

C a r g i 11 74-7461

Water r e d u c i b l e s h o r t t o f a a l k y d

Cargi

C a r g i 11 74-7470

Water r e d u c i b l e c h a i n stopped a1 kyd

Cargi

C a r g i 1 1 74-7472

Water r e d u c i b l e f a t t y a c i d a l k y d

Cargill

C a r g i 11 74-7474

Water r e d u c i b l e c h a i n stopped a1 kyd

C a r g i 11

C a r g i 1 74-7476

Water r e d u c i b l e f a t t y a c i d a l k y d

Cargill

C a r g i 1 74-7478

Water r e d u c i b l e o h e n o l i c m o d i f i e d C a r g i l l a1 kyd

C a r g i 1 74-7407

Water r e d u c i b l e c h a i n stopped a1 kyd

C a r g i 11

C a r g i 11 74-7495

Water r e d u c i b l e c h a i n stopped a1 k y d

C a r g i 11

C a r g i 11 108-1 775

Waterborne p o l y e s t e r d i s p e r s i o n

C a r g i 11

C a r g i l l 5150

C a r g i 11

C a r g i l l 7203

O i 1 free polyester

C a r g i 11

C a r g i l l 7474

Waterborne a1 kyd r e s i n

C a r g i 11

C a t a l y s t 600

Organic a c i d c a t a l y s t

Am Cyan

C e l i t e 281

D i atamaceous s i 1 ica

Cel it e

C e l i t e 499

D i atomaceous s i 1 ica

Cel it e

Cel l o s i ze ER-15M

Hydroxyethyl c e l l u l o s e

Un Carb

Cel l o s i ze ER-3OM

Hydroxyethyl c e l l u l o s e

Un Carb

Cel l o s i ze ER-4400

Hydroxyethyl c e l l u l o s e

Un Carb

Cel l o s i ze QP-40

Hydroxyethyl c e l l u l o s e

Un Carb

Cel l o s i ze QP-4400

Hydroxyethyl c e l l u l o s e

Un Carb

Trade Named Raw Materials

465

CHEMICAL DESCRIPTION Hydroxyethyl c e l l u l o s e

SOURCE Un Carb

Hydroxyethyl c e l l u l o s e

Un Carb

Chemcor AS-35-3

Wax e m u l s i o n

ChemCo r

Chempol 10-0091

Water r e d u c i b l e s h o r t o x i d i z i n g o i l alkyd

Freeman

Chempol 10-0094

Water r e d u c i b l e s h o r t o x i d i z i n g o i l alkyd

Freeman

Chempol 10-0095

Water r e d u c i b l e s h o r t o i l a l k y d

Freeman

Chempol 10-0097

Water r e d u c i b l e s h o r t o i l a l k y d

Freeman

Chempol 10-01 73

Water r e d u c i b l e c h a i n stopped a1 kyd

Freeman

Chempol 10-0453

Water r e d u c i b l e s t y r e n a t e d epoxy ester

Freeman

Chempol 10-0501

H i g h performance p o l y e s t e r

Freeman

Chempol 10-0503

Saturated polyester

Freeman

Chempol 10-0509

Water r e d u c i b l e h y d r o x y f u n c t i o n a l thermosetting a c r y l i c

Freeman

Chempol 10-1105

Water r e d u c i b l e coconut a

Freeman

Chempol 10-1 21 0

Water r e d u c i b l e s h o r t o i 1

Freeman

Chempol 10-1 300

Water r e d u c i b l e a c r y l i c a copolymer

Freeman

Chempol 10-1313

Water r e d u c i b l e a c r y l i c a copolymer

Freeman

Chempol 10-1 706

Water r e d u c i b l e a c r y l i c copolymer Freeman

Chempol 20-4301

Water-based

Chroma-Chem 896-9901

Industrial colorant

Hul s

Chrome Oxide X-1134

Pigment

C i ba-

RAW MATERIAL C e l l o s i z e QP- 5,000 C e l l o s i z e QP-

5,000H

a c r y l i c dispersion

Freeman

466

Water-Based Point Formulations

RAW MATERIAL Chrome Y e l l o w X3356

CHEMICAL DESCRIPTION Ye1 1o w

C i ba-

CMD 560-8290

C u r i n g agent

Rhone-

CMD WJ60-8537

C u r i n g agent

Rhone-

CMD 9012

A c r y l ic d i s p e r s i on

Rhone-

CMD 9790

A c r y l ic d i s p e r s i on

Rhone-

C o b a l t Cyclodex-6%

Drier

Hul s

C o b a l t Hydrocure-5%

Drier,

catalyst

OMGroup

C o b a l t Hydrocure I 1

D r ier,

catalyst

OMGroup

Colanyl Colorants

Predispersed pigments

Hoechst

Col 1 o i d X-0137-MC-33

A n t i foam

Rhone-

C o l l o i d 111

Dispersant

Rhone-

Col l o i d 226

Dispersant

Rhone-

Col 1o i d 226/35

Dispersant

Rhone-

C o l l o i d 261

Dispersant

Rhone-

C o l l o i d 270

Dispersant

Rhone-

Col l o i d 286

Dispersant

Rhone-

C o l l o i d 600

Defoamer

Rhone-

C o l l o i d 640

Defoamer

Rhone-

C o l l o i d 643

Defoamer

Rhone-

C o l l o i d 650

A n t i foam

Rhone-

C o l l o i d 653

A n t i foam

Rhone-

Col l o i d 677

A n t i foam

Rhone-

C o l l o i d 679

A n t i foam

Rhone-

C o l l o i d 681-F

Antifoam

Rhone-

SOURCE

Trade Named Raw Materials

467

R A W MATERIAL C o l l o i d 694

CHEMICAL DESCRIPTION Defoamer

SOURCE Rhone-

C o l l o i d 697

Defoamer

Rhone-

C o l o r - S p e r s e 188-A

Nonionic s u r f a c t a n t

Henkel

C o l o r t r e n d 888-9907

Lamp b l a c k

Huls

Composition T

Dispersant

Cal gon

Concofoc 690

Surfactant

Cont in-

Copperas Red R-7098

Red

Col umb-

Coroc A-2678-M

Addi t i ve

Freeman

Cosan 145

Preservative

Cosan

CR-800 CR-813 CT-136

A i rProd

Cycat 4040

Catalyst

AmCyan

Cyclodex C o b a l t (6%)

Drier

Hul s

Cyclodex Manganese (6%) D r i e r

Hul s

Cyclodex Z i r c o n i um ( 1 2 % ) D r ie r

Hul s

Cymel 301

Melami ne-formaldehyde r e s i n

Am Cyan

Cymel 303

Me1ami ne-formal dehyde r e s i n

Am Cyan

Cymel 303LF

Melami ne-formaldehyde r e s i n

Am Cyan

Cymel 325

Melami ne-formaldehyde r e s

Am Cyan

Cymel 327

Melamine-formaldehyde r e s

Am Cyan

Cymel 350

Melamine-formaldehyde

res

Am Cyan

Cymel 370

Melamine-formaldehyde r e s

Am Cyan

Cymel 373

Melamine-formaldehyde r e s

Am Cyan

468

Water-Based Paint Formulations

RAW MATERIAL Cyme1 385

CHEMICAL DESCRIPTION Cross-1 in k i ng agent

Am Cyan

Cyzac 4040

Cat a 1y s t

Am Cyan

Dalamar Y e l l o w YT820D Dal pad-A

SOURCE

Harmon Coalescent

Dow Malvern

Daper N o v a c i t e Dapro 1181

Foam suppressor

Daniel

Darvan No. 7

D i s p e r s i ng agent

Vander-

DC-29

Silicone

DowCorn

Deefo 806-102

Defoamer

Ultra

Deefo 916

Defoamer

Ultra

DeeFo 3000

Oef oamer

Ultra Degussa

Degussa TS-100 Dehydran 1293

Defoamer

Henkel

Dehydran 1620

Defoamer

Henkel

D e x t r o 1 OC-50

W e t t i n g agent

Dexter

Dimethylethanolamine

Pennwal

D i s p e r s a n t OR-681M

Rohma

D i sperbyk

W e t t i n g / d i s p e r s i ng a d d i t i v e

Daniel

D i sperse-Ayd W22 DMAMP-00

BYk

2-Dimethylamino-2-methyl-l-

I MC

20% w a t e r DMEA

N e u t r a l i z i n g amine

Un Carb

Dow 65

Defoamer

Dow

Trade Named Raw Materials

469

SOURCE

DOW 762-W

CHEMICAL DESCRIPTION L a t e x polymer s o l u t i o n

Dow

Dowanol DB

Glycol ether

Dow

Dowanol DPM

Glycol ether

Dow

Dowanol EB

Glycol ether

Dow

Dowanol PNB

Glycol ether

Dow

Dowanol PPh

Glycol ether

Dow

Dow C o r n i n g 14

Additive

DowCorn

Dow C o r n i n g #57

A d d i t i ve

DowCorn

D o w i c i l 75

Preservative

Dow

Dow L a t e x RAP 213NA

Styrene/butadiene l a t e x

Dow

Drewplus L-405

Foam c o n t r o l agent

Drew

Drewpl us L-418

Foam c o n t r o l agent

Drew

Drewpl us L-464

Foam c o n t r o l agent

Drew

Drewplus L-475

Foam c o n t r o l agent

Drew

Drewpl us L-484

Foam c o n t r o l agent

Drew

Drewpl us L-493

Foam c o n t r o l agent

Drew

Drewplus Y-250

Foam c o n t r o l agent

Drew

DSX 1514

Rheo ogy m o d i f i e r

Hen k e l

DSX 1550

Rheo ogy m o d i f i e r

Henkel

Duramac 2400

Soya a l k y d r e s i n

McWhort

Durami t e

Cal c um c a r b o n a t e

ECC

RAW MATERIAL

470

Water-Based Paint Formulations

SOURCE

RAW MATERIAL EA-1075

CHEMICAL DESCRIPTION Anti - s e t t l i n g a i d

N L Chem

E k t a s o l v e DE

Sol v e n t

Eastman

E k t a s o l v e E6

Solvent

Eastman

E k t a s o l v e EEH

Sol v e n t

East man

E k t a s o l v e EP

E t h y l e n e g l y c o l monopropyl e t h e r

Eastman Rohm&

E m u l s i o n E-2774 Enco A r o m a t i c 150

High f l a s h a r o m a t i c hydrocarbon

Exxon

Epi -Cure W50-8535

Epoxy c u r i n g a g e n t

Rhone-

Epi -Rez WJ-3520

Epoxy r e s i n

Rhone-

E p i - r e z 15-5522

Epoxy r e s i n

Rhone-

E p i - r e z 510

Epoxy r e s i n

Rhone-

E p o t u f 38-690

Epoxy r e s i n

ReichhMcCl osk

Epoxy E s t e r P-2017- . S - l l latex

Grace

Everflex E

Vinyl-acrylic

E v e r f l e x GT

V i n y l copolymer e m u l s i o n

Grace

E x k i n #1

A n t i - s k i n n i n g agent

Hul s

E x k i n #2

A n t i - s k i n n i n g agent

Hul s

E m u l s i o n E-2189

Rohm&

Emu1s i o n E-2573

Rohm&

E m u l s i o n E-2955

Rohm&

E x x a t e 600

Oxo-acet a t e

Exxon

E x x a t e 1300

Oxo-acetate

Exxon

Trade Named Raw Materials

471

RAW MATERIAL FC- 120

CHEMICAL D E S C R I P T I O N Fluorosurfactant

SOURCE 3m

FC-129

Fluorosurfactant

3M

FC-430

Fluorosurfactant

3M

F l a t t i n g Agent TS-100

F l a t t i n g agent

Degussa

Flexbond 325

Vinyl-acrylic

emulsion

A i rProd

F l e x b o n d 380 DEV

Vinyl-acrylic

emulsion

A i rProd

Flexbond 471

A c r y l i c emulsion

A i rProd

F l u o r a d FC 129/431

Fluorosurfactant

3M

Foamaster AP

Defoamer

Henkel

Foamaster DS

Defoamer

Henkel

Foamaster G

Defoamer

Henkel

Foamaster 0

Defoamer

Henkel

Foamaster R

Defoamer

Henkel

Foamaster TCX

Defoamer

Henkel

Foamaster VF

Defoamer

Henkel

Foamaster VL

Defoamer

Henkel

Foamex 1488

A n t i foam

Goldsc-

F o a m k i l l FBF

Foam c o n t r o l a g e n t

C r u c i b-

Foamki 11 639Q

Foam c o n t r o l agent

C r u c i b-

Foamburst 363

472

Water-Based Paint Formulations

RAW MATERIAL Gamasperse 6532

CHEMICAL DESCRIPTION Calcium carbonate

SOURCE Georgia

Garnet Toner X-2433

Toner

C i ba-

GE60

Defoamer

GE

Genepoxy 370-H55

Epoxy emu1 s i on

Daubert

Glomax LL

C a l c i n e d aluminum s i l i c a t e

DryBran

G o l d Bond R

Silica

Go1dBon

GT-674 P h t h a l o Green

Green

duPont

Halox BW-100

Calcium barium p h o s p h o s i l i c a t e

Halox

Halox SW-111 Halox

Calcium s t r o n t i u m p h o s p h o s i l i c a t e Halox

Halox SZP-391

Non-lead i n h i b i t i v e pigment

Hal ox

Hansa Y e l l o w 6-1230

Pigment

Ha r shaw

HEI-SCORE-XAB

Corrosion i n h i b i t o r

Whi t t a k

He1 iogen 81 ue L6875F

P h t h a l o b l u e pigment

BASF

He1 iogen 81 ue L6975F

P h t h a l o b l u e pigment

BASF

He1 iogen B l ue L7071 F

P h t h a l o b l u e pigment

BASF

H e l i o g e n Green LE690

Green p h t h a l o c y a n i n e pigment

BASF

Heloxy 8

Epoxy m o d i f i e r

Rhone-

H e r c u l e s SGL

Defoamer

Aqual on

H e r c u l e s 7H3SF

Sodium CMC

Aqual on

H e r c u l e s 501

Defoamer

Aqual on

Heubach Y-539-D

Zinc yellow

Heubach Heubach

Heucophos ZPO Heucophos ZBZ

Zinc yellow

Heubach

Trade Named Raw Materials

473

SOURCE

R A W MATERIAL Heucophthal B l u e RF BT-62 7-D

CHEMICAL DESCRIPTION B1ue

Heubach

Heucophthal B l u e RF BT-698-D

B1ue

Heubach

Hexyl C e l l o s o l v e

Coalescent

UnCarb

Hi-Sol

H i g h f l a s h a r o m a t i c hydrocarbon

Ashland

Hoover Brown 7148

Brown

Hoover

Horsehead RF-30

Zinc oxide

NJ Z i n c

Horsehead XX-503

Zinc oxide

NJ Z i n c

15

Huber

Huber 70C Hubercarb (2-6

Calci'um c a r b o n a t e

Huber

Hubercarb (2-325

C a l c i um c a r b o n a t e

Huber

Hydro-Cem C a l c i u m

Catalyst

OMGroup

Hydro-Cen Z i r c o n i um

Catalyst

OMGroup

Hydro-Cure C o b a l t

Catalyst

OMGroup

Hydro-Cure Manganese

Catalyst

OMG r ou p

Hydro-Paste 8726

S i 1b e r -

Hydro-Paste 82255

S i 1b e r -

s t a b i 1iz e r

Hypermer PS2

Polymeric d i s p e r s a n t ,

Iceberg

Anhydrous aluminum s i 1 i c a t e

Burgess

I g e p a l CO-610

Non-ionic s u r f a c t a n t

GAF

I g e p a l CO-630

Non-ionic s u r f a c t a n t

GAF

I g e p a l CTA-639

Surfa c tant

GAF

IC1

474

Water-Based Paint Formulations

RAW MATERIAL Imperial Brazi 1 Yellow X-2860

CHEMICAL D E S C R I P T I O N Pigment

SOURCE C i ba-

I m p e r i a l B r a z i 1 Ye1 low X-2866

Pigment

C i ba-

I m s i l A-8

M i c r o n i z e d m i c r o c r y s t a l 1 ine s i 1i c a

Unimin

I m s i l A-10

Micronized m i c r o c r y s t a l l i n e silica

Unimin

I m s i l A-15

M i c r o n i z e d m i c r o c r y s t a l 1 ine silica

Unimin

I m s i l A-25

M i c r o n i zed m i c r o c r y s t a l 1 ine

Unimin

silica I n t e r c a r 4% Calcium

Drier

Interst

I n t e r c a r 6% C o b a l t

Drier

Inter-

I n t e r c a r 6% Manganese

Drier

Inter-

I n t e r c a r 6% Z i r c o n i urn

D r ier

Inter-

I n t e r c i d e T-0

M i c r o b i o s t a t i c agent

Inter-

IT-325

Talc

Vander-

J o n c r y l SCX-1520

A c r y l i c polymer

Johnson

J o n c r y l 56

A c r y l i c polymer

Johnson

J o n c r y l 540

A c r y l ic polymer

Johnson

Kadox-515

Zinc oxide

NJ Z i n c

Kadox 911

Zinc oxide

NJ Z i n c

Kaopaque 105

A1 umi num s i 1 ic a t e

DryBran

Trade Named Raw Materials

RAW MATERIAL

CHEMICAL DESCRIPTION

475

SOURCE

Kathon LX

Fungicide

Rohm&

K-Cure 1040

Catalyst

King

Kelecin 1081

Soybean oil

Rei ch-

Kelsol 860

Oil copolymer

Rei ch-

Kelsol 3900

Oxidizing alkyd. % solids: 75

Rei ch-

Kelsol 3902

Oxidizing alkyd. % solids: 75

Reich-

Kelsol 3904

Oxidizing alkyd. % solids: 75

Rei ch-

Kelsol 3905

Water-reducible alkyd

Reich-

Kelsol 3906

Oxidizing alkyd. % solids: 75

Rei ch-

Kelsol 3907

Oxidizing alkyd. % solids: 75

Rei ch-

Kelsol 3909

Oxidizing alkyd. ?6 solids: 75

Reich-

Kelsol 3910

Oxidizing alkyd. % solids: 75

Rei ch-

Kelsol 3918

Oxidizing alkyd. % solids: 70

Rei ch-

Kelsol 3919

Oxidizing alkyd. % solids: 70

Reich-

Kelsol 3922

Oxidizing alkyd. % solids: 80

Rei ch-

Kelsol 3931

Modified oil. % solids

45

Rei ch-

Kelsol 3937

Modified oil. % solids

45

Rei ch-

Kelsol 3939

Modified oil. % solids

45

Reich-

Kelsol 3950

Oxidizing alkyd. % sol ds: 70

Rei ch-

Kelsol 3960

Oxidizing alkyd. % sol ds: 75

Rei ch-

Kelsol 3961

Oxidizing alkyd. % solids: 75

Rei ch-

Kelsol 3962

Oxidizing alkyd. % solids: 70

Reich-

Kelsol 3963

Oxidizing alkyd. % solids: 70

Rei ch-

Kelsol 3970

Oxidizing alkyd. % solids: 75

Rei ch-

476

Water-Based Paint Formulations

RAW MATERIAL K e l s o l 3980

CHEMICAL DESCRIPTION SOURCE N o n - o x i d i z i n g a l k y d . ?6 s o l i d s : 75 R e i c h -

K e l s o l 3990

Oxidizing alkyd. % solids:

K e l s o l 4069

Acrylic polyester. % solids:

55

Rei ch-

K e l s o l 4097

A c r y l i c p o l y e s t e r . % s o l i d s : 55

Reich-

K e l s o l 5293

Polyester. % s o l i d s :

Rei ch-

K-F1 ex UD-320W

Polyol

King

K-Flex 188

Polyol

King

Kodaf 1 ex T X I B

Plasticizer

Eastman

Korthix

Thi x o t r o p i c agent

Kaopol-

KP- 140

P1a s t ic i z e r

FMC

K r o l o r Y e l l o w KY-7810

Pigment

duPont

L-5310

Flow c o n t r o l agent

UnCarb

L-7605

Flow c o n t r o l agent

UnCarb

Lactimon WS

W e t t i n g / d i s p e r s i ng a d d i t i v e

Byk-

L i naqua

M o d i f i e d o i l . % s o l i d s : 85

Rei ch-

L i q u a z i nc AQ-90

Mar/sanding a i d

W i tco

75

Rei ch-

70

K r a y g e l 136

Lodyne S-107

C i ba-

Lodyne S-1076

C i ba-

L u b r i z o l 2063

L u b r i z-

Trade Named Raw Materials

477

R A W MATERIAL Magnacat

CHEMICAL DESCRIPTION Drier

SOURCE Ultra

Mai n c o t e AE-58

Acrylic latex

Rohm&

Mai n c o t e HG-54

Acrylic latex

Rohm&

Mai n c o t e T L - 5

Acrylic latex

Rohm&

Makon 10

S u r f a c t a n t . Nonoxynol-10

Stepan

Manchem APG

Adhesion p r o m o t e r

Manchem

Synthetic d r i e r

OMGroup

Drier

Huls

Manganese Cem-All

12%

Manganese Cyclodex(6%)

Manganese Hydrocure(5%) C a t a l y s t

OMGr ou p

Manganese Hydrocure I 1

Catalyst

OMGr ou p

Mapico 1075

I r o n oxide

Col umb-

Mapico Brown 422

I r o n oxide

Col umb-

Mapico B l a c k

I r o n oxide

Col umb-

Mapico Red 297

I r o n oxide

Col umb-

Mapico Red #347

I r o n oxide

Col umb-

Mapico Red 516 Medium

I r o n oxide

Col umb-

Mapico 347A

I r o n oxide

Col umb-

Mapico Y e l l o w 1000

I r o n oxide

Co 1umb-

Mapico Y e l l o w 1050

I r o n oxide

Col umb-

Mapico Y e l l o w 3100

I r o n oxide

Co 1 umb-

M e a r l i n F i n e - P e a r l # 1 3 9 V Powdered p e a r l pigment

Mearl

Medi um Chrome Ye1 l o w X2075

Ye1 l o w

C i ba-

Medium Chrome Y e l l o w X-3356

Yellow

C i ba-

478

Water-Based Paint Formulations

RAW MATERIAL Merbac 35

CHEMICAL DESCRIPTION Bactericide

SOURCE Cal gon

Methocel HG-400

Hydroxypropyl m e t h y l c e l l u l o s e

Dow

Methocel J-12-HS

Hydroxypropyl m e t h y l c e l l u l o s e

Dow

Methyl Carbi t o 1

D i e t h y l e n e g l y c o l monomethyl ether/UnCarb

M e t h y l Propasol

Sol v e n t

UnCarb

Mica C-3000

Lamina mica pigment

Smith

Mica 325WG

Mica

KMG

Michem Emulsion 39235

Wax e m u l s i o n

M ichel-

M i chem Emu1 s i on 43040

Wax e m u l s i o n

M ichel-

M i cheml ube 1 10

Wax a d d i t i v e

M ichel-

M i cheml ube 155

Wax a d d i t i v e

Michel-

Michemlube 511

Wax a d d i t i v e

M ichel-

M i cheml ube 743

Wax a d d i t i v e

M i chel-

Minex 4

Nephel ine s y e n i t e

Unimin

Minex 7

Nephel ine s y e n i t e

Unimin

Minex 10

Nephel ine s y e n i t e

Unimin

Min-U-Si1

10

Micron-sized

silica

Unimin

Min-U-Si1

15

M i c r o n - s i zed s i 1 ica

Uni m i n

Min-U-Si1

40

M i c r o n - s i zed s i 1 ic a

Uni m i n

M o l y b d a t e Orange UE-637-D

Orange

Heubach

Moly-whi t e M Z A P

A n t i - c o r r o s ve pigment

SherWi 1

Monarch B l u e X3367

B1ue

C i ba-

M o n a s t r a l B l u e BT

P h t h a l o c y a n ne b l u e

C i ba-

Trade Named Raw Materials

479

R A W MATERIAL M o n a s t r a l Red Y RT-759-D

CHEMICAL DESCRIPTION Red

SOURCE C i ba-

Monastral V i o l e t R RT-201 - D

V iolet

C i ba-

A n t i - s e t t l i n g agent

NLChem

N a c o r r 1552

Rust i n h i b i t o r

King

Nacure 155

Catalyst

King

Nacure 5225

Catalyst

King

N a l c o 435-36

Antifoam

Nalco

N a l c o 655-769

A n t i foam

Nalco

N a l c o 955-815

Antifoam

Nalco

N a l c o #2300

A n t i foam

Nalco

N a l c o 2302

A n t i foam

Nalco

N a l c o 2309

A n t i foam

Nalco

Nalzin 2

Z i n c hydroxy p h o s p h i t e

Rheox

N a t r o s o l P l u s , 330

Modified hydroxyethylcellulose

Aqualon

Natrosol Plus

Modified hydroxyethylcellulose

Aqualon

N a t r o s o l 250

Hydroxycellulose

Aqual on

N a t r o s o l 250HR

Hydroxyethylcellulose

Aqual on

N a t r o s o l 250MR

Hydroxyethylcellulose

Aqualon

N e o c r y l A-640

A c r y l ic copolymer

ICIRes

Neosil A

S i 1 ica e x t e n d e r

Tammsco

N i a x PCP-0301

Polyester poly01 r e s i n

UnCarb

M-P-A

1075

480

Water-Based Paint Formulations

RAW MATERIAL N i c k e l HCT

CHEMICAL D E S C R I P T I O N

SOURCE Novamet

N i g r o s i ne 128-6 Conc. Pdr

Nopco KFS

Defoamer

Henkel

Nopco NDW

Defoamer

Henkel

Nopco NXZ

Defoamer

Henkel

Nopco 1907

Defoamer

Henkel

Nopcoci de N-40-D

Fungicide

Henkel

Nopcoci de N-96

M i 1dewci de

Henkel

Nopcosperse 44

Dispersant

Henkel

Novaci t e L207A

S i l i c a e x t e n d e r pigment

Malvern

Novaci t e L-337

S i l i c a e x t e n d e r p gment

Malvern

Novaci t e S-325

S i l i c a e x t e n d e r p gment

Malvern

Novaperm F3RK70

Hoechst

Novaperm Red F5RK

Hoechst

Nuoci de 404-D

Mildewcide

Hul s

Nuocure Manganese 6%

Catalyst

Huls

Nuocure C o b a l t 10%

Catalyst

Hul s

Nuocure CK-10

Catalyst

Hul s

Nuocure Mn

Catalyst

Hul s

Nuosept 9 5

Preservative

Hul s

Nuosept 145

P r e s e r v a t ive

Huls

Nuosperse 657

D i s p e r s i n g agent

Hul s

Nyad G

Wol 1a s t o n i t e

Nyco

Trade Named Raw Materials

481

SOURCE

RAW MATERIAL N y t a l 300

CHEMICAL DESCRIPTION Talc

Vander-

N y t a l 400

Talc

Vander-

OK-41 2

F l a t t ng agent

Degussa

OK-500

F l a t t ng agent

Degussa

Oncor F-31

A n t i - c o r r o s i v e pigment

NLChem

Oncor M50

A n t i - c o r r o s i v e pigment

NLChem

Optiwhi t e

Anhydrous aluminum s i l i c a t e

Burgess

Oswego Orange X-2065

Orange

C i ba-

PA-320

A n t i foam

USMovi d

PA-454

A n t i foam

USMovi d

P a i n t A d d i t i v e #14

Flow and l e v e l i n g agent

DowCorn

Palomar Green 65406

Green

M i 1es

P a r a p l ex WP-1

Plasticizer

Rohm&

Pasco 311

Zinc oxide

Pacific

P a t c o t e 519

Defoamer

Patco

P a t c o t e 531

Defoamer

Patco

P a t c o t e 550

Defoamer

Patco

P a t c o t e 577

Defoamer

Patco

P a t c o t e 847

Defoamer

Patco

PAG-188

482

Water -Based Paint Formulations

RAW MATERIAL P a t c o t e 888

CHEMICAL D E S C R I P T I O N Defoamer

SOURCE Patco

Pentex 99

Anionic surfactant

Rhone-

P h t h a l o B l u e BT-417D

81 ue

duPont

P l i o l i t e 7103

S t y r e n e - b u t a d i e n e copolymer

Goodye-

P l i o l i t e 7104

S t y r e n e - b u t a d i e n e copolymer

Goodye-

P o l y c o 2161

P o l y v i n y l a c e t a t e emulsion

Rohm&

Pol ycompound W-953

Leveling a i d

BASF

P o l y g l o s s 90

C 1 ay

Huber

Polymon B l u e

Pigment

IC1

Polyphase AF-1

Fungicide

Troy

P o l y w e t ND-2

Dispersant/surfactant

Uni r o y -

Propasol B

Industrial solvent

UnCarb

Propasol P

Industrial solvent

UnCarb

Propyl Carbi t o 1

I n d u s t r i a1 s o l v e n t

UnCarb

P r o p y l Cel l o s o l v e

I n d u s t r i a1 s o l v e n t

UnCarb

P r o p y l Propasol

Coalescent

UnCarb

P r o x e l GXL

Chemical b i o c i d e

IC1

Pyrax WA

P y r o p h y l l it e m i n e r a l

Vander-

QR-681 -M

Rheology modi f ie r

Rohm&

Polyphobe 111

Trade Named Raw Materials

CHEMICAL DESCRIPTION

483

SOURCE

RAW MATERIALS R-2899D

Red ir o n o x i d e

P f iz e r

Raven B l a c k 16

Carbon b l a c k

Col umb-

Raven #14 Powder

Carbon b l a c k

Col umb-

Raven 150

Carbon b l a c k

Col umb-

Raven 420

Carbon b l a c k

Col umb-

Raven 1020

Carbon b l a c k

Col umb-

Raven 1035

Carbon b l a c k

Col umb-

Raven 1250

Carbon b l a c k

Col umb-

Raven 1255

Carbon b l a c k

Col umb-

Raven 2000

Carbon b l a c k

Col umb-

Raybo 62-HydroFlo

Addi t i ve

Raybo

Red I r o n Oxide R-4098

Pure r e d i r o n o x i d e

P f iz e r

Red Oxide R0-3097

Red i r o n o x i d e

Harcros

Red Oxide 130M

Red i r o n o x i d e

Red Oxide #4098-D

Red i r o n o x i d e

P f iz e r

Resimene 1-720

Me1ami ne r e s i n

Monsan-

Resimene 740

Me1ami ne r e s i n

Mon san -

Resimene 745

Me1ami ne r e s i n

Mon san-

Resimene 797

Melami ne r e s i n

Monsan-

Resin BAL-389

Water b o r n e p o l y e s t e r

Amoco

Resin WA-17-2T

Water-Reducible

Eastman

R e s i n WA-17-6C

Polyester r e s i n

Eastman

R e s i n WB-17-INS

Polyester r e s i n

East man

Resin WB-151

A i r drying alkyd

Amoco

a l k y d enamel

484

Water-Based Paint Formulations

RAW MATERIAL Resin WE-300

CHEMICAL DESCRIPTION Po 1yes t e r

SOURCE Amoco

Resin WB-408

Alkyd r e s i n

Amoco

Res1 n WE-3623

Alkyd r e s i n

Amoco

Resin WS-3-1C

Polyester r e s i n

Eastman

Resin WS-3-2C

Polyester r e s i n

Eastman

R e s i n WS-17-1T

Polyester r e s i n

Eastman

Rex Orange X-2806

M o l y b d a t e . Red 104

C i ba-

R h e o l a t e 255

R h e o l o g i c a l addi t i ve

Rheox

R h e o l a t e 278

Rheological a d d i t i v e

Rheox

Rheology M o d i f i e r QR-708

Thickener

Rohm&

Rheology M o d i f i e r OR-1001 T h i c k e n e r

Rohm&

Rhodopol 2 3

Xanthan

Rhone-

Rhoplex AC-33

A c r y l i c emu s i o n . 44.5% s o l i d s

Rohm&

Rhopl ex AC-64

A c r y l i c emu s i o n . 60.5% s o l i d s

Rohm&

Rhopl ex AC-388

A c r y l i c l a t e x . 50% s o l i d s

Rohm&

Rhoplex AC-417

A c r y l i c l a t e x . 48% s o l i d s

Rohm&

Rhopl ex AC-490

A c r y l i c l a t e x . 46% s o l i d s

Rohm&

Rhoplex AC-507

A c r y l i c l a t e x . 46.5% s o l i d s

Rohm&

Rhopl ex AC-604

A c r y l ic 1 a t e x . 46.0% sol i d s

Rohm&

Rhopl ex AC-658

A c r y l i c l a t e x . 47.0% s o l i d s

Rohm&

Rhoplex AC-707

Acrylic latex

Rohm&

Rhoplex AC-829

A c r y l i c l a t e x . 55.0% s o l i d s

Rohm&

Rhoplex AC-1024

A c r y l i c l a t e x . 55.0% s o l i d s

Rohm&

Rhopl ex AC-1230

A c r y l i c l a t e x . 47.0% s o l i d s

Rohm&

Trade Named Raw Materials

485

SOURCE

RAW MATERIAL Rhopl ex AC-1822

CHEMICAL DESCRIPTION A c r y l i c l a t e x . 46.5% s o l i d s

Rohm&

Rhopl ex AC-2045

A c r y l ic 1 a t e x

Rohm&

Rhoplex CL-103

A c r y l ic 1a t e x

Rohm&

Rhoplex CL-104

A c r y l ic 1a t e x

Rohm&

Rhoplex MC-76

A c r y l ic 1a t e x

Rohm&

Rhoplex MV-2

A c r y l i c l a t e x . 46.0% s o l i d s

Rohm&

Rhoplex MV-9

A c r y l i c l a t e x . 45.5% s o l i d s

Rohm&

Rhopl ex MV-23

A c r y l i c l a t e x . 43% s o l i d s

Rohm&

Rhopl ex SG-10

Acrylic latex

Rohm&

Rhoplex WL-71

A c r y l i c p o l y m e r . 41.5% s o l i d s

Rohm&

Rhopl ex WL-96

A c r y l i c polymer

42% s o l i d s

Rohm& Rohm&

RM-025 Ropaque OP-62

Opaque polymer

Rohm&

Ross&Rowe 551

Modified l e c i t h n

Ross&

JMHuber

Samhide 503 Sant i c i z e r 160

P1a s t i c i z e r

Monsan-

Satintone # l

C a l c i n e d aluminum s i l i c a t e

Engel -

S a t i n t o n e US

C a l c i n e d aluminum s i l i c a t e

Engel -

Sati ntone W

Cal c i ned a1 umi num s i 1 ic a t e

Engel -

SCT 270

Associative thickener

UnCarb

SCT 275

Associative thickener

UnCarb

Shieldex

I n h i b i t i v e pigment

Grace

486

Water -Based Paint Formulations

RAW M A T E R I A L S i c o r ZNP-M

CHEMICAL DESCRIPTION A n t i - c o r r o s i o n pigment

BASF

S i l i c a #19

Silica

WC&D

S i l w e t L-77

S u r f a c e a c t i v e copolymer

UnCarb

S i l w e t L-7600

S u r f a c e a c t i v e copolymer

UnCarb

S i l w e t 7605

S u r f a c e a c t i v e copolymer

UnCarb

Skane M8

M i 1dewci de

Rohm&

Skino #l

A n t i s k i n n i ng agent

OMGr o up

S l i p Ayd 18

Surface c o n d i t i o n e r

Daniel

Snowf 1ake

Calcium c a r b o n a t e

ECC

Snow*Tex 45

Calcined c l a y

U S S i 1i-

Special Black 4

Carbon b ack

Degussa

S p e c i a l B l a c k 4A

Carbon b ac k

Degussa

Spensol L44

Urethane p o l y 0 1

Reich-

Stapa H y d r o l a c W 6 0 n . l

Aluminum pigment

A1 umi n-

Sterl ing R

Carbon b l a c k

Cabot

Zinc o x i d e

S t . Joe

S t r o d e x MOK-70

Surfactant

Dexter

S t r o n t i u m Chromate 51365

S t r o n t i u m chromate

Mineral

S t r o n t i u m Chromate 30-AC-3008

S t r o n t i u m chromate

H i 1t o n -

Sun F a s t 264-8142

Pigment

SunChem

Super-Ad-It

Fungicide

Hul s

Super Beckamine 27-568

Synthetic resin

Rei ch-

SOURCE

Spaceri t e S-11

St.

Joe #40 ZnO

Trade Named Raw Materials

RAW MATERIAL Supercoat

CHEMICAL D E S C R I P T I O N

487

SOURCE ECC

S u r f y n o l DF-75

Surfactant

A i rProd

S u r f y n o l GA

Surfactant

A i rProd

S u r f y n o l PC

Surfactant

A i rProd

S u r f y n o l TG

Surfactant

A i rProd

S u r f y n o l 104

Surfactant

A i rProd

S u r f y n o l 104A

Surfactant

A i rProd

S u r f y n o l 104BC

Surfactant

A i rProd

S u r f y n o l 104E

Surfactant

A i rProd

S u r f y n o l 104H

Surfactant

A i rProd

sws

A n t i foam

Wacker

S y l o i d 72

S i l i c a f l a t t i n g agent

Davi son

S y l o i d 74

S i l i c a f l a t t i n g agent

Davi son

S y l o i d 74x3500

S i l i c a f l a t t i n g agent

Davi son

S y l o i d 83

S i l i c a f l a t t i n g agent

Davi son

S y l o i d 161

S i l i c a f l a t t i n g agent

Davi son

S y l o i d 166

S i l i c a f l a t t i n g agent

Davi son

S y l o i d 169

S i l i c a f l a t t i n g agent

Davi son

S y l o i d 234

S i l i c a f l a t t i n g agent

Davi son

S y l o i d 308

S i l i c a f l a t t i n g agent

Davi son

S y l o i d 978

S i l i c a f l a t t 5 n g agent

Davi son

Syntex 3981

Accelerator

Rhone-

Synthemul 40-412

A c r y l i c p o l y m e r . % s o l i d s : 50

Reich-

Synthemul 40-422

A c r y l i c polymer. % s o l i d s :

Rei ch-

211

49

488

Water-Based Paint Formulations

RAW MATERIAL Synthemul 40-423

CHEMICAL DESCRIPTION A c r y l i c p o l y m e r . % s o l d s : 45

SOURCE Rei ch-

Synthemul 40-424

A c r y l c p o l y m e r . % s o l ds: 40

Rei ch-

Synthemul 40-430

A c r y l c p o l y m e r . % s o l i d s : 50

Rei ch-

Synthemul 40-431

A c r y l c p o l y m e r . % s o l i d s : 50

Rei ch-

Synthemul 97-603

A c r y l c p o l y m e r . % s o l i d s : 45

Rei ch-

Synthemul 97-799

A c r y l i c p o l y m e r . % s o l i d s : 50

Rei ch-

S y n t h e t i c I r o n Oxide Y e l l o w 1103

Mineral

S y n t h e t i c Red I r o n Oxide R0-3097

Harcros

S y n t h e t i c Y e l l o w I r o n Oxide YLO-3288-D

Harcros

T a l c 399

Extender pigment

WC&D

T a l c 499

Extender pigment

WC&D

T a l c r o n MP40-27

Talc

P f iz e r

Tamol SG-1

Dispersant

Rohm&

Tamol 165

Dispersant

Rohm&

Tamol 681

Dispersant

Rohm&

Tamol 731

Dispersant

Rohm&

Tamol 850

Dispersant

Rohm&

Tamol 960

Dispersant

Rohm&

Tamol 1124

Dispersant

Rohm&

Tamol 1254

Dispersant

Rohm&

Tan 10A

Col umb-

Tego 1488

Golds-

Trade Named Raw Materials

489

RAW MATERIAL Tektamer 38

CHEMICAL DESCRIPTION Preservative

SOURCE Cal gon

Tenneco 8800 L i n e

Lampblack O.S/Raw Umber 0 . 2

Hul s

T e r g i t o 1 NP-40

Noni on ic s u r f a c t a n t

UnCarb

Texanol

Coalescent

Eastman

T h i c k e n e r LN

GAF

T i n u v i n 440

C i ba-

T i n u v i n 1130

C i ba-

T i o n a RCL-9

T i t a n i um d i o x i d e

SCM

T i ona RCL-535

T i t a n i um d i o x i d e

SCM

T i ona RCL-628

T i t a n i um d i o x i d e

SCM

T i o x i d e TR92

Titanium dioxide

T i o x i de

T i -Pure R-700

High g l o s s t i t a n i u m d i o x i d e

DuPont

T i - P u r e R-702

Titanium dioxide

DuPont

T i - P u r e R-900

Titanium dioxide.

Rutile

DuPont

T i -Pure R-9OOHG

Titanium dioxide. R u t i l e

DuPont

T i -Pure R-901

T i t a n i u m d i o x i d e . R u t i l e . 8 8 % assay DuPont

T i - P u r e R-902

T i t a n i u m d i o x i d e . R u t i l e . g l % assay DuPont

T i -Pure R-931

T i t a n i u m d i o x i d e . R u t i l e . 8 5 % assay DuPont

T i -Pure R-960

T i t a n i u m d i o x i d e . R u t i l e . 8 9 % assay DuPont

T i - P u r e R-960 VHG

T i t a n i urn d i o x i d e . R u t i 1 e

DuPont

T i t a n o x AWD

Titanium dioxide

Kronos

T i t a n o x 2020

T i t a n i u m d i o x i d e . R u t i l e . 9 4 % assay Kronos

T i t a n o x 2101

T i t a n i u m d i o x i d e . R u t i l e . 9 2 % assay Kronos

T i t a n o x 2160

T i t a n i um d i o x i d e . R u t i 1e . 90% assay Kronos

490

Water-Based Paint Formulations

RAW MATERIAL T o l u i d i n e Red RD-0027

CHEMICAL DESCRIPTION

SOURCE Uhlich

T r i b u t o x y E t h y l Phosphate

FMC

T r i t o n CA

W e t t i n g agent

UnCarb

T r i t o n CF-10

W e t t i n g agent

UnCarb

T r t o n GR-7

Wett ng agent

UnCarb

T r tor1 GR-7M

Wett ng agent

UnCarb

T r t o n N-57

Wett ng agent

UnCarb

T r t o n N-101

Wett ng agent

UnCarb

T r i t o n X-100

W e t t i n g agent

UnCarb

T r i t o n X-102

W e t t i n g agent

UnCarb

T r i t o n X-114

W e t t i n g agent

Uncarb

T r i t o n X-207

W e t t i n g agent

UnCarb

T r i t o n X-405

W e t t i n g agent

UnCarb

Tronox CR-800

T i t a n i u m d i o x i d e . R u t i l e . 9 5 % assay K e r r -

Tronox CR-808

Titanium dioxide

Kerr-

Tronox CR-812

Titanium dioxide

Kerr-

Tronox CR-813

T i t a n i um d i o x i d e

Kerr-

Tronox CR-820

T i t a n i um d i o x i d e . R u t i l e . 8 7 % assay K e r r -

Tronox CR-821

Titanium dioxide

Kerr-

Tronox CR-828

Titanium dioxide

Kerr-

Troysan Polyphase AF-1

Fungicide

Troy

Troysan 174

Fungicide

Troy

Troysan 186

Fungicide

Troy

Troysan 364

Fungicide

Troy

TS- 100

F1a t t ing agent

Degussa

Trade Named Raw Materials

491

RAW MATERIAL Ucar 367

CHEMICAL DESCRIPTION V i n y l - a c r y l i c polymer

SOURCE UnCarb

Ucar L a t e x 376

V i n y l - a c r y l ic polymer

UnCarb

Ucar 379

V i n y l - a c r y l ic 1a t e x

UnCarb

Ucar L a t e x 430

A c r y l i c polymer

UnCarb UnCarb

Ucar 522 Ucar 525

M o d i f i e d a c r y l i c polymer

UnCarb

Ucar L a t e x 624

A c r y l ic 1 a t e x

UnCarb

Ucar L a t e x 625

A c r y l ic 1a t e x

UnCarb

Ucar Polyphobe 102

Thickener

UnCarb

Ucar Polyphobe 104

Rheology m o d i f i e r

UnCarb

Ucar 4431X

A c r y l i c l a t e x polymer

UnCarb

Ucar F i l m e r I B T

UnCarb

Ucar L a t e x 154

UnCarb

Ucar SCT 200

Thickener/rheology m o d i f i e r

UnCarb

Ucar SCT 270

Thickener/rheology m o d i f i e r

UnCarb

Ucar SCT 275

Thickener/rheology m o d i f i e r

UnCarb

Ucar S o l v e n t 2LM

D i p r o p y l ene g l y c o l monoethyl

UnCarb

UCD 4820Q

Bee

Uformi t e MM83

Urea-forma dehyde r e s i n

Rei ch-

Uni t a n e OR-600

Titanium d oxide. R u t i l e .

Kemi r a

Unocal 3084 U v i n u l N539

Rohm& UV a b s o r b e r

BASF

492

Water-Based Paint Formulations

RAW MATERIAL Vancide TH

CHEMICAL D E S C R I P T I O N 8 a c t e r i c i d e - f u n g i c i de

SOURCE Vander-

Van Dyke Brown

Pigment

Landers

Van-Gel

Thixotrope

Vander-

Thixotrope

Vander-

Woll a s t o n i t e

Vander-

A 1 ip h a t ic s o l v e n t

Exxon

Veegum T

Magnesi um a1 umi num s i 1 ic a t e

Vander-

Vera B l a n c

C a l c i um c a r b o n a t e

NLChems

Van-Gel

8

Vansi 1 W-10 V a r s o l No.

1

V e r s a f l o w 102

Shamro-

V i c r o n 1515

Ground l i m e s t o n e

P f iz e r

Vinac 885

P o l y v i n y l a c e t a t e homopolymer

A i rProd

WA-8

Opaque s t a i n

USCel 1 -

W a l l p o l 40-136

S y n t h e t i c r e s i n emulsion

Reich-

Water R e d u c i b l e M o d i f i e d P o l y o l e f i n 73-7358

C a r g i 11

Wave 345

Wet adhesion t e r p o l y m e r

A i rProd

WB-1 38 D i s p e r s i on

Polyester r e s i n

Amoco

WE-389 D i s p e r s i o n

Polyester r e s i n

Amoco

WD-2348 T i n t Paste

Black

Dani e l s

W i tcobond W234

Aqueous p o l y u r e t h a n e d i s p e r s i o n

Witco

W i t c o 3056-A

W itco

Trade Named Raw Materials

493

RAW MATERIAL X-1134 CP

CHEMICAL DESCRIPTION Cr203 Green

SOURCE C i ba-

X-1843 Madras Orange

Orange

C i ba-

X-2806 Red Orange

Orange

C i ba-

Rohm&

XAMA-7 XX-503R

Y-5775

Fast Yellow

Z i n c Oxide

Zinc

Ye1 1ow

Harmon

Y e l l o w I r o n Oxide 2288D

P f iz e r

Y e l l o w I r o n Oxide YLO-1888D

P f iz e r

YLO-3288D

F e r r i c oxide

P f iz e r

Zeolex 80

Sodium a l u m i n o s i l i c a t e

JMHuber

Z i n c Oxide XX-503

Zinc oxide

NJZi nc

Z i n c Oxide XX-601

Zinc oxide

N J Z i nc

Z i n c Phosphate 50852

Z i n c phosphate

Mineral

Z i n c Y e l l o w Y-539D

Zinc yellow

Heubach

Z i r c o n i u m Hydro-Cem

Zirconium d r i e r ,

Z i r c o n i um H y d r o c u r e

Drier catalyst

Zopaque RCL-9

T i t a n i um d i o x i d e . R u t i l e . 94% assay SCM

12%

Mooney OMGroup

494

Water-Based Paint Formulations

CHEMICAL DECRIPTION C a l c i um carbonate

SOURCE ECC

13-3060 Novoperm A 2 0

Red

Hoechst

76 RES 4076

Polymer emulsion

Rohm&

106 Lo M i c r o n B a r y t e s

Extender pigment

WC&D

290 Lo M i c r o n B a r y t e s

Extender pigment

WC&D

325 M i c a

Mica

English

3 9 9 Lo M i c r o n T a l c

Extender pigment

WC&D

499 T a l c

Extender pigment

WC&D

1160 S i l i c a

Silica

Illin-

RAW MATERIAL #1 White #10 White

301 1

496

Water -Based Paint Formulations

A i r P r o d u c t s and Chemicals

7201 H a m i l t o n B l v d . A l l e n t o w n , PA 18195 (215)-481-4911/(800)-345-3148

ARC0 Chemical Co. 3801 West Chester P i k e Newtown Square, PA 19073

(215)-359-2000

Akzo Chemicals, I n c . 300 S. R i v e r s i d e P l a z a Chicago, I L 60175 (312)-906-7500/(B00)-257-8292

Asarco, I n c . 180 Maiden Lane New York, NY 10038

A l c o a I n d u s t r i a l Chemicals P . O . Box 67 B a u x i t e , AR 72011

Ashland Chemical Co. P . O . Box 2219 Columbus, OH 43216

(501)-776-4981/(800)-643-8771

(614)-889-3333/(800)-828-7659

American Cyanamid Co. Chemicals Group One Cyanamid P l a z a Wayne, NJ 07470

BASF Corp.

(21 2)-510-2000

100 C h e r r y H i 11 Road P a r s i p p a n y , NJ 07054 (201 )-316-3000/(800)-526-1072

(201)-831-2000/(800)-443-0443 Buckman L a b o r a t o r i e s I n t ’ l . I n c . 1256 N . McLean B l v d . Memphis, TN 38108 (901)-278-0330/(BOO)-EWCKMAN

American L e c i t h i n Co. 33 T u r n e r Rd. P.O. Box 1908 Danbury, CT 06813

(203)-790-2700 American Powdered M e t a l s , 225 Broadway New York, NY 10007

Inc.

(212)-267-4900/(800)-322-0323 Amoco Chemical Co. 200 E . Randolph D r . Chicago, I L 60601

(312)-856-3200/(800)-621-4567 Angus Chemical Co. 1500 E . Lake Cook Rd. B u f f a l o Grove, I L 60089

(708)-215-8600/(800)-362-2580 Aqua1 on P . O . Box 15417 2711 C e n t r e v i l e Rd. W i 1m i n g t o n , DE 19850

(302)-996-2000/(800)-345-6104

Burgess Pigment Co. P . O . Box 349 Sandersvi 11e, GA 31 082

(912)-552-2544/(800)-841-8999 Byk-Chemi e USA 524 S . C h e r r y S t . Wall in g f o r d , CT 06492

(203)-265-2066 Cabot Corp. R t . 36 West T u s c o l a , I L 61953

(217)-253-3370/(800)-222-6745 Calgon Corp. P . O . Box 1346 P i t t s b u r g h , PA 15230 (412)-777-8000/(800)-4-CARBON

Suppliers' Addresses

Cargill, Inc. Box 5630 M i n n e a p o l i s , MN 55440

(612)-475-6478/(800)-535-1443

D a u b e r t Chemical Co. S . C e n t r a l Ave. Chicago, I L 60638 (708)-496-7350 Davi son Chemi c a l D i v . Grace 8 Co. P.O. Box 2117 B a l t i m o r e , MD 21203

Cel it e Corp. P.O. Box 519 Lompoc, CA 93438 (805)-735-7791

W.R.

Chemical Corp. o f America 2 C a r l t o n Ave. E. R u t h e r f o r d , N J 07073 (201)-438-5800

Degussa Corp. 65 C h a l l e n g e r Rd. R i d g e f i e l d Park, N J 07305 (201 )-641-6100

C i ba-Gei gy Corp. 7 Skyline D r . Hawthorne, NY 10532

D e x t e r Chemical Corp. 845 Edgewater Road Bronx, NY 10474

(914)-347-4700/(800)-431-1900 Colloids, Inc. 1525 Church S t . M a r i e t t a , GA 30060

Dow Chemical USA 2020 W i l l a r d H Dow C e n t e r M i d l a n d , M I 40674 (800)-447-4DOW

Col umbi an Chemicals Co. 1600 Parkwood C i r c l e S u i t e 400 A t l a n t a , GA 30339

Dow C o r n i n g Corp. Box 0994 M i d l a n d , M I 48686 (51 7)-496-4000

(404)-951-5700/(800)-235-4003 C o n t i n e n t a l Chemical Co. 2686 L i s b o n Rd. C l e v e l a n d , OH 44104

Drew I n d u s t r i a l D i v . A s h l a n d Chemical I n c . One Drew P l a z a Boonton, NJ 07005

(216)-721-4747/(800)-929-4633

(201)-263-7800/(800)-526-1015

Cosan Chemical Corp. 400 1 4 t h S t . C a r l s t a d t , NJ 27072 (201 1-460-9300

D r y Branch K a o l i n Co. Route #1 BOX 468-D D r y Branch, GA 30120

(912)-7500-3500/(800)-DBK-CLAY C r u c i b l e Chemical Co., P.O. Box 6786 G r e e n v i l l e , SC 29606

Inc.

(803)-277-1284/(800)-845-8873 Daniel Products 400 Claremont Ave. J e r s e y C i t y , NJ 07304 (201)-432-0800

DuPont Co. 1007 M a r k e t S t . W i l m i n g t o n , DE 19898 (800) -441 -751 5 Durkee/SCM Chemicals 2701 B r o e n i n g Hwy B a l t i m o r e , MD 21222 (301)-288-8884/(800)-638-3234

497

498

Water-Based Paint Formulations

Eastman Chemical Co. P . O . Box 431 K i n g s p o r t , TN 37662

G e o r g i a M a r b l e Co. 1201 R o b e r t s B l v d . , Kennesaw, GA 30144

(615)-229-2318/(800)-EASTMAN

(404)-421-6500

ECC I n t e r n a t i o n a l

Gold Bond B l d g . P r o d u c t s D i v . N a t i o n a l Gypsum Co. 2001 R e x f o r d Rd. C h a r l o t t e , NC 28211

5775 Peachtree-Dunwoody Rd. A t l a n t a , GA 30342 (404)-843-1551/(800)-843-3222

B l d g . 100

(704)-365-7300 E n g e l h a r d Corp. 101 Wood Ave. I s e l i n , NJ 08830

(908)-205-5000 E n g l i s h Mica Co. Ridgeway C e n t e r B l d g . Stamford, CT 06905

(203)-324-9531

Goldschmidt Chemica P . O . Box 1299 914 E. Randolph Rd. Hopewell, VA 23860

Corp.

(804)-541-8658/(800 -446-1 809 Goodyear T i r e & Rubber Co. 1144 E . Market S t . Akron, OH 44316

Exxon Chemical Americas 13501 K a t y Frwy Houston, TX 77079

W.R.

(713)-870-6000/(800)-231-6633

55 Hayden Ave.

(216)-796-3010 Grace & Co.-Conn

L e x i n g t o n , MA 02173 FMC Corp. P . O . Box 4239 GCS New York, NY 10163

(215)-299-6000/(800)-732-3278 GAF Chemicals Corp. 1361 A l p s Rd. Wayne, NJ 07470

(201)-626-3000 GE S i 1 i c o n e s 260 Hudson R i v e r Rd. W a t e r f o r d , NY 12188

(518)-237-3330/(800)-255-8886 General E l e c t r i c 21800 Tungsten Rd. E u c l i d , OH 44117

(216)-266-2451/(800)-255-8886 Genstar Stone P r o d u c t s Co. Exec P l a z a I V 11350 McCormick Rd. Hunt V a l l e y , MD 21031

(410)-527-4000

(617)-661-6600 Hammond Lead P r o d u c t s , P.O. Box 6408 5231 Hohman Ave. Hammond, I N 46325

Inc.

(219)-931-9360 H a r c r o s Chemical s I n c 5200 Speaker Rd. Kansas C i t y , KS 66106

.

(913)-321-3131 Harmon C o l o r s Corp. P . O . Box 419 Hawthorne, NJ 07507

(201)-274-3232 Harshaw/Fi l t r o l P a r t n e r s h i p 30100 C h a g r i n B l v d . C l e v e l a n d , OH 44124 Henkel Corp. 300 B r o o k s i d e Ave. Ambler, PA 19002

(215)-628-1000/(800)-922-0605

Suppliers' Addresses

Hercules, I n c . Hercules Plaza W i 1m i ngton, DE 19894 (800)-247-4372

I C 1 Specialties Concord P i k e & New Murphy Rd. W i 1m i n g t o n , DE 19897

Heucotech , L t d . 99 Newbold Road F a i r l e s s H i l l s , PA 19030 (215)-736-9533/(8OO)-HEUBACH

Indusmi n 365 B l o o r S t . - S u i t e 200 T o r o n t o , ON CN M4W 3L4

H i 1t o n - D a v i s Co.

2235 Langdon Farm R d . C i n c i n n a t i , OH 45237

(302)-886-3000/(800)-822-8215

International Minerals & Chemicals Corp. 421 E . Hawley S t . M u n d e l e i n , I L 60060

(513)-841-4000/(800)-477-1022 Hoechst Celanese Corp. Speci a1 t y Chemicals Group 5200 77 C e n t e r D r i v e C h a r l o t t e , NC 28217

(704)-559-6000/(800)-365-2436 Hoover C o l o r Corp. P.O. Box 218 Hiwassee, VA 24347 (7031-980-7233 J.M. Huber Corp. C a l c i u m Carbonate D i v . 2029 Woodlands Pkwv S t . L o u i s , MO 63146

(217)-224-1100/(800)-637-8176 J.M. Huber Corp. Clay D i v . One Huber Rd. Macon, GA 31298

(912)-745-4751/(800)-637-8176 H u l s America I n c .

80 C e n t e n n i a l Ave. Piscataway, NJ 08855 (908)-980-6800/(800)-631-5275 I C 1 R e s i n s US 730 Main S t . W i l m i n g t o n , MA 01887

(508)-658-6600/(800)-225-0947

I n t e r s t a b Chemicals, I n c . 500 J e r s e y Ave. P . O . Box 638 New B r u n s w i c k , NJ 08903 S . C . Johnson Polymer 1525 Howe S t . Raci ne, W I 53403

(414)-631-4875/(800)-231-7868 Kaopolite, Inc. 2444 M o r r i s Ave. Union, NJ 07083 (908)-851-2974 Kemira, I n c . Box 368 Savannah, GA 31402 (912)-236-6171/(800)-4-KEMIRA Kerr-McGee Chemical Corp. Kerr-McGee C t r . P . O . Box 25861 Oklahoma C i t y , OK 73125

(405)-270-1313/(800)-654-3911 King I n d u s t r i e s , I n c . Science R d . Norwalk, CT 06852

(203)-866-555l/(800)-431-7900 KMG M i n e r a l s , I n c . P . O . Box 729 1433 Grover R d . K i n g s Mountain, NC 28086

(704)-739-3616/(800)-443-MICA

499

500

Water-Based Paint Formulations

Kronos, I n c . P . O . Box 60087 3000 N . Sam Houston Pkwy Houston, TX 77205

Miles Inc. Mobay Rd. Pittsburgh,

PA 15205 (412)-777-2000/(800)-662-2927

(7131-987-6300 Landers-Segal C o l o r c o 84 Dayton Ave. P a s s a i c , NJ 07055

.

M i n e r a l Pigments Corp. Davis C o l o r s 7011 M u i r k i r k Rd. B e l t s v i 1 l e , MD 20705

(201 ) -779-8948 L u b r i z o l Corp. 29400 Lakeland B l v d . W i c k l i f f e , OH 44092

Monsanto Chemical Co. 800 N . L i n d b e r g h B l v d . S t . L o u i s , MO 63167

(314)-694-1000/(800)-325-4330

(216 )-943-4200 Mooney Chemicals I n c . Mal l i n c k r o d t S p e c i a l t y Chemicals2301 S c r a n t o n Rd. 16305 S w i n g l e y Ridge D r . C l e v e l a n d , OH 44113 S t . L o u i s , MO 63017 (314)-539-1241/(800)-325-7155 N a l c o Chemical Co. One N a l c o C t r . M a l v e r n M i n e r a l s Co. Napervi 1 l e , I L 60563 P . O . Box 1238 (708)-305-1000 Hot S p r i n g s N a t i o n a l P a r k , AK 71902 New J e r s e y Z i n c Co. (501)-623-8893 F o u r t h S t . & F r a n k l i n Ave. P a l m e r t o n , PA 18071 Manchem, I n c . 105 C o l l e g e Road East NL Chemicals, I n c . P . O . Box 700 P r i n c e t o n F o r r e s t a l Center P r i n c e t o n , NJ 08540 H i g h t s t o w n , NJ 08520 McCloskey V a r n i s h Co. 4155 N.W. Yern Ave. P o r t l a n d , OR 97210

Novamet S p e c i a l t y P r o d u c t s , 10 L a w l i n s Pk. Wyckoff, MJ 07481

Inc.

(201 )-891-7976 McWho r t e r 400 East C o t t a g e P l a c e C a r p e n t e r s v i l l e , I L 60110 The Mearl Corp. 41 E. 42 S t . New York, NY 10017

(2121-573-8500 Michelman, I n c . 9089 S h e l l Road C i n c i n n a t i , OH 45236

(513)-793-7766

H u l s America I n c .

80 C e n t e n n i a l Ave. Piscataway, NJ 08855 (908)-980-6800/(800)-631-5275 Nyco M i n e r a l s P . O . Box 368 W i 1 1s b o r o , NY

(5181-963-4262

nc

.

2996

Suppliers’ Addresses

2301 S c r a n t o n Rd. C l e v e l a n d , OH 44113

Sandoz Chemicals Corp. 4000 Monroe Rd. C h a r l o t t e , NC 28205

(216)-781-8383/(800)-321-9696

(704)-331-7078/(800)-631-8077

Pasco Z i n c P r o d u c t s Corp. P . O . Box 280998 3380 F i t e Rd. Memphis, TN 38186

SCM Chemical s

Patco Polymer A d d i t i v e s C . J . P a t t e r s o n Co. 3947 Broadway Kansas C i t y , MO 64111

Shamrock T e c h n o l o g i e s , Foot o f P a c i f i c S t . Newark, NJ 07114 (201)-242-2999

OM Group I n c .

2701 B r o e n i n g Hwy B a l t i m o r e , MD 21222

(301)-288-8884/(800)-638-3234 Inc.

(816)-561-9050/(800)-669-2250 Pfizer, Inc. 235 E . 42 S t . New Y o r k , NY 10017 (212)-573-7217 Raybo Chemical Co. P.O. Box 2155K H u n t i n g t o n , WV 25722

Sherwin W i l l i a m s Co. Chemicals D i v . P . O . Box 6520 C l e v e l a n d , OH 44101 (216)-566-2344 S i l b e r l i n e Mfg. Co., P.O. Box A L a n s f o r d , PA 18232 (71 7)-668-6050

Inc.

R e i c h h o l d Chemicals, I n c . P.O. Box 13582 Steoan Co. Research T r i a n g l e Park, NC27709 22 W. F r o n t a g e Rd. (919)-990-7500/(800)-448-3482 N o r t h f i e l d , I L 60093 (708)-446-7500/(800)-745-7837 Rheox, I n c . P . O . Box 700 Sun Chemical Corp. H i g h t s t o w n , NJ 08520 4526 C h i c k e r i n g Ave. C i n c i n n a t i , OH 45242 (6091-443-2500

(513)-681-5950/(800)-543-2323 Rhone-Poulenc Performance R e s i n s & C o a t i n g s 9808 B l u e g r a s s Pkwy J e f f e r s o n t o w n , KY 40299 (502)-499-4011/(800)-626-2613 Rohm & Haas Co. Independence M a l l West P h i l a d e l p h i a , PA 19105

(215)-592-3000/(710)-670-5335

Tammsco, I n c . P.O. Box J Tamms, I L 62988 Thompson-Hayward Chemical Co. 5200 Speaker Rd. Kansas C i t y , KS 66106 (913)-321-3131

501

502

Water-Based Paint Formulations

3M Corp. B l d g 225-3s-05 S t . P a u l , MN 55144

.

(612)-733-lllO/(800)-362-3456

V a n d e r b i l t Co., Box 5150 30 W i n f i e l d S t . Norwalk, CT 06856 R.T. P.O.

Inc.

(203)-853-1400/(800)-243-6064 T r o y Corp. 72 Eagle Rock Ave. East Hanover, N J 07936 (201)-864-4300

Wacker S i l i c o n e s Corp. 3301 S u t t o n Rd. A d r i a n , M I 49221

(517)-264-8500/(800)-246-0063 U l r i c h Chemical I n c . 3111 N . P o s t Rd. I n d i a n a p o l i s , I N 46226 (3171-898-6632 U l t r a Additives, Inc. 460 S t r a i g h t S t . P a t e r s o n , NJ 07501

(201)-279-?306/(800)-524-0055

W h i t t a k e r Corp. H e i c o Chemical D i v . Delaware Watergap, PA ( 71 7 ) -476-0353

8327

W h i t t a k e r , C l a r k & Dan e l s , 1000 C o o l i d g e S t . S . P l a i n f i e l d , NJ 07080

Inc

(908)-561-6100/(800)-732-0562 Unimin Corp. 258 E l m S t . New Canaan, CT 06840 (203)-966-8880/(800)-243-9004

W i t c o Corp. 520 Madison Ave. New York, NY 10022

(212)-605-3941/(800)-238-9150 Union C a r b i d e Chemical s and P1a s t ic s 39 O l d R i d g e b u r y Rd. Danbury, CT 06817 (2031-794-5300 Uni r o y a l Chemical Co. Benson Rd. M i d d l e b u r y , CT 06749

(203)-573-2000/(800)-243-3024 U . S . S i l i c a Co. P.O. Box 187 B e r k e l e y S p r i n g s , WV 25411

(304)-258-2500/(800)-243-7500

Z i n c Corp. o f America 300 F r a n k f o r t Rd. Monaca, PA 15061

(412)-774-1020/(800)-962-7500