Hazardous Chemicals Desk Reference
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Hazardous Chemicals Desk Reference Sixth Edition
Richard J. Lewis, Sr.
633 WILEY
A JOHN WILEY & SONS, INC., PUBLICATION
Copyright 0 2008 by John Wiley & Sons, Inc. All rights reserved. Published by John Wiley & Sons, Inc., Hoboken, New Jersey. Published simultaneously in Canada. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at lcopyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 11 1 River Street, Hoboken, NJ 07030, (201) 748-601 1, fax (201) 7486008, or online at http://www.wiley,comlgo/permission. Limit of LiabilityiDisclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate. Neither the publisher nor author shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages. For general information on our other products and services or for technical support, please contact our Customer Care Department within the United States at (800) 762-2974, outside the United States at (317) 5723993 or fax (317) 572-4002. Wiley also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic format. For information about Wiley products, visit our web site at www.wiley.com. Library of Congress Cataloging-in-Publication Data: Lewis, Richard J., Sr. Hazardous chemicals desk reference / Richard J. Lewis, Sr. - 6th ed. p. cm. Includes index. ISBN 978-0-470-1 8024-2 (cloth) 1. Hazardous substances-Handbooks, manuals, etc. I. Title. T55.3.H3L49 2008 604.74~22 2008007188 Printed in the United States of America. 10 9 8 7 6 5 4 3 2 1
Dedicated to Grace Ross Lewis. Her effort and advice made this edition possible. Welcome to Ava Grace Herrmann, the latest addition to the new generation to carry the torch.
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Contents Preface
ix
Introduction
xi xix
Key to Abbreviations General Chemical Entries
1
CAS Number Cross-Index
1457
Synonym Cross-Index
1487
DOT Guide Cross-Index
1947
Vii
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Preface
This sixth edition of the Haxardous Chemicals Desk Reference again fills the need for a reference work of moderate size that serves the information needs of those who work with hazardous chemicals. Over 5,800 entries are included. Over 500 new entries were added. Some entries present in previous editions were removed to make room for more relevant substances and maintain the book at a reasonable size. Two-thirds of the entries have been revised for t h s edition. Most of the new entries were selected because they are on the EPA TSCA Inventory. These are reported to be used in commerce in the United States. Emphasis was placed on adding and updating physical properties and updating all DOT Classifications. The information was extracted from Dangerous Propedes Oflndm-ttial Matenals, Eleventh Edition. Citation to toxicity data and other less relevant information will be found in the above cited work. When cross-references to entries are not found in this book, they can be found in Dangerous Properties OflndivstnalMatenals, Eleventh Edition. Numerous synonyms have been added to assist in locating the many materials that are known under a variety of systematic and common names. The synonym cross-index contains the entry name as well as each synonym. T h s index should be consulted first to locate a material by name. Synonyms are given in English and also in other major languages such as French, German, Dutch, Polish, Japanese, and Italian. Many additional physical and chemical properties have been added. Whenever available, physical descriptions, formulas, molecular weights, melting points, boiling points, explosion limits, flash points, densities, autoignition temperatures, and the like have been supplied. A court order has vacated the OSHA h r Standards set in 1989 and contained in 29CFR 1910.1000. OSHA has decided to enforce only pre-1989 air standards. We have elected to include both the Transitional Limits that went into effect on December 31,1992, and the Final Rule limits that went into effect September 1, 1989. These represent the current best judgment as to appropriate workplace air levels. While they may not be enforceable by OSHA, they are better guides than the OSHA Air Standards adopted in 1969. The following classes of data are new or have been updated for all entries for which they apply. ix
Preface
X
1. ACGIH TLVs and BEIs reflect the latest recommendations and now include intended changes. 2. German 1LZtlK and BAT reflect the latest recommendations. 3. NTP 10th Annual Report O n Carcinogens entries are identified. 4. DOT classifications were updated reflecting the HM-181 rule making. 5. CAS Registry numbers are provided for additional entries. Each entry concludes with a safety profile, a textual summary of the hazards presented by the entry. The discussion of human exposures includes target organs and specific effects reported. Fire and explosion hazards are briefly summarized in terms of conditions of flammable or reactive hazard. Where feasible, fire-fighting materials and methods are discussed. Materials which are known to be incompatible with an entry are listed here. Also included in the safety profile are comments on disaster hazards which serve to alert users of materials to the dangers that may be encountered on entering storage premises during a fire or other emergency. Although the presence of water, steam, acid fumes, or powerful vibrations can cause the decomposition of many materials into dangerous compounds, of particular concern are high temperatures (such as those resulting from a fire) since these can cause many otherwise mild chemicals to emit highly toxic gases or vapors such as NO,, SO,, acids, and so forth, or evolve vapors of antimony, arsenic, mercury, and the like. Three cross-indices are provided as Appendices to permit rapid location of a material if either a Chemical Abstract Service (CAS) number, a synonym, or DOT Guide Number for the material is the point of entry. Every effort has been made to include the most current and complete information. The author welcomes comments or corrections to the data presented.
Richard J. Lewis, Sr.
Acknowledgments
I extend thanks to Bob Esposito for his encouragement. My thanks to Melissa Yanuzzi for her expert professional advice and assistance in converting the manuscript to this volume.
Introduction
The list of potentially hazardous materials includes drugs, food addtives, preservatives, ores, pesticides, dyes, detergents, lubricants, soaps, plastics, extracts from plant and animal sources, plants and animals that are toxic by contact or consumption, and industrial intermediates and waste products from production processes. Some of the information refers to materials of undefined composition. The chemicals included are assumed to exhibit the reported toxic effect in their pure state unless otherwise noted. However, even in the case of a supposedly “pure” chemical, there is usually some degree of uncertainty as to its exact composition and the impurities that may be present. This possibility must be considered in attempting to interpret the data presented because the toxic effects observed could in some cases be caused by a contaminant. Some radioactive materials are included but the effect reported is the chemically produced effect rather than the radiation effect. For each entry the following data are provided when available: the DPIM code, hazard rating, entry name, CAS number, DOT number, molecular formula, molecular weight, line structural formula, a description of the material and physical properties, and synonyms. Following this are listed the toxicity data with references for reports of primary s h and eye irritation, mutation, reproductive, carcinogenic, and acute toxic dose data. The Consensus Reports section contains, where available, NTP 8th Annual Report on Carcinogens notation, IARC reviews, NTP Carcinogenesis Testing Program results, EPA Extremely Hazardous Substances List, the EPA Genetic Toxicology Program, and the Community bght-ToKnow List. We also indcate the presence of the material in the update of the EPA TSCA inventory of chemicals in use in the United States. The next grouping consists of the US. Occupational Safety and Health Administration’s (OSHA) permissible exposure levels, the American Conference of Governmental Industrial Hygienists’ (ACGIH) Threshold Limit Values (TLVs), German Research Society’s (MAK) values, National Institute for Occupational Safety and Health (NIOSH) recommended exposure levels, and US. Department of Transportation (DOT) classifications. Each entry concludes with a Safety Profile that dscusses the toxic and other hazards of the entry. The Safety Profile concludes with the OSHA and NIOSH occupational analytical method, referenced by method name or number. 1. DPIM E n 5 Code identifies each entry by a unique code consisting of three letters and three numbers, for example, AAA123. The first letter of the entry code indicates the alphabetical position of the entry. Codes begnning with “A” are assigned to entries indexed with the A’s. Each listing in the cross-indexes is referenced to its appropriate entry by the DPIM entry code. 2. En@ Name is the name of each material, selected, where possible, to be a commonly used designation. x1
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3. Haxard Rating (HR:) is assigned to each material in the form of a number (1, 2, or 3) that briefly identifies the level of the toxicity or hazard. The letter “D” is used where the data available are insufficient to indicate a relative rating. In most cases a “D” rating is assigned when only in-vitro mutagenic or experimental reproductive data are available. Ratings are assigned on the basis of low (l),medium (2), or high (3) toxic, fire, explosive, or reactivity hazard. The number “3” indicates an LD50 below 400 mg/kg or an LC50 below 100 ppm; or that the material is explosive, highly flammable, or highly reactive. The number “2” indicates an LD50 of 400-4,000 mg/kg or an LC50 of 100-500 ppm; or that the material is flammable or reactive. The number “1” indicates an LD50 of 4000-40,000 mg/kg or an LC50 of 500-5000 ppm; or that the material is combustible or has some reactivity hazard. 4. Chemical Abstracts Seruice Regis@ Number (GAS:)is a numeric designation assigned by the American Chemical Society’s Chemical Abstracts Service and uniquely identifies a specific chemical compound. This entry allows one to conclusively identify a material regardless of the name or naming system used. 5. DOT: indcates a four-digt hazard code assigned by the U S . Department of Transportation. This code is recognized internationally and is in agreement with the United Nations codng system. The code is used on transport documents, labels, and placards. It is also used to determine the regulations for shipping the material. 6. Molecular Fomula (mfl or atomicfomula (af) designates the elemental composition of the material and is structured according to the Hdl System (see Journal of the American Chemical SocieiJ, 22(8): 478-494, 1900), in which carbon and hydrogen (if present) are listed first, followed by the other elemental symbols in alphabetical order. The formulas for compounds that do not contain carbon are ordered strictly alphabetically by element symbol. Compounds such as salts or those containing waters of hydration have molecular formulas incorporating the CAS dot-disconnect convention. In this convention, the components are listed individually and separated by a period. The individual components of the formula are given in order of decreasing carbon atom count, and the component ratios given. A lowercase “x” indicates that the ratio is unknown. A lower case “n” indcates a repeating, polymer-like structure. The formula is obtained from one of the cited references or a chemical reference text, or derived from the name of the material. 7. Molecular Weight (mw:)or atomic weight (aw:)is calculated from the molecular formula, using standard elemental molecular weights (carbon = 12.01). 8. Stmctural Fomula is a line formula indicating the structure of a given material. 9. Properties (PROP:) are selected to be useful in evaluating the hazard of a material and designing its proper storage and use procedures. A definition of the material is included where necessary. The physical description of the material may refer to the form, color, and odor to aid in positive identification. When available, the boiling point, melting point, density, vapor pressure, vapor density, and refractive index are given. The flash point, autoignition temperature, and lower and upper explosive limits are included to aid in fire protection and control. An indication is given of the solubhty or miscibility of the material in water and common solvents. Unless otherwise indicated, temperature is given in Celsius, pressure in millimeters of mercury. Levels identified as “IDLH:” indicate concentrations that meet the definition of “immediately dangerous to life or health concentrations’’ (IDLHs). These are defined according to the NIOSH Respirator Decision Logc (DHHS WIOSH] Publication No. 87-108, NTIS Publication No. PB-91-151183). It is a situation ”that poses a threat of exposure to airborne contaminants when that exposure is likely to cause death or
Introduction immedate or delayed permanent adverse health effects or prevent escape from such an environment." 10. S_nonyyms for the entry name are listed alphabetically. Synonyms include other chemical names, common or generic names, foreign names (with the language in parentheses), or codes. Some synonyms consist in whole or in part of regstered trademarks. These trademarks are not identified as such. The reader is cautioned that some synonyms, particularly common names, may be ambiguous and refer to more than one material. 11. Consensw Reports lines supply additional information to enable the reader to make knowledgeable evaluations of potential chemical hazards. Two types of reviews are listed: (a) International Agency for Research on Cancer (IARC) monograph reviews, which are published by the United Nations World Health Organization (WHO); and (?J) the National Toxicology Program (NTP). a. Cancer Reviews. In the U.N. International Agency for Research on Cancer (IARC) monographs, information on suspected environmental carcinogens is examined, and summaries of avadable data with appropriate references are presented. Included in these reviews are synonyms, physical and chemical properties, uses and occurrence, and biologcal data relevant to the evaluation of carcinogenic risk to humans. The monographs in the series contain an evaluation of over 1200 materials. The format of the IARC data line is as follows. The entry "IARC Cancer Review:" indicates that the carcinogenicity data pertaining to a compound have been reviewed by the IARC committee. The committee's conclusions are summarized in three words. The first word indicates whether the data pertain to humans or to animals. The next two words indicate the degree of carcinogenic risk as defined by IARC. For experimental animals the evidence of carcinogenicity is assessed by IARC and judged to fall into one of four groups defined as follows: (1) Sufficient Evidence of carcinogenicity is provided when there is an increased incidence of malignant tumors: (a) in multiple species or strains; (b) in multiple experiments (preferably with different routes of administration or using different dose levels); or (c) to an unusual degree with regard to the incidence, site, or type of tumor, or age at onset. Additional evidence may be provided by data on dose-response effects. (2) Limited Evidence of carcinogenicity is avadable when the data suggest a carcinogenic effect but are limited because: (a) the studies involve a single species, strain, or experiment; (b) the experiments are restricted by inadequate dosage levels, inadequate duration of exposure to the agent, inadequate period of follow-up, poor survival, the use of too few animals, or inadequate reporting; or (c) the neoplasms produced often occur spontaneously and, in the past, have been dfficult to classify as malignant by hstologcal criteria alone (for example, lung adenomas and adenocarcinomas, and liver tumors in certain strains of mice). (3) Inadequate Evidence is avadable when, because of major qualitative or quantitative limitations, the studies cannot be interpreted as showing either the presence or absence of a carcinogenic effect. (4) No Evidence applies when several adequate studies are avadable that show that within the h t a t i o n s of the tests used, the chemical is not carcinogenic. It should be noted that the categories Sufiient Evidence and Limited Evidence refer only to the strength of the experimental evidence that these chemicals are carcinogenic and not to the extent of their carcinogenic activity nor to the mechanism involved. The classification of any chemical may change as new information becomes available. The evidence for carcinogenicity from studies in humans is assessed by the IARC committees and judged to fall into one of four groups defined as follows:
Introduction
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(1) Sufficient Evidence of carcinogenicity indicates that there is a causal relationship between the exposure and human cancer. (2) Limited Evidence of carcinogenicity indicates that a causal relationship is credble, but that alternative explanations, such as chance, bias, or confounding, could not adequately be excluded. (3) Inadequate Evidence, which applies to both positive and negative evidence, indicates that one of two conditions prevailed: (a) there are few pertinent data; or (b) the available studies, while showing evidence of association, do not exclude chance, bias, or confoundng. (4) No Evidence applies when several adequate studes are available that do not show evidence of carcinogenicity. This cancer review reflects only the conclusion of the IARC committee based on the data available for the committee's evaluation. Hence, for some substances there may be a dsparity between the IARC determination and the information on the tumorigenic data lines (see paragraph 15). Also, some substances previously reviewed by IARC may be reexamined as addtional data become available. These substances wdl contain multiple IARC review lines, each of whch is referenced to the applicable IARC monograph volume. An IARC entry indcates that some carcinogenicity data pertaining to a compound have been reviewed by the IARC committee. It indicates whether the data pertain to humans or to animals and whether the results of the determination are positive, suspected, indefinite, or negative, or whether there are no data. This cancer review reflects only the conclusion of the IARC committee, based on the data available at the time of the committee's evaluation. Hence, for some materials there may be disagreement between the IARC determination and the tumorigenicity information in the toxicity data lines. 6.ATP Status. The notation "NTP 10th Annual Report on Carcinogens" indcated that the entry is listed on the report made to the U S . Congress by the National Toxicology Program (NTP) as required by law. This listing implies that the entry is assumed to be a human carcinogen. Another NTP notation indicates that the material has been tested by the NTP under its Carcinogenesis Testing Program. These entries are also identified as National Cancer Institute (NCI), which reported the studes before the NCI Carcinogenesis Testing Program was absorbed by NTP. To obtain addtional information about NTP, the Carcinogenesis Testing Program, or the status of a particular material under test, contact the Toxicolog~7 Information and Scientific Evaluation Group, NTP/TRTP/NIEHS, Mail Drop 18-01, P.O. Box 12233, Research Triangle Park, NC 27709. c. EPA Extreme4 Haxardous Substances L s t . Ths list was developed by the U.S. Environmental Protection Agency (EPA) as required by the Superfund Amendments and Reauthorization Act of 1986 (SARA). Title 111, Section 304 requires notification by facilities of a release of certain extremely hazardous substances. These 402 substances were listed by the EPA in the FederalRegister of November 17, 1986. d. Communig Rzght-To-Know L s t . Ths list was developed by the EPA as required by the Superfund Amendments and Reauthorization Act of 1986 (SARA). Title 111, Sections 311-312 require manufacturing fachties to prepare Material Safety Data Sheets and notify local authorities of the presence of listed chemicals. Both specific chemicals and classes of chemicals are covered by these sections. e. EPA Genetic Toxicology Program (GENE-TOX). This status line indicates that the material has had genetic effects reported in the literature during the period 1969-1979. The test protocol in the literature is evaluated by an EPA expert panel on mutations, and the positive or negative genetic effect of the substance is reported. To obtain additional information
xv
Introduction
about this program, contact GENE-TOX Program, USEPA, 401 M Street, SW, TS796, Washngton, DC 20460, telephone (202) 260-1513. f: E P A T S C A Status Line. Ths line indlcates that the material appears on the chemical inventory prepared by the Environmental Protection Agency in accordance with provisions of the Toxic Substances Control Act (TSCA). Materials reported in the inventory include those that are produced commercially in or are imported into this country. The reader should note, however, that materials already regulated by the EPA under FIFRA and by the Food and Drug Administration under the Food, Drug, and Cosmetic Act, as amended, are not included in the TSCA inventory. Sidarly, alcohol, tobacco, and explosive materials are not regulated under TSCA. TSCA regulations should be consulted for an exact definition of reporting requirements. For addltional information about TSCA, contact EPA, Office of Toxic Substances, Washington, DC 20402. Specific questions about the inventory can be directed to the EPA Office of Industry Assistance, telephone (800) 424-9065. 18. Standards and Recommendations section contains regulations by agencies of the U.S. government or recommendations by expert groups. “OSHA” refers to standards promulgated under Section 6 of the Occupational Safety and Health Act of 1970. “DOT” refers to materials regulated for shipment by the Department of Transportation. Because of frequent changes to and litigation of federal regulations, it is recommended that the reader contact the applicable agency for information about the current standards for a particular material. Omission of a material or regulatory notation from this e l t i o n does not imply any relief from regulatory responsibdity. a. O S H A A i r Contaminant Jtandards. The values given are for the revised standards that were published in January 13, 1989 and were scheduled to take effect from September 1, 1989 through December 31, 1992. These are noted with the entry “OSHA PEL:” followed by “TWA” or “CL,” meaning either time-weighted average or cehng value, respectively, to whch workers can be exposed for a normal 8-hour day, 40-hour work week without dl effects. For some materials, TWA, CL, and Pk (peak) values are given in the standard. In those cases, all three are listed. Finally, some entries may be followed by the designation “(skin).” Ths designation inlcates that the compound may be absorbed by the skin and that, even though the air concentration may be below the standard, significant addltional exposure through the skin may be possible. 6. A C G I H Threshold Limit Values. The American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values are noted with the entry “ACGIH TLV:” followed by “TWA” or “CL,” meaning either time-weighted average or cehng value, respectively, to which workers can be exposed for a normal 8-hour day, 40-hour work week without ill effects. The notation “CL” indicates a ceiling limit that must not be exceeded. The notation ‘‘skm’’ indlcates that the material penetrates intact skin, and skin contact should be avoided even though the TLV concentration is not exceeded. STEL indicates a short-term exposure limit, usually a 15-minute time-weighted average, which should not be exceeded. Biological Exposure Indices (BEI:) are, according to the ACGIH, set to provide a warning level “. . .of biologcal response to the chemical, or warning levels of that chemical or its metabolic product(s) in tissues, fluids, or exhaled air of exposed workers. . . .” The latest annual TLV list is contained in the publication Threshold L m i t Vahes and Biological Eqosure Indices. This publication should be consulted for future trends in recommendations. The ACGIH TLVs are adopted in whole or in part by many countries and local administrative agencies throughout the world. As a result, these recommendations have a major effect on the control of workplace contaminant concentrations. The ACGIH may be contacted for additional information at Kemper Woods Center, 1330 Kemper Meadow Drive, Cincinnati, O H 45240.
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c. DFG LMAK. These lines contain the German Research Society’s Maximum Allowable Concentration values. Those materials that are classified as to workplace hazard potential by the German Research Society are noted on this line. The MAK values are also revised annually and discussions of materials under consideration for MAK assignment are included in the annual publication together with the current values. B A T : indcates Biologcal Tolerance Value for a Working Material which is defined as, ‘‘. . .the maximum permissible quantity of a chemical compound, its metabolites, or any deviation from the norm of biological parameters induced by these substances in exposed humans.” TRK: values are Technical Guiding Concentrations for workplace control of carcinogens. For additional information, write to Deutsche Forschungsgemeinschaft (German Research Society), Kennedyallee 40, D-5300 Bonn 2, Federal Republic of Germany. The publication Maximum Concentrations at the Workplace and Biological Tolerance Valuesfor Working Materials Report N o . 34 can be obtained from VCH Publishers, Inc., 303 N.W. 12th Ave, Deerfield Beach, FL 33442-1788 or Verlag Chemie GmbH, Buchausliefemng, P.O. Box 1260/1280, D-6940 Weinheim, Federal Republic of Germany. d NIOJH REL This line indlcates that a NIOSH criteria document recommendng a certain occupational exposure has been published for this compound or for a class of compounds to which this material belongs. These documents contain extensive data, analysis, and references. The more recent publications can be obtained from the National Institute for Occupational Safety and Health, U S . Department of Health and Human Services, 4676 Columbia Pkwy., Cincinnati, O H 45226. e. DOT Clas.r$cation. This is the hazard classification according to the U S . Department of Transportation (DO?? or the International Maritime Organization (IMO). This classification gives an indication of the hazards expected in transportation, and serves as a guide to the development of proper labels, placards, and shipping instructions. The basic hazard classes include compressed gases, flammables, oxidlzers, corrosives, explosives, radoactive materials, and poisons. Although a material may be designated by only one hazard class, additional hazards may be indicated by adding labels or by using other means as directed by DOT. Many materials are regulated under general headings such as “pesticides” or “combustible liquids” as defined in the regulations. These are not noted here, as their specific concentration or properties must be known for proper classification. Special regulations may govern slupment by air. This information should serve only as a guide, because the regulation of transported materials is carefully controlled in most countries by federal and local agencies. Because there are frequent changes to regulations, it is recommended that the reader contact the applicable agency for information about the current standards for a particular material. United States transportation regulations are found in 40 CFR, Parts 100 to 189. Contact the U.S. Department of Transportation, Materials Transportation Bureau, Washington, DC 20590. 12. Safe$ ProjLes are text summaries of the reported hazards of the entry. The word “experimental” indicates that the reported effects resulted from a controlled exposure of laboratory animals to the substance. Toxic effects reported include carcinogenic, reproductive, acute lethal, and human nonlethal effects, skin and eye irritation, and positive mutation study results. Human effects are identified either by human or more specifically by man, woman, child, or infant. Specific symptoms or organ systems effects are reported when available. Carcinogenicity potential is denoted by the words “confirmed,” “suspected,” or “questionable.” The substance entries are grouped into three classes based on experimental evidence and the opinion of expert review groups. The OSHA, IARC, ACGIH, and DFG hMI< decision schedules are not related or synchronized. Thus, an entry may have had a
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recent review by only one group. The most stringent classification of any regulation or expert group is taken as governing. Class I--Confirmed Carcinogens These substances are capable of causing cancer in exposed humans. An entry was assigned to this class if it had one or more of the following data items present: a. an OSHA regulated carcinogen b. an ACGIH assignment as a human or animal carcinogen c. a DFG M I < assignment as a confirmed human or animal carcinogen d. an IARC assignment of human or animal sufficient evidence of carcinogenicity, or higher e. NTP 10th Annual Report on Carcinogens Class 11--Suspected Carcinogens These substances may be capable of causing cancer in exposed humans. The evidence is suggestive, but not sufficient to convince expert review committees. Some entries have not yet had expert review, but contain experimental reports of carcinogenic activity. In particular, an entry is included if it has positive reports of carcinogenic endpoint in two species. As more studies are published, many Class I1 carcinogens will have their carcinogenicity confirmed. On the other hand, some wdl be judged noncarcinogenic in the future. An entry was assigned to this class if it had one or more of the following data items present: a. an ACGIH assignment of suspected carcinogen b. a DFG hlAK assignment of suspected carcinogen c. an IARC assignment of human or animal limited evidence d. two animal studies reporting positive carcinogenic endpoint in different species Class 111--Questionable Carcinogens For these entries there is minimal published evidence of possible carcinogenic activity. The reported endpoint is often neoplastic growth with no spread or invasion characteristic of carcinogenic pathology. An even weaker endpoint is that of equivocal tumorigenic agent (ETA). Reports are assigned this designation when the study was defective. The study may have lacked control animals, may have used a very small sample size, often may lack complete pathology reporting, or may suffer many other study design defects. hlany of these studies were designed for other than carcinogenic evaluation, and the reported carcinogenic effect is a by-product of the study, not the goal. The data are presented because some of the substances studied may be carcinogens. There are insufficient data to affirm or deny the possibdq. An entry was assigned to this class if it had one or more of the following data items present: a. an IARC assignment of inadequate or no evidence b. a single human report of carcinogenicity c. a single experimental carcinogenic report, or duplicate reports in the same species d. one or more experimental neoplastic or equivocal tumorigenic agent reports Fire and explosion hazards are briefly summarized in terms of conditions of flammable or reactive hazard. Materials that are incompatible with the entry are listed here. Fire and explosion hazards are briefly summarized in terms of conditions of flammable or reactive hazard. Fire-fighting materials and methods are discussed where feasible. A material with a flash point of l0OoF or less is considered dangerous; if the flash point is from 100 to 200°F, the flammabihty is considered moderate; if it is above 200°F,the flammabhty is considered low (the material is considered combustible), Also included in the safety profie are disaster hazards comments, which serve to alert users of materials, safety professionals, researchers, supervisors, and firefighters to the
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dangers that may be encountered on entering storage premises during a fire or other emergency. Although the presence of water, steam, acid fumes, or powerful vibrations can cause many materials to decompose into dangerous compounds, we are particularly concerned with h g h temperatures (such as those resulting from a fire) because these can cause many otherwise inert chemicals to emit hghly toxic gases or vapors such as NO,, SO,, acids, and so forth, or evolve vapors of antimony, arsenic, mercury, and the like.
Key to Abbreviations
abs - absolute ACGIH - American Conference of Governmental Industrial Hygienists af - atomic formula alc - alcohol alk - alkaline amorph - amorphous anhyd - anhydrous approx - approximately aq - aqueous atm - atmosphere autoign - autoignition aw - atomic weight BE1 - ACGIH Biologcal Exposure Indexes bp - boiling point b range - boding range CAS - Chemical Abstracts Service cc - cubic centimeter CC - closed cup CL - ceding concentration COC - Cleveland open cup compd(s) - compound(s) conc - concentration, concentrated contg - containing cqst - crystal(s), crystalline d - density D - day(s) decomp - decomposition deliq - deliquescent dil - dilute D O T - US.Department of Transportation EPA - US.Environmental Protection Agency eth - ether 0- Fahrenheit FCC - Food Chemical Codex FDA - US.Food and Drug Administration flam - flammable flash p - flash point fp - freezing point g - gram glac - glacial gran - granular, granules H - hour(s) H R - hazard rating htd - heated htg - heating hygr - hygroscopic IARC - International Agency for Research on Cancer
immisc - immiscible incomp - incompatible insol - insoluble IU - International Unit kg - kilogram (one thousand grams) L - liter lel - lower explosive limit liq - liquid hf - minute(s) mz - cubic meter mf - molecular formula mg - milligram misc - miscible mL - milliliter mm - millimeter mod - moderately mp - melting point mppcf - mlllion particles per cubic foot mw - molecular weight m, u - micro mg - microgram N - refractive index ng - nanogram NIOSH - National Institute for Occupational Safety and Health nonflam - nonflammable NTP - National Toxicology Program OBS - obsolete OC - open cup org - organic ORhf - other regulated material (DOT) OSHA - Occupational Safety and Health Administration Pa - Pascals PEL - permissible exposure level pet - petroleum pg - picogram (one trillionth of a gram) Pk - peak concentration pmole - picomole powd - powder ppb - parts per billion (./v) pph - parts per hundred (v/v)(percent) ppm - parts per mlllion (v/v) ppt - parts per trillion (v/v) prac - practically prep - preparation PROP - properties refr - refractive
xix
Key to Abbreviations rhomb - rhombic S, sec - second(s) sl, slt - slight sltly - slightly sol - soluble soln - solution solv(s) - solvent(s) spar - sparingly spont - spontaneous0y) STEL - short-term exposure limit sub1 - sublimes TCC - Tag closed cup tech - technical temp - temperature TLV - Threshold Limit Value TOC - Tag open cup TWA - time weighted average uel - upper explosive limit unk - unknown, unreported
xx ULC, ulc - Underwriters Laboratory Classification USDA - US.Department of Agriculture vac - vacuum vap - vapor vap d - vapor density vap press - vapor pressure visc - viscosity vol - volume W - week(s) Y - year(s) YO- percent(age) > - greater than < - less than <= - less than or equal to => - greater than or equal to O
- degrees of temperature in Celsius (centigrade) - temperature in Fahrenheit
O F
A or flame; can react vigorously with oxidizing materials. Forms heat-sensitive explosive peroxides on contact with air. %'hen heated to decomposition it emits acrid smoke and fumes. See also ETHERS and ALDEHYDES.
AAC250 CAS: 8021-27-0 HR: 1 ABIES ALBA OIL PROP: Colorless to pale-yellow oil from the steam distillation of the crushed cones of Abies A l b a Mill (FCTXAV 12,807,74). SYNS: OIL OF ABIES ALBA
OIL OF FGR
OIL OF
SILVER FIR 0 OIL OF SILVER PIKE 0 SILVER FIR
AAG250 CAS: 75-07-0 HR: 3 ACETALDEHYDE DOT: UN 1089 mf: CzH40 mw: 44.06 PROP: Colorless, fuming liquid; pungent, fruity odor. Mp: -123.5', bp: 20.8', lel: 4.o0/o, uel: 57%, flash p: -36°F (CC), d: 0.804 @ 0"/20", autoign temp: 347'F, vap d: 1.52. Misc in water, alc, and eth. IDLH 2000 ppm.
NEEDLE OIL 0 SIL\'ER FIR OIL. 0 SILVER PINE OIL
0 TEMPLIN OIL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low toxicity by ingestion or skin contact. A s h n irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
AAGOOO ACETAL
CAS: 105-57-7
HR: 3
SYNS: ACETALDEHYD (GERMAN) 0 ACECTIC ALDEHYDE 0 ALDEHYDE ;\CETIQUE (FRENCH) 0
DOT: UN 1088 mf: C6H1402 mw: 118.20 PROP: Colorless, volatile liquid; agreeable odor, nutty aftertaste. Mp: -looo, bp: 102.7", flash p: -5°F (CC), lel: l.65%, uel: 10.4%, d: 0.831, autoign temp: 446'F, vap press: 10 mm @ J KO", vap d: 4.08. Sltly sol in water; misc in alc and eth. SYNS: ACETAAL (DUTCH) 0
ALDEIDE ACETICA (ITALIAN) 0 BTkLlNAL 0 ETHYL ALDEHYDE 0 FEhU No. 2003 0 KCI-Cj6326 0 OCTOKY XL.DEHYD (T'OLISH) NUMBER KO01
0 RCRA WASTE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,77,87; Animal Sufficient Evidence IMEMDT 36,101,85; Human Inadequate Evidence IhIEMDT 36,101,85. O n Community kght-To-Ihow List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 100 ppm; STEL 150 ppm ACGIH TLV: CL 25, Confirmed Animal Carcinogen. DFG MAK: 50 ppm (90 mg/m3), Suspected Carcinogen DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intratracheal and intravenous routes. A human systemic
ACETAL DIETHY-
LIQUE (FRENCH) I3 ACETALE (ITALIAX) 0 1,lDIAETHOXY-AETHAN (GERMAN) 0 DIAETHYI.. ACETAL (GERMAN) 0 1,l-DIETHOXY-ETHAAN (DUTCH) 0 1,l-DIETHOXYETHANE 0 DIETHYI. ACETAL 0 1,l-DIETOSSIETANO (ITALIAN) 0 ETHYLIDENE DIETHYL ETHER 0 USAF DO-45
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Moderately toxic by ingestion, inhalation, and intraperitoneal routes. A s h n and eye irritant. A narcotic. Dangerous fire hazard when exposed to heat
1
2
AAG500
ACETALDEHYDE AMMONIA
irritant by inhalation. An experimental routes. A human systemic irritant by inhalation. An experimental teratogen. Other experimental reproductive effects. A s h n and severe eye irritant. A narcotic. Human mutation data reported. A common air contaminant. Highly flammable liquid. Mixtures of 30-60% of the vapor in air ignite above 100". It can react violently with acid anhydrides, alcohols, ketones, phenols, NH3, HCN, H2S, halogens, P, isocyanates, strong alkalies, and amines. Reactions with cobalt chloride, mercury(l1) chlorate, or mercury(l1) perchlorate form violently in the presence of traces of metals or acids. Reaction with oxygen may lead to detonation. When heated to decomposition it emits acrid smoke and fumes. AAGSOO CAS: 75-39-8 HR: 2 ACETALDEHYDE AMMONIA DOT: UN 1841 mf: C2H40*H3N mw: 61.10 PROP: White, crystalline solid. Bp: 1lo", mp: 97". Very sol in water, alc; sltly sol in eth. SYNS: ACETALDEHYDE, AMINE SALT 0 ALDEHYDE I\hfhIONIA 0 1-ASIINOETHANOL0 a-AMINOETHYL ALCOHOL R ETHANOL, I-AMINO-(8CI,9CI) DOT CLASSIFICATION: 9; Label: CLASS 9 SAFETY PROFILE: It readily decomposes
into acetaldehyde and ammonia when heated, causing the hazards of these substances. Moderate fire and explosion hazard when exposed to heat or flame. Can react with oxidizing materials. When heated to decomposition it emits toxic fumes of NH3 and NO,. AAG850 CAS: 105-82-8 HR: 1 ACETALDEHYDE-DI-n-PROPYL ACETAL mf: C8H1802 mw: 146.26 SYNS: ACETALDEHYDE, DIPROPYL ACETAL 0
1,l-
DIPROPOXYETHANE 0 DIPROPYL ACETAL 0 nPROPYL ACETAL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
SAFETY PROFILE: A s h n irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
AAHOOO CAS: 16568-02-8 HR: 3 ACETALDEHYDE-N-METHYL-N-FORMYLHYDRAZONE mf: C ~ H S N Z O mw: 100.14 SYNS: ACETALDEHYDE-N-FOIL-N-METHYLHYDRAZONE 0 ETHYLIDENE GYROMITRIN 0 GYROMIT" 0 N-METHYI-N-FORMYLHYDRA-ZONE of ACETALDEHYDE
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 7,391,87. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison via ingestion and possibly other routes. Questionable carcinogen with experimental carcinogenic and tumorigenic data. When heated to decomposition it emits toxic fumes of NO,.
AAH250 CAS: 107-29-9 HR: 3 ACETALDEHYDE OXIME DOT: UN 2332 mf: CzHsNO mw: 59.08 PROP: A water-sol, crystalline material; sol in alc, eth. Mp: (a) 46.5", mp: (p) 12", d: 0.966, bp: 114.5", flash p: 572°F. SYNS: ACETALDOXIME 0 ALDOXIME 0 ETHAN-AL OXIME AM-5
ETHYLIDENEHYDROXYLAMINE
USAF
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison via intraperitoneal route. Mutation data reported. A dangerous fire hazard with a flash point at room temperature. When heated to decomposition it emits toxic fumes of NO,. See also ALDEHYDES.
AAH750 CAS: 107-89-1 HR: 3 ACETALDOL DOT: UN 2839 mf: C4H802 mw: 88.12 PROP: Clear, whte-to-yellow syrupy liquid. Bp: 83' @? 20 mm, flash p: 150°F (OC), d: 1.11, autoign temp: 482"F, vap d: 3.04.
ACETAMINE YELLOW CG
SYNS: ALDOL 0 3-BUTANOLAL 0 3-HYDROXYBUTANAL 0 P-HYDROXYBUTYRALDEHYDE 0 3HYDROXYBUTYRALDEHI'DE 0 OXYBUTANAL 0 OXYBUTYRIC ALDEHYDE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison via skm contact.
Moderately toxic by ingestion. A skin and eye irritant. A flammable liquid and fire hazard when exposed to heat or flame; emits crotonaldehyde and water when heated. See CROTONALDEHYDE. Can react with oxidtzing materials. AAIOOO CAS: 60-35-5 HR: 3 AC ETAMIDE mf: C2H5NO mw: 59.08 PROP: Colorless crystals; mousy odor. Mp: 81", bp: 221.2", d: 1.159 @ 20°/4", vap press: 1 mm @? 65". Decomp in hot water. SYNS: ACETIC ACID ASfIDE 0 ACETIMIDIC ACID 0 AMID KYSELINY OCTOVE (POLISH) 0 ETHANARIIDE 0 hIETHANECARBOXhhfIDE 0 NCI-C02108
CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 7,389,87. On Community fight-To-Know List. Reported in EPA TSCA Inventory. DFG MAK: Suspected Carcinogen SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and neoplastigenic data. Moderately toxic by intraperitoneal and possibly other routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also AMIDES. When heated to decomposition it emits toxic fumes of NO,. AA1250 CAS: 59-66-5 HR: 3 5-ACETAMIDE-1,3,4-THIADIAZOLE-2SULFONAMIDE mf: C4H6N403S2 mw: 222.26 SYNS: 2-ACETAhlIDO-5 SULI'ONA5lIDO-l,3,4THIADIAZOLE 0 ACETAMIDOTHIADIAZOLESULFONAMIDE 0 ACETAMOX 0 ACETAZOLAMID 0 ACETAZOMMIDE 0 ACETAZOLEAMIDE 0 ACETOZAUSIIDE 0 2-ACETYLAhIINO-1,3,4THlADIAZOLE-5-SULFOS~~~~lDE 0 S-(5-(A,\IINO-
AAQ250
3
SULFONY12)-1,3,4-THIADIAZOL-2-YL)ACETAXIlDE 0 CARBONIC ANHYDRASE INHIBITOR NO. 6063 0 CIDARIEX 0 DEFILTMN 0 DEHYDRATIN 0 DIXCARB 0 DIAKXRB 0 DIAhIOX 0 DIDOC 0 DILUMWN 0 DIURAhIID 0 DIURETICU,\I-HOLZINGER 0 DIUTXZOL 0 DONhIOX 0 EDEXIOX 0 EUhIICTON 0 FONURIT 0 GLAUPAX 0 GLUPAX 0 SIUIRARIID 0 NATRIONEX 0 NEPHRAXIIDE 0 PHONURIT 0 N-(5-
El
SULFAMOYL1,3,4-THIADIAZOL-2-YL)ACET-ASIIDE 0 VETAMOX
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous and intravenous routes. Moderately toxic by intraperitoneal route. Human systemic effects by ingestion: dyspnea. An experimental teratogen by many routes. Other experimental reproductive effects. When heated to decomposition it emits very toxic fumes of NO, and SO,. A carbonic anhydrase inhibitor and dmretic used to treat glaucoma. AAL750 CAS: 531-82-8 HR: 3 2-ACETAMIDO-4-(5-NITRO-2-FURYL)TH IA 2 0 LE mf: CgH:N304S mw: 253.25 SYNS: 2-ACEThhlINO-4-(5-NITRO-2-FURYI,)THIA ZOLE 0 2-ACE~1LIINO-4-(j-NITRO-2-FURn)THIAZOLE 0 N-(4-(5-NITRO-2-FURANYL)-2THIAZ0LYL)ACETAhIIDE 0 N-(4-(5-NITRO-2-FCRYL)-2 THIAZO1,k'L)ACETh~~IDE0 N-(4-(5-NITRO-2FuRYL)THIAZOL-2-n)ACETASIIDE
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 1,181,72; IMEMDT 7,185,74. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, tumorigenic, and neoplastigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of SO, and NO,.
AAQ250 CAS: 2832-40-8 HR: 2 ACETAMINE YELLOW CG mf: CljHt5N30~ mw: 269.33 PROP: Brownish-yellow powder. Mp: 268"-270" Solubility in water: <0.1 mg/mL @? 18", 95Y0 etoh: 1-5 mg/mL @? 22"
4
AAQ500
ACETANILIDE
SYNS: ACETAMIDE, N-(4-((2-HYDROXY-j-;CIETHYL-TSCA Inventory. IARC Cancer Review: PHENYL)AZO)PHENYL)- 0 4-ACETA~IlDO-2'-HMROXY-5'-bfETHYLAZOBENZENE 0 ACETATE FAST YELLOW G 0 ACETOQUINONE LIGHT YELLOW 0 ACETOQUISONE LIGHT YELLOW 4JLZ 0 ALTCO SPERSE FAST YELLOY GFN NEW a ASIACEL YELLOW G 0 ARTISIL DIRECT YELLOW G 0 ARTISIL YELLOW G 0 ARTISIL YELLOW 2 G S 0 CALCOSYN YELLO\YT GC 0 CALCOSYN YELLOW GCN 0 CELLITON DISCHARGE YELLO\Y GL 0 CELLITON FAST YELLOW' G 0 CELLITON FAST YELLOW GA 0 CELLITON FAST YELLO\Y GA-CF 0 CELLITON YELLOW G 0 CELUTATEYELLOWGH 0 C.I. 11855 0 C.I. 3/11855 0 CJBACETE YELLOW GBA 0 CIBACET YELLOW GBA 0 CIBACET YELLOT' 2GC 0 C.I. DISPERSE YELLOW 3 0 CILLA FAST YELLOW G 0 C.I. SOLVENT YELLOW 92 0 C.I. SOLVENT YELLOW 99 0 DIACELLITON FAST YELLOW G 0 DISPERSE FAST YELLOW G 0 DISPERSE YELLOW G 0 DISPERSE YELLOW 3 0 DISPERSIVE YELLOW 3T 0 DISPERSE YELLOW Z 0 DISPERSOL FAST YELLOW G 0 DISPERSOL PRINTING YELLOW G 0 DISPERSOL YELLOW A-G 0 DURGACET YELLOW G 0 DUROSPERSE YELLOW G 0 EASTONE YELLOW GN 0 ESTEROQUINONE LIGHT YELLOW 4JL 0 ESTONE YELLOW GN 0 FENACET FAST YELLOW G 0 FENACET YELLOW G 0 GENACRON YELLOW G 0 HISPACET FAST YELLOW G 0 HISPERSE YELLOW G 0
N-(4-((2-HYDROXY-5-METHYLPHENYL)AZO)PHESYL)ACETAhlIDE 0 4'-((6-HYDROXY-mT0LYL)AZO)ACETANILIDE 0 INTERCHEM ACETATE YELLOW G 0 INTERCHEM DISPERSE YELLOW GH 0 INTRhSPERSE YELLOK' GBA 0 ISTRASPERSE YELLOW GBA EXTR4 0 KAYALON FAST YELLOW G 0 KAYASET YELLOW G 0 KCA -ACETATE FAST YELLOW G 0 MICROSETILE YELLOW GR 0 hiIKETOS FAST YELLOW G 0 NACELAX FAST YELLOW CG 0 SCIC53781 0 NO\7ALOiV YELLOW 2GS 0 NYLOQUINONE LIGHT YELLOW 4JL 0 NYLOQUINONE YELLOW 4J 0 OSTACET YELLOW P2G 0 PALhCET YELLOW GN 0 PALANIL YELLOW G 0 PAhWCEL YELLOW G-3 0 PERLITOX YELLOW' G 0 RELITON YELLOW C 0 RESIREN YELLOW T G 0 SAFARITONE YELLOW G 0 SASURON YELLOW PA3 0 SERINYL HOSIERY YELLOW G D 0 SERIPLAS YELLOW G D 0 SERISOL FAST YELLOW G D 0 SETACYL YELLO\Y' G 0 SETACYL YELLOW 2GX 0 SETACYL YELLOW P-2GL 0 SILOTRAS YELLOW TSG 0 SUPRACET FAST YELLOW G 0 SYXTEN YELLOLY' 2G 0 SYNTON YELLOW 2G 0 TEMSIL YELLOW GBX EXTRA 0 TER4SIL YELLOW 2GC 0 TERTRANESE YELLOW N-2GL 0 TULADISPERSE FAST YELLOW 2G 0 VONTERYL YELLOW G 0 VOXTERYL YELLO\V R 0 YELLOW RELITON G 0 YELLOW Z 0 ZLUT DISPERZNI 3 0 ZLUT ROZPOUSTEDLOVA 71
CONSENSUS REPORTS: Community Rght-To-Know List. Reported in EPA
Group 3 IhlEMDT 48,149,90; Animal Inadequate Evidence IMEMDT 8,97,75; NTP Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NTPTR" NTP-TR222,82. SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic and carcinogenic data. Low toxicity by intraperitoneal route. An allergen. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. AAQSOO CAS: 103-84-4 HR: 3 AC ETANILIDE mf: CsH9NO mw: 135.18 PROP: White, shining, crystalline scales. Mp: 113.5", bp: 305", flash p: 345°F (OC), d: 1.2105 @ 4'/4", autoign temp: 1004'F, vap press: 1 mm @ 114.0", vap d: 4.65. Somewhat sol in water, alc, and eth. SYNS: ACETAMIDE, N-PHENYL- 0 ACETAMIDOBENZENE 0 ACETANL 0 ACETANILID 0 ACETIC ACID ANILIDE 0 ACETOANILIDE 0 ACETYL AhlINOBESZENE 0 ACETYWNILINE 0 NACETYLANILINE O AN O ANILINE, N-ACETYT>- O AXTIFEBRIN 0 PHESALGENE 0 PHENALGIX 0 hPHENYLACETAMIDE 0 USAF EK-3
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: A human poison by an unspecified route. Poison by ingestion and intravenous routes. Moderately toxic by intraperitoneal route. Human systemic effects by ingestion: hallucinations and dstorted perceptions, sleepiness, constipation, cyanosis, respiratory stimulation, hdney damage, methemoglobinemiacarboxyhemoglobinemia, and decreased body temperature. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. Combustible when exposed to heat or flame. See also ANILINE.
ACETICACID
AAS250 CAS: 5421-48-7 HR: 3 (ACETATO)(DIETHOXYPH0sPHINYL)MERCURY mf: C6H13HgOjP mw: 396.75 PROP: IDLH 10 mg/m3 (as Hg). SYN:
(DIETHOXY-PH0SPHINYL)MERCCRYACETATE
CONSENSUS REPORTS: Mercury and its compounds are on the Community RlghtTo-Know Lst. OSHA PEL: CL 0.1 rng(Hg)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Hg)/m3 (shn);
BEI: 35 pg/g creatinine total inorganic mercury in urine preshift; 15 pg/g creatinine total inorganic mercury in blood at end of s h f t at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Organomercury) TWA 0.01 mg(Hg)/mj SAFETY PROFILE: Poison by intraperitoneal route. See also MERCURY COMPOUNDS. When heated to decomposition it emits very toxic fumes of Hg and PO,. AAS500 CAS: 21450-81-7 HR: 3 (ACETAT0)(2,3,5,6-TETRAMETHYLPHENYL)MERCURY mf: C12H16Hg02 mw: 392.87 PROP: IDLH 10 mg/m3 (as Hg). SYN:
(2,3,j,6-TETKIhfETHYLPHEiWL)MERCURY ACETATE
CONSENSUS REPORTS: Mercury and its compounds are on the Community RightTo-Know List. OSHA PEL: CL 0.1 mg(Hg)/m3 (skm) ACGIH TLV: TWA 0.1 mg(Hg)/mj (shn); BEI: 35 pg/g creatinine total inorganic mercury in urine preshift; 15 pg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NlOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skm) SAFETY PROFILE: Poison by intravenous route. See also MERCURY COhIPOUNDS. When heated to decomposition it emits toxic fumes of Hg.
AAT250
5
AAT250 CAS: 64-19-7 ACETIC ACID DOT: UN 2789/UN 2790 mf: C2H402 mw: 60.06 PROP: Clear, colorless liquid; pungent odor. Mp: 16.7', bp: 118.1', flash p: 109'F (CC), lel: 5.4%, uel: 16.0% @ 212'F, d: 1.049 @ 20°/4', autoign temp: 869'F, vap press: 11.4 mm (@? 20°, vap d: 2.07. m s c in water, alc, and eth. IDLH 50 ppm. SYNS: ACETIC ACID (aqueous soluaon) (Dog 0 ACETIC ACID, glacial or aceuc acid soluaon, >8Oo/0 acid, by weight (UN 2790) (DOT) 0 ACETIC ACID, GLACIAL 0 ACETIC ACID soluuon, >lo% but not >80°'o acid, b r weight (US 2790) (DOT) 0 ACIDE ACETIQUE (FRENCH) 0 ACID0 ACETIC0 (ITALIAN) 0 AZIJNZUUR (DUTCH) 0 ESSIGSAEURE (GERMAN) 0 ETHANOIC ACID 0 ETHYLIC ACID 0 FEMA No 2006 0 GLACIAL ACETIC ACID 0 METHANE-CARBOXYLIC ACID 0 OCTOWY KWAS (POLISH) 0 VINEGAR ACID
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 10 ppm ACGIH TLV: TWA 10 ppm; STEL 15 ppm DFG MAK: 10 ppm (25 mg/m3) DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A human poison by an unspecified route. Moderately toxic by various routes. A severe eye and s h n irritant. Can cause burns, lachrymation, and conjunctivitis. Human systemic effects by ingestion: changes in the esophagus, ulceration, or bleedmg from the small and large intestines. Human systemic irritant effects and mucous membrane irritant. Experimental reproductive effects. Mutation data reported. A common air contaminant. A flammable liquid. A fire and explosion hazard when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use CO2, dry chemical, alcohol foam, foam and mist. When heated to decomposition it emits irritating fumes. Potentially explosive reaction with 5azidotetrazole, bromine pentafluoride, chromium trioxide, hydrogen peroxide, potassium permanganate, sodium peroxide, and phosphorus trichloride. Potentially violent reactions with acetaldehyde and acetic anhydride. Ignites on contact with
6
AAUOOO
ACETIC ACID, CITRONELLYL ESTER
potassium tert-butoxide. Incompatible with chromic acid, nitric acid, 2-amino-ethanol, NH4N03, ClF3, chlorosulfonic acid, ( 0 3 + diallyl methyl carbinol), ethplenediamine, ethylene imine, (HN03 + acetone), oleum, HC104, permanganates, P(OCN)3, KOH, NaOH, xylene. AAUOOO CAS: 150-84-5 HR: 1 ACETIC ACID, CITRONELLYL ESTER mf: C12H2202 mw: 198.34 PROP: Found in oils of Citronella Ceylon, geranium, and about 20 other oils (FCTXAV 11,1011,73). Colorless liquid; fruity odor. D: 0.883-0.893, refr index: 1.440-1.450, flash p: 212’F. Sol in alc and fixed oils; insol in glycerin, propylene glycol, and water @ 229’. SYNS: ACETIC ACID-3,7-DI~IETHYI~-6-OCTEN-l-YL ESTER 0 CITRONELLYL ACETATE (FCC) 0 2,6DIMETHYL-2-OCTEN-8-OL ACETATE 0 3,7-DIhfETHYI6-OCTEN-1-YL :ICETATE 0 F‘EXLI NO, 2311 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion. A human skin irritant. See also ESTERS. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
AAU250 CAS: 18461-55-7 HR: 3 ACETIC ACID-~,~-DINITRO-O-CRESYL ESTER mf: C1HaN206 mw: 240.19 SYNS: 4,6-DINITRO-o-KRESYLESTER KYSELISY OCTOVE (CLECH) 0 DNOK-ACETAT (CZECH)
NlOSH REL: (Dinitro ortho-Cresyl) TWA
0.2 mg/m3 SAFETY PROFILE: Poison by ingestion and
intraperitoneal routes. A s h n and severe eye irritant. When heated to decomposition it emits toxic fumes of NO,. AAWOOO CAS: 56856-83-8 HR: 3 AC ETlC ACID METHYLNITROSAM INOMETHYL ESTER mf: C4HaN203 mw: 132.14 SYNS: a-ACETOXY DIhIETHYLNITR0SA;CIINE 0 rZC~TOXY;2IETHYL-?rl~THYL-SITROSA~IIN (GERMAS) 0 ACETOXY\IETHYL METHYLSITRO-SAXIINE 0 N-a-
ACETOXYhIETHYL-N-hlETHYL-NITROSASIINE0 1ACETOXY-h-NITROSODIMETH-YLAMIhE 0 AMMh 0 ANN (GERMAN) 0 DANN-OAC0 hL451N 0 SIETHYL(ACET0XYhlETHYL)NITRO-SAMISE 0 N-NITROSO-X(ACET0XY)XIETHYL-N-METHYLAMINE 0 1-SITROSON-METHYL-N-ACETOXYblETHYLriMINE
SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Experimental teratogenic data. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also NITROSAMINES, N-NITROSO COMPOUNDS, and ESTERS.
AAXl75 CAS: 9003-22-9 HR: 1 ACETIC ACID, VINYL ESTER, POLYMER with CHLOROETHYLENE mf: ( C ~ H ~ O Y C ~ H ~ C ~ ) ~ PROP: White powder with bland odor. D: 1.4 SYNS: A 15 (polrmerj ACETIC ACID ETHEXYL ESTER POLYMER ulth CHLORETHEhE (9CI) 0 BAKELITE LP 70 0 BAKELITE VLFV 0 BAKELITE VMCC 0 BAKELITE VYNS 0 BREON 351 0 CHLOROETHYLESEVINYL ACETATE POLYMER 0 CORVIC 236581 0 DEKKALAC 61 0 DIAMOND SHAMROCK 744 0 EXON 450 0 EXON 454 0 GEON 135 0 HOSTAFLEX I T 150 0 LEUCOWI, PA 1302 0 NORVISYL P 6 0 OPALON 400 0 PLIOVAC A 0 0 POLYVINYL CHLORIDE-POLYVIhYL ACETATE 0 PVC CO R D 0 0 RHODOPAS 6000 0 SARPIFAN HP 1 0 SLONATEX 0 SOLVIC 523KC 0 SLMILIT PCX 0 TENNUS 0563 0 TYGON 0 VA4GD0 VINNOI, H 10/60 0 VINYL ACETATE-VINYL CHLORIDE COPOLYMER 0 VINYL ACETATE-VINYL CHLO-RIDE POLYMER 0 VINYL CHLORIDE-VINYL ACETATE POLYMER 0 VINYLITE VYDR 21 0 VLVF 0 VRKC 0 VYNV” CONSENSUS REPORTS: IARC Cancer
Review: Animal Limited Evidence IMEMDT 19,377,79. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of HC1.
ACETISOEUGENOL
AAX250 CAS: 9003-20-7 HR: 1 ACETIC ACID VINYL ESTER POLYMERS mf: ( C ~ H G O Z ) ~ PROP: Clear, water-white solid resin. Sol in benzene, acetone; insol in water. SYNS: ACETIC ACID ETHENYL ESTER HOMOPOLYMER 0 ASAHISOL 1527 0 ASB 516 0 AYAA 0 AYAF 0 BAKELITE AYAA 0 BAKELITE LP 90 0 BASCOREZ 0 BOND CH 18 0 BOOKSAVER 0 BORDEN 2123 0 CEVIAN A 678 0 D 50 0 DANFIRM 0 DARATAK 0 DCA 70 0 DUVILAX BD 20 0 ELMER'S GLUE ALL U EP 1463 0 FOfiMVAR 1285 0 GELVA CSV 16 0 GOHSENYL E 50 Y 0 KURARE OM 100 0 LEMAC 1000 MERCKOGEN 6000 0 MOVINYL 114 0 NATIONAL 1201207 0 POLYVINYL ACETATE (FCC) 0 PROTEX (T'OLYMER) 0 RHODOPAS ?vl 0 SOVIOL 0 SP 60 ESTER 0 TOABOND 40H 0 UCAR 130 0 VA 0112 0 VINAC B 7 0 VINYL ACETATE HOMOPOLYMER 0 VINYL ACETATE POLYMER 0 VINYL ACETATE RESIN 0 VINYL PRODUCTS R 10688 0 WINACET D CONSENSUS REPORTS: IARC Cancer Review: Animal Inadequate Evidence IMEMDT 19,341,79.Reported in EPA TSCA Inventory. SAFETY PROFILE: Very low toxicity by ingestion. Questionable carcinogen. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
AAX500 CAS: 108-24-7 HR: 3 ACETIC ANHYDRIDE DOT: UN 1715 mf: C4H603 mw: 102.10 PROP: Colorless, very mobile, strongly refractive liquid; very strong, irritating, acetic odor. Mp: -73.1°, bp: 139.55', flash p: 129OF (CC), d: 1.082 @ 20°/4", lel: 2.9%, uel: 10.3%, autoign temp: 734'F, vap press: 10 mm @ 36.0°, vap d: 3.52. Sltly sol in water; sol in org solvs. Decomp in hot water and hot alc; misc in alc and eth. IDLH 200 PPm. SYNS: ACETANHYDRIDE 0 ACETIC ACID, ANHYDRIDE (9CI) 0 ACETIC OXIDE 0 ACETYL ANHYDRIDE 0 ACETYL ETHER 0 ACETYL OXIDE 0 ANHYDRIDE ACETIQUE (FRENCW 0 ANHY-DRID KYSELINY OCTOVE ANIDRIDE ACETICA (ITALIAN) AZIJNZIXKANHYDRIDE (DUTCH) 0 ESSIGSAEUREANHYDRID (GERMAN) 0 ETHANOIC ANHYDRATE 0 OCTOWY BEZWODNIK (POLISH)
AAX750
7
CONSENSUS REPORTS: Reported in
EPA TSCA Inventory. OSHA PEL: CL 5 pprn ACGIH TLV: TWA 5 ppm. DFG MAK: 5 pprn (20 mg/m3) NlOSH REL: Acetic Anhydride: CL 5 pprn DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Moderately toxic by inhalation, ingestion, and s h n contact. A s h n and severe eye irritant. A flammable liquid. A fire and explosion hazard when exposed to heat or flame. Potentially explosive reactions with barium peroxide, boric acid, chromium trioxide, 1,3diphenyltriazene, hydrochloric acid + water, hypochlorous acid, nitric acid, perchloric acid + water, peroxyacetic acid, potassium permanganate, tetrafluoroboric acid, 4toluenesulfonic acid + water, and acetic acid + water. Reactions with ethanol + sodium hydrogen sulfate, and hydrogen peroxide form explosive products. Reactions with ammonium nitrate + hexamethylenetetrammonium acetate + nitric acid form as products the military explosives RDX and HMX. Reacts violently with N-tert-butyl-phthalimic acid + tetrafluoroboric acid, chromic acid, glycerol + phosphoryl chloride, and metal nitrates (e.g., copper or sodium nitrates). Incompatible with 2-aminoethanol, aniline, chlorosulfonic acid, (CrOs + acetic acid), ethylene-diamine, ethyleneimine, glycerol, oleum, HF, permanganates, NaOH, Na202, H z S 0 4 , water, N202, (glycerol + phosphoryl chloride). When heated to decomposition it emits toxic fumes; can react vigorously with oxidizing materials, wdl react violently on contact with water or steam. Used in production of drugs of abuse. To fight fire, use COz, dry chemical, water mist, alcohol foam. See also ANHYDRIDES. AAX750 CAS: 93-29-8 ACETISOEUGENOL mfi C 1 2 H 1 4 0 3 mw: 206.26
HR: 2
8
AAYOOO
ACETOACETANILIDE
PROP: White crystals; clove odor. Flash p:
SYNS: 2-ACF':TOACE~Lh?rlINOTOLUESE0
153°F. Sol in alc, chloroform, eth; insol in water.
ACF,TO~\CF,TYI,-2-~IETHYLANILInE0 2'-RlETHYLACFU3A4CET.\NLIDE
SY NS: 4-X(:ETOXY-3-hIETHOIY- 1-PROPENYI.BEXZESE 0 ACI7T;LISOEL'GENOL 0 F E h U No. 2470 0 ISOECGENOL ACETATE 0 ISOEUGENYI, ACETATE (FCC) 0 2-51I'TIIO);Y-4-PROPENYL-P~~E~YL ACETATE
CONSENSUS REPORTS: Reported in EPA
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NO,.
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
ABAJOO CAS: 92-15-9 HR: 2 AC ETOAC ETYL-O-ANIS1DINE mf: C I I H I ~ N O ~ mw: 207.25 PROP: Cqstals. Mp: 86.6", flash p: 325°F (OC), d: 1.132 @ 86.6"/20", vap d: 7.0.
AAYOOO CAS: 102-01-2 HR: 2 ACETOACETANILIDE mf: CloHlIN02 mw: 177.22 PROP: White, crystalline solid. Mp: 86", bp: decomp, flash p: 365°F (COC), d: 1.260 @ 2O", vap press: 0.01 mm @ 20".
SYNS: o-ACETOACETANISIDE 0 ACETOACET-oANISIDIN (CZECH) 0 ACETOACETIC ACID-oANiSIIIIDE 0 2-hCETOACEnWIRII90A;ISOLE 0 ACETOACETYL-o-~\~ISIDE 0 ACETOACETYL-oANISINE 0 o-;\IETHOXYACETOACET~~~ILIDE 0 2hIETHOXY,ICETOACETA~II~IDE 0 2'-RIETHOSY4CETOACETANILIDE
N 0 ACETI\NII.IDE, 2-,\CETYL- 0 .,\CETOI\C~,TA~IIDOHEIL'%EZE 3 ACETO-ACETANLID 0 ACETOACETIC ACID ANILIIIE 0 ACETOACETIC :\KII,IDI! 0 ((,~(:r~rOhCETII~)-A5IINO)B~NZI!SE 0 11,ISE 0 ACETILACET'~N1LIDE0 u-.\CET;I.,ICI;.T;\NII.IDE 0 N-(ACETYLACETYL)AN11,lSE 0 .ISILID I
CONSENSUS REPORTS: Reported in EPA
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. A weak allergen. See also ACETANILIDE. Combustible when exposed to heat or flame. See ANILINE and CYANIDE for disaster hazard. When heated to decomposition it emits toxic NO, fumes. To fight fire, use alcohol foam, water mist, COz, dry chemical.
ABAOOO CAS: 93-68-5 HR: 2 ACETOAC ET-0-TOLU IDI DE mf: C I I H I ~ N O ~ mw: 191.25 PROP: Crystals. Mp: 106", bp: decomp, d: 1.300 @ 20", vap press: 0.01 mm @ 20", flash p: 320°F (COC).
TSCA Inventory. SAFETY PROFILE: A skin and eye irritant. When heated to decomposition it emits toxic fumes of NO,. Combustible when exposed to heat or flame or oxidizing materials. To fight fire, use COZ,mist, dry chemicals.
ABA750 CAS: 1271-55-2 HR: 3 ACETOFERROCENE mf: C I ~ H I Z F ~ O mw: 228.09 PROP: Orange crystals from heptane. Mp: 85-86'. SYNS: ACETYLFERROCFSE 0 1ACETYLFERROCENE FERROCENE, I~CETYL-0 MONACETILFERROCENE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison by ocular and intravenous routes. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
ABBOOO CAS: 968-81-0 HR: 3 ACETOHEXAMI DE mf: C15H2oN204S mw: 324.43
2'-ACE TONAPH THONE ABC500
PROP: Crystals from aq ethanol. Mp: 188-1 89".
SYNS: HYDROXYACETONE 0 l-HYDROXY-2PROPANONE
SYNS: ACETYL METHYL CARBINOL 0 Z-BUTAN-OL3-ONE 0 2,3-BUTANOLONE 0 DIMETHYL-KETOL 0 FEMA No 2008 3-HYDROXY-2-BUTASONE0 1HYDROXYETHYL METHYL KETOXE 0 y-HYDROXY-POXOBUTANE
TSCA Inventory.
9
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. CYCLOHEXYLUREA 0 4-ACETYI-N-((CYCLOHEXYLAMIN0)CARBONYL)-BENZENE-SULFONAhtIDE SAFETY PROFILE: Moderately toxic by 0 CYCL4MIDE 0 DIMELIN 0 DIMELOR 0 DYMELOR ingestion. Mutation data reported. An 0 NCI-COO3247 0 ORDIMEL 0 TSIKLhhIID allergen. Implicated in aplastic anemia. A 10 CONSENSUS REPORTS: NCI gram dose may be fatal to an adult. S h n Carcinogenesis Bioassay (feed); No contact, inhalation, or ingestion can cause Evidence: mouse, rat NCITR* NCI-CGasthma, sneezing, irritation of eyes and nose, TR-50,78. Reported in EPA TSCA hves, and eczema. Combustible when Inventory. exposed to heat or flame. When heated to SAFETY PROFILE: Human reproductive decomposition it emits acrid smoke and effects by an unspecified route: stillbirth. fumes. Mildly toxic by ingestion. When heated to decomposition it emits very toxic fumes of ABC475 CAS: 941-98-0 HR: 2 SO, and NO,. 1'-ACETONAPHTHONE mf: C12H100 mw: 170.22 ABB500 CAS: 513-86-0 HR: 3 PROP: Crystals. Mp: 34', bp: 302', flash p: AC ETOIN >230°F, d: 1.120. DOT: UN 2621 SYNS: 1-ACETONAPHTHALENE 0 a-ACETOmf: C4Hs02 mw: 88.12 NAPHTHONE 0 1-ACETONAPHTHONE 0 1PROP: Sltly yellow liquid or crystalline solid; ACETYLNAPHTHALENE 0 ETHANONE, 1-(1NAPHTHALENYL)-(9CI) 0 METHYL a-NAPHTHYL buttery odor. D: 1.016, bp: 147-148", refr KETONE 0 METHYL 1-NAPHTHYLKETONE 0 aindex: 1.417, mp: 15", flash p: 106°F. Wsc METHYL NAPHTHYL KETOSE 0 1-(1-NAPHTHwith water, alc, propylene glycol; insol in ALENYL)ETHANONE 0 a-NAPHTHYL METHYL vegetable oil. KETONE 0 1-NAPHTHYLMETHYL KETONE SYN s: 1-@-ACET'iLBENZENESLLFONYL)-3-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Experimental reproductive effects. LWdly toxic by subcutaneous route. A moderate skin irritant. Flammable liquid. When heated to decomposition it emits acrid smoke and fumes. See also KETONES.
ABCOOO CAS: 116-09-6 HR: 2 ACETOL (1) mf: C3H602 mw: 74.09 PROP: Colorless liquid. D: 1.084 @ 20°/4", fp: -17' (approx), mp: -7", bp: 145-146" decomp. Wsc in water, alc, and eth.
CONSENSUS REPORTS: Reported in EPA DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Moderately toxic by ingestion. A s h n irritant. A combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
ABCSOO CAS: 93-08-3 HR: 2 2I-ACETONAPHTHONE mf: C12H100 mw: 170.22 PROP: White needles; orange-blossom odor. Flash p: 264"F, mp: 56", bp: 301-303". Sol in fixed oils; sltly sol in propylene glycol; insol in glycerin. SYNS: P-ACETONAPHTHALENE 0 ACETONAPHTHONE 0 P-ACETONAPHTHONE 0 2ACETONAPHTHONE 0 P-ACETYLNAPHTHALENE 0 2-ACETYLNAPHTHALEXE 0 FEhlA No. 2723 0 METHYL-P-NAPHTHYL KETONE (FCC) 0 METHYL-2NAPHTHYL KETONE 0 P-METHYL NAPHTHYL KETONE 0 l-(Z-NAPHTHALENYL)ETHAr\NONE 0 p-
10 ABC750
ACETONE
NAPHTHYL METHYL KETONE 0 2-SAPHTHYL 5IETHYL KETOSE 0 O R W G E CRYSTALS
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Moderately toxic by
ingestion. A human s h n irritant. Flammable liquid. When heated to decomposition it emits acrid smoke and fumes. ABC750 CAS: 67-64-1 HR: 3 ACETONE DOT: UN 1090/UN 1091 mf: C3Hb0 mw: 58.09 PROP: Volatde, colorless liquid; fragrant mintllke odor. Mp: -94.6", bp: 56.2" @ 20 mm, refr index: 1.356, flash p: 0°F (CC), lel: 2.6%, uel: 12.8%, d: 0.7972 @ l j " , autoign temp: (color) 869"F, vap press: 240 hPa @ 20°, vap d: 2.00. Misc in water, alc, org solvs, and ether. IDLH 2500 ppm [lo% LEL]. SYNS: ACETON (CER\L.\N, DUTCH, POIJSH) 0 .ICETONE OILS (DOq 0 CHEVRON ACETONE 0 DISIETHYLFOR\L\LDEHYDE Ll DIXETHYLKETAL 0 DIMETHYL KETONE 3 FEhfA No. 3326 0 KETONE, DIMETHYL 0 I(ETO?\'E PROPANE 0 P-ICETOPROPANE 0 METHk'I. KETONE 0 PROPANONE 0 2PROPASOXE 0 PYROACETIC ACID 0 PYROACETIC ETHER 0 RCRA WASTE NUMBER COO2 CONSENSUS REPORTS: On Community hght-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 750 ppm; STEL 1000 PPM ACGIH TLV: TWA 500 ppm; STEL 750 ppm; Not Classifiable as a Human Carcinogen; BEI: 50 mg/L acetone in urine at end of shift. DFG MAK: 500 ppm (1200 mg/m3) NIOSH REL: (Ketones) 10H TVVA 590 mgh3 DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by various routes. A s h n and severe eye irritant. Human systemic effects by inhalation: changes in EEG, changes in
carbohydrate metabolism, nasal effects, conjunctiva irritation, respiratory system effects, nausea and vomiting, and muscle weakness. Human systemic effects by ingestion: coma, kidney damage, and metabolic changes. Narcotic in high concentration. In industry, no injurious effects have been reported other than s h n irritation resulting from its defatting action, or headache from prolonged inhalation. Experimental reproductive effects. A common air contaminant. Highly flammable liquid. Dangerous disaster hazard due to fire and explosion hazard; can react vigorously with oxidizing materials. Potentially explosive reaction with nitric acid + sulfuric acid, bromine trifluoride, nitrosyl chloride + platinum, nitrosyl perchlorate, chromyl chloride, thiotrithiazyl perchlorate, and (2,4,6-trichloro-l,3,5triazine + water). Reacts to form explosive peroxide products with 2-methyl-1,3butadiene, hydrogen peroxide, and peroxomonosulfuric acid. Ignites on contact with activated carbon, chromium trioxide, dioxygen difluoride + carbon dioxide, and potassium-tert-butoxide. Reacts violently with bromoform, chloroform + alkalies, bromine, and sulfur dichloride. Incompatible with CrO, (nitric + acetic acid), NOC1, nitryl perchlorate, permonosulfuric acid, NaOBr, (sulfuric acid + potassium dichromate), (tho-diglycol + hydrogen peroxide), trichloromelamine, air, HNO3, chloroform, and H2S04. To fight fire, use Con, dry chemical, alcohol foam. Used in production of drugs of abuse. ABDOOO CAS: 57-15-8 HR: 3 ACETONE CHLOROFORM mf: C4H7C130 mw: 177.46 PROP: Hydrated crystals; camphor odor. Mp: 97" (78" anhyd), bp: 167". SYNS: AhHYDROUS CHLOROBUTAhOL i3 CHLORBUTANOL 0 CHLORBUTOL CHLORETONE 0 CHLOROBUTANOL 0 CLORTRAB 0 HCP 0 METHAFORM 0 SEDAFORM TRICHLORO-tert-BUTYI ALCOHOL 0 tert-TRICHLOROBUTYLALCOHOL 0
p-ACETOPHENETIDIDE P,P,P-TRICHLORO-tert-BUTYLALCOHOL 0 1,1,1-
TRICHLORO-2-METHYL-2-PROPANOL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion. A
narcotic. A s h n and eye irritant. Mutation data reported. See also CHLORAL HYDRATE, whch acts similarly. Dangerous; can react with oxidizing materials. Combustible when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Cl-. See also PHOSGENE. ABEOOO HR: 3 ACETONE PEROXIDE PROP: Shipped as a liquid or absorbed on cornstarch. The trimeric form is crystalhe. Mp: 97". SAFETY PROFILE: Severe skin and eye irritant. Flammable by spontaneous chemical reaction; can react vigorously with reducing materials. The trimeric form is shock-sensitive and static-electricitysensitive and may detonate. ABESOO CAS: 75-05-8 HR: 3 AC ETONlTRlLE DOT: UN 1648 mf: C2H3N mw: 41.06 PROP: Colorless liquid; almond-ethereal, aromatic odor. Mp: -45", bp: 81.1", flash p: 42°F (COC), d: 0.7868 @ 2Oo/2O0, vap d: 1.42, vap press: 100 mm @ 27", lel: 4.4%, uel: l6%, autoign temp: 975°F. MISCin water, alc, and org solvs. Immisc in pet eth. IDLH 500 ppm. SYNS: ACETONITRIL (GERMAN, DUTCH) 0 CYANOMETHANE 0 CYANURE de METHYL (FRENCH) 0 ETHANENITRILE ETHYL NITRILE 0 METHANECARBONITRILE 0 METHANE, CYANO- 0 METHYL CYANIDE 0 METHYLKYANID 0 NCI-C60822 0 RCRA WASTE NUMBER U003 0 USAF EK-488
CONSENSUS REPORTS: On Community fight-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 40 ppm; STEL 60 ppm ACGIH TLV: TWA 20 pprn skin; Not Classifiable as a Human Carcinogen.
ABG750
11
DFG MAK: 40 pprn (70 mg/m3) NIOSH REL: (Nitriles) TWA 34 mg/m3 DOT CLASSIFICATION: 3; Label:
Flammable Liquid, Poison SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Moderately toxic by several routes. An experimental teratogen. Other experimental reproductive effects. A skm and severe eye irritant. Human systemic effects by ingestion: convulsions, nausea or vomiting, and metabolic acidosis. Human respiratory system effects by inhalation. Mutation data reported. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Explosion Hazard: See also CYANIDE and NITRILES. When heated to decomposition it emits highly toxic fumes of CN- and NO,. Potentially explosive reaction with lanthanide perchlorates and nitrogen-fluorine compounds. Exothermic reaction with sulfuric acid at 53°C. Will react with water, steam, acids to produce toxic and flammable vapors. Incompatible with oleum, chlorosulfonic acid, perchlorates, nitrating agents, inchum, dinitrogen tetraoxide, N-fluoro compounds (e.g., perfluorourea + acetonitrile), HN03, so3. To fight fire, use foam, Con, dry chemical. ABG750 CAS: 6244-2 HR: 3 I>-ACETOPHENETIDIDE mf: C I O H I ~ N O ~ mw: 179.24 PROP: Solid. Mp: 137-138', bp: 242-245".
s:
SYN 1-ACETAMIDO-4-ETHOXYBENZENE 0 ACETO-p-PHENALIDE 0 p-ACETOPHENETIDE 0 ACETO-p-PHENETIDIDE 0 ACETOPHENETIDIN 0 ACETOPHENETIDINE 0 ACETO-CPHENETIDIKE 0 ACETOPHENETIN 0 ACET-p-PHEKALIDE 0 ACET-pPHENETIDIN 0 ACETPHENETIDIN 0 pACETPHENETIDIN 0 ACETYLPHENETIDIN 0 NACETYL-p-PHENETIDINE O ACHROCIDIN O ANAPAC 0 APC 0 ASA COMPOUND 0 BROMO SELTZER 0 BUFF-A-COMP 0 CITIW-FORT 0 CODE,\Il'IIWL 0 COMMOTIONAL 0 CONTRADOL 0 CORICIDI?: 0 CORIFORTE 0 CORYBAN-D 0 DAPRISAL 0 DARVOS COMPOUND DASIKON o ESIPIRIN COMPOUND p-ETHOXYACETANILIDE 0 4-ETHOXYACETANILIDE 0 N-p-ETHOXYPHENYLACETAMIDE 0 N-(4ETH0XYPHENYL)ACETAMIDE 0 FENACETIXA 0 FIORINAL 0 MELABON 0 PARACETOPHEK'ETIDIN 0 PERCOBARB 0 PERCODAN 0 p-PHENACETIN 0 RCRA
12 ABHOOO
ACETOPHENONE
\X'.\STE NCMBFR El87 0 SINUT.\B 0 TETILICYDIN 0 XARIL 0 ZACTIRIY COLIPOUKD
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 2A IhiEMDT 7,310,87; Animal Inadequate Evidence IMEMDT 13,141,77; Human Limited Evidence IMEiMDT 13,141,77; IhlEhfDT 24,135,80; Animal Limited Evidence IMEMDT 24,135,80; IMEMDT 24,135,80. Reported in EPA TSCA Inventory. SAFETY PROFILE: Confirmed carcinogen producing tumors of the lildney and bladder. A human poison by an unspecified route. Poison by intravenous and possibly other routes. Moderately toxic by several routes. Human systemic effects by ingestion: cyanosis, liver damage, and methemoglobinemiacarboxyhemo-globinemia. Experimental teratogenic data. Other experimental reproductive effects. Mutation data reported. Chronic effects consist of weight loss, insomnia, shortness of breath, weakness, and often aplastic anemia. When heated to decomposition it emits toxic fumes of NO,.
Moderately toxic by ingestion. A skin and severe eye irritant. Mutation data reported. Narcotic in high concentration. A hypnotic. Flammable liquid. To fight fire, use foam, C O 2 , dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also IGTONES. ABHSOO CAS: 61-00-7 HR: 3 ACETOPROMAZIN E mf: C I ~ H Z N ~ O S mw: 326.49 PROP: Orange oil. Bp: 208-210"@ 0.08 mm. SYNS: ACEPROhLlZINA 0 ACEPROMAZISE 0 ACEPROMIZISA 0 ACETAZINE 0 ACETHYLPROhIAZIN 0 3-ACETYL-10-(3-DIMETHYL Ah11NOPROPYL)PHENOTHIAZINE C ACETYLPROMAZISE C ASXTRAS 0 ANERGAS 0 ATMVET 0 ATSETOZIN 0 AY-57,062 0 AZBPRO-MAZINE 0 1522 CB 0 10-(3-DIMETHYL-ASIINOPROPROPYL)PHENOTHIAZINE-3-ETHYLONE 0 1-(10-(3-(DIMETHYIAMINO)PR0PYL)-1OH-PHENOTHIALIN-2-YL)ETHANONE 0 10(3-DISIETHYLh;\iINOPROPYL)PHENOTHIAZIPU'-3YLMETHYL KETONE 0 LISERGAN 0 SOTESQUIL NOTENSIL 0 NOTESIL 0 PLEGECYI, 0 PLEGICIN PLIVAPHEN 0 SOPRINTIN 0 SOPRONTIN 0 SOPROTIN 0 SV-1522 0 VETRiNQUIL 0 VY-1172
DOT CLASSIFICATION: 3; Label:
Flammable Liquid ABHOOO CAS: 98-86-2 HR: 3 ACETOPHENONE mf: CsHsO mw: 120.16 PROP: Colorless liquid or plates; sweet, pungent odor. Mp: 19.7', bp: 202.3', d: 1.026 @ 20"/4", vap d: 4.14, vap press: 1 mm @ l5", autoign temp: 1060°F. Very sol in propylene glycol and fixed oils; sol in alc, chloroform, and eth; sltly sol in water; insol in glycerin. SYNS: .lCETYI,BENZENE 0 BESZOYL METHIDE 0 DYMEX 0 FhMA No. 2009 0 I-IYPNONE 0 KFTONE METHYL PHENYL 0 METHYL PHENYI, KETOSE 0 1I'HENYLETH.%NONE C PHENYL METHYL KETONE 0 USriF EK-496 CONSENSUS REPORTS: Reported in EPA
TSCY Inventory. ACGIH TLV: 10 ppm. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison by intraperitoneal and subcutaneous routes.
SAFETY PROFILE: Poison by ingestion, intravenous, and subcutaneous routes. A flammable liquid. When heated to decomposition it emits toxic fumes of SO, and NO,. See also KETONES. An animal tranquilizer.
ABIOOO CAS: 350-03-8 HR: 3 3-ACETOPYRIDINE mf: C ~ H T N O mw: 121.15 PROP: Liquid. Bp: 220", bp: 106' @ 12 mm. Sol in water. SYNS: P-ACETYLPYRIDINE 0 3-ACETYL-PYRIDINE 0 hlETHYL PYRIDYL KETONE 0 LIETHYL-P-PYRIDYL KETONE 0 hlETHYI-3-PYRJDYL KETONE 0 PYRIDINE, 3-ACETYL-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison by ingestion.
Moderately toxic by intraperitoneal route.
2-(ACETOXYMERCURI)-4-NlTRO-ANlLlNE
Mutation data reported. A flammable liquid. When heated to decomposition emits toxic fumes of NO,. See also KETONES. AB1500 CAS: 88-IS-3 HR: 3 2-ACETOTHIENONE mf: C6H60S mw: 126.18 PROP: Liquid. D: 1.16 @ 24 mm, mp: 9', bp: 213-214'. SYNS: 2-ACETOTHIOPHENE
2-ACETYLTHIO-
PHENE
ABQ250
13
CHLORIDE ACETATE 0 (2-HYDRO-XYETHYL)TRIMETHYLAMMONIUMCHLORIDE ACETATE 0 OVISOT 0 TL 1505
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous, intravenous, and parenteral routes. Moderately toxic by ingestion. When heated to decomposition it emits very toxic fumes of NO, and C1-. A cholinergic agent. See also CHOLINE ACETATE (ESTER).
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison by intraperitoneal route. A flammable liquid. When heated to decomposition emits toxic fumes of SO,.
ABJ250 CAS: 103-89-9 HR: 2 p-ACETOTOLUIDIDE mf: C9H11NO mw: 149.21 PROP: Crystals from alc. Bp: 307', fp: 335°F (CC), mp: 146', d: 1.212, vap d: 5.14. SYNS: p-ACETAMIDOTOLUENE0 p-ACETOTOLUIDE 0 4-ACETOTOLUIDE 0 4-(ACE?nAMIN0)TOLUENE 0 N-ACETYL-p-TOLUIDIDE0 ACETYL-p-TOLUIDINE 0 p-METHYLACETANILIDE 0 4-METHYMCETANILIDE 0 4'-METHYLACETANILIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. See also ACETANILIDE. Combustible. When heated to decomposition it emits toxic fumes of NO,. To fight fire, use water, foam, CO2, dry chemical.
ABOOOO CAS: 60-31-1 HR: 3 2-ACETOXYETHYLTRIMETHYLAMMONIUM CHLORIDE mf: C ~ H I ~ N O ~ * Cmw: ~ 181.69 PROP: Deliquescent crystals, powder. Mp: 149-152'. SYNS: ACECOLINE 0 ACETYLCHOLINE CHLORIDE 0 ACETYLCHOLINE HYDROCHLORIDE 0 ACETYLCHOLINIUM CHLORIDE 0 Z-(ACETYL-OXY)N,N,N-TRIhlETHYLETHANAMINIUM CHLORIDE 0 ACH CHLORIDE 0 ARTEROCOLINE 0 CHOLINE
ABQOOO CAS: 6283-24-5 HR: 3 p-(ACET0XYMERCURI)ANlLlNE mf: C8HgHgN02 mw: 351.77 PROP: Colorless prisms from (CHCb). Mp: 166-1 67'. Insol in water, Et20. Sltly sol in aqueous ethanol, CHCl3. SYNS: (ACETATO)@-AMINOPHENn)?rlERCURY 0 pAMINOPHENYLMERCURIC ACETATE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. On Community Right-ToKnow List. OSHA PEL: CL 0.1 mg(Hg)/m3 (skm) ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 pg/g creatinine total inorganic mercury in urine preshft; 15 pg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NlOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (shn) SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. See also MERCURY COMPOUNDS, ANILINE. When heated to decomposition it emits very toxic fumes of NO, and Hg.
ABQ250 CAS: 54481-45-7 HR: 3 2-(ACETOXYMERCURI)-4-NITROANILINE mf: CsHsHgN204 mw: 396.77 SYN: ACETATO(2-AIMINO-j-NITROPHENYL)MERCURY
OSHA PEL: CL 0.1 mg(Hg)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin);
BEI: 35 pg/g creatinine total inorganic mercury in urine preshift; 15 pg/g creatinine
14 ABUOOO
17-ACETOXY-19-NOR-17-a-PREGN-4-EN-20-YN-3-
total inorganic mercury in blood at end of shft at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (shn) SAFETY PROFILE: Poison by intraperitoneal route. See also MERCURY COMPOUNDS, NITRO COMPOUNDS of AROMATIC HYDROCARBONS. When heated to decomposition it emits very toxic fumes of Hg and NO,.
the treatment of menstrual dsorders and uterine bleedmg. ABUSOO CAS: 62-38-4 HR: 3 ACETOXYPHENYLMERCURY DOT: UN 1674 mf: CsHsHgOz mw: 336.75 PROP: Lustrous crystals. Mp: 149-152'. Sltly sol in water. SYNS: ACETATE PHENYLMERCURIQUE (FRENCH)
0
(ACETAT0)PHENYLMERCURY 0 ACETIC ACID, PHENYLMERCURY DERIV. 0 (ACETOXYMERCURIBENZENE 0 AGROSAN 0 AGROSAND 0 AGROSAN G N 5 0 ALGIhfYCIN 0 ANTIMUCIN X'DR 0 BENZENE, ABUOOO CAS: 51-98-9 HR: 3 (ACETOXY-MERCURI) 0 BENZENE, (ACETOXYMERCURIO). 0 BUFEN 0 CEKCSIL 0 CELMER 0 17-ACETOXY-19-NOR-I 7-a-PREGN-4CERESAN 0 CERESAN UNIVERSAL 0 CERESOL 0 EN-20-YN -3-ONE CONTRA CREME 0 DYANACIDE 0 FEMMA 0 FENYLmf: C22H28O3 mw: 340.50 MERCURIACETAT (CZECH) 0 FhL4 0 FUNGITOX OR 0 PROP: Crystals from MezCO/hexane. Mp: GALLOTOX 0 HL-331 0 HONG KIEN 0 HOSTAQUICK 161-163". 0 KWIKSAN 0 LEYTOSAN 0 LIQUIPHENE 0 SYNS: 17-P-ACETOXY-19-NOR-17-a-PREGN-4-EN-20MERCURIPHENYL ACETATE 0 MERCURY(I1) YW3-0NE 0 (17-a)-17-(ACETYLOXY)-19-NORPREGN-4ACETATE, PHENYL- 0 MERCURY, ACETOXYPHENYLEK-20-YN-3-ONE 0 17-ACETYLOXY-(17-a)-190 MERGAMMA 0 MERSOLITE 0 MERSOLITE 8 0 NORPREGN-4-ESTREN-17-P-OL-ACETATE-3-ONE 0 17METASOL 30 0 NORFORMS 0 NYLMERATE 0 OCTAN E S T 0 17-a-ETHINYL-19-NORTEST-OSTERONE FENYLRTUTNATY (CZECH) 0 PAMISAN 0 PHENMAD ACETATE 0 17-a-ETHINYL-19-NORTESTOSTERONE0 PHENOMERCURIC ACETATE 0 PHENYLMERCURL 17-P-ACETATE 0 17-a-ETHYNYL-17-P-ACETOXY-19ACETATE 0 PHENYL MERCURIC ACETATE 0 NORANDROST-4-EN-3-ONE 0 17-a-ETHYNYL-17PHENYL-MERCURY ACETATE 0 PHENYLQUECKHYDROXYESTR-4-EN-3-ONEACETATE 0 17-aSILBERACETAT (GERMAN) 0 PHIX 0 PMA 0 PMAC 0 ETHYNYL-19-NORTESTO-STERONE ACETATE 0 17PRWCETATE 0 PhlAL 0 P U S 0 PUIWSAN-SC-10 0 HYDROXY-19-NOR-17-a-PREGN-4-EN-2O-YN-3-ONE PURATURF 10 0 QUICKSAN 0 RCRA WASTE NUbIBER ACETATE 0 17-P-HYDROXY-19-NOR-17-a-PREGN-4PO92 0 SANITIZED SPG 0 SC-110 0 SCUTL 0 EN-20-YN-3-ONE ACETATE 0 NORETHINDRONE-17SEEDTOX 0 SHIMMEREX 0 SPOR-KIL 0 TAG 0 TAG ACETATE 0 19-NORETHISTERONE ACETATE 0 19331 0 TAG FUNGICIDE 0 TAG HL 331 0 TRIGOSAN 0 NORETHYNYLTESTOSTERONE ACETATE 0 ZIARNIK NORETHYSTERONE ACETATE 0 NORLUTATE 0 CONSENSUS REPORTS: IARC Cancer NORLUTINE ACETATE 0 ORLUT'4TE
CONSENSUS REPORTS: IARC Cancer
Review: Animal Limited Evidence IMEMDT 21,441,79; Animal Sufficient Evidence IMEMDT 6,179,74. EPA Genetic Toxicology Program. SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic data. Human reproductive effects by ingestion and implant routes: menstrual cycle changes, postpartum effects, and changes in fertility. A human teratogen by an unspecified route with developmental abnormalities of the urogenital system. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. Used in
Review: Group 2B, Human Inadequate Evidence IMEMDT 58,239,93. EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Mercury and its compounds are on the Community Right-To-Know List. OSHA PEL: CL 0.1 mg(Hg)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Hg)/m3 (shn); BEI: 35 pg/g creatinine total inorganic mercury in urine preshift; 15 pg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
ACETOXYTRIPHENYLSTANNANE NlOSH REL: (Mercury, Aryl and Inorganic)
CL 0.1 mg/m3 (skin) DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion,
intravenous, intraperitoneal, subcutaneous, and possibly other routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also MERCURY COMPOUNDS. When heated to decomposition it emits toxic fumes of Hg. ABU800 CAS: 2114-33-2 HR: 1 2-ACETOXY-1-PHENYLPROPANE mf: CllH1402 mw: 178.25 SYNS: ACETIC ACID, a-METHYL-PHEXETHYLESTER 0 BENZYLMETHYLCARBINYLACETATE 0 RIETHYLBENZYLC4RBINYL ACETATE 0 a-METHYL-PPHENYLETHYL ACETATE 0 1-PHENYL-2-PROPANOL ACETATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
ABW6OO CAS: 13121-71-6 HR: 3 ACETOXYTRICYCLOHEXYLSTANNANE mf: C20H3602Sn mw: 427.25 PROP: Rod-like crystals from aqueous ethanol. Mp: 61-63'. SYN: STANNANE,ACETOXYTRICYCLOHEXYLOSHA PEL: TWA 0.1 mg(Sn)/m' ACGIH TLV: TWA 0.1 mg(Sn)/m3 (skin) SAFETY PROFILE: Poison by ingestion.
When heated to decomposition it emits toxic fumes of Sn. ABW750 CAS: 1907-13-7 HR: 3 ACETOXYTRIETHYLSTANNANE mfi C&1802Sfl mW: 264.95 SYNS: ACETOXYTRIETHYLTIN 0 TRIAETHYLZINNACETAT (GERMAN) 0 TRIETHYLTIN ACETATE OSHA PEL: TWA 0.1 mg(Sn)/m3 (skm) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m3 (shn). NlOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3
ABX250
15
SAFETY PROFILE: Poison by ingestion and intravenous routes. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating Sn+ fumes.
ABXOOO CAS: 289746-3 HR: 3 ACETOXYTRIHEXYLSTANNANE mf: C20H4202Sn mw: 433.31 SYNS: ACETOXYTRIHEXYLTIN 0 TRIHEXYLTIN ACETATE 0 TRI-N-HEXYLZINNACETAT(GERMAN) OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m3 (skin). NlOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by shn contact and intravenous routes. Moderately toxic by ingestion. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and Sn+ fumes. ABX250 CAS: 900-95-8 HR: 3 ACETOXYTRIPHENYLSTANNANE mf: C20HlsOzSn mw: 409.07 PROP: White, crystalline solid. Mp: 120-123'. Practically insol. SYNS: ACETATE de TRIPHENYL-ETAIN (FRENCH) 0 ACETATO dl STAGNO TRIFENILE (ITALIAN) 0 ACETAT0TRIPHENYLSTd4NNANE0 ACETOXYTRIPHENYT-STANNAN (GERMAN) 0 ACETOXYTRIPHENYLSTANNANE0 ACETOXYTRIPHENYL-TIN 0 (ACETYLOXYTRIPHENYL-STANAE (9Cl) 0 BATASAN 0 BRESTAN 0 ENT 25,208 0 FEN-OLOVO ACETATE 0 FENTIN ACETAAT (DUTCH) 0 FENTIN ACETAT (GERMAN) 0 FENTIN ACETATE 0 FENTINE ACETATE (FRENCH) 0 FINTIN ACETATO (ITALIAN) 0 GC 6936 0 HOE-2824 0 LIROhlATIN 0 LIROSTANOL 0 PHENTIN ACETATE 0 PHENTINOACETATE 0 SUZU 0 TINESTAN 0 TINESTAN 60 W 0 TIN TRIPHENYL ACETATE 0 T r r A 0 TPZA 0 TRIFENYLTINACETAAT (DUTCH) 0 TRIPHENYLACETO STANNANE 0 TRIPHENYL-TIN ACETATE 0 TRIPHENYLZINNACETAT (GERMAN) 0 TUBOTIN 0 VP 1940 CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
16 ABXSOO ACETPHENARSINE NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion, intraperitoneal, intravenous, and subcutaneous routes. Moderately toxic by skin contact. Questionable carcinogen with experimental neoplastigenic data. An experimental teratogen. Other experimental reproductive effects. A fungicide and algicide used as a wood preservative. When heated to decomposition it emits acrid smoke and Sn' fumes. See also TIN COMPOUNDS.
ABXSOO CAS: 97-44-9 HR: 3 ACETPHENARSINE mf: CsHloAsNOs mw: 275.11 PROP: Crystalline material. Mp: 220-221'. Decomp @ 240-250'. Sltly sol in water. SYNS: 3-ACETAMIDO-4-HYDROXY-PHENYL ARSONIC ACID 0 ACETARSOL 0 ACETARSONE 0 3ACETYLAMINO-4-HYDROXYPHENYLARSONICACID 0
decomposition it emits very toxic fumes of NO, and As. ABX750 CAS: 123-54-6 HR: 3 ACETYL ACETONE DOT: UN 2310 mf: C5H802 mw: 100.13 PROP: Colorless to sltly yellow liquid; pleasant odor. Mp: -23.2', bp: 139' @ 746 mm, flash p: 105'F (OC), d: 0.952-0.962, refr index: 1.402, vap d: 3.45, autoign temp: 644'F. MISCin alc, ether, chloroform, acetone, glacial acetic acid, and propylene glycol; insol in glycerin and water. SYNS: ACETOACETONE 0 DIACETYLMETHANE 0 FEMA No. 2841 0 PENTANEDIONE 0 2,4PENTANEDIONE (FCC) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Lquid SAFETY PROFILE: Poison by ingestion and
(3-(ACETYLAhlINO)-4-HYDROXYPHENYL)-ARSONINE intraperitoneal routes. (9CI) 0 N-ACETYL-4-HYDROXY-m-ARSANILIC ACID 0 inhalation. A skin and
AMARSAN 0 AMOEBAL 0 ARSONIC ACID 0 ARSPHEN 0 DEVEGAN 0 DISPARICIDA 0 DYNARSAN 0 EHRLICH 594 0 F 190 0 190 F 0 FOURNEAU 190 0 GINARSOL 0 GOYL 0 GYNOPLIX 0 KHAROPHEN 0 KUBARSOL 0 LIMARSOL MALAGRIDE 0 MEXYL 0 MON-ARGAN 0 NILACID 0 ORALCID 0 ORARSAN 0 OSARSAL 0 OSARSOLE 0 OSVARSAN 0 PALLICID 0 PAROXYL 0 SPIROCID 0 SPIROZID 0 STO-VARSAL 0 STOVARSOL 0 STOVARSOLAN 0 SVC 0 VAGISEPT 0 VAGOFLOR
CONSENSUS REPORTS: Arsenic and its
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 500 kg(As)/m3 ACGIH TLV: BEI: 35 P (As)/L inorganic arsenic and methylated metabolites in urine SAFETY PROFILE: Poison by ingestion and intravenous routes. Human systemic effects by ingestion: respiratory system, endocrine system, dermatitis, and fever. Human systemic effects by intravagmal route: hallucinations, dlstorted perceptions, convulsions, nausea or vomiting, decreased urine volume, and fever. Mutation data reported. See also ARSENIC COMPOUNDS. When heated to
Moderately toxic by severe eye irritant. Experimental reproductive effects. Mutation data reported. Flammable liquid when exposed to heat or flame. Incompatible with oxidning materials. To fight fire, use alcohol foam, COZ,dry chemical.
ABYOOO CAS: 28322-02-3 4-ACETYLAMINOFLUORENE mf: C ~ ~ H I ~ N Omw: 223.29
HR: 3
SYNS: 4-ACETYLAMINOFLUOREN (GERMAN) 0 NFLUOREN-4-YLACETAMIDE O N-4FLUORENYLACETAMIDE
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intraperitoneal route. Questionable carcinogen with experimental tumorigenic data. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
ABY9OO CAS: 140-40-9 HR: 3 2-ACETYLAMINO-5-NITROTHIMOLE mf: CsHsN303S mw: 187.19
ACETYL CHLORIDE PROP: Needles from alc, elongated plates from acetic acid. The commercial product may be yellow. Mp: 264-265'. Sol in aq solns of NaOH and NH3 with deep orange color. SYNS: ACETARTIDE, N-(5-NITRO-2-THIAZOLYL)- 0 ACETYL ENHEPTIN 0 ACINITRAZOL 0 ACINITRAZOLE 0 AMETOTERINA 0 AMINITROZOL 0 AMINITROZOLE 0 CYZINE PREMIX 0 ENHEMIN A 0 GYNOFON 0 LAVOFLAGIN 0 NITAZOL 0 NITAZOLE 0 NITHIAMIDE 0 5-NITRO-2-ACETIWhlINOTIAZOLO 0 N-(5-NITRO-2-THIAZOLYL)ACETAhTIDE 0 PLEOCIDE 0 TRICHLORAD 0 TRICHOCID 0 TRICHOiMAN 0 TRICHORAD 0 TRICHORAL 0 TRICOGEN 0 TRICOLAVAL O TRICORAL O TRICOSTERIL O TRIKOLAVAL O TRITHEON SAFETY PROFILE: Poison by ingestion. Mutation data reported. When heated to
decomposition it emits toxic fumes of SO, and NO,.
ACA9OO HR: D ACETYLATED MONOGLYCERIDES PROP: Esters of glycerin with acetic acid and edible fat-forming fatty acids. (FCC 111) May be whte to pale yellow liquids or solids; bland taste. Sol in alc, acetone; insol in water. SYN: ACETYLATED MONO- and DIGLYCERIDES SAFETY PROFILE: When heated to
decomposition it emits acrid smoke and irritating fumes.
ACB250 CAS: 460-07-1 1-ACETYLAZIRIDINE mf: C4H7NO mw: 85.12
HR: 3
SYN: ACETYLETHYLENEIMINE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intraperitoneal route. Questionable carcinogen with experimental tumorigenic and neoplastigenic data. When heated to decomposition it emits toxic fumes of NO,.
ACC250 CAS: 644-31-5 HR: 3 ACETYL BENZOYL PEROXIDE (solid) mfi C9H804 mw: 180.17
ACF750
17
PROP: White crystals. Mp: 36-37',
bp: 130' @ 19 mm. Sol in oils, alc, ether, and chloroform. DOT CLASSIFICATION: Forbidden SAFETY PROFILE: Poison by inhalation and ingestion. Severe irritant. A powerful oxidzing agent that is corrosive to the skin and mucous membranes. See also PEROXIDES, ORGANIC. Dangerous; shock or heat will cause detonation with evolution of toxic fumes; will react with water or steam to produce heat; can react vigorously with reducing materials. Flammable by spontaneous chemical reaction. To fight fire, use Con or dry chemical. When heated to decomposition it emits acrid smoke and fumes.
ACD750 CAS: 506-96-7 HR: 3 ACETYL BROMIDE DOT: UN 1716 mf: C2H3BrO mw: 122.96 PROP: Colorless, fuming liquid; turns yellow in air. Mp: -96.5', bp: 76.7', d: 1.52 @ 9.5'/4'. Decomp in water and alc; misc in benzene, ether, and chloroform. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by ingestion, inhalation, skin contact, and intraperitoneal routes. See also HYDROBROMIC ACID and ACETIC ACID. Violent reaction on contact with water, steam, methanol, or ethanol produces toxic and reactive HBr. When heated to decomposition it emits hghly corrosive and toxic fumes of carbonyl bromide and bromine. To fight fire, use dry chemical, C02. ACF750 CAS: 75-36-5 HR: 3 ACETYL CHLORIDE DOT: UN 1717 mf: CZH3C10 mw: 78.50 PROP: Colorless, pungent liquid. Fuming in air. Mp: -112', bp: 51-52', flash p: 40'F (CC), autoign temp: 734'F, d: 1.1051 @ 20'/4', vap d: 2.70, lel: 5%. Decomp in
18
A CHOOO
N-ACE TYL-I-CYSTElNE
water and alc; misc in benzene, ether, and chloroform. Sol in EtzO, C6H6. SYNS: ACETIC ACID CHLORIDE 0 ACETIC CHLORIDE 0 ETHANOYL CHLORIDE NUME%ERU006
RCRA WASTE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid, Corrosive SAFETY PROFILE: Poison by inhalation. Moderately toxic by ingestion. A human systemic irritant by inhalation. Violent hydrolysis reaction with water or steam produces heat, acetic acid, HC1, and other corrosive chlorides. May decompose during preparation. Dangerous fire hazard when exposed to heat or flame. Explosion hazard by spontaneous chemical reaction with dimethyl sulfoxide or ethanol. Also incompatible with Pcb. When heated to decomposition it emits hghly toxic fumes of phosgene and C1-. To fight fxe, use C02 or dry chemical. See also CHLORIDES.
ACHOOO CAS: 616-91-1 HR: 3 N-ACETYL-I-CYSTEINE mf: CsHsN03S mw: 163.21 PROP: Crystals from water. Mp: 109-110'. SYNS: I-a-ACETAMIDO-~-;2.IERC~4PTOPROPIONIC ACID 0 ACETEIN 0 ACETYLCYSTEINE 0 NACETYLCYSTEINE O N-ACETYLN-CYSTEINE O NACETYL-I-CYSTEINE (9CI) O N-ACETYL-3-MERCAPTOAL4NINE 0 AIRBRON 0 BRONCHOL-YSIN 0 FLUIMLCETIN FLCIMUCIL 0 FLUMICIL 0 INSPIR MERCAMURIC ACID 0 (R-MERCAP-TURIC ACID 0 MUCOLYTICUM 0 MUCOLYTICUMLAPPE 0 MUCObIYST 0 MVIUCOSOLVIN 0 NAC 0 NAC-TB 0 NSC-1 11180 0 PARVOLEX 0 RESPAIRE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by other routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and SO,,
ACHO9O CAS: 22439-58-3 HR: 3 2-ACETYLDIBENZOTHIOPHENE PROP: A liquid. mf: Ct4HtOOS mw: 226.30
SYNS: KETONE, 2-DIBENZOTHIENYL METHYL 0 DIBENZOTHIEN-2-YL METHYL KETONE DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison by intravenous
route. A flammable liquid. When heated to decomposition it emits toxic vapors of SO,. AC1500 CAS: 2386-25-6 HR: 3 3-ACETYL-2,4-DIMETHYL-PYRROLE mf: CsHllNO mw: 137.20 PROP: Solid. Mp: 137'. SYN: 2,4-DIMETHYLPYRROL-3-YLMETHYL KETONE DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison by intravenous
and intraperitoneal routes. A flammable liquid. When heated to decomposition it emits toxic fumes of NO,. See also KETONES. AC1550 CAS: 1500-94-3 HR: 3 3-ACETYL-2,5-DIMETHYL-PYRROLE mf: CsHltNO mw: 137.20 SYNS: 2,5-DIMETHYLPYRROL-3-YLMETHYL KETONE KETONE, 2,5-DIMETHYLPYRROL-3-YL METHYL DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intra-
peritoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,. AC1640 CAS: 117568-24-8 HR: 3 10-ACETYLDITHRANOL mf: C16H120j mw: 284.28 SYNS: lO-(ACETYLOXY)-1,8-DIHYDROXY-9(lOH)ANTHRACENONE 0 DITHRANOL, 10-ACETYL- 0 9(1OH)-ANTHRACENONE, I,8-DIHYDROXY-10-(10XOETHYL)- 0 9(10H)-ANTHRACENONE,10(ACETYL0XY)-1,8-DIHYDROXY-
SAFETY PROFILE: A poison by ingestion. A skin irritant. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
AC1750 CAS: 74-86-2 ACETYLENE DOT: UN 1001
HR: 3
trans-ACETYLENE DlCHLORlDE ACKOOO
mf: CzH2 mw: 26.04 PROP: Colorless gas; garlic-like odor. Flammable. Bp: -84.0" (subl), lel: 2.S0/o, uel: 82%, mp: -81.8', flash p: 0°F (CC), d: 1.173 g/L @ ,'O autoign temp: 581'F, vap press: 40 atm @ 16.8', vap d: 0.91, d: @quid) 0.613 @ -80°, d: (solid) 0.730 @ -85'. Sltly sol in water; mod sol in ethanol and acetic acid; very sol in MezCO; almost misc in ether. SYNS: ACETYLEN 0 ACETYLENE, dissolved (DOT) 0 ETHINE 0 ETHYNE 0 NARCYLEN CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: CL 2500 pprn ACGIH TLV: Simple asphyxiant NIOSH REL: (Acetylene) 10H TWA no exposure >2500 pprn DOT CLASSIFICATION: Forbidden; DOT Class 2.1; Label: Flammable Gas SAFETY PROFILE: Mtldly toxic by inhalation. Human systemic effects by inhalation: headache and dyspnea. Narcotic in high concentration. In general industrial practice, acetylene does not constitute a serious toxic hazard. It is a very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderate explosion hazard when exposed to heat or flame or by spontaneous chemical reaction. At high pressures and moderate temperatures, and in the absence of air, acetylene has been known to decompose explosively. Reacts with copper to form the explosive copper acetylide. Incompatible with brass, copper salts, copper carbide, powdered Co, Hg, Hg salts, K, Ag and Ag salts, RbH, CsH, halogens, HN03, NaH, oxidants. Acetylene + halide + UV can explode. Molten I< ignites in C2Hz and then explodes. CzHz reacts vigorously with trifluoromethyl hypo fluorite. With 02, C2H2 can detonate very powerfully. See ACETYLIDES. When ignited, it burns with an intensely hot flame; can react vigorously with oxidizing materials. When mixed with 0 2 in proportions of 40% or more, acetylene acts as a narcotic and has been used in anesthesia. Acetylene
19
acts as a simple asphyxlant by diluting the 0 2 in the air to a level that w d not support life. However, the presence of impurities in commercial acetylene may result in the production of symptoms before an asphyxiant concentration is reached. Thus: 10% in air produces a slight intoxication, 20% produces a staggering gait, 30% produces general incoordination, 33% leads to unconsciousness in 7 minutes, up to 80% produces complete anesthesia, increased blood pressure, narcosis, and stimulated respiration. Dizziness, headache, mild gastric symptoms, and (in h g h concentration) semi-asphyxia and brief loss of consciousness have all been reported. See ARGON for a dmussion of simple asphyxiants. To fight fire, use COz, water spray, or dry chemical. Stop flow of gas. ACJ125 HR: 3 ACETYLENE COMPOUNDS and ALKYNES SAFETY PROFILE: The carbon-carbon triple bond is explosively unstable in many acetylenic compounds. Both the lower alkynes (i.e., propyne, butadyne, etc.) and lugher compounds may undergo explosive decomposition. The presence of halogens and heavy metal derivatives may increase these explosive tendencies. See also ACETYLENE, ACETYLIDES, and specific compounds. ACKOOO CAS: 156-60-5 HR: 2 trans-ACETYLENE DICHLORIDE mf: CzH2C12 mw: 96.94 PROP: Colorless liquid; pleasant odor. Mp: -50°, bp: 48', flash p: 36'F, autoign temp: 860'F, lel: 9.7%, uel: 12.8%, d: 1.2743 @ 25"/4', vap press: 400 mm @ 30.8', vap d: 3.34. SYNS: trans-DICHLOROETHYLENE 0 trans-1,ZDICHLOROETHnENE (IMAK) 0 RCR4 WASTE NUMBER U079 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: 200 pprn (800 mg/m3)
20
ACK250
ACETYLENE TETRABROMIDE
SAFETY PROFILE: Moderately toxic by
ingestion. Mddly toxic by inhalation. Human systemic effects by inhalation: sleep, hallucinations, and distorted perceptions. Experimental reproductive effects. A skin and eye irritant. Mutation data reported. Exposure to high vapor concentration can cause nausea, vomiting, weakness, tremor, and cramps. Recovery is usually prompt following removal from exposure. Dermatitis may result from defatting action on shn. Dangerous fire hazard when exposed to heat, flame, or oxidtzers. Moderate explosion hazard in the form of vapor when exposed to flame. Violent reaction with difluoromethylene dihypofluorite. Forms shock-sensitive explosive mixtures with &nitrogen tetraoxide. Reaction with solid caustic alkahes or their concentrated solutions produces chloracetylene gas that ignites spontaneously in air. Reacts violently with N204, KOH, Na, NaOH. Moderate explosion hazard in the form of vapor when exposed to flame. Can react vigorously with oxidizing materials. To fight fire, use water spray, foam, C02, dry chemical. When heated to decomposition it emits toxic fumes of C1-. See also CHLORIDES; CHLORINATED HYDROCARBONS, ALIPHATIC; and ACETYLENE COMPOUNDS. ACK250 CAS: 79-27-6 HR: 3 ACETYLENE TETRABROMIDE mf: C2H2Br4 mw: 345.68 PROP: Colorless to yellow liquid. Bp: 151" @! 54 mm, fp: -lo, d: 2.9638 (@ 20"/4", mp: 0.lo, autoign temp: 635°F. IDLH 8 ppm. SYNS: MGTHAMANN'SLIQUID 0 TBE 0 1,1,2,2TETRkBROhfAETHAN(GERMAN) 0 TETRABROMOACETYLENE 0 i ,i,2,2-TETRABROMOETANO (ITALIAN) 0 S-TETRABROMOETHANE 0 1,1,2,2TETRABROMOETHANE 0 1,1,2,2-TETRABROOhfETHMN (DUTCH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 1 ppm
ACGIH TLV: TWA 1 pprn DFG MAK: 1 pprn (14 mg/m3) SAFETY PROFILE: Poison by inhalation,
ingestion, and intraperitoneal routes. An eye and skin irritant and a narcotic. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported. When heated it emits hghly toxic fumes of carbonyl bromide and Br-. See also ACETYLENE COMPOUNDS and BROMIDES. ACL750 CAS: 88-29-9 HR: 3 ACETYL ETHYL TETRAMETHYL TETRALIN mf: C18H260 mw: 258.44 PROP: m t e crystals. SYNS: ACETYLETHYL TETRAMETHYLTETRALIN 0 6-ACETYL-l,1,4,4-TETRAMETHYL-7-ETHYL-1,2,3,4,TETRALIN 0 7-ACETYL-1,1,4,4-TETRAMETHYI-i ,2,3,4TETRAHYDRONAPHTHALENE0 AETT 0
ETHhNONE-l-(3-ETHYL-5,6,7,8-TETRHYDRO-5,5,8,8TETRAhlETHYL-2-NAPHTHALENn) (9CI) 0 3'-ETHYL j',6',7',8'-TETRAHYDR0-j',jt,8'-TET~~~ETH-YL-2'ACETONAPHTHONE 0 1-(3-ETHYL-5,6,7,8TETRAHYDRO-j,j,8,8-TETRAMETH~-2-~~PHTHALENYLJ-ETHANONE0 MUSK 36A 0 POLYCYCLIC MUSK 0 VERSALIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion.
Moderately toxic by skin contact. A sktn and eye irritant. Exposure causes blue coloration of internal organs and central nervous system effects, e.g., hyperexcitabdity, tremors, lack of coordination, hunched back, and loss of weight. It is slowly metabolized and excreted via feces. Symptoms persist for 90 days after exposure. Severity of symptoms seems proportional to length of exposure. It is freely absorbed via human shn. When heated to decomposition it emits acrid smoke and fumes. ACMOOO CAS: 557-99-3 ACETYL FLUORIDE mf: C2H3FO mw: 62.05
HR: 3
ACETYLIDES
PROP: Liquid or gas. D: 1.002 @ 15'/4', mp: -60', bp: 20.8'. Sltly sol in alc, ether,
acetone, and benzene. SYNS: FLUORID KYSELINY OCTOVE 0 METHYL-
ACOOOO
21
SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
CARBONYL FLUORIDE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift. NIOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m3 SAFETY PROFILE: Poison by inhalation. See also FLUORIDES. When heated to decomposition it emits toxic fumes of F-.
ACM750 CAS: 1068-57-1 HR: 3 ACETYL HYDRAZIDE mf: C2H6N20 mw: 74.10 PROP: Needles from ethanol. Mp: 67', bp: 127' @ 18 mm. SYNS: ACETHYDMZIDE 0 ACETOHYDRAZIDE 0 N-ACETYLHYDRAZINE 0 ENT 61,241 0 ETHANEHYDRAZONICACID 0 MONOACETYLHYDIWZINE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion,
subcutaneous, and intraperitoneal routes. Mutation data reported. Exposure can cause hemolysis and liver damage. See also PHENYLHYDRAZINE.When heated to decomposition it emits toxic fumes of NO,. ACN300 CAS: 39543-84-5 HR: 3 2-ACETYL-4-(2-HYDROXY-3-tertBUTYLAMINOPROP0XY)BENZOFUR AN mf: C17HzN04 mw: 305.41 PROP: A liquid. SYNS: 1-(4-(3-((1,1-DIMETHYLETHYL)AMINO)-2-
ACN3lO CAS: 39543-94-7 HR: 3 2-ACETYL-7-(2-HYDROXY-3-secBUTYLAMINO-PROPOXY)BENZOFURAN mfi C17H23N04 mw: 305.41 PROP: A liquid. SYNS: ETHANONE, 1-(7-(2-HYDROXu-3-((1METHYLPROPYL)AMINO)PROPOXY)-2BENZ0FURANYL)- 0 KETONE,7-(3-(sec-
BUTYLAMINO)-2-HYDROXYPROPOXY)-2BENZOFUIWNYL METHYL
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
ACN320 CAS: 39543-80-1 HR: 3 2-ACETYL-7-(2-HY DROXY-3-tertBUTYL-AMINOPROP0XY)BENZOFURAN mf: C 1 7 H 2 3 N 0 4 mw: 305.41 PROP: A liquid. SYNS: KETONE, 7-(3-(tert-BUTYLAMINO)-2HYDROXYPROPOXY)-2-BENZOFUIWNYL METHYL 0 1-(7-(3-((1,1-DIMETHYLETHYL)AMINO)-2HYDROXYPROPOXY)-2-BENZOFURANn)ETHA NONE 0 ETHANONE, 1-(7-(3-((1,l-DIMETHYL-ETHYL)AMINO)-
2-HYDROXYPROPOXY)-2-BENZOFURANYL)-
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
ACOOOO HR: 3 ACETYLIDES PROP: Colorless, flammable gases with HYDROXYPROPOXY)-2-BENZOFURANYL)ETHA NONE odor similar to garlic. Can decompose 0 ETHANOKE, 1-(4-(3-((1,1-DIMETHYL-ETHYL)AMISO)spontaneously if pressure exceeds 15 PSIG. 2-HYDROXYPROPOXI~-2-BENZOFURANYL)0 KETONE, 4-(3-(tert-BUTYLAMINO)-2-HYDROXYPROP- SAFETY PROFILE: Severe explosion OXY)-2-BENZOFURANYLMETHYL hazard when shocked or exposed to heat. DOT CLASSIFICATION: 3; Label: Acetylides are very sensitive to shock, Flammable Liquid friction, and heat. They explode readily and
22
AC0320
5-ACETYLINDOLINE
are among the few commercial explosives that contain no oxygen or nitrogen and therefore produce no gas. The explosion simply results from the large amount of heat instantaneously produced. Acetylides are used for detonating compositions, or in combination with lead azide in detonating rivets, where the acetylides reduce the flash point of the more insensitive azides. They are in a class with the fulminates and the azides as primary detonants. Because these materials are so sensitive to shock and temperature, they must be handled with extreme care. They must be kept cool, and should be kept wet if they are to be stored. (See FULMINATES for suggested precautions in storage and handling of acetylides.) Metal powders, such as finely dvided Cu or Ag, should not be stored or kept with acetylene or acetylides because it is possible for these substances to react with these metal powders to form very sensitive acetylides, although they are not dangerous in themselves, can cause enough of a flash to i p t e a possibly explosive mixture of gases and thus cause an explosion in a warehouse or storage area. Examples of commercially used acetylides are silver acetylide and copper acetylide. See also ACETYLENE. See also indmidual compounds. AC0320 CAS: 16078-34-5 5-ACETYLINDOLINE mf: CloHllNO mw: 161.22 PROP: A liquid.
HR: 3
ACQ275 CAS: 65-82-7 HR: 3 N-ACETYL-I-METHIONINE mf: C7H13N03S mw:191.24 PROP: Colorless or white crystals or powder; odorless. Sol in water, alc, alkali and mineral acids; insol in ether. SYNS: ACETYLMETHIONINE 0 NACETYLMETHIONINE O METHIONAMINE CONSENSUS REPORTS: EPA TSCA Chemical Inventory, JUNE 1993 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition emits toxic fumes of NO,.
ACR400 CAS: 28895-91-2 HR: 3 ACETYLMETHYLNITROSOUREA mf: C4H7N303 mw: 145.14 SYNS: ACETYL-METHYL-NITROSO-HARNSTOFF (GERMAN) 0 N'-ACETYL-METHYLNITROSOUREA0 NMETHYL-N-NITROSO-N'-ACETYLUREA U 1-R;IETHYL-lNITROSOACETYLUREA
SYNS: INDOLINE, 5-ACETYL- 0 KETONE, 5INDOLINYL METHYL
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
AC0500 CAS: 507-02-8 ACETYL IODIDE DOT: UN 1898 mf: C2H310 mw: 169.95
PROP: Brown, transparent, fuming liquid. Bp: 108O, d: 2.067 @ 2Oo/4O, decomp in water and alc; sol in ether. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: Proposed: (inhalable fraction) 0.1 mg/m3; Not Classifiable as a Human Carcinogen) DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A toxic, corrosive material. Reacts with water or steam to produce toxic and corrosive fumes. Dangerous to use. When heated to decomposition it emits toxic fumes of I-. See also IODIDES.
HR: 3
SAFETY PROFILE: Poison by ingestion. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
ACRSOO CAS: 1053-74-3 HR: 3 3-ACETYL-I 0-(3'mN-METHYL-PIPERAZINO-N'-PR0PYL)-PHENOTHIAZIN mf: C Z ~ H Z ~ N ~ O Smw: 381.58 PROP: A liquid. SYNS: KETONE, METHYL 10-(3-(4-METHYL-lPIPERAZINYL)PROPYL)PHENOTHIAZIN-2-YL 0
ACETYLSALICYLIC ACID METHYL 10-(3-(4-METHYL-l-PIPERAZINYL)PRODYL)PHENOTHIAZIN-2-YLKETONE
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intravenous route. Moderately toxic by ingestion. A flammable liquid. When heated to decomposition it emits toxic vapors of
so,.
ACT250 CAS: 5275-694 HR: 3 2-ACETYL-5-NITROFURAN mfi C6HjNO4 mw: 155.12 PROP: IDLH 2000 ppm. SYN: (5-NITRO-2-FURYL) METHYL KETONE CONSENSUS REPORTS: EPA Genetic Toxicology Program. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Poison by subcutaneous route. Moderately toxic by ingestion. Mutation data reported. See also KETONES. A flammable liquid. When heated to decomposition it emits toxic fumes of NO,. ARW2OO CAS: 717514 1 -2 HR: 3 AVERMECTIN B(SUB 1) SYNS: AVID EC 0 ABAMECTIN 0 AFFIRM 0 AGRIMEK 0 AVERMECTIN B(SL'B 1) TECHNICAL GRADE 0 AVOMEC 0 MK 936 0 VERTIMEC 0 ZEPHYR
SAFETY PROFILE: A poison by ingestion and intracerebral routes. Moderately toxic by inhalation and s h n contact. When heated to decomposition it emits acrid smoke and irritating vapors.
ACVSOO CAS: 110-22-5 HR: 3 ACETYL PEROXIDE mf: C4H604 mw: 118.04 PROP: Solid or colorless crystals or liquid with very pungent odor. D: 1.18, mp: 30°, bp: 63' @ 21 mm. Sltly sol in cold water, decomp. SYNS: ACETYL PEROXIDE, not >25% in solution (UN 2084) (DOT) 0 ACETYL PEROXIDE, solid, or >25% in solution (DO?? 0 DIACETONE PEROXIDES, solid, or >25% in solution (DO9 0 DIACETYL PEROXIDE (MAK)
ADA725
23
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: Strong Skin Effects DOT CLASS IFlCAT1ON : Forbidden SAFETY PROFILE: Severe skin and eye irritant. Questionable carcinogen with experimental tumorigenic data. Dangerous fire hazard by spontaneous chemical reaction. A powerful oxidizing agent; can cause ignition of organic materials on contact. Severe explosion hazard when shocked or exposed to heat. It may explode spontaneously in storage and should be used as soon as prepared. It will react with water or steam to produce heat; can react vigorously with reducing materials; emits toxic fumes on contact with acid or acid fumes. To fight fire, use C02, dry chemical. Storage and Handling: Must be kept below 27' and not warmed over 30'. Do not add to hot materials. Do not add accelerator to this material. Store in origmal container with vented cap. Avoid bodily contact. This material is nearly always stored and handled as a 25% solution in an inert solvent. See also ACETYL PEROXIDE 25% solution (in dimethyl phthalate); and PEROXIDES, ORGANIC.
ADA725 CAS: 50-78-2 HR: 3 ACETYLSALICYLIC ACID mf: C 9 H 8 0 4 mw: 180.17 PROP: Colorless needles, crystals. Mp: 135', fp: 118'. Very sldy sol in alc, sol in benzene. Solubihty in water = 1% @ 37', in ether = 5% @ 20'. SYNS: AC 5230 0 ACENTERINE 0 ACESAL 0 ACETAL a ACETICIT. ACETILSALICILICO ACETILUM ACIDULATUM 0 ACETISAL 0 ACETOL 0 A C E T O N E 0 ACETOPHEN 0 ACETOSAL 0 ACETOSALIC ACID 0 ACETOSALIN 0 o-ACETOXYBENZOIC ACID 0 2-ACETOXYBENZOIC ACID 0 ACETYLIN 0 2-(ACETYL0XY)BENZOIC ACID 0 ACETYLSAL 0 ACETYLSALICYLSAEURE (GERMAN) 0 ACIDE ACETYLSALICYLIQUE (FRENCH) 0 ACIDO oACETIL-BENZOICO (ITALIAiV) 0 ACIDO ACETILSALICILICO (ITALIAN) 0 ACIDUM ACETYLSALICYLICUM 0 ACIME'ITEN 0 ACISAL 0 ACYLPYRIN 0 ASA 0 A.S.A. 0 A.S.A. EhPIRIN 0 ASAGRAN 0 ASATARD 0 ASPALON 0 ASPERGL'M 0
24
ADD400
ACETYL TRIBUTYL ClTRATE
ASPIRDROPS 0 ASPIRIN 0 ASPIRINE 0 ASPRO 0 ASTERIC 0 BENASPIR 0 BL4LPIRINIA 0 CAPRIN 0 OCARBOXWHENYL ACETATE 0 COLFANT 0 CONTRHEUMA RETARD 0 CRYSTAR 0 DELGESIC 0 DOLE,4N pH 8 0 DURAMhX 0 ECM ECOTRIN 0 EbiPIRIN 0 ENDYDOL 0 ENTERICIK 0 ENTEROPHEN 0 ENTEROSARINE 0 ENTROPHEN 0 EXTREN GLOBOID 0 HELICON 0 IDRAGIN 0 MEASURIN 0 NEURONIKA 0 NOVID 0 POLOPIRYNA 0 RHECMIN TABLETTEN 0 RHODINE 0 SALACETIN 0 SALCETOGEN 0 SALETIN 0 SOLPYRON 0 XAXA
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 mg/m3 ACGIH TLV: TWA 5 mg/m3 SAFETY PROFILE: Poison by ingestion, intraperitoneal, and possibly other routes. Human systemic effects by ingestion: acute pulmonary edema, body temperature increase, changes in kidney tubules, coma, constipation, dehydration, hematuria, hepatitis, nausea or vomiting, respiratory stimulation, somnolence, tinnitus, decreased urine volume. Implicated in aplastic anemia. A 10 gram dose to an adult may be fatal. A human teratogen. Human reproductive effects by ingestion and possibly other routes: menstrual cycle changes, parturition, various effects on newborn including Apgar score, developmental abnormalities of the cardlovascular and respiratory systems. Experimental animal reproductive effects. Human mutation data reported. An allergen; skin contact, inhalation, or ingestion can cause asthma, sneezing, irritation of eyes and nose, hves, and eczema. Combustible when exposed to heat or flame. When heated to decomposition it emits acrid smoke and fumes.
ADD750 CAS: 77-894 HR: 2 ACETYL TRIETHYL CITRATE mf: C14Hz208 mw: 318.36 PROP: Bp: 197' @ 15 mm. SYNS: ATEC 0 CITRIC ACID, ACETYL TRIETHYL ESTER 0 CITROFLEX A 2 0 1,2,3-PROPANETRICARBOXYLIC ACID, 2-(ACETYL0XY)-, TRIETHYL ESTER (9CI) 0 TRICARBALLYLIC ACID, P-ACETOXYTRIBUTYL ESTER 0 TRIETHYL ACETYLCITRATE 0 TRIETHYL CITRATE, ACETATE 0 TRIETHYLESTER KYSELINY ACETYLCITRONOVE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by intraperitoneal route. Mildly toxic by ingestion. See also ESTERS. When heated to decomposition it emits acrid smoke and fumes.
ADEOSO CAS: 19005-95-9 HR: 3 3-ACETYL-2,4,5-TRIMETHYL-PYRROLE mfi CgH13NO mw: 151.23 PROP: A liquid. SYNS: KETONE, METHYL 2,4,5-TFUMETHYL-PYRROL3-YL 0 METHYL 2,4,5-TRIMETHYLPYRROL-3-X KETONE
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by
intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,. ADE075 CAS: 1218-34-4 HR: 2 ACETYLTRYPTOPHAN mE C13H14N203 mw: 246.29 PROP: Solid. Mp: 190". SYNS: ACETYL-I-TRP 0 ACETYI-1-TRYPTOPHAN 0 N-ACETYL-LTRYPTOPHAN 0 N-ACETYLTRYPTOPHAN 0 (S)-N-ACETYLTRYPTOPHAN 0 AC-TRY
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. ADD400 CAS: 77-90-7 HR: D ACETYL TRIBUTYL CITRATE PROP: Clear viscous liquid. Mp: -80", bp: 172'-174', d: 1.05. Insol in water. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes.
SAFETY PROFILE: Moderately toxic by
some routes. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of NO,. ADF250 CAS: 12788-93-1 ACID BUTYL PHOSPHATE DOT: UN 1718
HR: 3
ACROLEIN
mf: C4H1004P mw: 153.1 PROP: Water-white liquid; sol in alc, acetone, and toluene; insol in water, petroleum, and naphtha. D: 1.120-1.125 @ 250/40°, flash p: 230°F (COC). SYNS: n-BUTYLACID PHOSPHATE 0 BUTYL PHOSPHORIC ACID DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Toxic and corrosive.
Combustible when exposed to heat or flame. When heated to decomposition it emits highly toxic fumes of PO,. See also ESTERS and PHOSPHORIC ACID. ADG250 CAS: 18472-87-2 HR: 3 ACID RED 92 mf: C20H2BrK405*2Na mw: 829.64 PROP: Orange-red crystals or powder. Sol in water and ethanol. SYNS: AIZEN ACID PHLOXINE PB 0 C.I. 45410 0 '2.1. ACID RED 92 0 CYANOSIN 0 CYANOSIN (ACID DYE) 0 CYANOSINE 0 D and C RED NO. 28 0 EOSIN BLUE 0 EOSINE BLUE 0 EOSINE BLUISH 0 FOOD DYE RED No. 104 0 FOOD RED No. 104 0 JAPAN RED 104 0 ORIENT WATER PINK 2 0 PHLOXIN B 0 PHLOXINE B 0 PHLOXINE P 0 RED 104 0 11969 RED 0 RED No. 104 0 3427 VERI PUR PINK CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intravenous route. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits very toxic fumes of Br-, C1-, and NazO. ADJSOO CAS: 260-94-6 HR: 3 ACRIDINE DOT: UN 2713 mw: 179.23 mf: C 1 3 H 9 N PROP: Small, colorless needles or prisms. Mp: 110.5', bp: 346', d: 1.005 @ 19.7'/4', vap press: 1 mm @ 129.4'. Sltly sol in hot water; sol in alc, ether, and CSz. SYNS: 9-AZAANTHRACENE 0
10-AZXANTHRACENE
0 BENZO@)QUINOLINE 0 2,3-BENZOQUINOLINE 0
DIBENZO@,e)PYRIDINE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.2 mg/m3
ADROOO
25
DOT CLASSIFICATION: 6.1; Label: ISEEP
AWAY FROM FOOD SAFETY PROFILE: Poison by ingestion, subcutaneous, and intravenous routes. Mutation data reported. A skin, eye, and mucous membrane irritant. When heated to decomposition it emits toxic fumes of NO,. ADJ550 CAS: 7101-57-7 HR: 3 ACRlDlNE-9-CARBOXAMIDE, N,NDIETHYL-1,2,3,4-TETRAHYDROmf: C 1 8 H 2 2 N 2 0 mw: 282.42 PROP: A liquid. SYNS: ACRIDINE-9-CARBOXAMIDE, 1,2,3,4TETRAHYDRO-N,N-DIETHYL- 0 KETONE, DIETHYLAMINO(l,2,3,4-TETRAHYDRO-9-ACRIDINYL)
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
ADQ6OO CAS: 29023-85-6 HR: 3 4-(9-ACRIDINYL)-2-METHYL-3THIOSEMICARBAZONE ACETONE mfi C I ~ H I ~ N ~ Smw: 322.46 SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO, and SO,. ADROOO CAS: 107-02-8 HR: 3 ACROLEIN DOT: UN 1092 mf: C3H40 mw: 56.07 PROP: Colorless or yellowish liquid; lachrymatoq, disagreeable, choking odor. Mp: -87.7', bp: 52.5', flash p:
26
ADRSOO
ACROLEIN DIMER
PROPENAL (CZECH) 0 2-PROPENAL 0 PROP-2-EN-l0 2-PROPEN-1-ONE PROPYLENE ALDEHYDE 0 RCRA WASTE NUMBER PO03 0 SLIhfICIDE
SYNS: ACROLEIN DIMER, stabilized (DOT) 0 3,4-
AL
DIHYDRO-2H-PYRAN-2-CARBOXALDEHYDE 0 2,3DIHYDRO-1,4-PYRr\N-2-KARF3OXALDEHYD 0 2-
CONSENSUS REPORTS: IARC Cancer
FORMYL-3,4-DIHYDRO-2H-PYRAN 0 5-HEXENAL, 2,6EPOXY- 0 PYRAN ALDEHYDE
Review: Group 3 IMEMDT 7,78,87; Animal Inadequate Evidence IMEMDT 36,133,85; IMEMDT 19,479,79; Human Inadequate Evidence IMEMDT 36,133,85. Community Right-To-Know List. EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 ppm; STEL 0.3 ppm ACGIH TLV: STEL CL 0.1 ppm (skin); Not Classifiable as a Human Carcinogen DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans DOT CLASSIFICATION: 6.1; Label: Poison, Flammable Liquid SAFETY PROFILE: Human poison by inhalation and intradermal routes. Poison experimentally by most routes. Human systemic irritant and pulmonary system effects by inhalation include: lachrymation, delayed hypersensitivity with multiple organ involvement, and respiratory system damage. Severe eye and skin irritant. Experimental reproductive effects. Human mutation data reported. Questionable carcinogen. Dangerous fire hazard when exposed to heat, flame, or oxidizers. An explosion hazard. Incompatible with amines, SOz, metal salts, oxidants, (light + heat). Violent polymerization reaction on contact with strong acid, strong base, weak acid conditions (e.g., nitrous fumes, sulfur dioxide, carbon dioxide), thiourea, or dimethylamine. When heated to decomposition it emits highly toxic fumes; can react vigorously with oxidizing materials. To fight fire, use COZ,dry chemical, or alcohol foam, ADR5OO CAS: 100-73-2 HR: 2 ACROLEIN DIMER DOT: UN 2607 mf: CbHgO2 mw: 112.14 PROP: Liquid, sol in water. D: 1.0775 (20°), bp: 151.3', fp: -lOOo, flash p: 118'F (OC).
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Mildly toxic by ingestion. A skin and severe eye irritant. A flammable liquid when exposed to heat, flame, or powerful oxidizing agents. To fight fire, use alcohol foam and multipurpose dry chemical. When heated to decomposition it emits acrid smoke and fumes.
ADS250 CAS: 79-06-1 HR: 3 ACRY LAMlDE DOT: UN 2074 mf: C3HjNO mw: 71.09 PROP: White, crystalhe solid. Leaflets from (CbHb). Mp: 84.5' f.0.3', bp: 125' @ 25 mm, d: 1.122 @ 30', vap press: 1.6 mm @ 84.5', vap d: 2.45. Very sol in water, alc, and ether. IDLH 60 mg/m3. SYNS: ACRYLIC AMIDE 0 AKRYLAMID (CZECH) 0 AMID KYSELINY AKRYLOVE ETHYLENECARBOXAMIDE PROPENAMIDE 0 2PROPENAMIDE 0 RCRA WASTE NUMBER U007 0 VINYL AMIDE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 39,41,86. EPA Extremely Hazardous Substances List. Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.03 mg/m3 (skin) ACGIH TLV: Animal Carcinogen, TWA 0.03 mg/m3 (skin) DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: TWA 0.3 mg/m3 DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Poison by ingestion, skin contact, and intraperitoneal routes. Experimental reproductive effects. Mutation data reported. A skin and eye irritant.
ACRYLONITRILE
Intoxication from it has caused a peripheral neuropathy, erythema, and peeling palms. In industry, intoxication is mainly via dermal route, next via inhalation, and last via ingestion. Time of onset varied from 1-24 months to 8 years. Symptoms were, via dermal route, a numbness, tingling, and touch tenderness. In a couple of weeks, coldness of extremities; later, excessive sweating, bluish-red and peeling palms, marked fatigue and limb weakness. It is dangerous because it can be absorbed through the unbroken skin. From animal experiments it seems to be a central nervous system toxin. Adult rats fed an average of 30 mg/kg for 14 days were all partially paralyzed and had reduced their food consumption by 50 percent. Polymerizes violently at its melting point. When heated to decomposition it emits acrid fumes and NO,. ADS400 HR: D ACRY LATE-ACRYLAMlDE RESINS SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. ADS750 CAS: 79-10-7 HR: 3 ACRYLIC ACID DOT: UN 2218 mf: C3H402 mw: 72.07 PROP: Lquid with acrid odor. Misc in water, benzene, alc, chloroform, ether, and acetone. Mp: 13O, bp: 141" (polymerizes), d: 1.062, vap press: 10 mm @ 39.9", flash p: 130'F (OC), vap d: 2.45. SYNS: ACROLEIC ACID 0 ACRYLIC ACID, GLACIAL 0 ACRYLIC ACID, inhibited (DOT) 0 ETHYLENECARBOXYLIC ACID 0 GLACIAL ACRYLIC ACID 0 KYSELINA AKRYLOVA 0 PROPENE ACID 0 PROPENOIC ACID 0 2-PROPENOIC ACID (9CI) 0 RCRA WASTE NUiMBER U008 0 VINYLFORMIC ACID
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Human Inadequate Evidence IMEMDT 19,47,79. Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 10 ppm (skin)
ADXSUU
27
ACGIH TLV: 2 ppm (skin); Not Classifiable as a Human Carcinogen DOT CLASSIFICATION: 8; Label:
Corrosive SAFETY PROFILE: Poison by ingestion,
s h n contact, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. A severe skin and eye irritant. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Corrosive. Flammable liquid. May undergo exothermic polymerization at room temperature. May become explosive if confined. A fire hazard when exposed to heat or flame. ADTO50 CAS: 17831-71-9 HR: 2 ACRYLIC ACID, DIESTER with TETRAETHYLENE GLYCOL mf: C14H2207 mw: 302.36 PROP: Photosensitive polyimide resin. SYNS: ACRYLIC ACID, OXYBIS(E,THYLENEOXYETHYLENE) ESTER 0 2-PROPENOIC ACID, OXYBIS(2,lETHANEDIYLOXY-2,l-ETHANE-D1YL)ESTER 0 TETRAETHYLENE GLYCOL DIACRYLATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderate skin and
severe eye irritant. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. ADXSOO CAS: 107-13-1 HR: 3 ACRYLONITRILE DOT: UN 1093 mf: C3H3N mw: 53.07 PROP: Colorless, mobile liquid; mild odor. Mp: -82', bp: 77.3', fp: -83", flash p: 30°F (TCC), lel: 3.1%, uel: 17'/0, d: 0.806 @ 2Oo/4O, autoign temp: 898'F, vap press: 100 mm @ 22.8", vap d: 1.83, flash p: (of 5% aq soh) <50°F. Sol in water. IDLH 85 ppm. SYNS: ACRITET 0 ACRYLNITRIL (GERMAN, DUTCH) 0 ACRYLON 0 ACRYLONITRILE, inhibited (DOT) 0 ACRYLONITRILE MONOMER AKRYLONITRYL (POLISH) 0 CARBACRYL 0 CIANURO di VINILE (ITALIAN) 0 CYANOETHYLENE 0 CYANURE de VINYLE (FRENCH) 0 ENT 54 0 FUMIGRAIN 0
28
ADY500
ACRYLONITRILE POLYMER with STYRENE
MILLERS FUbfIGRAIN 0 NITRILE ACRILICO (ITALIAN) 0 NITRILE ACRYLIQUE (FRENCH) 0 PROPENENITRILE 0 2-PROPENENITRILE 0 RCRA WASTE NUUhIBER COO9 0 TL 314 0 V C S 0 VENTOX 0 VINYL CYANIDE 0 VINYLKYANID
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 2A IMEMDT 7,79,87; Human Limited Evidence IMEMDT 19,73,79; Animal Limited Evidence IMEMDT 19,73,79. Community Right-To-Know List. EPA Extremely Hazardous Substances Lst. Reported in EPA TSCA Inventory. OSHA PEL: TWA 2 ppm; CL 10 ppm/l5M; Cancer Hazard ACGIH TLV: TVG’A 2 ppm (skin), Confirmed Animal Carcinogen. DFG MAK: DFG TRIG Animal Carcinogen, Suspected Human Carcinogen NlOSH REL: TWA 1 ppm; CL 10 ppm/l5M DOT CLASSIFICATION: 3; Label: Flammable Liquid, Poison SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by inhalation, ingestion, skin contact, and other routes. Human systemic effects by inhalation and s h n contact: conjunctiva irritation, somnolence, general anesthesia, cyanosis, and diarrhea. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. Dangerous fire hazard when exposed to heat, flame, or oxiduers. Moderate explosion hazard when exposed to flame. Can react vigorously with oxidizing materials (see also CYANIDE). Acrylonitrile closely resembles hydrocyanic acid in its toxic action. By inhibiting the respiratory enzymes of tissue, it renders the tissue cells incapable of oxygen absorption. Poisoning is acute; there is little evidence of cumulative action on repeated exposure. Exposure to low concentration is followed by flushing of the face and increased salivation; further exposure results in irritation of the eyes and nose, photophobia, deepened respiration. If exposure continues, shallow respiration,
nausea, vomiting, weakness, an oppressive feeling in the chest, and occasionally headache and diarrhea are other complaints. Several cases of mild jaundice accompanied by mild anemia and leucocytosis have been reported. Urinalysis is generally negative, except for an increase in bile pigment. Serum and bile thocyanates are raised. See also HYDROCYANIC ACID. Unstable and easily oxidued. Explosive polymerization may occur on storage with silver nitrate. Potentially explosive reactions with benzyltrimethylammonium hydroxide + pyrrole, tetrahydrocarbazole + benzyltrimethylammonium hydroxide. Violent reactions with strong acids (e.g., nitric or sulfuric), strong bases, azoisobutyronitrile, &benzoyl peroxide, ditert-butylperoxide, or bromine. Incompatible with AgN03 and amines. To fight fire, use C02, dry chemical, or alcohol foam. When heated to decomposition it emits toxic fumes of NO, and CN-. See also NITRILES and CYANIDE. ADY5OO CAS: 9003-54-7 HR: 3 ACRYLONITRILE POLYMER with STYRENE mf: (CsHs*C3H3N), SYNS: ACRILAFIL 0 ACRYLOKITRILE-STYRENE COPOLYMER 0 ACRYLONITRILE-STYRENE POLYMER 0 ACRYLONITRILE-STYRENE RESIN 0 ACS 0 AS GlCL 0 BAKELITE RMD 4511 0 CEVIAN HL 0 DIALUX 0 ESTYRENE AS 0 KOSTIL 0 LITAC 0 LURAN 0 LUSTRAN POLYSTYRENE-ACRYLONITRILE 0 2PROPENENITRILE POLYMER with ETHENYLBENZENE 0 REXENE 106 0 SANREX 0 SN 20 0 STYREKACRYLONITRILEPOLYMER 0 STYRENEACRYLONITRILE COPOLYhiER 0 TERULAN KP 2540 TYRIL
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Human No Adequate Data IMEMDT 19,73,79; Animal No Adequate Data IMEMDT 19,73,79. Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community RtghtT o - K ~ o wList. SAFETY PROFILE: Moderately to hghly toxic by ingestion. Questionable carcinogen.
ADlPlC ACID
See also NITRILES. When heated to decomposition it emits toxic fumes of NO, and CN-. AEB750 CAS: 102488-99-3 HR: 3 ACTINOMYCIN L SYN: ACTINOMYCIN 2104L CONSENSUS REPORTS: IARC Cancer
Review: Animal Sufficient Evidence IMEMDT 10,29,76. SAFETY PROFILE: Confirmed carcinogen with experimental neoplastigenic data. AECOOO CAS: 12623-78-8 ACTINOMYCIN S
HR: 3
SYN: ACTINOMYCIN 1048A CONSENSUS REPORTS: IARC Cancer
Review: Animal Limited Evidence IMEMDT 10,29,76; No Adequate Data IMEMDT 10,29,76. SAFETY PROFILE: Suspected carcinogen with experimental neoplastigenic data. AED250 CAS: 665-66-7 HR: 3 1-ADAMANTANAMINE HYDROCHLORIDE mf: CloHt7N*ClH mw: 187.74 PROP: Crystals from EtOH/EtzO. Sol in water and ethanol; prac insol in Et2O. SYNS: ADAMANTANAMINE HYDROCHLORIDE 0 ADAMANTINE HYDROCHLORIDE 0 ADAMANTYLAMINE HYDROCHLORIDE 0 1-ADAMANTYI-AMINE HYDROCHLORIDE 0 AMANTADINE HYDROCHLORIDE 0 XMAZOLON 0 AMINO-ADAMANTANE HYDROCHLORIDE 0 1-AMINO-ADAMANTENE HYDROCHLORIDE 0 EXP 105-1 0 MANTADAN 0 NSC
AEN250
29
decomposition it emits very toxic fumes of NO, and HC1. AEHOOO CAS: 73-24-5 HR: 3 ADENINE mf: CsHsNs mw: 135.15 PROP: Needles. Mp: 360-365' (anhyd) decomp. SYNS: ADENINIMINE 0 6-AiMINOPURINE 0 6AMINO-1H-PURINE 0 6-AMINO-3H-PURINE 0 6AMINO-9H-PURINE 0 1,6-DIHWRO-6-II\IINO-PURINE 0 3,6-DIHYDRO-6-IMINOPURINE 0 LEUCO-4 0 1HPURIN-6-AMINE 0 USAF CB-18 0 VITAiMIN B4
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. An experimental teratogen. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
AENOOO CAS: 628-94-4 HR: 2 ADlPAMlDE mf: C6H12N202 mw: 144.20 PROP: Crystals. Mp: 220'. Sol in alc. SYNS: ADIPIC ACID DIAMIDE
0 ADIPIC DIAMIDE 0 1,4-BUTANEDICARBOXAMIDE 0 HEXANEDIAMIDE (9Cr) NCI-C02095
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits toxic fumes of NO,.
83653 0 SYMMETREL 0 TRICYCLO(3.3.1.1.(3,7))DECANt-A;CIINE, HYDROCHLORIDE (9CI) 0 VIROFRAL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Human poison by ingestion. Poison by ingestion, intraperitoneal, and intravenous routes. A human teratogen with developmental abnormalities of the circulatory system. Experimental reproductive effects. Human systemic effects by ingestion: distorted perceptions, euphoria, excitement, hallucinations. When heated to
AEN250 CAS: 124-04-9 HR: 3 ADlPlC ACID mf: C6H1004 mw: 146.16 PROP: White monochic prisms. Mp: 152', flash p: 385'F (CC), d: 1.360 @ 25'/4", vap press: 1 mm @ 159.5', vap d: 5.04, autoign temp: 788'F, bp: 337.5'. Very sol in alc. Sol in acetone, water = 1.4% @ 15'; 0.6% @ 15' in ether. SYNS: ACIFLOCTIN 0 ACINEWEN 0 ADILACTETTEN 0 ADIPINIC ACID 0 1,4BUTANEDICARBOXYLIC ACID n FEMAN ~201 . 1
t ,6-
30 AEOOOO ADlPlC ACID BIS(2-ETHYLHEXYL) ESTER HEWNEDIOIC ACID 0 KYSELINA ADIPOVA (CZECH) 0 MOLTEN ADIPIC ACID
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. ACGIH TLV: TWA 5 mg/3 SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by other routes. A severe eye irritant. Combustible when exposed to heat or flame; can react with oxidzing materials. When heated to decomposition it emits acrid smoke and fumes. AEOOOO CAS: 103-23-1 HR: 2 ADlPlC ACID BIS(2-ETHYLHEXYL) ESTER mf: C22H4204 mw: 370.64 PROP: Liquid. D: 0.927 @ 20'/4', bp: 181-185' @ 2 mm. SYNS: ADIPOL 2EH 0 BEHA 0 BIS(2-ETHYL-HEXYL) ADIPATE 0 BISOFLEX DOA 0 DEHA 0 DI-2ETHYLHEXYL ADIPATE 0 DIOCTYL ADIPATE 0 DOA 0 EFFEMOLL DOA 0 ERGOPUST AdDO 0 FLEXOL A 26 0 HEXANEDIOIC ACID, BIS(2-ETHYL-HEXYL) ESTER 0 HEXANEDIOIC ACID, DIOCTYL ESTER 0 KODAFLEX DOA 0 MONOPLEX DOA 0 NCIG4386 0 OCTYL ADIPATE 0 PUSTOMOLL DOA 0 PX-238 0 REOMOL DOA 0 RUCOFLEX PLASTICIZER DOA 0 SICOL 250 0 TRUFLEX DOA 0 VESTINOL OA 0 WICKENOL 158 0 W'ITAMOL 320 CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 29,257,82. NTP Carcinogenesis Bioassay (feed); Clear Evidence: mouse NTPTR" NTP-TR-212,82; No Evidence: rat NTPTR* NTP-TR212,82. Community Right-To-Know List. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by intravenous route. Mildly toxic by ingestion. Experimental reproductive effects. Mutation data reported. An eye and s h n irritant. Questionable carcinogen with experimental carcinogenic data. See also ESTERS. When heated to decomposition it emits acrid smoke and irritating fumes.
AE0750 CAS: 105-99-7 HR: 2 ADlPlC ACID DIBUTYL ESTER mf: C14H2604 mw: 258.40
PROP: Clear liquid. Mp: -20°, bp: 149', d:
0.960. Flash Pt.: 155'. Insol in water. SYNS: BUTYL. ADIPATE 0 DIBUTYL ADIPATE 0 DIN-BUTYL ADIPATE 0 DIBUTYL ADIPINATE 0 DIBUTYL HEXANEDIOATE 0 EXPERIMENTAL TICK REPELLENT 3 0 HEXANEDIOIC ACID-DIBUTYL ESTER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by several routes. An experimental teratogen. Skin and eye irritant. See also ESTERS. A combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
AER250 CAS: 111-69-3 HR: 3 ADlPONlTRlLE DOT: UN 2205 mf: C6HgN2 mw: 108.16 PROP: Water-white liquid; practically odorless. Mp: 2.3', bp: 295', flash p: 199.4'F (OC), d: 0.965 @ 20°/4", vap d: 3.73. Sol in EtOH, CHCl3; insol in HzO, Et20, CS2. SYNS: ADIPIC ACID DISITRILE 0 ADIPIC ACID NITRILE 0 ADIPODINITRILE 0 1,4-DICYANOBUTXNE 0 HEXANEDINITRILE 0 HEXANEDIOIC ACID DINITRILE 0 NITRILE ADIPICO (ITALIAN) 0 TETRAMETHYLENE CYANIDE CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community RightTo-Know List. ACGIH TLV: TWA 2 ppm (skm) NIOSH REL: TWA 18 mg/m3 DOT CLASSIFICATION: 6.1; Label: I a E P AWAY FROM FOOD SAFETY PROFILE: Poison by inhalation, ingestion, subcutaneous, and intraperitoneal routes. The nitrile group wdl behave as a cyanide when ingested or absorbed in the body. It produces disturbances of the respiration and circulation, irritation of the stomach and intestines, and loss of weight. Its low vapor pressure at room temperature makes exposure to harmful concentrations of its vapors unlikely if handled with reasonable care in well-venulated areas.
AFLATOXIN 82 AEU750
Flammable when exposed to heat or flame. When heated to decomposition it emits toxic fumes of CN-. Can react with oxidizing materials. To fight fire, use foam, C02, dry chemical. See also HYDROCYANIC ACID and NITRILES. AES750 CAS: 23214-92-8 HR: 3 ADRIAMYCIN mf: C27H29NOlt.ClH mw: 543.57 PROP: Isolated from cultures of Streptomyces peucehus vac Caesius.
31
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 7,83,87; Human Sufficient Evidence IMEMDT 7,83,87; Animal Sufficient Evidence IMEMDT 7,83,87 SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic data. Human poison by ingestion. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also various aflatoxins.
SYNS: AD&$0 ADRIAMYCIN-HCI 0 ADRIAMYCIN SEMIQUINONE 0 ADRIBLASTINA 0 DOXO-RUBICIN 0 DX 0 F.1 106 0 14-HYDROXYDAUNO-MYCIN 0 14'HYDROXYDAUNOMYCIN 0 14-HYDROXYDAUNORUBICINE 0 KW-125 0 NCI-C01514 0 NSC-123127
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2A IMEMDT 7,82,87; Animal Sufficient Evidence IMEMDT 7,82,87; Human Inadequate Evidence IMEMDT 7,82,87. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal, subcutaneous, parenteral, and intravenous routes. Human systemic effects by intravenous route: cardiac myopathy including infarction, nausea or vomiting, and effects on the hair. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and HC1.
AET6OO CAS: 116425-35-5 HR: 3 AERUGIDIOL mE Ct5H2203 mw: 250.34 SYN: G(lH)-AZULENONE, 2,3,3A,7,8,8A-HEXr\HYDRO1,3A-DIHYDROXY-l,4-DIMETHYL7-(1 -METHYLETHYL1DENE)-, (lS,3AR,8AR)-
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors.
AET750 CAS: 1402-68-2 HR: 3 AFLATOXIN PROP: Colorless to pale yellow crystals.
AEU250 CAS: 1162-65-8 HR: 3 AFLATOXIN B1 mf: Ct7H1206 mw: 312.29 PROP: A crystalline material. Mp: 268'. SYNS: AFBI 0 AFLATOXIN B CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 7,83,87; Animal Sufficient Evidence IMEMDT 10,51,76; 1,145,72. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic, neoplas tigenic, and carcinogenic data. Acute poison by ingestion, intraperitoneal, and possibly other routes. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits acrid smoke. See also various aflatoxins. AEU750 CAS: 7220-81-7 AFLATOXIN 8 2 mf: C17H1406 mw: 314.31 PROP: Yellow crystals with blue fluorescence from MeOH.
HR: 3
SYN: DIHYDROAFLATOXINB1 CONSENSUS REPORTS: IARC Cancer
Review: Animal Sufficient Evidence IMEMDT 10,51,76; Animal Limited Evidence IMEMDT 1,145,72. SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic data. Poison by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and fumes. See also various aflatoxins.
32 AEVOOO AFLATOXlN Gl AEVOOO CAS: 1165-39-5 HR: 3 AFLATOXIN G1 mf: C17H1207 mw: 328.29 PROP: Needles from MeOH exhibiting green fluorescence. Mp: 247-250'. Metabolite of Aspetgiillzlssflavzls link exfies. CONSENSUS REPORTS: IARC Cancer Review: Animal Sufficient Evidence IMEMDT 10,51,76. SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic and neoplastigenic data. Poison by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also various aflatoxins. AEV250 HR: 3 AFLATOXIN G1 mixed with AFLATOXIN B1 PROP: Metabolites of Aspetgihsflavzls link exfnes, Aflatoxin G1, 56.4%; Alfatoxin B1, 37.7%. SAFETY PROFILE: Confirmed human carcinogen with experimental carcino-genic, neoplastigenic, and tumorigenic data. See also various aflatoxins. AEWOOO CAS: 6795-23-9 HR: 3 AFLATOXIN M1 mf: C17H1207 mw: 328.29 PROP: Crystals from MeOH exhbiting blue-violet fluorescence. Mp: 299' (decomp). SYN: 4-HYDROXYAFLATOXINB1 CONSENSUS REPORTS: IARC Cancer
Review: Group 2B; Animal Sufficient Evidence IMEMDT 10,51,76; Animal Sufficient Evidence IMEMDT 56,245,93; Human Inadequate Evidence IMEMDT 56,245,93. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. Poison by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also various aflatoxins.
AEW5OO CAS: 29611-03-8 HR: 2 AFLATOXIN Ro mf: C17H1406 mw: 314.31 PROP: Crystals from Cs&/hexane. Mp: 224-226'. SYNS: AFL 0 AFLATOXICOL 0 AFLATOXICOL NATURAL EPIMER SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also various aflatoxins.
AEX250 CAS: 9002-18-0 HR: 1 AGAR PROP: Extracted from the red algae Rhodop_yyceae.Unground: in thin, translucent, membranous strips; ground: pale buff powder. Sol in boiling water; insol in cold water and org solvs. SYNS: AGAR-AGAR 0 AGAR AGAR FLAKE 0 AGARAGAR GUM 0 BENGAL GELATIN 0 BENGAL ISINGLASS 0 CEYLON ISINGLASS 0 CHINESE ISINGLASS 0 DIGENEA SIMPLEX hlUCILAGE 0 GELOSE 0 JAPAN AGAR 0 JAPAN ISINGLASS 0 LAYOR CARANG 0 NCI-C50475 CONSENSUS REPORTS: NTP Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NTPTR* NTP-TR230,82. Reported in EPA TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion. When heated to decomposition it emits acrid smoke and fumes.
AEX850 CAS: 644-06-4 HR: 2 AGERATOCHROMENE mf: C13H1603 mw: 220.29 PROP: Pale-yellow needles from MeOH or oil. Mp: 49-50', bp: 145-150' at 4 mm. SYNS: 2H-1-BENZOPYRAN, 6,7-DIhlETHOXY-2,2DIMETHYL- 0 6,7-DIMETHOXY-2,2-DIivfETHYL-2HBENZO@)PYRAN 0 PRECOCENE 2 0 PRECOCENE I1 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Questionable carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
ALDACTAZIDE
-AFG250 HR: 2 AIR, refrigerated liquid DOT: UN 1002/UN 1003 PROP: Bluish, mobile liquid. 0 2 + Nz. Bp: -189' (lid;flash p: none; autoign temp: none. SYNS: AIR, compressed (UN 1002) (DO? 0 AIR, refrigerated liquid (cryogenicliquid) (UN 1003) (DOq 0 AIR, refrigerated liquid (cryogenicliquid) non-pressuized (UN 1003) (DO? DOT CLASSIFICATION: 2.2; Label:
Nonflammable Gas, Oxidizer (UN 1003); DOT Class: 2.2; Label: Nonflammable Gas (UN 1002); DOT Class: Nonflammable Gas; Label: Nonflammable Gas. SAFETY PROFILE: Lquid air can cause tissue damage due to low temperature. Personnel exposed to compressed air may develop caisson disease (the bends, the chokes) if decompression is too rapid. Moderate explosion hazard when containers under pressure are shocked or exposed to heat or flame. Flammable materials, e.g., ethyl ether, hydrocarbons, or charcoal, which have been in contact with liquid air may explode very easily. Ordmary oxidation is greatly accelerated in compressed air. Moderately dangerous disaster hazard; can react vigorously with reducing materials. AFH400 CAS: 3011-89-0 HR: D AKLOMIDE mf: C7H5CIN203 mw: 200.60 PROP: Crystals and gray scales from alc. Mp: 172'.
33
CONSENSUS REPORTS: Reported in
EPA TSCA Inventory. SAFETY PROFILE: Mutation data
reported. When heated to decomposition it emits toxic fumes of NO,. AF1850 CAS: 70536-17-3 HR: 3 ALBUMIN MACRO AGGREGATES SYNS: ALBUMIN 0 MAA SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it
emits acrid smoke and irritating fumes. AFJOOO HR: 3 ALCOHOL, DENATURED DOT: NA 1986/NA 1987 PROP: Liquid. Composed of alcohol and denaturants. SYNS: DENATURED ALCOHOL (DO? 0 DENATURED SPIRITS DOT CLASSIFICATION: 3; Label: Flammable Liquid (NA 1987); DOT Class: 3; Label: Flammable Liquid, Poison (NA 1986) SAFETY PROFILE: Potentially poisonous by ingestion. Toxicity depends upon alcohols in question, generally ethanol with methanol as a denaturant. A flammable liquid and dangerous fire hazard; can react vigorously with oxidzing materials. Moderate explosion hazard. See ETHANOL, METHYL ALCOHOL, and n-PROPYL ALCOHOL.
AFJ5OO CAS: 52-01-7 SYNS: AKLOMIX 0 ~-CHLORO-~-NITROBENZALMIDE ALDACTAZIDE SAFETY PROFILE: When heated to
decomposition emits toxic fumes of C1- and NO,.
AFJSOO
HR: 3
mf: C24H3204S mw: 416.62 PROP: Crystals. Mp: 134-135'. SYNS: 7-a-ACETYLTHIO-3-OXO-17-a-PREGN-4-ENEPl,l?-P-CARBOLACTONE 0 7-a-ACETYLTHIO-3-0x0-
AFH625 CAS: 56-41-7 HR: D I-ALANINE mf: C3H7N02 mw: 89.09 PROP: White crystalline powder; odorless with a sweet taste. Mp: 297' (decomp). Sol in water; insol in EtOH. SYNS: ALANINE 0 a-ALANINE 0 I-(+)-AMNINE 0 1a-ALANINE 0 (S)-ALANINE 0 1-2-AMINO-PROPANOIC ACID 0 (S)-2-AMINOPROPANOICACID 0 aAMINOPROPIONIC ACID
17-P-PREGN-4-ENE-21,17-P-CARBOLACTONE 0 ALDACTIDE 0 ALDACTONE 0 ALDACTONE A 0 3-(3-
KETO-7-a-ACETYLTHIO-17-P-HYDROXY-4ANDROSTEN-17-a-YL)PROPIONIC ACID LACTONE 0 OSIREN 0 OSYROL 0 3'-(3-OXO-?-a-ACETYL-THIO-17j3-HYDROXYANDROST-4-EN-l?-~-YL)PRO-PIONIC ACID LACTONE 0 17-a-PREGN-4-ENE-21-CARBOXYLIC ACID, 1-HYDROXY-7-a-MERCAPTO-3-OXO-a-LACTONE 0 SC 9420 0 SC 15983 0 SPIRESIS 0 SPIRIDON 0 SPIROCTANIE 0 SPIRO(17H-
CYCLOPENTA(a)PHENANTHRENE-l7,2'-(3'H)-FURAN) 0
34 AFJ700
ALDEHYDE C-I0 DIMETHYLACETAL
SPIRO(l7H-CYCLOPENTA(a)PHENAN-THRENE17,2'(5'H)FURAN),PREGN-4-ENE-21-CARBOXYLICACID DERIV. 0 SPIROLACTONE 0 SPIROLAKTON 0 SPIROL4NG 0 SPIROXE 0 SPIRONOLACTONE 0 SPIROSOLACTONE A n URACTONE VEROSPIRON 0 VEROSPIRONE
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,344,87; Animal Limited Evidence IMEMDT 24,259,80; Human Inadequate Evidence IMEMDT 24,259,80. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Human reproductive effects by ingestion and possibly other routes: men, impotence and breast development; women, menstrual cycle changes or disorders, changes in the breasts and lactation. An experimental teratogen. Other experimental reproductive effects. Other human systemic effects by ingestion: agranulocytosis, kidney tubule damage, increased urine volume, and changes in blood sodium and calcium levels. Questionable carcinogen. When heated to decomposition it emits toxic fumes of SO,. Used to treat hypertension, edema of congestive heart failure, cirrhosis, and kidney failure.
production of acetaldehyde in 1982 was 281,000 tons. The world production of acrolein in 1975 was 59,000 tons. Aldehydes occur in nature and are gaseous by-products of incomplete combustion of wood and coal, in exhaust from gasoline and diesel engines, industrial waste gases and fumes, tobacco smoke, and wood fires. Formaldehyde and acetaldehyde are carcinogens. Many of the aldehydes are mutagens. They are reactive compounds participating in oxidation, reduction, addtion, and polymerization reactions. All the aldehydes possess anesthetic properties, but this is obscured by their highly irritating action on the eyes and mucous membranes of the respiratory tract. The lower aldehydes, very soluble in water, act chiefly on the eyes and tissues of the upper respiratory tract. The higher aldehydes, less soluble in water, tend to penetrate more deeply into the respiratory system and may affect the lungs. Some hgher aldehydes and also the aromatic aldehydes may exhbit much lower toxicity. See also specific compounds.
AFJ700 CAS: 7779-41-1 HR: 1 ALDEHYDE C-10 DIMETHYLACETAL mf: C 1 2 H 2 6 0 2 mw: 202.38 PROP: Fragrance ingredient.
AFK250 CAS: 309-00-2 HR: 3 ALDRIN DOT: UN 2761/NA 2762 mf: C12HaC16 mw: 364.90 PROP: Crystals. Mp: 104-10S0. Sol in Me2C0, C&h,; sldy sol in pet ether; almost insol in H20. IDLH 25 mg/m3.
SYNS: DECANAL, DIbIETHYLACETAL 0
SYNS: ALDREX 0 ALDREX 30 0 ALDRIX, cast sohd
DECYLALDEHYDE DMA 0 1,l-DIMETHOXY-DECANE 0 10,lO-DIMETHOXYDECANE
(DOq 0 ALDRINE (FRENCH) 0 ALDRITE 0 ALDROSOL 0 ALTOX 0 COMPOUND 118 0 DRINOX 0 ENT 15,949 0 HEXACHLORO-HEXAHYDRO-endo-exoDIMETHANONAPHTHAL-ENE 0 1,2,3,4,10,10HEX4CHLORO- 1,4,4a,j,8,Sa-HEX4HMR0-1,4,5,8DIMETHANONAPHTHALENE 0 1,2,3,4,10,10-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A shn irritant. When
heated to decomposition it emits acrid smoke and irritating fumes. AFJ800 HR: 2 ALDEHYDES PROP: A class of chemicals with the general formula R*CHO, and characterized by an unsaturated carbonyl group (C=O). SAFETY PROFILE: Aldehydes are widely used in many industrial processes. The US
HEXACHLORO-1,4,4a,5,8,8a-HEXAHYDRO-1,4-endo-exo5,s-DIMETHANO-NAPHTHALENE 0 1,2,3,4,10,10HEXACHLORO-l,4,4a,5,8,8a-HEXAHYDRO-exo-l,4,-endo5&DIMETHANONAPHTMLENE 0 HHDN 0 NCICOO044 0 OCTALENE 0 RCRA WASTE NUMBER PO04 0 SEEDRIN
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,88,87; Human Inadequate Evidence IMEMDT 5,25,74; Animal Inadequate Evidence IMEMDT 5,25,74; NCI Carcinogenesis
ALLETHRIN
Bioassay (feed); Clear Evidence: mouse NCITR* NCI-CG-TR-21,78; Inadequate Studtes: rat NCITR* NCI-CG-TR-21,78. EPA Genetic Toxicology Program. EPA Extremely Hazardous Substances List. Community kght-To-Know Lst. OSHA PEL: TWA 0.25 mg/m3 (skin) ACGIH TLV: TWA (inhalable fraction) 0.05 mg/m3; (skm); Confirmed Animal Carcinogen with Unknown Revelance to Humans DFG MAK: 0.25 mg/m3 NIOSH REL: (Aldrin) Reduce to lowest detectable level DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by ingestion, skin contact, intravenous, and intraperitoneal routes. Human systemic effects by ingestion: excitement, tremors, and nausea or vomiting. An experimental teratogen. Other experimental reproductive effects. Continued acute exposure causes liver damage. Human mutation data reported. See also CHLORINATED HYDROCARBONS. When heated to decomposition it emits toxic fumes of Cl-. AFK925 HR: D ALGAE MEAL, DRIED PROP: Mixture of algae cells from Spongiococctlm,molasses, corn steep liquor, and a maximum of 0.3% ethoxyquin. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. AFLOOO CAS: 9005-32-7 HR: 2 ALGlNlC ACID PROP: Extracted from brown seaweeds. m t e to yellow white fibrous powder; odorless and tasteless. Sol in alkaline solutions; insol in org solvs. SYNS: KELACID 0 LANDALGINE 0 NORGINE 0 PLOYMANNURONIC ACID 0 SAZZIO
AFR250
35
SAFETY PROFILE: Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating fumes.
AFM250 HR: 3 ALIPHATIC and AROMATIC EPOXIDES SAFETY PROFILE: Suspected carcinogen with experimental tumors of the skin, lung, and blood-forming tissues. AFMSOO HR: 1 ALKALIES PROP: A term loosely applied to the hydroxides and carbonates of the alkali metals and alkaline earth metals, as well as the bicarbonate and hydroxide of ammonium. They can neutralize acids, change the color of indtcators, and impart a soapy taste and feel to aq s o h . SAFETY PROFILE: Variable toxicity. As a group, they constitute the commonest causes of contact dermatitis. Systemically ammonia is most troublesome. See also AMMONIA. See also specific compound. AFN250 HR: 2 ALKANES PROP: All colorless neutral liquids with light odors. See also indtvidual alkanes as listed (n-pentane, n-hexane, n-heptane, n-octane). SAFETY PROFILE: Hexane can cause neuropathy with chronic exposure. Other alkanes or mixtures may have the same effect. Many are dangerous fire hazards when exposed to flame, heat, or oxidzers. AFR250 CAS: 584-79-2 ALLETHRIN mfi C19H2603 mw: 302.45 PROP: A viscous liquid.
HR: 3
SYNS: (+)-ALLELRETHONYL (+)-cis,trans-CHRYSANTHEMATE 0 d-ALLETHRIN 0 d-trans ALLE-THRIN 0 ALLETHRIS I 0 ALLEVIATE 0 ALLYL CINERIPI’ 0 ALLYL HOMOLOG of CINERIN I 0 dJ-2-ALLYL-4HYDROXY-3-METHYL-2-CYCLOPENTENTEN-l-ONE-d,1CHRYSANTHEMUM MONOCARBOXYLATE 0 3-ALLYL-
CONSENSUS REPORTS: Reported in EPA
4-KETO-2-METHYLCYCLOPENTENYL CHRYSAN-
TSCA Inventory.
THEMUMMONOCARBOXYIATE 0 3-ALLYL-2METHYL-4-0x0-2-CYCLOPENTEN-1 -YL
36
AFS800
ALLO-GLAUCOTOXIGENIN
CHRYSANTHEMATE 0 dl-3-ALLYL-Z-METHYL-4OXOCYCLOPENT-2-ENYL dl-as mans CHRYSAXTHEMATE 0 ALLYLRETHRONYL.dl-as-transCHRYSANTHEMATE 0 BIOALLETHRIN 0 BIOALTRINA 0 CINERIN I ALLYL HOMOLOG 0 DEPALLETHRIN 0 ENT 17,510 0 EXTHRIN 0 FDA 1446 0 FMC 249 0 NECARBOXYLIC ACID 0 NIA 249 0 OMS 468 0 PALLETHRINE 0 PYNAMIN 0 PYNAMIN-FORTE 0 PYRESIN 0 PYRESYN 0 SYNTHETIC PYRETHRINS
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intravenous, intracerebral, and intraperitoneal routes. Moderately toxic by ingestion and skin contact. An allergen. An insecticide. It can cause liver and kidney damage by all routes of entry into the body. Lung congestion may occur due to exposure. Local contact may cause contact dermatitis. Inhalation may cause asthma, coughing, wheezing, running nose and eyes. Mutation data reported. See also ALLYL COMPOUNDS and ESTERS. Slight fire hazard. When heated to decomposition it emits acrid fumes.
AFS800 CAS: 14155-65-8 ALLO-GLAUCOTOXIGENIN mf: C 2 & 2 0 6 mw: 404.55
HR: 3
SYNS: ALLOGLXCOTOXIGENIN 0 ALLOGLUCOTOXIGENIN 0 S-a-CARD-20(22)ENOLIDE, 3-P,14,15-P-TRIHYDROXY-19-OXO0 CARD(3-P,520(22)-ENOLIDE, 19-OXO-3,14,1S-TRIHYDROXI-, a,lj.p)- 0 (3-P,5-a,l5-P)-19-OXO-3,14,15-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
intraperitoneal, intravenous, subcutaneous, and rectal routes. Moderately toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Produces dlabetes in experimental animals. Decomposes in storage to release C O 2 . Do not store in sealed container. Explodes when heated above 170'C. When heated to decomposition it emits toxic fumes of NO,. AFU750 CAS: 591-87-7 HR: 3 ALLYL ACETATE DOT: UN 2333 mf: C 5 H ~ 0 2 mw: 100.13 PROP: Liquid. Vap d: 3.45, bp: 103-104', d: 0.928, flash p: 72'F. Insol in water. SYNS: ACETIC ACID ALL%
ESTER ACETIC ACID2-PROPENYL ESTER 0 3-ACETOXWROPENE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid, Poison SAFETY PROFILE: Poison by ingestion. Moderately toxic by inhalation and s h n contact. A skin and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes. Dangerous fire hazard. See also ALLYL COMPOUNDS.
TRIHYDROXYCARD-20(22)-ENOLIDE
SAFETY PROFILE: A poison by intravenous route. When heated to decomposition it emits acrid smoke and irritating vapors.
AFT750 CAS: 50-71-5 HR: 3 ALLOXAN mf: C 4 H 2 N 2 0 4 mw: 142.08 PROP: Orthorhombic crystals from AcOH or by subl. Mp: 256' (decomp), d: 1.70. Sol in water, alc, benzene, and acetone. SYNS: MESOXALYLCARBAMIDE 0 MESOXALYLUREA 0 2,4,5,6(lH,3H)PYRIMIDINETETRONE 0 2,4,j,6-PYRIhlIDINTETRON (CZECH) 0 2,4,5,6TETRAOXOHEXAHYDROPYRIMIDINE
AFVSOO CAS: 107-18-6 HR: 3 ALLYL ALCOHOL DOT: UN 1098 mf: C 3 H 6 0 mw: 58.09 PROP: Limpid liquid; pungent odor. Mp: -129', fp: -50°, bp: 96-97', lel: 2.5%, uel: l8%, flash p: 70°F (CC), d: 0.854 @ 20°/4', autoign temp: 713'F, vap press: 10 mm @ 10.5', vap d: 2.00. MISCin water, alc, and ether. IDLH 20 ppm. SYNS: ALCOOL ALLILCO (ITALIAN) 0 ALCOOL ALLYLIQUE (FRENCH) 0 ALLILOWY ALKOHOL (POLISH) 0 ALLYL AL 0 ALLYLALKOHOL (GERMAN) 0 ALLYLIC ALCOHOL 0 3-HYDROXY-PROPENE 0 ORVINYLCARBINOL 0 PROPENOL 0 PROPEN-1-OL-3 0 1-PROPEN-3-OL 0 2-PROPEN-1-OL 0 PROPENYL
p-ALLYLANISOLE ALCOHOL 0 2-PROPENYL ALCOHOL 0 RCRA WASTE NUM3ER PO05 0 SHELL UNDRAUTTED A VINYLCARBINOL 0 WEED DRENCH
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 2 ppm; STEL 4 ppm (skin) ACGIH TLV: 0.5 ppm (skin); Not Classifiable as a Human Carcinogen DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans DOT CLASSIFICATION: 6.1; Label: Poison, Flammable Liquid SAFETY PROFILE: Suspected carcinogen. Poison by inhalation, ingestion, skin contact, subcutaneous, intraperitoneal, and possibly other routes. A slim, severe eye (human), and systemic irritant. Mutation data reported. Dangerous fire and explosion hazard when exposed to heat, flame, or oxidizers. Explosive or violent reaction with sulfuric acid, alkali + 2,4,6-trichloro-1,3,5triazine, or 2,4,6-tris(bromoamino)-1,3,5triazine. Reaction with carbon tetrachloride produces explosively unstable halogenated C4 epoxides. Incompatible with chlorosulfonic acid, HN03, H2S04, oleum, NaOH, dally1 phosphte, PC13, and tri-nbromomelamine. When heated to decomposition it emits acrid smoke and fumes. To fight fire, use COz, alcohol foam, dry chemical. See also ALLYL COMPOUNDS.
AFWOOO CAS: 107-11-9 HR: 3 ALLY LAMlNE DOT: UN 2334 mf: C3H7N mw: 57.11 PROP: Colorless liquid, burning taste, sharp ammonia odor. Bp: 56-5-58', d: 0.761 @ 20'/4', flash p: -20'F, autoign temp: 705'F, vap d: 2.00, lel: 2.2%, uel: 22%. Misc in water, alc, and ether. SYNS: 3-AMINOPROPENE 0 3-AMINOPROPYLENE 0 MONOALLYLAMINE 0 2-PROPENAMINE 0 2-PROPEN1-AMINE
AFW750
37
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison, Flammable Liquid SAFETY PROFILE: Poison by inhalation, ingestion, intraperitoneal, and skm contact routes. Human systemic effects by inhalation: lacrymation and lung effects. A systemic irritant. Mutation data reported. A severe eye and skin irritant. Extraordnary precautions against fumes are advised. Dangerous fire and explosion hazard when exposed to heat, flame, or oxidzers. Highly reactive. When heated to decomposition it emits toxic fumes of NO,. To fight fire, use alcohol foam, C02, dry chemical. See also ALLYL COMPOUNDS and AMINES.
AFW750 CAS: 140-67-0 HR: 2 p-ALLYLANISOLE mf: C1oH120 mw: 148.22 PROP: Isolated from rind of Persea Gratissima Gartb, and from Oil of Estragon; found in oils of Russian Anise, Basil, Fennel, Turpentine, and others (FCTXAV 14,601,76). Colorless to sltly yellow liquid; anise odor. Bp: 102' at 16 mm, d: 0.960-0.968, refr index: 1.519-1.524, flash p: 178'F. Sol in alc; insol in water. SYNS: 4-ALLYL-1-METHOXYBENZENE 0 CHAVICOL RlETHYL ETHER 0 ESDRAGOL 0 ISOANETHOLE 0 pMETHOXYALLYLBENZENE 0 l-hfETHOXY-4-(2PR0PENYL)BENZENE 0 iMETHYL CHAVICOL 0 NCIC60946 0 TARRAGON CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderate acute toxicity by many routes. A skin irritant. Questionable carcinogen with experimental carcinogenic and neoplastigenic data. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS. A spice used in foods, liqueurs, and perfumes.
38
AFYOOO
ALLYL BROMIDE
AFYOOO CAS: 106-95-6 HR: 3 ALLYL BROMIDE DOT: UN 1099 mf: C J H ~ B ~ mw: 120.99 PROP: Colorless liquid; pungent odor. Mp: -119O, bp: 71.3O, flash p: 30°F, d: 1.3980 @ 2Oo/4O, autoign temp: 563'F, vap d: 4.17, lel: 4.4'/0, uek 7.3%. Insol in water. SYNS: BROMALLYLENE 0 1-BROMO-2-PROPENE 0 3-BROMOPROPENE 0 3-BROMOPROPYLENE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid, Poison SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. M d l y toxic by inhalation. Human mutation data reported. See also ALLYL CHLORIDE and ALLYL COMPOUNDS. Dangerous fire and explosion hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Br-. To fight fire, use alcohol foam, water spray or mist, COz, dry chemical. AGA5OO CAS: 123-68-2 HR: 3 ALLYL CAPROATE mf: C9Ht602 mW: 156.25 PROP: Bp: 186-1 88'. Insol in water; sol in alc and ether. SYNS: ALLYL HEXANOATE (FCC) 0 FEMA No. 2032 0 2-PROPENYL-N-HEXANOATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion and
skin contact. Mutation data reported. An irritant to human skin. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS. AGB250 CAS: 107-05-1 HR: 3 ALLYL CHLORIDE DOT: UN 1100 mf: C3H5C1 mw: 76.53 PROP: Colorless liquid with pungent odor. Mp: -136.4", bp: 44.6", d: 0.938 @ 2Oo/4O, fp: -134.5', flash p: -25OF, lel: 2.9%, uel: 11.2%, autoign temp: 905OF, vap d: 2.64.
Misc in org solvs. Sltly sol in water. IDLH 250 ppm. SYNS: ALLILE (CLORURO d-1) (ITALIAN) 0 ALLYLCHLORID (GERMAN) 0 ALLYLE (CHLORURE d') (FRENCH) 0 CHLORALLYLENE 0 CHLOROALLYLENE 0 3-CHLOROPRENE 0 1-CHLORO PROPENE-2 0 1CHLORO-2-PROPENE 0 3-CHLOROPROPENE 0 3CHLORO-1-PROPENE 0 a-CHLOROPROPYLENE 0 3CHLOROPROPYLENE 0 3-CHLORO-1-PROPYLENE 0 3-CHLORPROPEN (GERMAN) 0 NCI-CO4615 0 2PROPENYL CHLORIDE CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 36,39,85; NCI Carcinogenesis Bioassay (gavage); No Evidence: rat NCITR" NCI-CG-TR-73,78; Clear Evidence: mouse NCITR" NCI-CGTR-73,78. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-To-Know List. OSHA PEL: TWA 1 ppm; STEL 2 ppm ACGIH TLV: TWA 1 ppm; STEL 2 ppm; Animal Carcinogen DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NlOSH REL: TWA 1 ppm; CL 3 ppm/l5M DOT CLASSIFICATION: 3; Label: Flammable Liquid, Poison SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic data. Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion, inhalation, and skin contact. Experimental teratogenic and reproductive effects. A s h n and eye irritant. Human mutation data reported. Chronic exposure may cause liver and lildney damage. The vapors of ally1 chloride are quite irritating to the eyes, nose, and throat. Contact of the liquid with the skin may lead, in addition to local vasoconstriction and numbness, to rapid absorption and distribution through the body. If remedial measures are not taken promptly, such contact may result in burns and internal injuries. Inhalation may cause headache, dizziness, and in htgh concentration, loss of consciousness; however, even in low concentration, its odor in most cases is irritating enough to give warning of its presence. Concentration of
ALLYL CYCLOHEXANEPROPIONATE AGCSOO
the vapors high enough to cause serious effects, includlng damage to the lungs, especially on repeated exposure, may not be intolerable. Consequently, the warning characteristics should never be disregarded. In general, precautions should be taken AT ALL TIMES to avoid splllage and accumulation of noticeable concentration of the vapors in the atmosphere. Acute exposure in experimental animals has resulted in marked inflammation of lungs, irritation of shn, and swelling of the hdneys. Chronically exposed animals have shown degenerative changes in the liver and kidneys. Reported human exposures have been principally cases of irritation of the eyes, shn, and respiratory tract, sometimes accompanied by aches and pains in the bones. Liver and hdney injury is possible. Dangerous fire and explosion hazard when exposed to heat, flame, or oxidlzers. Vigorous or explosive reaction above -7O’C with alkyl aluminum chlorides (e.g., trichlorotriethyl dialuminum, ethyl aluminum dichloride, or diethyl aluminum chloride) + aromatic hydrocarbons (e.g., benzene or toluene). Violently exothermic polymerization reaction with Lewis acids (e.g., aluminum chloride, boron trifluoride, or sulfuric acid) and metals (e.g., aluminum, magnesium, zinc, or galvanized metals). Incompatible with HN03, ethylene imine, ethylenedlamine, chlorosulfonic acid, oleum, NaOH. To fight fire, use C02, alcohol foam, dry chemical. See also CHLORINATED HYDROCARBONS; ALIPHATIC; ALLYL COMPOUNDS; and CHLORIDES. Storage and Handling: Keep cool, away from heat sources. Maintain good vendation. Work in a fume hood or with closed system if possible; otherwise, use adequate vendation so that the odor of allyl chloride does not persist. If it should be necessary to enter an area in which the odor of allyl chloride is at all noticeable, use a gas mask equipped with an “organic vapor”
39
canister. Do not dlsregard the warning odor or eye irritation of allyl chloride. AGB500 CAS: 2937-50-0 HR: 3 ALLYL CHLOROCARBONATE DOT: UN 1722 mf: C4HjC102 mw: 120.54 PROP: Liquid. Bp: 106-114’, flash p: 88’F (CC), d: 1.14, vap d: 4.2. SYNS: ALLYL CHLOROFORRATE
0 ALLYL CHLOROFORMATE (DOT) 0 ALLYLESTER KYSELINY CHLORMRAVENCI 0 CHLOROFORIvIIC ACID ALLYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive,
Poison SAFETY PROFILE: Poison by inhalation and ingestion. Corrosive. Dangerous when exposed to heat, open flame (or sparks), or powerful oxidizers. Can react with oxidizing materials. To fight fire, use alcohol foam, spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also ALLYL COMPOUNDS and ESTERS.
AGCOOO CAS: 1866-31-5 HR: 2 ALLYL CINNAMATE mfi C12H1202 mw: 188.24 PROP: Colorless to light-yellow liquid; cherry odor. D: 1.052 @ 25’/25’, bp: 150-152’ @ 15 mm. Insol in water; sol in alc; very sol in ether. SYNS: ALLYI-3-PHENYLACRYLATE 0 PROPENYL CINNAMATE 0 VINYL CARBINYL CINNAMrZTE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Human skm irritant. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS.
AGCSOO CAS: 2705-87-5 HR: 3 ALLYL CYCLOHEXANEPROPIONATE mf: C12H2002 mw: 196.32 PROP: Colorless liquid; pineapple odor. D: 0.945-0.950, refr index: 1.457-1.463, flash p:
40
AGE250
4-ALLYL-l,2-DIMETHOXYBENZENE
212OF. Misc in alc, chloroform, ether; insol in glycerin and water. SYNS: 3-ALLYLCYCLOHEXYLPROPIONATE
0
ALLYL HEXAHYDROPHENYLPROPIONATE 0 F E U No.2026
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion.
When heated to decomposition it emits acrid smoke and irritating fumes. Combustible liquid. See ALLYL COMPOUNDS and ESTERS. AGE250 CAS: 93-15-2 HR: 3 4-ALLYL-1,2-DIMETHOXYBENZENE mf: C l l H 1 4 0 2 mw: 178.25 PROP: Colorless to pale-yellow liquid; clove, carnation odor. Bp: 255', d: 1.032-1.036, refr index: 1.532, fp: -4', flash p: 212'F. Sol in fured oils; insol in glycerin and propylene glycol. SYNS: l-ALLYL-3,4-DIMETHOXENZENE 0 4ALLYLVERATROLE 0 1,2-DIMETHOXY-4-ALLYLBENZENE 0 1-(3,4-DIMETHOXWHENYL)-2-PROPENE 0 ENT 21,040 0 1,3,CEUGENOL METHYL ETHER 0 ECGENYL METHYL ETHER 0 F E U No. 2475 0 METHYL EUGENOL (FCC) 0 VERATROLE METHTiL ETHER
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. Reported in EPA TSCA Inventory. SAFETY PROFILE: Confirmed carcinogen. Poison by intravenous route. Moderately toxic by ingestion and intraperitoneal routes. A shn irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. Some other alkenylbenzenes have carcinogenic activity. See also EUGENOL, ALLYL COMPOUNDS, and ETHERS.
AGHOOO CAS: 1838-59-1 HR: 3 ALLYL FORMATE DOT: UN 2336 mf: C4H602 mw: 86.10 PROP: Liquid, sltly water-sol, sol in org solvs. D: 0.948 @ 18'/4', bp: 83', flash p: <-50°F.
SYNS: ALLYLESTER KYSELINY MRAVENCI
0
FORMIC ACID, ALLYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid, Poison SAFETY PROFILE: Poison by ingestion. Moderately toxic by inhalation. Very flammable and reactive. Dangerous fire hazard. See also ALLYL COMPOUNDS and ESTERS. When heated to decomposition it yields irritating smoke and fumes. AGHl5O CAS: 106-92-3 HR: 3 ALLYL GLYCIDYL ETHER DOT: UN 2219 mfi C 6 H 1 0 0 2 mw: 114.16 PROP: Bp: 153.9', fp: -100' (forms glass), flash p: 135'F (OC), d: 0.9698 @ 20'/4', vap press: 21.59 mm @ 60°, vap d: 3.94. IDLH 50 ppm. SYNS: AGE 0 ALLIL-GLICIDIL-ETERE (ITALIAN) 0 1ALLILOSSI-2,3 EPOSSIPROPANO (ITALIAN) 0 ALLYL2,3-EPOXYPROPYL ETHER 0 ALLYL-GLYCIDAETHER (GERMAN) 0 l-ALLYLOXY-2,3-EPOXY-PROPAAN (DUTCH) l-ALLYLOXY-2,3-EPOXYPROPAN (GERMAN) 0 l-(ALLYLOXY)-2,3-EPOXROPANE 0 NCIX56666 0 OXYDE d'ALLYLE et de GLYCIDYLE (FRENCH) 0 ((2-PROPENYL0XY)METHYL)OXIRANE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 ppm; STEL 10 ppm ACGIH TLV: 1 ppm; Not Classifiable as a Human Carcinogen DFG MAK: Confirmed Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Glycidyl Ethers) CL 45 mg/m3/ 15M DOT CLASSIFICATION: 3; Label: Flammable Liquid, Poison SAFETY PROFILE: Confirmed animal carcinogen. Poison by ingestion. Moderately toxic by inhalation and s h n contact. Mutation data reported. A severe skin and eye irritant. Can cause central nervous system depression and pulmonary edema. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, C02, dry chemical.
ALLYL ISOTHIOCYANATE
When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS. AGH250 CAS: 142-19-8 HR: 2 ALLYL HEPTANOATE mfi C10H1802 mw: 170.28 PROP: Colorless to pale-yellow liquid; fruity, sweet, pineapple odor. D: 0.880, refr index: 1.426, flash p: 154'F. SYNS: ALLYL EXANTHATE 0 ALLYL HEPTOATE 0 ALLYL HEPTYLATE 0 FEhL4 No. 2031 0 2-PROPENYL HEPTANOATE
CONSENSUS REPORTS: Reported in EPA
AGJ250
41
mf: C16H240 mw: 232.40 PROP: Colorless to yellow liquid; fruity, woody odor. D: 0.928-0.935, refr index: 1.503i1.507, flash p: 212'F. Sol in alc; insol in water @ 265'. SYNS: FEbLA No. 2033 1-(2,6,6-TRIhiETHYL-2CYCLOHEXEN-1-YL)-1,6-HEPTADIEN-3-ONE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS.
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and s h n contact. A human skin irritant. See also ALL= COMPOUNDS and ESTERS. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
AGJOOO CAS: 1476-23-9 HR: 3 ALLYL ISOCYANATE DOT: UN 2206/UN 2207/UN 2478/UN 3080 mf: C4H5NO mw: 83.10 PROP: Liquid. Bp: 85'. SYN: ISOCYANIC ACID, ALLYL ESTER
AG1250 CAS: 556-56-9 HR: 3 ALLYL IODIDE DOT: UN 1723 mf: C3Hd mw: 167.98 PROP: Yellow liquid; pungent odor. Mp: -99', bp: 103.1', d: 1.825 @ 20'/4', vap d 5.8. SYNS: 3-IODOPROPENE 0 3-IODO-1-PROPENE 0 3IODOPROPYLENE 0 I-PROPENE, 3-IODO-(9CI)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD (UN 2207); DOT Class: 6.1; Label: Poison (LJN 2206); DOT Class: 6.1; Label: Poison, Flammable Liquid (UN 3080); DOT Class: 3; Label: Flammable Liquid, Poison (UN 2478) SAFETY PROFILE: A poison. See also ALLYL COMPOUNDS and ESTERS. A flammable liquid. When heated to decomposition it emits toxic fumes of NO,.
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: Proposed: (inhalable fraction) 0.1 mg/m3; Not Classifiable as a Human Carcinogen) DOT CLASSIFICATION: 3; Label: Flammable Liquid, Corrosive SAFETY PROFILE: Poison by inhalation and ingestion. Mutation data reported. A powerful irritant. A flammable liquid. Incompatible with oxi&zing materials. To fight fire, use water, foam, COz, dry chemical. When heated to decomposition it emits hghly toxic fumes of I-. See also ALLYL COMPOUNDS and IODIDES.
AGJ250 CAS: 57-06-7 HR: 3 ALLY L ISOTHIOCYANATE DOT: UN 1545 mfi C4HjNS mw: 99.16 PROP: Colorless to pale-yellow liquid oil; irritating odor with mustard taste. Mp: -80°, d: 1.015 @ 15'/4O, bp: 150.7', fp: -80", flash p: 115'F, d: 1.013-1.016 @ 25'/25', vap press: 10 mm @ 38.3', vap d: 3.41, refr index: 1.527-1.531. Misc with alc, carbon &sulfide, and ether.
AG1500 CAS: 79-78-7 ALLYL a-IONONE
SYNS: AITC 0 ALLYL ISORHODANIDE 0 ALLYL ISOSULFOCYANATE ALLYL ISOTHIOCYANATE, stabilized (DOT) 0 ALLYL MUSTARD OIL 0
HR: 2
42
AGJ500
ALLYL MERCAPTAN
ALLYLSENFOEL (GERMAN) 0 ALLYL SEVENOLUM 0 ALLYL THIOCARBONIMIDE 0 ARTIFICIAL MUSTARD OIL 0 CARBOSPOL 0 FEMA No. 2034 0 ISOTHIOCYANATE d'ALLYLE (FRENCH) 0 3-ISOTHIOCYANATO-1-PROPENE 0 MCSTARD OIL 0 NCI-C50464 0 OIL O F I\.nrSTA4RD, aruficial 0 OLEUhi SINAPIS VOLATILE 0 2-PROPENYL ISOTHIO-CYANATE 0 REDSKIN 0 SENF OEL (GERMAN) 0 SYNTHETIC MUSTARD OIL 0 VOLATILE OIL OF MUSTARD
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 36,55,85; NTP Carcinogenesis Bioassay (gavage); No Evidence: mouse NTPTR* NTP-TR-234,82; Clear Evidence: rat NTPTR* NTP-TR234,82. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Suspected carcinogen with experimental neoplastigenic and tumorigenic data. Poison by ingestion, skin contact, intravenous, subcutaneous, and intraperitoneal routes. Experimental teratogenic and reproductive effects. An eye irritant. An allergen. May cause contact dermatitis. Mutation data reported. A flammable liquid. Highly reactive. When heated to decomposition (above 250') or on contact with acid or acid fumes it emits highly toxic fumes of CN-, SO,, and NO,. To fight fire, use foam, CO2, dry chemical. See also ALLYL COMPOUNDS and ESTERS. AGJ500 HR: 3 ALLYL MERCAPTAN mf: C3H6S mw: 74.15 PROP: Water-whte liquid with a strong garlic odor, darkens on standing. D: 0.925 @ 23'/4O, bp: 68', flash p: 14'F. SYN: 2-PROPENE-1-THIOL SAFETY PROFILE: Poison by inhalation and ingestion. Strong irritant to shn and mucous membranes. When heated to
decomposition it emits highly toxic fumes of SO,. Very dangerous fire hazard. To fight fire, use water mist or spray, alcohol foam, Con, or dry chemical. See also ALLYL COMPOUNDS and MERCAPTANS.
AGMSOO CAS: 4230-97-1 HR: 2 ALLYL OCTANOATE mf: CllH2002 mw: 184.31 PROP: Colorless liquid; fruity odor. D: 0.8550.861, refr index: 1.425, flash p: 151'F. Sol in alc, fixed oils; sltly sol in propylene glycol; insol in glycerin and water @ 260'. SYNS: ALLYL CAPRYLATE
FEMA No. 2037 0 OCTANOIC ACID ALLYL ESTER 0 OCTANOIC ACID-2PROPENYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A s h n irritant. See also ALLYL COMPOUNDS and ESTERS. When heated to decomposition it emits acrid smoke and irritating fumes.
AGQ750 CAS: 7493-74-5 HR: 2 ALLYL PHENOXYACETATE mf: CllH1203 mw: 192.23 PROP: Colorless to light-yellow liquid; heavy fruit odor. SYN: ACETATE PA. CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and skin contact. When heated to decomposition it emits acrid smoke and irritating fumes. See also A L L K COMPOUNDS.
AGQ775 CAS: 21905-27-1 HR: 3 ALLYL PHENYL ARSlNlC ACID mf: CsHllAs02 mw: 226.12 SYNS: ALLYLHYDROXYPHENYLARSINE OXIDE 0 ARSINE OXIDE, ALLYLHYDROXTPHENYLOSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it
emits toxic fumes of As. AGRSOO CAS: 2179-59-1 HR: 1 ALLYL PROPYL DlSULFlDE mf: C6H12S2 mw: 148.30 PROP: Lquid with pungent odor. Bp: 66-69' @ 16 mm. OSHA PEL: TWA 2 ppm; STEL 3 ppm
ALUMINUM ACGIH TLV: W A 2 ppm; STEL 3 ppm;
(Proposed: 0.5 pprn (sensitizer)) DFG MAK: 2 pprn (12 mg/m3) NIOSH REL: (Ally1 Propyl Disulfide): TWA 2 ppm; STEL 3 pprn SAFETY PROFILE: A powerful irritant. Moderately flammable by exposure to heat, flame, or oxidizers. When heated to decomposition it emits highly toxic SO,. To fight fire, use foam, C02, dry chemical. See also ALLYL COMPOUNDS. AGU250 CAS: 107-37-9 HR: 3 ALLYL TRICHLOROSILANE DOT: UN 1724 mf: C3H5C13Si mw: 175.52 PROP: Colorless liquid; pungent, irritating odor. D: 1.222 @ 20'/4', bp: 116' @ 750 mm, flash p: 95°F (COC). SYNS: ALLYLTRICHLOROSILANE, stabhzed (DOV0 SILANE, TRICHLOROALLYL- 0 TRICHLOROALLYLSILAXE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive,
Flammable Liquid SAFETY PROFILE: Poison by intravenous route. Corrosive. See ALLYL COMPOUNDS. When heated to decomposition it emits toxic C1-. A dangerous fire hazard. To fight fire, use foam, mist, spray, dry chemical.
AGW750 CAS: 569-58-4 HR: 1 ALUMINON mf: C22H23N309 mw: 473.48 PROP: Reddish-brown powder. Sol in H2O; sltly sol in EtOH; insol in non-polar solvs. SYNS: AMMONIUM AURINTRICARBOXYLATE 0 AURINE-TRICARBOXYLATE d'AMMONIUM (FRENCH) 0 AURINTRICARBOXYLIC ACID AMMONIUM SALT 0 C.I. MORDANT VIOLET 39, TRIAMMONIUM SALT (8CI) 0 LYSOFON 0 TRIAMMONIUM AURINTRICARBOXYLATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Human reproductive
effects by ingestion: changes in male fertility. Experimental reproductive effects. Mutation data reported. When heated to
AGXOOO
43
decomposition it emits toxic fumes of NH3 and NO,. AGXOOO CAS: 7429-90-5 HR: 3 ALUMINUM DOT: UN 1309/UN 1396/NA 9260 af: A1 aw: 26.98 PROP: Hard, strong, silvery-whte ducule metal: in bulk form protected from oxidation in air by coherent A1203 coating. Mp: 660°, bp: 2494' @ 24 mm, d: 2.702, vap press: 1 mm @ 1284'. Sol in HC1, H2S04, hot water, and alkalies. SYNS: A 00 0 A 95 0 A 99
0 A 995 0 A 999 0 AA 1099
0 AA1199 0 AD 1 0 ADlhl 0 ADO 0 AE 0 ALAUN
(GERMAN) 0 ALLBRI ALUMINUM PASTE and POWDER 0 ALUMINA FIBRE 0 ALUMINIUhl BRONZE 0 ALUMINUM FLAKE 0 ALUMINUM 27 0 ALUMINUM A00 0 ALUMINUM DEHYDRATED 0 ALUMINUM METAL (OSHA) 0 ALUMINUM, molten @A 9260) (DOT) 0 ALUMINUM POWDER 0 ALUMINUM POWDER, coated (US1309) (DOT) 0 ALUMINUM POWDER, uncoated (UN 1396) (DOT) 0 ALUMIXLM PYRO POWDERS (OSHA) 0 ALUMINUhI WELDING FUMES (OSHA) A 0 A1 0 AR2 0 AVO0 0 AVO00 0 C.I. 77000 0 EMANAY ATOMIZED ALUMINUM POWDER 0 JISC 3108 0 JISC 3110 0 L16 0 METANA ALUMINUM PASTE 0 NORAL ALUiMINUM 0 NORAL EXTRA FINE LINING GRADE 0 NORAL INK GRADE ALUMINUM 0 NORAL NON-LEAFING GRADE 0 PAP-1
CONSENSUS REPORTS: Community Right-To-Know List (fume or dust). Reported in EPA TSCA Inventory. OSHA PEL: Total Dust: TWA 15 mg/m3; Respirable Fraction: TWA 5 mg/m3; Ppro Powders and Weldlng Fumes: 5 mg/m3; Soluble Salts and Alkyls: 2 mg/m3 ACGlH TLV: (Proposed: Metal and Insoluble Compounds 1 mg/m3) DFG MAK: 1.5 mg/m3; BAT: 200 pg/L in urine at end of shift DOT CLASSIFICATION: 9; Label: CLASS 9 (NA 9260); DOT Class: 4.1; Label: Flammable Solid (UN 1309); DOT Class: 4.3; Label: Dangerous When Wet (UN 1396) SAFETY PROFILE: Although aluminum is not generally regarded as an industrial poison, inhalation of finely dwided powder has been reported to cause pulmonary fibrosis. It is a reactive metal and the
44 AGX250 ALUMINUM AMMONIUM SULFATE greatest industrial hazards are with chemical reactions. As with other metals the powder and dust are the most dangerous forms. Dust is moderately flammable and explosive by heat, flame, or chemical reaction with powerful oxidizers. To fight fire, use special mixtures of dry chemical. Powdered aluminum undergoes the following dangerous interactions: explosive reaction after a delay period with KC104 + Ba(NO3)2 + mo3 + H20, also with Ba(N03)2 + mo3 + sulfur + vegetable adhesives + HzO. Wxtures with powdered AgC1, NH4NO3 or NH4NO3 + Ca(N03)2 + formamide + H20 are powerful explosives. Murture with ammonium peroxodisulfate + water is explosive. Violent or explosive "thermite" reaction when heated with metal oxides, oxosalts (nitrates, sulfates), or sulfides, and with hot copper oxide worked with an iron or steel tool. Potentially explosive reaction with ccl4 during ball milling operations. Many violent or explosive reactions with the following halocarbons have occurred in industry: bromomethane, bromotrifluoromethane, ccl4, chlorodfluoromethane, chloroform, chloromethane, chloromethane + 2methylpropane, dchlorodifluoromethane, 1,2-dichloroethane, dichloromethane, 1,2dichloropropane, 1,2-difluorotetrafluoroethane, fluorotrichloroethane, hexachloroethane + alcohol, polytrifluoroethylene oils and greases, tetrachloroethylene, tetrafluoromethane, 1,1,1trichloroethane, trichloroethylene, 1,1,2trichlorotrifluoro-ethane, and trichlorotrifluoroethane-dchlorobenzene. Potentially explosive reaction with chloroform amidinium nitrate. Ignites on contact with vapors of AsCl3, SC4, Se2C12, and Pc15. Reacts violently on heating with Sb or As. Ignites on heating in SbCl3 vapor. Ignites on contact with barium peroxide. Potentially violent reaction with sodium acetylide. Mixture with sodum peroxide may ignite or react violently. Spontaneously igmtes in CS2 vapor. Halogens: ignites in
chlorine gas, foil reacts vigorously with liquid Br2, violent reaction with H20 + 12. Violent reaction with hydrochloric acid, hydro-fluoric acid, and hydrogen chloride gas. Violent reaction with disulfur dbromide. Violent reaction with the nonmetals phosphorus, sulfur, and selenium. Violent reaction or ignition with the interhalogens: bromine pentafluoride, chlorine fluoride, iodne chloride, iodine pentafluoride, and iodne heptafluoride. Burns when heated in CO2. Ignites on contact with 0 2 , and mixtures with 0 2 + H20 ignite and react violently. Mixture with picric acid + water ignites after a delay period. Explosive reaction above 800°C with sodium sulfate. Violent reaction with sulfur when heated. Exothermic reaction with iron powder + water releases explosive hydrogen gas. Aluminum powder also forms sensitive explosive mixtures with oxidants such as: liquid Cl2 and other halogens, N204, tetranitromethane, bromates, iodates, NaC103, KC103, and other chlorates, NaN03, aqueous nitrates, KC104 and other perchlorate salts, nitryl fluoride, ammonium peroxodisulfate, sodium peroxide, zinc peroxide, and other peroxides, red phosphorus, and powdered polytetrafluoroethylene (PTFE). Bulk aluminum may undergo the following dangerous interactions: exothermic reaction with butanol, methanol, 2-propanol, or other alcohols, sodium hydroxide to release explosive hydrogen gas. Reaction with dborane forms pyrophoric product. Ignition on contact with niobium oxide + sulfur. Explosive reaction with molten metal oxides, oxosalts (nitrates, sulfates), sulfides, and sodium carbonate. Reaction with arsenic trioxide + sodum arsenate + sodium hydroxide produces the toxic arsine gas. Violent reaction with chlorine trifluoride. Incandescent reaction with formic acid. Potentially violent alloy formation with palladium, platinum at mp of Al,600OC. Vigorous dssolution reaction in
ALUMINUM CHLORIDE HYDROXIDE AHAOOO
methanol + carbon tetrachloride. Vigorous amalgamation reaction with mercury(I1) salts + moisture. Violent reaction with molten silicon steels. Violent exothermic reaction above 600'C with sodium diuranate. AGX250 HR: 1 ALUMINUM AMMONIUM SULFATE mf: Ala(S04)3(NH4)zS04*24H20 mw: 906 PROP: Colorless crystals; odorless with sweet taste. D: 1.645, mp: 94.5', bp: loses 20 waters @ 120'. Sol in water, glycerin; insol in alc. SAFETY PROFILE: Irritating if inhaled or ingested. Upon decomposition it emits toxic fumes of NO, and SO,. AGX750 CAS: 7727-15-3 HR: 2 ALUMINUM BROMIDE DOT: UN 1725/UN 2580 mf: AlBr3 mw: 266.71 PROP: White to yellow-red lumps. Mp: 97.5', bp: 263.3' @ 748 mm, d: 3.2, vap press: 1 mm @ 81.3'. SYNS: ALUMINUM BROMIDE, anhydrous (UN 1725) (DOT) 0 ALUMINUM BROMIDE, soluuon (UN 2580) (DOT) 0 ALUMINUM TRIBROhIIDE 0 TRIBROMOALUMINUM
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 2 mg(Al)/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A toxic, corrosive material. See also BROMIDES and ALUMINUM COMPOUNDS. Mixtures with sodium or potassium explode violently upon impact. When heated to decomposition it emits toxic fumes of Br-. Do not add HzO to anhydrous material. Hydrolysis can be violent.
AGY750 CAS: 7446-70-0 HR: 3 ALUMINUM CHLORIDE DOT: UN 1726/UN 2581 mf: A1Cb mw: 133.33 PROP: White or colorless hexagonal deliquescent crystals or moisture sensitive plates. D: 2.44, mp: 192' @ 2.5 atm, bp:
45
sub1 @ 181', vap press: 1 mm @ 100.0'. Violently sol in water; sol in alc and ether. SYNS: ALLUMINIO(CLORUR0 DI) (ITALIAK) 0 ALUMINUMCHLORID (GERMAN) 0 ALUMINUM CHLORIDE (1:3) 0 ALUMINUM CHLORIDE, anhydrous (DOT) 0 ALUMINUM CHLORIDE, soluuon (DOT) 0 ALUMINUM TRICHLORIDE 0 CHLORURE d'ALUMINUM (FRENCH) 0 PEARSALL 0 TRICHLOROALUMINUM
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 2 mg(Al)/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. Mutation data reported. The dust is an irritant by ingestion, inhalation, and skin contact. Highly exothermic polymerization reactions with alkenes. Incompatible with nitrobenaenes or nitrobenzene + phenol. Highly exothermic reaction with water or steam produces toxic fumes of HC1. See also ALUMINUM COMPOUNDS, CHLORIDES, and HYDROCHLORIC ACID.
AHAOOO CAS: 12042-91-0 HR: 2 ALUMINUM CHLORIDE HYDROXIDE mf: AlzClHjOs mw: 174.46 SYNS: ALUMMUM CHLORHYDRATE 0 ALUMINUM CHLORHYDROL 0 ALUMINUM CHLORHYDROXIDE 0 ALUMINUM CHLOROHYDROXIDE 0 ALUMINUM HYDROXIDE CHLORIDE 0 ALUMINUM HYDROXYCHLORIDE 0 ASTRINGEN 0 BASIC ALUMINUM CHLORATE 0 CHLORHYDROL 0 CHLORHYDROL, GRANULAR 0 CHLORHYDROL, IMPALPABLE 0 CHLOROHYDROL 0 CHLOROPENTAHYDROXYDIALUMINUM 0 LOCRON EXTRh 0 LOCRON FLAKES 0 LOCRON POWDER 0 LOCRON SOLUTION 0 MACRO-SPHERICAL 95 0 MICRO DRY 0 K'ICKENOL 303 0 WICKENOL 321 0 WICKENOL 323 0 WICKENOL 324
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 2 mg(Al)/m3 SAFETY PROFILE: A mild human skin irritant. See also ALUMINUM COMPOUNDS, CHLORIDES, and SODIUM HYDROXIDE. When heated to decomposition it emits toxic fumes of Cl-.
46 AHA250
ALUMINUM DEXTRAN
AHA250 CAS: 7047-84-9 HR: 1 ALUMINUM DEXTRAN mf: C1sH37A104 mw: 344.48 PROP: Powder. A complex containing aluminum and dextran, a chain of molecular weight 2500, corresponding to a chain of 15 anhydroglucose units.
mf: AlH, mw: 30.01 PROP: Colorless powder or white amorph or microcrystal air- and moisture-sensitive solid. Usually made in THF or EtzO and used in sittr. Several solid forms exist. Solids AlH3.nEt20, n = 0.3-3 obtained from Et2O. Sol in EtzO, THF.
SYNS: ALUMINUM MONOSTEARATE 0 ALUiMlNUM STEARATE (ACGIH) 0 STEARIC ACID, ALUMINIUM SALT
SYNS: ALANE ALUMINUMTRIHYDRIDE ALUMINUM TRIHYDRIDE
CONSENSUS REPORTS: EPA TSCA
Chemical Inventory. ACGlH TLV: (Proposed: Metal and Insoluble
Compounds 1 mg/m3) SAFETY PROFILE: A nuisance dust. When
heated to decomposition it emits acrid smoke and fumes. See also ALUMINUM COMPOUNDS. AHBOOO CAS: 7784-18-1 HR: 3 ALUMINUM FLUORIDE mf: AlF3 mw: 83.98 PROP: Solid, colorless crystals. Mp: 1291', sub1 @ 1260°, d: 2.88, vap press: 1 mm @ 1238', bp: 1537'. Sparingly sol in water; insol in org solvs. SYNS: ALUMINUM FLUORURE (FRENCH) 0 ALUMINUM TRIFLUORIDE 0 FLUORID HLINITY (CZECH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 2.5 mgO/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shft; TWA 2 mg(Al)/m3 NIOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(Fj/m3 SAFETY PROFILE: A poison by ingestion. Moderately toxic by subcutaneous route. A severe eye irritant. Violently impact-sensitive when in contact with Na and I<. When heated to decomposition it emits toxic fumes of F-. See also FLUORIDES and ALUMINUM COMPOUNDS.
AHBSOO CAS: 7784-21-6 ALUMINUM HYDRIDE DOT: UN 2463
HR: 3
a-
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 2 mg(Al)/m3 DOT CLASSIFICATION: 4.3; Label: Dangerous When Wet SAFETY PROFILE: Hydrides of some metals (such as ASH$ are extremely toxic. Dangerous fire hazard. An unstable material which is spontaneously flammable in air or 0 2 . Evolves explosive HZupon contact with moisture. Severe explosion hazard by chemical reaction wherein HZgas is produced, also in contact with methyl ethers contaminated by Con. Mixtures with tetrazole derivatives are explosive. Reacts with oxidzing materials. On contact with acid or acid fumes, it can emit toxic fumes. See also HYDRIDES and ALUMINUM COMPOUNDS.
AHCOOO CAS: 21645-51-2 HR: 3 ALUMINUM HYDROXIDE mf: AlH303 mw: 78.01 PROP: White, crystalline powder, balls, or granules. Solid from water. D: 2.42, mp: loses H20 @ 300'. Practically insol in water; sol in mineral acids, alkalies, and caustic soda. SYNS: AF 260 0 ALCOA 331 0 ALUMIGEL 0 ALUMINA HYDRATE 0 ALUMINA HYDRATED 0 ALUMINA TRIHYDRATE 0 a-ALUMINA TRIHYDRATE 0 ALUMINIC ACID 0 ALUMINUM HYDRATE 0 ALUMINUM(I1I) HYDROXIDE 0 ALUMINUM HYDROXIDE GEL 0 ALUMINUM OXIDE HYDRATE 0 ALUMINUM OXIDE TRIHYDRATE 0 ALUMINUM TRIHYDRAT 0 ALUMINUM TRIHYDROXIDE 0 ALUSAL AiMBEROL ST 140F 0 AMDHOJEL 0 BACO AF 260 0 BRITISH ALUMINUM AF 260 0 C.I. 77002 0 GHA 331 0 H 46 0 HIGILITE 0 HYDRAL 705 0 LIQUIGEL 0 PGA 0 TRIHYDRATED ALUMINA
ALUMINUM OXIDE (2:3) AHE250 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 2 mg(Al)/m3 DFG MAK: 1.5 mg/m3 SAFETY PROFILE: Poison by intraperitoneal route. Human systemic effects by ingestion: fever, osteomalacia, and gastrointestinal effects. When coprecipitated with bismuth hydroxide and reduced by H2, it is violently flammable in air. Incompatible with chlorinated rubber.
AHC250 CAS: 24623-77-6 HR: 3 ALUMINUM HYDROXIDE OXIDE mf: AlH02 mw: 59.99 PROP: White solid. Sol in hot NaOH. SYNS: ALUMINUM METAHYDROXIDE 0 HYDRATED ALUMINA CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 2 mg(Al)/m3 SAFETY PROFILE: Poison by intratracheal route. See also ALUMINUM COMPOUNDS.
AHC750 CAS: 18917-91-4 ALUMINUM LACTATE mf: CsHlsA109 mw: 294.22
HR: D
SYNS: ALUMINUM, TRIS(2-HYDROXY-PROPANOATO0'),02(9CI) 0 ALUMINUM, TRIS(LACTAT0)-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An experimental
teratogen. Other experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes. AHD250 HR: 3 ALUMINUM MAGNESIUM PHOSPHIDE DOT: UN 1419 mf: Mg3AlP3 mw: 192.8 SYN: MAGNESIUIM ALUMINUM PHOSPHIDE (DO9 ACGIH TLV: TWA 2 mg(Al)/m3 DOT CLASSIFICATION: 4.3; Label:
Dangerous When Wet, Poison SAFETY PROFILE: A poison. Dangerous fire hazard. Evolves spontaneously flammable PH3 in contact with water. See also PHOSPHIDES, PHOSPHINE,
47
ALUMINUM COMPOUNDS, and MAGNESIUM COMPOUNDS. AHD650 CAS: 1976-28-9 HR: D ALUM INUM NlCOTlNATE mf: C18H12AlN306 mw: 393.30 PROP: Solid. SYNS: ALUNITINE 0 MICALEX 0 NICOTINIC ACID, ALUMINUM SALT 0 3-PYRIDINECARBOXYLICACID, ALUhlINUhI SALT 0 TRIS(NICTINAT0)ALUMINUM SAFETY PROFILE: When heated to
decomposition it emits toxic fumes of NO,. AHD750 CAS: 13473-90-0 HR: 3 ALUMINUM(II1) NITRATE (1 :3) DOT: UN 1438 mf: N30pA1 mw: 213.01 PROP: White crystals or very hygroscopic solid. Bp: 50" @ 0.01 mm. SYNS: ALUMINUM NITRATE (DOV 0 ALUMINUM TRINITRATE 0 NITRIC ACID, ALUhlINUM SALT 0 NITRIC ACID, ALUMINUIvi(3+) SALT CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 2 mg(Al)/m3 DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: A poison. A severe eye and mdd skin irritant. A powerful oxidmer. When heated to decomposition it emits toxic NO,. See NITRATES and ALUMINUM COMPOUNDS. A nitrating agent.
AHE250 CAS: 1344-28-1 HR: 3 ALUMINUM OXIDE (2:3) mf: A1203 mw: 101.96 PROP: W t e powder or solid. Mp: 2050°, bp: 2977", d: 3.5-4.0, vap press: 1 mm @ 2158". Sol in hot NaOH. SYNS: A 1 (sorbent) 0 A1-0109 P 0 ABRAREX 0 ACTIVATED ALUMINUhl OXIDE 0 ALCOA F 1 0 ALMITE 0 ALON 0 ALUMINA 0 a-ALUMINA (OSHA) 0 P-ALUMINA 0 y-ALUMINA 0 ALUMINUM OXIDE 0 a-ALUMINUM OXIDE 0 P-ALUMINUM OXIDE 0 yALUMINUM OXIDE 0 ALUMINUM SESQUIOXIDE ALUMITE 0 ALUNDUhl 0 BROCECMrlNN, ALUMINUM OXIDE 0 CAB-0-GRIP 0 COhPALOX 0 DIALUMINUM TRIOXIDE 0 DISPAL 0 DOTMENT 324 0 FASERTON G 2 (OXIDE) 0 KHP 2 0 LUCALOX 0 MICROGRIT WCA 0 PS 1 0 RC 172DBM
48
AHE750
ALUMINUM PHOSPHIDE
CONSENSUS REP0RTS: Community
Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: Total Dust: TWA 10 mg/m3; (Proposed: 1 mg/m3); Respirable Fraction: TWA 5 mg/m3 ACGIH TLV: (Proposed: Metal and Insoluble Compounds 1 mg/m3) DFG MAK: Animal Carcinogen, Suspected Human Carcinogen; 1.5 mg/m3 SAFETY PROFILE: Suspected carcinogen with experimental neoplastigenic and tumorigenic data by implantation. Inhalation of finely divided particles may cause lung damage (Shaver's disease). Exothermic reaction above 200'C with halocarbon vapors produces toxic HC1 and phosgene. See also ALUMINUM COMPOUNDS. AHE750 CAS: 20859-73-8 HR: 3 ALUMINUM PHOSPHIDE DOT: UN 1397 mf: A1P mw: 57.95 PROP: Dark-gray or dark-yellow moisturesensitive crystals stable up to 10'. D: 2.85 @ 25'/4', mp: >lOOOo. SYNS: AIP 0 AL-PHOS 0 ALUMINUMFOSFIDE (DUTCH) 0 ALUMINUM MONOPHOSPHIDE 0 CELPHIDE 0 CELPHOS 0 DELICIA 0 DETIA GAS EX-B 0 FOSFURI d~ALLUMINIO (ITALIAN) 0 FUMITOXIN 0 PHOSPHURES d'ALUMINUM (FRJZNCH) 0 PHOSTOXIN 0 QUICKPHOS 0 RCRA WASTE NUiMBER PO06
CONSENSUS REPORTS: EPA Extremely
Hazardous Substances List. Reported in EPA TSCA Inventory. ACGIH TLV: TWA 2 mg(Al)/m3 DOT CLASSIFICATION: 4.3; Label: Dangerous When Wet, Poison SAFETY PROFILE: A human poison by inhalation and ingestion. Dangerous; in contact with water, steam, or alkali it slowly yields PH3, which is spontaneously flammable in air. Explosive reaction on contact with mineral acids produces phosphine. When heated to decomposition it yields toxic PO,. See also ALUMINUM COMPOUNDS, PHOSPHIDES, and PHOSPHINE.
AHGOOO CAS: 11138-49-1 HR: 2 ALUMINUM SODIUM OXIDE DOT: UN 1819/UN 2812 mf: NaAl02 mw: 82.0 PROP: White, hygroscopic powder. Mp: 1650'. Sol in water; insol in alc, strongly alkaline aqueous solutions. SYNS: P-ALUMINA 0 !.3"-ALUhffNA 0 J 242 0 NALCO 680 0 SODIUM ALUMINATE, solid (UN 2812) (DO?? 0 SODIUM ALUMINATE, solution (UN 1819) (DO7 0 SODIUiM ALUMINUM OXIDE 0 SODIUM POLYALUMINATE
ACGIH TLV: TWA 2 mg(Al)/m3 DOT CLASSIFICATION: 4.3; Label:
Dangerous When Wet SAFETY PROFILE: Moderate irritant to shn, eyes, and mucous membranes. A corrosive substance. When heated to decomposition it emits toxic fumes of NazO. AHGSOO HR: 2 ALUMINUM SODIUM SULFATE mf: NaAl (S04)2#12H20 mw: 458.29 PROP: Colorless crystals. Mp: 61'; d: 1.675. Anhydrous: sol in alc; sltly sol in water. Dodecahydrate: sol in water and alc. SYNS: SODA ALUM 0 SODIUM ALUMINUM SULFATE SAFETY PROFILE: A weak sensitizer. A general-purpose food addtive. Local contact may cause contact dermatitis. An irritant. See also SULFATES and ALUMINUM COMPOUNDS. When heated to decomposition it emits toxic fumes of SO, and Na20. AHG750 CAS: 10043-01-3 HR: 2 ALUMINUM SULFATE (2:3) mf: O&*2A1 mw: 342.14 PROP: White powder; sweet taste. Mp: decomp @ 770°, d: 2.71. Solubility in water 36.4% @ 20'. SYNS: ALUM 0 ALUMINUMALUM ALUMINUM SULFATE 0 ALUMINUM SULPHATE 0 ALUMINUM TRISULFATE 0 CAKE ALUM 0 DIALUMINUM SULPHATE 0 DIALUMINUM TRISULFATE 0 SULFURIC ACID, ALUMINUM SALT (3:2)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA FIFRA 1988
AMIDES AHL750
pesticide subject to regstration or reregstration. ACGlH TLV: TWA 2 mg(Al)/m3 SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Experimental reproductive effects. Human mutation data reported. Hydrolyzes to form sulfuric acid, whch irritates tissue, especially lungs. When heated to decomposition it emits toxic fumes of SO,. AHG875 CASE16962-07-5 HR: 3 ALUMINUM TETRAHYDROBORATE DOT: UN 2870 mf: A1*3BH4 mw: 71.53 SYNS: ALUMINUM BOROHYDRIDE (DOT) 0 ALUMINEM BOROHYDRIDE m devlces (DOT) 0 ALUMINUM HYDROBORATE 0 BORATE(1-), TETRAHYDRO-, ALUMlNUM (3:l) (9CI) ACGIH TLV: TWA 2 mg(Al)/m3 DOT CLASSIFICATION: 4.2; Label:
Spontaneously Combustible, Dangerous When Wet SAFETY PROFILE: A poison. Spontaneously flammable in air. Explodes in oxygen with traces of water. Incompatible with alkenes and water. See also ALUMINUM COMPOUNDS and BORON COMPOUNDS. AHJ750 CAS: 52645-53-1 HR: 3 AMBUSH mf: C21H20C1203 mw: 391.31 PROP: Crystals or pale-yellow viscous liquid. Bp: 220' @ 0.05 mm. SYNS: AI3-29158 0 BW-21-2 0 ECTIBAN 0 EXMIN 0 FMC 33297 0 FMC 41655 0 ICI-PP 557 0 KESTREL pesticide) 0 NDRC-143 0 NIA 33297 0 OUTFLANK 0 OUTFLANK-STOCKADE 0 PERMETHRIN (USDA) 0 PEILMETRIN (HUNGARIAN) 0 PERMETRINA PORTUGUESE) 0 3-PHENOXYBENZYL (*)-3-(2,2-DICHLORO-
49
decomposition it emits toxic fumes of Cl-. See also ESTERS. AHKSOO CAS: 50-07-7 HR: 3 AMETYCIN mf: Ci jH18N405 mw: 334.37 PROP: Deep blue-violet crystals. Sol in H20, MeOH, Me2CO. SYNS: 7-AMINO-9-a-METHOXITOSANE
0 MIT-C
0 MITO-C 0 MITOCIN-C 0 MITOLMYCIN0
MITOMYCIN-C 0 MITOMYCINUM 0 MMC 0 MUTAMYCIN 0 MUTAMYCIN (MITOMYCIN for INJECTION) 0 MYTOMYCIN 0 NCI-C04706 0 NSC26980 0 RCRA WASTE NUMBER U0lO
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 10,171,76; NCI Carcinogenesis Studes (ipr); Clear Evidence: rat RRCRBU 52,1,75; No Evidence: mouse RRCRBU 52,1,75. EPA Extremely Hazardous Substances List. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Human systemic effects by intravenous route: dyspnea and lung fibrosis, hemolysis with or without anemia, changes in tubules (including acute renal failure, acute tubular necrosis), normocytic anemia. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also CARBAMATES and ESTERS.
AHL750 HR: D AMIDES VINYL)-2,2-DIMETHYLCYCLOPRO-PANECARBOXYL- PROP: Organic compounds containing the ATE 0 (3-PHENOXuPHENYL-rVIETHYL-3-(2,2-DICHLOstructural group -CONHz, and closely RETHENYL)-2,2-DIMETHYLCYCLOPROPANECARBOrelated to the organic acids with the XYLATE 0 POUNCE 0 PP 557 0 S-3151 0 SBP-1513 0 grouping -COOH. Common examples are: TALCORD 0 W'L 43479 acetamide (CH3CONH2) and urea SAFETY PROFILE: Poison by inhalation, (CO(NH2)2). intravenous, and intracerebral routes. SAFETY PROFILE: Most of the saturated Moderately toxic by ingestion. Experimental amides have low toxicity, but the reproductive effects. Mutation data unsaturated and N-substituted amides are reported. A skin irritant. When heated to
El
50 A ~ 0 2 5 0 " - A MIDINOSULFANILAMIDE irritants and may be absorbed via skin contact. Can cause injury to the liver, hdney, and brain. AH0250 CAS: 57-67-0 HR: 2 N'-AMIDINOSULFANILAMIDE mf: C7H10N402S mw: 214.27 PROP: Colorless, monoclinic crystals or needles from aqueous solns. Mp: 189-190'. Sltly sol in alc; insol in ether; solubility in water = 0.19% @ 37'. SYNS: ABIGUANIL 0 4-AhlIr\lO-N-(AMINOIh~INOMETHYL)BENZENESULFONAMIDE 0 p-AMINOBENZENESULFONYLGUANIDINE 0 N-pASIINOBENZENESULPHONYLGUANIDINE MONOHYDRATE 0 4-ANINO-N-@IAMINOMETH~ENE)BENZENESULFONAhlIDE 0 ATERIAN 0 BENZENESLLFONAMIDE, 4-AMINO-N-
(DIAhfIN0METHYLENE)- 0 N]-(DIAMINOhIETHYLENE)SULFANILAMIDE 0 GANIDAN 0 GUAMIDE 0 GUANICIL 0 GUANIDAN 0 GUANIDINE, SULFANILYL- 0 Ni-GUANn-SULF-APU'IWMIDE 0 RESULFON 0 RP 2275 0 RUOCID 0 SHIGATOX 0 SUGANYL 0 SULFAGUANIDINE 0 SULFAGUINE 0 SULFANILGUANIDINE 0 SULF-ANILYLGUANIDINE 0 SULFOGUANIDINE 0 SULFOGUENIL 0 SULFOQUANIDINE 0 SULGIN 0 SULPHA-GUANIDINE
AHR240 CAS: 99-92-3 HR: 3 p-AMINOACETOPHENONE mf: CsH9NO mw: 135.18 PROP: Crystalline. Mp: 106O, bp: 293-295'. Sol in C6H6, alc, hot acids, and ether. Insol in water. SYNS: 4-ACETYLANILINE 0 4'-AhlINOACETOPHENONE 0 p-AMINOACETYLBENZENE USAF EK631 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NO,. See also AROMATIC AMINES.
AHRSOO CAS: 99-03-6 HR: 2 3'-AMINOACETOPHENONE mf: CsH9NO mw: 135.18 PROP: Yellow, oily liquid or pale-yellow plates from alc. Bp: 251' (slt decornp), mp: 97-99', Insol in water; sol in alc and ether. SYNS: m-ACETYLANILINE 0 3-ACETYLANILINE 0 pAMINOACETOPHENONE 0 m-AMINOACETOPHENONE 0 m-AMINOACETYLBENZENE CONSENSUS REPORTS: Reported in EPA
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
TSCA Inventory.
SAFETY PROFILE: Moderately toxic by ingestion. Mddly toxic by skin contact. A s h n and eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also AROMATIC AMINES.
SAFETY PROFILE: Moderately toxic by
intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. See also SULFONATES. When heated to decomposition it emits very toxic fumes of SO, and NO,. AHP750 HR: D AMINES PROP: A large group of organic compounds containing nitrogen and considered as derived from ammonia (NH3) by replacement of one or more hydrogen atoms by an organic radlcal. See also specific compounds. SAFETY PROFILE: Variable toxicity; some are poisons, some are only slightly toxic. Many are skin irritants and some are sensitizers. See also AROMATIC AMINES and AMINES, FATTY.
AIA750 CAS: 82-45-1 HR: 2 1-AMINOANTHRAQUlNONE mf: C14HgN02 mw: 223.24 PROP: Orange to red needles. Mp: 256', bp: sublimes. Insol in water; sol in HC1, alc, benzene, ether, and chloroform. SYNS: 1-AMINO-9,1O-ANTHRACENEDIOU i E O l AMINOANTHRACHINON (CZECH) 0 aAMINOANTHRAQUINONE 0 I-AMINO-9,lOANTHRAQUINONE 0 a-ANTHRAQUINONn-AMINE 0 C.I. 37275 0 DIAZO FAST RED AL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by intraperitoneal route. An eye irritant. Questionable carcinogen with experimental
m-AMINOBENZAL FLUORIDE AID500
tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic NO,. See also AMINES. AIBOOO CAS: 117-79-3 HR: 3 2-AMINOANTHRAQUINONE mf: C14H9N02 mw: 223.24 PROP: Red needles from alc. Mp: 302-306', bp: sublimes. Insol in water and ether; sol in alc and benzene. SYNS: 2-AMIN0-9,lO-ANTHRACENEDIONE 0 2AMINO-9,lO-ANTHRAQUINONE 0 P-AMINOANTHRAQUINONE 0 P-ANTHRAQUINONYL-AMINE 0 NCI-C01876
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 2?,191,82. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NCITR* NCI-CGTR-l44,78. Community Right-To-Know List. Reported in EPA TSCA Inventory. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic via intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic NO,. See also AMINES.
AIC250 CAS: 97-56-3 HR: 3 2-AMINO-5-AZOTOLUENE mf: C I ~ H I ~ N ~mw: 225.32 PROP: Yellow leaflets from alc. Mp: 100'. SYNS: AAT 0 0-AAT 0 o-AMIDOAZOTOLUOL (GERMAN) 0 AMINOAZOTOLUENE (indicator) 0 oAMINOAZOTOLUENE (MAK) 0 4'-AMINO-2,3'AZOTOLUENE 0 4'-AMINO-2:3'-AZOTOLUENE 0 oAMINOAZOTOLUENO (SPANISH) 0 o-AMINOAZOTOLUOL 0 4-AMINO-2',3-DIMETHYLAZOBENZENE 0 4'-AMINO-2,3'-DIMETHKAZOBENZENE 0 o-AT 0 BRASILAZINA OIL YELLOW R 0 BUTTERYELLOW 0 C.I. 11160 0 C.I. 11160B 0 C.I. SOLVENT YELLOW 3 0 2',3-DIMETHYL-4AMINOAZOBENZENE 0 FAST GARNET GBC BASE 0 FAST OIL YELLOW 0 FAST YELLOW AT 0 FAST YELLOW B 0 HIDACO OIL YELLOW 0 2-METHYL-4-((2METHYLPHENYL)-AZ0)BENZENAMINE 0 OAAT 0 OIL YELLOW 0 OIL YELLOW 21 0 OIL YELLOW 2681 0 OIL YELLOW A 0 OIL YELLOW AT 0 OIL YELLOW C 0 OIL YELLOW I 0 OIL YELLOW 2R 0 OIL YELLOW T
51
0 ORGANOL YELLOW 25 0 SOMALIA YELLOW R 0 SUDAN YELLOW RRA 0 o-TOLUENEAZ0-oTOLUIDINE 0 o-TOLUOL-AZO-o-TOLUIDIN (GERMAN) 0 ~-(o-TOLYLAZO)-~-AMINOTOLC'ENE 0 4(0-TOLYLAZ0)-o-TOLUIDINE 0 TULABASE FAST GARNET GB 0 TULABASE FAST GARNET GBC 0 WAXAKOL YELLOW NL
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT ?,56,87; Animal Sufficient Evidence IMEMDT 8,61,75. Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. DFG MAK: Animal Carcinogen; Suspected Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by ingestion. Moderately toxic by subcutaneous route. An experimental teratogen. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also AROMATIC AMINES.
AID500 CAS: 98-16-8 HR: 3 m-AMINOBENZAL FLU0RIDE DOT: UN 2948 mf: C7H6F3N mw: 161.14 PROP: Colorless liquid with aniline-like odor. Mp: 3', bp: 189', d: 1.303 @ 15.5'/15.5', vap d: 5.56. SYNS: m-AMINOBENZOTRIFLUORDE 0 3AMINOBENZOTRIFLUORIDE 0 m-VRIFLUOR0METHYL)ANILINE 0 3-VRIFLUOROMETHYL)ANILINE 0 3-(TRIFLUOROMETHYLBENZENAhfINE 0 USAF MA-4 CONSENSUS REPORTS: EPA Extremely Hazardous Substances Ltst. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by inhalation, ingestion, and intraperitoneal routes. May be moderately toxic by other routes. See also AMINES and FLUORIDES. When heated to decomposition it emits very toxic fumes of F- and NO,.
52 AIF500
2-AMINOBENZENETHIOL
AIF500 CAS: 137-07-5 HR: 3 2-AMINOBENZENETHIOL mf: C6H7NS mw: 125.20 PROP: Needles or liquid. Mp: 23-26', bp: 227.2', flash p: 175'F, d: 1.168, vap d: 4.3. SYNS: o-ASIINOTHIOPHENOL 0 2-AMINOTHIOPHENOL 0 o-MERCAPTOANILINE 0 USAF EK4376 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. Moderately flammable. Can react with oxilzing materials. To fight fire, use water, foam, C02, mist or spray, dry chemical.
AIGOOO CAS: 934-32-7 HR: 3 2-AMINOBENZIMIDAZOLE mf: C7HiN3 mw: 133.17 PROP: Aqueous leaflets or plates from water. Mp: 222-224". Sol in water, alkalies, alc, acetone; very sltly sol in ether. SYN: USAF EK-4037 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Moderately toxic by ingestion. An experimental teratogen. Mutation data reported. When heated to decomposition it emits toxic NO,. See also A R O U T I C AMINES.
AIHOOO CAS: 52329-60-9 2-AMIN0-6-BENZIMIDAZOLYL PHENYLKETONE mf: C14HllN30 mw: 237.28
HR: 3
SYNS: 2-AMINO-5-BENZOYLBENZIMIDAZOLE 0 BEKZIMIDAZOLE, 2-AMINO-5-BENZOYL 0 G-1029 0 KETONE, 2-AMINO-5-BENZIhlIDAZOL~PHENYL 0 METHANONE, (2-A~IISO-1H-BENZInIIDAZOL-5YL)PHENYL- 0 R 18986
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Acute poison by intraperitoneal route. Moderately toxic by ingestion. An experimental teratogen. See also KETONES. A flammable liquid. When heated to decomposition it emits very toxic fumes of NO,.
AIH600 CAS: 150-13-0 HR: 2 p-AMINOBENZOIC ACID mf: C7H7N02 mw: 137.15 PROP: Yellowish to red crystals or prisms. D: 1.374, mp: 187-1 88.5'. Sol in water, alkalies, EtOH, Et20, C6H6. SYNS: ACID0 p-ANINOBENZOICO 0 AMBEN 0 AMINOBENZOIC ACID 0 y-AMINOBENZOIC ACID 0 4-ASIINOBENZOIC ACID 0 1-AMINO-4-CARBOXYBENZENE 0 ANTICANITIC VITAMIN 0 ANTICHROMOTRICHIA FACTOR 0 BACL VITAMIN H1 0 BENZOIC ACID, 4-AMINO- 0 p-CARBOXY-ANILINE 0 4-CARBOXYANILINE 0 p-CARBOXY-PHENYLAMINE 0 CHROMOTRICHIA FACTOR 0 anu-CHROMOTRICHIA FACTOR 0 KYSELINA p-AMINOBENZOOVA 0 PABA 0 P A B A N O ~ PARAMINOL PARANATE SC'NBRELLA 0 TRICHOCHROMOGENIC FACTOR 0 VITAMIN BX 0 VITAMIN H CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 16,249,78. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and intravenous routes. Ingesting large doses can cause nausea, vomiting, skin rash, methemoglobinemia, and possibly toxic hepatitis. Experimental reproductive effects. Mutation data reported. Questionable carcinogen. Combustible. When heated to decomposition it emits toxic fumes of NO,. A topical sunscreen.
AIR250 CAS: 1137-41-3 HR: 3 p-AMINOBENZOPHENONE mf: C I ~ H I I N O mw: 197.25 PROP: Leaflets from alc. Mp: 124O, bp: 246 @ 13 mm. Very sltly sol in cold water; very sol in alc. SYN: USAF A-233 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. See also KETONES and AMINES. When heated to decomposition it emits toxic fumes of NO,.
AIT250 CAS: 51-05-8 HR: 3 p-AMINOBENZOYLDIETHYLAMINOETHANOL HYDROCHLORIDE mf: C I ~ H ~ O N ~ O ~ * Cmw: ~ H272.81
5-AMINO-l-BIS(DlMETHYLAMIDE)-PHOSPHORYL-3- AIXOOO 53 PROP: Mono- or triclinic, six-sided plates.
Mp: 153-156'. Sol in H20, EtOH; insol in EtaO. SY NS: ALLOCAINE 0 p-AMINOBENZOIC ACID-2DIETHYLAMNOETHYL ESTER, HYDROCHLORIDE 0 4-AMINOBENZOIC ACID 2-(DIETHYLAMINO)-ETHYL ESTER, HYDROCHLORIDE 0 AMINOCAINE 0 ANADOLOR 0 ANESTHESOL 0 ANESTIL 0 ATOXICOCAINE 0 BERNOCAINE 0 CETAIN 0 CHLOROCAINE 0 DIETHYLAMlNOETHANOL-4AhflNOBENZOATE HYDROCHLORIDE 0 2DIETHYLAiMINOETHYI-p-AMINOBENZOATE HYDROCHLORIDE DUGERASE 0 ETHOCAIXE 0 IROCAINE 0 ISOCAINE-ASID 0 ISOCAINE-HEISLER 0 JUVOCAINE 0 KEROCAINE 0 LACTOCAINE 0 NAUCAINE 0 NEOCAINE 0 NOVOCAINCHLORHYDRAT (GERMAN) 0 NOVOCAINE HYDROCHLORIDE 0 NOVOCAIN HYDROCHLORID (GERMAN) 0 PARACAIN 0 PLANOCAINE 0 PROCAINE HYDROCHLORIDE 0 SCUROCAINE 0 SEVICAINE 0 SYNCAINE 0 TOPOKAIN 0 WESTOCAINE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Human systemic effects: acute renal fdure. May have human reproductive effects. See also ESTERS. When heated to decomposition it emits very toxic fumes of HC1 and NO,. Used as a local anesthetic.
LIFEAiMPlL 0 MARISILAN 0 NSC-528986 0 NUVAPEN 0 OMNIPEN 0 P-50 0 PENBRISTOL 0 PENBRITIN 0 PENBRITIN PAEDIATRIC 0 PENBRITIN SYRUP 0 PENBROCK 0 PENICLINE 0 PENTREX 0 PENTREXL 0 PFIZERPEN A 0 POLYCILLIN 0 PONECIL 0 PRINCIPEN 0 Q I D A h P 0 RO-AiMPEN 0 SEMICILLIN 0 SK-AMPICILLIN 0 SYNPENIN 0 TOKIOCILLIN 0 TOLOMOL 0 TOTACILLIN 0 TOTALCICLINA 0 TOTAPEN 0 ULTRABION 0 ULTRABRON 0 VICCILLIN 0 VICCILLIN S 0 VICILLIN 0 WY-5103
CONSENSUS REPORTS: EPA Genetic Toxicology Program. IARC Cancer Review: Group 3 IMEMDT 50,153,90; Animal Limited Evidence IMEMDT 50,153,90; Human Inadequate Evidence IMEMDT 50,153,90. SAFETY PROFILE: Poison by intracerebral route. Moderately toxic by intraperitoneal route. Human systemic effects by ingestion: fever, agranulocytosis, and other blood effects. An experimental teratogen. Mutation data reported. Questionable carcinogen. When heated to decomposition it emits very toxic fumes of NO, and SO,.
AIXOOO CAS: 1031-47-6 HR: 3 5-AMINO-1-BIS(DIMETHYLAMIDE)PHOSPHORYL-3-PHENYL-1,2,4TRIAZOLE mf: C 1 2 H 1 9 N 6 0 P mw: 294.34 PROP: Solid from alc (ad. Mp: 167-168'. Sol in most org solvs; spar sol in H 2 0 . SYNS: 5-AMINO-l-
AIV500 CAS: 69-53-4 HR: 3 AMINOBENZYLPENICILLIN mf: C 1 6 H 1 g N 3 0 4 S mw: 349.44 PROP: Solid. Mp: 199-202' (decomp).
BIS(DIMETHYLAMIDO)PHOSPHORYL-3-PHENYL-1,2,4TRIAZOLE 0 5.AMINO-l-(BIS(DI~IETHYLAMINO)PHOSPHINYL)-3-PHENYL-l,2,4-TRIAZOLE 0 5AMINO-3-FENIL-l-BIS(-DIMETILAMINO)-FOSFORIL-
SYNS: ACILLIN
BIS(DIMETHYL-AMINO)-FOSFORYL-1,2,4-TRIAZOOL
0 ADOBACILLIN 0 ALPEN 0
AMBLOSIN 0 AMCILL 0 AMFIPEN 0 d-(-)-ctAMINOBENZYLPENICILLIN 0 d-(-)-ctAMINOPENICILLIN 0 6-(d(-)-a-AMINOPHENYIIICETAM1DO)PENICILLANICACID 0 (AMINOPHENYLMETHYL)-PENICILLIN 0 AMIPENIX S 0 AMPERIL 0 AMPI-BOL 0 AMPICILLIN (USDA) 0 dAMPICILLIN 0 d-(-)-AMPICILLIN 0 AMPICILLIN A 0 AMPICILLIN ACID 0 AMPICILLIN ANHYDRATE 0 AMPICIN 0 AMPIKEL 0 AMPIMED 0 A,MPIPEN-IN 0 AiWLISOM 0 AiMPLITAL 0 AMPY-PENYL 0 AUSTRAPEN 0 AY-6108 0 BINOTAL 0 BON-APICILLIN 0 BRITACIL 0 BRL 0 BRL 1341 0 COPHARCILIN 0 CYMBI 0 DIVERCILLIN 0 DOKTACILLIN 0 GRAMPENIL 0 GUICITRINA 0 GUICITRINE 0
1,2,4-TRIAZOLO (ITALIAN) 0 5-AMINO-3-FENYI-l(DUTCH) 0 5-AMINO-3-PHENYL-l-
BIS(DIMETHYLAMIN0)-PHOSPHORYL-1 H-l,2,4TRL4ZOL (GERMAN) 0 5-AMIN0-3-PHENYL-l-BIS
(DIMETHYL-AMINO)-PHOSPHORYLE-l,Z,4-TRIAZOLE (FRENCH) 0 5-AMINO-3-PHENYL-l,2,4-TRIAZOLE-l-YLN,N,N',N'-TETRAiMETHYLl'HOSl'H-ODIAMIDE0 5AMINO-3-PHENYL-I,2,4-TRIAZOLYL-lBIS(DIMETHYLAMID0)PHOSPHATE0 5-AhIINO-3PHENYL-l,2,4-TRIAZOLYL-N,N,N'N'-TETRAMETHYLPHOSPHONAMIDE 0 p-(5-AMINO-3-PHENYL-lH-1,2,4TRIAZOL-1-YL.)-N,iX,X;'-TETRAMETHYL PHOSPHOEIC DIAMIDE 0 BIS(DIMETHYLAMINO)-3-AhfINO-5PHENYLTRIAZOLYL PHOSPHINE OXIDE 0 ENT 27,223 0 NIAGAIt4 5943 0 3-PHENYL-5-AMINO-1,2,4TRIAZOLYI-( 1)-(N,N'-TETRAMETHYL)
54 AIX250 AMlNOBlS(PROPYLAM1NE) DIAMIDOPHOSPHONATE 0 TRIAMIFOS (GERMAN, DUTCH, ITALIAN) 0 TRIAMIPHOS 0 TRIAiWHOS 0 VC'EPSIN 0 WEPSYN 0 N'EPSYN 155 0 WP 155
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. SAFETY PROFILE: Poison by ingestion, skin contact, intraperitoneal, and possibly other routes. An experimental teratogen. Mutation data reported. When heated to decomposition it emits very toxic fumes of PO, and NO,.
AIX250 CAS: 56-18-8 HR: 3 AMINOBlS(PR0PYLAMINE) DOT: UN 2269 mf: C6H17N3 mw: 131.26 PROP: Liquid. Bp: 100" @ 2 mm. SYNS: AMINOBIS(rR0PYLhMINE) 0 BIS-(3A51IPU'OPROPYL)AMINE 0 3,3-DIAMINODIPROPYLAMINE 0 3,3'-DIAMINODIPROPYLAMINE 0 DIPROPYLENETRIAMINE 0 IMINOBIS(I'R0PYLAMINE) 0 3,3'-IhlINOBIS(PROPYLi\MINE) 0 1,3PROPANEDIAMINE, N-(3-AMINOPROPYL)- 0 PROPYLAMINE, 3,3'-IMINOBISCONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by skin contact.
Moderately toxic by ingestion. A shn and severe eye irritant. When heated to decomposition it emits toxic fumes of NO,. An explosive.
by ingestion: changes in tubules (includmg acute renal failure, acute tubular necrosis), hematuria, and increased body temperature. Experimental reproductive effects. An eye irritant. When heated to decomposition it emits toxic fumes such as NO,. AJD750 CAS: 26148-68-5 HR: 3 AMINO-a-CARBOLINE mf: CllH9N3 mw: 183.2 PROP: Crystals from CHCls/hexane or EtOH. Mp: 202-203". SYNS: 2-AMINO-a-CARBOLINE 0 2-AMINO-9HPYRID0(2,3-B)INDOLE CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 40,245,86. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
AJK750 CAS: 1951-25-3 HR: 3 AMINODARONE mf: C Z ~ H Z ~ I Z N Omw: ~ 645.35 SYNS: AMIODARONE
0 2-BUTYL-3-BENZOFbRANYL
p-((2-DIETHYLAMINO)ETHOXY)-m,m-DIIODOPHEXYL KETONE 0 2-BUTYL3-(3,5-DIIODO-4-(2-
DIETHYLAMINOETHOXY-BENZ0YL)BENZOFURAN 0 2-N-BUTn-3',5'-DIIODO-4'-N-
DIETHYLAMINOETHOXY-3-BENZOYLBESZOYLBEXZOFVRAN 0 L. 3428 0 LABAZ
AJDOOO CAS: 60-32-2 HR: 2 6-AMINOCAPROIC ACID mf: C6H13N02 mw: 131.20 PROP: Leaflets. Mp: 204-206'. Sol in water; insol in EtOH. SYNS: ACEPMMINE 0 ACS 0 AFIBRIN 0 AMICAR 0 AMINOCAPROIC ACID 0 w-AMINOCAPROIC ACID 0 &AMINOCAPROIC ACID 0 o-AMINOHEXANOIC ACID 0 AMINOKAPRON 0 CAPRALENSE 0 CAPRAMOL 0 CAPROCID 0 CAPROLISIN 0 CL 10304 0 CY 116 0 EACA 0 EACA KABI 0 EACS 0 EPSAMON 0 EPSICAPRON 0 HEMOCAPROL 0 HEMOPAR 0 HEPIN 0 IPSILON 0 177J.D. 0 &-LEUCIPU'E0 &-NORLEUCINE 0 NSC-26154 0 RESPRAMIN CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Human systemic effects by ingestion: photosensitivity of the shn. A flammable liquid. When heated to decomposition it emits very toxic fumes of I- and NO,. A coronary vasoddator.
AJQIOO CAS: 109-55-7 HR: 3 1-AMINO-3-DIMETHYLAMINOPROPANE mf: C5H14N2 mw: 102.21 PROP: Colorless liquid. Mp: <-70°, bp: 132-135", flash p: 100°F (OC), d: 0.8100 @ 30°, vap press: 10 mm @ 30°, vap d: 3.52.
SAFETY PROFILE: Moderately toxic by
SYNS: N,N-DIh~ETHYI-N-(3-AINOPROPYL)-AMINE
intravenous route. Human systemic effects
0
3-(DIllrETHYLAMINO)PROPYLAMINE 0 N,N-
4-AMINODIPHENYL AJSl00 DIMETHYL-1,3-DIAMINOPROPANE 0 N,N-DIMETHYL1,3-PROPANEDIAMINE0 N,N-DIMETHYL-1,3PROPYLENEDIAMINE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and skin contact. A skin and eye irritant. Very flammable when exposed to heat, flame, or oxidmers. Reaction with 1,2dichloroethane produces explosive acetylene gas. This and other amines igmte on contact with cellulose nitrate of h g h surface area. To fight fire, use alcohol foam, COZ,dry chemical. When heated to decomposition it emits toxic fumes of NO,. See also AMINES.
AJQ6OO CAS: 77094-11-2 HR: 3 2-AMINO-3,4-DIMETHYLIMIDAZ0(4,5f)QUlNOLlNE mf: C12H12N4 mw: 212.28 PROP: Solid. Mp: 296-298' (sealed tube).
55
Data IMEMDT 40,283,86; Human Inadequate Evidence IMEMDT 56,211,93. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. AJR500 CAS: 68808-54-8 HR: 3 3-AMINO-1,4-DIMETHYL-5H-PYRIDO(4,3-b)lNDOLE ACETATE mf: C I ~ H ~ ~ N ~ * C Z H ~mw: O Z271.35 PROP: Pale-brown needles or small prisms from EtOAc. Mp: 252-262'. SYNS: 1,4-DIMETHYI-5H-PYRIDO(4,3-b)INDOL-3AhlINE ACETATE 0 1,4-DIMETHYT-5H-PYRID0(4,3b)INDOL-3-AMINEMONOACETATE 0 TRP-P-1 (ACETATE)
SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
SYNS: 3,4-DIMETHYL-3H-IMIDAZO(4,5-QQUINOLIN-AJSIOO 2-AMINE 0 MeIQ
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 56,197,93; Animal Sufficient Evidence IMEMDT 56,197,93; Animal Inadequate Evidence IMEMDT 40,275,86; Human No Adequate Data IMEMDT 40,275,86; Human Inadequate Evidence IMEMDT 56,197,93. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
CAS: 92-67-1 HR: 3 4-AMINODIPHENYL mf: ClzHllN mw: 169.24 PROP: Leaflets or colorless crystals from alc (a$. Mp: 53', bp: 302O, d: 1.160 @ 20°/200, autoign temp: 842'F.
SYNS: p-AMINOBIPHENYL 0 4-AMINOBIPHENYL 0 4-AMINODIFENIL (SPANISH) 0 p-AMINO-DIPHENYL 0 BIPHENYLAMINE U (1,l1-BIPHENYL)-4-A1MINE 0 pBIPHENYLAMINE 0 4-BIPHENYL-AMINE 0 PARAAMINODIPHENYL 0 p-PHENYLANILINE 0 XENYLAMIN (CZECH) 0 XENYLAMINE CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 7,91,87; Human Limited AJQ675 CAS: 77500-04-0 HR: 3 Evidence IMEMDT 1,74,72; Animal 2-AMINO-3,8-DIMETHYLlMlDAZO(4,5Sufficient Evidence IMEMDT 1,74,72; f)QUINOXALINE Human Sufficient Evidence IMEMDT mf: CllHllNs mw: 213.27 28,151,82. Reported in EPA TSCA PROP: Crystals. Mp: 295-300' (sealed tube). Inventory. EPA Genetic Toxicology SYNS: 2-AMINO-3,8-DIMETHYI-3H-IMIDAZO(4,5Program. Community Right-To-Know List. QQUINOXALINE 0 ~,~-DIIMETHYL~H-IMIDAZO(~,~OSHA PEL: Cancer Suspect Agent QQUINOXALIN-2-AMINE CONSENSUS REPORTS: IARC Cancer ACGIH TLV: Confirmed Human Carcinogen DFG MAK: Human Carcinogen Review: Group 2B IMEMDT 56,211,93; Animal Sufficient Evidence IMEMDT SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic 56,211,93; Animal Inadequate Evidence and tumorigenic data. Poison by ingestion IMEMDT 40,283,86; Human No Adequate and intraperitoneal routes. Human mutation
56
AJSSOO
2-AMINO-ETHANESELENOL HYDROCHLORIDE
data reported. An irritant. Effects resemble those of benzidine. See also BENZIDINE. Slight to moderate fire hazard when exposed to heat, flames (sparks), or powerful oxidzers. To fight fire, use water spray, mist, dry chemical. When heated to decomposition it emits toxic fumes of NO,. See also AROMATIC AMINES.
AJU250 CAS: 929-06-6 2-AMINOETHOXYETHANOL DOT: UN 3055 mf: C4HllN02 mw: 105.16
HR: 2
SYNS: 2-(2-AMINOETHOXY)ETHANOL 0
AJS9OO CAS: 2697-65-6 HR: 3 2-AMINO-ETHANESELENOL HYDROCHLORIDE mf: C2H7NSe.ClH mw: 160.52 SYN: ETHANESELENOL, 2-AMINO-,
DIGLYCOIAMINE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Moderately toxic by
HYDROCHLORIDE
OSHA PEL: TWA 0.2 mg(Se)/m3 ACGIH TLV: TWA 0.2 mg(Se)/m3 SAFETY PROFILE: Poison by ingestion.
skin contact. Mildly toxic by ingestion. Severe eye and skin irritant. Corrosive and a powerful irritant. When heated to decomposition it emits toxic fumes of NO,.
When heated to decomposition it emits toxic fumes of NO,, Se, and HC1. AJS950 CAS: 2697-60-1 HR: 3 2-AMINOETHANESELENOSULFURIC ACID mf: C2H7N03SSe mw: 204.12 SYN: SELENOSULFURIC ACID, 2-AhlINOETHYL ESTER
OSHA PEL: TWA 0.2 mg(Se)/m3 ACGIH TLV: TWA 0.2 mg(Se)/m3 SAFETY PROFILE: Poison by
intraperitoneal route. When heated to decomposition it emits toxic fumes of NO,, SO,, and Se. AJT250 CAS: 60-23-1 HR: 3 2-AMINOETHANETHIOL mf: C2H7NS mw: 77.16 PROP: Crystals from alc. Mp: 99-100'. Sol in MeOH, EtOH; spar sol in water. SYNS: 2-AMIhOETHYL MERCAPTAN 0 BECAPTAN CISTEAMINA (ITALIAN) 0 CYCTEIKAMINE 0 CYSTEAMIDE 0 CYSTEAhiINE 0 DECARBOXYCYSTEINE 0 LAMBRATES U MEA 0 MECFLIMINE 0 hiERCAhlINE 0 MERCAPTAMINE XlERCAPTOETHYLAhIINE 0 (2-hlERCAPT0ETHYL)ASIINE 0 THIOETHANOLAMINE
Moderately toxic by ingestion. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of SO, and NO,.
p-
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intravenous, subcutaneous, and intraperitoneal routes.
AJVOOO CAS: 132-32-1 HR: 3 3-AMINO-9-ETHYLCARBAZOLE mfi C14H14N2 mw: 210.30 PROP: Solid. Mp: 98-100'. In cancer bioassay both free amine and hydrochloride salt were used. NCITR* NCI-CG-TR-93,78. SYN: 3-AMINO-N-ETHYLCARBAZOLE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. Poison by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NO,. AJV250 CAS: 6109-97-3 HR: 3 3-AMINO-9-ETHYLCARBAZOLEHYDROCHLORIDE mf: C14H14N2.ClH mw: 246.76 PROP: In cancer bioassay both free amine and hydrochloride salt used. NCITR* NCICG-TR-93,78. SYN: NCI-C03043 CONSENSUS REPORTS: NCI Carcinogenesis Bioassay Completed; Results Positive: mouse, rat NCITR* NCI-CG-TR93,78.
1-AMINO-2-METHYLANTHRAQUINONE AKP750 SAFETY PROFILE: Suspected carcinogen
with experimental carcinogenic data. Poison by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and HC1. AKBOOO CAS: 140-31-8 HR: 3 N-AMINOETHYLPIPERAZINE DOT: UN 2815 mf: C6Hi5N3 mw: 129.24 PROP: Lght-colored liquid. D: 0.9852 @? 2Oo/2O0, mp: -19", bp: 220.4", flash p: 200°F (OC), vap d: 4.4.
57
CIBACET RED 3B 0 CIBACET RED E3B 0 CILLA FAST PINK BN 0 C.I. 60710 0 C.I. DISPERSE RED 15 0 C.1. SOLVENT RED 53 0 DIACELLITON FAST PINK B 0 DISPERSE FAST PINK B 0 DISPERSE RED 15 0 DISPERSE RED 25 0 DISPERSOL ORANGE D-G 0 DURANOL RED 2B 0 FENACET FAST PINK B 0 1HYDROXY-4-AMINO-ANTHRAQUINONE 0 4HYDROXY-1-ANTHRA-QUINONYLAMINE 0 INTERCHEM ACETATE PINK BLF 0 INTERCHEM HISPERSE PINK BH 0 MICROSETILE PINK BN 0 NACELAN PINK B 0 NEOSETILE PINK BN 0 ORACET RED 3B 0 PARA M 0 PERLITON PINK 3B 0 SERISOL FAST RED 2B 0 SETACYL PINK 3B 0 SUPRACET BRILLIANT RED 2B
CONSENSUS REPORTS: Reported in EPA
SYNS: AMINOETHYLPIPERAZINE 0 N-@-
TSCA Inventory.
AMIN0ETHYL)PIPERAZINE 0 N-(~-AIMINOETHYL)PIPERAZINE 0 1-(2-AMINOETHYL)PIPERAZINE 0 USAF DO-46
SAFETY PROFILE: Poison by intravenous route. Moderately toxic by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by
intraperitoneal route. Moderately toxic by ingestion and s h n contact. Experimental reproductive effects. A skin and eye irritant. Mutation data reported. See also AMINES. Moderately flammable when exposed to heat, flame, sparks, or powerful oxidlzers. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NO,. AKE250 CAS: 116-85-8 HR: 3 1-AMINO-4-HYDROXYANTHRAQUINONE mf: C14H9N03 mw: 239.24 PROP: Red-violet powder or pink plates from C6H6, violet needles from pet ether. Mp: 207-208". Sol in water, HC1, alc, ether, and benzene. SYNS: 1A-40A 0 ACETATE FAST RED 2B 0 ACETOQUINONE LIGHT GOOSEBERRYRL ACETYLON FAST PINK B D AMACEL PINK B 0 1AMINO-4-HYDROXY-9,lO-ANTHRACENEDIONE 0 1AMINO-4-OXYANTHRAQUINONE 0 9,lOANTHRACENEDIONE, l-AMINO-4-HYDROxY-(9CI)0 ANTHRAQUINONE, 1-AMINO-CHYDROXY-0 ARTISIL DIRECT RED 3BP 0 ARTISIL RED 3BP 0 CALCOSYN PINK B 0 CELANTHRENE RED 3BN 0 CELLITON FAST PINK BA-CF 0 CELLITON FAST PINK BN 0 CELUTATE PINK B 0 CELUTATE PINK BN 0 CELUTATE PINK BY 0 CERVEN DISPERZNI 15 0 CIBACETE RED 3B 0
AK1900 CAS: 102516-61-0 HR: 3 3-(((3-AMINO4-HYDROXYPHENYL)PHENYLARS1N0)TH I0)ALANINE mf: C I ~ H I ~ A S N ~ O ~mw: S 380.32 SYN: ALANINE, 3-(((3-AMINO-4-HYDROXYPHENYL)PHENYLARSINO)THIO)-
OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it
emits toxic fumes of NO,, SO,, and AS. AKP750 CAS: 82-28-0 HR: 3 1-AMINO-2-METHYLANTHRAQUINONE mf: ClsHllNOz mw: 237.27 SYNS: ACETATE FAST ORANGE R 0 ACETOQUINONE LIGHT ORANGE JL 0 l-AMINO-2METHYL-9,lO-ANTHRACENEDIONE 0 ARTISIL ORANGE 3RP 0 CELLITON ORANGE R 0 C.I. 60700 0 C.I. DISPERSE ORANGE 11 0 CILLA ORANGE R 0 DISPERSE ORANGE 0 DURANOL ORANGE G 0 2METHYL1-ANTHRAQUINONYLAMINE0 MICROSETILE ORANGE RA 0 NCI-C01901 0 NYLOQUINONE ORANGE JR 0 PERLITON ORANGE 3R 0 SERISOL ORANGE YL 0 SUPRACET ORANGE R CONSENSUS REPORTS: NTP 10th Report
on Carcinoge,ns.IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Lmited Evidence IMEMDT 27,199,82. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NCITR* NCI-CG-
58
AKS250
2-AMINO-6-METHYLDIPYRIDO( l12-a:3',2'-d)lMIDAZOL E
TR-111,78. Community kght-To-IGow List. Reported in EPA TSCA Inventory. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. AKS250 CAS: 67730-11-4 HR: 3 2-AMINO-6-METHYLDIPYRIDO(1,2a: 3',2'-d)lMIDAZOLE mf: C I I H I O N ~ mw: 198.25 PROP: Yellow prisms from MeOH/EtOAc. SYNS: GLU-P-I 0 6-ME-GLU-P-2 0 6-METHYL DIPYRIDO(1,2-a:3',2'-d)IMIDAZOL-2-AMINE
CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 40,223,86. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. AKT6OO CAS: 76180-96-6 HR: 3 2-AMINO-3-METHYLIMIDAZO(4,5f)QUINOLINE mf: C I I H I O N ~ mw: 198.25 PROP: Crystals from MeOH (a$. CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2A IMEMDT 56,165,93; Animal Sufficient Evidence IMEMDT 40,261$6; Animal Sufficient Evidence IMEMDT 56,165,93; Human No Adequate Data IMEMDT 40,261$6; Human Inadequate Evidence IMEMDT 56,165,93. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. AKZ2OO CAS: 105650-23-5 HR: 3 2-AMINO-1-METHYL-6-PHENYLIMIDAZ0(4,5-B)PY RIDINE mf: C13H12N4 mw: 224.29 SYNS: IMIDAZO(4,5-B)PYRIDINE,2-AMINO-lMETHYL-6-PHENYL- 0 lH-IbIIDAZO(4,5-B)PYRIDIN-2-
AMINE, 1-METHYL-6-PHENYI-(9CI)0 lH-IXIIDAZO(4,jB)PYRIDINE,2-AMINO-1-METHYL-6-PHENYL- 0 PHIP
CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 56,229,93; Animal Sufficient Evidence IMEMDT 56,229,93; Human Inadequate Evidence IMEMDT 56,229,93. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic vapors of NO,. ALDSOO CAS: 62450-07-1 HR: 3 3-AMINO-1-METHYL-5H-PYRID0(4,3b)lNDOLE mf: C I Z H I I N ~ mw: 197.26 SYNS: 3-AMINO-l-~ZETHn-y-CARBOLINE 0 1hlETHYI-3-AMINO-jH-PYRIDO(4,3-b)INDOLE 0 TRP-P2 0 TRYPTOPHAN P2
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 31,255,83. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
ALD750 CAS: 68006-83-7 HR: 3 2-AMINO-3-METHYL-9H-PYRID0(2,3b)INDOLE mf: C12HllN3 mw: 197.2 PROP: Crystals from CHC13/hexane. Mp: 215-218'. SYN: 2-AMINO-3-METHYL-a-CARBOLINE CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 40,253,86. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
2-((4-AMINO-P-NITROPHENYL)AMINO)-ETHANOL
ALF250 CAS: 127-79-7 HR: 2 4-AMINO-N-(4-METHYL-2-PYRlMlDlNYL)-BENZENESULFONAMIDE mf: C l l H 1 2 N 4 0 2 S mw: 264.33 PROP: Cream-colored powder, darkens on exposure to light. Mp: 237' (decomp). Spar sol in water. SYNS: A-310 0 @-AMINOBENZOLSULFONYL))-2AMINO-4-METHYLPYRIMIDIN (GERMAN) 0 CREMOiMERAZINE 0 DEBENAL-M 0 KELAMERAZINE 0 MEBACID 0 MESULFA 0 METHYLPYRIMAL 0 N1-(4METHYL-2-PYRIMIDIN-YL)SULFANILAMIDE 0 METHYLSULFAZIN 0 PERCOCCIDE 0 PRIMAL-M 0 PYRALCID 0 PYRIMAL M 0 ROMEZIN 0 RP 2632 0 2643-RP 0 SEPTACIL 0 SULFAMEMDINE 0 SCLFAMERAZIN 0 SULFAMETHYLDIAZINE 0 SCLPHAMERAZINE 0 SUMEDINE 0 VETA-MERAZINE
AL0750
59
ALL750 CAS: 5307-14-2 HR: 3 4-AMINO-2-NITROANILINE mf: C~H7N302 mw: 153.16 PROP: Black needles with strong green reflection from water. Mp: 137". SYNS: C.I. 76070 0 C.I. OXIDATION BASE 22 0 1,4DIAMINO-2-NITROBENZENE 0 DURAFUR BROWN 0 DURAFUR BROWN 2R 0 DYE GS 0 FOURAMIEN 2R 0 FOURRINE 36 0 FOURRINE BROWN 2R 0 NCI-C02222 0 2NDB 0 2-NITRO-l,4-BENZENEDIAMINE 0 2NITRO-l,4-DIAMINOBENZENE 0 NITRO-pPHENYLENEDIAMINE 0 2-NITRO-1,CPHENYLENEDIAMINE 0 o-NITRO-p-PHENYLENEDIAMINE (MAY, 0 2-NITRO-p-PHENYLENEDIAMINE 0 2-NP 0 2-N-pPDA 0 2-NPPD 0 OXIDATION BASE 22 0 URSOL BROWN RR 0 ZOBA BROWN RR
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal CONSENSUS REPORTS: Reported in EPA Inadequate Evidence IMEMDT 16,73,78. TSCA Inventory. NCI Carcinogenesis Bioassay (feed); No SAFETY PROFILE: Moderately toxic by Evidence: rat NCITR* NCI-CG-TR-169,79; intravenous and subcutaneous routes. Clear Evidence: mouse NCITR* NCI-CGExperimental reproductive effects. When TR-169,79. Reported in EPA TSCA heated to decomposition it emits very toxic Inventory. EPA Genetic Toxicology fumes of NO, and SO,. Program. DFG MAK: Confirmed Animal Carcinogen ALL500 CAS: 99-56-9 HR: 2 with Unknown Relevance to Humans 2-AMINO-4-NITROANILINE SAFETY PROFILE: Suspected carcinogen mf: C6H7N302 mw: 153.16 with experimental carcinogenic and PROP: Dark-red needles from water. Mp: neoplastigenic data. Poison by 201'. Sol in EtOH, Me2C0, C6H6, CHCl3; intraperitoneal route. Moderately toxic by mod sol in dd acids. SYNS: C.I. 76020 0 1,2-DIAMINO-4-NITROBENZENE ingestion. An experimental teratogen. Other 0 NCI-C03941 0 4NDB 0 4-NITRO-1,2-BENZENEDIexperimental reproductive effects. Mutation 0 p-NITROAMINE 0 4-NITRO-l,2-DIAMINOBENZENE data reported. When heated to 0-PHENYLENE-DIAMINE 0 4-NITRO-0-PHENYLENEdecomposition it emits toxic fumes of NO,.
0 4DIAMINE 0 4-NITRO-1,2-PHENYLENEDIAMINE KOPD
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 16,63,78. NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* NCI-CGTR-180,79. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Questionable carcinogen. When heated to decomposition it emits toxic fumes of NO,.
AL0750 CAS: 2871-01-4 HR: 2 2-((4-AMIN0-2-NlTROPHENYL)AMINO)ETHANOL mf: C8HllN303 mw: 197.22 SYNS: ETHANOL, 2-((4-AMINO-2-NITROPHENYL)AMINO)- 0 HC RED NO. 3 0 4-(2-HYDROXYETHYL)AMINO-3-NITROANILINE 0 N1-(2-HYDROXYETH-
YL)-2-NITRO-p-PHENYLENE-DIAMINE 0 NCI-C54022
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 57,153,93; Human Inadequate Evidence IMEMDT 57,153,93; Animal Inadequate Evidence IMEMDT 57,153,93. NTP Carcinogenesis Studies (gavage); Equivocal Evidence:
60 ALQOOO
2-AMINO-5-NITROTHIAZOLE
mouse NTPTR* NTP-TR-281,86; No Evidence: rat NTPTR* NTP-TR-281,86. Reported in EPA TSCA Inventory. SAFETY PROFILE: Questionable carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. ALQOOO CAS: 121-66-4 HR: 3 2-AMI N0-5-N ITROTHIAZOLE mf: C3H3N302S mw: 145.15 PROP: Solid. Mp: 195-196'. SYNS: AMINONITROTHIAZOLE 0 AMINONITROTHIAZOLCM 0 AMINZOL SOLUBLE 0 ENHEMIN 0 ESTIWMIN 0 NCI-C03065 0 NITRAMIN 0 NITRAMINE 0 5-NITRO-2-AMINOTHIAZOLE 0 NITROMIS I D 0 5-NITRO-2-THIAZOLYLAMINE 0 USAF EK-6561 CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 31,71,83. NCI Carcinogenesis Bioassay (feed); No Evidence: mouse NCITR* NCI-CG-TR53,78; Clear Evidence: rat NCITR* NCICG-TR-53,78. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic, tumorigenic, and neoplastigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and SO,. Incompatible with HN03 and H2S04. An antiprotozoal agent. ALQ625 CAS: 58-60-6 HR: D AMINONUCLEOSIDE PUROMYCIN mf: Ci2Hi&03 mw: 294.36 SYNS: AMINONUCLEOSIDE 0 SAN 0 SYTLOMYCIN AMINONUCLEOSIDE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An experimental
teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
ALQ640 CAS: 92065-91-3 HR: 3 2-AMINO-2-OXOETHYL-2,2-DlMETHYLN-((( METHYLAMIN0)CARBONYL)0XY)PROPANIMIDOTHIOATE mf: CgH17N303S mw: 247.35 SYN
PROPANIMIDOTHIOIC ACID, 2,Z-DIblETHYL-N(((METHYLAMIN0)CARBONYL)OXTi)-,2-ASfIK0-2OXOETHYL ESTER
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO, and SO,.
ALS990 CAS: 591-27-5 HR: 3 m-AMINOPHENOL DOT: UN 2946 mf: C6H7NO mw: 109.14 PROP: Prisms from toluene. Mp: 123'. Sol in water and alc; sltly sol in ether. SYNS: m-AMINOFENOL (CZECH) 0 3-AMINO-IHYDROXYE5ENZENE 0 m-AMINOPHENOL (DOq 0 3AMINOPHENOL 0 BASF URSOL E G C I. 76545 0 C.I. OXIDATION BASE 7 0 FOURAMINE EG 0 FOURRINE 65 0 FOURRINE E G 0 FURRO E G 0 FUTRASIINE EG 0 3-HYDROXYANILINE 0 S A K O TEG 0 P E W G O L EG 0 RENAL E G 0 TERTRAL EG 0 URSOL E G 0 ZOBA EG CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by ingestion, subcutaneous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. A skin and eye irritant. When heated to decomposition it emits toxic fumes of NO,.
ALTO00 CAS: 95-55-6 HR: 3 2-AM INOPHENOL DOT: UN 2512 mf: C7H7NO mw: 109.14 PROP: Colorless needles. Mp: 173', bp: subl. Sol in water and alc; very sol in ether. SYNS: 2-AMINO-I-HYDROXYBENZENE 0 oAMINOPHENOL 0 BASF URSOL 3GA 0 BENZOFCR G G 0 C.I. 76520 0 C.I. OXIDATION BASE 17 0 FOLRAMINE OP 0 o-HYDROXYANILINE 0 2-HYDROXYANILINE 0 NAKO YELLOW EGA 0 PARADONE OLIVE GREEN B 0 PELAGOL 3GA 0 PELAGOL GREY G G 0 ZOBA 3GA
PAMINOPROPIONITRILE FUMARA TE AM6 750 6 1 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP
AWAY FROM FOOD SAFETY PROFILE: Poison by intraperitoneal and subcutaneous routes. Moderately toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. An eye irritant. Mutation data reported. When heated to decomposition it emits toxic NO,. See also AROMATIC AMINES. ALT250 CAS: 123-30-8 HR: 3 4-AMINOPHENOL DOT: UN 2512 mf: C6H7NO mw: 109.14 PROP: Colorless crystals or plates from water; sltly sol in water, alc, and ether; insol in chloroform. Mp: 189.6-190.2', bp: 284' (decomp). SYNS: ACTIVOL 0 p-AMINOFENOL (CZECH) 0 4AMINO-l-HYDROXYBENZENE 0 p-AMINOPHENOL (DOT) 0 BASF URSOL P BASE 0 BENZOFUR P 0 CERTINAL 0 C.I. OXIDATION BASE 6A 0 CITOL 0 DURAFUR BROWN RB 0 FOURAMINE P 0 FOURFZNE 84 0 FOURRINE P BASE 0 FURRO P BASE 0 pHYDROXYANILINE 0 4-HYDROXYANILINE 0 NAKO BROWK R 0 PAP 0 PARANOL 0 PELAGOL GREY P BASE 0 PELAGOL P BASE 0 RENAL AC 0 RODINAL 0 TERTRAL P BASE 0 URSOL P 0 URSOL P BASE 0 ZOBA BROWN P BASE
mf: CsH6AsNO*2HzO mw: 219.09 SYNS: ANILINE, p-ARSENOSO-, DIHYDRATE 0 4ARSENOSOANILINE, DIHYDRATE 0 ARSINE, @AMINOPHENYL)OXO, DIHYDRATE
OSHA PEL: TWA 0.5 mg(As)/m3 ACGIH TLV: BEI: 35 p (As)/L inorganic
arsenic and methylated metabolites in urine SAFETY PROFILE: Poison by intraperitoneal and intravenous routes. When heated to decomposition it emits toxic fumes of NO, and As. ALXl20 CAS: 219959-86-1 HR: 3 AMINOPHENYLNORHARMAN mf: C17H13N3 mw: 259.31 SYNS: 9-(4'-AMINOPHENYL)-9H-PYRID0(3,4B)INDOLE 0 BENZENAMINE, 4-(9H-PYRID0(3,4B)INDOL-9-YL)-
SAFETY PROFILE: A poison by ingestion.
Questionable carcinogen with experimental neoplastigenic data reported. Mutation data reported. When heated to decomposition it emits toxic vapors of NO,. AM6500 CAS: 151-18-8 HR: 2 3-AMINOPROPIONITRILE mf: C3H6N2 mw: 70.11 PROP: Liquid; amine odor. Bp: 185'. SYNS: P-AMINOPROPIONITRILE 0 BAPN 0 pCYANOETHYLAMNE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by ingestion, subcutaneous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. An allergen and skin and eye irritant. Mutation data reported. Can cause contact dermatitis, bronchial asthma, and methemoglobinemia with cyanosis. When heated to decomposition it emits toxic fumes of NO,.
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community EghtTo-Ihow Lst. SAFETY PROFILE: Moderately toxic by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Nitriles usually have cyanide-like effects. See also CYANIDE. Easily oxidized and unstable. A storage hazard; it polymerizes to an explosive yellow solid. When heated to decomposition it emits toxic fumes of CNand NO,. For fire and explosion hazards see CYANIDE.
ALVI 00 CAS: 73791-39-6 HR: 3 p-AMINOPHENYLARSINE OXIDE DIHYDRATE
AMB750 CAS: 2079-89-2 HR: 2 B-AMINOPROPIONITRILEFUMARATE mf: C3H6N2*2C4H404 mw: 302.27
62 AMCOOO p-AMINOPROPIOPHENONE SYNS: P-APN 0 BAPN FUMARATE 0 DI-0AMINOPROPIONITRILE FUhWRATE 0 DI-BAPN FUhWRATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Cyanide and its compounds are on the Community RightTo-Know List. SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. An experimental teratogen. When heated to decomposition it emits toxic fumes of NO, and CN-. See also NITRILES. AMCOOO CAS: 70-69-9 HR: 3 p-AMINOPROPI0PHEN0NE mf: C ~ H I I N O mw: 149.21 PROP: Needles from water. Mp: 140". SYNS: 1-(4-AMISOPHENYL)-l-PROPA~OSE 0 ETHYL-p-AhIINOPHENYL KETONE 0 PAPP 0 PARhMINOPROPIOPHEhONE 0 USAF UCTL-1856
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Ingestion of large doses can cause cyanosis. A flammable liquid. When heated to decomposition it emits toxic fumes of NO,.
AMESOO CAS: 299-26-3 3-(2-AMIN0PROPYL)INDOLE mfi C I I H I ~ N ~ mw: 174.27
HR: 3
SYNS: INDOPAN 0 a-METHYL-PINDOLAETHYLA;2.IINE (GERMAN) 0 a-METHYL-@ INDOLEETHYLAiMINE 0 a-hlETHYLTRYPTAMIKE SAFETY PROFILE: Poison by ingestion and
intraperitoneal routes. Moderately toxic by subcutaneous route. Human psychotropic effects by ingestion. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of NO,. AMF250 CAS: 123-00-2 HR: 3 4-AMINOPROPYLMORPHOLINE mf: C7H16N20 mw: 144.25
PROP: Liquid, Mp: -15", bp: 224.7", flash
p: 220°F (OC), d: 0.9872 @ 2Oo/2O0, vap press: 0.06 mm @ 20°, vap d: 4.97. SYNS: N-(3-AMINOPROPYJJMORFOLIN 0 N-(3AhIINOPR0PYL)MORPHOLINE 0 MORPHOLINE, NAMNOPROPYLCONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A corrosive material.
Moderately toxic by several routes. A severe skin and eye irritant. Combustible. Can react with oxidizing materials. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits toxic fumes of NO,. AMG750 CAS: 54-62-6 HR: 3 AMlNOPTERlDlNE mf: C19H20N8Oj mw: 440.47 PROP: Yellow needles, sol in sodium hydroxide s o h SYNS: 4-AMINO-4-DEOXYPTEROYLGLUTAMATE 0 4-AMINO-PGA 0 AMINOPTERIN 0 4AMINOPTEROYLGLUTAMIC ACID 0 APGA 0 ENT 26,079 0 FOLIC ACID, 4-AMINO- 0 NSC-739 CONSENSUS REPORTS: EPA Extremely Hazardous Substances Llst. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Human and experimental teratogenic data. Other experimental reproductive effects. Mutation data reported. Human systemic effects by ingestion: gastrointestinal. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NO,.
AMIOOO CAS: 504-29-0 HR: 3 2-AMIN0PYRID INE DOT: UN 2671 mf: C5H6N2 mw: 94.13 PROP: T k t e powder or crystals from ligroin. Mp: 58.1, bp: 210.6'. Sol in water and ether; very sol in alc; sltly sol in ligroin. IDLH 5 ppm. SYNS: o-AMINOPYRIDINE 0 a-AMINOPYRIDINE AMISO-2-PYRIDISE 0 a-PYRIDINAMINE 0 aPYRIDYLAMINE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.5 ppm
AMINOPYRINE SODIUM SULFONATE
AMKSOO
ACGIH TLV: TWA 0.5 ppm DFG MAK: 0.5 ppm (2 mg/m3) DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion,
distorted perceptions, dyspnea, nausea or vomiting. When heated to decomposition it emits toxic fumes of NO,.
inhalation, subcutaneous, intravenous, and intraperitoneal routes. Toxic effects resemble strychnine poisoning. Human systemic effects by inhalation: somnolence, convulsions, and antipsychotic effects. Human central nervous system effects by inhalation. When heated to decomposition it emits highly toxic fumes of NO,.
AM1600 CAS: 143621-35-6 HR: 3 3-AMINO-PYRIDINE-P-CARBOXALDEHYDE mf: C7H9N5S mw: 195.27
AM1250 CAS: 462-08-8 HR: 3 3-AMINOPYRIDINE DOT: UN 2671 mf: C5H& mw: 94.13 PROP: Leaflets or crystals from benzene or ligroin. Mp: 64", bp: 251'. Very sol in water, alc, ether; insol in ligroin.
SYNS: 2-((3-AMINO-2-PYRIDI,UYL)I\.IETHYLENE)HYDRAZINECARBOTHIOAMIDE0 3-
AIMINOPYRIDINE-~-CARBOXALDEHYDE THIOSEMICARBAZONE 0 HYDRAZINECARBOTHIOAMIDE, 2-((3-AMINO-Z-PYRIDISYL)L)hlETHYLENE)0 TRIAPINE
SAFETY PROFILE: A poison by intravenous route. When heated to decomposition it emits toxic vapors of NO, and SO,.
SYNS: m-AMINOPYRIDINE(DOT) 0 AMINO-3PYRIDIKE 0 3-PYRIDINAMINE0 3-PYRIDYLAMINE
AMK5OO CAS: 68-89-3 HR: 3 AMINOPYRINE SODIUM SULFONATE mf: C13H17N304S*Na mw: 334.38 PROP: Minute crystals. Sol in water.
CONSENSUS REPORTS: Reported in EPA
SYNS:
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion,
intraperitoneal, subcutaneous, and intravenous routes. When heated to decomposition it emits toxic fumes of NO,. AM1500 CAS: 504-24-5 HR: 3 4-AM IN0PYRIDINE DOT: UN 2671 mf: CjHbN2 mw: 94.13 PROP: Needles or crystals from benzene. Mp: 158'; sol in water; sltly sol in benzene and ether. SYNS: AMINO-CPYRIDINE 0 y-AMINOPYRIDINE 0 p-AMINOPYRIDINE 0 4-AP 0 AVITROL 0 4PYRIDINAMINE 0 4-PYRIDYLAMINE 0 RCRA WASTE NUMBER PO08 0 VMI 10-3 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Human systemic effects by ingestion: hallucinations and
63
(XNTIPYRINYLMETHYLAMIN0)hlETHANESULFONIC ACID SODIUM SALT 0 METHYLAMINO-ANTIPYRINE SODIUM METHANESULFONATE 0 4-METHYLAMINO1,5-DIMETHYL-2-PHENYL-3-PYRAZOLONE SODIUM METHANESULFONATE 0 METHYLAhlINOPHENYLDIMETHYLP~ZOLONE METHANESULFONATESODIUM 0 1-PHENYL-2,3DIhlETHYL-5-PYRAZOLONE-4-hlETH~MINOMETHANESULFONATESODIUhl0 1-PHENYL-2,3-
DI?VIETHnPYRAZOLONE-(5)-4-rMETHMAMINOMETHANESULFONICACID SODIUM 0 PHENYL DIMETHYL PYRAZOLON METHYL AMINOMETH-ANE SODIUM SULFONATE 0 4-SODIUM METHANESULFONATE METHYLAMINE-ANTIPYRINE 0 SODIUM METHYLAMINO-ANTIPYNE METHANESULFONATE 0
SODIUM-4-I\lETHYLAMINO-1,5-DIMETHYI-Z-
PHENYL-3-PYRAZOLONE4-METHANESULFONATE0 SODIUM NORAMIDOPYRINE METHANESULFONATE 0 S0DICR.I-1-PHENYL-2,3-DIhlETHYL-4-hlETHYL-
AMINOPYRAZOLON-N-METHANE-SULFONATE 0 S0DIUR.I-1-PHENYL-2,3-DI~iETHn-j-PYRhZOLONE-4METHYLAMINO METHANE-SULFONATE 0 SODIUM PHENYLDIMETHYL-PYRAZOLONMETH~~iINOMETHANE SULFONATE
SAFETY PROFILE: Poison by
subcutaneous route. Moderately toxic by several other routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. Questionable carcinogen with experimental neoplastigenic data. See also
64
AMN300
4-AMINO-l,2,5-SELENADIAZOLE-3-CARBOXAMlDE
SULFONATES. When heated to decomposition it emits very toxic fumes of NO,, Na20, and SO,.
PROP: Prismatic crystals from water. Mp: 242' (decomp), bp: 167' @ 13 mm. Sltly sol in water.
AMN300 CAS: 7722-06-7 HR: 3 4-AMINO-1,2,5-SELENADIAZOLE-3CARBOXAMIDE mf: C3H4N40Se mw: 191.07
300 0 COMPLEXON I 0 GLYCINE, N,N-
SYNS: N,N-BIS(CARB0XYMETHYL)GLYCINE0 CHEL
SYNS: NSC-84963 0 1,2,5-SELENADLAZOLE-3CARBOXAMIDE, 4-AMINO-
OSHA PEL: TWA 0.2 mg(Se)/m3 ACGIH TLV: TWA 0.2 mg(Se)/m3 SAFETY PROFILE: Poison by
intraperitoneal route. When heated to decomposition it emits toxic fumes of NO, and Se. AMQSOO CAS: 23757-42-8 HR: 3 4-AMINO-2,2,5,5-TETRAKlS(TRIFLUOROMETHYL)-3-IMIDAZOLlNE mf: C7H3Ft2N3 mw: 357.13 PROP: Solid. Mp: 159.7-1 60.4'. SYNS: 5-AMINO-2,2,4,4-TETRhKIS(TRIFLUOROMETHYL)IMIDAZOLIDINE 0 EXP 338
SAFETY PROFILE: Poison by ingestion, intraperitoneal, and intravenous routes. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits very toxic fumes of F- and NO,.
AMR500 CAS: 26861-87-0 HR: 3 2-AMINO-I ,3,4-THIADIAZOLEHYDROCHLORIDE mf: C2H3N3S*ClH mw: 137.60 SYNS: 2-AhIINO-l,3,4-THIADIAZOLE, MONOHYDROCHLORIDE 0 ATDA HYDROCHLORIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits very toxic fumes of HC1, SO,, and NO,.
AMT500 CAS: 139-13-9 AMlNOTRlACETlC ACID mf: C6H9N06 mw: 191.16
HR: 3
BIS(CARBOXYMETHYL)-(9CI)0 HAMPSHIRE NTA ACID 0 KOMPLEXON I 0 KYSELINA NITRILOTRIOCTOVA 0 NCI-C02766 0 NITRILOTRIACETIC ACID 0 NTA 0 TITRIPLEX I 0 TRIGLYCINE 0 TRIGLYCOLLAhlIC ACID 0 TRILON A 0 a-a',a"TRIMETHYLAiMINETRICARBOXYLIC ACID 0 VERSENE NTA ACID
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 48,181,90; Animal Sufficient Evidence IMEMDT 48,181,90; Human No Adequate Data IMEMDT 48,181,90. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NCITR* NCI-CG-TR-6,77. Reported in EPA TSCA Inventory. Community Right-To-Know List. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NO,.
AMWOOO CAS: 2432-99-7 11-AMINOUNDECANOIC ACID mf: C1tH23N02 mw: 201.35 PROP: Solid. Mp: 190-192'.
HR: 3
SYNS: AMINOUNDECANOIC ACID 0 11AMINOUNDECYLIC ACID 0 NCI-C50613
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Lmited Evidence IMEMDT 39,239,86. NTP Carcinogenesis Bioassay (feed): Clear Evidence: mouse, rat NTPTR* NTP-TR21 6,82. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion. Questionable carcinogen with experimental carcinogenic and neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
AMMONIA
AMY500
65
AMY050 GAS: 61-82-5 HR: 3 AMITROLE mf: C 2 H 4 N 4 mw: 84.10 PROP: Crystals from H20, EtOH, or EtOAc. Mp: 159".
data reported. When heated to decomposition it emits toxic fumes of NO,. An herbicide and plant growth regulator,
SYNS: AMEROL 0 AMINOTRIAZOLE 0 2AMINOTRIAZOLE 0 2-AMINO-1,3,4-TRIAZOLE 0 3AMINOTRIAZOLE 0 3-AMINO-s-TRIAZOLE 0 3AMINO-1,2,4-TRIAZOLE (ACGIH) 0 3-AMINO-1,2,4TRIAZOLE 0 3-AiM"-lH-1,2,4-TNAZOLE 0 AMINOTRIAZOLE (PLANT REGULATOR) 0 AMINO TRIAZOLE WEEDKILLER 90 0 AMINOTRIAZOLSPRITZPULVER 0 AMITOL 0 AhffTRIL 0 AMITRIL T.L. 0 AMITROL 0 AMITROL 90 0 AMITROL-T 0 AMIZOL 0 AMIZOL D 0 AMIZOL DP NAU 0 AMIZOL F 0 AT 0 ATA 0 3,A-T 0 AT-90 AT LIQUID 0 AZAPLANT 0 AZAPLANT KOiMBI 0 AZOLAN 0 AZOLE 0 CAMPAPRIM A 1544 0 CYTROL 0 CYTROL AMITROLET 0 CYTROLE 0 DIUROL 0 DIUROL 5030 0 DOMATOL fl DOMATOL 88 0 ELMASIL 0 EMISOL Cl EMISOL 50 0 EMISOL F 0 ENT 25,445 0 FENAhfINE 0 FENAVAR 0 HERBIDAL TOTAL 0 HERBIZOLE 0 KLEER-LOT 0 ORGA-414 0 RADOXONE TL 0 RAMIZOL 0 RCRA WASTE NUMBER UOll 0 SIMAZOL 0 SOLUTION CONCENTREE T271 0 TRIAZOLAMINE 0 lH-1,2,4-TRIAZOL-3-AhfINE 0 USAF XR-22 0 VOROX 0 VOROX AA 0 VOROX AS 0 WEEDAR ADS 0 WEEDAR AT 0 W'EEDAZIN 0 WEEDAZIN ARGINIT R WEEDAZOL 0 WEEDAZOL GP2 0 WEEDAZOL SUPER 0 WEEDAZOL T 0 WEEDAZOL TL 0 WEEDEX GRANULAT 0 WEEDOCLOR 0 X-ALL L q u d
AMY500 CAS: 766441-7 HR: 3 AMMONIA DOT: UN 1005 mf: H3N mw: 17.04 PROP: Colorless, alkaline, nonflammable gas with extremely pungent odor; liquefied by compression. Mp: -77.7', bp: -33.35', lei: l6%, uel: 25%, d: 0.771 g/liter @ Oo, 0.817 g/liter @ -79O, autoign temp: 1204'F, vap press: 10 atm @ 25.7', vap d: 0.6. Very sol in water; moderately sol in alc. IDLH 300 ppm.
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,92,87; Human Inadequate Evidence IMEMDT 41,293,86; IMEMDT 7,31,74; Animal Sufficient Evidence IMEMDT 7,31,74; IMEMDT 41,293,86. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 0.2 mg/m3 ACGIH TLV: TWA 0.2 mg/m3; Animal Carcinogen DFG MAK: 0.2 mg/m3 (as total dust); Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, tumorigenic, and neoplastigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. Mutation
SYNS: AM-FOL 0 AMMONIA ANHYDROUS 0 AMMONIA, anhydrous, hquefied (DOT) 0 AMMONIAC (FRENCH) 0 AMMONIACA (ITALIAN) 0 AMMONIA GAS 0 AMMONIAK (GERMAN) 0 AMMONIA SOLUTIONS, relauve densty <0.880 at 15 degrees C in water, wlth >50% ammonla (DOT) 0 AMONIAK (POLISH) 0 ANHYDROUS AMMONIA o NITRO-SIL R 717 SPIRIT of HARTSHORN
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 35 ppm ACGIH TLV: TWA 25 ppm; STEL 35 ppm DFG MAK: 20 ppm (14 mg/m3) NIOSH REL: CL 50 pprn DOT CLASSIFICATION:2.3; Label: Poison Gas; DOT Class: 2.2; Label: Nonflammable Gas SAFETY PROFILE: A human poison by an unspecified route. Poison experimentally by inhalation. An eye, mucous membrane, and systemic irritant by inhalation. Mutation data reported. A common air contaminant. Difficult to ignite. Explosion hazard when exposed to flame or in a fire. NH3 + air in a fire can detonate. Potentially violent or explosive reactions on contact with interhalogens (e.g., bromine pentafluoride, chlorine trifluoride), 1,2-&chloroethane (with liquid NH3), boron halides, chloroformamideium nitrate, ethylene oxide (polymerization reaction), magnesium
66
AMY700
AMMONIATED GLYCYRRHIZIN
perchlorate, nitrogen trichloride, oxygen + platinum, or strong oxidants (e.g., potassium chlorate, nitryl chloride, chromyl chloride, &chlorine oxide, chromium trioxide, trioxygen difluoride, nitric acid, hydrogen peroxide, tetramethylammonium amide, thiocarbonyl azide thiocyanate, sulfinyl chloride, thiotriazyl chloride, ammonium peroxodsulfate, fluorine, nitrogen oxide, dinitrogen tetraoxide, and liquid oxygen). Forms sensitive explosive mixtures with air + hydrocarbons, 1-chloro-2,4&nitrobenzene, 2- or 4-chloronitrobenzene (above 16O0C/3O bar), ethanol + silver nitrate, germanium derivatives, stibine, and chlorine. Reactions with silver chloride, silver nitrate, silver azide, and silver oxide form the explosive silver nitride. Reactions with chlorine azide, bromine, iodme, iodine + potassium, heaLy metals and their compounds (e.g., gold(lI1) chloride, mercury, and potassium thallium amide ammoniate), tellurium halides (e.g., tellurium tetrabromide and tellurium tetrachloride) and pentaborane(9) give explosive products. Incompatible in contact with Ag, acetaldehyde, acrolein, B, BI3, halogens, HC103, C10, chlorites, chlorosilane, (ethylene dichloride + liquid ammonia), Au, hexachloromelamine, (hydrazine + alkali metals), HBr, HOC1, Mg(C104)2, N204, NCh, NF3, OFz, P205, P203, picric acid, (K + ASH$, (K + PH3), (K + NaN02), potassium ferricyanide, potassium mercuric cyanide, (Na + CO), Sb, S, SC12, tellurium hydropentachloride, trichloromelamine, N02C1, SbH3, tetramethylammonium amide, SOC12, and thiotrithiazylchloride. Incandescent reaction when heated with calcium. Emits toxic fumes of NH3 and NO, when exposed to heat. To fight fire, stop flow of gas. AMY700 CAS: 1407-03-0 HR: D AMMONIATED GLYCYRRHIZIN PROP: From roots of G&)mhipglabra. SYN: R;IONOAMhIOMUM GLYCYRRHIZINATE
SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes.
ANAOOO CAS: 631-61-8 HR: 3 AMMONIUM ACETATE mf: C2H402*H3N mw: 77.10 PROP: Crystals. Mp: 114', d: 1.07. SYN: ACETIC ACID, AMMONIUM SALT CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Moderately toxic by intraperitoneal route. When heated to decomposition it emits toxic fumes of NO, and NH3.
ANA750 CAS: 12164-94-2 HR: 3 AMMONIUM AZIDE mf: H4N4 mw: 60.08 PROP: Colorless plates. Mp: 160', bp: explodes, d: 1.346, vap press: 1 mm @ 59.2' (sublimes). DOT CLASSIFlCATlON: Forbidden SAFETY PROFILE: Poison by inhalation and ingestion. See also AZIDES. Moderately flammable. Unstable. Explosion hazard upon rapid heating. ANB250 CAS: 1066-33-7 HR: 3 AMMONIUM BICARBONATE (1 : I ) mf: HCOpH4N mw: 79.1 PROP: Hard, colorless to white crystals or solid; faint ammonia odor, stable at room temp, volatile. Decomp below mp. Mp: 107.5' (rapid heating), d: 1.586. Sol in water; insol in alc. SYNS: ACID AMMONIUM CARBONATE 0 AhLVONIUM CARBONATE 0 AJMMONIUMHYDROGEN CARBONATE 0 CARBONIC ACID, MONOAMMONIUM SALT 0 MONOAMhIONIUM CARBONATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of NO, and NH3.
ANBSOO CAS: 7789-09-5 AMMONIUM BICHROMATE DOT: UN 1439
HR: 3
AMMONIUM CARBONATE ANEOOO
mf: CrzH8N207 mw: 252.10 PROP: Bright red-orange crystals; air-stable monoclinic crystals. Mp: decomp, d: 2.936. Sol in water and alc. IDLH Ca [15 mg/m3 {as Cr(VI)Il.
SYNS: AMMONIO (DICROMATO DI) (ITALIAN) 0
AMMONIUMBICHROMAAT (DUTCH) 0 AMMONIUMDDICHROMJAT(DUTCH) 0 AMMONIUW DICHROMAT (GERMAN) 0 AMMONIUM DICHROiMATE 0 AMMONIUM DICHROMATEO 0 BICHROiMATE d'AMMONIUM (FRENCH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Chromium and its compounds are on the Community RightT o - K ~ o wList. OSHA PEL: CL 0.1 mg(Cr03)/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m3; Confirmed Human Carcinogen NlOSH REL: (Chromium(V1)) TWA 25 pg(Cr(VI))/m3; CL 50 pg/m3/15M DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: Confirmed human carcinogen. Poison by inhalation, ingestion, shn contact, and subcutaneous routes. See also CHROMIUM COMPOUNDS. An unstable oxidizer. Moderately flammable; reacts with reducing agents.
67
CONSENSUS REPORTS: Cadmium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m' (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood DFG MAK: DFG BAT: Blood: 1.5 pg/dL; Urine: 15 pg/dL; Suspected Carcinogen NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. A poison. When heated to decomposition it emits toxic fumes of NH3, NO,, and C1-. See also CADMIUM COMPOUNDS.
AND750 CAS: 1111-78-0 HR: 3 AMMONIUM CARBAMATE mf: C H ~ N O Z * H ~ N mw: 78.09 PROP: White, crystalhe, rhombic powder; sol in water and alc; ammonia odor. Sublimes at 60'. SYN AMMONIUM AMINOFORMATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. ANBGOO CAS: 10192-30-0 AMMONIUM BlSULFlTE mf: H3N*H203S mw: 99.12 PROP: A solid.
HR: 2
SYNS: AMMONIUM HYDROGEN SULFITE 0 AMMONIUM MONOSULFITE 0 MONOAMMONIUM SULFITE 0 SULFUROUS ACID, MONOALMMONIUM SALT
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A corrosive solid.
When heated to decomposition it emits toxic vapors of NH4-.
SAFETY PROFILE: Poison by intravenous route. See also CARBAMATES.
ANEOOO CAS: 506-87-6 HR: 3 AMMONIUM CARBONATE mf: (NH4)2C03 mw: 96.11 PROP: Colorless crystals; strong odor of NH3; sharp taste. Decomposes on standing to ammonium bicarbonate. Mp: 58'. Sltly sol in water. SYNS: AMMONIUMCARBONAT (GERMAN) 0 CARBONIC ACID, AMMONIUM SALT 0 CARBONIC ACID, DIAMMONIUM SALT 0 DIAMMONIUM CARBONATE CONSENSUS REPORTS: Reported in EPA
AND250 HR: 3 AMMONIUM CADMIUM CHLORIDE mf: 4NH4CKdC12 mw: 397.3 PROP: Colorless, rhombic crystals. D: 2.01; sol in water.
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous and intravenous routes. When heated to decomposition it emits toxic fumes of NO, and NH3.
68
ANE250
AMMONIUM CHLORATE
ANE250 CAS: 10192-29-7 HR: 3 AMMONIUM CHLORATE mfi ClH3N03 mw: 100.49 PROP: White, unstable, colorless crystals or needles. Very soluble in water. SYN: CHLORIC ACID, AhDfONIUhf SALT DOT CLASSIFICATION: Forbidden SAFETY PROFILE: A powerful oxidizer.
Moderately flammable due to spontaneous chemical reaction. Explosion hazard due to shock, chemical reaction, or exposure to heat. A storage hazard; it map explode at room temperature. Explodes when heated to 100°C. When contaminat-ed it is very sensitive. Solution in water may explode if heated or dried. When heated to decomposition it emits highly toxic fumes of C1- and NO,. Incompat-ible with reducing materials; BrF3; BrFj. ANEJOO CAS: 12125-02-9 HR: 3 AMMONIUM CHLORIDE mfi H4N*C1 mw: 53.50 PROP: White, hygroscopic solid or crystals; salty taste. Bp: 520', mp: 337.8', d: 1.520, vap press: 1 mm @ 160.4' (sublimes). Sol in water, alc, and glycerin. SYNS: AMCHLOR 0 AMMONERIC AhlMONIUMCHLORID (GERMAX) 0 AhLVONIUM STRIATE 0 CHLORID AMONNY (CZECH) 0 DARAMMOK 0 SAL AMMONIA 0 SAL AMMONIAC 0 SALAMMONITE 0 SALMIAC CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: (Fume) TWA 10 mg/m3; STEL 20 mg/m3 ACGIH TLV: TWA 10 mg/m3; STEL 20 mg/m3; (Proposed: 1 mg/m3). SAFETY PROFILE: Poison by subcutaneous, intravenous, and intramuscular routes. Moderately toxic by other routes. A severe eye irritant. Mutation data reported. Explosive reaction with potassium chlorate or bromine trifluoride. Violent reaction (ignition) with bromine pentafluoride, NH4, Nos, and IF7. Reaction with hydrogen cyanide may give the explosive nitrogen trichloride. When heated
to decomposition it emits very toxic fumes of NO,, C1-, and NH3. ANF250 CAS: 16919-58-7 HR: 3 AMMONIUM CHLOROPLATINATE mf: C16Pt*2H4N mw: 443.89 PROP: Cubic, yellow crystals or solid. D: 3.065, mp: decomp. Aq solns slowly photoreduce with substitution. Sol in water. IDLH 4 mg/m3 (as Pt). SYNS: AMMONIUM HEXACHLOROPIATIN-ATE(I~0 AMMONIUM PLATINIC CHLORIDE 0 DIAblIvlONIUM HEXACHLOROPIATINATE (2-) 0 PIATINIC AMMONIUM CHLORIDE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.002 rng(Ft)/m3 ACGIH TLV: TWA 0.002 mg(Pt)/m3 SAFETY PROFILE: Poison by inhalation and ingestion. Human pulmonary system effects by inhalation. See also PLATINUM COMPOUNDS. An explosively unstable compound. Incompatible with KOH (boiling with alkali yields a product which, after drying, will explode @ 205' or if mixed with combustibles). When heated to decomposition it emits very toxic fumes of C1-, NO,, and NH3.
ANFSOO CAS: 7788-98-9 HR: 3 AMMONIUM CHROMATE mf: (NH4)2Cr04 mw: 152.10 PROP: Yellow, crystalline material. Mp: decomp @ 180°, d: 1.91 @ 12". Sol in cold water. IDLH Ca [15 mg/m3 {as Cr(VI)}]. SYNS: AMMONIUM CHROMATE(VI) 0 CHROMIC ACID, DIAMMONIUM SALT 0 DIAMMONIUM CHROMATE 0 NEUTRAL AMMONIUM CHROhL4TE CONSENSUS REPORTS: Chromium and its compounds are on the Community Right-To-Know List. OSHA PEL: CL 0.1 mg(CrO$/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m3; Confirmed Human Carcinogen NIOSH REL: (Chromium(V1)) TWA 25 lg(Cr(VI))/m3; CL 50 pg/m3/15M SAFETY PROFILE: A poison. Mutation data reported. See also CHROMIUM COMPOUNDS. A powerful oxidizer. An
AMMONIUM FLUOROBERYLLATE ANH300
explosion hazard when shocked or heated. When heated to decomposition it emits toxic fumes of NH3, Cr03, and NO,. Incompatible with reducing agents. ANF750 HR: 3 AMMONIUM CHROMIC SULFATE mf: NH4Cr(S04)2*12H20 mw: 478.4 PROP: Green or violet crystals. Mp: 94" (-9H20 @ 94O), d: 1.720, water sol. IDLH Ca [15 mg/m3 {as Cr(VI)}]. CONSENSUS REPORTS: Chromium and its compounds are on the Community Right-To-Know L s t . OSHA PEL: CL 0.1 mg(Cr03)/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m3; Confirmed Human Carcinogen NIOSH REL: (Chromium(VI)) TWA 25 pg(Cr(VI))/m3; CL 50 pg/m3/15M SAFETY PROFILE: A confirmed carcinogen. Poison. See also CHROMIUM COMPOUNDS and SULFATES. When heated to decomposition it emits toxic fumes of NH3, NO,, and SO,. ANF800 CAS: 7632-50-0 HR: 2 AMMONIUM CITRATE mf: C ~ H ~ O ~ * X H ~mw: N 31 1.42 PROP: Granules or crystals. D: 1.48. Sol in water; sltly sol in alc. SYNS: AMMONIUM CITRATE, DIBASIC (DOT) 0 CITRIC ACID, AMMONIUM SALT 0 DIAMMONIUM CITRATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Experimental poison by
intravenous route. A skin and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes. ANHOOO CAS: 13826-83-0 HR: 3 AMMONIUM FLUOBORATE mfi NH4BF4 mw: 104.86 PROP: W t e , colorless, rhombic crystals. D: 1.871 @ 1 5 O , mp: sublimes. Sol in NH40H and water. SYNS: AMMONIUM BOROFLUORIDE 0 AMMONIUM FLUOROBORATE 0 AMMONIUM
69
TETRAFLUOROBORATE 0 AMMONIUM TETRAFLUOROBORATE (1-)
CONSENSUS REPORTS: ReDorted in I
EPA TSCA Inventory. OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mgm/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shft; 10 mg/g creatinine of fluorides in urine at end of shift. NlOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m3 SAFETY PROFILE: A poison and strong irritant. See also FLUORIDES and BORON COMPOUNDS. When heated to decomposition it emits very toxic fumes of F-, NO,, and NH3. ANH250 CAS: 12125-01-8 HR: 3 AMMONIUM FLUORIDE DOT: UN 2505 mf: H4N.F mw: 37.05 PROP: White, colorless, deliquescent crystals. Mp: sublimes, d: 1.009 @ 25'. Very sol in water; sltly sol in alc. SYNS: AMMONIUM FLUORURE (FRENCH) 0 NEUTRAL AMMONIUM FLUORIDE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3
mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift. NlOSH REL: (fluorides, inorganic)-TWA 2.5 mdF) /m3 DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by subcutaneous and intraperitoneal routes. See also FLUORIDES. When heated to decomposition it emits very toxic fumes of F-, NO,, and NH3. Incompatible with ClF3. ANH300 CAS: 14874-86-3 HR: 3 AMMONIUM FLUOROBERYLLATE mfi BeFp2H4N mw: 121.11 SYNS: AMMONIUM TETRAFLUOROBERYLLATE 0 BERYLLATE(2-), TETRAFLUORO-, DIA~hl3fONIUR.I, (T-4)0 BERYLLhTE(2-), TETRAFLUORO-, DIAMMONIUM 0 DIAMMONIUM BERYLLIUM-TETRAFLUORIDE 0
70 AN1250
AMMONIUM HEXAFLUOROTITANATE
DIAIMMONIUMTETRA-FLUOROBERYLLATE 0 (T-4)TETRAFLCORO-BERyLLATE(2-)DIAMMONIUM
SAFETY PROFILE: A poison by ingestion,
inhalation, and intraperitoneal routes. When heated to decomposition it emits toxic vapors of NH4-, Be, and F-. AN1250 CAS: 16962-40-6 HR: 3 AMMONIUM HEXAFLUOROTITANATE mf: F6Ti*H& mw: 193.96 PROP: White solid. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shft. NIOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m3 SAFETY PROFILE: Poison by intravenous route. See also FLUORIDES, AMMONIA, and TITANIUM COMPOUNDS. When heated to decomposition it emits very toxic fumes of F- and NO,. AN1500 CAS: 13815-31-1 HR: 3 AMMONIUM HEXAFLUOROVANADATE mf: F ~ H I ~ N ~ Vmw: 219.09 SYN: HEXAFLUORO VANADATE (3.) TRIAMMON-IUM SALT
OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3
mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shft; TWA 0.05 mg(V205)/m3 NIOSH REL: (Vanadmm Compounds) CL 0.05 m g o /m3/ 15M SAFETY PROFILE: Poison by intravenous route. See also FLUORIDES and VANADIUM COMPOUNDS. When heated to decomposition it emits very toxic NH3, NO,, VO,, and fluorides. ANJOOO CAS: 1341-49-7 HR: 3 AMMONIUM HYDROGEN FLUORIDE DOT: UN 1727/UN 2817 mf: F2H5N mw: 57.06
PROP: W t e , colorless crystals. D: 1.51,
mp: 126', bp: 239'. Will etch glass. Very sol in water; sltly sol in alc. SYNS: ACID AMMONIUM FLUORIDE 0 AMMONIUM BIFLUORIDE 0 AMMONIUM DIFLUORIDE AMMONIUM FLUORIDE comp. wth HYDROGEN FLUORIDE (1:l) 0 AMMONIUM HYDROFLUORIDE 0 AMMONIUM HYDROGEN BIFLUORIDE 0 AM7VONIUM HYDROGEN DIFLUORIDE 0 AMMONIUM HYDROGEN FLUORIDE, solid (UN 1727) (DO?? 0 AMMONIUM HYDROGEN FLUORIDE, solution (UN 2817) (Don
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift. NIOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m3 DOT CLASSIFICATION: 8; Label: Corrosive (UN 1727); DOT Class: 8; Label: Corrosive, Poison (UN2817) SAFETY PROFILE: Caustic poison and strong irritant by all routes. See also HYDROFLUORIC ACID. When heated to decomposition it emits very toxic fumes of F-, NO,, and NH3.
ANJSOO CAS: 7803-63-6 HR: 2 AMMONIUM HYDROGEN SULFATE DOT: UN 2506 mf: NH4HS04 mw: 115.11 PROP: White rhombic crystals; sol in water; insol in acetone. Mp: 146.9', d: 1.78. SYNS: ACID AMMONIUM SULFATE 0 AMMONIUM ACID SULFATE 0 AMMONIUM BISULFATE 0 AMMONIUM MONOHYDROGEN SULFATE 0 MONOAMMONIUM SULFATE 0 SULFURIC ACID, MONOAMMONIUM SALT
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Moderately toxic by
ingestion. A corrosive. See also SULFATES. Dangerous; when heated to decomposition it emits highly toxic fumes of sulfuric acid and SO,, NH3, and NO,.
AMMONIUM MERCAPTOACETATE
ANMSOO
71
ANJ750 CAS: 12124-99-1 HR: 3 AMMONIUM HYDROSULFIDE mf: NH4HS mw: 51.11 PROP: Powder or crystals. Mp: 118' (150 atm), d: 1.17, vap press: 400 mm @ 21.8'.
AgzO, (Ag20 + CzHjOH), AgMn04, HzS04. Dangerous; liquid can inflict burns. Use with adequate ventilation. When heated to decomposition it emits NH3 and NO,.
SYNS: AMMONIUM BISULFIDE 0 AMMONIUM HYDROGEN SULFIDE 0 AMMONIUM HYDROSULFIDE, solution (DOT) 0 AiMIiONIUM MERCAPTAN 0 AMMONIUM SULFHYDRATE 0 MONOAMMONIUM SULFIDE 0 SIRNIK AMONNY 0 TRUE AMMONIUM SULFIDE
ANLIOO CAS: 57267-78-4 HR: 1 AMMONIUM ISETHIONATE mf: C2Hj04S*H3N mw: 142.17
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion,
subcutaneous, and intravenous routes. Moderately toxic by skin contact. Pyroforic in air. See also SULFIDES. When heated to decomposition it emits very toxic fumes of SO,, NO,, and NH3. Incompatible with zinc. ANK250 CAS: 1336-21-6 HR: 3 AMMONIUM HYDROXIDE DOT: NA 2672 mf: H4N*HO mw: 35.06 PROP: Clear, colorless liquid solution of ammonia; very pungent odor. D: 0.90, mp: -77'. Sol in water. S o h contains not more than 44% ammonia. SYNS: AMMONIA AQUEOUS 0 AMMONIA WATER 29% 0 AMMONIA SOLUTIONS, with >lo% but not >35% ammonia (US 2672) (DOT) 0 AMMONIA SOLUTIONS, with >35% but not >50% ammonia (US 2073) (DOT) 0 AQUA AMMONIA CONSENSUS REPORTS: Reported in EPA TSCA Inventory. NIOSH REL: (Ammonia) CL 50 ppm DOT CLASSIFICATION: 8; Label: Corrosive (UN 2672); DOT Class: 2.2; Label: Nonflammable Gas (UN 2073) SAFETY PROFILE: A human poison by ingestion. An experimental poison by inhalation and ingestion. A severe eye irritant. Human systemic irritant effects by ocular and inhalation routes. Mutation data reported. Incompatible with acrolein, nitromethane, acrylic acid, chlorosulfonic acid, dimethyl sulfate, halogens, (Au + aqua regia), HC1, HF, HN03, oleum, ppropiolactone, propylene oxide, AgNO3,
SYNS: ETHANESULFONIC ACID, 2-HYDROXY-, AMMONIUM SALT 0 2-HYDROmTHANE-SULFONIC ACID A,MiiONIUM SALT CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An eye irritant. When heated to decomposition it emits toxic fumes of SO,, NH3, and NO,.
ANMOOO HR: 3 AMMONIUM MAGNESIUM CHROMATE mf: (NH4)2Cr04*MgCr04*6H20 mw: 400.5 PROP: Yellow crystals. Mp: decomp, d: 1.84. Very water-sol. IDLH Ca [15 mg/m3 {as C r 0 1 1 . CONSENSUS REPORTS: Chromium and its compounds are on the Community Right-To-Know List. OSHA PEL: CL 0.1 mg(Cr03)/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m3; Confirmed Human Carcinogen NIOSH REL: (Chromium(VI)) TWA 25 pg(Cr(VI))/rn3; CL 50 pg/m3/15M SAFETY PROFILE: A confirmed carcinogen. A poison. See also CHROMIUM COMPOUNDS and MAGNESIUM COMPOUNDS. Moderately flammable; can explode. Incompatible with reducing agents. When heated to decomposition it can emit toxic fumes of NH3 and NO,. ANMBOO CAS: 5421-46-5 HR: 3 AMMONIUM MERCAPTOACETATE mf: C ~ H ~ O Z S * H ~ Nmw: 108.15 PROP: Colorless liquid; strong skunk-like odor.
72 ANM750
AMMONIUM MOLYBDATE
SYNS: AMhlONIUM THIOGLYCOLATE 0 AMMONIUM THIOGLYCOLLATE 0 THIO-GLYCOLLIC ACID, AMMONIUM SALT 0 USAF MO-2 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. An allergen; can cause contact dermatitis. Emits hydrogen sulfide. See also SULFIDES. When heated to decomposition it emits very toxic NO,, SO,, and NH3.
ANM750 CAS: 13106-76-8 HR: 3 AMMONIUM MOLYBDATE mf: Mo04*2H4N mw: 196.04 PROP: F h t e solid. Sol in water. IDLH 1000 mg/m3 (as Mo). SYNS: AMhIOKIUM PARAMOLYBDATE 0 DIAMMONLM MOLYBDATE 0 MOLYBDIC ACID DIAMhlONIUhi SALT CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 mg(Mo)/m3 ACGlH TLV: TWA Soluble Compounds: TWA 0.5 mg(Mo)/m3 Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Moderately toxic by other routes. An irritant. See also MOLYBDENUM COMPOUNDS. When heated to decomposition it emits toxic fumes of NH3 and NO,.
ANN000 CAS: 6484-52-2 HR: 3 AMMONIUM(1) NITRATE(1:I) DOT: UN 0222/UN 1942/UN 2426 mf: HNOpH3N mw: 80.06 PROP: Colorless crystals. Mp: 169.6", d: 1.725 @ 25", bp: decomp >210'. Solubility: 192/100 @ 20'. SYNS: AMMONIUM NITRATE 0 AMMONIUM NITRATE, h q u d (hot concentrated soluuon) (UN 2426) (DOT) 0 AMLI1LlONIUM NITRATE, with >O 2% combusuble substances (US 0222) (DOT) 0 AMMONIUM NITRATE, with not >O 2% of combusuble substances (UN 1942) (DOT) 0 AMMONIUM SALTPETER 0 HERCO PRILLS 0 NITRIC ACID, A4131OSIU.M SALT U VARIOFORM I
CONSENSUS REPORTS: Community
fight-To-I(now List. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 5.1; Label: Oxidizer (UN 2426); DOT Class: EXPLOSIVE 1.1D; Label: EXPLOSIVE 1.1D (UN 0222); DOT Class: 5.1; Label: Oxidizer (UN 1942) SAFETY PROFILE: A powerful oxidizer and an allergen. See also NITRATES. A relatively stable explosive that has, however, caused many industrial explosions. Violent or explosive spontaneous reactions with acetic anhydride + nitric acid, ammonium sulfate + potassium, copper iron(I1) sulfide, sawdust, urea, barium nitrate, hot water, and ammonium chloride + water + zinc. Forms heat- or shock-sensitive explosive mixtures with acetic acid, aluminum + calcium nitrate + formamide (a blasting explosive), ammonia, charcoal + metal oxides (e.g., rust, copper oxide, zinc oxide above 8OoC), chloride salts (e.g., ammonium chloride, calcium chloride, iron(I1I) chloride, and aluminum chloride), cyanoguanidine, feruhzers (e.g., super phosphate + organic materials above 9OoC), hydrocarbon oils, powdered metals (e.g., aluminum, antimony, bismuth, cadmium, chromium, cobalt, copper, iron, lead, magnesium, manganese, nickel, tin, zinc, brass, stainless steel, titanium, and potassium), nonmetals (e.g., charcoal, and phosphorus), organic fuels (e.g., wax, oils, and stearates), potassium permanganate, sugar, sulfur, and trinitroanisole. Reaction with alkali metals (e.g., sodium) forms an explosive product. Ignites on contact with ammonium &chromate, potassium dichromate, potassium chromate, barium chloride, sodium chloride, potassium nitrate, and chromium(V1) salts. Can ignite when mixed with acetic acid. Use water in large amounts to fight fire. It is important that the mass of materials be kept cool and that burning be extinguished promptly. Ventilate well. May explode under confinement and high temperatures. When heated to decomposition it emits hghly toxic fumes of
AMMONIUM PEROXYCHROMATE ANQ750
NO,. Can react vigorously with reducing materials. Incompatible with, (NH4C1 + heat), (C + heat), organic matter, P,NaOC1, NaC104. Occasional explosions in presence of oil, (NH4)2S04 with K or Na.
73
can emit toxic fumes of NH3 and NO,. See also OXALATES.
ANPOOO HR: 3 AMMONIUM PENTA PEROXODICHROMATE mf: CrzHgNzOlz mw: 332.2 AN0500 CAS: 135-20-6 HR: 3 PROP: IDLH Ca [15 mg/m3 (as Cr(VI))]. AMMONIUM-N-NITROSOPHENYLCONSENSUS REPORTS: Chromium and HYDROXYLAMINE its compounds are on the Community mf: C G H G N ~ O ~ * H ~ mw: N 156.19 Right-To-Know Lst. PROP: Needles from water. Mp: 163-1 64". OSHA PEL: CL 0.1 mg(CrOs)/m3 Sol in water and alc; insol in EtzO. SYNS: CUPFERRON 0 N-HYDROXY-N-NITROSOACGIH TLV: TWA 0.05 mg(Cr)/m3; BENZENAMINE, AMMONIUM SALT 0 KUPFERRON Confirmed Human Carcinogen (CZECH) 0 NCI-C03258 0 N-NITROSOFENYLNIOSH REL: (Chromium(VI)) TWA 25 HYDROXYLAMIN AMONNY (CZECH) 0 8pg(Cr(VI))/m3; CL 50 pg/m3/15M NITROSOPHENYLHYDROXYLAMIN ANVONIUM SALZ (GERMAN) 0 S - I \ ; I T R O S O P H E N Y L H Y D R O - ~ ~ I ~ - ESAFETY PROFILE: A confirmed AMMONIUM SALT carcinogen. An unstable compound. CONSENSUS REPORTS: NTP 10th Report Detonation can be initiated by heat, friction, on Carcinogens. NCI Carcinogenesis or impact. See also CHROMIUM Bioassay (feed); Clear Evidence: mouse, rat COMPOUNDS. Explodes @ 50". When NCITR* NCI-CG-TR-100,78. Reported in heated to decomposition it emits toxic EPA TSCA Inventory. Community Rightfumes of NO,. T o - K ~ o wList. SAFETY PROFILE: Confirmed carcinogen ANP625 CAS: 3825-26-1 HR: 3 with experimental carcinogenic and AMMONIUM PERFLUOROOCTANOATE tumorigenic data. Poison by intravenous mf: C ~ F I ~ O Z * H ~ Nmw: 431.13 route. An eye irritant. Solutions with PROP: Solid. thorium salts are unstable explosives above SYNS: AMMONIUM PENTADECAFLUOROOCTANATE 0 A;\LMONIUMPERFLUORO-CAPRILATE 15°C. Solutions with titanium or zirconium 0 AiXMONIUM PERFLUORO-CAPRYLATE 0 APFO 0 salts are unstable explosives above 40'C. FC-143 0 PERFLUORO-AMMONIUM OCTANOATE When heated to decomposition it emits very CONSENSUS REPORTS: Reported in EPA toxic NH3 and NO,. See also N-NITROSO TSCA Inventory. COMPOUNDS and AMINES. ACGIH TLV: 0.01 mg/m3; Animal Carcinogen AN0750 CAS: 1113-38-8 HR: 3 SAFETY PROFILE: Confirmed carcinogen. AMMONIUM OXALATE Poison by inhalation. Moderately toxic by mf: CzHz04*2H3N mw: 124.12 ingestion. An eye and skin irritant. PROP: Colorless crystals. Mp: decomp, d: Experimental reproductive effects. When 1.50. Sltly sol in water. heated to decomposition it emits toxic SYNS: ETHANEDIOIC ACID DIAMMONIUN SALT 0 fumes of F- and NH3. OXALIC ACID, DIAIMMONIUM SALT DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD ANQ750 HR: 3 CONSENSUS REPORTS: Reported in EPA AMMONIUM PEROXYCHROMATE TSCA Inventory. mf: (NH4)3CrOz mw: 234.1 SAFETY PROFILE: A poison. Can react PROP: Red-brown crystals. Mp: decomp @ violently with (NaOCl+ ammonium 40°, bp: explodes @ 50'. acetate). When heated to decomposition it
74 ANROOO AMMONIUM PERSULFATE CONSENSUS REPORTS: Chromium and
its compounds are on the Community Right-To-Know List. IDLH Ca [I 5 mg/m3 {as Cr(vr,)I. OSHA PEL: CL 0.1 mg(Cr03)/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m3; Confirmed Human Carcinogen NIOSH REL: (Chromium(V1)) TWA 25 lg(Cr(VI))/m3; CL 50 ~g/m3/15M SAFETY PROFILE: A confirmed carcinogen. A poison. See also CHROMIUM COMPOUNDS. Moderately flammable by chemical reaction with reducing agents. A powerful oxidzer. Moderately explosive when heated. When heated to decomposition it emits toxic fumes of NO, and NH3. ANROOO CAS: 7727-54-0 HR: 3 AMMONIUM PERSULFATE DOT: UN 1444 mf: 0&*2H4N mw: 228.22 PROP: Colorless, white, monoclinic crystals. Mp: decomp @ 120°, d: 1.982. Stable as dry solid; decomposes in H20 forming 0 2 . SYNS: AMMONIUM PEROXYDISULFATE 0 PERSULFATE d'AMMONIUM (FRENCH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 0.1 mg/m3 DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Moderately toxic by ingestion. A powerful oxidizer that can react vigorously with reducing agents. Releases oxygen when heated. Mxtures with sodium peroxide are explosives sensitive to friction, heating above 75'C, or contact with C02 or water. Mixtures with (powdered aluminum + water) or (zinc + ammonia) are explosive. Violent reaction with iron or solutions of ammonia + silver salts. Solution with sulfuric acid is a strong oxidzing cleaning solution. When heated to decomposition it emits toxic fumes of SO,, NH3, and NO,.
ANRSOO CAS: 7783-28-0 HR: 2 AMMONIUM PHOSPHATE, DIBASIC
mf: H6N2*H304P mw: 132.08 PROP: White crystals or powder; salty taste. D: 1.619, mp: 185' (decomp). Sol in water; insol in alc. SYNS: AMMONIUM PHOSPHATE 0 DIAMMON-IUM HYDROGEN PHOSPHATE 0 DIBASIC AMMONIUM PHOSPHATE 0 SECONDARY AMMONIUM PHOSPHATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low to moderate
toxicity. See also PHOSPHATES. When heated to decomposition it emits very toxic fumes of PO,, NO,, and NH3. ANR750 CAS: 7772-76-1 HR: 2 AMMONIUM PHOSPHATE, MONOBASIC mf: NH4H2P04 mw: 115 PROP: Brilliant-white crystals or powder. D: 1.803 @ 19', mp: 190'. Sol in water. SAFETY PROFILE: Incompatible with NaOC1. ANSSOO CAS: 131-74-8 HR: 3 AMMONIUM PICRATE DOT: UN 0004/UN 1310 mf: C6H3N307*H3N mw: 246.16 PROP: Red or yellow, rhombic crystals. D: 1.719, mp: decomp, bp: explodes @ 423'. Solubility: 1.1/100 @ 20'. SYNS: AMMONIUM CARBAZOATE 0 AMMONIUM PICRATE, dry or wetted with
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: EXPLOSIVE 1.1D; Label: EXPLOSIVE 1.1D (UN 0004) SAFETY PROFILE: An allergen. Moderately irritating to skin, eyes, and mucous membranes. Moderately flammable by spontaneous chemical reaction. A powerful oxidizer that reacts vigorously with reducing materials. Dangerous explosive when shocked or heated. The presence of trace
AMMONIUM TELLURATE ANV750
metals increases its heat sensitivity. See PICRIC ACID, NITRATES, and EXPLOSIVES, HIGH. When heated to decomposition it emits highly toxic fumes of NO,. ANT000 CASE9080-17-5 HR: 3 AMMONIUM POLYSULFIDE (solution) DOT: UN 2818 SYNS: AWKONIUM POLYSULFIDE, solution (DOT) o AhlMONIUM SULFIDE (POLY-) 0 AMMONIUM SULFIDE, solution, red 0 A W O N I U M TRISULFIDE 0 AP-S 0 DIAMMONIUM TRISULFIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive,
Poison SAFETY PROFILE: Poison by ingestion. Moderately toxic by skin contact. See also AMMONIUM HYDROSULFIDE. When heated to decomposition it emits very toxic fumes of NO,, SO,, and HzS.
ANTI 00 HR: D AMMONIUM POTASSIUM HYDROGEN PHOSPHATE CONSENSUS REPORTS: Carcinogenic Determination: Indefinite IARC** 9,245,75. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. ANT300 CAS: 19441-09-9 HR: 3 AMMONIUM REINECKATE HYDRATE mf: C ~ H ~ O N ~ S ~ * C ~ *mw: H ~354.47 O SYN: CHROMATE(1-),DIAMMINETETRAKIS(lSOTHIOCYANAT0)-, AMMONIUM, HYDRATE
OSHA PEL: CL 0.1 mg(Cr03)/m3 SAFETY PROFILE: Poison by
subcutaneous and intravenous routes. When heated to decomposition it emits toxic fumes of NO,, SO,, and CR. ANU650 CAS: 7773-06-0 HR: 2 AMMONIUM SULFAMATE mf: H2N03S*H4N mw: 114.14 PROP: Deliquescent, hygroscopic, crystalline material (white crystalline solid). Bp: 160' (decomp), mp: 131'. Sol in water,
75
liq NH3, formamide, and glycerol. IDLH 1500 mg/m3. SYNS: AMCIDE
U AMICIDE 0
AM,MAT 0 A,MMATE
0 AMMONIUM AMIDOSULFONATE 0 AhfMONIUM
AMIDOSULPHATE 0 AMMONIUM-SALZ der AMIDOSULFONSAEURE (GERMAN) 0 AMMONIUM SULPHAiMATE 0 AMS 0 IKURIN 0 MONOAMMONIUM SULFAMATE 0 SULFAhtATE 0 SULFAMIC ACID, hlONOAMMONIUM SALT 0 SULFMNSAEURE (GERMAN)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 10 mg/m3; Respirable Fraction: 5 mg/m3; (Proposed: 1 mg/m3). ACGIH TLV: TWA 10 mg/m3; (Proposed: 1 mg/m3). DFG MAK: 15 mg/m3 SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Somewhat explosive when heated or by spontaneous chemical reaction in a hot acid solution. A powerful oxidizer. When heated to decomposition it emits very toxic fumes of NH3, NO,, and SO,. See also SULFONATES and SULFAMIC ACID.
ANU750 CAS: 7783-20-2 HR: 2 AMMONIUM SULFATE (2:l) mf: HsNz04S mw: 132.16 PROP: White rhombic crystals. Mp: >280° (decomp), d: 1.77. Sol in water; insol in alc. SYNS: AMMONIL'M SULPHATE 0
DIAbLMONIUM SULFATE 0 SULFURIC ACID, DIAMMONIUM SALT
CONSENSUS REPORTS: Community Right-To-Know List. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by several routes. Human systemic effects by ingestion: hypermotility, diarrhea, nausea or vomiting. See also SULFATES. Incandescent reaction on heating with potassium chlorate. Reaction with sodmm hypochlorite gves the unstable explosive nitrogen trichloride. Incompatible with (K + NH4N03), KNOz, (NaK + NH4N03). When heated to decomposition it emits very toxic fumes of NO,, NH3, and SO,.
ANV750 CAS: 13453-06-0 AMMONIUM TELLURATE
HR: D
76 ANV800
AMMONIUM TETRACHLORO-PLA TINATE
mf: (NH4)2Te04 mw: 227.7 PROP: W t e powder. Mp: decomp, d: 3.01 @ 25". SYN: TELLURIC ACID, AMMONIUM SALT CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 0.1 mg(Te)/m3 ACGIH TLV: TWA 0.1 mg(Te)/m3 SAFETY PROFILE: Human mutation data reported. See also TELLURIUM COMPOUNDS. When heated to decomposition it emits very toxic fumes of Te, NO,, and NH3. ANV800 CAS: 13820-41-2 HR: 3 AMMONIUM TETRACHLOROPLATINATE mf: CLPt*2H4N mw: 372.99 PROP: Red-brown solid or crystals. Mp: 140-150O (decomp), d: 2.936. Sol in water. IDLH 4 mg/m3 (as Pt). SYNS: PLATINATE(2-),TETRACHLORO-, DIAMMONILN 0 TETRAMINE PLATINUM(I1) CHLORIDE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.002 mg(!?t)/m3 ACGIH TLV: TWA 0.002 mg(Pt)/m3 SAFETY PROFILE: Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of NH3, C1-, and Pt.
ANWSOO HR: 3 AMMONIUM TETRAPEROXO CHROMATE mf: CrH12N308 mw: 234.2 PROP: IDLH Ca [15 mg/m3 {as Cr(VI)}]. CONSENSUS REPORTS: Chromium and its compounds are on the Community fight-To-Know List. OSHA PEL: CL 0.1 mg(Cr03)/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m'; Confirmed Human Carcinogen NIOSH REL: (Chromium(V1)) TWA 25 ~g(Cr(VI))/m3;CL 50 ~g/m3/15M SAFETY PROFILE: A confirmed carcinogen. A poison. Impact explodes @ 50' or in contact with H2S04. See also
CHROMIUM COMPOUNDS. Incompatible with H2S04. When heated to decomposition it emits toxic fumes of NO,. ANW750 CAS: 1762-95-4 HR: 3 AMMONIUM THIOCYANATE mf: CNS*H4N mw: 76.13 PROP: Colorless solid or deliquescent crystals. Mp: 149.6', bp: decomp @ 170°, d: 1.305. Very sol in H20, EtOH; sol in MeOH, Me2CO; prac insol in CHCb and EtOAc. SYNS: ALXMONIUMRHODANATE 0 AMMONIUM RHODANIDE 0 AMMONIUM SULFOCYANATE 0 AMMONIUM SULFOCYANIDE 0 AMTHIO 0 RHODANID 0 RHODANIDE 0 TRANS-AID 0 USAF EK-P-433 0 WEEDAZOL TL CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Human systemic effects by ingestion: hallucinations and distorted perceptions, nausea or vomiting, and other gastrointestinal effects. See also THIOCYANATES. When heated to decomposition it emits toxic fumes of NH3, NO,, SO,, and CN-. Incompatible with KC103 and mixtures with Pb(N03)2.
ANY250 CAS: 7803-55-6 HR: 3 AMMONIUM VANADATE DOT: UN 2859 mf: 03VH4N mw: 116.99 PROP: Colorless to yellow crystals or solid. Mp: 200" (decomp), d: 2.326. SYNS: AMMONIUM METAVANADATE ( D O 3 0 RCRA WASTE NUiMBER P119 0 VANADIC ACID, AMMONIUM SALT CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. ACGIH TLV: TWA 0.05 rng(VzOs)/m3 NIOSH REL: (Vanadmm Compounds) CL 0.05 mg(V)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion, subcutaneous, intravenous, intratracheal, and intraperitoneal routes. Moderately toxic
AMPHOTERICIN B AOC500
by skin contact. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also VANADIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of NH3, VO,, and NO,. ANY750 HR: 3 AMMONIUM VANADO-ARSENATE mf: H40N100 j.3As205'404Vz mw: 1228.78 CONSENSUS REPORTS: Arsenic and its compounds are on the Community kghtTo-Know List. ACGIH TLV: TLV 0.01 mg/m3Confirmed Human Carcinogen; BEI: 35 (As)/L inorganic arsenic and methylated metabolites in urine NlOSH REL: (Vanadium Compounds) CL 0.05 mg(V)/m3/15M; (Arsenic, Inorganic) CL 2 ~g(As)/m3/15M SAFETY PROFILE: Confirmed human carcinogen. Poison by subcutaneous and intravenous routes. See ARSENIC and VANADIUM COMPOUNDS. When heated to decomposition it emits very toxic NO,, NH3, and As.
77
ADENOSINE PHOSPHATE 0 ADENOSINE-5'PHOSPHATE 0 ADENOSINE-5-PHOSPHORIC ACID 0 ADENOVITE 0 ADENYL 0 ADENYLIC ACID 0 tertADENYLIC ACID 0 AjMP 0 5-AMP 0 5'-AMP 0 AMP (nucleoude) 0 CARDIOMONE 0 ERGADENYLIC ACID 0 LYCEDAN 0 MUSCLE ADENYLIC ACID 0 MY-B-DEN 0 MYOSTON 0 NSC-20264 0 PHOSADEN 0 PHOSPHADEN 0 PHOSPHENTASIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Slightly toxic by intraperitoneal route. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of PO, and NO,.
AOA500 CAS: 51-64-9 d-AMPHETAMINE mf: C9H13N mw: 135.23 PROP: Oil. Bp: 102' @ 16 mm.
HR: 3
SYNS: d-Z-A;2;IINO-l-PHENYLPROPANE 0 (+)AMPHETAMINE 0 AMSUSTAIN 0 DEPHADREN 0 DEXhMPHETAhlINE 0 DEXEDRINE 0 aMETHYLPHENETHYLAMINE, d-FORM 0 d-1-PHENYL2-AMINOPROPAN (GERMAN) 0 d-l-PHENYL-2AMINOPROPANE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion,
subcutaneous, intravenous, and intraperitoneal routes. Experimental AOAl00 CAS: 61336-70-7 HR: 2 reproductive effects. Chronic exposure AMOXlClLLlN TRIHYDRATE causes central nervous system damage and mfi C I ~ H I ~ N ~ O ~ S * ~ Hmw: Z O419.50 blood-pressure effects. When heated to SYNS: a-AMINO-p-HYDROXYBENZYLPENICILLIN TRIHYDRATE 0 (ZS-(2-a,j-a,6-P(s*)))-G-((AMIXO(4- decomposition it emits toxic NO,. See other HYDROXYPHENYL)ACETYL)AMINO)-3,3-DIMETHYL-7amphetamine entries. 0x0-4-THIA-1 -AZABICYCLO-(3.2.0)HEPTANE-2CARBOXYLIC ACID TRIHYDRATE 0 BRL 2333 TRIHYDRATE
SAFETY PROFILE: Moderately toxic. An
experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of SO, and NO,. AOA125 CAS: 61-19-8 HR: 1 AMP mf: CloH14Nj07P mw: 347.26 PROP: Solid. Mp: 196-200'. SYNS: ADEiVOSINE-5'-MONOPHOSPHATE U ADENOSINE-5-MONOPHOSPHORICACID 0 ADENOSINE-5'-MONOPHOSl'HORIC ACID 0
AOC500 CAS: 1397-89-3 HR: 3 AMPHOTERICIN B mfi C47H73N017 mw: 924.21 PROP: Deep-yellow prisms from DMF. Insol in H20. SYNS: AMB 0 AMPHOMORONAL 0 AMPHOTERICIN beta 0 AMPHOTERICINE B 0 AWHOZONE 0 FUNGILIN 0 FUNGISONE 0 FUNGIZONE 0 IAB 0 IODOACETAMIDE 0 MYSTECLIN-F 0 NSC-527017 0 TEGOPEN SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Human systemic effects by intravenous route: leukopenia, lung changes, and cardiac changes.
78 AODIZ
AMPICILLIN TRIHYDRATE
Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
ASIYLESTER KYSELINY OCTOVE 0 BIRVENOEL 0 OCTAN AMYLU POLISH) 0 PEAR OIL 0 PENTACETATE 0 I-PENTANOL ACETATE IIi PENTYL ACETATE 0 n-PENTYL ACETATE 0 I-PENTYL ACETATE 0 PRIiMARYAMYL ACETATE
AOD125 CAS: 7177-48-2 HR: 1 AMPICILLIN TRIHYDRATE mfi C I G H I ~ N ~ O ~ S * ~ Hmw: ~ O403.50
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TVG'A 100 ppm ACGIH TLV: TWA 50 ppm; STEL 100 ppm DFG MAK: 50 ppm DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by intraperitoneal route. Human systemic effects by inhalation: conjunctiva irritation, headache, and somnolence. A human eye irritant. Apparently more toxic than butyl acetate. Chronic toxicity is of a low order. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. Moderately explosive in the form of vapor when exposed to flame. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS, AMYL ALCOHOL, and ACETIC ACID.
SYNS: AMCAP 0 AMCILL 0 AMINOBEXZYLPENICILLIN TRIHYDRATE 0 aAMINOBENZYLPENICILLIN TRIHYDRATE 0 AiWERIL 0 AhPICHEL 0 AMPIKEL 0 AMPINOVA 0 A W L I N 0 ANCILLIN 0 CYMBI 0 DIVERCILLIN 0 LIFEAMPIL 0 MOREPEN ?4CI-C56086 PEN A PENSYN 0 POLYCILLIN 0 PRINCILLIN 0 RO-ARPEN 0 TRAFARBIOT 0 UKOPEK 0 VIDOPEN SAFETY PROFILE: Mildly toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of SO, and NO,.
AOD175 CAS: 121-25-5 HR: D AMPROLIUM mf: C I ~ H I ~ C I N ~mw: 278.78 PROP: Crystals from methanol + ethanol. Decomp 248-249'. Sol in water, methanol, 95% ether; insol in isopropanol, butanol, hoxane, acetone, ethyl acetate, acetonitrile, isooctane.
AOD735 CAS: 626-38-0 HR: 3 sec-AMYL ACETATE SYNs 1-[(4-A~~INO-2-PROP~-5-PYRIMIDINYL)DOT: UN 1104 ;LIETHn]-2-METHnPYRIDINIUN CHLORIDE 0 1-(4C7H1402 mw: 130.21 A h l I ~ O - 2 - n - P R O P ~ - 5 - P ~ ~ ~ I D I N Y L ~ ~ E T H ~ ) - 2mf: PICOLINIUM CHLORIDE 0 CORID PROP: Colorless liquid. Bp: 120°, flash p: SAFETY PROFILE: When heated to 73.4'F (CC), d: 0.862-0.866 @ 2O0/2Oo, vap decomposition emits toxic fumes of C1-. d: 4.48, lel: 1.10/0,uel: 7.5%. Sltly sol in water; misc in alc and ether. IDLH 1000 AOD725 CAS: 628-63-7 HR: 3 PPm* n-AMYL ACETATE SYNS: 2-ACETOXYPENTANE 0 sek.AMYLESTER KYSELINY OCTOVE 0 2-AMYLESTER KYSELINY DOT: UN 1104 OCTOVE 0 1-METHYLBUTYL ACETATE 0 2mf: C7H1402 mw: 130.21 PENTANOL, ACETATE 0 2-PENTYL ACETATE PROP: Colorless liquid; pear- or banana-like CONSENSUS REPORTS: Reported in EPA odor. Mp: -78.5', bp: 148' @ 737 mm, TSCA Inventory. ULC: 55-60, lel: 1.1%, uel: 7.5%, flash p: OSHA PEL: TWA 125 ppm 77'F (CC), d: 0.879 @ 2Oo/2O0, autoign ACGIH TLV: TWA 50 ppm; STEL 100 pprn temp: 714'F, vap d: 4.5. Very sltly sol in DFG MAK: 50 ppm water; misc in alc and ether. IDLH 1000 DOT CLASSIFICATION: 3; Label: PPm. Flammable Liquid SYNS: ACETATE d'AMYLE (FRENCH) 0 ACETIC ACID, A i m ESTER 0 AMYL ACETATE (DOT) 0 AlMYL ACETIC ESTER 0 AhIYLAZETAT (GEILMAN) 0
SAFETY PROFILE: Mildly toxic by
inhalation. Human systemic effects by
a-AMYL CINNAMALDEHYDE AOG500
79
inhalation: conjunctiva irritation. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. Moderately explosive in the form of vapor when exposed to heat or flame. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
cause headache, nausea, vomiting, delirium, and methemoglobin formation. Mutation data reported. Extremely flammable if exposed to heat, flame, or powerful oxiduers. Moderately explosive when exposed to flame. Incompatible with oxidzing materials, hydrogen trisulfide. To fight fire, use alcohol foam, dry chemical.
AOD750 HR: 2 AMYL ACETATE (mixed isomers) mfi C7H1402 mw: 130.21 PROP: Colorless liquid; pear-like odor. Mp: -78.5', bp: 148' @ 737 mm, ULC: 55-60, lel: 1.1%, uel: 7.5%, flash p: 77'F (CC), d: 0.879 @ 2Oo/2O0, autoign temp: 714'F, vap d: 4.5.
AOE200 CAS: 598-74-3 iso-AMYLAMINE DOT: UN 2733/UN 2734 mf: CsH13N mw: 87.19
SYN: ACETIC ACID, AMYL ESTER ACGIH TLV: TWA 50 ppm; STEL 100 ppm DFG MAK: 100 ppm (525 mg/m3) SAFETY PROFILE: A s h n irritant. Mildly
toxic by ingestion. Dangerous fire hazard; can react with oxidizing materials. Moderately explosive in the form of vapor when exposed to flame. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. AOEOOO CAS: 71-41-0 HR: 3 AMYL ALCOHOL mf: C5H120 mw: 88.17 PROP: Clear liquid. Mp: -79', bp: 137.8', flash p: 91'F (CC), d: 0.8168 @ 2O0/2Oo, ULC: 40, lel: 1.2%, uel: 10% @ 212'F, vap press: 1 mm @ 13.6', 10 mm @ 44.9', vap d: 3.04. Sol in water; misc in alc and ether. SYNS: ALCOOLAMYLIQUE (FRENCH) 0 N-AMYL ALCOHOL 0 AMYL ALCOHOL, NORMAL 0 NAMYLALKOHOL (CZECH) o s - n u m c A m s o L o NPENTANOL O PENTANOL-1 O PENTAN-1-OL O PENTASOL 0 PENTYL ALCOHOL 0 PRIiMhRY AMYL ALCOHOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and s h n contact. An eye and upper respiratory irritant by inhalation. A severe skin and eye irritant. Ingestion can
HR: 3
SYNS: 2-BUTANAMISE, 3-METHYL-(9CI) 1,2DIMETHYLPROPANAMINE 0 1,Z-DIMETHXPROPYLAMINE 0 3-METHX-2-BUTANAMINE 0 PROPYLAMINE, 1,2-DIMETHYLCONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive, Flammable Liquid (UN 2734); D O T Class: 3; Label: Flammable Lquid, Corrosive (UN 2733) SAFETY PROFILE: Poison by intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
AOGOOO CAS: 540-18-1 HR: 2 n-AMYL BUTYRATE mf: C9H1802 mw: 158.27 PROP: Colorless liquid. D: 0.871, mp: -73.2', bp: 186.4'. Sol in water, misc with alc and ether. SYNS: AiMYL BUTYRATE BUTAKOIC ACID PENTYL ESTER 0 PENTYL BUTYRATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes.
AOG500 CAS: 122-40-7 HR: 2 a-AMYL CINNAMALDEHYDE mf: C14H180 mw: 202.32 PROP: Pale-yellow oil or liquid; floral jasmine odor. D: 0.963, refr index: 1.554, bp: 174-175' @ 20 mm. Sol in fixed oils; insol in glycerin and propylene glycol.
80
AOG600
AMYL CINNAMATE
SYNS: a-A,Mn CINNAMIC ALDEHYDE 0 a - A M n - P PHENYLACROLEIN 0 F E U 4 No. 2061 0 JASMINALDEHYDE 0 a-PENTYLCINNAM-ALDEHYDE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
ingestion. A severe skin irritant. See also ALDEHYDES. When heated to decomposition it emits acrid smoke and irritating fumes. AOG600 HR: 1 AMYL CINNAMATE mf: C14Ht802 mw: 218.28 PROP: Colorless to pale-yellow liquid; slt cocoa odor. D: 0.992-0.997, refr index: 1.535, flash p: 212'F. Sol in fixed oils; sltly sol in propylene glycol; insol in glycerin @ 310'. SYNS: FEMA No. 2063 0 I S O A M n CINNAMATE 0 ISOAMYL 3-PENTYL PROPENATE SAFETY PROFILE: Combustible liquid. W e n heated to decomposition it emits acrid smoke and irritating fumes.
AOHlOO CAS: 68527-78-6 HR: I AMYL CINNAMYLIDENE METHYL ANTH RANLATE mf: C22H2jN02 mw: 335.48 SYNS: ANTHRANILIC ACID, W(2-BENZYLIDENEHEPTYLIDENE)., METHYL ESTER 0 METHYL N(P-PENTYLCINNAMYLIDENE)ANTH~NI~TE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A skin irritant. When heated to decomposition it emits toxic fumes of NO,.
A01200 CAS: 692-95-5 AMYLDICHLORARSINE mf: CSHIIASC~Z mw: 216.98
HR: 3
SYNS: N-AMYL,DICHLORARSINE 0 ARSINE, AhWDICHLORO- ARSINE, DICHLOROPENTYL- 0 DICHLOROPENTYLARSINE 0 PENTYLDICHLOROARSINE OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by skin contact.
Moderately toxic by inhalation. When heated to decomposition it emits toxic fumes of As and C1-.
A01800 CAS: 25377-72-4 n-AMYLENE PENTENE DOT: UN 1108 mf: C5HlO mw: 70.15
HR: 3
SYNS: AMYLENE 0 PENTYLENE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Moderately toxic. Very
flammable; reacts with heat, flame, and oxidizing materials. To fight fire, use foam, C02, dry chemical. AOJOOO HR: 3 AMYLENES, MIXED DOT: UN 1106 mf: C5HlO mw: 70.58 PROP: Water-white liquid. Bp: 32.2', flash p: O'F, d: 0.66 @ 20'. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic. Very flammable; reacts with heat, flame, and oxidlzing materials. To fight fire, use foam, C02, dry chemical. AOJ500 CAS: 638-49-3 HR: 3 n-AMYL FORMATE mf: C6H1202 mw: 116.18 PROP: Clear liquid. D: 0.902,0.893 @ 15'/4', mp: -73.5', bp: 130.4', flash p: 80'F. Very sltly sol in water; misc in alc and ether. SYNS: AMYL FORMATE PENTYL FORMATE
PENTYL FORMATE 0 n-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Very low toxicity by
several routes. A s h n irritant. See also ESTERS. Dangerously flammable; reacts vigorously with heat, flame, oxidizing materials. To fight fire, use foam, C02, dry chemical. AOK750 CAS: 105-30-6 AMYL METHYL ALCOHOL
HR: 2
4-n-AMYLPHENOL AOM250
mf: C6H14O mw: 102.20 PROP: Liquid. Bp: 130°, flash p: 114'F (CC), d: 0.804, vap d: 3.52. SYNS: 1,3-DIMETHYLBUTANOL 0 ISOHEXYL ALCOHOL 0 ISOPROPYL DIiMETHYL CARBINOL 0 METHYLAMYL ALCOHOL 0 METHYL. ISOBUTYL CARBINOL 0 2-METHYLPENTANOL-1 0 2-METHYL-2PROPYLETHANOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and skin contact. A skin and severe eye irritant. Human systemic irritant by inhalation. A flammable liquid; can react with oxidizing materials. To fight fire, use Con, dry chemical. When heated to decomposition it emits smoke and acrid fumes.
AOLOOO CAS: 13256-07-0 HR: 3 n-AMYL-N-METHYLNlTROSAMlNE mf: CGHI~NZO mw: 130.22 SYNS: AMN 0 METHYLAMnNITROSAhlIN (GERMAN) METHYLAMnNITROSAiMINE 0 METHYL-N-AMYLNITROSAMINE 0 N-METHYL-N-NITROSOPENTYLAlMINE 0 METHYL-N-PENTYL-NITROSAMINE 0 N-NITROSO-N-METHYL-N-AMYL-AMINE 0 NITROSOMETHYL-N-PENTYLAMINE
CONSENSUS REPORTS: EPA Genetic
Toxicology Program. SAFETY PROFILE: Poison by ingestion, subcutaneous, and intraperitoneal routes. Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic NO,. See also NITROSAMINES and N-NITROSO COMPOUNDS. AOL250 CAS: 1002-16-0 HR: 3 AMYL NITRATE DOT: UN 1112 mf: C5HllN03 mw: 133.17 PROP: Lquid. Bp: 145O, flash p: 125OF (OC), d: 0.99. SYNS: AMYLESTER KYSELINY DUSICNE d'AMYLE (FRENCH)
DOT CLASSIFICATION: 3; Label:
Flammable Liquid
0 NITRATE
81
SAFETY PROFiLE: Moderately toxic by
inhalation. A flammable liquid. An oxidizing agent. When heated to decomposition it emits toxic fumes of NO,. AOL500 CAS: 463-04-7 HR: 3 n-AMYL NITRITE mf: CsHllNOz mw: 117.17 PROP: Clear, yellowish liquid; peculiar, ethereal, fruity odor and pungent, aromatic taste. Bp: 104O, d: 0.853 @ 2Oo/4O, autoign temp: 408'F, vap d: 4.0. SYNS: AMYL NITRITE (DOT 0 1-NITROPENTANE 0 NITROUS ACID, PENTYL ESTER 0 PENTYL NITRITE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by inhalation and ingestion. Causes flushing of skin, rapid pulse, headache, and fall in blood pressure. Mutation data reported. See also NITRITES and ESTERS. Flammable when exposed to heat or flame or by spontaneous chemical reaction. To fight fire, use alcohol foam. An oxidizing material. Vapors explode when heated. It will react with oxidizing or reducing materials. When heated to decomposition it emits toxic fumes of NO,.
AOM125 CAS: 9032-08-0 HR: D AMYLOGLUCOSIDASE PROP: A powder derived from Rhizopzls nivezls with diatomaceous earth as a carrier. SYNS: CARBOHYDRASE 0 GLUCOMYLASE SAFETY PROFILE: When heated to
decomposition it emits acrid smoke and irritating fumes. AOM250 CAS: 14938-35-3 HR: 2 4-n-AMYLPHENOL mf: CIIHIGO mw: 164.27 PROP: A liquid. Bp: 342", vap d: 5.66, flash p: 219OF (OC), d: 0.966. SYN: p-PENTYLPHENOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP
AWAY FROM FOOD
82
A OM500
2-sec-AMYLPHENOL
SAFETY PROFILE: Questionable
SYNS: AhWL PROPANOATE
carcinogen with experimental neoplas tigenic data. Moderately flammable. T o fight fire, use foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
0 FEMA No. 2082 0 ISOAhIYL PROPIONATE 0 PENTYL
AOM500 CAS: 26401-74-1 HR: 3 2-see-AMYLPHENOL mf: CllH160 mw: 164.27 PROP: Clear, straw-colored liquid. D: 0.955-0.971 @ 3Oo/3O0, bp: 235-250°, flash p: 200°F. Very sltly sol in water; sol in oils and org solvs. SYN: o-(sec-PENTYL)PHENOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous
route. Questionable carcinogen with experimental neoplastigenic data by skin contact. Moderately flammable when exposed to heat or flame. To fight fire, use foam, fog, dry chemical, water mist or spray, multipurpose dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. AON300 CAS: 131-18-0 AMYL PHTHALATE mf: C18H2604 mw: 306.44
HR: D
SYNS: AMOIL 0 1,2-BENZENEDICARBOXYLICACID, DIPENTYL ESTER 0 DIAMYL PHTHALATE 0 DIPENTYL PHTHALATE 0 DI-n-PENTYL-PHTHALATE 0 DPP 0 PHTHALIC ACID, DIPENTYL ESTER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes.
AON350 CAS: 624-54-4 HR: 3 AMYL PROPIONATE mf: C8H1602 mw: 144.24 PROP: Colorless liquid; fruity, apricotpineapple odor. D: 0.866, refr index: 1.405-1.409, flash p: 106°F. Sol in alc, fixed oils; insol in glycerin, propylene glycol, water @ 160".
0 n-AMYL PROPIOXATE
PROPANOATE 0 n-PENTYL PROPANOATE 0 PENTYL PROPIONATE 0 PROPANOIC ACID, PESTYL ESTER 0 PROPIONIC ACID, PENTYL ESTER (bCI,7CI,8CI)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low toxicity by ingestion and skin contact. An eye irritant. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
AON750 CAS: 64-43-7 HR: 3 AMYTAL SODIUM mf: C l l H 1 7 N 2 0 3 a N a mw: 248.29 SYNS: 5-ETHYL-5-ISOPENTYLBARBIT~RICACID SODIUM SALT 0 5-ETHYI-5-(3-METHYLBUTYLBARBITURIC ACID, SODIUM DERIVATIVE 0 5ISOAh~-j-ETHYIBARBITURICACID, SODIUM DERIVATIVE 0 SODIL'M AIMYLOBARBITOSE 0 SODIUM ETHYLISOAMYLBARBITURATE 0 SODIUM ISOAMYLETHYL BARBITURATE SAFETY PROFILE: Poison by ingestion,
subcutaneous, intravenous, and intraperitoneal routes. When heated to decomposition it emits toxic NO, and NazO. A00760 CAS: 8015-64-3 HR: 2 ANGELICA OIL, root PROP: Extracted from roots of Angelica archangelica L. A pale-yellow to amber liquid; pungent odor with bittersweet taste. Sol in fixed oils; sltly sol in mineral oil; insol in glycerin, propylene glycol. SYNS: ANGELICA ROOT OIL 0 ANGELIKA OEL 0 OILS, ANGELICA ROOT CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes.
A00790 HR: D ANGELICA SEED OIL PROP: Extracted from seeds of Angelica archangelica L. A light yellow liquid; sweet taste. Sol in fixed oils; sltly sol in mineral oil; insol in glycerin, propylene glycol.
ANILINE
AOQOOO
83
SAFETY PROFILE: When heated to
DFG MAK: 2 pprn (7.7 mg/m3), Confirmed
decomposition it emits acrid smoke and irritating fumes.
Animal Carcinogen with Unknown Relevance to Humans; BAT: 1 mg/L in urine at end of shift DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Suspected carcinogen with experimental neoplastigenic data. A human poison by an unspecified route. Poison experimentally by most routes incluhng inhalation and ingestion. Experimental reproductive effects. A skin and severe eye irritant, and a rmld sensitizer. In the body, aniline causes formation of methemoglobin, resulting in prolonged anoxemia and depression of the central nervous system; less acute exposure causes hemolysis of the red blood cells, followed by stimulation of the bone marrow. The liver may be affected with resulting jaundice. Long-term exposure to a d n e dye manufacture has been associated with malignant bladder growths. A common air contaminant, A combustible liquid when exposed to heat or flame. To fight fire, use alcohol foam, COz, dry chemical. It can react vigorously with oxidizing materials. When heated to decomposition it emits hghly toxic fumes of NO,. Spontaneously explosive reactions occur with benzenediazonium-2-carboxylate, dibenzoyl peroxide, fluorine nitrate, nitrosyl perchlorate, red fuming nitric acid, peroxodisulfuric acid, and tetranitromethane. Violent reactions with boron trichloride, peroxyformic acid, dhsopropyl peroxydicarbonate, fluorine, trichloronitromethane (145OC), acetic anhydride, chlorosulfonic acid, hexachloromelamine, (HN03 + Nz04 + HzS04), (nitrobenzene + glycerin), oleum, (HCHO + HC104), perchromates, KzOZ,ppropiolactone, AgC104, NazOn, HzS04, trichloromelamine, acids, peroxydisulfuric acid, F03C1, diisopropyl peroxy-&carbonate, n-haloimides, and trichloronitromethane. Ignites on contact with sodium peroxide + water. Forms heat- or shock-sensitive explosive mixtures with anhnium chloride
AOP500 HR: 2 ANHYDRIDES PROP: Chemical compounds derived from acids by elimination of a molecule of water. Thus, sulfur trioxide (so3) is the anhydride of sulfuric acid (HzS04); carbon &oxide (C02) is the anhydride of carbonic acid (HzC03); phthalic acid ( C ~ H ~ ( C O Z H ) ~ ) minus water gives phthalic anhydride (C~H~(COZ)O). T h s term should not be confused with anhydrous, meaning without water. SAFETY PROFILE: Anhydrides are aci&c and react with bases in tissue. Thus, they tend to attack and irritate tissue. AOQOOO CAS: 62-53-3 HR: 3 AN ILINE DOT: UN 1547 mf: C6H7N mw: 93.14 PROP: Colorless, oily liquid whch darkens on exposure to light; characteristic odor. Mp: -6', bp: 184.4', lel: 1.3%, ULC: 20-25, flash p: 158°F (CC), fp: -6.2', d: 1.02 @ 20°/4', autoign temp: 1139OF, vap press: 1 mm @ 34.8', vap d: 3.22. IDLH 100 ppm. SYNS: AMINOBESZENE
0 AMINOPHEN 0 ANILIN (CZECH) 0 ANILINA (ITALIAN, POLISH) 0 ANILINE OIL 0 BENZENAMINE 0 BLUE OIL 0 C.I. 76000 0 HUILE d'ANILINE (FRENCH) 0 NCI-C03736 0 PHENYLAiWNE
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,99,87; Animal Inadequate Evidence IMEMDT 4,27,74; Human No Evidence IMEMDT 4,27,74. EPA Extremely Hazardous Substances List. Community Fhght-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 2 pprn (skin) ACGlH TLV: TWA 2 pprn (skm);Animal Carcinogen; BEI: 50 mg/g creatinine of total p-aminophenol in urine at end of shift or 1.5% of hemoglobin for methemoglobin in blood during or end of shift.
84 AOQ500 ANILINE DYES (detonates at 240°C/7.6 bar), nitromethane, hydrogen peroxide, 1-chloro-2,3epoxypropane, and peroxomonosulfuric acid. Reactions with perchloryl fluoride, perchloric acid, and ozone form explosive products. AOQ500 ANILINE DYES
HR: 2
SAFETY PROFILE: The finished dyes are generally very much less toxic than many of the intermediates occurring or used in the manufacture of the dyes. Some of the aniline dyes cause local irritating effects to the eyes, mucous membranes, and shn; the basic dyes are believed to be more irritating than the acid dyes. Allergic responses to a d n e dyes have been known to occur. See also specific compounds. When heated to decomposition they emit toxic fumes of NO, and possibly
CHLORIDE 0 HEXAMETHYL-p-ROSANILINE CHLORIDE 0 HEXAMETHYL-p-ROSANILINE HYDROCHLORIDE 0 HEXAMETHYL VIOLET 0 HIDACO BRILLIANT CRYSTAL VIOLET 0 HIDACO CRYSTAL VIOLET 0 KRISTALL-VIOLETT 0 MEROXYL 0 MEROXYLAN 0 MEROXYLAN-WANDER 0 MEROXYL-WANDER 0 METHYLROS-ANILINCHLORID 0 METHYLROSANILINE CHLOR-IDE METHYLROSANILINUbI CHLOIMTUhI 0 METHYL VIOLET 10B 0 METHYL VIOLET 10BD 0 METHYL VIOLET lOBK 0 METHYL VIOLET 10BN 0 METHYL VIOLET 5BN0 0 METHYL VIOLET lOBNS 0 METHYL VIOLET 5B0 0 METHYL VIOLET lOBO 0 hlETHYLVIOLETT 0 MITSUI CRYSTAL VIOLET 0 NCIC55969 0 OXIUIMN 0 OXYCOLOR 0 OXYOZYL 0 PAPER BLUE R 0 PARAROSANILINE, N,N,N',N',N",N"HEXAMETHYL-, CHLORIDE 0 PUSTORESIN VIOLET 5 B 0 0 PYOKTANIN 0 PYOVERM 0 VERMICID 0 VIANIN 0 VIOCID 0 12416 VIOLET 0 VIOLET 6BN 0 VIOLET 5B0 0 VIOLET CP 0 VIOLET GENCIANOVA 0 VIOLET KRYSTALOVA 0 VIOLET XXIII 0 VIOLET ZASADITA 3
CONSENSUS REPORTS: Reported in EPA
so,.
TSCA Inventory.
AOR500 CAS: 548-62-9 HR: 3 ANILINE VIOLET mf: C25H30NpCl mw: 408.03 PROP: Dark green powder or bright blueviolet crystals. Mp: 215" (decomp). Sol in HzO, EtOH, CHCl3.
SAFETY PROFILE: Poison by ingestion, intravenous, and intraperitoneal routes, An experimental teratogen. Other experimental reproductive effects. A human sktn irritant. Human mutation data reported. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits very toxic fumes of NO, and C1-.
SYNS: ADERGOX 0 AIZEN CRYSTALVIOLET 0 AIZEN CRYSTAL VIOLET EXTRA PURE 0 ANILINE VIOLET PYOKTANINE 0 ATMONIL 0 AVERMIN 0 AXURIS 0 BADIL 0 BASIC VIOLET 3 0 BASIC VIOLET BN 0 BISMUTH VIOLET 0 BLAUES PYOKTANIN 0 BRILLIANT VIOLET 5B 0 CALCOZINE VIOLET C 0 CALCOZINE VIOLET 6BN 0 C.1 42555 0 C.I. BASIC VIOLET 3 0 CRYSTAL VIOLET 0 CRYSTAL VIOLET A 0 0 CRYSTAL VIOLET A O S 0 CRYSTAL VIOLET 6B 0 CRYSTAL VIOLET 10B 0 CRYSTAL VIOLET BASE 0 CRYSTAL VIOLET 5 B 0 0 CRYSTAL VIOLET 6BO 0 CRYSTAL VIOLET BP 0 CRYSTAL VIOLET BPC 0 CRYSTAL VIOLET 0 0 CRYSTAL VIOLET CHLORIDE 0 CRYSTAL VIOLET EXTRA PURE 0 CRYSTAL VIOLET EXTRA PURE APN 0 CRYSTAL VIOLET EXTRA PURE APNX 0 CRYSTAL VIOLET FN 0 CRYSTAL VIOLET HL2 0 CRYSTAL VIOLET PURE DSC 0 CRYSTAL VIOLET PURE DSC BRILLIANT 0 CRYSTAL VIOLET SS 0 CRYSTAL VIOLET TECHNICAL 0 CRYSTAL VIOLET USP 0 GENTERSAL 0 GENTIAN VIOLET 0 GENTIANAVIOLETT 0 GENTIAVERM 0 GENTICID 0 GENTIOLETTEN 0 HECTOGRAPH VIOLET SR 0 HECTO VIOLET R 0 HEXAMETHYLPARA-OSANILINE
AOR640 CAS: 5410-78-6 HR: 3 4-ANILINODICHLOROARSlNE, HYDROCHLORlDE mf: C ~ H ~ A S C ~ Z N * C ~mw: H 274.41 SYNS: ANILINE, p-DICHLOROARSINO-, HYDROCHLORIDE 0 ARSINE, @-AMIN0PHENYL)DICHLORO-, HYDROCHLORIDE 0 p-DICHLOROARSINOANILINE HYDROCHLORIDE OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of NO,, As, C1-, and HC1. AOR750 CAS: 122-98-5 HR: 3 2-ANILINOETHANOL mf: CsHllNO mw: 137.20 PROP: D: 1.1, bp: 268O, flash p: 305°F (OC). Sltly sol in water.
p-ANISIC ACID, HYDRAZIDE SYNS: N-(2-HYDROXYETHYL)PHESYLAMINE 0 2(PHENYLAMIN0)ETHANOL 0 PHENYL ETHANOLAMINE 0 N-PHENYLETHANOLAMINE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by skin contact, intraperitoneal, and intravenous routes. Moderately toxic by ingestion. A skin and severe eye irritant. Combustible when exposed to heat or flame. To fight fire, use dry chemical, water mist. When heated to decomposition it emits toxic fumes of NO,.
AOV500
85
AOU250 CAS: 8007-70-3 HR: 2 ANISE OIL PROP: Consists of (8O-9O0/o) anethole and small quantities of methyl chavicol, pmethoxyacetophenone, and other materials. Found in the dried ripe fruit of Impinella animm L. (FCTXAV 11,855,73). D: 0.978-0.988 @ 25'/25'. SYNS: ANISEED OIL 0 ANIS OEL (GERMAN) 0 OIL OF ANISE 0 STAR ANISE OIL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
AOT525 CAS: 135-02-4 HR: 2 0-ANISALDEHYDE PROP: Crystals. Mp: 37-39', bp: 238O, d: 1.127, flash p: 244'F. Sol in water. mf: C8HsO2 mw: 136.16 SYNS: 2-ANISALDEHYDE 0 BENZALDEHYDE, 2hlETHOXY-(9CI) 0 o-METHOXYBENZALDEHYDE 0 2METHOXYBENZALDEHYDE 0 6-METHOXYBENZALDEHYDE 0 2-METHOXYBENZENECARBOXALDEHYDE 0 SALICYLALDEHYDEMETHYL ETHER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
AOT530 CAS: 123-11-5 HR: 2 p-ANISALDEHYDE mf: C8HsO2 mw: 136.15 PROP: Colorless oil; hawthorn odor. D: 1.123 @ 20'/4', refr index: 1.571-1.574, mp: O', bp: 247-248', flash p: 250OF. Misc in alc, ether, fixed oils; sol in propylene glycol; insol in glycerin and water. SYNS: ANISIC ALDEHYDE 0 FEMA No. 2670 0 4METHOXYBENZALDEHYDE 0 p-METHOXYBENZALDEHYDE (FCC) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A s h n irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
ingestion. A weak sensitizer. May cause contact dermatitis. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. AOVOOO CAS: 94-30-4 HR: 2 p-ANISIC ACID, ETHYL ESTER mf: C10H1203 mw: 180.21 PROP: Colorless liquid; fruity, anise odor. D: 1.103 @ 25'/25', refr index: 1.522-1.526, mp: 7-8", bp: 263', flash p: 212'F. Sol in alc and ether; sltly sol in water. SYNS: ETHYL ANISATE 0 ETHYL-p-ANISATE (FCC) 0 ETHYL-p-METHOXYBENZOATE 0 ETHYL-4METHOXYBENZOATE 0 FEMA No. 2420
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. See also ESTERS. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
AOV500 CAS: 3290-99-1 p-ANISIC ACID, HYDRAZIDE mf: CsH10N202 mw: 166.20
HR: 3
SYNS: ANISIC ACID HYDRAZIDE 0 ANISIC HYDMZIDE 0 ANISOYLHYDRAZINE 0 pANISOYLHYDRAZINE 0 p-METHOXYBENZOIC ACID HYDRAZIDE 0 4-METHOXYBENZOIC ACID HYDRAZIDE I3 p-METHOXYBENZOIC HYDRAZIDE 0 @-METHOXYBENZ0YL)HYDRAZINE 0 4METHOXYBENZOYLHYDRAZINE 0 4-METHOXYBENZOYL HYDRAZIDE SAFETY PROFILE: Poison by intravenous route. Questionable carcinogen with experimental neoplastigenic data. When
86
AOV900
0-ANISIDINE
heated to decomposition it emits toxic fumes of NO,. AOV900 CAS: 90-04-0 HR: 3 0-ANISIDINE DOT: UN 2431 mf: C7H9NO mw: 123.17 PROP: Yellowish liquid. Mp: 5O, bp: 225'. Sol in acids; insol in H20; misc in EtOH, EtzO, CbH6. IDLH 50 mg/m3. SYNS: o-AMINOANISOLE 0 2-AMINOANISOLE 0 1AMINO-2-METHOXYBENZENE 0 2-ANISIDINE 0 oANISYLAMINE 0 BENZENAMINE, 2-METHOXY-(9CI) 0 2-METHOXY-1-AMINOBENZENE 0 oMETHOXYANILINE 0 2-METHOXYANILINE 0 2METHOXYBENZENAMINE 0 o-METHOXYPHENYLAMINE
CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 7,56,87; Human h t e d Evidence IMEMDT 27,63,82. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. Community Right-To-Know List. OSHA PEL: TWA 0.5 mg/m3 ACGIH TLV: TWA 0.5 mg/m3 (shn); Animal Carcinogen DFG MAK: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Confirmed carcinogen. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. AOWOOO CAS: 104-94-9 HR: 1 p-ANISIDINE mf: C7HgNO mw: 123.16 PROP: Crystals, plates from aq soln. D: 1.089 @ 55'/55', mp: 57O, bp: 246', vap d: 4.28. Sol in alc, ether, and hot water (insol in cold water). IDLH 50 mg/m3. SYNS: p-AMINOANISOLE 0 4-AiWNOANISOLE 0 1AMINO-4-METHOXYBENZENE 0 4-ANISIDINE 0 pANISYLAMINE 0 p-METHOXYANILINE 0 4METHOXYANILINE 0 4-METHOXYBENZENAMINE 0 4-METHOXYBENZENEAMINE 0 p-METHOXIPHENYLAMINE CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Human Inadequate Evidence IMEMDT
27,63,82. Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.5 mg/m3 ACGIH TLV: TWA 0.5 mg/m3 (shn); Not Classifiable as a Human Carcinogen DFG MAK: 0.1 ppm (0.51 mg/m3) SAFETY PROFILE: Moderately toxic by several routes. A mild sensitizer. May cause a contact dermatitis. Mutation data reported. Questionable carcinogen. See also ANILINE. When heated to decomposition it emits toxic fumes of NO,. AOX250 CAS: 134-29-2 HR: 3 0-ANISIDINE HYDROCHLORIDE mf: C7HgNO*ClH mw: 159.63 SYNS: o-AMINOANISOLE HYDROCHLORIDE 0 2AMINOANISOLE HYDROCHLORIDE 0 o-ANISYL AMINE HYDROCHLORIDE 0 BENZENAMINE, 2METHOXY-, HYDROCHLORIDE ( 9 0 0 C.I. 37115 0 FAST RED BB BASE 0 2-METHOXI-1-AMINOBENZENE HYDROCHLORIDE 0 o-METHOXYANILINE HYDROCHLORIDE 0 2-METHOXYANILINE HYDROCHLORIDE 0 2-METHOXYBENZENAMINE HYDROCHLORIDE 0 2-METHOXYBENZENE-AhNE HYDROCHLORIDE 0 o-METHOXYPHENYL-ANINE HYDROCHLORIDE 0 NCI-C03747 CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 27,63,82; Human No Adequate Data IMEMDT 27,63,82. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NCITR* NCI-CG-TR-89,78. Community Right-ToKnow List. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and HC1.
AOX500 CAS: 20265-97-8 HR: 1 P-ANISIDINE HYDROCHLORIDE mf: C7H9NO.ClH mw: 159.63 SYN: NCI-C03758 CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 27,63,82;
ANOXOMER
NCI Carcinogenesis Bioassay (feed); No Evidence: mouse NCITR* NCI-CG-TR116,78; Inadequate Studies: rat NCITR* NCI-CG-TR-116,78. Reported in EPA TSCA Inventory. SAFETY PROFILE: Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and HC1. AOX750 CAS: 100-66-3 HR: 3 ANISOLE DOT: UN 2222 mfi C7HsO mw: 108.15 PROP: Mobile liquid, clear straw color; phenol, anise odor. Vapor d: 3.72, mp: -37.3', bp: 153.8', flash p: 125'F (COC), d: 0.983-0.988, refr index: 1.513-1.518, vap press: 10 mm @ 42.2', autoign temp: 887'F. Insol in water; sol in alc and ether. SYNS: BENZENE, METHOXY 0 ETHER, METHYL PHESYL 0 FEMA No. 2097 0 METHOXYBENZENE 0 METHYL PHENYL ETHER 0 PHENYL METHYL ETHER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Moderately toxic by ingestion and inhalation. A skin irritant. A flammable liquid. To fight fire, use foam, C02, dry chemical. When heated to decomposition it emits acrid fumes.
AOY250 CAS: 100-07-2 HR: 3 ANISOYL CHLORIDE DOT: UN 1729 mfi CsH7C102 mw: 170.60 PROP: Needle-like crystals. Mp: 22', bp: 160-164' @ 35 mm. Insol in water; sol in ether and acetone. SYNS: p-ANISYOL CHLORIDE 0 BENZOYL CHLORIDE, METHOXY-(9CI) 0 METHOXY-BENZOYL CHLORIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Corrosive to skin, eyes,
mucous membranes, and other tissue.
APE300
87
Evolves HC1 by hydrolysis. A storage hazard; can explode spontaneously at room temperature. When heated to decomposition it emits toxic fumes of Cland may explode. AOY270 CAS: 72432-14-5 N-ANISOYL-GABA mf: C12HljN04 mw: 237.26
HR: 3
SYN: BUTANOIC ACID, 4-((4-METHOXYBENZ0YL)AMINO)SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO,.
AOY400 HR: 1 ANISYL ACETATE mf: C10H1203 mw: 180.20 PROP: Colorless to slt yellow liquid; fruity, balsamic odor. D: 1.104, refr index: 1.511-1.516, flash p: 210'F. Sol in alc and most oils; insol in glycerin and propylene glycol. SYNS: FEMA No. 2098 0 p-METHOXYBENZYL ACETATE SAFETY PROFILE: Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
APE100 HR: 2 ANNATTO EXTRACT PROP: From solvent extraction of Bixa orellana L. seeds (JAPMA8 49,218,60). Yellow-red solutions or powder. SYNS: ACHIOTE 0 BIXA ORELLANA SAFETY PROFILE: Moderately toxic by
intraperitoneal route. Human systemic effects by s h n contact. When heated to decomposition it emits acrid smoke and irritating fumes. APE300 CAS: 60837-57-2 HR: D ANOXOMER PROP: A polymer consisting of 1,4benzenediol, 2-(1,l -dimethylethyl)-polymer with diethylbenzene, 4-(1,ldimethylethyl)phenol, 4-methoxyphenol, 4,4'(1-methylethylidene)bis(phenol) and 4methylphenol.
88 APG 100
2-ANTHRA CENAMINE
SAFETY PROFILE: When heated to
decomposition it emits acrid smoke and irritating fumes. APGIOO CAS: 613-13-8 HR: 2 2-ANTHRACENAMINE mf: C I ~ H I I N mw: 193.26 PROP: Yellow leaflets from alcohol. Mp: 238', bp: subl @ 93' @ 9 mm. Insol in water; sltly sol in alc and ether. SYNS: P-AMINOANTHRACENE 0 2-AMINOANTHRACENE 0 2-ANTHRACYLAMINE 0 2-ANTHRAMINE 0 2-ANTHRYLAMINE SAFETY PROFILE: Moderately toxic by intraperitoneal route. Suspected carcinogen with experimental carcinogenic and tumorigenic data. An experimental teratogen. Mutation data reported. See also AMINES. When heated to decomposition it emits toxic fumes of NO,.
APGSOO CAS: 120-12-7 HR: 2 ANTHRACENE mf: C14H10 mw: 178.24 PROP: Colorless crystals, monoclinic plates from EtOH, violet fluorescence when pure. Mp: 217O, lel: O.Go/0, flash p: 250'F (CC), d: 1.24 @ 27'/4", autoign temp: 1004'F, vap press: 1 mm @ 145.0' (subl), vap d: 6.15, bp: 339.9". Insol in water. Solubility in alc @ 1.9/100 @ 20"; in ether 12.2/100 @ 20'.
exposed to flame, Ca(OCl)z, chromic acid. To fight fire, use water, foam, COz, water spray or mist, dry chemical. Explodes on contact with fluorine. APE00 CAS: 118-92-3 HR: 2 ANTHRANILIC ACID mf: C7H7N02 mw: 137.15 PROP: Needle-like crystals or leaflets. Mp: 144-148', bp: subl, d: 1.412 @ 20". Solubility: in water: 0.35/100 @ 14", in 90% alc: 10.7/100 @ lo', in ether: 16/100 @ 70'. SYNS: o-AMIDOBENZOIC ACID 0 o-AMINOBENZOIC ACID 0 2-AMINOBENZOIC ACID 0 1AMINO-2-CARBOXYE3ENZENE 0 CARBOXY-ANILINE 0 o-CARBOXYANILINE 0 2-CARBOXY-ANILINE 0 NCI-C01730 0 VITAMIN L CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 16,265,78. NTP Carcinogenesis Bioassay (feed): N o Evidence: mouse, rat NCITR* NCI-TR36,78. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Experimental reproductive effects. Human mutation data reported. Questionable carcinogen with experimental tumorigenic data. Combustible. When heated to decomposition it emits toxic fumes of NO,.
SYNS: ANTHRACEN (GERMAN) 0 ANTHRACIN 0 GREEN OIL 0 PARANAPHTHALENE 0 TETRA OLIVE N2G
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 32,105,83; Human No Adequate Data IMEMDT 32,105,83. Reported in EPA TSCA Inventory. Community fight-To-Know List. OSHA PEL: TWA 0.2 mg/m3 SAFETY PROFILE: Moderately toxic by intraperitoneal route. A skin irritant and allergen. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. Mutation data reported. Combustible when exposed to heat, flame, or oxidizing materials. Moderately explosive when
AP1750 CAS: 87-29-6 HR: 2 ANTHRANILIC ACID, CINNAMYL ESTER mf: C I ~ H I ~ N O Z mw: 253.32 PROP: Reddish-yellow powder; balsamic odor. Mp: 60°, flash p: 212°F. Sol in alc, chloroform, ether; insol in water. SYNS: 2-AMINOBENZOIC ACID-3-PHENYI-2PROPENYL ESTER 0 CINNAlMn ALCOHOL ANTHRANIJATE 0 CINNAMYL-o-AMINO-BENZOATE 0 CINNAMYL-2-AMINOBENZOATE 0 C I N N A M n ANTHRANIJATE (FCC) 0 FEMA No. 2295 0 NCI-C03510 0 3-PHENYL-2-PROPENYL-ANTHRANILATE 0 3PHENYL-2-PROPEN-1-YL ANTHRANILATE CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 31,133,83; Animal Inadequate Evidence IMEMDT 16,287,78; NCI Carcinogenesis Bioassay
ANTIHELMYCIN
(feed); Clear Evidence: mouse, rat NCITR* NCI-CG-TR-196,80. Reported in EPA TSCA Inventory. SAFETY PROFI LE: Suspected carcinogen with experimental carcinogenic and neoplastigenic data. Mutation data reported. See also ESTERS. Combustible liquid. When heated to decomposition it emits toxic fumes of NO,. APJ250 CAS: 134-20-3 HR: 2 ANTHRANILIC ACID, METHYL ESTER mf: CgHsN02 mw: 151.18 PROP: Crystals or plates from alc or colorless liquid; grape odor. D: 1.161-1.169, mp: 24-25', bp: 225-230' (@ 15 mm, flash p: 21 9°F. Very sol in water, propylene glycol, hot abs alc (23/100); insol in ether, chloroform, and glycerin. SYNS: o-AhlINOBENZOIC ACID METHYL ESTER
2-
AMINOBENZOIC ACID METHYL ESTER 0 oCARBOMETHOXYANILINE 0 2-CARBOMETHOXYANILINE 0 FEMA S o . 2682 0 2-@tETHOXYCARB0NYL)ANILINE METHYL o-AMINOBENZOATE 0 METHYL 2-AMINOBENZOATE 0 iMETHYL ANTHRANILATE (FCC) 0 METHYLESTER KYSELINY ANTHRANILOVE 0 NEROLI OIL, ARTIFICAL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Experimental reproductive effects. A skin irritant. See also ESTERS. Combustible liquid. When heated to decomposition it emits toxic fumes of NO,.
APJ5OO CAS: 133-18-6 HR: I ANTHRANILIC ACID, PHENETHYL ESTER mf: C15H15N02 mw: 241.31 PROP: Whlte to yellow crystals; grape odor. SYNS: BENZOIC ACID, 2-AMINO-, 2-PHENYLETHYL ESTER BENZYLCARBISYL ASTHRANILATE 0 pPHENETHYL-o-AMINO-BENZOATE 0 PHENETHYL ANTHRANILATE 0 2-PHENYLETHYL-oAMINOBENZOATE 0 PHENYL-ETHYL ANTHRANILATE 0 2-PHENYLETHYL ANTHRANILATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
AQBOOO
89
SAFETY PROFILE: A s h n irritant. See also ESTERS. When heated to decomposition it emits toxic fumes of NO,.
APK250 CAS: 84-65-1 HR: 2 ANTHRAQUINONE mf: C14H~02 mw: 208.22 PROP: Yellow rhombic crystals from PhNO2 or AcOH. Mp: 286', bp: 376.9", flash p: 365'F (CC), d: 1.438, vap press: 1 mm (@ 190.0°, vap d: 7.16. Sol in hot C6H6, toluene, PhN02; mod sol in EtOH; sltly sol in Et2O. Insol in water. SYNS: 9,lO-ANTHRACENEDIONE 0 ANTHRADIONE 0 9,lO-ANTHRAQUINONE 0 9,lODIOXOANTHRACENE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by intraperitoneal route. A mild allergen. Mutation data reported. Combustible when exposed to heat or flame. To fight fire, use water, foam, CO2, water spray or mist, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
APK850 CAS: 131-14-6 HR: 1 2,6-ANTHRAQUINONYLDIAMlNE mf: C14H10N202 mw: 238.26 PROP: Reddish-brown prisms. Mp: 310-320". Insol in CHCl3. SYNS: 9,1O-ANTHRACENEDIONE, 2,6-DIAMINO- 0 ANTHRAQUINONE, 2,6-DIAMINO- 0 2,G-DIAMINOANTHRACHINON 0 2,6-DIAMINOANTHRA-QUI"E 0
2,6-DIAMINO-9,10-ANTHRAQUINONE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
AQBOOO CAS: 31282-04-9 HR: 3 ANTIHELMYCIN mf: C20H37N3013 mw: 527.60 PROP: Amorphous. Mp: 160-1 80' (decomp). SYNS: HYGROMIX-8 0 HYGROMYCIN B (CSDA)
90 AQB750 ANTIMONY SAFETY PROFILE: Poison by
intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. AQB750 CAS: 7440-36-0 HR: 3 ANTIMONY DOT: UN 2871 af: Sb aw: 121.75 PROP: Silvery or gray, lustrous metalloid. Mp: 630°, bp: 1635", d: 6.684 @ 25', vap press: 1 mm @ 886'. Insol in water; sol in hot concentrated H2S04. IDLH 50 mg/m3 (as Sb). SYNS: ASTIMONY BLACK 0 ANTIMONY POWDER (DOT) 0 ANTIMONY REGULUS 0 ANTYMON (POLISH) 0 C.I. 77050 0 STIBIUM
CONSENSUS REPORTS: Antimony and its
compounds are on the Community RtghtTo-Know L s t . Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 DFG MAK: 0.5 mg(Sb)/m3 NlOSH REL: TWA 0.5 mg(Sb)/m3 DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: An experimental poison by intraperitoneal route. Questionable carcinogen with experimental carcinogenic data. Moderate fire and explosion hazard in the forms of dust and vapor when exposed to heat or flame. See also POWDERED METALS. When heated or on contact with acid it emits toxic fumes of SbH3. Electrolysis of acid sulfides and stirred Sb halide yields explosive Sb. It can react violently with NH4N03, halogens, BrN3, BrF3, HC103, C10, ClF3, HN03, m03, KMn04, K202, NaN03, oxidants. AQC500 CAS: 10025-91-9 HR: 3 ANTIMONY(III) CHLORIDE DOT: UN 1733 mf: C4Sb mw: 228.10 PROP: Colorless, rhombic, deliq, hygroscopic crystals whch fume in the air. D: 3.06, mp: 73.4", bp: 220°, vap press: 1 mm @ 49.2" (subl). Sol in cold EtOH, CS2,
EtzO, ccl4, and H2O (small amounts); insol in quinoline, other org bases. SYNS: ANTIMOISE (TRICHLORURE d? 0 ANTIMONIO (TRICLORURO &) 0 ANTIMONOUS CHLORIDE 0 ANTIMONOUS CHLORIDE (DOT) 0 ANTIMONTRICHLORID 0 ANTIMONY BCTTER 0 ANTIMONY CHLORIDE 0 ANTIMONY CHLORIDE (DOT) 0 ANTIMONY TRICHLORIDE 0 ANTIMONY TRICHLORIDE, hqmd (DOT) 0 ANTIMONY TRICHLORIDE, solid (DOT) 0 ANTIMONY TRICHLORIDE, soluuon (DOT) 0 ANTIMO-ONTRICHLORIDE 0 BUTTER of ANTIMONY 0 CHLORID ANTIMONITY 0 CHLORURE ANTIMONIEUX 0 C I 77056 0 STIBINE, TRICHLORO- 0 TRICHLOROSTIBINE 0 TRICHLORURE d'ANTIMOINE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community RightT o - K ~ o wLst. OSHA PEL: TWA 500 pg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Moderately toxic by ingestion. Human pulmonary system effects by inhalation. Corrosive by vigorous reaction with moisture, generating heat and hydrogen chloride gas (a strong irritant), whch can cause pulmonary edema when inhaled. Systemic effects can be caused by the antimony. See also ANTIMONY COMPOUNDS. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of chlorine and antimony. It can react violently with aluminum, potassium, sodmm.
AQDOOO CAS: 7647-18-9 HR: 3 ANTIMONY(V) CHLORIDE DOT: UN 1730/UN 1731 mf: ClsSb mw: 299.01 PROP: Colorless or red-yellow oil or liquid; offensive odor. Mp: , '4 bp: 140', d: 2.336, vap press: 1 mm @ 22.7'. Decomp in water; sol in HC1, HBr, CSz, ccl4, and CHCl3. SYNS: ANTIMONIC CHLORIDE 0 ANTIMONIO (PENTACLORURO DI) (ITALIAN) 0 ANTIMONPENTACHLORID ( G E R i i N ) 0 ANTIMONY PENTACHLOR-
ANTIMONYL-2,4-DIHYDROXY PYRIMIDINE IDE 0 ANTIMONY PENTACHLORIDE (DOV 0 ANTIMONY PERCHLORIDE 0 ANTIMOONPENTACHLORIDE (DUTCH) 0 BUTTER of ANTIMONY 0 PENTACHLOROANTIMONY 0 PENTACHLORURE d'ANTIMOINE (FRENCH) 0 PERCHLORURE d'ANTIMOINE (FRENCH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community EghtTo-Know List. OSHA PEL: TWA 500 ~g(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by ingestion. Corrosive. Mutation data reported. See ANTIMONY COMPOUNDS and ANTIMONYPII) CHLORIDE. When heated to decomposition it emits very toxic fumes of C1- and Sb.
AQD500 HR: 3 ANTIMONY COMPOUNDS CONSENSUS REPORTS: On Community fight-To-Know List. SAFETY PROFILE: Most antimony compounds are poisons by ingestion, inhalation, and intraperitoneal routes. See also ANTIMONY. Locally antimony compounds irritate the skin and mucous membranes. Sb+++and hot HC103 can form an explosive mixture. AQEOOO CAS: 7783-56-4 HR: 3 ANTIMONY(III) FLUORIDE (1 :3) DOT: NA 1549 mf: F3Sb mw: 178.75 PROP: Colorless, rhombic, very deliq crystals. Mp: 292", bp: 376" (subl), d: 4.379 @ 20.9'. Ready sol in water with part hydrolysis, sol in polar org solvs. Insol in C6H6, chlorobenzene, pet ether. SYNS: ANTIMOINE FLUORURE (FRENCH) 0 ANTIMONOUS FLUORIDE 0 ANTIMONY TRIFLUORIDE 0 ANTIMONY TRIFLUORIDE, solid or solution (DO?) 0 STIBINE, TRIFLUORO- (9Cl) 0 TRIFLUOROANTIMONY 0 TRIFLUOROSTIBINE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Antimony and its
AQE305
91
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(Sb)/m3; TWA 2.5 m g O / m j ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of slxft; TWA 0.5 mg(Sb)/m3 NIOSH REL: TWA 0.5 mg(Sb)/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by subcutaneous route. Corrosive to skin and eyes. See also FLUORIDES and ANTIMONY COMPOUNDS. When heated to decomposition it emits very toxic fumes of F- and Sb. AQE250 CAS: 58164-88-8 HR: 3 ANTIMONY LACTATE DOT: UN 1550 mf: CgH150g*Sb mw: 388.99 PROP: Tan mass, water-sol. SYNS: ANTIMONY LACTATE, solid (DO?) 0 LACTIC ACID, ANTIMONY SALT 0 PROPANOIC ACID, 2HYDROXY-, TRIANHYDRIDE with ANTIMONIC ACID (H3Sb03) (9CI)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Antimony and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/mj NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3 DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: A poison. See also ANTIMONY COMPOUNDS. When heated to decomposition it emits toxic fumes of Sb. AQE305 CAS: 77824-44-3 HR: 3 ANTIMONYL-2,4-DIHYDROXY PYRIMID1NE mf: CsH6N406Sbz mw: 497.68 SYN : 2,4,10,12-TETRAOXA-6,16,17,18-TETRAAZA-3,11DISTIBATRICYCLO(I1.3.1.1 5,g)OCTADECA3,lI-DIHYDROXY1(17),5,7,9(18),13,15-HEXAENE,
OSHA PEL: TWA 0.5 mg(Sb)/m3
92 AQE320 ANTIMONYL-7-FORMYL-8-HYDROXY-QUlNOLINE-5ACGIH TLV: TWA 0.5 mg(Sb)/m3 NIOSH REL: 10H TWA 0.5 mg(Sb)/m3 SAFETY PROFILE: Poison by
intraperitoneal route. When heated to decomposition it emits toxic fumes of NO, and Sb. AQE320 CAS: 77824-43-2 HR: 3 ANTIMONY L-7-FORMYL-8-HYDROXYQUINOLINE-5-SULPHONATE mf: CzoH11Nz011SzSb*2Na mw: 687.18
SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Poison by intravenous and subcutaneous routes. Moderately toxic by other routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also ANTIMONY COMPOUNDS. When heated to decomposition it emits toxic Sb fumes. Incompatible with chlorinated rubber and heat of 21 6" and with BrF3.
SYN: 5-QUINOLINESULFONIC ACID, 8,8'((HYDROXISTIBYLENE)BIS(OXY))BIS(7-FORMYL)-, DISODIUM SALT
OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 NIOSH REL: ZOH TWA 0.5 mg(Sb)/m3 SAFETY PROFILE: Poison by
intraperitoneal route. When heated to decomposition it emits toxic fumes of NO,, SO,, and Sb. AQFOOO CAS: 1309-64-4 HR: 3 ANTIMONY OXIDE mf: 03Sbz mw: 291.50 PROP: E h t e cubes. D: 5.2, mp: 650°, bp: 1550" (subl). Very sltly sol in water; sol in KOH and HC1. SYNS: A 1530 0 A 1582 0 A 1588LP 0 AMSPEC-KR 0 ANTIMONIOUS OXIDE 0 ANTIMONY(3+) OXIDE 0 ANTIMONY PEROXIDE 0 ANTIMONY SESQUIOXIDE 0 ANTIMONY TRIOXIDE 0 ANTIMONY WHITE 0 ANTOX 0 ANZON-TMS 0 AP 50 0 BLUE STAR 0 CHEMETRON FIRE SHIELD 0 C.I. 77052 0 C.I. PIGMENT WHITE 11 0 DECHLOR-ANE A - 0 0 DIANTIMONY TRIOXIDE 0 EXITELITE 0 EXTREMA 0 FLOWERS of ANTIMONY 0 NCI-C55152 0 NYACOL A 1530 0 SENARMONTITE 0 THERMOGUARD B 0 THERMOGUARD S 0 TIMONOX 0 TWINKLING STAR 0 VALENTINITE 0 WEISSPIESSGLANZ 0 WHITE STAR
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community RightT o - K ~ o wList. OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3; Suspected Carcinogen DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: TWA 0.5 mg(Sb)/m3
AQF250 CAS: 7783-70-2 HR: 3 ANTIMONY(V) PENTAFLUORIDE DOT: UN 1732 mf: FsSb mw: 216.75 PROP: Oily, colorless liquid. Very reactive. Mp: 7.0°, bp: 149.5", d: @q,) 2.99 @ 23". Sol in water and I@. SYNS: ANTIMONY FLUORIDE 0 ANTIhlONY(V) FLUORIDE 0 ANTIMONY PENTAFLUORIDE (DOq 0 PENTAFLUOROANTIMONY CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community RightTo-Know List. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 NIOSH REL: (Antimony) TWA 0.5 mg(Sb) /m3 DOT CLASSIFICATION: 8; Label: Corrosive, Poison SAFETY PROFILE: A poison by inhalation. A very reactive, corrosive liquid to skin, eyes, mucous membranes. See also FLUORIDES and ANTIMONY COMPOUNDS. Violent reaction with phosphates. When heated to decomposition it emits very toxic fumes of F and Sb.
AQFSOO CAS: 1315-04-4 HR: 3 ANTIMONY PENTASULFIDE mf: SSSb2 mw: 403.80 PROP: Dark orange-yellow powder or solid. Mp: 75" (decomp), d: 4.120. Insol dilute aqueous acids; sol conc HC1.
I-ANTIMONY POTASSIUM TARTRATE AQHOOO SYNS: ANTIMONLAL SAFFRON 0 ANTIMONIC SULFIDE ANTIMONY RED 0 ANTIMONY SULFIDE 0 C.I. 77061 0 GOLDEN ANTIMONY SULFIDE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 NlOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3 SAFETY PROFILE: Moderately toxic by intraperitoneal route. See also ANTIMONY COMPOUNDS and SULFIDES. Flammable when exposed to heat or by chemical reaction with powerful oxidtzers. Use water to fight fire. Moderately explosive when shocked or by spontaneous chemical reaction in contact with powerful oxidtzers. When heated to decomposition or on contact with acid or acid fumes it emits highly toxic fumes of oxides of sulfur and antimony. Incompatible with water or steam to produce toxic and flammable vapors and with oxidizers, e.g., Ag(C103)2, HC103, C102, Mg(C103)2, TlO,Zn(ClO3)z.
AQF750 CAS: 1314-60-9 HR: 2 ANTIMONY PENTOXIDE mf: O5Sb2 mw: 323.50 PROP: Yellowish-white powder or deep yellow crystals. D: 3.78, mp: decomp @ 380”. Insol in water; sltly sol in warm KOH soh.
AQG250 CAS: 28300-74-5 HR: 3 ANTIMONY POTASSIUM TARTRATE DOT: UN 1551 mfi CsH4012Sb2*3H20*2K mw: 635.88 PROP: Colorless crystals to whte powder. D: 2.607, mp: loses H20 @ 100”. SYNS: ANTIMONYL POTASSIUM TARTRATE 0 EMETIQUE (FRENCH) 0 ENT 50,434 0 POTASSIUM ANTIMONYL TARTRATE 0 POTASSIUM ANTIMONYL d-TARTRATE POTASSIUM ANTIMONY TARTRATE 0 TARTAR EMETIC 0 TARTARIZED ANTIMONY 0 TARTRATE ANTIMONIO-POTASSIQUE (FRENCH) 0 TARTRATED ANTIMONY CONSENSUS REPORTS: Antimony and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m’ NlOSH REL: (Antimony) TWA 0.5 mg(Sb) /m3 DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Human poison by intravenous route, producing liver and kidney changes, somnolence, dyspnea, and pupillary dilation. Poison by ingestion, subcutaneous, intravenous, intramuscular, and intraperitoneal routes. Large doses cause severe liver damage. Human mutation data reported. Used medicinally, the therapeutic dose is close to the toxic dose. Upon decomposition it emits toxic fumes of K20 and Sb.
SYNS: ANTIMONIC “ACID”
AQHOOO CAS: 11071-15-1 HR: 3 I-ANTIMONY POTASSIUM TARTRATE mf: C4H507Sb.K mw: 325.94
CONSENSUS REPORTS: Reported in EPA
SYNS: POTASSIUM ANTIMONYL-1-TARTRATE 0 ITARTARIC ACID, ANTIMONY POTASSIUM SALT
ANTIMONIC OXIDE 0 ANTIMONY PENTAOXIDE 0 DIANTIMONY PENTOXIDE 0 STIBIC ANHYDRIDE
TSCA Inventory. Antimony and its compounds are on the Community fightTo-Know List. OSHA PEL: TWA 500 ~g(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 NlOSH REL: (Antimony) TWA 0.5 mg(Sb) /m3 SAFETY PROFILE: Moderately toxic by intraperitoneal route. See also ANTIMONY COMPOUNDS.
93
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community RightT o - K ~ o wList. OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 NlOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3 SAFETY PROFILE: Poison by intraperitoneal route. See also ANTIMONY COMPOUNDS. When heated to
94 AQH800 ANTIMONY SODIUM GLUCONATE decomposition it emits toxic fumes of Sb and K20.
SYNS: ACETIC ACID, TRMNHYDRIDE with ANTIMONIC ACID 0 ANTIMONYOII) ACETATE 0 OCTAN ANTIMONITY (CZECH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community Right~To-Know O List. OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 ACID, CYCLIC ESTER with ANTIMONIC ACID (HgSb2Og) NlOSH REL: (Antimony) TWA 0.5 (2:l),TRISODIUMSALT, NONA-HYDRATE 0 dGLUCONIC ACID, 2,42',4'-0-(OXYDISTIBYLIDYNE)BIS-,mg(Sb)/m3 Sb,Sb'-DIOXIDE, TRISODIUM SALT, NONAHYDRATE 0 SAFETY PROFILE: Mildly toxic by hWOSTIBIN 0 PENTOSTAIM 0 SODIUM ingestion. A skin and eye irritant. Mutation STIBOGLUCONATE 0 SOLUSTIBOSAN 0 SOLUSTIN 0 data reported. See also ANTIMONY SOLUSURMIN 0 SOLYUSUILMIN 0 STIBANATE 0 COMPOUNDS. When heated to STIBANOSE 0 STIBATIN 0 STIBINOL decomposition it emits acrid smoke and OSHA PEL: TWA 0.5 mg(Sb)/m3 irritating fumes. ACGIH TLV: TWA 0.5 mg(Sb)/m3
AQH800 CAS: 16037-91-5 HR: 3 ANTIMONY SODIUM GLUCONATE mf: C I Z H ~ ~ O I ~ S ~ ~ * ~ mw: N~*~H 1048.91 SYNS: ESTIBOGLUCONATO SODICO 0 d-GLUCONIC
NlOSH REL: (Antimony) 10H TWA 0.5
mg(Sb)/m3 SAFETY PROFILE: Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Sb.
AQ1750 CAS: 34521-09-0 HR: 3 ANTIMONY SODIUM TARTRATE mf: C8H401zSbp2Na mw: 581.60 SYNS: ANTIMONY SODIUM OXIDE-1-(+)-TARTRATE 0 NATRIUMANTIMONYLTARTRAT (GERMAN) 0 SODIUM ANTIMONYL TARTRATE 0 SODIUM ANTIMONY TARTRATE 0 STIBNAL 0 STIBUNAL
CONSENSUS REPORTS: Antimony and its
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 NlOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3 SAFETY PROFILE: Poison by subcutaneous, intravenous, and intraperitoneal routes. Human toxic effects by intravenous route. Human mutation data reported. See also ANTIMONY COMPOUNDS. When heated to decomposition it emits toxic fumes of Sb. AQJ750 CAS: 6923-52-0 ANTIMONY TRIACETATE mf: C6Hg06*Sb mw: 298.90
HR: 1
AQKOOO CAS: 7789-61-9 HR: 3 ANTIMONY TRIBROMIDE DOT: NA 1549 mf: BaSb mw: 361.48 PROP: Yellow or white, deliquescent, crystalline mass becoming amber yellow when fused. Hygroscopic. Decomp by water. Mp: 96O, bp: 280°, d: 4.145, vap press: 1 mm @ 93.9'. SYNS: ANTIMONY TRIBROMIDE 0 ANTIMONY TRIBROMIDE, solid or solution (DOq 0 TRIBROMOSTIBINE
CONSENSUS REPORTS: Antimony and its compounds are on the Community RightTo-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.5 mg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m' DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A poison. Corrosive to skin, eyes, and mucous membranes. Reaction with water liberates HBr and antimony trioxide. Can cause severe burns. See also ANTIMONY COMPOUNDS.
AQLSOO CAS: 1345-04-6 HR: 3 ANTIMONY TRISULFIDE mf: S3Sb2 mw: 339.68 PROP: Red-to-black crystals. Mp: 563O, d: 4.64. Sol in H2S04; solubility in water: 0.002/100 @ 20' (decomp).
ANTU SYNS: ANTIMONOUS SULFIDE 0 ANTIMONY GLANCE 0 ANTIMONY ORANGE 0 ANTIMONY SESQUISULFIDE 0 ANTIMONY SULFIDE 0 ANTIMONY TRISULFIDE COLLOID 0 ANTIMONY VERMILION 0 BLACK ANTIMONY 0 C.I. 77060 0 C.I. PIGMENT RED 107 0 CRIMSON ANTIMONY 0 DIANTIMONY TRISULFIDE 0 LYMPHOSCAN 13 NEEDLE ANTIMONY CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 47,291$9; Animal Limited Evidence IMEMDT 47,291,89; Human Inadequate Evidence IMEMDT 47,291,89. Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community RightT o - K ~ o wL s t . OSHA PEL: TWA 500 pg(Sb)/m3 ACGIH TLV: TWA 0.5 mg(Sb)/m3 NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3 SAFETY PROFILE: Poison by intraperitoneal route. Human blood and gastrointestinal system effects by inhalation. Questionable carcinogen. See also ANTIMONY COMPOUNDS and SULFIDES. Spontaneously flammable when exposed to strong oxidizers. Flammable when exposed to heat or flame. Moderately explosive by spontaneous reaction with chlorates, perchlorates, C10, thallic oxide. When heated to decomposition or on contact with acid or acid fumes it emits hghly toxic fumes of oxides of sulfur and antimony. Will react with water or steam to produce toxic and flammable vapors.
AQNOOO CAS: 60-80-0 HR: 3 ANTIPYRINE mf: CllH12N20 mw: 188.23 PROP: Fine, white crystals, leaflets, or scales. Mp: 113", bp: 319" @ 174 mm, d: 1.19. Very sol in water and alc; sltly sol in ether. SYNS: DIMETHYLOXYQUINAZINE
0 2,3-DIMETHYL-
l-PHENYL-3-PYRAZOLIN-5-ONE 0 2,3-DIMETHYL-1PHENYL-5-PYRAZOLONE 0 OXYDIMETHYLQUINAZINE 0 PHENAZONE (pharmaceutical) 0 1PHENYL-2,3-DIMETHYL-PYRAZOLE-5-ONE 0 1-
PHENYL-2,3-DIMETHYL-j-PYRAZOLONE
AQN635
95
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: A human Doison bv 1 an unspecified route. Moderately toxic via ingestion, subcutaneous, and intravenous routes. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. i
AQN635 CAS: 86-88-4 HR: 3 ANTU DOT: UN 1651 mf: CIIHION~S mw: 202.29 PROP: Crystals or prisms with bitter taste. Mp: 198". Sltly sol in H20; sol in Me2CO. IDLH 100 mg/m3. SYNS: ALPHANAPHTHYL THIOUREA 0 ALPHANAPHTYL THIOUREE (FRENCH) 0 ALRATO 0 ANTURAT 0 CHEMICAL 109 0 DIRAX 0 KILL KANTZ 0 KRYSID 0 1-NAFTIL-TIOUREA (ITALIAN) 0 1NAFTYLTHIOUREUM (DUTCH) 0 1-NAPHTHALENYLTHIOUREA 0 a-NAPHTHALTHIOHARNSTOFF (GERMAN) 0 a-NAPHTHOTHIOUREA 0 aNAPHTHYLTHIOCARBAMIDE 0 1-NAPHTHYLTHIOHARNSTOFF (GERMAN) 0 a-NAPHTHKTHIOUREA 0 1-NAPHTHYLTHIOUREA (MAK) 0 1-(1NAPHTHYL)-2-THIOUREA 0 N-(l-NAPHTHYL)-2THIOUREA 0 a-NAPHTHYLTHIOUREA (DOq 0 1NAPHTHYL-THIOUREE (FRENCH) 0 NAPHTOX 0 RATTRACK 0 RCRA WASTE NUiMBER PO72 0 SMEESANA 0 U-5227 0 USAF EK-P-5976 CONSENSUS REPORTS: IARC Cancer
Review: Animal Inadequate Evidence IMEMDT 30,347,83. Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. EPA Genetic Toxicology Program. OSHA PEL: TWA 0.3 mg/m3 ACGIH TLV: TWA 0.3 mg/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.3 mg/m3 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Moderately toxic to humans by an unspecified route. Questionable carcinogen with experimental tumorigenic data. Mutagenic data. A rodenticide used extensively. Death is caused by pulmonary edema. Chronic
96 AQ0300 PAPO-8'-CAROTENAL toxicity has been known to cause dermatitis and a decrease in the white blood cells. When heated to decomposition it emits toxic fumes of NO, and SO,. AQ0300 CAS: 1107-26-2 HR: D P-APO-~'-CAROTENAL mf: C&400 mw: 416.65 PROP: Fine crystalline powder with dark metahc sheen or violet crystals. Mp: 139'. Sol in chloroform; sltly sol in acetone; insol in water. SYNS: APO 0 APOCAROTENAL SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. AQPOOO CAS: 1937-37-7 HR: 3 APOMINE BLACK GX mf: C34H25N907S2*2Na mw: 781.78 SYNS: AHCO DIRECT BLACK GX 0 AIREDALE BLACK E D 0 AIZEN DIRECT DEEP BLACK E H 0 AIZEN DIRECT DEEP BLACK GH 0 AIZEN DIRECT DEEP BLACK RH 0 AMANIL BLACK GL 0 AMANIL BLACK W D 0 ATLANTIC BLACK BD 0 ATLANTIC BLACK C 0 ATLANTIC BLACK E 0 ATLANTIC BLACK EA 0 ATLANTIC BLACK GAC 0 ATLANTIC BLACK G G 0 ATLANTIC BLACK GXCW 0 ATLANTIC BLACK GXOO 0 ATLANTIC BLACK SD 0 ATUL DIRECT BLACK E 0 AZINE DEEP BLACK EW 0 AZOCARD BLACK EW 0 AZOMINE BLACK EWO 0 BELAMINE BLACK GX 0 BENCIDAL BLACK E 0 BENZAMIL BLACK E 0 BENZO DEEP BLACK E 0 BENZO LEATHER BLACK E 0 BENZOFOF&t BLACK BCN-CF 0 BLACK 2EIvfE3L 0 BLACK 4EIvBL 0 BRASILAMINA BLACK GN 0 BRILLIANT CHROME LEATHER BLACK H 0 CALCOMINE BLACK 0 CALCOMINE BLACK E X 0 CARBIDE BLACK E 0 CERN PRIiMA 38 0 CHLORAMINE BLACK C 0 CHLORAMINE BLACK EC 0 CHLORAMINE BLACK ERT 0 CHLORAMINE BLACK EX 0 CHLORAMINE BLACK EXR 0 CHLORAMINE BLACK XO 0 CHLORAMINE CARBON BLACK S 0 CHLORAMINE CARBON BLACK SJ 0 CHLORAMINE CARBON BLACK SN 0 CHLORAZOL BLACK E 0 CHLORAZOL BLACK E (BIOLOGICAL STAIN) 0 CHLORAZOL BLACK EA 0 CHLORAZOL BLACK EN 0 CHLORAZOL BURL BLACK E 0 CHLORAZOL LEATHER BLACK ENP 0 CHLORAZOL SILK BLACK G 0 CHROME LEATHER BLACK E 0 CHROME LEATHER BLACK EC 0 CHROME LEATHER BLACK EM 0 CHROME LEATHER BLACK G 0 CHROME LEATHER BRILLIANT BLACK ER 0 C.I. 30235 0 C.I. DIRECT BLACK 38 0 C.I. DIRECT BLACK 38, DISODIUM SALT 0
COIR DEEP BLACK C 0 COLUiMBIA BLACK EP 0 DIACOTTON DEEP BLACK 0 DUCOTTON DEEP BLACK RX 0 DIAMINE DEEP BLACK EC 0 DIAMINE DIRECT BLACK E 0 DIAPHTAhffNE BLACK V 0 DIAZINE BLACK E 0 DIAZINE DIRECT BLACK E 0 DIAZINE DIRECT BLACK G 0 DIAZOL BLACK 2V 0 DIPHENYL DEEP BLACK G 0 DIRECT BLACK A 0 DIRECT BLACK BILU 0 DIRECT BLACK CX 0 DIRECT BLACK CXR 0 DIRECT BLACK E 0 DIRECT BLACK EW 0 DIRECT BLACK EX 0 DIRECT BLACK FR 0 DIRECT BLACK GAC 0 DIRECT BLACK GK' 0 DIRECT BLACK GX 0 DIRECT BLACK GXR 0 DIRECT BLACK JET 0 DIRECT BLACK META 0 DIRECT BLACK IMETHYL 0 DIRECT BLACK N 0 DIRECT BLACK RX 0 DIRECT BLACK SD 0 DIRECT BLACK WS 0 DIRECT BLACK Z 0 DIRECT BLACK 3 0 DIRECT BLACK 38 0 DIRECT DEEP BLACK E 0 DIRECT DEEP BLACK E EXTRA 0 DIRECT DEEP BLACK EA-CF 0 DIRECT DEEP BLACK EAC 0 DIRECT DEEP BLACK EVV 0 DIRECT DEEP BLACK EX 0 ENIANIL BLACK CN 0 ERIE BLACK B 0 ERIE BLACK BF 0 ERIE BLACK GAC 0 ERIE BLACK GXOO 0 ERIE BLACK JET 0 ERIE BLACK NUG 0 ERIE BLACK M O O 0 ERIE BRILLIANT BLACK S 0 ERIE FIBRE BLACK VP 0 FENAMIN BLACK E 0 FIBRE BLACK VF 0 FIXANOL BLACK E 0 FORMALINE BLACK C 0 FORMIC BLACK BA 0 FORMIC BLACK C 0 FORMIC BLACK CW 0 FORMIC BLACK MTG 0 FORMIC BLACK TG 0 HISPAMIN BLACK E F 0 INTERCHEM DIRECT BLACK Z 0 KAYAKU DIRECT DEEP BLACK EX 0 KAYAKU DIRECT DEEP BLACK GX 0 KAYAKU DIRECT DEEP BLACK S 0 KAYAKU DIRECT LEATHER BLACK EX 0 KAYAKU DIRECT SPECIAL BLACK ArlX 0 LURAZOL BLACK BA 0 META BLACK 0 MITSUI DIRECT BLACK EX 0 MITSUI DIRECT BLACK GX 0 NCI-C54557 0 NIPPON DEEP BLACK 0 NIPPON DEEP BLACK GX 0 PAPER BLACK BA 0 PAPER BLACK T 0 PAPER DEEP BLACK C 0 PARAMINE BLACK B 0 PARAMINE BLACK E 0 PEERAMINE BLACK E 0 PEERAMINE BLACK GXOO 0 PHENAMINE BLACK BCN-CF 0 PHENAMINE BLACK CL 0 PHENAMINE BLACK E 0 PHENAMINE BLACK E 200 0 PHENO BLACK EP 0 PHENO BLACK SGN 0 PONTAMINE BLACK E 0 PO&-TARIINE BLACK EBN 0 SANDOPEL BLACK EX 0 SERISTAN BLACK B 0 TELON FAST BLACK E 0 TETRAZO DEEP BLACK G 0 TERTRODIRECT BLACK E 0 TETRODIRECT BLACK EFD 0 UNION BLACK EM 0 VONDACEL BLACK X
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Animal Sufficient Evidence IMEMDT 29,295,82; Human Limited Evidence IMEMDT 29,295,82. Reported in EPA TSCA Inventory. NTP Carcinogenesis Bioassay (feed): Clear Evidence: rat NCICTR* NCI-TR-108,78; No Evidence:
ARATHANE
mouse NCICTR NCI-TR-108,78. On Community-hght-To-Know List. SAFETY PROFILE: Confirmed carcinogen with carcinogenic and tumorigenic data. Moderately toxic by ingestion and inhalation. An eye irritant. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO,, Na20, and s02. AQQ125 CAS: 17185-68-1 HR: 3 AQUA-I ,2-DIAMINOPROPANEDIPEROXOCHROMIUM(IV) DIHYDRATE mf: C ~ H I ~ C ~ N ~ O ~mw: ~ H 244.16 ~ O PROP: IDLH Ca [15 mg/m3 {as Cr(VI)}]. CONSENSUS REPORTS: Chromium and its compounds are on the Community Right-To-Know List. OSHA PEL: CL 0.1 mg(Cr03)/m3 ACGlH TLV: TWA 0.05 mg(Cr)/m3; Confirmed Human Carcinogen NIOSH REL: (Chromium(V1)) TWA 25 pg(Cr(VI))/m3; CL 50 ~g/m3/15M SAFETY PROFILE: A confirmed carcinogen. May explode spontaneously at room temperature. Upon decomposition it emits toxic fumes of NO,. See also CHROMIUM COMPOUNDS. AQQ500 CAS: 9000-01-5 HR: 2 ARABIC GUM mw: 240,000 PROP: Yellowish-amber lumps. A gum from the stems and branches ofAcucia senegal (I Wild. ,. or ) of Acacid (Fam. Legzlminosue). Sol in water; insol in alc. SYNS: ACACIA 0 ACACIA DEALBATA GUM 0 ACACIA GUM 0 ACACIA SENEGAL 0 ACACIA SYRUP 0 AUSTRALWS GUM 0 GUMARABIC 0 GUM OVALINE 0 GUM SENEGAL 0 INDIAN GUM 0 NCIC50748 0 SENEGAL GUiM 0 STARSOL No. 1 0 WATTLE GUM CONSENSUS REPORTS: NTP Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NTPTR* NTP-TR227,82. Reported in EPA TSCA Inventory. SAFETY PROFILE: Very low toxicity by ingestion. Inhalation or ingestion has produced hives, eczema, and angiodema.
AQT500
97
Experimental reproductive effects. A severe eye irritant. A weak allergen. Mutation data reported. Combustible. When heated to decomposition it emits acrid smoke. AQQ900 CAS: 5536-17-4 HR: 3 9-p-d-ARABINO FURANOSYL ADENINE mf: C10H13N504 mw: 267.28 PROP: Needles. Mp: 257-257.5'. SYNS: ADENINE ARABINOSIDE 0 ARABINOSYLADENINE 0 P-d-ARABINOSYLADENINE 0 9-ARABINOSYLADENINE 0 VIDARABIN 0 VIDARABINE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intravenous routes. Moderately toxic by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. Human systemic effects by intravenous route: central nervous system, blood, and other effects. A s h n and eye irritant. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
AQR800 CAS: 9036-66-2 HR: D ARABINOGALACTAN PROP: Derived from water extraction of Western larch wood having galactose units and arabinose units in the ratio of approx. 6:l. Mp: >200° (decomp). Sol in water. SYNS: (+)-ARABINOGALACTAN 0 LARCH GUM 0 POLYARABINOGALACTAN SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes.
AQT5OO CAS: 39300-45-3 HR: 3 ARATHANE mf: C18H24N206 mw: 364.44 PROP: Lquid. SYNS: CAPRYLDINITROPHESYL CROTONATE CAPRYL-4,6-DINITROPHENYL CROTONATE
0 2-
0
CROTONATE de 2,4-DINITRO 6-(I-METHYL-HEPTYL)PHENYLE (FRENCH) 0 4,6-DINITRO-Z-CAPRYLPHENYL CROTONATE 0 4,6-DINITRO-2-(2-CAPRYL)PHENYL CROTONATE 0 DINITRO(1-METHYLHEPTYL)PHENYL CROTONATE 0 2,4-DINITRO-6-(1-METHYLHEMYL)PHENYL CROTONATE 0 2,4-DINITR0-6-(2-OCTYL)-
98 AQT750 ARECOLINE TOXIN 0 TOXIN, BLUE GREEN ALGA, MICROCYSTIS AERUGINOSA 0 TOXIN I (MICROCYSTIS 0 (6-(1-METHYL-HEPTYL)-2,3-DINITRO-PHENYL)- AERUGINOSA) 0 TOXIN-LR 0 TOXIN T 17 (MICROCYSTIS AERUGINOSA) CROTONAT (GERMAN) 0 2-(1-METHYLHEPTYL)-4,6DINITROPHENYL CROTONATE 0 (6-(1-METIL-EPITL)SAFETY PROFILE: A poison by ingestion, 2,4-DINITRO-FENIL)-CROTONATO (ITALIAN) PHENYL CROTONATE 0 ENT 24,727 0 (6-(l-METHYLHEMYL-2,4-DINITRO-FENYL-CROTONAAT (DUTCH)
SAFETY PROFILE: Poison by ingestion and
intravenous routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Questionable carcinogen with experimental neoplastigenic data. See NITRATES. When heated to decomposition it emits toxic fumes of NO,. AQT750 CAS: 63-75-2 HR: 3 ARECOLINE mf: CgH13N02 mw: 155.22 PROP: Oily liquid. Bp: 94" (@, 17 mm. SYNS: ARECAIDINE METHYL ESTER 0 ARECOLINE
inhalation, intraperitoneal, and intravenous route. Experimental reproductive effects. When heated to decomposition it emits toxic vapors of NO,.
AQWOOO CAS: 1119-34-2 HR: 2 I-ARGININE MONOHYDROCHLORIDE mf: C~H14N402.ClH mw: 210.70 PROP: White crystalline powder; odorless. Mp: 222-235' (decomp). Very sol in water; sltly sol in alc. SYNS: ARGAMINE 0 ARGININE HYDRO-CHLORIDE 0 I-ARGININE HYDROCHLORIDE 0 ARGININE MONOHYDROCHLORIDE 0 ARGIVENE 0 DETOXARGIN 0 1-HYDROCHLORIDE ARGININE 0 LEVARGIN 0 MINOPHAGEN A 0 R-GENE
BASE 0 METHYL-1,2,5,6-TETRA-HYDRO-l -METHYLNICOTINATE 0 N-METHYL-A-TETRAHYDRONICOTIK- CONSENSUS REPORTS: Reported in EPA IC ACID METHYL ESTER 0 N-METHYLTETRAHYDROTSCA Inventory. PYRIDINE-P-CARBO-XYLIC ACID METHYL ESTER 0 SAFETY PROFILE: Moderately toxic by 1,2,5,6-TETRA-HYDRO-l -METHYLNICOTINIC ACID, intraperitoneal route. Mildly toxic by METHYL ESTER
CONSENSUS REPORTS: IARC Cancer
Review: Animal Inadequate Evidence IMEMDT 37,141,85. SAFETY PROFILE: Poison by subcutaneous and intraperitoneal routes. Moderately toxic by ingestion. Questionable carcinogen with experimental neoplastigenic data. It mimics the action of acetylcholine, a neurotransmitter, and is a parasympathetic nervous system stimulant. Its action on the central nervous system can cause tremors. Human mutation data reported. It is easily nitrosated to several nitrosamines. See also ESTERS and NITROSAMINES. It is the major alkaloid found in betel quid. Combustible, can react with oxidzing materials. When heated to decomposition it emits hghly toxic fumes of NO,. AQV990 CAS: 101043-37-2 HR: 3 5-I-ARGININECYANOGINOSIN LA mf: C49H74N10012 mw: 995.33 SYNS: AKERSTOX 0 CYANOGINOSIN LA, 5-1ARGININE- 0 CYANOGINOSIN LR 0 MICROCYSTIN-A 0 MICROCYSTIN-LR 0 MICROCYSTIS AERUGINOSA
ingestion. An experimental teratogen. When heated to decomposition it emits very toxic fumes of NO, and HC1. AQW250 CAS: 7440-37-1 HR: 1 ARGON afi Ar aw: 39.94 DOT: UN 1006/UN 1951 PROP: Colorless, inert, odorless, tasteless, monatomic gas. Forms no true chemical compds. Forms clathrates with H20 and hydroquinone. Forms complex with HBr. Mp: -189.2", bp: -185.7", d: 1.784 g/L @ 0", 1.40 @ -186", 1.65 (@, -233'. Solubility in water 3.36 mL/l00 g (@, 20". CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 2.2; Label: Nonflammable Gas SAFETY PROFILE: A simple asphyxlant gas. As an inert gas, it has no specific inherent dangerous properties. Gases of this type have no specific toxicity effect, but they act by excluding 0 2 from the lungs. The effect of simple asphyxiant gases is
ARSACETIN SODIUM SALT AQZ900
proportional to the extent to whch they dirmnish the amount (partial pressure) of 0 2 in the air that is breathed. The oxygen may be diminished to 75% of its normal percentage in air before appreciable symptoms develop, and t h s in turn requires the presence of a simple asphyxiant in a concentration of 33% in the mixture of air and gas. When the simple asphyxiant reaches a concentration of 50%, marked symptoms can be produced. A concentration of 75% is fatal in a matter of minutes. The first symptoms produced by simple asphyxiant gases such as argon are rapid respirations and air hunger. Mental alertness is diminished and muscular coordination is impaired. Later, judgment becomes faulty and all sensations are depressed. Emotional instability often results and fatigue occurs rapidly. As the asphyxia progresses, there may be nausea and vomiting, prostration, and loss of consciousness, and finally, convulsions, deep coma, and death.
99
ARISTOLOCHINE mE C 1 7 H l l N 0 7 mw: 341.29 PROP: Crystals from DMF/EtOH, EtOH, or MeOH/EtnO. Mp: 281-286' (decomp). From alcoholic extract of Aristolochia indico (CNCRA6 42,35,64). SYNS: ARISTOLOCHIC ACID 0 BIRTHWORT 13 8METHOXY-6-NITROPHENANTHOL-(3,4-d)-1,3DIOXOLE-5-CARBOXYLICACID 0 NSC-50413
SAFETY PROFILE: Confirmed carcinogen.
Poison by ingestion, intraperitoneal, and intravenous routes. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. From "International Register of Potentially Toxic Chemicals: April 1982." Vol. 5 No. 1: The Ministry of Health of the Federal Republic of Germany has withdrawn from the national market drugs containing aristolochic acid. The decision resulted from the demonstration of a carcinogenic potential in a three-month ingestion toxicity study undertaken in rats. Aristolochic acid is claimed to promote phagocytosis and to have immunostimulant activity. A growth-inhibiting effect on AQXSOO CAS: 76-25-5 HR: 3 experimentally induced tumors has been ARISTOCORT ACETONIDE described, but this effect has not been mf: C 2 4 H 3 1 0 6 F mw: 434.55 shown to have any clinical relevance. SYNS: ACETOSPAN 0 ARISTODERM 0 ARISTOGEL Extracts of species of Aristolochiacea have 0 9-a-FLUORO-1l-P,21-DIHYDROXY-l6-atradtionally been used as a bitter, and a ISOPROYLIDENEDIOXY-1,CPREGNADIENE, 3,ZODIONE 0 9-a-FLUORO-16-HYDROXYPREDNISOL-ONE broad range of therapeutic effects has been ACETONIDE 0 9-a-FLUORO-lG-a-17-aclaimed. ISOPBOPYLEDENEDIOXY PREDNISOLONE 0 9-a-
FLUORO-16-a-l7-a-ISOPROPYLIDENEDIOXYd-1HYDROCORTISONE 0 FLUTONE 0 KENACORT-A 0 KENALOG 0 TRAMACIN 0 TRIAMCINCOLONE ACETONIDE 0 TRIAMCINOLONEACETONIDE 0 TRIAMCINOLONE-16,17-ACETONIDE 0 VETALOG
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits acrid smoke and toxic fumes of F-. AQY250
CAS: 313-67-7
HR: 3
AQY750 HR: 3 AROMATIC AMINES PROP: Amines that contain one or more rings of unsaturated or cyclic HC, such as benzene. There are vast numbers of such amines. The term is largely due to the characteristic odor. SAFETY PROFILE: Many of these aromatic amines are recognized as carcinogenic to the human bladder, ureter, and renal pelvis, intestines, lung, liver, and prostate. See also AMINES. AQZSOO CAS: 585-54-6 ARSACETIN SODIUM SALT
HR: 3
100 ARA 700 9-ARSAFLUORENINIC ACID
mf: CaH9AsN04.Na
mw: 281.09
SYNS: ARSACETIN 0 ARSANILIC ACID, N-ACETYL-, SODIUM SALT 0 ARSONIC ACID, (4(ACETYLAMIN0)PHENYL)-, MONOSODIUM SALT (9CI) 0 SODIUM ACETYLARSANILATE
OSHA PEL: TWA 0.5 mg(As)/m3 ACGIH TLV: BEI: 35 I.L (As)/L inorganic
arsenic and methylated metabolites in urine SAFETY PROFILE: Poison by intravenous route. Moderately toxic by subcutaneous route. When heated to decomposition it emits toxic fumes of NO, and As. ARAIOO CAS: 5687-22-9 9-ARSAFLUORENINIC ACID mf: C12H9As02 mw: 260.13
HR: 3
SYNS: ARSAFLUORINIC ACID 0 SH-BENZ(B)ARSINDOLE, 5-HYDROXY-, 5-OXIDE 0 DIBENZARSENOLE, 5-HYDROXY-, 5-OXIDE 0 5HDIBENZARSOLE, 5-HYDROXY-, 5-OXIDE 0 DIBENZARSENOLIC ACID SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of As.
ARA250 CAS: 98-50-0 HR: 3 ARSANILIC ACID mf: C6HdsN03 mw: 217.06 PROP: Needles from aq solns. Mp: 232', bp: decomp, -HzO @ 15'. Insol in MezCO, CHCl3, C6H6; sltly sol in EtOH; sol in Et20, HzO, conc acids, alkalies. SYNS: p-AMINOBENZENEARSONIC ACID 4AMINOBENZENEARSOSIC ACID 0 AMINOPHENYLARSINE ACID 0 p-AMINOPHENYLARSINE ACID 0 p-AMINOPHENYLARSINIC ACID 0 4AMINOPHENYLARSONIC ACID 0 p-ANILINE-ARSONIC ACID 0 ANTOXYLIC ACID 0 p-ARSANIL-IC ACID 0 4ARSANILIC ACID 0 ATOXYLIC ACID CONSENSUS REPORTS: IARC Cancer Review: Animal Inadequate Evidence IMEMDT 23,39,80. Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(As)/m3 ACGIH TLV: BEI: 35 (As)/L inorganic arsenic and methylated metabolites in urine SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Moderately toxic by ingestion. Flammable, decomposes with
heat to yield flammable vapors. When heated to decomposition or on contact with acid or acid fumes it emits highly toxic fumes of As and NO,. See also ARSENIC COMPOUNDS and ANILINE. ARA5OO CAS: 127-85-5 HR: 3 ARSANILIC ACID, MONOSODIUM SALT DOT: UN 2473 mf: C6H7AsN03*Na mw: 239.05 PROP: Tetrahydrate: white, odorless, crystalhe powder; faint salty taste. Sol in water; somewhat sol in alc. SYNS: (4-AMIN0PHENYL)ARSONIC ACID SODIUM SALT 0 ANHYDROUS SODIUM ARSANILATE 0 ARSAMIN 0 ARSANILIC ACID SODIUM SALT 0 ARSINOSOLVIN 0 ARSONIC ACID, (4-AMINOPHENYL-, MONOSODIUM SALT ( 9 0 0 ATOXYL 0 MONOSODIUM (4-AMIN0PHENYL)-ARSONATE 0 NCIC61176 0 NUARSOL 0 PIGLET PRO-GEN V 0 PROGEN SODIUM 0 PROTOXYL 0 SOAMIN 0 SODIUM AMINARSONATE 0 SODIUM p-AMINO-BENZENEARSONATE 0 SODIUM AMINOPHENOL ARSONATE 0 SODIUM p-AMINOPHENYIARSON-ATE 0 SODIUMANALINE ARSONATE 0 SODIUM ANILARSONATE 0 SODIUM ARSANILATE 0 SODIUM ARSANILATE (DOT) 0 SODIUM p-ARSANILATE 0 SODIUM ARSONILATE 0 SONATE 0 TRYPOXYL
CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightTO-IGIOWh s t . OSHA PEL: TWA 0.5 mg(As)/m3 ACGIH TLV: BEI: 35 I.L (As)/L inorganic arsenic and methylated metabolites in urine DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by subcutaneous route. Can cause blindness. When heated to decomposition it emits very toxic fumes of As and NO,.
ARA750 CAS: 7440-38-2 HR: 3 ARSENIC DOT: UN 1558 af: As aw: 74.92 PROP: Silvery to black, brittle, crystalhe, or amorphous metalloid. Mp: 814' @ 36 am, bp: sub1 @ 612", d: black crystals 5.724 @ 14O, black amorphous 4.7, vap press: 1 mm
0-ARSENIC ACID ARB250
@ 372" (subl). Insol in water; sol in HN03. IDLH 5 mg/m3 (as As).
m-ARSENIC ACID mf: AsH03 mw: 123.93
SYNS: ARSEN (GERMAN,
SYN: METAARSENIC ACID
POLISH) ARSENIC, metallic (DOT) 0 ARSENIC BLACK 0 ARSENIC-75 0 ARSENICALS 0 COLLOIDAL ARSENIC 0 GREY ARSENIC 0 METALLIC ARSENIC
CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 7,100,87; Human Sufficient Evidence IMEMDT 23,39,80; Human Inadequate Evidence IMEMDT 2,48,73. Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine DFG MAK: DFG TRIC 0.2 mg/m3 calculated as arsenic in that portion of dust that can possibly be inhaled NIOSH REL: CL 2 pg(As)/m3 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen producing liver tumors. Poison by subcutaneous, intramuscular, and intraperitoneal routes. Human systemic skin and gastrointestinal effects by ingestion. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Flammable in the form of dust when exposed to heat or flame or by chemical reaction with powerful oxidizers such as bromates, chlorates, iodates, peroxides, lithium, NC4, m 0 3 , Khfn04, Rb2C2, AgN04, NOC1, IF5, CrO3, CIF3, C10, BrF3, BrFj, BrN3, RbGBCH, CsC3BCH. Slightly explosive in the form of dust when exposed to flame. When heated or on contact with acid or acid fumes, it emits highly toxic fumes; can react vigorously on contact with oxidizing materials. Incompatible with bromine azide, dirubidium acetylide, halogens, palladium, zinc, platinum, NCh, AgN03, CrO3, Na202, hexafluoroisopropylideneamino lithum.
ARB000
CAS: 10102-53-1
HR: 3
101
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community RghtTo-Know Lst. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine DFG MAK: Human Carcinogen NIOSH REL: (Arsenic, Inorganic) CL 2 wg(As)/m3/15M SAFETY PROFILE: Confirmed human carcinogen. When heated to decomposition it emits toxic fumes of arsenic. See also ARSENIC COMPOUNDS.
ARB250 CAS: 7778-39-4 0-ARSENIC ACID DOT: UN 1553/UN 1554 mf: AsH304 mw: 141.95
HR: 3
SYNS: ACIDE ARSENIQUE LIQUIDE (FRENCH) 0 ARSENATE 0 ARSENIC ACID, liquid (DOV 0 ARSENIC ACID, solid (DOT) 0 DESICCANT L-10 0 HI-YIELD DESICCANT H-10 0 ORTHOARSENIC ACID 0 RCRA WASTE NUMBER PO10 0 ZOTOX 0 ZOTOX CRAB GRASS KILLER
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community fightTo-Know List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine DFG MAK: Human Carcinogen NIOSH REL: (Arsenic, Inorganic) CL 2 pg(As)/m3/1 5M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion. An experimental teratogen. Human mutation data reported. When heated to
102 ARB750
ARSENIC ACID, CALCIUM SALT (2:3)
decomposition it emits toxic fumes of arsenic. See also ARSENIC COMPOUNDS. ARB750 CAS: 7778-44-1 HR: 3 ARSENIC ACID, CALCIUM SALT (2:3) DOT: UN 1573 mf: As20p3Ca mw: 398.08 PROP: Colorless, amorphous powder. D: 3.620. Solubdtty in water: 0.013/100 @ 25". IDLH 5 mg/m3 (as As). SYNS: ARSENIATE de CALCIUM 0 CALCIUMARSENAT 0 CALCIUM ARSENATE O O r ) 0 CALCIUM ORTHOARSENATE 0 CHIP-CAL 0 CHIP-CAL GRANULAR 0 CUCUMBER DUST 0 FENCAL 0 FLAC 0 KALO 0 KALZIUMARSENIAT (GERMAN) 0 KILMAG 0 PENCAL SECURITY 0 SPRACAL 0 TRICALCIUM ARSENATE 0 TRICALCIUMARSENAT (GERMAN) 0 TURF-CAL CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 7,100,87; Human Sufficient Evidence IMEMDT 23,39,80; Animal No Evidence IMEMDT 2,48,73; Animal Inadequate Evidence IMEMDT 23,39,80. Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community RightTo-Know List. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine DFG MAK: Human Carcinogen NlOSH REL: CL 2 pg(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion. Moderately toxic by shn contact. When heated to decomposition it emits toxic fumes of arsenic.
ARC000 CAS: 7778-43-0 HR: 3 ARSENIC ACID, DISODIUM SALT mf: Na2HAs0407H20 mw: 312.01 PROP: Colorless whte powder or solid, effloresces. D: 1.88, mp: -7H20 (@ 130",
bp: decomp @! 150". Solubility in water: 61/100 (@ 15"; sol in glycerin. SYNS: DISODIUM ARSENATE 0 DISODIUM ARSENIC ACID 0 DISODIUM HYDROGEN ARSENATE 0 DISODIUM HYDROGEN ORTHO-ARSENATE 0 DISODIUM MONOHYDROGEN ARSENATE 0 SODIUM ACID ARSENATE 0 SODIUM ARSENATE 0 SODIUM ARSENATE DIBASIC, anhydrous CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community RightTo-Ihow List. OSHA PEL: TWA 0.5 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Arsenic, Inorganic) CL 2 Ilg(As)/m3/15M DFG MAK: Human Carcinogen SAFETY PROFILE: Confirmed human carcinogen. Poison by intraperitoneal route. Human mutation data reported. When heated to decomposition it emits toxic fumes of arsenic. See ARSENIC COMPOUNDS.
ARC250 CAS: 10048-95-0 HR: 3 ARSENIC ACID, DISODIUM SALT, HEPTAHYDRATE mf: AsH0402Na.7H20 mw: 427.05 PROP: Prisms. Mp: 40". Very sol in water; sltly sol in EtOH. SYNS: DISODIUM ARSENATE, HEPTAHYDRATE 0 SODIUM ACID ARSENATE, HEPTAHYDRATE 0 SODIUM ARSENATE, DIBASIC, HEPTAHYDRATE 0 SODIUM ARSENATE HEMAHYDRATE CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Arsenic, Inorganic) CL 2 pg(As)/m3/15M DFG MAK: Human Carcinogen
ARSENIC ACID, MONOPOTASSIUM SALT ARD250 SAFETY PROFILE: Confirmed human carcinogen. Poison by subcutaneous route. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. See also ARSENIC COMPOUNDS. When heated to decomposition it emits toxic fumes of arsenic.
ARC500 CAS: 7774-41-6 HR: 3 ARSENIC ACID, HEMIHYDRATE mf: AsH304*1/2HzO mw: 150.96 PROP: White, translucent crystals. Mp: 35.5', bp: -H20 @ 160°, d: 2.0-2.5. SYNS: ARSENIC ACID, solid (DOT) 0 ORTHOARSENIC ACID HEMIHYDRATE CONSENSUS REPORTS: Arsenic and its compounds are on the Community RghtTo-Know Lst. OSHA PEL: TWA 0.01 mg(As); Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Arsenic, Inorganic) CL 2 pg(As)/m3/15M DFG MAK: Human Carcinogen SAFETY PROFILE: Confirmed human carcinogen. Poison by intravenous route. When heated to decomposition it emits toxic fumes of arsenic. See also ARSENIC COMPOUNDS.
ARC750 CAS: 7645-25-2 HR: 3 ARSENIC ACID, LEAD SALT DOT: UN 1617 mf: AsH304*7Pb mw: 1592.28 SYNS: ARSENIATE de PLOlK3(FRENCH) 0 LEAD ARSENATE CONSENSUS REPORTS: Arsenic compounds and lead compounds are on the Community Rght-To-Know List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine
103
NIOSH REL: (Lead, Inorganic): 10H TWA 0.10 mg(Pb)/m3; (Arsenic, Inorganic): CL 0.002 mg(As)/m3/15M DFG MAK: Human Carcinogen DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion. See also LEAD COMPOUNDS and ARSENIC COMPOUNDS. When heated to decomposition it emits very toxic fumes of lead and arsenic.
ARDOOO CAS: 10103-50-1 HR: 3 ARSENIC ACID, MAGNESIUM SALT DOT: UN 1622 mf: AsH304*7Mg mw: 312.12 PROP: Monoclinic, whte crystals. D: 2.60-2.61. SYNS: ARSENIATE de MAGNESIUM (FRENCH) 0 MAGNESIUM ARSENATE 0 MAGNESIUM ARSENATE PHOSPHOR CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 P (As)/L inorganic arsenic and methylated metabolites in urine DFG MAK: Human Carcinogen NlOSH REL: (Arsenic, Inorganic) CL 2 ,Mg(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion. When heated to decomposition it emits toxic fumes of arsenic. See also ARSENIC COMPOUNDS.
ARD250 CAS: 7784-41-0 HR: 3 ARSENIC ACID, MONOPOTASSIUM SALT DOT: UN 1677 mf: AsH204.K mw: 180.04 SYNS: MACQUER'S SALT 0 MONOPOTASSIUM ARSENATE 0 MONOPOTASSIUM DIHYDROGEN ARSENATE 0 POTASSIUM ACID ARSENATE 0
104 ARD500
ARSENIC ACID, MONOSODIUM SALT
POTASSIUM ARSENATE 0 POTASSIUhI ARSENATE, MONOBASIC 0 POTASSIUM DIHYDROGEN ARSENATE 0 POTASSIUM HYDROGEN ARSENATE
CONSENSUS REPORTS: IARC Cancer
Review: Human Sufficient Evidence IMEMDT 23,39,80. Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community RlghtTo-Know List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Arsenic, Inorganic) CL 2 pg(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen. Mutation data reported. When heated to decomposition it emits toxic fumes of arsenic. See also ARSENIC COMPOUNDS. ARDSOO CAS: 15120-17-9 HR: 3 ARSENIC ACID, MONOSODIUM SALT mf: AsOpNa mw: 145.91 PROP: Needle-like fibrous hygroscopic crystals. Sol in water. SYNS: ARSENIC ACID, SODIUM SALT (9CI) 0 SODIUM ARSENATE 0 SODIUhl METAARSENATE SODIUM MONOHYDROGEN ARSENATE CONSENSUS REPORTS: Arsenic and its
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine DFG MAK: Human Carcinogen NIOSH REL: (Arsenic, Inorganic) CL 2 Pg(As)/m3/15M SAFETY PROFILE: Confirmed human carcinogen. A poison. Mutation data reported. See also ARSENIC COMPOUNDS. When heated to
decomposition it emits toxic fumes of arsenic. ARD6OO CAS: 10103-60-3 HR: 3 ARSENIC ACID, MONOSODIUM SALT mf: AsHzO4oNa mw: 163.93 PROP: Solid. Mp: 118'. SYNS: MONOSODIUM ARSENATE 0 SODIUM ARSENATE 0 SODIUM DIHYDROGEN ARSENATE SODIUM DIHYDROGES ORTHOARSENATE CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightTo-Know L s t . OSHA PEL: TWA 0.5 mg(As)/m3; Cancer Hazard ACGIH TLV: BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: CL 2 pg(As)/m3/15M DFG MAK: Human Carcinogen SAFETY PROFILE: Confirmed human carcinogen. Poison by intravenous route. When heated to decomposition it emits toxic fumes of arsenic.
ARD750 CAS: 7631-89-2 HR: 3 ARSENIC ACID, SODIUM SALT DOT: UN 1685 mf: AsH30407Na mw: 202.94 SYNS: FATSCO ANT POISON
SODIUM ARSENATE
(DOT) 0 SODIUM METAARSENATE 0 SODIUM
ORTHOARSENATE 0 SWEENEY'S ANT-GO
CONSENSUS REPORTS: IARC Cancer Review: Human Sufficient Evidence IMEMDT 23,39,80; Animal Inadequate Evidence IMEMDT 2,48,73;IMEMDT 23,39,80. Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community Right-To-Know List. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: CL 2 pg(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic
ARSENIC CHLORIDE ARFSOO
data. Poison by ingestion, intravenous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of As and Na2O. See also ARSENIC COMPOUNDS. ARE000 CAS: 64070-83-3 HR: 3 ARSENIC(V) ACID, TRISODIUM SALT, HEPTAHYDRATE (1 :3:7) mf: As04*3Naa7H20 mw: 334.03 SYN: TRISODIUM ARSENATE, HEPTAHYDRATE CONSENSUS REPORTS: Arsenic and its
compounds are on the Community RightT o - K ~ o wList. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 I.I (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Arsenic, Inorganic) CL 2 pg(As)/m3115M DFG MAK: Human Carcinogen SAFETY PROFILE: Confirmed human carcinogen. Poison by intraperitoneal route. See also ARSENIC COMPOUNDS. When heated to decomposition it emits toxic fumes of arsenic. ARE500 CAS: 8028-73-7 ARSENICAL DUST DOT: UN 1562
HR: 3
SYNS: ARSENICAL FLUE DUST 0 FLUE DUST, ARSENIC CONTAINING CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community RightT o - K ~ o wList. OSHA PEL: TWA 0.5 mg(As)/m3 ACGIH TLV: BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: CL 2 pg(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A poison. See also ARSENIC COMPOUNDS.
ARE750
CAS: 8028-73-7
HR: 3
105
ARSENICAL FLUE DUST DOT: UN 1562 CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightTo-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.5 mg(As)/m3 DFG MAK: Human Carcinogen DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic data. Poison by inhalation and ingestion. See also ARSENIC COMPOUNDS. ARF250 CAS: 7784-33-0 HR: 3 ARSENIC(II1) BROMIDE DOT: UN 1555 mf: AsBr3 mw: 314.65 PROP: Colorless, deliquescent, rhombic crystals. Mp: 32.8", bp: 220.0", vap press: 1 mm @ 41.8", d: 3.3972 @ 25O, @q) 3.3282. SYNS: ARSENIC TRIBROMIDE 0 ARSENOUS BROMIDE 0 ARSENOUS TRIBROMIDE 0 TRIBROMOARSINE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community RightT O - ~ OhW st. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 ,J (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Arsenic, Inorganic) CL 2 pg(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen. A poison. See also ARSENIC COMPOUNDS and BROMIDES. When heated to decomposition it emits very toxic fumes of As and Br-.
ARFSOO CAS: 7784-34-1 HR: 3 ARSENIC CHLORIDE DOT: UN 1560 mf: AsCl3 mw: 181.27 PROP: Colorless, oily liquid. Freezing to colorless crystals with pearly sheen. Fumes
106 ARF750
ARSENIC COMPOUNDS
in air. D: 2.15 @ 25O, mp: - 1 6 O , bp: 130'. Decomp in water and by UV light; misc in chloroform, CC4, ether, iodine, P, S, alkali ioldes, oils and fats. Vap d: 6.25, vap press: 10 mm @ 23.5'. SYNS: ARSENIC BUTTER 0 ARSENIC(II1) CHLORIDE 0 ARSENIOUS CHLORIDE 0 ARSENOUS CHLORIDE 0 ARSENOUS TRICHLORIDE (9CI) 0 CHLORURE d'ARSENIC (FREXCH) cl CHLORURE ARSENIEUX (FRENCH) 0 FUMING LIQUID ARSENIC 0 TRICHLOROARSINE 0 TRICHLORURE d'ARSENIC (FRENCH)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Arsenic and its compounds are on the Community RightTo-Ibow List. EPA Extremely Hazardous Substances Lst. OSHA PEL: OSHA: Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 )J (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Arsenic, Inorganic) CL 2 pg(As)/m3/1 5M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen. A poison via inhalation. See also ARSENIC COMPOUNDS and CHLORIDES. Very poisonous; fumes in air. Mutation data reported. When heated to decomposition it emits very toxic fumes of As and C1-. Highly reactive. Explodes with Na, K, and Al on impact.
ARF750 ARSENIC COMPOUNDS
HR: 3
SYN: ARSENICALS
CONSENSUS REPORTS: Arsenic and its compounds are on the Community kghtTo-Know List. OSHA PEL: Inorganic: TWA 0.01 mg(As)/m3; Cancer Hazard; Organic: TWA 0.5 mg(As)/m3 ACGIH TLV: Inorganic: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: CL 2 pg(As)/m3/15M
SAFETY PROFILE: Inorganic compounds
are confirmed human carcinogens producing tumors of the mouth, esophagus, larynx, bladder, and paranasal sinus. Recognized carcinogens of the skin, lungs, and liver. Used as insecticides, herbicides, silvicides, defoliants, desiccants, and rodenticides. Poisoning from arsenic compounds may be acute or chronic. Acute poisoning usually results from swallowing arsenic compounds; chronic poisoning from either swallowing or inhaling. Acute allergic reactions to arsenic compounds used in medical therapy have been fairly common, the type and severity of reaction depending upon the compound. Inorganic arsenicals are more toxic than organics. Trivalent is more toxic than pentavalent. Acute arsenic poisoning (from ingestion) results in marked irritation of the stomach and intestines with nausea, vomiting, and darrhea. In severe cases, the vomitus and stools are bloody and the patient goes into collapse and shock with weak, rapid pulse, cold sweats, coma, and death. Chronic arsenic poisoning, whether through ingestion or inhalation, may manifest itself in many different ways. There may be disturbances of the digestive system such as loss of appetite, cramps, nausea, constipation, or diarrhea. Liver damage may occur, resulting in jaundice. Disturbances of the blood, kidneys, and nervous system are not infrequent. Arsenic can cause a variety of skin abnormalities including itching, pigmentation, and even cancerous changes. A characteristic of arsenic poisoning is the great variety of sympt-oms that can be produced. Dangerous; when heated to decomposition, or when metallic arsenic contacts acids or acid fumes, or when water solutions of arsenicals are in contact with active metals such as Fe, Al, or Zn, highly toxic fumes of arsenic are emitted.
ARGSOO ARSENIC HEMISELENIDE mf: AszSe mw: 228.78
HR: 3
ARSENIC PENTOXIDE ARHSOO CONSENSUS REPORTS: Arsenic compounds and its compounds as well as
selenium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard; TWA 0.2 mg(Se)/m3 ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine; TWA 0.2 mg(Se)/m3 DFG MAK: DFG TRIC 0.2 mg/m3 calculated as arsenic in that portion of dust that can possibly be inhaled; 0.1 mg(Se)/m3 NlOSH REL: CL 2 pg(As)/m3 SAFETY PROFILE: Confirmed human carcinogen. When heated to decomposition it emits fumes of As and Se. Incompatible with oxidizing materials. When heated to decomposition it emits htghly toxic fumes of Se and arsenic. See ARSENIC COMPOUNDS and SELENIUM COMPOUNDS. ARG750 CAS: 7784-45-4 HR: 3 ARSENIC IODIDE mf: As13 mw: 455.62 PROP: Lustrous, orange-red, hexagonal crystals, leaves or platelets. Mp: 146O, bp: 403O, d: 4.38 (@, 13'. Sol in Hz0, EtzO, CS2, xylene, dioxan; sltly sol in conc HC1. SYNS: ARSENIC TRIIODIDE 0 ARSENOUS IODIDE 0 ARSENOUS TRIIODIDE (9CI) 0 TRIIODOARSINE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Arsenic and its compounds are on the Community kghtT o - K ~ o wList. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine; Proposed: (inhalable fraction) 0.1 mg/m3; Not Classifiable as a Human Carcinogen) NlOSH REL: (Arsenic, Inorganic) CL 2 pg(As)/m3/1 5M SAFETY PROFILE: Confirmed human carcinogen. A poison. See also ARSENIC
107
COMPOUNDS and IODIDES. Can form a shock-sensitive compound with sodium or potassium. When heated to decomposition it emits very toxic fumes of I- and arsenic. ARH250 HR: 3 ARSENIC PENTASULFIDE mf: As& mw: 310.2 PROP: Brownish-yellow, glassy, amorphous, highly refractive mass. Mp: 500" (subl). CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.01 mg(As)/m3 ACGIH TLV: TLV 0.01 mg/m3Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NlOSH REL: CL 2 pg(As)/m3/15M SAFETY PROFILE: Confirmed human carcinogen. See also ARSENIC COMPOUNDS and SULFIDES. Flammable in the form of dust when exposed to heat or flame. Explosive when intimately mixed with powerful oxidizers, such as Cl2, m03,or chlorates. Will react with water and steam to produce toxic and flammable vapors. Incompatible with water, steam, and strong oxidizers. ARHSOO CAS: 1303-28-2 HR: 3 ARSENIC PENTOXIDE DOT: UN 1559 mf: A ~ 2 0 j mw: 229.84 PROP: White, amorphous, deliquescent solid. Mp: decornp (@ 800", d: 4.32. Sol in alc. Very sol in H20. SYNS: ANHYDRIDE ARSEXIQUE (FREXCH) 0 ARSENIC ACID 0 ARSENIC ACID ANHYDRIDE 0 ARSENIC ANHYDRIDE 0 ARSENIC OXIDE 0 ARSENIC0 OXIDE 0 DIARSENIC PENTOXIDE 0 RCRA WASTE NUMBER PO1 1 0 ZOTOX
CONSENSUS REPORTS: IARC Cancer Review: Human Sufficient Evidence IMEMDT 23,39,80. Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community Right-
Ioa ARIOOO ARSENIC SULFIDE
To-Know List. EPA Extremely Hazardous Substances List. OSHA PEL: OSHA: Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 1.1 (As)/L inorganic arsenic and methylated metabolites in urine DFG MAK: Human Carcinogen NlOSH REL: CL 2 1.1g(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion and intravenous routes. Experimental reproductive effects. Mutation data reported. Reacts vigorously with Rb2C2. When heated to decomposition it emits toxic fumes of arsenic. See also ARSENIC COMPOUNDS.
SAFETY PROFILE: Confirmed human
carcinogen with experimental tumorigenic data. A poison. Reacts violently with H202, (m03+ S). When heated to decomposition or on contact with acid or acid fumes it emits highly toxic fumes of S02, H2S, and As. Reacts with water or steam to emit toxic and flammable vapors. AR1250 CAS: 7784-35-2 HR: 3 ARSENIC TRlFLUOR1DE mf: AsF3 mw: 131.92 PROP: Very mobile, colorless liquid which fumes in air and is readily hydrolyzed. D: 3.01, mp: -5.95', bp: 63', vap press: 100 mm @ 13.2', 400 mm @ 41.5'. Insol in water; sol in alc, benzene, and mercury. SYNS: ARSENIC FLUORIDE
0 ARSENOUS FLUORIDE
0 TRIFLUOROARSINE
ARIOOO CAS: 1303-33-9 HR: 3 ARSENIC SULFIDE DOT: NA 1557 mf: As2S3 mw: 246.04 PROP: Red needles or yellow in polycrystal form. Bp: 707', d: 3.43, mp: 327'. Insol in water; sol in alkalies. SYNS: ARSENIC SESQUISULFIDE 0 ARSENIC SULFIDE YELLOW 0 ARSEKIC SLLPHIDE 0 ARSENIC TERSULPHIDE 0 ARSENIC TRISULFIDE 0 ARSENIC TRISULFIDE (DOq 0 ARSENIC YELLOW 0 ARSENIOUS SULPHIDE 0 ARSENOUS SULFIDE 0 AURIPIGMENT 0 C.I. 77086 0 C.I. PIGMENT YELLOW 0 DIARSENIC TRISULFIDE 0 DIARSENIC TRISULPHIDE 0 KING'S GOLD 0 KING'S YELLOW 0 ORPIMEKT CONSENSUS REPORTS: IARC Cancer Review: Human Sufficient Evidence IMEMDT 23,39,80. Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community RightTo-Know List. OSHA PEL: OSHA: Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 1.1 (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Arsenic, Inorganic) CL 2 cLg(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community fightTo-Know List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: T W A 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 1.1 (As)/L inorganic arsenic and methylated metabolites in urine NlOSH REL: (Arsenic, Inorganic) CL 2 1.1g(As)/m~/1 5M SAFETY PROFILE: Confirmed human carcinogen. A poison by inhalation. Strong reaction with P203. When heated to decomposition it emits very toxic fumes of As and F-. See also FLUORIDES and ARSENIC COMPOUNDS.
AR1750 CAS: 1327-53-3 HR: 3 ARSENIC TRlOXlDE DOT: UN 1561 mf: As203 mw: 197.84 PROP: Colorless, rhombic crystals (dimer, claudetite), or whlte powder. D: 4.15, mp: 312", bp: 460'. Solubihty in water: 1.82/100 @ 20'; sol in alc. Cubes: Colorless. D: 3.865, mp: 309'. Solubility in water: 1.2/100 @ 20'.
ARSENIDES ARJ250
SYNS: ACIDE ARSENIECX 0 ANHYDRIDE ARSENIEUX 0 ARSENIC BLANC 0 ARSENIC OXIDE 0 ARSENIC(I1I) OXIDE 0 ARSENIC SESQUIOXIDE 0 ARSESICUM ALBUM 0 ARSENIGEN SAURE 0 ARSENIOUS ACID 0 ARSENIOUS OXIDE 0 ARSENIOC‘STRIOXIDE 0 ARSENITE 0 ARSENOLITE 0 ARSENOUS ACID 0 ARSENOUS ACID ANHYDRIDE 0 ARSENOUS ANHYDRIDE 0 ARSENOUS OXIDE 0 ARSENOUS OXIDE ANHYDRIDE 0 ARSENTRIOXIDE 0 ARSODENT 0 CWUDELITE 0 CLAUDETITE 0 CRUDE ARSENIC 0 DIARSENIC TRIOXIDE 0 RCRA WASTE NUMBER PO12 0 WHITE ARSENIC CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 7,100,87; Human hmited Evidence IMEMDT 2,48,73; Human Sufficient Evidence IMEMDT 23,39,80; Animal Inadequate Evidence IMEMDT 2,48,73;IMEMDT 23,39,80. Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community Eght-To-Know List. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine DFG MAK: Human Carcinogen NIOSH REL: CL 2 pg(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen with experimental neoplastigenic and tumorigenic data. Poison by ingestion, subcutaneous, and intravenous routes. Human systemic effects by ingestion: sleep changes, muscle weakness, hypermotiltty, darrhea, cardiac arrhythmias, coma, fatty degeneration of the liver, depressed renal function tests. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Reacts vigorously with Rb2C2, CIF3, F2, Hg, OF2, NaC103. See also ARSENIC COMPOUNDS.
ARJOOO HR: 3 ARSENIC TRIOXIDE mixed with SELENIUM DIOXIDE (1:l) mf: AsOpOzSe mw: 233.88
109
SYN: SELENIUM DIOXIDE mixed with ARSENIC TRIOXIDE (1:l) CONSENSUS REPORTS: Arsenic and its compounds, as well as selenium and its compounds, are on the Community RightTo-Know List. OSHA PEL: T W A 0.01 mg(As)/mJ; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 IJ (As)/L inorganic arsenic and methylated metabolites in urine DFG MAK: 0.1 mg(Se)/m3 NIOSH REL: (Arsenic, Inorganic): CL 0.002 mg(As)/m3/15M SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic data. See also ARSENIC COMPOUNDS and SELENIUM COMPOUNDS. When heated to decomposition it emits very toxic fumes of As and Se.
ARJIOO CAS: 56320-22-0 HR: 3 ARSENIC TRISULFIDE DOT: NA 1557 mf: AsSz mw: 139.04 PROP: A solid. SYNS: ARSENIC DISULFIDE 0 ARSENIC SULFIDE (DOT)
OSHA PEL: OSHA: Cancer Hazard DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human
carcinogen. A poison. When heated to decomposition it emits toxic vapors of As and SO,. ARJ250 HR: 3 ARS ENIDES CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightTo-Know List. SAFETY PROFILE: Compounds of arsenic and hydrogen or metals (i.e., transitional, alkaline earth, or rare-earth). These materials are dangerous because they readily emit very toxic arsine and arsenic fumes when exposed to heat, moisture, acids, and acid fumes.
110 ARJSOO
ARSENIOUS ACID, SODIUM SALT
ARJSOO CAS: 14060-38-9 HR: 3 ARSENIOUS ACID, SODIUM SALT mf: AsH30307’Na mw: 286.88 PROP: Colorless or grayish-white powder. D: 1.87. SYNS: ARSENIOUS ACID, SODIUM SALT POLYMERS 0 ARSONIC ACID, SODIUM SALT (9CI) NATRIUMARSENIT (GERMAN) 0 SODIUM ORTHOARSENITE
CONSENSUS REPORTS: Arsenic and its compounds are on the Community RghtTo-Know List. OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Arsenic, Inorganic) CL 2 Ilg(As)/m3/15M SAFETY PROFILE: Confirmed human carcinogen. Poison by intraperitoneal and subcutaneous routes. Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of arsenic.
ARJ750 CAS: 1303-18-0 HR: 3 ARSENOPYRITE mf: AsFeS mw: 162.83 SYNS: ARSENOMARCASITE 0 MISPICKEL CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightTo-Know L s t . OSHA PEL: TWA 0.01 mg(As)/m3 ACGIH TLV: BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Arsenic, Inorganic) CL 2 pg(As)/m3115M SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits very toxic fumes of As and SO,.
decomposition it emits toxic fumes of NO, and As. ARJ760 CAS: 4164-07-2 HR: 3 p-ARSENOSO-N,N-BIS(2-CHLOROETHYL)ANILINE mf: CioH12AsC12NO mw: 308.05 SYN : ANILINE, p-ARSENOSO-S,N-BIS(2CHLOROETHYL-
OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by
intraperitoneal route. When heated to decomposition it emits toxic fumes of NO,, As, and Cl-. ARJ770 CAS: 5185-80-8 HR: 3 p-ARSENOSO-N,N-BIS(2-HYDROXYETHYL)ANILINE mf: CioHi&N03 mw: 27’1.17 SYN : ANILINE, p-ARSENOSO-N,N-BIS(2HYDR0XYETHYL)-
OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by
intraperitoneal route. When heated to decomposition it emits toxic fumes of NO, and As. ARJ800 CAS: 4164-06-1 HR: 3 p-ARSENOSO-N,N-DIETHYLANlLlNE mfi CioHi&NO mw: 239.17’ SYN : ANILINE, p-ARSENOSO-N,N-DIETHYLOSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of NO, and As. ARJSOO CAS: 63951-03-1 HR: 3 ARSENOXIDE SODIUM mf: CGH5AsNOpNa mw: 221.03 SYN: PHENOL, 2-AMINO-4-ARSENOSO-, SODIUM SALT
ARJ755 CAS: 1122-90-3 HR: 3 p-ARSENOSOANILINE mf: C6H6AsNO mw: 183.05 SYN: ANILINE, p-ARSENOSOOSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intraperitoneal route. When heated to
OSHA PEL: TWA 0.5 mg(As)/m3 ACGIH TLV: BEI: 35 p (As)/L inorganic
arsenic and methylated metabolites in urine SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of NO, and As. ARK250
CAS: 7784-42-1
HR: 3
ASBESTOS
ARSINE DOT: UN 2188 mf: AsH3 mw: 77.95 PROP: Thermally unstable, colorless; gas with mild garlic odor. D: 2.695 g/L, bp: -62.5’, vap d: 2.66, mp: -1 16’. Readily oxidzed to As203. Very little tendency to protonate. Solubility in water: 28 mg/100 @ 20’. Sol in benzene and chloroform. IDLH 3 PPm.
SYNS: ARSENIC HYDRID 0 ARSENIC HYDRIDE 0 ARSENIC TRIHYDRIDE 0 ARSENIURETTED HYDROGEN 0 ARSENOUS HYDRIDE 0 ARSENOWODOR (POLISH) 0 ARSENWASSERSTOFF (GERMAN) 0 HYDROGEN ARSENIDE CONSENSUS REPORTS: IARC Cancer
Review: Human Sufficient Evidence IMEMDT 23,39,80. Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community kghtTo-Know List. EPA Extremely Hazardous Substances Lst. OSHA PEL: TWA 0.05 ppm ACGIH TLV: TWA 0.005 ppm DFG MAK: 0.05 ppm (0.16 mg/m3) NIOSH REL: (Arsine) CL 2 pg(As)/m3/15M DOT CLASSIFICATION: 2.3; Label: Poison Gas, Flammable Gas SAFETY PROFILE: Confirmed human carcinogen. Poison by inhalation. Human red blood cell, gastrointestinal system, central nervous system, and other systemic effects by inhalation. Flammable when exposed to flame. Moderately explosive when exposed to Cl2, HN03, (K + NH$, open flame, or powerful shock. Dangerous, more toxic than its oxidation product. When heated to decomposition it emits highly toxic fumes of arsenic. See also ARSENIC, ARSENIC COMPOUNDS, and HYDRIDES. ARL250 CAS: 8022-37-5 HR: 2 ARTEMISIA OIL PROP: Chef constituent is Thujone, and found in the plant Al;temisiu ubsinthim L. (FCTXAV 13,681,75). SYNS: ABSINTHIUM 0 ARTEMISIA OIL (WOILM\YIOOD) 0 OIL, ARTEMISIA
ARM250
111
CONSENSUS REPORTS: Reported in
EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. An allergen. Habitual users develop “absinthtsm” with tremors, vertigo, vomiting, and hallucinations. May cause a contact dermatitis. When heated to decomposition it emits acrid smoke and irritating fumes. ARM000 CAS: 13425-94-0 HR: 3 ASALIN mf: C22H33C12N304 mw: 474.48 SYNS: N-ACETYI-SARCOLYSIL VALINE ETHYL ETHER 0 ASALINE 0 AZALINE 0 ETHYL ESTER of N
ACETYL-dl-SARCOSYLYL-d-VALINE
SAFETY PROFILE: Poison by ingestion, intramuscular, rectal, and intraperitoneal routes. An experimental teratogen. See also ESTERS.
ARM250 CAS: 1332-21-4 ASBESTOS DOT: NA 2212
HR: 3
SYNS: AMIANTHUS 0 AMOSITE (OBS.) 0 AMPHIBOLE 0 ASBEST (GERMAN) 0 ASBESTOS FIBER 0 FIBROUS GRUNERITE 0 NCI-C08991 0 SERPENTINE CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 7,106,87; Human Sufficient Evidence IMEMDT 2,17,73; IMEMDT 14,11,77; Animal Sufficient Evidence IMEMDT 2,17,73; IMEMDT 14,11,77. Reported in EPA TSCA Inventory. On Community Right-To-Know List. EPA Genetic Toxicology Program. OSHA PEL: TWA 2 d o n fibers/m3; CL 10 million fibers/m3; Cancer and Lung Disease Hazard ACGIH TLV: TWA 0.1 fibers/cc; Confirmed Human Carcinogen DFG MAK: DFG TRK: (Fine dust particles that are able to reach the alveolar area of the lung) crocidolite: 0.05 x 106 fibers/m3 (0.025 mg/m3) (definition of fiber: length greater than 5 pm; diameter less than 3 pm; length/dameter greater than 3:1, equivalent to 1 fiber/cc); chrysotile, amosite, anthophylltte, tremolite, actinolite: 1 x 106
112
ARM260
ASBESTOS, ACTlNOLlTE
fibers/m3 (0.05 mg/m3), applicable when there is more than 2.5% asbestos in the dust; 2.0 mg/m3, applicable when there is less than or equal to 2.5 weight percent asbestos in fine dust NlOSH REL: (asbestos): 0.1 fb/cc in a 400 L air sample DOT CLASSIFICATION: 9; Label: CLASS 9 SAFETY PROFILE: Confirmed human carcinogen producing lung tumors. Experimental neoplastigenic and tumorigenic data. Human pulmonary system effects by inhalation. Usually at least 4 to 7 years of exposure are required before serious lung damage (fibrosis) results. Mutation data reported. A common air contaminant. ARM260 CAS: 77536-66-4 ASBESTOS, ACTINOLITE DOT: NA 2212 SYNS: ACTINOLITE ASBESTOS
HR: 3
IMEMDT 14,11,77; Human Sufficient Evidence IMEMDT 2,17,73; IMEMDT 14,11,77. NTP Carcinogenesis Studies (feed); No Evidence: hamster NTPTR* NTP-TR-249,83. EPA Genetic Toxicology Program. OSHA PEL: TWA 2 miltton fibers/m3; CL 10 million fibers/m3; Cancer Hazard ACGIH TLV: TWA 0.1 fibers/cc; Confirmed Human Carcinogen DFG MAK: DFG TRK: (Fine dust particles that are able to reach the alveolar area of the lung) 1 X 106 fibers/m3 (0.05 mg/m3), applicable when there is more than 2.5% asbestos in the dust NlOSH REL: (asbestos): 0.1 fb/cc in a 400 L air sample SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported.
ASBESTOS (ACGIH)
CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 7,106,87; Animal Sufficient Evidence IMEMDT 14,11,77. OSHA PEL: TWA 2 million fibers/m3; CL 10 d o n fibers/m3; Cancer Hazard ACGIH TLV: TWA 0.1 fibers/cc; Confirmed Human Carcinogen DFG MAK: DFG TRIC (Fine dust particles that are able to reach the alveolar area of the lung) 1 X 106 fibers/m3 (0.05 mg/m3), applicable when there is more than 2.5% asbestos in the dust NlOSH REL: (asbestos): 0.1 fb/cc in a 400 L air sample DOT CLASSIFICATION: 9; Label: CLASS 9 SAFETY PROFILE: Confirmed human carcinogen. See also other asbestos entries. ARM262 CAS: 12172-73-5 ASBESTOS, AMOSITE
HR: 3
SYNS: AMOSITE ASBESTOS 0 ASBESTOS (ACGIH) 0 MYSORITE 0 NCI-C60253A
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 7,106,87; Animal Sufficient Evidence IMEMDT 2,17,73;
ARM264 CAS: 77536-67-5 ASBESTOS, ANTHOPHYLITE
HR: 3
SYNS: ANTHOPHYTJTE 0 ASBESTOS (ACGIH) 0 AZBOLEN ASBESTOS 0 FERROANTHOPHYLLITE
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Animal Sufficient Evidence IMEMDT 2,17,73; IMEMDT 14,11,77; Human Sufficient Evidence IMEMDT 14,11,77. EPA Genetic Toxicology Program. OSHA PEL: TWA 2 million fibers/m3; CL 10 million fibers/m3; Cancer Hazard ACGIH TLV: TWA 0.1 fibers/cc; Confirmed Human Carcinogen DFG MAK: DFG TRK. (Fine dust particles that are able to reach the alveolar area of the lung) 1 X 106 fibers/m3 (0.05 mg/m3), applicable when there is more than 2.5% asbestos in the dust NlOSH REL: (asbestos): 0.1 fb/cc in a 400 L air sample SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported.
ASBESTOS, TREMOLITE ARM280
ARM266 CAS: 17068-78-9 HR: 3 ASBESTOS, ANTHOPHYLLITE SYNS: AZBOLEN ASBESTOS 0 16 F CONSENSUS REPORTS: NTP 10th Report on Carcinogens. ACGIH TLV: TWA 0.1 fibers/cc; Confirmed Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. Mutation data reported. ARM268 CAS: 12001-29-5 HR: 3 ASBESTOS, CHRYSOTILE DOT: NA 2212 PROP: Silky whte to green to brownish fibers. SYNS: 7-45 ASBESTOS 0 ASBESTOS (ACGIH) 0 AVIBEST C 0 CALIDRIA RG 100 0 CALIDRIA RG 144 0 CALIDRIA RG 600 0 CASSIAR AK 0 CHRYSOTILE ASBESTOS 0 HOOKER NO. 1 CHRYSOTILE ASBESTOS 0 K6-30 0 METAXITE 0 NCI-C61223A 0 PLXSTIBEST 20 0 5R04 0 RG 600 0 SERPENTINE 0 SERPENTINE CHRYSOTILE 0 SYLODEX 0 WHITE ASBESTOS 0 WHITE ASBESTOS (chiyotile, actinolite, anthophyllite, uemolite) (DOT)
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Human Sufficient Evidence IMEMDT 2,17,73; Animal Sufficient Evidence IMEMDT 2,17,73. NTP Carcinogenesis Studes (feed); Some Evidence: rat NTPTR* NTP-TR-295,85. EPA Genetic Toxicology Program. OSHA PEL: TWA 2 million fibers/m3; CL 10 million fibers/m3; Cancer Hazard ACGIH TLV: TWA 0.1 fibers/cc; Confirmed Human Carcinogen DFG MAK: DFG TRK: (Fine dust particles that are able to reach the alveolar area of the lung) 1 X 106 fibers/m3 (0.05 mg/m3), applicable when there is more than 2.5% asbestos in the dust NIOSH REL: (asbestos): 0.1 fb/cc in a 400 L air sample DOT CLASSIFICATION: 9; Label: CLASS 9 SAFETY PROFILE: Confirmed human carcinogen producing tumors of the lung. Human mutation data reported. Poison by intraperitoneal route. Human systemic
113
effects by inhalation: lung fibrosis, dyspnea, and cough. ARM275 CAS: 12001-28-4 HR: 3 ASBESTOS, CROCIDOLITE DOT: NA 2212 mf: ONa2Fe2033FeOsSi02H20 mw: 765.98 SYNS: AMORPHOUS CROCIDOLITE ASBESTOS 0 ASBESTOS (ACGIH) 0 BLUE ASBESTOS (DOT) 0 BROWN ASBESTOS (DOT) 0 CROCIDOLITE ASBESTOS 0 CROCIDOLITE (DOT) 0 FIBROUS CROCIDOLITE ASBESTOS 0 KROKYDOLITH (GERMAN) 0 NCI-C09007
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Animal Sufficient Evidence IMEMDT 14,11,77, IMEMDT 2,17,73; Human Sufficient Evidence IMEMDT 14,11,77. EPA Genetic Toxicology Program. OSHA PEL: TWA 2 million fibers/m3; CL 10 million fibers/m3; Cancer Hazard ACGIH TLV: TWA 0.1 fibers/cc; Confirmed Human Carcinogen DFG MAK: DFG TRK: (Fine dust particles that are able to reach the alveolar area of the lung) crocidolite: 0.05 X 106 fibers/m3 (0.025 mg/m3) (definition of fiber: length greater than 5 pm; diameter less than 3 pm; length/diameter greater than 3:1, equivalent to 1 fiber/cc) NIOSH REL: (asbestos): 0.1 fb/cc in a 400 L air sample DOT CLASSIFICATION: 9; Label: CLASS 9 SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data by inhalation. Human mutation data reported. ARM280 CAS: 77536-68-6 HR: 3 ASBESTOS, TREMOLITE DOT: NA 2212 SYNS: ASBESTOS (ACGIH) 0 FIBROUS TREMOLITE 0 NCI-C08991 0 TREMOLITE ASBESTOS
CONSENSUS REPORTS: IARC Cancer Review: Human Sufficient Evidence IMEMDT 14,11,77; Animal Sufficient Evidence IMEMDT 14,21,77. OSHA PEL: TWA 2 million fibers/m3; CL 10 million fibers/m3; Cancer Hazard
114 ARM500
ASCARIDOLE
ACGIH TLV: TWA 0.1 fibers/cc; Confirmed
Human Carcinogen DFG MAK: DFG TRI< (Fine dust particles that are able to reach the alveolar area of the lung) 1 x 106 fibers/m3 (0.05 mg/m3), applicable when there is more than 2.5% asbestos in the dust NIOSH REL: (asbestos): 0.1 fb/cc in a 400 L air sample DOT CLASSIFICATION: 9; Label: CLASS 9 SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic and neoplastigenic data. ARM500 CAS: 512-85-6 HR: 3 ASCARIDOLE mf: CtoH1602 mw: 168.26 PROP: Colorless unstable liquid. Mp: 3.3', bp: 40" @ 2 mm, 115' @ 15 mm, d: 1.010 @ 20'/4".
VITAMISIN 0 VITASCORBOL 0 XITIX 0 1XYLOASCORBIC ACID
CONSENSUS REPORTS: NTP
Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NTPTR* NTP-TR247,83; NTI?TR* NTP-TR-214,82. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and intravenous routes. Human systemic effects by intravenous route: blood, changes in tubules (including acute renal failure, acute tubular necrosis). An experimental teratogen. Other experimental reproductive effects. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
ARN125 CAS: 134-03-2 HR: D ASCORBIC ACID SODIUM SALT mf: C&806*Na mw: 199.13 PROP: Minute white to yellow crystals; SYNS: ASCARIDOL 0 ASCARIDOLE (orgamc peroxide) at 218". Freely sol in odorless. Decomp (DOT) 0 ASCARISIN 0 2,3-DIOXABICYCLO(2.2.2)OCT-5water; very sltly sol in alc; insol in ENE, 1-1SOPROPYL-CMETHYL- 0 l-METHYL-4-(1METHYLETHYL)-2,3-DIOXABICYCLO(2.2.2)OCT-5-ENEchloroform, ether. 0 1,4-PEROXIDO-p-MENTHENE-2
DOT CLASSIFICATION: Forbidden SAFETY PROFILE: Poison by ingestion.
Questionable carcinogen with experimental neoplastigenic and tumorigenic data. Flammable by spontaneous chemical reaction. An oxidizer. Explodes when heated >130" or when exposed to organic acids. Dangerous; heating emits toxic fumes and may explode; reacts with reducing materials. See also CHENOPODIUM OIL and PEROXIDES, ORGANIC. ARNOOO CAS: 50-81-7 HR: 2 I-ASCORBIC ACID mi: C6H806 mw: 176.14 PROP: White crystals. Mp: 192'. Sol in water; sltly sol in alc; insol in ether, chloroform, benzene, petroleum ether, fured oils, and fats. SYNS: ASCORBIC ACID 0 I(+)-ASCORBIC ACID 0 ASCORBUTINA 0 CEVITAMIC ACID 0 CEVITAMIN 0 FEMA No. 2109 0 3-KETO-I-GULOFURANOLACTONE 0 1-3-KETOTHREOHEXURONIC ACID LACTONE 0 NATRASCORB INJECTABLE 0 NCK54808 0 3-0X0-1GULOFUR4NOLACTONE 0 VITACIN 0 VITAMIN C 0
SYNS: I-ASCORBIC ACID SODIUM SALT 0 ASCORBICIN 0 ASCORBIN 0 CEBITATE 0 CENOLATE 0 ISKIA-C 0 MONOSODIUM ASCORBATE 0 NATRASCORB 0 NATRI-C 0 SODASCORBATE 0 SODIUM ASCORBATE (FCC) 0 SODIUM-1-ASCORBATE 0 VITAMIN C 0 VITAMIN C SODIUM CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Human mutation data reported. When heated to decomposition it emits toxic fumes of Na2O.
ARNISO HR: D ASCORBYL PALMITATE mfi C22H3807 mw: 414.54 PROP: Wte-to-yellowish powder; slt odor. Very sltly sol in water, vegetable oil. SYN: PALMITOYL, I-ASCORBIC ACID SAFETY PROFILE: When heated to
decomposition it emits acrid smoke and irritating fumes. ARN810 CAS: 70-47-3 HR: D I-AS PARAGINE mf: C4HgN203*H20 mw: 150.13
ATABRINE
ARQ250
115
PROP: W t e crystalhe powder or rhombic
PROP: Black or dark-brown mass. Bp:
hemihedral crystals; sltly sweet taste. Mp: 234'. Sol in water; insol in alc, ether.
<470°, flash p: 400°F (CC), d: 0.95-1.1, autoign temp: 905'F.
SYN: 1-a-AhfINOSUCCINAMIC ACID SAFETY PROFILE: When heated to
SYNS: ASPHALT, at or above its Fp (DOT) 0 ASPHALT FUMES (ACGIH) 0 ASPHALT, PETROLEUM 0 ASPHALTUM 0 BITUMEN (MAK) 0 JUDEAN PITCH 0 hlINERAL PITCH 0 PETROLEUM ASPHALT 0 PETROLEUM BITUMEN 0 PETROLEUM PITCH 0 PETROLEUM ROOFING TAR 0 ROAD ASPHALT (DOT) 0 ROAD TAR (DO9
decomposition emits toxic fumes of NO,. ARN825 CAS: 2283947-0 HR: 1 ASPARTAME mf: C14HlaN205 mw: 294.34 PROP: White crystalline powder from water or alc; odorless with a sweet taste. Mp: 190'. Sltly sol in water, alc. SYNS: 3-ARfINO-N-(aCARB0XYPHENETHYL)SUCCINAMICACID N-METHYL ESTER, stereoisomer 0 ASPARTYLPHENYLALANINE METHYL ESTER 0 N-l-a-ASPARTIL-1PHENYLAIANINE 1-METHYL ESTER (9CI) 0 CANDEREL DIPEPTIDE SWEETENER EQUAL METHYL ASPARTYLPHENYLALANATE 0 1-METHYL N-l-a-ASPARTIL-l-PHEN\iYLALANISE 0 NUTRASKCEET 0 SWEET DIPEMIDE
SAFETY PROFILE: Human systemic effects by ingestion: allergc dermatitis. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of NO,.
ARN850 CAS: 56-84-8 HR: 1 I-ASPARTIC ACID mf: C4H7NO4 mw: 133.10 PROP: Colorless to white crystals or leaflets; acid taste. Mp: 270'. Sltly sol in water; insol in alc, ether. SYNS: (S)-AMINOBUTANEDIOICACID 0 IAhfINOSUCCINIC ACID 0 ASPARAGIC ACID 0 1ASPARAGIC ACID 0 ASPARAGINIC ACID 0 1ASPARAGINIC ACID 0 ASPARTIC ACID 0 (l-ASPARTIC ACID 0 1-(+)-ASPARTICACID 0 (S)-ASPARTICACID CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low toxicity by intraperitoneal route. When heated to decomposition emits toxic fumes of NO,.
AR0500 CAS: 8052-42-4 ASPHALT DOT: NA 1999
HR: 3
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,133,87; Human Inadequate Evidence IMEMDT 35,39,85. Reported in EPA TSCA Inventory. ACGIH TLV: TWA 0.5 mg/m3; Not Classifiable as a Human Carcinogen DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Asphalt Fumes) CL 5 mg/m3/15M DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. A moderate irritant. May contain carcinogenic components. Combustible when exposed to heat or flame. To fight fire, use foam, CO2, or dry chemical.
ARQ250 CAS: 83-89-6 HR: 3 ATABRINE mf: C23H30ClN30 mw: 400.01 PROP: Bright yellow crystals. Mp: decomp @ 248". SYNS: ACRICHINE 0 ACRINAMINE 0 ACRIQUINE 0 AKRICHIN 0 ANTIMALARINA 0 6-CHLORO-9-((4(DIETHYL AMINO)-I-METHYL BUTYL)AMINO)-2METHOXYACRIDINE 0 3-CHLORO-7-METHOXY-9-(1METHYL-4-DIETHYLAMINOBU~M1NO)ACRIDlNE 0 ERION 0 HAFFKININE 0 MEPACRINE 0 2METHOXY-6-CHLORO-9-DIETHYL4MINOPENTYLAMINOACRIDINE 0 QUINACRINE
SAFETY PROFILE: Poison by intravenous
and subcutaneous routes. Moderately toxic by ingestion. Mutation data reported. Experimental reproductive effects. Has been implicated in aplastic anemia. When heated to decomposition, it emits very toxic fumes of Cl- and NO,.
116 ARQGOO
ATRANORIN
ARQ600 CAS: 479-20-9 ATRANORIN mf: ClsHlsOs mw: 374.35
HR: 3
SYN: BENZOIC ACID, 3-FOR%m-2,4-DIHMROXY-6METHYL-, 3-HYDROXr-4-(METHOXYCARBONYL)-2,5DIMETHYLPHENYL ESTER SAFETY PROFILE: A poison by skin
contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating vapors.
SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. A skin and severe eye irritant. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of ClandNO,.
ARQ725 CAS: 1912-24-9 HR: 3 ATRAZINE mf: C8H14ClNj mw: 215.72 PROP: Crystals. Mp: 175-177'. Solubllity at 25': in water: 70 ppm; ether: 12,000 ppm; chloroform: 52,000 ppm; methanol: 18,000 PPm*
ARROOO CAS: 51-55-8 HR: 3 ATROPINE mf: C17H23N03 mw: 289.41 PROP: Solid. Mp: 116-1 17'. Colorless crystalline alkaloid.
CHLORO-4-ETHYLAMINEISOPROPYLAMINE-s-
CONSENSUS REPORTS: Reported in EPA
SYNS: ATROPIN (GERMAN) 0 EYEULES 0 dlHYOSCYAMINE 0 2-PHENYLHYDRACRYLIC ACID-3-aTROPANYL ESTER 0 P-PHENYL-y-OXYPROPIONNINE-0 0 AATREX 8OW' 0 2-AETHYLAMINO-4-CHLOR SAEURE-TROPYL-ESTER (GERMAN) 0 1-a-H,5-a-H6-ISOPROPYLA;LIINO-l,3,5-TRIAZIN (GERMAN) 0 2AETHYLAblINO-4-ISOPROPYLAIMINO-6-CHLOR-1,3,5- TROPAN-3-a-OL (_+)-TROPATE(ESTER) 0 dl-TROPANYL-2-HYDROXI-1-PHENYLPROPIOKATE 0 TROPIC TRIAZIN (GERMAN) 0 AKTIKON 0 AKTIKON PK 0 ACID, ESTER with TROPINE 0 TROPIC ACID-3-aAKTINIT A 0 AKTINIT PK 0 ARGEZIN 12ATAZINAX TROPANYL ESTER 0 TROPINE TROPATE 0 dl0 ATRANEX 0 ATRASINE 0 ATRATOL A 0 ATRAZIN TROPYLTROPATE 0 (i)-TROPYL TROPATE 0 ATRED 0 ATREX 0 CANDEX 0 CEKUZINA-T 0 2SYNS: A 361 0 AATREX 0 AATREX 4L 0 AATREX
TRIAZINE 0 l-CHLORO-3-ETHYLAMINO-5TSCA Inventory. ISOPROPYMhlINO-s-TRIAZINE 0 l-CHLORO-3SAFETY PROFILE: Poison by ingestion, ETHYLAhlINO-5-ISOPROP~~~INO-2,4,6-TRIAZINE 0 intravenous, and 2 - C H L O R O - ~ - E T H Y L A ~ ~ I ~ O - ~ - I S O P R O P Y L A I ~ I ~ O -subcutaneous, STRIAZINE 0 2-CHLORO-4-ETHYMMINO-Gintraperitoneal routes. Human systemic ISOPROPYLAMINO-1,3,j-TRIAZINE 0 6-CHLORO-Neffects by ingestion and intramuscular ETHYL-X-(1-METHYLETHYL)-l,3,5-TRIAZINE-2,4routes: visual field changes, mydriasis DIAMINE (9CI) 0 2-CHLORO-4-(2-PROPYL4MINO)-6@updlarydtlation), and muscle weakness. ETHYLAMINO-s-TRIAZINE 0 CRISATRINA 0 An experimental teratogen. Other CRISAZINE 0 CYAZIN 0 FARMCO ATRAZINE 0 FENAMIN 0 FENAMINE 0 FENATROL 0 G 30027 0 experimental reproductive effects. An GEIGY 30,027 0 GESAPRIM 0 GESOPRIM 0 GRIFFEX alkaloid. When heated to decomposition it 0 HUNGAZIN 0 HUNGAZIN PK 0 INAKOR 0 emits toxic fumes of NO,. OLEOGESAPRIM 0 PRIMATOL 0 PRIMAZE 0 RADAZIN 0 RADIZINE 0 SHELL A T U Z I N E ARRSOO CAS: 5548-1 HR: 3 HERBICIDE 0 STRAZINE 0 TRIAZINE A 1294 0 ATROPINE SULFATE (2:l) VECTAL 0 VECTAL SC 0 WEEDEX A 0 WONUK 0 ZEAZIN 0 ZEAZINE mf: mw: 676.90
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 mg/m3 ACGIH TLV: TWA 5 mg/m3; Not Classifiable as a Human Carcinogen DFG MAK: 2 mg/m3
PROP: Crystals. Mp: 190-194'. SYNS: ATROPIN SIRAN (CZECH) 0 ATROPINSULFAT (GERMAN) 0 SULFATE d'ATROPINE (FRENCH) 0 l-aH,5-a-H-TROPAN-3-a-OL (+)-TROPATE (ESTER), SULFATE (2:l) SALT 0 d-TROPANYL-Z-HYDROXY-1PHENYLPROPIONATE SULFATE 0 TROPINTRAN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
AZASERINE
ASASOO
117
SAFETY PROFILE: Poison by
SYNS: BROMETHOL 0 ETHOBROM
subcutaneous, intravenous, and intraperitoneal routes. Moderately toxic by ingestion. Human (child) pulmonary system effects by ingestion. Human systemic effects: decreased body temperature, cardiac arrhythmias. An experimental teratogen. Other experimental reproductive effects. See also ATROPINE. When heated to decomposition it emits very toxic fumes of NO, and SO,.
0 NARKOJAN 0 RENARCOL 0 TRIBROMETHANOL
ART250 CAS: 12192-57-3 HR: 3 1-AUROTHIO-d-GLUCOPYRANOSE mf: C ~ H I I O ~ S * A U mw: 392.20 PROP: Yellow crystals from EtOH (a$. Sol in water, insol in org solvs. SYNS: AUREOTAN 0 AUROMY'OSE 0 AUROTAN 0 AUROTHIOGLUCOSE 0 AURUMINE 0 AUTHRON 0 BRENOL 0 (d-GLGCOPYRAN0S'iLTHIO)GOLD 0 (l-dGLUCOSYLTHI0)GOLD 0 GLYSANOL B 0 GOLD THIOGLUCOSE 0 GTG 0 ORONOL 0 ROMOSOL 0 SOLGANAL 0 SOLGANAL B 0 (I-THIO-d-GLUCOPYRANOSAT0)GOLD 0 1-THIO-GLUCOPYRANOSE, MONOGOLD(1 f) SALT 0 THIOGLUCOSE d'OR (FRENCH) CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 13,39,77. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. A deadly human poison by an unspecified route. An experimental poison by intramuscular route. Moderately toxic by subcutaneous and intravenous routes. Human systemic effects: nausea or vomiting, cholestatic jaundlce, and eye effects. An experimental teratogen. Other experimental reproductive effects. See also GOLD COMPOUNDS. When heated to decomposition it emits very toxic fumes of SO,. Used to treat rheumatoid arthritis. ARW250 CAS: 75-80-9 HR: 3 AVERTIN mf: C2H3B1-30 mw: 282.78 PROP: Crystals, needles, or prisms with ethereal odor and aromatic taste. Mp: 80', bp: 92-93' @ 10 mm. Sltly water-sol; sol in alc and org solvs.
0 NARCOLAN
0 2,2,2-TRIBROMOETK4NOL 0 TRIBROMOETHYL
ALCOHOL 0 2,2,2-TRIBROMOETHYL ALCOHOL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous
and intraperitoneal routes. Moderately toxic by ingestion and other routes. Dangerous when heated; see also BROMIDES. ARYOOO CAS: 320-67-2 HR: 3 AZACYTIDINE mf: CaH12N405 mw: 244.24 PROP: Solid. Mp: 232-234' (decomp). SYNS: 5-AC 0 5-ACZ 0 4-AMINO-l-P-dRIBOFURANOSYL-d-TRIAZIN-2(1H)-ONE 0 4-AMINO-lP-d-RIBOFURANOSYL-I,3,5-TRIAZIN-2(1H)-ONE 0 ANTIBIOTIC I2 18496 0 AZACITIDINE 0 5AZACYTIDINE 0 5'-AZACYTIDINE 0 LADAKAMYCIN 0 MYLOSAR 0 NCI-C01569 0 NSC-102816 0 U 18496
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Lmited Evidence IMEMDT 26,37,81; NCI Carcinogenesis Bioassay (ipr); Inadequate Studies: rat NCITR* NCI-CG-TR-42,78; Clear Evidence: mouse NCITR* NCI-CGTR-42,78. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic data. Poison by ingestion, intravenous, and intraperitoneal routes. Human systemic effects by intravenous route: nausea, vomiting and dlarrhea, reduction in white cell count (luekopenia and agranulocytosis). An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. A skin irritant. When heated to decomposition it emits toxic fumes of NO,.
ASA500 CAS: 115-02-6 HR: 3 AZASERINE mf: CjH7N304 mw: 173.15 PROP: Light-yellow needles from EtOH (a$. Mp: 146-162' (decomp). Produced by
El
118 ASAGOO
AZASPIRACID
Review: Group 2B IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 10,73,76. EPA Genetic Toxicology Program. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by ingestion, intraperitoneal, and subcutaneous routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
Animal Limited Evidence IMEMDT 26,47,81. NCI Carcinogenesis Studies (ipr); No Evidence: rat CANCAR 40,1935,77; Clear Evidence: mouse CANCAR 40,1935,77. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed human carcinogen producing bladder tumors and leukemia. Poison by subcutaneous, intradermal, and intraperitoneal routes. Moderately toxic by ingestion. Human systemic effects: liver changes, hypermotility, diarrhea, nausea or vomiting, increased body temperature, BP lowering, decreased urine volume or anuria, normocytic anemia, bone marrow changes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and SO,. An immunosuppressant.
ASA6OO CAS: 214899-21-5 HR: 3 AZASPIRACID mf: C47H71N012 mw: 842.08 SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO,.
ASH500 CAS: 86-50-0 HR: 3 AZINPHOS METHYL mf: CloH12N303PS2 mw: 317.34 PROP: Crystals or brown, waxy solid. D: 1.44, mp: 74'. Very sltly sol in water, very sol in CHCl3, toluene. IDLH 10 mg/m3.
ASB250 CAS: 446-86-6 HR: 3 AZATHIOPRINE mf: C9H7N702S mw: 277.29 PROP: Pale-yellow crystals from MezCO (ad. Mp: 243-244' (decomp).
SYNS: AZINFOS-METHYL (DUTCH) 0 AZINPHOS METHYL, liquid (Dog 0 AZINPHOS-METILE (ITALIAN) 0 BAY 9027 0 BAYER 17147 0 BENZOTRlAZINE derivative of a METHYL DITHIOPHOSPHATE 0 BENZOTRIAZINEDITHIOPHOSPHORIC ACID DIhETHOXY ESTER 0 CARFENE 0 COTNION METHYL 0 CRYSTHION 2L 0 CRYSTHYON 0 DBD 0
the strain Strejh'omycesfragihs (85ERAY 2,1249,78). SYNS: AZASERIN 0 1-AZASERINE 0 AZS 0 CI-337 0 CL 337 0 CN-15,757 0 DIAZOACETATE @STER)-lSERINE 0 I-DIAZOACETATE (ESTER) SERINE 0 DIAZO-ACETICACID ESTER with SERINE 0 oDIAZOACETYL-I-SERINE NSC-742 0 P-165 0 RCRA WASTE NUMBER U015 I-SERINE DIAZOACETATE 0 1-SERINEDIAZOACETATE (ester)
CONSENSUS REPORTS: IARC Cancer
S-(3,4-DIHYDRO-4-OXO-BENZO(a)(1,2,3)TRIAZIN-3SYNS: AZANIN 0 AZATIOPRIN 0 AZOTHIOPRINE 0 %METHYL)-0,O-DIMETHYL PHOSPHORODITHIOATE BW 57-322 0 CCUCOL 0 IMURAN 0 IMUREK 0 0 S-(3,4-DIHYDRO-4-OXO-1,2,3-BENZOTRIAZIN-3IhlUREL 0 YLMETHYL)-0,O-DIMETHYLPHOSPHORODITHIOATE METHYL"TROIMIDAZOLYLh~ERCAI'T0PURINE 0 60 0,O-DIMETHYL-S-(BENZAZIMINOMETHYL) (l'-METHYL-4'-NITRO-5'-1WDAZOLn)-MERCAPTODITHIOPHOSPHATE 0 O,O-DIMETHYL-S-(1,2,3PURINE 0 6-(METHYL-p-NITRO-5-IiMIDAZOLYL)BENZOTRIAZINYL-4-KET0)METHYL PHOSPHOROTHIOPURINE 0 6-(1-METHYL-p-NITRO-5-IMIDAZOLDITHIOATE 0 O,O-DIMETHYJ-S-(3,4-DIHYDRO-4YL)-THIOPLRINE 0 6-((1-METHYI-4-NITROIMIDAZOL- KETO-1,2,3-BENZOTRIAZINYL-3-METHYL) 5-YL)THIO)PURINE0 6-(l-~ETHYL-4-NITROIMIDAZDITHIOPHOSPHATE 0 DIMETHYLDITHIOOL-5-YLTHI0)PURINE 0 6-((1-METHYL-.I-NITRO-lH- PHOSPHORIC ACID N-METHYLBENZAZIMIDEESTER 0 O,O-DIMETHYL-S-(4-OXO-3H-1,2,3-BENZOTRIZIANEIhfIDAZOL-5-YL)THIO)-lH-PL!RINE 0 NCI-C03474 0 3-METHYL)PHOSPHORODITHIOATE0 0,O-DIMETHNSC-39084 0 ROMSUL
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 7,119,87; Human Sufficient Evidence IMEMDT 26,47,81;
YL-S-(4-OXOBENZOTRIAZINO-3-METHYL)PHOSPHORO-DITHIOATE 0 O,O-DIMETHYL-S-(4-OXO-l,2,3BENZOTRIAZINO(3)-METHYL) THIOTHIONOPHOSPHATE 0 O,O-DIMETHYL-S-((4-OXO-3H-1,2,3-
BENZOTRIAZIN-3-YL)-METHYL)-DITHIOFOSFAAT
AZOBENZENE (DUTCH) 0 O,O-DIMETHYL-S-((4-OXO-3H-l,2,3BENZOTRIAZIN-3-YL)-METHYL)-DITHIOPHOSPHAT (GERMAN) 0 O,O-DIMETHYL-S-4-OXO-1,2,3BENZOTRIAZIN-3(4H)-YLMETHYL PHOSPHORODL THIOATE 0 O,O-DIMETIL-S-((4-OXO-3H-l,2,3BENZOTRIAZIN-3-IL)-METIL)-DITIOFOSFATO (ITALIAN) 0 ENT 23,233 0 GOTHNION 0 GUSATHION 0 GUTHION (DO?) 0 3-(MERCAlTOMETHYL)-1,2,3-
BENZOTRlAZIN-4(3H)-ONE-O,O-DIMETHYL PHOSPHORODITHIOATE 0 3-(MERCAlTOMETHYL)-
ASL250
119
Limited Evidence IMEMDT 9,47,75. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion, skin contact, and intravenous routes. A sktn and eye irritant. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
1,2,3-BENZOTRIAZIN-4(3H)-ONE-O,O-DIMETHYL PHOSPHORODITHIOATE-S-ESTER METHYLAZINPHOS 0 N-METHYLBENZAZIMIDE, DIMETHYLDITHIOPHOSPHORIC ACID ESTER 0 METHYL GUTHION 0 IMETILTRIAZOTION 0 NCICOO066
CONSENSUS REPORTS: NCI Carcinogenesis Bioassay (feed); Inadequate Studies: rat NCITR* NCI-CG-TR-69,78; No Evidence: mouse NCITR* NCI-CGTR-69,78. EPA Genetic Toxicology Program. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.2 mg/m3 (skin) ACGIH TLV: TWA 0.2 mg/m3 (skin, sensitizer); Not Classifiable as a Human Carcinogen DFG MAK: 0.2 mg/m3 SAFETY PROFILE: Poison by inhalation, ingestion, skin contact, intravenous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. Questionable carcinogen with experimental tumorigenic data. See also PARATHION and ESTERS. When heated to decomposition it emits very toxic fumes of PO,, SO,, and NO,.
ASIOOO CAS: 1072-52-2 1-AZIRIDINE ETHANOL mf: C4HgNO mw: 87.14 PROP: Liquid. Bp: 154-1 56'.
HR: 3
SYNS: 2-(1-AZIRlDINYL)ETHANOL0 P-HYDROXY-1ETHYLAZIRIDINE 0 N-(P-HYDROXYETHYL) 0 NAZIRIDINE 0 2-HYDROXY-1-ETHYLAZIRIDINE (2-HYDR0XYETHYL)AZIRIDINEO N-HYDROXYETHYL ETHYLENE IMINE 0 N-(2-HYDROXYETHYL)ETHYLENIMINE0 1-(2-HYDR0XYETHYL)ETHYLENIMINE CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal
AS1300 CAS: 4638-44-2 HR: 3 1AZIRIDINYL m-(BIS(2-CHLOROETHYL)AMINO)PHENYL KETONE mf: C13H16C12N20 mw: 287.21 PROP: A liquid. DOT CLASSIFICATION: 3; Label: Flammable Lquid SAFETY PROFILE: A poison by an unspecified route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO, and Cl-. ASL250 CAS: 103-33-3 HR: 2 AZOBENZENE mf: C12H10N2 mw: 182.23 PROP: Orange, monoclinic crystals. Mp: 68', bp: 297', d: 1.203 @, 20'/4', vap press: 1 mm @, 103.5'. Insol in water. Solubihty in alc = 4.2/100 @, 20' in ether (ligroin) = 12/100 @, 20'. SYNS: AZOBENZEEN (DUTCH) 0 AZOBENZIDE 0 AZOBENZOL 0 AZOBISBENZENE 0 AZODIBENZENE 0 AZODIBENZENEAZOFUME 0 BENZENEAZOBENZENE 0 DIAZOBEXZENE 0 DIPHENYLDIAZEXE 0 1,2-DIPHENYLDIAZENE 0 DIPHENYLDIIMIDE 0 ENT 14,611 0 NCI-C02926 0 USAF EK-704 CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 8,75,75; NCI Carcinogenesis Bioassay (feed); Clear Evidence: rat NCITR* NCI-CG-TR-154,79; No Evidence: mouse NCITR* NCI-CGTR-154,79. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and possibly other routes. Questionable carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. When heated to decomposition it emits toxic fumes of NO,.
120 ASL750
AZOBISISOBUTYLONITRILE
ASL750 CAS: 78-67-1 HR: 3 AZOBISISOBUTYLONITRILE DOT: UN 2952 mf: mw: 164.24 PROP: Crystals from EtOH. Mp: 107' (decomp).
mf: C12H10N20 mw: 198.23 PROP: Yellow, rhombic crystals. D: 1.248 @? 2Oo/2O0, mp: 36', bp: decomp. Insol in water; solubility in alc = 11.4/ 100 @? 15", solubility in ether @groin) = 43.5/100 @? 15'.
SYNS: ACETO AZIB 0 AIBN 0 a,a'-AZOBISISOBUTYLONITRILE 0 AZOBISISOBUTYRONITRILE 0 2,2'AZOBIS(ISOBUTYR0NITRILE)Cl 2,2'-AZOBIS(2;IIETHYLPROPIONITRILE) 0 AZODIISOBUTYRONITRILE 0 a,a'-AZODIISOBUTYRONITRILE 0 2,2'AZODIISOBUTYRONITRILE 0 AZODIISOBUTYRO0 NITRILE (Dog0 2,2'-DICYANO-Z,2'-AZOPROPANE POLY-ZOLE AZDN POROFOR 57 0 VAZO 64
SYNS: AZOBENZENE OXIDE 0 AZOSSIBENZENE (ITALIAN) 0 AZOXYBENZEEN (DUTCH) 0 AZOXYBENZIDE 0 AZOXYBENZOL (GERMAN) 0 AZOXYDIBENZENE 0 ORDINARY AZOXYBENZENE
CONSENSUS REPORTS: Cyanide and its
compounds are on the Community RightTo-Know List. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 4.1; Label: Flammable Solid, Explosive SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. Easily oxidized, unstable. Violent exothermic decomposition when heated. Solution in acetone may decompose explosively. Explodes when heated with heptane. When heated to decomposition it emits toxic fumes of NO, and CN-. See also NITRILES. A free-radcal generator. ASM3OO CAS: 123-77-3 HR: 3 AZODICARBONAMIDE mf: C2H4N402 mw: 116.08 PROP: Yellow to orange-red crystalline powder. Mp: above 180" (decomp). Sltly sol in dimethyl sulfoxide; insol in water, org solvs. SAFETY PROFILE: Flammable solid. When heated to decomposition it emits toxic fumes of NO,. AS0750 CAS: 495-48-7 AZOXYBENZENE
HR: 3
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous route. Moderately toxic by ingestion, skin contact, and other routes. A skin and eye irritant. Mutation data reported. Combustible. When heated to decomposition it emits toxic fumes of NO,. ASP000 CAS: 16301-26-1 AZOXYETHANE mf: C4H10N20 mw: 102.16 PROP: Bp: 46'.
HR: 3
SYNS: AZOXYAETHAN (GERMAN) 0 DIETHYLDIAZENE-1-OXIDE SAFETY PROFILE: Poison by
subcutaneous and intravenous routes. An experimental teratogen. Questionable carcinogen with experimental carcinogenic and tumorigenic data. When heated to decomposition it emits toxic fumes of NO,. ASP250 CAS: 25843-45-2 AZOXYMETHANE mf: C2H6N20 mw: 74.10 PROP: Oil. Bp: 98'.
HR: 3
SYN: AOM SAFETY PROFILE: Suspected carcinogen
with experimental carcinogenic and mmorigenic data. Poison by subcutaneous route. An experimental teratogen. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,
PROP: White to brownish-gray powder. Disagreeable odor. Sol in water, pyridine, ethanol; less sol in acetone, ether, chloroform, pentane, benzene.
BACOOO CAS: 9014-01-1 HR: 3 BACILLUS SUBTILE CARLSBERG PROP: A commercial raw proteolytic enzyme used in laundry detergents (FCTXAV 7,581,69). SYNS: ALCALASE 0 Am-ENZYME 0 BACILLOPEPTIDASE A 0 BACILLOPEPTIDASE B 0 BIOPRASE 0 COLISTINASE 0 E.C. 3.4.4.16 0 E.C. 3.4.21.14 0 MAXATASE 0 NAGARSE 0 SUBTILISIN (9C1, ACGIH) 0 SUBTILISIN CARLSBURG 0 SUBTILISIN NOVO 0 SUBTILOPEPTIDASE A 0 SUBTILOPEPTIDASE B 0 SUBTILOPEPTIDASE BPN’ 0 SUBTILOPEPTIDASE C 0 THERMOASE PC-10 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: CL 0.00006 mg/m3 SAFETY PROFILE: Moderately toxic by ingestion. An eye irritant. When heated to decomposition it emits toxic fumes of NO,.
BAC250 CAS: 1405-87-4 HR: 3 BACITRACIN PROP: White to pale-buff, hygroscopic powder; odorless or slt odor. Freely sol in water, alc, methanol, and glacial acetic acid; insol in acetone, chloroform, and ether. When heated to decomposition it emits acrid smoke and irritating fumes. SYNS: AYFIVIN 0 BACIGUENT 0 BACI-JEL 0 BACILIQUIN 0 BACITEK OINTMENT 0 FORTRACIN 0 PARENTRACIN 0 PENITRACIN 0 TOPITRACIN 0 USAF CB-7 0 ZUTRACIN CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion and subcutaneous routes. Mutation data reported.
SYNS: BMD 0 FORTRACIN (BACITRACIN-MD) 0 KEMITRACIN 10 0 MD BACITRACIN CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low oral toxicity. When heated to decomposition it emits acrid smoke and irritating fumes.
BAD400 HR: D BAKER’S YEAST EXTRACT PROP: From ruptured cells of Saccbaromyces cerevisiae. Liquid, paste or powder. Water sol. SYNS: AUTOLYZED YEAST EXTRACT 0 BAKERS YEAST GLYCAN SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes.
BAD750 CAS: 59-52-9 HR: 3 BAL mf: C3HsOS2 mw: 124.23 PROP: Viscous, oily liquid; pungent odor. Bp: 140’ @ 40 mm, vap d: 4.3, d: 1.2385 @ 25’/4’. SYNS: BRITISH ANTILEWISITE 0 DICAPTOL 0 DIMERCAPROL PROPANOL 0 DIMERCAPTOL 0 2,3DIMERCAPTOL-1-PROPA!!OL 0 DIMERCAPTOPROPANOL 0 2,3-DIMERCAPTOPROPANOL 0 2,3DI?riERCAPTOPROPL4N-l- 0 L 0 DITHIOGLYCEROL 0 1,2-DITHIOGLYCEROL 0 2,3-DITHIOPROPANOL 0 SULFACTIN 0 USAF ME-1 CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison via ingestion, intramuscular, parenteral, intraperitoneal, and intravenous routes. Experimental teratogenic effects. Human systemic effects by intramuscular route: hemorrhage and
BAC260 CAS: 55852-84-1 HR: 1 BACITRACIN METHYLENE DISALICYLATE 121
122
BAE750
BALSAM of PERU
dermatitis. Human blood and systemic skin effects by intramuscular route. It causes redness and swelling when applied locally to the shn, but does not produce blisters or ulcers. Intensely irritating to eyes and mucous membranes. Systemic symptoms are caused by injection. When heated to decomposition, it emits toxic fumes of SO,. Used as an antidote to arsenic, gold, and mercury poisoning.
BAE750 HR: 1 BALSAM of PERU PROP: Dark-brown, viscid liquid; vanilla odor. Sol in fixed oils; sltly sol in propylene glycol; insol in glycerin. Extracted from Mymylon pereirae Klotpch SYNS: BALSAM PERU OIL (FCC) 0 PERUVIAN BALSAM SAFETY PROFILE: A mild allergen.
Combustible when heated. When heated to decomposition it emits acrid smoke and irritating fumes.
BAG250 CAS: 144-02-5 HR: 3 BARBITAL SODIUM mf: CsH12N203*Na mw: 207.21 PROP: Bitter crystals or powder. SYNS: BARBITAL Na 0 BARBITAL SOLUBLE 0 BARBITONE SODIUM 0 DIETHYLBARBITURATE MONOSODIUM 0 5,5-DIETHYLBARBITURIC ACID SODIUM deriv. 0 DIETHYLMALONYLUREA SODIUM 0 EMBINAL 0 MEDINAL 0 NATRINAL 0 NATRIUMBARBITALS ( G E M N ) 0 NERVOSETON 0 2,4,6(1H,3H,5H)-PYRIMIDINETRIONE,5,5-DIETHYL-, MONOSODIUM SALT (9CI) 0 SODIUM BARBITAL 0 SODIUM BARBITONE 0 SODIUM DIETHYLBARBITURATE 0 SODIUIM-~,~-DIETHYLBARBITURATE 0 SODIUM ETHYLBARBITAL 0 SODIUM MALONYLUREA 0 SODIUM VERONAL 0 SOLUBLE BARBITAL 0 SOPRINAL 0 THYALONE 0 VERONAL SODIUM SAFETY PROFILE: Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Large doses cause marked depression (sometimes preceded by excitation), prolonged coma, and death. Experimental teratogenic and reproductive effects. Allergic shn reactions may occur on contact. Implicated in development of aplastic anemia. Questionable carcinogin
with experimental tumorigenic and neoplastigenic data. A truly habit-forming drug. Other experimental reproductive effects. Mutation data reported. Combustible. When heated to decomposition it emits toxic fumes of NO, and NazO. See also BARBITURATES.
BAH250 CAS: 7440-39-3 HR: 3 BARIUM DOT: UN 1400 af: Ba aw: 137.36 PROP: Silver-white, sltly lustrous, somewhat malleable metal. Mp: 727', bp: 1640°, d: 3.5 @ 20', vap press: 10 mm @ 1049'. Dissolves in H2O forming Ba(OH)2 s o h . Solution in NH30) blue-black soh. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Community Right-ToKnow List. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 DOT CLASSIFICATION: 4.3; Label: Dangerous When Wet SAFETY PROFILE: Water and stomach acids solubilize barium salts and can cause poisoning. Symptoms are vomiting, colic, diarrhea, slow irregular pulse, transient hypertension, and convulsive tremors and muscular paralysis. Death may occur in a few hours to a few days. Half-life of barium in bone has been estimated at 50 days. Dust is dangerous and explosive when exposed to heat, flame, or chemical reaction. Violent or explosive reaction with water, CCh, fluorotrichloromethane, trichloroethylene, and C2C14. Incompatible with acids, C2CLF3, C2H2FCl3, CzHC13 and water, 1,1,2trichlorotrifluoroethane, and fluorotrichloroethane. The powder may ignite or explode in air or other oxidizing gases. See also BARIUM COMPOUNDS. BAHSOO CAS: 543-80-6 BARIUM ACETATE mf: C4H60~Ba mw: 255.44
HR: 3
BARIUM CADMIUM STEARATE PROP: White or colorless crystals. Decomp on heating with BaC03 formation. Very sol in Hz0. SYNS: ACETIC ACID, BARIUM SALT 0 BARIUM DIACETATE 0 OCTAN BARNATY (CZECH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Barium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 SAFETY PROFILE: Poison via ingestion, intravenous, and subcutaneous routes. When heated to decomposition it emits acrid smoke and fumes. See also BARIUM COMPOUNDS.
BAIOOO CAS: 18810-58-7 HR: 3 BARIUM AZIDE DOT: UN 0224/UN 1571 mf: BaN6 mw: 221.40 PROP: Monoclinic prisms or crystals, decomp on heating with loss of N2 at about 12'. Mp: evolves Nz at about 120', bp: explodes, d: 2.936. Very sol in H20; sltly sol in EtOH; ins01 in EtzO. SYNS: BARIUM AZIDE, dry or wetted with <50% water, by weight (UN 0224) (DOT) 0 BARIUM AZIDE, wetted with not 6 0 % water, by weight (UN 1571) (DOT) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Barium and its compounds are on the Community fightTo-Know List. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 DOT CLASS1FlCATION: EXPLOSIVE 1.1A; Label: EXPLOSIVE 1.1A, Poison (UN 0224); DOT Class: 4.1; Label: Flammable Solid, Poison (UN 1571) SAFETY PROFILE: A poison. Moderate explosion hazard when shocked or heated to 275'. Spontaneously flammable in air. Very unstable. When heated to decomposition it emits toxic fumes of NO,. See also
BA1800
123
BARIUM C O W O U N D S (soluble) and AZIDES.
BA1750 CAS: 13967-90-3 HR: 3 BARIUM BROMATE DOT: UN 2719 mf: Ba(Br03)2*H20 mw: 41 1.21 PROP: White or colorless crystals or crystalline powder. Decomp on heating with 0 2 evolution and BaBr2 formation. Mp: decomp @ 260', d: 3.99 @ 18'. CONSENSUS REPORTS: Barium and its compounds are on the Community RightTo-Know List. EPA TSCA Chemical Inventory. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 DOT CLASSIFICATION: 5.1; Label: Oxidizer, Poison SAFETY PROFILE: Very toxic. Fire hazard by chemical reaction with easily oxidued materials. Explodes at 300". Mmures with sulfur are unstable storage hazards; igniting immediately at 91'C and after a 2-1 1 day delay period at room temperature. Incompatible with Al, As, C, Cu, metal sulfides, organic matter, P, and reducing materials. When heated to decomposition it emits toxic fumes of Br-. See also BARIUM COMPOUNDS (soluble) and BROMINE. BA1800 CAS: 1191-79-3 HR: 3 BARIUM CADMIUM STEARATE mfi C72H14008*Ba*Cd mw: 1383.86 SYNS: CADMIUM BARIUM STEARATE 0 OCTADECANOIC ACID, BARIUM CADMIUM SALT (4:l:l) (9CI) D STWRIC ACID, BARIUM CADMIUM SALT (4:l:l) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.01 mg(Cd)/m3; Suspected Carcinogen NIOSH REL: TWA reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Moderately toxic by ingestion.
124
BAJ250
BARIUM CARBONATE (1:l)
When heated to decomposition it emits toxic fumes of Ba and Cd.
DFG MAK: 0.5 mg(Ba)/m3 DOT CLASSIFICATION: 5.1; Label:
Oxidizer, Poison BAJ250 CAS: 513-77-9 HR: 3 BARIUM CARBONATE (1 :1) mf: C03.Ba mw: 197.35 PROP: White orthorhombic powder or crystals, becomes hexagonal at 8' and cubic at 976'. Decomp on heating with C02 loss. Mp: 1740' @ 90 atm, bp: decomp, d: 4.43. Dissolves in acids to form corresponding Ba salts. Practically insol in H2O; insol in alc EtOH. SYNS: BARIUM CARBONATE 0 CARBONIC ACID, BARIUhI SALT (1:l) 0 C.I. 77099 0 C.I. PIGMENT WHITE 10
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Barium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 SAFETY PROFILE: Poison by ingestion, intravenous, and intraperitoneal routes. Human systemic effects by ingestion: stomach ulcers, muscle weakness, paresthesias and paralysis, hypermotility, diarrhea, nausea or vomiting, lung changes. Experimental reproductive effects. Incompatible with BrF3 and 2furanpercarboxylic acid. See also BARIUM COMPOUNDS (soluble).
BAJSOO CAS: 13477-00-4 HR: 3 BARIUM CHLORATE DOT: UN 1445 mf: C1206.Ba mw: 304.24 PROP: Colorless prisms or white powder. Mp: loses HzO @ 414', d: 3.18. SYN: CHLORIC ACID, BARIUM SALT
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Barium and its compounds are on the Community RightTo-Know Lst. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen
SAFETY PROFILE: A poison. For fire and explosion hazards, see CHLORATES. Incompatible with Al, As, C, charcoal, Cu, MnOz, metal sulfides, S4N4, organic matter, P, S. See also BARIUM COMPOUNDS (soluble).
BAKOOO CAS: 10361-37-2 HR: 3 BARIUM CHLORIDE mf: BaC12 mw: 208.24 PROP: Colorless, deliquescent, orthorhombic, flat crystals. Undergoes orthorhombic to cubic phase transition at 9'. Mp: transition @ 925' to cubic crystals, bp: 1560', d: 3.856 @ 24'. Very sol in HzO; practically insol in EtOH. IDLH 50 mg/m3 (as Ba). SYNS: BARIUM DICHLORIDE
0 NCI-C61074 0 SBa
0108E
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Barium and its compounds are on the Community RightTo-Know List. EPA Genetic Toxicology Program. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 SAFETY PROFILE: A poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Inhalation absorption of barium chloride equals 60-80%; oral absorption equals 10-30%. Experimental reproductive effects. Mutation data reported. See also BARIUM COMPOUNDS (soluble). When heated to decomposition it emits toxic fumes of C1-.
BAK250 CAS: 10294-40-3 HR: 3 BARIUM CHROMATE(V1) mf: Ba.Ci-04 mw: 255.36 PROP: Heavy, pale-yellow, crystalline powder; darkens on heating. D: 4.498 @ 15'. Sol in strong acids; insol in org solvents.
BARIUM FLUORIDE
SYNS: BARIUM CHROiMATE (1:l) 0 BARIUM CHROMATE OXIDE 0 BARYTA YELLOW 0 CHROMIC ACID, BARIUM SALT (1:l) 0 C.I. 77103 I3 C.I. PIGMENT YELLOW 31 0 LEMON CHROME 0 LEMON YELLOW 0 PERMANENT YELLOW 0 STEINBUHL YELLOW 0 ULTRAMARINE YELLOW
CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 7,165,87; Animal Inadequate Evidence IMEMDT 2,100,73; Human Sufficient Evidence IMEMDT 23,205,80. Reported in EPA TSCA Inventory. Barium and its compounds are on the Community RghtTo-Know List. OSHA PEL: TWA 0.1 mg (C303)m3; 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen; 0.05 mg(Cr)/m3; Confirmed Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 NIOSH REL: TWA 0.001 mg(Cr(VI))/m3 SAFETY PROFILE: Confirmed human carcinogen. A poison. Mutation data reported. Reacts vigorously with reducing materials. See also BARIUM COMPOUNDS (soluble) and CHROMIUM COMPOUNDS. Used in pyrotechnics and as an explosive initiator.
BAK5OO HR: 3 BARIUM COMPOUNDS (soluble) CONSENSUS REPORTS: Barium and its compounds are on the Community RightTo-Know List. OSHA PEL: Soluble Compounds: TWA 0.5 mg(Ba)/m3 ACGIH TLV: Soluble Compounds:TWA 0.5 mg/m3 DFG MAK: Soluble Compounds: 0.5 mg/m3 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: The chromate is a human carcinogen. The soluble barium salts, such as the chloride and sulfide, are poisonous when ingested. The insoluble sulfate used in radiography is not acutely toxic. See also BARIUM SULFATE. Few cases of industrial systemic poisoning have been reported, but one investigator describes a fatal case of poisoning attributed
BAMOOO
125
to barium oxide, the symptoms being severe abdominal pain with vomiting, dyspnea, rapid pulse, paralysis of the arm and leg, and eventually cyanosis and death. The same investigator produced paralysis in animals with barium oxide and carbonate. The usual result of exposure to the sulfide, oxide, and carbonate is irritation of the eyes, nose, and throat, and of the skin, producing dermatitis. The salts mentioned are somewhat caustic. BAK750 CAS: 542-62-1 HR: 3 BARIUM CYANIDE DOT: UN 1565 mf: CzBaNz mw: 189.38 PROP: White, crystalline powder. SYNS: BARIUM CYANIDE, solid (DOT) 0 BARIUM DICYANIDE 0 RCRA WASTE NUMBER PO13
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds, as well as barium and its compounds, are on the Community RghtTo-Know List. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A deadly poison. See also CYANIDE and BARIUM COMPOUNDS (soluble). When heated to decomposition it emits toxic fumes of CN-.
BAL275 CAS: 6332-68-9 HR: 3 BARIUM DIBENZYLPHOSPHATE mf: CzsHzsBaOsPz mw: 691.84 OSHA P E l : TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of PO, and Ba. BAMOOO CAS: 7787-32-8 BARIUM FLUORIDE mf: BaFz mw: 175.34
HR: 3
126
BAN250
BARIUM(I1) NITRATE (1:2)
PROP: White, colorless powder or cubic crystals. Mp: 1368', bp: 2137', d: 4.89. Sltly sol in Hz0. SYN: BARYUhl FLUORURE (FRENCH) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Barium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(Ba)/m3; 2.5 mg(F) /m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen; TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift. DFG MAK: 0.5 mg(Ba)/m3 NIOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m3 SAFETY PROFILE: A poison by ingestion and intraperitoneal routes. Moderately toxic by subcutaneous route. An experimental teratogen. See also FLUORIDES and BARIUM COMPOUNDS (soluble). When heated to decomposition it emits toxic fumes of F-.
BAN250 CAS: 10022-31-8 HR: 3 BARIUM(I1) NITRATE (1 :2) DOT: UN 1446 mf: N206*Ba mw: 261.36 PROP: Luswous, colorless, cubic crystals. Mp: 592', bp: decomp, d: 3.24 @ 23'. Decomp on heating with evolution of NOz and 0 2 and formation of BaO. Insol in EtOH. IDLH 50 mg/m3 (as Ba). SYNS: BARIUM DINITRATE 0 BARIUM NITRATE (DOq 0 DUSICNAN BARNATY (CZECH) 0 NITRATE de BARYUhl (FRENCH) 0 NITRIC ACID, BARIUM SALT
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Barium and its compounds are on the Community RightTo-IOlow List. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3
DOT CLASSIFICATION: 5.1; Label:
Oxidizer, Poison SAFETY PROFILE: A poison by ingestion,
subcutaneous, parenteral, and intravenous routes. An irritant to slun and eyes. When heated to decomposition it emits very toxic fumes of NO,. An oxiduer. Mixtures with finely divided aluminum-magnesium alloys are easily ignitable and extremely sensitive to friction or impact. Such mixtures are used in chemical photoflash applications. Incompatible with (Mg + BaO2 + Zn), Al, and Mg alloys. When heated to decomposition it emits toxic fumes of NO,. See also BARIUM COMPOUNDS (soluble) and NITRATES. BAOOOO CASE1304-28-5 HR: 3 BARIUM OXIDE DOT: UN 1884 mf: BaO mw: 153.34 PROP: White to yellowish-white powder or cubic crystals; moisture-sensitive. Mp: 1913', bp: 2000' (approx), d: 5.72. Mod sol in EtOH; insol in MezCO. SYNS: BARIUM MONOXIDE 0 BARIUhI PROTOXIDE 0 BARYTA 0 CALCINED BARYTA 0 OXYDE de BARWhl (FRENCH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Barium and its compounds are on the Community RtghtTo-Know List. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: A poison via subcutaneous route. See also BARIUM COMPOUNDS (soluble). Combustible by spontaneous chemical reaction; produces heat on contact with water or steam. Reacts with HzO, Ba(OH)2. Incompatible with HzS, hydroxylamine, N204, triuranium octaoxide,
so3.
BARIUM STYPHNATE BAO900
BA0250 CAS: 1304-29-6 HR: 3 BARIUM PEROXIDE DOT: UN 1449 mf: BaO2 mw: 169.34 PROP: Pale, grayish-white powder. Mp: 450', bp: loses 0 2 @ 800', d: 4.96. Decomp on heating to BaO and 0 2 . Dissolves in water with formation of H202. SYNS: BARIO (PEROSSIDO di) (ITALIAIV) q BARIUM BINOXIDE 0 BARIUM DIOXIDE 0 BARIUMPEROXID (GERMAN) 0 BARIUMPEROXYDE (DUTCH) q BARIUM SUPEROXIDE 0 DIOXYDE de BARYUM (FRENCH) 0 PEROXYDE de BARYUM (FRENCH) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Barium and its compounds are on the Community kghtTo-Know List. OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 DOT CLASSIFICATION: 5.1; Label: Oxidizer, Poison SAFETY PROFILE: A poison via subcutaneous route. A powerful oxidtzer. Explodes on contact with acetic anhydride. Ignites when mixed with calcium-silicon alloys, powdered aluminum, powdered magnesium, water + organic compounds. Mixtures with propane react violently when heated. The powder ignites when heated to 265'C with selenium. Wood ignites with friction from the peroxide. Incompatible with H2S, water, peroxyformic acid, hydroxylamine solution, mixture of (Mg + Zn + Ba(N03)2), and organic matter. See also BARIUM COMPOUNDS (soluble) and PEROXIDES, INORGANIC.
BA0300 CAS: 50864-67-0 BARIUM POLYSULFIDE
HR: 3
SYNS : BARIUMPOLYSULFID q BARIUM SULFIDE 0 SOLABARUSOLBAR OSHA PEL: TWA 0.5 mg(Ba)/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not
Classifiable as a Human Carcinogen DFG MAK: 0.5 mg(Ba)/m3 SAFETY PROFILE: Poison by ingestion. Human systemic effects by ingestion: flaccid
127
paralysis without anesthesia, muscle weakness, and dyspnea. When heated to decomposition it emits toxic fumes of SO, and Ba.
BA0750 CAS: 17125-80-3 HR: 3 BARIUM SlLlCOFLUORlDE mf: F&i*Ba mw: 279.43 PROP: White or colorless rhombohedra1 crystalhe powder. D: 4.29 @ 21'/4', mp: 300' (decomp). Decomp on heating to form SiF4 and BaF2. Sltly sol in H20. Insol in EtOH. SYNS: BARIUM FLUOROSILICATE 0 BARIUM FLUOSILICATE q BARIUM HEXAFLUOROSILICATE 0 BARIUM HEXAFLUOROSILICATE(2.) 0 BARIUMSILICOFLUORID 0 BARIUM SILICON FLUORIDE 0 SILICATE(2-), HEXAFLUORO-, BARIUM 0 SILICATE(2-), HEXAFLUORO-, BARIUM (1:l) (9CI) 0 SILICON FLUORIDE BARIUM SALT CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Barium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(Ba)/m3; TWA 2.5 mgO/m3 ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen; TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shlft; 10 mg/g creatinine of fluorides in urine at end of shlft. DFG MAK: 0.5 mg(Ba)/m3 NIOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m3 DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic fumes of F-. See also BARIUM COMPOUNDS (soluble).
BA0900 CAS: 20236-55-9 HR: 3 BARIUM STYPHNATE DOT: NA 0473 SYNS: 1,3-BENZENEDIOL,2,4,6-TRINITRO-, BARIUM SALT, HYDRATE (2:l:l) 0 RESORCINOL, 2,4,6TRINITRO-, BARIUM SALT, HYDRATE (2l:l)
DOT CLASSIFICATION: Explosive 1.1A;
Label: Explosive 1.1A
128
BAPO00
BARlUM SULFATE
SAFETY PROFILE: An explosive. When heated to decomposition it emits toxic
vapors of NO, and fumes of Ba.
BAPOOO CAS: 7727-43-7 HR: 2 BARIUM SULFATE mfi 0&Ba mw: 233.40 PROP: m t e , heavy, orthorhombic, odorless powder or crystals. Undergoes orthorhombic to monoclinic phase transition at 11'. D: 4.50 @ 15', mp: 1580'. Sltly sol in H20. Insol in water or dilute acids. SYNS: ACTYBARYTE 0 ARTIFICLALBARITE 0 ARTIFICIAL HEAVY SPAR 0 BAKONTAL 0 BARIDOL 0 BARITE 0 BARITOP 0 BAROSPERSE 0 BAROTRAST 0 BARYTA WHITE 0 BARYTES 0 BAYRITES 0 BLANC FIXE 0 C.I. 77120 0 C.I. PIGMENT WHITE 21 0 CITOBARYUM 0 COLONATRAST 0 ENAMEL WHITE 0 ESOPHOTRAST 0 EWEISS 0 E-Z-PAQUE 0 FINEMEAL 0 LACTOBARYT 0 LIQUIBARINE 0 MACROPAQUE 0 NEOBAR 0 ORATRAST 0 PERMANENT WHITE 0 PRECIPITATED BARIUM SULPHATE 0 RAYBAR 0 REDI-FLOW 0 SOLBAR 0 SULFURIC ACID, BARIUM SALT (1:l) 0 SUPRAMIKE 0 TRAVAD 0 UNIBARYT CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Barium and its compounds are on the Community RightTo-Know List. OSHA PEL: Total Dust: TWA 10 mg/m3; Respirable Fraction: 5 mg/m3 ACGIH TLV: TWA (nuisance particulate) 10 mg/m3 of total dust (when toxic impurities are not present, e.g., quartz <1%) SAFETY PROFILE: Questionable carcinogen with experimental tumorigenic data. Mutation data reported. A relatively insoluble salt used as an opaque medium in radtography. Soluble impurities can lead to toxic reactions. Heating with aluminum can produce an explosion. Incompatible with aluminum and potassium. When heated to decomposition it emits toxic fumes of SO,.
BAP250 CAS: 21109-95-5 HR: 3 BARIUM SULFIDE mfi Bas mw: 169.4 PROP: Cubic, colorless crystals. Moisturesensitive. D: 4.25 @ 15', mp: 1200'.
CONSENSUS REPORTS: Barium and its
compounds are on the Community RightTo-Know List. SAFETY PROFILE: A poison. Flammable by spontaneous chemical reaction, air, moisture, or acid fumes may cause it to ignite. For explosion and disaster hazards, see SULFIDES. To fight fxe, use COz, dry chemical. Reacts violently with phosphorus(V) oxide. Mxtures with lead dioxide, potassium chlorate, or potassium nitrite explode when heated. Incompatible with ChO, Ca(N03)~,Sr(NO3)2, Ca(C103)z, Sr(C103)2, (C103)z. See also BARIUM COMPOUNDS (soluble) and SULFIDES.
BAP750 CAS: 12009-21-1 HR: 2 BARIUM ZIRCONIUM(IV) OXIDE mf: 04Zr4*Ba mw: 566.22 PROP: Light gray-buff powder or white powder. D: 5.52, mp: 2510'. Insol in water and alkalies; sltly sol in acid. IDLH 50 mg/m3 (as Zr). SYNS: BARIUM ZIRCONATE 0 BARIUM ZIRCONIUM OXIDE 0 BARIUM ZIRCONIUM TRIOXIDE 0 ZIRCONATE, BARIUM (1:l) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Barium and its compounds are on the Community RightT o - K ~ o wLst. OSHA PEL: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr) /m3 ACGIH TLV: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3 DFG MAK: 1 mg(Zr)/m3 SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Inhalation produces interstitial pneumonitis. See also ZIRCONIUM COMPOUNDS and BARIUM COMPOUNDS.
BAR250 CAS: 8015-73-4 HR: 2 BASIL OIL PROP: Contains about 55% methyl chavicol and 35% of alcohols calculated as lenatoal and other compounds found in the leaves of 0dmz.m resilizrm L (FCTXAR 11,855,73).A pale-yellow liquid; floral, spicy odor. Sol in
BENADRYL HYDROCHLORIDE
BAU750
129
fured oils and propylene glycol; insol in glycerin.
CONSENSUS REPORTS: Cyanide and its compounds are on the Community Right-
SYNS: BASIL OIL, E U R O P a U TYPE PCC) 0 BASIL OIL, SWEET 0 OCIMUM BASILICUM OIL 0 OIL OF BASIL 0 OILS, BASIL
T o - K ~ o wList.
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A sktn and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
BAT500 HR: 2 BAY OIL PROP: Consists mainly of eugenol and chavicol (55-65%), major portion of balance consists of terpenes (a-pinene, myrcene, and dlpentene), small quantities of citrol, nerol, cineol, and other terpenoids have also been found (FCTXAV 11,855,73).Yellow or brown liquid; aromatic odor, pungent, spicy taste. Sol in alc and glacial acetic acid. SYNS: BAY LEAF OIL 0 BOIS d'lNDE 0 LAUREL LEAF OIL 0 MYRCIA OIL 0 MYRICIA OIL 0 OIL OF BAY 0 OIL OF MYRCIA CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke.
SAFETY PROFILE: Poison by ingestion. An experimental teratogen. When heated to decomposition it emits very toxic fumes of CN-, NO,, PO,, and SO,. See also NITRILES.
BAT850 CAS: 8021-39-4 HR: 3 BEECHWOOD CRESOATE PROP: Yellowish, greasy, liquid with smokey odor and sharp burned taste. Relatively sol in water. SYNS: CRESOATE, WOOD 0 RCRA WASTE NUMBER U051
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. Reported in EPA TSCA
Inventory. SAFETY PROFILE: Confirmed carcinogen. When heated to decomposition it emits acrid smoke and irritating fumes.
BAUOOO CAS: 8012-89-3 HR: 1 BEESWAX PROP: Yellow to brownish-yellow, soft to brittle wax. Mp: 62-65', d: 0.95-0.96. Sol in chloroform, ether, fured oils; sltly sol in alc. SYNS: BEESWAX, WHITE 0 BEESWAX, YELLOW SAFETY PROFILE: A mdd allergen.
Combustible when heated.
BAT750 CAS: 14816-18-3 HR: 3 BAYTHION mf: C I Z H I S N ~ O ~ P S mw: 298.32 PROP: Liquid. D: 1.176' @ 20 mm, fp: 5-6', bp: 102' @ 0.01 mm (decomp). SYNS: n 77488 BAY 5621 BAY 77488 BAYRE 77488 0 BENZOYL CYANIDE-o-(DIETHOXIPHOSPHINOTHI0YL)OXIME 0 0,O-DIAETHYL-0-p CYANBENZYLIDEN-AMINO)-THlONPHOSPHAT (GERMAN) 0 O,O-DIAETHYL-o-(a-CYANO-
BAU750 CAS: 147-24-0 HR: 3 BENADRYL HYDROCHLORIDE mf: C17H21NO*ClH mw: 291.85 PROP: Crystals from EtOH/EtzO. Mp: 161-162'. Sol in Hz0.
SYNS: AMBENYL 0 BAX 0 BENA 0 BENADRYL 0 BENDYLATE 0 BENOCTEN 0 BENZEHIST 0 BENZHYDRAMINE HYDROCHLORIDE 0 2-(BENZHYDRYL0 X V - X,U-DIMETHXETHYL-AMINEHYDROBENZYLIDENAMIS0)-MONOTHIOPHOSPHAT CHLORIDE 0 DABXEN 0 DIFENHYDRAMINE (GERMAN) 0 ~-(((DIETHOXYPHOSPHINOHYDROCHLORIDE 0 DIMETHYLAMINE THI0YL)OXY)IhlINO)BENZENEACETONITRILE0 (DIETHOXY-THIOPHOSPHORYLOXYIMIN0)-PHENYL BENZHYDRYL ESTER HYDROCHLORIDE 0 pDIMETHYLAMINOETHYL BENZHYDRYL ESTER ACETONITRILE 0 0,O-DIETHYL PHOSPHOROHYDROCHLORIDE 0 DIPHENYLHYDRAMINE THIOATE, o-ESTER wth PHENYLGLYOXYLONITRILE HYDROCHLORIDE 0 2-@IPHENYLMETHOXY)-N,NOXIME 0 ENT 27,488 0 4-ETHOXY-7-PHENYL3,5DIOXA-6-AZA-4-PHOSPHAOCT-6-ENE-8-NITRILE-4-DIMETHYL-ETHANAMINEHYDROCHLORIDE 2DIPHENYLRIETHOXY-N,N-DIMETHYLETHYLAMINE SULFIDE 0 PHENYLGLYOXYLONITRILE OXIME-0,OHYDROCHLORIDE 0 DOLESTAN 0 ELDADRYL 0 DIETHYL PHOSPHOROTHIOATE 0 PHOXIME 0 FELBEN 0 FENYLHIST 0 HALBMOND 0 a-HYDRPHOXIN 0 SEBACIL 0 VALEXONE 0 VOLATON
130 BAV575
BENOMYL
OXYDIPHENYLMETHANE- DIMETH THY LA MI NO ETHYL ETHER HYDROCHLORIDE 0 NCIX56075 0 ROHYDRA 0 SK-DIPHENHYDRAMINE0 VALDREKE 0 WEHYDRYL
irritant. When heated to decomposition it emits toxic fumes of NO,. See also CARBAMATES.
CONSENSUS REPORTS: Reported in NTP
Carcinogenesis Studies (feed); Equivocal Evidence: rat NTPTR* NTP-TR-355,89; (feed); No Evidence: mouse NTPTR* NTPTR-355,89. SAFETY PROFILE: Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Human systemic effects by ingestion or skin contact: arrhythmias, ataxia, blood pressure elevation, convulsions, distorted perceptions, eye effects, and hallucinations. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits very toxic fumes of NO, and HC1. See also ESTERS and ETHERS. BAV575 CAS: 17804-35-2 HR: 3 BENOMYL mf: C14H18N403 mw: 290.36 PROP: Very sltly sol in Hz0; sol in CHCL; less sol in other org solvents.
BAV750 CAS: 1302-78-9 HR: 1 BENTONITE PROP: A clay containing appreciable amounts of the clay mineral montmordlonite; light yellow or green, cream, pink, gray to black solid. Insol in water and common org solvs. SYNS: ALBAGEL PREMIUM USP 4444 0 BENTONITE 2073 0 BENTONITE MAGMA 0 HI-JEL 0 IXNITE I.G.B.A. 0 MAGBOND 0 MONTMORILLONITE 0 PANTHER CREEK BENTONITE 0 SOUTHERN BENTONITE 0 TIXOTON 0 VOLCWY 0 VOLCLAY BENTONITE BC 0 WLKINITE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route causing blood clotting. Questionable carcinogen with experimental tumorigenic data.
BAW250 CAS: 205-99-2 HR: 3 BENZ(e)ACEPHENANTHRYLENE mf: CzoH12 mw: 252.32 PROP: Needles from CsH6 or EtOH. Mp: 168'.
SYNS: ARILATE 0 BBC 0 BENLATE 50 0 BENOMYL 50W 0 BKM 0 l - ( B C ~ C A R S ~ ~ O n ) - 2 - B E N Z I M I D - SYNS: 3,4-BENZ(e)ACEPHENANTHRYLENE 0 2,3AZOLECARBAMICACID, METHYL ESTER 0 1BENZFLUORANTHENE 0 3,4-BENZFLUORANTHENE ~UTnCARBAMOYL)-2-BENZlMIDAZOL-METHYL0 BENZO@)FLUORANTHENE 0 BENZO(e)FLUORCARBAhVIAT (GERMAN) 0 l-(N-BUTYLCARBAhfOYL))-2ANTHENE 0 2,3-BENZOFLUORANTHENE 0 3,4(METHOXY-CARBOXhMID0)-BENZIMIDAZOL BENZOFLUOFUNTHENE 0 2,3-BENZOFLUOR(GERMAN) 0 DU PONT 1991 0 FUNDASOL 0 ANTHRENE 0 B@)F FUNGICIDE 1991 0 MBC 0 METHYL-l-(BUTYLCONSENSUS REPORTS: NTP 10th Report CARB~~lOYL)-2-BENZIR.IIDAZOLYLCARB~TE 0 TERSAN 1991 on Carcinogens. IARC Cancer Review:
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: Total Dust: TWA 10 mg/m3; Respirable Fraction: 5 mg/m3 ACGIH TLV: TWA 10 mg/m3; Not Classifiable as a Human Carcinogen; (Proposed: 1 mg/m3; Not Classifiable as a Human Carcinogen) SAFETY PROFILE: Poison by ingestion. Mildly toxic by inhalation. Experimental teratogenic and reproductive effects. Human mutation data reported. A human skin
Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 32,147,83; IMEMDT 3,69,73. EPA Genetic Toxicology Program. ACGIH TLV: Suspected Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
BENZAL GLYCERYL ACETAL
BAY300 CAS: 98-87-3 HR: 3 BENZAL CHLORIDE DOT: UN 1886 mf: C7H& mw: 161.03 PROP: Very refractive liquid. Mp: -16', bp: 214', d: 1.29. SYNS: BENZYL DICHLORIDE 0 BENZYLENE CHLORIDE 0 BENZYLIDENE CHLORIDE 0 BENZYLIDENE CHLORIDE (DOT) 0 CHLOROBENZAL 0 CHLORURE de BENZYLIDENE 0 (DICHLOROMETHYL)BENZENE 0 a-a-DICHLOROTOLUENE 0 RCRA WASTE NUMBER UO17 0 TOLUENE, a-aDICHLORO-
CONSENSUS REPORTS: IARC Cancer Review: Human Inadequate Evidence IMEMDT 29,65,82; Animal Limited Evidence IMEMDT 29,65,82. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. EPA Extremely Hazardous Substances List. Community Right-To-Know List. DFG MAK: Confirmed Human Carcinogen DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Poison by inhalation. Moderately toxic by ingestion. A strong irritant and lachrymator. Causes central nervous system depression. Mutation data reported. When heated to decomposition it emits toxic fumes of C1-. See also CHLORINATED HYDROCARBONS, AROMATIC.
BAY500 CAS: 100-52-7 HR: 3 BENZALDEHYDE mfi C7H60 mw: 106.13 PROP: Colorless liquid; burning taste with bitter almond odor. Mp: -26', bp: 179', fp: -56.9' (to -55O), flash p: 148'F, d: 1.041, autoign temp: 377'F, vap press: 1 mm @ 26.2', vap d: 3.65, refr index: 1.544. Sltly sol in water; misc in alc, ether, oils. SYNS: ALMOND ARTIFICIAL ESSENTIAL OIL 0 ARTIFICIAL ALMOND OIL 0 BENZENECARBALDEHYDE 0 BENZENECARBONAL 0 BENZOIC ALDEHYDE 0 FEMA No. 2127 0 NCI-136133
CONSENSUS REPORTS: NTP
Carcinogenesis Stucbes (gavage); Some Evidence mouse; NTP-TR-378,90; No
BBAOOO
131
Evidence: rat NTP-TR-378,90. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Moderately toxic by subcutaneous route. An allergen. Acts as a feeble local anesthetic. Local contact may cause contact dermatitis. Causes central nervous system depression in small doses and convulsions in larger doses. A skin irritant. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Combustible liquid. To fight fire, use water (may be used as a blanket), alcohol, foam, dry chemical. A strong reducing agent. Reacts violently with peroxyformic acid and other oxidizers. See also ALDEHYDES. BAY750 CAS: 633-03-4 HR: 3 BENZALDEHYDEGREEN mf: C27H33N2*H04S mw: 482.69 PROP: Bright green crystals or powder. Mp: 210' (decomp). Sol in H20, EtOH, and CHCl3. SYNS: ADC BRILLIANT GREEN CRYSTALS 0 AIZEN DIAMOND GREEN GH 0 ANILINE GREEN 0 ASTRA DIAMOND GREEN GX 0 AVON GREEN A-4379 0 BASIC BRIGHT GREEN 0 BRILLIANT GREEN SULFATE 0 CALCOZINE BRILLIANT GREEN G 0 C.I. 42040 0 C.I. BASIC GREEN 1, SULFATE (1:l) 0 DEORLENE GREEN JJO 0 DIAMOND GREEN G 0 EMERALD GREEN 0 ETHYL GREEN 0 FAST GREEN JJO 0 HIDACO BRILLIANT GREEN 0 MALACHITE GREEN G 0 MITSUI BRILLIANT GREEN G 0 TERTROPHENE BRILLIANT GREEN G 0 TOKYO ANILINE BRILLIANT GREEN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion, intraperitoneal, and intravenous routes. A rmld human skin irritant. Mutation data reported. See also ALDEHYDES and SULFATES. When heated to decomposition it emits very toxic fumes of NO,, NH3, and SO,.
BBAOOO CAS: 1708-39-0 BENZALGLYCERYLACETAL mf: C10H1203 mw: 180.22
HR: 2
132 BBC250 BENZ(a)ANTHRACENE PROP: Colorless to pale-yellow liquid; mild
almond odor. D: 1.183-1.1 93, refr index: 1.535-1.541, flash p: 165'F. SYNS: BENZALDEHYDE GLYCERYL ACETAL (FCC) 0
HYDROXYPHENYL KETONE 0 2-ETHYL-3-@HYDROXYBENZ0YL)BENZOFURAN 0 2-ETHYL-4HYDROXY-3-BENZOYLBEKZOFURAN 0 ETHYL2 (HYDROXY-4BENZ0YL)-3BENZOFURANNE 0 FRAGMX
BENZE'LIDENEGLYCEROL 0 BUTYL PHENYL ACETATE 0 F E U No. 2209 0 2-PHENYI-m-DIOXhN-5OL
TSCA Inventory.
SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Mildly toxic by skin contact. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
BBC250 CAS: 56-55-3 HR: 3 BENZ(a)ANTHRACENE mf: C18H12 mw: 228.30 PROP: Colorless leaflets or plates from EtOH/AcOH. Mp: 160°, bp: 400'. SYNS: BA 0 BENZANTHRACENE 0 1,2-
CONSENSUS REPORTS: Reported in EPA DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. A flammable liquid. When heated to decomposition it emits acrid and irritating smoke and fumes. See also KETONES.
BBJ750 CAS: 59-97-2 HR: 3 BENZAZOLINE HYDROCHLORIDE mf: CloHlzNz*ClH mw: 196.70 PROP: Solid. Mp: 171-172'. SYNS: ARTERODY 0 BENZYLIMIDAZOLINE
BENZANTHRACENE 0 1,2-BENZ(a)ANTHRACENE0 1,2-BENZANTHRAZEN(GERNAN) 0 BENZANTHRENE I 3 1,2-BENZANTHRENE0 BENZOANTHRACENE 0 BENZO(a)ANTHRACENE0 1,2-BENZOANTHRACENE 0 BENZO(a)PHENANTHRENE 0 BENZO@)PHENANTHRENE 0 2,3-BENZOPHENANTHRENE 0 2,3BENZPHENANTHRENE 0 NAPHTHANTHRACENE 0 R C M WASTE NUMBER U018 0 TETRAPHENE
HYDROCHLORIDE 0 2-BENZYL-2-IMIDAZOLINE MONOHYDROCHLORIDE 0 IMIDALINE HYDROCHLORIDE 0 PRISCOL 0 PRISCOLINE HYDROCHLORIDE 0 TOLAVAD 0 TOLAZOLINE CHLORIDE 0 TOLAZOLINE HYDROCHLORIDE 0 TOLPAL
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
TSCA Inventory.
Group 2A IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 32,135,83; IMEMDT 3,45,73. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. ACGIH TLV: Suspected Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data by skin contact and other routes. Poison by intravenous route. Human mutation data reported. It is found in oils, waxes, smoke, food, drugs. When heated to decomposition it emits acrid smoke and irritating fumes. BBJ500 CAS: 1477-19-6 BENZARONE mf: C17H1403 mw: 266.31 PROP: Solid. Mp: 126-127'.
HR: 3
SYNS: BENZOFURAN, (2-ETHYI-3-(4'-HYDROXYBENZOYL)) 0 2-ETHYL-3-BENZOFURAiiYLp-
CONSENSUS REPORTS: Reported in EPA SAFETY PROFILE: Poison by ingestion, intravenous, and intraperitoneal routes. Human systemic effects by intravenous route: change in heart rate, sweating, ulceration or bleeding from duodeum, ulceration or bleeding from small intestine, unspecified vascular effects. When heated to decomposition it emits very toxic fumes of NO, and HC1.
BBKOOO CAS: 300-62-9 HR: 3 BENZEDRINE mfi CgH13N mw: 135.23 PROP: Liquid or oil. Bp: 203', flash p: <212'F (OC), d: 0.931, vap d: 4.65. Sltly sol in H20. SYNS: ACTEDRON 0 ADIPAN 0 ALLODENE 0 dlAMPHEThVlNE 0 ANOREXIDE 0 (?)-BENZEDRINE 0 dl-BENZEDRINE 0 DEOXYNOREPHEDRINE 0 (&)DESOXYNOREPHEDRINE 0 racemic-DESOXYNOREPHEDRINE 0 ELASTONON ISOAMYCIN 0 ISOMYN 0 MECODRIN 0 a-METHYLBENZENEETHANEAMINE
BENZENAMINE HYDROCHLORIDE 0 dl-a-METHYLPHENETHYINE 0 (+)-aM E T H Y L P H E N E T H Y I N E 0 NOREPHEDRANE 0 NOVYDRINE 0 ORTEDRINE 0 PHENEDRINE 0 dl-lPHENYL-2-AMINOPROPANE0 PROFAMINA 0 PROPISAMINE 0 PSYCHEDRINE 0 RAPHETAiMINE 0 SIiMPATEDRIN 0 STnlPAMINE 0 SYMPATEDRINE 0 WECI(AM1NE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. SAFETY PROFILE: A deadly human poison by an unspecified route. An experimental poison by ingestion, subcutaneous, intraperitoneal, and intravenous routes. Experimental reproductive effects. Mutation data reported. A central nervous system stimulant. Overdoses cause hyperactivity, restlessness, insomnia, rapid pulse, rise in blood pressure, dilated pupils, dryness of the throat. Combustible when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of NO,. To fight fxe, use COz, dry chemical, alcohol foam, water mist, fog. See other benzedrine entries.
BBK500 CAS: 51-63-8 HR: 3 d-BENZEDRINE SULFATE mE Ci8H26N2*H204S mw: 368.54 PROP: Plates. SYNS: ACEDRON 0 ADJUDETS 0 ADRIXINE 0 AFATIN 0 ALBEMAP 0 AMDEX 0 d-AMFETASUL 0 AMITRENE 0 AMPHAETEX 0 AMPHEDRINE 0 AMPHEREX 0 (+)-hVPHETAMNE SULFATE 0 dAMPHETAMINE SULFATE 0 AMSUSTAIN 0 APETAIN 0 ARDEX 0 BETAFEDRINA 0 BETAFEDRIVE 0 dBETAPHEDRINE 0 CARRTIME 0 CRADEX 0 DADEX 0 DADOX d-CITIL1?*fINE0 DELLIPSOIDS 0 DEPHADREN 0 DESOXYN 0 DEXAIME 0 DEXALINE 0 DEXALVE 0 DEXAMED 0 DEXAMINE 0 DEXAMPHAMINE 0 DEXAMPHETAMINE 0 DEXAMPHETAMINE SULFATE 0 DEXAhrYL 0 DEXEDRINA DEXEDRINE SULFATE DEXIES DEXTROAMPHETAiiINE SULFATE 0 DEXTRO-aMETHYLPHENETHYLAMINE SULFATE 0 DEXTRO-IPHENYL-2-AMINOPROPANESULFATE 0 DEXTRO-PPHENYLISOPROPYLAMINE SULFATE 0 FASTBALLS 0 HEARTS 0 (S)-a-METHYL-BENZENEETHANAMINE SULFATE (2:l) 0 d - a - M E T H Y L P H E N E T H Y I N E SULFATE 0 ORANGES 0 PELLCAFS PELLCAP 0 PELLCAPS 0 PERKE 0 PHENOPROMIN 0 d-lPHENYL-2-AMINOPROPANESULFATE 0 d-P-
BBLOOO
133
PHENYLISOPROPYLhl.IINESULFATE 0 PHETADEX 0 PSYCHODRINE 0 REVIDEX 0 SIiMPAMINA-D 0 SYMPAMINA-D 0 TEMPODEX 0 TCPHEThMINE 0 TYDEX 0 ZAMINE
SAFETY PROFILE: Poison by ingestion, intraperitoneal, subcutaneous, and intravenous routes. A human teratogen that causes developmental abnormalities of the central nervous system. Experimental reproductive effects including other teratogenic effects. A habit-forming stimulant. When heated to decomposition it emits very toxic fumes of SO, and NO,. See also other benzidrine compounds and SULFATES.
BBLOOO CAS: 142-04-1 HR: 3 BENZENAMINE HYDROCHLORIDE DOT: UN 1548 mf: C6H,N*ClH mw: 129.60 PROP: Crystals. Vap d: 4.46, d: 1.22, mp: 1 9 8 O , bp: 245O, flash p: 380’F (OC). SYNS: ANILINE CHLORIDE 0 ANILINE HYDROCHLORIDE (DOT) 0 “ANILINE SALT” 0 ANILINIUM CHLORIDE 0 CHLORHYDRATE d’ANILINE (FRENCH) 0 CHLORID ANILINU (CZECH) 0 NCIC03736 0 PHENYLAMINE HYDROCHLORIDE 0 SUL ANILINOVA (CZECH) 0 USAF EK-442
CONSENSUS REPORTS: IARC Cancer Review: Animal Limited Evidence IMEMDT 27,39,82. NCI Carcinogenesis Bioassay Completed; Results Positive: rat NCITR* NCI-CG-TR-130,78; Results Negative: mouse NCITR* NCI-CG-TR130,78. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental teratogenic effects. Human mutation data reported. A s h n and eye irritant. Combustible when exposed to heat or flame. When heated to decomposition or on contact with acid or acid fumes, it emits highly toxic fumes of aniline and chlorine compounds. Reacts explosively with aniline
134
BBL250 BENZENE
at 24OoC/7.6 bar. Can react vigorously with oxidizing materials. To fight fire, use water, C02, water mist or spray, dry chemical. See also ANILINE.
BBL250 CAS: 71-43-2 HR: 3 BENZENE DOT: UN 1114 mf: C6H6 MW: 78.12 PROP: Clear, colorless liquid. Mp: 5.51', bp: 80.093-80.094", flash p: 12'F (CC), d: 0.8794 @ 20°, autoign temp: 1044'F, lel: 1.4%, uel: 8.O%, vap press: 100 mm @ 26.1', vap d: 2.77, ULC: 95-100. Very sltly sol in H20; misc in most org solvs. IDLH 500 ppm. SYNS: (6)ANNULENE 0 BENZEEN (DUTCH) 0 BENZEN (POLISH) 0 BENZIN (OBS.) 0 BENZINE (OBS.) 0 BENZOL (DOT 0 BENZOLE 0 BENZOLENE 0 BENZOLO (ITALIAN) 0 BICARBURET of HYDROGEN 0 CARBON OIL 0 COAL NAPHTHA 0 CYCLOHEXATRIENE 0 FENZEN (CZECH) 0 MINERAL NAPHTHA 0 MOTOR BENZOL 0 NCI-C55276 0 NITRATION BENZENE 0 PHENE 0 PHENYL HYDRIDE 0 PYROBENZOL 0 PYROBENZOLE 0 RCRA WASTE NUMBER UO19
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 1 IMEMDT 7,120,87; Human Limited Evidence IMEMDT 7,203,74; Animal Inadequate Evidence IMEMDT 7,203,74; IARC Cancer Review: Animal Limited Evidence IMEMDT 29,93,82; Human Sufficient Evidence IMEMDT 29,93,82. NTP Carcinogenesis Studies (gavage); Clear Evidence: mouse, rat NTPTR* NTP-TR-289,86. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. On Community Rtght-ToKnow Llst. OSHA PEL: TWA 1 ppm; STEL 5 ppm; Pk 5 ppm/l5M/8H; Cancer Hazard ACGIH TLV: TWA 0.5 ppm; STEL 2.5 ppm (skin); Confirmed Human Carcinogen; BEI: 25 p/g creatinine of Sphenylmercapturic acid in urine at end of shift DFG MAK: DFG TRK: Human Carcinogen NIOSH REL: TWA 0.32 mg/m3; CL 3.2 mg/m3/ 15M
DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Confirmed human carcinogen producing myeloid leukemia, Hodgkin's dsease, and lymphomas by inhalation. Experimental carcinogenic, neoplastigenic, and tumorigenic data. A human poison by inhalation. An experimental poison by s h n contact, intraperitoneal, intravenous, and possibly other routes. Moderately toxic by ingestion and subcutaneous routes. A severe eye and moderate sktn irritant. Human systemic effects by inhalation and ingestion: blood changes, increased body temperature. Experimental teratogenic and reproductive effects. Human mutation data reported. A narcotic. In industry, inhalation is the primary route of chronic benzene poisoning. Poisoning by skin contact has been reported. Recent (1987) research indicates that effects are seen at less than 1 ppm. Exposures needed to be reduced to 0.1 ppm before no toxic effects were observed. Elimination is chiefly through the lungs. A common air contaminant. A dangerous fire hazard when exposed to heat or flame. Explodes on contact with diborane, bromine pentafluoride, permanganic acid, peroxornonosulfuric acid, and peroxodisulfuric acid. Forms sensitive, explosive mixtures with iodine pentafluoride, silver perchlorate, nitryl perchlorate, nitric acid, liquid oxygen, ozone, and arsenic pentafluoride + potassium methoxide (explodes above 30'C). Ignites on contact with sodium peroxide + water, dioxygenyl tetrafluoroborate, iodine heptafluoride, and dioxygen difluoride. Vigorous or incandescent reaction with hydrogen + Raney nickel (above 21OoC), uranium hexafluoride, and bromine trifluoride. Can react vigorously with oxidzing materials, such as Cla, Cr03,02, NC104,03, perchlorates, (ACl3 + FC104), (H2S04 + permanganates), KzOZ,(AGIO4 + acetic acid), Na202. Moderate explosion hazard
BENZENEACETALDEHYDE
when exposed to heat or flame. Use with adequate venulation. To fight fire, use foam, CO2, dry chemical. Poisoning occurs most commonly via inhalation of the vapor, although benzene can penetrate the skin and cause poisoning. Locally, benzene has a comparatively strong irritating effect, producing erythema and burning, and, in more severe cases, edema and even blistering. Exposure to high concentrations of the vapor (3000 ppm or higher) may result from failure of equipment or spillage. Such exposure, while rare in industry, may cause acute poisoning, characterized by the narcotic action of benzene on the central nervous system. The anesthetic action of benzene is sirmlar to that of other anesthetic gases, consisting of a preluninary stage of excitation followed by depression and, if exposure is continued, death through respiratory failure. The chronic, rather than the acute, form of benzene poisoning is important in industry. It is a recognized leukemogen. There is no specific blood picture occurring in cases of chronic benzol poisoning. The bone marrow may be hypoplastic, normal, or hyperplastic, the changes reflected in the peripheral blood. Anemia, leucopenia, macrocytosis, reticulocytosis, thrombocytopenia, h g h color index, and prolonged bleeding time may be present. Cases of myeloid leukemia have been reported. For the worker, repeated blood examinations are necessary, inclulng hemoglobin determinations, white and red cell counts, and dlfferential smears. Where a worker shows a progressive drop in either red or white cells, or where the white count remains below <5000/mm3 or the red count remains below 4.0 d o n / m m 3 , on two successive monthly examinations, the worker should be immediately removed from benzene exposure. Elimination is chefly through the lungs, when fresh air is breathed. The portion that is absorbed is oxidized, and the oxidation products are combined with sulfuric and glycuronic acids and eliminated in the urine. This may be
BBLSOO
135
used as a lagnostic sign. Benzene has a definite cumulative action, and exposure to a relatively h g h concentration is not serious from the point of view of causing damage to the blood-forming system, provided the exposure is not repeated. In acute poisoning, the worker becomes confused and dizzy, complains of tightening of the leg muscles and of pressure over the forehead, then passes into a stage of excitement. If allowed to remain exposed, he quickly becomes stupefied and lapses into coma. In nonfatal cases, recovery is usually complete with no permanent disabhty. In chronic poisoning the onset is slow, with the symptoms vague; fatigue, headache, dizziness, nausea and loss of appetite, loss of weight, and weakness are common complaints in early cases. Later, pallor, nosebleeds, bleeding gums, menorrhagia, petechiae, and purpura may develop. There is great inlvidual variation in the signs and symptoms of chronic benzene poisoning. BBL500 CAS: 122-78-1 HR: 2 BENZENEACETALDEHYDE mf: CgHsO mw: 120.16 PROP: Oily, colorless liquid that polymerizes and grows more viscous on standing; odor similar to lilac and hyacinth. Has been crystallized, mp: 33-34', d: (25/25) 1.023-1.030, refr index: 1.525-1.545, bp: (10) 7 8 O , n: (20/D) 1.524-1.528, flash p: 154'F. Sltly sol in water; sol in alc, ether, and propylene glycol. One part is sol in two parts of 80% alc forming a clear solution. SYNS: FEMA No. 2874 0 HYACINTHIN 0 I'M 0 PHENYLACETALDEHYDE (FCC) 0 PHENYLACETIC ALDEHYDE 0 PHENYLETHANAL 0 cL-TOLUALDEHYDE 0 a-TOLUIC L D E H Y D E
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Human skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.
136 BBL750 BENZENEARSONIC ACID
BBL750 CAS: 98-05-5 HR: 3 BENZENEARSONIC ACID mf: C6H7As03 mw: 202.05 PROP: Colorless crystals from water. D: 1.760, mp: 160' decomp. Sol in water. SYNS: PHENYL ARSENIC ACID 0 PHENYLARSONIC ACID
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. Arsenic and its compounds are on the Community fightTo-Know List. OSHA PEL: TWA 0.5 mg/(As)m3 ACGIH TLV: BEI: 35 (As)/L inorganic arsenic and methylated metabolites in urine SAFETY PROFILE: A deadly poison by ingestion and intravenous routes. See also ARSENIC COMPOUNDS. When heated to decomposition it emits toxic fumes of As.
BBPOOO CAS: 123-61-5 HR: 3 BENZENE-l,3-DIISOCYANATE mf: CsH4N202 mw: 160.14 PROP: Crystals. Mp: 51-55', bp: 102-104O @ 8 mm. SYNS: BENZENE-1,3-DIISOCYAiVATE 0 BENZENE, 1,3-DIISOCYANATO- 0 1,3-DIISOCYANATOBENZENE NACCONATE 400 0 m-PHENYLENE DIISOCYANATE 0 m-PHENYLENE ISOCYANATE 0
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community fightTo-Know List. NIOSH REL: TWA (Diisocyanates) 0.005 ppm; CL 0.02 ppm/lOM SAFETY PROFILE: A sensitizer at very low concentrations. Deadly poison by intravenous route. When heated to decomposition it emits toxic fumes of NO, and CN-. See also ESTERS.
BBP250 CAS: 623-26-7 HR: 2 p-BENZENEDINITRILE mf: CsH4N2 mw: 128.14 PROP: Crystals. Mp: 222O, vap d: 4.42. SYNS: 4-CYrtUOBENZONITRILE 0 p-DICYANOBENZENE 0 1,4-DICYANOBENZENE 0 NITRIL KYSELINY TEREFTALOVE (CZECH) 0 p-PDN 0 pPHTHALODINITRILE 0 TEREFTALODINITRIL (CZECH) 0 TEREPHTHALONITRILE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Cyanide and its compounds are on the Community RightTo-Know List. SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. An eye irritant. When heated to decomposition it emits toxic fumes of CN- and NO,. See also NITRILES. BBP750 CAS: 608-73-1 HR: 3 BENZENE HEXACHLORIDE mf: C6H6C16 mw: 290.82 PROP: Technical grade contains 68.7% aBHC,6.5% p-BHC,and 13.5% yBHC (JPFCD2 14,305,79). White, crystalline powder. Mp: 113O, vap press: 0.0317 mm @ 20'. SYNS: BHC (USDA) 0 COMPOUND-666 0 DBH 0 ENT 8,601 0 GAMMEXANE 0 HCCH 0 HEXA 0 HEXACHLOROHEXACHLORANOHEXACHLOROCYCLOHEXANE 0 1,2,3,4,5,6-HEXACHLOROCYCLOHEXANE 0 HEXYLAN 0 JACUTIN 0 LATKA 666
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Animal Sufficient Evidence IMEMDT 5,47,74. ACGIH TLV: TWA 0.5 mg/m3 (skin) SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data by ingestion and skin contact. Poison by ingestion, s h n contact, and subcutaneous routes. Human systemic effects by inhalation: headache, nausea or vomiting, and fever. Implicated in aplastic anemia. Experimental reproductive effects. Mutation data reported. Lindane is more toxic than DDT or dieldrin. Potentially violent reaction with dlmethylformamide + iron. When heated to decomposition it emits highly toxic fumes of phosgene, HC1, and C1-. See other benzenehexachloride entries. A toxic organochlorine that is persistent in the environment and accumulates in mammalian tissue. For cattle, the oral LD50 <= 100 mg/kg. The various isomers have dlfferent actions; the y (lindane) and a
BENZENE HEXACHLORIDE-).isomer
isomers are central nervous system stimulants, the principal symptom being convulsions. The p and A isomers are central nervous system depressants. The use of thermal vaporizers with lindane has caused acute poisoning by inhalation. The dangerous acute dose of the technical mixture has been estimated at about 30 g and the dangerous dose of lindane at about 7 to 15 g. However, as already mentioned, a single dose of 45 mg (or approximately 0.65 mg/kg) of lindane caused convulsions. Lindane shows a marked dfference in toxicity to dfferent species. Its toxic effect on laboratory animals compares favorably with that of DDT, but for several domestic animals, notably calves, h d a n e is more toxic than DDT or Qeldrin. On a chronic systemic basis the a, p and y isomers are experimental carcinogens. Has been implicated in aplastic anemia. Dermatitis and perhaps other manifestations based on sensitivity represent a sort of chronic, though probably not systemic intoxication, which has been observed in humans. The signs and symptoms of confirmed acute poisoning in humans have paralleled those in experimental animals. These signs and symptoms are: excitation, hyperirritability, loss of equhbrium, clonictonic convulsions, and later depression. There is some evidence that the pulmonary edema and vascular collapse may be of neurogenic origm also. The symptoms in animals systemically poisoned by the yisomer alone are essentially similar to those caused by mixtures, although the onset may be earlier. Workers acutely exposed to high air concentrations of lindane and its decomposition products show headache, nausea, and irritation of eyes, nose, and throat. In rare instances, urticaria has followed exposure to lindane vapor. Unlike the signs and symptoms already mentioned, this allergic manifestation occurs only in
BBQSOO 137
susceptible individuals, and usually only after a period of sensitization. BBQOOO CAS: 319-84-6 HR: 3 BENZENE HEXACHLORIDE-a-isomer mf: C6H&16 mW: 290.82 PROP: Solid. Mp: 158'. SYNS: a-BENZEKEHEXACHLORIDE 0 a-BHC c1 EXT
9,232 0 a-HCH 0 a-HEXACHLORANE 0 HEXACHLORCYCLOHEXAN ( G E k W ) 0 a-HEXACHLOROCYCLOHEXANE 0 a-l,2,3,4,5,6-HEXACHLOROCYCLOHEXANE W K ) 0 ~-CX,~-~,~-P,~-~,~-P,~-P-HEXA CHLOROCYCLOHEXANED a-LINDANE
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Animal Sufficient Evidence IMEMDT 20,195,79; IMEMDT 5,47,74. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DFG MAK: 0.5 mg/m3 SAFETY PROFILE: ConfEmed carcinogen with experimental carcinogenic, tumorigenic, and neoplastigenic data. Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of C1-. See also BENZENE HEXACHLORIDE and other benzenehexachloride entries. BBQSOO CAS: 58-89-9 HR: 3 BENZENE HEXACHLORIDE-yisomer mf: C6H6C16 mW: 290.82 PROP: Solid. Mp: 112.5'. SYNS: AALINDAN 0 AFICIDE 0 AGRISOL G-20 0 AGROCIDE 0 AGRONEXIT 0 AMEISENATOD 0 AMEISENMITTEL MERCK 0 APARSIN 0 APHTIRIA 0 APLIDAL 0 ARBITEX 0 BBH 0 BEN-HEX 0 BENTOX 10 0 y-BENZENE HEXACHLORIDE 0 BEXOL 0 BHC 0 y-BHC 0 CEJANEX 0 CHLORESENE 0 CODECHIKE 0 DBH 0 DETMOLEXTRAKT 0 DETOX 25 0 DEVORAN 0 DOL GRANULE 0 DRILL TOX-SPEZIALAGLUKON 0 ENT 7,796 0 ENTOMOXAN 0 EXAGAMA 0 FORLIN 0 GALLOGAMA 0 GAMACID 0 GAMAPHEX 0 GfMENE 0 GAMISO 0 GAMMA-COL 0 G A W H E X A 0 GAMMAHEXATiSE U G A i i L I N U GAMMOPAZ U HCCH 0 HCH 0 11-HCH 0 HECLOTOX 0 HEXACHLORAN 0 y-HEXACHLORAN 0 y-HEXACHLORANE 0 y-HEXACHLOROBENZENE 0 l-a,2-a,3-P,4-a,5-a,6-pHEXACHLOROCYCLOHEXANE0 y-HEXACHLOROCYCLOHEXANE (;MAK) 0 1,2,3,4,5,6-HEXACHLOROCYCLOHEXANE, "(-ISOMER 0 HEXATOX 0 HEXICIDE
138 BBQ750 BENZENEHEXACHLORIDE (mixed isomers) 0 HGI 0 INEXIT 0 ISOTOX 0 JACUTIN 0 KOKOTINE 0 KWELL 0 LENDINE 0 LENTOX 0 LIDENAL 0 LINDAGRAIN 0 LINDANE (ACGIH, DOT, USDA) 0 LINTOX 0 MILBOL 49 0 SISZYCOL 0 NCI-COO204 0 NEO-SCABICIDOL 0 N E X T 0 NOVIGAM 0 OVADZIAK 0 PEDRACZAK 0 QUELLADA 0 RCRA WASTE NUMBER U129 0 SANG gamma 0 STREUSEX 0 TAP 85 0 VITON
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Animal Sufficient Evidence IMEMDT 5,47,74; IMEMDT 20,195,79. NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR" NCI-CGTR-14,77. EPA Extremely Hazardous Substances List. EPA Genetic Toxicology Program. Community Rtght-To-Know List. Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.5 mg/m3 (skin) ACGIH TLV: TWA 0.5 mg/m3 (skin) DFG MAK: 0.1 mg/m3; Not Classifiable as a Human Carcinoge SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. A human systemic poison by ingestion. Also a poison by ingestion, s h n contact, intraperitoneal, intravenous, and intramuscular routes. Human systemic effects by ingestion: convulsions, dyspnea, and cyanosis. Experimental teratogenic and reproductive effects. Mutation data reported. See also BENZENE HEXACHLORIDE and other benzene hexachloride entries. When heated to decomposition it emits toxic fumes of C1-, HC1, and phosgene.
BBQ750 HR: 3 BENZENEHEXACHLORIDE (mixed isomers) mf: C6H6C16 mW: 290.82 PROP: Technical BHC contains about 64% a, 10% p, 13% "I,9% A, and 1% E isomers of 1,2,3,4,5,6-hexachlorocyclohexane(IARC"" 5,47,74). SYNS: BENZAHEX 0 BENZEX 0 DOL 0 DOLMIX 0 FBHC 0 FHCH 0 1,2,3,4,5,6-HEXACHLOROCYCLOHEXAXE (mixture of isomers) 0 HEXYCLAN 0 KOTOL 0 SOPROCIDE 0 TECHNICAL BHC 0 TECHNICAL HCH
CONSENSUS REPORTS: IARC Cancer
Review: Animal Sufficient Evidence IMEMDT 5,47,74; IMEMDT 20,195,79. SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic and neoplastigenic data. Poison by inhalation and ingestion. Human systemic effects by an unspecified route: convulsions. Potentially dangerous reaction with DMF in presence of Fe, also CCL. When heated to decomposition it emits hghly toxic fumes of C1-, HC1, and phosgene. See also BENZENE HEXACHLORIDE and other benzenehexachloride entries.
BBROOO CAS: 319-85-7 HR: 3 trans-a-BENZENEHEXACHLORIDE mf: C6H6C16 mW: 290.82 PROP: Solid. Mp: 297'. SYNS: p-BENZENEHEXACHLORIDE p-BHC ENT 9,233 p-HCH p-HEXACHLOROBENZENE 0 pHEXACHLOROCYCLOHEXANE
l-a,2-p,3-a,4-P,5-a,6-
p-HEXACHLOROCYCLOHEXE
0 p-1,2,3,4,5,6-
H E X A C H L O R O C Y C L O H E E (MhK) 0 p-ISOMER 0 p-LINDANE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Animal Sufficient Evidence IMEMDT 5,47,74; Animal Limited Evidence IMEMDT 20,195,79. Reported in EPA TSCA Inventory. DFG MAK: 0.5 mg/m3 SAFETY PROFILE: Confirmed carcinogen with experimental neoplastigenic data. Mildly toxic by ingestion. When heated to decomposition it emits very toxic fumes of C1-, HC1, and phosgene. See also BENZENE HEXACHLORIDE and other benzenehexachloride entries.
BBS250 CAS: 98-11-3 HR: 3 BENZENESULFONICACID mf: C & j 0 3 S mW: 158.18 PROP: Deliquescent plates or tablets. Mp:
43-44O. SYN: PHENYLSULFONIC ACID CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
BENZHYDRAZIDE SAFETY PROFILE: Poison by ingestion,
sbn contact, and probably inhalation. A severe skin and eye irritant. See also SULFATES and SULFONATES. BBS300 CAS: 80-17-1 HR: 3 BENZENESULFONIC HYDRAZIDE DOT: UN 2970 mf: C6HaNz02S mw: 172.22 SYNS: BENZENESULFOHYDRAZIDE0 BENZENESULFONIC ACID, HYDRAZIDE 0 BENZENESULFONOHYDRAZIDE 0 BENZENE-SULFONYL HYDRAZIDE 0 BENZENESULFONYLHYDRAZINE 0 BENZENE SULPHONOHYDRAZIDE 0 CELOGEN BSH 0 ChKhZ 9 0 GENITRON BSH 0 HYDRAZIDE BSG 0 SITROPORE OBSH 0 PHENYLSULFOHYDRAZIDE 0 PHENYLSULFONYLHYDRAZIDE 0 PHENYLSULFONYLHYDRAZINE 0 POROFOR BSH 0 POROFOR-BSHPULVER 0 POROFOR ChKhZ 9
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 4.1; Label:
Flammable Solid SAFETY PROFILE: Poison by ingestion. A
flammable solid. When heated to decomposition it emits toxic vapors of NO, and SO,. BBS750 CAS: 98-09-9 HR: 3 BENZENESULFONYL CHLORIDE DOT: UN 2225 mf: C&,C102S mw: 176.62 PROP: Liquid. D: 1.384 (@, 15'/15', mp: 24.5', bp: 251-252'. SYNS: BENZENE SULFONCHLORIDE 0 BEXZENESULFONIC (ACID) CHLORIDE 0 BENZENE SULPHONYL CHLORIDE (DOT) 0 BENZENO-SULFOCHLOREK (POLISH) 0 BENZENOSULPHOCHLORIDE BSC-REFINE D 0 PHENYL-SULFONYL CHLORIDE 0 RCRA WASTE NUb53ER U020
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by
intraperitoneal route. A dangerous storage hazard. It may explode in a sealed bottle. Explosive reaction with &methyl sulfoxide. Reacts vigorously with methyl formamide. When heated to decomposition it emits
BBV250
139
toxic fumes of C1- and SO,. See also SULFONATES. BBT250 CAS: 368-43-4 HR: 3 BENZENESULPHONYL FLUORIDE mfi C6HsF02S mw: 160.17 PROP: Clear liquid. Bp: 209', fp: -5', flash p: 196'F, d: 1.329, vap press: 8 mm (@, 80', vap d: 5.52. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: A poison by intraperitoneal route. Slightly irritating to sbn. Flammable when exposed to heat or flame. It can react vigorously with oxihzing materials. To fight fire, use water, foam, COz, water spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of F- and SO,. See also FLUORIDES and SULFATES. BBU250 CAS: 533-73-3 HR: 3 1,2,4-BENZENETRIOL mf: C6HbO3 mw: 126.12 PROP: Plates from Et2O. Mp: 140.5' (subl). Sol in water. SYNS: HYDROXYHYDROQUINONE 0 HYDROXYQUINOL OXYHYDROCHINOK (GERhtAN) 0 OXYHYDROQUINONE 0 l,Z,CTRIHYDROXYEiENZENE
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by subcutaneous and intraperitoneal routes. Human mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
BBV250 CAS: 613-94-5 HR: 3 BENZHYDRAZIDE mf: C7HsN20 mw: 136.17 PROP: Crystals from water. Mp: 112.5'. Sol in water, acids, EtOH, C6H6, and Me2CO. SYNS: BENZOHYDRAZIDE 0 BENZOHYDRAZINE BENZOIC HYDIWZIDE 0 BENZOYL HYDRAZIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous route. Questionable
140
BBVSOO
BENZHYDRYL
carcinogen with experimental carcinogenic and neoplastigenic data. Violent reaction with benzeneseleninic acid. When heated to decomposition it emits toxic fumes of NO,.
BBVSOO CAS: 58-73-1 HR: 3 BENZHYDRYL mf: C17HzlNO mw: 255.39 PROP: Oil. Bp: 163-167' @I 3 mm. SYNS: ALERYL 0 ALLEDRYL 0 ALLERGAN B 0 ALLERGEVAL 0 XLLERGICAL 0 W E R G I N 0 ALLERGINA 0 ALLERGIVAL 0 AMIDRYL 0 ANTISTOMINUM 0 ANTOMIN 0 AUTOMIN 0 BAGAODRYL 0 BARAMINE 0 BENA 0 BENACHLOR 0 BENADON 0 BENADRIN 0 BENADRYL 0 BENALLERGIN 0 BENAPON 0 BENODIN 0 BENODINE 0 BENYLAN 0 BENZANTINE 0 BENZHYDRAMINE 0 BENZHYDRAMINUM 0 BENZHYDRIL 0 oBENZHYDRYLDIMETHYINOETHANOL 0 2(BENZHYDRYL0XY)-N,N-DIMETHYLETHUINE 0
BBWSOO CAS: 132-69-4 HR: 3 BENZIDAMINE HYDROCHLORIDE mf: C I ~ H Z ~ N ~ O * C ~mw: H 345.91 PROP: Mp: 160'. Very sol in H20. SYNS: AF 864 0 BENALGIN 0 BENZINDAVINE HYDROCHLORIDE 0 BENZYDAMINE HYDROCHLORIDE 0 1-BENZYL-3-y-DIMETHYL AhfINOPROPOXY-1H-INDAZOLE HYDROCHLORIDE 0 1-BEI\iZYL-3-(3-(DIMETHYLAMINO)PROPOXY)-lHINDAZOLE HYDROCHLORIDE 0 BENZYRIN 0 DIFFLAM 0 N,N-DIMETHYL-3((l-PHENYLMETHYL)-l HINDAZOL-3-YL)OXY-1-PROPANAMINEHYDROCHLORIDE 0 DORINAMIN 0 ENZAMIN 0 EPIROTIN 0 IMOTRYL 0 INDOLIN 0 RIRILIM 0 RIRIPEN 0 SALYZORON 0 TAMAS 0 TANTUM 0 VERAX
SAFETY PROFILE: Poison by intraperitoneal, subcutaneous, and intravenous routes. Moderately toxic by ingestion. An experimental teratogen. Other experimental animal reproductive effects. An 2-(BENZOHYDRYLOXY)-N,N-DIMETHYLETHYLA?bfINE eye irritant. A nonsteroidal antiinflammatory analgesic. When heated to 0 BETRAMIN 0 DABYLEN 0 DEBENDRIN 0 DERMISTINE 0 DERMODRIN 0 DESENTOL 0 decomposition it emits very toxic fumes of DIABENYL 0 DIABYLEN 0 DIBONDRIN 0 DIFEDRYL HC1 and NO,.
0 DIFENHYDRAMIN 0 DIFENIDRAMINA (ITALIAN) 0 DIHIDRAL 0 DIMEDROL 0 DIMEDRYL 0 p-
DIMETHYLAMINO-AETHYL-BENZHYDRYLAETHER (GERMAN) p-DIMETHYLAMINOETHANOL DIPHENYLMETHYL ETHER 0 a-(Z-DIMETHYL&\fINOETH0XY)DIPHENYLhlETHANE 0 p-DIMETHYLAMINOETHYLBENZHYDRYLETHER 0 DIPHANTINE 0 DIPHENYLHYDMMINE 0 24,DIPHENYLbfETHOw-N,N-DIMETHYLETHYLAMINE 0 DRYISTAN 0 DRYLISTAN 0 DYLAMON 0 ETANAUTINE 0 HISTAXIN 0 HYADRINE 0 IBIODRAL 0 MEDIDRYL 0 M E P W R Y L 0 NAUSEN 0 PROBEDRYL 0 RESTAMIN 0 RESTAMINE 0 RIGIDIL 0 RIGIDYL 0 S51 0 SYNTEDRIL 0 SYNTODRIL 0 VENA
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Deadly human poison by an unspecified route. Poison by ingestion, intravenous, intraperitoneal, and subcutaneous routes. Experimental reproductive effects. Human systemic effects by ingestion: somnolence, alteration of operant conditioning, changes in psychophysiological tests. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also ETHERS.
BBXOOO CAS: 92-87-5 HR: 3 BENZlDlNE DOT: UN 1885 mf: ClzHlzNz mw: 184.26 PROP: Grayish-yellow, crystalline powder; white or sltly reddish crystals, powder, or leaf from water or alc. Mp: 127.5-128.7' @ 740 mm, bp: 401.7', d: 1.250 @I 20'/4'. SYNS: BENZIDIN
(CZECH) 0 BENZIDINA (ITALWIY) BENZYDYNA (POLISH) 0 p,p-BIANILINE 0 4,4'BIANILINE 0 (l,l'-BIPHENYL)-4,4'-DIAMINE (9C9 0 4,4'BIPHENYLDIAMINE 0 4,4'-BIPHENYLENEDIAMINE0 C.I. 37225 0 C.I. AZOIC DIAZO COMPONENT 112 0 p,p'DIAMINOBIPHENYL 0 4,4'-DIAMINOBIPHENYL0 4,4'DIAMINO-1,1'-BIPHENYL 0 p-DIAMINODIPHENYL 0 4,4'-DIAMINODIPHENYL0 p,p'-DIANILINE 0 4,4'DIPHENYLENEDIAMINE 0 FAST CORINTH BASE B 0 NCI-C03361 0 RCRA WASTE NUMBER UO21 0
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Human Limited Evidence IMEMDT 1,80,72; Human Sufficient Evidence IMEMDT 29,149,82; Animal Sufficient Evidence IMEMDT 1,80,72;IMEMDT 29,149,82. EPA Genetic Toxicology
a-BENZIL MONOXIME BCA300 141
Program. Community kght-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: OSHA: Cancer Suspect Agent ACGIH TLV: Confirmed Human Carcinogen DFG MAK: Human Carcinogen DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen producing bladder tumors. Experimental carcinogenic and tumorigenic data. Poison by ingestion and intraperitoneal routes. Human mutation data reported. Can cause damage to blood, including hemolysis and bone marrow depression. On ingestion causes nausea and vomiting, which may be followed by liver and kidney damage. Any exposure is considered extremely hazardous. When heated to decomposition it emits highly toxic fumes of NO,. See also AROMATIC AMINES. BBX750 CAS: 531-85-1 HR: 2 BENZIDINE HYDROCHLORIDE mfi C I ~ H I Z N ~ * ~ C ~mw: H 257.18 PROP: Leaflets. So1 in H2O. SYNS: (l,l'-BIPHENYL)-4,4'-DIAMINE, DIHYDROCHLORIDE 0 DIHIDROCLORURO de BENZIDINA (SPASISH) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. Human mutation data reported. When heated to decomposition it emits very toxic fumes of HC1 and NO,.
BBYOOO CAS: 531-86-2 HR: 3 BENZIDINE SULFATE mf: C I ~ H I ~ N ~ * H ~ Omw: ~ S282.34 PROP: Hair dye. SYN: (1,l'-BIPHENYL)-4,4'-DIAMINE SULFATE (1:l) OSHA PEL: OSHA: Carcinogen SAFETY PROFILE: Confirmed human
carcinogen with experimental carcinogenic data. See also BENZIDINE and SULFATES. When heated to decomposition it emits toxic fumes of SO, and NO,.
BBY300 HR: 2 BENZIDINE SULPHATE and HYDRAZINE-BENZENE mf: C ~ H ~ N ~ * C ~ ~ H * Z N ~ * mw: HZO~S 390.50 SYN: HYDRAZINE-BENZENE and BENZIDINE SULFATE
SAFETY PROFILE: Suspected carcinogen
with experimental carcinogenic data. When heated to decomposition it emits toxic fumes of NO, and SO,. BCAOOO CAS: 57-37-4 HR: 3 BENZlLlC ACID-P-DIETHYLAMINOETHYL ESTER HYDROCHLORIDE mf: C2oH25NOs*ClH mw: 363.92 PROP: Crystals from MeKO. Mp: 177-178'. Sol in H20; ins01 in Et2O. SYNS: ACTOZINE 0 AMIOYL 0 AMISYL 0 AMITAKON 0 AMIZIL HYDROCHLORIDE 0 ARCADINE 0 AY-5406 0 BENACTIZINE HYDROCHLORIDE 0 BENACTYZIN (CZECH) 0 BENACTYZINE CHLORIDE 0 BENACTYZINE HYDROCHLORIDE 0 BENAKTIN 0 BENZILATE DU DIETHYLAMINOETHANOL CHLORHYDRATE (FRENCH) 0 CAFRON CEDAD 0 CEVANOL 0 DESTENDO 0 P-DIETHYLAMINOETHYL BENZILATE HYDRO-CHLORIDE 0 2DIETHYLAMINOETHYLBENZILATE HYDROCHLORIDE 0 2-DIETHYLAMINO-ETHYLDIPHENYLGLYCOLATE HYDROCHLORIDE 0 Z-(DIFENYLHYDROXYACETOXY)ETHYL-DIETHYLAMMONIUMCHLORID (CZECH) 0 DIPHENYL-GLYCOLLIC ACID-2(DIETHYL4hlINO)ETHYL ESTER HYDROCHLORIDE 0 FOBEX 0 IBIOTYZIL 0 KATRON 0 LEUCIDIL 0 NERVACTON 0 NERVATIL 0 NEURAKTIL 0 NEUROBENZIL 0 NEUROLEPTONE 0 NUTINAL 0 PARASAN 0 PARPON 0 PHOBEX 0 PROCALM 0 STOIKON SUAVITIL 0 TRANQUILLIN 0 VALLADAN 0 WIN 5606
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion, intraperitoneal, subcutaneous, intradermal, and intravenous routes. Human systemic effects by ingestion of very small amounts: toxic psychosis. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of NO, and HC1.
BCA3OO CAS: 14090-77-8 U-BENZIL MONOXIME mf: C14HllN02 mw: 225.26
HR: 3
142
BCB750 BENZIMIDAZOLE
SYNS: a-BENZIL MONOOXIME 0 BENZIL, MONOXIME 0 BENZIL, MONOOXIME 0 BENZIL, p,MONOXIME 0 BENZIL, OXIME 0 1,2-DIPHENYL ETHANEDIONE MONOXIME 0 ETHANEDIONE, DIPHENYL, MONOOXIME SAFETY PROFILE: A poison by
intravenous route. Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of NO,. BCB750 CAS: 51-17-2 HR: 3 BENZIMIDAZOLE mf: C7H6N2 mw: 118.15 PROP: Tabular crystals or plates. Mp: 170.5', bp: >360°. Sol in alc; sparingly sol in water. SYNS: 3-AZAINDOLE 0 AZINDOLE 0 oBENZIMIDAZOLE 0 1H-BENZINIDAZOLE (9CI) 0 BENZIMINAZOLE 0 1,3-BENZODUZOLE 0 BESZOIMIDAZOLE 0 BZI U 1,3-DIAZAINDE?iE D N,N'-METHENYL-o-PHENYLENEDItlMINE 0 NSC-759
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits highly toxic fumes of NO,.
BCCSOO CAS: 583-39-1 HR: 3 2-BENZIMIDAZOLETHIOL mf: C7H6N2S mw: 150.21 PROP: Plates from alc (aq). Mp: 298'. Sol in EtOH; sltly sol in H20. SYNS: ANTIEGENE MB 0 ANTIOXIDANT MB (CZECH) 0 AOMB 0 ASM hlB 0 2-MERCAPTOBENZIMIDAZOLE 0 MERCAPTOBENZOIMIDAZOLE 0 2-MERCAPTOBENZOIMIDAZOLE 0 MERKAPTOBENZIMIDAZOL (CZECH) 0 NCI-C60980 0 oPHENYLENETHIOUREA 0 USAF EK-6540 0 USAF XF21
CONSENSUS REPORTS: Reported in EPA
BCESOO CAS: 81-07-2 HR: 3 1,2-BENZISOTHIAZOL-3(2H)-ONE-l,1DIOXIDE mf: C7HsN03S mw: 183.19 PROP: White crystals or powder from water; odorless with sweet taste. Mp: 224' (decomp), bp: subl. Sol in water, alc, chloroform, and ether. SYNS: ANHYDRO-o-SULFAMINEBENZOIC ACID 0 3BENZISOTHIAZOLINONE-1,l-DIOXIDE 0 o-BENZOIC SULPHIMIDE 0 o-BENZOSULFIMIDE 0 BENZOSULPHIMIDE 0 BENZO-2-SULPHIMIDE 0 o-BENZOYL SULFIMIDE 0 o-BENZOYL SULPHIMIDE 0 1,2DIHYDRO-2-KETOBENZISOSULFONAZOLE 0 1,2DIHYDRO-2-KETOBENZISOSULPHONAZOLE 0 2,3DIHYDRO-3-OXOBENZISOSULFONAZOLE0 2,3-
DIHYDRO-3-OXOBENZISOSULPHONAZOLE GARANTOSE 0 GLUCID 0 GLUSIDE 0 HERMESETAS 0
3-HYDROXYBENZISOTHIAZOL-S,S-DIOXIDE 0
INSOLUBLE SACCHARINE 0 KANDISET 0 NATREEN 0 RCRA WASTE NUMBER U202 0 SACARINA SACCAHARIMIDE 0 SACCHARINA 0 SACCHARIN ACID 0 SACCHARINE 0 SACCHARINOL 0 SACCHARINOSE 0 SACCHAROL 0 SAXIN 0 SUCRE EDULCOR 0 SUCRETI'E 0 o-SULFOBENZIMIDE 0 oSULFOBENZOIC ACID IMIDE 0 2-SULPHOBENZOIC IMIDE 0 SYKOSE 0 SYNCAL 0 ZAHARINA
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,334,87; Human Inadequate Evidence IMEMDT 22,111,80; Animal Sufficient Evidence IMEMDT 22,111$0. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. Community Right-ToKnow List. SAFETY PROFILE: Confirmed carcinogen with experimental neoplastigenic and tumorigenic data. Mtld acute toxicity by ingestion. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits toxic NO, and SO,.
TSCA Inventory. SAFETY PROFILE: Poison by
intraperitoneal and intravenous routes. Moderately toxic by ingestion. Skin and eye irritant. When heated to decomposition it emits toxic fumes of SO, and NO,. See also MERCAPTANS.
BCH750 CAS: 10085-81-1 HR: 3 BENZOCTAMINE HYDROCHLORIDE mf: ClsH19NaClH mw: 285.84 PROP: Solid. Mp: 320-322'. SYNS: BA 30,803 0
1-
METHYLAMINOMETHYLDIBENZO(b,c)BICYCL0(2,2,2)0 CTADIENE HYDROCHLORIDE 0 N-METHYLETHANO-
ANTHRACENE-9-(lOH)-METHYLAMINE HYDROCHLORIDE 0 TACITIN
BENZO(k)FLUORANTHENE BCJ280 143 SAFETY PROFILE: Poison by intravenous
route. Moderately toxic by ingestion. Experimental teratogenic effects. A sedative and muscle relaxant. When heated to decomposition it emits very toxic fumes of NO, and HC1-.
BC1500 CAS: 135-87-5 HR: 3 BENZODIOXANE HYDROCHLORIDE mf: C I ~ H I ~ N O ~ * C ~mw: H 269.80 PROP: Solid. Mp: 232-236'. SYNS: BENODAINE HYDROCHLORIDE 0
1-(1,4-
BENZODIOXAN-2-YLMETHYL)PIPERIDlNEHYDROCHLORIDE 0 F 933 0 FOL'RiiEAL' 933 0 2PIPERIDINOMETHYL-1,4-BENZODIOXAN HYDROCHLORIDE 0 2-(1-PIPERIDYLMETHYL)-1,4BENZODIOXAN HYDROCHLORIDE 0 PIPEROXANE HYDROCHLORIDE
SAFETY PROFILE: Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion and subcutaneous routes. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of NO, and HC1.
BCJOOO CAS: 5208-87-7 HR: 3 1,3-BENZODIOXOLE-5-(2-PROPEN-lOL) mf: C10H1003 mw: 178.20
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits
toxic vapors of NO,.
BCJ150 CAS: 54531-52-1 HR: 3 BENZODOL mf: ( C ~ H ~ A S O ~ C H ~ O ) , PROP: Sol in water, alc, and NaOH. SYNS: ARSONIC ACID, (4-HYDROXYPHENYL)-, polymer with FORMALDEHYDE 0 (4-HYDROXYPHENYL)ARSONIC ACID polymer with FORMALDEHYDE 0 POLYBENZARSOL OSHA PEL: TWA 0.5 mg(As)/m3 ACGIH TLV: BEI: 35 P (As)/L inorganic
arsenic and methylated metabolites in urine SAFETY PROFILE: Poison by intraperitoneal route. Low toxicity by ingestion. When heated to decomposition it emits toxic fumes of As.
BCJ250 CAS: 205-82-3 HR: 3 BENZO(j)FLUORANTHENE mf: CzoHlz mw: 252.32 PROP: Yellow crystals from EtOH. Mp: 165', bp: 240-260' @ 2 mm. SYNS: 10,ll-BENZFLUORANTHENE0 BENZ(j)FLUOROAWTHRENE 0 BEXZO(l)FLUOR4NTHENE 0 7&BENZOFLUORANTHENE 0 B(j)F 0 DIBENZO(a,jk)FLUORENE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: METHYLENEDIOXY-4-(l-HYDROXYALLYL)BENZENE Group 2B IMEMDT 7,56,87; Animal 0 a-VINYLPIPERONYLALCOHOL Limited Evidence IMEMDT 3,82,73; SAFETY PROFILE: Suspected carcinogen Animal Sufficient Evidence IMEMDT with experimental carcinogenic, 32,155,83. neoplastigenic, and tumorigenic data. SAFETY PROFILE: Confirmed carcinogen Human mutation data reported. When with experimental carcinogenic, heated to decomposition it emits acrid neoplastigenic, and tumorigenic data. smoke and irritating fumes, Mutation data reported. When heated to decomposition it emits acrid smoke and BCJ005 CAS: 22791-33-9 HR: 3 irritating fumes. 1,3-BENZODlOXOL-4-OL, 2,2DIMETHYL-, ACETY LMETHYLBCJ280 CAS: 207-08-9 HR: 3 CARBAMATE BENZO(k)FLUORANTHENE mf: C13H15N05 mw: 265.29 mf: C20H12 mw: 252.32 SYNS: ACETYZlMETHYLCARBAMICACID 2,2DIMETHYL-l,3-BENZODIOXOL-4-YL ESTER 0 PROP: Yellow prisms from C6H6 or AcOH. CARBAMIC ACID, ACETYLMETHYL-, 2,2-DIMETHYL-l,3Mp: 217', bp: 480'. SYNS: 1'-HYDROXYSAFROLE0
1,2-
BENZODIOXOL-4-YLESTER 0 CARBAMIC ACID, ACETYLMETHYL-, 2,3-(lSOPROPXlDENEDI0XY)PHENYL ESTER 0 NC-6897, ACETYL DERIVATIVE
SYNS: 8$BENZOFLUORANTHENE 0 11,12BENZOFLUORANTHENE 0 11,12-
144
BCK250
BENZOFURAN
BENZOQFLUORANTHENE 0 2,3,1',S'BINAPHTHYLENE 0 DIBENZO@,jk)FLUORENE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 32,163,83; Human No Adequate Data IMEMDT 32,163,83. SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
BCK250 CAS: 271-89-6 HR: 2 BENZOFURAN mf: CsH6O mw: 118.14 PROP: hquid. D: 1.078' @? 15'/15', bp: 166.5-168' @? 735 mm. SYNS: BENZO@)FURAN 0 2,3-BENZOFURAN 0 BENZOFURnrRAN 0 COUMARONE 0 NCI-C56166 0 1OXINDENE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. NTP Carcinogenesis Studles (gavage): Clear Evidence: mouse NTPTR* NTP-TR-370,89; kavage): Some Evidence: rat NTFTR* NTP-TR-370,89. EPA TSCA Chemical Inventory. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data reported. Moderately toxic by intraperitoneal route. Mutation data reported. When heated to decomposition it emits acrid smoke and fumes.
BCL750 CAS: 65-85-0 HR: 2 BENZOIC ACID mf: C7H602 mw: 122.13 PROP: White crystalhe powder, leaflets, or needles from water. Mp: 122', bp: 249', flash p: 250°F (CC), d: 1.316, autoign temp: 1060'F, vap press: 1 mm @? 96.0' (sublimes), vap d: 4.21. Very sltly sol in water; sol in alc, ether, chloroform, and fixed oils. SYNS: ACIDE BENZOIQUE (FRENCH) 0 BENZENECARBOXYLIC ACID 0 BENZENEFORMIC ACID 0 BENZENEMETHANOIC ACID 0 BENZOATE 0 BENZOESAEURE (GERMAN) 0 BENZOIC ACID (DO?)
0 CARBOXYBENZENE 0 DRACYLIC ACID 0 KYSELINA BENZOOVA (CZECH) 0 PHENYL CARBOXYLIC ACID 0 PHENYLFORMIC ACID 0 RETARDER BA 0 RETARDEX 0 SALVO LIQUID 0 SALVO POWDER 0 TENN-PLAS
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by ingestion, subcutaneous, and intraperitoneal routes. A severe eye irritant. A human s h and severe eye irritant. Mutation data reported. Combustible when exposed to heat or flame; can react with oxidzing materials. The powder burns rapidly in oxygen. To fight fire, use water, COz, water spray or mist, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
BCMOOO CAS: 120-51-4 HR: 2 BENZOIC ACID, BENZYL ESTER mf: C14H1202 mw: 212.26 PROP: Leaflets found in Peru and tolu balsams, in ylang-ylang, and in about 20 other essential oils PCTXAV 11,1011,73). Colorless oily liquid; slt aromatic odor. Mp. 21°, bp: 324', flash p: 298'F (CC), d: 1.116, refr index: 1.568, vap d: 7.3, autoign temp: 898'F. Msc with alc, chloroform, ether; insol in glycerin, water. SYNS: ASCABIN 0 ASCABIOL 0 BENYLATE 0 BENZOIC ACID, PHENYLMETHYL ESTER 0 BEKZYL ALCOHOL BENZOIC ESTER 0 BENZYL BENZENECARBOXYLATE 0 BENZYL BENZOATE (FCC) 0 BENZYLETS 0 BENZYL PHENYLFORMATE 0 COLEBENZ 0 FEMA No. 2138 0 NOVOSCABIN 0 PERUSCABIN 0 SCABANCA 0 VANZOATE 0 VENZONATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and skin contact. Combustible liquid. Can react with oxidning materials. To fight fire, use COz, water spray or mist, dry chemical. When heated to decomposition it emits acrid and irritating fumes and smoke. See also ESTERS.
BENZOPHENONE BCS250
BCP250 CAS: 119-53-9 HR: 3 BENZOIN mfi C14H1202 mw: 212.26 PROP: Externally reddish yellow, internally milky white tree resin with agreeable vanillalike odor. SYNS: ACETOPHENONE, 2-HYDROXY-2-PHENYL- 0 BENZOYLPHENYLCARBINOL 0 BITTER ALAfOND OIL CAMPHOR 0 ETHANONE, 2-HYDROXY-l,2-DIPHENYL0 FENYL-a-HYDROXYBENZYLKETON 0 a-HYDROXYBENZYL PHENYL KETONE 0 a-HYDROXY-aPHENYLACETOPHENONE 0 2-HYDROXY-2-PHENYLACETOPHENONE 0 KETONE, a-HYDROXYBENZYL PHENYL 0 NCLC50011 0 WY-42956
CONSENSUS REPORTS: NCI
Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* NCI-CGTR-204,80. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Slightly toxic by ingestion and skin contact. Mutation data reported. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also KETONES. BCP690 CAS: 190133-94-9 HR: 3 5H-BENZO(d)NAPHTH(2,1-B)AZEPIN12-0L, 11-CHLORO-6,6AY7,8,9,1 3bHEXAHYDRO-7-METHYL-, HYDROCHLORIDE, (6asYl3br)mf: C19H2oClNO*ClH mw: 350.29 SYN: (-)-SCH 39166 HYDROCHLORIDE SAFETY PROFILE: A poison by intramuscular route. When heated to decomposition it emits toxic vapors of NO,, HC1, and C1-. BCQ250 CAS: 100-47-0 HR: 3 BENZONITRILE DOT: UN 2224 mf: C7H5N mw: 103.13 PROP: Transparent, colorless oil; almondlike odor. D: 1.246 @ 20'/4', bp: 191', mp: -12.8'. SYNS: BENZENENITRILE 0 BENZOIC ACID NITRILE 0 BENZONITRILE (DO?? 0 CYANOBENZENE 0 FENYLKYANID 0 PHENYL CYANIDE
145
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community RightTo-Know List. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by intraperitoneal and subcutaneous routes. Moderately toxic by ingestion, inhalation, and skin contact. See also NITRILES. A skin irritant. Combustible liquid. When heated to decomposition it emits toxic fumes of CN- and NO,.
BCQSOO CAS: 189-55-9 HR: 3 BENZO(rst)PENTAPHENE mf: C24H14 mw: 302.38 PROP: Green-yellow needles from toluene. Mp: 280-282', bp: 275' @ 0.05 mm (subl). SYNS: DB(a,i)P 0 DIBENZO(a,i)PYRENE 0 DIBENZO@,h)PYRENE 0 1,2,7,8-DIBENZOPYRENE0 3,4:9,10-DIBENZOPYRENE0 DIBENZ(a,i)PYRENE 0 1,2:7,8-DIBENZPYRENE0 3,49,10-DIBENZPYRENE 0 RCRA WASTE NUMBER UOG4
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 3,215,73; IMEMDT 32,337,83. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental neoplastigenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. BCS250 CAS: 119-61-9 HR: 3 BENZOPHENONE mfi C13H100 mw: 182.23 PROP: Rhombic prisms (stable form), monoclinic prisms (labile form), white crystals; persistent rose-like odor. Mp (a): 49', mp (p): 26', mp (y): 47', bp: 305.4', d (a): 1.0976 @ 50'/50', d (p): 1.108 @ 23'/40', vap press: 1 mm @ 108.2. Sol in fixed oils; sltly sol in propylene glycol; ins01 in glycerin. SYNS: BENZOYLBENZENE 0 DIPHENYL KETONE 0 DIPHENYLMETHANONE 0 FEMA No. 2134 0 aOXODIPHENYLMETHANE 0 PHENYL KETONE
146 BCS750 BENZO(a)PYRENE CONSENSUS REPORTS: Reported in EPA
SAFETY PROFILE: Suspected carcinogen
TSCA Inventory.
with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and fumes.
DOT CLASSIFICATION: 3; Label:
Flammable Lquid SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Combustible when heated. Incompatible with oxidlzers. When heated to decomposition it emits acrid and irritating fumes. See also KETONES.
BCS750 CAS: 50-32-8 HR: 3 BENZO(a)PYRENE mf: CzoHlz mw: 252.32 PROP: Pale-yellow crystals. Mp: 177', bp: 312' @ 10 mm. Insol in water; sol in benzene, toluene, and xylene. SYNS: BENZO(d,e,f)CHRYSENE 0 3,4-BENZOPIRENE (ITALMS) 0 3,4-BENZOPYRENE 0 6,7-BENZOPYRENE 0 BENZ(a)PYRENE 0 3,4-BENZPYREN (GERMAN) 0 3,4-BENZ(a)PYRENE 0 3P-BENZYPYRENE 0 B(a)P 0 R C M KASTE NUMBER U022
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2A IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 32,211,83; IMEMDT 3,91,73. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.2 mg/m3 SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. A poison via subcutaneous, intraperitoneal, and intrarenal routes. Experimental teratogenic and reproductive effects. Human mutation data reported. A skin irritant. A common air contaminant of water, food, and smoke. When heated to decomposition it emits acrid smoke and fumes. See other benzopyrenes.
BCV250 CAS: 21247-98-3 HR: 3 BENZO(a)PYRENE-6-METHANOL mf: CztH140 mw: 282.35 PROP: Pale-yellow crystals from C6H6. Mp: 270-271 '. SYN: 6-HYDROXYMETHYLBENZO(a)PYRENE
CONSENSUS REPORTS: EPA Genetic
Toxicology Program.
BDC250 CAS: 583-63-1 HR: 3 0-BENZOQUINONE mf: C6H402 mw: 108.10 PROP: Solid. Mp: 60-70' (decomp). SYNS: 1,2-BENZOQUINONE 0 BENZOQUINONE POP 0 3,5-CYCLOHEXADIENE-l,2-DIONE 0 oQUINONE
SAFETY PROFILE: A poison. Mutation
data reported. When heated to decomposition it emits acrid smoke and irritating fumes. BDE750 CAS: 120-78-5 HR: 3 BENZOTHIAZOLE DISULFIDE mf: C I ~ H ~ N ~ S mw: ~ 332.48 PROP: Cream to pale-yellow powder. Mp: 186', d: 1.5. SYNS: ALTAX 0 BENZOTHIAZOLYLDISULFIDE 0 2BENZOTHIAZOLYL DISULFIDE 0 BIS(BENZOTHIA20LYL)DISULFIDE 0 BIS(2-BENZOTHIAZYL) DISULFIDE 0 DI-2-BENZOTHIAZOLYLDISULFIDE0 DIBENZOTHIAZYL DISULFIDE 0 2,2'-DIBENZOTHIAZYLDISULFIDE 0 DIBENZOYL-THIAZYL DISULFIDE 0 DIBENZTHIAZYL DISULFIDE 0 2,2'DITHIOBIS(BENZOTHIAZ0LE)0 DWUSIARCZEK DWUBENZOTIAZYLU (POLISH) 0 hIBTS 0 MBTS RUBBER ACCELERATOR 0 2-MERCAPTOBENZOTHIAZOLEDISULFIDE 0 2-MERCAPTOBENZOTHIAZYLDISULFIDE 0 ROYAL MBTS 0 THIOFIDE 0 USAF B-33 0 USAF CY-5 0 USAF EK-5432 VULKACIT DM 0 WLKACIT DM/MGC
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous
and intraperitoneal routes. Slightly toxic by ingestion. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of SO, and NO,. See also SULFIDES.
BENZOTRIFLUORIDE
BDFOOO CAS: 149-30-4 HR: 3 2-BENZOTHIAZOLETHIOL mf: C7HjNS2 mw: 167.25 PROP: Light-yellow powder or needles from MeOH (a$. Mp: 177-179'. Sltly sol in EtOH, EtzO, and AcOH; insol in Hz0; sol in alkalies. SYNS: BENZOTHIAZOLE-2-THIONE 0 2(3H)BENZOTHIAZOLETHIONE 0 2-BENZOTHIAZOLYL MERCAPTAN 0 CAPTAX 0 KAPTAX 0 MBT 0 MERCAPTOBENZOTHIAZOLE0 2-MERCAPTOBENZOTHIAZOLE 0 2-MERKAPTOBENZOTIAZOL0 2-MERKAFTOBENZTHIAZOL0 NCI-C56519 0 PENNAC iMBT POWDER 0 ROKON 0 ROTAX 0 SULFADENE 0 USAF GY-3 0 USAF XR-29 0 WLKACIT MERCAPTO
BDH500
147
Experimental teratogenic effects. An eye irritant. Mutation data reported. See also MERCAPTANS and SULFIDES. When heated to decomposition it emits very toxic fumes of NO, and SO,.
BDHOOO CAS: 90-16-4 HR: 3 1,2,3-BENZOTRlAZIN-4(1H)-ONE mf: C7HsN30 mw: 147.15 PROP: Needles from cyclohexane. SYNS: BENZAZIMIDE 0 BENZAZIMIDONE 0 BENZOKETCTRIAZINE 0 3H-1,2,3-BENZOTRZAZIN-4ONE 0 CKETOBENZOTRZAZINE 0 USAF hIA-2 CONSENSUS REPORTS: Reported in EPA
CONSENSUS REPORTS: NTP
TSCA Inventory.
Carcinogenesis Studies (gavage); Some Evidence: rat NTPTR* NTP-TR-332,88: (gavage); Equivocal Evidence: mouse NTPTR* NTP-TR-332,88. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion and intraperitoneal routes. Experimental teratogenic and reproductive effects. Mutation data reported. Incompatible with oxidizers. When heated to decomposition or on contact with acids or acid fumes it emits toxic SO, and NO,. See also MERCAPTANS.
SAFETY PROFILE: Poison by intraperitoneal route. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of NO,.
BDGOOO CAS: 102-77-2 HR: 3 2-BENZOTHIAZOLYL-NMORPHOLINOSULFIDE mf: CIIHIZNZOS~ mw: 252.37 SYNS: AMAX 0 2-BENZOTHIAZOLYLSULFENYL MOWHOLINE 0 4-(2-BENZOTHIAZOLYLTHIO)MORPHOLINE 0 2-(MOWHOLINOTHIO)BENZOTHIAZOLE 0 MORPHOLINYLMERCAPTOBENZOTHIAZOLE 0 2-(4-MORPHOLINYLTHIO)BENZOTHIAZOLE 0 N-(0XYDIETHYLENE)BENZOTHIAZOLE-2-SULFEN-AVIDE 0 SANTOCURE MOR 0 SULFENAMIDE M 0 USAF CY-7 0 VULCAFOR BSM CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. Questionable carcinogen with experimental neoplastigenic data.
BDH250 CAS: 95-14-7 HR: 3 1H-BENZOTRIAZOLE mf: C6HjN3 mw: 119.14 PROP: Needles from C6H6. Mp: 100'. Sol in C6H6. SYNS: 1,2-AMINOZOPHENYLENE 0 AZIMIDOBENZENE 0 AZIMINOBENZENE 0 BENZENE AZIMIDE 0 BENZISOTRIAZOLE 0 1,2,3-BENZOTRIAZOLE 0 COBRATEC #99 0 2,3-DIAZAINDOLE 0 NCI-C03521 0 NSC-3058 0 1,2,3-TRIAZAINDENE 0 U6233 CONSENSUS REPORTS: NCI Carcinogenesis Bioassay (feed); Inadequate Studies: mouse, rat NCITR* NCI-CG-TR88,78. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Moderately toxic by ingestion and intraperitoneal routes. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. May detonate at 22OOC or during vacuum distillation. When heated to decomposition it emits toxic fumes of NO,.
BDHSOO CAS: 98-08-8 BENZOTRIFLUORIDE DOT: UN 2338 mf: C7HjF3 mw: 146.12
HR: 3
148
BDJ250
S-((3-BENZOXAZOLINYL-6-CHLORO-2-OXO) METHYL)
PROP: Water-whtte liquid; aromatic odor.
CONSENSUS REPORTS: EPA: Farm
Mp: -29.1', bp: 98-99' (@ 725 mm, flash p: 54'F (CC), d: 1.197 (@ 15.5"/15.5', vap d: 5.04, vap press: 11 mm (@ 0'.
Worker Field Reentry FEREAC 39,16888,74. SAFETY PROFILE: Poison by ingestion, skin contact, and possibly other routes. A cholinesterase inhibitor. See also PARATHION. When heated to decomposition it emits very toxic fumes of C1-, NO,, PO,, and SO,.
SYNS: BENZENYL FLUORIDE 0 BENZYLIDYNE FLUORIDE 0 PHENYLFLUOROFORM 0 FRIFLUOROMETHYL)BENZENE 0 a,a,a-TRIFLUOROTOLUENE0 a-TRIFLUOROTOLUENE 0 USXF MA-16 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison by
intraperitoneal route. Moderately toxic by subcutaneous route. See also FLUORIDES. Dangerous fire hazard, To fight fire, use water, foam, COz, spray mist, dry chemical. When heated to decomposition it emits toxic fumes of F-. Incompatible with oxihzing materials.
BDJ250 CAS: 2310-17-0 HR: 3 S-((3-BENZOXAZOLINYL-6-CHLORO-P0XO)METHYL) 0,O-DIETHYLPHOSPHORODITHIOATE mf: C I Z H I ~ C ~ N O ~ P Smw: ~ 367.82 PROP: Crystals with garlic odor. Mp: 47.5-48.0'. Insol in H20 and hydrocarbons.
BDL750 CAS: 582-61-6 BENZOYL AZIDE mf: C7H5N30 mw: 147.14
HR: 3
SYNS: BENZAZIDE 0 BENZOIC ACID AZIDE DOT CLASSIFICATION: Forbidden SAFETY PROFILE: May explode when
heated above 120'C. See also AZIDES.
BDL860 CAS: 611-95-0 p-BENZOYLBENZOIC ACID mf: C14H1003 mw: 226.23
HR: 3
SYN: BENZOIC ACID, 4-BENZOYLSAFETY PROFILE: A poison by
intravenous route. When heated to decomposition it emits acrid smoke and irritating vapors.
BDMSOO CAS: 98-88-4 HR: 3 BENZOYL CHLORIDE (MERCAPTOMETHYL)-2-BENZOXAZOLINONE)-O,O- DOT: UN 1736 D I E T H X PHOSPHORODITHIOATE 0 3-(6-CHLORO-2mf: C7H5C10 mw: 140.57 OXOBENZOXAZOLIN-3-YL)METHYL-O,O-DIETHYL PROP: Colorless, fuming, pungent liquid; PHOSPHOROTHIOLOTHIONATE 0 0,O-DWETHYL-Sdecomposes in water. Fp: -lo,mp: -0.5', (~-CHLOR-~-OXO-BE~(~J)-~,~-OXALIN-~-YL)-~~ETHYLbp: 197', flash p: 162'F (CC), d: 1.22 (@ DIT HIOPHOSPHAT (GERMAN) 0 0,O-DIETHYL-S-((6CHLOOR-2-OXO-BENZOXAZOLIN-3-X)-METHYL)- 15'/15', vap press: 1 mm (@ 32.1', vap d: DITHIO FOSFAAT (DUTCH) 0 0,O-DIETHYL-S-(6CHLOROBESZOXAZOLINYL-3-;I.IETHYL)DITHIOPH- 4.88. SYNS: AZOFENE
0 BENZOPHOSPHATE 0 BENZPHOS 0 CHIPSUN 11974 0 S-(6-CHLORO-3-
SYNS: BENZENECARBONYLCHLORIDE 0 BENZOIC OSPH,4TE 0 O,O-DIETHYL-S-((6-CHLORO-2ACID, CHLORIDE 0 BENZOYL CHLORIDE (DOT) 0 aPHOSPHOROOXOBENZOX4ZOLIN-3-YL)METHYL) DITHIOATE 0 O,O-DIETHYL-S-(6-CHLORO-2-OXO- CHLOROBENZALDEHYDE CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87, PHORYLMETHYL-6-CHLOROBESZOXAZOLOXE-2 0 Human Inadequate Evidence IMEMDT O,O-DIETIL-S-((6-CLORO-2-OXO-BEKZOSSAZOSSAZOLIN-329,83,82; Animal Inadequate Evidence IL)-METIL)-DITIOFOSFA4T0 (ITALWS) 0 ENT 27,163 0 IMEMDT 29,83,82. Community Right-ToFOZXLON 0 NIA-9241 0 NIAGARA 9241 0 NPH-1091 0 PHASOLON 0 PHOSALON 0 PHOSALONE 0 Know List. Reported in EPA TSCA PHOZALON 0 RHODIA RP 11974 0 RUBITOX 0 Inventory. EPA Genetic Toxicology ZOLON 0 ZOLONE 0 ZOLONE Phl ZOOLON Program. DFG MAK: Confirmed Human Carcinogen DOT CLASSIFICATION: 8; Label: Corrosive BENZOX%ZOLIN-3-YL)METHYL-PHOSPHORO THIOLOTHIONATE 0 3-DIETHYLDITHIOPHOS-
BENZOYL PEROXIDE BDSOOO 149 SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data by skin contact. Human systemic effects by inhalation: unspecified effects on olfaction and respiratory systems. Corrosive effects on the skin, eyes, and mucous membranes by inhalation. Flammable when exposed to heat or flame. Will react with water or steam to produce heat and toxic and corrosive fumes. Violent or explosive reaction with dimethyl sulfoxide, and aluminum chloride + naphthalene. To fight fire, use alcohol foam, COZ,dry chemical. Incompatible with dimethyl sulfoxide, (NaN3 + KOH), water, steam, and oxidizers. When heated to decomposition it emits toxic fumes of C1-. See also CHLORIDES and ALDEHYDES.
BDN6OO CAS: 110690-43-2 HR: 3 3-(3-(6-BENZOYLOXY-3-CYANO-2PYRlDYLOXYCARBONYL)BENZOYL) -1-ETHOXYMETHYL-5FLUOROURACIL mf: C Z E H I ~ F N ~ O Emw: 558.51 SYNS: BENZOIC ACID, 3-((3-(ETHOXYMETHYL)-5FLUOR0-3,6-DIHYDRO-2,6-DIOXO-l(2H)PYRIM1DINYL)CARB 0NYL)-, 0 BOF-A2 0 EMITEFUR
SAFETY PROFILE: A poison by ingestion and subcutaneous routes. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic vapors of NO, and F-.
BDR750 CAS: 4342-36-3 HR: 3 BENZOYLOXYTRIBUTYLSTANNANE mf: C19H3z02Sn mw: 41 1.20 SYNS: TRIBUTYLTIN BENZOATE 0 TRI-N-BUTYLZINN BENZOATE (GERMAN)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: T'WA 0.1 mg(Sn)/m3 (slun) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). DFG MAK: 0.0021 ppm (0.05 mg/m3) NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion and intravenous routes. Moderately toxic by subcutaneous route. See also TIN
COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes. BDSOOO CAS: 94-36-0 HR: 3 BENZOYL PEROXIDE mf: C14H1004 mw: 242.24 PROP: m t e , granular, tasteless, odorless powder or prisms. Mp: 106-108.6' (decomp), bp: decomposes explosively, autoign temp: 176'F. Sol in benzene, acetone, chloroform; sltly sol in alc; insol in water. IDLH 1500 mg/m3. SYNS: ACETOXYL 0 ACNEGEL 0 AZTEC BPO 0 BENOXYL 0 BENZAC 0 BENZAKNEW 0 BENZOIC ACID, PEROXIDE 0 BENZOPEROXIDE 0 BENZOYL 0 BENZOYLPEROXID (GERMAN) 0 BENZOYLPEROXYDE (DUTCH) 0 BENZOYL SUPEROXIDE 0 BZF-60 0 CADET 0 CADOX 0 CLEARASILBENZOYL PEROXIDE LOTION 0 CLEARASIL BP ACNE TREATMENT 0 CUTICURA ACNE CREAM 0 DEBROXIDE 0 DIBENZOYLPEROXID (GERMAN) 0 DIBENZOYL PEROXIDE (MAK) 0 DIBENZOYLPEROXYDE (DUTCH) 0 DIPHENYLGLYOXAL PEROXIDE 0 DRY AND CLEAR 0 EPI-CLEAR 0 FOSTEX 0 GAROX 0 INCIDOL 0 LOROXIDE 0 LUCIDOL 0 LUPERCO 0 LUPEROX FL 0 NAYPER B and BO 0 NOROX BZP-250 0 NOVADELOX 0 OXY-5 0 OXY-10 0 OXYLITE 0 OXY WASH 0 PANOXYL 0 PEROSSIDO di BENZOILE (ITALIAN) 0 PEROXYDE de BENZOYLE (FRENCH) 0 PERSADOX 0 QUINOLOR COMPOUND 0 SULFOXYL 0 SUPEROX 0 THERADERM 0 TOPEX 0 VANOXIDE 0 XERAC CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 36,267,85; Human Inadequate Evidence IMEMDT 36,267,85. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-To-Know List. OSHA PEL: TWA 5 mg/m3 ACGlH TLV: TWA 5 mg/m3; Not Classifiable as a Human Carcinogen DFG MAK: 5 mg/m3; Weak allergn and skin irritant NIOSH REL: (Benzoyl Peroxide) T'WA 5 mg/m3 SAFETY PROFILE: Poison by intraperitoneal route. Can cause dermatitis, asthmatic effects, testicular atrophy, and vasodilation. An allergen and eye irritant.
150
BDUSOO 2-(m-BENZOYLPHENYL)PROPlONlC ACID
Human mutation data reported. Questionable carcinogen with experimental tumorigenic data. Moderate fire hazard by spontaneous chemical reaction in contact with reducing agents. It igilltes readily and burns rapidly. A powerful oxidizer. Dangerous explosion hazard; may explode spontaneously when heated to above melting point, or when overheated under confinement. It is moderately sensitive to heat, shock, friction, or contact with combustible materials. Explosive decomposition above the mp (103') forms flammable products. Explosive or violent reaction on contact with N,N-dmethylaniline, aniline, &methyl sulfide, lithium tetrahydroaluminate, and Nbromosuccinimide + 4-toluk acid. Mixture with carbon tetrachloride + ethylene explodes at elevated temperatures and pressures. Reacts violently in contact with various organic or inorganic acids, alcohols, amines, metallic naphthenates, as well as with polymerization accelerators, e.g., dlmethylaniline, and (ccl4 + Violent reaction with charcoal when heated above 50'. Decomposition produces dense whte smoke of benzoic acid, phenyl benzoate, terphenyls, biphenyls, benzene, and carbon dioxide. Vigorous reaction leading to ignition with methylmethacrylate, and vinyl acetate + ethyl acetate. To fight fire, use water spray, foam. All precautions must be taken to guard against fire and explosion hazards. Keep in a cool place, out of the drect rays of the sun, away from sparks, open flames, and other sources of heat, avoid shock, rough handling, friction from grinding, etc. Isolated storage is required; keep away from possible contact with acids, alcohols, ethers, or other reducing agents or polymerization catalysts such as dimethylanhe. Complete instructions on storage and handling available from manufacturer. See also PEROXIDES. BDUSOO CAS: 22071-15-4 HR: 3 2-(m-BENZOYLPHENYL)PROPIONIC
ACID mf: C16H1403
mw: 254.30
SYNS: ALRHEUMAT
ALRHEUMUM mBENZOYLHYDRATROPIC ACID 0 3BENZOYLHYDRATROPIC ACID I3 2-(3-BENZOYLPHENYL)PROPIONICACID 0 CAPISTEK 0 FASTUM 0 ISO-K 0 KEFENID 0 KETOPROFEN 0 KETOPRON 0 LERTUS 0 MEPROFEN ORUDIS I3 ORWAIL 0 PROFENID 0 19583 RP
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion,
subcutaneous, intravenous, rectal, and intraperitoneal routes. Human systemic effects by an unspecified route: headache, nausea or vomiting, and degenerative changes in the brain, changes in kidney tubules. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes. An antiinflammatory and analgesic agent. BDXOOO CAS: 140-11-4 HR: 3 BENZYLACETATE mf: CgH1002 mw: 150.19 PROP: Colorless liquid; sweet, floral fruity odor. Mp: -51.5', bp: 134' @ 102 mm, flash p: 21 6'F (CC), d: 1.06, autoign temp: 862'F, vap press: 1 mm @? 45', vap d: 5.1, refr index: 1.501. Sol in alc, most fixed oils, propylene glycol; insol in glycerin and water @? 214". SYNS: ACETIC ACID BENZYL ESTER 0 ACETIC ACID PHENYLMETHYL ESTER 0 a-ACETOXYTOLUENE 0 BENZYL ETHANOATE 0 FEMA No. 2135 I3 NCI-C06508
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 40,109,86. NTP Carcinogenesis Studies (gavage); Some Evidence: mouse, rat NTPTR* NTP-TR250,86. Reported in EPA TSCA Inventory. ACGIH TLV: TWA 10 ppm; Not Classifiable as a Human Carcinogen SAFETY PROFILE: A poison by inhalation. Moderately toxic by ingestion and subcutaneous routes. Human systemic effects by inhalation: an antipsychotic, unspecified respiratory and urinary system
BENZYL BUTYL PHTHALATE
effects. Questionable carcinogen with experimental tumorigenic data. Combustible liquid. To fight fire, use alcohol foam, CO2. When heated to decomposition it emits irritating fumes. See also ESTERS.
BDX500 CAS: 100-51-6 HR: 3 BENZYL ALCOHOL mf: C7H80 mw: 108.15 PROP: Found in jasmine, hyacinth, ylangylang oils, and at least two dozen other essential oils (FCTXAV 11,1011,73). Waterwhite liquid; faint, aromatic odor, sharp burning taste. Mp: -15.3", bp: 205.3', flash p: 213°F (CC), d: 1.050, autoign temp: 817"F, vap press: 1 mm @ 58.0°, vap d: 3.72, refr index: 1.540. Misc with alc, chloroform, ether, and water @ 206"(decomp). Moderately sol in water. SYNS: BENZAL ALCOHOL 0 BENZENECARBncTOL 0 BENZENEVETHANOL 0 BENZOYL ALCOHOL 0 F E W NO, 2137 0 HYDROXYTOLUENE 0 a-HYDROXYTOLUENE 0 NCI-C06111 0 PHENOLCARBINOL 0 PHENYLCARBINOL 0 PHENYLMETHANOL 0 PHEN&METHYL ALCOHOL 0 a-TOLUENOL CONSENSUS REPORTS: EPA Genetic Toxicology Program.Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion, intraperitoneal, intravenous, and parenteral routes. Moderately toxic by inhalation, skin contact, and subcutaneous routes. A moderate skm and severe eye irritant. Mutation data reported. Combustible liquid. Mixtures with sulfuric acid decompose explosively at 180". Exothermic polymerization is catalyzed by HBr + iron when heated above 100". To fight fxe, use alcohol foam, COa, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also ALCOHOLS.
BDY669 CAS: 61-33-6 HR: 3 BENZYL-6-AMINOPENICILLINICACID mf: Ci6H18N204S mw: 334.42 PROP: Crystals. SYNS: ABBOCILLIN 0 (5R,6R)-BENXnPENICILIN 0 BENZOPENICILLIN 0 BENZYLPENICILLIN 0 BENZYLPENICILLIN G 0 BENZYLPENICILLINIC ACID
BECSOO 151
0 CILLORAL 0 CILOPEN 0 COMPOCILLIN G 0 COSMOPEN 0 DROPCILLIN 0 FREE BENZYLPENICILLIN 0 GALOFAK 0 GELACILLIN 0 LIQUACILLIN 0 PENICILLIN G 0 PHENYLACETAMIDOPENICILLANIC ACID 0 (PHENYLMETHYL) PENICILLINIC ACID 0 PRADUPEN 0 SPECILLINE G
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by ingestion, intravenous, intracerebral, intraspinal, subcutaneous, and possibly other routes. Human (chdd) systemic effects by parenteral route: changes in cochlear (inner ear) structure or function, convulsions, and dyspnea. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and SO,. See other penicfin entries.
BECOOO CAS: 100-39-0 HR: 2 BENZYL BROMIDE DOT: UN 1737 mf: C7H7Br mw: 171.05 PROP: Clear, refractive liquid; pleasant odor, lachrymator, ins01 in water. Mp: -4.0°, bp: 198", d: 1.438 @ 22"/0°, vap d: 5.8. SYNS: PROM0METHYL)BENZENE 0 p-(BROMOMETHYL)NITROBENZENE 0 BROMOPHENYLMETHANE 0 03-BROMOTOLUENE 0 Ce BROMOTOLUENE (DOT) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison,
Corrosive SAFETY PROFILE: Intensely irritating and corrosive to skin, eyes, and mucous membranes. Large doses cause central nervous system depression. Mutation data reported. Reaction with molecular sieve produces toxic hydrogen bromide gas. See also BROMIDES.
BECSOO CAS: 85-68-7 HR: 2 BENZYL BUTYL PHTHALATE mf: Ci9Hzo04 mw: 312.39 PROP: Clear, oily liquid. Mp: <-35", bp: 370°, flash p: 390°F, d: 1.116 @ 25"/25", vap d: 10.8.
152
BED000
BENZYL n-BUTYRATE
SYNS: BBP 0 1,2-BENZENEDIChRBOXYLIC ACID, BUTYL PHENYLMETHYL ESTER 0 BUTYL BENZYL PHTHilLATE 0 n-BUTYL BENZYL PHTHALATE 0 NCIC54375 0 PALATINOL BB 0 SANTICIZER 160 0 SICOL 160 0 UNIMOLL BB CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 29,193,82; NTP Carcinogenesis Bioassay (feed); No Evidence: mouse NTPTR* NTP-TR-213,82; Clear Evidence: rat NTPTR* NTP-TR213,82. Reported in EPA TSCA Inventory. Community Rtght-To-Know List. SAFETY PROFILE: Questionable carcinogen with experimental carcinogenic data. Moderately toxic by ingestion, s h n contact, and intraperitoneal routes. Experimental reproductive effects. See also ESTERS. Combustible when exposed to heat or flame; can react with oxidizers. To fight fKe, use spray or mist, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. BED000 CAS: 103-37-7 HR: 2 BENZYL n-BUTYRATE mf: C11H1402 mw: 178.25 PROP: Colorless liquid; floral plum-like odor. D: 1.006, refr index: 1.492, flash p: 212'F. Sol in fixed oils; insol in glycerin, propylene glycol, water @ 239'. SYNS: BENZYL n-BUTANOATE 0 FEW4 No. 2140 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. See also ESTERS. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. BEE375 CAS: 100-44-7 HR: 3 BENZYL CHLORIDE DOT: UN 1738 mf: C7H7C1 mw: 126.59 PROP: Colorless liquid, very refractive; irritating, unpleasant odor. Mp: -48', bp: 99' @ 62 mm, lel: 1.1%, flash p: 153'F, d: 1.11 @ 4"/4', autoign temp: 1085'F, vap d: 4.36. IDLH 10 ppm.
SYNS: BENZILE (CLORURO di) (ITALIAN) 0 BENZYLCHLORID ( G E R i i N ) 0 BENZYLE (CHLORURE de) (FRENCH) 0 CHLOROMETHYLBENZENE 0 C H L O R O P H E N Y L M E T W E 0 aCHLOROTOLUENE 0 (trCHLOROTOLUENE 0 aCHLORTOLC'OL (GERMAN) 0 CHLORURE de BENZYLE (FRENCH) 0 NCI-C06360 0 RCRA WASTE NUMBER PO28 0 TOLYL CHLORIDE
CONSENSUS REPORTS: IARC Cancer Review: Animal Limited Evidence IMEMDT 29,49,82; Animal Sufficient Evidence IMEMDT 11,217,76;Human Inadequate Evidence IMEMDT 29,49,82. EPA Genetic Toxicology Program. Community Rtght-To-Know List. Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 1 ppm ACGIH TLV: TWA 1 ppm; Animal Carcinogen DFG MAK: Confirmed Human Carcinogen NIOSH REL: (Benzyl Chloride) CL 5 mg/m3/ 15M DOT CLASSIFICATION: 6.1; Label: Poison, Corrosive SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by inhalation. Moderately toxic by ingestion and subcutaneous routes. Experimental reproductive effects. Human mutation data reported. A corrosive irritant to shn, eyes, and mucous membranes. Flammable and moderately explosive when exposed to heat or flame. Can react vigorously with oxidizing materials. May explode during disdlation. The decomposition rate can reach explosive violence in presence of metals such as iron. Catalytic impurities (e.g., aluminum, iron, rust) or s o l u m acetate + pyridme + iron (at 115OC) may cause violent polymerization reactions. Wdl react with water or steam to produce toxic and corrosive fumes. Incompatible with dimethyl sulfoxide. Used in production of drugs of abuse. When heated to decomposition it emits toxic fumes of C1-. See also CHLORINATED HYDROCARBONS, AROMATIC.
BENZYLDIMETHYLDODECYLAMMONIUM CHLORIDE
BEF500 CAS: 501-53-1 HR: 3 BENZYL CHLOROFORMATE DOT: UN 1739 mf: CgH7C102 mw: 170.60 PROP: Colorless to pale-yellow liquid or oil; odor of phosgene. Mp: O', bp: 103' @ 20 mm. SYNS: BENZYLCARBONYL CHLORIDE 0 BENZYL CHLOROCARBONATE (DOT) 0 BENZYL CHLOROFORMATE (DOT) 0 BENZYLOXYCARBONYL CHLORIDE 0 BZCF CARBOBENZOXY CHLORIDE 0 CARBOBENZYLOXY CHLORIDE 0 CHLOROFORMIC ACID BENZYL ESTER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by ingestion and
inhalation routes. A powerful corrosive irritant. Thermally unstable. Will react with water or steam to produce toxic and corrosive fumes and heat. Iron salts catalyze the explosive decomposition of the ester. When heated to decomposition it emits toxic fumes of C1- and phosgene. See also PHOSGENE, ESTERS, and CHLORIDES.
BEG750 CAS: 103-41-3 HR: 2 BENZYL CINNAMATE mf: C16H1402 mw: 238.30 PROP: Found in balsams of Peru, tolu, styrax, copaiba, and others (FCTXAV 11,1011,73). White crystals; aromatic odor. Mp: 39', bp: 350.0°, vap press: 1 mm @ 173.8', flash p: 212'F. Sol in fBed oils; insol in glycerin and propylene glycol.
BEMOOO 153
BEL525 CAS: 7083-24-1 HR: 3 BENZYL 1-(2-(DIMETHYLAMINO)PR0PYL)PYRROL-2-YL, CITRATE KETONE mf: C I ~ H Z Z N Z ~ * C ~ mw: H ~462.55 ~~ SYN: 1-(2-(DIMETHYLAMINo)PROPYL)-2(I'HENYLACETYL)PYRROLE
CITRATE
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by
intravenous route. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating vapors.
BEL550 CAS: 73747-22-5 HR: 3 BENZYLDIMETHYLAMMONIUM HEXAFLUOROARSENATE mf: C~HI~N*ASFGH mw: 325.16 SYNS: BENZYLrLIINE, N,N-DIMETHYC, HEXAFLUOROARSENATE (1.) 0 N,N-DIMETHYLBENZYLM I N E HEXAFLUOROARSENATE OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of NO,, F-, and As.
BEL850 CAS: 10094-34-5 HR: 1 BENZYL DIMETHYLCARBINYL nBUTYRATE mf: CMHZOOZ mw: 220.34 PROP: Colorless liquid with plum aroma. Mp: >70°. SYNS: BENZYL DIMETHYLCARBINYLBUTYRATE 0 BU'NRIC ACID, a-a-DIMETHYLPHENETHYLESTER 0 DIMETHYLBENZYLCARBINYLBUTYRATE 0 a-aDIMETHYLPHENETHYLBUTYRATE CONSENSUS REPORTS: Reported in EPA
SYNS: BENZYL ALCOHOL CINNAMIC ESTER 0
TSCA Inventory.
BENZYL *(-PHENYLACRYLATE0 CINNhVEIN 0 transCINNAMIC ACID BENZYL ESTER 0 FEMA No. 2142 0 3PHENYL-2-PROPENOICACID PHENYLMETHYL ESTER (9CQ
SAFETY PROFILE: Low oral toxicity. A
s h n irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
ingestion. A mdd allergen and s h n irritant. Combustible liquid. See also ESTERS. When heated to decomposition it emits acrid smoke and irritating f m e s .
BEMOOO CAS: 139-07-1 HR: 3 BENZYLDIMETHYLDODECYLAMMONIU M CHLORIDE mf: C21H3gN.Cl mw: 340.05 PROP: Solid. Mp: 31-32', SYN: DODECYL DIMETHYL BENZYLAhOfONILJM CHLORIDE SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. A slun and eye
154
BEM750
1-BENZYL-2,5-DIMETHYL SEROTONIN HYDROCHLORIDE
irritant. When heated to decomposition it emits very toxic fumes of NO,, NH3, and
c1-.
When heated to decomposition it emits very toxic fumes of C1-, NH3, and NO,. A topical anti-infective agent.
BEM750 CAS: 525-02-0 HR: 3 1-BENZYL-P,&DIMETHYL SEROTONIN HYDROCHLORIDE mf: CjgH22N20*ClH mw: 330.89 PROP: Solid. Mp: 230-231'.
BE0250 CAS: 103-50-4 HR: 2 BENZYL ETHER mf: C14H140 mw: 198.28 PROP: Colorless to pale-yellow liquid. Mp: 5', bp: 182-183' @ 22 mm, flash p: 275'F SYNS: 3-(2-AhfIXOETHYL)-I-BENZYL-5-METHOXT-2(CC), d: 1.056, vap d: 6.84, refr index: 1.557. METHYLINDOLE HYDROCHLORIDE 0 BAS 0 BENAKSERIN HYDROCHLORIDE BENZYL ANTISEROTONIN 0 1-BENZYL-2-METHYL-3-(2AMINOETHYL)-5-METHOXYINDOLE HYDROCHLORIDE 0 I-BENZYL-2-METHYL-5-METHOXYTRYPTAMINE HYDROCHLORIDE 0 SEROTONIN BENZYL ANALOG 0 WOOLLEY'S ANTISEROTONIN
SAFETY PROFILE: Poison by intraperitoneal route. A serotonin antagonist that causes psychotropic effects in humans. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of HC1 and NO,.
SYNS: BENZYL OXIDE (CZECH) 0 DIBENZYLETHER (CZECH) 0 FEMA No. 2371
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Vapors are probably narcotic in high concentration. A sktn and eye irritant. Combustible when exposed to heat or flame; can react with oxidzing materials. Moderate explosion hazard by spontaneous chemical reaction. To fight fire, use COz, dry chemical. See also ETHERS.
BEN000 CAS: 121-54-0 HR: 3 BENZYLDIMETHYL(2-(2-(p-(l,1,3,3TETRAMETHYLBUTYL)PHENOXY)ET H0XY)ETHYL) AMMONIUM CHLORIDE mf: C27H42NOyCl mw: 448.15 PROP: Colorless crystals or plates. Mp: 164-166'. Very sol in H20; sol in MeZCO, EtOH, and CHCl3.
BEP250 CAS: 104-57-4 HR: 2 BENZYL FORMATE mf: C ~ H ~ O Z mw: 136.16 PROP: Colorless liquid with powerful fruity, spicy odor. D: 1.083-1.092, bp: 202'. Insol in water.
SYNS: ANTI-GERhf 77 0 ANTISEPTOL 0
TSCA Inventory.
BENZETHONIUM CHLORIDE 0 BENZETONIUM CHLORIDE 0 BENZYL,DIMETHYL-p-(1,1,3,3TETRAMETHYLBU"L)PHENOXYETHOXYETHYWiMMONIUM CHLORIDE 0 BZT 0 DIAPP 0
SAFETY PROFILE: Moderately toxic by ingestion and skin contact. Mutation data reported. Probably narcotic in high concentrations. See also ESTERS. When heated to decomposition it emits acrid, irritating fumes.
DIISOBUTYLPHENOXYETHOXYETHYLDIMETHYL BENZYL AMMONIUM CHLORIDE 0 DISILYN 0 HYAhfINE 0 HYAMINE 1622 0 NCI-C61494 0 p-tertOCTYLPHENOXYETHOXYETHYLDIMETHYLBENZYL AMMONIUM CHLORIDE 0 PHEMERIDE 0 PHEMEROL CHLORIDE 0 PHEMITHYN 0 POLYMINE D 0 QUATRACHLOR 0 SOLAMINE
SYNS: BENZYL ALCOHOL FORMATE 0 BENZYL METHANOATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
BEPSOO CAS: 10453-86-8 HR: 3 5-BENZYL-3-FURYL METHYL(k)cis,trans-CHRYSANTHEMATE mf: Cz2H2603 mw: 338.48
SAFETY PROFILE: Poison by ingestion, subcutaneous, intraperitoneal, and intravenous routes. A severe eye irritant. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported.
SYNS: BENZOFUROLINE 0 BENZYLFUROLINE 0 (5BENZK-3-FURYL) ,METHYL-2,2-DIMETHYL-3-(2METHYLPR0PENYL)-CYCLOPROPANECARBOXYLATE 0 CHRYSON 0 CHRYSRON 0 DIMETHYL-3-(2METHYL- 1-PROPENYL)CYCLOPROPANECARBOXYLATE 0 Eh-T 27,474 0 FhfC 17370 0 FOR-SYK
CONSENSUS REPORTS: Reported in EPA
BENZYLPENCILLINDIBENZYLETHYLENEDIAMINESALT 0 NIA 17170 0 NRDC 104 0 NSC-195022 0 OMS-I206 0 PREMGARD 0 PYNOSECT 0 PYRETHERM 0 RESMETHRIN 0 RESMETRINA (PORTUGUESE) 0 SBP1382 0 S.B. PENICK 1382 0 SYNTHRIN
CONSENSUS REPORTS: EPA FIFRA
1988 pesticide subject to regstration or reregistration. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by ingestion, and intravenous routes. Moderately toxic by inhalation and skin contact. When heated to decomposition it emits acrid and irritating fumes. See also ESTERS.
BES3OO CAS: 52098-16-5 HR: 3 1-BENZYL-2-INDOLYL HYDROXYMETHYL KETONE mf: C I ~ H I ~ N O Z mw: 265.33 SYNS: l-BENZYL-2-(HYDROXYACETYL)INDOLE 0 KETONE, 1-BENZYL-2-INDOLYLHYDROXYMETHYL
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by
intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
BEU250 CAS: 622-78-6 HR: 3 BENZYL-ISOTHIOCYANATE mf: CsH7NS mw: 149.22 PROP: Orange-red, crystalline solid. Mp: 41°, bp: 230°, d: 1.125 SYNS: BENZYL MUSTARD
OIL BENZYLSENFOEL ( G E W ) 0 ISOTHIOCYANIC ACID BENZYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal and subcutaneous routes. Intensely irritating. Mutation data reported. Moderate fire hazard via heat, flame, and oxidzers. To fight fire, use water, spray, foam, dry che.nica1.When heated to decomposition it emits very toxic NO, and SO,. See also ESTERS and THIOCYANATES.
BEU500 CAS: 538-28-3 HR: 3 BENZYLISOTHIOUREA HYDROCHLORIDE
BFC750
155
mf: CsHloN2S.ClH mw: 202.72 PROP: Dimorphic. Mp: 146-148’. SYNS: BENZYLISOTHIOURONIUMCHLORIDE 0 2BENZYLISOTHIOURONIUMCHLORIDE 0 BENZYL THIOPSEUDOUREAHYDROCHLORIDE 0 2-BENZYL2-THIO-PSEUDOUREA HYDROCHLORIDE 0 BENZYLTHIURONIUM CHLORIDE 0 S-BENZYLTHIURONIUM CHLORIDE 0 BTKH 0 ISOTHIOURONIUM CHLORIDE, BENZYL 0 2-THIO-2-BENZYL-PSEUDOUREA HYDROCHLORIDE 0 TL 944 0 USAF EK-2124 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion,
intraperitoneal, subcutaneous, and intravenous routes. When heated to decomposition it emits very toxic fumes of HC1, SO,, and NO,.
BFC200 CAS: 101670-78-4 HR: 3 5-BENZYLOXY-3-ISONIPECOTOYLINDOLE mfi C~tH21N202 mw: 333.44 SYNS: INDOLE, S-BENZnOXY-3-ISONIPECOTOYLKETONE, 5-BENZYLOXY-3-INDOLXl4-PIPERIDYL
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
BFC750 CAS: 1538-09-6 HR: 2 BENZYLPENClLLlNDlBENZYLETHYLEN EDlAMlNE SALT mf: C32H3~N40sS2~Ci6H20N2 mw: 909.22 PROP: Crystals. Mp: 123-124’. SYNS: BEACILLIN 0 BEN-P 0 BENZACILLIN 0 BENZATHINE BENZYLPENICILLIN 0 BENZATHINE PENICILLIN 0 BENZATHINE PENICILLIN G 0 BENZETHACIL 0 BENZYLPENICILLIN BENZATHINE 0 BICA-PENICILLIN 0 BICILLIN 0 CEPACILINA 0 CEPACILLINA 0 CILLENTA 0 DBED DIPENCILLIN G 0 DBED PENICILLIN 0 DEBECILLIN 0 DEBECYLINA 0 DIAMINE DIPENICILLIN G 0 DIAMINOCILLIAN U DIBENCIL 0 DIBENCILLIN 0 N,N’-DIBENZYLETHYI, ENEDIAMINE BISPENZYL PENICILLIN) 0 DIBENZYLETHYLENEDI~~INE-DI-PENICILLIN G 0 N,N’DIBENZYLETHYLENEDIAMINE, compounded with PENICILLIN G (1:2) 0 DIPO-SAFT 0 DURABIOTIC 0 DUM-PENITA 0 DURODENIN 0 EXTENCILLINE U EXTENICILLINE 0 LENTOCILLIN 0 LENTOPENIL 0
156 BFD250 BENZYL PENlClLLlNlC ACID SODIUM SALT LEOhWPEN 0 LONGACILIAN 0 LONGICIL 0 LPG 0 MEGACILLIN SUSPENSION 0 MOLDAMIN 0 NCIC56100 0 NEOLIN 0 PENADUR 0 PENADUR L-A 0 PENDEPON 0 PEN-DI-BEN 0 PENDITAX 0 PENDURAN 0 PENICILLIN G, compounded wlth N,N'DIBENZYLETHYLEXEDLUfINE (2:l) 0 PENICILLIN G SALT of N,N'-DIBENZYLETHYLENEDI~~INE 0 PENIDURAL 0 PENIDURE 0 PENILENTE 0 PERRAPEN 0 RETARPEN 0 TARDOCILLIN 0 VETARCILLIN 0 VICIN 0 WYCILLINA
PROP: Colorless liquid; sweet, floral odor with honey undertone. D: 1.095-1.099, refr index: 1.553-1.558, flash p: 212'F. Sol in alc, chloroform, ether. SYN: FEMA No. 2149 SAFETY PROFILE: Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
CONSENSUS REPORTS: Reported in EPA
BFD760 CAS: 3762-27-4 HR: 3 BENZYLPHOSPHONIC ACID DIBUTYL ESTER mf: Ci jHzj03P mw: 284.37 SYNS: DI-N-BUTYL BENZYLPHOSPHONATE 0
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of NO, and SO,. See other penicdtn entries.
BFD250 CAS: 69-57-8 HR: 3 BENZYL PENlClLLlNlC ACID SODIUM SALT mf: C I ~ H I ~ N ~ O ~ S *mw: N ~356.40 PROP: Needles from butanol (ad. Mp: 215' (decomp). Sol in Hz0 and MeOH. SYNS: AMERICAN PENICILLIN 0 BENZYLPENICILLIN SODIUM 0 CRYSTAPEN U MYCOFARM 0 NOVOCILLIN 0 PEN-A-BRASIVE 0 PENICILLIN-G, MOKOSODIUM SALT 0 PEPU'ICILLIN G, SODIUM 0 PENICILLIN G, SODIUM SALT 0 PENILARYN 0 PENZYLPENICILLIN SODIUM SALT 0 SODIUM BENZYLPENICILLIS 0 SODIUM BENZYLPENICILLIN G 0 SODIUM BENZYLPENICILLINATE 0 SODIUM PENICILLIN 0 SODIULI PENICILLIN G 0 SODIUiM PENICILLIN I1 0 VETICILLIN
CONSENSUS REPORTS: EPA Genetic
Toxicology Program. SAFETY PROFILE: Poison by intracerebral, parented, and intramuscular routes. Moderately toxic via intravenous route. Mildly toxic by ingestion. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits very toxic fumes of NO,, NazO, and SO,. An antibiotic. See other penicillin entries. BFD400 BENZYL PHENYLACETATE mf: C15H1402 mw: 226.27
HR: 1
PHOSPHONIC ACID, BENZYL-, DIBUTYL ESTER 0 PHOSPHONIC ACID, (PHENYLMETHYL)-,DIBUTYL ESTER
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of PO,.
BFD800 HR: D BENZYL PROPIONATE mf: C10H1202 mw: 164.20 PROP: Colorless liquid; sweet, floral fruity odor. D: 1.028-1.032, refr index: 1.496-1.500. Sol alc, most oils; sltly sol in propylene glycol; insol in glycerin, water. SYN: FEMA No. 2150 SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. BFJ750 CAS: 118-58-1 HR: 2 BENZYL SALICYLATE mfi C14H1203 mw: 228.26 PROP: Thick colorless liquid; pleasant odor. Bp: 208' @ 26 mm, d 1.175 @ 20°, refr index: 1.579. Sol in fixed oils; insol in glycerin and propylene glycol. SYNS: BENZYL-o-HYDROXYBENZOATE 0 FEMA No. 2151
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
ingestion. See also BENZYL ALCOHOL, SALICYLIC ACID, and ESTERS. Combustible when exposed to heat or flame. When heated to decomposition it
BERGAMOT OIL rectified BFOOOO 157
emits acrid smoke and irritating fumes. Incompatible with oxidzing materials.
DFG MAK: Confirmed Human Carcinogen DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Confirmed carcinogen
BFLOOO CAS: 3012-37-1 HR: 3 BENZYL THIOCYANATE mf: C8H7NS mw: 149.22 PROP: Orange-red crystals or solid. Mp: 41-42', bp: 230', d: 1.125.
with experimental carcinogenic data by skin contact and neoplastigenic data by inhalation. Experimental poison by inhalation. Corrosive to the skin, eyes, and mucous membranes. Large doses can cause central nervous system depression. Mutation data reported. When heated to decomposition it emits toxic fumes of C1-. See also CHLORINATED HYDROCARBONS, AROMATIC.
SYNS: BENZYL MUSTARD OIL 0 PHENYLS4ETHYL ESTER THIOCYANIC ACID (9CI) 0 SOLVAT 14 0 aTHIOCYANATOTOLUENE 0 TROPEOLIN CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous and intraperitoneal routes. See also THIOCYANATES. When heated to decomposition it emits very toxic fumes of NO,, SO,, and CN-. BFL250 CAS: 90-07-7 HR: 3 BENZYL TRICHLORIDE DOT: UN 2226 mf: C7H5Cl3 mw: 195.47 PROP: Clear, colorless to yellowish liquid; penetrating odor. Mp: -5', bp: 221°, d: 1.38 @ 15.5'/15.5', vap d: 6.77. SYNS: BENZENYL CHLORIDE 0 BENZENYL TRICHLORIDE BENZOIC TRICHLORIDE 0 BENZOTRICHLORIDE (DOT, RWK) 0 BENZYLIDYNE CHLORIDE 0 CHLORURE de BENZENYLE (FRENCH) 0 PHENYL CHLOROFORV 0 PHENYLTRICHLOROMETHANE 0 RCRA WASTE NUMBER U023 0 TOLUENE TRICHLORIDE 0 TRICHLOORMETHYLBENZEEN (DLTCH) 0 TRICHLORMETHYLBENZOL (GERhLilN) 0 TRICHLOROMETHYLBENZENE0 1~RICHLOR0METHYL)BENZENE0 TRICLOROMETILBENZENE (ITALIAN) 0 TRICHLOROPHENYL 14ETHANE 0 a,a,a-TRICHLOROTOLUENE 0 o,w,oTRICHLOROTOLUEXE 0 TRICLOROTOLUENE (ITALIAN) CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Human Limited Evidence IMEMDT 29,73,82; Animal Sufficient Evidence IMEMDT 29,73,82. EPA Genetic Toxicology Program. EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. ACGIH TLV: CL 0.1 (skin); Suspected Human Carcinogen
BFM750 CAS: 4525-46-6 HR: 3 BENZYL TRIMETHYL AMMONIUM IODIDE mf: CloH16N*I mw: 277.17 PROP: Solid. Mp: 181-182'. SYNS: BENZYLDIMETHYLAMINE METHIODIDE 0 PHENMETHYL TRIMETHYLA;LGZIONIUMIODIDE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: Proposed: (inhalable fraction) 0.1 mg/m3; Not Classifiable as a Human Carcinogen) SAFETY PROFILE: Poison by intraperitoneal and intravenous routes. See also IODIDES. When heated to decomposition it emits very toxic fumes of NO,, NH3, and I-.
BFOOOO CAS: 8007-75-8 HR: 1 BERGAMOT OIL rectified PROP: Yellow-green liquid; agreeable odor. Composition: 1-halyl acetate, 1-linalool, dlimonene, Qpentene, bergaptene. By rectification of bergamot oil expressed, under vacuum, to remove completely the furocoumarins and other related nonvolatile residues; found in the fruit of citrus Betgamia niso etpoiteazr (Fam. btaceae) (FCTXAV 11,1011,73). D: 0.875-0.880 @ 25'/25'. Misc with alc, glacial acetic acid; sol in fEed oils; insol in glycerin, propylene glycol. SYNS: BERGAMOTTE OEL (GERRlrlN) 0 OIL OF BERGAMOT, coldpressed 0 OIL OF BERGAMOT, rectified CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
158 ~ ~ 0 2 5 BERTRANDITE 0 SAFETY PROFILE: Mildly toxic by
ingestion. A rmld skin irritant and allergen. Combustible. When heated to decomposition it emits acrid smoke and irritating fumes. BF0250 CAS: 12161-82-9 HR: 3 BERTRANDITE mfi Hto09Siz*HzO*Be4 mw: 264.34 PROP: Colorless, pale-yellow, orthorhombic crystals. SYN: BERYLLIUM SILICATE HYDRATE CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Reported in EPA TSCA Inventory. Beryllium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/ m3 ACGIH TLV: TWA 0.002 mg(Be)/mj; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/mj (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Berylhum) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen. See also BERYLLIUM and BERYLLIUM COMPOUNDS. When heated to decomposition it emits very toxic fumes of BeO.
Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,4133; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Reported in EPA TSCA Inventory. Berylhum and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be) /m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skm); Confirmed Human Carcinogen) NlOSH REL: (Berylhum) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. See also BERYLLIUM COMPOUNDS and SILICATES. When heated to decomposition it emits toxic fumes of BeO. BF0750 CAS: 7440-41-7 HR: 3 BERYLLIUM DOT: UN 1966/UN 1567 af: Be aw: 9.01 PROP: A silvery-white, relatively soft, lustrous metal, ductile at red heat. Unreactive to H20 and air; dlssolves vigorously in dil acids. Be reacts with aq alkalies or Hz. Mp: 1287-1292", bp: 2970", d: 1.85. IDLH 4 mg/m3 (as Be). SYNS: BERYLLIUhi-9 0 BERYLLIUM COMPOUNDS, (UN1567) (DOV 0 GLUCINIUhi 0 GLUCINUM 0 RCRA WASTE NUMBER PO15 n.0.s. (UN 1566) (DO? 0 BERYLLIUM, powder
BF0500 CAS: 1302-52-9 HR: 3 BERYL mf: AlzOt~Si6*3Be mw: 537.53 PROP: Colorless, white, blue-green, greenyellow, yellow, or blue crystals. D: 2.63-2.91. SYNS: BERYLLIUM ALUMINOSILICATE 0 BERYLLIUM ALUMINUM SILICATE 0 BERYL ORE
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review:
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Berylhum and its compounds are on the Community
BERYLLIUM ALUMINUM ALLOY
Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be) /m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be>/m’; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) DFG MAK: DFG TRIC Animal Carcinogen, Suspected Human Carcinogen. Grinding of beryllium metal and alloys: 0.005 mg/m3 calculated as beryllium in that portion of dust that can possibly be inhaled; other beryllium compounds: 0.002 mg/m3 calculated as beryllium in that portion of dust that can possibly be inhaled NIOSH REL: CL not to exceed 0.0005 mg(Be)/m3 DOT CLASSIFICATION: 6.1; Label: Poison (UN 1566); DOT Class: 6.1; Label: Poison, Flammable Solid (UN 1567) SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. A deadly poison by intravenous route. Human systemic effects by inhalation: lung fibrosis, dyspnea, and weight loss. Human mutation data reported. See also BERYLLIUM COMPOUNDS. A moderate fire hazard in the form of dust or powder, or when exposed to flame or by spontaneous chemical reaction. Slight explosion hazard in the form of powder or dust. Incompatible with halocarbons. Reacts incandescently with fluorine or chlorine. hhxtures of the powder with C c 4 or trichloroethylene will flash or spark on impact. When heated to decomposition in air it emits very toxic fumes of BeO. Reacts with Li and P. BFPOOO CAS: 543-81-7 HR: 3 BERYLLIUM ACETATE mf: C4H60pBe mw: 127.11 PROP: Plates. Mp: decomp @ 300’. SYN: BERYLLIUM ACETATE.NORMAL
BFP250
159
CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community fight-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be) /m3 ACGIH TLV: “A 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 rng(Be)/m’; STEL 0.0002 mg(Be)/m3 (sensitizer) ( s h ) ; Confirmed Human Carcinogen) DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen. Poison by intraperitoneal route. See also BERYLLIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of BeO.
BFP250 CAS: 12770-50-2 HR: 3 BERYLLIUM ALUMINUM ALLOY PROP: Alloy is 62% beryllium and 38% aluminum (ENVRAL 21,63,80). SYNS: ALUMINUM ALLOY, AI,Be 0 ALUMINUM BERYLLIUM ALLOY
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community fight-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed:
160
BFPSOO BERYLLIUM CARBONATE
TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) ( s h ) ; Confirmed Human Carcinogen) DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. See also BERYLLIUM COMPOUNDS. When heated to decomposition it emits very toxic BeO. BFP500 CAS: 66104-24-3 HR: 3 BERYLLIUM CARBONATE mf: CzHzBe308 mw: 181.07 PROP: White powder. Decomposes >200°. Insol in water. SYNS: BERYLLIUM CARBONATE, BASIC BERYLLIUMOXIDE CARBONATE BIS(CARB0NATO(2-))DIHYDROXYTRIBERYLLIUM
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Reported in EPA TSCA Inventory. Beryllium and its compounds are on the Community RightTo-Know Lst. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: CL not to exceed 0.0005 mg(Be) /m3 SAFETY PROFILE: Confirmed carcinogen. See also BERYLLIUM COMPOUNDS. When heated to decomposition it emits toxic B e 0 dust.
BFP750 CAS: 13106-47-3 HR: 3 BERYLLIUM CARBONATE (1:1) mf: COpBe mw: 69.02 PROP: Insol in water. Decomposes in hot water. SYN: CARBONIC ACID BERYLLIUM SALT (1:l) CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,4133; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Reported in EPA TSCA Inventory. Beryllium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) ( s h ) ; Confirmed Human Carcinogen) DFG MAK: 50 ppm (90 mg/m3) NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen. Poison by intraperitoneal route. See also BERYLLIUM COMPOUNDS. When heated to decomposition it emits highly toxic fumes of BeO. BFQOOO CAS: 7787-47-5 HR: 3 BERYLLIUM CHLORIDE mf: BeC12 mw: 79.91 PROP: Colorless, deliquescent needles, or orthorhombic crystals. Undergoes transition to high temp orthorhombic polymorph at 4’. Mp: 415’, bp: 520°, d: 1.899 @ 25’, vap press: 1 mm @ 291’ (subl). Very sol in H20, EtOH, E g o , or Py; sltly sol in CbH6, CHCb, CS2; insol in NH3 or MeKO. SYN: BERYLLIUM DICHLORIDE CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,4133;
BERYLLIUM COMPOUNDS BFQSOO 161
Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. Beryllium and its compounds are on the Community RtghtTo-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. Poison by ingestion and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of B e 0 and C1-. See also BERYLLIUM COMPOUNDS and CHLORIDES. BFQBOO HR: 3 BERYLLIUM COMPOUNDS PROP: Pure beryllium is a hard, brittle, silvery metal. Mp: 1278', bp: 2970°, d: 1.85. Beryllium oxide: white powder. Mp: 2530°, d: 3.0. Beryhum chloride: white to faintly yellow powder, deliquescent. Mp: 399', bp: 482'. Beryllium fluoride: glassy, hygroscopic solid. Mp: 545', d: 2.0. Beryllium nitrate: white to slightly yellow crystals. Mp: 60'). Beryllium sulfate: Mp: 550'. CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93.
Beryllium and its compounds are on the Community Rtght-To-Know Lm. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(I3e)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) DFG MAK: DFG TRIG Animal Carcinogen, Suspected Human Carcinogen. Grinding of beryhum metal and alloys: 0.005 mg/m3 calculated as beryllium in that portion of dust that can possibly be inhaled; other beryllium compounds: 0.002 mg/m3 calculated as beryllium in that portion of dust that can possibly be inhaled SAFETY PROFILE: Confirmed carcinogens. Beryllium compounds can enter the body through inhalation of dusts and fumes and may act locally on the skin. Even alloys of low beryhum content have been shown to be dangerous. In industry, inhalation of the dust can cause severe lung damage with symptoms appearing within months. Effects have been reported in persons living near processing plants and in families of beryllium workers. The fluoride, ammonium fluoride, sulfate, oxide, and hydroxide occur during extraction from beryllium ore. Exposure to the oxide may occur in processing of beryllium alloys and beryhum ceramics. The extraction of Be from its ore is attended by exposure to acid salts of the metal, particularly the fluoride (BeFZ), the ammonium fluoride and sulfate (BeS04), and also to beryllium oxide (BeO), and hydroxide pe(OH)z]. Exposure to the oxide also occurs in the casting of beryllium alloys and in operations with beryllia ceramics. In the manufacture of fluorescent powders, lamps, and sign tubes, there may be exposure to beryllium carbonate and to more complex salts, such as ZnMnBe s k a t e . Exposure to beryllium compounds encountered in the extraction of the metal
0
162
BFQ500
BERYLLIUM COMPOUNDS
or its oxide from the ore, particularly the halide salts, has been attended, in certain indviduals, by the development of dermatitis of an edematous and papulovesicular type, chronic skm ulcers, rhinitis, nasopharyngtis, epistaxis, bronchitis, and in severe cases, by the development of an acute pneumonitis, with cough, scanty sputum, low-grade fever, rales, dyspnea, and substernal pain. Radiographs show dffuse haziness throughout both lungs, followed by the appearance of soft, ill-defined opacities. The condition occurs whde the worker is exposed, sometimes within 1 or 2 months of starting work, and recovery occurs within 2 months, as a rule, though radiographic changes sometimes persist for longer periods. Occasionally, recovery may not occur and lung fibrosis results. In severe cases of pneumonitis, the patient may dte. Necropsies have revealed diffuse pulmonary edema, hemorrhagic extravasation, large numbers of plasma cells, and a relative absence of polymorphonuclear infdtration. On the basis of experimental work with animals, certain investigators are of the opinion that the acute upper and lower respiratory effects are due chiefly to the acid radtcal present in the dust or fume, but this view has little support. A delayed form of lung dsease, characterized by the occurrence of granulomatous areas in the lung tissue, has been reported in workers manufacturing fluorescent powders, lamps, and sign tubes, casting beryllium master alloys, and producing beryllium from beryl ore. Symptoms can start during exposure, but they may be delayed up to 5 years or more after the last exposure. The commonest symptoms are coughing, shortness of breath, loss of appetite, loss of weight, and fatigue. Rales are usually present in the bases and axillae, and the red cell count is frequently elevated. Cyanosis is common, and the pulse and respiratory rates are often increased. Radiographically, three stages of the disease are described: (1) a
dffuse, uniform granular shadowing extending throughout both lung fields; (2) a dffuse reticular pattern on the granular background; and (3) the appearance of dstinct nodules scattered through the lungs, with some enlargement and blurring of the hilar shadows. The intensity of the shadowing is usually greater in the middle third of the lung fields. The prognosis is poor. Clinical improvement may occur gradually over a period of several years, but there appears to be little tendency for the radtographic shadowing to clear. In certain cases, the dlsease has progressed gradually for some months or years, with death resulting from respiratory and cardiac failure. In several instances necropsies have shown the presence of a diffuse fibrosis with coarse strands of hyalinized collagen between the alveoli and, in some places, replacing them. The hyalinized areas contain granulomatous foci, the alveolar walls are thickened and fibrosed, the blood vessels being engorged and dilated. In some cases the hilar lymph nodes show granulomatous change and fibrosis. Granulomatous change has also been noted in the liver and hyaline fibrosis in the spleen. Two cases of delayed lung disease coming to autopsy have presented papular lesions on the dorsum of the hands; on the biopsy these showed “sarcoid-like” lesions with central necrosis. Several cases have been reported in which localized granulomatous lesions developed following penetrating wounds caused by splinters of glass from broken fluorescent light tubes. Several weeks or months following the accident, s w e h g s were noted in the injured areas and excision revealed granulomatous tumors, which in one case was shown to contain beryllium. There is no specific treatment, but temporary remissions have been produced by ACTH and cortisone.
BERYLLIUM FLUORIDE
BFQ750 CAS: 12010-12-7 HR: 3 BERYLLIUM COMPOUND with NIOBIUM (12:l) mf: BelzNb mw: 201.03 CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGlH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Beryllium) CL not to exceed 0.005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. When heated to decomposition in air it emits very toxic fumes of BeO. See also BERYLLIUM COMPOUNDS and NIOBIUM. BFROOO CAS: 12232-67-6 HR: 3 BERYLLIUM COMPOUND with TITANIUM (12:l) mf: Be12Ti mw: 156.02 SYN: TITANIUM compounded with BERKLIUM (1:12) CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Berylhum and its compounds are on the Community Rtght-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; f?roposed:
BFRSOO 163
TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. See also BERYLLIUM COMPOUNDS and TITANIUM COMPOUNDS. When heated to decomposition it emits very toxic fumes of BeO.
BFR250 CAS: 12400-16-7 HR: 3 BERYLLIUM COMPOUND with VANADIUM (12:l) mf: BelzV mw: 159.06 SYN: VANADIUM compounded with BERYLLIUM (1:12) CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/mj; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/mj; STEL 0.0002 mg(Be)/mj (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3; (REL to Vanadium) 1.O mgO/m3 SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. See also BERYLLIUM COMPOUNDS and VANADIUM COMPOUNDS. When heated to decomposition it emits very toxic fumes of B e 0 and VO,.
BFR500 CAS: 7787-49-7 BERYLLlUM FLUORIDE mf: BeF2 mw: 47.01
HR: 3
164
BFR750
BERYLLIUM HYDRIDE
PROP: Amorphous, colorless, hexagonal
crystals. Undergoes transition from low temp quartz to high-temp quartz structure types at 2'. Readily forms glass. Mp: 552', d: 1.986 @ 25'. Sub1 @ 8'. Very sol in H20; sltly sol in EtOH. SYN: BERYLLIUM DIFLUOIUDE CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72;Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community Right-To-Know List, Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen); TWA 2.5 mg(q/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift. NIOSH REL: (Berylhum) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data by inhalation. Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. See also BERYLLIUM COMPOUNDS and FLUORIDES. Incompatible with Mg. When heated to decomposition, it emits very toxic fumes of B e 0 and F-. BFR750 CAS: 7787-52-2 HR: 3 BERYLLIUM HYDRIDE mf: BeH2 mw: 11.03 PROP: White solid. CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT
58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community Rtght-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be) /m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen); TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift. NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen. A dangerous fire hazard, When heated to 220'C it liberates explosive hydrogen gas. Reacts violently with methanol, water, and dilute acids. When heated to decomposition it emits toxic fumes of BeO. See BERYLLIUM COMPOUNDS and HYDRIDES. BFSOOO CAS: 13598-15-7 HR: 3 BERYLLIUM HYDROGEN PHOSPHATE (1:I) mf: BeH04P mw: 104.99 SYNS: BERYLLIUM PHOSPHATE 0 PHOSPHORIC ACID, BERYLLIUM SALT (1:l) 0 PHOSPHOROUS ACID, BERYLLIUM SALT
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3
BERYLLIUM NITRATE ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intravenous route. See also BERYLLIUM COMPOUNDS and PHOSPHATES. When heated to decomposition it emits very toxic fumes of B e 0 and PO,.
BFS250 CAS: 13327-32-7 HR: 3 BERYLLlUM HYDROXIDE mf: H202*Be mw: 43.03 PROP: Colorless, orthorhombic, amorphous powder or crystals. Decomp on heating with H20 loss forming BeO. Mp: decomp @, 138". Practically insol in H20. SYNS: BERYLLIUM DIHYDROXIDE 0 BERYLLIUhI HYDRATE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg (Be) / m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intravenous
BFTOOO
165
route. See also BERYLLIUM COMPOUNDS. When heated to decomposition it emits very toxic fumes of BeO. BFS750 HR: 3 BERYLLIUM MANGANESE ZINC SILICATE mfi BeMn04SiZn mw: 221.41 SYNS: MANGANESE ZINC BERYLLIUM SILICATE 0 ZINC MANGANESE BERYLLIUM SILICATE
CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72;Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium, manganese, zinc, and their compounds are on the Community RightTo-Ihow List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be) /m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 rng(Be)/m'; STEL 0.0002 mg(Be)/m3 (sensitizer) ( s h ) ; Confirmed Human Carcinogen) NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. When heated to decomposition it emits very toxic fumes of B e 0 and ZnO. See also BERYLLIUM COMPOUNDS, MANGANESE COMPOUNDS, and ZINC COMPOUNDS.
BFTOOO CAS: 13597-99-4 HR: 3 BERYLLIUM NITRATE DOT: UN 2464 mf: BeN206 mw: 133.03 PROP: Deliquescent, white, amorphous solid or white-yellowish crystals. Mp: 60°, bp: decomp @, 100-200'. SYNS: BERYLLIUM DINITRATE 0 NITRIC ACID, BERYLLIUM SALT
166 BFT250
BERYLLIUM OXIDE
CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community Rtght-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M, CL 0.025 mg(Be) /m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: CL not to exceed 0.0005 mg(Be)/ m3 DOT CLASSIFICATION: 5.1; Label: Oxidizer, Poison SAFETY PROFILE: Confirmed carcinogen. Poison by intraperitoneal, intravenous, and subcutaneous routes. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of B e 0 and NO,. See also BERYLLIUM COMPOUNDS and NITRATES. BFT250 CAS: 7304-56-9 HR: 3 BERYLLIUM OXIDE mf: B e 0 mw: 25.01 PROP: m t e , amorphous powder or whte, hexagonal crystals; piezoelectric and pyroelectric. Undergoes hexagonal to tetragonal transition at 21'. Mp: 2507O, bp: 3900' (approx), d: 3.025. Dissolves in conc HzS04 and in fused KOH. Sltly sol in HzO. SYNS: BERYLLIA 0 BERYLLIUM MONOXIDE 0 THERMALOX
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human
Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient
Evidence IMEMDT 58,41,93. Berylltum and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be) /m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (sktn); Confirmed Human Carcinogen) NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. Experimental teratogenic data. Other experimental reproductive effects. See also BERYLLIUM COMPOUNDS. Incompatible with (Mg + heat). When heated to decomposition it emits very toxic fumes of BeO. BFT500 CAS: 19049-40-2 HR: 3 BERYLLIUM OXYACETATE mf: CtzHtsBe4013 mw: 406.34 PROP: Colorless cubic crystals from CHCL. Undergoes cubic to orthorhombic transition at 1'. Mp: 284O, bp: 331'. Sol in CHCl3, AcOH; sltly sol in EtOH and EtzO. SYNS: BERYLLIUM ACETATE, BASIC 0 BERYLLIUM OXIDE ACETATE 0 HEXAKISgl-ACETATO-O:O?-y4OXOTETRABERYLLIUM 0 HEXAKIS(pACETATO)-k40XOTETRABERYLLIUR.f CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be) /m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed:
BERYLLIUM SULFATE (1:l)
TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Berylhum) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen. See BERYLLIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of BeO. BFT750 CAS: 63990-88-5 HR: 3 BERYLLIUM OXYFLUORIDE mfi BeFzOz mw: 79.01 CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community fight-To-Know Lst. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be) /m3 ACGIH TLV: TWA 0.002 mg(Be)/rn'; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen. Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. See also BERYLLIUM COMPOUNDS and FLUORIDES. When heated to decomposition it emits very toxic fumes of B e 0 and F-. BFUOOO CAS: 13597-95-0 HR: 3 BERYLLIUM PERCHLORATE mfi Be(C104)~ mw: 207.91 PROP: Very hygroscopic crystals, sol in water: 148.6 g/100 mL. CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT
BFU250
167
58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72;Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg (Be) / m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: CL not to exceed 0.0005 mg(Be) / m3 SAFETY PROFILE: Confirmed carcinogen. A powerful oxidant used in propellant and igniter systems. When heated to decomposition it emits toxic fumes of C1and BeO. See also BERYLLIUM COMPOUNDS and PERCHLORATES. BFU250 CAS: 13510-49-1 HR: 3 BERYLLIUM SULFATE (1:l) mf: 04S*Be mw: 105.07 PROP: Colorless, tetragonal, hygroscopic crystals. Undergoes polymorphic transitions at 5" and 6". On further heating dissoc without melting to BeO, sos, SOz, and 0 2 crystals. Mp: 550-600' (decomp), d: 2.443. Insol in HzO. SYN: SULFURIC ACID, BERYLLIUM SALT (1:l) CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be) /m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m?; STEL 0.0002
168
BFUSOO
BERYLLIUM SULFATE TETRA-HYDRATE (1:1:4)
mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Berylhum) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. Acute poison by inhalation, ingestion, intraperitoneal, subcutaneous, intravenous, and intratracheal routes. See also BERYLLIUM COMPOUNDS and SULFATES. Mutation data reported. When heated to decomposition it emits very toxic fumes of SO, and BeO. BFUSOO CAS: 7787-56-6 HR: 3 BERYLLIUM SULFATE TETRAHYDRATE (1:1:4) mf: 04S*Be*4HzO mw: 177.15 PROP: Colorless, tetragonal crystals. Decomp on heating with H20 loss. Very sol in H20. SYNS: BERYLLIUM SULPHATE TETRAHYDRATE 0 SULFURIC ACID, BERYLLIUM SALT (l:l), TETRAHYDRATE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72;Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryhum and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) ( s h ) ; Confirmed Human Carcinogen) NIOSH REL: CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data by inhalation. Deadly poison by subcutaneous and intravenous routes. Human mutation data reported. See also BERYLLIUM
COMPOUNDS and SULFATES. When heated to decomposition it emits very toxic fumes of B e 0 and SO,. BFU750 HI?: 3 BERYLLIUM TETRAHYDROBORATE mf: B2BeH8 mw: 38.70 CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community &ght-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen. Ignites and then explodes in air or on contact with water. Upon decomposition it emits toxic fumes of B e 0 and BOX.See also BERYLLIUM COMPOUNDS and BORON COMPOUNDS. BFVOOO HR: 3 BERYLLIUM TETRAHYDROBORATETRIMETHYLAMlNE mfi C3H17BzBeN mw: 97.78 CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds are on the Community Right-To-Know List.
A-BHC OSHA PEL: TWA 0.002 mg(Be)/m3; STEL
0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) ( s h ) ; Confirmed Human Carcinogen) NIOSH REL: CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen. It will ignite in contact with air or water. When heated to decomposition it emits toxic fumes of BeO, BOX,and NO,. See also BERYLLIUM COMPOUNDS and BORON COMPOUNDS.
BFV250 CAS: 39413-47-3 HR: 3 BERYLLIUM ZINC SILICATE mf: OzSi*Zn*Be mw: 134.47 SYN: ZINC BERYLLIUM SILICATE CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Beryllium and its compounds, as well as zinc and its compounds, are on the Community RightTo-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3 SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of B e 0 and ZnO. See also BERYLLIUM COMPOUNDS, ZINC COMPOUNDS, and SILICATES.
BFWSOO
169
BFWOOO HR: 3 BETEL NUT PROP: Mottled brown with fawn color. Extract of 50 g sun-dried betel nut in 100 mL boiling water (IJCNAW 17,469,76). SYNS: ARECA CATECHC ARECA CATECHU Linn., fruit extract 0 ARECA CATECHL! Linn., nut extract 0 BN 0 PINANG 0 POOGIPHALATV, nut extract 0 SUPARI, nut extract CONSENSUS REPORTS: IARC Cancer Review: Animal Limited Evidence IMEMDT 37,141,85. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and neoplastigenic data. Moderately toxic by intraperitoneal route. Experimental teratogenic and reproductive effects. When heated to decomposition it emits toxic fumes of NO,. See also ARECA NUT, other betel entries, and SMOKELESS TOBACCO.
BFWI 25 BETEL QUID EXTRACT
HR: 2
CONSENSUS REPORTS: IARC Cancer Review: Human Inadequate Evidence IMEMDT 37,141,85; Animal Limited Evidence IMEMDT 37,141,85. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data by skin contact. Human mutation data reported. See other betel entries.
BFWI 35 BETEL TOBACCO EXTRACT
HR: 3
SYN: JAFFNA TOBACCO CONSENSUS REPORTS: IARC Cancer
Review: Human Sufficient Evidence IMEMDT 37,141,85; Animal Lmited Evidence IMEMDT 37,141,85. SAFETY PROFILE: Confirmed human carcinogen, Human mutation data reported. See also SMOKELESS TOBACCO and other betel entries.
BFW500 A-BHC mf: C6H&16
CAS: 319-86-8 mW: 290.82
HR: 2
170
BFW750
BHT (food grade)
PROP: Solid. Mp: 129-132'. SYNS: A-BENZENEHEXACHLORIDE
SAFETY PROFILE: Poison by 0 ENT 9,234 0
intraperitoneal and intravenous routes.
l-a,2-a,3-a,4-P,5-a,6-~-HEXACHLOROCYCLOHEXNE 0 Moderately toxic by ingestion. An A-HEXACHLOROCYCLOHEXNE 0 A-1,2,3,4,5,6HEXKHLOROCYCLOHEXANE 0 A-LINDANE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of C1-. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
BFW750 CAS: 128-37-0 HR: 2 BHT (food grade) mf: C15H240 mw: 220.39 PROP: White, crystalline solid; faint characteristic odor. Bp: 265', fp: 68', flash p: 260°F ("OC), d: 1.048 @ 20'/4', vap d: 7.6, mp: 71'. Sol in alc; insol in water and propylene glycol. SYNS: ADVASTAB 401 0 AGIDOL 0 ANTIOXIDANT
experimental teratogen. Other experimental reproductive effects. A human s h n irritant. A skin and eye irritant. Questionable carcinogen with experimental carcinogenic and neoplastigenic data. Combustible when exposed to heat or flame. It can react with oxidizing materials. To fight fire, use COz, dry chemical. When heated to decomposition it emits acrid smoke and fumes. BFXOOO CAS: 613-35-4 HR: 3 4',4"'-BI ACETANILIDE mf: C16H16N202 mw: 268.34 PROP: Solid. Mp: 317'. SYNS: N,iX'-(l,l'-BIPHENYL)-4,4'-DD(LBIS-ACETAMlDE 4',4"'-BIACETANILIDE 0 N,Nt-4,4'-BIPHENYLYLENEBISACETAMIDE 0 4,4'-DIACETYLAMINOBIPHENYL 0 N,V-DLACETYL BENZIDINE 0 4,4'-DIACETYLBENZIDINE
DBPC 0 AIWTIOXIDANT 29 0 A 0 29 0 A 0 4K 0 2,6CONSENSUS REPORTS: IARC Cancer BIS(1,l-DIhlETHYLETHYL)-4-METHYLPHENOL 0 BUKS 0 BUTYLATED HYDROXYTOLUENE 0 BUTYLHYDROReview: Group 2B IMEMDT 7,56,87; XYTOLUENE 0 CAO 1 0 CAO 3 0 CATALIN CAO-3 0 Animal Sufficient Evidence IMEMDT CHEMANOX 11 0 DBMP 0 DBPC (techtucal grade) 0 16,293,78. Reported in EPA TSCA DIBUTYLATED HYDROXYTOLUENE 0 2,6-DI-rertInventory. BCTYL-p-CRESOL (OSHA, ACGIH) 0 2,6-DI-tert-BUTYLSAFETY PROFILE: Suspected carcinogen 1-HYDROXI-4-METHYLBENZENE 0 3,5-DI-tert-BUTYL4-HYDROXYTOLUENE 0 2,6-DI-terc.BUlYL-p-KRESOL with experimental carcinogenic, (CZECH) 0 2,6-DI-tert-BUTYL-p-METHYLPHENOL 0 2,6neoplastigenic, and tumorigenic data. DI-tert-BUTYL-4-METHYLPHENOL 0 FEMA No. 2184 0 Mutation data reported. When heated to 4-HYDROXY-3,5-DI-tert-BUTYLTOLUENE 0 IhfPRLVOL decomposition it emits toxic fumes of NO,. 0 IONOL 0 IONOL (anuoxldant) 0 4-hlETHYL-2,6-DIterc BUTYLFENOL (CZECH) 0 METHYL-DI-tertCAS: 2130-56-5 HR: 2 BUTYLPHENOL 0 4-METHYL-2,G-DI-tert-BUTYLPHEN-BFX250 S,S'-BIANTHRANILIC ACID OL 0 NCI-C03598 0 NONOX TBC 0 PARABAR 441 0 SCSTANE 0 TENOX BHT 0 TOPANOL 0 VANLUBE mf: C~H12N204 mw: 272.28 PCX
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 40,161,86. NCI Carcinogenesis Bioassay Completed; (feed): N o Evidence: mouse, rat NCITR* NCI-CG-TR-150,79. Reported in EPA TSCA Inventory. EPA Genetic Toxicology
Program. OSHA PEL: TLV 10 mg/m3 ACGIH TLV: TLV 10 mg/m3; Not
Classifiable as a Human Carcinogen
PROP: Needles. Mp: 300'. SYNS: 3,3'-BENZIDINEDICARBOXYLIC ACID 0 4,4'-
DIAMINOBIPHENYL-3,3'-DICARBOXYLIC ACID 0 4,4'DIAMINO-3,3'-BIPHENYLDDICARBOXYLIC ACID 0 3,3'DICARBOX3T3ENZIDI;\jE 0 KW-AS BENZYDYNODWLTKAROKSYLOWY(POLISH)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Questionable
carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
BIPHENYL
BFXSOO CAS: 103-29-7 HR: 3 BIBENZYL mf: C14H14 mw: 182.28 PROP: Flash p: 264'F, autoign temp: 896'F, d: 1.0, vap d: 6.29, bp: 284', mp: 52'. SYNS: DIBENZYL 0 1,2-DIPHENKETHANE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous
route. Moderately toxic by intraperitoneal route. Combustible. To fight fire, use water, spray, mist, alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
BGA750 CAS: 1464-53-5 HR: 3 1,l'-BI(ETHYLENE OXIDE) mf: C4H602 mw: 86.10 PROP: Colorless liquid. Bp: 142', mp: 19', d: 1.113 @ 18'/4'. SYNS: BIOXIRANE 0 2,2'-BIOXIRANE 0 BUTADIEN DIOXYD (GERMAN) 0 BUTADIENE DIEPOXIDE 0 1,3BUTADIENE DIEPOXIDE 0 BUTADIENE DIOXIDE 0 BUTANE DIEPOXIDE 0 DEB 0 DIEPOXYBUTANE 0 2,4-DIEPOXYBUTANE 0 1,2:3,4-DIEPOXYBUTANE 0 DIOXYBUTADIENE 0 ENT 26,592 0 ERYTHRITOL ANHYDRIDE 0 RCRA WASTE NUiMBER U085 CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. EPA Extremely Hazardous Substances List. EPA Genetic Toxicology Program. Community Right-To-Know List. Reported in EPA TSCA Inventory. SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. Poison by ingestion, inhalation, skin contact, and intraperitoneal routes. Human mutation data reported. A severe s h n and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
BGC250 CAS: 69382-20-3 HR: 3 BINDON ETHYL ETHER mf: C2oH1403 mw: 302.34 SYNS: BINDON ATHYLATHER 0 2-(3-ETHOXY-lINDANYLIDENE)-1,3-DINDANDIONE
SAFETY PROFILE: Poison by
intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it
BGEOOO 171
emits acrid smoke and irritating fumes. See also ETHERS.
BGD088 CAS: 205943-18-6 HR: 3 BIOREX mf: C Z ~ H ~ ~ C ~ Z N O ~C8H10* ~C~~H~OOS~ C S H ~ N O * C ~ H ~ Omw: ~ 1062.24 SYN: CYCLOPROPANECARBOXC ACID, 3-(2,2DICHLOROETHENYL)-2,2-DIMETHYL-, CYANO(3PHENOXYPHENYL)METHYL ESTER, MIXED WITH ACETIC ACID ANHYDRIDE, 5-((2-(Z-BUTOXYETHO~
ETHOXY)METHYL)-6-PROPYLn-l,3-BENZODIOXOLE, DIMETHYLBENZENE AND 1-METHYL 2-PYRROLIDIN ONE
SAFETY PROFILE: A poison by ingestion.
When heated to decomposition it emits toxic vapors of NO, and C1-.
BGD100 CAS: 58-85-5 HR: D BIOTIN mf: C I I I H I G N ~ ~ ~ S mw: 244.31 PROP: White crystalline powder or fine long needles. Mp: 232-233'. Sltly sol in water, alc; insol in common org solvs. SYNS: BIOEPIDERM 0 BIOS I1 0 (+)-BIOTIN 0 dBIOTIN 0 D-BIOTIN 0 D-(+)-BIOTIN 0 COENZYME R 0 FACTOR S 0 FACTORS (VITAMIN) 0 VITAMIN B7 0 VITAMIN H CONSENSUS REPORTS: EPA TSCA Chemical Inventory, JUNE 1993. SAFETY PR0FI LE : Experimental reproductive effects. When heated to decomposition it emits toxic fumes of NO,,
so,.
BGEOOO CAS: 92-52-4 HR: 3 BIPHENYL mf: ClzHlo mw: 154.22 PROP: Monoclinic, whlte scales, with a pleasant odor. Mp: 71°, bp: 255", flash p: 235'F (CC), d: 0.991 @ 75'/4', autoign temp: 1004'F, vap d: 5.31, lel: 0.6% @ 232', uel: 5.8% @ 331'F. IDLH 100 mg/m3. SYNS: BIBENZENE 0 1,l'-BIPHENYL 0 DIPHENYL (OSHA) 0 LEMONENE 0 PHENADOR-X 0 PHENYLBENZENE 0 PHPH 0 XENENE
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory, Community Rtght-ToKnow List. OSHA PEL: TWA 0.2 ppm
172
BGJ250 2-BIPHENYLOL
ACGIH TLV: TWA 0.2 ppm DFG MAK: 0.16 ppm (1 mg/m3) SAFETY PROFILE: Poison by intravenous
heated to decomposition it emits acrid smoke and irritating fumes.
route. Moderately toxic by ingestion. A powerful irritant by inhalation in humans. Human systemic effects by inhalation of very small amounts: flaccid paralysis, nausea or vomiting, and other unspecified gastrointestinal effects. Questionable carcinogen with experimental tumorigenic and neoplastigenic data. Mutation data reported. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use COz, dry chemical, water spray, mist, fog. When heated to decomposition it emits acrid smoke and fumes.
BGJSOO CAS: 92-69-3 HR: 3 4-BIPHENYLOL mf: ClzHloO mw: 170.22 PROP: Needles or plates from EtOH (ad. Mp: 164-1 65O, bp: 305-308'. SYNS: p-HYDROXYBIPHENYL 0 4-
BGJ250 CAS: 90-43-7 "R: 3 2-BIPHENYLOL mf: ClzHloO mw: 170.22 PROP: Needles from pet ether. Mp: 56O, bp: 275'. SYNS: o-BIPHENYLOL 0 (1,1t-BIPHENYL)-2-OL0 oDIPHENYLOL 0 DOWCIDE 1 0 DOWCIDE 1 ANTIMICROBIAL 0 2-HYDROXYBIFENYL(CZECH) 0 o-HYDROXYBIPHENYL 0 2-HYDROXYBIPHENYL 0 oHYDROXYDIPHENYL 2-HYDROXYDIPHENYL 0 KIWI LC'STR 277 0 XCI-C50351 0 OPP 0 ORTHOHYDROXYDIPHENYL 0 ORTHOPHENYL-PHENOL 0 ORTHOXENOL 0 o-PHENYLPHENOL 0 2-PHENYLPHENOL 0 PREVENTOL 0 EXTRA 0 REMOL TRF 0 TETROSIN OE 0 TORSITE 0 TUMESCAL OPE 0 USAF EK-2219 0 o-XENOL
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IhIEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 30,329,83; NTP Carcinogenesis Studies (dermal); No Evidence: mouse NTPTR* NTP-TR-301,86. Reported in EPA TSCA Inventory. On Community Right-To-Know List. SAFETY PROFILE: A poison by intraperitoneal route. Moderately toxic by ingestion and possibly other routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. Severe eye and moderate skin irritant. Questionable carcinogen with experimental carcinogenic data. When
HYDROXYBIPHEXYL 0 p-HYDROXYDIPHENYL 0 4HYDROXYDIPHEKYL 0 PARAXENOL 0 pPHENYLPHENOL 0 4-PHENYLPHENOL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Acute poison by intraperitoneal route. Questionable carcinogen with experimental carcinogenic and tumorigenic data. When heated to decomposition it emits acrid, irritating fumes.
BGJ750 CAS: 132-27-4 HR: 3 2-BIPHENYLOL, SODIUM SALT mf: C12H90*Na mw: 192.20 SYNS: BACTROL 0 (l,l'-BIPHENYL)-2-OL,SODIUM SALT 0 D.C.S. 0 DORVICIDE A 0 DOWICIDE 0 DOWICIDE A 0 DOWICIDE A & A FLAKES 0 DOWIZID A 0 2-HYDROXYBIPHENYL SODIUM SALT 0 2-HYDROXYDIPHENYL SODICM 0 2-HYDROXYDIPHENYL, SODIUM SALT 0 MIL-DU-RID 0 MYSTOX WFA 0 NATRIPHENE 0 OPP-Na 0 OPP-SODIUM 0 ORPHENOL 0 PHENOL, o-PHENYL-,SODIUM denv. 0 o-PHENYLPHENOL, SODIUM SALT 0 2-PHENYLPHENOL SODIUM SALT 0 PREVENTOL-ON 0 PREVENTOL ON & ON EXTRA 0 SODIUM 2BIPHENYLOLATE 0 SODIUM (1,l'-BIPHENYL)-2-OUTE 0 SODIUM, (2-B1PHENYLYLOXY)-0 S0DIU;LI 2HYDROXYDIPHENYL 0 SODIUM ORTHO PHENYLPHENATE 0 SODIUM o-PHENYLPHENATE 0 SODIUM 2-PHENYLPHENATE 0 SODIVM oPHENYLPHENOL 0 SODIUM o-PHENYLPHENOLATE 0 SODIUM o-PHENYLPHENOXIDE 0 SOPP 0 STOPMOLD B 0 TOPANE
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 30,329,83. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data.
BIRCH TAR OIL BG0750
Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. A human sktn irritant. A severe skin irritant to experimental animals. When heated to decomposition it emits toxic fumes of Na2O. See also 2-BIPHENYLOL. BGK5OO CAS: 91-95-2 HR: 3 3,3',4,4'-BIPHENYLTETRAMINE mf: C12H14N4 mw: 214.30 PROP: Crystals from MeOH. Mp: 178-179'. SYNS: 3,3'-DIAMINOBENZIDENE 0 3,3',4,4'DIPHENYLTETRrtMINE BIPHENYL
3,3',4,4'-TETIINO-
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic data. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also AROMATIC AMINES.
BGK750 CAS: 7411-49-6 HR: 3 3,3',4,4'-BIPHENY LTETRAMINE TETRAHYDROCHLORIDE mf: ClzH14N4*4ClH mw: 360.14 PROP: Crystals. Sol in acids. SYNS: 3,3'-DIAMINOBENZIDINETETRAHYDROCHLORIDE 0 3,3',4,4'-TETlUAJMINOBIPHEXYL TETRAHYDROCHLORIDE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Suspected carcinogen with experimental neoplastigenic and tumorigenic data. Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of HC1 and NO,. See also AROMATIC AMINES.
BGM100 CAS: 37940-57-1 HR: 3 4-BIPHENYLYL ETHYLKETONE mf: C15H140 mw: 210.29
173
SYNS: KETONE, 4-BIPHENYLETHYL 4PHENYLPROPIOPHENONE PROPIOPHENONE, 4'PHENYL DOT CLASSIFICATION: 3; Label:
Flammable Lquid SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating vapors.
BG0500 CAS: 366-18-7 HR: 3 2,2'-BIPYRIDINE mf: CloHgN2 mw: 156.20 PROP: White crystals or prisms from pet ether. Mp: 69.7', bp: 272-273'. Sol in H20, EtOH, Et20, C6H6, CHCl3, and dilute acids. SYNS: BIPYRIDINE a,a'-BIPYRIDINE 0 a,a'BIPYRIDYL 0 2,2'-BIPYRIDYL 0 2,2'-BYPYRIDIN 0 CI588 cz,a'-DIPYRIDYL 0 2,2'-DIPYRIDYL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion,
subcutaneous, and intraperitoneal routes. Experimental teratogenic data. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. BG0750 CAS: 8001-88-5 HR: 2 BIRCH TAR OIL PROP: Brown liquid; leather-like odor. D: 0.886-0.950. Found in the tar of the bark and wood of Betzllapendzlla Roth (Fam. Betzrlaceae) and prepared by steam dlstillation of the tar obtained by dry dtsdlation of the bark and wood (FCTXAV 11,1011,73). Sol in fixed oils; insol in glycerin, mineral oil, and propylene glycol. SYN: BIRCH TAR OIL, RECTIFIED (FCC) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: A skin irritant. Moderately irritating to eyes and mucous membranes. A mild allergen. Combustible when exposed to heat or flame; can react with oxidlzing materials.
174
BGP250 2,7-BIS(ACETAMIDO)FLUORENE
BGP250 CAS: 304-28-9 HR: 3 2,7-BIS(ACETAMIDO)FLUORENE mf: C17H16N202 mw: 280.35 SYNS: 2,7-DIACEThhlIDOFLUORENE 0 2,7DIACETYLAhlINOFLUORENE 0 2,7-FAA 0 N,N'FLUOREN-2,7-YLBISACETA\4IDE 0 2,7FLUORENYLBISACETAhiIDE 0 N,N'-FLUOREN-2,7YLESEBISACETAMIDE 0 N,N'-2,7-FLUORENYLE&EBISACETAhlIDE 0 N,N'-(FLUOREN-2,7YLENE)BIS(ACETYLAMlNE) 0 N,N1-2,7-FLUORENYLENEDIACETAMIDE
CONSENSUS REPORTS: EPA Genetic
Toxicology Program. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. BGQOOO CAS: 5967-09-9 HR: 3 BIS(ACETOXYDIBUTY LSTANNANE) OXIDE mf: C20H4205Sn2 mw: 600.00 SYNS: BIS(DIBUTYLACET0XYTIN)OXIDE 0 DIACETOXYTETRABUTYLDISTANNOXANE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (sku?) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (shn). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by intravenous route. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
BGTOOO CAS: 28434-86-8 HR : 3 BlS(4-AMINO-3-CHLOROPHENYL) ETHER mf: C12H10C12N20 mw: 269.14 SYNS: 3,3'-DICHLOR-4,4'-DIINO-DIPHENYLAETHER (GERMAN) 0 3,3'-DICHLORO-4,4'DIAhlINODIPHENYL ETHER 0 4,4'-0XYBIS(2CHLOROANILINE) 0 4,4'-OXYBIS(2-CHLOROBENZENAMINE)
CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 16,309,78.
SAFETY PROFILE: Suspected carcinogen
with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of C1and NO,. See also ETHERS. BGT250 CAS: 314-13-6 HR: 3 4,4'-BIS(1-AMINO-8-HYDROXY-PY4DISULFO-7-NAPHTHYLAZO)-3,3'BITOLYL, TETRASODIUM SALT mf: C34H24N6014S4*4Na mw: 960.84 PROP: Blue crystals with brownlgreen luster. Sol in HzO, EtOH, acid, and alkalies. SYNS: 4,4'-BIS(7-(1-rZI\lINO-8-HYDROXY-2,4-DISULFO)NAPHTHYLAZO)-3,3' -BITOLYL, TETRASODIUM SALT 0 4,4'-BIS(l-A\lINO-8-HYDROXY-2,4-DISULPHO-7NAPHTHYLAZO)-3,3'-BITOLYL, TETRrlSODIUM SALT 0 BLEKIT EVANSA POLISH) 0 CHLORAZOL SKY BLUE FF 0 C.I. 23860 0 C.I. DIRECT BLUE 53 0 DIAMINE SKY BLUE FF 0 DIAZOBLEU 0 DMZOL PURE BLUE FF 0 DYE EVANS BLUE 0 EB 0 EVABLIX 0 EVASS BLUE DYE 0 GEIGY-BLAU 536 0 T 1824
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 8,151,75. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by intravenous route. An experimental teratogen. Other experimental reproductive effects. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of SO,, Na20, and NO,.
BGU6OO CAS: 7300-34-7 HR: 3 1,4-BIS(3-AMINOPROPOXY)BUTANE mf: C12H24N202 mw: 228.38 SYNS: 1,4-BIS(y-AVINOPROPOXY)BUTAXE 0 1,4BUTANEDIOL BIS(3-AhIINOPROPYL) ETHER 0 a,OMEGA-DIAiilINO-4,9-DIOXhDODECANE 0 1,12DIAMINO-4,9-DIOXADODECANE 0 4,9-DIOXh-1,12DIAMINODODECANE 0 4,9-DIOXADODECANE-l,12DIAMINE 0 I-PROPANAMINE, 3,3'-(1,4-BUTANEDIYLBIS(0XY))BIS- 0 PROPYLAMINE, 3,3'-pETRAMETHYLENEDI0XY)BIS- 0 3,3'-(TETRAMETHYLENEDIOXY)BIS(l'ROPYLAMINE) 0 3,3'-(TETRAMETHYLENEDIOXu)DI(PROPANAMINE)
BIS(2-BENZOTHIAZOLYLTHI0)ZINC BHA750
175
SAFETY PROFILE: A poison by skin contact. Moderately toxic by ingestion and inhalation. When heated to decomposition it emits toxic vapors of NO,.
SAFETY PROFILE: Poison by intraperitoneal route. An eye irritant. When heated to decomposition it emits toxic fumes of SO, and C1-.
BGU750 CAS: 105-83-9 HR: 3 BIS(yAMINOPR0PY L)METHYLAMINE mf: C7H19N3 mw: 145.29 PROP: Liquid, completely miscible in water. D: 0.9307 @ 2Oo/2O0, bp: 240.6', fp: -29.6', flash p: 220OF. SYNS: BIS(~-AMINOPROPYL)METHYLAMINE 0
BGY700 CAS: 1271-54-1 HR: 3 BIS-BENZENECHROMIUM mfi ClzH12Cr mw: 208.24 PROP: Aw-sensitive brown-black crystals. Mp: 284-285'. sol h C6H6; Sldy Sol in EtzO. IDLH 250 mg/m3 [as Cr(II)]. SYNS: CHROMIUM, BIS(BENZENE)-(BCI) 0
BIS(3-AMINOPROPn)~~ETHYL;LMINE 0 N,N-BIS(yAhUNOPR0PYL)METHYLAMLAMINE 0 N,N-BIS(SA M I N O P R 0 P Y L ) M E T H Y I N E 0 3,7'-DIAMINO-NMETHYLDIPROPU34INE 0 METHYLBIS(3AMINOPR0PX)AMISE
CHROMIUM, BIS(eta6)-BENZENE)-(9CI) CHROMIUM(lI), DIPHENYL 0 DIBENZENECHROMIUM 0 DIPHENYLCHROMIUM
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by inhalation and s h n contact. Moderately toxic by ingestion. A skin and severe eye irritant. See also M I N E S . Combustible when exposed to heat or flame. To fight fire, use foam, fog, dry chemical. When heated to decomposition it emits toxic fumes of NO,.
BGVOOO CAS: 7209-38-3 HR: 3 1,CBIS(AMINOPROPYL)PIPERAZINE mf: C I O H X N ~ mw: 200.38 SYN: BIS(AMINOPR0PYL)PIPEMZINE (DOT) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. A corrosive material and a powerful irritant to shn, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of NO,. BGW100 CAS: 3426-43-5 HR: 3 ~,~'-BIS(((~-ANILINO-~-METHOXY-STRIAZIN-2-YL)AMINO)-2,2'STILBENEDISULFONIC ACID) DlSODlUM SALT mfi C34Hz8N1oOsSzo2Na mw: 814.82 SYN DISODICTM-4,4'-BIS((/I-~ILIN0-6-RIETHOXY-sTRIAZIN-2-YL)AMINO)STILBENE-2,2'-DISULFONATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
OSHA PEL: TWA 0.5 mg(Cr)/m3 ACGIH TLV: TWA 0.5 mg(Cr)/m'; Not Classifiable as a Carcinogen SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of Cr. BGY720 CAS: 12089-29-1 HR: 3 BIS(BEN2ENE)CHROMIUMIODIDE mf: CIzH12Cr*I mw: 335.14 PROP: Light-sensitive, air-stable yellow solid. Sol in Hz0 and EtOH. IDLH 25 mg/m3 [as Cr(III)]. SYNS: BIS(BENZENE)CHROMIUiM(I+)IODIDE 0 CHROMIUM(l+), BIS(BENZENE)-,IODIDE (8CI) 0 (CHROMIUM(l+).BIS(eta')-BENZENE)-, IODIDE (9CI) 0 CHROMIUM,BIS(BENZENE)IODO- 0 CHROMIUhI(III), DIPHENYL, IODIDE 0 DIBENZENECHROMIUM IODIDE 0 DlPHENYLCHROMIUM(l1I) IODIDE
OSHA PEL: TWA 0.5 mg(Cr)/m3; Not
Classifiable as a Carcinogen ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not Classifiable as a Carcinogen; Proposed:
(inhalable fraction) 0.1 mg/m3; Not Classifiable as a Human Carcinogen) SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of Cr and I-. BHA750 CAS: 155-04-4 HR: 3 BIS(2-BENZOTHIAZOLYLTHI0)ZINC mf: C I ~ H ~ N Z S ~ mw: ~ Z ~397.85 SYNS: 2-BENZOTHIAZOLETHIOL, ZINC SALT (2:l) 0 BIS(MERCAPTOBENZOTHIAZOLATO)ZINC 0 HEfiLAT
0
176
BHBOOO BIS(2-BENZOYLBENZOA T0)BIS
Zn-MBT 0 2-MERCAPTOBENZOTHIZOLE ZINC SALT 0 OXAF 0 PENNAC ZT 0 TISPERSE 1MB-58 0 USAF GY7 0 WLKACIT ZM 0 ZENITE 0 ZENITE SPECIAL 0 ZETAX 0 ZINC-2-BENZOTHUZOLETHIOLATE 0 ZINC BENZOTHIAZOLYLMERCAPTIDE 0 ZINC BENZOTHIAZOL2-YLTHIOLATE 0 ZINC BENZOTHIAZYL-2-MERCAPTIDE 0 ZINC MERCAPTOBENZOTHIAZOLATE 0 ZINC-ZMERCAPTOBENZOTHIAZOLE 0 ZINC MERCAPTOBENZOTHIAZOLE SALT 0 ZMBT 0 ZmMB
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Zinc compounds are on the Community kght-To-Know List. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits very toxic fumes of SO,, NO,, and ZnO. See also ZINC COMPOUNDS and MERCAPTANS.
BHBOOO CAS: 64092-23-5 HR: 3 BIS(2-BENZOYLBENZOATO)BIS(3-(1METHYL-2PYRR0LIDINYL)PYRIDINE) NICKEL TRIHYDRATE mf: C48H4&Ni06*3H20 mw: 887.75 PROP: IDLH Ca [lo mg/m3 (as Ni)]. SYN: NICOTINE, COMPOUND,with NICKEL@)-oBENZOYL BENZOATE TRIHYDRATE (2:l) CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. Nickel and its compounds are on the Community Rtght-To-Know List. OSHA PEL: TWA 0.1 mg(Ni)/m3 ACGIH TLV: TWA 0.1 mg(Ni)/m3; Not Classifiable as a Carcinogen NIOSH REL: (Inorganic Nickel) TWA 0.015 mg(Ni)/m3 SAFETY PROFILE: Confirmed Human Carcinogen. Poison by ingestion and intraperitoneal routes. See also NICKEL COMPOUNDS and NICOTINE. When heated to decomposition it emits toxic fumes of NO,.
BHB950 CAS: 4028-32-4 HR: 1 4,4'-BIS((4-BIS((2-HYDROXYETHYL)AM INO)-6-CHLORO-S-TRI AZIN-2Y L)AMINO)-2,2'-STILBENEDI-
SULFONIC ACID, DlSODlUM SALT mf: C ~ ~ H ~ O C ~ ~ N I O O I O mw: S~*~N~ 847.68 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: An eye irritant. When heated to decomposition it emits toxic fumes of NO,, SO,, and C1-. BHK250 CAS: 15546-16-4 HR: 3 BIS(BUTOXYMALE0YL0XY)DIBUTY LSTANNANE mf: C24H4008Sn mw: 575.33 SYNS: DI-N-BUTYLTINDI(M0NOBUTYL)MALEATE 0 DI-N-BUTn-ZINN-DI(MONOBUTYL)MALEINAT
(GERMAN)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (slun) ACGlH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
BHK5OO CAS: 29575-02-8 HR: 2 BIS(BUTOXYMALE0YL0XY)DIOCTY LS TANNANE mf: C32H5608Sn mW: 687.57 SYNS: DI-N-OCTYLTIN BIS(BUTYL MALEATE) 0 DIN-OCTYLTIN DIMONOBUTYLiMALEATE 0 DI-NOCTYLZINN-DIMONOBUTYLMALEINAT(GERMAN) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (sktn) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Moderately toxic by ingestion. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
trans-N,N-BIS(2-CHLOROBENZYL)-1,4-CYCLO
BHL100 CAS: 25155-25-3 HR: 1 u-a'-BIS(tert-6UTYLPEROXY)DIISOPROPYLBENZENE mf: CzoH3404 mw: 338.54
BHNOOO
177
it emits toxic fumes of SO,. See also SULFIDES.
ETHYLIDENE))BIS(l,l-DIMETHYLETHYLETHYL)0 PEROXIDE, (PHENYLENEDIISOPROPYLIDENE)BIS(tert BUTYL)- 0 pHENYLENEDIISOPROPYLIDENE)BIS(tertBUTYLPEROXIDE) 0 VUL-CUP 0 WL-CUP 40KE 0
BHM750 CAS: 94-17-7 HR: 2 BIS(pCHLOROBENZ0YL) PEROXIDE mf: C~HaC1204 mw: 311.12 PROP: A whte, granular material. Insol in water; sol in org solvs.
WL-CUP R
SYNS: CADPX PS 0 p-CHLOROBENZOYLPEROXIDE
CONSENSUS REPORTS: Reported in EPA
(DOT 0 p,p'-DICHLOROBENZOYLPEROXIDE CHLOROBENZOYL)PEROXIDE
SYNS: PEROXIDE, pHENYLENEBIS(1-METHY-
TSCA Inventory. SAFETY PROFILE: A skin irritant. When
heated to decomposition it emits acrid smoke and irritating fumes.
DI-(4-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
SAFETY PROFILE: Moderately toxic by intraperitoneal route. Probably an irritant to s h n and mucous membranes. Dangerous BHL800 CAS: 58705-49-0 HR: 3 fire hazard; a powerful oxidizer. Store in a 2,3-BIS(CARBOMETHOXYMERCAPT0)cool place away from fire hazards, sparks, QUINOXALINE open flames, and out of the direct rays of mf: C I ~ H I O N Z O ~ S Zmw: 310.36 the sun. Dangerous explosion hazard; this SYNS: AI3-25722 0 CARBONIC ACID, DITHIODI-, o,o'material may explode by heat (over 38') or DIMETHYL S,S'-(2,3-QUINOXALINEDIYL) ESTER 0 CARBONOTHIOICACID, S,S'-2,3-QUINOXALINEDIYL contamination. Any contaminant that acts as o,o'-DIMETHYL ESTER 0 CARBONIC ACID, THIO-, o,o'an accelerator to the polymerization or DIMETHYL S,S1-2,3-QUINOXALINEDIYL ESTER 0 decomposition of this material can cause an CARBONIC ACID, THIO-, 0-METHYL ESTER, S,SDIESTER WITH 2,3-QUINOXALINEDITHIOL 0 o,olexplosion. Heat or contact with certain DIMETHYL S,S'-2,3-QUINOXALINEDIYL fumes or mists can cause it to explode. To THIOCARBONATE 0 SAS 2185 fight small fires, use C02 or foam SAFETY PROFILE: A poison by extinguishers. Water spray or mist may also intravenous route. When heated to be used. Dry chemical is effective. When decomposition it emits toxic vapors of NO, heated to decomposition it emits toxic and SO,. fumes of C1-. See also PEROXIDES, ORGANIC. BHMOOO CAS: 111-17-1 HR: 3 BIS(2-CARBOXYETHYL) SULFIDE BHNOOO CAS: 366-93-8 HR: 3 mf: C6H1004S mw: 178.22 trans-N,N'-BIS(2-CHLOROBENZYL)-l,4PROP: Very sol in alc, hot water, acetate; CYCLOHEXAN EBIS(METHYLAMINE) sltly sol in water. Mp: 134'. DIHYDROCHLORIDE SYNS: DIETHYL SULFIDE-2,2'-DICARBOXYLIC ACID
0 KYSELINA-P,~'-THIODIPROPIONOVA (CZECH) 0 TDPA 0 2-(2,3,5,6-TETRAMETHYLPHENOXY)PROPIONIC ACID 0 4-THIAHEITANEDIOIC ACID 0 THIODIPROPIONIC ACID 0 P,!3'-THIODIPROPIONIC ACID 0 3,3'-THIODIPROPIONICACID 0 TYOX A
mf: C Z Z H Z ~ C ~ Z N Z * ~ C mw: ~ H464.34 SYNS: AY 9944 0 trans-l,4-BIS(2-DICHLOROBENZYLAMINOETHYTJCYCLOHEXANE DICHLORHYDRATE (FRENCH) 0 uans-N~"-(l,CCYCLOHEXYLENE-
DIMETHYLENE)BIS(2-CHLOROBENZ~hfINE) DIHYDROCHLORIDE
CONSENSUS REPORTS: Reported in EPA
SAFETY PROFILE: Poison by ingestion.
TSCA Inventory.
Experimental teratogenic and reproductive effects. Inhibits cholesterol synthesis. When heated to decomposition it emits very toxic fumes of NO, and C1-.
SAFETY PROFILE: A poison by
intraperitoneal and intravenous routes. Moderately toxic by ingestion. A skin and eye irritant. When heated to decomposition
178
BHN750
BIS-P-CHLOROETHYLAMINE
BHN750 CAS: 334-22-5 HR: 3 BIS-PCHLOROETHYLAMINE mf: C4HsClzN mw: 142.04 SYNS: N,N-BIS-~-CHLORAETHYL)-A~~lN (GERMAN) 0 NH-LOST 0 NOR-NITROGEN MUSTARD 0 NSC-
10873
SAFETY PROFILE: Poison by
intraperitoneal, subcutaneous, and intravenous routes. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic NO, and Cl-. BH0250 CAS: 821-48-7 HR: 3 BIS(2-CHLOROETHYL)AMINE HYDROCHLORIDE mf: C4HsC12N*ClH mw: 178.50 SYNS: BIS(P-CHLOR0ETHYL)AMINEHYDROCHLORIDE 0 N,N-BIS(2-CHLOROETHYL)AMINE HYDROCHLORIDE 0 BIS(2-CHLOR0ETHYL)AMMONIUM CHLORIDE 0 2-CHLORO-N-(2CHLOR0ETHYL)ETHANAMINEHYDROCHLORIDE 0 P$'-DICHLORODIETHYLAMINE HYDROCHLORIDE 0 2,2'-DICHLORODIETHYLAMlNE HYDROCHLORIDE 0 DI-2-CHLOROETHYLAMINE HYDROCHLORIDE 0 LEO 72a 0 NC 26 0 NOR-HN2 0 NOR-HN2 HYDROCHLORIDE 0 NOR-LOST HYDROCHLORID (GERMAN) 0 NORNITROGEN MUSTARD HYDROCHLORIDE 0 NSC10873 0 SK 555 0 TL 161
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: A poison by inhalation, intraperitoneal, intramuscular, and subcutaneous routes. An experimental teratogen. Human mutation data reported. When heated to decomposition it emits toxic fumes of NH3, NO,, and C1-.
BH0500 CAS: 1215-16-3 HR: 3 4'4 BIS(2-CHLOROETHYL)AMINO)ACETANILlDE mf: C I ~ H I G C ~ ~ mw: N ~ 275.20 ~ SYNS: p-ACETYLAMINOPHENYL DERIVATIVE of NITROGEN SIUSTARD 0 LONIN 3
SAFETY PROFILE: Poison via intraperitoneal route. An experimental teratogen. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,.
BHP150 CAS: 24813-03-4 HR: 3 1-((BIS(2-CHLOROETHYL)AMINO)BENZ0YL)PIPERIDINE mf: C16H22C12N20 mw: 329.30 SYNS: KETONE, r n - ( ~ 1 ~ ( 2 CHLOR0ETHYL)AMINO)PHENYL PIPERIDINO 0 PIPERIDINE, l-(rn-(EXS(Z-CHLOROETHYL)AMIN0)BENZOYL)-
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by an unspecified route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO, and C1-.
BHP750 CAS: 1492-93-9 HR: 3 4'4 BIS(2-CHLOROETHYL)AMINO)-2FLUORO ACETANILIDE mf: C12HljC12FN20 mw: 293.19 SYN : p-FLL'OROACETYLAMINOPHENYL DERIVATIVE of NITROGEN ML'STARD
SAFETY PROFILE: Poison by intraperitoneal route. An experimental teratogen. When heated to decomposition it emits very toxic fumes of C1-, F-, and NO,.
BHQ760 CAS: 21447-86-9 HR: 3 1434BIS(2-CHLOROETHYL)AMINO-4METHYLBENZOYL)AZIRIDINE) mf: C I ~ H I ~ C ~ ~ Nmw: ~ O301.24 SYNS: AZIRIDINE, 1-(3-(BIS(2-CHLOROETHYL)AMINO-p-TOLU0YL))- 0 KETONE, 1-AZIRIDINYL3(BlS(2-CHLOROETHYL)AMINO)-p-TOLYL
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by an unspecified route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO, and C1-.
BHR400 CAS: 21447-39-2 HR: 3 1-(3-(BlS(2-CHLOROETHYL)AMINO)-4METHYLBENZOYL)MORPHOLINE mf: C16H22C12N202 mw: 345.30 SYNS: KETONE, 3-(BIS(2-CHLOROETHYL)AMINO)-pTOLYL MORPHOLINO- 0 MORPHOLINE, 4-(3-(BIS(2-
CHLOR0ETHYL)AMINO)-p-T0LUOYL)-
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by an
unspecified route. A flammable liquid.
5-(BIS(2-CHLOROETHYL)AMINO)URACIL BIA250
When heated to decomposition it emits toxic vapors of NO, and C1-. BHT750 CAS: 531-76-0 HR: 3 dl-3-(p-(BlS(2-CHLOROETHYL)AMlNO)PHENYL)ALANINE mf: C13H18C12N202 mw: 305.23 PROP: Needles from MeOH. Mp: 180-1 81'.
179
PHENYL MORPHOLINO KETONE mf: C15HzoC12N202 mw: 331.27 DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: A poison by an unreported route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO, and C1-.
SYNS: 3-@-(BIS(2-
BIAl 00 CAS: 21447-87-0 HR: 3 34 BIS(2-CHLOROETHYL)AMINO)-pTOLYL PIPERIDYL KETONE 3307 0 p-DI-(2-CHLORAETHYL)-AMINO-dl-PHENYLmf: C I ~ H Z ~ C ~ Z N mw: ~ O 343.33 ALANIN (GERbIAN) 0 p-DI(2-CHLOR0ETHYL)AMINOSYNS: 1-(3-(BIS(2-CHLOROETHYL)AMINO)-pdl-PHENYLALANINE 0 MERFALAN 0 MERPHALAN CHLOR0ETHYL)AMINO)PHENYL)AJANINE 0 4-(BIS(2CHLOR0ETHYL)AMINO)-dl-PHENYLALANINE 0 CB-
o-hlERPHALAl 0 NCI-C04944 0 NSC-14210 0 PHENYLALANIN-LOST (GERMAN) dl-PHENYLALANINE MUSTARD 0 SAKOLYSIN (GERMAN) SARCOCLORIN 0 dl-SARCOLYSIN dl-SARCOLYSINE
TOLU0YL)PIPERIDINE 0 KETONE, 3-(BIS(2CHLOR0ETHYL)AMINO)-p-TOLYL PIPERIDYL- 0 PIPERIDINE, 1-(3-(BIS(2-CHLOROETHYL)AMINO)-pTOLU0YL)-
DOT CLASSIFICATION: 3; Label:
CONSENSUS REPORTS: IARC Cancer
Flammable Liquid
Review: Group 2B IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 9,167,75; NCI Carcinogenesis Studies (ipr); Clear Evidence: mouse CANCAR 40,1935,77;No Evidence: rat CANCAR 40,1935,77. SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic data. A poison by ingestion, intraperitoneal, intravenous, and intracerebral routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. An antineoplastic agent. When heated to decomposition it emits very toxic fumes of C1- and NO,.
SAFETY PROFILE: A poison by an unreported route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO, and C1-.
BHW3OO CAS: 5185-77-3 HR: 3 2-(p-BlS(2-CHLOROETHYL)AMlNOPHENYL)-l,3,2-DITHIARSENOLANE mf: C I ~ H I ~ S C ~ Z Nmw: S ~ 384.23 SYN: 1,3,2-DITHIARSENOLANE,2-@-BIS(2CHLOR0ETHYL)AMINOPHENYL)-
OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by
intraperitoneal route. When heated to decomposition it emits toxic fumes of NO,, SO,, As, and C1-. BHX3OO CAS: 4587-15-9 HR: 3 m-(BIS(2-CHLOROETHYL)AMINO)-
BIA250 CAS: 66-75-1 HR: 3 5-( BIS(2CHLOROETHYL)AMINO)URACIL mf: C8HllClzN302 mw: 252.12 PROP: Crystals from MeOH (ad. Mp: 206' (decomp). SYNS: AMINOURACIL hlC'STARD 5-(BIS(2CHLOROETHYL)AbfINO)-2,4(1 H,3H)PYRIMIDINEDIONE 0 5-N,N-BIS(2-CHLOROETHYL)AhfINOURACIL 0 CB4835 CHLORETHAMINACIL 0 DEMETHYLDOPAN 0 DESMETHYLDOPAN 0 5-(DI-@CHLOROETHYL)AMIN0)URACIL 5-(DI-2-CHLOROETHYL)AiMINOURACIL 2,6-DIHYDROXY-5-BIS(2-CHLOROETHYL)AMINOPYRAMIDINE 0 ENT 50,439 0 NCI-C04820 NORDOPAN 0 NSC-34462 0 RCRA WASTE NUMBER U237 SK-19849 0 U-8344 0 URACILLOST 0 URACILMOSTAW URACIL MUSTARD 0 URAMUSTIN 0 URAMUSTINE
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,370,87; Animal Sufficient Evidence IMEMDT 9,235,75; NCI Carcinogenesis Stucbes (ipr); Clear Evidence: mouse, rat RRCRBU 52,1,75. EPA Genetic Toxicology Program. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and
180
BIA300
N,N-BIS(2-CHLOROETHYL)-p-ARS-ANILIC ACID
neoplastigenic data. A deadly poison by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,.
or flame. Incompatible with oxidizers. To fight fre, use alcohol foam, foam, COz, dry chemical. When heated to decomposition it emits toxic fumes of C1-. See also CHLORIDES.
BIA300 CAS: 5185-71-7 HR: 3 N,N-BIS(2-CHLOROETHYL)-(>-ARSANlLlC ACID mf: C I O H I ~ A S C ~ ~ N O mw: ~ 342.07 SYN: p-ARSANILIC ACID, N,N-BIS(2-CHLOROETHYL)OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of NO,, As, and C1-.
BID800 CAS: 29023-83-4 HR: 3 9-(2,2-BlS(2-CHLOROETHYL)HYDRAZIN0)ACRIDINE MONOHYDROCHLORIDE mf: C I ~ H I ~ C ~ ~ N ~ *mw: C ~ 370.73 H
BID250 CAS: 538-07-8 HR: 3 BIS(2-CHLOROETHYL)ETHYLAMlNE mf: C6H13C12N mw: 170.10 SYNS: 2,2'-DICHLOROTRIETHYINE 0 ETHYLBIS(P-CHLOR0ETHYL)AMINE ETHYLBIS(2CHLOR0ETHYL)AMINE 0 ETHliL-S 0 HNl 0 TL 329 0 TL 1149
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. SAFETY PROFILE: Deadly poison by inhalation, s h contact, ingestion, intravenous, subcutaneous, and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of C1- and NO,.
BID750 CAS: 111-91-1 HR: 3 BlS(P-CHLOR0ETHYL)FORMAL mf: CsHloClzO2 mw: 173.05 PROP: Liquid. Bp: 217.5', flash p: 230'F (OC), d: 1.23, vap d: 5.9. SYNS: BIS(2-CHLOROETH0XY)METHANE 0 BIS(2CHLOR0ETHYL)FORMAL0 DICHLOROETHYL FORMAL DI-2-CHLOROETHYL FORMAL FORMALDEHYDE BIS(P-CHLOROETHYL)ACETAL 0 1,1'-(METHYLENEBIS(OXY)BIS(2-CHLOROETHANE)) 0 RCRA WASTE NUMBER U024
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion, inhalation, and skin contact. A s h n and eye irritant. Combustible when exposed to heat
SYNS: ACRIDINE, 9-(2,2-BIS(Z-CHLOROETHYL)HYDRAZIN0)-,MONOHYDROCHLORIDE 0 9-(2',2'-BISP-CHLORO-ETHYLHYDRAZIN0)ACRIDINE HYDROCHLORIDE
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO,, HC1, and C1-.
BIE250 CAS: 51-75-2 HR: 3 BlS(P-CHLOR0ETHYL)METHYLAMlNE mf: C5HllC12N mw: 156.07 PROP: Dark liquid. Mp: 1' @ 10 mm, bp: 86-87' @ 11 mm, d: 1.09 @ 25', vap press: 0.17 mm @ 25', vap d: 5.9. Sltly sol in water. SYNS: BIS(2-CHL0ROETHYL)METHYLAhiINE0 N,NBIS(2-CHL0ROETHYL)iMETHYLAMINE CARYOLYSIN CHLORMETHINE 0 CLORAMIN 0 DICHLORAMINE DICHLOREN (GERMAN) p , p t - ~ N-METHYLAMINE 0 DI(2-CHLOR0ETHYL)METHYLAhlINE 0 2,2'-DICHLORO-N-METHYLDIETHYLAMINE EMBICHIN 0 ENT 25,294 0 HN2 iMBA 0 MECHLORETHhhlINE 0 N-METHYL-BISCHLORAETHYLAMIN (GERMAN) 0 METHYLBIS(PCHLOROETHWJAMINE N-METHYL-BIS@CHLOR0ETHYL)AMINE N-METHYI-BIS(2N-METHYL-2,Z'CHLOR0ETHYL)hMINE@AK) DICHLORODIETHYLAMINE hlETHYLDI(2CHLOR0ETHYL)AMINE 0 N-METHYL-LOST 0 MUSTARGEN 0 MUSTINE 0 MUTAGEN 0 NITROGEN hKETARD 0 N-LOST (GERMAN) 0 NSC-762 0 TL 146 0
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. Community Rtght-To-Know List. DFG MAK: Human Carcinogen SAFETY PROFILE: Confirmed human carcinogen producing skin tumors by skin contact. Experimental carcinogenic,
~
~
N,N-BIS(2-CHLOROETHYL)-2-NAPHTH-YLAMlNE BIF250 181
tumorigenic, and neoplastigenic data. A deadly poison by inhalation, ingestion, skin contact, and most other routes. Experimental teratogenic and reproductive effects. A powerful s h n and eye irritant. Human mutation data reported. It has been used as a blistering agent in chemical warfare. When heated to decomposition it emits very toxic fumes of C1- and NO,.
BIE500 CAS: 55-86-7 HR: 3 BIS(2-CHLOR0ETHYL)METHYLAMlNE HYDROCHLORIDE mf: C5HllChN*ClH mw: 192.53 PROP: Leaflets from Me2CO or CHCL. Mp: 119'. SYNS: ANTIMIT 0 AZOTOYPERITE 0
C 6866 0 CAROLYSINE 0 CARYOLYSINE 0 CARYOLYSINE HYDROCHLORIDE 0 CHLORAiMIN 0 CHLORAIMINE 0 CHLORAMIN HYDROCHLORIDE 0 CHLORETHAhfINE 0 CHLORETHAZINE 0 CHLORMETHINE HYDROCHLORIDE 0 CHLORhIETHINUM 0 2-CHLORO-N-(2-
CHLOR0ETHYL)-N-METHYLETHANAMINE
0 NSC-762 HYDROCHLORIDE 0 PLIVA 0 STICKSTOFFLOST 0 ZAGREB
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2A IMEMDT 7,269,87; Animal Sufficient Evidence IMEMDT 9,193,75. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Deadly poison by ingestion, intravenous, subcutaneous, intraperitoneal, and parenteral routes. Experimental teratogenic and reproductive effects. Human systemic effects by intravenous route: nausea or vomiting, reduction in the number of whte blood cells and blood platelets. Other experimental reproductive effects. Human mutation data reported.
BIF250 CAS: 494-03-1 HR: 3 N,N-BIS(2-CHLOROETHYL)-2-NAPHTHYLAMINE mf: C I ~ H I S C ~ ~ Nmw: 268.20 PROP: Platelets from pet ether. Mp: 54-56', bp: 210' @ 5 mm.
HYDROCHLORIDE 0 D E M 0 DICHLOREN 0 DICHLOREN HYDROCHLORIDE 0 P,W-DICHLORODIETHYL-N-METHYLAMINE HYDROCHLORIDE 0 DI(2-CHLOROETHYL)iMETHYLAMINE HYDROCHLORIDE 0 1,5-DICHLORO-3-METHY3SYNS: 2-BIS(2AZAPENTANE HYDROCHLORIDE 0 2,2'-DICHLORO-NCHLOR0ETHYL)AMINONAPHTHALENE 0 BIS(2METHYLDIETHUVINE HYDROCHLORIDE 0 CHLOROETHYL)-P-NAPHTHYLAMINE 0 CHLORDIMITAN 0 EMBECHINE 0 EhlBICHIN 0 EMBICHIN NAFTINA CHLORNAPHAZIN 0 CHLORNAPHTHIN HYDROCHLORIDE 0 EMBIKHINE 0 ERASOL 0 0 CHLORONAFTINA 0 CHLORONAPHTHINE 0 ERASOL HYDROCHLORIDE 0 ERASOL-ID0 0 CLORNAPHAZINE 0 DICHLOROETHYLPHN2.HC10 HN2 HYDROCHLORIDE 0 KLORAhIIN 0 NAPHTHYLAMINE 0 DI(2-CHLOROETHYL)-PN-LOST 0 MBA HYDROCHLORIDE 0 NAPHTHYLAMINE 0 N,N-DI(2-CHLOROETHYL)-PMEBICHLORAMINE 0 MECHLORETHAA4INE NAPHTHYLAMINE 0 2-N,N-DI(2-CHLOROETHYL)HYDROCHLORIDE 0 MERCHLORETHANAMINE 0 NAPHTHYLAMINE 0 ERYSAN 0 NAPHTHYLAMINE METHYLBIS(P-CHLOR0ETHYL)AMINEHYDROCHLORIDE 0 N-METHYL-BIS-P-CHLORETH~~~INE MUSTARD 0 P-NAPHTHYL-BIS-(P-CHLOR0ETHYL)AMINE 0 2-NAPHTHYIBIS(2-CHLOROETHYL)A\IINE HYDROCHLORIDE 0 METHYLBIS(2-CHLORO0 P-NAPHTHYL-DI-(2-CHLOROETHYL)AMINE 0 NSCETHYL)AMINE HYDROCHLORIDE 0 N-METHYLBIS(262209 0 R48 0 RCRA WASTE NUhBER U026 CHLOR0ETHYL)AMINEHYDROCHLORIDE 0 NMETHYL-2,2'-DICHLORODIETHYLAMINE HYDROCONSENSUS REPORTS: IARC Cancer CHLORIDE 0 N-METHYL-DI-2-CHLOROETHYLAMINE Review: Group 1 IMEMDT 7,130,87; HYDROCHLORIDE 0 hIETHYLDI(P-CHLOROAnimal Sufficient Evidence IMEMDT ETHYL)AMINE HYDROCHLORIDE 0 METHYLDI(24,119,74; Human Sufficient Evidence CHLOR0ETHYL)AMINEHYDROCHLORIDE 0 IMEMDT 4,119,74. EPA Genetic MITOXINE 0 N-MUSTARD (GERMAN) 0 MUSTARGEN Toxicology Program. iMLTSTrlRGEN HYDROCHLORIDE 0 AKSTINE HYDROCHLOR o MUSTINE HYDROCHLORIDE n NCISAFETY PROFILE: Confirmed human C56382 0 NITOL 0 NITOL "TAKEDA" 0 NITROGEN carcinogen producing bladder tumors. MUSTARD HYDROCHLORIDE 0 NITROGRANULOGEN Human and experimental carcinogenic data. 0 NITROGRANULOGEN HYDROCHLORIDE 0 NSC-762
Moderately toxic by intraperitoneal route.
182
BIF750
N,N-BIS(2-CHLOROETHYL)-N-NITROSOUREA
When heated to decomposition it emits very toxic fumes of C1- and NO,.
p: 221’F, d: 1.2741 @ 20°/4’, vap d: 5.4, vap press: 0.09 mm @ 30’. SYNS: BIS(~-CHLOROETHYL)SULFIDE0 BIS(2-
BIF750 CAS: 154-93-8 HR: 3 N,N’-BIS(2-CHLOROETHYL)-N-NITROSOUREA mf: C~H9C12N302 mw: 214.07 PROP: Light-yellow powder. Mp: 30-32’. SYNS: BCNU 0 BiCNU 0 BISCHLOROETHYLNITROSOUREA 0 BIS(2-CHLOR0ETHYL)NITROSOUREA 0 1,3-BIS@-CHLOROETHYL)-1NITROSOUREA 0 1,3-BIS-(2-CHLOROETHYL)-lNITROSOUREA 0 CARbKBRIS 0 CARMUSTIN 0 CARMUSTINE 0 FDA 0345 0 NCI-C04773 0 NITRUMON 0 NSC-409962 0 SK 27702 0 SRI 1720
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 2A IMEMDT 7,150,87; Human Limited Evidence IMEMDT 26,79,81; Animal Sufficient Evidence IMEMDT 26,79,81. NCI Carcinogenesis Studies (ipr); Some Evidence: rat CANCAR 40,1935,77; Clear Evidence: mouse CANCAR 40,1935,77. EPA Genetic Toxicology
Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. A human poison by parenteral route. An experimental poison by ingestion, intravenous, intraperitoneal, parenteral, and subcutaneous routes. Human systemic effects by parenteral, intravenous, and possibly other routes: nausea or vomiting, reduced white blood cell and blood platelet counts, bone marrow damage, and potentially fatal respiratory system effects including lung fibrosis, dyspnea, and cyanosis. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,. See also N-NITROSO COMPOUNDS.
BIH250 CAS: 505-60-2 HR: 3 BlS(2-CHLOR0ETHYL)SULFlDE mf: C4HsClzS mw: 159.08 PROP: Colorless (if pure), to light-yellow, oily liquid. Mp: 13-14’, bp: 215-217’, flash
CHLOR0ETHYL)SULPHIDE 0 l-CHLORO-2-@CHLOROETHYLTHI0)ETHANE 0 p,P-DICHLORETHYLSULPHIDE 0 2,2’-DICHLORODIETHYL SULFIDE 0 DI-2-CHLOROETHYLSULFIDE 0 p,p’DICHLOROETHYLSULFIDE 0 2,2’-DICHLOROETHYL SULPHIDE @MK) 0 DISTILLED iMUSTARD 0 W E S T O F F “LOST” 0 MUSTARD GAS 0 MUSTARD HD 0 MUSTARD VAPOR 0 SCHWEFEL-LOST 0 S-LOST 0 S MUSTARD 0 SULFUR MUSTARD 0 SULFUR ;~.~TSTARD GAS SULPHUR MUSTARD GAS i,i’THlOBlS(2-CHLOROETHANE) 0 YELLOW CROSS LIQUID 0 YPERITE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 7,259,87; Animal Sufficient Evidence IMEMDT 9,181,75; Human Limited Evidence IMEMDT 9,181,75. EPA Extremely Hazardous Substances Lst. Community Right-ToKnow List. EPA Genetic Toxicology Program.Reported in EPA TSCA Inventory. DFG MAK: Human Carcinogen SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. A human poison by inhalation and subcutaneous routes. An experimental poison by inhalation, skin contact, subcutaneous, and intravenous routes. An experimental teratogen. A severe human skin and eye irritant. Human mutation data reported. A military blistering gas. Strongly affects the skin, eyes, lungs, and gastric system. Pulmonary lesions are often fatal. It penetrates the skin deeply and injures blood vessels. Minute amounts can cause inflammation. Secondary infections are common. Combustible when exposed to heat or flame; can be ignited by a large explosive charge. It w d react with water or steam to produce toxic and corrosive fumes. Vigorous reaction with oxidizing materials. Incompatible with bleaching powder. To fight fire, use water, foam, Con, dry chemical. Dangerous; when heated to decomposition or on contact with acid or
BIS(CHLOR0METHYL) ETHER
acid fumes it emits hghly toxic fumes of SO, and C1-. See also SULFIDES and CHLORIDES.
B11250 CAS: 108-60-1 HR: 3 BlS(2-CHLOROISOPROPYL) ETHER DOT: UN 2490 mf: C6H12C120 mw: 171.08 PROP: Colorless liquid. Bp: 187.8', fp: >-20°, flash p: 185'F (OC), d: 1.11 @ 25'/25', vap d: 6.0, vap press: 0.10 mm @ 20'. SYNS: BIS(P-CHLOROISOPROPYL)ETHER BIS(2CHLORO-1-METHYLETHYL)ETHER 0 BIS(1-CHLORO2-PROPYL) ETHER (2-CHLORO-I-METHYLETHYL) ETHER 0 DCIP 0 DCIP (nematocide) 0 DICHLORODIISOPROPYL ETHER 0 P,!3-DICHLORODIISOPROPYL ETHER 0 DICHLOROISOPROPYL ETHER 0 2,2'DICHLOROISOPROPYL ETHER 0 DICHLOROISOPROPYL ETHER (DOT) 0 NCI-C50044 0 NEMAMORT 0 2,2'-OXyBIS(l-CHLOROPROPANE)0 PROPANE, 2,2'-OXYBIS(l-CHLORO)- 0 RCRA WASTE NUMBER U027
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Lmited Evidence IMEMDT 41,149,86. NCI Carcinogenesis Bioassay (gavage); No Evidence: rat NCITR* NCI-CG-TR-191,79. Community Right-To-Know List. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion. Moderately toxic by skin contact and inhalation. An eye irritant. Questionable carcinogen. Mutation data reported. A corrosive material. Moderate fire hazard when exposed to heat, flame, or powerful oxidners. Incompatible with oxiQzing materials. To fight fire, use water to blanket fire; foam, COz, dry chemical. When heated to decomposition it emits highly toxic fumes of C1-. See also ETHERS.
BIJ250 CAS: 13483-18-6 HR: 2 BIS-l,2-(CHLOROMETHOXY)ETHANE mf: C4HsCL02 mw: 159.02 PROP: Viscous liquid. Bp: 99-100' @ 22 mm, d: 1.2879 @ 14'/15'. SYN: ETHYLENE GLYCOL BIS(CHLOR0METHYL)ETHER
BIKOOO 183
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 15,31,77. Reported in EPA TSCA Inventory. Glycol ethers are on the Community Right-ToKnow List. SAFETY PROFILE: Questionable carcinogen with experimental neoplastigenic data. See also GLYCOL ETHERS. When heated to decomposition it emits toxic fumes of C1-.
BIKOOO CAS: 542-88-1 HR: 3 BIS(CHLOR0METHYL) ETHER DOT: UN 2249 mf: C2H4C120 mw: 114.96 PROP: Volatile liquid. Bp: 105', d: 1.315 @ 20°, vap d: 4.0, flash p: <19', fp: -41.5'. SYNS: BCME 0 BIS-CME 0 CHLORO(CHLOR0METH0XY)METHANE L3 DICHLORDIMETHYLAETHER (GERMAN) 0 ~~I~~DICHLORODIMETHYL ETHER (DOT) 0 sym-DICHLOROMETHYL ETHER 0 DIhlETHYL-1,l'DICHLOROETHER 0 OXYBIS(CHLOR0METHANE) RCRA WASTE NUMBER PO16
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 1 IMEMDT 7,131,87; Animal Sufficient Evidence IMEMDT 4,231,74; Human Sufficient Evidence IMEMDT 4,231,74. Community Right-To-Know Lst. EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. OSHA PEL: OSHA: Cancer Suspect Agent ACGIH TLV: TWA 0.001 ppm; Confirmed Human Carcinogen DFG MAK: Human Carcinogen DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by inhalation, ingestion, and skin contact. Human systemic effects by inhalation: irritation of the conjunctiva, unspecified nasal and respiratory effects. Human mutation data reported. A dangerous fire hazard. When heated to decomposition it emits very toxic fumes of C1-. See also ETHERS.
184
BIK250
BIS(CHLOR0METHYL)KETONE
BIK250 CAS: 534-07-6 HR: 3 BlS(CHLOR0METHYL)KETONE DOT: UN 2649 mf: C3H4ChO mw: 126.97 PROP: Crystals. Mp: 45O, bp: 173O, d: 1.3826 @ 46'/4', vap d: 4.38. Sol in water. SYNS: sym-DICHLOROACETONE0 a,a'-
ETHANE 0 2,2-BIS(4-CHLOROPHENYL)-l,l-DICHLOROETHANE DDD 0 p,p'-DDD 0 l,l-DICHLOOR-2,2BIS(4-CHLOOR FENYL)-ETHAAN (DUTCH) 1,l-
DICHLOROACETONE 0 a,y-DICHLOROACETONE 0 1,3-DICHLOROACETONE 1,3-DICHLOROACETONE
DICHLORO-2,2-BIS(PARrlCHLOROPHENYL)ETHANE (DOT) I,l-DICHLORO-2,2-DI(4-CHLOROPHEN~)-
(DOT) 0 1,3-DICHLORO-2-PROPANONE
ETHANE 0 DICHLORODIPHENYL DICHLOROETHANE p,p'-DICHLORODIPHENYLDICHLOROETHANE 0 1,l-DICLORO-2,2-BIS(4-CLORO-FENIL)ETANO (ITALIAN) DILENE 0 ENT 4,225 0 ME-1700 NCI-COO475 0 RCRA WASTE NUMBER UOGO 0 RHOTHANE RHOTHANE D-3 ROTHANE 0 p,p'TDE 0 TDE (DOV 0 TETRACHLORODIPHENYLETHANE
CONSENSUS REPORTS: EPA Genetic
Toxicology Program.Reported in EPA TSCA Inventory. EPA Exu-emely Hazardous Substances List. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by inhalation. Mutation data reported. A systemic irritant by ingestion and inhalation routes. See also KETONES. Dangerous; when heated to decomposition it emits hghly toxic fumes of
c1-.
BIM250 CAS: 55-56-1 HR: 3 1,6-BIS(5-(p-CHLOROPHENYL)BIGUANIDIN0)HEXANE mf: C22Hd12N10 mw: 505.52 PROP: Solid. Mp: 134'. SYNS: 1,6-BIS@CHLOROPHENYLDIGUANID0)HEXANE 0 CHLORHEXIDIN (CZECH) 0 CHLORHEXIDINE 0 1,6-DI(4'-
CHLOROPHENYLDIGUANID0)HEXANE 1,l'HEXAMETHYLENEBIS(5-@-CHLOROPHENYLBIGUANIDE) 0 HIBITANE ROTERSEPT 0 STERIDO
NOLVASAN 0
SAFETY PROFILE: Poison by intraperitoneal and intravenous routes. Mildly toxic by ingestion. Experimental reproductive effects. A human s h n irritant. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,.
BIM500 CAS: 72-54-8 HR: 3 1,I-BIS(CCHLOROPHENYL)-2,2DICHLOROETHANE mf: C14H10C14 mw: 320.04 PROP: Crystalline solid from pet ether. Mp: 11l0,vap d: 11. SYNS: 1,1-BIS@-CHLOROPHENYL)-2,2-DICHLOROE T W U E 0 2,2-BIS@-CHLOROPHENYL)-l ,I-DICHLORO-
DICHLOR-2,2-BIS(4-CHLOR-PHENYL)-AETHAN (GERMAN) 0 1,1-DICHLORO-2,2-BIS@CHLOR0PHENYL)ETHANE 0 1,l-DICHLORO-2,2-BIS@CHLOR0PHENYL)ETHANE (DOT) 0 1,I-DICHLORO2,2-BIS(4-CHLOROPHENYL)-ETHANE (FRENCH) 0 1,l-
CONSENSUS REPORTS: IARC Cancer Review: Animal Sufficient Evidence IMEMDT 5,83,74. NCI Carcinogenesis Bioassay (feed); Clear Evidence: rat NCITR* NCI-CG-TR-131,78; No Evidence: mouse NCITR* NCI-CG-TR-131,78. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by ingestion. Moderately toxic by skin contact. Mutation data reported. An insecticide. When heated to decomposition it emits toxic fumes of C1-. See also DDT.
BIM750 CAS: 72-55-9 HR: 3 2,2-BIS(p-CHLOROPHENYL)-1,1-DICHLOROETHYLENE mf: c14H8Cb mw: 318.02 SYNS: DDE 0 p,p'-DDE 0 DDT DEHYDROCHLORIDE 0 1,I-DICHLORO-2,2-BIS@-CHLOROPHENYL)-ETHYLENE 0 p,p'-DICHLORODIPHENYLDICHLOROETHYLENE 0 l,l'-(DICHLOROETHENYLIDENE)BIS(4CHLOROBENZENE) 0 NCI-COO555
CONSENSUS REPORTS: IARC Cancer Review: Animal Limited Evidence IMEMDT 5,83,74. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse NCITR* NCI-CG-TR-131,78; NO Evidence: rat NCITR* NCI-CG-TR-131,78. EPA Genetic Toxicology Program. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and neoplastigenic data. Poison by ingestion.
N,N-BIS(2-CYANO-2-METHYLPROPlONALDEHYDEO-
Experimental reproductive effects. Mutation data reported. An insecticide. When heated to decomposition it emits very toxic fumes of C1-. See also CHLORINATED HYDROCARBONS, ALIPHATIC. B10750 CAS: 115-32-2 HR: 3 1,l-BIS(p-CHLOROPHENYL)-2,2,2TRICHLOROETHANOL mf: C14H9CljO mw: 370.48 PROP: Solid. Mp: 78.5'. Material used in cancer bioassay was 40-60°/o pure NCITR* NCI-CG-TR-90,78. SYNS: ACARIN 0 l,l-BIS(CHLOROPHENYL)-2,2,2TRICHLOROETHANOL 0 1,I -BIS(4-CHLOROPHENYL)2,2,2-TRICHLOROETHANOL0 CARBAX 0 CEKUDIFOL 0
4-CHLORO-a-(4-CHLOROPHENYL)-a-(TRICHLORO-
METHYL)BENZENEMETK4NOL 0 CPCA 0 DECOFOL 0 DICHLOROKELTHANE 0 DI-@-CHLOR0PHENYL)TRICHLOROMETHYLCARBINOL 0 4,4'-DICHLORO-aFRICHLOR0METHYL)BENZHYDROL 0 DICOFOL 0 DTMC 0 ENT 23,648 0 W 293 0 HIFOL 0 KELTANE 0 p,p'-KELTHANE 0 KELTHANE (DOT) 0 KELTHANE DUST BASE 0 KELTHANETHANOL 0 hlILBOL 0 MITIGAN 0 NCI-COO486 0 2,2,2-TRICHLOOR-l,l-BIS(4CHLOOR FENYL)-ETHANOL(DUTCH) 0 l,l,lTRICHLOR-2,2-BIS(4-CHLORPHENn)-AETHhNOL ( G E R " ) 0 2,2,2-TRICHLOR-l,l-BIS(4-CHLORPHENYL-AETHANOL (GERMAN) 0 2,2,2-TRICHLORO1,l-BIS(4-CHLOROPHENYL)-ETHANOL (F'RENCH) 0 2,2,2-TRICHLORO-1,1-BIS(4-CLORO-FENIL)-ETANOLO (ITALIAN) 0 2,2,2-TRICHLORO-l,l-D1-(4CHLOR0PHENYL)ETHANOL
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 30,87,83. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse NCITR* NCI-CG-TR90,78; No Evidence: rat NCITR* NCI-CGTR-90,78. Community Right-To-Know List. SAFETY PROFILE: Poison by ingestion and shn contact. Moderately toxic by intraperitoneal route. Human mutation data reported. Questionable carcinogen with experimental carcinogenic data. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of C1-. BIQ250 CAS: 40334-69-8 HR: 3 BIS(2-CHLOROVINYL)CHLOROARSINE
mf: C4HdsC13
BIQ660 185
mw: 233.35
SYNS: DICHLOROVINYLARSINE CHLORIDE 0 DICHLOROVINYLCHLOROARINE (DO?? 0 L-2 0 LEWISITE I1
CONSENSUS REPORTS: Arsenic and its compounds are on the Community fightTo-Know List. OSHA PEL: TWA 0.5 mg(As)/m3 DOT CLASSIFICATION: Forbidden SAFETY PROFILE: A poison by skm contact and subcutaneous routes. When heated to decomposition it emits very toxic fumes of As and C1-. See also ARSENIC COMPOUNDS.
BIQ500 CAS: 111-94-4 HR: 3 BlS(PCYAN0ETHYL)AMINE mf: C G H ~ N ~ mw: 123.18 PROP: Liquid. Mp: -5.5', bp: 135' @ 1 mm, d: 1.463 @ 25', vap d: 3.3. SYNS: BBCE 0 BIS-(2-CYAVOETHYL)AMINE 0 N,NBIS(2-CYAN0ETHYL)AMINE0 2-CYANO-N-(2-CYANOETHYL)ETHANAMINE 0 DI(Z-CIANOETIL)ARfMINA (ITALIAN) 0 2,2'-DICYANODIETHYINE 0 DI-(2CYAN0ETHYL)AMINE 0 IDPN 0 3,3'-IMINOBISPROPANENITRILE 0 IMINO-~,~-DIPROPIONITRILE 0 p,p-IMINODIPROPIONITRILE ~,~-IMINODIPROPIONITRILE 0 3,3'-IMINODIPROPIONITRILE 0 2341 IS. 0 USAF A-8564 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community RightTo-Know List. SAFETY PROFILE: A poison by intraperitoneal route. Moderately toxic by ingestion and skin contact. Experimental teratogenic and reproductive effects. A skin and severe eye irritant. A storage hazard, may explode in a sealed container. When heated to decomposition it emits toxic fumes of NO, and CN-. See also NITRILES and AMINES.
BIQ660 CAS: 63942-43-8 HR: 3 N,N'-BIS(2-CYANO-2-METHYLPROPlONALDEHYDEO-(N-METHYLCARBAM0YL)OXIME)SULFIDE mf: C14H20N604S mw: 368.46 SYN: 5,11-DIOXA-9-THIA-4,7,9,12TETRhAZAPENTADECA-3,12-DIENEDINITRILE, 6,lODIOXO-2,2,7,9,14,14-HEXAMETHYL-
186
BIS500
BIS(DECANOYL0XY) DI-n-BUTYL-STANNANE
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO, and SO,.
BIS500 CAS: 3465-75-6 HR: 3 BE(DECANOYL0XY)DI-n-BUTYLSTANNANE mf: CzgH5604Sn mw: 575.53 SYN: BIS(DECANOYL0XY)DI-N-BUTYLTIN OSHA PEL: TWA 0.1 mg(Sn)/rn' ( s h ) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion. A severe skin and eye irritant. See also TIN COMPOUNDS. When heated to decomposition it emits acrid and irritant fumes. BIV900 CAS: 73926-85-9 HR: 3 BIS(DlBUTYLAMM0NIUM)HEXACHLOR OSTANNATE mf: C I ~ H ~ O N ~ * Cmw: ~ ~ 591.97 S~ SYNS: AMMONIUMYL, DIBUTYL, HEXACHLOROSTA"ATE(2-) (21) 0 DIBUTYLAMINE, HEXACHLOROSTANNANE (2:l)
OSHA PEL: TWA 2 mg(Sn)/m3 ACGIH TLV: TWA 2 mg(Sn)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it
emits toxic fumes of NO,, Sn, and C1-. BIW750 CAS: 13927-77-0 HR: 3 BIS(DIBUTYLDITHIOCARBAMAT0)NICK EL mf: C18H36N2S4*Ni mw: 467.51 PROP: Green crystals from C6H&tOH. Mp: 91'. sol in C6H6, MeKO. SYNS: DIBUTYLDITHIOCARBAMIC ACID, NICKEL SALT 0 NICKEL D I B U T Y L D I T H I O C A R B A E 0 W CHEKAM 104 0 VANGUARD N
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. Reported in EPA TSCA
Inventory. Nickel and its compounds are on the Community Right-To-Know List. SAFETY PROFILE: Low toxicity by ingestion. Confirmed human carcinogen with experimental tumorigenic data. See also
NICKEL COMPOUNDS and CARBAMATES. When heated to decomposition it emits very toxic fumes of SO, and NO,. BIXOOO CAS: 136-23-2 HR: 3 BIS(DIBUTYLDlTHlOCARBAMAT0)ZI" mf: C1gH3gN&Zn mw: 476.19 PROP: White powder. Mp: 104-108', d: 1.24 @ 2Oo/2O0. SYNS: ACETO ZDBD 0 BUTAZATE 0 BUTAZATE 50D 0 BUTYL ZIMATE 0 B U T n ZIRAM 0 DIBUTYL DITHIO-CARBAMIC ACID ZINC COMPLEX 0 DIBUTYLDITHIOCARBAMICACID ZINC SALT 0 USAF GY-5 0 WLCACURE 0 WLKACIT LDB/C 0 ZINCBIBUTYLDITHIOCARBAMATE 0 ZINC-DIBUTYLDITHIOCARBAMATE 0 ZINC-N,N-DIBUTYLDITHIOCARBMTE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Zinc and its compounds are on the Community Right-To-Know List. SAFETY PROFILE: Poison by intraperitoneal route. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits very toxic fumes of NO,, ZnO, and SO,. See also ZINC COMTOUNDS and CARBAMATES. BIX500 CAS: 15442-77-0 HR: 3 BIS(3,4-DICHLOROBENZOATO)NlCKEL mf: C14H6C14Ni04 mw: 438.71 CONSENSUS REPORTS: NTP 10th Report on Carcinogens. Nickel and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.1 mg (Ni)/m3 ACGIH TLV: TWA 0.2 mg(Ni)/m3; Human Carcinogen) NIOSH REL: (Inorganic Nickel) TWA 0.015 mg(Ni)/m3 SAFETY PROFILE: Confirmed human carcinogen. Poison by intravenous route. See also NICKEL COMPOUNDS and CHLORIDES. When heated to decomposition it emits toxic fumes of C1-.
BIS(DIETHYLDITHlOCARBAMAT0)MERCURY BJB750 187
BJK560 CAS: 30947-30-9 HR: 3 ((3,5-BIS(1,1-DIMETHYLETHY L)-4HYDROXYPHENYL)METHYL)PHOSP HONIC ACID, MONOETHYL ESTER, NICKEL(2+) SALT (2:l) mf: C34H560&*Ni mw: 713.55 SYNS: IRGASTAB 2002 0 IRGASTAB 2002 HT CONSENSUS REPORTS: NTP 10th Report on Carcinogens. SAFETY PROFILE: Confirmed human carcinogen. Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of PO, and Ni. BIX750 CAS: 133-14-2 HR: 3 BIS(2,4-DICHLOROBENZOYL)PEROXIDE mf: C14H6C1404 mw: 380.00 SYNS: CADOX TS 0 CADOX TS 40,50 0 DI-2,4DICHLOROBENZOYLPEROXIDE, >75% with water (DOT) 0 LLPERCO CST CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: Forbidden SAFETY PROFILE: Poison by intraperitoneal route. Explosion Hazard: Pure compound is extremely shock sensitive and decomposes rapidly @ 80". When heated to decomposition it emits toxic fumes of C1-. See also PEROXIDES, ORGANIC; and ESTERS.
BJA2OO CAS: 90466-79-8 HR: 3 BIS(2,P-DIETHOXYETHYL)DISELENIDE mf: Ct2H2604Se2 mw: 392.30 SYN DISELENIDE, BIS(2,2-DIETHOXYETHX)OSHA PEL: TWA 0.2 mg(Se)/m3 ACGIH TLV: TWA 0.2 mg(Se)/m3 SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of Se.
BJBSOO CAS: 14239-68-0 HR: 3 BIS(DlETHYLDlTHlOCARBAMAT0)CAD MlUM mf: C I O H ~ O C ~ N ~mw: S ~ 408.96 SYNS: CADMIUM DIETHYL DITHIOCARBAMATE 0 ETHYL ChDiMATE 0 ETHYL TUADS
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cadmium and its compounds are on the Community RlghtTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood DFG MAK: DFG BAT: Blood 1.5 pg/dL; Urine 15 pg/dL, Suspected Carcinogen NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and SO,. See also CADMIUM COMPOUNDS and CARBAMATES.
BJ B750 CAS: 14239-51-1 HR: 3 BIS(DIETHYLDITHIOCARBAMAT0)MER CURY mf: CloHzoHgNzS4 mw: 497.15 PROP: Yellow crystals from Me2CO. Mp: 127-130'. IDLH 10 mg/m3 (as Hg). CONSENSUS REPORTS: Mercury and its compounds are on the Community RightTo-Know List. OSHA PEL: CL 0.1 mg(Hg)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 pg/g creatinine total inorganic mercury in urine preshift; 15 pg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Organomercury): TWA 0.01 mg/m3; STEL 0.03 mg/m3 (skm) SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. See also MERCURY COMPOUNDS and CARBAMATES. When heated to decomposition it emits very toxic fumes of NO,, SO,, and Hg.
1aa
BJCOOO BIS(DIETHYLDITHIOCARBAMATO)ZINC
BJCOOO CAS: 14324-55-1 HR: 3 BIS(DlETHYLDITHIOCARBAMAT0)ZINC mf: C I O H ~ ~ N ~ S ~ mw: * Z ~363.95 PROP: White powder. D: 1.47 @ 2Oo/2O0. SYNS: DIETHYLDITHIOCARBAMCACID ZINC SALT 0 ETHAZATE 0 ETHYL CYMATE 0 ETHYL ZIiMATE 0 ETHYL ZIRUM 0 WLCACURE 0 WLKACIT LDA 0 ZINC DIETHYLDITHIOCARBAMATE 0 ZINC-X,NDIETHYLDITHIOCARBAMATE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Zinc and its compounds are on the Community Right-To-Know Lst. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. Severe irritant to eyes, nose, and throat. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and SO,. See also ZINC COMPOUNDS and CARBAMATES.
BJE550 CAS: 2162-74-5 HR: 3 BIS(2,6-DIISOPROPYLPHENYL)CARBODIIMIDE mf: C25H34Nz mw: 362.61 SYNS: BENZENAMINE, N,N'-METHANETETMYLBIS(2,6-BIS(l-METHYLETHYL)0 CARBO D 0 CARBODIIMIDE, BIS(2,6-DIISOPROPYLPHENYL)-0 N,N'-METHANETETRAYLBIS(2,6-BIS(lMETHYLETHYL)BENZENAMINE) 0 STABOXOL 1
SAFETY PROFILE: A poison by ingestion,
intraperitoneal, and inhalation. When heated to decomposition it emits toxic vapors of NO,. BJE750 CAS: 115-26-4 HR: 3 BE(DIMETHYLAMID0)FLUORO PHOSPHATE mf: C ~ H I Z F N ~ O P mw: 154.15 PROP: Liquid. Misc in H20 and most org solvs. D: 1.115 mm @ 20°, bp: 67' @ 4 mm. SYNS: BFP 0 BFPO 0 BIS(DIMETHYL4MIDO)PHOSPHORYL FLUORIDE 0 BIS(DIMETHYUMIN0)FLUOROPHOSPHATE 0 BISDIMETHYWhfINOFLUOROPHOSPHINE OXIDE 0 CR 409 0 DIFO 0 DIMEFOX 0 DMF 0 ENT 19,109 0 FLUOPHOSPHORIC ACID DI(DIMETHYLAM1DE) 0 FLUORURE de N,N,N',N'TETRAMETHYLEPHOSPHORO-DIAMIDE (FRENCH) 0
HANANE 0 PESTOX IV 0 PESTOX XIV 0 PESTOX 14 0 T-2002 0 TERRA-SYSTAM 0 TERRA-SYTAM 0 TERRASYTUM 0 N,N,N',N'-TETRAMETHYL-DIAMIDOFOSFORZUUR-FLUORIDE(DUTCH) 0 TETRAMETHYLDXMIDOPHOSPHORIC FLUORIDE 0 N,N,N',N'TET~~lETHYL-D~~~IDO-PHOSPHORSAEUREFLUORID (GERMAN) 0 TETRAMETHYLPHOSPHORODIAMIDIC FLUORIDE 0 N,N,N,N-TETRAMETHYLPHOSPHORODIAMIDICFLUORIDE 0 N,N,N',N'TETRAMETIL-FOSFORODIMIDO-FLUORURO (ITALIAN) 0 TETRA SYTAM 0 TL 792 0 WACKER S 14/10
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shft. NlOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m3 SAFETY PROFILE: Poison by ingestion, skm contact, intraperitoneal, subcutaneous, and intravenous routes. When heated to decomposition it emits very toxic fumes of F-, NO,, and PO,.
BJ FOOO CAS: 494-38-2 HR: 3 3,6-BIS(DIMETHYLAMINO)ACRlDlNE mf: C17H19N3 mw: 265.39 PROP: Yellow needles from EtOH. Mp: 180-181'. Sol in EtOH and Me2CO. SYNS: ACRIDINE ORANGE 0 ACRIDINE ORANGE FREE BASE 0 BASIC ORANGE 3RN 0 2,8BISDIMETHYLNIINOACRIDINE 0 BRILLIANT ACRIDINE ORANGE E 0 C.I. 46005 0 C.I. No. 46005:l 0 C.I. BASIC ORANGE 14 0 C.I. SOLVENT ORANGE 15 0 ~,~-DI(DIIMETHYTAMINO)ACRIDINE 0 EUCHRYSINE 0 RHODULINE ORANGE 0 SOLVENT ORANGE 15 0 N,N,N'-TETRAhlETHYL-3,6-ACRIDINEDI&VINE 0 WAXOLINE ORANGE A CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 16,145,78. SAFETY PROFILE: Poison by subcutaneous route. Questionable carcinogen with experimental tumorigenic and carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
BlS(DlMETHYLDlTHl0CARBAMATO)ZINC
BJH750 CAS: 3033-62-3 HR: 3 BlS(2-DIMETHYLAMINOETHYL) ETHER mf: CEH~ONZO mw: 160.30 PROP: Bp: 180-182'. SYN: DIMAEE 0 NIAX CATALYSTAL CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 0.05 ppm; STEL 0.15 PPm (skin)) SAFETY PROFILE: Poison by skin contact. Moderately toxic by ingestion. Experimental reproductive effects. A severe skin and eye irritant. See also ETHERS. When heated to decomposition it emits toxic fumes of NO,.
BJKSOO
189
decomposition it emits very toxic fumes of NO,, SO,, and C1-. BJK500 CAS: 137-30-4 HR: 3 BIS(DIMETHYLDITHIOCARBAMAT0)ZINC mf: C ~ H I ~ N Z S ~ * mw: Z ~ 305.81 PROP: White powder. Mp: 248-250°, d: 1.65 @ 2Oo/2O0. SYNS: AAPROTECT 0 AAVOLEX 0 M Z I R A 0
ACCELERATOR L 0 ACETO ZDED 0 ACETO ZDMD 0 ALCOBAM Zhl 0 AMYL ZIhWTE 0 ANTENE 0 BIS(D1METHYLCARBAMODITHIOATO-S,S')ZINC 0 BIS(DIMETHYLD1THIOCARBAMATEde ZINC) (FRENCH) 0 BIS(N,N-DIMETILDITIOCARBAMMATO) DI ZINC0 (ITALIAN) 0 CARBAMIC ACID, DIMETHYLDITHIO-, ZINC SALT (2:l) 0 CARBAZINC 0 BJ1250 CAS: 61-73-4 HR: 3 CIRAM 0 CORONA COROZATE 0 COROZATE 0 3,7-BIS(DIMETHYL AMIN0)PHENAZA CUMAN 0 CUMAN L 0 CYMATE 0 THlONlUM CHLORIDE DIMETHYLCARBAMODITHIOIC ACID, ZINC COMPLEX mf: C ~ ~ H I ~ N ~ S *mw: C ~319.88 0 DIMETHYLCARBAMODITHIOIC ACID, ZINC SALT 0 PROP: Dark bronze-green crystals with DIhlETHYLDITHIOCARBAMATE ZINC SALT 0 bronze luster. Sol in H20 and EtOH. DIMETHYLDITHIOCARBAhfIC ACID, ZINC SALT 0 DRUPINA 90 0 ENT 988 0 EPTAC 1 0 FUCLASIN 0 SYNS: AIZEN METHYLENE BLUE BH 0 BASIC BLUE 9 0 3,7-BIS(DISfETHYINO)PHENOTHIAZIN-5-IL?M FUCLASIN ULTRA 0 FUKLASIN 0 FUNGOSTOP 0 HELMAT ZDM 0 HEXAZIR 0 KARBAM WHITE 0 CHLORIDE 0 CALCOZINE BLUE ZF 0 CHROhiOSMON METHASAN 0 METHAZATE 0 METHYL ZIMATE 0 0 C I 52015 (CZECH) 0 C I BASIC BLUE 9 0 D&C BLUE METHYL ZINEB 0 METHYL ZIRAM 0 hiEXENE 0 NUMBER 1 0 EXTERNAL BLUE 1 0 HIDACO MEZENE 0 hfILBAM 0 MILBAN 0 MOLURAME 0 METHYLENE BLCE SALT FREE 0 LEATHER PURE MYCRONIL 0 NCI-C50442 0 ORCHARD BRAND ZIRAhi BLUE HB 0 METHYLENE BLUE 0 METHYLENE BLUE A 0 METHYLENE BLUE BB 0 METHYLENE BLUE BB 0 POhWRSOL Z FORTE 0 PRODARAM 0 RHODIACID 0 SOXINAL PZ 0 SOXINOL PZ 0 TRICARBAMIX Z 0 ZINC FREE 0 METHYLENE BLUE CHLORIDE 0 METHYLENE BLUE CHLORIDE (biologm.1 stain) 0 TSIMAT 0 TSIRAM (RUSSIAN) 0 CSAF P-2 0 VANCIDE MZ-96 0 ZERLATE 0 ZIMATE 0 ZIMhTE METHYL 0 SIETHYLENE BLUE D 0 METHYLENE BLUE (medicinal) ZINC BIS(DIMETHYLDITHI0CARBAMATE) 0 ZINC 0 METHYLENE BLUE I (melcinal) 0 METHYLENE BIS(DIMETHYLDITHIOCARBAhi0YL)DISULPHIDE0 BLUE N F (melcinal) 0 METHYLENE BLUE ZINC DIMETHYLDITHIOCARBAMATE 0 ZINC N,NPOLYCHROME 0 METHYLENE BLUE USP (mednnal) 0 D I M E T H Y L D I T H I O C A R B I T E 0 ZINCMATE 0 METHYLENE BLUE USP XI1 (melcmal) 0 ZINK-BIS(N,N-DIMETHYL-DITHIOCARBAMAA~ METHYLENIUM CERULEUM 0 hiETHYLTHIONINE (DUTCH) 0 ZINK-BIS(N,N-DIMETHYLCHLORIDE 0 METHYLTHIONIUM CHLORIDE 0 DITHIOCARBAM.4~ (GERMAN) 0 ZINKCARBAbLATE hlITSUI METHYLENE BLUE 0 MODR METHYLENOVA 0ZINK-~,N-DI~IETHYL-DITHIOCA~AhW~ (CZECH) 0 SANDOCRYL BLUE BRL 0 SCHULTZ No (GERMAN) 0 ZIRAM 0 ZIRAhlVIS 0 ZIRASAN 0 1038 0 SWISS BLUE 0 TETRAMETHYLTHIONINE ZIRBERK 0 ZIREX 90 0 ZIRIDE 0 ZIRTHANE 0 CHLORIDE 0 YAMAMOTO METHYLENE BLUE B ZITOX
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion, intraperitoneal, intravenous, and subcutaneous routes. Human systemic effects: cyanosis, blood changes. Experimental reproductive effects. Mutation data reported. When heated to
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 12,259,76; NTP Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NTPTR* NTP-TR238,83. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. Zinc and its compounds are on the Community Right-To-Know List.
190 BJKGOO
(((3,5-BIS(1,I-DIMETHYLETHYL)-4-HYDROXYPHENYL)
SAFETY PROFILE: Poison by ingestion,
intraperitoneal, and intravenous routes. Moderately toxic by inhalation. Questionable carcinogen with experimental carcinogenic and tumorigenic data. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. See also ZINC COMPOUNDS and CARBAMATES. Severe irritant to eyes, nose, and throat. When heated to decomposition it emits very toxic fumes of NO, and SO,. BJK6OO CAS: 80387-97-9 HR: D (((3,5-BIS(1 ¶I-DIMETHYLETHYL)4HYDROXYPHENYL)METHYL)THIO)A CETIC ACID 2-ETHYLHEXYL ESTER mf: CzjH4203S mw: 422.73 SYN: ACETIC ACID, (((3,5-BIS(l,l-DIhfETHYLETHYL)-4HYDR0XYl'HENYL)METHYL)THIO)-, 2-ETHYLHEXYL ESTER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An experimental
teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of SO,. BJK780 CAS: 32613-12-0 HR: 3 1,l '-BIS(DIMETHYLOCT0XYSILYL)FERROCENE mf: C30H54Fe02Siz mw: 558.87 SYNS: t,i'BIS(DIMETHYL(OCTYL0XY)SILYL)FERROCENE0 FERROCENE, l,l'-BIS(DIMETHYL(OCTYLO~SILYL)-
MONO-THIURAD 0 MONOTHIURAM 0 PENNAC MS 0 TETRAMETHYLTHIURAMMONIUMSULFIDE 0 TETRAMETHYLTHIURAMMONOSULFIDE 0 TET~IETHYLTHIURAM SULFIDE 0 TETRAMETHYL TRITHIO CARBAMIC ANHYDRIDE 0 1,t'-THIOBIS(iW,NDIMETHYLTHI0)FORMAMIDE 0 THIONEX 0 THIONEX RUBBER ACCELERATOR 0 TMTM 0 TMTMS 0 UNADS 0 USAF B-32 0 USAF EK-P-6255 0 VULKACIT THIURAM MS/C
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. An experimental teratogen. When heated to decomposition it emits very toxic fumes of NO, and SO,. See also SULFIDES.
BJM700 CAS: 38998-91-3 HR: 3 BIS(1,3-DITHIOCYANAT0-ly1,3,3TETRABUTYLDISTANNOXANE) mf: C36HnN402S4Sn4 mw: 1196.12 SYNS: DISTANNOXANE, BIS(l,3-DITHIOCYANATO1,1,3,3-TETRABUTn)- 0 DI-p(THIOCYANATOD1-n-
BUTYLSTANNYLOXO)BIS(THIOCYANATODI-nBUTYLTIN)
OSHA PEL: TWA 0.1 mg(Sn)/m3 ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg/m3 (skin) NIOSH REL: 10H TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it
emits toxic fumes of NO,, SO,, and Sn.
SAFETY PROFILE: A poison by inhalation. Low toxicity by ingestion. When heated to
BJN250 CAS: 2386-90-5 HR: 2 BIS(2,3-EPOXYCYCLOPENTYL) ETHER mf: C10H1403 mw: 182.24
decomposition it emits acrid smoke and irritating vapors.
SYNS: EP-205 0 ERR 4205
BJ L600 CAS: 97-74-5 HR: 3 BIS(DIMETHYLTHIOCARBAM0YL)SULFIDE mf: C ~ H I ~ N Z S ~mw: 208.38 PROP: Yellow crystals from EtOH. Mp: 104'. Very sol in EtOH, CHCl3; sltly sol in cold EtzO. SYNS: ACETO TMTM 0 BIS(DIMETHYLTHI0CARBAMYL) MONOSULFIDE 0 CARBAIvIlCACID, DIMETHYLDITHIO-,ANHYDROSULFIDE 0 MONEX 0
2,2'-0XYBIS-6-
OXABICYCLO-(3.1.O)HEXANE
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A systemic irritant by skin contact and ingestion. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic and neoplastigenic data. See also ETHERS. When heated to decomposition it emits acrid smoke and irritating fumes.
BIS(2-E THYLHEXANOYLOXY)DlBU TYL S TANNANE
BJ0225 CAS: 109-44-4 HR: 2 BIS(2-ETHOXYETHYL) ADIPATE mf: C14H2606 mw: 290.40 SYNS: ADIPIC ACID, BIS(2-ETHOXYETHYL)ESTER 0 DIETHOXY ETHYL ADIPATE 0 HEXANOIC ACID, BIS(2-ETHOXk'ETHYL) ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A severe skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
BJPOOO CAS: 122-34-9 HR: 3 2,4-BIS(ETHYLAMINO)-6-CHLORO-sTRlAZlNE mf: C7H12ClNj mw: 201 -69 PROP: Crystals. Mp: 228-229'. SYNS: AKTINIT S 0 AQUAZINE 0 BATAZINA 0 2,4BIS(AETHYL&fINO)-6-CHLOR- 1,3,5-TRIAZIN (GERMAN) 0 BITEMOL 0 BITEMOL S 50 0 CAT (herbicide) 0 CDT 0 CEKUSAN 0 CEKUZINA-S 0 CET 0 l-CHLORO-3,5-BISETHYLAMINO-2,4,6-TRL4ZINE 0 2CHLORO-4,6-BIS(ETHYLAMINO)-s-TRIAZIWE0 2CHLORO-4,6-BIS(ETHYINO)-l,3,5-TRIAZINE 0 FRAMED 0 GEIGY 27,692 0 GESARAN 0 GESATOP 0 HERBAZIN HERBEX HERBOXY HUNGAZIN DT 0 PREMhZINE 0 PRIMATOL S 0 RADOCON 0 RADOKOR 0 SIMhNEX 0 SIMAZIN 0 SIhUZINE (LEDA) 0 SIMAZINE 8OW 0 TAFAZINE 0 TAPHAZINE 0 ZEAPUR
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Moderately toxic by ingestion. Questionable carcinogen with experimental tumorigenic data. An experimental teratogen. Other experimental reproductive effects. A s h n and eye irritant. Mutation data reported. May cause weight loss and reduced red blood cell count. When heated to decomposition it emits very toxic fumes of C1- and NO,.
BJQ250
191
NATO)- 0 COPPER(2+),BIS(ETHYLENEDIAblINE)-, TETRAKIS(THIOCYANATOMERCURATE(2-).
POLYMERS
~
I,
ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin);
BEI: 35 pg/g creatinine total inorganic mercury in urine preshft; 15 pg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Organomercury): TWA 0.01 mg/m3; STEL 0.03 mg/m3 (shn) SAFETY PROFILE: Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of NO,, SO,, Hg, and C1-. BJP450 CAS: 1192-75-2 HR: 3 BISETHYLENEUREA mf: C5HsN20 mw: 112.15 SYNS: AZIRIDINE, 1,l'-CARBONYLBIS- 0 BIS(1AZIRID1NYL)KETONE 0 CARBONYLBIS(AZIRID1NE)0 CARBONYLBIS(1-AZIRIDINE)0 DIETHYLEKECTREA 0 N,N'-DIETHYLENEUREA
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
BJQ250 CAS: 2781-10-4 HR: 3 BIS(2-ETHYLHEXANOYL0XY)DIBUTY L STANNANE mf: C24H4804Sn mw: 519.41 SYNS: DIBUTYLBIS((2-ETHYLHEXAN0YL)OXY)STANNANE 0 DIBUTYLBIS((Z-ETHYI-10XOHEXYLJOXY)-STANNANE(9CI) 0 DIBUTYLTIN BIS(a-ETHYLHEXANOATE) 0 DIBUTYLTIN BIS(2ETHYLHEXANOATE) 0 DIBUTYLTIN DI(2ETHYLHEXANOATE) DI-n-BUTYLTIN DI-2ETHYLHEXANOATE 0 DIBUTYLTIN DI(2ETHYLHEXOATE)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. BJP425 CAS: 29471-80-5 HR: 3 BIS(ETHYLENEDIAMINE)(MERCURICTE OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL TRATHlOCYANAT0)COPPER mf: ( C ~ H ~ ~ C U N ~ * C ~ H ~ N ~ S ~ ) ~0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA PROP: IDLH 10 mg/m3 (as Hg). SYNS: COPPER, 0.1 mg(Sn) /m3 BIS(ETHYLENEDLt\INE)(MERCURICTETRATHIOCYA
192 BJR750
BIS(2-ETHYLHEXYL) PHOSPHATE
SAFETY PROFILE: Poison by ingestion and intravenous routes. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
BJR750 CAS: 298-07-7 HR: 3 BIS(2-ETHYLHEXYL) PHOSPHATE mf: C16H3504P mw: 322.48 PROP: Viscous liquid. D: 0.975 @ 25 mm, bp: 155' @ 0.015 mm. sol in C6H6, hexane, and 4-methyl-2-pentanone; sltly sol in H20. SYNS: BIS(2-ETHYLHEXYL)HYDROGENPHOSPHATE 0 BIS(2-ETHYLHEXYL)ORTHOPHOSPHORIC ACID 0 BIS(2-ETHYLHEXYL)PHOSPHORICACID 0 DEHPA EXTRACTANT 0 DI(2-ETHYLHEXYL)PHOSPHATE0 DI-2(ETHYLHEXYL)PHOSPHORICACID 0 DI-(2-
ETHYLHEXYL)PHOSPHORICACID (DOV 0 2-ETHYL-lHEXANOL HYDROGEN PHOSPHATE 0 HDEHP 0 KYSELINA DI-(2-ETHYLHEXYL)FOSFORECNA
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. A corrosive material. A severe eye and skin irritant. When heated to decomposition it emits toxic fumes of PO,.
BJS250 CAS: 122-62-3 HR: 2 BIS(2-ETHYLHEXYL) SEBACATE mf: Cz~H5004 mw: 426.76 PROP: Light, clear liquid; rmld odor. Mp: -48', fp: -55', bp: 256' @ 5 mm, flash p: 410'F, d: 0.914 @ 2Oo/4O, vap d: 14.7. SYNS: BISOFLEX DOS 0 DECANEDIOIC ACID, BIS(2ETHYLHEXYL) ESTER 0 DI(2ETHYLHEXYL)SEBACATE 0 DIOCTYL SEBACATE 0 DOS 0 2-ETHYLHEXYL SEBACATE 0 MONOPLEX DOS 0 OCTOIL S 0 OCTYL SEBACATE 0 PX 438 0 STALFLEX DOS 0 UNIFLEX DOS
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
ingestion and intravenous routes. See also ESTERS. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, C02, dry chemical. When heated to decomposition it emits acrid and irritating fumes.
BJT250 CAS: 2440-45-1 HR: 3 BIS(ETHYLMERCUR1)PHOSPHATE mf: C4HllHg204P mw: 555.30 PROP: Solid. IDLH 10 mg/m3 (as Hg). SYNS: ETHYLMERCURIC PHOSPHATE 0 ETHYLhIERCURY PHOSPHATE 0 LIGNASAN FUNGICIDE 0 LIGNASAN-X 0 NEW' IMPROVED CERESAN 0 XEW IMPROVED GRANOSAK
CONSENSUS REPORTS: Mercury and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.01 mg(Hg)/m3; STEL 0.03 mg/m3 (skin) ACGIH TLV: TWA 0.01 mg(Hg)/m3; BEI: 35 pg/g creatinine total inorganic mercury in urine preshift; 15 pg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Poison by ingestion and subcutaneous routes. See also MERCURY COMPOUNDS, ORGANIC. An experimental teratogen. When heated to decomposition it emits very toxic fumes of Hg and PO,.
BJT800 CAS: 18771-38-5 HR: 3 BIS(ETHYLTHI0)METHYLENE MALONONITRILE mf: CsHioNzSz mw: 198.32 SYNS: CP 26890 (BIS(ETHYLTHI0)METHYLENE)PROPANEDINITRILE 0 MALONONITRILE,CARBONYL-,DIETHYL MERCAPTOLE 0 PROPANEDINITRILE, (BIS(ETHYLTHI0)METHYLENE)-
SAFETY PROFILE: A poison by ingestion
and s h n contact. A severe eye irritant. When heated to decomposition it emits toxic vapors of NO, and SO,. BJ UOOO CAS: 502-55-6 HR: 3 BIS(ETHYLXANTH0GEN) DlSULFlDE mfi C6Hio0zS4 mw: 242.40 PROP: Yellow needles. Mp: 28-32'. SYNS: AULIGEN 0 BEK 0 BEXIDE 0 BEXT 0 BIETHYLXANTHOGENTRISULFIDE 0 BIS(ETHYLXANTH1C)DISULFIDE 0 DEX 0 DIETHYLDITHIO BIS~HIONOFORhUTE)0 DIETHYL DIXANTHOGEN 0 DIETHYL XAiiTHOGENATE 0 DIETHYLXANTH-
BISHYDROXYCOUMARIN BJZOOO OGEN DISULFIDE 0 DITHIOBIS(THIOFORM1C ACID)o,o-DIETHYLESTER 0 DIXANTHOGEN 0 ETHYL X4NTHOGEN DISULFIDE 0 EXD 0 K PREPARATION 0 THIOPEROXYDICARBONICACID DIETHYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact and possibly other routes. See also ESTERS and SULFIDES. When heated to decomposition it emits hghly toxic fumes of SO,.
BJW800 CAS: 4387-13-7 HR: 3 BIS(F0RMY LMETHYL) MERCURY mf: C4H6Hg02 mw: 286.69 PROP: Crystals from EtOH. Mp: 92-94'. IDLH 10 mg/m3 (as Hg). SYN MERCURIDIACETALDEHME OSHA PEL: CL 0.1 mg(Hg)/m3 (skin) ACGIH TLV: TWA 0.01 mg(Hg)/m3; BEI: 35 Fg/g creatinine total inorganic mercury in urine preshft; 15 Fg/g creatinine total inorganic mercury in blood at end of shft at end of workweek. DFG MAK: Confxmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Organomercury): TWA 0.01 mg/m3; STEL 0.03 mg/m3 (sktn) SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of Hg. BJW825 CAS: 5188-42-1 HR: 3 BI S(G UANI DI NIUM) CHROMATE mf: C Z H I O N ~ * C ~ H Z Omw: ~ 236.20 PROP: IDLH Ca [15 mg/m3 {as Cr(VI)}]. SYN: BIGUANIDINE, CHROMATE OSHA PEL: CL 0.1 mg(CrO$/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m3; Confirmed Human Carcinogen NIOSH REL: (Chromium(VI)) TWA 0.025 mg/m3; CL 0.05 mg/l5M SAFETY PROFILE: A confirmed carcinogen. Poison by intravenous route. When heated to decomposition it emits toxic fumes of NO, and Cr.
193
BJX800 CAS: 63270-67-7 HR: 3 BIS(1-HISTIDINAT0)MANGANESE TETRAHY DRATE mf: Ci2Hi6MflN604*4Hz0 mw: 435.36 SYNS: MANGANESE,BISQ-HISTIDINAT0)-, TETRAHYDRATE 0 iMAiGANESE, BISO-HISTIDINATON,O)-, TETRAHYDRATE
OSHA PEL: CL 5 mg(Mn)/m3 ACGIH TLV: TWA 5 mg(Mn)/m3 SAFETY PROFILE: Poison by an
unspecified route. When heated to decomposition it emits toxic fumes of NO, and Mn. BJZOOO CAS: 66-76-2 HR: 3 BISHYDROXYCOUMARIN mf: C19H1206 mw: 336.31 PROP: Very small crystals from cyclohexanone with a slight pleasant odor and bitter taste. Mp: 288-289'. Sol in alkali. SYNS: ACADYL 0 ACAVYL 0 ANTITROMBOSIN 0 BARACOUMIN 0 BHC 0 BIS(4-HYDROXYCOUMARIN-3=)METHANE 0 CUMA 0 CUMID 0 DICOUMARIN 0 DICOUMAROL 0 DICUMAN 0 DICUMARINE 0 DI-(4HYDROXI-3-C0UMARINYL)METHANE 0 DI-4-
HYDROXY-3,3'-METHYLENEDICOUMARIN 0 DUFALONE 0 KUMORAN 0 MELITOXIN 0 3,3'METHYLEEN-BIS(4-HYDROXY-CUMARINE) (DUTCH) 0 3,3'-METHYLEN-BIS(4-HYDROXY-CUMARIN)(GERMAN) 0
3,3'-METHYLENEBIS(4-HYDROXY-l,2-BENZOPYR-
ONE) 0 3,3'-METHYLENEBIS(4-HYDROXYCOUMARIN) 0
~,~'-METHYLENE-BIS(~-HYDROXYCOLJLMARINE)
(FRENCH) 0 3,3'-METILEN-BIS(4IDROSSI-CUMARINA) (ITALIAN) 0 TEMPARIN 0 TROMBOSAN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion,
subcutaneous, intravenous, and intraperitoneal routes. An experimental teratogen. Human reproductive effects by ingestion and possibly other routes: fetal death, unspecified developmental abnormalities, sullbirth, and unspecified neonatal effects. An anticoagulant. Excessive doses can cause hemorrhages. When heated to decomposition it emits acrid smoke and fumes. See also WARFARIN.
194
BKAOOO
BIS(4-HYDROXY-3-COUMARIN)ACETIC ACID ETHYL
BKAOOO CAS: 548-00-5 HR: 3 BlS(4-HYDROXY-3-COUMARIN) ACETIC ACID ETHYL ESTER mf: C22H1608 mw: 408.38 PROP: Amorphous or crystalline from Me2CO. Mp: 151" (amorphous), mp: 173' (crystalline). SYNS: BIS-3,3'-(4-HYDROXYCOUSMRISYL)ACETIC
AMIDE 0 LAUROYL DIETHANOWhlIDE 0 LAURYL DIETHANOLAhfIDE 0 LDA 0 LDE 0 MONAhlID 150LVC' 0 NCI-C55323 0 NINOL AA62 0 NINOL AA-62 EXTRA 0 NINOL 4821 0 ONYXOL 345 0 REWOMID DLMS 0 RICHAMIDE 6310 0 ROLANID CD 0 STANDAhlIDD LD 0 STEINAMID DL 203 S 0 SUPER AhfIDE L-9A 0 SYNOTOL L-60 0 UNAMIDE J-56 0 VARAMID ML 1
CONSENSUS REPORTS: Reported in EPA
ACID ETHYL ESTER 0 BIS-(4-HYDROXY-3-COUMhRIN- TSCA Inventory. YL)ETHYL ACET'4TE 0 BIS(4-HYDROXY-2-0x0-2H-1SAFETY PROFILE: Moderately toxic by BENZOPYRAii-3-YL)ACETICACID ETHYL ESTER 0 ingestion. When heated to decomposition BOEA 0 B.O.E.A. 0 3,3'-(CARBOXYMETHYLENE)BIS(4emits toxic fumes of NO,. See also HYDROXYCOUMARIN) ETHYL ESTER 0 DICUMACYL AMIDES. 0 ETHYL BISCOUMACETATE 0 ETHYL BIS(4HYDROXYC0UMARINYL)ACETATE 0 ETHYL BIS(4-
HYDROXY-3-C0UMARINYL)ACETATE 0
BKF250
CAS: 2784-94-3
it
HR: 3
ETHYLDICOUMAROL 0 ETHYLDICOUMAROL N',N'-BIS(2-HY DROXYETHYL)-N-METHACETATE 0 ETHYL-4,4'-DIHYDROXYDICOUMARINYLY L-2-NITRO-p-PHENYLENEDl AMlNE 3,3'-ACETATE 0 NEODICOUIclrZRIN 0 NEODImf: CllH17N304 mw: 255.31 COUhlAROL 0 NEODICUMARINUhl 0 PELENTAN 0 SYNS: HC BLUE 1 0 NCI-C04159 STABILENE 0 TROhfBARIN 0 TROMBIL 0 CONSENSUS REPORTS: IARC Cancer TROMBOLYSAN 0 TROlMEXrW 0 TROMEXAN E T H n ACETATE Review: Group 2B IMEMDT 57,129,93;
SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. An experimental teratogen. Human reproductive effects by ingestion: developmental abnormalities of the cardiovascular system, stillbirth, and unspecified neonatal effects. An anticoagulant. See also WARFARIN and ESTERS. When heated to decomposition it emits acrid and irritating fumes.
BKESOO CAS: 120-40-1 HR: 2 N,N-BIS(2-HYDROXYETHY L)DODECAN AMIDE mf: C16H33N03 mw: 287.50 PROP: Solid. Mp: 36" SYNS: BIS(2-HYDR0XYETHYL)LAURAMIDE0 N,NBIS(HYDR0XYETHYL)LAURAhiIDE 0 N,N-BIS(PHYDR0XYETHYL)LAURAMIDE 0 N,N-BIS(2HYDROXYETHYL)L4LRhMIDE 0 CLINDROL l0lCG 0 CLISDROL SUPERAiMIDE lO0L 0 COCO DIETHANOLAhlIDE 0 COCONUT OIL AhfIDE of DIETHANOLAhIINE 0 COhiPERWN LD 0 CONDENSATE PL 0 CRILLON L D.E. 0 DIETHANOLLAURAMIDE 0 N,NDIETHANOLWURAiifIDE 0 N,K-DIETHANOLLAURIC ACID AhfIDE 0 EMID 6511 0 EMID 6541 0 ETHYLAN MLD 0 HETAMIDE ML 0 LAURAhfIDE DEA 0 LAURIC ACID DIETHANOLAhfIDE 0 LAURIC DIETHANOL-
Animal Sufficient Evidence IMEMDT 57,129,93; Human Inadequate Evidence IMEMDT 57,129,93. NTP Carcinogenesis Studies (feed); Some Evidence: rat NTPTR* NTP-TR-271,85; (feed); Clear Evidence: mouse NTPTR* NTP-TR-271,85. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. Mutation data reported. See also M I N E S . When heated to decomposition it emits toxic fumes of NO,. BKHSOO CAS: 794-93-4 HR: 3 BIS(HYDROXYMETHYL)FURATRIZINE mf: C I I H I I N ~ O ~ mw: 293.27 PROP: Yellow crystals. Mp: 161' (decomp). SYNS: 3-BIS(HYDROXYMETHYL)AMlNO-6-(5-NITRO2-FURYLETHENYL)-1,2,4-TRIAZINE 0 DHNT
0 3DI(HYDROXYMETHYL)~llNO-6-(5-NITRO-2-FUETHENYL)-1,2,4-TRMZINE0 3-DI(HYDROXYMETHYL)-
AMINO-6-(2-(5-NITRO-2-FCRYL)VlNYL)-l,2,4-TRL4ZINE DIHYDROXYMETHYL FURATRIZINE 0 FURATONE 0 FURATONE-S 0 N-(6-(5-NITROFURFURYLIDENE0
METHYL)-l,2,4-TRMZIN-3-YL)I;\IINODIMETHANOL 0 6-(5-SITRO-2-~~R~VI~YL)-3-~l~ROXYDl~~ETHYLrZIMINO)-l,2,4-TRIAZENE 0 N-(6-(2-(5-NITRO-2FURYL)VINYL)-l,2,4-TRZAZIN-3-YL)IMINODI~lETH;\NOL 0 ((6-(2-(5-NITRO-2-FURYL)VINYL)-as-TRL4ZIN-3YL)IMINO)DIMETHANOL0 PANFURAN-S
BIS(ISOOCTYLOXYCARB0NYLMETHYLTHIO) CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 24,77,80; Human No Adequate Data IMEMDT 24,77,80. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. Moderately toxic by ingestion, intraperitoneal, and subcutaneous routes. Mutation data reported. An antibacterial agent. When heated to decomposition it emits toxic fumes of NO,.
BKK750
195
ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds)
TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Moderately toxic by ingestion. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of SO,. BKKSOO CAS: 26636-01-1 HR: 2 BIS(ISO0CTYLOXYCARBONYLMETHYL THI0)DIMETHYLSTANNANE mf: C22H~04SzSn mw: 555.47
BKJ275 CAS: 15702-65-5 HR: 3 BIS(8-HYDROXYQUINOLINE-5SULFONIC ACID) MANGANESE(I1) mf: C18H12N20&*Mn mw: 503.38
SYNS: BIS(2ETHYLHEXYLOXYCARBONYETHYLTHI0)DIMETH YLSTANNANE 0 DIMETHYL-TIN BIS(ISOOCTYLTHI0GLYCOLLATE) 0 DIMETHYLZINN-S,S'-BIS(ISO0CTYL-THIOGLYCOLAT) (GERMAN)
SYNS: BIS(5-SVLFO-8-QUINOLINOLATO-K',08)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 ( s h ) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Moderately toxic by ingestion. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of SO,.
iMANGANESE(II) 0 MANGANESE, BIS(S-SULFO-8QUINOLINOLAT0)-
OSHA PEL: CL 5 mg(Mn)/m3 ACGIH TLV: TWA 5 mg(Mn)/m3 SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of NO,, SO,, and Mn.
BKJSOO CAS: 73816-43-0 HR: 3 BIS(3-INDOLEMETHYLENEMORPH0LINIUM)HEXA-CHLOROSTANNATE mf: C26H3oN402*C16Sn mw: 761.99 SYN: MORPHOLINIUM,(3-INDOLYLMETHYLENE)-, HEXACHLOROSTA"ATE(2-) (2:l) OSHA PEL: TWA 2 mg(Sn)/m3 ACGIH TLV: TWA 2 mg(Sn)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it
emits toxic fumes of NO,, Sn, and C1-.
BKK250 CAS: 25168-24-5 HR: 2 BIS(ISO0CTYLOXYCARBONYLMETHYL THI0)DIBUTYL STANNANE mf: C28H5604S2Sn mW: 639.65 SYNS: BIS(2ETHYLHEXYLOXYCARBONYLMETHYLTHI0)DlBUTYL STANNANE 0 DIBUTYL-TIN BIS(ISOOCTYLTHI0GLYCOLLATE) 0 DIBUTnZINN-S,S'-BISQSOOCTYLTHIOGLYCOLAT) (GERMAN)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin)
BKK750 CAS: 26401-97-8 HR: 2 BIS(ISOOCTYLOXYCARB0NYLMETHYL THI0)DIOCTYL STANNANE mf: C36H7204S2Sn mw: 751.89 SYNS: ADVASTAB 17 h I 0 0 BIS(MERCAPTOACETATE)DIOCT(LTINBISQSOOCTYL) ESTER 0 DIISOOCTYL ((DIOCTYLSTANNYLENE). DITHI0)DIACETATE 0 DIOCTYLTIN BIS(ISO0CTYL MERCAPTOACETATE) 0 DIOCTYLTIN-S,S'BISQSOOCTYLMERCAPTOACETATE) 0 DIOCTYLTIN BIS(ISO0CTYLTHIOGLYCOLATE) 13 DIOCTYL-TIN BIS(ISOOCTYLTHIOGLYC0LLATE) 0 DI-n-OCTYLTIN DIISOOCTYLTHIOGLYCOLATE 0 DI-n-OCTYL-ZINNDI-ISOOCTYLTHIOGLYKOLAT(GERMAN) 0 DOTG 0 THERMOLITE 831
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
196
BKLOOO
BIS(lSO0CTYLOXYMALEOYLOXY)DIOCTYL
DFG MAK: 0.1 mg(Sn)/m3 calculated as total
dust NIOSH REL: (Organotin Compounds) TWA
0.1 mg(Sn)/m3 SAFETY PROFILE: Moderately toxic by ingestion and skin contact. An experimental teratogen. See also TIN COMPOUNDS and MERCAPTANS. When heated to decomposition it emits toxic fumes of SO,.
BKLOOO CAS: 33568-99-9 HR: 2 BIS(ISO0CTYLOXYMALEOYL0XY)DIOC TYLSTANNANE mf: C40H720sSn mw: 799.81 SYNS: (Z,Z)-BIS((3CARBOXYACRYL0YL)OXY)DIOCTYL-STANN ANE DIISOOCTYL ESTER (8CI) 0 (Z,Z)-4,4'-((DIOCTYL-
STANNYLENE)BIS(OXY))BIS(4-OXO-2-BUTANOIC ACID) DIISOOCTYL ESTER 0 DIOCTYLTINBIS(ISO0ClTL MALEATE)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (sktn) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (shn). DFG MAK: 0.1 mg(Sn)/m3 calculated as total dust NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn) /m3 SAFETY PROFILE: Moderately toxic by ingestion. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
BKL250 CAS: 7287-19-6 HR: 2 2,4-BIS(ISOPROPY LAMINOh6-METHYLMERCAPTO-S-TRIAZINE mf: CIOHWN~S mw: 241.40 PROP: Solid. Mp: 118-120". Very sltly sol in H20.
SYNS: 4 ,6 - B I S ( I S O P ROP~~l INO)-2-hl E T HnMERCAPTO-s-TUZISE 0 2 , 4 - B I S ~ S O P R O P ~ f I N O ) 6-METHYLTHIO-s-TRWZIXE0 2,4-BIS(ISOPROPYLAhlINO)-6-METHYLTHIO-l,3,5-TRIAZINE 0 N,N'-BIS(1METHYLETHYL)-6-bfETHn-THIO-1,3,5-TRIAZINE-2,4DIAhfINE 0 CAPAROL 0 G 34161 0 GESAGARD 0 MERKAZIN 0 2-hlETHYLMERCAPTO-4,6-BIS(ISOPROPYLAhfINO)-s-TRZAZINE0 2-METHYLTHIO-4,GBIS(IS O P R O P ~ C I ~ O) -s-T R IAZ INE C l POLISIN D PRIMd4TOLQ 0 PROVETREX 0 PROMETRIN 0
PROIMETRYN 0 PROMETRYKE (LiSDA) 0 SELEKTIN 0 SESAGARD
SAFETY PROFILE: Moderately toxic by
ingestion. Experimental reproductive effects. An eye irritant. Mutation data reported. An herbicide. When heated to decomposition it emits very toxic fumes of NO, and SO,. See also MERCAPTL4NS.
BKL750 CAS: 3006-93-7 HR: 3 1,3-BISMALEIMIDO BENZENE mf: C14H8N204 mw: 268.24 SYNS:
1,3-D1~4LEIMIDOBENZENED HVA 2 0 HVA2 CURING AGENT 0 M-PHDM 0 N,N'-(m-PHENXENE)BISX4LEIMIDE 0 1,l'-(m-PHENXENE)BIS-IHPYROLE-2,5-DIONE(9CI) 0 N,N'-(m-PHENYLENEDIMALEIMIDE)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion, inhalation, and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NO,.
BKMSOO CAS: 1187-00-4 HR: 3 BIS(METHANE SULF0NYL)-d-MANNITOL mf: C8H18010S2 mW: 338.38 SYNS: 1,6-BIS-o-METHYLSULFONYL-d-MANNITOL 0 CB 2511 0 1,6-DI?rlESYL-d-MNITOL I3 1,6DIMETHANESULFONATE-d-MANNITOL 0 1,6DIMETHANE-SULFONOXY-d-MANNITOL 0 1,6-
DIMETHANESULPHONOXY-l,6-DIDEOXY-dMANNITOL 0 DMM 0 d-MANNITOLBUSULFAN 0 MANNITOL MYLERAN 0 MANNOGRANOL 0 MM 0 NSC-37538
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intravenous route. Moderately toxic by intraperitoneal route. Wdly toxic by ingestion. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of SO,.
BK0250 CAS: 15546-11-9 HR: 3 BIS(METHOXYMALE0YL0XY)DIBUTYL STANNANE mf: C18H280&1 mw: 491.15
N,N-BISMORPHOLINE DISULFIDE BKUSOO 197 SYNS: DIBUTYLBIS((3-CARBOXYACRYLOYL)OXY)STAYNANE DIMETHYL ESTER (Z,Z) (8CI) 0 DIBUTYLTIN BIS(METHYL MALEATE) 0 DIBUTYLTIN BIS(MON0METHYL MALEATE) 0 DIBUTYLTIN METHYL MALEATE 0 6,6-DIBUTYL-4,8,11-TRIOXO5,7,12-TRIOXA-6-STANNATRIDECA-2,9-DIENOIC ACID METHYL ESTER 0 DI-n-BUTYLZINN-DIMONOMETHYLMALEINAT (GERMAN) 0 STAN-GUARD 156
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes. BKS640 CAS: 81877-66-9 HR: 3 1,2:5,6-BIS-0-(1 -METHYLETHYL1DENE)a-d-GLUCOFURANOSE, ((((24DIMETHYLAMINO)-2-0x0-1 (METHYLTH10)ETHYLIDENE)AM INO) 0XY)CARBONYL)METHYLAMIDOSULFITE mf: C I ~ H ~ I N ~ O I O mw: S ~ 525.65 SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO, and SO,.
-
BKS810 CAS: 3810-81-9 HR: 3 BIS(METHYLMERCUR1C)SULFATE mf: C2H6Hg204S mw: 527.32 PROP: Platelets from water. Sltly sol in EtOH. Mp: 255' (decomp). SYNS: ARETAN-NIELW 0 B 4992 0 BIS-(METHYL iMERCURY)-SULFATE 0 BIS-(METHYLMERKURISULFAT 0 CERESAN UNIVERSAL-FEUCHTBEIZE 0 CEREWET 0 COMPOUND-4992 0 MERCURY, SULFATOBIS(METHYL- 0 METHYLMERCURIC SULFATE 0 SULFURIC ACID, BIS(METHYLbfERCURY) SALT
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Poison by ingestion. When heated to decomposition it emits toxic fumes of SO, and Hg.
BKT300 CAS: 63942-42-7 HR: 3 N,N'-BIS(2-METHYLSULFONYL-2METHYLPROPIONALDEHYDE-o-(NMETHYLCARBAMOYL)OXIME)SULFIDE mf: C14H26N40& mw: 474.62 SYN
PROPANAL, 2-METHYL-2-@ETHYLSULFONYL)o,o'-(THIOBIS((METHYL1MINO)CARBONYL))DIOXIME
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO, and SO,.
BKUl2O CAS: 63942-44-9 HR: 3 N,N'-BIS(l -METHYLTHIO-1-(N,N-DIMETHYLCARB0NYL)FORMALDEHYDE-o-(N-METHYLCARBAM0YL)OXIME)SULFIDE mf: C14H24N606S3 mW: 468.62 SYN ETHANIMIDOTHIOIC ACID, N,N'(THIOBIS((METHYLAiiINO)CARBONYLOXY))BIS(2(DIMETHyLAMINO)-2-OXO-, DIMETHYL ESTER
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO, and SO,.
BKUSOO CAS: 103-34-4 HR: 3 N,N'-BISM0RPH0LINE DISULFIDE mf: C8H16N202S2 mw: 236.38 PROP: Tan to gray powder or crystals. Mp: 124-125', d: 1.36 @ 25'. SYNS: ACCEL R 0 BISMORPHOLINO DISULFIDE 0 DIMORPHOLINE DISULFIDE 0 DIMORPHOLINO DISULFIDE 0 DITHIOBISMORPHOLINE 0 4,4'DITHIOBIS(MORPH0LINE) 0 N,N-DITHIODIMORPHOLINE 0 4,4'-DITHIODIMORPHOLINE 0 4,4'DITHIOMORPHOLINE 0 MORPHOLINE DISULFIDE 0 MORPHOLINODISULFIDE 0 SULFASAN 0 SULFASAN R POWDER 0 USAF B-17 0 USAF EK-T-6645
OSHA PEL: TWA 0.01 mg(Hg)/mj; STEL
CONSENSUS REPORTS: Reported in EPA
0.03 mg/mj (skin) ACGIH TLV: TWA 0.01 rng(Hg)/mj; BEI: 35 pg/g creatinine total inorganic mercury in urine preshift; 15 Fg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion. Mutation data reported. See also MORPHOLINE. When
198
BKU750
BISMUTH
heated to decomposition it emits very toxic fumes of NO, and SO,. BKU750 CAS: 7440-69-9 HR: 3 BISMUTH af: Bi aw: 208.98 PROP: Hexagonal silver-white or reddish metahc crystals. Mp: 271.3', bp: 1420-1560', d: 9.80, vap press: 1 mm @ 1021'. SYN: BISMUTH-209 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poisonous to humans. See also BISMUTH COMPOUNDS. Flammable when exposed to flame. Reaction with [Bi(OH)3 + Al(OH)3], coprecipitated and H2 reduced produces a spontaneously flammable product. Moderately dangerous, can react with acid or acid fumes to emit toxic fumes. Incompatible with Al, BrF3, acids, NOF, NH4NO3, HC103, Clz, IF5, HN03, HC104. BKV750 HR: 3 BISMUTH COMPOUNDS SAFETY PROFILE: Bismuth and its salts can cause kidney damage, although the degree of such damage is usually mild. Large doses can be fatal. Industrially it is considered one of the less toxic of the heavy metals, although intoxication has occurred from its use in medicine. The sirmlarity between the pharmacologc and toxic behavior of lead and bismuth has been pointed out in the literature. Like lead, bismuth may be liberated from tissue deposits during periods of acidosis. Serious and sometimes fatal poisoning may occur from the injection of large doses into closed cavities and from extensive application to burns. Death of animals from bismuth nephritis following injections of soluble salts occurs w i t h several hours to 24 days, the time being generally inversely proportional to the dose, and it appears to be in the order of 5-10 times hgher than the dose by slow intravenous injection for rabbits. It is stated
that the administration of bismuth should be stopped when gingivitis appears, for otherwise serious ulcerative stomatitis is likely to result. Other toxic results may develop, such as malaise, albuminuria, diarrhea, skin reactions, and sometimes serious exodermatitis. Industrial bismuth poisoning has not been reported, although bismuth absorbed in industrial cases may complicate a diagnosis of plumbism, since the dark line in the gums, which is often present in lead poisoning, is also produced by bismuth. All bismuth compounds do not have equal toxicity. See also individual entries. Treatment and Antidotes: Personnel showing some of the symptoms noted above, which might indcate that they were absorbing too much bismuth into the body, should be removed from exposure as soon as possible. Get medical advice. Personnel should be cautioned against careless handling of these materials. BKWOOO CAS: 21260-46-8 HR: 1 BISMUTH DIMETHYL DITHIOCARBAMATE mf: C ~ H I ~ N ~ S ~ *mw: B ~569.64 SYNS: BISMATE 0 TRIS(DIMETHYLDITHI0CARBAMAT0)BISMUTH
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low toxicity by ingestion. Questionable carcinogen with experimental tumorigenic data. See also BISMUTH COMPOUNDS and CARBAMATES. When heated to decomposition it emits very toxic fumes of SO, and NO,.
BKW250 CAS: 10361-44-1 HR: 3 BISMUTH NITRATE mf: Bfl309 mw: 395.01 PROP: Triclinic, colorless, sltly hygroscopic crystals. Bp: -5H20 @ 80°, d: 2.83, mp: 30' (decomp). SYN: NITRIC ACID, BISMUTH(3+) SALT CONSENSUS REPORTS: Reported in EPA TSCA Inventory.
BIS(8-0XYQUINOLINE)COPPER SAFETY PROFILE: Poison by intravenous route. Moderately toxic by intraperitoneal route. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of Bi and NO,. See also BISMUTH COMPOUNDS and NITRATES,
BKYOOO CAS: 1304-82-1 HR: 3 BISMUTH TELLURIDE mf: BizTe3 mw: 800.76 PROP: Gray crystals or solid. D: 7.7. SYNS: BISMUTH SESQUITELLURIDE 0 BISiMUTH TELLURIDE, UNDOPED
BLC250 199
ZIRCONIUM COMPOUNDS and NITRATES. When heated to decomposition it emits toxic fumes of NO,. BLCOOO CAS: 868-18-8 HR: 2 BlSODlUM TARTRATE mf: C4H406*2Na mw: 194.06 PROP: Transparent crystals; colorless and odorless. Sol in water. SYNS: 2,3-DIHYDROXY-(T-(R*,R*))-BUTANEDIOIC ACID DISODIUM SALT ( 9 0 0 DISODIUM TARTRATE 0 DISODIUM I-(+)-TARTRATE 0 SODIUM TARTRATE (FCC) SODIUM 1-(+)-TARTRATE
CONSENSUS REPORTS: Reported in EPA
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: Total Dust: TWA 0.1 mgpe)/m3; Respirable Fraction: TWA 5 mg/m3; Se doped: 5 mg/m3 ACGIH TLV: TWA 10 mg/m3; Not Classifiable as a Human Carcinogen; Se doped: 5 mg/m3; Not Classifiable as a Human Carcinogen SAFETY PROFILE: Moderate fire hazard by spontaneous chemical reaction with powerful oxidzers. Reacts with moisture to evolve a toxic gas. Slight explosion hazard by chemical reaction with powerful oxidners; reacts with moisture. When heated to decomposition it emits toxic fumes of Te. See also BISMUTH COMPOUNDS and TELLURIUM COMPOUNDS.
TSCA Inventory.
BLAOOO CAS: 13826-66-9 HR: 2 BIS(NITRATO-0)OXOZIRCONIUM mf: Nz07Zr mw: 231.24 PROP: IDLH 50 mg/m3 (as Zr). SYN: ZIRCONYL NITRATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3 ACGIH TLV: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr) /m3 DFG MAK: 1 mg(Zr)/m3 SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. See also
SAFETY PROFILE: Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes.
BLC250 CAS: 10380-28-6 HR: 3 BlS(8-0XYQUlNOLINE)COPPER mf: C18H12CuN202 mw: 351.86 PROP: Yellow-green powder or crystals. Insol in Hz0 and common org solvs. SYNS: BIOQUIN 0 BIOQUIN 1 0 BIS(8QUINOLINAT0)COPPER 0 BIS(8-QUINOLINOLAT0)COPPER 0 BIS(8-QUINOLINOLATO-N1,08)COPPER 0 CELLU-QUIN 0 COPPER-8 0 COPPER HYDROXYQUINOLATE 0 COPPER-8-HYDROXYQUINOLATE 0 COPPER-8-HYDROXYQUINOLINATE0 COPPER-8-HYDROXYQUINOLINE0 COPPER OXINATE 0 COPPER (2+) OXINATE 0 COPPER OXINE 0 COPPER OXYQUINOLATE 0 COPPER OXYQUINOL INE 0 COPPER QUINOLATE 0 COPPER-8-QUINOLATE COPPER-8-QUINOLINOL 0 COPPER QUINOLINOLATE 0 COPPER-8-QUINOLINOLATE 0 CUNILATE CUNILATE 2472 0 CUPRIC-8-HYDROXYQUINOLATE 0 CUPRIC-8-QUINOLINOLATE DOKIRIN 0 FRUITDO 0 8-HYDROXYQUINOLINE COPPER COMPLEX 0 MILiiER 0 OXME COPPER 0 OXINE COPPER 0 OXINE CUIVRE 0 OXYQUINOLINOLEATE de CUIVRE (FRENCH) 0 QUINONDO
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 15,103,77. Reported in EPA TSCA Inventory. Copper and its compounds are on the Community Right-To-Know List. EPA FIFRA 1988 pesticide subject to registration or reregistration.
200
BLDOOO
BISPENTAFLUOROSULFUR OXIDE
SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion and inhalation. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. See also COPPER COMPOUNDS. When heated to decomposition it emits toxic fumes of NO,.
BLDOOO CAS: 42310-84-9 HR: 3 BISPENTAFLUOROSULFUROXIDE mf: FloOSz mw: 270.12 PROP: Colorless liquid. Mp: -118O, bp: 31'. SYN: SULFUR FLUORIDE OXIDE OSHA PEL: TWA 2.5 mgm/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3
mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift. NIOSH REL: TWA 2.5 mg(F)/m3 SAFETY PROFILE: Poison by inhalation. See also FLUORIDES. When heated to decomposition it emits very toxic fumes of F- and SO,. BLD500 CAS: 80-05-7 HR: 3 BISPHENOL A mf: CljH1602 mw: 228.31 PROP: White flakes; mild phenolic odor. Mp: 156-157', bp: 250-252' @ 13 mm. Insol in water; sol in alcohol and dilute alkalies; sltly sol in CC4. SYNS: BISFEROL A (GERMAN) 0 2,2-BIS-4'HYDROXYFENYLPROPAN (CZECH) 0 BIS(4HYDROXYPHENYL) DIMETHYLMETHANE 0 BIS(4HYDR0XYPHENYL)PROPANE 0 2,2-BIS@HYDR0XYPHENYL)PROPANE 0 2,2-BIS(4HYDR0XYPHENYL)PROPANE 0 DIAN 0 p,p'DIHYDROXYDIPHENYLDIMETHYLMETHANE 0 4,4'DIHYDROXiDIPHENYLDIMETHYLMETHANE 0 p,p'DIHMROXMIPHENYLPROPANE 0 2,2-(4,4'DIHYDROXYD1PHENYL)PROPANE 0 4,4'DIHYDROXYDIPHENYLPROPANE 0 4,4'DIHYDROXYDIPHENYL-2,2-PROPANE 0 4,4'DIHYDROXY-2,2-DIPHENYLPROPANE 0 P-DI-pHYDROXYPHENYLPROPANE 0 2,2-D1(4HYDR0XIPHENYL)PROPANE 0 DIMETHYL BIS@HYDR0XYPHENYL)METHANE 0 DIMETHYLMETHYLENE-p,p'-DIPHENOL 0 2,2-DI(4-PHENYLOL)PROPANE 0 p,p'-ISOPROPYLIDENE-BISPHENOL 0 4,4'ISOPROPYLIDENEBISPHENOL 0 p,p'ISOPROPYLIDENEDIPHENOL 0 NCK50635
CONSENSUS REPORTS: NTP Carcinogenesis Bioassay (feed); Inadequate Studies: mouse, rat NTITR* NTP-TR21 5,82. Community Right-To-Know List. Reported in EPA TSCA Inventory. DFG MAK: 5 ppm SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion, inhalation, and skin contact. Experimental teratogenic and reproductive effects. A skin and eye irritant. When heated to decomposition it emits acrid and irritating fumes.
BLD750 CAS: 1675-54-3 HR: 3 BISPHENOL A DIGLYCIDYL ETHER mf: Cz1H2404 mw: 340.45 SYNS: 2,2-BIS(4-(2,3EPOXYPROPYL0XY)PHENYL)PROPANE 0 BIS(4GLYCIDYL0XkTHENYL)DIMETHYLAMETHANE 0 2,ZBIS@-GLYCIDYL0XYPHENYL)PROPANE0 BIS(4HYDR0XYPHENYL)DIMETHYETHANE DIGLYCIDYL ETHER 0 2,2-BIS(p-HYDROXYPHENYL)PROPANE, DIGLYCIDYL ETHER 0 2,2-BIS(4HYDROXYPHENYL)PROPANE, DIGLYCIDYL ETHER 0 D.E.R 332 0 DIGLYCIDYL BISPHENOL A ETHER 0 DIGLYCIDYL ETHER of 2,2-BIS@-HYDROXYPHENYL)PROPANE 0 DIGLYCIDYL ETHER of 2,2-BIS(4HYDR0XYPHENYL)PROPANE 0 DIGLYCIDYL ETHER of BISPHENOL A 0 DIGLYCIDYL ETHER of 4,4'ISOPROPYLIDEKEDIPHENOL 0 4,C-DIHYDROXYDIPHENYLDIMETHYLMETHANE DIGLYCIDYL ETHER 0 p,p'-DIHYDROXYDIPHEPYLDIMETHYLiMETH ANE DIGLYCIDYL ETHER 0 EPI-REZ 508 0 EPI-RE2 510 0 EPON 828 0 EPOXIDE A 0 ERl-2774 0 4,4'ISOPROPYLIDENEDIPHENOL DIGLYCIDYL ETHER 0 2,2'-((1-,\IETHYLETHYLIDENE)BIS(4,1PHENYLENE0XYMETHYLENE))BISOXIRANE
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Suspected carcinogen. Poison by s h contact. Mildly toxic by ingestion. Mutation data reported. A s h n and severe eye irritant. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic and tumorigenic data. See also ETHERS. When heated to decomposition it emits acrid and irritating fumes.
BIS(TRIETHYL TIN) SULFATE
BLNSOO 201
BLE5OO CAS: 74-31-7 HR: 3 1,4-BlS(PHENYL AMIN0)BENZENE mf: C I ~ H I ~ N mw: ~ 260.36 PROP: Gray crystals or solid. D: 1.20, mp: 147O, vap d: 9.0.
BLL750 CAS: 56-35-9 HR: 3 BIS(TRIBUTYL TIN)OXIDE mf: C24H540Sn2 mw: 596.16 PROP: Air-sensitive liquid. D: 1.17 @ 2Oo/4O, bp: 220-230' @ 10 mm.
SYNS: AGERITE 0 AGERITEDPPD 0 N,N'-DIFENYLp-FENYLENDIAMIN (CZECH) 0 DIPHENYLpPHENYLENEDIAMINE 0 N,N'-DIPHENYL-pPHENYLENEDIAMINE 0 DPPD 0 FLEXAMINE G 0 JZF 0 NONOX DPPD 0 p-PHENYLAMINODIP H E N W I N E 0 4-PHENYLAMINODIPHENYINE 0 USAF GY-2
SYNS: BIOMET TBTO 0 BIS-(TRI-N-BUTYLC1N)OXID
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. A weak allergen. Experimental teratogenic and reproductive effects. An eye irritant. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Combustible when exposed to heat or flame; can react with oxidizing materials. When heated to decomposition it emits toxic fumes of NO,.
BLKOOO CAS: 128-80-3 HR: 2 1,4-BlS(p-TOLYLAMINO)ANTHRAQUINONE mf: C28H~N202 mw: 418.52 PROP: Dark green crystals or powder. Sol in C6H6 or acids; sltly sol in MezCO; insol in H2O and EtOH. SYNS: ALIZARINE CYANINE GREEN BASE 0 AiMAPLAST GREEN OZ 0 ARLOSOL GREEN B 0 BIS1,4-p-TOLYLAMINOANTHRCHINON (CZECH) 0 CGREEN 10 0 C.I. 61565 0 C.I. SOLVENT GREEN 3 0 CYANINE GREEN G BASE 0 D&C GREEN No. 6 0 1,4DI-p-TOLUIDINOANTHRAQUINONE 0 FAT SOLUBLE GREEN ANTHRAQUINONE 0 11091 GREEN 0 GREEN No. 2 0 MICRO-LEX GREEN 5B 0 NITRO FAST GREEN GB 0 ORGANOL FAST GREEN J 0 QUINIZARINE GREEN BASE 0 SUDAN GREEN 4B 0 TOY0 ORIEBTAL OIL BLUE G 0 WAXOLIBE GREEB CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. An eye irritant. When heated to decomposition it emits toxic fumes of NO,.
(CZECH) 0 BIS(TRIBUTYL0XIDE) of TIN 0
BIS(TRIBVTYLSTANNYL)OXIDE0 BISVRI-NBUTYLZ1NN)-OXYD (GERMAN) 0 BTO 0 BUTINOX 0 C-Sn-9 0 ENT 24,979 0 HEXABUTYLDISTANNOXANE 0 HEXABUTYLDITIN 0 KYSLICNIK TRI-NBUTYLCINICITY (CZECH) 0 L.S. 3394 0 OTBE (FRENCH) 0 OXYBIS(TRIBUTYLTIN) 0 OXYDE de TRIBUTYLETAIN 0 TBOT 0 TBTO 0 TRI-n-BUTYLSTANNANE OXIDE 0 TRIBUTYLTIN OXIDE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). DFG MAK: 0.0021 ppm (0.05 mg/m3) NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: A poison by ingestion, intraperitoneal, and intravenous routes. Moderately toxic by skin contact. An experimental teratogen. Other experimental reproductive effects. Questionable carcinogen with experimental carcinogenic data. Mutation data reported. A severe eye irritant. See also TIN COMPOUNDS. When heated to decomposition it emits acrid and irritating fumes.
BLN500 CAS: 57-52-3 HR: 3 BIS(TR1ETHYL TIN) SULFATE mf: C12H3004SSn2 mw: 507.86 SYNS: TRIAETHYLZINNSULFAT (GERMAN) 0 TRIETHYLHYDROXY-STANNANESULFATE (2:l) (SCl) 0 TRIETHYLHYDROXYTIN SULFATE 0 TRIETHnTIN SULPHATE OSHA PEL: TWA 0.1 mg(Sn)/m3 ( s h ) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion, intraperitoneal, subcutaneous, intravenous, and parenteral routes. See also TIN COMPOUNDS and SULFATES. When
202
BLQ525 BIS(TRIFLUOROMETHYLTHIO)-MERCURY
heated to decomposition it emits toxic fumes of SO,. BLQ525 CAS: 21259-75-6 HR: 3 BlS(TRIFLUOROMETHYLTHI0)MERCURY mf: C2F6HgS2 mw: 402.73 SYN: MERCURY, BIS(TRIFLUOROMETHYLTHI0)ACGIH TLV: TWA 0.01. STEL 0.03 mg/m3
(shn) NIOSH REL: (MERCURY, ORGANO) TWA 0.01 mg/m3. STEL 0.03 mg/m3 (Sk) SAFETY PROFILE: A poison by intravenous route. When heated to decomposition it emits toxic vapors of SO, and Hg.
BLS250 CAS: 14264-16-5 HR: 3 BlS(TRIPHENYLPH0SPHINE)DICHLORONICKEL mf: C~H54Pz*C12Ni mw: 534.33 SYNS: BIS(TRI-NBUTYLPH0SPHINE)DICHLORONICKEL 0 TRIBUTYLPHOSPHINE compounded with NICKELCHLORIDE (2:l)
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. Reported in EPA TSCA Inventory. Nickel and its compounds are on the Community Right-To-Know Lst. OSHA PEL: TWA 0.1 mg (Ni)/m3 ACGIH TLV: TWA 0.2 mg(Ni)/m3; Human Carcinogen) SAFETY PROFILE: Confirmed human carcinogen. Poison by intravenous route. See also NICKEL COMPOUNDS. When heated to decomposition it emits very toxic fumes of C1- and PO,.
BLS750 CAS: 1624-02-8 HR: 2 BIS(TRIPHENYL S1LYL)CHROMATE mf: C36H30Cr04Si2 mw: 634.84 PROP: IDLH Ca [l5 mg/m3 {as Cr(VI))]. SYN: CHROMIC ACID, BIS(TRIPHENYLS1LYL) ESTER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Chromium and its compounds are on the Community RightTo-Know List. OSHA PEL: CL 0.1 mg(CrO$/m3 ACGIH TLV: TWA 0.05 mg(CrOs)/m3
NIOSH REL: (Chromium(VI)): TWA 0.025
mg(CrO)/m3; CL 0.05/15M SAFETY PROFILE: Moderately toxic by ingestion and skin contact. See also CHROMIUM COMPOUNDS and ESTERS. When heated to decomposition it emits toxic fumes of CrO3 particulates. BLS900 CAS: 73940-87-1 HR: 3 BIS(TR1PHENYLTIN)ACETYLENEDICAR BOXYLATE mf: C40H3004Sn2 mw: 812.08 SYNS: ETHYNYLENEBIS(CARBONYLOXY)BIS(TRIPHENYLSTA NNANE) 0 STANNANE,ETHYNYLENEBIS(CARB0NYLOXY)BIS(TRIPHENYL-
OSHA PEL: TWA 0.1 mg(Sn)/m3 ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg/m3 (sktn) NIOSH REL: (Organotin compound): 10H TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of Sn. BLT300 CAS: 1067-29-4 HR: 3 BIS(TRIPR0PYLTIN)OXIDE mf: ClgH420Sn2 mw: 511.98 PROP: Air-sensitive liquid. Bp: 154.5' @ 3.5 mm. SYNS: DISTANNOXANE, 1,1,1,3,3,3-HEXAPROPYI-0 1,I ,I ,3,3,3-HEXAPROPYLDISTANNOXANE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg/m3 (skin) NIOSH REL: (Organotin Compound): 10H TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of Sn.
BLT775 CAS: 38402-95-8 HR: 3 BIS(TRIS(p-DIMETHYLAMINOPHENYL)PHOSPHINE 0XIDE)STANNIC CHLORIDE COMPLEX mf: C4gH60N602P2*C14Sn mw: 1075.57 SYN: PHOSPHINE OXIDE, TRIS@-DIMETHYLAMINOPHENYL)-, compounded with STANNIC CHLORIDE (2:l)
BLADEX OSHA PEL: TWA 2 mg(Sn)/m3 ACGIH TLV: TWA 2 mg(Sn)/m3 SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of NO,, PO,, Sn, and C1-. BLUOOO CAS: 13356-08-6 HR: 2 BIS(TRIS(P,P-DIMETHY LPHENETHYL)TIN)OXIDE mfi C6oH780Sn2 mw: 1052.76 PROP: Crystals or powder. Sol in CHCl3, C6H6. Sltly sol in MezCO; insol in Hz0. SYNS: BENDEX 0 BISpRIS(2-METHYL-2PHENYLPR0PYL)TIN)OXIDE 0 DI(TRI-(2,2-DIMETHYL2-PHENYLETHYL)TIN)OXIDE0 ENT 27,738 0 FENBUTATIN OXIDE 0 HEXAKIS(P,P-DIMETHYLPHENETHYL)DISTANNOXANE0 HEXAKIS(2METHYL-2-PHENYLPR0PYL)DISTANNOXANE 0 SD 14114 0 SHELLSD-14114 0 TORQUE 0 VENDEX
OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/mj; STEL
0.2 mg(Sn)/mj (sktn). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Moderately toxic by ingestion and skin contact. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes. BLV250 CAS: 13394-86-0 (m,o'-BIT0LYL)-4-AMINE mf: C14HljN mw: 197.30 PROP: Oil. Bp: 201' @ 15 mm.
HR: 3
SYNS: 2',3-DIMETHYL-4-AMINOBIPHENYL 0 3,2'DIMETHYL-4-AMNOBIPHENYL 0 3,2'-DIMETHYL-4AMINODIPHENYL 0 3,2'-DIMETHYL-4BIPHENYLAMINE 0 3,2'-DMAB
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. Moderately toxic by intraperitoneal route. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also AROMATIC M I N E S .
BLW750 203
BLVSOO CAS: 8013-76-1 HR: 3 BITTER ALMOND OIL PROP: Volatile oil from dried ripe kernels of bitter almonds or from other kernels containing amygdalin, such as apricots, cherries, plums, and especially peaches. Colorless liquid; strong almond odor. Bp: 179', d: 1.045-1.070 @ 15'. Sltly sol in water; sol in fured oils and propylene glycol; insol in glycerin. SYNS: ALMOND OIL BITTER, FFPA (FCC) 0 OIL, BITTER ALMOND
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A human poison by ingestion. Moderately toxic by skin contact. A s h n irritant. When heated to decomposition it emits toxic fumes of CN-.
BLW250 CAS: 8006-82-4 HR: 1 BLACK PEPPER OIL PROP: From steam &stillation of dried fruit of Piper nigmlm L (Fam. Piperaceae). Main constituents include a- and p-pinene, pcaryophyllene, l-limonene, d-hydrocarveol, piperidine, and piperrine (FCTXAV 16,637,78).A colorless to greenish liquid; odor and taste of pepper. Sol in fixed oils, mineral oil, propylene glycol; sltly sol in glycerin. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: A moderate skin irritant. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. BLW750 CAS: 21725-46-2 HR: 3 BLADEX mf: C9H13ClN6 mw: 240.73 PROP: A white, crystalhe material. Mp: 167'. SYNS: BLADEX 80WP 0 2-CHLORO-4-(1-CYANO-lMETHYLETHYLAMINO)-6-ETHYLAMINO-l,3,5TRIAZINE 0 2-CHLORO-4-ETHYLAMINO-6-(l-CYANO1-METHYL)ETHYLAMINO-s-TRIAZINE 0 2-(4-CHLORO-
~-ETHYLA~MINO-S-TRIAZINE-~-YL~~UNO)-~-METH PROPIONITRILE 0 2-(4-CHLORO-6-ETHYLAMINO-l,3,5-
TRIAZINE-2-YLAMINO)-2-METHnPROPIONITRI 0 2-((4-CHLORO-6-(ETHYINO)-l,3,5-TRIAZIN-2-
204 BLYOOO BLEOMYCIN n ) A M I N O ) - 2 - ~ ~ E T H n - P R O P A " I T R I L0 E 2-((4-
SAFETY PROFILE: When heated to
CHLORO-6-(ETHYLhMINO)-s-TRIAZIN-2-YL)AhfINO)-2hiETHYLPROPIONITRILE 0 CYAVAZINE 0 DW3418 0 FORTROL 0 PAYZE 0 SD 15418 0 WL 19805
CONSENSUS REPORTS: EPA Genetic Toxicology Program.Cyanide and its compounds are on the Community RightTo-Know List. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Moderately toxic by shn contact. An experimental teratogen. Mutation data reported. See also NITRILES. An herbicide. When heated to decomposition it emits very toxic fumes of C1-, NO,, and CN-.
BLYOOO CAS: 11056-06-7 HR: 3 BLEOMYCIN PROP: A group of related glycopeptide antibiotics isolated from Streptomyces vertidus. SYNS: BLENOXAlVE BLEO BLEOCIN 0 BLM CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,134,87; Human Inadequate Evidence IMEMDT 26,97,81. EPA Genetic Toxicology Program. SAFETY PROFILE: A human poison by intravenous route; moderately toxic to humans by intramuscular route. Poison experimentally by intravenous and intraperitoneal routes. Human systemic effects by ingestion and intramuscular routes: dyspnea and fibrosing alveolitis (lung), Experimental reproductive effects. An eye irritant. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See other bleomycin entries. BMA550 HR: D BOlS de ROSE OIL PROP: From steam distillation of chipped wood of Aniba rosaeodora var. amaxonica Ducke, (Fam. Lauraceae). Colorless to pale yellow liquid; slt pleasant floral odor. Sol in fixed oils, propylene glycol, mineral oil; sltly sol in glycerin. SYN: LIGNALOE OIL
decomposition it emits acrid smoke and irritating fumes. BMA750 CAS: 8001-85-2 HR: 2 BONE OIL PROP: Product of destructive distillation of bones in preparation of bone charcoal containing nitrogenous compounds such as pyridine, a n h e , methylamine, and pyrrole (27ZTAP 3,25,69). SYNS: ANIMAL OIL 0 DIPPEL'S OIL OIL OF HARTSHORV
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. When heated to decomposition it
emits toxic fumes of NO,. BMCOOO CAS: 10043-35-3 HR: 3 BORIC ACID mf: BH303 mw: 61.84 PROP: White crystals, powder, or pearly scales. Mp: 171' (decomp), loses 1.5 H20 @ 300°, d: 1.435 @ 15". SYNS: BORACIC ACID U BOROFAX 0 BORSAEC'RE (GERMAN) 0 NCI-C56417 0 ORTHOBORIC ACID 0 THREE ELEPHANT
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A human poison by ingestion and possibly other routes. Moderately toxic by skin contact and subcutaneous routes in humans. Poison experimentally by inhalation and subcutaneous routes. Moderately toxic experimentally by intraperitoneal and intravenous routes. Human systemic effects: anorexia, changes in kidney tubules, nausea or vomiting, wakefulness. Ingestion or absorption by other routes may also cause diarrhea, abdominal cramps, erythematous lesions on skin and mucous membranes, circulatory collapse, tachycardia, cyanosis, delirium, convulsions, and coma. Death has occurred from ingestion of less than 5 g in infants, and from 5 to 20 g in adults. Chronic exposure may result in borism (dry skin, eruptions, and gastrointestinal
BORON
dsturbances) . Experimental reproductive effects. Mutation data reported. A human shn irritant. See also BORON COMPOUNDS. Incompatible with K, (CH3C0)20. BMC250 CAS: 34099-73-5 HR: 3 BORIC ACID, ETHYL ESTER DOT: UN 1176 mf: C2H7BO3 mw: 89.90 PROP: Colorless liquid, mild odor, decomp in water. Bp: 120°, flash p: 52'F (CC), d: 0.864 @ 26.5', vap d: 5.04. SYN: ETHYL BORATE (DOT)
DOT CLASSIFICATION: 3; Label:
BMDSOO 205
chemical. When heated to decomposition it emits acrid smoke and fumes. BMD100 CAS: 76-49-3 HR: 1 BORNYL ACETATE mf: C12H2002 mw: 196.29 PROP: Colorless liquid or whte crystalline solid; sweet, piney odor. D: 0.981-0.985, refr index: 1.462, flash p: 192'F. Sol in alc, fixed oils; sltly sol in water; ins01 in glycerin, propylene glycol @ 226'. SYNS: LBORNYLACETATE 0 FEiMANo. 2159
SAFETY PROFILE: Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
Flammable Liquid SAFETY PROFILE: A severe eye irritant. See also BORON COMPOUNDS and ESTERS. Dangerous fire hazard when exposed to heat or flame; wdl react with water or steam to produce flammable vapors. Incompatible with oxidmers, heat, and open flame. To fight fire, use COZ,dry chemical.
BMD300 CAS: 464-41-5 2-BORNYL CHLORIDE mf: C1OH17C1 mw: 172.72
HR: 3
SYNS: BORNANE, 2-CHLORO-, endo- 0 2-CHLOROCAhlPHANE 0 BICYCLO(2.2.1)HElTANE, Z-CHLORO1,7,7-TRIMETHYI-, endo- 0 BORNYL CHLORIDE 13 TERPENE HYDROCHLORIDE 0 TURPENTINE CAMPHOR 0 endo-2-CHLORO-1,7,7-TRIMETHYLBICYCLO(2.2.1)HEMANE
SAFETY PROFILE: A poison by inhalation.
BMDOOO CAS: 507-70-0 HR: 3 BORNEOL DOT: UN 1312 mf: C10H180 mw: 154.28 PROP: Hexagonal crystals; peppery odor and burning taste. Mp: 208', bp: 212', flash p: 150'F, d: 1.01 @ 20'/4', vap d: 5.31. SYNS: BAROS CAMPHOR 0 BHIMSAIM CAMPHOR 0 BICYCLO(2.2.1)HEMAV-2-OL, 1,7,7-TRIMETHYL-, endo(9CI) 0 2-BORNANOL, endo- 0 BORNEO CAMPHOR 0 trans-BORNEOL BORVEOL (DOT) BORNYL ALCOHOL 0 CAMPHASE, 2-HYDROXY- 0 2CAhlPHANOL 0 CAMPHOL 0 DRYOBALANOPS CAMPHOR 0 2-HYDROXYCMIPHANE 0 RWLAYAN CAMPHOR 0 SUMATRA CAMPHOR 0 endo-1,7,7TRIMETHYL-BICYCL0(2.2.1)HEPTAN-2-OL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 4.1; Label:
Flammable Solid SAFETY PROFILE: Moderately toxic by ingestion. Mutation data reported. A mild irritant. Flammable when exposed to heat or flame; can react with oxidizing materials. To fight fire, use water, C02, water spray, dry
Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of c1-. BMD500 CAS: 7440-42-8 HR: 3 BORON af: B aw: 10.81 PROP: Monoclinic crystals, yellow or brown amorphous powder. Mp: 2190°, bp: 3660°, d: 3.33 @ 20'. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: A poison by ingestion. See also BORON COMPOUNDS. A relatively inert metal except in the form of powder or when exposed to highly oxidizing agents. Amorphous boron is very reactive, sometimes violently. Flammable in the form of dust when exposed to air, or by chemical reaction. An explosion hazard in the form of dust, which ignites on contact with air. Reacts with NaOH at 5', Na2C03 at 8'. Reacts explosively when ground with lead
206
BMESOO BORON COMPOUNDS
fluoride or silver fluoride. Ignites in contact with gaseous chlorine or fluorine at room temperature. Incompatible with NH3, Brz, BrF3, CS~CZ, Cl2, CuO, HI03, PbOz, HN03, NO, NOF, N20, ICC103, m03,Rb2C2, S, BrF5, IF5, metal fluorides, interhalogens, nitryl fluoride (FN02), OFz, I
FUSED BORIC ACID
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
OSHA PEL: Total Dust: TWA 10 mg/m3;
Respirable Fraction: TWA 5 mg/m3 ACGIH TLV: TWA 10 mg/m3 DFG MAK: 15 mg/m3 SAFETY PROFILE: Moderately toxic by
ingestion and intraperitoneal routes. An eye and s h n irritant. A pesticide. Mixed with CaO and put into fused CaC12, the mixture incandesces. See also BORON COMPOUNDS. BMG400 CAS: 10294-33-4 HR: 3 BORON TRlBROMlDE DOT: UN 2692 mf: BBr3 mw: 250.54 PROP: Colorless, fuming liquid. Very moisture-sensitive, Mp: -46', bp: 91.3', d: 2.650 @ O', vap press: 40 mm @ 14.0', 100 mm @ 33.5'. Sol in CC4, SO2 (l), SCh; mod sol in methylcyclohexane. SYNS: BORON BROMIDE 0 TRONA CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: CL 1 ppm ACGIH TLV: CL 1 ppm DOT CLASSIFICATION: 8; Label: Corrosive, Poison SAFETY PROFILE: A poison. Corrosive. A skin, eye, and mucous membrane irritant. Dangerous; may explode when heated. This and other boron halides react with water or steam to produce toxic and corrosive fumes and may explode. Incompatible with I<; Na. When heated to decomposition it emits toxic fumes of Br-. See also BORON COMPOUNDS and HYDROBROMIC ACID. BMG500 CAS: 10294-34-5 HR: 3 BORON TRICHLORIDE DOT: UN 1741 mf: BC13 mw: 117.16 PROP: Colorless gas, fuming liquid. Pungent, irritating odor. Very easily hydrolyzed. Mp: -107', bp: 12.5', d: 1.349 @ 11°/4', vap press: 1 atm @ 12.7', vap d: 4.03.
BORON TRIFLUORIDE-DIMETHYL ETHER SYNS: BORON CHLORIDE 0 CHLORURE de BORE (FRENCH) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. EPA Extremely Hazardous Substances List. DOT CLASSIFICATION: 2.3; Label: Poison Gas, Corrosive SAFETY PROFILE: A poison by inhalation. A corrosive and severe irritant to skin, eyes, and mucous membranes. Reacts with water or steam to produce heat, toxic and corrosive fumes. Violent reaction with aniline or phosphine. Incompatible with hexafluorisopropylidene amino lithium, NO2, grease, organic matter, 0 2 . When heated to decomposition it emits toxic fumes of C1-. See also BORON COMPOUNDS and HYDROCHLORIC ACID. BMG700 CAS: 7637-07-2 HR: 3 BORON TRIFLUORIDE DOT: UN 1008 mf: BF3 mw: 67.81 PROP: Colorless nonflammable gas; pungent, irritating odor. Mp: -128.4', bp: -lOO.Oo, d: 2.99 g/L. Sol in H20, and org solvs, e.g., alcohols, ethers (forming adducts). IDLH 25 ppm. SYNS: BORON FLUORIDE 0 FLUORURE de BORE (FRENCH)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. EPA Extremely Hazardous Substances List. OSHA PEL: CL 1 ppm ACGIH TLV: CL 1 ppm DFG MAK: 1 pprn (3 mg/m3) NIOSH REL: (Boron Trifluoride) No Exposure Limit DOT CLASSIFICATION: 2.3; Label: Poison Gas SAFETY PROFILE: A poison by inhalation. A strong irritant. See also BORON COMPOUNDS and FLUORIDES. A nonflammable gas. Dangerous; when heated to decomposition or upon contact with water or steam, wdl produce toxic and corrosive fumes of F-. Incompatible with
BMHOOO 207
alkali metals, alkaline earth metals (except Mg), alkyl nitrates, and CaO. BMG750 CAS: 7578-36-1 HR: 3 BORON TRIFLUORIDE-ACETIC ACID COMPLEX DOT: UN 1742 SYNS: ACETIC ACID, compd. with BORON FLUORIDE (BF3) (BCI) 0 BORON FLUORIDE, compd. with ACETIC ACID CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A very corrosive material. When heated to decomposition it
emits very toxic fumes of F-, B oxides. See BORON COMPOUNDS, ACETIC ACID, and FLUORIDES. BMG800 CAS: 13319-75-0 HR: 2 BORON TRIFLUORIDE DIHYDRATE DOT: UN 2851 mf: BFp2H20 mw: 103.85 SYNS: BORANE, TRIFLUORO-,DIHYDRATE 0 BORON FLUORIDE DIHYDRATE 0 BORON TRIFLUORIDE DIHYDRATE (DOT,! DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Moderately toxic by
inhalation. A corrosive irritant. When heated to decomposition it emits toxic vapors of B and F-. BMHOOO CAS: 353-42-4 HR: 3 BORON TRIFLUORIDE-DIMETHYL ETHER DOT: UN 2965 mf: C2H60.BF3 mw: 113.89 PROP: Moisture-sensitive liquid. D: 1.239, mp: -14', bp: 126-127'. SYNS: BORON TRIFLUORIDE DIMETHK ETHERATE (DOT)
FLUORID BORITY-DIMETHYLETHER(1:l)
CONSENSUS REPORTS: EPA Extremely
Hazardous Substances List. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 4.3; Label: Dangerous When Wet, Corrosive, Flammable Liquid SAFETY PROFILE: Poison by inhalation. Corrosive. Flammable liquid. When heated
208 BMK290 BOTRYODIPLODIN to decomposition it emits toxic fumes of F-. See also ETHERS and BORON COMPOUNDS.
BMK290 CAS: 27098-03-9 HR: 3 BOTRYODIPLODIN mf: C7H1203 mw: 144.19 PROP: Crystals from EtzO. Mp: 50-52'. SYNS: (-)-BOTRYODIPLODIN 0 2-HYDROXY-3METHYL-4-ACETYLTETRAHYDROFURANE 0 METHYL TETRAHYDRO-5-HYDROXY-4-METHYL-3-FURYL KETONE 0 1-PETRAHYDRO-5-HYDROXY-4-METHYL-3FURAiiYL)-ETHANONE (9Cg
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison. Human mutation data reported. A flammable liquid. When heated to decomposition it emits acrid smoke and fumes. See also KETONES.
BMLOOO HR: 3 BRACKEN FERN, DRIED SYNS: 1-CYCLOHEXENE-1-CARBOXYLIC ACID, 3,4,5 0 S. EGRELTRI ATUNUN (TURKISH) 0 PTERIDIUM AQUILINUN 0 PTERIS AQUALINA
CONSENSUS REPORTS: IARC Cancer Review: Human Inadequate Evidence IMEMDT 40,47,86; Animal Sufficient Evidence IMEMDT 40,47,86. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental teratogenic and reproductive effects. Mutation data reported.
BMM500 CAS: 2580-78-1 HR: 2 BRILLIANT BLUE R mf: C Z Z H I ~ N Z O I I S ~ ~mw: ~~N 626.56 ~ SYNS: CAVALITE BRILLIANT BLUE R 0 C.I. 61200 0 C.I. REACTIVE BLUE 19 0 C.I. REACTIVE BLUE 19, DISODIUM SALT 0 REACTNE BLUE 19 0 REMALAN BRILLIANT BLUE R 0 REMAZOL BRILLIANT BLUE R
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROF1LE: Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits very toxic fumes of NaaO, NO,, and SO,. See also SULFONATES.
BMM575 CAS: 59803-98-4 BRlMONlDlNE mfi CllHloBrN5 mw: 292.17 SYNS: 5-BROMO-6-(2-IMIDAZOLIN-2-
HR: 3
YLAMIN0)QUINOXALINE 0 LK 14304-18 0 6QUINOXALINAMINE, 5-BROMO-N-(4,5-DIHYDRO-l HIMIDAZOL-2-YL)- 0 UK 14304 0 UK14304
SAFETY PROFILE: A poison by ingestion.
When heated to decomposition it emits toxic vapors of NO, and Br-. BMM650 CAS: 314-40-9 HR: 2 BROMACIL mf: C9H13BrN202 mw: 261.15 PROP: Crystals or solid from EtOH (ad. Sltly sol in H20; mod sol in strong aq bases from MezCO, MeCN, and EtOH. SYNS: BOREA 0 BROMAZIL 0 5-BROMO-3-secBUTYL-6-METHYLURACIL 0 5-BROMO-6-METHYL-3-(1-
METHYLPROPYL)-2,4(1H,3H)-PYRIMIDINEDIONE 0 5BROMO-6-METHYL-3-(1-METHYLPROPYL)URACIL 0 3-
sek.BUTYL-5-BROM-6-METHYLURACIL (GERMAN) 0 CYNOGAN 0 DU PONT HERBICIDE 976 0 EEREX GRANULAR WEED KILLER 0 EEREX WATER SOLUBLE CONCENTRATE W E D KILLER 0 HERBICIDE 976 0 HYVAR 0 HYVAREX 0 HYVAR X 0 HYVAR X BROMACIL 0 HYVAR X WEED KILLER 0 KROVAR 11 0 NALKIL 0 URAGAN 0 URAGON 0 UROX B WATER SOLUBLE CONCENTRATE WEED KILLER 0 UROX HX GRANULAR WEED KILLER
CONSENSUS REPORTS: EPA Genetic
Toxicology Program. OSHA PEL: T W A 10 ppm ACGIH TLV: TWA 10 mg/m3; Animal Carcinogen SAFETY PROFILE: Moderately toxic by ingestion. An experimental teratogen. Mutation data reported. Questionable carcinogen. An herbicide. When heated to decomposition it emits very toxic fumes of Br- and NO,. BMNSOO HR: 3 BROMATES SAFETY PROFILE: Generally considered to be more toxic than chlorates; cause central nervous system paralysis. They may form methemoglobin, but less actively than chlorates. See also specific compounds. Flammable in the form of gas, vapor, or dust by chemical reaction with (powdered
BROMINE BMPOOO 209
metals + acids); Al; As; CaH2; C; Cu; powdered metals; metal sulfides; organic matter; PH4I; P; SrH; S; (H2S04 + metals). When heated to decomposition they emit toxic fumes of Br-; can react with reducing materials.
taste. Sol in alc, chloroform, ether, hexane, fixed oils; insol in water. SYN: VEGETABLE (SOYBEAN) OIL, brominated SAFETY PROF1LE : Experimental reproductive effects. When heated to decomposition it ernits toxic fumes of Br-.
BMOOOO CAS: 9001-00-7 HR: 3 BROMELAIN PROP: From pineapples Ananas comosz~sand Ananas bracteattls L White to tan amorphous powder. Sol in water; insol in alc, chloroform, ether.
BMPOOO CAS: 7726-95-6 HR: 3 BROMINE DOT: UN 1744 mf: Br2 mw: 159.82 PROP: Rhombic crystals or dark red-brown liquid with a strong disagreeable pungent odor. Strong oxidant. Fp: -7.3', bp: 59.5', d: 2.928 @ 59O, 3.12 @ 20', vap press: 175 mm @ 21', 1 atm @ 58.2', vap d: 5.5. Sol in H20. Msc in most org solvs, although it may react. IDLH 3 ppm.
SYNS: ANANASE 0 BROMELAINS 0 BROMELIN 0 E.C. 3.4.4.240 EXTRANASE 0 INFLAMEN 0 PLANT PROTEASE CONCENTRATE 0 TRAUMANASE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison via intraperitoneal and intravenous routes. When heated to decomposition it emits acrid smoke and fumes.
BM0750 BROMIDES
HR: 3
SAFETY PROFILE: The most common inorganic bromides are Na, K, NH4, Ca, and Mg bromides. Methyl and ethyl bromides are among the most common organic bromides. The inorganic bromides produce depression, emaciation, and, in severe cases, psychosis and mental deterioration. Bromide rashes (bromoderma), especially of the face and resembling acne and fumnculosis, often occur when bromide inhalation or administration is prolonged. Organic bromides, such as methyl bromide and ethyl bromide, are volaule liquids of relatively high toxicity. See also specific compounds. When strongly heated they emit highly toxic fumes of Br-.
BM0825 CAS: 68952-98-7 HR: D BROMINATED VEGETABLE (SOYBEAN) OIL PROP: Pale-yellow to dark-brown viscous, oily liquid; bland or fruity odor and bland
SYNS: BROM (GERMAN) 0 BROME (FRENCH) 0 BROMINE, solution (DOT) 0 BROMO (ITALIAN) 0 BROOM (DUTCH) CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 0.1 ppm; STEL 0.3 ppm ACGIH TLV: TWA 0.1 ppm; STEL 0.2 ppm DFG MAK: 0.1 ppm (0.66 mg/m3) DOT CLASSIFICATION: 8; Label: Corrosive, Poison SAFETY PROFILE: A human poison by ingestion and moderately toxic by inhalation. A poison by ingestion and inhalation experimentally. Corrosive. The action of bromine is essentially the same as that of chlorine, irritating the mucous membranes of the eyes and upper respiratory tract. Severe exposure may result in pulmonary edema. Usually, however, the irritant qualities of the chemical force the worker to leave the exposure area before serious poisoning can result. Chronic exposure is similar to the therapeutic ingestion of excessive bromides. See also BROMIDES. Regular physical examinations should be made of people who work with bromine or bromides. Flammable in the form of liquid or vapor by spontaneous chemical reaction with reducing materials. A
210
BMP250
BROMINE AZlDE
very powerful oxidzer. Highly dangerous; when heated it emits highly toxic fumes; wdl react with water or steam to produce toxic and corrosive fumes. Reacts explosively with dlethylzinc, germane, dsilane, dmethylformamide, hydrogen, isobutyrophenone, metal azides ('particularly silver or sodum azide), potassium, silane and homologs, praseodymium, antimony, trimethylamine, ammonia. Mixtures with lithium or sodium are shock-sensitive explosives. Ignition on contact with germanium, mono- or di-alkali metal acetylides, trialkyl boranes, copper acetylides. Violent reaction with carbonyl compounds (aldehydes, ketones, carboxylic acids), diethyl ether, phosphine, natural rubber, aluminum, mercury, titanium. Vigorous reaction with methanol and other alcohols, tetrahydrofuran, mixtures of ethanol and phosphorus. Incompatible with acetaldehyde, C2H2, acrylonitrile, NH3, Sb, B, Ca3N2, CszO, Cs2C2, CSC~H, ClFG, CuH2, dimethyl formamide, ethyl phosphine, Fz, F e L , isobutyrophenone, LiZC2, LizSi2, Mg3P2, Ni(Co)r, NI3, olefins, OF2,03, P, PO,, RbzC2, RbC2H, N a G , NaC2H, SaP, Sn, UC2,ZrC2, reducing materials. BMP250 CAS: 13973-87-0 HR: 3 BROMINE AZIDE mf: BrN3 mw: 121.93 PROP: Crystals or red liquid. Mp: 45O, bp: explodes. SYNS: BROMINE NITRIDE 0 NITROGEN BROMIDE
DOT CLASSIFICATION: Forbidden SAFETY PROFILE: A poison. Can explode
spontaneously. The solid, liquid and vapor are shock-sensitive explosives. Concentrated solutions in organic solvents may explode. Moderate fire hazard in the form of vapor by chemical reaction. A powerful oxidant. Moderately explosive when exposed to heat. The liquid explodes on contact with arsenic, sodium, silver foil, or phosphorus. Incompatible with Sb, ethyl ether, Ag, metals. When heated to decomposition it
emits highly toxic fumes of Br- and explodes. See also BROMINE and AZIDES. BMQOOO CAS: 7789-30-2 HR: 3 BROMINE PENTAFLUORIDE DOT: UN 1745 mf: BrF5 mw: 174.91 PROP: Colorless fuming liquid. An extremely vigorous fluorinating agent. Mp: -60.5', bp: 40.5', d: 2.466 @ 25O, vap d: 6.05. OSHA PEL: TWA 0.1 ppm; TWA 2.5 mg(E) /m3 ACGIH TLV: TWA 0.1 ppm; TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shlft. NIOSH REL: (Inorganic Fluorides) TWA 2.5 mgO/m3 DOT CLASSIFICATION: 5.1; Label: Oxidizer, Poison, Corrosive SAFETY PROFILE: A poisonous, corrosive, and extremely reactive gas. It is a powerful oxidizer. Will react with water or steam to produce toxic and corrosive fumes. The liquefied gas reacts violently with many organic compounds and some inorganic compounds. Explodes or ignites on contact with hydrogen-containing materials (e.g., acetic acid, ammonia, benzene, ethanol, hydrogen, hydrogen sulfide, methane, cork, grease, paper, wax, chloromethane). Reacts violently and may i p t e on contact with acids, halogens, nonmetals, metal hahdes, metals, oxides, concentrated nitric or sulfuric acids, aluminum powder, ammonium chloride, antimony, arsenic, arsenic pentoxide, barium, bismuth, boron powder, boron trioxide, calcium oxide, carbon monoxide, charcoal, chlorine, chromium, chromium trioxide, cobalt powder, iodine, iodne pentoxide, iridium powder, iron powder, lithium powder, manganese, magnesium oxide, molybdenum, molybdenum trioxide, nickel powder, red phosphorus, phosphorus pentoxide,
~-BROMOACETYL-UXZ-DIPHENYL-~-PIPERIDINEMETHANOLBMS300 21 1
potassium iodide, rhodlum powder, selenium, sulfur, sulfur dioxide, tellurium, tungsten, tungsten trioxide, water, zinc. When heated to decomposition it emits very toxic fumes of F- and Br-. See also BROMINE and FLUORIDES.
BMQ325 CAS: 7787-71-5 HR: 3 BROMINE TRIFLUORIDE DOT: UN 1746 mf: BrF3 mw: 136.91 PROP: Colorless, fuming liquid. Mp: 8.8", bp: 127", d: 2.84. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mgO/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shft. NIOSH REL: (Inorganic Fluorides) TWA 2.5 mg(F) /m3 DOT CLASSIFICATION: 5.1; Label: Oxidizer, Poison, Corrosive SAFETY PROFILE: Poisonous and corrosive. Very reactive, a powerful oxidizer. Explosive or violent reaction with organic materials, water, acetone, ammonium halides, antimony, antimony trichloride oxide, arsenic, benzene, boron, bromine, carbon, carbon monoxide, carbon tetrachloride, carbon tetraiodlde, chloromethane, cobalt, ether, halogens, iodine, powdered molybdenum, niobium, 2pentanone, phosphorus, potassium hexachloroplatinate, pyridine, sihcon, silicone grease, sulfur, tantalum, tin dichloride, titanium, toluene, vanadurn, uranium, uranium hexafluoride. Incompatible with Sb203, BaC12, Bi205, CdC12, CaC12, CsC1, LiC1, MnI03, metals, Nb205, PtBr4, PtC14, (Pt + KFO), I a r , KC1, KI, RhBr4, RbC1, AgC1, NaBr, NaC1, NaI, Ta205, Sn, W, UO,, rubber, plastics. The product of reaction with pyridine ignites when dry. When heated to decomposition it emits toxic fumes of F- and Br-. Very dangerous. See also BROMINE
PENTAFLUORIDE, FLUORIDES, and BROMINE. ~~
~~
~
BMQ800 CAS: 61288-13-9 HR: 3 BROMKAL 80 CONSENSUS REPORTS: NTP 10th Report on Carcinogens, 2000: Reasonably anticipated to be human carcinogen SAFETY PROFILE: Confirmed carcinogen. BMR750 CASE79-08-3 HR: 3 a-BROMOACETIC ACID DOT: UN 1938 mf: C2H302Br mw: 138.04 PROP: Hygroscopic crystals, sol in water and alc. D: 1.93, mp: 50°, bp: 208". Sol in H20 and EtOH. SYNS: ACIDE BROMACETIQUE (FRENCH) 0 BROMOACETIC ACID 0 BROMOACETIC ACID, solid or solution (DOT) 0 BROMOETHANOIC ACID 0 aBROMOETHANOICACID 0 KYSELINA BROMOCTOVA 0 MONOBROMESSIGSAEURE (GERMAN) 0 MONOBROMOACETIC ACID 0 TO NTU CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by ingestion,
intraperitoneal, and intravenous routes. Irritating and corrosive to skin and mucous membranes. Mutation data reported. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.
BMS300 CAS: 143-84-0 HR: 3 1-BROMOACETYL-CX-~-DIPHENY L-4PIPERIDINEMETHANOL mf: C20H22BrN02 mw: 388.34 SYNS: KETONE, BROMOMETHYL.4(DIPHENYLHYDR0XYMETHYL)PIl'ERIDINO
0 4-
PIPERIDINEMETHANOL, 1-BROhlOACETYL-a-aDIPHENYL-
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO, and Br-.
212
BMT15O
3-BROMOALLYL ISOCYANATE
BMT150 CAS: 101652-13-5 HR: 3 3-BROMOALLYL ISOCYANATE DOT: UN 2206/UN 2207/UN 2478/UN 3080 mf: ChH4BrNO mw: 162.00 SYN: ISOCYANIC ACID, 3-BROSIOALLYL ESTER DOT CLASSIFICATION: 6.1; Label: KEEP
AWAY FROM FOOD (UN2207); 6.1; Label: Poison (UN2206); 6.1; Label: Poison, Flammable Liquid (UN3080); 3; Label: Flammable Liquid, Poison (UN2478) SAFETY PROFILE: A poison by intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO, and Br-.
BMW250 CAS: 5798-79-8 HR: 3 BROMOBENZYLNITRILE mf: CsHGBrN mw: 196.06 PROP: Pure: Yellowish-whte crystals. Tech: brown, oily liquid with pungent odor of sour fruit; mp: 29', bp: 242', fp: 25.5', flash p: none, d: 1.5160 @ 20°, vap d 6.8, vap press: 0.011mm @ 20'. SYNS: BBC
BBN BRO~MBENZYLCYANIDE aBROMOBENZYL CYANIDE 0 a-BROMOBENZYLNITRILE 0 a-BROMOPHENYLACETONITRILE 0 aBROMO-a-TOLUXITRILE 0 CA 0 CARIITE
CONSENSUS REPORTS: Cyanide and its compounds are on the Community RightTo-Know List. SAFETY PROFILE: Poison by ingestion. Moderately toxic to humans by inhalation. When heated to decomposition it emits very toxic fumes of NO,, Br-, and CN-. See also NITRILES.
BMXSOO CAS: 109-65-9 HR: 3 1-BROMOBUTANE DOT: UN 1126 mf: C4HgBr mw: 137.04 PROP: Colorless to pale straw-colored liquid. Mp: -112.3', bp: 101.6', flash p: 65'F (OC), d: 1.276 @ 20'/8', autoign temp: 509'F, vap d: 4.72, lel: 2.8% @ 212'F, uel: 6.6% @ 212'F. SYNS: BCTYL BROMIDE (DOT) 0 n-BUTrZ BROMIDE (DOT)
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by intraperitoneal route. Mddly toxic by inhalation. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Violent reaction with bromobenzene + sodium above 30'C. Can react with oxidizing materials. To fight fire, use CO2, dry chemical, mist or spray. See also BROMIDES.
BMX750 CASE78-76-2 HR: 2 2-BROMOBUTANE DOT: UN 2339 mf: C4H9Br mw: 137.04 PROP: Colorless liquid. Fp: <-50', bp: 91.4', flash p: 70'F, d: 1.257 @? 25'/25'. SYNS: sec-BUTY'L BROMIDE 0 METHYLETHYLBROMOMETHANE CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Narcotic in high concentrations. Questionable carcinogen with experimental neoplastigenic data. See also BROMIDES and CHLORINATED HYDROCARBONS, ALIPHATIC. Flammable liquid. Dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Br-; can react with oxidzing materials. To fight fire, use water, spray or mist, foam, Con, dry chemical.
BNA250 CAS: 353-59-3 HR: 1 BROMOCHLORODIFLUOROMETHANE DOT: UN 1974 mf: CBrClFz mw: 165.37 PROP: Colorless gas. Fp: -160.5', bp: -4'. SYNS: CHLORODIFLUOROBROhfOh~ETHANE(DOT) 0 CHLORODIFLUOROMONOBROMO,I.IETHANE 0 FLUGEX t2Bt U FLUOROCARBON 1211 U FREON 12Bt 0 HALON 1211 0 R12B1 (DOT)
2-BROMO-1,5-DIAMINO-4,8-DIHYDRO BNCBOO 2 13 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 2.2; Label:
Nonflammable Gas SAFETY PROFILE: Mutation data reported. An asphyxiant. See also ARGON for description of inert gas asphyxiants. When heated to decomposition it emits very toxic fumes of Br-, C1-, and F-.
BNA350 CAS: 122322-22-9 HR: 3 2-(3-BROMO-4-CHLOROPHENYL)-4CHLORO-5-((6-CHLORO-3PYRlDlNYL)METHOXY)-3(2H)PYRlDAZlNONE mf: C16H9BrCl3N302 mw: 461.54 SYN: 3(2H)-PYRIDAZINONE,2-(3-BROMO-4CHLOROPHENYL-4-CHLORO-5-((6-CHLORO-3PYRIDINYL)METHOXY,-
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits
toxic vapors of NO,, Br-, and C1-.
BNA750 CAS: 41 198-08-7 HR: 3 0-(4-BROMO-2-CHLOROPHENYL)-0ETHYL-S-PROPYL PHOSPHOROTHIOATE mf: C I I H ~ S B ~ C ~ O ~ Pmw: S 373.65 SYNS: CGA 15324 0 CURACRON 0 POLYCRON 0 PROFENOFOS 0 SELECRON SAFETY PROFILE: Poison by ingestion and skin contact. When heated to decomposition
it emits very toxic SO,, PO,, Br-, and C1-. See also ESTERS.
BNA825 CAS: 109-70-6 HR: 2 1-BROMO-3-CHLOROPROPANE DOT: UN 2688 mf: CsH6BrCl mw: 157.45 PROP: Bp: 142-143'. SYNS: 3-BROMOPROPYL CHLORIDE 0
1,3-CHBP 0 wCHLOROBROMOPROPANE 0 l-CHLORO-3BROMOPROPANE (DOq 0 3-CHLOROPROPYL BROMIDE 0 TRIMETHYLENEBROMIDE CHLORIDE 0 TRIMETHYLENE CHLOROBROMIDE
SAFETY PROFILE: Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of C1- and Br-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and BROMIDES.
BNA880 CAS: 3737-00-6 HR: 3 3-BROMO-1-CHLOROPROPENE mf: C3H4BrC1 mw: 155.42 SYN: 1-PROPENE, 3-BROMO-1-CHLOROSAFETY PROFILE: A poison by ingestion.
Low toxicity by inhalation. Human systemic effects. When heated to decomposition it emits toxic vapors of Br- and C1-.
BNC750 CAS: 59-14-3 HR: 2 5-BROMO-2'-DEOXYURIDINE mf: C9HllBrN205 mw: 307.13 PROP: Solid. Mp: 187-189'. SYNS: BDU 0 5-BDU 0 BROMODEOXYURIDINE 0 5BROMODEOXYURIDINE 0 5-BRObfO-2DEOXYURIDINE 0 5-BROMODESOXYURIDINE0 BROMOURACIL DEOXYRIBOSIDE 0 5-BROMOURACIL DEOXYRIBOSIDE 0 5-BROMOURACIL-2DEOXYRIBOSIDE 0 BROXURIDINE 0 BRUDR 0 BUDR 0 5-BUDR CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by subcutaneous, intravenous, intraperitoneal, and possibly other routes. Mildly toxic by ingestion. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of Br- and NO,.
BNC800 CAS: 27312-17-0 HR: 1 2-BROMO-1,5-DIAMINO-4,8-DIHYDROXYANTHRAQUINONE mfi C14HgBrN204 mw: 349.16 SYNS: ANTHRAQUINONE, 2-BROM0-1,5-DIAMINO4,8-DIHYDROXY- 0 MODR OSTACETOVA LR
CONSENSUS REPORTS: Reported in EPA
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
TSCA Inventory.
SAFETY PROFILE: An eye irritant. When heated to decomposition it emits toxic fumes of NO, and Br-.
DOT CLASSIFICATION: 6.1; Label: KEEP
AWAY FROM FOOD
2 14
6ND500 5ROMODICHLOROME THAN E
BNDSOO CAS: 75-27-4 HR: 3 BROMODICHLOROMETHANE mf: CHBrCh mw: 163.83 PROP: Colorless liquid. Mp: -57.1', bp: 88.4-88.6', d: 1.971 @ 2S0/250. SYNS: BDCM 0 DICHLOROBROMOMETHE 0 NCI-C55243 CONSENSUS REPORTS: NTP 10th Report on Carcinogens. NTP Carcinogenesis
Studes (gavage); Clear Evidence: rat, mouse NTPTR* NTP-TR-321,87. EPA Genetic Toxicology Program. Community Right-ToKnow List. Reported in EPA TSCA Inventory. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by ingestion. Human mutation data reported. When heated to decomposition it emits very toxic fumes of Br- and C1-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and BROMIDES. BNG750 CAS: 776-74-9 HR: 3 BROMODIPHENYLMETHANE DOT: UN 1770 mf: C13H11Br mw: 247.15 PROP: Solid. Mp: 45', bp: 184' @ 20 mm. Decomp in hot water; sol in alc; very sol in benzene. SYN: DIPHENYLMETHYL BROMIDE (DO13 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A corrosive poison. When heated to decomposition it emits
toxic fumes of Br-. See also BROMIDES. BNHOOO CAS: 776-74-9 HR: 3 BROMODIPHENYLMETHANE(solution) DOT: UN 1770 mf: C13H11Br mw: 247.15 SYN: DIPHENYL METHYL BROMIDE, solution (DOT CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A corrosive, irritating liquid, When heated to decomposition it
emits toxic fumes of Br-. See also
BROMODIPHENYLMETHANE and BROMIDES. BNHSOO CAS: 17372-87-1 HR: 3 BROMOEOSINE mf: C20HSBr40j*2Na mw: 693.90 PROP: Red crystals with bluish tinge, or brownish-red powder. Sol in H2O; sltly sol in EtOH; insol in EtaO. SYNS: AIZEN EOSINE GH 0 BROMO ACID 0 BROMOFLUORESCEIC ACID 0 BROMO FLUORESCEIN 0 BRONZE BROMO 0 CERTIQUAL EOSINE 0 C.I. 45380 0 D&C RED No. 22 0 DISODIUM EOSIN 0 EOSINE 0 EOSINE SODIUM SALT 0 EOSINE YELLOWISH 0 EOSIN GELBLICH (GERMAN) 0 FENAZO EOSINE XG U HIDACID DIBROMO FLUORESCEIN 0 IRGALITE BRONZE RED CL 0 PHLOXINE TONER B 0 PHLOX RED TONER X-1354 0 PURE EOSINE W 0 11445 RED 0 SODIUM EOSINATE 0 SYMULER EOSIN TONER 0 2,4,5,7-TETRABROMO-9o-CARBOXY!?HENYL-~-HYDROXY-~-ISOUNTHONE, DISODIUM SALT 0 2,4,5,7-TETMBROMO-3,6FLUORANDIOL 0 TETRABROMOFLUORESCEIN 0 2',4',5',7'-TETRABROMOFLUORESCEIN DISODIUM SALT 0 TETRABROMOFLUORESCEIN S 0 TETRABROMOFLUORESCEIN SOLUBLE 0 2-(2,4,5,7-
TETRABROMO-6-HYDROXY-3-0x0-3H-UNTHENE-9YL)BENZOIC ACID, DISODIUM SALT 0 TOY0 EOSINE G 0 1903YELLOW PINK
CONSENSUS REPORTS: IARC Cancer Review: Animal Inadequate Evidence IMEMDT 15,183,77. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Moderately toxic by ingestion. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits very toxic fumes of Br- and NazO. See also BROMIDES.
BNIOOO CAS: 3132-64-7 HR: 3 3-BROMO-1,2-EPOXYPROPANE DOT: UN 2558 mfi C3H5BrO mw: 136.99 PROP: Flash p: <22O. SYNS: EPIBROMHYDRIN 0 EPIBROMOHYDRIN (DOT) 0 EPIBROMOHYDRINE
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.
BROMOFORM BNLOOO 215 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by
intraperitoneal route. Human mutation data reported. A dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.
BN1500 CAS: 540-51-2 HR: 3 2-BROMO ETHANOL mf: CzH5BrO mw: 124.98 PROP: D: 1.79 @ 0'/4', bp: 149-150'. SYNS: BE 0 BROMOETHANOL 0 ETHYLENEBROMOHYDRIN 0 GLYCOL BROiMOHYDRIN CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.
BNKOOO CAS: 77-65-6 HR: 3 2-BROMO-2-ETHYLBUTYRYLUREA mfi C7H13BrN202 mw: 237.13 PROP: Solid. Mp: 116-119'. SYNS: ADALIN
0 ADDISOMNOL 0 N(AhIINOCARBONYL)-2-BROMO-2-ETHYLBUTANAhflDE 0 BROMACETOCARBAMIDE 0 BROMADAL 0 BROhfADEL 0 BROMODIETHYLACETYLCARBAiiIDE 0 BROMODIETHYLACETYLUREA 0 (a-BROhlO-aETHYLBUTYRYL)CARBAMIDE 0 (a-BR0MO-aETHYLBUTYRYL)UREA 0 1-BROMO-ETHYL-BUTYRYG UREA 0 2-BROMO-2-ETHYLBUTUREA 0 CARBOMAL 0 DIACID 0 DORMITLJRIN 0 FYDALIN 0 HOGGAR 0 KARBROMAL 0 KARTRYL 0 NCI-C03805 0 NENESIN 0 NYCTAL 0 PARKOSED 0 PELIDORM 0 PIANADXLIN 0 PUNADALIN 0 TILDIN 0 URADAL
CONSENSUS REPORTS: NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* NCI-CGTR-l73,79. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion, subcutaneous, and possibly other routes. Moderately toxic via intravenous and
intraperitoneal routes. Mutation data reported. A sedative,- hypnotic, and central nt&ous system depressant. When heated to decomposition it emits very toxic fumes of NO, and Br-. I -
BNLOO0 CAS: 75-25-2 HR: 3 BROMOFORM DOT: UN 2515 mf: CHBr3 mw: 252.75 PROP: Colorless heavy liquid or hexagonal crystals. Mp: 6-7', bp: 149', flash p: none, d: 2.887 @ 2Oo/4O. IDLH 850 ppm. SYNS: BROMOFORME (FRENCH) 0 BROMOFORMIO (ITALIAN) 0 METHENYL TRIBROMIDE 0 NCI-C55130 0 RCRA WASTE NUMBER U225 0 TRIBROMMETHAAN (DUTCH) 0 TRIBROMMETHAN (GERMAN) 0 TRIBROMOMETAN (ITALWN) 0 TRIBROMOMETHANE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Community Right-ToKnow List. OSHA PEL: TWA 0.5 ppm (skin) ACGIH TLV: TWA 0.5 ppm (skin); Animal Carcinogen DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Suspected carcinogen with experimental neoplastigenic data. A human poison by ingestion. Moderately toxic by intraperitoneal and subcutaneous routes. Human mutation data reported. A lachrymator. It can damage the liver to a serious degree and cause death. It has anesthetic properties simdar to those of chloroform, but is not sufficiently volatile for inhalation purposes and is far too toxic for human use. As a sedative and antitussive its medicinal application has resulted in numerous poisonings. Inhalation of small amounts causes irritation, provoking the flow of tears and saliva, and reddening of the face. Abuse can lead to adhction and serious consequences. Explosive reaction with crown ethers or potassium hydroxide. Violent reaction with acetone or bases. Incompatible with Li or NaK alloys. When
2 16
BNL275
BROMO(2-HYDROXYETHYL) MERCUR Y
heated to decomposition it emits hghly toxic fumes of Br-. See also BROMIDES.
SYN: METHYL BROMIDE and ETHYLENE DIBROMIDE MIXTURE, liquid (DOT)
BNL275 CAS: 23483-74-1 HR: 3 BROMO(2-HYDR0XYETHYL)MERCURY AMMONIA SALT
BROMIDES. When heated to decomposition it emits toxic fumes of Br-.
SYNS: 2-(BROMOMERCURI) ETHANOL-AMMONL4 (1:0.8 moles) compound 0 MERCURY, BROMO(2HYDROXYETHYL-, compound with AiiMONIA (1:O.B moles)
OSHA PEL: TWA 0.01 mg(Hg)/m3; CL 0.03
mg(Hg)/m3 (shn) ACGIH TLV: TWA 0.01 mg(Hg)/m3; BEI:
35 pg/g creatinine total inorganic mercury in urine preshift; 15 pg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of NH3, Hg, and Br-.
DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A poison. See also
BNN550 CAS: 128-93-8 HR: 1 1-BROMO-4-(METHYLAMINO)ANTHRAQUINONE mf: CI~HIOBTNOZ mw: 316.17 PROP: Red-brown needles from Py. Mp: 195-196'. SYNS: 9,10-ANTHRACENEDIONE, 1-BROMO-4(METHYLAMINO)- ANTHRAQUINONE, l-BROMO-4(METHYLAMINO)- 0 l-METHYLAMINO-4BROMANTHRACHINON 0 l-(METHYLAMINO)-C BROMOANTHRAQUINONE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An eye irritant. When heated to decomposition it emits toxic fumes of NO, and Br-.
BNM250 CAS: 478-84-2 HR: 3 2-BROMO-d-LYSERGIC ACID DIETHYLAMIDE mf: C20H26BrN30 mw: 404.40
BNP250 CAS: 107-82-4 HR: 3 1-BROMO-3-METHYL BUTANE DOT: UN 2341 mf: CsHllBr mw: 151.05 SYNS: BOL 0 BOL-148 0 d-2-BROM-DIETHYLAMIDE PROP: Colorless liquid. D: 1.210, mp: of LYSERGIC ACID 0 BROSI LSD 0 BROMLYSER-112', bp: 120-121', flash p: 21'. Sltly sol GA-IDE 0 2-BROWd-LYSERGIC ACID DIETHYL AMINE 0 2-BROMO-9,10-DIDEHYDRO-N,N-DIETHYL-Gin water; misc with alc and ether. hlETHnERGOLINE-8-P-CA~OXt\XlIDE0 BROMOLYSERGIDE 0 9,10-DIDEH"DRO-N,N-
SYNS: ISOXhfYL BROMIDE
DIETH~-2-BR0510-G-METHYLERGOLINE-8-~-
CONSENSUS REPORTS: EPA Genetic Toxicology Program. EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by intraperitoneal route. Flammable liquid. Dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.
CARBOXAMIDE 0 USAF SZ-l
SAFETY PROFILE: Poison by intraperitoneal and intravenous routes. Experimental teratogenic and reproductive effects. Human systemic effects by ingestion: ddation of the arteries or veins. Many lysergic acid derivatives have central nervous system effects. When heated to decomposition it emits very toxic fumes such as Br- and NO,. See other lysergic acid derivatives.
BNM750 HR: 3 BROMOMETHANE mixed with DIBROMOETHANE DOT: UN 1647
0
0 ISOPENTYL BROMIDE
3-METHYLBUTYL BROMIDE
BNP750 CAS: 496-67-3 HR: 2 2-BROMO-3-METHYLBUTYRYLUREA mf: CGHIIB~NZOZ mw: 223.10 SYNS: ABROVAL 0 ALLUVAL 0 ALURAL 0 N(AMINOCARBONYL)-2-BROMO-3-METHYLBUTANA&fIDE 0 BROMARAL 0 BROMCARBAMIDE 0 BROMISO-
4-BROMOPHENYLACETONITRILE BNV750 217 VAL 0 BROMISOVALERYLUREA 0 a-BROMISOSYNS: 2-BROMO-2-NITROPAE-1,3-DIOL[3 2VALERYLUREA 0 BROMISOVALUM 0 BROMIZOVAL BROMO-2-NITROPROPAN-1,3-DIOL 0 P-BROMO-PBROMOCARBAMIDE o a-BROMO-p-DIMETHYL NITROTRIMETHYLENEGLYCOL 0 BRONOCOT 0 PROPANOYLUREA 0 a-BROIMOISOVALERIC ACID BRONOPOL 0 BRONOSOL UREIDE 0 a-BROMOISOVALEROYLUREA 0 (aCONSENSUS REPORTS: Reported in BROMOIS0VALERYL)UREA 0 BROMOVAL 0 EPA TSCA Inventory. BROMOVALEROCARBA??IDE 0 BROMOVALERYLSAFETY PROFILE: Poison by ingestion, UREA 0 BROMOXIL 0 BROMURAL 0 BROMLWAN 0 subcutaneous, intravenous, and BROMVALERYLURFA 0 BROMVALETONE 0 intraperitoneal routes. Moderately toxic by BROMVALETONUM 0 BROMVALUREA 0 BROMYL 0 skin contact. An eye and human s h n irritant. BROVALIN 0 BROVALUREA 0 BROVARIN 0 B W 0 CALMOTIN 0 DIAGRABROMYL 0 DIBROLUUR 0 An antiseptic. When heated to DORMIGENE 0 ISOBROMYL 0 ISOVAL 0 MONOdecomposition it emits very toxic fumes of BROMOISOVALERYLUREA 0 2-MONOBROMOISONO, and Br-. VALERYLUREA 0 PIVADORM 0 PIVADORN 0 SOMNUROL 0 UPIOL 0 U V A L E M
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Human systemic effects by ingestion: nausea or vomiting, and coma. A sedative and hypnotic agent. When heated to decomposition it emits very toxic fumes of Br- and NO,.
BNR750 CAS: 78-77-3 HR: 2 1-BROMO-2-METHYLPROPANE mf: C4H9Br mw: 137.04 PROP: Liquid. Flash p: 22'C, d: 1.253 @! 2Oo/4O, fp: -117.4', bp: 90.5-91'. SYNS: 1-BUTYL BROMIDE
0 iso-BUTYL BROMIDE 0
ISOBUTYL BROMIDE
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Lquid SAFETY PROFILE: Questionable carcinogen with experimental neoplastigenic data. Moderately toxic by intraperitoneal route. A dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.
BNT250 CAS: 52-51-7 HR: 3 2-BROMO-2-NITRO-l,3-PROPANEDIOL mf: C3H6BrN04 mw: 200.01 PROP: Crystals. Mp: 130-133'. Very sol in H2O.
BNUSOO CAS: 107-81-3 HR: 3 2-BROMOPENTANE DOT: UN 2343 mf: CsHllBr mw: 151.07 PROP: Colorless to yellow liquid; strong odor. Bp: 120°, fp: <-30°, d 1.211 @! 25'/25', flash p: 90'F. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Poison by intraperitoneal route. Mildly toxic by inhalation. A local irritant and narcotic in high concentration. Ingestion can cause liver damage. A dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES and CHLORINATED HYDROCARBONS, ALIPHATIC.
BNV750 CAS: 16532-79-9 HR: 3 4-BROMOPHENYLACETONITRILE mf: CgH6BrN mw: 196.06 SYNS: 4-BROMOBENZENEACETONITRILE 0 pBROMOBENZYL CYANIDE 0 4-BROMOBENZYLCYANIDE 0 p-BROMOPHENYLACETONITRILE0 2-(4BROM0PHENYL)ACETONITRILE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community RightTo-Know List. SAFETY PROFILE: Poison by intravenous route. See also BROMIDES and
218
BNV752 4-((3-((4-BROMOPHENYL)AMINO)-4,5-DIHYDRO-
NITRILES. When heated to decomposition it emits very toxic fumes of Br-, NO,, and CN-. BNV752 CAS: 301644-27-9 HR: 3 4-((3-((4-BROMOPHENYL)AMI")-4,5DlHYDRO-2H-BENZ(gNDAZOL-2YL)ACETYL)MORPHOLINE mf: C23H23BrN402 mw: 467.37 SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO, and Br-. BNV800 CAS: 107359-69-3 HR: 3 2-(4-BROMOPHENYL)-4-CHLORO-5-((4CHLOROPHENYL)METHOXY)-3(2H)PYRIDAZINONE mfi C17H11BrC12N202 mw: 426.11
SYNS: 1-BROMOPROPANE (DOT,! 0 PROPYL BROMIDE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Mildly toxic by inhalation. Experimental reproductive effects. Mutation data reported. Dangerous fire hazard when heated or exposed to flame or oxidizers. To fight fire, use water, foam, C02, dry chemical. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.
BNYOOO CAS: 75-26-3 HR: 3 2-BROMOPROPANE DOT: UN 2344 mw: 122.98 SYN: 3(2H)-PYRIDAZINONE,2-(4-BROMOPHENYL-4-mf: C3H7Br CHLORO-5-((4-CHLOROPHENYL)METHOXY)PROP: Liquid. Flash p: <14O, d: 1.31 @ SAFETY PROFILE: A poison by ingestion. 20°/4", fp: -89", bp: 59.35'. When heated to decomposition it emits SYN: ISOPROPYL BROMIDE toxic vapors of NO,, Br-, and C1-. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. BNX035 CAS: 107359-76-2 HR: 3 DOT CLASSIFICATION: 3; Label: 5-((4-BROMOPHENYL)METHOXY)-4Flammable Liquid CHLORO-2-(4-CHLORO-2-FLUOROSAFETY PROFILE: Moderately toxic by PHENYL)-3(2H)-PYRlDAZlNONE intraperitoneal route. A very flammable mf: C1~H10BrC12FN202 mw: 444.10 liquid and dangerous fire hazard. When SYN: 3(2H)-PYRIDAZINONE,5-((4-BROMOPHENYL)heated to decomposition it emits toxic METHOXY)-4-CHLORO-2-(4-CHLORO-2-FLUOROPHENfumes of Br-. See also BROMIDES. YL)SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits BNZOOO CAS: 598-31-2 HR: 3 toxic vapors of NO,, F-, Br-, and C1-. BROMO-2-PROP ANONE DOT: UN 1569 BNX330 CAS: 315706-76-4 HR: 3 mf: C3H5BrO mw: 136.99 3-(4-BROMOPHENYL)-N-(CPROPYLPROP: bquid whch turns violet rapidly. D: CYCL0HEXYL)-2-PROPENAMIDE 1.634", fp: -36.5', bp: 136.5" @ 725 mm. mf: C18H24BrNO mw: 350.30 SYNS: ACETONYL BROMIDE ACETYL METHYL SAFETY PROFILE: A poison by ingestion. BROMIDE 0 BROMOACETONE 0 BROMOACETONE (DOT 0 BROMOACETONE,liquid (DO'IJ 0 BROhlOWhen heated to decomposition it emits METHYL METHYL KETONE 0 1-BROMO-2-PROPANtoxic vapors of NO, and Br-. ONE 0 MONOBROMOACETONE 0 RCRA WASTE NUMBER PO17
BNX750 CAS: 106-94-5 HR: 3 1-BROMOPROPANE mf: C3H7Br mw: 123.01 PROP: Liquid. Mp: -llOo, bp: 71', d: 1.35 @ 20°/4", autoign temp: 914'F, flash p: <22", lel: 4.6%.
DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A poisonous gas.
Moderately toxic to humans by inhalation. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.
BROMOTRIETHYLSTANNANE
BOB250 CAS: 590-92-1 HR: 2 3-BROMOPROPIONIC ACID mf: C3HsB1-02 mw: 152.99 PROP: Plates. D: 1.485, mp: 62.5', bp: 140-142' @ 45 mm. SYN: P-BROMOPROPIONIC ACID CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by intraperitoneal route. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.
BOC600 CAS: 122322-20-7 HR: 3 5-((6-BROMO-3-PYRlDlNYL)METHOXY)4-CHLORO-2-(4-CHLOROPHENYL)3(2H)-PYRIDAZINONE mf: C16H10BrC12N302 mw: 427.10 SYN: 3(2H)-PYRIDAZINONE, 5-((6-BROM0-3PYRIDINYL)METHOXY)-4-CHLORO-2-(4-CHLOROPHENYL)-
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO,, Br-, and C1-.
BOE750 CAS: 13465-73-1 HR: 3 BROMOSILANE mf: BrH3Si mw: 111.02 SYN: SILYL BROMIDE DOT CLASS1FlCATlON : Forbidden SAFETY PROFILE: Ignites spontaneously upon exposure to air. When heated to
decomposition it emits toxic fumes of Br-. BOF500 CAS: 128-08-5 HR: 3 N-BROMOSUCCINIMIDE mf: C4H4BrNOz mw: 178.00 PROP: m t e to pale-buff, fme, orthorhombic, crystalline powder with faint odor of bromine. Mp: 173-175', d: 2.098. Sol in Me2CO; sltly sol in AcOH, H20, and CC4; prac insol in hexane. SYNS: I-BROMO-2,5-PYRROLIDINEDIONE 0 XBROMOSUCCIMIDE 0 SUCCINBROMIMIDE 0 SUCCINIBROMIMIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
801750
219
SAFETY PROFILE: Poison by intraperitoneal route. An irritating poison to shn, eyes, and mucous membranes. Reacts explosively with a d m e , dtallyl sulfide, and hydrazine hydrate. Explosive reaction with propiononitrile after heating to 105'C for 24 hours. Violent reaction with dtbenzoyl peroxide + 4 - t o k acid. When heated to decomposition it emits toxic fumes of Brand NO,. See also BROMIDES and NITROGEN MONOXIDE.
BOG255 CAS: 106-38-7 p-BROMOTOLUENE mf: C7H7Br mw: 171.05
HR: 2
SYNS: PARABROMOTOLUENE 0 TOLUENE, pBROMOCONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by inhalation and intraperitoneal routes. When heated to decomposition it emits toxic vapors of Br-.
BOH750 CAS: 75-62-7 HR: 3 BROMOTRICHLOROMETHANE mf: CBrCb mw: 198.27 PROP: Colorless liquid. Fp: -5.8', bp: 104.2', d: 2.01 @ 20'/4'. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Narcotic in high concentration. Mutation data reported. See also CHLOROFORM. Incompatible with ethylene. When heated to decomposition it emits very toxic fumes of C1- and Br-. B01750 CAS: 2767-54-6 HR: 3 BROMOTRIETHYLSTANNANE mfi C6H15BrSn mw: 285.81 PROP: Colorless liquid. D: 1.630, mp: -13.5', bp: 221.' Sol in org solvs. SYNS: TRIETHYLSTANNIUM BROMIDE 0 TRIETHYL TIN BROMIDE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin)
220
BOJOOO
BROMO TRIFLUOROETHYLENE
ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m3 (skm). NlOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Moderately toxic by inhalation. Experimental reproductive effects. See also TIN COMPOUNDS and BROMIDES. When heated to decomposition it emits toxic fumes of Br-.
BOJOOO CAS: 598-73-2 HR: 3 BROMO TRIFLUOROETHYLENE mf: B r F G mw: 160.94 PROP: Gas. Bp: -2.5'. SYNS: BROMOTRIFLUOROETHENE 0 TRIFLUOROBROMOETHYLENE 0 TRIFLUOROVINYLBROMIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison. A flammable
gas. I p t e s spontaneously in air. Incompatible with powerful oxidmers, 0 2 . When heated to decomposition it emits highly toxic fumes of Br-, F-, and COCF2.
BOLO00 CAS: 51-20-7 HR: 2 5-BROMOURACI L mf: C4H3BrN202 mw: 191.00 PROP: Prisms from H20. Mp: 293'. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by intraperitoneal route. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of Br- and NO,. BOL750 CAS: 357-57-3 HR: 3 BRUCINE DOT: UN 1570 mf: C23H~N204 mw: 394.51 PROP: Crystals, powder, or monoclinic prisms. Mp: 105' (hydrate), mp: 78' (anhydrate). Sol in EtOH and CHCL; sltly sol in C6H6 and Et2O. An alkaloid extracted from Styhnas seeds (WQCHM* 4,-,74). SYNS: BRUCINA (ITALIAN) 0 (-)-BRUCINE 0 BRUCINE (DOV 0 2,3-DIhfETHOXYSTRYCHNIDIN-10ONE 0 DIMETHOXY STRYCHNINE (DOV 0 2,3-
DIMETHOXYSTRYCHNINE 0 10,lI-DIMETHYSTRYCHNINE 0 STRYCHNIDIN-10-ONE,2,3DIhIETHOXY(9CI) 0 STRYCHNINE, 2,3-DIMETHOXY0 RCRA WASTE NUMBER PO18
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A poison by
subcutaneous, intravenous, and intraperitoneal routes. An alkaloid-like strychnine, but one-sixth as toxic. When heated to decomposition it emits toxic fumes of NO,. See also STRYCHNINE.
BOM250 CAS: 129-74-8 HR: 3 BUCLlZlNE DIHYDROCHLORIDE mf: C ~ E H U C ~ N Z * ~ C mw: ~ H 506.00 PROP: Crystals. Mp: 265-266'. SYNS: BUCLODIN 0 l-@-tert-BUTYLBENZn)-4-@CHLOROD1PHENYLhlETHYL)PIPEMZINE DIHYDROCHLORIDE 0
[email protected])PIPEMZINEDIHYDROCHLORIDE 0 1-@-CHLOROBENZHYDRYL)-4-@-tert-BUlTLBENZYL)DIETHKENEDIAMINE DIHYDROCHLORIDE 0 l-pCHLOROBENZHYDRYL-4-p-(tert)-BUTYLBENZYLPIPERAZINE DIHYDROCHLORIDE 0 HISTABUTYZINE DIHYDROCHLORIDE 0 LONGIFENE 0 SOFTRAN 0 UCB 4445 0 VIBAZINE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. An experimental teratogen. When heated to decomposition it emits very toxic fumes of NO, and HC1.
BOO632 CAS: 5486-03-3 BUQUINOLATE mf: C20HnN05 mw: 361.42 PROP: Crystals. Mp: 288-291".
HR: D
SYNS: BONAID 0 ETHYL-6,7-DIISOBUTOXY-4HYDROXYQUINOLINE-3-CARBOXYLATE 0 4HYDROXY-6,7-BIS(2-METHYLPROPOXY)-3QUINOLINECARBOXYLIC ACID ETHER ESTER 0 4-
HYDROXY-6,7-DIISOBUTOXY-3QUINOLINECARBOXYLIC ACID ETHYL ESTER
SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes.
BOP100 CAS: 25339-57-5 BUTADIENE DOT: UN 1010
HR: 3
BUTANE
mf: C4H6
mw: 54.10
SYNS: BUTADIENES,inhibited ('DO9 0 PLIOLITE DOT CLASSIFICATION: 2.1; Label:
Flammable Gas SAFETY PROFILE: A flammable gas. When heated to decomposition it emits acrid smoke and irritating vapors.
BOP500 CAS: 106-99-0 HR: 3 1,SBUTADIENE mf: C4H6 mw: 54.10 PROP: Colorless gas; rmld aromatic odor. Very reactive. Bp: -2.6', rnp: -113', fp: -108.9', flash p: -105'F, lel: 2.0%, uel: llSO/O,d: 0.621 @ 20"/4', autoign temp: 788'F, vap d: 1.87, vap press: 1840 mm @ 21'. IDLH 2000 ppm [lOYoLEL]. SYNS: BIETHYLENE 0 BIVINYL 0 BUTADIEEN (DUTCH) 0 BUTADIEN (DUTCH) 0 BUTAA-l,3-DIEEN (POLISH) 0 BUTL4-1,3-DIEN(GERMAN) 0 BUTA-1,3DIENE 0 a-y-BUTADIENE 0 DIVINYL 0 ERYTHRENE 0 NCI-C50602 0 PYRROLYLENE 0 VINYLETHYLENE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2A IMEMDT 54,237,92; Animal Sufficient Evidence IMEMDT 39,155,86; IARC Cancer Review: Animal Sufficient Evidence IMEMDT 54,237,92; Human Lmited Evidence IMEMDT 54,237,92; Human Inadequate Evidence IMEMDT 39,155,86; NTP Carcinogenesis Studies (inhalation); Clear Evidence: mouse NTPTR* NTP-TR-288,84. Reported in EPA TSCA Inventory. Community RightTo-Know List. OSHA PEL: TWA 1 ppm; STEL 5 ppm ACGlH TLV: TWA 2 ppm; Suspected Human Carcinogen DFG MAK: Confirmed Human Carcinogen NlOSH REL: Reduce to lowest feasible level SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. An experimental teratogen. Mutation data reported. Inhalation of high concentrations can cause unconsciousness and death. Human systemic effects by inhalation: cough, hallucinations, dstorted perceptions, changes in the visual field and other
BOR500 221
unspecified eye effects. The vapors are irritating to eyes and mucous membranes. If spilled on s h n or clohng, it can cause burns or frostbite (due to rapid vaporization). Chronic systemic poisoning in humans has not been reported. Dangerous fire hazard when exposed to heat, flame, or powerful oxidizers. Upon exposure to air it forms explosive peroxides sensitive to heat, shock, or heating above 27'C. May decompose explosively when heated above 2OO0C/1.O kbar. Explodes on contact with aluminum tetrahydroborate. Potentially explosive reaction with NO, + 0 2 , ethanol + iodne + mercury oxide (at 35'C), ClOz, crotonaldehyde (above 1SO'C), buten-3-yne (with heat and pressure). Reaction with sodlum nitrite forms a spontaneously flammable product. Exothermic reaction with boron trifluoride etherate + phenol. To fight fire, stop flow of gas. When heated to decomposition it emits acrid smoke and fumes. v
,
BOP750 CAS: 30031-64-2 HR: 3 I-BUTADIENE DlEPOXlDE mf: C4H602 mw: 86.10 PROP: Solid or liquid. Mp: 24-25.6', bp: 144.5-145'. SYNS: (S-(R*,R*))-Z,Z'-BIOXIRANE 0 I-DIEPOXYBUTANE 0 (2S,3S)-DIEPOxiSUTANE 0 1-1,2:3,4DIEPOXYBUTANE 0 (2S,3S)-1,2:3,4-DIEPOXYBUTANE 0 NSC-32606
CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 11,115,76. EPA Genetic Toxicology Program. SAFETY PROFILE: Suspected carcinogen with experimental neoplastigenic data. Poison by intraperitoneal route. Mutation data reDorted. When heated to I decompos ion it emits acrid and irritating fumes. CAS: 106-97-8 BOR500 BUTANE DOT: UN 01 1 mw: 58.14 mf: C4H10
HR: 3
222
BOSOOO
1,4-BUTANEDIAMINE
PROP: Colorless gas; faint disagreeable odor. Bp: -0.5', fp: -135', lel: 1.go/o, uel: 8.5%, flash p: -76'F (CC), d: 0.599, autoign temp: 761'F, vap press: 2 atm @ 18.8', vap d: 2.046. Sltly sol in H20; mod sol in Et2O and CHCL. SYNS: n-BUTANE (DOT) 0 BUTANE MIXTURES (DOT,! 0 BUTANEN (DUTCH) 0 BUTANI (ITALIAN) 0 DIETHYL 0 METHYLETHYLMETHANE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 800 pprn ACGIH TLV: TWA 800 pprn DFG MAK: 1000 ppm (2400 mg/m3) DOT CLASSIFICATION: 2.1; Label: Flammable Gas SAFETY PROFILE: Mildly toxic by inhalation. Causes drowsiness. An asphyxlant. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. Highly explosive when exposed to flame, or when mixed with pi(C0)4 + 0 2 1 . To fight fire, stop flow of gas. When heated to decomposition it emits acrid smoke and fumes.
BOSOOO CAS: 110-60-1 HR: 3 1,4-BUTANED1AM1NE mf: C4Ht2Nz mw: 88.18 PROP: Crystals with strong odor. Mp: 27-28', bp: 158-1 59'. SYNS: BUTYLENEDIAMINE 0 1,4-BUTYLENEDIAXfINE 0 1,4-DIAMINOBUTANE 0 PUTRESCIN 0 PUTRESCINE 0 TETRAMETHYLENEDIAMINE0 1,4TETRAhfETHYLENEDIAMINE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous, intravenous, and rectal routes. Moderately toxic by ingestion. An experimental teratogen. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also 1,3-BUTANEDIAMINE and AMINES. BOS250 CAS: 584-03-2 1,2-BUTANEDIOL mf: C4H1002 mw: 90.14
HR: 2
PROP: D: 1.0, vap d: 3.1, bp: 194', flash p:
194OF. SYN: 1,2-BCTYLENE GLYCOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Combustible when exposed to heat or flame. To fight fire, use alcohol foam. When heated to decomposition it emits acrid and irritating fumes.
BOS500 CAS: 107-88-0 HR: 1 1,3-BUTANEDIOL mf: C4H1002 mw: 90.14 PROP: Viscous liquid. Bp: 207.5', fp: <-50°, flash p: 250'F, d 1.006 @ 2Oo/2O0, autoign temp: 741'F, vap press: 0.06 mm @ 20°, vap d: 3.2. SYNS: 1,3-BUTANDIOL(GEILhWV) 0 BUTANE-1,3DIOL 0 P-BCTYLENE GLYCOL 0 1,3-BUTYLENE GLYCOL (FCC) 0 1,3-DIHMROXYBUTANE 0 METHYLTRIMETHYLENE GLYCOL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: M d l y toxic by ingestion and subcutaneous routes. A skin and eye irritant. See also ETHYLENE GLYCOL. Experimental reproductive effects. Combustible when exposed to heat or flame. Incompatible with oxidizing materials. To fight fire, use foam, alcohol foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
BOS750 CAS: 110-63-4 HR: 3 1,4-BUTANEDlOL mf: C4H1002 mw: 90.14 PROP: Nearly odorless, colorless, viscous liquid or crystals; to needles on chilling. Mp: 16O, bp: 230°, flash p: 250'F (OC), d: 1.02 @ 20', vap d: 3.1. SYNS: BUTANE-l,4-DIOL 0 1,CBUTYLENEGLYCOL 0 1,CDIHYDROXYBCTANE 0 1,4-TETRAhfETHYLENE GLYCOL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A human poison by an unspecified route. Moderately toxic by
2,3-BUTANEDIONE
ingestion and intraperitoneal routes. Human systemic effects: altered sleep time. Combustible when exposed to heat or flame. To fight fire, use alcohol foam, mist, foam, C02, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid smoke and fumes. BOTOOO CASE513-85-9 HR: 1 2,3-BUTANEDIOL mf: C4H1002 mw: 90.14 PROP: Colorless liquid or solid. Bp: 180°, fp: 19', flash p: 185'F (TOC), d: 1.0095 @ 2Oo/2O0, autoign temp: 756'F, vap press: 0.17 mm @ 20', vap d: 3.1. SYNS: 2,3-BUTYLENEGLYCOL0 2,3DIHYDROXYBUTAKE 0 DIMETHYLENE GLYCOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion. See also ETHYLENE GLYCOL. Flammable when exposed to heat or flame. Incompatible with oxidizing materials. To fight fire, use alcohol foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
BOT250 CAS: 55-98-1 HR: 3 1,CBUTANEDIOL DIMETHYL SULFONATE mf: CbH140~Sz mw: 246.32 PROP: White crystals or needles. Mp: 116'. SYNS: 1,4-BIS(METHANESULFONOXY)BUTANE0 (1,4-BIS(METHANESULFONYLOXY)BUTANE) 0 BISULFAN 0 BISULPHANE 0 1,4-BUTANEDIOL DIMETHANESULPHONATE 0 BUZULFAN 0 C.B. 2041 0 CITOSULFAN 0 1,4-DIMESYLOXUTANE 0 1,4DIMETHANESULFONOXYBUTANE 0 1,4DI(METHA?VESULFONYLOXY)BCTANE0 1,4DIMETHANESULPHONYLOXUTANE 0 1,4DIMETHYLSULFONOXYBUTANE 0 GT41 0 GT 2041 0 LEUCOSULFAN 0 EviABLIN 0 METHANESULFONIC ACID TETRAMETHYLENE ESTER 0 MIELUCIN 0 MISULBAN 0 MITOSTAW 0 iMYELOLEUKON 0 MYLERAN 0 NCI-C01592 0 NSC-750 0 SULPHABUTIN 0 TETRAMETHYLENE BIS(METHANESULF0NATE)0 TETRAMETHYLENE DIMETHANE SULFONATE 0 X 149
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
BOT500
223
Group 1 IMEMDT 7,137,87; Animal Inadequate Evidence IMEMDT 4,247,74; Huma; Inadequate Evidence IMEMDT 4,247,74. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen producing leukemia, kidney, and uterine tumors. Experimental neoplastigenic and tumorigenic data. Poison by ingestion, subcutaneous, intraperitoneal, intravenous, and possibly other routes. Ingestion by pregnant women can cause cancer of the reproductive system of the fetus includtng the uterus. Human teratogenic effects by ingestion and possibly other routes include developmental abnormaltties of the eye, ear, craniofacial area including the nose and tongue, gastrointestinal system, endocrine system, urogenital system, and other unspecified areas. Other human reproductive effects by ingestion and possibly other routes include: impotence, changes in the uterus, cervix, and vagina, and menstrual-cycle dtsorders. Experimental reproductive effects. Human systemic effects by ingestion: general arteriolar or venous ddation of the eye, changes in structure or function of salivary glands. When heated to decomposition it emits toxic fumes of SO,. See also SULFONATES. BOT500 CAS: 431-03-8 HR: 3 2,3-BUTANEDIONE DOT: UN 2346 mf: C4H602 mw: 86.10 PROP: Greenish-yellow liquid; strong odor. Bp: 8 8 O , flash p: 80'F, d: 0.9904 @ 15'/15', refr index: 1.393-1.397, vap d: 3.00. Msc in alc, fEed oils, propylene glycol; sol in glycerin, alc, water. SYNS: BIACETYL 0 BUTADIONE 0 BUTANEDIONE (DOT) 0 DIACETYL (FCC) 0 2,3-DIKETOBUTANE 0 DIMETHYL DIKETONE 0 DIMETHYLGLYOXAL 0 GLYOXAL, DIMETHYL- 0 FEMA No. 2370
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
224
BOU250 BUTANE SULTONE
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by ingestion
and intraperitoneal routes. A skin irritant. Human inhalation hazard in popcorn manufacture. Human mutation data reported. Flammable liquid. Dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also KETONES. BOU250 CAS: 1633-83-6 HR: 3 BUTANE SULTONE mf: C4Hs03S mw: 136.18 PROP: Liquid. D: 1.33 @ 20'/4', mp: 12.5-14.5', bp: 134-136' @ 4 mm. SYNS: BUTANESULFONE 0 A-BUTANE SULTONE 0 1,4-BUTAlVESULTONE (AUK) 0 1,4-BUTYLENE SULFONE 0 A-VALEROSULTONE
CONSENSUS REPORTS: EPA Genetic
Toxicology Program.Reported in EPA TSCA Inventory. DFG MAK: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic data. Poison by subcutaneous, intravenous, and intraperitoneal routes. Moderately toxic by ingestion. Experimental reproductive effects. Human mutation data reported. See also SULFONATES. When heated to decomposition it emits toxic fumes of SO,. BOVOOO CAS: 96-48-0 HR: 2 4-BUTANOLIDE mf: C4H602 mw: 86.10 PROP: Colorless liquid; mild caramel odor. Mp: -44', bp: 203-204', flash p: 209'F (OC), d: 1.441 @ O', refr index: 1.434-1.454 @ 25', vap d: 3.0. Misc in HzO. SYNS: y-6480 0 y-BL 0 BLO 0 BLON 0 BUTYRIC ACID LACTONE 0 a-BUTYROLACTONE 0 yBUTYROLACTONE (FCC) 0 BUTYRYL LACTONE 0 4DEOXYTETRONIC ACID 0 DIHYDRO-Z(3H)-n'RANONE 0 FEMA No. 3291 0 4-HYDROXYBUTANOIC ACID LACTONE 0 y-HYDROXYBUTYRIC ACID CYCLIC ESTER 0 4-HYDROXYBUTYRIC ACID y-LACTONE 0 y-
HYDROXYBUTYROLACTONE 0 NCIX55878 0 TETRAHYDRO-2-FURANONE
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal No Evidence IMEMDT 11,231,76. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion, intravenous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Questionable carcinogen with experimental tumorigenic data by skin contact. Mutation data reported. Less acutely toxic than ppropiolactone. Combustible when exposed to heat or flame; can react with oxidizing materials. T o fight fire, use foam, alcohol foam, COZ,dry chemical. Potentially explosive reaction with butanol + 2,4dichlorophenol + sodium hydroxide. When heated to decomposition it emits acrid and irritating fumes. BOW250 CAS: 25167-67-3 HR: 3 1-BUTENE mf: C4H8 mw: 56.11 PROP: A colorless, flammable gas; sltly aromatic odor. Bp: -6.3', fp: -185.3', lel: l.6%, uel: 9.3%, flash p: -80' (-112'F), d: 0.668 @ O0/1', vap d: 2.93, vap press: 3480 mm @ 21', autoign temp: 723'F. SYNS: BUTYLENE 0 WBUTYLENE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. ACGIH TLV: (Proposed: TWA 250 ppm.) SAFETY PROFILE: A simple asphyxlant. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. To fight fire, stop flow of gas. Moderately explosive when exposed to flame. Mxtures with aluminum tetrahydroborate explode after an induction period. When heated to decomposition it emits acrid smoke and fumes. BOX750 CAS: 106-88-7 1-BUTENE OXIDE DOT: UN 3022 mfi C4H80 mw: 72.12
HR: 3
2-BUTOXYETHANOL PROP: Colorless liquid. D: 0.8312 @I
2Oo/2O0, bp: 63', flash p: 5'F, lel: 1.5%, uel: 18.3%. Sol in water; misc with most org solvs. SYNS: BUTYLENE OXIDE 0 1,2-BUTYLENEOXIDE 0 1,2-BUTYLENEOXIDE, stabilized (DOT) 0 EPOXYBUTANE 0 1,2-EPOXYBUTANE ETHYLENE OXIDE, ETHYL- 0 ETHYL ETHYLENE OXIDE 0 ETHYLOXIRANE 0 NCI-C55527
CONSENSUS REPORTS: NTP
Carcinogenesis Studies (inhalation); Clear Evidence: rat; No Evidence: mouse NTPTR* NTP-TR-329,88. Community Right-To-Know List. EPA Genetic Toxicology Program.Reported in EPA TSCA Inventory. DFG MAK: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by ingestion and s h n contact. Mtldly toxic by inhalation. Experimental reproductive effects. Mutation data reported. Dangerous fire hazard when exposed to heat, flame, or powerful oxidizers. To fight fire, use dry chemical, water spray, mist or fog, alcohol foam. When heated to decomposition it emits acrid smoke and fumes. BOY000 CAS: 6117-91-5 HR: 2 2-BUTEN-1-OL mf: mw: 72.12 PROP: Colorless liquid. Mp: <30°, bp: 118', flash p: 92"F, d: 0.8726 @I 0°/4', vap d: 2.49. SYNS: 2-BUTENOL 0 2-BUTENYL ALCOHOL 0 CROTONYL ALCOHOL 0 CROTYL ALCOHOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and skin contact. Mutation data reported. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. To fight fire, use alcohol foam, COz, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also ALCOHOLS.
BPJ850 225
BOY500 CAS: 78-94-4 HR: 3 3-BUTEN-2-ONE DOT: UN 1251 mf: C ~ H G O mw: 70.10 PROP: Colorless liquid; powerfully irritating odor. Bp: 81.4', flash p: 20'F (CC), d: 0.8393 @I 25'/4', vap d 2.41. SYNS: ACETYL ETHYLENE 0 3-BUTENE-2-ONE 0 METHYLENE ACETONE 0 METHYL-VINYL-CETONE (FRENCH) 0 METHYLVINYLKETON (GERMAN) 0 METHYL VINYL KETONE 0 y-0x0-a-BUTYLENE 0 VINYL METHYL KETONE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. ACGIH TLV: STEL CL 0.2 ppm ( s h , sensitizer) DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Poison by ingestion, inhalation, and intraperitoneal routes. A severe irritant to skin, eyes, and mucous membranes. A lachrymator. Mutation data reported. See also KETONES. Dangerous fire hazard when exposed to heat, flame, or oxidizers. To fight fire, use COz, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
BPJ850 CAS: 111-76-2 HR: 3 2-BUTOXYETHANOL DOT: UN 2369 mf: C6H1402 mw: 118.20 PROP: Clear, mobile liquid; pleasant odor. Fp: -74.8', bp: 171-172', flash p: l6O'F (COC), d: 0.9012 @I 2Oo/2O0, vap press: 300 mm @ 140'. IDLH 700 ppm. SYNS: BUCS 0 BUTOKSYETYLOVC'YALKOHOL (POLISH) 0 2-BUTOSSI-ETANOLO(ITALIAN) 0 2BUTOXY-AETHAVOL ( G E R \ W ) 0 BUTOXYETHANOL 0 n-BUTOXYETHANOL 0 2-BUTOXY-1-ETHANOL0 BUTYL CELLOSOLVE 0 o-BUTYL ETHYLENE GLYCOL 0 BUTYL GLYCOL 0 BUTYLGLYCOL (FRENCH, GERMAN) 0 BUTYL OXITOL 0 DOWANOL EB 0 EGBE 0 EKTASOLVE EB 0 ETHYLENE GLYCOL-nBUTYL ETHER 0 ETHYLENE GLYCOL MONOBUTYL ETHER (MAY D O T 0 GAFCOL EB 0 GLYCOL BUTYL ETHER 0 GLYCOL ETHER EB 0 GLYCOL ETHER EB ACETATE 0 GLYCOL MONOBUTYL ETHER 0 JEFFERSOL EB 0 MONOBUTYL GLYCOL ETHER 0 3Om-I-HElTANOL 0 POLY-SOLV EB
226
BPK250
2-BUTOXYETHANOL PHOSPHATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Glycol ethers are on the Community kght-To-Know List. OSHA PEL: TWA 25 pprn (skin) ACGIH TLV: 20 ppm (skin); Confirmed Animal Carcinogen. DFG MAK: 20 pprn (98 mg/m3) DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by ingestion, skin contact, intraperitoneal, and intravenous routes. Moderately toxic via inhalation and subcutaneous routes. Human systemic effects by inhalation: nausea or vomiting, headache, unspecified eye effects. Experimental teratogenic and reproductive effects. A skin irritant. Combustible liquid when exposed to heat or flame. To fight fire, use foam, C02, dry chemical. Incompatible with oxidizing materials, heat, and flame. When heated to decomposition it emits acrid smoke and irritating fumes. BPK250 CAS: 78-51-3 HR: 3 2-BUTOXYETHANOL PHOSPHATE mf: C18H3907P mw: 398.54 PROP: Light-colored liquid; butyl-like odor. Mp: -70', bp: 200-230' @? 4 mm, flash p: 435'F, d: 1.02 @? 2Oo/2O0, vap press: 0.03 mm @? 150°, vap d: 13.8. SYNS: KP 140 0 KRONITEX KP-140 0
PHOSFLEX TBEP O TBEP O TRI(2-BUTOXYETHANOL PHOSPHATE) 0 TRIBUTOXYETHYLPHOSPHATE 0 TRI(2-BUTOXYETHYL) PHOSPHATE 0 TRIBUTYL CELLOSOLVE PHOSPHATE 0 TRIS(2-BUTOXYETHYL)ESTER PHOSPHORIC ACID 0 TRIS(2-BUTOXYETHYL) PHOSPHATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by intravenous route. Moderately toxic by ingestion. A skin and eye irritant. Combustible when exposed to heat or flame. Dangerous; see also PHOSPHATES; can react with oxidizing materials. To fight fire, use water, foam, COz, dry chemical. When heated to decomposition it emits toxic fumes of PO,.
BPLSOO CAS: 124-16-3 HR: 2 1-BUTOXY ETHOXY-2-PROPANOL mf: C9H2003 mw: 176.29 PROP: D: 0.9310 @? 2Oo/2O0, bp: 230.3', fp: -90°, flash p: 250'F (OC). Sol in water. SYN: 1-(2-BUTOXYETHOXu)-2-PROPANOL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and skin contact. A s h n and eye irritant. Combustible when exposed to heat or flame. T o fight fire, use alcohol foam, dry chemical, spray, or mist. When heated to decomposition it emits acrid and irritating fumes.
BPMOOO CAS: 112-07-2 HR: 3 2-BUTOXYETHYL ACETATE mf: C8H1603 mw: 160.24 PROP: Colorless liquid; fruity odor. Bp: 192.3', d: 0.9424 @? 20°/200, fp: -63.5', flash p: 190'F. Sol in hydrocarbons and org solvs; ins01 in water. SYNS: 2-BCTOXYETHANOLACETATE 0 2BUTOXYETHYL ESTER ACETIC ACID BUTYL CELLOSOLVE ACETATE 0 EKTASOLVE EB ACETATE 0 ETHYLENE GLYCOL IMONOBUTYL ETHER ACETATE (MAK) 0 GLYCOL MONOBUTYL ETHER ACETATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Glycol ethers are on the Community Right-To-Know List. ACGIH TLV: 20 ppm; Confirmed Animal Carcinogen DFG MAK: 20 pprn (130 mg/m3) SAFETY PROFILE: Moderately toxic by ingestion and skin contact. Mild skin irritant. Flammable when exposed to heat, flame, or oxidizers. To fight fire, use alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS. BPU750 CAS: 123-86-4 HR: 3 n-BUTYL ACETATE DOT: UN 1123 mf: C6H1202 mw: 116.18 PROP: Colorless liquid; strong fruity odor. Fp: -77', bp: 126', ULC: 50-60, lel: 1.4%,
BUTYL ACETOACETATE
uel: 7.5%, flash p: 72"F, d: 0.88 @ 2Oo/2O0, refr index: 1.393-1.396, autoign temp: 797'F, vap press: 15 mm @ 25". N s c with alc, ether, and propylene glycol. Sol in EtOH, Et2C0, and Me2CO; insol in H20. IDLH 1700 ppm [10%LEL]. SYNS: ACETATE de BUTYLE (FRENCH) 0 ACETIC ACID n-BUTYL ESTER 0 BUTILE (ACETATI &) (ITALIAN) 0 BUTYLACETAT (GERMAN) 0 BUTYL ACETATEOI-BUTYLACETATEOBUTYLACETATEN (DUTCH) 0 BUTYLE (ACETATE de) (FRENCH) 0 BUTYL. ETHANOATE 0 FEMA No. 2174 0 OCTAN n-BUTYLU POLISH) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 150 ppm; STEL 200 pprn ACGIH TLV: Proposed: 150 ppm; STEL 200 PPm DFG MAK: 100 ppm (480 mg/m3) DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by intraperitoneal route. M d l y toxic by inhalation and ingestion. An experimental teratogen. A skm and severe eye irritant. Human systemic effects by inhalation: conjunctiva irritation, unspecified nasal and respiratory system effects. A mild allergen. High concentrations are irritating to eyes and respiratory tract and cause narcosis. Evidence of chronic systemic toxicity is inconclusive. Flammable liquid. Moderately explosive when exposed to flame. Ignites on contact with potassium tert-butoxide. To fight fire, use alcohol foam, COZ,dry chemical. When heated to decomposition it emits acrid and irritating fumes. See also ESTERS.
BPVOOO CAS: 105-46-4 HR: 3 sec-BUTYL ACETATE DOT: UN 1123 mf: C6H1202 mw: 116.18 PROP: Colorless liquid; mdd odor. Bp: 112", flash p: 18", d: 0.862-0.866 @ 2Oo/2O0, vap d: 4.00, lel: 1.3%, uel: 7.5%. IDLH 1700 ppm [lOYoLEL]. SYNS: ACETATE de BUTYLE SECONDAIRE (FRENCH) 0 ACETIC ACID-2-BUTOXY ESTER 0 ACETIC ACID-1-
BPV250
227
METHYLPROPYL ESTER ( 9 0 2-BUTANOL ACETATE 0 sec-BUTYL ACETATE 0 2-BUTYL ACETATE 0 secBUTYL ALCOHOL ACETATE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 200 pprn ACGIH TLV: TWA 200 ppm DFG MAK: 100 ppm (480 mg/m3) DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: An irritant and allergen. See also ESTERS. Flammable liquid. To fight fire, use alcohol foam, COz, dry chemical. When heated to decomposition it emits acrid and irritating fumes.
BPV100 CAS: 540-88-5 HR: 3 tert-BUTYL ACETATE DOT: UN 1123 mf: C~H1202 mw: 116.18 PROP: Liquid. Bp: 97-98". IDLH 1500 pprn [l O%LEL]. SYNS: ACETIC ACID-tert-BUTYL ESTER 0 ACETIC ACID-l,l-DIMETHXETHYL ESTER 0 TEXACO LE4D APPRECIATOR 0 T W
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 200 ppm ACGIH TLV: TWA 200 ppm DFG MAK: 100 pprn (480 mg/m3) DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Poison by inhalation and ingestion. Flammable. To fight fire, use alcohol foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
BPV250 CAS: 591-60-6 HR: 1 BUTYL ACETOACETATE mf: C8H1403 mw: 158.22 PROP: Bp: 214", flash p: 185"F, d: 0.96, vap d: 5.55. SYNS: ACETOACETIC ACID BUTYL ESTER 0 3-0x0BUTANOIC ACID BUTYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mddly toxic by ingestion. A skin and eye irritant. See also
228
BPWl00
n-BUTYL ACRYLATE
ESTERS. Flammable. T o fight fire, use alcohol foam, C02, dry chemical. When heated to decomposition it emits acrid and irritating fumes. BPW100 CAS: 141-32-2 HR: 3 n-BUTYL ACRYLATE DOT: UN 2348 .~ mf: C7H1202 mw: 128.19 PROP: Water-white, extremely reactive monomer. Bp: 69' @ 50 mm, fp: -64.6', flash p: 120°F (OC), d: 0.89 @ 25'/25', vap press: 10 mm @ 35.5', vap d: 4.42. SYNS: ACRYLIC ACID BUTYL ESTER 0 ACRYLIC ACID n-BUTYL ESTER (MAK) 0 BUTYL ACRYLATE 0 BUTYWCRYLATE, INHIBITED (DO?? 0 BUTYL-2PROPESOATE ~I
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT39,67,86* Reported in EPA TSCA Inventory. Community fight-To-Ihow List. OSHA PEL: TWA 10 pprn ACGIH TLV: TwA PPm (sensitizer); Not Classifiable as a Carcinogen DFG MAK: 2 ppm (11 mg/m3) DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY by ingestion, inhalation, skin contact, and intraperitoneal routes. Experimental reproductive effects. A skin and eye irritant. Questionable carcinogen. A flammable liquid when exposed to heat Or flame* To fight fire, use foam, COz, dry chemical. Incompatible with oxidzing materials. When heated to decomposition it emits acrid and irritating fumes. See also ESTERS.
BPWSOO CAS: 71-36-3 HR: 3 n-BUTYL ALCOHOL mf: C4H100 mw: 74.14 PROP: Colorless liquid; vinous odor. Bp: 117.4', ULC: 40, lel: 1.4%, uel: 11.2%, fp: -90°, flash p: 95-100°F, d: 0.80978 @ 20°/4', autoign temp: 689'F, vap press: 5.5 mm @ 20°, vap d: 2.55. Misc in alc, ether, and org solvs. Mod sol in water. IDLH 1400 pprn [
SYNS: ALCOOL BUTYLIQUE (FRENCH)
0 BUTANOL (FRENCH) 0 n-BUTANOL 0 BUTAN-1-OL 0 1BUTANOL 0 BUTANOL (DOT) 0 BUTANOLEN (DUTCH) BUTANOLO (ITALIAN) 0 B U T n ALCOHOL (DOT) 0 BUTYL HYDROXIDE 0 BUTYLOWY ALKOHOL POLISH) 0 BUTYRIC or NORMAL PRIMARY BUTYL ALCOHOL CCS 203 0 FEMA NO.2178 1-HYDROXYBUTANE 0 METHYLOLPROPANE 0 PROPYLCARBINOL PROPYLMETHANOL 0 RCRA WASTE NUMBER U031
CONSENSUS REPORTS: Community Right-To-Know Lst. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. OSHA PEL: CL 50 ppm (sktn) ACGIH TLV: TWA 20 ppm DFG MAK: 100 pprn (310mg/m3) SAFETY PROFILE: A poison by intravenous route. Moderately toxic by skin contact, ingestion, subcutaneous, and intraperitoneal routes. Human systemic effects by inhalation: conjunctiva irritation, unspecified respiratory system effects, and nasal effects. Experimental reproductive effects, A Severe sktn and eye irritant. Though animal experiments have shown the butyl alcohols to possess toxic properties, they have produced few cases of poisoning in industry, probably because of their low voladty, The use of normal butyl alcohol is reported to have resulted in irritation of the eyes, with corneal inflammation, slight headache and hzziness, slight irritation of the nose and throat, and dermatitis about the fingern& and along the side of the fingers. Keratitis has also been reported. Mutation data reported. See also ALCOHOLS. Flammable liquid. Moderately explosive when exposed to flame. Incompatible with Al, chromium trioxide, oxidizing materials. To fight fire, use water spray, alcohol foam, COz, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
BPW750 CAS: 78-92-2 sec-BUTYL ALCOHOL mf: C4H100 mw: 74.14
HR: 3
n-BUTYLAMINE PROP: Colorless liquid. Mp: -89", bp: 99.5", flash p: 14", d: 0.808 @ 20"/4", autoign temp: 763"F, vap press: 10 mm @ 20°, vap d: 2.55, lel: 1.7% @ 212"F, uel: 9.8% @ 212°F. IDLH 2000 ppm. SYNS: ALCOOL BUTYLIQUE SECONDAIRE (FRENCH) 0
sec-BUTANOL (DOT) 0 BUTAN-2-OL 0 2-BUTANOL
0 BUTANOL SECONDAIRE (FRENCH) 0 2-BUTYL
ALCOHOL 0 BUTYLENE HYDRATE 0 CCS 301 0 ETHYLMETHYL CARBINOL 0 2-HYDROXYBUTANE 0 METHYLETHYLCARBINOL 0 S.B.A.
CONSENSUS REPORTS: Community fight-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 100 ppm ACGIH TLV: TWA 100 pprn DFG MAK: 100 pprn (310 mg/m3) SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Mildly toxic by ingestion. Experimental reproductive effects. A skin and eye irritant. See also nBUTYL ALCOHOL and ALCOHOLS. Dangerous fire hazard when exposed to heat or flame. Auto-oxidizes to an explosive peroxide. Ignites on contact with chromium trioxide. To fight fire, use water spray, alcohol foam, C02, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid smoke and fumes.
BPXOOO CAS: 75-65-0 HR: 3 tert-BUTYL ALCOHOL mf: C4H100 mw: 74.14 PROP: Colorless liquid or rhombic prisms or plates with camphoraceous odor. Mp: 25.5", bp: 82.8", flash p: 50°F (CC), d: 0.781 @ 25"/4", autoign temp: 896"F, vap press: 40 mm @ 24.5", vap d: 2.55, lel: 2.4%, uel: 8.0%. MISCin H20.IDLH 1600 ppm. SYNS: ALCOOL BUTYLIQUE TERTIAIRE (FRENCH) 0 ten-BUTAh-OL 0 BUTANOL TERTIAIRE (FRENCH) 0 tert-BUTYL HYDROXIDE 0 1,l-DIMETHYLETHANOL 0 2-METHYL-2-PROPANOL 0 NCK55367 0 TRIMETHYL CARBINOL
CONSENSUS REPORTS: Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology
Program. OSHA PEL: TWA 100 ppm; STEL 150 pprn
BPX750
229
ACGIH TLV: TWA 100 ppm; Not
Classifiable as a Human Carcinogen DFG MAK: 100 ppm (310 mg/m3) SAFETY PROFILE: Moderately toxic by ingestion, intravenous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Dangerous fire hazard when exposed to heat or flame. Moderately explosive in the form of vapor when exposed to flame. Ignites on contact with potassium-sodum alloys. To fight fire, use alcohol foam, C02, dry chemical. Incompatible with oxidizing materials, H202. See also n-BUTYL ALCOHOL and ALCOHOLS. BPX750 CAS: 109-73-9 HR: 3 n-BUTYLAMINE DOT: UN 1125 mf: C ~ H I I N mw: 73.16 PROP: Liquid; ammonia-like odor. Mp: -50°, bp: 78", flash p: 10°F (OC), 10°F (CC), d: 0.74-0.76 @ 2Oo/2O0, autoign temp: 594"F, vap d: 2.52, lel: 1.7%, uel: 9.8%. IDLH 300 ppm. SYNS: 1-AMINO-BUTAAN (DUTCH) 0 1AMINOBUTAN (GERMAN) 0 1-AMNOBUTANE 0 1BUTANAMINE 0 n-BUTIIAMINA (ITALIAN) 0 nBUTYLAMIN (GERMAN) 0 BUTYLA&fINE (OSHA) 0 MONOBUTILhhfIh~A MONOBUTYLAMINE 0 MONOn-BUTYLAMINE 0 NORVALAMINE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: CL 5 ppm (skin) ACGIH TLV: CL 5 pprn DFG MAK: 5 ppm (15 mg/m3) DOT CLASSIFICATION: 3; Label: Flammable Liquid; DOT Class: 3; Label: Flammable Liquid, Corrosive SAFETY PROFILE: Poison by ingestion, skin contact, and intravenous routes. Moderately toxic by inhalation, intraperitoneal, and parenteral routes. A corrosive and severe s h n irritant. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. A flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxidzing materials. To fight fire, use alcohol foam,
230 BP YO00 see-BUTYLAMINE Con, dry chemical. Explodes on contact with perchloryl fluoride. When heated to decomposition it emits toxic fumes of NO,. See also AMINES. BPYOOO CAS: 13952-84-6 HR: 3 sec-B UTYLAMINE DOT: UN 2733/UN 2734 mfi C ~ H I I N mw: 73.16 PROP: Liquid. Mp: -104', bp: 63', flash p: 15'F, d: 0.724 @ 20'. SYNS: 2-AB 0 2-AMINOBC'TANE 0 BUTAFUME 0 2BUTANAMINE 0 DECCOTANE 0 FRUCOTE 0 1METHYLPROPYLAMINE 0 TLJTANE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: 5 ppm (15 mg/m3) DOT CLASSIFICATION: 8; Label: Corrosive, Flammable Lquid (UN 2734); DOT Class: 3; Label: Flammable Liquid, Corrosive (UN 2733) SAFETY PROFILE: A poison by ingestion. A powerful irritant. Moderately toxic by skin contact. Dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, water spray or mist, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits toxic fumes of NO,. A fungicide.
BPY250 CAS: 75-64-9 HR: 3 tert-BUTYLAMlNE DOT: UN 2733/UN 2734 mfi C ~ H I I N mw: 73.16 PROP: Colorless liquid. Mp: -67.5', bp: 46.4', fp: -72.65', d: 0.700 @ 15', lel: 1.7% @ 212'F, uel: 8.9% @ 212'F, vap d: 2.5, autoign temp: 716'F. SYNS: 2-AMINOISOBUTANE 0 2-AMINO-2METHYLPROPANE 0 BUTYLAMINE, tertiary 0 1,lDIMETHYLETHYUMINE 0 TRIMETHYLAMINOMETHANE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: 5 ppm (15 mg/m3) DOT CLASSIFICATION: 8; Label: Corrosive, Flammable Liquid (UN 2734); DOT Class: 3; Label: Flammable Liquid, Corrosive (UN 2733)
SAFETY PROFILE: Poison by ingestion. Moderately toxic to humans by inhalation. A
corrosive liquid. See also n-BUTYLAMINE and AMINES. Very dangerous fire hazard when exposed to heat or flame. Very exothermic reaction with 2,2-dibromo-l,3dimethylcyclopropanoic acid. T o fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NO,. BQCOOO CAS: 111-75-1 HR: 2 2-BUTYLAMINOETHANOL mfi CsHlsNO mw: 117.22 PROP: Lquid. Bp: 200°, flash p: 170'F (OC), d: 0.89, vap d: 4.03. Sol in H 2 0 . SYN: 2 - n - B U k T L A M I N O E T H O L CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. A skin and severe eye irritant. See also AMINES. Combustible when exposed to heat or flame. To fight fire, use alcohol foam, foam, Con, dry chemical. Incompatible with oxihzing materials. When heated to decomposition it emits toxic fumes of NO,. BQD250 CAS: 3775-90-4 HR: 3 tert-BUTYL AMINO ETHYL METHAC RY LATE mf: C10H19N02 mw: 185.30 PROP: Liquid. Bp: 100-105', d: 0.914, flash p: 205'F (OC). SYNS: AGEFLEX FM-4 0 2-(tert-BUTYLAMINO)ETHYL IMETHACRYLATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. See also ESTERS and AMINES. Combustible when exposed to heat or flame. To fight fire, use alcohol foam, water spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of NO,.
BQH850 CAS: 1126-78-9 N-BUTYLANILINE DOT: UN 2738 mf: CloHlsN mw: 149.26
HR: 3
n-BUTYLBENZENE PROP: Liquid. D: 0.936 @ 20'/4',
bp: 249'. Sol in acids, EtOH, C6H6, CHCL; insol in H2O. SYNS: BENZENAMINE, N-BUTYL-(9CI) 0 N-(nBUTYL)ANILINE 0 N-n-BUTYLANILINE (DOT) 0 NBUTYLBENZENAMINE (9CI) O 4 - ( P H E N U V I N O ) BUTANE CONSENSUS REPORTS: Reported in EPA
BQl750
231
PROP: White crystalhe powder. Mp:
140-141'. Sol in alc; insol in water, propylene glycol. SYN: 4-HYDROXYMETHYL2.6-DI-tertBUTYLPHENOL
SAFETY PROFILE: When heated to
decomposition it emits acrid smoke and irritating fumes.
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by an
unspecified route. Moderately toxic by skin contact and ingestion. A s h and eye irritant. When heated to decomposition it emits toxic fumes of NO,. See also ANILINE DYES.
BQIOOO CAS: 25013-16-5 HR: 3 BUTYLATED HYDROXYANISOLE mf: CllH1602 mw: 180.27 PROP: White waxy solid; faint characteristic odor. Mp: 104-105'. Sol in alc and propylene glycol; insol in water. SYNS: ANTRANCINE 12 0 BHA (FCC) 0 BUTYLHYDROXYANISOLE 0 tert-BUTYLHYDROXYANISOLE 0 tert-BUTYI-4-HYDROXYANISOLE 0 2(3)-tert-BUTYL-4HYDROXYANISOLE 0 BUTYLOHYDROKSYANIZOL (POLISH) 0 EMBANOX 0 FEMA NO.2183 0 NIPANTIOX I-F 0 PREMERGE PLUS 0 SUSTANE SUSTANE 1-F 0 TENOX BHA 0 VERTAC
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 40,123,86. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic by ingestion and intraperitoneal routes. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits acrid and irritating fumes.
BQ1050 HR: D BUTYLATED HYDROXYMETHYLPHENOL mf: C 1 5 H 2 4 0 2 mw: 236.35
BQ1250 CAS: 1070-19-5 tert-BUTYL AZIDOFORMATE mf: C s H 9 N 3 0 2 mw: 143.17 PROP: Bp: 73-74' @ 70 ~ITI.
HR: 3
SYNS: t-BUTOXYCARBONYL AZIDE 0 tertBUTOXYCARBONYL AZIDE (DOT) 0 ten-BUTYLOXYCARBONYLAZIDE 0 CARBONAZIDIC ACID, 1,tDIMETHYLETHYL ESTER 0 FORMIC ACID, AZIDO-, ten-BUTYL ESTER CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASS IFICAT1ON : Forbidden SAFETY PROFILE: An unstable shock- and heat-sensitive explosive. It may explode above 100°C and i p t e s at 143°C. When heated to decomposition it emits toxic fumes of NO,. See also AZIDES.
BQ1750 CAS: 104-51-8 HR: 1 n-BUTYLBENZENE mf: C10H14 mw: 134.24 PROP: Colorless liquid. Mp: -81.2', bp: 182.1', d: 0.875 @ 13'/4', vap press: 1 mm @ 22.7', autoign temp: 774'F, lel: O.8%, uel: 5.8%, vap d: 4.6. SYN LPHENYLBUTANE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Mildly toxic by
ingestion. Flammable when exposed to heat or flame. To fight fire, use alcohol foam, C02, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid and irritating fumes.
232 BQJOOO see-BUTYLBENZENE BQJOOO CAS: 135-98-8 HR: 3 sec-BUTYLBENZENE mf: C10H14 mw: 134.24 PROP: Colorless liquid. Mp: -82.7', bp: 173.5', fp: -75.8', flash p: 126'F (TOC), d: 0.8621 @ 20°, vap press: 1 mm @ 18.6', vap d: 4.62, autoign temp: 788'F, lel: O.8%, uel: 6.9%. SYN: 2-PHENYLBUTANE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
PHENYLACETATE 0 n-BUTYL PHENYLACETATE 0 PHENYLETHANOICACID BUTYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low toxicity by ingestion. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
BQJSOO CAS: 583-03-9 HR: 3 a-BUTYLBENZENEMETHANOL mf: CllH160 mw: 164.27 SYNS: a-BUTYLBENZYLALCOHOL 0 FENIPENTOL
Flammable Liquid SAFETY PROFILE: Moderately toxic by
ingestion. A skin and eye irritant. Flammable liquid when exposed to heat or flame. To fight fire, use foam, COz, dry chemical, water spray or mist. Incompatible with oxidzing materials. When heated to decomposition it emits acrid smoke and fumes.
BQJ250 CAS: 98-06-6 HR: 3 tert-BUTYLBENZENE mf: CloHt4 mw: 134.24 PROP: Colorless liquid. Bp: 170-171', fp: -58', flash p: 140'F (TOC), d: 0.8665 @ 20°, vap press: 1 mm @ 13.0', vap d: 4.62, autoign temp: 842'F, lel: 0.7% @ 212'F, uel: 5.7% @ 212'F. SYNS: 2-METHYL2-PHENYLPROPANE0 PSEUDOBUTYLBENZENE 0 TRIMETHYLPHENYLMETHANE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
0 1-HYDROXY-1-PHENYLPENTANE 0 PANCORAL 0 PC 1 0 PH BC 0 PHENYLBUTYLCARBINOL 0 1-PHENYL-1-HYDROXYPENTANE 0 PHENYLPENTAN-OL 0 1PHENYLPENTANOL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. An experimental teratogen. Other experimental reproductive effects. Stimulates the production of bile by the liver. When heated to decomposition it emits acrid smoke and irritating fumes.
BQK250 CAS: 136-60-7 HR: 2 BUTYL BENZOATE mf: CllHt402 mw: 178.25 PROP: liquid. Mp: -21.5', bp: 248-249', flash p: 225'F (OC), d: 1.01 @ 15'/15', vap press: <0.01 mm @ 20°, vap d: 6.15. SYNS: ANTHRAPOLE AZ 0 BENZOIC ACID-n-BUTYL ESTER 0 n-BUTYL BENZOATE 0 DAI CAN XBN
DOT CLASSIFICATION: 3; Label:
Flammable Liquid
CONSENSUS REPORTS: Reported in EPA
SAFETY PROFILE: Mildly toxic by
TSCA Inventory.
ingestion. Flammable liquid when exposed to heat or flame. To fight fire, use foam, COz, dry chemical, water spray, fog, mist. Incompatible with oxidizing materials. When heated to decomposition it emits acrid smoke and fumes.
SAFETY PROFILE: Moderately toxic by
BQJ350 CAS: 122-43-0 BUTYLBENZENEACETATE mf: C12H1602 mw: 192.28
HR: 1
SYNS: ACETIC ACID, PHENYL-,BUTYL ESTER 0 BENZENEACETIC ACID, BUTYL ESTER (9CQ 0 BUTYL
skin contact. Mildly toxic by ingestion. Severe skin irritant and moderate eye irritant. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use Con, dry chemical, water mist, fog, spray. When heated to decomposition it emits acrid and irritating fumes. See also ESTERS.
BUTYL BUTYROLACTATE
B Q K ~ O O CAS: 98-73-7 HR: 2 p-tert-BUTYL BENZOIC ACID mf: CttH1402 mw: 178.25 PROP: Colorless, fine, crystalhe powder. Mp: 163-164.4', d: 1.142 @ 2Oo/4O. SYN: TBBA CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
ingestion. Experimental reproductive effects. An irritant. Combustible when exposed to heat or flame. Incompatible with oxidzing materials. To fight fire, use foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
BQMOOO CAS: 102-79-4 HR: 2 N-BUTYL-N,N-BIS(HYDR0XY ETHYL)AMINE mf: CgH19N02 mw: 161.28 PROP: Liquid. Mp: -70°, bp: 273-275', flash p: 245'F (OC), d: 0.97, vap d: 5.55. SYNS: N-BUTYLDIETHANOLAMINE 0 N-BUTYL-2,2'IMINODIETHANOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mddly toxic via ingestion. A skin and severe eye irritant. Combustible when exposed to heat or flame. To fight fire, use alcohol foam, foam, COz, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits toxic fumes of NO,. See also AMINES.
BQM250 CAS: 507-19-7 HR: 2 tert-BUTYL BROMIDE mf: C4H9Br mw: 137.04 PROP: Colorless liquid. Mp: -20°, bp: 72.8", fp: -16.3', d: 1.20 @ 15'/4O. SYNS: 2-BROMOISOBUTANE 0 2-BROhIO-2METHYLPROPANE (DOT) 0 TRIMETHYLBROMOMETHANE CONSENSUS REPORTS: EPA Genetic Toxicology Program.Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid
BQPOOO 233
SAFETY PROFILE: Moderately toxic by intraperitoneal route. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of BrSee also BROMIDES.
BQM500 CAS: 109-21-7 HR: 3 n-BUTYL n-BUTANOATE mf: CgH1602 mw: 144.24 PROP: Colorless liquid; pineapple odor. Bp: 166O, flash p: 128'F (OC), d: 0.67-0.871, refr index: 1.405, vap d: 5.0. Misc with alc, ether, vegetable oils; sltly sol in propylene glycol, water. SYNS: BUTYL BUTYRATE (FCC) 0 n-BUTYL BUTYRATE 0 n-BUTYL n-BU'NRATE 0 FEMA No. 2186 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic via intraperitoneal route. Mildly toxic by ingestion. Moderately irritating to eyes, s h , and mucous membranes by inhalation. Narcotic in h g h concentrations. Flammable liquid. To fight fire, use alcohol foam, foam, C02, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid and irritating fumes.
BQPOOO CAS: 7492-70-8 HR: 1 BUTYL BUTYROLACTATE mf: CllH2004 mw: 216.28 PROP: Colorless liquid; butter, creamlike odor. D: 0.970, refr index: 1.420, flash p: 212'F. Misc with alc, fixed oils; sol in propylene glycol; insol in water. SYNS: BUTANOIC ACID-2-BUTOXY-l-METHYI-2OXOETHYL ESTER (9Cr) BUTYL BUTYRYL LACTATE 0 BUTYRIC ACID ESTER with BUTYL LACTATE 0 FEhW No. 2190 0 LACTIC ACID, BUTYL ESTER, BUTYfL4TE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A skin irritant. See also ESTERS. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
234 BQP250 BUTYL CARBAMATE BQP250 CAS: 592-35-8 HR: 3 BUTYL CARBAMATE mf: CsHllN02 mw: 117.17 SYNS: CARBAMIC ACID, BUTYL ESTER 0 USAF EL101 n WAF FO-I
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison via intraperitoneal route. Moderately toxic via subcutaneous route. Experimental teratogenic effects. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported. See also CARBAMATES. When heated to decomposition it emits toxic fumes of NO,.
BQP500 CAS: 124-17-4 HR: 2 BUTYL CARBITOL ACETATE mf: C10H2004 mw: 204.30 PROP: Colorless liquid. Fp: -32.2', bp: 247', flash p: 240'F (OC), d: 0.981 @ 2O0/2Oo, autoign temp: 570'F, vap press: 0.01 mm @ 20'. SYNS: 2-(2-BUTOXYETHOXY)ETHANOL ACETATE 0 Z-(Z-BUTOXYETHOXY)ETHYL ACETATE DIETHYLENE GLYCOL BUTYL ETHER ACETATE 0 DIGLYCOL MONOBUTYL ETHER ACETATE 0 EKTASOLVE DB ACETATE 0 GLYCOL ETHER DB ACETATE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Glycol ethers are on the Community Right-To-Know List. SAFETY PROFILE: Moderately toxic by ingestion. Mild skin and eye irritant. Combustible when exposed to heat or flame. To fight fire, use foam, C02, dry chemical. Incompatible with oxidizing materials, heat, flame. When heated to decomposition it emits acrid smoke and irritating fumes.
BQP750 CAS: 85-70-1 HR: 2 BUTYL CARBOBUTOXYMETHYL PHTHALATE mf: C18H2406 mw: 336.42 SYNS: BUTYL PHTHALATE BUTYL GLYCOLATE BUTYL PHTHALYL BUTYL GLYCOLATE 0 DIBUTYL-o(0-CARBOXYBENZOYL) GLYCOLATE 0 DIBUTYL-oCARBOXYBENZOYLOXYACETATE 0 SANTICIZIER B16
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic via intraperitoneal route. Experimental teratogenic and reproductive effects. Mutation data reported. An eye irritant. When heated to decomposition it emits acrid and irritating fumes.
BQQ250 CAS: 38252-74-3 HR: 3 N-BUTYL-(3-CARBOXY PROPYL)NITROSAMINE mf: C8H16N203 mw: 188.26 SYNS: BCPN 4(BUTYLNITROSOAMIN0)BUTANOICACID 0 NNITROSO-N-BUTYL-N-(3-CA~O~ROPYL)AMINE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Animal Limited Evidence IMEMDT 17,51,78. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also NITROSAMINES.
BQQ750 CAS: 109-69-3 HR: 3 n-BUTYL CHLORIDE mf: C4HgCl mw: 92.58 PROP: Colorless liquid. Mp: -123.1°, bp: 78.5', lel: 1.9%, uel: 10.1%, flash p: 15'F (OC), d: 0.892 @ 15', autoign temp: 860'F, fp: -123.1', vap d: 3.20. SYNS: BUTYLCHLORIDE (DOT) 0 1CHLOROBUTANE (DOT) 0 CHLORURE de BUTYLE (FRENCH) 0 NCI-C06155 0 N-PROPYLCARBINYL CH L0RIDE
CONSENSUS REPORTS: NTP
Carcinogenesis Studes (gavage); No Evidence: mouse, rat NTPTR* NTP-TR312,86. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Mutation data reported. See CHLORINATED HYDROCARBONS, ALIPHATIC. Skin and eye irritant. Dangerous fire hazard when exposed to heat or flame. Moderately explosive when
n-BUTYLDIETHYLTIN IODIDE
exposed to flame. When heated to decomposition it emits hghly toxic fumes of phosgene and C1-. To fight fire, use foam, COa, dry chemical. Incompatible with oxidizing materials. BQROOO CAS: 507-20-0 HR: 3 tert-BUTYL CHLORIDE mf: C4H9C1 mw: 92.58 PROP: Liquid. Flash p: 32'F, d: 0.87, vap d: 3.2, bp: 51", fp: -27.1'. SYNS: 2-CHLOROISOBUTANE R 2-CHLORO-2METHYLPROPANE 0 TRIMETHYLCHLOROMETHE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Questionable carcinogen with experimental neoplastigenic data. Dangerous fire hazard when exposed to heat, flame (sparks), and oxidlzers. To fight fue, use water, spray, fog, alcohol foam, dry chemical. When heated to decomposition it emits toxic fumes of C1-. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
BQR100 CAS: 107-59-5 HR: 3 tert-BUTYL CHLOROACETATE mf: C6HllClOZ mw: 150.62 SYNS: ACETIC ACID, CHLORO-, ten-BUTYL ESTER 0 ACETIC ACID, CHLORO-, 1,l-DIMETHYLETHYL ESTER 0 CHLOROACETIC ACID tert-BU?n ESTER 0 1,lDIMETHYLETHYL CHLOROACETATE
SAFETY PROFILE: A poison by ingestion. Moderately toxic by inhalation s h n contact. S severe sluin and moderate eye irritant. When heated to decomposition it emits toxic vapors of C1-.
BQVOOO CAS: 1189-85-1 HR: 3 tert-BUTYL CHROMATE mf: C8H18CT04 mw: 230.26 PROP: Red crystals from pet ether. IDLH 15 mg/m3 (as Cr(VI)}. SYN: CHROMIC ACID, DI-tert-BUTYL ESTER CONSENSUS REPORTS: Chromium and its compounds are on the Community Right-To-Know List. OSHA PEL: CL 0.1 mg(CrOs)/m3 (skin) ACGlH TLV: CL 0.1 mg(CrOs)/rn3 (skin)
BRA550 235
NIOSH REL: (Chromium(VI)) CL 0.001 Ma(CrlVI))lm3 SiFETY PROFILE: A very flammable mixture. When heated to decomposition it emits acrid and irritating fumes. See CHROMIUM COMPOUNDS and ESTERS.
BQV750 CAS: 2409-55-4 HR: 3 2-tert-BUTYL-p-CRESOL mf: CllH160 mw: 164.27 PROP: Clear liquid, sol in org solvs and aqueous potassium hydroxide. Fp: 23.1', bp: 118-119' @ 14 mm, d: 0.922, flash p: 116'F. SYNS: 2-tert-BUTYLp-KRESOL (CZECH) 0 2-tertBUTYLCMETHYLPHENOL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion and skin contact. Questionable carcinogen with experimental neoplastigenic data. A severe skin and eye irritant. Mutation data reported. Flammable liquid when exposed to heat, flame, or oxidizers. T o fight fire, use alcohol foam, foam, water spray, fog, dry chemical. When heated to decomposition it emits acrid and irritating fumes.
BQY300 CAS: 684-82-2 HR: 3 sec-BUTYLDICHLOROARSINE mf: C4H9AsCL mw: 202.95 SYNS: ARSINE, sec-BUTYLDICHLORO- 0 ARSONOC'S DICHLORIDE, (1-METHYLPROPYL)-(9CI) 0 sec-BUTYLDICHLORARSINE 0 DICHLORO(1-METHYLPROPYLARSINE
OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by inhalation. When heated to decomposition it emits
toxic fumes of As and C1-. BRA550 CAS: 17563-48-3 HR: 3 n-BUTYLDIETHYLTINIODIDE mf: CsH19ISn mw: 360.86 SYN: STANNANE, BUTYLDIETHYLIODOOSHA PEL: TWA 0.1 mg(Sn)/m3
236 BRFSOO 4-BUTYL-l,P-DIPHENYL-3,5-DIOXO ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg/m3 (skin) NIOSH REL: (Organotin compound): 10H TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of Sn and I-.
BRF5OO CAS: 50-33-9 HR: 3 4-BUTYL-1,2-DIPHENYL-3,5-DIOXO PYRAZOLlDlNE mf: C19H20N20~ mw: 308.41 PROP: Crystals from EtOH. Mp: 105.5-106.5°. SYNS: ALINDOR 0 ALQOVERIN 0 ANERVAL 0 ANTADOL 0 ANUSPIRrtMIN 0 ARTIZIN 0 ARTRIZONE 0 ARTROPAN 0 AZDID 0 AZOLID 0 BENZONE 0 BETAZED 0 BUSONE 0 BUTACOMPREN 0 BUTACOTE 0 BUTALAN 0 BUTALGINA 0 BUTALIDON 0 BUTAPIRAZOL 0 BUTAPYRAZOLE 0 BUTARECBON 0 BUTARTRINA 0 BUTAZINA 0 BUTAZONA 0 BUTAZONE 0 BUTIDIONA 0 BUTONE 0 BUTOZ 0 4-BUTYL-1,Z-DIPHENYLPYRAZOLIDINE3,5-DIONE 0 BUTYLPYRIN 0 BUVETZONE 0 BUZON 0 DIGIBUTINA 0 DIOSSIDONE 0 3,5-DIOXO-1,2DIPHENYL-4-N-BUTYLPYRAZOLIDENE 0 DIOZOL 0 DIPHEBUZOL 0 DIPHENYLBUTAZONE 0 1,2-
DIPHENYL-4-BUTYL-3,5-DIOXOPYRAZOLIDINE 0 ELMEDAL 0 EQUI BUTE 0 ERIBUTAZONE 0 ESTEVE 0 FENARTIL 0 FENIBUTAZONA 0 FENIBUTOL 0 FENILBUTINE 0 FENILIDINA 0 FENOTONE 0 FENYLBUTAZON 0 FLEXAZONE 0 INTALBUT 0 IPSOFLAME 0 LINGEL 0 MALGESIC 0 MEPHABUTAZONE 0 MERIZONE 0 NADOZONE 0 NCI-C56531 0 NOVOPHENYL 0 PHEBUZIN 0 PHENBUTAZOL 0 PHENOPYRINE 0 PHENYLBUTAZO N (GERMAN) 0 PHENYLBUTAZONE 0 PIRARREUMOL “B” 0 PRAECIRHEUMIN 0 PYRAZOLIDIN 0 REUDO 0 REUMASYL 0 REUMAZOL 0 REUPOLAR 0 RUBATONE 0 SCANBUTAZONE 0 SHIGRODIN 0 TAZONE 0 TEVCODYNE 0 THERAZONE 0 TODALGIL 0 UZONE 0 WESCOZONE 0 ZOLAPHEN 0 ZOLIDINUM 0 ZORANE
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,316,87; Human Inadequate Evidence IMEMDT 13,183,77. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected human carcinogen producing leukemia. A human poison by parenteral route. An experimental
poison by ingestion, intraperitoneal, subcutaneous, intravenous, and intramuscular routes. Human systemic effects by ingestion and possibly other routes: fever, blood pressure increase, other unspecified vascular effects, damage to kidney tubules and glomeruli, decreased urine volume, blood in the urine, reduction in the number of whte blood cells, and agranulocytosis. Experimental teratogenic and reproductive effects. Human mutation data reported. An eye irritant. An antiinflammatory agent. When heated to decomposition it emits toxic fumes of NO,. BRF550 CAS: 20333-40-8 HR: 3 BUTYL DISELENIDE mf: CsHisSez mW: 272.18 SYNS: DIBUTYL DISELENIDE 0 DI-n-BUTYLDISELENIDE 0 DIBUTYLDISELENIUM 0 DISELENIDE, DIBUTYL(9Cr)
OSHA PEL: TWA 0.2 mg(Se)/m3 ACGIH TLV: TWA 0.2 mg(Se)/m3 SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of Se. BRH750 CAS: 142-96-1 HR: 3 n-BUTYL ETHER DOT: UN 1149 mf: C8H18O mw: 130.26 PROP: Colorless liquid. Mp: -98”, bp: 142O, flash p: 77OF, d 0.784 @ Oo/4O, autoign temp: 382’F, vap d: 4.48, lel: 1S%, uel: 7.6%. SYNS: 1-BUTOXYBUTANE 0 BUTYL ETHER (DOT) 0 DI-n-BUTYL ETHER (DOT) 0 DIBUTYL OXIDE 0 ETHER BUTYLIQUE (FRENCH) 0 1,l’-OXYBIS(BUTANE)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Mildly toxic by inhalation, ingestion, and skin contact. Human systemic effects by inhalation: conjunctiva irritation and unspecified nasal effects. An experimental skin and human eye irritant. See also ETHERS. Dangerous fire hazard when exposed to heat, flame, or
n-BUTYL FORMATE BRKOOO 237
oxidizers. Incompatible with NCL and oxidizing materials. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
BRH760 CAS: 6863-58-7 sec-BUTYL ETHER mf: CsHlaO mw: 130.26
HR: 3
SYNS: BIS(2-BUTYL)ETHER0 BUTANE, 2,2'-OXYBIS( 9 0 0 DI-sec-BUTYL ETHER 0 2,2'-OXYBISBUTANE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Poison by inhalation. A
flammable liquid. When heated to decomposition it emits acrid smoke and irritating vapors.
BRIO00 CAS: 123-05-7 HR: 3 BUTYLETHYLACETALDEHYDE mf: CBHIBO mw: 128.24 PROP: Bp: 163.4', flash p: 125'F (OC), autoign temp: 387'F, d: 0.8205, vap press: 1.8 mm @ 20°, vap d: 4.42. SYNS: ETHYLBUTYLACETALDEHME 0 ÐYLCAPROALDEHME 0 2-ETHYLHEXALDEHYDE 0 ETHYLHEXALDEHYDE(DOT) 2-ETHYLHEXANAL 0 P-PROPYL-a-ETHYLACROLEIN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Mildly toxic by inhalation and s h n contact. An eye and severe skin irritant. See also ALDEHYDES. Dangerous fire hazard; spontaneously flammable in air. To fight fire, use foam, C02, dry chemical, water spray, mist, fog. Incompatible with oxidizing materials. When heated to decomposition it emits acrid and irritating fumes.
BR1250 CAS: 149-57-5 HR: 2 BUTYL ETHYL ACETIC ACID mf: C8H1602 mw: 144.24 PROP: Flash p: 260'F (OC), bp: 225-228'. SYNS: a-ETHYLCAPROICACID 0 2-ETHYLHEXANOIC ACID 0 2-ETHYLHEXOICACID
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 5 mg/m3 SAFETY PROFILE: Moderately toxic by ingestion and s h n contact. An experimental teratogen. A skin and severe eye irritant. Combustible when exposed to heat or flame. When heated to decomposition, it emits acrid and irritating fumes.
BRJ750 CAS: 2425-74-3 HR: 3 tert-BUTYL FORMAMIDE mf: CsHllNO mw: 101.17 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: A poison by intravenous route. When heated to decomposition it emits toxic fumes of NO,. BRKOOO CAS: 592-84-7 HR: 3 n-BUTYL FORMATE DOT: UN 1128 mf: c5H1002 mw: 102.15 PROP: Colorless liquid. Mp: -goo, bp: 106.0', flash p: 64'F (CC), d: 0.91 1, autoign temp: 612'F, vap press: 40 mm @ 31.6', vap d: 3.52, lel: 1.7%, uel: 8%. SYNS: BUTYLESTER KYSELINY MRAVENCI 0 B U m FORMATE (DOT) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Moderately toxic by
ingestion. Mildly toxic by inhalation. Human systemic effects by inhalation: muscle contractions and spasticity, conjunctiva irritation, and unspecified respiratory changes. An irritant and narcotic in high concentrations. See also ESTERS, nBUTYL ALCOHOL, and FORMIC ACID. Dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, foam, C02, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid and irritating fumes.
238
BRK750
n-BUTYL GLYCIDYL ETHER
BRK750 CAS: 2426-08-6 HR: 3 n-BUTYL GLYCIDYL ETHER mf: C7H1402 mw: 130.21 PROP: Bp: 327'. IDLH 250 ppm. SYNS: AGEFLEX BGE 0 BGE 0 BGE (OSHA) 0
SAFETY PROFILE: Low toxicity by ingestion and skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
BUTYL GLYCIDYL ETHER 0 2,3-EPOXYPROPYLBUTYL ETHER 0 ETHER, BUTYL 2,3-EPOXYPROPYL 0 ETHER, BUTYL GLYCIDYL 0 GLYCIDYL BUTYL ETHER 0 TK 10408
BRM250 CAS: 75-91-2 HR: 2 tert-BUTYLHYDROPEROXIDE mf: c4H1002 mw: 90.14 PROP: Water-whte liquid. Flash p: 80°F or above, fp: -35O, d 0.860, mp: -8O, bp: 40' @ 23 mm, vap d: 2.07. Sltly sol in water; very sol in esters and alc. SYNS: terc.BUTYLHYDROPEROXID (CZECH) 0
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 25 ppm ACGIH TLV: TWA 25 ppm DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Glycidyl Ethers) CL 30 mg/m3/15M SAFETY PROFILE: Suspected Carcinogen. Moderately toxic by ingestion, skin contact, and inuaperitoneal routes. Mildly toxic by inhalation. An experimental teratogen. Mutation data reported. A sktn and severe eye irritant. See also ETHERS. When heated to decomposition it emits acrid and irritating fumes.
BRK800 CAS: 7665-72-7 HR: 3 t-BUTYL GLYCIDYL ETHER mf: C7H1402 mw: 130.21 SYNS: t-BGE 0 1,l-DIMETHYLETHYLGLYCIDYL ETHER 0 OXIRANE, ((1,l-DIMETHYLETHOXY) METHYL). 0 PROPANE, 1-tert-BUTOXY-2,3-EPOXY-
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Suspected carcinogen. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
BRK9OO CAS: 626-82-4 HR: 1 BUTYL HEXANOATE mf: C10H2002 mw: 172.30 SYNS: BUTYL CAPROATE 0 n-BUTYL HEXANOATE 0 HEXANOIC ACID, BUTYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
CADOX TBH 0 1,l-DLMETHYLETHYLHYDROPEROXIDE 0 HYDROPEROXYDEde BUTYLE TERTIAIRE (FRENCH) 0 2-HYDROPEROXY-2METHYLPROPANE 0 PERBUTYL H 0 TBHP-70 0 TRIGONOX A-75 (CZECH)
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DFG MAK: Moderate skin effects DOT CLASSIFICATION: Forbidden SAFETY PROFILE: Moderately toxic by ingestion and inhalation. A severe skin and eye irritant. Mutation data reported. At highest dosage levels, symptoms noted were severe depression, incoordmation, and cyanosis. Death was due to respiratory arrest. Very dangerous fxe hazard when exposed to heat or flame, or by spontaneous chemical reaction such as with reducing materials. Moderately explosive; may explode during distillation. Violent reaction with traces of acid. Concentrated solutions may ignite spontaneously on contact with molecular sieve. Mixtures with transition metal salts may react vigorously and release oxygen. Forms an unstable solution with 1,2-dichloroethane. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC.
BRMSOO CAS: 1948-33-0 tert-BUTYLHYDROQUINONE mf: ClOH1402 mw: 166.24
HR: 3
n-BUTYL LACTATE
BRRGOO 239
PROP: White crystahne solid; characteristic
DOT CLASSIFICATION: 3; Label:
odor. Mp: 126.5-128.5'. Sol in alc, ether; insol in water.
Flammable Liquid, Poison; DOT Class: 6.1; Label: Poison; DOT Class: 6.1; Label: Poison, Flammable Liquid; DOT Class: 3; Label: Flammable Liquid, Poison SAFETY PROFILE: A poison by ingestion and intravenous routes. Mddly toxic by inhalation. A powerful irritant to eyes, skin, and mucous membranes. A flammable liquid. See also CYANATES and NITROGEN MONOXIDE.
SYNS: MONO-tert-BUTYLHYDROQUINONE 0 MTBHQ 0 SUSTANE TBHQ (FCC) 0 TENOX TBHQ CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
intraperitoneal route. Moderately toxic by ingestion and inhalation. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
BRQ100 CAS: 551-08-6 HR: 2 3-BUTYLIDENE PHTHALIDE mf: C1zH1202 mw: 188.24 PROP: Needles from CHCl3. Mp: 82-83'. SYNS: BUTYLIDENE PHTHALIDE 0 n-BUTYLIDENE PHTHhLIDE 0 1(3H)-ISOBENZOFuRANONE, 3BUTYLIDENE-(9CI) 0 PHTHALIDE, 3-BUTYLIDENE-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
BRQ350 HR: 3 BUTYL ISOBUTYRATE mf: C8H1602 mw: 44.44 PROP: Colorless liquid; apple-pineapple odor. D: 0.859-0.864, refr index: 1.401, flash p: 113'F. M w with alc, ether, fixed oils; insol in glycerin, propylene glycol, water @ 166'. SYN: FEW4 No. 2188 SAFETY PROFILE: Flammable liquid.
When heated to decomposition it emits acrid smoke and irritating fumes.
BRQSOO CAS: 111-36-4 HR: 3 n-BUTYL ISOCYANATE DOT: UN 2485 mf: CsHsNO mw: 99.15 PROP: Colorless liquid. Bp: 115', d: 0.880 @ 20°/4'. SYNS: BIC 0 ISOCYANIC ACID, BUTYL ESTER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
BRQ800 CAS: 73791-40-9 HR: 3 BUTYL(lSOPR0PYL)ARSlNIC ACID mf: C ~ H ~ ~ A S O Zmw: 208.16 SYNS: ARSINE OXIDE, BUTYLHWROXYISOPROPYG 0
BUTYLHYDROXYISOPROPYRSINE OXIDE
OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of As.
BRR6OO CAS: 138-22-7 HR: 3 n-BUTYL LACTATE mf: C7H1403 mw: 146.21 PROP: Liquid. Sltly sol in water; misc in alc and ether. Mp: -43', bp: 188', flash p: l6O'F (OC), d: 0.968, autoign temp: 720'F, vap d: 5.04, vap press: 0.4 mm @ 20'. SYNS: BUTYL a-HYDROXYPROPIONATE 0 BUTYL LACTATE 0 2-HYDROXYPROPANOIC ACID, BUTYL ESTER 0 LACTIC ACID, BUTYL ESTER CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 ppm ACGIH TLV: TWA 5 ppm SAFETY PROFILE: Poison by intraperitoneal route. A skin irritant. Toxic concentration in air for humans is about 4 ppm. Flammable when exposed to heat or flame; can react with oxidizing materials. To fight fire, use alcohol foam, foam, COz, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS, n-BUTYL ALCOHOL, and LACTIC ACID.
240
BRR800
N-BUTYLMELAMINE
BRR800 CAS: 5606-24-6 N-BUTYLMELAMINE mf: C7H14N6 mw: 182.27
HR: 3
DIMETHYL-4-OXO-2H-PYRrtU-6-CARBOXYLIC ACID 0 n-BUTYLMESITYLOXIDOXALATE 0 2-CARBO-n-
BUTOXY-6,6-DIMETHYL-5,6-DIHYDRO-1,4-PYRONE 0 3,4-DIHYDRO-2,2-DIMETHYL-4-OXO-2H-PYRhN-6-
SYNS: ~,~-DI~~~MINO-~-BUTYLAMINO-S-TRIAZINE 0 CARBOXYLIC ACID-n-BUTn ESTER 0 DIHDYROPYR-
MELAVINE, BUTYL- 0 s-TRIAZINE,2,6-DIAlr;IINO-4BUTYLAMINO- 0 1,3,5-TRIAZINE-2,4,6-TRLKMINE, NB u m
SAFETY PROFILE: A poison by intravenous route. When heated to decomposition it emits toxic vapors of NO,.
BRR9OO CAS: 109-79-5 HR: 3 n-BUTYL MERCAPTAN DOT: UN 2347 mf: C~HIOS mw: 90.20 PROP: Colorless liquid; skunk-like odor. Mp: -116O, bp: 98O, d: 0.8365 @ 25'/4O, flash p: 35OF, vap d: 3.1. IDLH 500 ppm. SYNS: BUTANETHIOL (OSHA) 0 BUTYL MERCAPTAN 0 n-BUTYL MERCAPTAN (ACGIH,DOV 0 NCI-C60866 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.5 ppm ACGIH TLV: TWA 0.5 pprn DFG MAK: 0.5 pprn (1.9 mg/m3) NlOSH REL: (n-Alkane Mono Thiols) CL 0.5 ppm/l5M DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. An eye irritant. Dangerous fire hazard by exposure to heat, flame, sparks, or powerful oxidizers. Reacts violently with HN03. Incompatible with acids, acid fumes, oxidizing materials, heat, flame, and sparks. To fight fire, use alcohol foam. When heated to decomposition it emits toxic SO,. See also MERCAPTANS.
ONE 0 CZ,CZ-DIMETHYG~'-CARBOBUTOXY-DIHYDROy-PYRONE 0 2,2-DIMETHYL-6-CARBOBUTOXY-2,3DIHYDRO-CPYRONE 0 ENT 9 INDALONE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Produces liver necrosis in experimental animals. A rmld skin irritant. See also OXALATES and ESTERS. Combustible when exposed to heat or flame. When heated to decomposition it emits acrid fumes.
BRUSOO CAS: 83-66-9 HR: 3 6-tert-BUTYLS-METHYL-2,4-DINITRO ANISOLE mf: CIZHI~NZOS mw: 268.30 SYNS: 2,6-DINITRO-3-METHOXY-4-tertBUTYLTOLUENE 0 MUSK AMBRE?TE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by ingestion. Mutation data reported. A skm irritant. When heated to decomposition it emits toxic fumes of NO,. See also AROMATIC AMINES.
BRU780 CAS: 628-28-4 HR: 3 BUTYL METHYL ETHER (DOT) DOT: UN 2350 mw: 88.17 mf: CsH120 SYNS: BUTANE, l-blETHOXY-(9CI) 0 ETHER, BUTYL METHYL 0 a-METHOXYBUTANE 0 1METHOXYBUTANE 0 METHYL BUTYL ETHER 0 METHYL n-BUiTL ETHER DOT CLASSIFICATION: 3; Label:
Flammable Liquid BRTOOO CAS: 532-34-3 HR: 2 n-BUTYL MESITYL OXIDE OXALATE mf: C12H1804 mw: 226.30 PROP: Yellow to pale-red liquid. Bp: 256-270°, d: 1.052-1.060 @ 2Oo/4O, flash p: 315OF. SYNS: B M 0 0 0 BUTOPYRONOXYL 0 BUTYL,-3,4DIHYDR0-2,2-DIMETHYL-4-OXO-ZH-PYRAN-6CARBOXYTATE 0 n-BUTYL ESTER of 3,4-DIHYDRO-2,2-
SAFETY PROFILE: Poison by inhalation. A
flammable liquid. When heated to decomposition it emits acrid smoke and irritating vapors. BRVSOO CAS: 544-16-1 n-BUTYL NITRITE mf: C4HsN02 mw: 103.14
HR: 3
2-BUTYL-1-OCTANOL BSASOO 241 PROP: Oily liquid, characteristic odor, m i x
in alc and ether. Bp: 78', d: 0.9114 @ 0°/4', vap d: 3.5, flash p: 10'. SYNS: BUTYL NITRITE (DOT) 0 NBN
0 NCI-C56553
0 NITROUS ACID-n-BUTYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by ingestion
and intraperitoneal routes. Mildly toxic by inhalation. An irritant. Human systemic effects by ingestion: methemoglobinemiacarboxyhemoglobinemia. Resembles amyl nitrite in causing fall in blood pressure, headache, pulse throbbing, and weakness. Mutation data reported. Flammable when exposed to heat or flame or by spontaneous chemical reaction. When heated to decomposition it emits toxic fumes of NO,. See also NITRITES, n-BUTYL ALCOHOL, and ESTERS. BRV750 CAS: 924-43-6 HR: 3 sec-BUTYL NITRITE mf: C4H9N02 mw: 103.14 PROP: Lquid. Bp: 68', d: 0.8981 @ 0°/4', vap d: 3.5. SYNS: NITROUS ACID-sec-BUTYL ESTER 0 NITROUS ACID-1 -METHYL PROPYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
ingestion, inhalation, and intraperitoneal routes. Mutation data reported. Flammable when exposed to heat or flame or by spontaneous chemical reaction. An oxiQzer. Potentially explosive. To fight fire, use water, spray, foam, dry chemical. When heated to decomposition it emits toxic fumes of NO,. See also n-BUTYL NITRITE, NITRITES, and ESTERS. BRYSOO CAS: 924-16-3 HR: 3 n-BUTYL-N-NITROSO-1-BUTAMINE mf: CSHI~NZO mw: 158.28 PROP: Pale-yellow liquid. Bp: 235'. SYNS: DBN 0 DBNA 0 DI-n-BUTYLNITROSAMMIN (GERMAN) 0 DIBUTYLNITROSOAMINE 0 DI-nBUTYLNITROSAhlINE 0 N,N-DI-n-BUTYLNITROSAMINE 0 &-,I;-DIBUTYLNITROSOAINE 0 NDBA 0
N - N I T R O S O D I B U T I N E 0 N-NITROSODI-nBUTYLAiiINE (MAK) 0 RCRA WASTE NUMBER El72
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Supn'cient Evidence IMEMDT 28,151,82; IMEMDT 17,51,78; IMEMDT 4,197,74; Human Limited Evidence IMEMDT 17,51,78. Community Right-ToKnow List. EPA Genetic Toxicology Program.Reported in EPA TSCA Inventory. DFG MAK: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, tumorigenic, and neoplastigenic data. Moderately toxic by ingestion, subcutaneous, and intraperitoneal routes. Experimental teratogenic effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also NITROSAMINES.
BSA250 CAS: 869-01-2 HR: 3 n-BUTYLNITROSOUREA mf: C5HllN302 mw: 145.19 PROP: Solid. Mp: 82.5-84'. SYNS: BNU 0 BUTYLXITROSOHARNSTOFF (GERMAN) 0 N-n-BUTYL-N-NITROSOUREA 0 1BUTYL-1-NITROSOUREA 0 N-NITROSOBUTYLUREA
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. A poison by ingestion. Moderately toxic by subcutaneous route. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also NITROSAMINES.
BSASOO CAS: 3913-02-8 HR: 1 2-BUTYL-1-0CTANOL mf: C12H260 mw: 186.38 PROP: Liquid. Mp: -80', flash p: 230'F (OC), bp: 253.3', d: 0.8355 @ 20°/200, vap d: 6.42. SYN: 2-BUTYLOCTYL ALCOHOL
242
BSC250
tert-BUTYL PERACETATE
CONSENSUS REPORTS: Reported in EPA
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
TSCA Inventory.
SAFETY PROFILE: Mildly toxic by ingestion, A s h n and eye irritant. See also ALCOHOLS. Combustible when exposed to heat or flame. Incompatible with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid and irritating fumes.
SAFETY PROFILE: Moderately toxic by ingestion. A skin and eye irritant. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. See also PEROXIDES, ORGANIC. Potentially explosive when heated above 115'C. Explosive reaction on contact with organic matter or copperQ) bromide + limonene. When heated to decomposition it emits acrid smoke and fumes.
BSC250 CAS: 107-71-1 HR: 3 tert-BUTYL PERACETATE mf: C~H1203 mw: 132.18 PROP: Clear, colorless, benzene solution; insol in water; sol in org solvs. D: 0.923, vap press: 50 mm @ 2G0, flash p: <80'F (COC). SYNS: t-BUTYL PERACETATE 0 t-BUTYL PEROXYACETATE 0 ten-BUTYL PEROXYACETATE, >76% in solution (DO7 ETUNEPEROXOIC ACID, 1,lDIMETHYLETHYL ESTER 0 LUPERSOL 70 0 TRIGONOX F-C50
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: Moderate s h n irritant DOT CLASS1FlCATlON : Forbidden SAFETY PROFILE: Moderately toxic by ingestion. Mildly toxic by inhalation. Moderate s h n and eye irritant. A shock- and heat-sensitive explosive. Dangerous fire hazard when exposed to heat, flame, reducing agents. To fight fire, use dry chemical, alcohol foam, spray and mist. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC; and ESTERS.
BSCSOO CAS: 614-45-9 HR: 3 tert-BUTYL PERBENZOATE mf: CllH1403 mw: 194.25 PROP: Colorless to slightly yellow liquid; mild aromatic odor. Bp: 112' (decomp), flash p: 19', fp: 8', vap press: 0.33 mm @ 50°, d: 1.O. Insol in water; sol in org solvs. SYNS: terc.BUTYLESTER KYSELINY PEROXYBENZOOVE (CZECH) 0 terc.BUTYLPER-BENZOAN (CZECH) 0 t-BUTYL PERBENZOATE 0 t-BUTYL PEROXY BENZOATE ESPEROX 10 0 NOVOX PERBENZOATE de BUTYLE TERTIAIRE (FRENCH) 0 TRIGONOX C
BSDOOO CAS: 19910-65-7 HR: 2 sec-BUTYL PEROXYDICARBONATE mf: Ci0Hi80~ mw: 234.28 SYNS: DI-sec-BUTYL PEROXYDICARBONATE 0 DIsec-BUTYL PEROXYDICARBONATE, not more than 52% in solution (DO'I) 0 DI-sec-BUTYL PEROXYDICARBONATE, technically pure (DO'I)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
s h n contact. See also PEROXIDES, ORGANIC. When heated to decomposition it emits acrid smoke and irritating fumes. BSD250 CAS: 927-07-1 HR: 3 tert-BUTYL PEROXYPIVALATE mf: C9H1803 mw: 174.27 PROP: Colorless liquid. D: 0.854 @ 25'/25', fp: <19', flash p: >155'F (OC), rapid decomp @ 21'. Insol in water and ethylene glycol; sol in most org solvs. SYNS: t-BUTYL PEROXYPIVALATE 0 tert-BUTYL PERPIVALATE 0 tert-BUTYL TRIMETHYLPEROXYACETATE 0 ESPEROX 31M 0 LUPERSOL 11 0 TRIGONOX 25/75 0 TRIGONOX 25-C75
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion. Moderately flammable by heat, flame (sparks), oxidizers. Can explode on heating. T o fight fire, use water, fog, mist, alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC.
p-tert-BUTYLPHENYL SALICYLATE
BSEOOO CAS: 89-72-5 HR: 3 o-sec-BUTYLPHENOL mf: C10H140 mw: 150.24 PROP: Colorless liquid. Bp: 226-228' @, 25 mm, fp: 12', flash p: 225'F, d: 0.981 @,
BSHlOO 243
SAFETY PROFILE: A poison. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. See also PHENOL and other butyl phenols. v
v
25'/25". SYN: 2-set-BUTYLFENOL (CZECH) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 5 pprn (skin) ACGIH TLV: TWA 5 pprn (skin) SAFETY PROFILE: A poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion and skin contact. A severe skin and eye irritant. Combustible when exposed to heat or flame. To fight fire, use foam, spray, C02, dry chemical. When heated to decomposition it emits acrid and irritating fumes. See also PHENOL and other butyl phenols.
BSE250 CAS: 99-71-8 HR: 3 p-sec-BUTYLPHENOL mf: ( C H ~ C H C ~ H ~ ) C G H ~ Omw: H 150.2 PROP: Nearly white flakes. Bp: 135.4-136.5' @, 25 mm, fp: 51', flash p: 240'F, d: 0.963@, 6Oo/6O0, mp: 60'. SYN: 4-sec BUTYL PHENOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
BSEJOO CAS: 98-54-4 HR: 3 4-t-BUTYLPHENOL mf: C10H140 mw: 150.24 PROP: Crystals, needles, or practically white flakes. Mp: 99', bp: 236-238', d: 0.9081 @, 114'/4', vap press: 1 mm @ 70.0', vap d:
5.1. SYNS: p-tert-BUTYLFENOL(CZECH) 0 BUTYLPHEN 0 p-tert-BUTYLPHENOL(MAK) 0 4-(1,l -DIMETHYLETHYL)PHENOL 0 1-HYDROXY-4-ten-BUTYLBENZENE 0 UCAR BUTYLPHENOL 4-T
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: 0.08 pprn (0.5 mg/m3) SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by skin contact and ingestion. A skin and severe eye irritant. Questionable carcinogen with experimental neoplastigenic data. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid and irritating fumes. See also PHENOL and other butyl phenols.
SAFETY PROFILE: Poison by intravenous
and intraperitoneal routes. Moderately toxic by ingestion. Combustible when exposed to heat or flame. When heated to decomposition it emits toxic fumes. To fight fire, use foam, COz, dry chemical. Incompatible with oxidizing materials. See also PHENOL and other butyl phenols.
BSF750 CAS: 1126-79-0 HR: 2 BUTYL PHENYL ETHER mf: C10H140 mw: 150.24 PROP: Liquid. Flash p: 180'F (OC), d: 0.9, vap d: 5.2,mp: -19', bp: 210'.
BSE450 CAS: 1638-22-8 HR: 2 4-n-BUTYLPHENOL mf: C1oH140 mw: 150.24 PROP: Solid or liquid. D: 0.976 @, 22'/4O, mp: 22', bp: 248". CONSENSUS REPORTS: Reported in EPA TSCA Inventory.
SAFETY PROFILE: Moderately toxic by ingestion. See also ETHERS. When heated to decomposition it emits acrid and irritating fumes.
SYN: BUTOXYPHENYL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
BSH100 CAS: 87-18-3 HR: 2 p-tert-BUTYLPHENYL SALICYLATE mf: C17H1803 mw: 270.13
244
BSH250
BUTYL PHOSPHOROTRITHIOATE
SYNS: BENZOIC ACID, 2-HYDROXY-,4-(1,1D1METHYLETHYL)PHENYL ESTER 0 p-terc.BC'TnFENYLESTER KYSELINY SALICYLOVE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes.
BSH250 CAS: 78-48-8 HR: 3 BUTYL PHOSPHOROTRITHIOATE rnfi C12H270PS3 mw: 314.54 PROP: Liquid. Bp: 167-170' @! 1 mm, d: 1.06 @! 20 mm. Insol in water; sol in aliphatic, aromatic, and chlorinated hydrocarbons. SYNS: B-1,776 0 BUTIFOS 0 BUTIPHOS 0 CHEMAGRO 1,776 CHEMAGRO B-1776 0 DEF 0 DEF DEFOLWNT 0 DE-GREEN 0 E-2-OFF D 0 FOS-FALL "A" 0 ORTHO PHOSPHATE DEFOLIANT 0 S,S,STRIBUTYL PHOSPHOROTRITHIOATE 0 S,S,STRIBUTYL TRITHIOPHOSPHATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by ingestion,
skin contact, and intraperitoneal routes. Experimental reproductive effects. Animal experiments show an anti-cholinesterase effect. When heated to decomposition it emits toxic fumes of PO, and SO,. See also PARATHION, PHOSPHATES, ESTERS, and SULFATES.
BSIOOO CAS: 536-69-6 HR: 3 5-BUTYL PlCOLlNlC ACID rnfi C10H13N02 mw: 179.24 PROP: Plates from pet ether. Mp: 108-109'. SYNS: 5-BUTYL-2-PYRIDINECARBOXYLICACID 0 FUSARIC ACID 0 FUSARINIC ACID
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: A poison by ingestion, intraperitoneal, subcutaneous, and intravenous routes. When heated to decomposition it emits toxic fumes of NO,.
BSJSOO CAS: 590-01-2 BUTYL PROPANOATE DOT: UN 1914
HR: 3
rnfi C7H1402 mw: 130.2 PROP: Water-white liquid; apple-like odor. Mp: -89.6', bp: 145.4', flash p: 90'F, d: 0.893 @! Oo/Oo, autoign temp: 800'F, vap d: 4.49. SYNS: BUTYL PROPIONATE 0 n-BUTYL PROPIONATE PROPANOIC ACID BUTYLESTER (9CI) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Mildly toxic by ingestion. A skin irritant. Dangerously flammable when exposed to heat or flame. To fight fire, use foam, C02, dry chemical. Incompatible with oxidizing materials. See also ESTERS, n-BUTYL ALCOHOL, and PROPIONIC ACID.
BSKOOO CAS: 98-29-3 HR: 3 4-tert-BUTYLPYROCATECHOL mf: C10H1402 mw: 166.24 PROP: Crystals. Fp: 52', bp: 285', flash p: 265'F, d: 1.049 @ GOo/25'. SYNS: 4-tert-BUTYLCATECHOL p-tertBUTYLPYROCATECHOL 0 4-tertBUTYLPYROKATECHIN (CZECH) 0 4-(1,lDIMETHYLETHYL)-l,2-BENZENEDIOL 0 SYNOX TBC CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by intravenous route. Moderately toxic by ingestion and skin absorption. A severe skin and eye irritant. Mutation data reported. Combustible when exposed to heat or flame. To fight fire, use Con, dry chemical, fog, mist. When heated to decomposition it emits acrid and irritating fumes.
BSL500 CAS: 2273-43-0 HR: 3 BUTYL STANNOIC ACID rnfi C4HloOzSn mw: 208.83 PROP: White infusible solid. Sol in MezCO. SYN: BUTYLHYDROXYOXOSTANNANE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
BUTYL TITANATE BSP250 245 NIOSH REL: (Organotin Compounds) TWA
0.1 mg(Sn)/m3 SAFETY PROFILE: A poison by intravenous route. See also TIN COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
BSMOOO CAS: 339-43-5 HR: 3 1 BUTYL-3-SULFANILYL UREA mfi CllH17N303S mw: 271.37 PROP: Solid. Mp: 144-145'. SYNS: ALENTIN 0 N-(4-
-
Ahl1NOBENZENESULFONYL)-N'-BLTYLUREA 0 4AMINO-N-((B~~lINO)CARBONYL)BENESULFONAMIDE G AMINOPHENUROBUTANE 0 BUCARBAN 0 BUCROL BUKARBAN 0 BURCOL 0 BUTISULFINA 0 N'-(sUTYLCARBAMOuL)SULFANIG AMIDE N~-(BUTYLCARBAMO~)SULFANILAMIDE N-BUTYLSULFANILYLUREA 0 CARBUTAMID 0 CARBUTAMIDE 0 CICLORAL 0 DIABORAL 0 EMEDAN G GLUCIDORAL 0 GLUCOFREN 0 GLYBUTAMIDE 0 INBUTON 0 INVENOL 0 N m I S A N 0 NADIZAN 0 NORBORAL 0 ORANIL 0 ORANYL 0 ORASULIN 0 N1SULFANILYL-N~-BUT~CARBAMIDE N ~ U L F A N I L YL-N2-BUTYLUREA 0 N-SULFANILYL-N'BUTYLUREE (FRENCH) 0 U 6987
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits very toxic fumes of NO, and SO,.
BSNSOO CAS: 628-83-1 HR: 3 n-BUTYL THlOCYANATE mf: CsH9NS mw: 115.21 SYNS: n-BUTYL RHODANATE 0 BUTYRHODANID (GERMAN) 0 1-THIOCYANOBUTANE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by ingestion
and subcutaneous routes. When heated to decomposition it emits very toxic fumes of NO, and SO,. See also THIOCYANATES.
BS0200 CAS: 70303-47-8 HR: 3 (BUTYLTHI0)TRIOCTYLSTANNANE mf: C28H60SSll mw: 547.63 SYNS: STANNANE, (BUTYLTHI0)TRIOCTYL- G TRIOCTYL(BUTYLTHI0)STANNANE
OSHA PEL: TWA 0.1 mg(Sn)/m3 ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg/m3 (slun) NIOSH REL: (Organotin compound): 10H TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of SO, and Sn.
BS0500 CAS: 1516-32-1 HR: 3 n-BUTYL THIOUREA mf: C ~ H I ~ N ~ Smw: 132.25 SYN: USAF D-5 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: A poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of NO, and SO,. BSP250 CAS: 5593-70-4 HR: 3 BUTYL TITANATE mf: C,&,604*Ti mw: 340.42 PROP: Colorless to light-yellow liquid or oil with the odor of butanol. Mp: -55', bp: 155' @ 1 mm, d: 0.993 @ 25'/4", flash p: 170'F, vap d: 11.5. SYN: TETRABUTYLTITANATE (CZECH) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Suspected carcinogen. A poison by intravenous route. Moderately toxic by ingestion. See n-BUTYL ALCOHOL and TITANIUM COMPOUNDS. Flammable when exposed to heat or flame. To fight fire, use water, spray, foam, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid and irritating fumes.
246
BSPSOO p-tert-BUTYLTOLUENE
BSPSOO CAS: 98-51-1 HR: 2 p-tert-BUTYLTOLUENE mf: CllH16 mw: 148.27 PROP: Colorless liquid. D: 0.861 @ 20'/4', mp: -54', bp: 189-192'. IDLH 100 ppm. SYNS: P - ~ ~ E T H n - r e r t - B U T E N Z E N0E1-METHYL4-tea-BUTYLBENZENE 0 TBT
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 10 ppm; STEL 20 pprn ACGIH TLV: TWA 1 pprn DFG MAK: 10 ppm (60 mg/m3) SAFETY PROFILE: Moderately toxic by inhalation and ingestion. A s h n and human eye irritant. Human systemic effects by inhalation: nausea or vomiting, conjunctiva irritation, unspecified effects on the sense of taste. Inhalation of vapors causes irritation of lungs and depression of central nervous system. Prolonged exposure may result in damage to liver and kidneys. Flammable when exposed to heat or flame. Incompatible with oxidizing materials. When heated to decomposition it emits acrid smoke and fumes.
BSQOOO CAS: 64-77-7 HR: 2 1-BUTYL-3-(p-TOLYL SULFONYL)UREA mf: C I Z H I S N ~ O ~ S mw: 270.38 PROP: Crystals. Mp: 128.5-129.5'. Insol in H2O; sol in CHClj, dd acids, and alkalies. SYNS: XGLICID 0 ARKOZAL 0 ARTOSIN 0 ARTOZIN 0 BUTAMID 0 N-((BUTYLNMINO)CARBONYL-4-METHYLBENZENESULFONAMIDE 0 1BUTYL-3-@-METHYLPHENYLSULFONYL)UREA 0 nBUTYL-N'-p-TOLUENESULFOI\;nUREA 0 N-n-BUTYLN'-TOSYLUREA 0 l-BUTYL-3-TOSYLUREA 0 BZ 55 0 D 860 0 DIABEN 0 DIABETAMID 0 DIABETOL 0 DIABUTON 0 DOLIPOL 0 D M B E T 0 HLS 831 0 IPOGLICONE 0 MOBENOL 0 NCI-CO1763 0 ORABET 0 ORALIN 0 OREZAV 0 ORINASE 0 ORINAZ 0 OTERBEN 0 RASTINOX 0 SK-TOLBUTAMIDE 0 S(SULFONYLp-METHYLBENZENE)-N'-N-BLTYLUREAO TOLBUSAL 0 TOLBUTAMID 0 TOLBUTAMIDE 0 l-pTOLUENESULFONYL-3-BUTYLUREA 0 TOLCINA 0 TOLUMID 0 TOLUVAiY 0 N-@-T0LYLSULFONYL)-N'BUTYLCARBAMIDE 0 3-@-TOLYL4-SULFONYL-lBUTYLUREA 0 TOLYLSULFONYLBUTYLURFA 0 UTLLBUTAhfIDE
CONSENSUS REPORTS: NCI
Carcinogenesis Bioassay (feed); No
Evidence: mouse, rat NCITR" NCI-CGTR-31,77. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by ingestion and several other routes. A human teratogen. Human reproductive effects by ingestion and possibly other routes: stillbirth, developmental abnormalities of the cardlovascular (circulatory) system and urogenital system, and unspecified neonatal effects. Human systemic effects by ingestion: nausea or vomiting, hypoglycemia. Other experimental teratogenic and reproductive effects. Mutation data reported. Implicated in aplastic anemia. When heated to decomposition it emits very toxic fumes of NO, and SO,. BSROOO CAS: 7521-80-4 HR: 3 BUTYLTRICHLOROSILANE DOT: UN 1747 mf: C4HoCljSi mw: 191.57 PROP: Colorless liquid. Vap d: 6.4, flash p: 130'F (OC), d: 1.16 @ 20'/4', bp: 148-149'. SYN: TRICHLOROBUTYLSIMNE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A corrosive poison. See also CHLOROSILANE. Flammable liquid when exposed to heat, flame (sparks), or oxidizers. To fight fire, use water to blanket fire, fog, mist, dry chemical, alcohol foam. Reacts with water or steam to produce heat and toxic and corrosive fumes. When heated to decomposition it emits highly toxic fumes of c1-. BSR250 CAS: 1118-46-3 HR: 2 BUTYL TRICHLORO STANNANE mf: C4H9CljSn mw: 282.17 PROP: Liquid. D: 0.85 @ 20'/4', bp: 93' @ 10 mm. SYN: CHLORID-N-BUTYLCINICITY (CZECH) CONSENSUS REPORTS: Reported in EPA TSCA Inventory.
1,1'-(2-BUP/NYLENEDIOXY)BIS(3-CHLORO) BSTSOO 247 OSHA PEL: TWA 0.1 mg(Sn)/m' (sktn) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m' (sktn). NIOSH REL: (Organotin Compounds) TWA
SAFETY PROFILE: Moderately toxic by
parenteral route. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
0.1 mg(Sn)/m3 SAFETY PROFILE: Moderately toxic by ingestion. A severe sktn and eye irritant.
Mutation data reported, See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of C1-. BSSOOO CAS: 25852-70-4 HR: 2 BUTY LTRIS(ISOOCTYLOXYCARB0NYL METHYLTHI0)STANNAN E mf: C34H6606S3Sll mW: 785.87 SYN: BUTYLTRIS(2-ETHKHEXnOXYCARBONYL1LIETHYLTHIO)STAVNANE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 ( s h ) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Moderately toxic by ingestion. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of SO,.
BSS100 CAS: 109-42-2 HR: 1 BUTYL 10-UNDECENOATE mf: CtsH2802 mw: 240.43 SYNS: BUTYL CNDECYLENATE 0 10-UNDECENOIC ACID, BUTYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion. A slam irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
BSS250 CAS: 592-31-4 HR: 2 N-BUTYLUREA mf: C5H12N20 mw: 116.19 PROP: Needles from C6H6. Mp: 96'. SYN: NCI-C02131 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. EPA Genetic Toxicology Program.
BSS5OO HR: 3 1-BUTYLUREA and SODIUM NITRITE (2:l) SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. An experimental teratogen. When heated to decomposition it emits toxic fumes of NO,. See also NITRITES. BST5OO CAS: 110-65-6 HR: 3 2-BUTYNE-l,4-DIOL DOT: UN 2716 mf: C4H6O2 mw: 86.10 PROP: Plates from EtOAc or C6H6. Mp: 57-57', bp: 145' @ 15 mm. Very sol in H20, EtOH; sltly sol in CHCL. SYN: 1,4-BUTYNEDIOL(DOT) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: A poison by ingestion. A skin sensitizer upon long or repeated contact. Moderately explosive. When heated to decomposition it emits acrid smoke and fumes and may explode. Explosive reaction with traces of alkaltes, alkali earth hydroxides, halide salts, strong acids, mercury salts + strong acids. See also ACETYLENE COMTOUNDS.
BST9OO CAS: 1606-83-3 HR: D 1,I '-(2-BUTYNYLENEDlOXY)BIS(3CHLORO)-2-PROPANOL) mf: C ~ ~ H I ~ C mw: ~ ~ 271.16 O ~ SYNS: 2-PROPANOL, 1,1'-(2-BUTYNYLENEDIOXY)BIS(3-CHLORO- 0 U 27,151 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Experimental reproductive effects. When heated to decomposition it emits toxic fumes of C1-.
248 BSU250 n-BUTYRALDEHYDE BSU250 CAS: 123-72-8 HR: 3 n-BUTYRALDEHYDE DOT: UN 1129 mf: C4H80 mw: 72.12 PROP: Colorless, mobile liquid; pungent, nutty odor. Mp: -loo', bp: 74.7', flash p: 20'F (CC), (-6'), d: 0.7988 @ 25', autoign temp: 446'F, lel: 2.5%, uel: 12.5%, vap d: 2.5. Sol in water; misc with ether @ 74.8'.
reported. Flammable liquid when exposed to heat or flame. To fight fire, use alcohol foam, dry chemical. Highly explosive. Can explode during vacuum disdlation. Incompatible with oxidzing materials, metallic impurities. When heated to decomposition it emits toxic fumes of NO,. See also ALDEHYDES.
SYNS: ALDEHYDE BUTYRIQUE (FRENCH) 0 ALDEIDE BUTIRRICA QTALIAN) 0 BUTAL 0 BUTALDEHYDEOBUTALYDEOBUTANALOnBUTANAL (CZECH) 0 n-BUTYL ALDEHYDE 0 BUTYRAL 0 BUTYRALDEHYD (GERMAN) 0 BUTYRALDEHYDE (CZECH) 0 BUTYRIC ALDEHYDE 0 FEMA No. 2219 0 NCI-C56291
BSWOOO CAS: 107-92-6 HR: 2 n-BUTYRIC ACID DOT: UN 2820 mfi C4H802 mw: 88.12 PROP: Colorless liquid; strong, rancidbutter odor. Mp: -7.9', bp: 163.5', flash p: Ibl'F, d: 0.9590 @ 2Oo/2O0, refr index: 1.397, autoign temp: 846'F, vap press: 0.43 mm @ 20', vap d: 3.04, lel: 2.0%, uel: 10.0%. Misc in H20, EtOH, EtnO.
CONSENSUS REPORTS: Community
Rght-To-Know List. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by ingestion, inhalation, skin contact, intraperitoneal, and subcutaneous routes. Severe skin and eye irritant. Human immunologcal effects by inhalation: delayed hypersensitivity. See also ALDEHYDES. Highly flammable liquid. To fight fire, use foam, COZ,dry chemical. Incompatible with oxidzing materials. Reacts vigorously with chlorosulfonic acid, HN03, oleum, H2S04. When heated to decomposition it emits acrid smoke and fumes.
BSU500 CASE110-69-0 HR: 3 n-BUTYRALDEHYDEOXIME DOT: UN 2840 mf: C4HgNO mw: 87.14 PROP: Liquid. Mp: -29.5', bp: 152', flash p: 136'F (CC), d: 0.923, vap d: 3.01. SYNS: BUTANAL OXIME 0 BUTYRALDOXIME (DOT 0 N-BUTYRALDOXIME 0 SKINO #1 0 TROYKYD ANTI-SKIN BTO 0 USAF AM-6
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intraperitoneal route. Mutation data
SYNS: BUTANOICACID 0 BUTTERSAEURE (GERMAN) 0 ETHYLACETIC ACID 0 FEMA No. 2221 0 1-PROPANECARBOXYLICACID 0 PROPYLFOILMIC ACID CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Moderately toxic by
ingestion, skm contact, subcutaneous, intraperitoneal, and intravenous routes. Human mutation data reported. Severe skin and eye irritant. A corrosive material. Combustible liquid. Could react with oxidizing materials. Incandescent reaction with chromium trioxide above 100'. T o fight fire, use alcohol foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
BSWSOO CAS: 539-90-2 HR: 1 BUTYRIC ACID ISOBUTYL ESTER mf: C8H1602 mw: 144.24 PROP: Colorless liquid; apple-pineapple odor. D: 0.858-0863, refr index: 1.402. Sol in alc, fixed oils; sltly sol in water; insol in glycerin. SYNS: FEhlA No. 2187 0 ISOBUTYL BUTANOATE 0 ISOBUTYL BUTYRATE (FCC) 0 2-METHYLPROPYL BUTYRATE
BUTYRIC ACID ISOBUTYL ESTER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: M d l y toxic by ingestion and intraduodenal routes. A skin irritant. See also ESTERS. When heated to decomposition it emits acrid smoke and irritating fumes.
BSW550 CAS: 106-31-0 BUTYRIC ANHYDRIDE DOT: UN 2739 mf: C8H1403 mw: 158.22
HR: 1
SYNS: ANHYDRID KYSELINY MASELNE 0 BUTANOIC ACID, ANHYDRIDE (9CI) 0 BUTANOIC ANHYDRIDE 0 BUTYRANHYDRID 0 BUTYRIC ACID ANHYDRIDE 0 n-BUTYRIC ACID ANHYDRIDE n-BU”RIC ANHYDRIDE 0 B U T Y R E OXIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Mildly toxic by
ingestion. A corrosive liquid. When heated to decomposition it emits acrid smoke and irritating vapors.
BSXOOO CAS: 3068-88-0 PSUTYROLACTONE mfi C4H602 mw: 86.10
HR: 3
SYNS: 3-HYDROXYBUTANOIC ACID-P-LACTONE 0 HYDROXYBUTYRIC ACID LACTONE 0 3HYDROXYBUTYRIC ACID LACTONE 0 4-METHYL-2OXETANONE
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 11,225,76. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mildly toxic by ingestion. A moderate skin irritant. Mutation data reported. When heated to
BSWSOO 249
decomposition it emits acrid and irritating fumes. See also 4-BUTYROLACTONE.
BSX250 CAS: 109-74-0 HR: 3 BUTYRONITRILE DOT: UN 241 1 mfi C4H7N mw: 69.12 PROP: Colorless liquid. D: 0.796 @ 15O, mp: -112.6’, bp: 117O, flash p: 79°F (OC). Sltly sol in water; sol in alc and ether. SYNS: BUTANENITRILE 0 n-BUTANENITRILE 0 BUTYRIC ACID NITRILE 0 BUTYRONITRILE (Don0 1-CYANOPROPANE 0 PROPYL CYANIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Cyanide and its compounds are on the Community kghtTo-Know List. NIOSH REL: (Nitriles) TWA 22 mg/m3 DOT CLASSIFICATION: 3; Label: Flammable Liquid, Poison SAFETY PROFILE: A poison by ingestion, s h n contact, intraperitoneal, and subcutaneous routes. Moderately toxic by inhalation. Experimental reproductive data. A skin irritant. Dangerous fire hazard when exposed to heat, flame, or oxidizers. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NO, and CN-.
BSY4OO CAS: 75464-11-8 10-BUTYRYLDITHRANOL mfi C18H1604 mw: 296.34
HR: 3
SYNS: 9(10H)-ANTHRACENONE, 1,s-DIHYDROXY-10(1-0XOBUTYL)- 0 10-BUTYRYLDITHRANOL 0 BUTANTRONE 0 BUTYRYL. DITHRANOL 0 DITHRANOL, 10-BUTYRM-
SAFETY PROFILE: A poison by ingestion.
A mild skin irritant. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
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C CAD000 CAS: 7440-43-9 HR: 3 CADMIUM af: Cd aw: 112.40 PROP: Hexagonal, ductile crystals or soft, silver-white, lustrous, malleable metal. Tarnishes in air,particularly moist air. Mp: 321', bp: 767', d: 8.642, vap press: 1 mm @, 394'. Sol in dil acids (Hz evolved). IDLH 9 mg/m3 (as Cd). SYNS: C.I. 77180 0 COLLOIDAL CADMIUM 0 JSADMIUM (GERMAN) CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 2,74,73; Animal Sufficient Evidence IMEMDT 11,39,76; Human Sufficient Evidence IMEMDT 58,119,93; Human Limited Evidence IMEMDT 7,139,87; Animal Limited Evidence IMEMDT 58,119,93. Cadmium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 5 pg(Cd)/rn3 ACGIH TLV: TWA 0.01 mg(Cd)/m3 (metal), Suspected Human Carcinogen; TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood DFG MAK: D F G BAT: Blood 1.5 pg/dL; Urine 15 pg/dL. MAK. Animal Carcinogen, Suspected Human Carcinogen NlOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic, tumorigenic, and neoplastigenic data. A human poison by inhalation and possibly other routes. Poison experimentally by ingestion, inhalation, intraperitoneal,
25 1
subcutaneous, and intravenous routes. In humans inhalation causes an excess of protein in the urine. Experimental teratogenic and reproductive effects. Mutation data reported. The dust igmtes spontaneously in air and is flammable and explosive when exposed to heat, flame, or by chemical reaction with oxidizing agents, metals, HN3, Zn, Se, and Te. Explodes on contact with hydrazoic acid. Violent or explosive reaction when heated with ammonium nitrate. Vigorous reaction when heated with nitryl fluoride. When heated to a high temperature it emits toxic fumes of Cd. See also CADMIUM COMPOUNDS. CAD250 CAS: 543-90-8 HR: 3 CADMIUM(II) ACETATE mf: C2H402*1/2Cd mw: 116.25 PROP: Monoclinic, colorless crystals; odor of acetic acid. Mp: 256', bp: decomp, d: 2.341. SYNS: ACETIC ACID, CADMIUM SALT 0 BIS(ACET0XY)CADMIUM 0 CADMIUM ACETATE (DOT) 0 CADMIUM DIACETATE 0 C.1.77185
CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Cadmium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by intraperitoneal route.
252
CAD275
CADMIUM ACETATE DIHYDRATE
An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of Cd. See also CADMIUM COMPOUNDS.
CAD275 CASE5743-04-4 HR: 3 CADMIUM ACETATE DIHYDRATE mf: C&604*Cd*2H20 mw: 266.54 PROP: Crystals, becoming anhydrous at 130'; slt acetic acid odor. D: 2.01,2.341 (anhydrous), mp: 255' (anhydrous). Sol in water and alc. SYNS: ACETIC ACID, CADMIUM SALT, DIHYDRATE 0
CADMIUM DIACETATE DIHYDRATE
OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.01 mg(Cd)/m3;
Suspected Carcinogen SAFETY PROFILE: Confirmed human
carcinogen. Mutation data reported. When heated to decomposition it emits toxic fumes of Cd.
CAD325 CAS: 22750-53-4 HR: 3 CADMIUM AMIDE mf: CdH4N2 mw: 144.46 PROP: R h t e solid, which turns brown in air. SYN: CADMIUM DMMIDE CONSENSUS REPORTS: Cadmium
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGlH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 kg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. May explode if heated. Reacts violently with water. When heated to decomposition it emits toxic fumes of Cd and NO,. See also CADMIUM COMPOUNDS and AMIDES.
CAD350 CAS: 14215-29-3 HR: 3 CADMIUM AZIDE
mf: CdN6 mw: 196.45 PROP: R h t e crystals. SYN: CADMIUM DWZIDE CONSENSUS REPORTS: Cadmium
compounds are on the Community RightTo-IGow List. OSHA PEL: TWA 5 kg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. The dry solid is an unstable heat- and friction-sensitive explosive. When heated to decomposition it emits toxic fumes of NO, and Cd. See also CADMIUM COMPOUNDS and AZIDES.
CAD500 CAS: 7495-93-4 HR: 3 CADMIUM BIS(2-ETHYLHEXYL) PHOSPHITE mf: C32H6806P2*Cd mW: 723.34 SYN: BIS(2-ETHYLHEXYL) ESTER PHOSPHOROUS ACID CADMIUM SALT CONSENSUS REPORTS: Cadmium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 kg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of PO, and Cd. See also CADMIUM COMPOUNDS.
CAD550 CAS: 20246-69-9 HR: 3 CADMIUM BIS(PENTYLDITHIOCARBAMATE) mf: CnH24NzS4*Cd mw: 437.02 SYNS: CADMIUM BIS(?-AMYLDITHIOCARBALMATE) 0 CrZDMIIIUM,BIS(PENTYLDITHI0CARBAMATO)- 0 CADMIUM D I A M n DITHIOCARBAMATE
CADMIUM CHLORATE CAEOOO 253 CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93. SAFETY PROFILE: Confirmed carcinogen. Low toxicity by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic vapors of NO,, C1-, and cadmium. CAD600 CAS: 7789-42-6 HR: 3 CADMIUM BROMIDE mf: BrzCd mw: 272.22 PROP: Pearly or colorless hexagonal crystals; hygroscopic. Mp: 570°, bp: 863', d: 5.192. Sol in water, alc, and Me2CO; moderately sol in acetone. SYN: CADMIUM DIBROMIDE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 ~g(Cd)/m3 ACGIH TLV: TWA 0.01 mg(Cd)/m3; Suspected Carcinogen SAFETY PROFILE: Confirmed human carcinogen. When heated to decomposition it emits toxic fumes of Cd and Br-. CAD750 CAS: 2191-10-8 HR: 3 CADMIUM CAPRYLATE mf: C16H300pCd mw: 398.86 SYN: OCTANOIC ACID, CADMIUM SALT (2:l) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cadmium and its compounds are on the Community RightTo-Ihow List. OSHA PEL: TWA 5 ~g(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 Fg/g creatinine in urine; 5 Pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion and intratracheal routes. When heated to decomposition it emits toxic fumes of Cd. See also CADMIUM COMPOUNDS.
CAD800 CAS: 513-78-0 HR: 3 CADMIUM CARBONATE mf: C03*Cd mw: 172.41 PROP: Powder. D: 4.258. SYNS: CADMIUM MONOCARBONATE 0 CARBONIC ACID, CADMIUM SALT 0 CHEMCARB 0 W C I T 0 MIKROKALCIT 0 SUPERMIKROKALCIT
CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93; Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 ~g(Cd)/m3 ACGIH TLV: TWA 0.01 mg(Cd)/m3; Suspected Carcinogen NIOSH REL: (Cadmium, dust and fume) lowest feasible concentration SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of cadmium. CAD900 CADMIUM CDTA SYNS: ACETIC ACID, (1,2-
HR: 3
CYCLOHEXYLIDENEDINITRLO)TETFL&, CADMIUM COMPLEX, TRANS- ZYKLOHEXANDIAMINETETRAESSIGSAEC'RE KADMIUMKOMPLEXE
CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93. SAFETY PROFILE: Confirmed carcinogen. A poison by intravenous route. When heated to decomposition it emits toxic vapors of NO, and cadmium. CAEOOO HR: 3 CADMIUM CHLORATE mf: CdC1206 mw: 279.31 PROP: Colorless, deliquescent prisms. Mp: 80°, d: 2.28 @?18'. CONSENSUS REPORTS: Cadmium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 ~g(Cd)/m3
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254 CAE250 CADMIUM CHLORIDE ACGIH TLV: TWA 0.002 mg(Cd)/m3
SAFETY PROFILE: Confirmed human
(respirable dust), Suspected Human Carcinogen); BEI: 5 Fg/g creatinine in urine; 5 Fg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. A powerful oxidzing agent. Flammable by chemical reaction with reducing agents. Moderate explosion hazard when shocked or exposed to heat. Violent or explosive reaction with sulfides (e.g., copper(I1) sulfide (explodes); antimonyQ1) sulfide; arsenic(lI1) sulfide; tin(I1) sulfide; tin(Iv) sulfide). When heated to decomposition it emits toxic fumes of Cd and C1-. See also CHLORATES.
carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion, inhalation, skin contact, intraperitoneal, subcutaneous, intravenous, and possibly other routes. Human systemic effects by ingestion: blood pressure, acute pulmonary edema, hypermotility, diarrhea. Experimental teratogenic and reproductive effects. Human mutation data reported. Reacts violently with BrF3 and K. When heated to decomposition it emits very toxic fumes of Cd and C1-. See also CADMIUM COMPOUNDS and CHLORIDES.
CAE250 CAS: 10108-64-2 HR: 3 CADMIUM CHLORIDE mf: CdCL mw: 183.30 PROP: Hexagonal, colorless crystals. Mp: 568O, bp: 969.6', d: 4.047 @ 25O, vap press: 10 mm @ 656'. Sol in H20: sltly sol in EtOH. SYNS: CADDY n
CADMIUM DICHLORIDE 0 KADMIUMCHLORID (GERMAN) 0 VI-CAD
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 2,74,73; Animal Sufficient Evidence IMEMDT 11,39,76; Human Sufficient Evidence IMEMDT 58,119,93; IARC Cancer Review: Animal Sufficient Evidence IMEMDT 58,119,93; EPA Genetic Toxicology Program.Cadmium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 Fg/g creatinine in urine; 5 Fg/L in blood DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Cadmium) Reduce to lowest feasible level
CAE375 CAS: 72589-96-9 HR: 3 CADMIUM CHLORIDE, DIHYDRATE mf: CdC12*2H20 mw: 219.34 PROP: White crystals. CONSENSUS REPORTS: Cadmium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 Fg/g creatinine in urine; 5 kg/L in blood DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic data. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of C1- and Cd. See also CADMIUM CHLORIDE, CADMIUM COMPOUNDS, and CHLORIDES. CAE425 CAS: 7790-78-5 HR: 3 CADMIUM CHLORIDE, HYDRATE ( 2 5 ) mf: CdC12*5/2H20 mw: 228.35 PROP: Crystals. CONSENSUS REPORTS: Cadmium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3
CADMIUM DIACETATE MONOHYDRATE ACGIH TLV: TWA 0.002 mg(Cd)/m3
(respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 Fg/L in blood DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion and intraperitoneal routes. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of C1- and Cd. See also CADMIUM CHLORIDE, CADMIUM COMPOUNDS, and CHLORIDES. CAE500 CAS: 35658-65-2 HR: 3 CADMIUM CHLORIDE, MONOHYDRATE mf: CdC12*H20 mw: 201.32 PROP: White powder. CONSENSUS REPORTS: Cadmium and its compounds are on the Community RightT o - K ~ o wLst. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 Fg/L in blood DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic and tumorigenic data. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of Cd and C1-. See also CADMIUM CHLORIDE, CADMIUM COMPOUNDS, and CHLORIDES. CAE750 HR: 3 CADMIUM COMPOUNDS CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93; Human Sufficient Evidence
CAE800 255
IMEMDT 58,119,93. Cadmium and its compounds are on the Community kghtTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood DFG MAK: DFG BAT: Blood 1.5 Fg/dL; Urine 15 pg/dL. MAK: Suspected Carcinogen NIOSH REL: (Cadmium, dust and fume) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogens producing lung tumors. Poison by ingestion. The irritating and emetic action is so violent, however, that little of the cadmium has time to be absorbed and fatal poisoning rarely ensues. Experimental carcinogens and teratogens. Cases of human poisoning have been reported from ingestion of food or beverages prepared or stored in cadmium-plated containers. Inhalation of fumes or dusts affects the respiratory tract and the kidneys. Brief exposure to high concentrations may result in pulmonary edema and death. Fatal concentrations may be breathed without sufficient discomfort to warn a worker to leave the exposure site. Cadmium oxide fumes can cause metal fume fever resembling that caused by zinc oxide fumes. When heated to decomposition cadmium compounds emit toxic fumes of Cd. CAE800 HR: 3 CADMIUM DIACETATE MONOHYDRATE mf: C4H604*Cd*H20 mw: 248.52 SYN CADMIUM(II)ACETATE,MONOHYDRATE CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93. ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood
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256
CAFSOO CADMIUM DlCYANlDE
SAFETY PROFILE: Confirmed carcinogen. Mutation data reported. When heated to
decomposition it emits toxic vapors of cadmium.
CAF500 HR: 3 CADMIUM DlCYANlDE mf: C2CdNz mw: 164.44 CONSENSUS REPORTS: Cadmium and its compounds and cyanide and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. A poison. Incompatible with magnesium. When heated to decomposition it emits toxic fumes of Cd and CN-. See also CADMIUM COMPOUNDS and CYANIDE. CAF750 CAS: 15954-91-3 HR: 3 CADMIUM(I1) EDTA COMPLEX SYN : (ETHYLENEDINITRIL0)TETRAACETICACID CADMIUM(II) COMPLEX
CONSENSUS REPORTS: Cadmium and its
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by intraperitoneal and intravenous routes. When heated to decomposition it emits toxic fumes of NO, and Cd.
CAGOOO CAS: 14486-19-2 HR: 3 CADMIUM FLUOBORATE mf: BzCdFs mw: 286.02
SYNS: BORATE(1-),TETRAFLUORO-, CADMIUM (21) (9CI) 0 CADMIUM FLUOROBORATE 0 CADMIUM TETRAFLUOROBORATE (7CI) 0 TL 1026
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Cadmium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEE 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Suspected human carcinogen. Poison by ingestion and inhalation. When heated to decomposition it emits very toxic fumes of Cd and F-. See TETRAFLUOROBORATE.
CAG250 CAS: 7790-79-6 HR: 3 CADMIUM FLUORIDE mf: CdFz mw: 150.40 PROP: Cubic, white, non-hygroscopic, nonvolatile crystals. Mp: 1078O, bp: 1748O, d: 6.64, vap press: 1 mm @ 1112'. Sltly sol in H20. SYN: CADMIUM FLUORURE (FRENCH) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Cadmium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by subcutaneous route. Violent reaction with K. When heated to decomposition it emits very toxic fumes of Cd and F-. See also FLUORIDES and CADMIUM COMPOUNDS.
CADMIUM NITRATE CAHOOO 257
CAGSOO CAS: 17010-21-8 HR: 3 CADMIUM FLUOSILICATE mf: CdF&i mw: 254.49 PROP: Hexagonal, colorless crystals. SYNS: CADMIUM FLUOROSILICATE 0 CADMIUM HEXAFLUOROSILICATE (7CI) 0 CADMIUM SILICON FLUORIDE 0 SILICATE(2-), HEXAFLUORO-, CADMIUM (8CI,9CI) 0 TL 1070 CONSENSUS REPORTS: Cadmium and its
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion and inhalation. When heated to decomposition it emits very toxic fumes of Cd and F-.
CAG6OO CAS: 22537-48-0 CADMIUM, ION (Cd*+) mf: Cd mw: 112.40
HR: 3
SYNS: CADMICM(2Cd2+) 0 CADMIUM CATION 0 CADMIUM ION CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93. ACGIH TLV: TWA 0.002 mg(Cd)/m' (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood SAFETY PROFILE: Confirmed carcinogen. A poison by intravenous route. Mutation data reported.
CAG750 CAS: 16039-55-7 HR: 3 CADMIUM LACTATE mfi C G H I O O ~ * C ~mw: 290.56 PROP: Needles. SYN: LACTIC ACID, CADMIUM SALT
CONSENSUS REPORTS: Cadmium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. A poison. When heated to decomposition it emits toxic fumes of Cd. See also CADMIUM COMPOUNDS.
CAG775 CAS: 2605-44-9 HR: 3 CADMIUM LAURATE mfi C24H4604#Cd mw: 511.10 SYNS: CADMIUM DILAURATE 0 CADMIUM DODECANOATE 0 DODECANOIC ACID, CADMIUM SALT (9CI) 0 LAURIC ACID, CADMIUM SALT (2:l) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 ~g(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood SAFETY PROFILE: Confirmed human carcinogen. Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of Cd.
CAHOOO CAS: 10325-94-7 HR: 3 CADMIUM NITRATE rnfi CdN206 mw: 236.42 PROP: Strongly hygroscopic, white, prismatic needles. Mp: 350-360". Very sol in H 2 0 ; sol in EtOAc. SYNS: CADMIUM DINITRATE 0 CADMIUM(II) NITRATE 0 NITRIC ACID. CADMIUM SALT
CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Cadmium and its compounds are on the Community Right-To-Know List.
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258
CAH250
CADMIUM(I1) NITRATE TETRAHYDRATE
OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3
(respirable dust), Suspected Human Carcinogen); BEI: 5 Fg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion and possibly other routes. Moderately toxic by inhalation. Mutation data reported. When heated to decomposition it emits very toxic fumes of Cd and NO,. See also CADMIUM COMPOUNDS and NITRATES.
CAH250 CAS: 10022-68-1 HR: 3 CADMIUM(I1) NITRATE TETRAHYDRATE (1 :2:4) mf: N206*Cd*4Hz0 mw: 308.50 PROP: Crystals in Hz0. Mp: 59.4'. SYNS: DUSICNAN KADEMNAT?' (CZECH) 0 NITRIC ACID, CADMIUM SALT, TETRAHYDMTE CONSENSUS REPORTS: Cadmium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion. A severe skin and moderate eye irritant. Mutation data reported. See also CADMIUM COMPOUNDS, CADMIUM NITRATE, and NITRATES. When heated to decomposition it emits very toxic fumes of Cd and NO,.
CAHSOO CAS: 1306-19-0 HR: 3 CADMIUM OXIDE mf: CdO mw: 128.40 PROP: (1) Amorphous, brown powder; (2) cubic, brown crystals. Changes color on heating. Mp (1): <1426", mp (2): decomp @ 950', bp: 1559', d (1):6.95, d (2): 8.15, vap
press: 1 mm @ 1000'. Sub1 at 7'. Insol in Hz0; sol in acids and NH3. IDLH 9 mg/m3 (as Cd). SYNS: CADMIUM MONOXIDE
KADMU TLENEK
(POLISH) 0 NCI-C02551
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 1 IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 2,74,73; Animal Sufficient Evidence IMEMDT 11,39,76; Animal Sufficient Evidence IMEMDT 58,11993; Human Lmited Evidence IMEMDT 11,39,76; Human Sufficient Evidence IMEMDT 58,119,93. Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. Cadmium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen with experimental neoplastigenic data. Poison by ingestion, inhalation, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Human systemic effects by inhalation include: change in the sense of smell, change in heart rate, blood pressure increase, an excess of protein in the urine, and other kidney or bladder changes. Mixtures with magnesium explode when heated. When heated to decomposition it emits toxic fumes of Cd. See also CADMIUM COMPOUNDS.
CAH750 CADMIUM OXIDE FUME mf: CdO mw: 128.40
HR: 3
SYN: CADMIUM FUME CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,119,93;
CADMIUM 2-PYRIDINETHIONE
Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93. Reported in EPA TSCA Inventory. Cadmium and its compounds are on the Community RightTo-Ihow List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 rng(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NlOSH REL: (Cadmium, dust and fume) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Moderately toxic to humans by inhalation. Human pulmonary system effects by inhalation, including: coughing, dlffcult breathing, and cyanosis. A strong irritant via inhalation. When heated to decomposition it emits toxic fumes of Cd. See also CADMIUM OXIDE and CADMIUM COMPOUNDS.
CAI000 CAS: 13477-17-3 HR: 3 CADMIUM PHOSPHATE mf: Cd30&*4H20 mw: 599.22 PROP: Amorphous or colorless crystals. Mp: 1180'. SYN: TL 1182 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Cadmium and its compounds are on the Community RightTo-Ihow List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NlOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by inhalation. When heated to decomposition it emits toxic fumes of Cd and PO,. See CADMIUM COMPOUNDS and PHOSPHATES.
CAI125 CAS: 12014-28-7 HR: 3 CADMIUM PHOSPHIDE
CAI350 259
mf: Cd$2 mw: 399.18 PROP: Gray needles or platelets. CONSENSUS REPORTS: Cadmium compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGlH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 Fg/g creatinine in urine; 5 pg/L in blood DFG MAK: DFG BAT: Blood 1.5 pg/dL; Urine 15 pg/dL. MAK: Suspected Carcinogen NlOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Explosive reaction with concentrated nitric acid. When heated to decomposition it emits toxic fumes of PO, and Cd. See also CADMIUM COMPOUNDS and PHOSPHIDES.
CAI250 HR: 3 CADMIUM PROPIONATE mf: CsHloCdOs mw: 258.55 CONSENSUS REPORTS: Cadmium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 Fg/g creatinine in urine; 5 pg/L in blood DFG MAK: DFG BAT: Blood 1.5 pg/dL; Urine 15 pg/dL. MAK Suspected Carcinogen NlOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. The salt has exploded. Incompatible with 3-pentanone vapor. When heated to decomposition it emits toxic fumes of Cd. See also CADMIUM COMPOUNDS. CAI350 CAS: 18897-36-4 HR: 3 CADMIUM 2-PYRIDINETHIONE mf: C I O H ~ C ~ N ~ O mw: ~ S ~364.72
260
CAM00
CADMIUM SALICYLATE
SYNS: CADMIUM, BIS(l-HYDROXY-2(1H)PYFUDINETHIONAT0)- 0 CADM1UR.IPT 0 CdPT OSHA PEL: TWA 5 ~g(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3
(respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 Fg/L in blood NIOSH REL: (Cadmium) TWA reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion and intravenous routes. When heated to decomposition it emits toxic fumes of NO,, SO,, and Cd. CAI400 CAS: 19010-79-8 HR: 3 CADMIUM SALICYLATE mf: C I ~ H I O C ~ O Gmw: 386.64 PROP: Monohydrate small needles or plates. Mp: 242'. Sltly sol in cold water, methanol, eth; very sol in b o h g water. SYNS: BIS(2-HYDROXYBENZOATO-O~Oz-), (T-4)CADiMIUM (9CI) 0 CADMIUM, BIS(SALICYLAT0)-
OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3
(respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion. When heated to decomposition it emits toxic fumes of Cd. CAI500 HR: 3 CADMIUM SELENIDE mf: CdSe mw: 191.36 PROP: Preparative hazard. CONSENSUS REPORTS: Cadmium and its compounds as well as selenium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 ~g(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 Fg/g creatinine in urine; 5 Fg/L in blood
DFG MAK: DFG BAT: Blood 1.5 pg/dL; Urine 15 pg/dL. MAK. Suspected Carcinogen; 0.1 mg(Se) /m3 NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Selenium compounds are considered to be poisons. When heated to decomposition it emits toxic fumes of Cd and Se. See also CADMIUM COMPOUNDS and SELENIUM COMPOUNDS.
CAI750 CAS: 141-00-4 HR: 3 CADMIUM SUCCINATE mf: C4H404*Cd mw: 228.48 SYNS: CADMINATE 0 SUCCINIC ACID, CADMIUM SALT (1:l)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cadmium and its compounds are on the Community RtghtTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 Fg/g creatinine in urine; 5 pg/L in blood DFG MAK: DFG BAT: Blood 1.5 Kg/dL; Urine 15 pg/dL,. MAK Suspected Carcinogen NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic fumes of Cd. See also CADMIUM COMPOUNDS.
CAJOOO CAS: 10124-36-4 HR: 3 CADMIUM SULFATE (1 :1) mf: 04S*Cd mw: 208.46 PROP: Rhombic, white crystals or prisms. Mp: lOOO', d: 4.691. Sol in HzO;very sltly sol in MeOH, EtOH, and EtOAc. SYNS: CADMIUM SCLFATE 0 CADMIUM SULPHATE 0 SULFURIC ACID, CADMIUM(2+) SALT 0 SULPHURIC ACID, CADMIVM SALT (1:l)
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
CADMIUM SULFIDE
Group 1 IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 2,74,73; Animal Sufficient Evidence IMEMDT 11,39,?6; Animal Sufficient Evidence IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Cadmium and its compounds are on the Community RtghtTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic data. Poison by ingestion, subcutaneous, and intraperitoneal routes. Experimental teratogenic and reproductive effects. Mutation data reported. See also CADMIUM COMPOUNDS and SULFATES. When heated to decomposition it emits very toxic fumes of Cd and SO,.
CAJ250 CAS: 7790-84-3 HR: 3 CADMIUM SULFATE (1 :1) HYDRATE (3:8) mf: 04S*Cd*8/3H20 mw: 256.51 PROP: Crystals from aq s o h @ 174'. SYNS: CADMIUM SULFATE OCTAHYDRATE 0 SULFURIC ACID, CADMIUM SALT, HYDRATE
CONSENSUS REPORTS: IARC Cancer Review: Animal Sufficient Evidence IMEMDT 2,74,73. Cadmium and its compounds are on the Community RtghtTo-Know List. OSHA PEL: TWA 5 ~g(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 Fg/g creatinine in urine; 5 Fg/L in blood
CAJ750 261
NIOSH REL: (Cadmium) Reduce to lowest
feasible level SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic and neoplastigenic data. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of Cd and SO,. See also CADMIUM SULFATE, CADMIUM COMPOUNDS, and SULFATES.
CAJ5OO CAS: 13477-21-9 HR: 3 CADMIUM SULFATE TETRAHYDRATE mf: 04S*C&4HzO mw: 280.54 SYN: SULFURIC ACID, CADMIUM SALT, TETRAHYDRATE CONSENSUS REPORTS: Cadmium and its compounds are on the Community fightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 Fg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen with experimental neoplastigenic data. When heated to decomposition it emits very toxic fumes of Cd and SO,. See also CADMIUM COMPOUNDS.
CAJ750 CAS: 1306-23-6 HR: 3 CADMIUM SULFIDE mf: CdS mw: 144.46 PROP: Hexagonal, lemon-yellow to orange crystals. Mp: 1750' @ 100 atm, bp: subl in Nz, subl @ 9', d: 4.82. Sltly sol in H20. SYNS: AURORA YELLOW 0 CADMIUM GOLDEN 366 0 CADMIUM LEMON YELLOW 527 0 CADMIUM MONOSULFIDE 0 CADMIUM ORANGE 0 CADMIUM PRIMROSE 819 0 CADMIUM SULPHIDE 0 CADMIUM YELLOW 0 CADMIUM YELLOW 000 0 CADMIUM YELLOW 892 I3 CADMIUiM YELLOW CONC. DEEP 0 CADMIUM YELLOW CONC. GOLDEN 0 CADhIIUM YELLOW CONC. LEMON CADMIUM YELLOW CONC. PRIMROSE 0 CADMIUM YELLOW 10G CONC. 0 CADMIUM YELLOW OZ DARK 0 CADMIUhl YELLOW PRIMROSE 47-4100 0 CADMOPUR GOLDEN YELLOW N
E
262
CAJ760 CADMIUM SULFIDE (AMORPHOUS)
0 CADMOPUR YELLOW 0 CAPSEBON 0 C.I. 17199 0 C.I. PIGMENT ORANGE 20 0 C.I. PIGMENT YELLOW 37 0 FERRO LEMON YELLOW 0 FERRO ORAlWGE YELLOW 0 FERRO YELLOW 0 GREENOCKITE 0 NCIC02711
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 1 IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 2,74,73; Animal Sufficient Evidence IMEMDT 11,39,76;Animal Sufficient Evidence IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93. EPA Genetic Toxicology Program. Cadmium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 pg(Cd)/m’ ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic and tumorigenic data. Moderately toxic by ingestion and inhalation. Human mutation data reported. When heated to decomposition it emits very toxic fumes of Cd and SO,. See also CADMIUM COMPOUNDS and SULFIDES.
CAJ760 HR: 3 CADMIUM SULFIDE (AMORPHOUS) CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93. SAFETY PROFILE: Confirmed carcinogen. Mutation data reported. When heated to decomposition it emits toxic vapors of cadmium. CAJ770 HR: 3 CADMIUM SULFIDE mixed with ZINC
SULFIDE (5:95) SYN: K-82 CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93. ACGIH TLV: TWA 0.002 mg(Cd)/m’ (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium, dust and fume) Reduce to lowest feasible level SAFETY PROFILE: Confirmed carcinogen. When heated to decomposition it emits toxic vapors of SO,, cadmium, and zinc.
CAJ772 CAS: 63661-05-2 HR: 3 CADMIUM SULFIDE mixed with ZINC SULFIDE (8:92) SYN: K-83 CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,119,93. ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 pg/L in blood NIOSH REL: (Cadmium, dust and fume) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. When heated to decomposition it emits toxic vapors of SO,, cadmium, and zinc.
CAKOOO HR: 3 CADMIUM THERMOVACUUM AEROSOL mf: Cd mw: 112.40 SYN: AEROSOL of THERMOVACUUM CADMIUM CONSENSUS REPORTS: IARC Cancer
Review: Group 1 IMEMDT 58,119,93; Human Sufficient Evidence IMEMDT 58,119,93; Animal Sufficient Evidence IMEMDT 58,115493. Cadmium and its compounds are on the Community fightTo-Know List.
CALCIUM ACETATE OSHA PEL: TWA 5 kg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3
(respirable dust), Suspected Human Carcinogen); BEI: 5 pg/g creatinine in urine; 5 kg/L in blood NIOSH REL: (Cadmium, dust and fume) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Moderately toxic by an unspecified route. When heated to decomposition it emits very toxic fumes of Cd. See also CADMIUM and CADMIUM COMPOUNDS.
CAL750 263
PROP: White, fleecy masses; odorless with bitter taste. Mp: 235' (anhyd). Sol in water, alc, chloroform, ether. SYNS: CAFFEIN 0 COFFEIN (GERMAN) 0 COFFEINE 0
3,7-DIHYDRO-I,3,7-TRIMETHYL-lH-PURNE-2,6-
DIONE 0 ELDIATRIC C 0 FEMA No. 2224 0 GUARANINE KOFFEIN (GERMAN) METHYLTHEOBROMIDE 0 I-METHYLTHEOBROMINE 0 7METHYLTHEOPHYLLINE 0 NCI-C02733 0 NO-DO2 0 ORGANEX 0 THEIN 0 THEINE 0 1,3,7-TRIMETHYL2,G-DIOXOPURINE 0 1,3,7-TRIiMETHYLXANTHINE
subcutaneous route. When heated to decomposition it emits toxic vapors of NO, and SO,.
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: A human poison by ingestion. An experimental poison by ingestion, subcutaneous, intraperitoneal, intramuscular, rectal, and intravenous routes. Human systemic effects: ataxia, blood pressure elevation, change in heart rate, changes in tubules, convulsions or effect on seizure threshold, dtarrhea, distorted perceptions, hallucinations, hypermotility, muscle contraction, musculoskeletal tumors, nausea or vomiting, toxic psychosis, tremors. A human teratogen causing developmental abnormalities of the craniofacial and musculoskeletal systems, pregnancy termination (abortion), and stillbirth. Human maternal effects include an unspecified effect on labor or chddbirth. Human mutation data reported. An experimental teratogen. Other experimental reproductive effects. Questionable carcinogen with experimental carcinogenic data. Large doses (above 1.0 g> cause palpitation, excitement, insomnia, dtzziness, headache, and vomiting. Continued excessive use of caffeine in tea or coffee may lead to digestive disturbances, constipation, palpitations, shortness of breath, and depressed mental states. It is also implicated in cardiac disorders under those condttions. When heated to decomposition it emits toxic fumes of NO,.
CAKSOO CAS: 58-08-2 CAFFEINE mf: C8H10N402 mw: 194.22
CAL750 CAS: 62-54-4 CALCIUM ACETATE mf: C4H604*Ca mw: 158.18
CAK250 CAS: 73419-42-8 HR: 3 CADMIUM-THIONEINE mf: C I ~ H ~ O N ~ ~ ~ Smw: Z *571.06 C~ PROP: Cadmium(I1) is bound to the protein thoneine from rat or rabbit liver (BCPCA6 26,25,77). CONSENSUS REPORTS: Cadmium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 5 pg(Cd)/m3 ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 kg/g creatinine in urine; 5 kg/L in blood NIOSH REL: (Cadmium) Reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. Deadly poison by intravenous route. When heated to decomposition it emits very toxic fumes of NO,, SO,, and Cd. See also CADMIUM COMPOUNDS. CAK285 CAS: 17650-98-5 HR: 3 CAERULEIN mf: C58H73N13021S2 mw: 1352.42 SYN: CERULEIN SAFETY PROFILE: A poison by
HR: 3
HR: 3
E
264 CAMOOO CALCIUM ACID METHYL ARSONATE PROP: Fine, white, hygroscopic, bulky
powder. Very sol in water; sltly sol in alc. SYNS: ACEWTE ofLIME 0 BROWN ACETATE 0 CALCIUM DIACETATE 0 GRAY ACETATE 0 LIME ACET24TE LIME PYROLIGNITE 0 SORBO-CALCIAN 0 SORBO-CALCION 0 T E L T O Z W 0 VINEGAR SALTS CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Mutation data reported. See also CALCIUM COMPOUNDS. When heated to decomposition it emits acrid smoke and fumes.
CAMOOO CAS: 5902-95-4 HR: 3 CALCIUM ACID METHYL ARSONATE mf: C2H&206*Ca mw: 318.02 SYNS: CALAR 0 CALCIUM ACID METHANEARSONATE 0 CALCIUM HYDROGEN METHANEARSOSATE 0 CALCIUM METHANEARSONATE 0 C A W 0 SUPER CRAB-E-RAD-CALAR 0 SUPER DALERAD 0 SUPER DAL-E-FL4D-CALAR 0 USAF AN-I1 CONSENSUS REPORTS: Arsenic and its
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(As)/m3 ACGIH TLV: BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine SAFETY PROFILE: Moderately toxic by intraperitoneal and possibly other routes. Arsenic compounds are considered to be poisons. An herbicide. When heated to decomposition it emits toxic fumes of As. See also ARSENIC COMPOUNDS and CALCIUM COMPOUNDS.
CAM200 CAS: 9005-35-0 HR: 3 CALCIUM ALGINATE mf: [(C6H706)2Ca], mw: 195.16 PROP: Whlte to yellow, granular powder. Insol in water, org s o h . SYNS: ALGIN COMBINACE
0 CA 33 0 CALGINATE 0 KALTOSTAT
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Moderately toxic by intraperitoneal
route. When heated to decomposition it emits acrid smoke and irritating fumes.
CAM222 CAS: 10103-62-5 HR: 3 CALCIUM ARSENATE mf: AsHsO4*xCa mw: 422.51 SYN: ARSENIC ACID, CALCIUM SALT CONSENSUS REPORTS: NTP 10th Report on Carcinogens, 20OO:known to be human
carcinogen SAFETY PROFILE: Confirmed human carcinogen. When heated to decomposition it emits toxic vapors of NO,.
CAM300 CAS: 15194-98-6 HR: 3 CALCIUM ARSENITE DOT: NA 1574 mf: As04*Ca mw: 179.00 SYNS: ARSENENOUS ACID, CALCIUM SALT (2:l) 0 CALCIUM ARSENITE, solid (DOT,! 0 PROTARS DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A poison. When heated
to decomposition it emits toxic vapors of As.
CAM500 CAS: 27152-57-4 CALCIUM ARSENITE DOT: NA 1574 mf: Asz06*3Ca mw: 366.08 PROP: Whlte, granular powder.
HR: 3
SYNS: ARSENIOUS ACID, CALCIUM SALT 0 CALCIUM ARSENITE, sohd (DOT,! ARSENITE
MONOCALCIUM
CONSENSUS REPORTS: Arsenic and its
compounds are on the Community RightTo-Know List. OSHA PEL: OSHA: Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 I.L (As)/L inorganic arsenic and methylated metabolites in urine; BEI: 10 Fg/g creatinine in urine; 10 pg/L in blood NIOSH REL: (Inorganic Arsenic) CL 0.002 mg(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed carcinogen. A poison by inhalation and ingestion. When heated to decomposition it emits toxic fumes of As. See also ARSENIC
CALCIUM CARBONATE
COMPOUNDS and CALCIUM COMPOUNDS.
CAM600 CAS: 5743-27-1 HR: D CALCIUM ASCORBATE mf: C12Ht4CaOt2*2H20 mw: 426.35 PROP: White crystalline powder; odorless. Sol in water; sltly sol in alc; insol in ether. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. CAM750 CAS: 6485-34-3 HR: 3 CALCIUM-0-BENZOSULFIMIDE mf: Ct4HtoN20&*Ca mw: 406.46 PROP: White, crystalline powder; odorless or faint aromatic odor; sol in water. SYNS: 1,2-BEN%ISOTHIAZOL-3(2H)-ONE-t,1DIOXIDE, CALCIUM SALT 0 CALCIUM-oBENZOSULPHIMIDE 0 CALCIUiM-2-BENZOSULPHIMIDE 0 CALCIUM SACCHARIN 0 CALCIUM SACCHARINA 0 CALCIUM SACCHARINATE 0 DARAMIN 0 SACCHARIN CALCIUM 0 SULPHOBENZOIC IMIDE CALCIUM SALT
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mutagenic data
reported. When heated to decomposition it emits toxic fumes of SO, and NO,.
CAN000 CAS: 13780-03-5 HR: 3 CALCIUM BlSULFlTE DOT: UN 1923 PROP: Colorless or sltly yellowish liquid; strong sulfur dioxide odor. D: 1.06. SYNS: CALCIUM DITHIONITE (DOT) 0 CALCIUM HYDROSULFITE (DOT) 0 SULFUROUS ACID, CALCIUM SALT (2:l) (8CI,9CI)
CAOOOO 265
CAN400 HR: 1 CALCIUM BROMATE mf: Ca(BrO3)z*HaO mw: 313.90 PROP: White crystalline powder. Very sol in water. SAFETY PROFILE: A nuisance dust. CAN750 CAS: 75-20-7 HR: 3 CALCIUM CARBIDE DOT: UN 1402 mf: CzCa mw: 64.10 PROP: Rhombic, moisture-sensitive, gray crystals. Mp: approx 2300', d: 2.222. SYNS: ACETYLENOGEN CALCIUM DICARBIDE
CALCIUM ACETYLIDE 0
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 4.3; Label: Dangerous When Wet SAFETY PROFILE: Reaction on contact with moisture forms explosive acetylene gas. Flammable on contact with moisture, acid or acid fumes; evolves heat or flammable vapors. Moderate explosion hazard. Incandescent reaction with Clz (245'C), Brz (35OoC),IS (305'C), HC1 gas + heat, PbFz, Mg + heat. Incompatible with Se, (KOH + Ch), AgN03, Na202, SnClz, S, water. Mixtures with iron(II1) chloride, iron(II1) oxide, tin(I1) chloride are easily ignited and burn fiercely. Vigorous reaction with methanol after an induction period. Addttion to silver nitrate solutions precipitates the dangerously explosive silver acetylide. Copper salt solutions behave similarly. See also CALCIUM HYDROXIDE and ACETYLENE.
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 4.2; Label:
Spontaneously Combustible SAFETY PROFILE: A poison via ingestion. Strong irritant via skin and eye contact, ingestion, and inhalation. Spontaneously combukible. When heated to decomposition it emits toxic fumes of SO,. See also SULFITES and SULFUROUS ACID.
CAOOOO CAS: 1317-65-3 HR: 1 CALCIUM CARBONATE mf: C O K a mw: 100.09 PROP: White microcrystalline powder. Mp: 825' (a),1339' (p) @ 102.5 atm, d: 2.7-2.95. Found in nature as the minerals limestone, marble, aragonite, calcite, and vaterite. Odorless, tasteless powder or crystals. Two crystalline forms are of commercial importance: aragonite, orthorhombic, mp:
266 CA0250 CALCIUM CARRAGHEENATE 825' (decomp), d: 2.83, formed at temperatures above 30"; calcite, hexagonalrhombohedral, mp: 1339' (102.5 atm), d: 2.711, formed at temperatures below 30'. At about 825' it decomposes into CaO and C02. Practically insol in water, alc; sol in dilute acids. SYNS: AGRICULTURAL LIMESTONE 0 AGSTONE 0 ARAGONITE 0 ATOMIT 0 BELL MINE PULVERIZED LIMESTONE 0 CALCITE 0 CARBONIC ACID, CALCIUM SALT (1:l) 0 CHALK 0 DOLOMITE 0 FRANKLIN 0 LIMESTONE (FCC) 0 LITHOGRAPHIC STONE 0 MARBLE 0 NATURAL CALCIUhl CARBONATE 0 PORTLAND STONE 0 SOHNHOFEN STONE 0 VATERITE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: Total Dust: 15 mg/m3; Respirable Fraction: 5 mg/m3 ACGIH TLV: TWA (nuisance particulate) 10 mg/m3 of total dust (when toxic impurities are not present, e.g., quartz <19'0) SAFETY PROFILE: A nuisance dust. An eye and skin irritant. Igmtes on contact with F2. Incompatible with acids, ammonium salts, (Mg + H2). Calcium carbonate is a common air contaminant. See also CALCIUM COMPOUNDS.
CA0250 CAS: 9049-05-2 HR: 2 CALCIUM CARRAGHEENATE PROP: A mixture of highly sulfated polygalactosides. It is extracted from seaweed (FAONAU 53A,398,74). SYNS: ALGIK GUM 0 CALCIUM CARAGEENIN 0 CALCIUM CARRAGEENAN 0 CARRAGEENAN, CALCIUM(I1) SALT 0 VISCAMN 402
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of SO,. See also CALCIUM COMPOUNDS.
CA0500 CAS: 10137-74-3 HR: 2 CALCIUM CHLORATE DOT: UN 1452/UN 2429 mf: C120Ka mw: 206.98
PROP: Monoclinic, yellowish-white, deliquescent crystals. Mp: 340' (loses H2O @ >loo'), I d: 2.711. Very sol in HzO. SYNS: CALCIUM CHLORATE, aqueous solution p o q CHLORATE de CALCIUM FRENCH)
DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: Moderately toxic by
ingestion and intraperitoneal routes. A powerful oxidant. Incompatible with Al, As, C, Cu, charcoal, MnO2, metal sulfides, S, &basic organic acids, organic matter, P. When heated to decomposition it emits toxic fumes of C1-. See also CHLORATES for fire, disaster, and explosion hazards.
CA0750 CAS: 10043-52-4 HR: 2 CALCIUM CHLORIDE mf: CaC12 mw: 110.98 PROP: Cubic, colorless, deliq crystals. Mp: 782', bp: >1600', d: 2.512 @! 25'. Very sol in H20; sol in EtOH, MezCO, and AcOH. SYNS: CALCIUM CHLORIDE, anhydrous 0 CALPLUS 0 CALTAC 0 DOWFLAKE 0 LIQUIDOW 0 PELADOW 0 SNOMELT 0 SUPERFLAKE ANHYDROUS
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. EPA FIFRA 1988 pesticide subject to registration or re-registration. SAFETY PROFILE: Moderately toxic by ingestion. Poison by intravenous, intramuscular, intraperitoneal, and subcutaneous routes. Human systemic effects: dermatitis, changes in calcium. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Reacts violently with (B203 + CaO), BrF3. Reaction with zinc releases explosive hydrogen gas. Catalyzes exothermic polymerization of methyl vinyl ether. Exothermic reaction with water. When heated to decomposition it emits toxic fumes of C1-. See also CALCIUM COMPOUNDS and CHLORIDES.
CAPO00 CAS: 14674-72-7 HR: 3 CALCIUM CHLORITE DOT: UN 1453 mf: CaC1204 mw: 174.98 PROP: White solid.
CALCIUM CYANAMIDE CAQ250 267 DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: A strong oxidizer.
Ignites on contact with potassium thiocyanate. Reaction with Clz yields explosive C 1 0 ~When . heated to decomposition it emits toxic fumes of C1-. See also CHLORITES and CALCIUM COMPOUNDS.
CAP500 CAS: 13765-19-0 HR: 3 CALCIUM CHROMATE mf: CrOpCa mw: 156.08 PROP: Monoclinic prisms; yellow colored crystals. Sltly sol in Hz0; insol in EtOH and MezCO. IDLH Ca [15 mg/m3 {as Cr(VI)}]. SYNS: CALCIUM CHROMATE (vr) 0 CALCIUM CHROME YELLOW 0 CALCIUM CHROMIUM OXIDE (CaCr04) 0 CALCIUM MONOCHROMATE 0 CHROMIC ACID, CALCIUM SALT (1:l) 0 C.I. 77223 0 C.I. PIGMENT YELLOW 33 0 GELBIN 0 RCRA WASTE NUMBER U032 0 YELLOW ULTRAMARINE
CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 49,49,90; Human Sufficient Evidence IMEMDT 23,205,80; Animal Sufficient Evidence IMEMDT 23,205,80. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Chromium and its compounds are on the Community Right-To-Know List. OSHA PEL: CL 0.1 mg(Cr03)/m3 ACGIH TLV: TWA 0.001 mg(Cr)/m3; Suspected Human Carcinogen DFG MAK: DFG TRK: 0.1 mg/m3 calculated as Cr03 in that portion of dust that can possibly be inhaled; 0.2 mg/m3 arcwelding by hand; others 0.1 mg/m3. Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Chromium(VI)) TWA 0.001 mg(Cr(VI))/m3 SAFETY PROFILE: Suspected human carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. Mutation data reported. A powerful oxiduer. Mixture with boron burns violently if ignited. See also CHROMIUM COMPOUNDS and CALCIUM COMPOUNDS.
CAP750 CAS: 10060-08-9 HR: 3 CALCIUM CHROMATE(V1) DIHYDRATE mf: Cr04*Ca*2HzO mw: 192.12 PROP: IDLH Ca [15 mg/m3 {as Cr(VI)}]. SYNS: CALCIUM CHROME YELLOW 0 CHROMIC ACID, CALCIUM SALT (l:l),DIHYDRATE 0 C.I. 77223 0 C.I. PIGMENT YELLOW 33 0 GELBIN YELLOW ULTRAMARINE 0 PIGMENT YELLOW 33 U STEINBUHL YELLOW
CONSENSUS REPORTS: IARC Cancer Review: Animal Sufficient Evidence IMEMDT 2,100,72. Chromium and its compounds are on the Community RightT o - K ~ o wL s t . OSHA PEL: CL 0.1 mg(Cr03)/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m3; Confirmed Human Carcinogen NIOSH REL: (Chromium(VI)) TWA 0.001 mg(Cr(VI))/m3 SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic and carcinogenic data. Poison by ingestion and implant routes. Mutation data reported. A powerful oxidizer. See also CHROMIUM COMPOUNDS and CALCIUM COMPOUNDS.
CAQOOO HR: 1 CALCIUM COMPOUNDS SAFETY PROFILE: The fumes evolved by burning calcium in air are composed of calcium oxide (quicklime), which is an irritant to the skin, eyes, and mucous membranes. Generally speaking, calcium compounds should be considered toxic only when they contain toxic components (such as arsenic, etc.) or as calcium oxide or hydroxide. Calcium compounds are common air contaminants. CAQ250 CAS: 156-62-7 HR: 3 CALCIUM CYANAMIDE DOT: UN 1403 mf: C N K a mw: 80.11 PROP: Hexagonal, rhombohedral, colorless, moisture-sensitive crystals. Mp: 1300°, sub1 @ >1500°. Decomposes in water. Compound not hydrated; compound
E
268
CAQSOO CALCIUM CYANIDE
contains more than 0.1% calcium (FEREAC 41,15972,76). SYNS: AERO-CYANAMID 0 AERO CYA&AMID GRhUULAR 0 AERO CYANAMID SPECIAL GRADE 0 ALZODEF 0 CALCIUM CARBIMIDE 0 CALCIUM CYANAMID 0 CCC 0 CYANAMIDE 0 CYANAMIDE CALCIQUE (FRENCH) 0 CYANAMIDE, CALCIUhl SALT (1.1) 0 CYANAhiID GRANULAR 0 CYANAMID SPECIAL GRADE 0 CY-L 500 0 LIME-NITROGEN (DO13 0 NCIC02937 0 NITROGEN LIME 0 NITROLIME 0 USAF CY2
CONSENSUS REPORTS: NCI
Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* NCI-CGTR-163,79. Community kght-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.5 mg/m3 ACGIH TLV: TWA 0.5 mg/m3; Not Classifiable as a Human Carcinogen DFG MAK: 1 mg/m3 DOT CLASSIFICATION: 4.3; Label: Dangerous When Wet SAFETY PROFILE: Poison by ingestion, inhalation, s h contact, intravenous, and intraperitoneal routes. Moderately toxic to humans by ingestion. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. The fatal dose, by ingestion, is probably around 20 to 30 g for an adult. It does not have a cyanide effect. Calcium cyanamide is not believed to have a cumulative action. Flammable. Reaction with water forms the explosive acetylene gas. When heated to decomposition it emits toxic fumes of NO, and CN-. See also CALCIUM COMPOUNDS, AMIDES, and CYANIDE. CAQ500 CAS: 592-01-8 HR: 3 CALCIUM CYANIDE DOT: UN 1575 mf: C2CaN2 mw: 92.12 PROP: Rhombohedral crystals or white powder. Mp: decomp >350°. SYNS: CALCID 0
CALCIUM CYANIDE MIXTURE, sohd (DO?? 0 CALCYAN 0 CALCYANIDE 0 CYANOGAS 0 CYANURE de CALCIUhf (FRENCH) 0 RCRA WASTE NUhlBER PO21
CONSENSUS REPORTS: Cyanide and its compounds are on the Community RightTo-Ikow List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 mg(CN)/m3 ACGIH TLV: CL 5 mg(CN)/m3 (shn) DFG MAK: 5 mg/m3 NIOSH REL: (Cyanide) CL 5 mg(CN)/mJ/l OM DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A deadly poison by ingestion and probably other routes. When heated to decomposition it emits toxic fumes of NO, and CN-. See also CALCIUM COMPOUNDS and CYANIDE.
CAR000 CAS: 139-06-0 HR: 3 CALCIUM CYCLOHEXYLSULPHAMATE mf: C1zH24N20&*Ca mw: 396.58 PROP: White, crystalline powder; almost odorless; freely sol in water; practically insol in alc, benzene, chloroform, and ether. SYNS: CALCIUM CYCLAMATE 0 CALCIUM CYCLOH E X A N E S U L F M T E 0 CALCIUM CYCLOHEXANE SULPHAhUTE 0 CALCIUM CYCLOHEXYLSULFAMATE 0 CYCLAMATE CALCIUM 0 CYCLAMATE, CALCIUM SALT 0 CYCLAN 0 CYCLOHEXANESULFAMICACID, CALCIUM SALT 0 CYCLOHEXYLSULPHAMIC ACID, CALCIUM SALT 0 CYLAN 0 DIETIL 0 KALZIUMZYKLAiMATE (GERMAN) 0 SUCARYL CALCIUM CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,178,87; Animal Limited Evidence IMEMDT 22,55,80; Human Inadequate Evidence IMEMDT 22,55,80. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by ingestion and intravenous routes. Experimental reproductive effects. Questionable carcinogen with experimental tumorigenic and neoplastigenic data. Human mutation data reported. When heated to decomposition it emits very toxic fumes of SO, and NO,. See also CALCIUM COMPOUNDS.
CALCIUM HYDROXIDE
CAR775 HR: D CALCIUM DISODIUM EDTA mf: C I O H I Z C ~ N Z N ~ Z O E * ~ Hmw: ZO 410.30 PROP: White crystalhe powder; hygroscopic with a faint salt taste. Sol in water. SYNS: CALCIEM DISODIUM EDETATE 0 CALCIUM DISODIUM ETHYLENEDWMINETETRAACETATE0 CALCIUM DISODIUM (ETHYLENEDINITRIL0)TETRAACETATE
SAFETY PROFILE: When heated to
decomposition it emits toxic fumes of NO,. CASOOO CAS: 7789-75-5 HR: 2 CALCIUM FLUORIDE mf: CaF2 mw: 78.08 PROP: Hygroscopic, cubic, colorless crystals; luminous with heat. Mp: 1418", d: 3.180. Practically insol in H20; insol in Me2CO; sol in acids. SYNS: ACID-SPAR 0 CALCIUM DIFLUORIDE 0 FLUORITE 0 FLUORSPAR 0 IRTRAN 3 0 LIPARITE 0 MET-SPAR
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shft; 10 mg/g creatinine of fluorides in urine at end of shift. NIOSH REL: (Inorganic Fluorides) TWA 2.5 mg(F) /m3 SAFETY PROFILE: Moderately toxic by intraperitoneal route. Mildly toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also FLUORIDES and CALCIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of F-.
CAS250 CASE544-17-2 HR: 3 CALCIUM FORMATE mf: C2H204*Ca mw: 130.12 PROP: Colorless, orthorhombic crystals. Also exists in several other polymorphic forms. Very sol in H20; insol in EtOH. SYNS: FORMC ACID, CALCIUM SALT 0 MRAVENCAN VAPENATY (CZECH)
CAT225 269
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Moderately toxic by ingestion. An eye irritant. When heated to decomposition it emits acrid smoke and fumes. See also CALCIUM COMPOUNDS.
CAS750 CAS: 299-28-5 HR: 2 CALCIUM GLUCONATE mf: C12H22014*Ca mw: 430.42 PROP: White, fluffy powder or granules; odorless and tasteless. Sol in hot water; less sol in cold water; insol in alc, acetic acid, and other org solvs. Mp: loses H20 @ 120'. SYNS: CALCICOL 0 CALCIOFON 0 CALCIPUR 0 CALCIUM d-GLUCONATE 0 CALCIUM HEXAGLUCONATE 0 CALGLUCOL 0 CALGLUCON 0 DRAGOCAL 0 EBUCIN 0 GLUCAL 0 GLUCOBIOGEN 0 GLUCONATE de CALCIUM (FRENCH) 0 GLUCONATO d~CALCIO 0 d-GLUCONIC ACID, CALCIUM SALT (2:l) (9CI) 0 KALPREX 0 NOVOCAL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
subcutaneous, intraperitoneal, and intravenous routes. Human systemic effects in infants by intramuscular route: dermatitis and fever. When heated to decomposition it emits acrid smoke and fumes. See also CALCIUM COMPOUNDS. CAS825 HR: 1 CALCIUM HEXAMETAPHOSPHATE SAFETY PROFILE: A nuisance dust. CAT225 CAS: 1305-62-0 HR: 2 CALCIUM HYDROXIDE mfi CaH202 mw: 74.10 PROP: Rhombic, trigonal, colorless crystals or white power; sltly bitter taste. Mp: loses H2O @ 580", bp: decomp, d 2.343. Sltly sol in water and glycerin; insol in alc. SYNS: BELL MINE 0 BIOCALC 0 CALCIUM DIHYDROXIDE 0 CALCIUM HYDRATE 0 CALCIUM HYDROXIDE (ACGIH, OSHA) 0 CALVIT 0 CARBOXIDE 0 HYDRATED LIME 0 ULKHYDRATE 0 KEMIKAL 0 LIU3UX 0 LIME MILK 0 LIME WATER 0 MILK O F LIME 0 SLAKED LIME
270
CAT500
CALCIUM IODATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 5 mg/m3 ACGIH TLV: TWA 5 mg/m3 SAFETY PROFILE: Mildly toxic by ingestion. A severe eye irritant. A skin, mucous membrane, and respiratory system irritant. Mutation data reported. Causes dermatitis. Dust is considered to be a significant industrial hazard. A common air contaminant. Violent reaction with maleic anhydride, nitroethane, nitromethane, nitroparaffins, nitropropane, phosphorus. Reaction with polychloiinated phenols + potassium nitrate forms extremely toxic products. See also CALCIUM COMPOUNDS.
CAT500 CAS: 7789-80-2 HR: 1 CALCIUM IODATE mf: Ca(I03)2*H20 mw: 407.90 PROP: White powder or colorless monoclinic crystals. Decomposes on heating. Sltly sol in water; insol in alc. SAFETY PROFILE: A nuisance dust.
OSHA PEL: TWA Total Dust: 10 mg/m3;
Respirable Fraction: 5 mg/m3 ACGIH TLV: Insoluble Compounds:
inhalable fraction, 10 mg(Mo) /m3,3 mg(Mo)/m3, respirable fraction. SAFETY PROFILE: Poison by intraperitoneal route. See also MOLYBDENUM and CALCIUM COMPOUNDS.
CAUOOO CAS: 10124-37-5 HR: 3 CALCIUM(I1) NITRATE (1 :2) DOT: UN 1454 mf: N206*Ca mw: 164.10 PROP: Hygroscopic, colorless, cubic crystals. Mp: 561'. Decomposes on heating. Very sol in H20 and EtOH; sol in MeOH and Me2CO; insol in Et20. SYNS: CALCIUM DINITRATE
0 CALCIUM NITRATE (DO?? 0 CALCIUM SALTPETER 0 NITRIC ACID, CALCIUM SALT (8C1,gCI) 0 NORGE SALTPETER 0 NORWAY SALTPETER 0 NORWEGUN SALTPETER 0 SYNFAT 1006
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: A poison by ingestion.
CAT650 CAS: 5001-51-4 HR: D CALCIUM LACTOBIONATE mf: C24H42Ca024 mw: 754.66 PROP: U k t e powder. Mp: 120' (decomp). Sol in water; insol in alc, ether.
An irritant. A strong oxidant. Forms powerfully explosive mixtures with aluminum + ammonium nitrate + formamide + water, ammonium nitrate + hydrocarbon oils, ammonium nitrate + water-soluble fuels, SYN: CALCIUM 4-(P-d-GALACTOSIDO)-d-GLUCONATEand organic materials. When heated to SAFETY PROFILE: When heated to decomposition it emits toxic fumes of NO,. decomposition it emits acrid smoke and See also NITRATES and CALCIUM irritating fumes. COMPOUNDS.
CAT750 CAS: 7789-82-4 HR: 3 CALCIUM MOLYBDATE mf: MoOpCa mw: 200.02 PROP: White crystals. An electrical conductor. Mp: 965' (decomp). Insol in H20. IDLH 1000 mg/m3 (as Mo).
CAU300 CAS: 142-17-6 HR: D CALCIUM OLEATE mf: C36H66Ca04 mW: 602.97 PROP: Pale yellow transparent solid.
SYNS: CALCIUM MOLYBDENUMOXIDE (Cahfo04) 0
SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes.
MOLYBDATE, CALCIUM 0 MOLYBDIC ACID (H2MoO4), CALCIUM SALT (1:l)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
SYNS: 9-OCTADECENOIC ACID CALCIUM SALT 0 OLEIC ACID CALCIUM SALT
CALCIUM PEROXIDE
CAUSOO CAS: 1305-78-8 HR: 3 CALCIUM OXIDE DOT: UN 1910 mf: CaO mw: 56.08 PROP: Cubic, colorless, white crystals. Mp: 2580', d: 3.37, bp: 2850'. Sol in water and glycerin; insol in alc. IDLH 25 mg/m3. SYNS: AIRLOCK 0 BELL CMLQ
0 BURNT LIME 0 CALCIA 0 CALOXOL CP2 0 CALOXOL W3 0 CALX 0 CALXYL 0 CML 21 0 CML 31 0 DESICAL P 0 LIME 0 LIME, BURNED 0 LIME, UNSLAKED (DOT,! 0 OXYDE de CALCIUM (FRENCH) 0 QUICKLIME (DO?) 0 RHENOSORB C 0 RHENOSORB F 0 WAPNIOWY TLENEK (POLISH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 mg/m3 ACGIH TLV: TWA 2 mg/m3 DFG MAK: 5 mg/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A caustic and irritating material. See also CALCIUM COMPOUNDS. A common air contaminant. A powerful caustic to living tissue. The powdered oxide may react explosively with water. Mixtures with ethanol may igmte if heated and thus can cause an air-vapor explosion. Violent reaction with (I3203 + CaC12) interhalogens (e.g., BF3, CIF3), Fz, HF, P205 + heat, water. Incandescent reaction with liquid HF. Incompatible with phosphoms(V) oxide.
CAU750 CAS: 137-08-6 HR: 2 CALCIUM-d-PANTOTHEN ATE mf: C19H34N201o*Ca mw: 490.63 PROP: m t e , sltly hygroscopic powder; odorless; bitter taste; crystals from MeOH. Mp: 195-196' (decomp). Sol in water and glycerin; insol in alc, chloroform, and ether. SYNS: CALCIUM d(+)-N-(a,r-DIHYDROX-~,PD1METHYLBUTYRYL)-P-ALANINATE 0 CALCIUM PANTHOTHENATE (FCC) 0 CALCIUM PANTOTHENATE 0 d-CALCIUM PANTOTHENATE 0 CALPANATE 0 DEXTRO CALCIUM PANTOTHENATE 0 N-(2,4-
DIHYDROXY-3,3-DIMETHYLBL!TYRYL-P-ALANINE CALCIUM 0 PANCAL 0 PANTHOJECT 0 PANTHOLIN 0 PANTOTHENATE CALCIUM 0 PANTOTHENIC ACID, CALCIUM SALT 0 (+)-PAJTOTHENIC ACID, CALCIUM SALT 0 VITAMIN B-5
CAV500 271
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by intraperitoneal, subcutaneous, and intravenous routes. Mildly toxic by ingestion. A vitamin. See also CALCIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of NO,.
CAV250 CAS: 10118-76-0 HR: 3 CALCIUM PERMANGANATE DOT: UN 1456 mf: MnaOs*Ca mw: 277.96 PROP: Violet, deliquescent crystals. Mp: decomp, d: 2.4. SYNS: ACERDOL
0 KALIUMPERMANGANAT
(GERMAPU') 0 PERIUNGANIC ACID(HMn04), CALCIUM SALT (8CI,9CI)
CONSENSUS REPORTS: Manganese and its compounds are on the Community Right-To-Know List. OSHA PEL: CL 5 mg(Mn)/m3 ACGIH TLV: TWA 0.03 mg(Mn)/m3 DOT CLASSIFICATION: 5.1; Label: Oxidlzer SAFETY PROFILE: Poison by intravenous route. See also CALCIUM COMPOUNDS, MANGANESE COMPOUNDS, and PERMANGANATES. A strong oxidant. May explode on contact with acetic acid or acetic anhydride. Ignites on contact with cellulose. Incompatible with hydrogen peroxide.
CAV500 CAS: 1305-79-9 HR: 3 CALCIUM PEROXIDE DOT: UN 1457 mf: CaOz mw: 72.08 PROP: Yellow crystals or powder or white crystals, decomposes in air.Mp: decomp @ 275'. Insol in water; sol in acids, forming hydrogen peroxide. SYNS: CALCIUM DIOXIDE 0 CALCIUM SUPEROXIDE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: Irritating in
concentrated form. Will react with moisture to form slaked lime. Flammable if hot and
E
272
CAW700
CALCIUM PHOSPHATE, DlBASlC
mixed with finely dwided combustible material. Mixtures with oxiduable materials can also be ignited by grinding and are explosion hazards. A strong alkali. An oxidizer. Mixtures with polysulfide polymers may ignite. See also CALCIUM COMPOUNDS, CALCIUM HYDROXIDE, and PEROXIDES, INORGANIC.
SAFETY PROFILE: Moderately toxic by ingestion. When heated to decomposition it
CAW100 CAS: 7757-93-9 HR: 1 CALCIUM PHOSPHATE. DlBASlC mf: CaHP04*2H20 mw: 172.09 PROP: White powder or crystals. Sol in ddute acid; insol in water, alc.
SYNS: CALCIUM RESINATE (UN 1313) (DOT) 0 CALCIUM RESINATE, fused (UN 1314) (DOV 0 LIMED ROSIN 0 RESIN ACIDS and ROSIN ACIDS, CALCIUM SALTS 0 URAPRINT 62-126
SYN: DICALCIUM PHOSPHATE SAFETY PROFILE: Skin and eye irritant. A
nuisance dust.
CAW250 CAS: 1305-99-3 HR: 3 CALCIUM PHOSPHIDE DOT: UN 1360 mf: Ca3P2 mw: 182.18 PROP: Red-brown crystals. Mp: >1600°, d: 2.238 @ 25". Insol in EtOH, Et20, and C6H6. SYNS: CALCIUM PHOTOPHOR PHOTOPHOR CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 4.3; Label: Dangerous When Wet, Poison SAFETY PROFILE: Highly toxic due to phosphde, which in presence of moisture emits phosphine. The phosphine may ignite spontaneously in air. Incandescent reaction with oxygen at 300°C. Incompatible with dichlorine oxide. When heated to decomposition it emits toxic fumes of PO,. See also CALCIUM COMPOUNDS and PHOSPHIDES.
CAW400 CAS: 4075-81-4 HR: 2 CALCIUM PROPIONATE mf: C6HloCa04 mw: 186.22 PROP: White crystals; faint odor of propionic acid. Sol in water. SYNS: BIOBAN-C 0 CALCIUM DIPROPIONATE CALCIUM PROPIONATE 0 PROPANOIC ACID, CALCIUM SALT (9Cg
0
emits acrid smoke and irritating fumes.
CAW500 CAS: 9007-13-0 HR: 2 CALCIUM RESINATE DOT: UN 1313/UN 1314 mf: Ca(C&6204)2 mw: 1349.50 PROP: Yellowish-whte, amorphous powder or lumps.
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 4.1; Label:
Flammable Solid SAFETY PROFILE: Flammable solid when heated; can react with oxidzing materials. When heated to decomposition it emits acrid smoke and fumes. See also CALCIUM COMPOUNDS.
CAW525 HI?: D CALCIUM RICINOLEATE SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. CAW850 CAS: 1344-95-2 HR: 1 CALCIUM SILICATE PROP: Varying proportions of CaO and Si02. White powder. Insol in water. SYNS: CALCIUM HYDROSILICATE 0 CALCIUM MONOSILICATE 0 CALCIUM POLYSILICATE 0 CALCIUM SILICATE, synthetic nonfibrous (ACGIH) I3 CALFLO E 0 CALSIL 0 CS LAFARGE 0 FLORITE R 0 iMARIhlET 45 0 MICROCAL 160 0 MICROCAL ET 0 MICRO-CEL 0 MICRO-CEL A 0 MICRO-CEL B 0 MICRO-CEL C 0 MICRO-CEL E 0 MICRO-CEL T 0 MICRO-CEL T26 0 MICRO-CEL T38 0 MICRO-CEL T41 0 PROMAXON P60 SILENE E F 0 SILMOS T 0 SOLEX STABINEX NW 7PS 0 STARLEX L 0 SW 400 0 TOYOFINE A OSHA PEL: Total Dust: 15 mg/m3;
Respirable Fraction: 5 mg/m3 ACGIH TLV: TWA (nuisance particulate) 10 mg/m3 of total dust (when toxic impurities
CALCIUM SULFATE
are not present, e.g., quartz <1%); Not Classifiable as a Human Carcinogen SAFETY PROFILE: A nuisance dust. CAX250 CAS: 16925-39-6 HR: 3 CALCIUM SlLlCOFLUORlDE mf: CaFsSi mw: 182.17 PROP: Whtte, crystalline powder. Hydrolyzes in HzO forming complex mixtures of products. Decomp on heating with formation of CaF2 and SiF4 at 225'. Sltly sol in EtOH. SYNS: CALCIUM FLUOROSILICATF. 0 CALCIUM FLUOSILICATE 0 CALCIUM HEXAFLUOROSILICATE 0 SILICATE(2-), HEXAFLUORO-, CALCIUM (1:1) (9CI) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift. NIOSH REL: (Inorganic Fluorides) TWA 2.5 mgO/m3 DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by ingestion and subcutaneous routes. See also CALCIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of F-. CAX260 CAS: 23209-59-8 HR: 3 CALCIUM SODIUM METAPHOSPHATE mf: H03P*Ca*Na mw: 143.05 SYN: METAPHOSPHORIC ACID, CALCIUM SODIUM SALT
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of PO,.
CAX275 CALCIUM SORBATE PROP: Solid. Sltly sol in water.
HR: D
CAXSOO 273
SAFETY PROFILE: When heated to
decomposition it emits acrid smoke and irritating fumes. CAX350 CAS: 1592-23-0 HR: 1 CALCIUM STEARATE PROP: Variable proportions of calcium stearate and calcium palmitate. Fine whte powder; slt characteristic odor. Insol in water, alc, ether. SYNS: AQUACAL
CALCIUM DISTEARATE 0 CALSTAR 0 FLEXICHEM 0 FLEXICHEM CS 0 G 339 S 0 NOPCOTE C 104 0 OCTADECANOIC ACID, CALCIUM SALT 0 STAVINOR 30 0 SYNPRO STEARATE 0 W T C O G 339s
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 10 mg/m3, total dust SAFETY PROFILE: A nuisance dust. When heated to decomposition it emits acrid smoke and irritating fumes.
CAXSOO CAS: 7778-18-9 HR: 1 CALCIUM SULFATE mf: CaS04 mw: 136.14 PROP: Pure anhydrous, colorless or white powder or odorless crystals. D: 2.964, mp: 1570'. Dissolves in acids. Sltly sol in HzO. SYNS: ANHYDROUS CALCIUM SULFATE 0 CRYSALBA 0 DRIERITE 0 GIBS 0 PLASTER of PARIS 0 THIOLITE OSHA PEL: Total Dust: 15 mg/m3; Respirable Fraction: 5 mg/m3 ACGlH TLV: TWA (nuisance particulate) 10 mg/m3 of total dust (when toxic impurities are not present, e.g., quartz <1%) DFG MAK: 6 mg/m3 SAFETY PROFILE: A nuisance dust. Reacts violently with aluminum when heated. Mixtures with diazomethane react exothermically and eventually explode. Mixtures with phosphorus ignite at high temperatures. When heated to decomposition it emits toxic fumes of SO,, See also CALCIUM COMPOUNDS and SULFATES.
E
274 CAX750 CALCIUM(I1) SULFATE DIHYDRATE (1:1:2) CAX750 CAS: 10101-41-4 HR: 1 CALCIUM(I1) SULFATE DIHYDRATE (1 :1:2) mf: O&*Ca*2Hz0 mw: 172.18 PROP: Colorless, monoclinic, hygroscopic crystals. D: 2.32, mp: 128O, bp: 163'. Sltly sol in water. SYNS: ALABASTER 0 ANNALINE 0 C.I. 77231 0 C.I. PIGMENT WHITE 25 0 GYPSUM 0 GYPSUM STONE 0 LAND PLASTER 0 LIGHT SPAR 0 MAGNESIA WHITE 0 MINERAL WHITE 0 NATIVE CALCIUM SULFATE 0 PRECIPITATED CALCIUM SULFATE 0 SATINITE 0 SATIN SPAR 0 SULFURIC ACID, CALCIUM(2+) SALT, DIHYDRATE 0 TERRA ALBA
OSHA PEL: Total Dust: 15 mg/m3;
Respirable Fraction: 5 mg/m3 ACGIH TLV: TWA (nuisance particulate) 10 mg/m3 of total dust (when toxic impurities are not present, e.g., quartz <1%) SAFETY PROFILE: Human systemic effects by inhalation: fibrosing alveolitis ('growth of fibrous tissue in the lung), unspecified respiratory system effects, and unspecified effects on the nose. Questionable carcinogen with experimental carcinogenic data. Long considered a nuisance dust (dependmg on silica content). When heated to decomposition it emits toxic fumes of SO,. See also CALCIUM SULFATE, CALCIUM COMPOUNDS, and SULFATES. CAY250 CAS: 2092-16-2 HR: 3 CALCIUM THIOCYANATE mf: CzNzS2*Ca mw: 156.24 PROP: m t e , deliquescent crystals. Very sol in Hz0; sol in MeOH and EtOH. SYNS: CALCIUhf DITHIOCYANATE 0 CALCIUM RHODANID (GERMAN) 0 CALCIUMRHODANID 0 CALCIUM SULFOCYANATE 0 THIOCYAN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intravenous routes. See also THIOCYANATES and CALCIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of NO, and SO,.
CAY500 CAS: 12111-24-9 HR: 2 CALCIUM TRISODIUM DIETHYLENE TRIAMINE PENTAAC ETATE mf: C14H1aN301pCaNa3 mw: 497.40 SYNS: Ba 2797 0 CALCIUM CHEL-330 0 CALCIUMDTPA 0 CALCIUM TRISODIUM CHEL 330 0 CALCIUM TRISODIUM DTPA 0 CALCIUM TRISODIUM PENTETATE 0 CALCIUM TIUSODIUM SALT of DIETHYLENETRZARfINEPENTAACETIC ACID 0 DIETHYLENETWMINE PENTAKETIC ACID, CALCIUM TRISODIUM SALT 0 DITRIPENTAT 0 DTPA CALCIUM TRISODIUM SALT 0 PENTACIN 0 PENTACINE 0 PENTETATE TRISODIUM CALCICM 0 PENTHAMIL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by intravenous and intraperitoneal routes. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NazO and NO,. See also CALCIUM COMPOUNDS.
CAY710 CAS: 68955-53-3 HR: 3 C12-14-tert-ALKYL AMINES SYN: PRIMENE 81-R SAFETY PROFILE: A poison by ingestion. Moderately toxic by skin contact. Low toxicity by inhalation. A severe skin irritant. When heated to decomposition it emits toxic vapors of NO,. CAY950 CAS: 8065-83-6 HR: 3 CALO-CLOR mf: ClzHgz*C12Hg mw: 743.57 ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 pg/g creatinine total inorganic mercury in urine preshift; 15 pg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skin) SAFETY PROFILE: Poison by ingestion. When heated to decomposition it emits toxic fumes of Hg and C1-. CBA5OO CAS: 79-92-5 CAMPHENE mfi CloH16 mw: 136.26
HR: 1
CANANGA OIL
CBCfOO 275
as a topical anti-infective and anti-itching agent. Flammable liquid when exposed to Mp: 50-51", bp: 159O, d: 0.842 @ 54'/4O, heat or flame; can react with oxidzingrefr index: 1.452 @ 55'. Sol in alc; misc in materials. Vapor is explosive when exposed fured oils; ins01 in water. SYNS: BICYCLO(2.2.1)HEPTANE,2,2-DIMETHYL-3- to heat or flame or CrO3. To fight fire, use METHYLENE-(9CI) 0 FEMA No. 2229 foam, carbon &oxide, dry chemical. See CONSENSUS REPORTS: Reported in EPA also KETONES and other camphor TSCA Inventory. entries. SAFETY PROFILE: Mutation data reported. Combustible; yields flammable vapors when CBBSOO CAS: 8008-51-3 HR: 3 heated and can react with oxidizing CAMPHOR OIL materials. To fight fire, use water spray, DOT: UN 1130 foam, fog, COz. When heated to PROP: Colorless or yellowish, oily, fragrant decomposition it emits acrid smoke and liquid. Bp: 175-200°, flash p: 117'F (CC), d: irritating fumes. 0.875-0.900 @ 2Oo/2O0. Insol in water; sol in chloroform, ether, oils, and in approx 3 CBA750 CAS: 76-22-2 HR: 3 vols alc. Found in the trees and bark of CAMPHOR Cinnamomum carphora sieb (Fam. Luraceae) DOT: UN 2717 and prepared by fractional Qsullation of mf: C10H160 mw: 152.26 crude camphor oil after the camphor has PROP: White, transparent, crystalhe been crystahzed out; a wlute, viscous liquid masses; penetrating odor; pungent, aromatic with cineole as the principal ingrelent along taste. Mp: 180°, bp: 204O, lel: O.6%, uel: with monoterpenes (FCTXAV 11,1011,73). 3.5%, flash p: 150'F (CC), d: 0.992 @ SYNS CAMPHOR OIL, RECTIFIED 0 CAMPHOR OIL WHITE 0 CAMPHOR OIL YELLOW 0 FORMOSA 25'/4O, autoign temp: 871'F, vap d: 5.24. CAMPHOR OIL 0 FORMOSE OIL OF CAMPHOR 0 IDLH 200 mg/rnj. PROP: Colorless cubic crystals; oily odor.
SYNS: 2-BORNANONE 0 2-ChMPHANONE 0
JAPANESE CAMPHOR OIL 0 JAPANESE OIL OF CAMPHOR 0 LIGHT CAMPHOR OIL 0 LIGHT OIL OF CAMPHOR 0 LIQUID CAMPHOR 0 OIL CAMPHOR SASSAFMSSY 0 OIL OF CAMPHOR RECTIFIED 0 OIL OF CAMPHOR WHITE 0 WHITE CAhPHOR OIL 0 WHITE OIL OF CAMPHOR
CAMPHOR-natural 0 CAMPHOR, syntheuc (ACGIH,DOV 0 FORMOSA CAMPHOR 0 GUM CAMPHOR 0 HUILE de CAMPHRE (FRENCH) 0 JAPAN CAMPHOR 0 KAMPFER (GERMAN) 0 2-KETO-1,7,7-TRIMETHYLNORCAMPHANE 0 LAUREL CAMPHOR 0 MATRICARIA CAMPHOR CONSENSUS REPORTS: 0 2-OXOBORNAVE 0 1,7,7-TRIiMETHKBICYCLO(2.2.1)TSCA Inventory. 2-HEPTANONE 0 1,7,7-TRIMETHYLSJORCAMPHOR
Reported in EPA
CONSENSUS REPORTS: Reported in EPA
DOT CLASSIFICATION: 3; Label:
TSCA Inventory. OSHA PEL: TWA 2 mg/mj ACGIH TLV: TWA 2 ppm; STEL 3 ppm; Not Classifiable as a Human Carcinogen DFG MAK: 2 ppm (13 mg/m3) DOT CLASSIFICATION: 4.2; Label: Flammable Solid SAFETY PROFILE: A human poison by ingestion and possibly other routes. An experimental poison by inhalation, subcutaneous, and intraperitoneal routes. A local irritant. Ingestion causes nausea, vomiting, dizziness, excitation, and convulsions. Mutation data reported. Used
Flammable Liquid SAFETY PROFILE: A human poison by
ingestion. Human systemic effects by ingestion: convulsions, tremors, and unspecified respiratory system effects. A skin irritant. Flammable liquid when exposed to heat or flame; can react with oxidzing materials. To fight fire, use foam, COz, dry chemical, mist, fog. See also SAFROL and CAMPHOR.
E
276
CBClOO CANANGA OIL
CBC100 HR: D CANANGA OIL PROP: From flowers of the tree Cunungu odorutu f. et Thorns., (Fam. Anonaceae). Yellow liquid; harsh floral odor. Sol in fixed oils, mineral oil; insol in glycerin, propylene glycol. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. CBC400 HR: D CANDIDA LIPOLYTICA PROP: Derived from Cundidu ii)o&icu Fam. Cryptococcaceae. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. CBE800 CAS: 514-78-3 HR: D CANTHAXANTHIN mf: C40H5202 mw: 564.80 PROP: Purple or dark crystalline powder. Mp: 218'. Sol in chloroform; very sltly sol in acetone; insol in water. SYNS: CANTHA 0
P-CAROTENE-4,4'-DIONE0 4,4'DIKETO-P-CAROTENE
SAFETY PROFILE: When heated to
decomposition it emits acrid smoke and irritating fumes.
CBF250 CAS: 302-22-7 HR: 3 CAP mf: Cz3H~C104 mw: 404.97 PROP: Crystals from MezCO/EtzO. Mp: 21 1-212O.
ACETOXYPROGESTERONE0 6-CHLORO-6-
DEHYDRO-17-a-ACETOXTiPROGESTERONE 0 6CHLORO-6-DEHYDRO-17-a-HYDROXYPROGESTERONE ACETATE 0 6-CHLORO-17-a-HYDROXYPREGNA4,6-DIENE-3,20-DIONEACETATE 0 6-CHLORO-17-aHYDROXY-A~-PROGESTERONE ACETATE CHLOROMADINONE ACETATE 0 6-CHLORO-A4,6-
PREGNADIENE-l7-a-OL3,20-DIONE-17-ACETATE 0 6CHLORO-PREGNA-4,6-DIEN-l7-a-OL-3,20-DIONE ACETATE 0 CLORDION 0 ClMrl 0 C-QUENS 0 6DEHYDRO-6-CHLORO-17-aACETOXYPROGESTERONE 0 LORMIN 0 LUTINYL, 0 NSC-92338 0 RS 1280 0 SKEDULE 0 ST 155
CONSENSUS REPORTS: IARC Cancer Review: Animal Limited Evidence IMEMDT 21,365,79; Animal Sufficient Evidence IMEMDT 6,149,74. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. Moderately toxic by intraperitoneal route. Human maternal and reproductive effects by ingestion, intramuscular, and possibly other routes: ovary, uterus, cervix, vagina, and fallopian tube changes; menstrual cycle changes or disorders; changes in ferthty; and other unspecified female effects. A human teratogen that causes developmental abnormalities of the endocrine system in the fetus. Experimental teratogenic and reproductive effects. An oral contraceptive. When heated to decomposition it emits toxic fumes of C1-.
CBF550 CAS: 485-50-7 I-CAPNOIDINE mf: CzoH17N06 mw: 367.38
HR: 3
SYNS: 17-ACETOXY-6-CHLOR0-6-DEHYDROG- SYNS: (-)-ADLUMIDINE
ESTERONE 0 17-a-ACETOXY-6-CHLORO-6DEHYDROPROGESTERONE 0 17-a-ACETOXY-6CHLORO-6,7-DEHYDROPROGESTERONE 0 17-a-
0 I-ADLUMIDINE 0 CAPNOIDINE 0 (-)-CAPNOIDINE 0 FUR0(3,4-E)-1,3BENZODIOXOL-8(6H)-ONE,6-(5,6,7,8-TETRAHYDRO-6METHYL-1,3-DIOXOL0(4,5-G) ISOQUINOLIN-5-YL.-,(R(R*,R*))-
ACETOXY-6-CHLOROPREGNA-4,6-DIENE-3,2O-DIONE SAFETY PROFILE: A poison by 0 17-a-ACETOXY-6-CHLOR0-4,6-PREGNADIENE-3,20intravenous route. When heated to DIONE 0 17-(ACETYLOXY)-6-CHLOROPREGNA-4,6-
decomposition it emits toxic vapors of NO,. DIENE-3,20-DIONE 0 CHLOILMADINON ACETATE 0 CHLORMADINONEACETATE 0 C H L O R W I N O N U (POLISH) 0 6-CHLORO-17-a-ACETOXY-4,6-PREGNDICBF700 CAS: 105-60-2 HR: 2 ENE-3,20-DIOiVE 0 A6-6-CHLORO-17-a-ACETOXYPROGESTERONE 0 6-CHLORO-A6-17-ACETOXYPROGESTERONE 0 6-CHLORO-A6-(17-a)ACETOXYPROGESTERONE 0 6-CHLORO-A6-DEHYDRO-17-
CAPROLACTAM mf: CGHIINO mw: 113.18
CAPTAN PROP: White crystals or leaflets from ligroin. Mp: 69', bp: 139' @ 12 mm, vap press: 6 mm @ 120'. SYNS: AMINOCAPROIC LACTAM 0 6-AMINOHEXANOIC ACID CYCLIC LACTAM 0 2-AZACYCLOHEPTANONE 0 6-CAPROLACTAM 0 (0-CAPROLACTAM (MAK) 0 CAPROUTTAME (FRENCH) 0 CYCLOHEXANONE ISO-OXIME 0 EPSYLON KAPROLAKTAM (POLISH) 0 HEXAHYDRO-2-AZEPINONE 0 HEXAHYDRO-2HAZEPIN-2-ONE 0 6-HEXANELACTAM 0 HEXANONE ISOXIME 0 HEXANONISOXIM (GERMAN) 0 1,6HEXOLACTAM 0 e-KAPROUKTAM (CZECH) 0 2KETOHEWfETHYLENIMINE 0 NCI-C50646 0 2OXOHEXAMETHYLENIMINE 0 2-PERHYDROAZEPINONE CONSENSUS REPORTS: IARC Cancer
Review: Group 4 IMEMDT 7,56,87; Animal No Evidence IMEMDT 39,247,86. NCI Carcinogenesis Studies (feed); No Evidence: mouse, rat NTPTR* NTP-TR-214,82. Reported in EPA TSCA Inventory. OSHA PEL: Dust: 1 mg/m3; STEL 3 mg/m3; Vapor: 5 ppm; STEL 10 ppm ACGIH TLV: TWA (aerosol and vapor) 5 mg/m3; Not Suspected as a Human Carcinogen DFG MAK: 5 mg/m3 NlOSH REL: (Caprolactam, dust) TWA 1 mg/m3; STEL 3 mg/m3; (Caprolactam, vapor) TWA 0.22 ppm; STEL 0.66 ppm SAFETY PROFILE: Moderately toxic by ingestion, skin contact, intraperitoneal, and subcutaneous routes. Human systemic effects by inhalation: nose and throat irritation, cough. Experimental reproductive effects. A skin and eye irritant. Potentially explosive reaction with acetic acid + dinitrogen trioxide. When heated to decomposition it emits toxic fumes of NO,.
CBF760 CAS: 465-42-9 CAPSANTHIN mf: C40H5603 mw: 584.88
HR: 3
SYN P,KAPPA-CAROTES-G'-ONE, 3,3'-DIHYDROXY-, (3R,3'S,5'R)SAFETY PROFILE: A poison by s h n contact. When heated to decomposition it emits acrid smoke and irritating vapors.
CBGOOO 277
CBF800 CAS: 2425-06-1 HR: 3 CAPTAFOL mf: C I O H ~ C ~ ~ N O Z S mw: 349.06 PROP: Crystals. Mp: 160-161'. SYNS: CAPTOFOL 0 DIFOLATAN 0 DIFOSAN 0 FOLCID 0 ORTHO 5865 0 SANSPOR 0 SULFONIiMIDE 0 SULPHEIMIDE 0 N-(l,l,2,2TETRACHLORA-ETHYLTHIO)CYCLOHEX-4-EN-l,4DIACARBOXIMID (GERhfiV) 0 N-(I,l,2,2TETRACHLORAETHYLTHI0)TETRAHYDROPHTHALAMID (GERMAN) 0 N-l,1,2,2TETRACHLOROETHYLMERCAPTO-4-CYCLOHEXENE1,2-CARBOXIMIDE 0 N-((1,1,2,2-TETRACHLORO-
ETHYL)SULFENYL)-cis-4-CYCLOHEXENE-l,2DICARBOXIMIDE 0 N-(1,1,2,2-TETRACHLORO-
ETHYLTHIO)-4-CYCLOHEXENE-l,2-DICARBOXIMIDE
CONSENSUS REPORTS: IARC Cancer Review: Group 2A IMEMDT 53,353,91; Animal Sufficient Evidence IMEMDT 53,353,91; Human No Available Data IMEMDT 53,353,91. EPA Genetic Toxicology Program. OSHA PEL: TWA 0.1 mg/m3 ACGIH TLV: TWA 0.1 mg/m3; Not Classifiable as a Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. A fungicide. When heated to decomposition it emits very toxic fumes of C1-, NO,, and SO,.
CBGOOO CAS: 133-06-2 HR: 3 CAPTAN mf: C9HsCbNOzS mw: 300.59 PROP: Odorless crystals from cc14 or C6H6. Mp: 172-173', d: 1.745. Practically insol in water; sol in benzene, alcohol, and chloroform. SYNS: AACAPTAN
0 AGROSOL S 0 AGROX 2-WAY
and 3-WAY 0 AMERCIDE 0 BANGTOS 0 BEAN SEED
PROTECTANT 0 CAPT'4F 0 CAPTAVCAPTENEET 26,538 0 CAPTANE 0 CAPTA"STREPTOMYC1N 7.5-0.1 POTATO SEED PIECE PROTECTAXT 0 CAPTEX 0 ENT 26,538 0 ESSO FUNGICIDE 406 0 FLIT 406 0 FUNGUS BAN TYPE I1 0 GLYODEX 3722 0 GRA?JOX PPM 0 GUSTAFSON CAPTAN 30-DD 0 HEXACAP 0 KAPTAN 0 LE CAPTANE (FRENCH) 0 MALIPUR 0 MERPAN 0 MICRO-CHECK 12 0 NCI-COO077 0 NERACID 0 ORTHOCIDE 0 OSOCIDE 0 SR406 0
278
CBG125 CARAMEL
STAUFFER CAFTAN 0 3a,4,7,7a-TETRAHYDRO-N-
CONSENSUS REPORTS: Reported in EPA
(TRICHLOR0hlETHANESULPHENYL)PHTHALIMlDE 0 TSCA Inventory. 3a,4,7,7a-TETRAHYDRO-2-((TRICHLOROMETHYL)THIO)SAFETY PROFILE: Mutation data reported. lH-ISOINDOLE-l,3(2H)-DIONE 0 1,2,3,6-TETRAHYDROWhen heated to decomposition it emits N-(TRICHLOROMETHYLTHI0)l’HTHALIMIDE0 N(lXICHLOR-METHYLTHIO)-PHTHALlMID (GERMAN) O N-TRICHLOROMETHYLMERCAIYTO-4-CYCLOHEXENE1,2-DICARBOXIMIDE 0 N-(TRICHLOROMETHYL-
acrid smoke and irritating fumes. CBGSOO
CAS: 8000-42-8
HR: 2
MERCAPTO)-A4-TETRAHYDROI’HTH4LIiZ.IIDE 0 NCARAWAY OIL TRICHLOROMETHYLTHIOCYCLOHEX-4-ENE-l,2DICARBOXIMIDE 0 N-TRICHLOROMETHYLTHIO-cis- PROP: The main constituent of caraway oil is 1-carvone; found in the fruits of Camm A4-CYCLOHEXENE-l,2-DICARBOXIMIDE 0 N((TRICHLOROMETHYL)THlO)-4-CYCLOHEXENE-1,2- carvi L (Fam. Umbell@rae) (FCTXAV DICARBOXIMIDE 0 TRICHLOROMETHYLTHOO-1,2,5,6TETRAHYDROPHTHALAMIDE 0 N-((TRICHLOROMETHYL)THIO)TETRAHYDROPHTHALIMIDE 0 N-
11,1011,73). Colorless liquid; odor and taste of caraway.
SYNS: KUEMMEL OIL (GERMAN) 0 OIL OF TRICHLOROhlETHYLTHIO-3A,4,7,7A-TETRAHYDROl’HTHALMIDE 0 VANCIDE 89 0 VANGARD K 0 VANICIDE 0 VONDCAPTAN
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Lmited Evidence IMEMDT 30,295,83. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse NCITR* NCI-CG-TR15,77; No Evidence: rat NCITR* NCI-CGTR-15,77. EPA Genetic Toxicology Program. Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 mg/m3 ACGIH TLV: TWA 5 mg/m3 (Sensitizer); Confirmed Animal Carcinogen with Unknown Revelance to Humans SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic to humans by ingestion. Moderately toxic experimentally by ingestion and inhalation routes. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental tumorigenic and neoplastigenic data. Human mutation data reported. When heated to decomposition it emits toxic fumes of C1-, SO,, and NO,. CBG125 CAS: 8028-89-5 HR: D CARAMEL PROP: Dark-brown to black liquid or solid; burnt-sugar odor, pleasant bitter taste. Sol in water (colloidal). SYN: CARAMEL COLOR
CARAWAY
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and skin contact. A skm irritant. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also 1(-)-CARVONE.
CBH750 HR: 3 CARBAMATES PROP: Compounds based upon carbamic acid, N H L O O H . Used only in the form of its numerous salts and derivatives. SAFETY PROFILE: Many carbamates are poisons or moderately toxic, and some are carcinogenic, teratogenic, or mutagenic. They are used as insecticides, fungicides, herbicides, and as accelerators in the vulcanization of rubber. There is little data on persistence or breakdown in the environment. The N-alkylcarbamates and thiocarbamates can react with nitrite under mildly acid conditions to form N-nitroso compounds. Nitrite is found in soils, in human saliva, and in cured meats. N-nitrosodimethylamine is formed by soil microorganisms from thiram. Other N-nitroso compounds could similarly be formed from other carbamate pesticides. However, the extent of the reaction of carbamates and nitrite in humans is not known. The N-nitrosodialkylamines formed from dalkylthiocarbamate pesticides and
N-(CAR6AMOYLMETHYL)ARSANILIC ACID
nitrite are potent animal carcinogens and mutagens. The N-nitroso derivatives of several N-alkylcarbamates produce cancers in experimental animals at small doses. Carbaryl, semicarbazide hydrochloride, npropyl carbamate, Maneb, Zineb, Ferbam, and Thiram are experimental teratogens. Many of the carbamates have central nervous system effects. Carbaryl and Zectran are acetylcholinesterase inhbitors. Ethylenethiourea, which produces thyroid carcinomas in rats and liver cell tumors in mice by ingestion, is formed from ethylenebisdithocarbamates such as Maneb and Zineb by metabolic processes and cookmg. See also individual compounds, NITROSAMINES, and N-NITROSO COMPOUNDS.
CBJ750 279
CBJOOO CAS: 121-59-5 HR: 3 N-CARBAMOYLARSANlLlC ACID mf: C7HgAsNz04 mw: 260.10 PROP: m t e , nearly odorless powder or needles from water. Sltly acid taste. Mp: 174'. Sltly sol in cold HzO and org solvs; sol in hot HzO. SYNS: AiMABEVAN AMEBAN 0 ARIEBARSONE 0 AMIBIARSON 0 AMINARSON 0 AMINARSONE 0 AMINOARSON (4-((AMINOCARBObXL)AMINO)PHENYL)ARSONIC ACID 0 ARStLMBIDE 0 pARSONOPHENYLUREA 0 p-CARBAMIDOBENZENEARSONIC ACID 0 CARBAMINOPHENYL-p-ARSONIC ACID 0 p-CARBAMINO PHENYL ARSONIC ACID 0 4CARBAMYTAMINOPHENYRSONIC ACID 0 NCARBAMYL ARSANILIC ACID U CARBARSONE WSDA) 0 CARBASONE 0 FENARSONE 0 HISTOCARB 0 LEUCARSONE 0 p-UREIDOBENZENEARSONIC ACID 0 4-UREIDO-1-PHENYLARSONIC ACID
CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightT o - h o w List. CB1250 CAS: 120-02-5 HR: 3 OSHA PEL: TWA 0.5 mg(As)/m3 4-CARBAMIDOPHENYL BIS(CARB0XY- ACGIH TLV: BEI: 35 1 (As)/L inorganic METHYLTHI0)ARSENITE arsenic and methylated metabolites in urine mf: C I I H I ~ A S N ~ O & mw: 392.30 SAFETY PROFILE: Poison by ingestion. SYNS: 2,2'-((4Moderately toxic by intraperitoneal route. ((Ah1ISOCARBONYL.)AMINO)PHENYL.)ARSINIDENE)BI Questionable carcinogen with experimental S(THI0)BISACETIC ACID 0 BIS(CARB0XYLMETHYLhIERCAPTO)@-UREID0PHENYL)ARSINE 0 tumorigenic data. See also ARSENIC BIS(CARBOXYMETHYLTHIO)@-UREID0PHENYL)COMPOUNDS. When heated to ARSINE 0 @-CARBAhlOYLAMIN0)PHENYLARSINOdecomposition it emits very toxic fumes of BIS(2-THIO-ACETIC ACID) CC 914 0 C.C. No. 914 0 As and NO,. MERCAPTOACETIC ACID, DIESTER with DITHIO-pUREIDOBENZENEARSONOUS ACID 0 PHENYL UREAp-DI(CARB0XYMETHYL) THIOAFSENITE 0 THIOCARBARSONE 0 @UREIDOPHENYIARSYLENEDITHI0)DIACETICACID
CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(As)/m3 ACGIH TLV: BEI: 35 1 (As)/L inorganic arsenic and methylated metabolites in urine SAFETY PROFILE: Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion. See also ARSENIC COMPOUNDS, MERCAPTANS, and ESTERS. When heated to decomposition it emits very toxic fumes of As and SO,.
CBJ750 CAS: 618-25-7 HR: 3 N-(CARBAM0YLMETHYL)ARSANlLlC ACID mf: C ~ H I I A S N ~ O ~mw: 274.13 PROP: White, crystalline powder. SYNS: (4-((2-AMINO-2-OXOETHYL)AMINO)PHENYL)ARSONIC ACID 0 4-ARSONOPHENYLGLYCINAMIDE 0 ~-((CARBAI'VOYLMETHYL)AMINO)BENZENEARSONIC ACID 0 SODIURI-N-PHENYLGLYCINAVIDE-p-ARSONATE 0 TRYPARSAMIDE
CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(As)/m3 ACGlH TLV: BEI: 35 (As)/L inorganic arsenic and methylated metabolites in urine
280
CBMOOO
CARBANlLlC ACID ISOPROPYL ESTER
SAFETY PROFILE: Poison by ingestion and
intramuscular route. Moderately toxic by intravenous route. See also ARSENIC COMPOUNDS. When heated to decomposition it emits very toxic fumes of As and NO,. CBMOOO CASE122-42-9 HR: 3 CARBANILIC ACID ISOPROPYL ESTER mf: CloH13N02 mw: 179.24 PROP: A whte, crystalhe solid; sol in acetone and benzene. Mp: 90". SYNS: BAN-HOE 0 BEET-KLEEN 0 CHEM-HOE 0 IFC 0 IPPC 0 ISOPROPIL-N-FENIL-CARBAMMATO (ITALIAN) 0 ISOPROPYL CARBANILATE 0 ISOPROPYL CARBANILIC ACID ESTER 0 ISOPROPYL-N-FENYLCARBAhLUT (DUTCH) 0 ISOPROPYL-N-PHENYLCARBkLMT (GERMAN) 0 ISOPROPYL PHENYLCARBAMATE 0 ISOPROPYLN-PHENYLCARBAMATE 0 o-ISOPROPYL-N-PHENYL CARBAMATE 0 ISOPROPYLN-PHENYLURETHAX ( G E W V ) 0 ORTHO GRASS KILLER 0 N-PHENYLCARBAMATE d'ISOPROPYLE (FRENCH) 0 PHENYLCARBAMIC ACID-I-METHYLETHYL ESTER 0 N-PHENYL ISOPROPYL CARBAMATE 0 PRELMALOX0 PROFAM 0 PROPHAM 0 TRIHERBIDE 0 TRIHERBIDE-IPC 0 TUBERIT 0 TUBERITE 0 USAF D-9OY2
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 12,189,76. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic to humans by ingestion. Moderately toxic experimentally by ingestion and possibly other routes. An experimental teratogen. Human mutation data reported. Questionable carcinogen with experimental neoplastigenic data. An herbicide. When heated to decomposition it emits toxic fumes of NO,. See also CARBAMATES. CBM500 CAS: 116-06-3 HR: 3 CARBANOLATE mf: C ~ H M N ~ O ~ Smw: 190.29 PROP: A solid material or crystals. Mp: 98-100". Sltly sol in water. SYNS: ALDECARB 0 ALDICARB (USDA) 0 ALDICARBE (FRENCH) 0 AMBUSH 0 EXT 27,093 0 2-
METHYG2-(METHYLTHIO)PROPANAL-O-((METHYLAMIN0)CARBONYL)OXIME 0 2-METHYL2-(METHYL-
THI0)PROPIONALDEHYDE-0-(METHYLCARBAMOYLOXIME 0 2-METHYLZ-(METHYLTHIO)PROPIONALDEHYDE OXIME 0 2-METHYL-2-METHYLTHIO-
PROPIONALDEHYD-O-(N-METHYL-CARBAMOYL)OXIM (GERMAN) 0 2-METIL-2-TIOMETIL-PROPIONALDEID-0-(N-METIL-CARBATTOIL)-OSSIMA (ITALIAN) 0 NCI-C08640 0 OMS-771 0 RCRA WASTE NUMBER PO70 0 TEMIC 0 TEMIK 0 TEMIK G10 0 UC-21149
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 53,93,91; Animal Inadequate Evidence IMEMDT 53,93,91; Human No Available Data IMEMDT 53,93,91. NCI Carcinogenesis Bioassay (feed); N o Evidence: mouse, rat NCITR* NCI-CG-TR-136,79. Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. SAFETY PROFILE: Deadly poison by ingestion, skin contact, subcutaneous, and possibly other routes. Human mutation data reported. Questionable carcinogen. A powerful systemic poison. In 1985 over 150 people in California exhibited toxic effects from eating watermelons contaminated with aldicarb. When heated to decomposition it emits very toxic fumes of NO, and SO,.
CBM750 CASE63-25-2 HR: 3 CARBARYL mf: C12HllN02 mw: 201.24 PROP: White crystals. Mp: 142", d: 1.232 @ 2Oo/2O0. IDLH 100 mg/m3. SYNS: ARILAT 0 ARILATE 0 ARYLAM 0 ATOXAN 0 BERCEMA NMC50 0 BUG MASTER 0 CAPROLIN 0 CARBAMINE 0 CARBARYL (ACGIH,DOT,OSHA) 0 CARBATOX 0 CARBATOX-60 0 CARBATOX-75 0 CARBAWR 0 CARBOMATE 0 CARPOLIN 0 CARYLDERM 0 CEKUBARYL 0 COMPOUND 7744 0 CRAG SEWN 0 CRUNCH 0 DENAPON 0 DEVICARB 0 DICARBAM 0 DYNA-CARBYL 0 ENT 23,969 0 EXPERIMENTAL INSECTICIDE 7744 0 GAMONIL 0 GERMAIN'S 0 HEXAVIN 0 KARBARYL (POLISH) 0 KARBASPRAY 0 KARBATOX 0 KARBATOX 75 0 KARBATOX ZAWIESINOWY 0 KARBOSEP 0 LATKA 7744 0 MENAPHTAM 0 N-METHYLCARBAMATE de 1NAPHTYLE 0 METHYLCARBAMATE-1-NAPHTHALENOL 0 METHYLCARBAMATE-1-NAPHTHOL0 NMETHYLCARBAMATE de I-NAPHTYLE (FRENCH) O METHYLCARBAMIC ACID-1-NAPHTHYL ESTER 0 NMETHYL-1-NAFTYL-CARBAWT (DUTCH) O NMETHYL-1-NAPHTHYL-CARBAMAT (GERMAN) O N-
CARBENDAZIM and SODIUM NITRITE (5:l) CBN375 281 ~ ~ E T H Y L a - N A P H T H Y L C A R0AN-METHYL-1~~~ NAPHTHYL CARBAMATE 0 N-METHYI-a-NAPHTHYL URETHAN 0 N-METIL-1-NAFTILCARBAMMATO (ITALIAN) 0 MONSUR 0 MUGAN 0 MLJRVIN 0 NAC 0 1-NAFTYLESTERKYSELINY METHYLKARBAMINOVE 0 a-NAFNLN-METHYLKARBAMAT 0 I-NAPHTHALENEOL, METHYLCARBAtL4TE (XI) 0 a-NAPHTHALENYL METHYLCARBAMATE 0 I-NAPHTHALENE METHEZCARBhhWTE 0 1-NAPHTHOLN-METHYLCARBAMATE 0 a-NAPHTHYL METHYLCARBAMATE 0 a-NAPHTHYL N-METHYLCARBAiifATE 0 1-NAPHTHYL METHYLCARBAMATE 0 1-NAPHTHYL N-METHYLCARBAMATE 0 1-NAPHTHYLN-METHYLKhRBA~~T 0 NMC 50 0 OLTITOX 0 OMS-29 0 PANAhI 0 POMEX 0 PROSEVOR 85 0 RAWON 0 RYLAM 0 SAVIT 0 SEFFEIIS 0 SEPTENE 0 SEVIMOL 0 SEVIN 0 SEVIN 4 0 SEVIN (OSHA) 0 SEWN 0 SOK 0 TERCYL 0 TOXAN 0 TRICAILVAM 0 UC 7744 0 UNION CARBIDE 7,744 0 VETOX 0 VIOXAN
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 12,37,76. Community hght-To-Ihow List. OSHA PEL: TWA 5 mg/rn3 ACGIH TLV: TWA 5 mg/m3; Not Classifiable as a Human Carcinogen; (Proposed: 1 mg/m3; Sen; Confirmed Animal Carcinogen with Unknown Revelance to Humans DFG MAK: 5 mg/m3 NIOSH REL: (Carbaryl) TWA 5 mg/m3 SAFETY PROFILE: Poison by ingestion, intravenous, intraperitoneal, and possibly other routes. Human systemic effects by ingestion: sensory change involving peripheral nerves and muscle weakness. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Human mutation data reported. An eye and severe skin irritant. Absorbed by all routes, although skin absorption is slow. No accumulation in tissue. Symptoms include blurred vision, headache, stomachache, vomiting. Symptoms sirmlar to but less severe than those due to parathion. A reversible cholinesterase inhibitor. See also CARBAMATES and ESTERS. When heated to decomposition it emits toxic fumes of NO,.
CBNOOO CAS: 86-74-8 HR: 3 CARBAZOLE mf: C12HgN mw: 167.22 PROP: White crystals or plates from xylene. Mp: 244.8', bp: 354.7', d: 1.10 @ 18'/4O, vap press: 400 mm @ 323.0'. Sltly sol in most org s o h ; sol in hot EtOH. SYNS: 9-AZAFLUORENE 0 9H-CARBAZOLE 0 DIBENZOPYRROLE 0 DIBENZO@,d)PYRROLE0 DIPHENYLENEIMINE 0 DIPHENYLENIMIDE 0 DIPHENYIENIMINE 0 USAF EK-600
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 32,239,83. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Questionable carcinogen. Moderately toxic by ingestion. Mutation data reported. A pesticide. When heated to decomposition it emits toxic fumes of NO,.
CBN100 CAS: 86-72-6 HR: 1 4-(3-CARBAZOLYLAMINO)PHENOL mf: C18H14Nz0 mw: 274.34 SYNS: CARBAZOLE, 3-@-HYDROXYANILINO)-0 3-(4'HYDR0XYFENYL)AMINOKARBAZOL 0 PHENOL, 4-(3CARBAZOLYLAMIN0)-0 R-BASE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A slan and eye irritant. When heated to decomposition it emits toxic fumes of NO,.
CBN375 HR: 3 CARBENDAZIM and SODIUM NITRITE (5:l) SYNS: METHYL-2-BENZIMIDAZOLECARBAMATE and SODIUhf NITRITE 0 SODIUM NITRITE and CARBENDAZIM (1:5) 0 SODIUhl NITRITE and METHYL-2-BENZIMIDAZOLE CARBAMATE
SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. An experimental teratogen. When heated to decomposition it emits toxic fumes of Na2O and NO,. See also NITRITES and CARBAMATES.
E
282
C5Q750 CARBITOL ACETATE
CBQ750 CAS: 112-15-2 HR: 2 CARBITOL ACETATE mf: CsH1604 mw: 176.24 PROP: Liquid. Bp: 217.4", fp: -25", flash p: 230°F (OC), d: 1.0114 @ 2Oo/2O0, vap press: 0.05 mm @ 20°, vap d: 6.07. SYNS: DIETHYLENE GLYCOL MONOETHYL ETHER ACETATE 0 DIGLYCOL MONOETHYL ETHER ACETATE EKTASOLVE de ACETATE 0 2-(2ETHOXYETH0XY)ETHANOL ACETATE 0 GLYCOL ETHER de ACETATE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Glycol ether compounds are on the Community fight-To-Know List. SAFETY PROFILE: Moderately toxic by ingestion. A skin and eye irritant. See also GLYCOL ETHERS. Combustible when exposed to heat; can react with oxidizing materials. To fight fire, use alcohol foam, water, C02, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
CBROOO CAS: 111-90-0 HR: 2 CARBITOL CELLOSOLVE mf: C6H1403 mw: 134.20 PROP: Very hygroscopic, colorless liquid; mild pleasant odor. Bp: 201.9", flash p: 201°F (OC), d: 0.986 @ 25"/4", vap d: 4.62. MISCin water. SYNS: APV 0 CARBITOL 0 CARBITOL SOLVENT 0 DIETHYLENE GLYCOL ETHYL ETHER 0 DIETHYLENE GLYCOL MONOETHYL ETHER DIGLYCOL MONOETHYL ETHER 0 DIOXITOL 0 D O W m O L 0 DOWANOL D E 0 ETHOXY DIGLYCOL 0 2-(2-ETHOXYETHOXY)ETHANOL 0 ETHYL CARBITOL 0 ETHYL DIETHYLENE GLYCOL ETHYLENE DIGLYCOL MONOETHYL ETHER 0 LOSUNGSMITTEL APV 0 MONOETHYL ETHER of DIETHYLENE GLYCOL POLY-SOLV 0 SOLVOSOL
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Glycol ether compounds are on the Community Right-To-Know List. SAFETY PROFILE: Moderately toxic by ingestion, intravenous, intraperitoneal, and possibly other routes. W d l y toxic by shn contact. A s h n and eye irritant. Experimental reproductive effects. Mutation data reported. Combustible when exposed to heat; can react with oxidizing materials.
To fight fire, use alcohol foam, COs, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. CBR125 CAS: 1138-80-3 HR: 3 CARBOBENZOXYLGLYCINE mf: CloH11N04 mw: 209.22 PROP: A solid. Mp: 119-120". SYNS: BENZYLOXYCARBONYLGLYCINE 0 NBENZYLOXYCARBONYLGLYCINE O NCARBOBENZOYLGLYCINE O CARBOBENZOYL GLYCINE 0 CARBOBENZYLOXYGLYCINE 0 NCARBOBENZYLOXYGLYCINE O (CBZ)GLY O 2-GLY
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravagnal route. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of NO,. See also ESTERS.
CBR250 CAS: 1722-62-9 HR: 3 CARBOCAINE HYDROCHLORIDE mf: C1jH22N200ClH mw: 282.85 PROP: A solid. Mp: 262-264". Sol in H20. SYNS: CHLOROCAIN 0 N-(2,6-DIMETHYLPHENYL)-lMETHYL-2-PIPERIDINECARBOXAMIDE-MONOHYDROCHLORIDE MEAVERIN 0 MEPIVACAINE HYDROCHLORIDE 0 dl-MEPIVACAINE HYDROCHLORIDE 0 MEPIVASTESIN 0 I-METHYL-2',6'PIPECOLOXYLIDIDE HYDROCHLORIDE 0 dl-lMETHYL-2',6'-PIPECOLOXYLIDIDE HYDROCHLORIDE 0 (1-METHYLA-PIPERIDINE-2-CARBOXYLIC ACID)-2,6DIMETHYLANILIDE HYDROCHLORIDE 0 SCANDICAIN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous, intravenous, subcutaneous, and implant routes. Experimental reproductive effects. An anesthetic. When heated to decomposition it emits very toxic fumes of HC1 and NO,. CBR300 CAS: 60731-46-6 HR: 3 CARBOCALCITONIN mf: C148H2~N42047 mw: 3364.34 SYNS: (AMINOSUBERIC ACID 1,7)-EEL CALCITONIN 0 1,7-DICARBACALCITONIN (sal), 1-BUTANOIC ACID26-I-ASPARTIC ACID-27-1-VALINE-29-l-ALA"E1,7DICARBACALCITONIN (EEL), 1-BUTAVOIC ACIDELCATONIN 0 HC-58
CARBOHYDRAZIDE CBSSOO 283 SAFETY PROFILE: A poison by ingestion,
subcutaneous, intravenous, and intramuscular routes. When heated to decomposition it emits acrid smoke and irritating vapors. CBR675 CAS: 638-23-3 HR: 2 CARBOCISTEINE mf: CsHsN04S mw: 179.21 PROP: 1-Form: Mp: 204-207'. dl-Form: Spherical aggregates of needles. SYNS: CARBOCIT 0 CARBOCYSTEINE 0 S(CARB0XYMETHYL)CYSTEINE O I-CARBOXYMETHYLCYSTEINE 0 3-(CARBOXYMETHYLTHIO)ALANINE 0 1-3-((CARBOXYMETHYL)THIO)ALANINE 0 FLUIFORT 0 L.J. 206 0 LOVISCOL 0 MUCICLAR 0 MUCOCIS 0 MUCODYNE 0 hIUCOLASE 0 MUCOLEX 0 MUCOPRONT 0 PECTOX 0 PULMOCLASE 0 REOMUCIL 0 RHINATHIOL 0 RINATIOL 0 THIODRIL 0 TRANSBRONCHIN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by intraperitoneal route. Mildly toxic by ingestion. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of SO, and NO,.
CBS275 CAS: 1563-66-2 HR: 3 CARBOFURAN mf: C12HljN03 mw: 221.28 PROP: White, crystalline solid; odorless. Mp: 150-1 52', d: 1.180 @ 20'/20', vap press: 2 x 10-5 mm @ 33'. Sltly sol in water.
ACGIH TLV: TWA 0.1 mg/m3; Not
Classifiable as a Human Carcinogen SAFETY PROFILE: Poison by inhalation,
ingestion, s h n contact, and intravenous routes. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also CARBAMATES. CBS400 HR: D CARBOHYDRASE, ASPERGILLUS PROP: From fermentation of AspeqiLLus ory.yae var. Tan amorphous powder or liquid. Sol in water. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. CBS410 HR: D CARBOHYDRASE and PROTEASE, mixed PROP: From controlled fermentation of BaGillzls lichenifomus var. Brown amorphous powders or liquid. Sol in water; insol in alc, chloroform, ether. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes.
CBSSOO CAS: 497-18-7 HR: 3 CARBOHYDRAZIDE mf: CH6N40 mw: 90.11 SYNS: BAY 70143 0 CURATERR 0 D 1221 0 2,3PROP: Crystals from EtOH (ad. Mp: DIHYDRO-2,2-DIR.IETHYLBENZOFURANYL7-N153-154'. Sol in H20; practically insol in METHYLCARBAMATE 0 2,3-DIHYDRO-2,2-DIMETHYLorg solvs. 7-BENZOFURANYL METHYLCARBAMATE 0 2,2DIhlETHYL-7-COUMARANYL-~-~lETHYLCARBM~TE SYNS: 4-AMINOSEMICARBAZIDE 0 CARBAZIC ACID 0 2,2-DIMETHYL-2,3-DIHYDROBENZOFURAN-7-YL HYDRAZIDE 0 CARBAZIDE CARBODIHYDRAZIDE ESTER, METHYLCARBMlIC ACID 0 2,2-DIMETHYL-2,30 CARBONIC ACID DIHYDRAZIDE 0 CARBONIC DIHYDRO-7-BENZOFURYLN-METHYLCARBAMATE DIHYDRAZIDE 0 CARBONOHYDRAZIDE 0 0 ENT 27,164 0 FMC 10242 0 FURADAN 0 FURODAX CARBONYLDIHYDRAZINE 0 1,3-DIAMINOUREA 0 METHYL CARBAMIC ACID 2,3-DIHYDRO-2,2DOT CLASSIFICATION: Forbidden DIhlETHYL-7-BEh'ZOnrRANnESTER 0 N U 10242 0 CONSENSUS REPORTS: Reported in EPA NIAGRA 10242 0 YALTOX
CONSENSUS REPORTS: EPA Extremely
Hazardous Substances List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 0.1 mg/m3
TSCA Inventory.
SAFETY PROFILE: Poison by intravenous
and intraperitoneal routes. Reacts with nitrous acid to form the explosive carbonic dazide. When heated to decomposition it emits toxic fumes of NO,.
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284
CBS750 4'-CARBOMETHOXY-P,3'-DIMETHYL
CBS750 CAS: 63042-08-0 HR: 2 4'-CARBOMETHOXY-2,3'-DlMETHYLAZOBENZENE mf: Ci6H16N203 mw: 284.34 SYNS: 4'-CARBOMETHOXY-2,3'DIMETHYLAZOBENZOL 0 CARBONIC ACID METHYL4-(o-TOLYLAZO)-o-TOLYL ESTER 0 2,3'DIMETHYTAZOBENZENE-4'-METHYLCARBONATE
SAFETY PROFILE: Questionable
carconigen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NO,. CBT250 CAS: 4564-87-8 HR: 3 CARBOMYCIN mf: C4~H67N016 mw: 842.10 PROP: Laths from MeOH (ad. Mp: 210-21 4' (decomp). SYNS: CARBOMYCIN A 0 DELTAMYCIN A
0 9-
DEOXY-12,13-EPOXY-9-OXOLEUCOMCIN V 3ACETATE 4B-(3-METHYLBUTANOATE) 0 M-4209 0 MAGNAiiWCIN 0 MAGNALWCIN A
SAFETY PROFILE: Poison by subcutaneous route. Moderately toxic by intravenous and intramuscular routes. When heated to decomposition it emits toxic fumes of NO,.
CBTSOO CAS: 7440-44-0 HR: 1 CARBON DOT: UN 1361/UN 1362 af:C aw: 12.01 PROP: Black crystals, powder or diamond form. Mp: 3652-3697' (subl), bp: approx 4200°, d (amorph): 1.8-2.1, d (graphite): 2.25, d (diamond): 3.51, vap press: 1 mm @ 3586". IDLH 1250 mg/m3. SYNS: ACTICARBONE 0 ACTIVATED CARBON 0 AG 3 0 AG 5 0 AG 3 (ADSORBENT 0 AG 5 (ADSORBENT) 0 AK (ADSORBENT 0 ANTHRASORB 0 AR 3 0 ART 2 0 AU 3 0 BAU 0 BG 6080 0 BLACK LEAD 0 CARBON, activated (DOT) 0 CARBON-12 0 CARBON, animal or vegetable origin (DOT) 0 CARBOPOL EXTRA 0 CARBOPOL h l 0 CARBOPOL Z 4 0 CARBOPOL Z EXTRA 0 CARBOSIEVE 0 CARBOSORBIT R 0 CECARBON 0 CF 8 0 CF 8 (CARBON) 0 C.I. 77265 0 C.I. PIGMENT BLACK 10 0 CLF I1 0 CMB 50 0 CMl3 200 0 COKE POWDER 0 COLUMBIA LCK 0 CONDUCTEX 0 CUZ 3 0 CWN 2 0 DARCO 0 FILTRASORB 0 FILTRASORB 200 0 FILTRASORB 400 0 GRAPHITE 0 GRAPHITE SYNTHETIC (ACGIH,OSHA) 0 GROSAFE 0
HYDRODARCO 0 IRGALITE 1104 0 JADO 0 K 257 0 MA 100 (CARBON) 0 NORIT 0 NUCHAR 0 OU-B 0 PELIKAN C 11/1431a 0 PLUMBAGO 0 SKG 0 SKT 0 SKT (ADSORBENT) 0 SU 2000 0 SUCHAR 681 0 SUPERSORBON IV 0 SUPERSORBON S 1 0 U 02 0 WATERCARB 0 WITCARB 940 0 XE 340 0 XF 4175L
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: (Natural graphte) TWA 2.5 mg/m3; (Synthetic graphite) TWA Total Dust: 10 mg/m3; Respirable Fraction: 5 mg/m3 ACGIH TLV: TWA 2 mg/m3 (respirable dust) DFG MAK: 1.5 mg/m3 DOT CLASSIFICATION: 4.2; Label: Spontaneously Combustible SAFETY PROFILE: Moderately toxic by intravenous route. Experimental reproductive effects. It can cause a dust irritation, particularly to the eyes and mucous membranes. See also CARBON BLACK, SOOT. Combustible when exposed to heat. Dust is explosive when exposed to heat or flame or oxides, peroxides, oxosalts, halogens, interhalogens, 0 2 , (NH4N03 + heat), (NH4C104 @ 240°), bromates, Ca(OC1)2, chlorates, (Cla + Cr(OC1)2), C10, iodates, 105, Pb(N03)~, HgN03, HN03, (oils + air), (K + air), NaaS, Zn(NO3)a. Incompatible with air, metals, oxidants, unsaturated oils.
CBT750 CAS: 1333-86-4 HR: 1 CARBON BLACK PROP: A generic term applied to a farmly of high-purity colloidal carbons commercially produced by carefully controlled pyrolysis of gaseous or liquid hydrocarbons. Carbon blacks, including commercial colloidal carbons such as furnace blacks, lampblacks and acetylene blacks, usually contain less than several tenths percent of extractable organic matter and less than one percent ash. IDLH 1750 mg/m3. SYNS: ACETYLENE BLACK 0 ARO 0 AROFLOW 0 AROGEN 0 AROMEX 0 AROTONE 0 AROVEL 0 ARROW 0 ATLANTIC 0 BLACK PEARLS 0 CANCARB 0 CARBODIS 0 CARBOLAC 0 CARBOLAC 1 0
CARBON DIOXIDE CARBOXfET 0 CARBON BLACK, ACETYLENE 0 CARBON BLACK BV and V 0 CARBON BLACK, CHANNEL 0 CARBON BLACK, FULUACE 0 CARBON BLACK, LAIMP 0 CARBON BLACK, THERMAL 0 CHANNEL BLACK 0 C.I. 77266 0 C.I. PIGMENT BLACK 6 0 C.I. PIGMENT BLACK 7 0 CK3 0 COLLOCARB 0 COLUiMBIA CARBON 0 CONDUCTEX 0 CONTINENTAL 0 CONTINEX 0 CORAX 0 CORAX P 0 CROFLEX 0 CROLAC 0 DEGUSSA 0 DELC'SSA BLACK F W 0 DIXIE 0 DJXIECELL 0 DIXIEDENSED 0 D I X I T H E ~ I DUREX 13EAGLE GERMANTOWN ELF 0 ELFTEX D ESSEX 0 EXCELSIOR 0 EXPLOSION ACETYLENE BLACK 0 EXPLOSION BLACK 0 FARBRUSS 0 FECTO 0 FLAbiRCSS 0 FURNAL 0 FURNEX 0 F " E X N 765 0 GAS-FURUACE BLACK 0 GASTEX 0 HUBER 0 HUMENEGRO 0 IMPINGEMENT BLACK 0 KETJENBLACK EC 0 KOSMINK 0 KOSMOBIL 0 KOSMOLAK 0 KOSMOS 0 KOSMOTHER\f 0 KOSMOVAR 0 XWGECOL 0 hiETANEX 0 MICRONEX 0 MIIKE 20 0 MODULEX 0 MOGUL 0 MOGUL L 0 MOLACCO 0 MONARCH 0 NEO-SPECTRA 0 NEO-SPECTRA I1 0 NEOTEX 0 OIL FURNACE BLACK 0 P-33 0 P68 0 P1250 0 PEERLESS 0 PELLETEX 0 PHILBLACK 0 PHILBLACK N 550 0 PHILBLACK N 765 0 PHILBLACK 0 0 PIGhlENT BLACK 7 0 PRINTEX 0 PRINTEX 60 0 RAVEN 0 RAVEN 30 0 RAVEN 420 0 RAVEN 500 0 RAVEN 8000 0 REBONEX 0 REGAL 0 REGAL 99 0 REGAL 300 0 REGAL 330 0 REGAL 600 0 REGAL 400R 0 REGAL SRF 0 REGENT 0 ROYAL SPECTRA 0 SEVACARB 0 SEVAL 0 SHAWINIGAN ACETYLENE BLACK 0 SHELL CARBON 0 SPECML BLACK 1V & V 0 SPECIAL SCHWARZ 0 SPHERON 0 SPHERON 6 0 STATEX 0 STATEX N 550 0 STERLING 0 STERLING N 765 0 STERLING NS 0 STERLING SO 1 0 SUPERBA 0 SUPERCARBOVAR 0 SUPER-SPECTRA 0 TEXAS 0 THERMAATOMIC BLACK 0 THERMAL ACETYLENE BLACK 0 THERMATOMIC 0 THERMAX 0 THERMBLACK 0 TINOLITE 0 7Ri 30 0 TORCH BRAND 0 TRIANGLE 0 UCET 0 UKARB 0 UNITED 0 VELVETEX 0 VCLCAN 0 WITCO 0 WITCOBLAK NO. 100 I3 WYEX
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,142,87; Human Inadequate Evidence IMEMDT 33,35,84; Animal Inadequate Evidence IMEMDT 33,35,84. OSHA PEL: TWA 3.5 mg/m3 ACGIH TLV: TWA 3.5 mg/m3; Not Classifiable as a Human Carcinogen NIOSH REL: (Carbon Black) TWA 3.5 mg/m3 SAFETY PROFILE: Mildly toxic by ingestion, inhalation, and skin contact.
CBU250 285
Questionable carcinogen. Mutation data reported. See also CARBON. A nuisance dust in high concentrations. W e it is true that the tiny particulates of carbon black contain some molecules of carcinogenic materials, the carcinogens are apparently held tightly and are not eluted by hot or cold water, gastric juices, or blood plasma. CBU250 CAS: 124-38-9 HR: 1 CARBON DIOXIDE DOT: UN 1013/UN 1845/UN 2187 mf: COa mw: 44.01 PROP: Colorless, odorless gas. Mp: 57' (sublimes @ -78.5'), vap d: 1.53 @ 78.2'. Sltly sol in water, forming HzC03. IDLH 40,000 ppm. SYNS: ANHYDRIDE CARBONIQUE (FRENCH) 0 CARBON DIOXIDE, refrigerated liqud (UN 2187) (DOT) 0 CARBON DIOXIDE, solid (LrN 1845) (DOT 13CARBONIC ACID ANHYDRIDE 0 CARBONIC ACID GAS 0 CARBONIC ANHYDRIDE 0 CARBON OXIDE 0 DRY ICE 0 DRY ICE (UN 1845) (DOT) 0 KHLADON 744 0 KOHLENDIOXYD (GEILZ.IAN) 0 KOHLENSAELRE (GERMAN) 0 R 744
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 10,000 ppm; STEL
30,000 ppm ACGIH TLV: TWA 5000 ppm; STEL 30,000
PPm DFG MAK: 5000 pprn (9100 mg/m3) NlOSH REL: (Carbon Dioxide) TWA 10,000
ppm; CL 30,000 ppm/lOM DOT CLASSIFICATION: 2.2; Label: Nonflammable Gas; DOT Class: 9; Label: None (UN 1845) SAFETY PROFILE: An asphpant. See discussion of simple asphyxiants under ARGON. Experimental teratogenic and reproductive effects. Contact of solid carbon dioxide snow with the skin can cause burns. Dusts of magnesium, zirconium, titanium, and some magnesium-aluminum alloys igmte and then explode in COa atmospheres. Dusts of aluminum, chromium, and manganese ignite and then explode when heated in COz. Several bulk metals wlll burn in COz. Reacts vigorously
286
CBVOOO CARBON DIOXIDE mixed with NITROUS OXIDE
with (Al + Na202), CszO, Mg(CzH5)2, Li, (Mg + NazOz), K, KHC, Na, Na2C2, NaK, Ti. C02 fire extingushers can produce hghly incendiary sparks of 5-1 5 mJ at 10-20 kV by electrostatic discharge. Incompatible with acrylaldehyde, aziridme, metal acetylides, sodium peroxide. CBVOOO CAS: 53569-62-3 HR: 2 CARBON DIOXIDE mixed with NITROUS OXIDE DOT: UN 1015 mf: C02*N20 mw: 88.03 SYNS: CARBON DIOXIDE, mixture with NITROGEN OXIDE (NzO) 0 CARBON DIOXIDE-NITROUS OXIDE mixture (DOT)
NIOSH REL: (Carbon Dioxide) TWA 10,000 ppm; CL 30,000 ppm/lOM; ( N 2 0 as Anesthetic Agent) TWA 25 ppm/lH DOT CLASSIFICATION: 2.2; Label: Nonflammable Gas SAFETY PROFILE: See components as listed. An anesthetic mixture. Combustible. An oxidizing mixture. Can react with reducing materials.
CBV250 CAS: 8063-77-2 HR: 1 CARBON DIOXIDE mixed with OXYGEN DOT: UN 1014 SYNS: CARBOGEN (8CI) 0 CARBON DIOXIDEOXYGEN mixture (DOT)
NIOSH REL: (Carbon Dioxide) TWA 10,000
ppm; CL 30,000 ppm/lOM DOT CLASSIFICATION: 2.2; Label: Nonflammable Gas SAFETY PROFILE: Possible asphyxiant. CBVSOO CAS: 75-15-0 HR: 3 CARBON DISULFIDE DOT: UN 1131 mf: CS2 mw: 76.13 PROP: Highly refracting, clear, colorless liquid; nearly odorless when pure. Mp: -111.6', d: 1.293 @ 0°/4', bp: 46.5", lel: 1.3%,uel: %YO,flash p: -22'F (CC), autoign temp: 257'F, vap press: 400 mm @ 28', vap d: 2.64. Wsc in EtOH, EtzO, and C6H6; sldy sol in H20. IDLH 500 ppm.
SYNS: CARBON BISULFIDE (DOV 0 CARBON BISULPHIDE 0 CARBON DISULPHIDE 0 CARBONE (SUFURE de) (FRENCH) 0 CARBONIO (SOLFURO di) (ITALIAN) 0 CARBON SULFIDE 0 CARBON SULPHIDE (DOT) 0 DITHIOCARBONIC ANHYDRIDE 0 KOHLENDISULFID (SCHWEFELKOHLENSTOFF) (GERMAN) 0 KOOLSTOFDISULFIDE (ZWAVEL KOOLSTOF) (DUTCH) 0 NCI-C04591 0 RCRA WASTE NUiMBER PO22 0 SCHWEFELKOHLENSTOFF (GERMAN) 0 SOLFURO di CARBONIO (ITALIAN) 0 SULPHOCARBONIC ANHYDRIDE 0 WEEVILTOX 0 WEGLA DWUSIARCZEK (POLISH) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-To-Know List. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 4 ppm; STEL 12 pprn (skin) ACGIH TLV: TWA 10 pprn (sktn); BEI: 5 mg (2-thiothiazolidine-4-carboxylicacid (TTCA))/g creatinine in urine DFG MAK: 5 pprn (16 mg/m3); BAT: 8 mg/L of 4-thio-4-thiazolidne carboxylic acid (TTCA) at end of shift NIOSH REL: (Carbon Disulfide) TWA 1 ppm; CL 10 ppm/ 15M DOT CLASSIFICATION: 3; Label: Flammable Liquid, Poison SAFETY PROFILE: A human poison by unspecified route. Mildly toxic to humans by inhalation. An experimental poison by intraperitoneal route. Human reproductive effects on spermatogenesis by inhalation. Experimental teratogenic and reproductive effects. Human mutation data reported. The main toxic effect is on the central nervous system, acting as a narcotic and anesthetic in acute poisoning with death following from respiratory failure. In chronic poisoning, the effect on the nervous system is one of central and peripheral damage, which may be permanent if the damage has been severe. Flammable liquid. A dangerous fire hazard when exposed to heat, flame, sparks, friction, or oxidning materials. Severe explosion hazard when exposed to heat or flame. Ignition and potentially explosive reaction when heated in contact with rust or iron. Mixtures with sodium or potassiumsodum alloys are powerful, shock-sensitive
CARBON MONOXIDE CBWZ~O 287
explosives. Explodes on contact with permanganic acid. Potentially explosive reaction with nitrogen oxide, chlorine (catalyzed by iron). Mixtures with dinitrogen tetraoxide are heat-, spark-, and shocksensitive explosives. Reacts with metal azides to produce shock- and heat-sensitive, explosive metal azidodtthioformates. Aluminum powder ignites in CS2 vapor. The vapor ignites on contact with fluorine. Reacts violently with azides, CsN3, C10, ethylamine diamine, ethylene imine, Pb(N3)2, LiN3, (H2so4 + permanganates), KN3, RbN3, NaN3, phenylcoppertriphenylphosphine complexes. Incompatible with air, metals, oxidants. To fight fxe, use water, COz, dry chemical, fog, mist. When heated to decomposition it emits highly toxic fumes of SO,. CBW400 CAS: 2463-45-8 HR: 3 CARBONIC ACID, CYCLIC 3-CHLOROPROPYLENE ESTER mf: C4HjC103 mw: 136.54 SYN: 1,3-DIOXOJAN-Z-ONE,4-(CHLOROMETHYLCONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of C1-.
CBW750 CAS: 630-08-0 HR: 3 CARBON MONOXIDE DOT: UN 1016/NA 9202 mE CO mw: 28.01 PROP: Colorless, odorless, tasteless gas. Mp: -213O, bp: -190°, lel: 12.5%, uel: 74.2%, d: (gas) 1.250 g/L @ Oo, @quid) 0.793, autoign temp: 1128OF. Very sltly sol in H20; sol in AcOH, MeOH, and EtOH. IDLH 1200 PPm. SYNS: CARBONE (OXYDE de) (FRENCH) 0 CARBONIC OXIDE 0 CARBON10 (OSSIDO &) (ITALIAN) 0 CARBON MONOXIDE (ACGIH,OSHA) 0 CARBON MONOXIDE (UN1016) (DOT 0 CARBON hlONOXIDE, refrigerated hqud (cryogemc hqud) (NA 9202) (DOT 0 CARBOX OXIDE (CO) 0 EXHAUST GAS 0 FLUE GAS 0 KOHLENMONOXID (GERMAN) 0
KOHLENOXYD (GERMAN) 0 KOOLMONOXYDE (DUTCH) 0 OXYDE de CARBONE (FRENCH) 0 WEGLh TLENEK (POLISH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 35 ppm; CL 200 pprn ACGIH TLV: 25 ppm; BEI: 3% of hemoglobin indicating carboxyhemoglobin in blood at end of shift; 20 pprn CO in endexhaled air at end of shift. DFG MAK: 30 ppm (35 mg/m3); BAT: 5% carboxyhemoglobin in blood at end of shift NIOSH REL: (Carbon Monoxide) TWA 35 ppm; CL 200 pprn DOT CLASSIFICATION: 2.3; Label: Poison Gas, Flammable Gas SAFETY PROFILE: Mddly toxic by inhalation in humans but has caused many fatalities. Experimental teratogenic and reproductive effects. Human systemic effects by inhalation: changes in psychophysiological tests and methemoglobinemiacarboxyhemoglobinemia. Can cause asphyxiation by preventing hemoglobin from bindmg oxygen. After removal from exposure, the half-life of elimination from the blood is one hour. Chronic exposure effects can occur at lower concentrations. A common air contaminant. Acute cases of poisoning resulting from brief exposures to h g h concentrations seldom result in any permanent dtsability if recovery takes place. Chronic effects as the result of repeated exposure to lower concentrations have been described, particularly in the Scandinavian literature. Auditory disturbances and contraction of the visual fields have been demonstrated. Glycosuria does occur, and heart irregularities have been reported. Other workers have found that where the poisoning has been relatively long and severe, cerebral congestion and edema may occur, resulting in long-lasting mental or nervous damage. Repeated exposure to low concentration of the gas, up to 100 ppm in air, is generally believed to cause no signs of poisoning or permanent damage.
2aa
cBxios
CARBONOCHLORIDICACID PHENYL ESTER
Industrially, sequelae are rare, as exposure, though often severe, is usually brief. It is a common air contaminant. A dangerous fire hazard when exposed to flame. Severe explosion hazard when exposed to heat or flame. Violent or explosive reaction on contact with bromine trifluoride, bromine pentafluoride, chlorine doxide, or peroxodsulfuryl &fluoride. Mixture of liquid CO with liquid 0 2 is explosive. Reacts with sodurn or potassium to form explosive products sensitive to shock, heat, or contact with water. Murture with copper powder + copper(I1) perchlorate + water forms an explosive complex. & m e of liquid CO with liquid dinitrogen oxide is a rocket propellant combination. Ignites on warming with iodine heptafluoride. Ignites on contact with cesium oxide + water. Potentially explosive reaction with iron(II1) oxide between 0' and 150'C. Exothermic reaction with CIF3, (Li + HzO), NF3,OFz, (K + 0 4 , AgzO, (Na + NH3). To fight fire, stop flow of gas.
mf: CBr4 mw: 331.65 PROP: Colorless, monoclinic tablets. Mp: (a)48.4', (p) 90.1", bp: 102' @ 50 mm, d: 2.961 @ 99.5'/4', vap press: 40 mm @ 96.3'. Sol in EtOH, Et20, and CHCb; insol in H20.
CBX109 CAS: 1885-14-9 HR: 3 CARBONOCHLORIDIC ACID PHENYL ESTER DOT: UN 2746 mf: C7HSC102 mw: 156.57 PROP: Bp: 68-71' @ 9 mm. SYNS: CHLOROFORMIC ACID PHENYL ESTER 0 FENYLESTER KYSELINY CHLORMRAVENCI (CZECHJ OPHENYLCHLOROCARBONATEOPHENYL CHLOROFORMATE 0 PHENYLCHLOROFOILMATE
CBYOOO CAS: 56-23-5 HR: 3 CARBON TETRACHLORIDE DOT: UN 1846 mf: cc14 mw: 153.81 PROP: Colorless liquid; heavy, ethereal odor. Mp: -22.6', bp: 76.8', flash p: none, d: 1.632 @ Oo/4O, vap press: 100 mm @ 23.0'. Sol in EtOH and EtzO; practically insol in H20. IDLH 200 ppm.
(DOT)
SYNS: BENZINOFORM
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison,
Corrosive SAFETY PROFILE: Poison by inhalation. Moderately toxic by ingestion and skin contact. A corrosive sktn and eye irritant. See also ESTERS. When heated to decomposition it emits toxic fumes of C1-.
CBX750 CAS: 558-13-4 CARBON TETRABROMIDE DOT: UN 2516
HR: 3
SYNS: BROMID UHLICITY 0 CARBON BROMIDE 0 METHANE, TETRABROMIDE 0 METHANE, TETRABROMO- 0 TETRABROMIDE METHANE 0 TETRABROMOMETHANE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 ppm; STEL 0.3 ppm ACGIH TLV: TWA 0.1 ppm; STEL 0.3 ppm DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by subcutaneous and intravenous routes. Narcotic in high concentration. Mixture with Li particles is an impact-sensitive explosive. Explodes on contact with hexacyclohexylddead. When heated to decomposition it emits toxic fumes of Br-. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
CARBONA CARBON CHLORIDE 0 CARBON TET 0 CZTEROCHLOREK WEGLA (POLISH) 0 ENT 4,705 0 FASCIOLIN 0 FLUKOIDS 0 METHANE TETRACHLORIDE 0 NECATORINA 0 NECATORINE 0 PERCHLOROMETHANE R 10 0 RCRA WASTE NUMBERU211 0 TETRACHLOORKOOLSTOF(DUTCH) 0 TETRACHLOORMETAAN 0 TETRACHLORKOHLENSTOFF, (GERMAN) 0 TETRACHLORMETHAN (GERhlAN) 0 TETRACHLOROCARBON 0 TETRACHLOROMETHANE TETRACHLOREREde CARBONE (FRENCH) U TETRACLOROMETANO(ITALIAN) 0 TETRACLORURO di CARBON10 (ITALIAN) 0 TETRAFINOL 0 TETRAFORM 0 TETRASOL D UNIVERM 0 VERIIOESTRICID
CARBON TETRACHLORlDE CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 2B IMEMDT 7,143,87; Animal Sufficient Evidence IMEMDT 20,371,79; IMEMDT 1,53,72; Human Inadequate Evidence IMEMDT 1,53,72; Human Limited Evidence IMEMDT 20,371,79. Community Right-To-Know List. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. OSHA PEL: TWA 2 ppm ACGIH TLV: TWA 5 ppm; STEL 10 (skin); Suspected Human Carcinogen DFG MAK: 10 ppm (64 mg/m3); BEI: 1.6 mL/m3 in alveolar air 1 hour after exposure; Suspected Carcinogen NIOSH REL: (Carbon Tetrachloride) CL 2 ppd6OM DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. A human poison by ingestion and possibly other routes. Poison by subcutaneous and intravenous routes. Mildly toxic by inhalation. Human systemic effects by inhalation and ingestion: nausea or vomiting, pupdlary constriction, coma, antipsychotic effects, tremors, somnolence, anorexia, unspecified respiratory system and gastrointestinal system effects. Experimental teratogenic and reproductive effects. An eye and skin irritant. Damages liver, kidneys, and lungs. Mutation data reported. A narcotic. Individual susceptibilityvaries widely. Contact dermatitis can result from skin contact. Carbon tetrachloride has a narcotic action resembling that of chloroform, though not as strong. Following exposure to high concentrations, the victim may become unconscious, and, if exposure is not terminated, death can follow from respiratory fdure. The aftereffects following recovery from narcosis are more serious than those of delayed chloroform poisoning, usually taking the form of damage to the kidneys, liver, and lungs. Exposure to lower
CBYO00 289
concentrations, insufficient to produce unconsciousness, usually results in severe gastrointestinal upset and may progress to serious hdney and hepatic damage. The kidney lesion is an acute nephrosis; the liver involvement consists of an acute degeneration of the central portions of the lobules. When recovery takes place, there may be no permanent dsability. Marked variation in individual susceptibdity to carbon tetrachloride exists; some persons appear to be unaffected by exposures that seriously poison their fellow workers. Alcoholism and previous liver and kidney damage seem to render the indwidual more susceptible. Concentrations on the order of 1000 to 1500 ppm are sufficient to cause symptoms if exposure continues for several hours. Repeated d d y exposure to such concentration may result in poisoning. Though the common form of poisoning following industrial exposure is usually one of gastrointestinal upset, which may be followed by renal damage, other cases have been reported in which the central nervous system has been affected, resulting in the production of polyneuritis, narrowing of the visual fields, and other neurologcal changes. Prolonged exposure to small amounts of carbon tetrachloride has also been reported as causing cirrhosis of the liver. Locally, a dermatitis may be produced following long or repeated contact with the liquid. The skin oils are removed and the s h n becomes red, cracked, and dry. The effect of carbon tetrachloride on the eyes either as a vapor or as a liquid, is one of irritation with lachrymation and burning. Industrial poisoning is usually acute with malaise, headache, nausea, dminess, and confusion, which may be followed by stupor and sometimes loss of consciousness. Symptoms of liver and kidney damage may follow later with development of dark urine, sometimes jaundice and liver enlargement, followed by scanty urine, albuminuria, and renal casts; uremia may develop and cause death. Where exposure has been less acute,
E
290
CBY250
CARBON TETRAFLUORIDE
the symptoms are usually headache, dizziness, nausea, vomiting, epigastric distress, loss of appetite, and fatigue. Visual disturbances (blind spots, spots before the eyes, a visual "haze," and restriction of the visual fields), secondary anemia, and occasionally a slight jaundice may occur. Dermatitis may be noticed on the exposed parts. Forms impact-sensitive explosive mixtures with particulates of many metals, e.g., aluminum (when ball milled or heated to 152' in a closed container), barium (bulk metal also reacts violently), beryllium, potassium (200 times more shock sensitive than mercury fulminate), potassium-sodium alloy (more sensitive than potassium), lithium, sodium, zinc (burns ready). Also forms explosive mixtures with chlorine trifluoride, calcium hypochlorite (heatsensitive), calcium dtsllicide (friction- and pressure- sensitive), triethyldialuminum trichloride (heat- sensitive), decaborane(l4) (impact-sensitive),dinitrogen tetraoxide. Violent or explosive reaction on contact with fluorine. Forms explosive mixtures with ethylene between 25' and 105' and between 30 and 80 bar. Potentially explosive reaction on contact with boranes. 9:l mixtures of methanol and cc14 react exothermically with aluminum, magnesium, or zinc. Potentially dangerous reaction with dimethyl formamide, 1,2,3,4,5,6hexachlorocyclohexane, or dtmethylacetamide when iron is present as a catalyst. CCh has caused explosions when used as a fire extingusher on wax and uranium fires. Incompatible with aluminum trichloride, dtbenzoyl peroxide, potassiumtert-butoxide. Vigorous exothermic reaction with ally1 alcohol, Al(C2H5)3, (benzoyl peroxide + C2H4), BrF3, diborane, dsilane, liquid 0 2 , Pu, (AgC104 + HCl), potassiumtert-butoxide, tetraethylenepentamine, tetrasilane, trisilane, Zr. When heated to decomposition it emits toxic fumes of C1and phosgene. It has been banned from household use by the FDA. See also
CHLORINATED HYDROCARBONS, ALIPHATIC.
CBY250 CAS: 75-73-0 HR: 2 CARBON TETRAFLUORIDE DOT: UN 1982 mf: CF4 mw: 88.01 PROP: Colorless gas. Mp: -184O, bp: -127.7', d: 1.96 @, -184'. Sltly sol in H20. SYNS: ARCTON 0 0 CARBON FLUORIDE
F 14 0 FC 14 0 FREON 14 0 HALOCARBON 14 0 HALON 14 0 METHANE,TETRAFLUORO- 0 PERFLUOROMETHANE 0 R 14 0 R14 (DOT) 0 REFRIGEaVT 14 0 REFRIGERANT R 14 0 R 14 (REFRIGERANT) 0 TETRAFLUOROCARBON 0 TETRAFLUOROMETHASE 0 TETRAFLUOROMETHANE(DOT)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 2.2;Label:
Nonflammable Gas SAFETY PROFILE: Mddly toxic by
inhalation. Less chronically toxic than carbon tetrachloride. Violent reaction with Al. When heated to decomposition it emits toxic fumes of F-. See also FLUORIDES.
CBY750 CAS: 75-46-7 HR: 2 CARBON TRIFLUORIDE DOT: UN 1984/UN 3136 mf: CHF3 mw: 70.02 PROP: Colorless, odorless gas. Mp: - 1 6 3 O , bp: -82.2', d: 1.52 (liquid) @? -100'. Sol in water. SYNS: ARCTON 0 CARBON TRIFLUORIDE 0 FLUOROFORM FISJORYL FREON 23 FREON F23 0 GENETRON 23 0 HALOCARBON 23 0 METHYL TRIFLUORIDE 0 R 23 0 TRIFLUOROMETHANE 0 TRIFLUOROMETHANE,refrigerated, liquid (UN 3136) (DOT) 0 TRIFLUOROMETHANE(UN 1984) (DOT) CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 2.2;Label: Nonflammable Gas SAFETY PROFILE: Narcotic in high concentration. A mild respiratory irritant. Mutation data reported. See also FLUORIDES. When heated to decomposition it emits toxic fumes of F-.
CARBOXINE CCCSOO 291
CCASOO CAS: 353-50-4 HR: 3 CARBONYL FLUORIDE DOT: UN 2417 mf: CFZO mw: 66.01 PROP: Colorless gas; pungent; hygroscopic. Readily hydrolyzes to COZand HF. Mp: -114O, bp: -83O, d: 1.139 @ -114'. SYNS: CARBON DIFLUORIDE OXIDE 0 CARBON FLUORIDE OXIDE 0 CARBONIC DIFLUORIDE 0 CARBON OXYFLUORIDE 0 CARBONYL DIFLUORIDE 0 DIFLUOROFORMALDEHYDE 0 FLUOPHOSGENE 0 F L U O R O F O R i i FLUORIDE 0 FLUOROPHOSGENE 0 RCRA WASTE NUMBER U033 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 2 ppm; STEL 5 ppm ACGIH TLV: TWA 2 ppm; STEL 5 ppm DOT CLASSIFICATION: 2.3; Label: Poison Gas SAFETY PROFILE: A poison. Moderately toxic by inhalation. A powerful irritant. Hydrolyzes instantly to form HF on contact with moisture. See also CARBONYLS, HYDROFLUORIC ACID, and FLUORINE. Incompatible with hexafluoroisoprop ylideneamino-lithium. When heated to decomposition it emits toxic fumes of CO and F-. See CARBON MONOXIDE for fire and explosion hazard.
CCB609 HR: 3 CARBONYLS PROP: The (CO) group with a metal 0. They may exist as dimeric acetylene derivatives (MOCOCOM) or as salts of hexahydroxybenzene. SAFETY PROFILE: Most carbonyls are hghly toxic. The toxicity of carbonyls depends in part, but not always entirely, on their ready decomposition, which releases carbon monoxide. Symptoms are due in part to carbon monoxide and in part to the direct irritating action of the carbonyl. See specific carbonyl in question. Many carbonyl metals igmte spontaneously in air, some with a delay period. Others are moderate fire and explosion hazards when exposed to heat or flame. Carbonyls of alkali metals are potentially explosive. Hypergolic reaction
with dinitrogen tetraoxide. They react with water or steam to produce toxic and flammable vapors; can react vigorously with oxidizing materials. When heated to decomposition they emit highly toxic fumes of carbon monoxide. See also CARBON MONOXIDE and POWDERED METALS. CCCOOO CAS: 463-58-1 HR: 3 CARBONYL SULFIDE DOT: UN 2204 mf: COS mw: 60.07 PROP: Gas or liquid. Hydrolyzed by water. Mp: -138.2', bp: 50.2", lel: 12%, uel: 28.5%, d: liq 1.24 @ -87O, vap d: 2.1, d: 1.19 @ 50 mm. Very sltly sol in water, alc, and toluene. SYNS: CARBON OXIDE SULFIDE 0 CARBON OXYSULFIDE 0 CARBONYL OXYCARBON SULFIDE
0
CONSENSUS REPORTS: Community Right-To-Know List. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 2.3; Label: Poison Gas, Flammable Gas SAFETY PROFILE: Poison by intraperitoneal route. Mildly toxic by inhalation. Narcotic in high concentration. An irritant. May liberate highly toxic hydrogen sulfide upon decomposition. A very dangerous fire hazard and moderate explosion hazard when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, stop flow of gas or use COz, dry chemical, or water spray. When heated to decomposition it emits toxic fumes of CO. See also CARBONYLS and SULFIDES.
CCC500 CAS: 5234-68-4 HR: 3 CARBOXINE mf: CIZHI~NOZS mw: 235.32 PROP: Solid. Sltly SO^ h HzO; SO^ in C6H6, EtOH, and MeOH. Very sol in Me2CO. SYNS: 5-CARBOXANILID0-2,3-DlHYDRO-G-METHYL 1,4-OXATHIIN CARBOXIN (USDA) 0 D 735 0 DCMO 0 2,3-DIHYDRO-5-CARBOXILIDO-6-METHYL-1,4OXATHIIN 0 5,6-DIHYDRO-2-METHYL-3-CARBOXANILIDO-l,4-OXATHIIN (GERMAN) 0 2,3-DIHYDRO-6-
292
CCESOO 2-CARBOXY-4'-(DIMETHYLAMINO)-AZOBENZENE
I\.IETHYL-l,4-OXATHIIN-5-CARBOXANILIDE 0 5,6CCGSOO CAS: 36568-91-9 HR: 3 DIHYDRO-2-METHYLl,4-OXATHIIN-3-CARBOX(4-(CARBOXY METHOXY)-3-CHLOROANILIDE 0 5,6-DIHYDRO-2-hlETH~-N-PHENYL-1,4OXATHIIN-3-CARBOXAMIDE 0 F 735 0 FLO PRO V SEED PROTECTANT 0 VITAVAX
SAFETY PROFILE: Poison by ingestion.
Moderately toxic by skin contact and possibly other routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and SO,. CCESOO CAS: 493-52-7 HR: 2 2-CARBOXY-4'-(DIMETHYLAMINO)AZOBENZENE mf: CljHl5N302 mw: 269.33 PROP: Shiny violet crystals. SYNS: C.I. 13020 0 C.I. ACID RED 2 0 p(DIMETHYLA?rlINO)AZOBENZENE-o-CARBOXYLIC ACID 0 4'-DI~IETHYLAMINOAZOBENZENE-2CARBOXYLIC ACID 0 o-(@-(DIMETHYLAMINO)PHENYL)AZO)BENZOIC ACID 0 2-((4-DIMETHYLhMIN0)PHENYLAZO)BENu'OICACID 0 METHYL RED
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 8,161,75. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFlLE : Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
CCF125 CAS: 12758-40-6 HR: 2 CARBOXYETHYLGERMANIUM SESQUIOXIDE mf: C6HloGe207 mw: 339.34 SYNS: B I S - P - C A R B O X ~ T H Y L G E I ~ ~ N I ~ ~ ~ SESQUIOXIDE 0 2-CARBOXYETHYLGERMASESQUIOXhXE 0 3,3'-(DIOXODIGER\fOXAiiYLENE) DIPROPANOIC ACID 0 DIPROPANOIC ACID GERMANIUM SESQUIOXIDE 0 Ge 132 0 GER?dANATE(2-),BIS(2-CARBOXYL4TOETHYL)TRIOXODI-, DIHYDROGEN ('XI) 0 3,3'-(GERVAi%OICAKHYDRIDE) DIPROPANOIC ACID
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
intravenous route. Experimental reproductive effects. See also GERMANIUM COMPOUNDS.
PHENYL)(5,5-DIETHYL-2,4,6(1H,3H,5H)-PYRIMIDINETRIONATO)-O~MERCURY, MONOSODIUM SALT mf: C16H1&1HgN206*Na mw: 593.39 PROP: IDLH 10 mg/m3 (as Hg). SYNS: MERBAPHEN 0 NOVASUROL CONSENSUS REPORTS: Mercury and its compounds are on the Community Right-
To-Know List. OSHA PEL: CL 0.1 mg(Hg)/m3 (shn) ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 kg/g creatinine total inorganic mercury in urine preshift; 15 pg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (shn) SAFETY PROFILE: Poison by intravenous route. See also MERCURY COMPOUNDS. When heated to decomposition it emits very toxic fumes of C1-, NO,, and Hg. CCH3OO CAS: 22041-28-7 HR: 3 1-CARBOXYMETHYL-1-METHYLPYRROLIDINIUM IODIDE METHYL ESTER mf: C ~ H I ~ N O ~ * Imw: 285.15 SYN: PYRROLIDINIUM, l-CARBOXYMETHYL-1METHYL-, IODIDE, M E T H E ESTER SAFETY PROFILE: A poison by intravenous route. When heated to decomposition it emits toxic vapors of NO, and I-.
cc1550 CAS: 1197-16-6 HR: 3 p-CARBOXY PHENYLARSENOXIDE mf: C7H~As03 mw: 212.04 SYNS: ARSINE, OXO(4-CARB0XY)PHENYL 0 BENZOIC ACID, 4-ARSENOSOOSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of As.
P-CAROTENE
CCJ625 CAS: 8000-66-6 HR: 1 CARDAMON OIL PROP: From the seed of Elettaria cardamomtln (L.) Maton (Fam. Zingibera.yeae). Colorless liquid; aromatic penetrating odor of cardamom, pungent taste. Misc with alc. SYNS: CARDAMON 0 OIL OF CARDAMON CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and fumes.
CCKOOO CAS: 3599-32-4 HR: 3 CARDIO-GREEN mf: C43H4&06S2*Na mw: 776.04 PROP: Green powder. Mp: 243-245' (decomp). SYNS: ICG 0 INDOCYANINE GREEN 0 IR 125 0 UJOVIRIDIN 0 WOFAVERDIN CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it
emits very toxic fumes of SO,, Na20, and NO,.
CCK685 293
SORBITRATE 0 SORBONIT 0 SORQUAD 0 SORQUAT 0 VASCARDIN 0 VASORBATE 0 VASOTRATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 4.1; Label:
Flammable Solid SAFETY PROFILE: Moderately toxic by ingestion, intraperitoneal, intramuscular, and subcutaneous routes. Experimental reproductive effects. Mutation data reported. A flammable solid. When heated to decomposition it emits toxic fumes of NO,. A coronary vasodilator. See also NITRATES.
CCK590 CAS: 1390-65-4 HR: D CARMINE mf: C22H20013 mw: 492.39 PROP: An aqueous extract of cochmeal obtained from the dried female insects Dacolopitls cocctls costa (Cosstls cacti L.). Bright red crystals from water. Decomp @ 250'. Sol in water, alc, ether; insol in benzene, chloroform. Carmine is the aluminum or calcium-aluminum lake on aluminum hydroxide substrate of carminic acid. SYNS: B ROSE LIQUID 0 CARMINIC ACID SAFETY PROFILE: When heated to
CCK125 CAS: 87-33-2 HR: 2 CARDIS DOT: UN 2907 mf: C6H8N208 mw: 236.16 PROP: Hard, colorless crystals. Mp: 71'. Sparingly sol in water. Freely sol in org solvs, such as acetone, alc, and ether.
decomposition it emits acrid smoke and irritating fumes.
SYNS: ASTRIDINE 0 CARD10 0 CARVANIL 0 CARVASIN 0 CEDOCARD 0 CLAODICAL 0 COROSORBIDE 0 COROVLISS 0 1,43,6-DIANHYDROSORBITOL-2,5-DINITRATE 0 DINITROSORBIDE 0 DISORLON 0 DURANITRAT 0 EURECOR 0 FLINDIX 0 GLENTONIN-RETARD 0 HARRICAL 0 IBD 0 ISDIN 0 ISO-BID 0 ISOKET 0 ISOiMACK 0 ISO-PUREN 0 ISORBID ISORDIL 0 ISORDIL TEhlBIDS 0 ISOSORBIDE DINITRATE 0 ISOSTENASE 0 ISOTRATE 0 KORODIL 0 LANGORAN 0 LASERDIL 0 MAYCOR 0 MONOCLAIR 0 MYOREXON 0 NITROSORBID 0 NITROSORBIDE 0 NITROSORBON 0 NOSIM 0 RESOIDAN 0 RIFLOC RETARD 0 RIGEDAL 0 SORBANGIL 0 SORBID 0 SORBIDE NITRATE 0 SORBIDILAT 0 SORBIDINITRATE 0 SORBISLO 0
SYNS: P-ALANYL-LHISTIDINE 0 I-CARNOSINE 0 1HISTIDINE, N-p-ALANYLIGNOTINE KARNOZZN 0 N-2-M
CCK665 CAS: 305-84-0 HR: 1 CARNOSINE mf: C9H14N403 mw: 226.27 PROP: Needles. Mp: 246-250' (decomp).
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of NO,.
CCK685 CAS: 7235-40-7 P-CAROTENE mf: C40H56 mW: 536.88
HR: D
294
CCL250
CARRAGEEN
PROP: Deep purple prisms from CbH6/MeOH; or red crystals from pet ether;
or crystalline powder. Mp: 183' (sealed tube). Sol in carbon disulfide, benzene, chloroform; sltly sol in ether, hexane, veg. oil; insol in water. SYN: CAROTENE SAFETY PROFILE: When heated to
decomposition it emits acrid smoke and irritating fumes.
CCL250 CAS: 9000-07-1 HR: 2 CARRAGEEN PROP: A sulfated polysaccharide. Dried plant of seaweed Cbondms m'spus, Cbondms ocellatus, Eucbeuma cottonid Eucbeuma pinosurn, Gigartina aciculaks, Gigartinapistillata, Gigartina radula, Gigartina stellata. Yellow-whte when powdered. Sol in water @ 80'; insol in org solvs. Dried, bleached Cbondms crispus containing salts of sulfated polygalactose esters. SYNS: 3,G-ANHMRO-d-GALACTAN 0 AUBYGEL GS 0 AUBYGUM DM 0 BURTONITE-V-40-E 0 CARASTAY 0 CAMSTAY G 0 CARRAGEENAN (FCC) 0 CARRAGEENAN GUM 0 CARRAGHEANIN 0 CARRAGHEEN 0 CARRAGHEENAN 0 CHONDRUS 0 CHONDRUS EXTRACT 0 COLLOID 775 0 COREINE 0 EUCHEUMA SPINOSUM GUM 0 FLANOGEN ELA 0 GALOZONE 0 GELCARIN 0 GELCARIN HMR 0 GELOZONE 0 GENU 0 GENUGEL 0 GENUGEL CJ 0 GENUGOL RLV 0 GENUVISCO J 0 GUM CARRAGEEXAN 0 GL'M CHON 2 0 GUM CHROND 0 IRISH GUM 0 IRISH MOSS EXTRACT 0 IRISH MOSS GELOSE 0 KILLEEN 0 LYGOiMME CDS 0 PEARLPUSS 0 PELLUGEL 0 PENCOGEL 0 PIG-WRACK 0 SATIAGEL GS 350 0 SATWGUM 3 0 SATIAGUM STANDARD 0 SEAKEM CARRAGEENIN 0 SEATREM 0 SELF ROCK MOSS 0 VISCARIN
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 10,181,76. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. When heated to decomposition it emits acrid smoke and fumes.
CCL500 HR: 3 CARRAGEENAN, DEGRADED PROP: Carrageenan derived from Eucbeuma spinosum, degraded by acid hydrolysis; average molecular weight 20,000-40,000 (CALEDQ 4,171,78). CONSENSUS REPORTS: IARC Cancer Review: Animal Sufficient Evidence IMEMDT 31,79,83. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. See also CARRAGEEN. When heated to decomposition it emits toxic fumes of SO,. CCL750 CAS: 8015-88-1 HR: 1 CARROT SEED OIL PROP: Distilled from the seeds of Daucus carota L (Fam. Umbel&rae) (FCTXAV 14,659,76). Light-yellow to amber liquid; aromatic odor. Sol in fixed oils, mineral oil; insol in glycerin, propylene glycol. SYNS: DAUCUS OIL 0 OILS, CARROT CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A skin irritant. When
heated to decomposition it emits acrid smoke and irritating fumes.
CCMOOO CAS: 499-75-2 HR: 3 CARVACROL mf: CmH140 mw: 150.24 PROP: Colorless to pale-yellow liquid; spicy thymol odor. D: 0.974-0.980, mp: 3.5', bp: 237-238', refr index: 1.521-1.526, flash p: 212'F. Sol in alc, ether; insol in water. SYNS: 2-p-CYMENOL 0 F E i W No. 2245 0 2HYDROXY-p-CYMENE 0 ISOPROPYI-o-CRESOL 0 5ISOPROPYL-2-METHYLPHENOL 0 ISOTHYMOL 0 2METHYL5-ISOPROPYLPHENOL 0 o-THYMOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion, intravenous, and subcutaneous routes. Moderately toxic by skin contact. A severe s h n irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
CASSIA OIL
CCM100 CAS: 2244-16-8 HR: 3 d-CARVONE mf: C 1 o H 1 4 0 mw: 150.24 PROP: Colorless liquid or oil; caraway odor. D: 0.956-0.960, bp: 230', refr index: 1.96-1.499. Sol in propylene glycol, fxed oils; misc in alc; insol in glycerin. SYNS: (+)-CARVONE 0 d(+)-CARVONE 0 (S)CARVONE 0 (S)-(+)-CARVONE 0 FEhf.4 No. 2249 0 d-pMENTHA-6,8,(9)-DIEN-2-ONE 0 d-l-METHYL-4ISOPROPENYL-6-CYCLOHEXEN-2-ONE 0 (S)-2-
CC0750 295
1.498-1.504, bp: 118-119" @? 9.7 mm, flash
p: 206'F. Sol in alc, ether; insol in water. SYNS: p-CARYOPHYLLENE p c c ) FEW, NO. 2252 8-METHYLENE-4,11,11-(TRIMETHYL)BICYCLO(7.2.0)CNDEC-4-EXE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
SIETHYL-5-(l-METHYLETHENYL)-2-CYCLOHEXEN-l ONE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion and
skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
CCMl2O CAS: 6485-40-1 HR: 3 I(-)-CARVONE mf: C10H140 mw: 150.22 PROP: Colorless liquid or oil; spearmint odor. D: 0.956-0.960, bp: 230-231', refr index: 1.495-1.499. Sol in propylene glycol, fixed oils; misc in alc; insol in glycerin. SYNS: (-)-CARVONE
0 1-CARVONE 0 (R)-CARVONE
1-6,8(9)-p-MENTHADIEN-2-ONE 0 (R)-(-)-P-MENTHA-~,~-DIEN-~-ONE 0 1-1-hfETHYL-4ISOPROPENYL-6-CYCLOHEXEN-2-ONE 0 (€9-2METHYI-5-(l-hfETHYLETHENYL)-2-CYCLOHEXEN-I0 FEMA No. 2249 0
ONE (9CI)
SAFETY PROFILE: Poison by intravenous route. Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes.
CCNOOO CAS: 87-44-5 HR: 1 CARYOPHYLLENE mf: C15H26 mw: 206.41 PROP: Colorless to sltly yellow oily liquid; clove odor. Found in oil of clove, cinnamon leaves, and copaiba balsam, and in minor quantities in various other essential oils, especially lavender; prepared by isolation from clove leaf oil, clove stem oil, cinnamon leaf oil, or pine oil fractions (FCTXAV 11,1011,73).D: 0.897-0.910, refr index:
CCN100 CAS: 1139-30-6 HR: 1 PCARYOPHYLLENE EPOXIDE mf: C 1 5 H 2 4 0 mw: 220.39 PROP: Crystals. Mp: 63.5-64'. SYNS: CARYOPHYLLENE EPOXIDE 0 CARYOPHYLLENE OXIDE 0 (-)-CARYOPHYLLENE OXIDE p-CARYOPHYLLEXE OXIDE EPOXYCARYOPHYLLENE 0 (-)-EPOXYDIHYDROCARYOPHYLLENE 0 5-OXATRICYCLO(8.2.0.04,6)DODECANE, 4,12,12-TRIMETHYL9-METHYLENE-, (1R,4R,bR,lOS)4,ll ,I 1-TRIMETHYL8-METHYLENE-5OXATRI-CYCLO(8.2.0.0(4,6))DODECANE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low toxicity by
ingestion and skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
CC0500 HR: D CASCARILLA OIL PROP: From steam distillation of bark of Croton cascariba Benn. or Cmton eluteria Benn. (Fam. Euphorbiaceae). Light yellow to brown liquid; spicy odor. Sol in fured oils; insol in glycerin, propylene glycol. SYN: SWEETWOOD BARK OIL SAFETY PROFILE: When heated to
decomposition it emits acrid smoke and irritating fumes.
CC0750 CAS: 8007-80-5 HR: 3 CASSIA OIL PROP: Chef constituent is cinnamic aldehyde, found in the leaves and twigs of Cinnamomum cassia blume (FCTXAV 13,91,75). Yellow liquid; cinnamon odor, spicy burning taste. Sol in fxed oils,
296 CCPOOO CASTOR BEAN propylene glycol; insol in glycerin, mineral Oil.
SYNS: ARTIFICIAL CINNAMON OIL 0 CINNAMON BARK OIL 0 CINNAMON BARK OIL, CEYLON TYPE (FCC) 0 CINNAMON OIL 0 KASSIA OEL ( G E R i V ) 0 OIL O F CASSIA 0 OIL OF CHINESE CINNAMON 0 OIL OF CINNAiMON 0 OIL OF CINNhhlON, CEYLON 0 OILS, CINNAMON CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by shn contact.
Moderately toxic by ingestion and intraperitoneal routes. A human s h n irritant. Mutation data reported. See also CINNAMALDEHYDE and ALDEHYDES. When heated to decomposition it emits acrid smoke and irritating fumes.
CCPOOO HR: 3 CASTOR BEAN DOT: UN 2969 PROP: An annual may grow higher than 15 feet. The large, lobed leaves may be 3 feet across. The spiny seed pods grow in clusters and contain plump seeds that are white with brown or black mottling. The seeds have a pleasant taste. SYNS: AFRICAN COFFEE TREE
0
CASTOR BEANS
(DOT) 0 CASTOR FLAKE (DOT) 0 CASTOR MEAL (DOT) 0 CASTOR OIL PLANT 0 CASTOR POMACE
(DOT 0 HIGUERETA (CUBA, PUERTO RICO) 0 HIGUERILLA (MEXICO) 0 KOLI W W A I I ) 0 LA'AU' A I M (HAWAII) 0 hWN'S MOTHERWORT 0 MEXICO WEED 0 PA'AILA (HAWAII) 0 PA4LMrZCHRISTI (HAITI) 0 RICIN (HAITI) 0 RICINO (PUERTO RICO) 0 RICINUS CObLMUNIS 0 STEADFAST 0 WONDER TREE
DOT CLASSIFICATION: 9; Label: None SAFETY PROFILE: Deadly poison by ingestion in humans. The seeds contain the deadly poison ricin, a plant lectin
(toxalbumin) which inhibits protein synthesis in the intestinal wall. Ingestion of the seeds can cause after a delay period of several hours: nausea, vomiting, diarrhea, and intestinal dysfunction. There may be massive fluid and electrolyte loss. Ingestion of as few as 2 seeds could be fatal. A potent allergen. When heated to decomposition it emits toxic fumes of NO,. See also RICIN.
CCP250 CAS: 8001-79-4 HR: 1 CASTOR OIL PROP: From seeds of Ricinus commzlnis L (Fam. Eupphorbiaceae).A colorless to paleyellow, viscous liquid; bland taste, characteristic odor. Mp: -12', bp: 313', flash p: 445'F (CC), d: 0.96, autoign temp: 840'F. Sol in alc; misc in abs alc, glacial acetic acid, chloroform, and ether. SYNS: AROMATIC CASTOR OIL 0 CASTOR OIL AROMATIC 0 COSMETOL 0 CRYSTAL 0 0 GOLD BOND 0 NCIX55163 0 NEOLOID 0 OIL O F PALMA CHRISTI 0 PHORBYOL 0 RICINUS OIL 0 RICIRUS OIL 0 TANGAUTANGAN OIL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An allergen. A human
skin and eye irritant. Combustible when exposed to heat. Spontaneous heating may occur. To fight fire, use CO2, dry chemical, fog, mist. See also CASTOR BEAN.
CCP850 CAS: 120-80-9 HR: 3 CATECHOL mfi C~H602 mw: 110.12 PROP: Colorless crystals or needles from water. Mp: 105O, bp: 240°, flash p: 261°F (CC), d: 1.341 @ 15', vap press: 10 mm @ 118.3', vap d: 3.79. Sol in water, chloroform, and benzene; very sol in alc and ether. SYNS: a-BENZENEDIOL 0 12-BENZENEDIOL 0 CATECHIN 0 C.I. 76500 0 C.I. OXIDATION BASE 26 0 a-DIHYDROXYBENZENE 0 1,2-DIHYDROXYBENZENE 0 o-DIOXYBENZENE 0 o-DIPHENOL 0 DURAFUR DEVELOPER C 0 FOURAMINE PCH 0 FOURRINE 68 0 0-HYDROQUINONE 0 0-HYDROXYPHENOL 0 2HYDROXYPHENOL 0 NCI-C55856 0 OXYPHENIC ACID 0 PELAGOL GREY C 0 0-PHENYLENEDIOL 0 PYROCATECHIN 0 PYROCATECHINIC ACID 0 PYROCATECHOL 0 PYROCATECHUIC ACID CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 15,155,77. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 5 ppm (skin) ACGIH TLV: TWA 5 ppm (shn); Animal Carcinogen
CEFTIOFUR CCS575 297 SAFETY PROFILE: Poison by ingestion,
subcutaneous, intraperitoneal, intravenous, and parenteral routes. Moderately toxic by shn contact. Experimental reproductive effects. Can cause dermatitis on skin contact. An allergen. Human mutation data reported. Questionable carcinogen. Systemic effects sirmlar to those of phenol. Combustible when exposed to heat or flame; can react vigorously with oxidizing materials. Hypergolic reaction with concentrated nitric acid. To fight fire, use water, COa, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also PHENOL. CCP900 CAS: 2050-46-6 HR: 1 CATECHOL DIETHYL ETHER mf: C10H1402 mw: 166.24 PROP: Crystals. Mp: 43-45', bp: 2 1 9 O , d: 1.o. SYNS: BENZENE, o-DIETHOXY- 0 BENZENE, 1,2DIETHOXY-(9CI) 0 o-DIETHOXYBENZENE 0 1,2DIETHOXYBENZENE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
CCQBOO CAS: 8007-20-3 HR: 2 CEDAR LEAF OIL PROP: Constituent is d-a-thujone, found in leaves of Thtlja accidentalis L (Fam. Ctlpremzaceae) (FCTXAV 12,807,74). Yellowish, volatile oil; strong sage odor. D: 0.910-0.920. Sol in fixed oils, mineral oil, propylene glycol; insol in glycerin. SYNS: OIL OF ARBOR VITAE 0 OIL OF CEDAR LEAF 0 OILS, CEDAR LEAF 0 OIL THUJA 0 OIL OF THUJA 0 OIL OF WHITE CEDAR 0 THUJA OIL 0 WHITE CEDAR OIL
decomposition it emits acrid smoke and fumes. See also ARTEMISIA OIL. CCR5lO CAS: 29597-36-2 CEDR-8-ENE EPOXIDE
HR: 1
SYNS: ANDRANE 0 CEDWVE, 8,9-EPOXIDE CONSENSUS REPORTS: Reported in
EPA TSCA Inventory. SAFETY PROFILE: Very low toxicity by ingestion and skin contact. A s h n irritant. When heated to decomposition it emits acrid smoke and irritating fumes. CCR524 CAS: 39900-38-4 CEDROL FORMATE mf: C16H2602 mw: 250.42 PROP: Cosmetic chemical.'
HR: 1
SYNS: CEDRYL FORMATE 0 lH-3-a-7-METHANOAZULEN-6-OL,OCTAHYDRO-3,6,8,8-TETRAMETHn-, FORMATE, (3R-(3-a-3a-P,6-a-7-P,8aa-))CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Very low toxicity by ingestion and s h n contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
CCR525 CAS: 67874-81-1 HR: 1 CEDROL METHYL ETHER mf: CI6H28O mw: 236.44 PROP: Colorless to pale yellow liquid. D: 0.97. SYNS: CEDRAMBER 0
lH-3a,7-METHANOAZULENE,
OCTAHYDRO-~-METHOXY-~,G,~,~-TETRAIV~ETHYL-,(~ (3-a-3a-P,6-a-7-P,8aa;))-
0 METHYLCEDRYLETHER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
TSCA Inventory.
ccs575 CEFTIOFUR PROP: Powder.
SAFETY PROFILE: Moderately toxic by ingestion and skin contact. A s h n irritant.
SAFETY PROFILE: When heated to decomposition it emits acrid smoke and
Ingestion of large quantities causes hypertension, bradycardia, tachypnea, convulsions, death. When heated to
irritating fumes.
CONSENSUS REPORTS: Reported in EPA
HR: D
298
CCT250 CELLOPHANE
CCT250 CAS: 9005-81-6 CELLOPHANE mf: ( C 6 H 1 0 0 j ) n
HR: 2
SYN: VISKING CELLOPHANE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Questionable
carcinogen with experimental tumorigenic data by implant. See also POLYMERS. When heated to decomposition it emits acrid smoke and irritating fumes.
CHROMEDIA CF 11 0 CUPRICELLULOSE 0 ELCEMA F 150 0 ELCElMA G 250 0 ELCEMA P 050 0 ELCEMA P 100 0 FRESENIUS D 6 0 HEWETEN 10 0 HYDROXYCELLULOSE 0 KINGCOT 0 LA 01 0 MN-CELLULOSE 0 ONOZUKA P 500 0 PYROCELLULOSE 0 RAYOPHANE 0 RAYWEB Q 0 REXCEL 0 SIGMACELL 0 SOLKA-FIL 0 SOLKA-FLOC 0 SOLKA-FLOC BW 0 SOLKA-FLOC BW 20 0 SOLKA-FLOC BW 100 0 SOLKAFLOC BW 200 0 SOLKA-FLOC BW 2030 0 SPARTOSE OW22 0 SULFITE CELLULOSE 0 TOMOFAN 0 TUNICIN 0 WHATMAN CC-31
OSHA PEL: Total Dust: 15 mg/m3;
Respirable Fraction: 5 mg/m3 CCUO50 CAS: 9004-38-0 HR: D CELLULOSEACETATE MONOPHTHALATE PROP: K h t e powder. Insoluble in water. SYNS: ACETYL PHTHALYL CELLULOSE 0 CAPWAKO 0 CELLACETATE O CELLULOSE, ACETATE (%I) 0 HYDROGEN 1,2-BENZENEDICARBOXYLATE CELLULOSE, ACETATE PHTHALATE 0 CELLULOSE ACETOPHTHALATE 0 CELLCLOSE ACETYLPHTHAL ATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An experimental teratogen. When heated to decomposition it emits acrid smoke and irritating fumes.
ccu100 HR: 1 CELLULOSE, MICROCRYSTALLINE PROP: Fine white crystalline powder from treatment of a-cellulose with mineral acids. Insol in water, most org solvs. SYN: CELLULOSE GEL SAFETY PROFILE: A nuisance dust. When
heated to decomposition it emits acrid smoke and irritating fumes. CCU150 CAS: 9004-34-6 HR: 1 CELLULOSE, POWDERED PROP: Fine white fibrous particles from treatment of bleached cellulose from wood or cotton. Insol in water and most org solvs. SYNS: ABICEL 0 P-AMYLOSE 0 ARBOCEL 0 ARBOCEL BC 200 0 ARBOCELL B 600/30 0 AVICEL 0 AVICEL 101 0 AVICEL 102 0 AVICEL PH 101 0 AVICEL PH 105 0 CELLEX MX 0 &CELLULOSE 0 CELLULOSE 248 0 CELLULOSE (ACGIH,OSHA) 0 CELLULOSE CRYSTALLINE 0 CELUFI 0 CEPO 0 CEPO CFM 0 CEPO S 20 0 CEPO S 40 0 CHROMEDIA CC 31 0
ACGIH TLV: TWA (nuisance particulate) 10
mg/m3 of total dust (when toxic impurities are not present, e.g., quartz <1%) SAFETY PROFILE: A nuisance dust. When heated to decomposition it emits acrid smoke and irritating fumes. CCU250 CAS: 9004-70-0 HR: 3 CELLULOSE TETRANITRATE DOT: UN 0340/UN 0341/UN 0342/UN 0343/UN 2059/UN 2555/UN 2556/UN 2557 mf: Ci2H16(ON02)406 mw: 504.3 PROP: m t e , amorphous solid. D: 1.66, flash p: 55'F. SYNS: AS 0 C 2018 0 CA 80-15 0 CELEX 0 CELLOIDIN 0 CELLULOSE NITRATE 0 CELLULOSE, NITRATE (9CI) 0 COLLODION 0 COLLODION CO?TON 0 COLLODION WOOL 0 COLLOXYLIN 0 CORIAL EM FINISH F 0 E 1440 0 FLEXIBLE COLLODION 0 FM-NTS 0 GUNCOTTON 0 HX 3/5 0 KODAK LR 115 0 LR 115 0 NITROCELLULOSE, dry or wetted with <25% water (or alcohol), by weight (UN 0340) (DOT) 0 NITROCELLULOSE, plasticized with not <18% plasticizing substance, by weight (UN 0343) (DOT) 0 NITROCELLULOSE, solution, flammable with not >12.6% nitrogen, by weight (UN 2059) (DOT) 0 NITROCELLULOSE, unmodified or plasticized with
12.6% nitrogen (UN 2556) (DOT) 0 NITROCELLULOSE with plasticizing not <18% plasticizing substance, by weight (UN 2557) (DOT) 0 NITROCELLULOSE with water not <25% water, by weight (UN 2555) (DOT) 0 NITROCELLULOSE E950 0 NITROCOTTON 0 NITRON 0 NITRON (NITROCELLULOSE) 0 NIXON N/C 0 NTs 62 0 NTs 218 0 NTs 222 0 NTs 539 0 NTs 542 0 PARLODION 0 PYRALIN PYROXXIN RF 10 RS R.S. NITROCELLULOSE 0 SOLUBLE GUN CO'ITON 0 SS 0 SYNPOR 0 TSAPOLAK 964 0 XYLOIDIN
CERIUM CCY250 299 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: EXPLOSIVE 1.1D; Label: EXPLOSIVE 1.1D (UN 0340, UN 0341); DOT Class: EXPLOSIVE 1.3C; Label: EXPLOSIVE 1.3C (UN 0343, UN 0342); DOT Class: 3; Label: Flammable Liquid (UN 2059); DOT Class: 4.1; Label: Flammable Solid (UN 2556, UN 2557, UN 2555) SAFETY PROFILE: Very low oral toxicity. Flammable solid. Highly dangerous fire hazard in the dry state when exposed to heat, flame, or powerful oxidizers. When wet with 35% of denatured ethanol it is about as hazardous as ethanol alone or gasoline. Dry cellulose tetranitrate burns rapidly with intense heat and ignites easily. Moderately dangerous explosion hazard. To fight fire, use copious volumes of water; alcohol foam. COZis effective in extinguishing fires of nitrocellulose solvents. See also EXPLOSIVES, HIGH.
ccw250 HR: 3 CEMENT (rubber) PROP: Flash p: 50'F or less. SYNS: CEMENT, RUBBER 0 RUBBER CEMENT SAFETY PROFILE: May contain benzene or other toxic solvents. See specific constituent. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials.
ccxooo CAS: 123-03-5 HR: 3 CEPACOL CHLORIDE mf: C21H3gN*C1 mw: 340.05 PROP: A solid. Mp: 87-88'. Sol in water. SYNS: ACETOQUAT CPC 0 AKTIVEX 0 AMMONYX CPC 0 BIOSEPT CEEPRYN 0 CEEPRYN CHLORIDE 0 CEPRIM 0 CETAMIUM 0 CETYLPYRIDINIUM CHLORIDE 0 N-CETYLPYRIDINIUM CHLORIDE 0 1CETYLPYRIDINIUM CHLORIDE 0 DOBENDAN 0 HEXADECYLPYRIDINIUM CHLORIDE 0 n-HEXADECYLPYRIDINIUM CHLORIDE 0 I-HEXADECYLPYRIDINIUM CHLORIDE 0 INTEXSAN CPC 0 PRISTACIN 0 PYRISEFT 0 QUATEfLUARIO CPC
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
SAFETY PROFILE: Poison by ingestion, intraperitoneal, subcutaneous, and intravenous routes. Moderately toxic by skin contact. A skin and eye irritant. When heated to decomposiuon it emits very toxic fumes of NO, and C1-.
E
CCX500 CAS: 21593-23-7 HR: 2 CEPHAPlRlN mfi C I ~ H I ~ N ~ ~ Gmw: S Z 423.49 PROP: Crystals from MezCO (a$. Mp: 155'. SYNS: CEFAPIRIN (GERMAN) 0 3-(HYDROXYMETHYL)-8-OXO-7-(2-(4-PYRIDYLTHIO)ACETAMIDO)-5THU-1 -AZABICYCL0(4.2.0)0CT-2-ENE-2-CARBOXYLIC ACID, ACETATE (ESTER)
SAFETY PROFILE: Moderately toxic by intraperitoneal route. Human systemic effects by intravenous route: jaundice. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of NO, and SO,.
CCY250 CAS: 7440-45-1 HR: 3 CERIUM af: Ce aw: 140.13 PROP: Malleable gray metal, forms lustrous crystals that tarnish in air. Cubic or hexagonal, steel-gray crystals. Mp: 804', bp: 3433', d: (cubic form): 6.90, hexagonal form: 6.75. Reacts with moist air readily and with HzO (slow in cold), acids, and alkalies. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Cerium resembles aluminum in its pharmacological action as well as in its chemical properties. The insoluble salts such as the oxalates are stated to be nontoxic even in large doses. It is used to prevent vomiting in pregnancy. The average dose is from 0.05 to 0.5 g. The effect on the central nervous system of the rare-earth metals following inhalation may preclude welding operations with these materials to any large extent. Cerium is stated to produce polycythemia but is useless in the treatment of anemia owing to its toxic effects. The salts of cerium increase the blood coagulation rate. See also RARE
300
CCYSOO CERIUM ACETATE
EARTHS. A strong reducing agent. Moderate fire hazard; ignites spontaneously in air at 150-180'. Moderate explosion hazard in the form of dust when exposed to flame. The metal or its alloys spark with friction. Many alloys are pyrophoric in air. See also IRON DUST. Explosive reaction with zinc. Very exothermic reaction with antimony or bismuth. Ignites when heated in atmospheres of CO2 + Nz, Clz, or Brz. Violent reaction when heated with phosphorus (4OO0C), silicon (1400'C).
CCY500 CASE537-00-8 HR: 3 CERIUM ACETATE mf: C~Hg06*Ce mw: 317.27 PROP: White powder. Sol in water. SYNS: CERIUM TRIACETATE 0 CEROUS ACETATE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Human central nervous system effects. See also CERIUM COMPOUNDS, When heated to decomposition it emits acrid and irritating fumes.
CCY750 CAS: 7790-86-5 HR: 3 CERIUM CHLORIDE mf: CeCL mw: 246.47 PROP: Colorless or white solid or deliquescent crystals. Mp: 722', bp: 1705', d: 3.92. Sol in water and THF. SYNS: CERICM(I1T) CHLORIDE 0 CERIUM TRICHLORIDE 0 CEROUS CHLORIDE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intravenous, intraperitoneal, and subcutaneous routes. Moderately toxic by ingestion. See also CERIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of C1-.
cczooo
CAS: 512-24-3 CERIUM CITRATE mf: C6HsOi.*Ce mw: 332.26
HR: 3
SYNS: CERIUMQIT) CITRATE 0 CEROUS CITRATE 0 2-HYDROXY-l,2,3-PROPASETRISCARBOXYLIC ACID CERIUM(3+) SALT (1:l) (9CT)
SAFETY PROFILE: Poison by intraperitoneal route. Experimental reproductive effects. See also CERIUM COMPOUNDS. When heated to decomposition it emits acrid and irritating fumes.
CDA250 HR: 2 CERIUM COMPOUNDS PROP: Compounds of cerium and the other rare-earth elements are generally of low toxicity. The greatest exposures are likely to be during manufacture of cerium. Exposed workers have experienced sensitivity to heat, itching, and slun lesions. Large doses to experimental animals have caused writhing, ataxia (loss of muscle coordination), labored respiration, sedation, hypotension, and death by cardiovascular collapse. The chloride, bromide, nitrate, bromate, and perchlorate salts are water soluble and thus are more likely to cause systemic effects when ingested. The sulfates, iodides, and iodates are less water soluble. Oxides, oxalates, sulfides, carbonates, fluorides, and phosphates are insoluble. The salts of cerium increase the blood coagulation rate. Cerium tartrate has been found to produce a direct injurious action on the hearts of small animals. Cerium oxalate has been used to suppress motion sickness and to suppress vomiting during pregnancy (by ingestion of 1 g/24 hr). The toxicity of cerium compounds may be taken to be that of cerium, except when the anion has a toxicity of its own. See also CERIUM and RARE EARTHS. CDA750 CAS: 7758-88-5 HR: 1 CERIUM FLUORIDE mf: CeF3 mw: 197.12 PROP: White, hexagonal crystals or solid. D: 6.16, mp: 1460°, bp: 2300'. Insol in water; sol in H2S04. SYNS: CERIUM FLUORURE (FRENCH) 0 CERIUM TRIFLUORIDE 0 CEROUS FLUORIDE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
CESIUM ARSENATE OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3
mg/g creatinine of fluorides in urine prior to shft; 10 mg/g creatinine of fluorides in urine at end of shift. NIOSH REL: (Inorganic Fluorides) TWA 2.5 m g O /m3 SAFETY PROFILE: Low toxicity by ingestion. See FLUORIDES and CERIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of F-. CDBOOO CAS: 10108-73-3 HR: 3 CERIUM(III) NITRATE mf: N309*Ce mw: 326.15 SYNS: CERIUM NITRATE 0 CERIUM(S+) NITRATE 0 CERIUM TRINITRATE 0 CEROUS NITRATE 0 DUSICNAS CERITY (CZECH) 0 NITRIC ACID, CERIUM(S+) SALT (8CI,9CI)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous
and intraperitoneal routes. Moderately toxic by ingestion. Experimental reproductive effects. See also CERIUM COMPOUNDS and NITRATES. When heated to decomposition it emits toxic fumes of NO,. CDB400 CAS: 13590-82-4 HR: D CERIUM(IV) SULFATE mf: OsSpCe mw: 332.24 PROP: Yellow crystals or powder. Sol in H20. SYNS: CERIC DISCLFATE
0 CERIC SULFATE 0
CERIC SULPHATE 0 CERIUM DISULFATE 0 CERIUhl SULFATE 0 CERIUM(4+) SULFATE 0 SULFURIC ACID, CERIUM SALT (2:l)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROF1LE : Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes.
CDCOOO CAS: 7440-46-2 CESIUM DOT: E N 1407 af: Cs aw: 132.91
HR: 3
CDC375 301
PROP: Bright, shiny, hexagonal crystals;
silver-white, ductile metal; or possibly a silvery liquid. Golden when ultra pure. Spontaneously ignites in the atmosphere forming cesium oxides, carbonates and hydroxide. Mp: 28.5', bp: 668', d: 1.873, vap press: 1 mm @ 279'. Reacts violently with H z 0 forming CsOH and dihydrogen. SYN: CESIUM-133 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 4.3; Label: Dangerous When Wet SAFETY PROFILE: Moderately toxic by intraperitoneal route. Cesium is quite similar to potassium in its elemental state. It has been shown, however, to have pronounced physiological action in experimentation with animals. Hyper-irritability, including marked spasms, has been shown to follow the administration of cesium in amounts equal to the potassium content of the diet. It has been found that replacing the potassium in the diet of rats with cesium caused death after 10-17 days. Ignites spontaneously in air. Violent reaction with water, moisture, or steam releases hydrogen gas whch explodes. Violent reaction with acids, halogens, and other oxidizing materials. Incandescent reaction with nonmetals (e.g., sulfur, phosphorus). See also SODIUM.
CDC375 CAS: 61136-62-7 HR: 3 CESIUM ARSENATE mf: As04*3Cs mw: 537.65 SYN: ARSENIC ACID, TRICESIUM SALT CONSENSUS REPORTS: Arsenic and its compounds are on the Community &ghtTo-Know List. OSHA PEL: OSHA: Cancer Hazard SAFETY PROFILE: Poison by ingestion. Experimental teratogenic effects by inhalation. When heated to decomposition it emits toxic fumes of As. See also ARSENIC COMPOUNDS and CESIUM.
E
302
CDCSOO
CESIUM BROMIDE
CDCSOO CAS: 7787-69-1 HR: 2 CESIUM BROMIDE mf: BrCs mw: 212.82 PROP: Deliquescent colorless cubic crystals. Mp: 636', bp: 1300'. Very sol in water. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by intraperitoneal route. See also CESIUM and BROMIDES. When heated to decomposition it emits toxic fumes of Br-. CDC750 CAS: 534-17-8 HR: 2 CESIUM CARBONATE mf: COp2Cs mw: 325.83 PROP: Deliquescent colorless monoclink crystals. Very sol in H20; sol in EtOH and Et20.
SYNS: CARBONIC ACID, DICESIUM SALT 0 DICESIUN CARBONATE CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and fumes. See also CESIUM.
CDDOOO CAS: 7647-17-8 HR: 2 CESIUM CHLORIDE mf: ClCs mw: 168.36 PROP: Deliquescent cubic crystals. Undergoes transition to high temp polymorph at 4'. D: 3.99, mp: 646', bp: 1209'. Very sol in HzO, MeOH, and EtOH; insol in Me2CO. SYNS: CESIUM MOSOCHLORIDE 0 DICESIUM DICHLORIDE 0 TRICESIUM TRICHLORIDE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Experimental reproductive effects. Mutation data reported. Reacts violently with BF3. See also CESIUM. When heated to decomposition it emits toxic fumes of C1-.
CDD500 CAS: 13400-13-0 HR: 3 CESIUM FLUORIDE mf: CsF mw: 151.91 PROP: Deliquescent colorless cubic crystals. Mp: 703", bp: 1251". Very sol in H20 and MeOH; insol in Py. SYNS: CESIUM MONOFLUORIDE 0 DICESIUM DIFLUORIDE 0 TRICESIUM TRIFLUORIDE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 2.5 mg(F)m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shft. NIOSH REL: (Inorganic Fluorides) TWA 2.5 mg(F) /m3 SAFETY PROFILE: A poison. Incompatible with benzenediazonium tetrafluoroborate and difluoroamine. When heated to decomposition it emits toxic fumes of F-.
CDD750 CAS: 21351-79-1 HR: 3 CESIUM HYDROXIDE DOT: UN 2681/UN 2682 mf: CsHO mw: 149.92 PROP: Colorless to yellowish, very deliquescent crystals. Undergoes transition from orthorhombic to cubic at 2'. Mp: 315', d: 3.675. Very sol in HzO and EtOH. SYNS: CAESIEM HYDROXIDE, sohd (UK2682) (DO1) 0 CAESIUhf HYDROXIDE, solution (UN 2681) (DOT) 0 CESIUM HYDRATE 0 CESIUM HYDROXIDE (ACGIH, OSHA) 0 CESIUM HYDROXIDE DINER
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 2 mg/m3 ACGIH TLV: TWA 2 mg/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. A powerful caustic. A corrosive s h n and eye irritant. See also CESIUM.
CDEOOO CAS: 7789-17-5 CESIUM IODIDE mf: CsI mw: 259.81
HR: 2
CHAMOMILE OIL (ROMAN) CDH750 303 PROP: Deliquescent colorless orthorhombic
DOT CLASSIFICATION: 3; Label:
crystals. Mp: 626', bp: 1280'. Very sol in H20; sol in EtOH.
Flammable Liquid
SYNS: CESIUM MONOIODIDE 0 DICESICM DIIODIDE 0 TRICESIUM TRIIODIDE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: Proposed: (inhalable fraction) 0.1 mg/m3; Not Classifiable as a Human Carcinogen) SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. See also CESIUM and IODIDES. When heated to decomposition, it emits toxic fumes of I-.
CDE250 CAS: 7789-18-6 HR: 2 CESIUM(1) NITRATE (1:1) DOT: UN 1451 mf: NOpCs mw: 194.92 PROP: Colorless, hexagonal or cubic, glittering crystalhe powder. Undergoes hexagonal to cubic transition at 1'. Piezoelectric. Mp: 414', bp: decomp, d: 3.685,2.71 @ 500' (lid.Very sol in H20; sol in Me2CO; sltly sol in EtOH. SYNS: CESIUM NITRATE (DO?? 0 NITRIC ACID, CESIUM SALT
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also CESIUM and NITRATES.
SAFETY PROFILE: Poison by intravenous route. See also KETONES. When heated to decomposition it emits acrid smoke and irritating fumes.
CDHSOO CAS: 8002-66-2 HR: 1 CHAMOMILE OIL PROP: By steam disullation of the flowers and stalks of Matdana chamomilla L. (FCTXAV 12,807,74). Blue-yellowish-brown liquid; strong odor and bitter aromatic taste. Composed of amyl and butyl esters of angelic, tiglic acids, and butyric acid. D: 0.905-0.915 @ 15'/15'. Sol in fixed oils, propylene glycol; insol in mineral oil, glycerin. SYNS: BLUE CHAMOMILE OIL 0 CAMOMILE OIL GERMAN 0 CHi4XlOMILE-GERbWN OIL 0 GERMAN CHAMOMILE OIL 0 HLXGARIAN CHAMOMILE OIL 0 KAhlILLENOEL 0 OILS, CK4MOMILE, GERMAN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low toxicity by ingestion and skin contact. A mild allergen. A skin irritant. See also ESTERS. When heated to decomposition it emits acrid and irritating fumes.
CDH750 CAS: 8015-92-7 HR: 1 CHAMOMILE OIL (ROMAN) PROP: Obtained by the steam disullation of the dried flowers of Anthemis nobilis L. (FCTXAV 12,807,74).Blue liquid, turning brownish-yellow; strong aromatic odor. Composition: Amy1 and butyl esters of CDHOOO CAS: 94-41-7 HR: 3 angelic and tiglic acids, butyric acid, etc. D: CHALCONE 0.905-0.915 @ 15'/15'. Sol in fixed oils, mf: CljH120 mw: 208.27 mineral oil, propylene glycol; insol in SYNS: 2-BENZAWCETOPHENONE 0 1-BENZOYLl- glycerin. PHENYLETHENE 0 P-BENZOYLSTIXENE 0 2SYN: CAMOMILE OIL, ENGLISH TYPE (FCC) BENZYLIDENEACETOPHENOXE 0 CINNAMOCONSENSUS REPORTS: Reported in EPA 3PHENONE 0 1,3-DIPHENYL-l-PROPEN-3-0NE TSCA Inventory. PHENUCRYLOPHENONE p-PHENYL-ACRYLOSAFETY PROFILE: Low toxicity by PHENONE 0 1-PHENYL-2-BENZOYLETHYLENE 0 ingestion and skin contact. A rmld allergen. PHENYL STYRYL KETONE CONSENSUS REPORTS: Reported in EPA A s h n irritant. See aIso ESTERS. TSCA Inventory. Combustible when heated. When heated to
304 CDIOOO CHARCOAL, ACTIVATED (DOT) decomposition it emits acrid smoke and irritating fumes.
chemical. When heated to decomposition it emits acrid smoke and fumes.
CDIOOO CAS: 64365-11-3 HR: 1 CHARCOAL, ACTIVATED (DOT) DOT: NA 1361 af: C aw: 12.01 PROP: Black porous solid, coarse granules or powder. Insol in water, org solvs.
CDJOOO CHARCOAL (SHELL) DOT: NA 1361 Spontaneously Combustible
SYNS: ACTIVATED CARBON 0 C24RBON,
SAFETY PROFILE: A flammable solid. See
ACTIVA4TED0 CARBORAFFIN 0 CARBORAFINE 0 KARBORAFIN 0 NUCHAR 722
also CHARCOAL (BRIQUETTES).
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 4.2; Label: Spontaneously Combustible SAFETY PROFILE: It can cause a dust irritation, particularly to the eyes and mucous membranes. Combustible when exposed to heat. Dust is flammable and explosive when exposed to heat or flame or oxides.
CD1250 CAS: 16291-96-6 HR: 2 CHARCOAL (BRIQUETTES) DOT: NA 1361 af: C aw: 12.01 PROP: Black amorphous solid. Composition: carbon + impurities. Mp: >3500", bp: 4200", d: 3.51. SYNS: CHARCOAL
CHARCOAL SCREENINGS (DOT 0 CHARCOAL WOOD (Dog
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 4.2; Label: Spontaneously Combustible SAFETY PROFILE: Carbon itself has no toxic action, but it contains impurities that may be toxic. Fire hazard: reacts with liquid air, Ba(C103)2, BrFj, C10, Ca(C103)2, ClF2, F2, HzOz, Mg(C103)2, ( 0 2 + wood), + air), K + perchlorates, peroxides, (I? KC103, m03,Ru04, AgNO3, NaC103, (AgC1 + NaOz), S, (S + NaN03), Zn(ClO3)z. Heats spontaneously, particularly when wet, freshly calcined, or tightly packed, and it can ignite and burn. Slight explosion hazard when exposed to heat or flame. To fight fire, use water, mist, foam, or dry
HI?: 3
SYN: CHARCOAL, SHELL (DOT DOT CLASSIFICATION: 4.2; Label:
CDM250 CAS: 1401-55-4 CHESTNUT TANNIN
HR: 3
SYNS: CASTANEA SATIVA MILL TANNIN 0 TANNIN from CHESTNUT
SAFETY PROFILE: Poison by
subcutaneous, intramuscular, intravenous, and intraperitoneal routes. Questionable carcinogen with experimental tumorigenic data. See also TANNIN. When heated to decomposition it emits acrid and irritating fumes.
CDN2OO CAS: 78-95-5 HR: 3 CHLORACETONE DOT: UN 1695 mf: C3HjC10 mw: 92.53 PROP: Colorless, lachrymatory liquid with pungent odor. Mp: -44.5", bp: 119", d: 1.162. SYNS: ACETONYL CHLORIDE 0 A-STOFF 0 CHLORACETONE CHLOROACETONE CHLOROACETONE, stabilized (DOT 0 CHLOROPROPANONE 0 1-CHLORO-2-PROPANONE0 MONOCHLORACETONE 0 MONOCHLOROACETONE 0 MONOCHLOROACETONE, inhibited (DOT) 0 MONOCHLOROACETONE, stabilized (DOT) 0 MONOCHLOROACETONE, unstabilized (DOT 0 TONITE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: CL 1 ppm (skin) DOT CLASSIFICATION: 6.1; Label: Poison (UN 1695); DOT Class: Forbidden SAFETY PROFILE: Poison by inhalation, ingestion, and skin contact. Mutation data reported. A lachrymator poison gas. See also CHLORINATED HYDROCARBONS, ALIPHATIC; ACETONE. Flammable when exposed to heat or flame, or oxidizers.
2-CHLORALL YL DIE THYLDl THlOCARBAMA TE
Old material can explode. When heated to decomposition it emits highly toxic fumes. CDNSOO CAS: 107-14-2 HR: 3 CHLORACETONITRILE DOT: UN 2668 mf: CzHzClN mw: 75.50 PROP: Fuming liquid. D: 1.193 @ 20°, bp: 126-1 27'. SYNS: CHLOROACETONITRILE(DOT,! 0 aCHLOROACETONITRILE 0 2-CHLOROACETONITRILE 0 CHLOROblETHYLCYANIDE 0 MONOCHLOROACETONITRILE 0 MONOCHLOROMETHYL CYANIDE 0 USAF KF-5
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community RightTo-Know List. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion, skin contact, and intraperitoneal routes. Moderately toxic by inhalation. A skin irritant. Human mutation data reported. Questionable carcinogen with experimental tumorigenic data. Flammable liquid. See also NITRILES. When heated to decomposition it emits very toxic fumes of C1-, NO,, and CN-.
CDN505 CAS: 1341-24-8 HR: 3 CHLORACETOPHENONE mf: CsH7C10 mw: 154.60 SYN: ETHANONE, 1-PHENYL-,MONOCHLORO DERIV.
SAFETY PROFILE: A poison by intravenous route. Low toxicity by inhalation. A mild eye irritant. When heated to decomposition it emits toxic vapors of c1-.
CDN550 CAS: 75-87-6 HR: 3 CHLORAL DOT: UN 2075 mf: CzHC13O mw: 147.38 SYNS: ACETALDEHYDE,TRICHLORO-(9CI)0 ANHYDROUS CHLORAL 0 CHLOR4L, anhydrous, inhibited (DOT,! 0 CLORALIO 0 GRASEX 0 RCRA WASTE NUMBER U034 0 TRICHLOROACETALDEHYDE 0 2,2,2-TRICHLOROACETALDEHYDE 0 TRICHLOROETHANAL
CDO250 305
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A poison. Mutation data reported.
CDOOOO CAS: 302-17-0 HR: 3 CHLORAL HYDRATE mf: C2HC13O*HzO mw: 165.40 PROP: Transparent, colorless crystals; aromatic, penetrating, sltly acrid odor and sltly bitter, caustic taste. Mp: 52', bp: 97.5', d: 1.9. SYNS: AQUACHLORAL 0 Bi 3411 0 CHLORALDURAT 0 DOILMAL 0 FELSULES 0 HYDRAL 0 HYDRAL de CHLORAL 0 KESSODRATE 0 LORIPU'AL 0 NOCTEC 0 NORTEC 0 NYCOTON 0 PHALDRONE 0 RECTULES 0 SK-CHLORAL HYDRATE 0 SObfNI SED 0 SOMNOS 0 SONTEC 0 TOSYL 0 TRAWOTOX 0 TRICHLORACETALDEHYD-HYDRAT (GERMAN) 0 TRICHLOROACETALDEHYDEHYDRATE 0 TRICHLOROACETALDEHYDEMONOHYDRATE 0 2,2,2-TRICHLORO-l,I -ETHANEDIOL
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: A human poison by ingestion and possibly other routes. Poison experimentally by ingestion, intravenous, and rectal routes. Moderately toxic by subcutaneous, parenteral, and intraperitoneal routes, Experimental reproductive effects. Human systemic effects by ingestion: general anesthetic, cardiac arrhythmias, blood pressure depression, eye effects, coma, pulse rate increase, arrhythmias. Human mutation data reported. Questionable carcinogen with experimental carcinogenic and tumorigenic data by skin contact. A sedative, anesthetic, and narcotic. Combustible when exposed to heat or flame. When heated to decomposition it emits toxic fumes of C1-.
CD0250 CAS: 95-06-7 HR: 3 2-CHLORALLYL DlETHYLDITHIOCARBAMATE mf: C8H14ClNSz mw: 223.80
E
306 CD0500 CHLORAMBUCIL PROP: Amber liauid or oil. BD: 129' 1 I
a,1 v
mm, d: 1088 @ 25'. Very sltly sol in H2O; sol in most org solvs. SYNS: CDEC 0 CHLORALLYLDIETHYLDITHIOCARBAMATE 0 2-CHLOROALLYLDIETHYLDITHIOCARBAMATE 0 2-CHLOROALLYL-N.KDIETHYLDITHIOCARBAlE 0 2-CHLORO-2PROPENE-I-THIOL DIETHYLDITHIOCARBAhtATE 0 2CHLORO-2-PROPENYL DIETHYLCARBAMODITHIOATE 0 CP 4572 0 DIETHYLCARBAMODITHIOIC ACID 2-CHLORO-2-PROPENYL ESTER DIETHYLDITHIOCARBAMIC ACID-2-CHLOROALLYL ESTER 0 NCI-COO453 0 SULFALLATE 0 THIOALLATE 0 VEGADEX 0 VEGADEX SUPER
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 30,283,83. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NCITR* NCI-CGTR-115,78. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by ingestion and s h n contact. Mutation data reported. An herbicide. When heated to decomposition it emits very toxic fumes of C1-, NO,, and SO,. See also ALLYL COMPOUNDS, CARBAMATES, and ESTERS.
CD0500 CAS: 305-03-3 HR: 3 CHLORAMBUCIL mf: C14H19ClzNOz mw: 304.24 PROP: Flattened needles from pet ether. Mp: 64-66'. Sol in EtzO. SYNS: AMBOCHLORIN 0 AMBOCLORIN 0 4-(BIS(2-
0 PHENYLBUTYRIC ACID NITROGEN MUSTARD 0 RCRA WASTE NUMBER U035
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group IMEMDT7,144,87; Human Inadequate Evidence IMEMDT 9,125,75; Human Limited Evidence IMEMDT 26,115,81; Animal Limited Evidence IMEMDT 26,115,81; Animal Sufficient Evidence IMEMDT 9,125,75. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen producing leukemia. Experimental carcinogenic and neoplastigenic data. Poison by ingestion, intravenous, intraperitoneal, and subcutaneous routes. Human systemic effects by ingestion: convulsions, cough, dyspnea, and interstitial fibrosis. Human reproductive effects by ingestion and possibly other routes: changes in spermatogenesis, menstrual cycle changes or disorders, and teratogenic effects of the fetal urogenital system. Experimental teratogenic and reproductive effects. Human mutation data reported. An anti-neoplastic agent. When heated to decomposition it emits very toxic fumes of C1- and NO,.
CDPOOO CAS: 127-65-1 HR: 3 CHLORAMINE T mf: C,HsClNO&Na mw: 228.66 PROP: Faintly yellow crystals or powder (as Na salt). Mp: 167-170" (as Na salt). Mod sol in HzO; insol in C6H6, CHCL; decomp in EtOH (Na salt).
SYNS: ACTI-CHLORE 0 AKTIVIN 0 ANEXOL BENZENESULFONAMIDE,N-CHLORO-CMETHYL-, SODIUM SALT (9C9 BERKENDYL 0 CHLORALONE CHLORASAN 0 CHLORASEPTINE CHLORAZAN CHLORAZENEOCHLORAZONEOCHLOROZONEO PHENYL)BUTYRIC ACID 0 CB 1348 0 CHLORAMINOCHLORSEPTOL 0 CLORINA CLOROSAN 0 PHEN 0 CHLOIWlMINOPHENE 0 CHLOROAMBUCIL 0 DESINFECT 0 EUCLORINA 0 GANSIL 0 GYNECHLOROBUTIN 0 CHLOROBUTINE 0 NJT-DI-2CLORINA 0 HALAMID 0 HELIOGEN KLORAMIN 0 CHLOROETHYL-y-p-AMIXOPHENYLBUTYRIC ACID 0 KLORAMINE-T 0 MCLTICHLOR SODIUM p-N,N-DI-@-CHLOROETHYL)Ah4INOPHENYL BUTYRIC CHLORUIINE T 0 SODIUM p-TOLUENESULFONYLACID 0 p-(N,X-DI-2-CHLOROETHYL)AMINOPHENYL CHLORAMIDE SODIUM TOSYLCHLORAMIDE 0 BUTYRIC ACID 0 y-@-DI(2-CHLOROETHYL)AIMINOTAMPULES TOCHLORINE 0 TOLAMINE 0 PHENYL)BUTYRIC ACID 0 ECLORIL ELCORIL 0 TOSYLCHLORAMIDE SODIUM LEUKERAN 0 LEUKERSAN LEUKORAN 0 CONSENSUS REPORTS: Reported in EPA LINFOLIZIN 0 LINFOLYSIN 0 NCI-C03485 0 NSC-3088 CHLOR0ETHYL)ltMINO)BENZENEBUTANOICACID y-@-BIS(2-CHLOROETHYL)AMINOPHENYL)BUTYRIC ACID 0 4-@-BIS@-CHLOROETHYL)A?.II;\iOPHENYL)BUTYRIC ACID 4-@-(BIS(2-CHLOROETHYL)AMINO)-
TSCA Inventory.
CHLORATES SAFETY PROFILE: Poison by parenteral and intravenous routes. Human mutagenic data reported. When heated to decomposition it emits toxic fumes of C1-, SO,, NarO, and NO,. See also SULFONATES and CHLORIDES.
CDP250 CAS: 56-75-7 HR: 3 CHLORAMPHENICOL mf: CllH12C12N20j mw: 323.15 PROP: Pale-yellow needles (H20 or 1,2dichloroethane) or crystals. Mp: 151’. Sltly sol in water. Sol in EtOH, EtOAc, and MeKO; insol in C6H6 and pet ether. SYNS: ALFICETYN 0 AMBOFEN 0 AhlPHENICOL 0 AMPHICOL 0 AXISECLOR 0 ANACETIN 0 AQUAMYCETIS 0 AUSTRACIL 0 AUSTRACOL 0 BIOCETIN 0 BIOPHENICOL 0 CAF 0 CAhI 0 CAP 0 CATIL4N 0 CHEhIICETIN 0 CHEMICETINA 0 CHLOMIN 0 CHLOMYCOL 0 CHLORAMEX 0 CHLORAMPICIN 0 CHLOIWhIFILIh 0 d-CHLOR0 AMPHENICOL 0 d-threo-CHLOR4hfPHENICOL CHLORAMSAAR 0 CHLORASOL 0 CHLORA-TABS 0 CHLORICOL 0 CHLORNITROMYCIN 0 CHLOROCAPS 0 CHLOROCID 0 CHLOROCIDIN C TETRAN 0 CHLOROCOL 0 CHLOROJECT L 0 CHLOROSMX 0 CHLOR0,MYCETIN 0 CHLORONITRIN 0 CHLOROPTIC 0 CHLOROWLES 0 CIDOCETINE 0 CIPLAMYCETIN 0 CLORAMIDINA 0 CLOROAMFENICOLO (ITALIAN) 0 CLORObIISAN 0 CLOROSINTEX 0 COMYCETIN 0 CPH 0 CYLPHENICOL 0 DESPHEN 0 DETREOMYCINE 0 DEXTROMYCETIN 0 d-(-)-threo-2DICHLOROACETAMIDO-l -p-NITROPHENYL-1,3PROPASEDIOL 0 d-threo-N-DICHLOROACETYL-1 -pNITROPHENYL-2-,~~IINO-1,3-PROPANEDIOL 0 d-(-)-
CDQOOO 307
NOVOCHLOROCAP 0 NOVOMYCETIN 0 NoVoPHENICoL NSC-3069 OmALENT OLEOMYCETIN 0 OPTHOCHLOR 0 OTOPHEN 0 PANTOVERNIL 0 PARAXIN 0 PETNAMYCETIN 0 QUEMICETINA RIVOIMYCIK ROMPHENIL SEPTICOL 0 SIXTOMICETINA 0 STANOMYCETIN 0 SYNTHOhIYCINE 0 TEVCOCIN 0 TIFOMYCINE 0 TREOMICETINA 0 U-6062 0 UNIMYCETIN 0 VETICOL
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,145,87; Human Limited Evidence IMEMDT 10,85,76. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed human carcinogen producing leukemia, aplastic anemia, and other bone marrow changes. Experimental tumorigenic data. Poison by intravenous and subcutaneous routes. Moderately toxic by ingestion and intraperitoneal routes. Human systemic effects by an unknown route: changes in plasma or blood volume, unspecified liver effects, and hemorrhaging. Experimental teratogenic and reproductive effects. Human mutation data reported. An antibiotic. When heated to decomposition it emits very toxic fumes of NO, and C1-. See also other chloramphenicol entries.
CDP700 CAS: 530-43-8 HR: 2 CHLORAMPHENICOL PALMITATE mf: C27H4~ClzN206 mw: 561.61 2,2-DICHLORO-N-(fi-HYDROXY-a-(HYDROXYMETHYL)p-NITROPHEh7YLETHYL)ACETAMIDE 0 d-(-)-threo-2,2PROP: Crystals from C6H6. Mp: 90’. DICHLORO-N-(~~-HYDROXY-~-(HE~ROXY;\IETHYL))-~SYNS: CAP-P 0 CAP-PALMITATE 0
NITROPHENETHYLACETAMIDE 0 d-threo-”(1 ,l’CHLORAMPHENICOL MONOPALMITATE 0 DIHYDROXY-1-p-NITROPHENYLISOPR0PYL)DETREOPAL 0 &ESTER PALMITIC ACID with D-threoDICHLOROACETAMIDE 0 DOCTAiiIICINA 0 (-)-2,2-DICHLORO-PU’-@-HYDROXY-a-(HYDROXYECONOCHLOR 0 EhlBACETIN 0 EMETREN 0 METHYL)-p-NITR0PHENETHYL)ACETAMIDE ENICOL 0 ENTEROVYCETIN 0 ERBAPLAST 0 SAFETY PROFILE: Moderately toxic by ERTILEN 0 FARMICETINA 0 FENICOL 0 GLOBENICoral route. An experimental teratogen. Other OL 0 GLOROUS 0 K4LOMYCETIN 0 HORTFENICOL experimental reproductive effects. An 0 I337A 0 INTRAMYCETIN 0 ISMICETIlvA 0 antibiotic. When heated to decomposition it ISOPHENICOL 0 ISOPTO FENICOL 0 KrlhWVER 0 emits very toxic fumes of NO, and C1-. See KEMICETINE 0 LEUKOMYAN 0 LEVOMYCETIN 0 also other chloramphenicol entries. LOROMISIN 0 MASTIPHEN IMEDIAMYCETINE SIICOCHLORINE 0 MICROCETINA 0 MYCHEL 0 hWCINOL 0 NCI-C55709 0 d-(-)-threo-l-p-NITROPHENYL-2-DICHLORACETrLIIID0-1,3-PROPANEDIOL 0 dthreo-l -@-NITROPHESYL-2-(DICHLOROACETYLA;1fI7VO)-l,3-PROPANEDIOL 0 NORISWCIN V 0
308 CDQOOO CHLORATES CDQOOO HR: 3 CHLORATES PROP: Chlorates are a combination of a metal or hydrogen and -c103 monovalent radical. They are crystalline and somewhat deliquescent. SAFETY PROFILE: The principal toxic effects of chlorates are the production of methemoglobin in the blood and destruction of red blood corpuscles. The latter may lead to irritation of the kidneys. Damage to heart muscle has been reported. Dangerous fire hazard in contact with flammable matter. When contaminated with oxidizable materials, they are particularly sensitive to friction, heat, and shock. They are powerful oxidning agents and can undergo violent reactions with reducing materials. Dangerous explosion hazard when shocked, exposed to heat, or rubbed, particularly when contaminated with sugar, charcoal, shellac, sulfur, starch, sawdust, sulfuric acid, ammonium compounds, cyanides, phosphorous or antimony sulfide, Al, (metals + acids), AS&, CaH2, MnOz, metal sulfides, organic acids, powdered metals, Hg3P4, PHI4, SCN, (S + Cu), Se, NaH2P02, SrH, Son. Chlorates when mixed with combustible materials may form explosive mixtures. For instance, potassium chlorate, when mixed with sulfur or with other combustible substances explodes on friction. Pure chlorates whch have been spdled on the floor, or mixed with small amounts of impurities, become very sensitive to shock and friction. Water is considered the best agent for fighting fires involving chlorates. When heated to decomposition they can emit toxic fumes of C1- and explode.
SAFETY PROFILE: Poison by ingestion,
subcutaneous, intravenous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits very toxic fumes of HC1 and NO,. CDR575 CAS: 5566-34-7 trans-CHLORDAN mf: CioH6Cl8 mw: 409.76
HR: 3
SYNS: 'y-CHLORDAX 0 y(trans)-CHLORDANE0 4,7METHANOINDAN, 2,2,4,5,6,7,8,8-OCTACHLORO-3a,4,7,7aTETRAHYDRO- 0 4,7-,\IETHANO-lH-INDENE, 2,2,4,5,6,7,8,8-OCTACHLORO-2,3,3a,4,7,7a-HEXAHMRO(9CI) 0 2,2,4,5,6,7,8,8-OCTXCHLORO-3a,4,7,7a-TETRAHYDRO-4,7-METHANOIND2W
CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 53,115,91; Animal Sufficient Evidence IMEMDT 53,115,91; Human Inadequate Evidence IMEMDT 53,115,91. SAFETY PROFILE: Confirmed carcinogen. Moderately toxic by ingestion. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of C1-. CDR750 CAS: 57-74-9 HR: 3 CHLORDANE mf: CioH6C18 mw: 409.76 PROP: Colorless to amber; odorless, viscous liquid. Bp: 175O, d: 1.57-1.63 @ 15.5'/15.5'. IDLH 100 mg/m3. SYNS: ASPON-CHLORDANE 0 BELT 0 CD 68 0 CHLOORDMN (DUTCH) 0 CHLORDAN 0 7-CHLORDAN 0 CHLORDANE, hqud (DOT) 0 CHLORINDAN 0 CHLORKILO CHLORODANEOCHLORTOXU CLORDAN (ITALLAN) 0 CLORODANE 0 CORTILANNEU 0 DICHLOROCHLORDENE DOWCHLOR 0 ENT 9,932 0 ENT 25,552-X 0 HCS 3260 KYPCHLOR 0 M 140 0 M 410 NCK00099 0 NIRAS 0 1,2,4,5,6,7,8,8OCTACHLOOR-~~,~,~,~~-TETRAHMRO-~,~-~~~OMETHANO-INDAAN (DUTCH) 0 OCTACHLOR 0 OCTACHLORODIHYDRODICYCLOPENTADIENE0 1,2,4,5,6,7,8,8-OCTACHLORO-2,3,3a,4,7,7a-HEXAHYDRO-
CDR250 CAS: 14362-31-3 HR: 3 CHLORCYCLIZINE HYDROCHLORIDE mf: C18H21ClN2*xClH mw: 556.08 SYNS: AH-289 HYDROCHLORIDE 0 CHLORCYCLIZINIUMCHLORIDE 0 1-@CHLOROBENZHYDRYL)-4-METHYLPlPERAZINE HYDROCHLORIDE 0 DIPARALENE HYDROCHLORIDE 0 ERVMIDE
4,7-hlETHANOINDENE 0 1,2,4,5,6,7,8&OCTACHLORO-
~,~,~~,~,~,~~-HEXAHYDRO-~,~-AMETHANO-~H 0 1,2,4,5,6,7,8,8-OCTACHLORO-3a,4,7,7a-HEXAH~RO-4,7METHYLENE INDANE 0 OCTACHLORO-4,7METHANOHYDROINDANE 0 OCTACHLORO-4,7METHANOTETRAHYDROINDANE 0 1,2,4,5,6,7,8,8-
OCTACHLORO-4,7-METHANO-3a,4,7,7a-TETRAHYDROINDANE 0 1,2,4,5,6,7,8,8-OCTACHLORO-3a,4,7,7aTETR4HYDRO-4,7-h4ETHAKOlNDAN 0 1,2,4,5,6,7,8,8-
CHLORDANE
CDR750 309
OCTACHLORO-3a,4,7,7a-TETRAHYDRO-4,7compounds show an extremely marked loss METHANOINDANE 0 1,2,4,5,6,?,10,10-OCTACHLOROof appetite and neurological symptoms. The 4,?,8,9-TETRAHYDRO-4,7-,ZIETHYLE"DANE 0 fatal dose to humans is unknown. It has 1,2,4,5,6,7,8,8-OCTACHLOR-3a,4,?,?a-TETRR0-4,?-
been estimated to be between 6 and 60 g(0.2 and 2 ounces). One person receiving OTTOCHLORO-~A,~,?,?A-TETR~IDRO-~,~-~~~Oan accidental slan application of 25% METANO-INDANO (ITALXN) RCRA WASTE solution (amounting to somethmg over 30 NULX3ERU036 0 SD 5532 0 SHELL SD-5532 0 g of technical chlordane) developed SYNKLOR 0 TAT CHLOR 4 0 TOPICHLOR 20 0 symptoms withm about 40 minutes and TOPICLOR TOPICLOR 20 0 TOXICHLOR VELSICOL 1068 ded, apparently of respiratory failure, before CONSENSUS REPORTS: IARC Cancer medical attention was obtained. In two Review: Group 2B lMEMDT 53,115,91; patients, death followed exposure to low Animal Sufficient Evidence IMEMDT ingestion doses of chlordane (2-4 g). On 20,45,79; Animal Limited Evidence IARC microscopic examination, both patients Monographs, Supplement. IMEMDT showed severe chronic fatty degeneration of 7,146,87; Animal Sufficient Evidence the liver, characteristic of chronic IMEMDT 53,115,91;Human Inadequate alcoholism. Although these two fatalities Evidence IMEMDT 20,45,79; Human cannot be attributed exclusively to Inadequate Evidence IMEMDT 53,115,91. chlordane, they are entirely consistent with NCI Carcinogenesis Bioassay (feed); Clear previous observations that the toxicity of Evidence: mouse NCITR* NCI-CG-TRother chlorinated hydrocarbons is much 8,77; No Evidence: rat NCITR* NCI-CGenhanced in the presence of chronic liver TR-8,77. EPA Genetic Toxicology Program. damage. The dangerous chronic dose in Community fight-To-Know List. EPA humans is unknown. Extremely Hazardous Substances List. Experimental animals exposed to repeated OSHA PEL: TWA 0.5 mg/m3 (shn) small doses exhibit hyperexcitabiltty, ACGIH TLV: TWA 0.5 mg/m3 (skin); tremors, and convulsions, and those that Animal Carcinogen survive long enough show marked anorexia DFG MAK: 0.5 mg/m3; Confirmed Animal and loss of weight. Symptoms in animals Carcinogen with Unknown Relevance to frequently occur withm an hour of the Humans administration of a large dose, but death SAFETY PROFILE: Confirmed carcinogen often is delayed for several days depending with experimental carcinogenic data. Poison on the dosage and route of administration. to humans by ingestion and possibly other In any event, symptoms are of longer routes. An experimental poison by ingestion, duration with chlordane than with DDT inhalation, intravenous, and intraperitoneal under similar condtions. routes. Moderately toxic by s h n contact. Laboratory analyses on poisoned animals Human systemic effects by ingestion or skin are essentially normal, except that the contact: tremors, convulsions, excitement, insecticide is found in tissues by means of ataxia (loss of muscle coordination), and bioassay. A method for specific, quantitative gastritis. Experimental teratogenic and chemical analysis for chlordane is now reproductive effects. Human mutation data available using small amounts of reported. Combustible liquid. It is no longer subcutaneous fat. Chronically poisoned permitted for use as a termiticide in homes. animals show degenerative changes in the A central nervous system stimulant whose liver and kidney tubules. exact mode of action is unknown, but it may When heated to decomposition chlordane involve microsomal enzyme stimulation. emits toxic fumes of C1-. Animals poisoned by this and related endo-METHANO-IPZDAN (GERMAN) 0 OCTA-KLOR 0 OKTATERR 0 ORTHO-KLOR 0 1,2,4,5,6,7,8,8-
E
31 0
CDR760
CHLORDANE
CDR760 CAS: 12789-03-6 HR: 3 CHLORDANE SYNS: CHLORDANE,TECHNICAL 0 4,7METHANOINDEN, 1,2,4,5,6,7,8,9-OCTACHLORO3A,4,7,7A-TETRAHYDRO-0 RCRA WASTE NUMBER U036
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 53,115,91; Animal Sufficient Evidence IMEMDT 53,115,91; Human Inadequate Evidence IMEMDT 53,115,91. SAFETY PROFILE: Suspected carcinogen. A poison by ingestion. Moderately toxic by skin contact. Experimental reproductive effects. Mutation data reported.
CDSOOO CAS: 115-28-6 HR: 3 CHLORENDIC ACID mf: CgH4C1604 mw: 388.83 SYNS: HET ACID 0 1,4,5,6,7,7-HEXACHLORO-5NORBORNENE-2,3-DICARBOXYLIC ACID 0 KYSELINA 3,6-ENDOMETHYLEN-3,4,5,6,7,7-HEXACHLOR-A4TETRAHYDROFTALOVA(CZECH) 0 KYSELINA HET (CZECH) 0 NCI-C55072
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. NTP Carcinogenesis Studies (feed); Clear Evidence: mouse, rat NTPTR* NTP-TR-304,87. Reported in EPA TSCA Inventory. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. A severe eye and mild skin irritant. When heated to decomposition it emits toxic fumes of C1-.
CDS125 CAS: 16672-87-0 HR: 2 CHLORETHEPHON mf: CzH6C103P mw: 144.50 PROP: Very hygroscopic needles from benzene. Mp: 74-75', Freely sol in water, methanol, acetone, ethylene glycol, propylene glycol; sltly sol in benzene, toluene; practically insol in pet ether. SYNS: AhlCHEM 68-250 0 BROMOFLOR 0 CAMPOSA44N0 CEP 0 2-CEPA 0 CEPHA 0 CEPHA lOLS 0 2-CHLORAETHYL-PHOSPHONSAEURE (GERMAN) 0 2-CHLORETHYLPHOSPHONICACID 0 2CHLOROETHANEPHOSPHONICACID 0 ETHEFON 0 ETHEL 0 ETHEPHON 0 ETHEVERSE 0 ETHREL 0 FLORDIMEX 0 FLOREL 0 G 996 0 KAMPOSAN 0 ROLL-FRUCT 0 TOMATHREL
CONSENSUS REPORTS: EPA Genetic
Toxicology Program. SAFETY PROFILE: Moderately toxic by ingestion. Mddly toxic by skin contact. A plant growth regulator. Caution: Spray formulations are quite acidic, about pH 1.O. May be irritating to exposed s h n and eyes, or if inhaled. When heated to decomposition it emits toxic fumes of C1and PO,. CDS750 CAS: 470-90-6 HR : 3 CHLORFENVINFOS mf: C1~H14Cl304P mw: 359.58 PROP: Amber liquid. Mp: -23', bp: 124-126' @ 0.008 mm. SYNS: APACHLOR 0 BIRLANE 0 C-10015 0 CFV 0 CGA 26351 0 CHLOFENVINPHOS 0 0-2-CHLOOR-l-
(2,4-DICHLOOR-FENYL)-VINYL-O,O-DIETHYLFOSFAAT (DUTCH) 0 0-2-CHLOR-l-(2,4-DICHLOR-PHENYL)VINYL-0,O-DIAETHYLPHOSPHAT (GERMAN) 0 CHLORFENVINFOS 0 CHLORFENVINPHOS 0 2CHLORO-l-(2,4-DICHLOROPHENYL)VINYL DIETHYL PHOSPHATE 0 P-2-CHLORO-l-(2',4'-DICHLOROPHENYL) VINYL DIETHYLPHOSPHATE 0 CHLOROFENVINPHOS 0 CHLORPHENVINFOS 0 CHLORPHENVINPHOS 0 0-2-CLORO-1-(2,4-DICLORO-FENIL)VINYL-0,O-DIETILFOSFATO (ITALIAN) 0 COMPOUND 4072 0 CVP 0 DERMATON 0 0,O-DWETHYL-0-1-(4,5-
DICHLORPHENYL)-2-CHLOR-VINYL-PHOSPHAT (GERMAN) 0 2,4-DICHLORO-a(CHLOR0METHYLENE)BENZYLALCOHOL DIETHYL PHOSPHATE 0 O,O-DIETHYI-O-(2-CHLORO-l-(2',4'DICHLOR0PHENYL)VINYL)PHOSPHATE 0 ENT 24,969 0 GC 4072 0 OMS 1328 0 PHOSPHATE de 0,ODIETHYLE et de 0-2-CHLORO-1-(2,4-DICHLOROPHENYL) VINYLE (FRENCH) 0 SAPECRON 0 SHELL 4072 0 STELADONE 0 SUPONA 0 SUPONE 0 UNITOX 0 VINYLPHATE
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. SAFETY PROFILE: Poison by ingestion, skin contact, intraperitoneal, subcutaneous, and intravenous routes. Human systemic effects by skin contact: unspecified blood system effects. Mutation data reported. A cholinesterase inhibitor. An insecticide. See also PARATHION. When heated to decomposition it emits very toxic fumes of C1- and PO,.
CHLORINATED CAMPHENE
CDT750 CAS: 96-24-2 HR: 3 CHLORHYDRIN DOT: UN 2689 mf: C3HL10z mw: 110.55 PROP: Colorless liquid. Bp: 213' decomp, d: 1.326. SYNS: a-CHLORHYDRIN 0 CHLORODEOXYGLYCEROL 0 1-CHLORO-2,3-DIHYDROXROPAXE 0 3-CHLORO-1,Z-DIHYDROXYPROPANE 0 CZCHLOROHYDRIN 0 I-CHLOROPROPANE-2,3-DIOL 0 1-CHLORO-2,3-PROPANEDIOL0 3-CHLOROPROPANE1J-DIOL 0 3-CHLORO-I,2-PROPANEDIOL3CHLOROPROPYLENEGYLCOL 0 P,P'-DIHYDROXYISOPROPYL CHLORIDE 0 2,3-DIHYDROXYPROPYL CHLORIDE 0 EPIBLOC 0 GLYCERIN-a-MONOCHLORHYDRIN 0 GLYCEROL CHLOROHYDRIN 0 GLYCEROL-a-CHLOROHYDRIIN0 GLYCEROL-aMONOCHLOROHYDRIN (DOT) 0 GLYCERYL-aCHLOROHYDRIN 0 MONOCHLORHYDRIN 0 MONOCHLOROHYDRIN 0 a-MONOCHLOROHYDRIN 0 u-5897
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Moderately toxic by inhalation. Experimental reproductive effects. A severe eye irritant. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. A chemosterilant for rodents. Combustible when exposed to heat or flame. Reaction with perchloric acid forms a sensitive explosive product more powerful than glyceryl nitrate. When heated to decomposition it emits toxic fumes of C1-.
CDUOOO CAS: 7790-93-4 HR: 3 CHLORIC ACID DOT: UN 2626 mf: C1H03 mw: 84.46 PROP: Colorless solution. Fairly stable in cold H20 up to 30%. Strong oxidant, stable as alkalt metal salts. Mp: <-20', bp: decomp @ 40', d: 1.282 @ 14.2'. SYN: CHLORIC 4CID, solution, containing not more than 10% acid (DOT)
CDVlOO 31 1
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: A poison. A strong irritant by ingestion and inhalation. Dangerous fire hazard; ignites organic matter upon contact. A very powerful oxidizing agent. Violent or explosive reaction with oxidlzable materials. Aqueous solutions decompose explosively during evaporation. Solutions greater than 40% are unstable. Reacts violently with NH3, Sb, Sb&, AS& Bi, CuS, PHI+ SnS2, SnS. Reaction with cellulose causes ignition after a delay period. Dangerous reaction with metal sulfides and metal chlorides (e.g., incandescent reaction with antimony trisulfide, arsenic trisulfide, tin(lI)sulfide, tin(Iv> sulfide, explosion on contact with copper sulfide). Reaction with metals (e.g., antimony, bismuth, iron) forms explosive products. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORATES and CHLORINE.
CDU250 HR: D CHLORIDES SAFETY PROFILE: Varies widely. Sodium chloride (table salt) has very low toxicity, while carbonyl chloride (phosgene) is lethal in small doses. Therefore, see specific entries. When heated to decomposition or on contact with acids or acid fumes, they evolve highly toxic chloride fumes. Some organic chlorides decompose to yield phosgene. CDVlOO CAS: 8001-35-2 HR: 3 CHLORINATED CAMPHENE mf: c~oH~oCls mw: 413.80 PROP: Yellow, waxy solid; pleasant piney odor. Mp: 65-90'. Almost ins01 in water; very sol in aromatic hydrocarbons. IDLH 200 mg/m3. SYNS: AGRICIDE MAGGOT KILLER (F)0 ALLTEX 0 ALLTOX 0 ATI'AC 6 0 ATTAC 6-3 0 CAMPHECHLOR 0 CAMPHOCHLOR 0 CAMPHOCLOR 0 CAMPHOFENE HUILEUX 0 CHEM-PHENE 0 CHLOROCATMPHENE 0 CLOR CHEM T-590 0 COMPOUND 3956 0 CRESTOXO
31 2
CDVl75
CHLORINATED DIPHENYL OXIDE
0 CRISTOXO 90 0 ENT 9,735 0 ESTONOX 0 FASCOTERPENE 0 GENIPHENE 0 GY-PHENE 0 HERCULES 3956 0 HERCULES TOXAPHENE 0 KAMFOCHLOR 0 M 5055 0 MELIPAX 0 hlOTOX 0 NCK00259 0 OCTACHLOROCAMPHENE 0 PCC 0 PENPHENE 0 PHENACIDE 0 PHENATOX 0 POLYCHLORCAMPHENE 0 POLYCHLORINATED CAMPHENES 0 POLYCHLOROCAMPHENE 0 RCRA WASTE NL'X3ER P123 0 STROBANE-T-90 0 SYNTHETIC 3956 0 TOXADUST 0 TOXAFEEN (DUTCH) 0 TOXAKIL 0 TOXAPHEN (GER\lAN) 0 TOXAPHENE 0 TOXON 63 0 TOXITHEN 0 VERTAC 90% 0 VERTAC TOXAPHENE 90
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Human Limited Evidence IMEMDT 20,327,79; Animal Sufficient Evidence IMEMDT 20,327,79. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NCITR* NCI-CG-TR-37,79. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.5 mg/m3; STEL 1 mg/m3 (skin) ACGIH TLV: TWA 0.5 mg/m3; STEL 1 mg/m3 ( s h ) ; Animal Carcinogen DFG MAK: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Human poison by ingestion and possibly other routes. Experimental poison by ingestion, intraperitoneal, and possibly other routes. Moderately toxic experimentally by inhalation and skin contact. Human systemic effects by ingestion and skin contact: somnolence, convulsions or effect on seizure threshold, coma, and allergic skin dermatitis. A s h n irritant; absorbed through the shn. Experimental teratogenic and reproductive effects. Human mutation data reported. Liver injury has been reported. Lethal amounts of toxaphene can enter the body through the mouth, lungs, and skin. Systemic absorption of the insecticide is increased by the presence of lgestible oils, and liquid preparations of the insecticide, which penetrate the skin more readily than do dusts and wettable powders.
A toxic mixture of organochlorine pesticides stored to some extent in body fat. It resembles chlordane and, to some extent, camphor in its physiological action. It causes diffuse stimulation of the brain and spinal cord resulting in generahzed convulsions of a tonic or clonic character. Death usually results from respiratory failure. Detoxification appears to occur in the liver. The lethal ingestion dose for humans is estimated to be 2-7 g, a toxicity of about four times that of DDT. At least seven human deaths have been reported due to toxaphene, all in chddren. Two families have been made ill by eating vegetables containing a large residue of toxaphene. When heated to decomposition it emits toxic fumes of C1-. CDV175 CAS: 31242-93-0 HR: 2 CHLORINATED DIPHENYL OXIDE mf: C12H4C160 mw: 376.86 PROP: Light-yellow, very viscous liquid. Bp: 230-260' @ 8 mm, d: 1.60 @ 2Oo/6O0, autoign temp: 1148'F, vap d: 13.0. IDLH 5 mg/m3. SYNS: BENZENE, l,l'-OXYBIS-, HEXACHLORO derivatives (9CI) 0 ETHER, HEXACHLOROPHENYL0 HEXACHLORODIPHENYLETHER 0 HEXACHLORODIPHENYL OXIDE 0 PHENYL ETHER, HEXACHLORO derivative (8CI) 0 TRICHLORO DIPHENYL ETHER 0 TRICHLORO DIPHENYL OXIDE
OSHA PEL: TWA 0.5 mg/m3 ACGIH TLV: TWA 0.5 mg/m3 DFG MAK: 0.5 mg/m3 SAFETY PROFILE: Moderately toxic by
ingestion and probably by inhalation. Combustible when exposed to heat, flame, or oxidizing materials. To fight fire, use water spray, fog, foam, dry chemical, COa. When heated to decomposition it emits toxic fumes of C1-. See also ETHERS and ALDRIN (a closely related compound). CDV250 HR: 2 CHLORINATED HYDROCARBONS, ALIPHATIC SYNS: ALIPHATIC CHLORINATED HYDROCARBONS 0 CHLORINATED HC, ALIPHATIC
CHLORINE SAFETY PROFILE: Suspected carcinogen with experimental tumors of the liver, lung, skin, and blood-forming tissues. The substitution of a chlorine (or other halogen) atom for a hydrogen greatly increases the anesthetic action of the aliphatic hydrocarbons and increases the range of their systemic effects. In many cases, the chlorine derivative is quite toxic. In general, the unsaturated chlorine derivatives are more narcotic but less toxic than the saturated derivatives. In the saturated group, the narcotic effect is proportional to the number of chlorine atoms. This relationship is not true for toxicity. In dealing with these chlorinated hydrocarbons, it must be remembered that a toxic action may result from repeated exposure to concentrations that are too low to produce a narcotic effect, and that, consequently, are too low to gve warning of danger. InQvidual susceptibility varies widely. Certain workmen may be seriously affected by concentrations that seem to have no effect on fellow employees at the same exposure. In general reactivity decreases with greater substitution of halogen for hydrogen atoms. Halogenated (i.e., fluorine-, chlorine-, or bromine-containing) acetylene compounds are unstable and should be treated as explosives. Lightly substituted haloalkanes are highly flammable and can react with Qvalent light metals to form dangerously reactive products. Lightly substituted haloalkenes are highly flammable, peroxidizable, and may polymerize violently. When heated to decomposition they emit highly toxic fumes of phosgene. They may react violently with Al, liquid 0 2 , K, and Na.
CDV500 HR: 3 CHLORINATED HYDROCARBONS, AROMATIC SYN: CHLORINATED HC AROMATIC SAFETY PROFILE: In most instances, it is difficult to prechct the toxicity of these compounds. However, in the case of most
CDV750 313
aromatic chlorine compounds, their toxicity is usually no greater, and frequently is less, than that of the corresponding aromatic hydrocarbons, with the notable exception of naphthalene and the various biphenyls. They can react with oxidizing materials. React violently with Al, liquid 0 2 , K, or Na. When heated to decomposition they emit toxic fumes of C1-. CDV575 HR: 3 CHLORINATED NAPHTHALENES SAFETY PROFILE: Questionable carcinogens that can cause tumors of the liver. Severe irritants by ingestion, inhalation, and skin contact. The action of the chlorinated naphthalenes on the body is quite sirmlar to that of the chlorinated biphenyls, the chief effects being the production of chloracne of the skin, and systemically an acute yellow atrophy of the liver. When heated to decomposition they emit toxic fumes of C1-.
CDV625 CAS: 56641-03-3 HR: 3 CHLORINATED POLYETHER POLYURETHAN PROP: Polymer formed from toluene dmocyanate and 1,4-butanediol and cured with 4,4'-methylenebis(o-chloroanit1ne) (CNREA8 36,3973,76). mf: ( C ~ ~ H ~ Z C ~ ~ N Z ~ C ~ H ~ N Z ~ Z * ( HzO), SYNS: OSTAMER 0 POLYURETHANE Y-238 0 Y-238 CONSENSUS REPORTS: IARC Cancer Review: Animal Sufficient Evidence IMEMDT 19,303,79. SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of C1- and NO,. CDV750 CAS: 7782-50-5 HR: 3 CHLORINE DOT: UN 1017 mf: Clz mw: 70.90 PROP: Greenish-yellow gas, liquid, or rhombic crystals. Mp: -lolo, bp: -34.9", d:
314 CDWOOO CHLORINE AZlDE @quid) 1.47 @ 0 ' (3.65 atm), vap press: 4800 mm @ 20°, vap d: 2.49. Sol in water. IDLH 10 ppm. SYNS: BERTHOLITE 0 CHLOOR (DUTCH) 0
CHLOR ( G E W N ) 0 CHLORE (FRENCH) 0 CHLORINE MOL. 0 CLORO (ITALIAN) 0 MOLECULAR CHLORINE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Community kght-ToKnow List. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.5 ppm; STEL 1 pprn ACGIH TLV: TWA 0.5 ppm; STEL 1 ppm; Not Classifiable as a Human Carcinogen DFG MAK: 0.5 ppm (1.5 mg/m3) NIOSH REL: (Chlorine) CL 0.5 ppm/l5M DOT CLASSIFICATION: 2.3; Label: Poison Gas SAFETY PROFILE: Moderately toxic to humans by inhalation. Very irritating by inhalation. Human mutation data reported. Human respiratory system effects by inhalation: changes in the trachea or bronchi, emphysema, chronic pulmonary edema or congestion, A strong irritant to eyes and mucous membranes. Questionable carcinogen. Chlorine is extremely irritating to the mucous membranes of the eyes and the respiratory tract at 3 ppm. Combines with moisture to form HC1. Both these substances, if present in quantity, cause inflammation of the tissues with which they come in contact. A concentration of 3.5 ppm produces a detectable odor; 15 ppm causes immediate irritation of the throat. Concentrations of 50 pprn are dangerous for even short exposures; 1000 pprn may be fatal, even when exposure is brief. Because of its intensely irritating properties, severe industrial exposure seldom occurs, as the worker is forced to leave the exposure area before he can be seriously affected. In cases where this is impossible, the initial irritation of the eyes and mucous membranes of the nose and throat is followed by coughing, a feeling of suffocation, and, later, pain and a feeling of constriction in the chest. If exposure has been severe, pulmonary edema
may follow, with rales being heard over the chest. It is a common air contaminant. Explodes on contact with acetylene + heat or UV light, air + ethylene, molten aluminum, ammonia, amidosulfuric acid, antimony trichloride + tetramethyl silane (at loo'), benzene + light, biuret, bromine pentafluoride + heat, tert-butanol, butyl rubber + naphtha, carbon disulfide + iron catalyst, chlorinated pyridine + iron powder, 3-chloropropyne, cobalt(I1) chloride + methanol, dborane, dbutyl phthalate (at 118'), dchloro(methy1)arsine (in a sealed container), diethyl ether, dimethyl phosphoramidiate, dioxygen &fluoride, dsilyl oxide, 4,4'-&thiodimorpholine, ethane over activated carbon (at 350'), fluorine + sparks, gasoline, glycerol (above 70' in a sealed container), hexachlorodisilane (above 300'), hydrocarbon oils or waxes, iron(II1) chloride + monomers (e.g., styrene), methane over mercury oxide, methanol, methanol + tetrapyridme cobalt(I1) chloride, naphtha + so&um hydroxide, nitrogen triiodide, oxygen difluoride, whte phosphorus (in liquid Clz), phosphorus compounds, polypropylene + zinc oxide, propane (at 300°), shcones when heated in a sealed container [e.g., polydimethyl siloxane (above 88'), polymethyl trifluoropropylsiloxane (above 68')], stibine, synthetic rubber (in liquid Clz), tetraselenium tetranitride, trimethyl thionophosphate. Explosive products are formed on reaction with alkylthiouronium salts, amidosulfuric acid, acidc ammonium chloride solutions, aziridine, bis(2,4-&nitrophenyl)disulfide, cyanuric acid, phenyl magnesium bromide. Mixtures with ethylene are explosives initiated by light, heat, or by the presence of mercury, mercury oxide, silver oxide, lead oxide (at 100'). Mxtures with hydrogen are explosives initiated by sparks, light, heating to over 280°, or the presence of yellow mercuric oxide or nitrogen trichloride. Murtures with hydrogen and other gases (e.g., air, hydrogen chloride, oxygen) are also explosive.
CHLORINE DIOXIDE
I p t i o n or explosive reaction with metals (e.g., aluminum, antimony powder, bismuth powder, brass, calcium powder, copper, germanium, iron, manganese, potassium, tin, vanadium powder). Reaction with some metals requires moist Clz or heat. Ignites with diethyl zinc (on contact), polyisobutylene (at 130'), metal acetylides, metal carbides, metal hydrides (e.g., potassium hydride, sodium hydride, copper hydride), metal phosphtdes (e.g., copper(I1) phosphide), methane + oxygen, hydrazine, hydroxylamine, calcium nitride, nonmetals (e.g., boron, active carbon, silicon, phosphorus), nonmetal hydrides (e.g., arsine, phosphine, silane), steel (above 200' or as low as 50" when impurities are present), sulfides (e.g., arsenic disulfide, boron trisulfide, mercuric sulfide), trialkyl boranes. Violent reaction with alcohols, N-aryl sulfinamides, dimethyl formamide, polychlorobiphenyl, sodium hydroxide, hydrochloric acid + dinitroanilines. Incandescent reaction when warmed with cesium oxide (above 150°), tellurium, arsenic, tungsten dioxide. Potentially dangerous reaction with hydrocarbons + Lewis acids releases toxic and reactive HC1 gas. Can react to cause fires or explosions upon contact with turpentine, illuminating gas, polypropylene, rubber, sulfamic acid, As2(CH3)4, UC2, acetaldehyde, alcohols, alkylisothiourea salts, alkyl phosphtnes, Al, Sb, As, As&, AsH3, Ba&, C6H6, Bi, B, BPIz, B2S3, brass, BrF5, Ca, (CaC2 + KOH), Ca(C102)2, Ca3N2, Cad%, C, CS2, Cs, CsHC2, C020, Cs3N, (C + Cr(OC1)2), CuH2, CuC2, dialklyl phosphines, diborane, dibutyl phthalate, Zn(C2Hj)2, C2H6, C2H4, ethylene imine, C2H5PH2, F2, Ge, glycerol, (NH2)2, (H20 + KOH), 12, hydroxylamine, Fe, FeC2, L,LzC2, b6c2, Mg, Mg2P3, Mn, Mn3P2, HgO, HgS, Hg, Hg&, CH4,Nb,NI3, OFz, HzSiO, (OF2 + Cu), PH3, I?, P(SNC)3, P203, PCB's, K, KHC2, KH, Ru, RuHC2, Si, SiH2, AgzO, Na, NaHC2, Na2C2, SnF2, SbH3, Sr3P, Te, Th, Sn, WO2, U, V, Zn, ZrC2.
CDW450 315
CDWOOO CAS: 13973-88-1 HR: 3 CHLORINE AZlDE mf: ClN3 mw: 77.48 PROP: An explosive gas. Bp: 15'. Sol in org solvs. SYN: NITROGEN CHLORIDE
DOT CLASS IFlCATlON: Forbidden SAFETY PROFILE: Strong irritant by
inhalation. An extremely unstable explosive. Reacts with liquid ammonia to form an explosive liquid. Explosive reaction with 1,3-buta&ene, CzHs, C2H4, CH4, C3H8, phopshorus, silver azide, sodium. Reacts with water or steam to produce toxic and corrosive fumes of HC1. Has been used as an initiator in chemical gas lasers. When heated to decomposition it emits toxic fumes of C1- and NO,. See also CHLORINE and AZIDES.
CDW450 CAS: 10049-04-4 HR: 3 CHLORINE DIOXIDE mf: C102 mw: 67.45 PROP: Red-yellow or orange-green gas or orange-red crystals. Unstable in light, stable in the dark. Mp: -59", bp: 1lo,d: 3.09 g/L @ 11'. Insol in water. IDLH 5 ppm. IDLH 4 mg/m3 (as Pt). SYNS: ALCIDE 0 ANTHIUM DIOXIDE 0 CHLORINE DIOXIDE, not hydrated (Dog 0 CHLORINE OXIDE 0 C H L O R I N E 0 OXIDE 0 CHLORINE PEROXIDE 0 CHLOROPEROXYL 0 CHLORYL RADICAL 0 DOXCIDE 50
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Community kght-ToKnow List. OSHA PEL: TWA 0.1 ppm; STEL 0.3 pprn ACGIH TLV: TWA 0.1 ppm; STEL 0.3 ppm DFG MAK: 0.1 ppm (0.28 mg/m3) DOT CLASSIFICATION: Forbidden SAFETY PROFILE: Moderately toxic by inhalation. Experimental reproductive effects. Mutation data reported. An eye irritant. A powerful explosive sensitive to spark, impact, sunlight, or heating rapidly to 100OC. A powerful oxidzer. Concentrations of greater than 10% in air are explosive. Explodes on mixing with carbon monoxide, hydrocarbons (e.g., butadiene, ethane,
316
CDX250
CHLORINE PENTAFLUORIDE
ethylene, methane, propane), fluoramines (e.g., difluoramine, trifluoramine). Mtxtures with hydrogen explode with sparking or contact with platinum. Explodes on contact with mercury, potassium hydroxide, phosphorus pentachloride + chlorine. Ignites or explodes on contact with nonmetals (e.g., phosphorus, sulfur, sugar). Reacts violently with F2, NHF2. Reacts with water or steam to produce toxic and corrosive fumes of HC1. When heated to decomposition it emits toxic fumes of C1-. See also CHLORINE. CDX250 CAS: 13637-63-3 HR: 3 CHLORINE PENTAFLUORIDE DOT: UN 2548 mf: ClF5 mw: 130.45 PROP: Colorless gas, extremely vigorous fluorinating agent. D: 2.105 @ -80°, mp: -103', bp: -13.1'. SYNS: CHLORINE FLUORIDE (CIF5) 0 CHLORINE PEXTAFLUORIDE (DOT)
OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3
mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift. NIOSH REL: (Inorganic Fluorides) TWA 2.5 mg(F)/m3 DOT CLASSIFICATION: 2.3; Label: Poison Gas, Oxidizer, Corrosive SAFETY PROFILE: Poison by inhalation. A corrosive material. Vigorous reaction in contact with water or anhydrous nitric acid. Violent reaction on contact with metals. When heated to decomposition it emits very toxic fumes of C1- and F-. See also CHLORINE, FLUORINE, FLUORIDES, and CHLORINE TRIFLUORIDE. CDX750 CAS: 7790-91-2 HR: 3 CHLORINE TRIFLUORIDE DOT: UN 1749 mf: C1F3 mw: 92.45 PROP: Colorless gas to yellow liquid; sweet odor. One of the most reactive chemical
compds known. Mp: - 8 3 O , bp: 11.8', d: 1.77 @ 13'. IDLH 20 ppm. SYNS: CHLORINE FLUORIDE 0 CHLOROTRIFLUORIDE 0 TRIFLUORURE de CHLORE (FRENCH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: CL 0.1 pprn ACGIH TLV: CL 0.1 pprn DFG MAK: 0.1 ppm (0.38 mg/m3) DOT CLASSIFICATION: 2.3; Label: Poison Gas, Oxidzer, Corrosive SAFETY PROFILE: Human poison by inhalation. An eye irritant. See also FLUORIDES, CHLORINE, and FLUORINE. Spontaneously flammable. A powerful oxidant whch may react violently with oxidzable materials. A rocket propellant. Explosive reaction with water, bis (trifluoromethyl)sulfide or -disulfide, polychlorotrifluoroethylene, trifluoromethanesulfenyl chloride, and other hydrogen- containing materials (e.g., ammonia, coal gas, hydrogen, hydrogen sulfide, methane, acetic acid, benzene, ether, cotton, paper, wood). Forms shock-sensitive explosive mixtures with highly chlorinated compounds (e.g., carbon tetrachloride), nitroaryl compounds (e.g., trinitrotoluene, hexanitrobiphenyl, hexanitrodiphenyl amine, hexanitrodiphenyl sulfide, hexanitrobphenyl ether). Reaction with ammonium fluoride or ammonium hydrogen fluoride forms explosive gaseous products. Ignition on contact with boron-containing materials, iodine, finely dvided refractory materials (e.g., asbestos, glass wool, sand, tungsten carbide), fluorinated polymers (with flowing trifluoride). Violent reaction with acids (e.g., nitric or sulfuric), chromium trioxide, ruthenium, selenium tetrafluoride (above 106OC), metals, metal oxides, metal salts, nonmetals, nonmetal salts, organic matter, glass wool, acetic acid, Al, Sb, As, Cu, Ir, Fe, Pb, Mg, Mo, Os, P, I<, Rh, Se, Si, Ag, Na, S, Te, Sn, W, Zn, oxides, CO, graphite, HgI2, HN03,
CHLOROACETICACID
KzCO3, KI, rubber, AgN3, AgN03, NaOH, VzPs, wo3. Incompatible with fuels, nitro compounds. When heated to decomposition or in reaction with water or steam it emits toxic fumes of F- and C1-. CDY250 HR: 3 CHLORITES SAFETY PROFILE: Many chlorite salts are heat- and impact-sensitive explosives. The metal salts are powerful oxidants. They are much less stable than the analogous chlorates. React violently with NH3, organic matter, or metals. See individual chlorites. CDY500 CAS: 107-20-0 HR: 3 CHLOROACETALDEHYDE DOT: UN 2232 mf: CZH3ClO mw: 78.50 PROP: Clear, colorless liquid; pungent odor. Bp: 90.0-100.1' (40% soln), fp: -16.3' (40% soln), flash p: 190'F, d: 1.19 @ 25'/25' (40% soln), vap press: 100 mm @ 45' (40% soln). IDLH 45 ppm. SYNS: CHLOROACETALDEHYDE MONOMER 0 2CHLOROACETALDEHYDE 0 2-CHLOROETHANAL 0 2-CHLORO-1-ETHANAL 0 MONOCHLOROACETALDEHYDE 0 RCRA WASTE NUMBER PO23
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: CL 1 ppm ACGIH TLV: CL 1 ppm DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Suspected carcinogen. Poison by ingestion, s h n contact, and intraperitoneal routes. Mutation data reported. Combustible when exposed to heat or flame. Reacts with oxidizing materials. To fight fire, use water, foam, COz, dry chemical. When heated to decomposition it emits toxic fumes of C1-. See also ALDEHYDES and CHLORIDES.
CDY850 CAS: 79-07-2 2-CHLOR0ACET AM1DE
HR:
CEAOOO 31 7
mf: CzH4ClNO mw: 93.52 PROP: Crystals. Mp: 120°, bp: 225' (decomp). Sol in HzO, EtOH; sltly sol in EtzO. SYNS: CHLORACETAMID (GERMAN) 0 CHLOROACETAXIDE 0 a-CHLOROACETAMIDE 0 2C H L O R O E T W A M I D E 0 USAF DO-29 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion, intravenous, and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits very toxic C1- and NO,. See also N-CHLOROACETAMIDE.
CEAOOO CAS: 79-11-8 HR: 3 CHLOROACETIC ACID DOT: UN 1750/UN 1751 mf: CzH3C102 mw: 94.50 PROP: Colorless crystals in three forms. Mp: (a) 61.3', (p) 56.2", (2) 52.5', bp: 189', flash p: 259'F, d: 1.58 @ 2O0/2Oo, vap d: 3.26. Very sol in H20; sol in org solvs. SYNS: XCIDE CHLORACETIQUE (FRENCH) 0 ACIDE MONOCHLORACETIQUE (FRENCH) 0 ACIDOMONOCLOROACETICO ( I T U V ) 0 CHLORACETIC ACID 0 CHLOROACETIC ACID, liquid (UN 1750) (DOq 0 CHLOROACETIC ACID, solid (UN 1751) (DOT 0 a-CHLOROACETIC ACID 0 CHLOROETHANOIC ACID 0 KYSELINA CHLOROCTOVA 0 MCA 0 MONOCHLOORAZIJNZUUR (DLTCH) 0 MONOCHLORACETIC ACID 0 MONOCHLORESSIGSAEURE (GERMAN) 0 MONOCHLOROACETIC ACID 0 MONOCHLOROETHANOIC ACID 0 NCI-C60231
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. EPA Extremely Hazardous Substances List. Community Rlght-ToKnow List. DOT CLASSIFICATION: 8; Label: Corrosive, Poison (UN 1750) SAFETY PROFILE: Poison by ingestion, inhalation, subcutaneous, and intravenous routes. A corrosive shn, eye, and mucous membrane irritant. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Combustible liquid when exposed to heat or flame. To fight fire, use water spray, fog, mist, dry chemical,
31a
CEAZO
a-CHLOROACETOPHENONE
foam. When heated to decomposition it emits toxic fumes of C1-. See also CHLORIDES. CEA750 CAS: 532-27-4 HR: 3 U-CHLOROACETOPHENONE DOT: UN 1697 mf: CaH7C10 mw: 154.60 PROP: Leaflets from pet ether. Mp: 54", bp: 139-141' @ 14 mm. IDLH 15 mg/m3. SYNS: CAP 0 CAP 0 CHEMICALMACE 0 CHLORACETOPHENONE 0 CL-CHLOROACETOPHENO S E 0 1-CHLOROACETOPHENONE 0 CHLOROACETOPHENONE, hquid or sohd (DOT 0 CHLOROMETHYL PHEXYL KETONE 0 2-CHLORO-1-PHENYLETHANONE 0 CN 0 ETH,4NONE, 2-CHLORO-lPHENYL- MACE (lachrymator) 0 NCI-C55107 0 PHENACYL CHLORIDE 0 PHENYLCHLOROMETHYLKETONE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Community fight-ToKnow List. OSHA PEL: TWA 0.05 ppm ACGIH TLV: TWA 0.05 ppm; Not Classifiable as a Human Carcinogen DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A human poison by inhalation. An experimental poison by ingestion, inhalation, intraperitoneal, and intravenous routes. Human systemic effects by inhalation: lachrymation, conjunctiva irritation, and unspecified eye effects, cough, and dyspnea. A severe eye and moderate skin irritant. Questionable carcinogen with experimental neoplastigenic data by s h n contact. A riot control agent. When heated to decomposition it emits toxic fumes of C1-. See also KETONES.
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
intraperitoneal route. Moderately toxic by ingestion. A powerful irritant and lachrymator. Human systemic effects by inhalation: lachrymation and unspecified effects on the eye and sense of smell. Combustible when exposed to heat or flame. To fight fire, use water, foam, alcohol foam, dry chemical. When heated to decomposition or on contact with water or steam it emits toxic fumes of C1-. CECOOO CAS: 140-49-8 HR: 2 4'-CHLOR0ACETY L AC ETANlLlDE mfi CloHloClN02 mw: 21 1.66 SYNS: p-ACETAhIIDOPHENACIZTCHLORIDE 0 p(ACETYL&\lIXO)PHENACYL CHLORIDE 4'(CHLOR0ACETYL)ACETANILIDE0 NCI-C03770
CONSENSUS REPORTS: NCI
Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* NCI- CGTR-177,79. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,. See also CHLORIDES. CEC100 CAS: 1132-20-3 HR: 3 N-(CHLOROACETYL)-3-AZABICYCLO(3.2.1)NONANE mf: CloH16ClNO mw: 201.72 SYNS: 3-AZABICYCLO(3.2.2)NOXANE, 3(CHLOR0ACETYL)-0 KETONE, 3-AZABICYCLO(3.2.2)NONYLCHLOROMETHYL
DOT CLASSIFICATION: 3; Label:
CEB250 CAS: 99-91-2 HR: 3 p-CHLOROACETOPHENONE mf: CsH7C10 mw: 154.60 PROP: Pale straw-colored liquid or white crystals; fragrant, non-persistent odor. Mp: 20°, bp: 236", fp: 59", d: 1.19 @ 20°, vap press: 0.012 mm @ O", vap d: 5.2, flash p: 244°F. SYNS: 4-CHLOROACETOPHENONE 0 4'CHLOROACETOPHESONE 0 L(4-CHLOROPHENYL)ETHANONE 0 USAF DO-1
Flammable Liquid SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO, and C1-.
CEC250 CAS: 79-04-9 CHLOROACETYL CHLORIDE DOT: UN 1752 mfi C2HzC120 mw: 112.94
HR: 3
3-CHLORO-4-AMINOANILINE CEGGOO 3 19 PROP: Water-whte or sltly yellow liquid. Bp: 108-110°, fp: -22.5', flash p: none, d: 1.495 @ 0 ' . SYNS: CHLORACETYL CHLORIDE 0 CHLORID KYSELINY CHLOROCTOVE 0 CHLOROACETIC ACID CHLORIDE 0 CHLOROACETIC CHLORIDE CHLORURE de CHLORACETYLE (FRENCH) 0 MONOCHLOROACETYL CHLORIDE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.05 ppm ACGIH TLV: TWA 0.05 ppm; STEL 0.15 PPm DOT CLASSIFICATION: 8; Label: Corrosive, Poison SAFETY PROFILE: Poison by ingestion and intravenous routes. Mildly toxic by inhalation. Corrosive. A lachrymator. When heated to decomposition it emits toxic fumes of C1-.
mf: C4HzClN mw: 87.51 PROP: bquid. Bp: 88O, flash p: 46.4'F. SYNS: CHLOROACRYLONITRILE CHLOROACRYLONITRILE
a-
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community RtghtTo-Know List. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Suspected carcinogen. Poison by intravenous route. A powerful irritant. A dangerous fire hazard when exposed to heat or flame. To fight fire, use water, dry chemical, C02, foam. When heated to decomposition it emits very toxic fumes of C1-, NO,, and CN-. See also NITRILES.
CEG550 CAS: 4080-31-3 HR: 3 1-(SCHLOROALLYL)-3,5,7-TRIAZA-lCEC300 CAS: 143-85-1 HR: 3 AZONIAADAMANTANE CHLORIDE ~-CHLOROACETYL-CX-CX-DIPHENYL-~- mf: CgH1&1N4*Cl mw: 251.19 PIPERIDINEMETHANOL SYNS: DOWCO 184 DOWICIDE Q D o w i c I L 75 mf: C.mH22ClN02 mw: 343.88 DOWICIL 100 0 QUATERUIUM 15 0 3,5,7-TRIAZA-lAZONIAADAMANTANE,1-(3-CHLOROALLYL-, SYNS: KETONE, CHLOROMETHYL 4QIPHENYL-
HYDR0XY;LIETHYL)PIPERIDINO0 4-PIPERIDINEMETHXNOL, 1-CHLOROACETYL-a-a-DIPHENYL
CHLORIDE
DOT CLASSIFICATION: 3; Label:
TSCA Inventory.
Flammable Liquid
SAFETY PROFILE: Poison by ingestion. Moderately toxic by s h n contact. Experimental teratogenic effects. A s h n irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NO, and C1-.
SAFETY PROFILE: A poison by
intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO, and C1-.
CONSENSUS REPORTS: Reported in EPA
CEC700 CAS: 24040-34-4 HR: 3 2-CHLOROACETYLFLUORENE CEG6OO CAS: 615-66-7 HR: 1 mf: ClsH11Cl0 mw: 242.71 3-CHLORO-4-AMINOANILINE SYNS: ETHANONE, 2-CHLORO-l-(9H-FLUOREN-2- mf: C6H7ClN2 mw: 142.60 YL)- 0 FLUORENE, 2-(CHLOR0ACETYL)-0 KETONE, PROP: Needles. Mp: 64'. CHLOROMETHYL 2-FLUORENYL SYNS: 3-CHLOR-p-FEKYLENDIAMIN(CZECH) 0 2DOT CLASSIFICATION: 3; Label: CHLORO-1,CBENZENEDLAMINE 0 o-CHLOR0-pFlammable bquid PHENYLENEDIAWNE 0 2-CHLORO-p-PHENmENESAFETY PROFILE: A poison by DIAMINE 0 C.I. 76065 0 URSOL BROWN 0 intraperitoneal route. A flammable liquid. CONSENSUS REPORTS: Reported in EPA When heated to decomposition it emits TSCA Inventory. toxic vapors of C1-. SAFETY PROFILE: An experimental teratogen. Other experimental reproductive effects. An eye irritant. Decomposes CEE750 CAS: 920-37-6 HR: 3 2-CHLOROACRYLONITRILE explosively at 165'C/33 mbar. When heated
E
320
CEH250 p-CHLORO-0-AMINOPHENOL
to decomposition it emits toxic fumes of C1-
and NO,. See also AROMATIC M I N E S . CEH250 CAS: 95-85-2 HR: 3 p-CHLORO-0-AMINOPHENOL DOT: UN 2673 mf: C&jClNO mw: 143.58 PROP: Plates from Hz0. Mp: 140-141O. SYN: 2-AMINO-4-CHLOROPHENOL (DOT) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A poison. Moderately
toxic by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,. See also AROMATIC M I N E S and CHLORIDES. CEH670 CAS: 95-51-2 HR: 3 2-CHLOROANILINE mf: CsHsClN mw: 127.58 PROP: Liquid. Mp: -1.94', bp: 208.84', d: 1.21 @ 20°/4". Practically insol in water; sol in most org s o h , also in acids. SYNS: 1-AMINO-2-CHLOROBENZENE 0 o-CHLORANILINE 0 o-CHLOROANILINE 0 o-CHLOROANILINE, liquid 0 o-CHLOROANILINE, solid 0 2-CHLOROBENZEXAILMINE (9CI) 0 FAST YELLOW GC BASE CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by skin contact, ingestion, and subcutaneous routes. Mutation data reported. When heated to decomposition it emits toxic fumes of C1and NO,. See also ANILINE DYES.
CEH675 CAS: 108-42-9 HR: 3 3-CHLOROANILINE mf: CsHsClN mw: 127.58 PROP: Liquid. Bp: 230.5', mp: -10.4', d: 1.2225 @ 1 5 ' / 1 5 O . Practically insol in water; sol in most common org solvs. SYNS: m-KMINOCHLOROBENZENE 0 l-AMINO-3CHLOROBENZENE 0 3-CHLOORANILINEN (DUTCH) 0 m-CHLORANILINE 0 m-CHLOROANILINE 0 3CHLOROANILINE (ITALIAN) 0 m-CHLOROANILINE, liquid 0 m-CHLOROANILINE, solid 0 3-CHLOROBEKZENAMINE 0 rn-CHLOROPHENYLAhlINE 0 3-
CHLOROPHENYLAR.IINE 0 FAST ORANGE GC BASE 0 ORANGE GC BASE
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion, s h n contact, subcutaneous, and intravenous routes. Mutation data reported. When heated to decomposition it emits toxic fumes of C1- and NO,. See also ANILINE DYES.
CEH680 CAS: 106-47-8 HR: 3 4-CHLOROANILINE mf: CsHsClN mw: 127.58 PROP: Orthorhombic crystals from alc or pet ether; needles from toluene. Mp: 70-71°, bp: 232O, d: 1.169. Sol in hot water; freely sol in alc, ether, acetone, carbon disulfide. SYNS: 1-AMINO-4-CHLOROBENZENE 0 4CHLORANILIS (CZECH) 0 p-CHLORANILINE 0 pCHLOROANILINE p-CHLOROANILINE, liqud D pCHLOROAKILINE, solid 0 4-CHLOROBENZENAMIINE 0 4-CHLOROBENZENEAMINE 0 4-CHLOROPHENYLAMINE 0 NCI-C02039 0 RCRA WASTE NUMBER PO24
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DFG MAK: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental neoplastigenic and tumorigenic data. Poison by ingestion, inhalation, s h contact, subcutaneous, and intravenous routes. A skin and severe eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of C1- and NO,. See also ANILINE DYES.
CEIOOO CAS: 82-44-0 HR: 3 1-CHLOROANTHRAQUINONE mf: C~HsC102 mw: 243.67 PROP: Yellow needles from EtOH. Mp: 162'. SYNS: I-CHLORANTHRACHIKON (CZECH) 0 CHLORO-9,10-ANTHRACEKEDIONE 0 aCHLOROANTHRAQUINONE 0 l-CHLORO-9,lOANTHRAQUINONE 0 a-MONOCHLOROANTHRAQUINONE
1-
0-CHLOROBENZONITRILE CEMOOO 321 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. An eye irritant. When heated to decomposition it emits very toxic fumes of C1- and NO,.
CE1500 CAS: 89-98-5 HR: 3 0-CHLOROBENZALDEHYDE mf: C7H5CIO mw: 140.57 PROP: Liquid or needles with strong odor. Fp: ll', bp: 213-214'. SYNS: o-CHLOORBENZALDEHYDE(DUTCH) 0 2CHLOORBENZALDEHYDE(DUTCH) 0 2-CHLORBENZALDEHYD (GERMAN) 0 2-CHLOROBENZALDEHYDE 0 o-CHLOROBENZENECARBOXALDEHYDE 0 2CLOROBENZALDEIDE (ITALIAN) 0 USAF M-7
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal and intravenous routes. When heated to decomposition it emits toxic fumes of C1-. See also ALDEHYDES and CHLORIDES.
CEJ125 CAS: 108-90-7 HR: 3 CHLOROBENZENE DOT: UN 1134 mf: CsHsC1 mw: 112.56 PROP: Clear, colorless liquid with faint odor. Bp: 131.7', lel: 1.3%, uel: 7.1% @ 150°, mp: -45", flash p: 85'F (CC), d: 1.11 @ 20"/4', autoign temp: 1180'F, vap press: 10 mm @ 22.2', vap d: 3.88. IDLH 1000 PPm. SYNS: BENZENE CHLORIDE 0 CHLOORBENZEEN (DUTCH) 0 CHLORBENZENE 0 CHLORBENZOL 0 CHLOROBENZEN (POLISH) 0 CHLOROBENZOL (DOT) 0 CLOROBENZENE (ITALIAN) 0 MCB 0 MONOCHLOORBENZEEN (DUTCH) 0 MONOCHLORBENZENE 0 MONOCHLORBENZOL (GERMAN) 0 MONOCHLOROBENZENE 0 MONOCLOROBENZENE (ITALIAN) 0 NCI-C54886 0 PHENYL CHLORIDE 0 RCRA WASTE NUMBER U037
CONSENSUS REPORTS: NTP
Carcinogenesis Studies (gavage); Some Evidence: rat NTITR* NTP-TR-261,85; No Evidence: mouse NTPTR* NTP-TR261,85. Reported in EPA TSCA Inventory. Community Right-To-Know List.
OSHA PEL: TWA 75 ppm ACGIH TLV: TWA 10 ppm; Animal Carcinogen; BEI: 150 mg/g creatinine of total 4-chlorocatechol in urine at end of shift; 25 mg/g creatinine of total pchloropohenol in urine at end of shift DFG MAK: 10 ppm (47 mg/m3) DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Suspected carcinogen. Moderately toxic by ingestion and intraperitoneal routes. Experimental teratogenic and reproductive effects. Mutation data reported. Strong narcotic with slight irritant qualities. Dichlorobenzols are strongly narcotic. Little is known of the effects of repeated exposures at lower concentrations, but it may cause hdney and liver damage. The industrial illnesses reported may possibly be due to nitrobenzol. Dangerous fire hazard when exposed to heat or flame. Moderate explosion hazard when exposed to heat or flame. Potentially explosive reaction with powdered sodium or phosphorus trichloride + sodtum. Violent reaction with AgC104. Reacts vigorously with oxidizers. See also CHLORINATED HYDROCARBONS, AROMATIC. To fight fire, use foam, COz, dry chemical, water to blanket fire. Associated with EPA Superfund sites.
CEMOOO CAS: 873-32-5 HR: 3 0-CHLOROBENZONITRILE mf: C7H4ClN mw: 137.57 PROP: Crystals. Mp: 42-43', bp: 232'. SYNS: o-CHLORBENZONITRIL (CZECH) 0 NITRIL KYSELINY-o-CHLORBENZOOVE (CZECH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community RightTo-Know List. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. An eye irritant. When heated to decomposition or on contact with water, steam, acid, or acid fumes it emits toxic fumes of C1- and CN-. See also NITRILES.
E
322 CEM825 p-CHLOROBENZOTRIFLUORIDE CEM825 CAS: 98-56-6 HR: 1 p-CHLOROBENZOTRIFLUORIDE mf: C,H&lF, mw: 180.56 PROP: Bp: 135-136'. SYNS: @-CHLOR0PHENYL)TRIFLUOROMETHANE 0 p-CHLOROTRIFLUOROMETHYLBENZENE 0 4CHLOROTRIFLUOROMETHYLBENZENE 0 1-CHLORO4-CrRIhiETHYL-BENZENE (9CI) 0 a,a,a-TRIFLUORO-4CHLOROTOLUENE 0 p-FRIFLUOROMETHYLCHLOROBENZENE 0 p-TRIFLCOROMETWYLPHENYL CHLORIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion and inhalation. Human mutation data reported. Flammable. Strongly exothermic reaction with sodium dimethylsulfinate. When heated to decomposition it emits toxic fumes of Fand C1-. See also CHLORINATED HYDROCARBONS, AROMATIC; and FLUORIDES.
CEO100 CAS: 14415-66-8 HR: 3 P-(p-CHLOROBENZOYL)-1-(P-MORPHOLIN0ETHYL)PYRROLE MONOHYDROCHLORIDE mf: C17H19ClN20pClH mw: 355.29 SYN: KETONE, p-CHLOROPHENYL 1-(2LIORPHOLIN OETHYL)PYRROL-2-YL, HYDROCHLORIDE DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,, HC1, and C1-.
CEQ6OO CAS: 2698-41-1 HR: 3 0-CHLOROBENZYLIDENE MALONONITRILE mf: CloHjClN2 mw: 188.62 PROP: W t e crystals. Mp: 95', bp: 313'. IDLH 2 mg/m3. SYNS: o-CHLOROBENZAL hLhLONONlTRILE 0 2CHLOROBENZAL MALONOKITRILE 0 o-CHLOROBENZYLIDENE MALONITRILE 0 2-CHLOROBENZYLIDENE Xt4LOKONITRILE 0 2-CHLOROBMN 0 CS 0 P,P-DICYANO-O-CHLOROSTYRENE 0 NCI-C55118 0 PROPANEDINITRILE((2-CHLOR0PHENYL)METHYLENE) 0 USAF KF-11
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its
compounds are on the Community fightTo-Know List. OSHA PEL: CL 0.05 pprn (skin) ACGIH TLV: CL 0.05 ppm (skm); Not Classifiable as a Human Carcinogen SAFETY PROFILE: Poison by ingestion, intraperitoneal, and intravenous routes. Moderately toxic by inhalation. Human systemic effects by inhalation: conjunctiva irritation, cough, and unspecified respiratory system effects. A human skin and eye irritant. Human exposure data suggest relatively low systemic toxicity, but intense irritation of eyes, skm, and mucous membranes. Mutation data reported. A tear gas used for riot control. When heated to decomposition it emits very toxic fumes of C1-, NO,, and CN-. See also NITRILES.
CES650 CAS: 74-97-5 HR: 2 CHLOROBROMOMETHANE DOT: UN 1887 mf: CH2BrC1 mw: 129.39 PROP: Clear, colorless liquid; sweet odor. Fp: -88', bp: 67.8', flash p: none, d: 1.930 @ 25'/25', vap d: 4.46. Sol in organic solvs; insol in water. IDLH 2000 ppm. SYNS: BROMOCHLORO~IETHANE HALON 1011 n METHYLENE CHLOROBROMIDE 0 MIL-B-4394-B 0 MONO-CHLORO-MONO-BROMO-METHtlh'E CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 200 ppm ACGIH TLV: TWA 200 pprn DFG MAK: 200 ppm (1100 mg/m3) DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Mildly toxic by ingestion and inhalation. Mutation data reported. This material has a narcotic action of moderate intensity, although of prolonged duration. Animals exposed for several weeks to 1000 pprn had blood bromide levels as high as 350 mgl100 g. Therefore, until further data are available, it should be considered at least as toxic as
3-CHLORO-N-(5-CHLORO-2,6-DINITRO- CEXBOO 323
carbon tetrachloride and more than minimal exposure to its vapors should be avoided. Dangerous; when heated to decomposition it emits hghly toxic fumes of Br- and C1-. See also BROMIDES and CHLORINATED HYDROCARBONS, ALIPHATIC. CETOOO CAS: 73926-87-1 HR: 3 trans-CHLOR0(2-(3-BROMOPROPIONAMID0)CYCLOHEXYL)MERCURY mf: C9H15BrClHgNO mw: 469.20 PROP: IDLH 10 mg/m3 (as Hg). SYNS: 3-BROhlO-X-(2-CHLOROMERCURICYCLOHEXYL)PROPIONAMIDE 0 MERCURY Q-CHLOR0(2-(3BROMOPROPION~IID0))-CYCLOHEXYL)
or oxidizers. To fight fEe, use water, water spray, fog, mist, dry chemical, alcohol foam. When heated to decomposition it emits toxic fumes of C1-. See also CHLORINATED HYDROCARBONS, ALIPHATIC .
CEU500 CAS: 928-51-8 HR: 2 4-CHLORO-1-BUTANOL mf: C4H9C10 mw: 108.58 PROP: D: 1.088 @ 20'/4', bp: 84-85' @ 16 mm. SYNS: 4-CHLORBUTAh-1-OL(GERMrlN) 0 4CHLORO-1-BUTANE-OL0 4-CHLOROBUTANOL 0 TETRAMETHYLENECHLOROHYDRIN
CONSENSUS REPORTS: Reported in EPA
CONSENSUS REPORTS: Mercury and its
TSCA Inventory.
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.01 mg(Hg)/m3; STEL 0.03 mg/m3 ( s h ) ACGIH TLV: TWA 0.1 mg(Hg)/m3 (shn); BEI: 35 bg/g creatinine total inorganic mercury in urine preshft; 15 pg/g creatinine total inorganic mercury in blood at end of shft at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Organomercury): TWA 0.01 mg/m3; STEL 0.03 mg/m3 (skin) SAFETY PROFILE: Poison bj intravenous route. See also MERCURY COMPOUNDS. When heated to decomposition it emits very toxic fumes of Br-, C1-, NO,, and Hg.
SAFETY PROFILE: Moderately toxic by ingestion. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of C1-. See also CHLORIDES and ALCOHOLS.
7 '
CEU250 CAS: 78-86-4 HR: 3 2-CHLOROBUTANE mf: C4H9C1 mw: 92.58 PROP: Flash p: 14'F, d: 0.87, vap d: 3.2, bp: 68.50". SYN: sec-BUTn CHLORIDE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: W d l y toxic by ingestion, inhalation, and skin contact. Questionable carcinogen with experimental neoplastigenic data. Dangerous fire hazard when exposed to heat, open flame (sparks),
E
CEV840 CAS: 76706-99-5 HR: 3 S-(4-CHLORO-2-BUTYNYL) DIPHENYLPHOSPHINOTHIOATE mf: C I ( I H ~ ~ C ~ O P Smw: 320.78 SYNS: 2-BUTYNE, I-CHLORO-4-NERCAPTO-,S-ESTER WITH DIPHENYLPHOSPHINOTHIOATE 0 PHOSPHINOTHIOIC ACID, DIPHENYL-, S-(4-CHLORO-2BUTYNYL) ESTER
SAFETY PROFILE: A poison by
subcutaneous route. When heated to decomposition it emits toxic vapors of PO,, SO,, and C1-. CEX800 CAS: 79622-59-6 HR: 2 3-CHLORO-N-(5-CHLORO-2,6-DlNlTRO4-TRIFLUOROMETHYLPHENYL)-5TRIFLUOROMETHYL-2-PYRIDINAMINE mf: C13H4C12FbN404 mw: 465.1 1 SYNS: 3-CHLORO-N-(3-CHLORO-5-TRIFLUOROMETHYL-2-PYRIDYL)-a,a,a-TRIFLUORO-2,6-DINITROp- 0 TOLUIDINE 0 ASC 66825 0 ASC 67178 0 FLUAZINAM 0 FROWNCIDE 0 IKF 1216 0 PP 192 0 2PYRIDINAMINE,3-CHLORO-N-(3-CHLORO-2,6-
DINITRO-4-(TRIFLL!OROMETHYL)PHENYL-5(TRIFLUOROMETHYLSHIRLJLV FLOW
SHIRLAN (ZENECA) 0
324 CFA500 2-CHLORO-N-(2-CHLOROETHYL) SAFETY PROFILE: Moderately toxic by
OSSIAhIINA 0 OSSICHLORIN 0 OXYAMINE 0 SIC-598
ingestion and inhalation. Experimental reproductive effects. When heated to decomposition it emits toxic vapors of NO,, F-,and C1-.
om2
Y L , OXIDE 0 HN2 AMINE OXIDE 0 HN2 OXIDE
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 9,209,75; EPA Genetic Toxicology Program. SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic data. Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Mutation data reported. An antineoplastic agent. When heated to decomposition it emits toxic fumes of C1- and NO,.
MUSTARD 0 MBXO 0 MECHLORETHANINE OXIDE 0 METHYL-BE@-CHLOR0ETHYL)AMINEOXIDE 0 METHYLFXS(~-CHLOROETHYL)AMINE N-OXIDE NMETHYL-DI-2-CHLOROETHYLAMIXE-N-OXIDE O MITOMEX 0 hIITOhfIN 0 NITROGEN MUSTARD OXIDE KITROGES MIJSTARD-N-OXIDE SITROhCIN 0 NMO 0 X-OXYD-LOST 0 N-OXYDMUSTARD 0 NSC-10107 0 OXY-NH2
CFA800 CAS: 107359-74-0 HR: 3 4-CHLORO-2-(4-CHLORO-2-FLUOROPHENYL)-5-((4-CHLOROPHENYL)METHOXY)-3(2H)-PYRlDAZlNONE mf: C I ~ H ~ O C ~ ~ F N ~mw: O Z399.64 SYN : 3(2H)-PYRIDAZINONE,4-CHLORO-2-(4-CHLORO-
SAFETY PROFILE: Poison by intravenous
2-FLUOROPHENYL)-5-((4-CHLOROPHENYL)hiETH0XY)-
and intraperitoneal routes. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of C1- and NO,.
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO,, F-,and C1-.
CFASOO CAS: 126-85-2 HR: 3 2-CHLORO-N-(2-CHLOROETHY L)-NMETHYLETHANAMINE-N-OXIDE mf: CjHllCl2NO mw: 172.07 SYNS: 2,2'-DICHLORO-N-hlETHTiLDIETHYLAhIINE-NOXIDE 0 DIETHYLAMISE, 2,2'-DICHLORO-S-METH-
CFA750 CAS: 302-70-5 HR: 3 2-CHLORO-N-(2-CHLOROETHY L)-NMETHYLETHANAMINE-N-OXIDE HYDROCHLORIDE mf: C ~ H I I C ~ ~ N O C ~ mw: H 208.53 PROP: A solid. Mp: 109-110'. SYNS CHLORMETHINE-N-OXIDEHYDROCHLORIDE 0 2,2'-DICHLORO-N-METHYLDIETHYLAMINE NOXIDE HYDROCHLORIDE O HN2 OXIDE HYDROCHLORIDE 0 hIBAO HYDROCHLORIDE 0 MECHLORETHAMINE OXIDE HYDROCHLORIDE 0 METHYL
BIS-(P-CHL0RAETHYL)-AhfIN-X-Om-HYDROCHLORID (GERXAN) 0 METHYLBIS(P-CHLOROETHYL)A\IIXE-N-OXIDE HYDROCHLORIDE 0 N-
METHYLBIS(2-CHLOR0ETHYL)AMINE-N-OXIDE HYDROCHLORIDE 0 N-METHYL-2,2'-DICHLORODIETHIU5fINE-N-OXIDE HYDROCHLORIDE 0
METHYLDI(2-CHLOR0ETHYL)AMIXE-N-OXIDE HYDROCHLORIDE 0 MITOSIEN 0 MUSTRON 0 NITROGEN MUSTARD OXIDE 0 NITROGEN hfUSTARD-N-OXIDE0 NITROGES MUSTARD-NOXIDE HYDROCHLORIDE 0 SITROMIM 0 NTROMIN HYDROCHLORIDE 0 N-OXYD-LOST 0 NSC-10107 0
CFC600 CAS: 122322-19-4 HR: 3 4-CHLORO-2-(4-C HLOROPHENYL)-5((6-IODO-3-PYRID1NYL)METHOXY)3(2H)-PYRIDAZINONE mf: C16H10C12IN302 mw: 474.09 SYN: 3(2H)-PYRIDAZISONE,4-CHLORO-2-(4CHLOROPHENYL-5-((6-IODO-3-PYRIDINYL)METH0XY)-
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO,, I-, and C1-.
CFD990 CAS: 59-50-7 HR: 3 4-CHLORO-m-CRESOL mf: C7HK10 mw: 142.59 PROP: Odorless crystals (when pure) from pet ether. Mp: 55.5', bp: 235'. Somewhat sol in water; very sol in org solvs. SYNS: APTAL 0 BAKTOL 0 BAKTOLAN 0 CXNDASEPTIC 0 p-CHLOR-m-CRESOL 0 CHLOROCRESOL 0 p-CHLOROCRESOL 0 p-CHLORO-m-CRESOL 6CHLORO-m-CRESOL 0 Z-CHLORO-HYDROXYTOLUENE 0 6-CHLORO-3-HYDROXYTOLUENE 0 4CHLORO-3-METHYLPHENOL0 3-hIETHYL-4CHLOROPHENOL 0 OTTAFACT 0 PARnIETOL 0
2-CHLORO-2',6-DIETHYL-N-(METHOXY-METHYL) CFXOOO 325 PAROL 0 PCMC 0 PREVENTOL CMK 0 RASCHIT 0 RASEN-ANICON 0 RCRA WASTE NUMBER U039
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Chlorophenol compounds are on the Community Rtght-To-Know List. SAFETY PROFILE: Poison by intravenous, subcutaneous, and intraperitoneal routes. Moderately toxic by ingestion. An allergen. Mutation data reported. Incompatible with sodium hydroxide. When heated to decomposition it emits toxic fumes of C1and phosgene. See also CRESOL and CHLOROPHENOLS.
CFKOOO CAS: 93-71-0 HR: 3 2-CHLORO-N,N-DIALLYLACETAMlDE mf: CgHlzClNO mw: 173.66 PROP: Amber liquid. Bp: 74' @ 0.3 mm. Sltly sol in water; sol in alc, hexane, and xylene. SYNS: ALIDOCHLOR 0 ALLIDOCHLOR 0 C D M 0 CDhAT 0 a-CHLORO-N,N-DIALLYLACETAMIDE 0 2CHLORO-N,N-DI-2-PROPEiVYLACETAMIDE 0 CP 6,343 0 DL%LLYLCHLOROACETAMIDE0 N,N-DLALLYICHLOROACETAMIDE 0 N,N-DIALLYL-a-CHLOROACETAMDE 0 N,N-DIALLYL-2-CHLOROACETAMIDE 0 NCI-C04035 0 RADOX 0 RANDOX 0 RANTOX T
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by skm contact. Moderately toxic by ingestion. An herbicide. When heated to decomposition it emits very toxic fumes of C1- and NO,. See also ALLYL COMPOUNDS.
CFK125 CAS: 95-83-0 HR: 3 4-CHLORO-1,2-DIAMINO BENZENE mf: C6H7ClN2 mw: 142.60 PROP: Leaflets from H2O. Mp: 76'. SYNS: p-CHLORO-o-PHENYLENEDIAVINE 0 4CHLORO-o-PHENYLENEDWhiINE 0 4-CHLORO-1,ZPHENYLENEDIAhlINE 0 4-CI-o-PD 1,2-DIrlMINO-4CHLOROBEXZENE 0 3,4-DIAMINOCHLOROBEXZENE 0 3,4-DIrtl.IINO-l-CHLOROBENZESE 0 NCI-C03292 0 URSOL OLIVE 6G
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Human Limited Evidence IMEMDT 27,81,82; Animal Sufficient Evidence IMEMDT
27,81,82. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NCITR* NCI-CG-TR-63,78. Reported in EPA TSCA Inventory. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Human mutation data reported. When heated to decomposition it emits toxic fumes of C1- and NO,. See also AROMATIC AMINES. CFK500 CAS: 124-48-1 HR: 2 CHLORODIBROMOMETHANE mf: CHBrzCl mw: 208.29 PROP: Colorless to pale-yellow, heavy liquid. Bp: 121-122', fp: -22", d: 2.440 @ 25'/25'. SYNS: CDBM 0 DIBRObIOCHLOROhlETHNE 0 NCI-C55254
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 52,243,91; Animal Limited Evidence IMEMDT 52,243,91; Human Inadequate Evidence IMEMDT 52,243,91. NTP Carcinogenesis Studies (gavage); Some Evidence: mouse NTPTR* NTP-TR-282,86; No Evidence: rat NTPTR* NTP-TR-282,85. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Questionable carcinogen with experimental carcinogenic data. Human mutation data reported. Compounds of this type are generally irritating and narcotic. See also BROMOFORM and CHLOROFORM. When heated to decomposition it emits toxic fumes of C1- and Br-. CFXOOO CAS: 15972-60-8 HR: 2 2-CHLORO-2',6'-DIETHYL-N-(METHOXYMETHYL)ACETANILIDE mf: C14H20ClN02 mw: 269.80 PROP: Crystals. Sltly sol in HzO;sol in Me2C0, C6H6, EtOH, and EtOAc. SYNS: ALACHLOR (USDA) 0 ALANEX 0 ALOCHLOR 0 CHLORESSIGSAEGRl-N-(METHOXYMETHYL)-2,6DIAETHYLANILID (GERMAN) 0 Z-CHLORO-N-(2,6DIETHYLPHENYL-rU'-(NETH0XYMETHYL)ACETAMIDE 0 CP 50144 0 LASSO 0 LAZO 0 METACHLOR METHACHLOR 0 PILLARZO
E
326
CFX250
1-CHLORO-1.1-DIFLUOROETHANE
CONSENSUS REPORTS: EPA Genetic
Toxicology Program. ACGIH TLV: inhalable fraction 1 mg/m3; (sensitizer);Confirmed Animal Carcinogen with Unknown Revelance to Humans SAFETY PROFILE: Moderately toxic by ingestion, skin contact, and possibly other routes. Questionable carcinogen with experimental carcinogenic data. Human mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,. CFX250 CAS: 75-68-3 HR: 1 1-CHLORO-1,l-DIFLUOROETHANE DOT: UN 2517 mf: CzH3ClFz mw: 100.50 PROP: Gas. Mp: -131', bp: -9.5', d: 1.19, lel: 9.0°/o, uel: 14.8%. Insol in water. SYNS: CFC 142b 0
CHLORODIFLUOROETHANES
(DOT) 0 CHLOROETHYLIDENEFLUORIDE 0 a-
CHLOROETHYLIDENEFLKORIDE n DIFLUOROCHLOROETHAhES (DOT) 0 1,l-DIFLUORO-lCHLOROETHANE 0 FC142b FLUOROCARBON FC142b 0 FREOS 142 0 FREON 142b 0 GENETRON 101 0 GENETRON 142b 0 GENTRON 142B 0 HYDROCHLOROFLUOROCARBON 142b 0 R142B (DOT)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: 1000 pprn (4200 mg/m3) DOT CLASSIFICATION: 2.1; Label: Flammable Gas SAFETY PROFILE: Very d d l y toxic by inhalation. Mutation data reported. A very dangerous fire hazard when exposed to heat, flame, or oxidzing materials. To fight fire, stop flow of gas. Can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of Fand C1-.
CFXSOO CAS: 75-45-6 HR: 1 CHLORODIFLUOROMETHANE DOT: UN 1018 mf: CHClF2 mw: 86.47 PROP: Gas. D: 1.49 @ 69'/4O, mp: -146', bp: -40.8', fp: -160', autoign temp: 1170'F. Sltly sol in water.
SYNS: ALGEON 22 0 ALGOFRENE 22 0 ALGOFRENE TYPE 6 0 ARCTON 4 0 ARCTON 22 0 CFC 22 0 CHLORODIFLUOROMETHANE 0 CHLORODIFLUOROMETHANE(ACGIH,DOT,OSHA) 0 DAIFLON 22 0 DIFLUOROCHLOROMETHANE 0 DIFLUOROiMONOCHLOROMETHANE 0 DYMEL 22 0 ELECTRO-CF22 0 ESKIMON 22 0 F 22 0 FC 22 0 FLUGENE 22 0 FLUOROCARBON-22 0 FORrtlJE 22 FREON 0 FREON 22 0 FRIGEN 0 FRIGEN 22 0 GENETRON 22 0 HALTRON 22 0 ISCEON 22 0 ISOTRON 22 0 KHALADON 22 0 MONOCHLORODIFLUOROMETHANE 0 PROPELLANT 22 0 R-22 0 R22 (DOT) 0 REFRIGERANT 22 0 UCON 22 0 UCON 22/HALOCARBON 22 CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,149,87; Human Inadequate Evidence IMEMDT 41,237,86; Animal Limited Evidence IMEMDT 41,237,86. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 1000 pprn ACGIH TLV: TWA 1000 ppm; Not Classifiable as a Human Carcinogen DFG MAK: 500 pprn (1800 mg/m3) DOT CLASSIFICATION: 2.2; Label: Nonflammable Gas SAFETY PROFILE: Mddly toxic by inhalation. Experimental reproductive effects. Mutation data reported. An asphpant in h g h concentrations. At elevated pressures, 50% mixtures with air are combustible although ignition is dfficult. When heated to decomposition it emits toxic fumes of F- and C1-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.
CFYOOO CAS: 58-93-5 HR: 3 6-CHLORO-3,4-DIHYDRO-PH-1,2,4BENZOTHIADIAZINE-7-SULFONAMIDE- 1,l-DIOXIDE mf: C7HsClN304S2 mw: 297.75 PROP: A solid. Mp: 273-275'. SYNS: AQUARIUS 0 AQUARIUS 0 BREMIL 0 6CHLORO-3,4-DIHYDRO-7-SULFAMOYL-2H-1,2,4BENZOTHIADIAZINE-1,l-DIOXIDE 0 6-CHLORO-7SULFAMOYL-3,4-DIHYDRO-2H-l,2,4-BENZOTHIADIAZINE-1,l-DIOXIDE 0 CHLOROSULTHJADIL 0 CHLORSULFONAMIDO DIHYDROBENZOTHIADIAZINE DIOXIDE 0 CHLORZIDE 0 CIDREX 0 DICHLOROSAL 0 DICHLOTIAZID 0 DICHLOTRIDE 0
l-CHLORO-2,4-DINITROBENZENE
CGMOOO 327
DICLOTRIDE 0 3,4-DIHYDRO-6-CHLORO-7-SULFALMYLCGH800 CAS: 29023-82-3 HR: 3 1,2,4-BENZOTHIADIAZINE-l,l-DIOXIDE 0 DIHYDRO2-CHLORO-9-(2,2-DIMETHYLHYCHLOROTHIAZID 0 DIHYDROCHLOROTHIAZIDE 0 DR INO)ACR IDINE 3,4-DIHYDROCHLOROTHIAZIDE 0 DIHYDROXYmf: CljH14ClN3 mw: 271.77 CHLOROTHIAZIDUM 0 DIREMA 0 DISALUNIL 0 SYN: ACRIDINE, 2-CHLORO-9-(2,2-DIMETHYLDRENOL 0 DYAZIDE 0 ESIDREX 0 ESIDRIX 0 HYDRAZIX0)FLUVIN 0 HCTZ 0 HCZ 0 HIDRIL 0 HIDROSAFETY PROFILE: A poison by ingestion. CHLORTIAZID 0 HIDRORONOL 0 HIDROTIAZIDA 0 When heated to decomposition it emits HYDRO-AQUIL 0 HYDROCHLORTHIAZID 0 toxic vapors of NO, and C1-. HYDRODIURETIC 0 HYDRO-DIURIL 0 HYDROSALURIC 0 HYDROTHIDE 0 HYPOTHIAZIDE 0 IDROTMZIDE 0 IVAUGAN 0 JEN-DIRIL 0 MASCHITT CGJ280 CAS: 17256-39-2 HR: 3 0 MEGADIURIL 0 NCI-C55925 0 NEFRIX 0 NEO1-CHLORO-N,N-DIMETHYL-P-PROPCODEMA 0 XEOFLUMEN 0 ORETIC 0 PAXURIN 0 ANAMINE HYDROCHLORIDE RO-HYDRAZIDE 0 SU 5879 0 THIARETIC 0 mf: CjH12ClN*ClH mw: 158.09 THIURETIC 0 THLARETIC 0 URODIAZIN 0 SYNS: (P-CHLOR0ISOPROPYL)DIMETHYLKMINE VETIDREX 0 ZIDE HYDROCHLORIDE 0 ETHYLAMINE,2-CHLORO-N,N-
AZ
CONSENSUS REPORTS: Reported in EPA TSCA Inventory.. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison bp intraperitoneal and intravenous routes. Moderately toxic by ingestion and subcutaneous routes. Human systemic effects by ingestion: sodum level changes, chlorine level changes, acute pulmonary edema, nausea or vomiting. Experimental reproductive effects. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. A duetic. When heated to decomposition it emits very toxic fumes of SO,, C1-, and NO,.
CGBSOO CAS: 1779-25-5 HR: 1 CHLORO DIISOBUTYL ALUMINUM mfi CsHldlC1 mw: 176.69 SYNS: ALLUMINIO DIISOBUTIL-hlONOCLORUR0 (ITALIAN) 0 BIS(IS0BUTYL)ALUMINUMCHLORIDE 0
CHLOROBIS(2-RfETHYLPROPYL)ALUMINL!Sf0 DIISOBUTYLALUMINUM CHLORIDE 0 DIISOBUTYLALUSIISUSI MONOCHLORIDE 0 DIISOBUTYLCHLOROhLL%iINUbi
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 2 mg(Al)/m3 SAFETY PROFILE: Mildly toxic by inhalation. See also ALUMINUM COMPOUNDS and CHLORIDES. Ignites spontaneously in air. When heated to decomposition it emits toxic fumes of C1-.
TRIMETHYL-, HYDROCHLORIDE 0 2-PROPAWAMINE, 1-CHLORO-N,N-DIMETHY, HYDROCHLORIDE
SAFETY PROFILE: A poison by ingestion. Moderately toxic by s h n contact. A severe eye irritant. When heated to decomposition it emits toxic vapors of NO,, HC1, and C1-.
CGL750 CAS: 25567-67-3 HR: 3 CHLORODINITROBENZENE DOT: UN 1577 mf: C6H3ClN204 mw: 202.56 SYNS: CHLORODINITROBENZENE (muted isomers) (DOT) 0 DINITROCHLOROBENZENE 0 DINITROCHLOROBENZENE (DOq
DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A poison by ingestion.
Mutation data reported. Potentially explosive. When heated to decomposition it emits very toxic fumes of C1- and NO,. See also other chloro-dinitrobenzenes. CGMOOO CAS: 97-00-7 HR: 3 1-CHLORO-2,4-DINITROBENZENE mf: C~H3ClN204 mw: 202.56 PROP: Yellow rhombic crystals from Et20; insol in water. Mp(a): 51', mp(p): 43', mp(y): 27', bp: 315' (sltly decornp), lel: 2.0%, uel: 22%, flash p: 382'F (CC), d(a): 1.687 @ 22', d(p): 1.680 @ 2Oo/4O, vap d: 6.98. SYNS: l-CHLOOR-2,4-DINITROBENZEEN (DCTCH) 0 l-CHLOR-2,4-DINITROBENZENE 0 4-CHLORO-1,3DINITROBENZENE 0 G-CHLORO-1,3-DINITROBEKZENE 0 l-CHLORO-2,4-DINITROBENZOL (GERMAN) 0 l-CLORO-2,4-DINITROBENZENE (ITALIAN) 0 2,4-DINITROCHLOROBENZENE 0 1,3-
E
328
CGNOOO
CHLORODIPHENYLARSINE
DINITRO-4-CHLOROBENZENE 0 2,4-DINITRO-lCHLOROBENZENE 0 DINITROCHLOROBENZOL 0 DNCB
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by skin contact and intraperitoneal routes. Moderately toxic by ingestion. A severe human skin and eye irritant. Acts as a primary irritant as well as a sensitizer of skin. An allergen. Mutation data reported. Combustible when exposed to heat or flame. A moderate explosion hazard when exposed to flame, sparks, heated to 150°, or when shocked in a sealed container. Explosive reaction with ammonia at 17OoC/40 bar. T o fight fire, use CO2, dry chemical. Reacts violently with hydrazine sulfate or hydrazine hydrate. See also NITRO COMPOUNDS of AROMATIC HYDROCARBONS.
CGNOOO CAS: 712-48-1 HR: 3 CHLORODIPHENYLARSINE DOT: UN 1699 mf: C12HmAsCl mw: 264.59 PROP: Colorless crystals when pure, technical product is dark-brown liquid. Mp: 44", bp: 333" (decornp), d: 1.333 @, 40" (solid), 1.358 @, 45' &quid), vap press: 0.00049 mm @ 20°, vap d: 9.15. Insol in H20; sol in org solvs. SYNS: BLUE CROSS 0 CLARK I 0 DA 0 DIPHENYLARSISOUS CHLORIDE 0 DIPHENYLCHLOORARSINE (DUTCH) 0 DIPHENYLCHLOROARSINE (DOT) 0 SNEEZING GAS CONSENSUS REPORTS: Arsenic and its
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(As)/m3 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A human poison by inhalation. Poison experimentally by inhalation and s h n contact. A powerfully irritating military poison. Exposure yields cold-like symptoms, plus headache, vomiting and nausea. A nonpersistent gas. Decontamination is by use of chlorine or caustic soda in confined spaces. When heated to decomposition it emits toxic
fumes of As and C1-. See also ARSENIC COMPOUNDS.
CG0500 CAS: 115-96-8 HR: 3 2-CHLOROETHANOL PHOSPHATE mf: C6H12C1304P mw: 285.50 PROP: Flash p: 421'F (COC), boiling range: 210-220' @, 20 mm, d: 1.425 @ 2Oo/2O0, autoign temp: 1115'F, vap press: 0.5 mm @, 145'. SYNS: CELLUFLEX 0 FYROL CEF 0 NCI-C60128 0 NIAX FLAME RETARDANT 3 CF 0 TRICHLORETHYL PHOSPHATE 0 TRI-P-CHLOROETHYL PHOSPHATE 0 TRI(2-CHLOR0ETHYL)PHOSPHATE0 TRIS(2CHLOR0ETHYL)ESTERPHOSPHORIC ACID 0 TRIS(PCHLOROETHYL) PHOSPHATE 0 TRIS(2-CHLOROETHYL) PHOSPHATE CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 48,109,90; Animal Inadequate Evidence IMEMDT 48,109,90. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental reproductive effects. Questionable carcinogen with experimental tumorigenic data. A skin and eye irritant. Combustible when exposed to heat or flame. When heated to decomposition it emits very toxic fumes of PO, and C1-. See also PHOSPHATES, CHLORIDES, and ESTERS.
CGU199 CAS: 627-11-2 HR: 3 2-CHLOROETHYL CHLOROFORMATE mf: C3H4C1202 mw: 142.97 PROP: Bp: 155.7', d: 1.3847, insoluble in water. SYNS: 2-CHLORETHYLESTER KYSELINY CHLORMRAVENCI 0 CHLOROFORMIC ACID 2CHLOROETHYLESTER 0 FORMIC ACID, CHLORO-, 2CHLOROETHYLESTER 0 TL 207 CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison, Corrosive
CHLOROETHYL ETHYL SULFIDE CGY750 329 SAFETY PROFILE: Poison by inhalation. May also cause fatahties by ingestion or s h n contact. May cause burns to the eyes and
skin. When heated to decomposition it emits toxic fumes of C1-. CGV250 CAS: 13010-47-4 HR: 3 1-(2-CHLOROETHYL)-3-CYCLOHEXYL1-NITROSOUREA mf: C9H16ClN302 mw: 233.73 PROP: Yellow powder. Mp: 90'.
CHLOROETHYL)-N-(I-METHYLETHYL)-2PROPANAMINE HYDROCHLORIDE 0 2(DIISOPROPYLAMIN0)ETHYLCHLORIDE HYDROCHLORIDE 0 2-PROPANAMINE,N-(2CHLOR0ETHYL)-N-(1-METHYLETHYL-, HYDROCHLORIDE 0 TRIETHYLttMINE, 2"-CHLORO1,It-DIMETHYL-,HYDROCHLORIDE
SAFETY PROFILE: A poison by ingestion, inhalation, and skin contact. A severe s h n and eye irritant. When heated to decomposition it emits toxic vapors of NO,, HC1, and C1-.
SYNS: BELUSTINE 0 CCNU 0 CECENU 0 CEENU 0 CGWOOO CAS: 107-99-3 HR: 3 CHLOROETHYLCYCLOHEXYLNITROSOUREA0 N-(2N-(2-CHLOROETHYL)DIMETHYLAMlNE CHLOR0ETHYL)-N'-CYCLOHEXYL-N-NITROSOLREA 0 (CHLORO-2-ETHYL)-l-CYCLOHEXYL-3-NITROSOUREA mf: C4HloClN mw: 107.60 0 CINC 0 (CLORO-2-ETIL)-l-CICLOESIL-3-NITROSO- PROP: Liquid. Vap d: 3.72. UREA (ITALIAN) 0 ICIG 1109 0 LOMUSTINE 0 NCISYNS: CHLORO(DIMETHYLAMIN0)ETHANE 0 pC04740 0 NSC-79037 0 RB 1509 0 SRI 2200 CHLOROETHYLDIMETHEfINE 0 (2-CHLORO-
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 2A IMEMDT 7,150,87; Human Limited Evidence IMEMDT 26,137,81; Animal Sufficient Evidence IMEMDT 26,137,81. NCI Carcinogenesis Studies (ipr); Clear Evidence: mouse CANCAR 40,1935,77; No Evidence: rat CANCAR 40,1935,77. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion, intraperitoneal, subcutaneous, intravenous, and possibly other routes. Human systemic effects by ingestion: anorexia, nausea or vomiting, leukopenia (decrease in the white blood cell count), and thrombocytopenia (decrease in the number of blood platelets). Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,. See also NNITROSO COMPOUNDS. CGV6OO CASE4261-68-1 HR: 3 2-CHLOROETHYLDIISOPROPYLAMINE HYDROCHLORIDE mf: CsH&lN*ClH mw: 200.18 SYNS: (P-CHLOR0ETHYL)DIISOPROPYLAMINE HYDROCHLORIDE 0 N-(CHLOROETHYLDIISOPROPYLAMINE HYDROCHLORIDE 0 N-(2-
ETHYL)DIMETHYLAMINE 0 DIiMETHYLAMINOETHYL CHLORIDE 0 p-(DIMETHYL%MINO)ETHYL CHLORIDE 0 2-DIMETHYLhhlINOETHYLCHLORIDE 0 DIMETHYL(2-CHLOR0ETHYL)AMINE0 HN 1 0 NITROGEN HALF IMLSTARD
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by an unspecified route. A systemic irritant. Mutation data reported. When heated to decomposition it emits highly toxic fumes of C1- and NO,.
CGY750 CAS: 693-07-2 HR: 3 CHLOROETHYL ETHYL SULFIDE mf: C4H9ClS mw: 124.64 PROP: Liquid with penetrating odor. D: 1.07 @ 25"/4', bp: 156.5'. SYNS: 2-CHLOROETHYLETHYL SULFIDE 0 2CHLOROETHYLETHYL THIOETHER 0 l-CHLORO-2(ETHYLTHI0)ETHANE 0 ETHYL-P-CHLOROETHYL SULFIDE 0 ETHYL-2-CHLOROETHYL SULFIDE 0 pETHYLMEWMOETHYLCHLORID (CZECH) 0 2(ETHYLTHI0)CHLOROETHANE 0 2-ETHYLTHIOGAS 0 h-MG ETHYL CHLORIDE 0 HALF-IMUST~~RD
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by ingestion and subcutaneous routes. Mutation data reported. A severe skin and eye irritant. See also ETHERS and SULFIDES. When
330
CHCSOO CHLOROETHYL MERCURY
heated to decomposition it emits very toxic fumes of C1- and SO,.
CHCSOO CAS: 107-27-7 HR: 3 CHLOROETHYL MERCURY mf: CaHsClHg mw: 265.11 PROP: Silvery, iridescent leaflets from EtOH. Mp: 196-198'. Sltly sol in Eta0 and EtOH; sol in CHCl3; insol in H20. IDLH 10 mg/m3 (as Hg). SYNS: CERESAN 0 EMC 0 ETHYLMERCURIC CHLORIDE 0 ETHYLMERCURY CHLORIDE 0 G A N O W N 0 GRANOSAN CONSENSUS REPORTS: Mercury and its
compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.01 mg(Hg)/m3; STEL 0.03 mg/m3 (skm) ACGIH TLV: TWA 0.01 mg(Hg)/m3; BEI: 35 pg/g creatinine total inorganic mercury in urine presluft; 15 pg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Organomercury) TWA 0.01 mg/m3; STEL 0.03 mg/m3 (skm) SAFETY PROFILE: Poison by ingestion, inhalation, skm contact, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. See also MERCURY COMPOUNDS, ORGANIC. When heated to decomposition it emits very toxic fumes of C1- and Hg.
CHC750 CAS: 3570-58-9 2-CHLOROETHYL METHANESULFONATE mf: C3HK103S mw: 158.61 PROP: Bp: 125-126' @? 9 mm. SYNS: CB 1506 0 p-
HR: 3
CHLOROETHYLMETHANESULFONATE 0 CHLOROETHYL METHANESULPHONATE 0 CHLOROMETHANE SULFONATE d'ETHYLE (FRENCH) D METHANESULFONIC ACID CHLOROETHYL ESTER 0 NSC-18016
CONSENSUS REPORTS: EPA Genetic
Toxicology Program.
SAFETY PROFILE: Poison by ingestion, intravenous, and intraperitoneal routes. Experimental reproductive effects. Mutation data reported. See also SULFONATES. When heated to decomposition it emits very toxic fumes of C1- and SO,.
CHD250 CAS: 13909-09-6 HR: 3 1-(2-CHLOROETHYL)-3-(4-METHYLCYCLOHEXYL)-1-NITROSOUREA mf: C10H1gClN302 mw: 247.76 PROP: Mp: 64" (decomp). SYNS: N-(~.CHLOROETHYL)-N'-(~~~~S-~-METHYLCYCLOHEXYL-N-NITROSOUREA0 1-(2-CHLOROETHYL)-3-(trans-4-IMETHYLCYCLOHEXYL)-lNITROSOUREA 0 ICIG 1110 0 ME-CCNU 0 METHYLCCNU 0 trans-METHYL-CCNU 0 IMETHYL-LOMUSTINE NCI-C04955 0 NSC-95441 0 SEMUSTINE
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 7,150,87; Animal Limited Evidence 7,150,87; Human Sufficient Evidence IMEMDT 7,150,87. NCI Carcinogenesis Studies (ipr); Clear Evidence: rat CANCAR 40,1935,77; No Evidence: mouse CANCAR 40,1935,77. SAFETY PROFILE: Confirmed human carcinogen producing leukemia. Experimental carcinogenic and tumorigenic data. Poison by ingestion, intraperitoneal, intravenous, and possibly other routes. Mutation data reported. Human systemic effects by ingestion: nausea or vomiting, damage to kidney tubules and glomeruli, and hematuria (blood in the urine). When heated to decomposition it emits very toxic fumes of C1- and NO,. See also N-NITROSO COMPOUNDS.
CHEOOO CAS: 3647-69-6 HR: D 4-(2-CHLOROETHYL)MORPHOLINE HYDROCHLORIDE mf: C6H12ClNO*ClH mw: 186.10 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,.
CHLOROFORM CHJSOO 331
CHFSOO CAS: 6296-45-3 HR: 2 2-CHLOROETHYL-NNITROSOURETHANE mf: CjH9ClN203 mw: 180.61 SYNS: N-(Z-CHLOROETHYL)-NNITROSOETHYLCARBAMATE 0 N-(P-CHL0ROETHYL)N-NITROSOURETHAN 0 ETHYL-N-(P-CHLOROETHYL)-N-NITROSOCARBASLATE 0 TL 154
SAFETY PROFILE: Poison by inhalation, ingestion, and intraperitoneal routes. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Many N-nitroso compounds are carcinogens. See also CARBAMATES and N-NITROSO COMPOUNDS. When heated to decomposition it emits very toxic fumes of C1- and NO,.
CHGOOO CAS: 113-18-8 HR: 3 1-CHLORO-3-ETHYL-I -PENTEN-4-YN-3OL mf: C7H9C10 mw: 144.61 PROP: Liquid with pungent, aromatic odor, slowly darkening on exposure to light and air. D: 1.065-1.070 @ 25'/4", bp: 173-174'. Msc most org solvents; immisc in HzO. SYNS: A 71 0 AETHYL-CHLORWOL 0 ALVINOL 0 ART~YNOL P-CHLOROLTNYL ETHYLETHYNYL CARBINOL 0 3-@-CHLOROVINYL)-l-PENTYN-3-OL 0 ETCHLORVINOLO 0 ETHCHLOROVYNOL 0 ETHCHLORVINYL 0 E T H C L O R W O L 0 ETHOCHLORVYNOL 0 ETHYI-P-CHLOROVINYLETHYNYL CARBINOL ETHYLCHLORVYNOL 0 NOR\IONSON 0 NORbIOSAN 0 NORMOSON 0 NOSTEL 0 PLACIDIL 0 PLACIDYL 0 ROERIDORM 0 SERENIL 0 SERENSIL
SAFETY PROFILE: Poison by ingestion,
subcutaneous, intraperitoneal, and intravenous routes. Human systemic effects by ingestion: general anesthesia and thrombocytopenia (reduction in the number of blood platelets). Human effects on newborn by an unspecified route: drug dependency and Apgar score (condtion of newborn). Experimental teratogenic and reproductive effects. When heated to decomposition it emits toxic fumes of C1-. CHI250 CAS: 110-75-8 HR: 3 2-CHLOROETHYL VINYL ETHER
mf: C4H7C10 mw: 106.56 PROP: Liquid. Mp: -70.3', bp: 108', d: 1.05 @ 20°/4", flash p: 80°F (OC). SYNS: 2-CHLORETHYL VIKYL ETHER 0 (2CHLOROETHOWETHENE 0 RCRA WASTE NUMF3ER U042 0 VINYL-P-CHLOROETHYL ETHER 0 VINYL-2-CHLOROETHYL ETHER
CONSENSUS REPORTS: Reported in
EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion. Moderately toxic by inhalation and skin contact. A severe eye and skin irritant. See also ETHERS. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Potentially explosive. May form dangerous peroxides on exposure to air. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits toxic fumes of C1-. See also CHLORIDES and ETHERS. CHI900 CAS: 593-70-4 CHLOROFLUOROMETHANE mf: CH2ClF mw: 68.48 PROP: Gas. Bp: -9'. SYNS: CFC 31 0 FC 31 0 FREON 31 0
HR: 3
MONOCHLOROMONOFLL!OROnlETHANE 0 R 31 0 R 31 (refrigerant)
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 41,229,86. DFG MAK: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by inhalation. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and F-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.
CHJ500 CAS: 67-66-3 HR: 3 CHLOROFORM DOT: UN 1888 mf: CHClj mw: 119.37 PROP: Colorless liquid; heavy, ethereal odor, Mp: -63.2', bp: 61.3', flash p: none, d: 1.481 @ 25"/4", vap press: 100 mm @
E
332
CHJ750 4-CHLORO-N-FURFURYL
10.4', vap d: 4.12. Sltly sol in HzO. IDLH 500 ppm. SYNS: CHLOROFORME (FRENCH)
CLOROFORMIO (ITALIAN) 0 FORMYL TRICHLORIDE 0 METHANE TRICHLORIDE 0 METHENYL TRICHLORIDE 0 METHYL TRICHLORIDE 0 NCI-C02686 0 R 20 (refrigerant) 0 RCRA WASTE NUMBER UO44 0 TCM 0 TRICHLOORMETHAAN (DUTCH) 0 TRICHLORMETHAN (CZECH) 0 TRICHLOROFORM 0 TRICHLOROMETHANE 0 TRICLOROMETANO (ITALIAN)
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,152,87; Animal Limited Evidence IMEMDT 1,61,72; Human Lirmted Evidence IMEMDT 20,401,79; Animal Sufficient Evidence IMEMDT 20,401,79. NCI Carcinogenesis Bioassay (gavage); Clear Evidence: mouse, rat NCITR* NCI-CG-TR,1976. EPA Genetic Toxicology Program. EPA Extremely Hazardous Substances List. Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 2 pprn ACGIH TLV: TWA 10 ppm; Suspected Human Carcinogen; Animal Carcinogen DFG MAK: 10 pprn (50 mg/m3); Confirmed Animal Carcinogen with Unknown Relevance to Humans) NIOSH REL: (Waste Anesthetic Gases and Vapors) CL 2 ppm/lH; (Chloroform) CL 2 ppd6OM DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. A human poison by ingestion and inhalation. An experimental poison by ingestion and intravenous routes. Moderately toxic experimentally by intraperitoneal and subcutaneous routes. Human systemic effects by inhalation: hallucinations and distorted perceptions, nausea, vomiting, and other unspecified gastrointestinal effects. Human mutation data reported. Experimental teratogenic and reproductive effects.
Inhalation of the concentrated vapor causes dilation of the pupils with reduced reaction to light, as well as reduced intraocular pressure (experimental). In the initial stages there is a feeling of warmth of the face and body, then an irritation of the mucous membranes, conjunctiva, and sktn; followed by excitation, loss of reflexes, sensation, and consciousness. Prolonged inhalation will bring on paralysis accompanied by carcbac-respiratory failure and finally death. Chloroform has been widely used as an anesthetic. However, due to its toxic effects, this use is being abandoned. Concentrations of 68,000-82,000 pprn in air can kill most animals in a few minutes. 14,000 pprn may cause death after an exposure of from 30 to 60 minutes. 5000-6000 pprn can be tolerated by animals for 1 hour without serious cbsturbances. The maximum concentration tolerated for several hours or for prolonged exposure with slight symptoms is 2000-2500 ppm. Prolonged administration as an anesthetic may lead to such serious effects as profound toxemia and damage to the liver, heart, and kidneys. Experimental prolonged but light anesthesia in dogs produces a typical hepatitis. Explosive reaction with socbum + methanol or sodium methoxide + methanol. Mixtures with sodum or potassium are impact-sensitive explosives. Reacts violently with acetone + alkali (e.g., sodium hydroxide, potassium hydroxide, or calcium hydroxide), Al, disilane, Li, Mg, methanol + alkali, nitrogen tetroxide, perchloric acid + phosphorus pentoxide, potassium-tertbutoxide, sodium methylate, NaK. Incompatible with dinitrogen tetraoxide, fluorine, metals, or triisopropylphosphine. Nonflammable. When heated to decomposition it emits toxic fumes of C1-. See also CHLORINATED HYDROCARBONS ,ALIPHATIC.
(-)-N-((5-CHLORO-SH YDROXY-9METHYL- 1-0XO-
CHJ750 CAS: 54-31-9 HR: 3 4-CHLORO-N-FURFURY L-5SULFAMOYLANTHRANILICACID mf: C12HllClN20jS mw: 330.76 PROP: Crystals from EtOH (a$. Mp: 206’. SYNS: AISEMIDE 0 ALUZINE 0 5(AMINOSCLFURANYL-4-CHLORO-2-((2FURWLYLMETHYL)A~~~INO)BE~’ZOIC ACID 0 BEROKALD 0 CHLOR-N:-(2-FURYLh4ETHYL-5SULFAMkUVTHMNILSAEL‘RE ( G E R W ’ ) 0 4-
CHLORO-K-(2-FL!RKMETHYL)-5-SL!LFAMOYLANTHRANILIC ACID 0 DESDEMIN 0 DIURAL 0 DRYPTAL 0 ERROLON 0 EUTENSIN 0 FRUSEMIDE 0 FRUSEMIN 0 FRUSID 0 FULSIX 0 FULUVAhfIDE 0 FURANTHRIL 0 FCRAhTHRYL 0 FL!RrWTRIL 0 FURESIS 0 FUROSEDON 0 FUROSEMID 0 FUROSEhlIDE 0 FUROSEMIDE “hlITA” 0 FURSEhfID 0 FURSEhfIDE 0 FUSID 0 HYDRO-RAPID 0 KATLEX 0 LASEX 0 LASIX 0 LB 502 0 LOWPSTRON 0 MACASIROOL 0 NCI-C55936 0 NICOROL 0 PREFEMIN 0 PROFEMIN 0 RADONNA 0 ROSEMIDE 0 SALIX 0 SEGURIL 0 TRANSIT 0 TROFURIT 0 UREX 0 UROSEMIDE
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 50,277,90; Human Inadequate Evidence IMEMDT 50,277,90; Animal Inadequate Evidence IMEMDT 50,277,90. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intravenous route. Moderately toxic by ingestion and intraperitoneal routes. Human systemic effects by intravenous route: change in the sensitivity of the ear to sound, tinnitus, unspecified effects on the heart, constriction of the arteries, a decrease in urine volume, interstitial nephritis, metabolic alkalosis, pulse rate decrease, fall in blood pressure. Ingestion can damage the liver. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of C1-, NO,, and SO,.
CHL250 CAS: 13654-91-6 HR: 3 CHLOROHEXYL ISOCYANATE DOT: UN 2206/UN 2207/UN 2478/UN
3080 mf: C7HloClNO
mw: 159.63
CHP250 333
SYNS: 6-CHLORHEXYLISOKYANAT 0 ISOCYAKIC ACID, 6-CHLOROHEXYL ESTER
DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD (UN 2207); DOT Class: 6.1; Label: Poison (UN 2206); DOT Class: 6.1; Label: Poison, Flammable Liquid (UN 3080); DOT Class: 3; Label: Flammable Lquid, Poison (UN 2478) SAFETY PROFILE: Poison by inhalation. See also THIOCYANATES and ESTERS. A flammable liquid. When heated to decomposition it emits very toxic fumes of C1- and NO,.
CHMOOO CASE615-67-8 HR: 3 CHLOROHYDROQUINONE mf: C6HjC102 mw: 144.56 PROP: Leaflets from CHCl3; needles from toluene. Mp: 106’, bp: 263’. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of C1-. See also CHLORIDES. CHP250 CAS: 303-47-9 HR: 3 (-)-N-((5-CHLORO-8-HYDROXY-3METHYL-1-0XO-7-ISOCHROMANYL)CARBONYL)S-PHENYLALANINE mf: C ~ ~ H I ~ C ~ Nmw: O ~403.84 PROP: Crystals from xylene. Mp: 169’. SYNS: (R)N-((5-CHLOR0-3,4-DIHYDRO-8-HYDROXY-3METHYL 1 - 0 x 0 - 1H-2-BENZOPYR4i%7-YL))PHENYL ALANINE 0 NCI-C56586 0 OCHRATOXIN A
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 2B IMEMDT 56,489,93; Animal Limited Evidence IMEMDT 31,191,83; Animal Sufficient Evidence IMEMDT 56,489,93; Human Inadequate Evidence IMEMDT 31,191,83; Human Inadequate Evidence IMEMDT 56,489,93. SAFETY PROFILE: Confirmed carcinogen with carcinogenic and neoplastigenic data. Poison by ingestion, intraperitoneal, intravenous, and subcutaneous routes.
334
CHP5OO 5-CHLORO-2-((2-HYDROXY
Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,.
CHR500 CAS: 130-26-7 HR: 3 5-CHLORO-7-IODO-8-QUINOLlNOL mf: C9H5ClINO mw: 305.50 PROP: Brownish-yellow powder, darkens when exposed to light. Sltly sol in EtaO.
SYNS: ALCHLOQUIN 0 AMEBIL 0 AMOENOL 0 BACTOL 0 BARQUINOL 0 BUDOFORM 0 CHINOFORM 0 5-CHLOR-7-JOD-S-HYDROXYCHINOLIN (GERbKN) 0 5-CHLORO-8-HYDROXY-7IODOQUINOLINE 0 5-CHLORO-7-IODO-8HYDROXYQUINOLINE 0 CHLOROIODOQUINE 0 SYNS: BRIGHT RED 0 BRILLIANT RED 0 BRILLIANT CLIOQUINOL 0 CLIQUINOL 0 ECZECIDIN 0 SCARLET 0 BRILLIANT TONER Z 0 BRONZE RED RO EMAFORM 0 ENTERO-BIO FORhf 0 ENTEROQUINOL 0 BRONZE SCARLET 0 5-CHLORO-2-((2-HYDROXY-l- 0 ENTEROSEPTOL 0 ENTERO-VIOFORhf 0 NAPHTHALENYL)AZO)-4-METHYLBENZENE ENTEROZOL 0 ENTERUM LOCORTEN 0 ENTROKIN SCLFONIC ACID, BARIUM SALT (2:l) 0 5-CHLORO-2-((20 HI-ENTEROL 0 HYDRIODIDE-ENTROL 0 HYDROXY-1-NAPHTHALENYL)AZO)-4-METHYLIODENTEROL 0 IODOCHLORHYDROXYQUINOL 0 BENZENE SULPHONIC ACID, BARIUM SALT 0 1-(4IODOCHLORHYDROXYQUINOLINE 0 7-IODO-5CHLORO-O-SULFO-~-TOLYL~~ZO)-~-NAPHTHOL,CHLORO-8-HYDROXYQUINOLINE 0 7-IODO-5BARIUM SALT 0 C.I. PIGMENT RED 0 COSMETIC CHLOROXINE 0 IODOENTEROL 0 NIOFORIM 0 CORAL RED KO BLUISH 0 DAIKICHI LAKE RED C 0 QUINAiiBICIDE 0 ROMETIN 0 VIOFORM 0 D&C RED No. 9 0 DESERT RED 0 ELJON LAKE RED C VIOFORM N.N.R. 0 HAMILTON RED 0 HELIO RED TONER LCLL 0 CONSENSUS REPORTS: Reported in EPA IRGALITE RED CBN 0 ISOL LAKE RED LCS 12527 0 TSCA Inventory. EPA Genetic Toxicology LAKE RED C 0 LATEXOL SCARLET R 0 LD RUBBER RED 16913 0 LUTETIA RED CLV 0 MICROTEX LAKE Program. RED CR 0 MOHICAN RED A-8008 0 NCIK53792 0 No. 3 SAFETY PROFILE: Poison by ingestion. C O X . SCARLET 0 PARIDINE RED LCL 0 PIGMENT Moderately toxic by intraperitoneal route. RED CD 0 POTOMAC RED 0 RECOLITE RED LAKE C Human systemic effects by ingestion: 0 1860 RED 0 RED SCARLET 0 SANYO LAKE RED C 0 change in central nervous system electrical SEGNALE RED LC 0 SIC0 LAKE RED 2L 0 SUPEROL function, optic nerve damage, and changes RED C RT-265 0 SYMULER LAKE RED C 0 TERMOin vision. Experimental teratogenic and SOLID0 RED LCG 0 TEXAN RED TONER D 0 TONER LAKE RED C 0 TRANSPARENT BRONZE SCARLET 0 reproductive effects. Human mutation data VULCAFIX SCARLET R 0 VULCAN RED LC 0 WLCOL reported. When heated to decomposition it FAST RED L 0 WAYNE RED X-2486
CHP500 CAS: 5160-02-1 HR: 2 5-CHLORO-2-((2-HYDROXY-1-NAPHTHYL)AZO)-I>-TOLUENESULFONIC ACID, BARIUM SALT mf: C17H12ClN20&*1/2Ba mw: 444.49
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 57,203,93; Animal Inadequate Evidence IMEMDT 8,107,75; Human No Adequate Data IMEMDT 8,107,75; Human Inadequate Evidence IMEMDT 57,203,93. NTP Carcinogenesis Bioassay (feed); Clear Evidence: rat NTPTR* NTP-TR-225,82; No Evidence: mouse NTPTR* NTP-TR225,82. Reported in EPA TSCA Inventory. SAFETY PROFILE: Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of SO,, NO,, and C1-. See also SULFONATES.
emits very toxic fumes of C1-, I-, and NO,.
CHS250 CAS: 4288-84-0 HR: D 1-CHLOR0-2-ISOPROPOXY-2PROPANOL mf: C6H13C102 mw: 152.64 SYNS: l-CHLORO-3-(PENTYLOXY)-2-PROPANOL 0 2PROPANOL, 1-CHLORO-3-ISOPROPOXY-0 U 25,352
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFlLE: Experimental
reproductive effects. When heated to decomposition it emits toxic fumes of C1-. CHUSOO CAS: 59-85-8 HR: 3 pCHLOROMERCURIC BENZOIC ACID mf: C7H5ClHg02 mw: 357.16 PROP: A solid. Mp: 273'.
7-CHLOROMETHYLBENZ(a)ANTHRACENE CIG250 335 SYNS: @-CARB0XYPHENYL)CHLOROMERCURY 0 p-
SAFETY PROFILE: Poison by ingestion,
(CHLOR0MERCURI)BENZOIC ACID 0 USAF D-3
subcutaneous, intravenous, and intraperitoneal routes. An antiseptic. See also MERCURY COMPOUNDS, ORGANIC; and CHLOROPHENOLS. When heated to decomposition it emits toxic fumes of C1- and Hg.
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Mercury and its compounds are on the Community RightTo-Know List. OSHA PEL: CL 0.1 mg(Hg)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 kg/g creatinine total inorganic mercury in urine preshft; 15 kg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (shn) SAFETY PROFILE: Poison by intraperitoneal route. See also MERCURY COMPOUNDS. When heated to decomposition it emits very toxic fumes of C1- and Hg. CHW675 CAS: 90-03-9 HR: 3 O-CHLOROMERCURIPHENOL mf: C6H5ClHgO mw: 329.15 PROP: Crystals from HzO. Mp: 152.5'. IDLH 10 mg/m3 (as Hg). SYNS: CHLORO(o-HYDR0XYPHENYL)MERCURY 0 oHYDROXYFENYLMERKURICHLORID 0 o-HYDROXYPHENYLMERCURIC CHLORIDE 0 MERCUFENOL CHLORIDE 0 MERCURY, CHLORO(2-HYDROXYPHENYL)- 0 MYRINGACAINE DROPS 0 PHENOL, o(CHL0ROMERCURI)- 0 SALICRESIN FLUID 0 U-7743 0 USPULUbl
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Mercury and its compounds as well as chlorophenol compounds are on the Community RightTo-Know List. OSHA PEL: CL 0.1 mg(Hg)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 kg/g creatinine total inorganic mercury in urine preshift; 15 kg/g creatinine total inorganic mercury in blood at end of shft at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skin)
CHW750 CAS: 623-07-4 HR: 3 p-CHLOROMERCURIPHENOL mf: CbHSClHgO mw: 329.15 PROP: Plates from MeKO. Mp: 226-227'. IDLH 10 mg/m3 (as Hg). SYNS: CHLORO@-HYDR0XYPHENYL)MERCURY
p-
(CHLOR0MERCURI)PHENOL
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Mercury and its compounds as well as chlorophenol compounds are on the Community hghtTo-Know List. OSHA PEL: CL 0.1 mg(Hg)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Hg)/m3 (sktn); BEI: 35 Fg/g creatinine total inorganic mercury in urine preshift; 15 kg/g creatinine total inorganic mercury in blood at end of shift at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (shn) SAFETY PROFILE: Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of C1- and Hg. See also MERCURY COMPOUNDS, ORGANIC; and CHLOROPHENOLS.
CIF775 CAS: 60177-39-1 HR: D CHLOROMETHYLATED AMINATED STRYENE-DIVINYLBENZENERESIN SAFETY PROFILE: When heated to decomposition it emits toxic fumes of C1and NOa. CIG250 CAS: 6325-54-8 HR: 3 7-CHLOROMETHYL BENZ(a)ANTHRACENE mf: C19H13C1 mw: 276.77 SYN: ICR 451
336
CIK750 3-CHLORO-4-METHYL-7-COUMARlNYL
SAFETY PROFILE: Poison by intravenous route. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic C1-. See also CHLORINATED HYDROCARBONS, AROMATIC.
CIK750 CAS: 321-54-0 HR: 3 3-CHLORO-4-METHYL-7-COUM ARINYL DIETHYLPHOSPHATE mf: Ci4Hi6C106P mw: 346.72 SYNS: COROXON 0 COUiMAPHOS-O-ANALOG 0
7-CHLOROMETHYL-12-METHYLBENZ(a)ANTHRACENE mf: C20H15C1 mw: 290.80 SYN: IRC 453 CONSENSUS REPORTS: EPA Genetic
Toxicology Program. SAFETY PROFILE: Poison by intravenous route. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic C1-. See also CHLORINATED HYDROCARBONS, AROMATIC.
COUMAPHOS OXYGEN ANALOG (USDA) 0 0,0-D1(2-
CHLOROETHYL)-7-(3-CHLORO-4-METHYLCOUbiARINYL)PHOSPHATE 0 O,O-DIETHYL-O-(3-CHLORO-4METHYLCOUMARIN-7-YL)PHOSPHATE0 DIETHYL-3CHLORO-4-hZETHYI-7-COUMARINYLPHOSPHATE 0 PHOSPHORIC ACID, DIETHYL ESTER, wth 3-CHLORO7-HYDROXY-4-METHYLCOUhRIN
SAFETY PROFILE: Deadly poison by ingestion. When heated to decomposition it emits very toxic fumes of PO, and C1-. See also ESTERS and PHOSPHATES.
CIL800 CAS: 4362-40-7 HR: 3 4-( CHLOROMETHYL)-2,2-DIMETHYL1,bDIOXOLANE mf: C6H11C102 mw: 150.62 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of C1-. CIMOOO CAS: 3188-13-4 HR: 3 CHLOROMETHYL ETHYL ETHER mf: C3H7C10 mw: 94.54 PROP: Flash p: <-2.2'F, bp: 83'. SYNS: CHLOROMETHOXY ETHANE 0 ETHOXY CHLOROMETHANE 0 ETHOXY METHYL CHLORIDE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by inhalation and ingestion. A very dangerous fire and explosion hazard when exposed to heat or flame. See also ETHERS.
CIN750
CAS: 13345-62-5 HR: 3
C10250 CAS: 107-30-2 HR: 3 CHLOROMETHYL METHYL ETHER DOT: UN 1239 mf: C2H5C10 mw: 80.52 PROP: Liquid. Flash p: <73.4'F, d: 1.070 @ 25 mm, bp: 59.5'. SYNS: CHLORDIMETHYLETHER(CZECH) 0 CKME
0 DIMETHYLCHLOROETHER ETHER METHYLIQUE MONOCHLORE (FRENCH) 0 METHYLCHLOROMETHYL ETHER (DO'I) METHYL. CHLOROMETHYL ETHER, anhydrous (DOT) 0 MONOCHLORODIMETHYL ETHER PWK) 0 RCRA WASTE NUMBER U046
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 1 IMEMDT 7,131,87; Animal Sufficient Evidence IMEMDT 4,239,74; Human Limited Evidence IMEMDT 4,239,74. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. Community Ihght-To-Know List. EPA Extremely Hazardous Substances List. OSHA PEL: OSHA: Cancer Suspect Agent ACGIH TLV: Suspected Human Carcinogen DFG MAK: Human Carcinogen NIOSH REL: (Methyl Chloromethyl Ether) TWA use 29 CFR 1910.1006 DOT CLASSIFICATION: 6.1; Label: Poison, Flammable Liquid SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic, tumorigenic, and neoplastigenic data. Poison by inhalation. Moderately toxic by ingestion. Human mutation data reported. A very dangerous fire hazard when exposed to heat or flame. T o fight fire, use alcohol foam,
4-CHLORO-2-METHYLPHENOXY
water, C02, or dry chemical. Reaction with dvalent metals forms a very reactive product. When heated to decomposition it emits toxic fumes of C1-. See also ETHERS and CHLORINATED HYDROCARBONS, ALIPHATIC. ClQ500 CAS: 16339-16-5 HR: 3 2-CHLORO-N-METHYL-N-NITROSOETHYLAMlNE mf: C3H7ClNzO mw: 122.57 SYNS: 2-CHLORO-2-METHYL-N-NITROSOE T W A M I N E 0 METHYL-2-CHLORAETHYLNITROSAMIN (GERMAN) 0 METHYL(2CHLOR0ETHYL)NITROSAIMINE 0 NNITROSOMETHYL-2-CHLOROETHUMINE
SAFETY PROFILE: Poison by ingestion, intravenous, and possibly other routes. Questionable carcinogen with experimental tumorigenic data. Many nitrosamine compounds are carcinogens. When heated to decomposition it emits very toxic fumes of C1- and NO,. See also NITROSAMINES.
CIR250 CAS: 94-74-6 HR: 3 (4-CHLORO-2-METHYLPHEN0XY)ACETIC ACID mf: C9H9C103 mw: 200.63 PROP: Crystals from C6H6 or toluene. Mp: 120°. SYNS: AGRITOX 0 AGROXONE 0 ANICON KOhIBI 0 ANICON M 0 BH IclCPA 0 BORDERMASTER 0 BROMINAL hl & PLUS 0 B-SELEKTONON M 0 CHIPTOX 0 4-CHLORO-o-CRESOXYACETIC ACID 0 4CHLORO-o-TOLOXYACETIC ACID 0 ((4-CHLORO-oT0LYL)OXY)ACETIC ACID 0 CHWASTOX CORbJOXM 0 DED-WEED 0 DICOPUR-M 0 DICOTEX 0 DOW MCP AMINE WEED KILLER 0 EMCEPAN 0 EMPAL 0 HEDAPUR M 52 0 HERBICIDE M 0 HORMOTUHO 0 4K-2M 0 KILSEM 0 KREZONE 0 LEGUMEXDB 0 LEUNA M 0 LEYSPRAY 0 LINORMONE 0 hl 40 0 2M4C 0 MCP 0 MCPA 0 MEPHANAC 0 METAXON 0 METHOXONE 0 2-METHYL-4-CHLOROPHENOXYACETIC ACID 0 2-METHYL-4-CHLORPHENOXYESSIGSAEURE (GERMAN) 0 2hf-4KH 0 NETAZOL 0 OKULTIN M 0 PHENOXYLENE SUPER 0 RAPHONE 0 RAZOL DOCK KILLER 0 RHOMENE 0 RHONOX 0 SEPPIC MMD 0 SHAMROX 0 SOVIET TECHNICAL HERBICIDE 2M-4C 0 TRASAN 0 U 46 M-FLUID 0 USTINEX 0 VACATE 0 VERDONE 0 VES4KONTUHO
CIR500 337
MCPA 0 WEEDAR MCPA CONCENTRATE 0 WEEDONE MCPA ESTER 0 WEED-RHAP 0 ZELAN
CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 7,156,87; Animal Inadequate Evidence IMEMDT 30,255,83; Human Inadequate Evidence IMEMDT 30,255,83; Human Limited Evidence IMEMDT 41,357,86. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFlLE: Suspected carcinogen. Poison by subcutaneous and intravenous routes. Moderately toxic by ingestion. Human systemic effects by ingestion: blood pressure decrease and coma. Experimental teratogenic and reproductive effects. Mutation data reported. An herbicide. When heated to decomposition it emits toxic fumes of C1-. CIR500 CAS: 93-65-2 HR: 3 4-CHLORO-2-METHYLPHENOXY-aPROPIONIC ACID mf: CKIHIICIO~ mw: 214.66 SYNS: ACIDE 2-(4-CHLORO-2-METHYLPHEN0XY)PROPIONIQUE (FRENCH) 0 ACID0 2-(4CLORO-2-METIL-FENOSSI)-PROPIONICO (ITALIAN) 0 BH MECOPROP 0 CHIPCO TURF HERBICIDE MCPP 0
2-(4-CHLOOR-2-METHYL-FENOXY)-PROPIONZUUR (DUTCH) 0 2-(4-CHLOR-2-METHYL-PHENOXY)PROPIONSAEURE (GERMAN) 0 (+)-a-(4-CHLORO-2METHYLPHENOXY) PROPIONIC ACID 0 2-(4-CHLORO2-METHYLPHEN0XY)PROPIONIC ACID 0 2-(4CHLOROPHENOXY-2-METHYL)PROPIONIC ACID 0 2@-CHLORO-o-TOLYL0XY)PROPIONICACID 0 CMPP 0 COMPITOX 0 FBC CiWP 0 HEDONAL MCPP 0 ISOCORNOX 0 KILPROP 0 LIRANOX 0 2M-4CP 0 MCPP 0 2-MCPP 0 MCPP 2,4-D 0 MCPP-D-4 0 MCPP-K-4 0 MECOMEC 0 MECOPEOP 0 MECOPER 0 MECOPEX 0 MECOPROP 0 MECOTURF 0 MECPROP 0 MEPRO 0 METHOXONE 0 a-(2-METHYL4-CHLOROPHENOXY)PROPIONIC ACID 0 2-(2-METHYL-4-CHLOROPHENOXY)PROPIONIC ACID 0 2-METHYL-4-CHLOROPHENOXY-a-PROPIONIC ACID 0 2-(2-METHYL-4-CHLORPHEN0XY)-PROPIONSAEURE (GERhWN) 0 2M 4KHP 0 N.B. MECOPROP 0 PROPAL 0 PROPONEX-PLUS 0 RANKOTEX 0 RD 4593 0 RUNCATEX 0 U 46 0 U 46 KV-ESTER U 46 KV-FLUID 0 VI-PAR 0 VI-PEX
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,156,87; Human Limited Evidence IMEMDT 41,357,86. EPA Genetic Toxicology
338
CIR750
7-CHLORO-1-METHYLd-PHENYL
Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen. Poison by ingestion. Moderately toxic by skin contact and intraperitoneal routes. Experimental teratogenic and reproductive effects. Mutation data reported. An herbicide. When heated to decomposition it emits toxic fumes of C1-. CIR750 CAS: 22316-47-8 HR: 3 7-CHLORO-1-METHYL-5-PHENYL-lH1,5-BENZODIAZEPINE-2,4(3H,5H)DlONE mf: C I ~ H I ~ C ~ N ~ Omw: Z 300.76 PROP: A solid. Mp: 180-182'. SYNS: CHLOREPIN [? CLOBAZAM CLOREPIN 0
PROP: Colorless, volatile liquid; disagreeable odor. Bp: 72.17', lel: 2.3'/0, uel: 9.3%, fp: <-80', d: 0.9257 @ 20'/4', vap press: 101.7 mm @ 20°, vap d: 3.12, flash p: -10'. Misc in alc and ether. SYNS: 3-CHLOR-2-METHYL-PROP-1-EN (GERMAN) 0 y-CHLOROISOBUTYLENE 0 3-CHLORO-2-IVIETHYI-lPROPENE 0 CHLORURE de METHALLYLE (FRENCH) 0 3-CLORO-2-METIL-PROP-1-ENE (ITALIAN) 0 CLORURO di METALLILE (ITALIAN) 0 ISOBUTENYL CHLORIDE 0 hlETHALLYL CHLORIDE 0 a-METHALLYL CHLORIDE 0 2-METHYL-ALLYLCHLORID(GERMAN) 0 pMETHYWLLYL CHLORIDE 0 2-METHYLALLYL CHLORIDE 0 METHYL ALLYL CHLORIDE (DOV 0 NCI-C54820 CONSENSUS REPORTS: NTP 10th Report on Carcinogens. NTP Carcinogenesis
Studies (gavage); Clear Evidence: mouse, rat NTPTR* NTP-TR-300,86. Reported in hlETHYL-8-CHLORO-l,2,4,5-TETRAHYDRO-2,4-DIOXOEPA TSCA Inventory. 3H-1,5-BENZODMZEPINE 0 RU-4723 0 URBAKYL DFG MAK: Confirmed Animal Carcinogen SAFETY PROFILE: Poison by ingestion and with Unknown Relevance to Humans intraperitoneal routes. Moderately toxic by DOT CLASSIFICATION: 3; Label: subcutaneous route. Human systemic effects Flammable Liquid by ingestion: wakefulness, withdrawal, SAFETY PROFI LE: Confirmed carcinogen nausea and vomiting. An experimental with experimental carcinogenic, teratogen. Other experimental reproductive neoplastigenic, and tumorigenic data. effects. A tranquhzer. When heated to Experimental reproductive effects. An decomposition it emits very toxic fumes of irritant. Human mutation data reported. NO, and C1-. See also DIAZEPAM. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderately CIS750 CAS: 2058-52-8 HR: 3 explosive when exposed to heat or flame. 2-CHLORO-I 1-(4-METHYLPIPERAZCan react vigorously with oxidizing INO)DIBENZO(b,f)(l,4)THIAZEPINE materials. To fight fire, use alcohol foam, mf: C I ~ H I E C ~ N ~ Smw: 343.90 C02, dry chemical. When heated to PROP: Crystals from EtzO/pet ether. hlp: decomposition it emits toxic fumes of C1-. 118-120'. See also CHLORINATED SYNs: Z-CHLORO-11-(43IETHYL-1-PIPERAZINYL)HYDROCARBONS, ALIPHATIC; and DIBENZO(b,f)(l,4)THIAZEPINE 0 DIBENZOALLYL COMPOUNDS. THMZEPINE SAFETY PROFILE: Poison by ingestion. An experimental teratogen. Other experimental ClVOOO CAS: 6959-48-4 HR: 3 reproductive effects. When heated to 3-(CHLOROMETHYL) PY RlDlNE decomposition it emits very toxic fumes of HYDROCHLORIDE mf: CGH&lN*ClH mw: 164.04 C1-, NO,, and SO,. FRISIUM 0 H-4723 0 HR 376 0 LV-2717 0 1-PHENYL-5-
CIU750 CAS: 563-47-3 HR: 3 3-CHLORO-2-METHYLPROPENE DOT: UN 2554 mf: C4HX1 mw: 90.56
SYN: NCI-C03838 CONSENSUS REPORTS: NCI
Carcinogenesis Bioassay (gavage); Clear Evidence: mouse, rat NCITR* NCI-CGTR-95,78. EPA Genetic Toxicology
Program.
CHLORO-O-NITROBENZENE CJB750 339 SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. Poison by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and C1-.
CJA185 CAS: 635-22-3 HR: 3 4-CHLORO-3-NITRO ANILINE mf: CsHsClN202 mw: 172.58 PROP: Yellow needles from HzO. Mp: 103'. SYN ANILINE, 4-CHLORO-3-NITROCONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Experimental reproductive effects. Skin and eye irritant. When heated to decomposition it emits toxic fumes of NO, and C1-. CJA950 CAS: 25167-93-5 HR: 3 CHLORONITROBENZENE DOT: UN 1578 mf: C6H4ClNOz mw: 157.56 SYNS: CHLORONITROBENZENE, ortho, hqud (DOT) 0 MONONITROCHLOROBENZENE 0 NITROCHLOROBENZENE
DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A poison. Mutation
data reported. When heated to decomposition it emits toxic fumes of C1and NO,. See also other chloronitrobenzene entries and NITRO COMPOUNDS of AROMATIC HYDROCARBONS. CJB250 CAS: 121-73-3 HR: 3 1-CHLORO-3-NITROBENZENE DOT: UN 1578 mf: C G H ~ C ~ N O Z mw: 157.56 PROP: Pale-yellow crystals or prisms. Mp: 46', flash p: 103', bp: 236', d: 1.534 @ 20'/4'. SYNS: CHLORO-m-NITROBENZENE 0 mCHLORONITROBENZENE 0 m-CHLORONITROBENZENE (DOT) 0 m-NITROCHLOROBENZENE 0 mNITROCHLOROBENZENE, solid (DOT
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison
SAFETY PROFILE: Poison by ingestion and inhalation. It forms methemoglobin in the body and gves rise to cyanosis and blood changes. Its effects are cumulative and analogous to those of nitrobenzene. The para compound is thought to be somewhat less toxic than the ortho compound. Chemically, it is probably converted in the body to chloroaniline, whch is also poisonous. In industry, it is the dust of h s material that is most often the source of intoxication. Flammable liquid and dangerous fire hazard when exposed to heat or flame. It can react with oxidizing materials. When heated to decomposition it emits toxic fumes of C1-, NO,, and phosgene. See also other chloronitrobenzene entries and NITRO COMPOUNDS of AROMATIC HYDROCARBONS.
CJB750 CAS: 88-73-3 HR: 3 CHLORO-O-NITROBENZENE DOT: UN 1578 mf: C6H4ClNOz mw: 157.56 PROP: Yellow crystals or needles. Mp: 32-33', bp: 245-246', d 1.348, flash p: 123'. SYNS: o-CHLORONITROBENZENE 0 o-CHLORONITROBENZENE, liquid (DOT) 0 l-CHLORO-2NITROBENZENE 0 2-CHLORONITROBENZENE 0 2CHLORO-l-NITROBENZENE 0 o-NITROCHLOROBENZENE 0 ONCB
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and neoplastigenic data. Poison by ingestion, skin contact, and probably inhalation. Combustible when exposed to heat or flame. To fight fire, use water, foam. Potentially explosive reaction with ammonia at 16OoC/30 bar. When heated to decomposition it emits toxic fumes of C1-, NO,, and phosgene. See also other chloronitrobenzene entries and NITRO
E
340 CJDGOO 4-CHLORO-2-NITROPHENYL COMPOUNDS of AROMATIC HYDROCARBONS. CJD6OO CAS: 135-12-6 HR: 1 4-CHLORO-2-NITROPHENYL pCHLOROPHENYL ETHER mf: C12H7C12N03 mw: 284.10 SYNS: BENZESE, 4-CHLORO-1-(4-CHLOROPHENOXY)-2-NITRO-0 4,4'-DICHLOR-2-NITRODIFENYLETHER 0 ETHER, 4-CHLOROPHENYL (4'CHLORO-2'-NITR0)PHENYL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A skin and eye irritant. When heated to decomposition it emits toxic fumes of NO, and C1-.
CJEOOO CAS: 600-25-9 HR: 3 1-CHLORO-1-NITROPROPANE mf: C&hC1N02 mw: 123.55 PROP: Liquid. Bp: 139.5', flash p: 144'F (OC), d: 1.209 @ 2Oo/2O0,vap d: 4.26. IDLH 100 ppm. SYN CHLORONITROPROPANE OSHA PEL: TWA 2 ppm ACGIH TLV: TWA 2 ppm DFG MAK: 20 pprn (100 mg/m3) SAFETY PROFILE: Poison by ingestion,
subcutaneous, and possibly other routes. Moderately toxic by inhalation. Causes injury to kidneys, liver, and cardiovascular system. Mutation data reported. Flammable liquid when exposed to heat, flame (sparks), and oxidizers. Moderately explosive when exposed to heat. To fight fire, use alcohol foam, water, C02, or dry chemical. When heated to decomposition it emits toxic fumes of C1- and NO,. See also other chloropropane entries and CHLORIDES. CJG800 CAS: 121-86-8 HR: 1 2-CHLORO-4-NITROTOLUENE mf: C7H6ClN02 mw: 171.59 PROP: Needles. Fp: 62', mp: 65'. SYN: TOLUENE, 2-CHLORO-4-NITROCONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
SAFETY PROFILE: A skin and eye irritant.
When heated to decomposition it emits toxic fumes of NO, and C1-. CJ1500 CAS: 76-15-3 HR: 1 CHLOROPENTAFLUOROETHANE DOT: UN 1020 mf: CzClFs mw: 154.47 PROP: Colorless gas. Bp: -37.7', mp: -106', d: 1.5678 @ -42'. Insol in water; sol in alc and ether. SYNS: F-115 0 FLUOROCARBON-115 0 FREON 115 0 GENETRON 115 0 HALOCARBON 115 0 MONOCHLOROPENTAFLUOROETHANE (DOV CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 1000 pprn ACGIH TLV: TWA 1000 pprn DOT CLASSIFICATION: 2.2; Label: Nonflammable Gas SAFETY PROFILE: Mddly toxic by inhalation. A nonflammable gas. When heated to decomposition it emits toxic fumes of F- and C1-.
CJJOOO CAS: 3691-35-8 HR: 3 CHLOROPHACINONE mf: C23HlsC103 mw: 374.83 SYNS: AFNOR 0 CAID 0 CHLOORFACIKON (DCTCH) 0 2(2.(4-CHLOOR-FENYL-Z-FENYL)-ACETYL)INDAAN-l,3-DION (DUTCH) 0 CHLORFACINON (GERMAN) 0 2-(a-p-CHLOROPHENYLhCETYLINDANE-l,3-DIONE 0 2-(@-CHLOROPHENYL)PHENYLACETYL)-1,3-II\;DANDIONE 0 2(2-(4-CHL0ROPHEW'LL)2-PHENYLACETYL)INDAN-1,3-DIONE 0 2-((4CHLOR0PHENYL)PHEh'CETYL-1 H-INDENE1,3(2H)-DIONE 0 CHLORPHACINON (ITALIAN) 0 2(2-
(4-CHLOR-PHENYL-2-PHENYL)ACETYJJlNDAX-l,3DION (GERMAN) 0 ((4-CHLORPHENYL-1-PHENYL) hCETYL-1,3-INDANDION (GERMAN) 0 1-(4CHLORPHENYL-1-PHENYLACETYL-INDAN-l,3-DION (GERMAN) 0 2(2-(4-CLORO-FENIL-2-FENIL)ACETIL)INDAN-1,3-DIONE(ITALIAN) 0 DELTA 0 DRAT 0 LIPHADIONE 0 LM 91 0 MICROZUL 0 MCRIOL 0 2-(2-PHENYL-2-(4-CHLOROPHENYL)ACETYL)-1,3-INDAiXDIONE 0 QUICK 0 M f U C I D E 0 M N A C 0 RATOhlET 0 RAVIAC 0 ROZOL 0 TOPITOX
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. SAFETY PROFILE: Poison by ingestion and s h n contact. Human systemic effects by ingestion: vascular changes. A pesticide.
4-CHLOROPHENOL CJK750 341
When heated to decomposition it emits toxic fumes of C1-.
CJJ250 CAS: 6164-98-3 HR: 3 CHLOROPHENAMIDINE mf: C I O H I ~ C ~ N ~mw: 196.70 PROP: Crystals. Mp: 32', bp: 163-165' @ 14 mm. SYNS: ACARON 0 BERMAT 0 C 8514 0 CARZOL 0 CDhf 0 CHLORDIMEFORM 0 CHLORFENAMIDINE 0
Nt-(4-CHLOR0-2-hfETHYLPHENYL)-N,NDIMETHYLiiETHANIMIDAMIDE 0 CHLOROPHENAMADIN 0 N'-(4-CHLORO-o-TOLYL)-N,NDIMETHYLFORMAMIDINE 0 CHLORPHENAMIDINE 0
N'-(4-CHLOR-o-TOLYL)-N,N-DIMETHYL-
FORMAMIDIN (GERMAN) 0 CIBA 8514 0 N,N-
DIMETHYL-N'-(2-METHYL-4-CHLOROPHENYL)FORMAMIDINE 0 N~-DIMETHYL-N'-(Z-METHYL-4C H L 0 R P H E N Y L ) - F O I D I N (GERMAN) 0 ENT 27,335 0 ENT 27,567 0 ED-333 0 FUNDAL 0 FUNDAL 500 0 FUNDEX 0 GALECRON 0 N'-(2-METHYL-C
CHLOROPHENYL-N,N-DIMETHYLFORMAMIDINE 0 N'-(2-METHYL4-CHLORPHENYL)-FOR~~~lDlNHYDROCHLORID (GERMAN) 0 NSC-190935 0 RS 141 0 SCHERING 36268 0 SN 36268 0 SPANON 0 SPANONE
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by ingestion, skin contact, and intraperitoneal routes. Experimental reproductive effects. Human mutation data reported. An eye irritant. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits very toxic fumes of NO, and C1-.
CJK250 CAS: 95-57-8 HR: 3 2-CHLOROPHENOL mf: CsHjC10 mw: 128.56 PROP: Lght-amber liquid. Mp: 9', fp: 7', bp: 174.9", d: 1.263 @ 20'/4', flash p: 147'F, vap press: 1 mm @ 12.1'. Sltly water sol; very sol in alc, ether, and alkali. SYNS: o-CHLOROPHENOL 0 0-CHLOROPHENOL liquid 0 o-CHLOROPHENOL, solid 0 o-CHLORPHENOL (GERMAN) 0 RCRA WASTE NUMBER U048 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Chlorophenol compounds are on the Community Right-To-Know List.
SAFETY PROFILE: Poison by ingestion, intraperitoneal, and intravenous routes. Experimental reproductive effects. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Flammable liquid when exposed to heat, flame, or oxidizers. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of Cl-. See also CHLOROPHENOLS and CHLORIDES.
E
CJKSOO CAS: 108-43-0 HR: 3 3-CHLOROPHENOL mf: C6HjC1O mw: 128.56 PROP: Crystals or needles from pet ether. Mp: 33', bp: 210-214', d: 1.245 @ 45'/4', vap press: 1 mm @?44.2', flash p: >112'. SYN: m-CHLOROPHENOL CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Chlorophenol compounds are on the Community Right-To-Know List. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental tumorigenic data by skin contact. Mutation data reported. Flammable or combustible liquid. When heated to decomposition it emits toxic fumes of C1-. See also CHLOROPHENOLS.
CJ K750 CAS: 106-48-9 HR: 3 4-CHLOROPHENOL DOT: UN 2020/UN 2021 mf: C6HjC10 mW: 128.56 PROP: Needle-like, white to straw-colored crystals; unpleasant odor. Flash p: 250'F, d: 1.246 @ 60'/25', vap press: 1 mm @ 49.8", mp: 43.5', d: 1.246 @ 60'/25' @ -form),&! mp: 34.2' (p-form) mp: 43.5' (y-form), bp: 220'. Sltly water sol; very sol in alc, chloroform, and ether. SYNS: p-CHLORFENOL (CZECH) 0 pCHLOROPHENOL 0 PARACHLOROPHENOL 0 PHENOL, 4-CHLOROCONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Chiorophenol compounds are on the Community Right-To-Know List.
342
CJLOOO CHLOROPHENOLS
SAFETY PROFILE: Poison by inhalation
and intraperitoneal routes. Moderately toxic by ingestion, s h n contact, and subcutaneous routes. A severe skin and eye irritant. Human systemic effects by inhalation: excitement, irritability. Mutation data reported. Combustible when exposed to heat or flame. T o fight fire, use water, spray, mist, fog, foam, dry chemical. When heated to decomposition it emits toxic fumes of C1-. See also CHLOROPHENOLS and CHLORIDES. CJ LOO0 HR: 3 CHLOROPHENOLS CONSENSUS REPORTS: Chlorophenol compounds are on the Community RightTo-Ihow List. SAFETY PROFILE: Many are suspected experimental carcinogens. Most are strong eye and skin irritants. They are systemic irritants by inhalation, ingestion, and s h contact. Generally mutagenic. Trichlorophenols are generally poisons and may be carcinogens. They may contain
2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) as a contaminant. Some trichlorophenols are used as herbicides (e.g., 2,4,5-T and silvex). Human exposure map cause chloracne, liver dysfunction, muscle weakness, and prophyria. Pentachlorophenol is a poison by several routes. Human exposure causes increased respiration, fever, tachycardia, muscle weakness, and cardiac fdure. Many toxic effects are due to impurities in commercialgrade material. A teratogen and mutagen. Pentachlorophenol and 2,4,6trichlorophenol may interfere with mitochondria1 oxidative phosphorylation, When heated to decomposition they emit toxic fumes of C1-. See also specific compounds, PHENOL, and CHLORIDES. CJM250 CAS: 58-39-9 HR: 3 4-(3-(2-CHLOROPHENOTHIAZlN-10YL)PROPYL)-1-PIPERAZINEETHANOL
mf: C21H26ClN30S mw: 404.01 PROP: Crystals from EtOAc. Mp: 100-101", bp: 278-281' @ 1 mm. SYNS: 2-CHLORO-10-3-(1-(2-HYDROXYETHYL)-4PIPERAZ1NYL)PROPYL PHEKOTHL4ZINE 0 DECENTAN 0 ETAPERAZIN 0 ETAPERAZINE 0 ETHAPERAZINE 0 FENTAZIN 0 1-(2-
HMROXYETHYL)-4-(3-(2-CHLORO-10PHENOTHIAZIN~)PROPYL)PIPER4ZINE 0 y-(4-(pHYDR0XYETHYL)PIPERAZIN-1 -X)PROPYL-2CHLOROPHENOTHIAZINE 0 1',1-(2-IDROSSIETIL)4-(3(2-CLORO-10-FEN0TIAZIL)PROPILPIPEFUZINA (ITALIAN) 0 PERFENAZINA (ITALIAN) 0 PERPHENAZIN 0 PERPHENAZINE 0 TRIFARON 0 TRILAFON
SAFETY PROFILE: Poison by ingestion,
intravenous, subcutaneous, intraperitoneal, and intramuscular routes. Human systemic effects by intramuscular route: muscle spasms. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of SO,, NO,, and c1-. CJM750 CAS: 2865-70-5 HR: 3 10-CHLOROPHENOXARSINE mf: C12HsAsC10 mw: 278.57 PROP: Colorless prisms from CHCb/octane. Mp: 122'. Very sol in C6H6, Me2C0, CHCl3; mod sol in EtOH, Et20, and AcOH. SYNS: 1O-CHLORO-lOH-PHENOXt\RSINE 0 10CHLOROPHEKOXYARSINE 0 DID 95
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Arsenic and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by ingestion. See also ARSINE and ARSENIC COMPOUNDS. When heated to decomposition it emits very toxic fumes of As and C1-. CJNOOO CAS: 122-88-3 HR: 2 p-CHLOROPHENOXYACETIC ACID mf: CsH7C103 mw: 186.60 PROP: Needles or prisms from H20. Mp: 159'.
1-(p-CHLORO-a-PHENYLBEN2YL)-- CJR909 343
SYNS: (4-CHLOROPHEN0XY)ACETICACID 0 4-CP 0 CPA 0 MARKS 4-CPA 0 PCPA 0 SURESET 0 T O i U T O FIX CONCENTRATE 0 T O i U T O HOLD 0 TOMATOTONE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Human mutation data reported. When heated to decomposition it emits toxic fumes of C1-.
CJ0250 CAS: 43121-43-3 HR: 3 1-(4-CHLOROPHENOXY)-S,bDlMETHYL-1-(1,2,4-TRIAZOL-l-YL)-2-BUTAN2-ONE mf: C14H16ClN302 mw: 293.78 PROP: A solid. Mp: 82-83'. SYNS: AMIRAL 0 BAY 6681 F 0 BAYLETON 0 BAYMEB-6447 0 l-((tert-BUTYLCARBONYL-4CHLOROPHENOXY)METHYL)-lH-l,2,4-TRIAZOLE 0 1(4-CHLOROPHENOXY)3,3-DIMETHn-l -(I H-l,2,4TRIAZOLl-YL)-2-BUTANONE 0 MEB 6447 0 TRIADIhlEFON
SAFETY PROFILE: Poison by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,. See also KETONES.
CJR210 CAS: 301644-25-7 HR: 3 4-((34(4-CHLOROPHENYL)AM INO)-4,5DlHYDRO-2H-BENZ(G)INDAZOL-2Y L)ACETYL)MORPHOLINE mf: C23H23ClN402 mw: 422.91 SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO, and C1-.
E
CJR220 CAS: 301644-24-6 HR: 3 3-((4-CHLOROPHENYL)AMINO)-4,5DlHYDRO-N-(PHENYLMETHYL)-2HBENZ(g)lNDAZOLE-2-ACETAMlDE mfi C26H23C~40 mw: 442.95 SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO, and C1-. CJR550 CAS: 3574-96-7 H R: 3 2-(0-CHLOROPHENYL)BENZIMIDAZOLE mf: C13HKlN2 mw: 228.69 SYNS: 1H-BENZIMIDAZOLE, 2-(2-CHLOROPHENYL)0
2-(2-CHLOROPHENYL)-lH-BENZIMIDAZOLE 0 G 572
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits
toxic vapors of NO, and C1-. CJR2OO CAS: 20265-96-7 HR: 3 4-CHLOROPHENYLAMINE HYDROCHLORIDE mfi C6H6C1NeC1H mw: 164.04 SYNS: 1-AhlINO-4-CHLOROBENZENE HYDROCHLORIDE 0 rtUILINE, p-CHLORO-, HYDROCHLORIDE 0 BENZENAMINE, 4-CHLORO-, HYDROCHLORIDE 0 p-CHLOROANILINE HYDROCHLORIDE 0 4-CHLOROANILINE HYDROCHLORIDE 0 p-CHLOROANILINIUM CHLORIDE 0 4-CHLOROBENZENAMINE HYDROCHLORIDE 0 p-CHLOROPHENYLAMINE HYDROCHLORIDE
CJR909 CAS: 68-88-2 HR: 3 1-(p-CHLORO-a-PHENYLBENZYL)-4-(2((2-HYDROXYETH0XY)ETHYL)PIPERAZINE) mf: C21H27ClN202 mw: 374.95 SYNS: ATARA 0 ATARAX 0 ATARAXOID 0 ATARAZOID 0 ATAZINA 0 ATERAX 0 1-@-
CHLOROBENZHYDRYL)-4-(2-(2-HYDROXYETHOXYETHYL)DIETHYLENEDIAMINE 0 1-@-CHLOROBENZ-
HYDRYL-4-(2-(2-HYDROXYETHOmETHYL)PIPERAZINE 0 N-(4-CHLOROBENZHYDRYL-N'(HYDROXYETH0XYETH~)PIPERAZINE0 1-@-
CONSENSUS REPORTS: NTP
CHLORODIPHENYLMETHYL)-4-(2-(2-HYDROXYETHO-
Carcinogenesis Studies (gavage): Clear Evidence: rat NTPTR* NTP-TR-351,89; (gavage); Some Evidence: mouse NTPTR* NTP-TR-351,89. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic vapors of NO,, HC1, and C1-.
XY)ETHYL)PIPERAZINE0 2-(2-(4-@-CHLORO-G PHENYLBENZYL-1-PIPERAZINYL)ETHOXY)ETHANOL 0 DEINAIT 0 EQUIPOISE 0 FENAROL 0 HYCHOTINE 0 HYDROXINE 0 HYDROXYCINE 0 HYDROXYZINE 0 IDROSSIZINA 0 NEO-CALMA NEUROZINA 0 NP 212 0 PAMAZONE 0 PARENTERAL 0 PAXISTIL 0 PLACIDOL 0 PLAXIDOL 0 TRAN-Q 0 TRAQUIZINE 0 UCB 492 0 U.CB 4492 0 VESPARAZ-WIRKSTOFF
SAFETY PROFILE: Poison by intravenous
and intraperitoneal routes. Moderately toxic by ingestion. Experimental teratogenic and
344
CJTBOO 2-(4-CHLOROPHENYL)-
reproductive effects. When heated to decomposition it emits very toxic fumes of C1- and NO,. CJT800 CAS: 128758-36-1 HR: 3 2-( 4-CHLOROPHENYL)-5-((4-CHLOROPHENYL)METHOXY)-4-lODO-3(2H)PYRIDAZINONE mf: C17HllClzIN202 mw: 473.10 SYN
3(2H)-PYRIDAZISOSE, 2-(4-CHLOROPHENYLj-5-
((4-CHLOROPHESYL)METHOX~-4-IODO-
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO,, I-, and C1-.
CJV250 CAS: 35367-38-5 HR: 2 1-(4-CHLOROPHENYL)-3-(2,6-DIFLUOROBENZ0YL)UREA mf: C14H9ClFzNzOz mw: 310.70 PROP: Crystals. Mp: 230-232'. SYNS: N-(((4-CHLOROPHENYL)AMINO)CARBONYL)2,6-DIFLL!OROBENZMMIDE 0 DIFLUBENZURON 0 DIFLURON 0 DIMILIN 0 DU 112307 0 ENT 29,054 0 OMS 1804 0 PDD 60401 0 PH 60-40 0 PHILIPS-DUPHAR PH 60-40 0 TH 6040 0 THOMPSON-HAYYYARDTH6040
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by skm contact. Mildly toxic by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1-, F-,and NO,. CJX750 CAS: 150-68-5 HR: 2 3-(pCHLOROPHENYL)-1,I-DIMETHYLUREA mf: CgHllClN20 mw: 198.67 PROP: Crystals or thin rectangular prisms from MeOH; slight odor. Mp: 170.5-171.51", vap press: 0.002 mm @ 100". Sltly sol in water and hydrocarbons. SYNS: 3-(4-CHLOOR-FENYL)-l,l-DIMETHYLCREUM (DUTCH) 0 CHLORFENIDIhl 0 S-@-CHLOROPHENYL)-S',S'-DIMETHYLUREA0 Nt-(4-CHLOROPHEXYL)N,N-DIMETHYLUREA 0 1-@-CHLOR0PHENYL)-3,3DIMETHYLUREA 0 3-(4-CHLOROPHENYL-l,1DIMETHYLUREA 0 L(4-CHLORO PHENYL)-3,3DIMETHYLUREE (FRENCH) 0 3-(4-CHLOR-PHENYL)1,I-DIMETHYLHhRNSTOFF(GERhlhN) 0 3-(4-CLOROFES1L)-1,l-DIMETIL-UREA(ITALIAN) 0 CMC 0 N,N-
DIMETHYL-N'-(4-CHLOROPHENYLjUREA 0 1,lDIMETHYL-3-@-CHL0ROPHENYL)UREL~ 0 HERBICIDES, MONURON 0 KARMEX MONURON HERBICIDE 0 K4R\fEX W. MOSURON HERBICIDE 0 LIROBETAREX 0 MONUREX 0 MONURON 0 MONCROX 0 MONURUON 0 MONUURON 0 NCIC02846 0 TELVAR 0 TELVAR MONURON WEEDKILLER 0 USAF P-8 0 USXF XR-41
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 12,167,76. Reported in EPA TSCA Inventory. EPA FIFRA 1988 pesticide subject to regstration or re-registration. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by ingestion, intraperitoneal, and possibly other routes. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic data. Mutation data reported. An herbicide. When heated to decomposition it emits very toxic fumes of NO, and C1-.
CJY120 CAS: 5131-60-2 HR: 3 4-CHLORO-m-PHENYLENEDlAMlNE mf: C6H7ClN2 mw: 142.60 PROP: Needles. Mp: 91". SYNS: C.I. 76027 0 4-CHLORO-1,3-BENZENEDIAMINE 0 l-CHLORO-2,4-DIAhfINOBENZENE 0 4-CHLOROPHENE-l,3-DIAMINE 0 4-CHLOROPHENYL-ENE-1,30 DIXMIXE 0 4-CHLORO-l,3-PHENYLENE-DIAhlINE 4-C1-m-PD 0 NCI-C03305
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 27,81,82. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NCITR" NCI-CGTR-85,78. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of C1and NO,. See also AROMATIC AMINES.
l-(~-CHLOROPHENYL)-5-ISOPROPYL-BIGUANlDE CKB250 345
CKA030 CAS: 90035-12-4 HR: 3 3-(3-(4-(2-(4-CHLOROPHENYL)ETHYL)PHENYL)-l,2,3,4-TETRAHYDRO-lNAPHTHALENYL)-4-HYDROXY2H-lBENZOPYRAN-2-ONE mfi C33H27C103 mw: 507.05 SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of C1-. CKA575 CAS: 21905-40-8 HR: 3 (m-CHLOROPHENYL)HYDROXY(p HYDROXYPHENETHYL)ARSINE OXIDE mfi C14H14AsC103 mw: 340.65 SYNS: ARSINE OXIDE, (rn-CHLOR0PHENYL)HYDROXY(P-HYDROXYPHENETHYL- 0 2-PHENYLZHYDROXYETHYL,rn-CHLOROPHENYLARSINIC ACID OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of As and C1-. CKA580 CAS: 24671-21-4 HR: 3 4-(4-(pCHLOROPHENY L)-CHYDROXYPIPERIDINO)-4'-(DIMETHYLAMINO)BUTYROPHENO NE mf: C23H29ClN202 mw: 400.99
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD (UN 2207); DOT Class: 6.1; Label: Poison (UN 2206); DOT Class: 6.1; Label: Poison, Flammable Liquid (UN 3080); DOT Class: 3; Label: Flammable Lquid, Poison (UN 2478) SAFETY PROFILE: Poison by inhalation and ingestion. A flammable liquid when exposed to heat or flame. When heated to decomposition it emits toxic fumes of C1-, CN-, and NO,. See also ESTERS and THIOCYANATES .
CKBOOO CAS: 104-12-1 HR: 3 p-CHLOROPHENYL ISOCYANATE DOT: UN 2206/UN 2207/UN 2478/UN 3080 mf: C7H4ClNO mw: 153.57 PROP: White solid or crystals. Mp: 31', bp: 204'. Sol in org solvs. SYNS: p-CHLORFENYLISOKYANAT (CZECH) 0 ISOCYANIC ACID-p-CHLOROPHENYLESTER 0 PCPI CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD (UN 2207); DOT 4-HYDROXYPIPERlDINO)-4'-(DIMETHYLAMINO)0 4Class: 6.1; Label: Poison (UN 2206); DOT (TlIMETHYLAMINO)PHENYL3-(4-(4-CHLOROPHENYL)Class: 6.1; Label: Poison, Flammable hquid 4-HYDROXYPIPERIDINO)-PROPYL KETONE (UN 3080); DOT Class: 3; Label: DOT CLASSIFICATION: 3; Label: Flammable Liquid, Poison (UN 2478) Flammable Liquid SAFETY PROFILE: Poison by ingestion and SAFETY PROFILE: A poison by inhalation. Unspecified human systemic intravenous route. A flammable liquid. effects. A severe eye and moderate skin When heated to decomposition it emits irritant. A flammable liquid when exposed to toxic vapors of NO, and Cl-. heat or flame. Dangerous, can explode on distillation. When heated to decomposition CKA750 CAS: 2909-38-8 HR: 3 it emits toxic fumes of C1-, CN-, and NO,. m-CHLOROPHENYL ISOCYANATE DOT: UN 2206/UN 2207/UN 2478/UN 3080 CKB250 CAS: 500-92-5 HR: 3 1-(P-CHLOROPHENYL)-~-ISOPROPYLmf: C7H4ClNO mw: 153.57 BIGUAN1DE PROP: Water-white liquid with irritating mf: CllHI&lNS mw: 253.77 odors. Mp: -4O, bp: 101' (@ 30 mm. Sol in PROP: White powder or rectangular plates org solvs. from toluene. Mp: 130-1 31'. SYNS: rn-CHLORFENYLISOKYANAT 0 ISOCYANIC SYNS: BUTYROPHENONE, 4-(4-@-CHLOR0PHENYL)-
ACID-rn-CHLOROPHENYL ESTER
SYNS: BIGUMAL 0 CHLORGUANIDE 0 CHLOROGUANIDE 0 PALUDRINE 0 PROGUANIL
E
346 CKDSOO 3-(4-CHLOROPHENYL)-1-METHOXY ACID mf: C7HsAsC102
SAFETY PROFILE: Poison by ingestion, intravenous, and intraperitoneal routes. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of C1- and NO,.
mw: 234.52
SYNS: ARSINE OXIDE, @-CHLOR0PHENYL)HYDROXYMETHYL- 0 @-CHLOR0PHENYL)HMROXYMETHYLARSINE OXIDE
OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intravenous
CKD500 CAS: 1746-81-2 HR: 2 3-(4-CHLOROPHENYL)-1-METHOXY-1 METHYLUREA mf: CgHllClN202 mw: 214.67 PROP: A solid. Mp: 76-78'. SYNS: AFESIN 0 ARESIN 0 AREZIN 0 AREZINE 0
-
ARRESIN 0 N-(4-CHLOROPHENn)-N'-~~ETHOXI-NMETHYLUREA 0 N'-(4-CHLOROPHEKYL)-NNETHOXY-N-METHYLUREA 0 3-(CCHLORPHENYL)-lMETHOXY-1-hlETHYLHAItlTSTOFF (GERMAN) 0 HOE 2747 0 MONOLINUROF 0 PRESWLIN
route. When heated to decomposition it emits toxic fumes of As and Cl-. CKFOOO CAS: 3942-54-9 HR: 3 O-CHLOROPHENYLMETHYLCARBAMATE mf: C8H8ClN02 mw: 185.62 SYNS 2 - C H L O R O P H E N Y L - N - h l E T H ~ C A ~ A ~ ~ A0T E CPMC 0 ETROFOL 0 HOPCIDE
SAFETY PROFILE: Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. When heated to decomposition it emits very toxic fumes of C1- and NO,.
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: A poison by ingestion and possibly other routes. An insecticide. See also CARBAMATES. When heated to decomposition it emits very toxic fumes of C1- and NO,.
CKD750 CAS: 1867-66-9 HR: 3 2-(0-CHLOROPHENYL)-2-(METHYLAMIN0)CYCLOHEXANONE HYDROCHLORIDE mf: C13Ht&lNO*ClH mw: 274.21 SYNS: CI 581 CL 369 0 CN-52,372-2 0 KETAJECT 0
CKJ100 CAS: 17766-66-4 HR: 3 4-(p-CHLOROPHENYL)PIPERAZINYL 3,4,5-TRIMETHYOXYPHENYL KETONE mf: C20H23ClN204 mw: 390.90 SYNS: l-@-CHLOROPHENYL-4-(3,4,5-
KETALqR 0 KETAMINE 0 KET'4MINE HMROCHLORIDE 0 KETANEST 0 KETASET 0 KETAVETOKETOWROVETAIAR
TRIMETHOXYBENZ0YL)PIPERAZINE 0 KETONE, 4@-CHLOR0PHENYL)PIPERAZIXYL 3,4,5-TRIMETHOXYPHENYL 0 PIPEMZINE, 1-@-CHLOR0PHENYL)-4-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
CONSENSUS REPORTS: EPA Genetic
Toxicology Program. SAFETY PROFILE: Poison by intramuscular, intraperitoneal, and intravenous routes. Moderately toxic by ingestion. Human systemic effects by intravenous and possibly other routes: analgesia, coma, hallucinations and distorted perceptions, dyspnea. An experimental teratogen. An anesthetic. When heated to decomposition it emits very toxic fumes of C1- and NO,. CKD800 CAS: 73791-42-1 HR: 3 (CCHLOROPHENYL)METHYLARSlNlC
(3,4,5-TRIMETHOXYBENZOYL)-
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO, and C1-.
CKK050 CAS: 23597-98-0 HR: 3 5-(p-CHLOROPHENYL)-2,3,5,6-TETRAHYDROIMIDAZO(1,~-c)QUINAZOLIN mf: C I ~ H I ~ C ~ Nmw: ~ 283.78 SYNS: AW-15'11290 IhfIDAZO(l,2-c)QUINAZOLINE, 5(4-CHLOROPHENYL)-2,3,5,6-TETRAHMRO0 IMIDAZO(1,2-c)QL!INAZOLINE, 2,3,5,6-TETRAHYDRO-5-@CHLOROPHENYL-
CHLOROPICRIN CKNSOO 347 SAFETY PROFILE: A poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic vapors of NO, and C1-.
CKMOOO CAS: 116-29-0 HR: 2 p-CHLOROPHENY L-2,4,5-TRICHLOROPHENYL SULFONE mf: C12HbC1402S mw: 356.04 PROP: Crystals. Mp: 148-149'. Nearly water-insol. SYNS: AKARITOX 0 AREDION 0 4-CHLOROPHENYL-2,4,5-TRICHLOROPHENYL SULFONE 0 pCHLOROPHENYL-2,4,5-TRICHLOROPHENYL
hydrolyzes to HC1 and evolves heat. When heated to decomposition it emits toxic fumes of C1-. See also CHLOROSILANES. CKNOOO CAS: 1406-65-1 CHLOROPHYLL PROP: Dark-green liquid.
HR: 3
SYNS: CHLOROFOLIN 0 CHLOROFYL 0 CHLOROPHYLLS 0 C.I. 1956 0 DEODOPHYLL 0 E 140 0 L-GRUEN No. 1 0 L-GRUEN No. 1 (GERMAN)
SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NO,.
SULPHONE 0 DUPHAR U ENT 23,737 0 F ? K 5488 0 MITION 0 NIA 5488 0 POLACARITOX 0 ROZTOZOL 0
CKNSOO CAS: 76-06-2 HR: 3 CHLOROPICRIN SULFONE-2,4,4',5-TETRACHLORODIPHENYL 0 DOT: UN 1580/UN 1583 TEDION 0 TEDION V-18 0 2,4,4',5-TETRACHLOORmf: CCLNOz mw: 164.37 DIFENYLSULFON (DUTCH) 0 2,4,4',5-TETRACHLORDIPHENYL-SULFON(GERMAN) 0 2,4,4',5-TETRACHLOPROP: Sltly oily, colorless liquid. D: 1.692 RODIPHENYL SULFONE 0 2,4,5,4'-TETRACHLORO@ 0.4', fp: -69', mp: -64', bp: 112.3' @ DIPHENYLSULPHONE 0 2,4,4',5-TETRACLORO766 mm, vap press: 40 mm @ 33.80, vap d: DIFENILSOLFONE (ITALIAN) 0 TETRADICHLONE 0 6.69. Sol in water, alc, and ether. IDLH 2 TETRADIFON 0 TETRADIPHON 0 TETRAFIDON 0 1,2,4-TRICHLOR0-5-((4-CHLOROPHENYL)SULFONYL)-PPm. BENZENE 0 V-18
CONSENSUS REPORTS: EPA Genetic
Toxicology Program. SAFETY PROFILE: Moderately toxic by ingestion. Mildly toxic by slun contact. An experimental teratogen. Used to control worms in crops. When heated to decomposition it emits highly toxic fumes of C1- and SO,. CKM250 CAS: 26571-79-9 HR: 3 CHLOROPHENYLTRICHLOROSILANE DOT: UN 1753 mf: C6H4ChSi mw: 245.99 PROP: Colorless to pale-yellow liquid, readily hydrolyzed by moisture with the liberation of HC1 (a mixture of 3 isomers). Bp: 230°, d: 1.439 @ 25'/25', flash p: 255'F (COC). DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A poison irritant by ingestion and inhalation. A corrosive irritant to the skin, eyes, and mucous membranes. Combustible when exposed to heat or flame. In contact with water it readily
SYNS: ACQUINITE 0 CHLOORPIKRINE (DUTCH) 0 CHLOR-0-PIC 0 CHLOROPICRIN,liquid (DOT) 0 CHLOROPICRIN,ABSORBED (DOT) 0 CHLOROPICRINE (FRENCH) 0 CHLORPIKRIN (GERMAN) 0 CLOROPICRINA (ITALIAN) 0 DOJYOPICRIN 0 DOLOCHLOR 0 LARVACIDE 0 MICROLYSIN 0 NCI-COO533 0 NITROCHLOROFORM 0 NITROTRICHLOROMETHANE 0 PIC-CLOR 0 PICFUME 0 PICRIDE 0 PROFUME A 0 PS 0 TRICHLOORNITROMETHAAN(DUTCH) 0 TRICHLORNITROMETHAN(GERMAN) 0 TRICHLORONITROMETHANE 0 TR-CLOR 0 TRICLORO-NITRO-METANO(ITALIAN)
CONSENSUS REPORTS: NCI Carcinogenesis Bioassay (gavage); No Evidence: mouse NCITR* NCI-GC-TR65,78. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 ppm ACGIH TLV: TWA 0.1 ppm; Not Classifiable as a Human Carcinogen DFG MAK: 0.1 ppm (0.68 mg/m3) DOT CLASSIFICATION: 6.1; Label: Poison (UN 1580); DOT Class: 6.1; Label: Poison, KEEP AWAY FROM FOOD (UN 1583) SAFETY PROFILE: Poison by ingestion, intravenous, and intraperitoneal routes. Moderately toxic by inhalation. Human
E
348 CKOXO CHLOROPLATINIC ACID systemic effects by inhalation: lachrymation, conjunctiva irritation, and pulmonary changes. Mutation data reported. A powerful irritant that affects all body surfaces. It causes lachrymation, vomiting, bronchitis, pulmonary edema, irritation to gastrointestinal and respiratory tracts. Questionable carcinogen with experimental tumorigenic data. An addrtional toxic effect is its reaction with SH-groups in hemoglobin, thus interfering with oxygen transport. Photochemical transformation of chloropicrin into phosgene (carboxp chloride, COC12) has been reported. A concentration of 1 ppm causes a smarting pain in the eyes and therefore in itself constitutes a good warning of exposure. Inhalation causes vomiting, probably due to swallowing saliva in which small amounts of chloropicrin have dssolved. Its primary lethal effect is to produce lung injury and it is a difficult gas to protect oneself against because it is chemically inert and does not react with the usual chemicals used in gas masks. Four ppm is sufficient to render a worker unfit for action and 20 ppm, when breathed from 1 to 2 minutes, causes definite bronchal or pulmonary lesions. Industrially it is used as a warning agent in commercial fumigants. It is more toxic than chlorine but less so than phosgene. Above a critical volume it can be shocked into detonation. Mixtures with 3bromopropyne are shock- and heat-sensitive explosives. Violent reaction with aniline + heat, alcoholic sodum hydroxide, sodium methoxide, and propargyl bromide. When heated to decomposition it emits very toxic fumes of C1- and NO,. Used for insect and rodent control in grain elevators and bins and as a soil fumigant and fungcide. See also NITRO COMPOUNDS. CK0750 CAS: 16941-12-1 CHLOROPLATINIC ACID DOT: UN 2507 mf: C16Pt*2H mw: 409.81
HR: 3
PROP: Reddrsh-brownish- yellow deliquescent solid or c r y s t h e mass. D: 2.431, mp: 60'. Easily sol in water and alc. IDLH 4 mg/m3 (as Pt). SYNS: CHLOROPLATINICN ACID DIHYDROGEN HEXACHLOROPLATINATE 0 DIHYDROGEN HEXACHLOROPIATINATE(2-) 0 HEXACHLOROPLATINIC ACID 0 HEX;ICHLOROPLATINIC(IV) ACID 0 HEXACHLOROPLATINIC(4+)ACID, HYDROGEN- 0 HYDROGEN HEXACHLOROPLATIN,ITE(4+) 0 PLATINIC CHLORIDE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 0.002 mg(Pt)/m3 ACGIH TLV: TWA 0.002 mg(Pt)/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Mutation data reported. See PLATINUM COMPOUNDS and CHLORIDES. Incompatible with BrF3. When heated to decomposition it emits toxic fumes of C1-.
CKPSOO CAS: 69-09-0 HR: 3 CHLOROPROMAZINE HYDROCHLORIDE mf: C17HIKlN&ClH mw: 355.35 SYNS: XMINAZIN MONOHYDROCHLORIDE 0 MZPLIACTIL MONOHYDROCHLORIDE 0 CHLORACTIL 0 CHLORAZIN 0 2-CHLORO-l0-(3DIMETHYLAMINOPROPYL) PHENOTHLIZINE MONOHYDROCHLORIDE 0 CHLOROPROMAZINE MONOHYDROCHLORIDE 0 CPZ 0 10-(3DIMETHYLAMINOPROPYL)-2-CHLOROPHENOTHIAZINE MONOHYDROCHLORIDE 0 HEBANIL 0 HIBANIL 0 HIBERNAL 0 HYBERNAL 0 KLORPROMAN 0 KLORPROMEX 0 WRGACTIL MONOHYDROCHLORIDE 0 LARGAKTYI. 0 MEGAPHEN 0 NCI-C05210 0 NEUUZINE 0 NORCOZINE 0 PHENOTHIAZINE HYDROCHLORIDE 0 PLEGOMAZIN 0 PROMACID 0 PROhWPAR 0 PROPAPHEN 0 PROPAPHENIN HYDROCHLORIDE 0 PSYCHOZINE 0 4560 RP HYDROCHLORIDE 0 SONAZINE 0 TAROCTYL 0 THORAZINE 0 THORAZINE HYDROCHLORIDE 0 TORAZINA 0 T U N Z I N E 0 UNITENSEN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion, intraperitoneal, intravenous, and subcutaneous routes. An experimental
2-CHLORO-1-PROPANOL CKRSOO 349
teratogen. Experimental reproductive effects. An anti-emetic and antipsychotic drug. Human systemic effects: anorexia (human), excitement, gastrointestinal changes, irritability, pulse rate increase, respiratory stimulation, rigidity, somnolence, sweating. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1-, NO,, and SO,. CKP6OO CAS: 627-30-5 HR: 2 3-CHLOROPROPANOL DOT: UN 2849 mf: C3H7C10 mw: 94.55 SYNS: 3-CHLORPROP24N-1-OL0 1-PROPANOL,3CHLORO- 0 TRIhiETHYLENE CHLOROHYDRIN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Moderately toxic by ingestion. Mutation data reported.
CKP750 CAS: 540-54-5 HR: 3 1-CHLOROPROPANE DOT: UN 1278 mf: C3H7C1 mw: 78.55 PROP: Colorless liquid, chloroform-like odor. Mp: -122.8", d: 0.897 @ 15"/4", bp: 46.60°, lel: 2.6%, uel: 11.1%, flash p:
See also CHLORINATED HYDROCARBONS ,ALIPHATIC , CKQOOO CAS: 75-29-6 HR: 3 2-CHLOROPROPANE DOT: UN 2356 mf: C3H7Cl mw: 78.54 PROP: Flash p: -25.6"F, lel: 2.8%, uel: 10.7%, d: 0.868 @ 15O, mp: -117", bp: 34.8". SYN: ISOPROPYL CHLORIDE DOT CLASSIFICATION: Flammable Liquid; Label: Flammable Lquid SAFETY PROFILE: Mutation data reported. A flammable liquid. A very dangerous fire hazard when exposed to heat, flame, or oxidners. When heated to decomposition it emits toxic fumes of C1-. See also 1CHLOROPROPANE. CKQ750 CAS: 15121-11-6 HR: 3 CHLOROPROPANEDIOL CYCLIC SULFITE mf: C3H5ClOsS mw: 156.69 SYN : 1-CHLOROMETHYLETHYLENEGLYCOL CYCLIC SULFITE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. See also SULFITES. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of C1- and SO,.
CKRSOO CAS: 78-89-7 HR: 3 2-CHLORO-1-PROPANOL DOT: UN 261 1 mf: C3H7C10 mw: 94.55 PROP: Colorless liquid; mild non-residual odor. Bp: 133.5", flash p: 125°F (CC), d: 1.103 @ 20", vap d: 3.26. SYNS: 2-CHLOROPROPANOL 0 2-CHLOROPROPYL ALCOHOL 0 PROPYLENECHLOROHYDRIN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. ACGIH TLV: TWA 1 ppm (skin); Not Classifiable as a Human Carcinogen DOT CLASSIFICATION: 6.1; Label: Poison
350
CKSOOO 2-CHLORO-1-PROPENE
SAFETY PROFILE: Poison by ingestion.
Moderately toxic by inhalation and skin contact. A skin and severe eye irritant. Flammable liquid when exposed to heat, flame, or powerful oxi&zers. To fight fire, use alcohol foam, C02, dry chemical. When heated to decomposition it emits toxic fumes of C1-. CKSOOO CAS: 557-98-2 HR: 3 2-CHLORO-1-PROPENE DOT: UN 2456 mf: CsHsCl mw: 76.53 PROP: Colorless liquid or gas. Bp: 22.65', fp: -137.4', d: 0.918 @ 9', flash p: -4', lel: 4.5'/0, uel: l6%, mp: -138.6'. SYN: 2-CHLOROPROPESE (DOT) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Mildly toxic by inhalation. Mutation data reported. Very dangerous fire hazard when exposed to heat, flame, sparks, or powerful oxidizers. To fight fire, use water, spray, mist, fog, dry chemical, alcohol foam. When heated to decomposition it emits toxic fumes of C1-. See also CHLORIDES. CKS750 CAS: 598-78.7 HR: 3 a-CHLOROPROPIONIC ACID DOT: UN 251 1 mf: C3HsC10~ mw: 108.53 PROP: Sol in water. D: 1.260-1.268 @ 20°, bp: 183-1 87O, flash p: 225'F, CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA 0.1 ppm (skin) DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by skin contact. A corrosive. Combustible when exposed to heat or flame. T o fight fire, use water, foam, alcohol foam. When heated to decomposition it emits toxic fumes of C1-. See also 3-CHLOROPROPIONIC ACID.
CKTOOO CAS: 17639-93-9 HR: 3 2-CHLOROPROPIONIC ACID METHYL ESTER DOT: UN 2933 mfi C4H7C102 mw: 122.56 SYN : METHYL-2-CHLOROPROPIONATE (DOT,! CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Poison by intraperitoneal route. See also ESTERS. A flammable liquid when exposed to heat or flame. When heated to decomposition it emits toxic fumes of C1-. CKTSOO CAS: 6285-05-8 HR: 3 p-CHLOROPROPIOPHENONE mf: C9H9C10 mw: 168.63 PROP: A solid. Mp: 37-38', bp: 134-137' @ 31 mm. SYN: USAF EK-5296 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal and intravenous routes. When heated to decomposition it emits toxic fumes of C1-. CKWOOO CAS: 109-09-1 HR: 3 2-CHLOROPYRIDINE DOT: E N 2822 mf: CsH4ClN mw: 113.55 PROP: Colorless, oily liquid or crystals. Mp: 65", bp: 170', d: 1.205 @ l5', vap press: 1 mm @ 13.3", vap d: 3.93. SYNS: o-CHLOROPYRIDINE 0 a-CHLOROPYRIDINE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion, inhalation, skm contact, and intraperitoneal routes. Combustible when exposed to heat or flame. Can react with oxidizing materials. When heated to decomposition it emits very toxic fumes of C1-, NO,, and phosgene.
CHLOROSULFURIC ACID
CLGSOO 351
bp: 188.6', d: 1.100 @ 20'/4". CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 50 ppm; STEL 75 ppm SYN : 3(2H)-PYRIDAZINONE, 5-((6-CHLORO-3ACGIH TLV: TWA 50 ppm; STEL 75 ppm PYRIDINYL)METHOXY)-2-(3,4-DICHLOROPHENYL)-4SAFETY PROFILE: A skin and eye irritant. IODOWhen heated to decomposition it emits SAFETY PROFILE: A poison by ingestion. toxic fumes of C1-. See also When heated to decomposition it emits CHLORINATED HYDROCARBONS, toxic vapors of NO,, I-, and C1-. AROMATIC . CLD750 CAS: 95-88-5 HR: 3 4-CHLORORESORCINOL CLG500 CAS: 7790-94-5 HR: 3 mf: C~HsCl02 mw: 144.56 CHLOROSULFURIC ACID PROP: Crystals from C6H6. Mp: 8 9 O , bp: DOT: UN 1754/UN 2240 mf: ClH03S mw: 116.52 147'. CONSENSUS REPORTS: Reported in EPA PROP: Strong acid; clear to cloudy or TSCA Inventory. EPA Genetic Toxicology colorless to pale-yellow liquid; sharp odor. Program. Chlorophenols are on the Fumes in moist air. Mp: -80°, bp: 155', d: Community Right-To-Know List. 1.77 @ 2 8 O , vap press: 1 mm @ 32O, vap d: SAFETY PROFILE: Poison by ingestion and 4.02. Sol in CHCL, CH2C12, and Py; insol in intraperitoneal routes. Experimental CSZand Cc4. SYNS: CHLOROSULFONIC ACID 0 CHLOROSULFONreproductive effects. An eye irritant. A hair IC ACID (with or without sulfur ttioxide) (UN 1754) (DOT) 0 dye component. When heated to CHROMOSULFURIC ACID (UN 2240) (DOT) 0 decomposition it emits toxic fumes of C1-. MONOCHLOROSULFURIC ACID 0 SULFONIC ACID, See also CHLOROPHENOLS and MONOCHLORIDE 0 SULFURIC CHLOROHYDRIN RESORCINOL. CONSENSUS REPORTS: Reported in EPA
CKW330 CAS: 122322-24-1 HR: 3 54(6-CHLORO-3-PYRIDINY L)METHOXY)-2-(3,4-DI CHLOR0PHENY L)-4IODO-3(2H)-PY RlDAZlNONE mf: C16H9C13IN302 mW: 508.53
HR: 3 CLE250 CHLOROSILANES PROP: Compounds of Si, C1, and H where the total number of atoms of C1 and H add up to 4. SiH,CL.,. SAFETY PROFILE: Poison by ingestion and inhalation, and a poisonous irritant to skin, eyes, and mucous membranes. Toxicity is based on HC1 which is formed upon hydrolysis of a chlorosilane. Self-ignites in air. With a little ammonia, it forms a selfigniting product. They react with water or steam to produce heat and toxic and corrosive fumes of HC1. When heated to decomposition they emit hghly toxic fumes of c1-. CLE750 CAS: 2039-87-4 0-CHLOROSTYRENE mf: CsH7C1 mu': 138.60
HR: 1
PROP: A solid. Mp: -63.15',
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive, Poison (UN 1754); DOT Class: 8; Label: Corrosive (UN 2240) SAFETY PROFILE: A poison irritant. See also SULFURIC ACID. Chlorosulfonic acid is corrosive, can cause severe acid burns and is very irritating to the eyes, lungs, and mucous membranes. It can cause acute toxic effects either in the liquid or vapor state. Inhalation of concentrated vapor may cause loss of consciousness with serious damage to lung tissue. Contact of liquid with the eyes can cause severe burns if the liquid is not immediately and completely removed. It also causes severe s h burns due to its highly corrosive action. Upon ingestion it wdl irritate the mouth, esophagus, and stomach to a serious degree and on contact with s h n cause dermatitis. It may cause conjunctivitis even in the vapor form. If
352
CLH750
CHLOROTHIAZIDE
spilled on a person, remove all contaminated clotlng, wash contaminated skin with copious amounts of water, followed by a baking soda solution. Irrigate eyes with warm water for 15 minutes. Consult a physician. Stored drums should be vented two times per month to control the hydrogen pressure, w l c h is produced by the action of acid on the drum metal. Decomposes explosively on contact with water, alcohol, or acids. Explosive reaction with phosphorus. Violent reaction with silver nitrate. Potentially violent reaction with sulfuric acid or &phenyl ether. Incompatible with acetic acid, acetic anhydride, acetonitrile, acrolein, acrylic acid, acrylonitrile, allyl alcohol, allyl chloride, 2-amino ethanol, ammonium hydroxide, aniline, n-butyraldehyde, creosote oil, cresol, cumene, dtchloroethyl ether, ðylene glycol monomethyl ether, diisobutylene, diisopropylether, epichloro hydrin, ethyl acetate, ethyl acrylate, ethylene chlorohydrin, ethylene cyanohydrin, ethylene &amine, ethylene glycol, ethylene glycol monoethyl ether acetate, ethylene imine, glyoxal, HC1, HF, HzOz, isoprene, mesityl oxide, metal powders, methyl ethyl ketone, HN03,2-nitropropane, ppropiolactone, propylene oxide, pyridene, NaOH, sulfolane, styrene monomer, vinyl acetate, vinylidene chloride, water, organic matter, combustibles. Dangerous. To fight fire, avoid water, use dry chemicals. When heated to decomposition it emits toxic fumes of C1- and SO,. See SULFURJC ACID, HYDROCHLORIC ACID, and SULFONATES. CLH750 CAS: 58-94-6 HR: 2 CHLOROTHIAZIDE mf: C7H6C1N304S2 mw: 295.73 PROP: Mp: 342.5'-343' (decomp). Sol in alkali. SYNS: ALURENE 0 CHLORIAZID 0 6-CHLORO-2H. 1,2,4-BENZOTHIADIAZINE-7-SULFONAMIDE1,lDIOXIDE 0 6-CHLORO-7-SULFAMOYL-2H-l,2,4BENZOTHIADIAZINE-1,l-DIOXIDE 0 CHLOROTHIAZID 0 CHLORSAL 0 CHLORTHIAZIDE 0
CHLORURIT CHLOTRIDE CLOTRIDE CT DIURESAL 0 DIURIL 0 DIURILIX 0 DIURITE 0 DIUTRID 0 FLUMEN 0 MINZIL 0 NEO-DEMA 0 SALISAN 0 SALUNIL 0 SALURETIL 0 SALLRIC U SKCHLOROTHIAZIDE 0 THIAZIDE 0 URINEX 0 WARDUZIDE 0 YADALAN
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology
Program. SAFETY PROFILE: Moderately_toxicby intraperitoneal and intravenous routes. Mddly toxic by ingestion. Experimental reproductive effects. Has been implicated in aplastic anemia. When heated to decomposition it emits very toxic fumes of SO,, NO,, and C1-.
CLH800 CAS: 7672-94-8 HR: 3 6-CHLORO-2-THIO-2H-1,3-BENZOXAZlNE-2,4(3H)-DIONE mf: CsH4ClN02S mw: 213.64 SYN : 2H-1,3-BENZOXAZINE-2,4(3H)-DIONE, 6CHLORO-2-THIO-
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO,, SO,, and C1-.
CLH820 CAS: 41219-30-1 HR: 3 6-CHLORO-CTHIOCHROMANYLO,ODIMETHYL DITHIOPHOSPHATE mf: C I I H I ~ C ~ O ~ P Smw: ~ 340.85 SYNS: S-(6-CHLORO-3,4-DIHYDRO-2H-l-BENZOTHIOPYRAN-4-YL) 0.0-DIMETHYL PHOSPHORODITHIOATE 0 PHOSPHORODITHIOIC ACID, S-(6-
CHLOR0-3,4-DIHYDRO-2H-l-BENZOTHIOPYRr\N-4-YL) o,o-DIMETHYL ESTER
SAFETY PROFILE: A poison by ingestion.
When heated to decomposition it emits toxic vapors of PO,, SO,, and C1-. CLJ750 CAS: 2812-73-9 HR: 3 CHLOROTHIOFORMIC ACID ETHYL ESTER DOT: UN 2826 mfi CsHsClOS mw: 124.59 PROP: Bp: 52-55' @, 40 mm. SYN: ETHYL CHLOROTHIOFOILMATE (DOT DOT CLASSIFICATION: 8; Label: Corrosive, Poison SAFETY PROFILE: Probably a poison by inhalation and ingestion. A corrosive irritant
3-CHLORO-p-TOLUlDlNE CLK215 353
to skin, eyes, and mucous membranes. See also ESTERS and CHLORIDES. Flammable when exposed to heat or flame. When heated to decomposition it emits very toxic fumes of C1- and SO,.
CLK100 CAS: 95-49-8 HR: 3 0-CHLOROTOLUENE DOT: UN 2238 mf: C7H7C1 mw: 126.59 PROP: Lquid. Mp: -34', bp: 159', d: 1.08 @? 20°/40. Volatile with steam. Sltly sol in water; freely sol in alc, benzene, chloroform, ether. SYNS: 2-CHLORO-1-METHYLBENZENE (9CI) 0 2CHLOROTOLUENE 0 HALSO 99 0 1-METHYL-2CHLOROBENZENE 0 2-METHYLCHLOROBENZENE0 o-TOLYL CHLORIDE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 50 ppm ACGIH TLV: TWA 50 ppm DOT CLASSIFICATION: 3; Label: Flammable Llquid SAFETY PROFILE: Moderately toxic by unspecified routes. Flammable when exposed to heat or flame. When heated to decomposition it emits toxic fumes of C1-. See also T O L E CHLORIDE and CHLORINATED HYDROCARBONS, AROMATIC.
CLK130 CAS: 25168-05-2 CHLOROTOLUENES DOT: UN 2238 mf: C7H7C1 mw: 126.59
HR: 3
SYNS: BENZENE, CHLOROMETHYL-(KI) 0 CHLOROMETHYLBENZENE 0 CHLOROTOLUENE C ar-CHLOROTOLUENE 0 TOLUENE, ar-CHLOROCONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label: SAFETY PROFILE: Low toxicity by
inhalation. A flammable liquid. When heated to decomposition it emits toxic vapors of c1-.
CAS: 87-60-5
SYNS: l-A?MIN0-2-CHLORO-G-METHYLBENZENE 0 l-AMINO-3-CHLORO-2-h~ETHYLBENZENE 0 2AMINO-6-CHLOROTOLUENE 0 AZOIC DIAZO COMPONENT 46 0 3-CHLORO-2-METHYLANILINE 0 3-CHLOR-2-TOLUIDIN(CZECH) 0 FAST SCARLET TR BASE 0 SCARLET TR BASE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of C1and NO,. See also other chloro toluidine entries.
CLK210 CAS: 615-65-6 HR: 3 2-CHLORO-p-TOLUIDINE mf: C7HgClN mw: 141.61 PROP: Liquid. D: 1.151 @ 20', mp: 7', bp: 219' @? 732 mm. SYNS: BENZENAMINE, 2-CHLORO-4-METHYL- 0 2CHLORO-4-METHYLANILINE0 2-CHLOR-4-TOLUIDIN (CZECH) 0 4-~lETHYL2-CHLOROkILINE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by ingestion. A severe eye and skin irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of C1- and NO,. See also other chloro toluidine entries.
CLK215 CAS: 95-74-9 HR: 3 3-CHLORO-p-TOLUIDINE mf: C7HaClN mw: 141.61 PROP: A solid or liquid. Mp: 26O, bp: 237-238.5'. SYNS: l-AMINO-3-CHLORO-4-METHYLBENZENE
Flammable Liquid
CLK2OO
3-CHLORO-0-TOLUIDINE mf: C7HaClN mw: 141.61 PROP: Bp: 245'.
HR: 3
4-AMINO-2-CHLOROTOLUENE0 2-CHLORO-4AMINOTOLUENE 0 3-CHLORO-4-METHYILINE 0 CPT 0 DKC 1347 0 DRC 1339 0 NCI-C02040
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. NCI Carcinogenogenesis Bioassay (Feed); Results Negative: Mouse, Rat NCITR* NCI-CG-TR-145,78
354 CLK220 ~-CHLORO-O-TOLUIDINE DOT CLASSIFICATION: 6.1; Label: KEEP
AWAY FROM FOOD SAFETY PROFILE: Poison by ingestion, intravenous, and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits toxic fumes of C1and NO,. See also other chloro toluidme entries. CLK220 CAS: 95-69-2 HR: 3 4-CHLORO-0-TOLUIDINE mf: C7H8ClN mw: 141.61 PROP: Leaflets from EtOH. Mp: 29-30', bp: 236-238' @ 730 mm. SYNS: AMARTHOL FAST RED TRBASE 0 2-AMINO-5CHLOROTOLUENE 0 AZOENE FAST RED TR BASE 0 AZOGENE FAST RED TR 0 AZOIC DIAZO COMPONENT 11 BASE 0 BRENTAAIINE FAST RED TR BASE 0 5CHLORO-2-AhlISOTOLUENE 0 4-CHLORO-2METHYLANILIXE 0 4-CHLORO-6-METHYLANILINE 0 4-CHLORO-2-hlETHYLBENZE?U'Ehl.IINE0 4-CHLORO2-TOLUIDINE 0 DAITO RED BASE TR 0 DEVAL RED K 0 DEVAL RED TR 0 DIAZO FAST RED TRA 0 FAST RED BASE TR 0 FAST RED 5CT BASE 0 FAST RED TR 0 FAST RED TR11 0 FAST RED TR BASE 0 FAST RED TRO BASE 0 KAKO RED TR BASE 0 KAMBAMINE RED 0 MITSUI RED TR 0 2-METHYL-4-CHLOROANILINE TR BASE 0 RED BASE CIBA IX 0 RED BASE IRGA M 0 RED BASE NTR 0 RED TR BASE 0 SANYO FAST RED TR BASE 0 TULABASE FAST RED TR
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2A IMEMDT 7,56,87; Human Inadequate Evidence IMEMDT 16,277,78; Animal Sufficient Evidence IMEMDT 30,61,83. Reported in EPA TSCA Inventory. DFG MAK: Human Carcinogen DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Confirmed carcinogen. Poison by ingestion and subcutaneous routes. Human mutation data reported. In the presence of copperpI) chloride catalyst decomposition occurs above 239'C. When heated to decomposition it emits toxic fumes of C1- and NO,. See also other chloro toluidme entries.
CLK225 CAS: 95-79-4 HR: 3 5-CHLORO-0-TOLUIDINE mf: C7HsClN mw: 141.61 PROP: Solid. Bp: 237' @ 722 mm, mp: 21-22', SYNS: ACCO FAST RED KB BASE 0 1-AMINO-3CHLORO-6-METHYLBENZENE0 2-rtMINO-4CHLOROTOLUENE 0 ANSIBASE RED KB 0 AZOENE FAST RED KB BASE 0 AZOIC DIAZO COMPONENT 32 0 4-CHLORO-2-AMINOTOLUENE0 3-CHLORO-60 METHYLANILINE 0 5-CHLORO-2-METHYLANILINE FAST RED KB AMINE 0 FAST RED KB BASE 0 FAST RED KB SALT 0 FAST RED KB SALT SUPRA 0 FAST RED KBS SALT 0 GENAZO RED KB SOLV 0 HILTONIL FAST RED KB BASE 0 LAKE RED KB BASE 0 METROGEN RED FOILMER KB SOLN 0 NAPHTHOSOL FAST RED KB BASE 0 NCI-C02051 0 PHARMAZOID RED KB 0 RED KB BASE 0 SPECTROLENE RED KB 0 STABLE RED KB BASE
CONSENSUS REPORTS: NTP
Carcinogenesis Bioassay (feed): Clear Evidence: mouse NCITR* NCI-TR-187,79; (feed): Inadequate Stules: rat NCITR" NCI-TR-187,79. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. Moderately toxic by ingestion. When heated to decomposition it emits very toxic fumes of C1- and NO,. See also AROMATIC AMINES. CLK227 CAS: a7-63-8 HR: 3 6-CHLORO-0-TOLUIDINE mf: C7HsClN mw: 141.61 SYNS: 2-AMINO-3-CHLOROTOLUENE0 3-CHLORO2-AMINOTOLUENE 0 6-CHLORO-2-METHYILINE 0 6-CHLORO-2-TOLC'IDINE0 o-TOLUIDINE, 6CHLORO-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by subcutaneous route. Mutation data reported.
CHLOROTRIBUTYLSTANNANE
When heated to decomposition it emits toxic vapors of NO, and C1-. CLK235 CAS: 3165-93-3 HR: 3 4-CHLORO-2-TOLUIDINE HYDROCHLORIDE DOT: UN 1579 mfi C7HsClN*ClH mw: 178.07
CLPSOO 355
CL0750 CAS: 569-57-3 HR: 3 CHLOROTRIANISENE mf: C23H21C103 mw: 380.89 PROP: Crystals from MeOH. Mp: 114-116'. SYNS: ANISENE
0 CHLORESTROLO 0 l,l',l"-(lCHLORO-1-ETHENYI-2-YLIDENE)-TRIS(4METHOXYBENZENE) 0 CHLOROTRIANIZEN 0 CHLOROTRISIN 0 CHLOROTRIS@-METHOXYPHEh-YL)ETHYLEh-E 0 CHLORTRIANISEK 0 CLORESTROLO 0 CLOROTRISIN 0 CTA 0 HORMONISENE 0 KHLORTRIANIZEN 0 MERBENTUL 0 METACE 0 NSC-10108 0 RMNIL 0 TACE 0 TACEFN 0 TRI-p-ANISYLCHLOROETHYLENE 0 TRIS@hIETH0XYPHENYL)CHLOROETHYLENE
SYNS: AMARTHOL FAST RED TR BASE 0 AhMRTHOL FAST RED TR SALT 0 2-ASIINO-5CHLOROTOLUENE HYDROCHLORIDE 0 AZANIL RED SALT TRD 0 AZOENE FAST RED TR SALT 0 AZOGENE FAST RED TR 0 AZOIC DIAZO COW PONENT 11 BASE 0 BRENTAMNE FAST RED TR SALT 0 CHLORHYDRATE de 4-CHLOROORTHO-TOLUIDINE CONSENSUS REPORTS: IARC Cancer (FRENCH) 0 5-CHLORO-2-AMINO-TOLUENE Review: Animal Inadequate Evidence HYDROCHLORIDE 0 4 - C H L O R O - 2 - M E T H Y I L I N E IMEMDT 21,139,79; Human Limited HYDROCHLORIDE 0 4-CHLORO-6-hlETHYLANLINE Evidence IMEMDT 21,139,79. HYDROCHLORIDE 0 4-CHLORO-2-hlETHYLBENZENESAFETY PROFILE: Suspected human AMINE HYDROCHLORIDE 0 4-CHLORO-o-TOLEIDINE carcinogen with experimental tumorigenic HYDROCHLORIDE 0 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE (DOT 0 C.I. 37085 0 C.I. AZOIC data. Human reproductive effects by DIAZO COMPONENT 11 0 DAITO RED SALT TR 0 ingestion: changes in ferulity. Used in cancer DEVOL RED K 0 DEVOL RED TA SALT 0 DEVOL RED treatment. When heated to decomposition it TR 0 DIAZO FAST RED TR 0 DIAZO FAST RED TIW 0 emits very toxic fumes of C1-. FAST RED 5CT SALT 0 FAST RED SALT TR 0 FAST RED SALT TRA 0 FAST RED SALT TRN 0 FAST RED TR SALT 0 HINDASOL RED TR SALT 0 KROMON GREEN CLP500 CAS: 1461-22-9 HR: 3 B 0 2-hlETHYL-4-CHLOROA"LINE HYDROCHLORIDE CHLOROTRIBUTYLSTANNANE 0 NATASOL FAST RED TR SALT 0 NCI-C02368 0 mf: C12H27ClSn mw: 325.53 NEUTROSEL RED TRVA 0 OFNA-PERL SALT RRA 0 PROP: Liquid. D: 1.2105 @ 20', bp: RCRA WASTE NUMBER U049 0 RED BASE CIBA IX 0 171-173' @ 25 mm. RED BASE IRGA IX 0 RED SALT CIBA IX 0 RED SALT SYNS: CHLORID TRI-n-BUTYLCINICITY (CZECH) 0 IRGA IX 0 RED TRS SALT 0 SANYO FAST RED SALT TRIBUTYLCHLOROSTANNANE 0 TRI-n-BUTYLTIN TR CHLORIDE 0 TRI-n-BUTYLZINN-CHLORID (GERMAN) CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 2A IMEMDT 48,123,90; Animal Inadequate Evidence, Human Inadequate Evidence IMEMDT 16,277,78. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse; No Evidence: rat NCITR* NCI-CG-TR-165,79. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by intraperitoneal route. When heated to decomposition it emits toxic fumes of NO, and C1-. See also other chloro toluidine entries.
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (sktn) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). DFG MAK: 0.0021 ppm (0.05 mg/m3) NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion and skin contact. A severe eye irritant. Mutation data reported. Tributyl tin compounds are extremely toxic to marine life. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of C1-.
356
CLP750 2-CHLORO-64TRICHLOROMETHYL)-
CLP750 CAS: 1929-82-4 HR: 3 2-CHLORO-6-(TRICHLOROMETHYL)PYRlDlNE mf: C6H3C14N mw: 230.70 PROP: Crystals. Mp: 62-63'. Very sltly sol in HzO.
CHLOROETHYLENE CHLOROETHYLENE 0 TRITHENE
TRIFLUOROMONOTRIFLUOROVINYL CHLORIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 2.1; Label:
SYNS: DOWCO-163 0 NITRAPYRIN (ACGIH) 0 N-
Flammable Gas
SERVE NITROGEN STABILIZER
SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Moderately toxic by inhalation. Very dangerous fire hazard when exposed to heat, flames (sparks), or oxidizers. T o fight fire, stop flow of gas. Violent reaction when mixed with (Brz + 0 2 ) or (CIF3 + water). Potentially explosive polymerization reaction with ethylene. Incompatible with 1,l-dchloroethylene; oxygen. When heated to decomposition it emits toxic fumes of F- and C1-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.
CONSENSUS REPORTS: NCI
Carcinogenesis Studes (ipr); Clear Evidence: mouse, rat RRCRBU 52,1,75. Reported in EPA TSCA Inventory. OSHA PEL: Total Dust: 15 mg/m3; Respirable Fraction: 5 mg/m3 ACGIH TLV: TWA 10 mg/m3; STEL 20 mg/m3; Not Classifiable as a Human Carcinogen SAFETY PROFILE: Poison by ingestion. Moderately toxic by s h n contact. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,. CLQ500 CAS: 15529-90-5 HR: 3 CHLORO(TR1ETHYLPH0SPHINE)GOLD mf: C ~ H ~ ~ A U C ~mw: P 350.60 PROP: Crystals from EtOH. Mp: 78', bp: 210' @ 0.03 mm. Sol in CHCl3 and EtOH. SYNS: SK&F 36914 0 TRIETHYLPHOSPHINEAUROUS CHLORIDE
SAFETY PROFILE: Poison by ingestion. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and PO,. See also PHOSPHINE and GOLD.
CLQ750 CAS: 79-38-9 HR: 3 CHLOROTRIFLUOROETHYLENE DOT: UN 1082 mf: C2ClF3 mw: 116.47 PROP: A gas. Fp: -157.5', bp: -26.2', flash p: -18'F, lel: 24%, uel: 40.3%. SYNS: l-CHLORO-l,2,2-TRIFLUOROETHYLENE 0 2CHLORO-l,1,2-TRIFLUOROETHYLENE 0 CHLORTRIFLUORAETHYLEN (GERXAN) 0 CTFE 0 DAIFLON 0 FLUOROPMST 3 0 GENETRON 1113 MONOCHLOROTRIFLUOROETHYLENE 0 TRIFLUOROCHLOROETHYLENE(DOT) 1,1,2-TRIFLUORO-2-
CLR250 CAS: 75-72-9 HI?: 1 CHLOROTRIFLUOROMETHANE DOT: UN 1022 mf: CClF3 mw: 104.46 PROP: Colorless gas; ethereal odor. Mp: -181', bp: -81.4', fp: -181'. SYNS: ARCTON 3 0
F 13 0 FREOK 13 GENETRON 13 0 HALOCARBON 13/UCON 13 0 MONOCHLOROTRIFLUOROMETHANE (Dog 0 R 13 0 R13 (DOT) 0 TRIFLUOROCHLOROMETHANE(DOT) 0 TRIFLUOROMETHYL CHLORIDE 0 TRIFLUOROIMONOCHLOROCARBON
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: 1000 ppm (4300 mg/m3) DOT CLASSIFICATION: 2.2; Label: Nonflammable Gas SAFETY PROFILE: A mild irritant. Narcotic in high concentrations. Reacts violently with Al. When heated to decomposition it emits highly toxic fumes of F- and C1-.
CLTOOO CAS: 1066-45-1 HR: 3 CHLOROTRIMETHYLSTANNANE mf: C3H9ClSn mw: 179.26 PROP: Colorless needles. Mp: 42', bp: 154-1 56'.
CHLOROVINYLARSINE DICHLORIDE SYNS: CHLOROTRIMETHYLTIN 0 TRIMETHYLCHLOROSTANNANE 0 TRIMETHYLCWLOROTIN 0 TRIMETHYLSTANNYL CHLORIDE 0 TRIMETHYLTIN CHLORIDE CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (slun) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (shn). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: A deadly poison by intravenous route. Experimental reproductive effects. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of C1-.
CLUOOO CAS: 639-58-7 HR: 3 CHLOROTRIPHENYLSTANNANE mfi ClsHlsClSn mw: 385.47 PROP: Colorless crystals from alc. Mp: 106', bp: 240' @ 13.5 mm. Insol in water; sol in org solvs. SYNS: AQUATIN 0 BRESTANOL 0 CHLOROTRIPHENYLTIN 0 FENTIN CHLORIDE 0 GC 8993 0 GENERAL CHEMICALS 8993 0 HOE 2872 0 LS 4442 0 TIXMATE 0 TPTC 0 TRIPHENYLCHLOROSTAM'JANE 0 TRIPHENYLCHLOROTIN 0 TRIPHENYLTIN CHLORIDE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.1 mg(Sn)/m' (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion, intraperitoneal, and intravenous routes. Experimental reproductive effects. Mutation data reported. An insect chemosterilant. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of C1-.
CLU250 CAS: 2279-76-7 HR: 3 CHLOROTRIPROPYLSTANNANE mfi C9H21ClSn mw: 283.44 PROP: Colorless liquid. D: 1.2678 @ 28', mp: -23.5'. Sol in org solvs.
CLVOOO 357
SYNS: TRIPROPYLTIN CHLORIDE 0 TRI-nPF.OPYLTIN CHLORIDE OSHA PEL: TWA 0.1 mg(Sn)/m3 ( s h ) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/rn' SAFETY PROFILE: Poison by intravenous route. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-.
CLU500 CAS: 10008-90-9 HR: 3 CHLORO(TRIV1NYL)STANNANE mf: CbHYClSn mw: 235.29 PROP: Colorless liquid. Bp: 59-60' @ 6 mm. SYN: TRIVINYLTIN CHLORIDE OSHA PEL: TWA 0.1 mg(Sn)/m3 (skm) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m3 (skin). NIOSH REL: TWA (Organotin Compounds) 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by intravenous route. See also TIN COMPOUNDS and CHLORIDES. When heated to decomposition it emits toxic fumes of C1-.
CLVOOO CAS: 541-25-3 HR: 3 CHLOROVINYLARSINE DlCHLORlDE mf: C2HAsCL mw: 207.31 PROP: Liquid; faint odor of geranium. Bp: 190' decomp, fp: -13', d: 1.888 @ 20'/4', vap press: 0.4 mm @ 20', vap d: 7.15. SYNS: (2-CHLOROETHENYL)ARSONOUS DICHLORIDE p-CHLOROVINYLBICHLOROARSINE 0 2-CHLOROVINYLDICHLOROARSINE 0 (2CHLOROV1NYL)DICHLOROARSINE 0 DICHLORO(2CHLOROV1NYL)ARSINE 0 LEFTSITE 0 LEE'ISITE (ARSENIC COMPOUND) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.EPA Extremely Hazardous Substances List. Arsenic and its compounds are on the Community Right-To-Know List. SAFETY PROFILE: A human poison by inhalation. Poison experimentally by inhalation, skin contact, subcutaneous, intraperitoneal, and intravenous routes. An
358
CL WOO0 4-CHLORO-3.5-XYLENOL
experimental teratogen. A blistering-type military poison. Lewisite is absorbed through skin; as little as 2 mL on the s h n can cause death. Has a delayed action similar to &sidled mustard gas. This gas exhibits a systemic poisoning effect on humans. When heated to decomposition it emits toxic fumes of C1- and As. See also ARSENIC COMPOUNDS. CLWOOO CAS: 88-04-0 HR: 3 4-CHLORO-3,5-XYLENOL mf: CgH9C10 mw: 156.62 PROP: Crystals or prisms from (C6H6); phenolic odor. Mp: 115.5', bp: 246'. Sltly water-sol.
CLW$OO CAS: 65089-17-0 HR: 3 2-((4-CHLOR0-6-(2,3-XYLIDIN0)-2PYRIMIDINYL)THlO)-N-(2HYDR0XYETHYL)ACETAMIDE mfi C I ~ H I ~ C ~ N ~ Omw: ~ S 366.90 PROP: Crystals from MeKO. Mp: 144- 146'. SYNS: BR-931 0 PIRINIXIL SAFETY PROFILE: Suspected carcinogen
with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1-, NO,, and SO,. CLXOOO CAS: 54749-90-5 HR: 3 CHLOROZOTOCIN mf: C9H16ClN307 mw: 313.73
SYNS: BENZYTOL 0 4-CHLORO-3,5-DIMETHYLPHENOL 0 CHLORO-XYLENOL 0 p-CHLORO-rnXYLENOL DESSON DETTOL ESPADOL HUSEPT EXTRA 0 OTTASEPT 0 OTTASEPT EXTRA 0 PC,W 0 RBA 777
YL)-1-NITROSOUREA 0 2-((((2-CHLOROETHYL)NITRO-
CONSENSUS REPORTS: Reported in EPA
2-(3-(2-CHLOROETHYL)-3-NITROSOUREIDO)-2-DEOXY-
TSCA Inventory. Chlorophenols are on the Community Right-To-Know List. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. An experimental teratogen. An eye irritant. An antimicrobial agent. See also CHLOROPHENOLS and CHLORINATED HYDROCARBONS, AROMATIC. When heated to decomposition it emits toxic fumes of C1-.
SYNS: 1-(2-CHLOROETHYL)-3-(d-GLVCOPYRANOS-2SOAMINO)CARBONYL)AMINO)-2-DEOXY-dGLUCOPYRANOSE 0 2-((((2-CHLOROETHYL)NITROSOAA4INO)CARBONYL)AhUNO)-2-DEOXY-d-GLUCOSE0 d-GLUCOSOPYRANOSE 0 2-(3-(2-CHLOROETHYL)-3NITROSOUREID0)-d-GLUCO-PYRANOSE 0 CHLZ 0 CZT 0 DCNU 0 NSC-178248 0 NSC-D 254157
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 2A IMEMDT 50,65,90; Animal Sufficient Evidence IMEMDT 50,65,90; Human No Adequate Data IMEMDT 50,65,90. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by subcutaneous, CLW250 CAS: 50892-23-4 HR: 3 intravenous, and intraperitoneal routes. (4-CHLORO-6-(2,3-XYLIDINO)-2-PYHuman systemic effects by intravenous RIMIDINYLTHI0)ACETIC ACID route: anorexia, leukopenia, nausea or mf: C14H14ClN302S mw: 323.82 vomiting, thrombocytopenia. Mutation data PROP: Crystals from EtOAc. Mp: reported. When heated to decomposition it 150-153'. SYNS: ((4-CHLORO-6-((2,3-DIMETHYLPHENYL)- emits very toxic fumes of C1- and NO,. See ~fINO)-2-PYRIMIDINYL)THIO)ACETIC ACID 0 WYalso NITROSAMINES. 14,643
SAFETY PROFILE: Moderately toxic by
ingestion. Suspected carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1-, NO,, and SO,.
CMA100 CAS: 2921-88-2 HR: 3 CHLORPYRlFOS mf: C ~ H I I C ~ N O ~ P Smw: 350.59 PROP: Crystals with mild mercaptan odor. Mp: 42-43.5'. Very sltly sol in HzO;sol in most org solvs.
CHOLESTEROL CMD750 359 SYNS: BRODAV 0 CHLORPYRIFOS-ETHYL 0 ethanol, butanol, acetone, ethyl acetate, and CHLORPYRIPHOS 0 CHLORPYRIPHOS-ETHYL 0 benzene; insol in ether and pet ether. DETMOL U.A. 0 O,O-DIAETHYI-0-3,5,6-TRICHLOR-2-SYNS: ACRONIZE 0 AUREOCINA 0 AUREOMYCIN PYRIDYLMONOTHIOPHOSPHAT0 0,O-DIETHYL 00 AUREOMYCIN A-377 0 AUREOiMYKOIN 0 BIO3,5,6-TRICHLORO-2-PYRIDYL PHOSPHOROTHIOATE 0 MITSIN 0 BIOMYCIN 0 7-CHLORO-4-(DIMETHYLDOWCO 179 0 DURSBAN 0 DURSBAN F 0 ENT 27,311 AMINO)-l,4,4a,5,5a,6,11,12a-OCTAHYDRO-2-NAPHTH0 ERADEX 0 ETHION, dry 0 LORSBAN 0 OMS-0971 0 ACENECARBOXAMIDE 0 7-CHLOROTETRACYCLINE PIRIDANE 0 2-PYRIDINOL,3,5,6-TRICHLORO-, 00 CHRYSOMYKINE 0 CTC 0 DUOMYCIN 0 FLAMYCIN ESTER with 0,O-DIETHYL PHOSPHOROTHIOATE 0 PYRINEX 0 STIPEND CONSENSUS REPORTS: Reported in EPA CONSENSUS REPORTS: EPA Genetic Toxicology Program. OSHA PEL: TWA 0.2 mg/m3 (shn) ACGIH TLV: TWA 0.1 mg/m3 (skin); Not Classifiable as a Human Carcinogen SAFETY PROFILE: Poison by ingestion, intraperitoneal, skin contact, and inhalation routes. Human systemic effects by ingestion: paresthesia, muscle weakness, coma. Experimental reproductive effects: developmental toxicity. Mutation data reported. When heated to decomposition it emits very toxic fumes of C1-, NO,, PO,, and SO,.
CMA250 CAS: 5598-13-0 HR: 2 CHLORPYRIFOS-METHYL mf: C7HSbN03PS mw: 322.53 PROP: A solid. Mp: 44.5-45.5’. Sltly sol in H20; very sol in org solvs. SYNS: O,O-DIMETHYL-O-(3,5,6-TRICHLORO-2PYRIDYL)PHOSPHOROTHIOATE 0 DOWCO 217 0 DURSBAN METHYL 0 ENT 27,520 0 METHYL CHLORPYRIFOS 0 METHYL DURSBAN 0 NOLTRAN 0 NSC-60380 0 OMS-1155 0 RELDAN 0 ZERTELL
SAFETY PROFILE: Moderately toxic by
ingestion, intraperitoneal, and skin contact routes. A skin irritant. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of C1-, NO,, PO,, and SO,. A pesticide. CMA750 CAS: 57-62-5 HR: 3 CHLORTETRACYCLINE mf: CzzH~3ClN208 mw: 478.92 PROP: Golden-yellow crystals. Mp: 168-1 69”. Sltly sol in water; very sol in aq s o h pH 7.65; freely sol in the cellos solve^,^' dioxane, “Carbitol”; sol in methanol,
TSCA Inventory. SAFETY PROFILE: Poison by intravenous
and intraperitoneal routes. Moderately toxic by ingestion. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of C1- and NO,. See also TETRACYCLINE. CMC750 CAS: 67-97-0 HR: 3 CHOLECALCIFEROL mf: C 2 7 H ~ 0 mw: 384.71 PROP: White crystals; odorless. Mp: 87-88’. Insol in water; sol in alc, chloroform, and fatty oils. SYNS: COLECALCIFEROL 0 7-DEHYDROCHOLESTROL, ACTIVATED 0 DELSTEROL 0 DEPARAL 0 D3-VIGANTOL 0 OLEOVITAMIN D3 0 RICKETON 0 9,lO-SECOCHOLESTA-5,7,10(19)-TRIEN-3-~-0L 0 TRIVITAN 0 VIGORSAN 0 VITAMIN D3 0 VITINC DAN-DEE-3
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion. An experimental teratogen. When heated to
decomposition it emits acrid smoke and irritating fumes. CMD750 CAS: 57-88-5 HR: 2 CHOLESTEROL mf: C27H460 mw: 386.73 PROP: White or faint yellow, pearly leaflets from aq alc. Mp: 148.5’ (anhyd), bp: 360’ (decornp). SYNS: CHOLEST-5-EN-3-p-OL 0 A’XHOLESTEN-3-POL 0 5-CHOLESTEN-3-p-OL 0 5:6-CHOLESTEN-3-p-OL 0 CHOLESTERIN 0 CHOLESTEROL BASE H 0 CHOLESTERYL ALCOHOL 0 CHOLESTRIN 0 CHOLESTROL 0 CORDULAN 0 DCSOLINE 0 DUSORAIV 0 DYTHOL 0 HYDROCERIN 0 3-pHYDROXYCHOLEST-5-ENE0 KATHRO 0 LANOL 0
360 CME250
CHOLESTERYL-p-BIS(2-CHLORO-
NIMCO CHOLESTEROL BASE H 0 PROVITAMIN D 0 SUPER HARTOLAN 0 TEGOLAN
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,161,87; Human Inadequate Evidence IMEMDT 31,95,83; Animal Inadequate Evidence IMEMDT 10,99,76. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE : Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. Used in pharmaceutical and dermal preparations as an emulsifying agent. When heated to decomposition it emits acrid smoke and irritating fumes.
CME250 CAS: 3546-10-9 HR: 3 CHOLESTERYL-p-BIS(2-CHLOROETHYL)AMINO PHENYLACETATE mf: C39H59ClzN02 mw: 644.89 SYNS: @-@1s(2CHLOR0ETHYL)AMINO)PHENYL)ACETATE CHOLESTEROL 0 @-(BIS(2-CHLOROETHYLAMIN0)PHENYL)ACETICACID CHOLESTEROL ESTER 0
(4-(BIS(2-CHLOROETHYL)AhfIKO)PHENYL)ACETIC
ACID CHOLESTERYL ESTER 0 5-CHOLESTEN-3-P-OL3 @-(BIS(2-CHLOROETHYL)AMI”n)ACETATE 0 FENESTERIS U FEXESTRIN U NCI-C01558 0 NSC104469 0 PHENESTERINE 0 PHENESTRIN
CONSENSUS REPORTS: NCI Carcinogenesis Bioassay (gavage); Clear Evidence: mouse, rat NCITR* NCI-CGTR-60,78. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and neoplastigenic data. When heated to decomposition it emits very toxic fumes of C1- and NO,.
CME400 CAS: 11041-12-6 HR: 2 CHOLESTYRAMINE SYNS: C H O L E S W V I N E CHLORIDE 0 CHOLESTYRAMINERESIN 0 COLESTYRAMIN 0 CUEMID 0 QUANTALAN 0 QUESTRAN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low toxicity by
ingestion. Questionable human carcinogen
producing colon tumors. An experimental teratogen. Other experimental reproductive effects. Toxic effects by ingestion: acidosis and nosebleeds. When heated to decomposition it emits acrid smoke and irritating fumes. CMF300 HR: D CHOLINE BITARTRATE mf: C0H19N07 mw: 253.25 PROP: m t e crystalline powder; acetic taste. Sol in water; sltly sol in alc; insol in ether, chloroform, benzene. SYN (2-HYDROXYETHYL)TRIhfETHYLAMhlOPU’IUM BITARTRATE
SAFETY PROFILE: When heated to
decomposition emits toxic fumes of NO,. CMF400 CAS: 999-81-5 HR: 3 CHOLINE DlCHLORlDE mf: C5HtsClNCl mw: 158.09 PROP: Crystals. Mp: 245’ (decomp). Very sol in H20. SYNS: ANTYWYLEGACZ 0 CCC P U N T GROWTH R E G U W T 0 CE CE CE 0 2-CHLORAETHYL TRIMETHYLAMMONIUMCHLORID 0 CHLORCHOLINCHLORID 0 CHLORCHOLINE CHLORIDE 0 CHLORMEQUAT 0 CHLORMEQUAT CHLORIDE 0 CHLOROCHOLINE CHLORIDE 0 (P-CHLOROETHYL)TRIMETHYLAiWONIUM CHLORIDE 0 (2CHLOR0ETHYL)TRIMETHUWMONIUM CHLORIDE 0
2-CHLORO-N,N,N-TRIMETHYLETHANAMINIUM
CHLORIDE 0 60-CS-16 0 CYCLOCEL 0 CYCOCEL 0 CYCOCEGEXTRA 0 CYCOGAN 0 CYCOGAN EXTRA 0 CYOCEL 0 EI 38,555 0 ETHrZNkMINIUM, 2-CHLORON,N,N-TRIMETHYL, CHLORIDE ( 9 0 R HICO CCC 0 HORMOCEL-2CCC 0 INCRECEL 0 LIHOCIN 0 NCIC02960 0 RETACEL 0 STABILAN 0 TRIMETHYL-PCHLORETHYLAMMONIUMCHLORID 0 TUR
CONSENSUS REPORTS: NTP Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* NCI-TR158,79. EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. SAFETY PROFILE: Human poison by ingestion and intravenous routes. Moderately toxic by skin contact. Human systemic effects: respiratory depression. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported.
CHROMIC(V1) ACID
When heated to decomposition it emits toxic fumes of C1-. CMF750 CAS: 67-48-1 HR: 3 CHOLINE HYDROCHLORIDE mf: CsH14NO*Cl mw: 139.65 PROP: Colorless to white, deliquescent, hygroscopic crystals; slt odor of trimethylamine. Sol in water and alc. SYNS: BIOCOLINA 0 CHLORIDE de CHOLINE (FRENCH) 0 CHOLINE CHLORHYDRATE 0 CHOLINE CHLORIDE (FCC) 0 CHOLINIUM CHLORIDE 0 HEPACHOLINE 0 (2-HYDR0XYETHYL)TRIMETHYLhMMONIUM CHLORIDE LIPOTRIL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
intraperitoneal and intravenous routes. Moderately toxic experimentally by ingestion and subcutaneous routes. Mutation data reported. A lipotropic agent which induces the reduction in fats contained in the liver. When heated to decomposition it emits toxic fumes of C1-, SO,, and NO,. See also CHOLINE. CMG800 CAS: 15005-90-0 HR: 3 CHROMALUM HEXAHYDRATE mf: Cr2012S3*6H20 mw: 500.30 PROP: IDLH 25 mg/m3 [as Cr(III)]. SYN : CHROMIUM(I1I) SULFATE, HEXAHMRATE (2:3:6)
OSHA PEL: TWA 0.5 mg(Cr)/m3 ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not
Classifiable as a Carcinogen. SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of SO, and Cr-. CMHOOO CAS: 1066-30-4 HR: 3 CHROMIC ACETATE mf: C6Hg06*CT mW: 229.15 PROP: Gray-green powder or bluish-green pasty mass. IDLH 25 mg/m3 [as Cr(III)]. SYNS: CHROMIC ACETATEFII) 0 CHROMIUM ACETATE 0 CHROMIUM(I1I) ACETATE 0 CHROMIUM TRIACETATE
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,165,87; Animal Inadequate Evidence IMEMDT
CMH250 361
2,100,73; IMEMDT 23,205,80. Chromium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.5 mg(Cr)/m3 ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not Classifiable as a Carcinogen SAFETY PROFILE: Questionable carcinogen with experimental tumorigenic data. Moderately toxic by intravenous route. Human mutation data reported. See also CHROMIUM COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes. CMH250 CAS: 7738-94-5 HR: 3 CHROMIC(V1) ACID mf: CrH204 mw: 118.02 PROP: Found in solution. IDLH Ca [15 mg/m3 (as Cr(vr>)]. SYNS: ACIDE CHROMIQUE (FRENCH) 0 CHROMIC ACID
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Chromium and its compounds are on the Community RghtTo-IGow List. OSHA PEL: CL 0.1 mg(CrO$/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m3, Confirmed Human Carcinogen DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Chromium(VI)) TWA 0.025 mg(Cr(VI))/m3; CL 0.05/15M SAFETY PROFILE: Confirmed human carcinogen. Poison by subcutaneous route. Mutation data reported. A powerful oxidzer. A powerful irritant of skm, eyes, and mucous membranes. Can cause a dermatitis, bronchoasthma, “chrome holes,” damage to the eyes. Dangerously reactive. Incompatible with acetic acid, acetic anhydride, tetrahydronaphthalene, acetone, alcohols, alkali metals, ammonia, arsenic, bromine penta fluoride, butyric acid, n,ndimethylformamide, hydrogen sulfide, peroxyformic acid, phosphorus, potassium hexacyanoferrate, pyridme, selenium,
E
362
CMH260
CHROMIC(III) ACID
sodium, sulfur, and many other materials. See also CHROMIUM COMPOUNDS.
neoplastigenic data. Very powerful oxidzer. See also CHROMIUM COMPOUNDS.
CMH260 CAS: 1308-14-1 HR: 3 CHROMIC(III) ACID mf: CrH303 mw: 103.03 PROP: Green flocculent solid or crystals. Readily hydrolyzed. Practically insol in H20; sol in mineral acids. IDLH 25 mg/m3 [as Cr(III)]. SYNS: CHROMIC 019 HYDROXIDE 0 CHROMIUM(I1I)
CM1500 CAS: 1308-31-2 HR: 3 CHROMITE (mineral) mf: Cr2FeO4 mw: 223.85 PROP: Black or brown-black cubic crystals. Relatively insol in acids. SYNS: CHROME ORE 0 CHROMITE 0 CHROMITE
HYDROXIDE 0 CHROMIUM TRIHYDROXIDE
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 49,49,90; Human Inadequate Evidence IMEMDT 49,49,90; Animal Inadequate Evidence IMEMDT 49,49,90. Reported in EPA TSCA Inventory. OSHA PEL: CL 0.1 rng(CrOs)/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m3; Confirmed Human Carcinogen NIOSH REL: (Chromium(VI)) TWA 0,001 mg(Cr) /m3 SAFETY PROFILE: A confirmed carcinogen. A poison. A powerful oxidizer. A powerful irritant of skin, eyes, and mucous membranes.
CM1250 CAS: 24613-89-6 HR: 3 CHROMIC CHROMATE mf: Cr301p2Cr mw: 452.00 SYNS: CHROMIC ACID, CHROMUM(3+) SALT (3:2) 0 CHROMIUM CHROMATE (MAK)
CONSENSUS REPORTS: IARC Cancer Review: Animal Sufficient Evidence IMEMDT 2,100,73. Reported in EPA TSCA Inventory. Chromium and its compounds are on the Community RightTo-Know List. OSHA PEL: CL 0.1 mg(CrO$/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m’; Confirmed Human Carcinogen DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Chromium(VI)) TWA 0.001 mg(Cr(VI))/m3 SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and
ORE 0 IRON CHROMITE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 3 IMEMDT 7,165,87; Animal Inadequate Evidence IMEMDT 23,205,80. Chromium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.5 mg(Cr)/m3 ACGIH TLV: TWA 0.05 mg/m3 (ore processing); Confirmed Human Carcinogen (ore processing) SAFETY PROFILE: Confirmed human carcinogen during ore processing. Human mutation data reported. See also CHROMIUM COMPOUNDS and IRON.
CM1750 CAS: 7440-47-3 HR 3 CHROMIUM af: Cr aw: 52.00 PROP: Hard, ductile, blue-white metal. Resists oxidation in air. Bp: 26’ @ 2690 mm. More reactive to acids than Mo or W and can be rendered passive. Rapidly attacked by fused NaOH + KNo3 or KClO4. IDLH 250 mg/m3 (as Cr). SYNS: CHROME 0 CHROMIUM METAL (OSHA) CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,165,87; Animal Inadequate Evidence IMEMDT 23,205,80. Chromium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 1 mg/m3 ACGIH TLV: TWA 0.5 (Cr)mg/m3; Not Classifiable as a Carcinogen SAFETY PROFILE: Confirmed human carcinogen with experimental tumorigenic data. Powder will explode spontaneously in air. Igmtes and is potentially explosive in
CHROMIUM COMPOUNDS CMJSOO 363
atmospheres of carbon dloxide. Violent or explosive reaction when heated with ammonium nitrate. May ignite or react violently with bromine pentafluoride. Incandescent reaction with nitrogen oxide or sulfur dloxide. Incompatible with oxidants. See also CHROMIUM COMPOUNDS. CMJOOO CAS: 628-52-4 HR: 3 CHROMIUM ACETATE HYDRATE mf: C4H604*Cr*H20 mw: 188.12 PROP: Air-sensitive dark red crystals. Stable in air for short period. Sltly sol in HzO and EtOH; sol in hot Hz0. IDLH 250 mg/m3 [as O I . SYNS: ACETIC ACID, CHROMIUM (2+) SALT (8CI,9CI)
0 CHROMIUM(Z+) ACETATE 0 CHROMIUM(II) ACETATE 0 CHROMIUM DIACETATE 0 CHROMOUS ACETATE 0 CHROMOUS ACETATE MONOHYDRATE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Chromium and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.5 mg(Cr)/m3 ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not Classifiable as a Carcinogen SAFETY PROFILE: Mildly toxic by ingestion. The anhydrous acetate ignites spontaneously in air. See also CHROMIUM COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
CMJ100 CAS: 29689-14-3 CHROMIUM CARBONATE mf: CHaO3*xCr mw: 426.03
HR: 1
SYNS: BASIC CHROMIUM CARBONATE 0 CARBONIC ACID, CHROMIUM SALT CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: When heated to decomposition it emits toxic fumes of Cr.
CMJ250 CAS: 10025-73-7 HR: 3 CHROMIUM CHLORIDE mf: C4Cr mw: 158.35
PROP: Red-violet flaky crystals. Mp: 1152O, bp: 1300' (subl). Insol in cold HzO; sltly sol in hot HzO. IDLH 25 mg/m3 [as Cr(III)]. SYNS: CHROMIC CHLORIDE 0 CHROMIUM(I1I) CHLORIDE (1:3) 0 CHROMIUM CHLORIDE, anhydrous CHROMIUM TRICHLORIDE C.I. 77295 PURATRON-IC CHROMIUM CHLORIDE 0 TRICHLOROCHROMIUM CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 49,49,90; Human Inadequate Evidence IMEMDT 49,49,90; Animal Inadequate Evidence IMEMDT 49,49,90. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Chromium and its compounds are on the Community Right-To-Know Lst. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.5 mg(Cr)/m3 ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not Classifiable as a Carcinogen SAFETY PROFILE: Poison by skin contact, inhalation, and intraperitoneal routes. Experimental teratogenic and reproductive effects. Human mutation data reported. Questionable carcinogen. Reacts violently with lithium under nitrogen atmosphere. When heated to decomposition it emits toxic fumes of C1-.
CMJSOO HR: 3 CHROMIUM COMPOUNDS CONSENSUS REPORTS: Chromium and its compounds are on the Community Right-To-Know List. SAFETY PROFILE: Chromate salts are suspected human carcinogens producing tumors of the lungs, nasal cavity, and paranasal sinus. Chromic acid and its salts have a corrosive action on the skin and mucous membranes. The lesions are confined to the exposed parts, affecting chefly the s h n of the hands and forearms and the mucous membranes of the nasal septum. The characteristic lesion is a deep, penetrating ulcer, which, for the most part, does not tend to suppurate, and which is slow in heahng. Small ulcers, about the size of a matchhead, may be found, chefly around the base of the nails, on the
364 CMJ560 CHROMIUM(III) FLUORIDE knuckles, dorsum of the hands and forearms. These ulcers tend to be clean and progress slowly. They are frequently painless, even though quite deep. They heal slowly and leave scars. On the mucous membranes of the nasal septum, the ulcers are usually accompanied by purulent discharge and crusting. If exposure continues, perforation of the nasal septum may result but produces no deformity of the nose. Hexavalent compounds are more toxic than the trivalent. Eczematous dermatitis due to trivalent chromium compounds has been reported. CMJ560 CAS: 7788-97-8 HR: 3 CHROMIUM(III) FLUORIDE DOT: UN 1756/UN 1757 mf: CrF3 mw: 109.00 PROP: IDLH 25 mg/m3 [as Cr(III)]. SYNS: CHROhIE FLUORURE 0 CHROMIC FLUORIDE 0 CHROMIC FLUORIDE, sohd (UN1756) (DOT) 0 CHROMIC FLUORIDE, soluuon (UN1757) (DOT) 0 CHROhfIC TRIFLUORIDE 0 CHROMIUM TRIFLUORIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: 8H TWA 0.5 mg(Cr)/m3; TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 0.5 mg(Cr)/m3; TWA 2.5 mg(F)/m3 NIOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A poison by ingestion. A corrosive. When heated to decomposition it emits toxic vapors of Cr and F-. CMJ6OO CAS: 13548-38-4 HR: 3 CHR0MIUM(III) NITRATE DOT: UN 2720 mf: CrN309 mw: 238.03 PROP: Very deliquescent, pale green powder. Non-volaule. Sol in H20, EtOAc, MeCN, and DMSO; insol in C6H6, CC4, and CHCL. IDLH 25 mg/m3 [as Cr(lII)]. SYNS: CHROMIC NITRATE 0 CHROMIUM NITRATE 0 CHROMIUM (3+) NITRATE 0 CHROMIUM NITRATE (DOT) 0 CHROMIUM TRINITRATE 0 NITRIC ACID, CHROMIUhl (3+) SALT
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 49,49,90; Human Inadequate Evidence IMEMDT 49,49,90; Animal Inadequate Evidence IMEMDT 49,49,90. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.5 mg(Cr)/m3 ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not Classifiable as a Carcinogen DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by subcutaneous and ingestion routes. Mutation data reported. Questionable carcinogen. When heated to decomposition it emits toxic fumes of NO, and Cr.
CMJ9OO CAS: 1308-38-9 HR: 3 CHROMIUM(III) OXIDE (2:3) mf: CrzO3 mw: 152.00 PROP: Green crystals. Mp: 2275'. IDLH 25 mg/m3 [as Cr(III)]. SYNS: ANADOMIS GREEN 0 ANIDRIDE CROhlIQUE (FRENCH) 0 CASALIS GREEN 0 CHROME GREEN 0 CHROME OCHER 0 CHROME OXIDE 0 CHROME OXIDE GREEN 0 CHROMIA 0 CHROMIC ACID 0 CHROhlIC ACID GREEN 0 CHROMIC OXIDE CHROhfIUhl OXIDE 0 CHROMIUM(II1) OXIDE 0 CHROMIUM(3+) OXIDE 0 CHROMICM SESQUIOXIDE 0 CHROMUM(3+) TRIOXIDE 0 C.1 77288 0 C.I. No. 77278 0 C I PIGMENT GREEN 17 0 DICHROMICiM TRIOXIDE 0 11661 GREEN 0 GREEN CHROME OXIDE 0 GREEN CHROMIC OXIDE 0 GREEN CINNABAR 0 GREEN ROUGE 0 GUIGNERS GREEN 0 LEAF GREEN 0 LEVANOX GREEN GA 0 OIL GREEN 0 OXIDE of CHROMIUM 0 ULTRAMARINE GREEN
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 3 IMEMDT 7,165,87; Animal Inadequate Evidence IMEMDT 23,205,80. Reported in EPA TSCA Inventory. Chromium and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.5 mg(Cr)/m3 ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not Classifiable as a Carcinogen DFG MAK: Suspected Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. Mutation data reported. Probably a severe
CHROMIUM PHOSPHATE
eye, skin, and mucous membrane irritant. A powerful oxidzer. Reacts violently with CLF3. See also CHROMIUM COMPOUNDS. CMKOOO CAS: 1333-82-0 HR: 3 CHROMIUM(VI) OXIDE (1 :3) DOT: UN 1463/NA 1463/UN 1755 mf: Cr03 mw: 100.00 PROP: Dark orange-red, rhombic, deliquescent crystals. D: 2.70, mp: 190°, bp: decomp, sol: 61.7 g/100 cc @ Oo, 67.45 g/100 cc @ 100'. Very sol in H20; sol in HzS04 and org solvs. IDLH 15 mg/m3 {as Cr(VI) 1. SYNS: ANHYDRIDE CHROMIQUE (FRENCH) 0 ANIDRIDE CROMICA (ITALIAN) 0 CHROME (TRIOXYDE de) (FRENCH) 0 CHROMIC ACID 0 CHROMIC(VI)ACID 0 CHROMIC ACID, sohd (NA 1463) (DOT) 0 CHROMIC ACID, soluuon (UX 1755) (DOT) 0 CHROMIC ANHYDRIDE 0 CHROMIC TRIOXIDE 0 CHROMIUM OXIDE 0 CHROMIUM(VI) OXIDE 0 CHROMIUM TRIOXIDE 0 CHROMIUM(6+)TRIOXIDE 0 CHROMIUM TRIOXIDE, anhydrous (DOT) 0 CHROhlIUM TRIOXIDE, anhydrous (L" 1463) (DOT) 0 CHROMO (TRIOSSIDO &) (ITALIAN) 0 CHROMSAEURErWHYDRID (GERMAN) 0 CHROMTRIOXID (GERMAN) 0 CHROOMTRIOXYDE (DUTCH) 0 CHROOMZUUROJHYDRIDE (DUTCH) 0 MONOCHROMIUM OXIDE C MONOCHROMIUM TRIOXIDE 5 PURATRONIC CHROMIUM TRIOXIDE
CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 7,165,87; Animal Sufficient Evidence IMEMDT 23,205,80. EPA Genetic Toxicology Program. Chromium and its compounds are on the Community kght-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: CL 0.1 mg(Cr03)/m3 ACGIH TLV: TWA 0.05 mg(Cr)/m'; Confirmed Human Carcinogen DFG MAK: 0.1 mg/m3, Suspected Carcinogen NlOSH REL: (Chromium(VI)) TWA 0.025 mg(Cr(VI))/m3; CL 0.05/15M DOT CLASSIFICATION: 5.1; Label: Oxiduer, Corrosive (NA 1463, UN 1463); DOT Class: 8; Label: Corrosive (UN 1755) SAFETY PROFILE: Confirmed human carcinogen producing nasal and lung
CMK300 365
tumors. Experimental carcinogenic and tumorigenic data. Poison by ingestion, intraperitoneal, and subcutaneous routes. Experimental teratogenic and reproductive effects. Human mutation data reported. Corrosive. Probably a severe eye, slim, and mucous membrane irritant. See also CHROMIUM COMPOUNDS. A powerful oxidzer. Explosive reaction with acetaldehyde, acetic acid + heat, acetic anhydride + heat, benzaldehyde, benzene, benzylthyladne, butyraldehyde, 1,3dimethylhexahydropyrimidone, dethyl ether, ethylacetate, isopropylacetate, methyl dioxane, pelargonic acid, pentyl acetate, phosphorus + heat, propionaldehyde, and other organic materials or solvents. Forms a friction- and heat-sensitive explosive mixture with potassium hexacyanoferrate. Ignites on contact with alcohols, acetic anhydride + tetrahydronaphthalene, acetone, butanol, chromium(I1) sulfide, cyclohexanol, dimethyl formamide, ethanol, ethylene glycol, methanol, 2-propanol, pyridme. Violent reaction with acetic anhydride + 3-methylphenol (above 75"C), acetylene, bromine pentafluoride, glycerol, hexamethylphosphoramide,peroxyformic acid, selenium, sodium amide. Incandescent reaction with alkali metals (e.g., sodmm, potassium), ammonia, arsenic, butyric acid (above lOO'C), chlorine trifluoride, hydrogen sulfide + heat, sodium + heat, and sulfur. Incompatible with N,Ndimethylformamide. CMK3OO CAS: 7789-04-0 HR: 1 CHROMIUM PHOSPHATE mf: Cr*H304P mw: 150.00 SYNS: ARNAUDON'S GREEN 0 ARNAUDON'S GREEX (HEhiIHEPTAHYDRATE) 0 CHROMIC PHOSPHATE 0 CHROMIUM MONOPHOSPHATE 0 CHROMIUM ORTHOPHOSPHATE 0 PHOSPHORIC ACID CHROhllUM 011) SALT 0 PHOSPHORIC ACID, CHROMIUM(3+) SALT (1:l) 0 PLESSY'S GREEN (HEMIHEPTAHYDRATE)
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 49,49,90; Human Inadequate Evidence IMEMDT
366
CMK400
CHROMIUM POTASSIUM ZINC OXIDE
49,49,90; IARC Cancer Review: Animal Inadequate Evidence IMEMDT 49,49,90. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.5 mg(Cr)/m3 ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not Classifiable as a Carcinogen SAFETY PROFILE: When heated to decomposition it emits toxic fumes of PO, and Cr.
CMK400 CAS: 37224-57-0 HR: 2 CHROMIUM POTASSIUM ZINC OXIDE SYNS: POTASSIUhi ZINC CHROMATE 0 ZINC POTASSIUM CHROMATE CONSENSUS REPORTS: IARC Cancer Review: Human Sufficient Evidence IMEMDT 23,205,80; Animal Sufficient Evidence IMEMDT 2,100,73. Chromium and its compounds, as well as zinc and its compounds, are on the Community kghtTo-Know List. OSHA PEL: CL 0.1 mg(CrOs)/m3 ACGIH TLV: TWA 0.01 mg(Cr)/m3; Confirmed Human Carcinogen DFG MAK: Human Carcinogen NIOSH REL: (Chromium (VI)) TWA 0,001 mg(Cr(VI))/m3 SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. When heated to decomposition it emits toxic fumes of Cr- and Zn-.
CMK425 CAS: 10031-37-5 HR: 3 CHROMIUM SULFATE, PENTADECAHYDRATE mf: 0&*2Cr*15HzO mw: 662.38 SYNS: SULFURIC ACID,CHROhfIUM(3+) SALT (3:2), PENTADECAHYDRATE 0 WOOL MORDANT ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not
Classifiable as a Carcinogen SAFETY PROFILE: Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of SO, and Cr.
CMKBOO CAS: 15930-94-6 HR: 3 CHROMIUM(6+)ZINC OXIDE HYDRATE (1 :2:6:1) mf: Cr04*H20z*Zn~*H20 mw: 298.78
SYNS: BL'ITERCUP YELLOW' 0 CHROMIC ACID, ZINC SALT (1:2) 0 ZINC CHROMATE HYDROXIDE 0 ZINC CHROiLWTE(V1) HYDROXIDE 0 ZINC HYDROXYCHROMATE 0 ZINC YELLOW' CONSENSUS REPORTS: IARC Cancer Review: Human Sufficient Evidence IMEMDT 23,205,80; Animal Sufficient Evidence IMEMDT 2,100,73. Chromium and its compounds, as well as zinc and its compounds, are on the Community RightTo-Ihow List. OSHA PEL: CL 0.1 mg(Cr03)/m3 ACGIH TLV: TWA 0.01 mg(Cr)/m3; Confirmed Human Carcinogen DFG MAK: Human Carcinogen NIOSH REL: (Chromium (VI)) TWA 0.001 mg(CrO)/m3 SAFETY PROFILE: Confirmed human carcinogen. Mutation data reported. When heated to decomposition it emits toxic fumes of ZnO. See also CHROMIUM and ZINC COMPOUNDS.
CML125 CAS: 14977-61-8 HR: 3 CHROMYL CHLORIDE DOT: UN 1758 mf: C12Cr02 mw: 154.90 PROP: Dark-red Liquid; yellow-red vapor; musty burning odor. Readily hydro1 to HC1 and Cr03. Fumes in air. Sol in org solvs and inorganic acid halides. Mp: -96.5', bp: 115.7', d: 1.9145 @ 25'/4', vap press: 20 mm @ 20'. IDLH Ca [15 mg/m3 {as Cr(V1))I.
SYNS: CHLORURE de CHROMYLE (FRENCH) 0 CHROMIC OXYCHLORIDE 0 CHROMIUhI CHLORIDE OXIDE 0 CHROMIUhl DICHLORIDE DIOXIDE 0 CHROhfIUhl DIOXIDE DICHLORIDE 0 CHRORiIUhl(V1) DIOXYCHLORIDE 0 CHROMIUM OXYCHLORIDE 0 CHROMOXYCHLORID (GERMAN) 0 CHROhlYLCHLORID (GERMAN) CHROOMOXYLCHLORIDE @ETCH) CROhiILE, CLORURO di (ITALIAN) 0 CROMO, OSSICLORURO d~(ITALIAN) DICHLORODIOXOCHROMIUM 0 DIOXODICHLOROCHROMIUhl 0 OXYCHLOKURE CHROhIIQUE (FRENCH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Chromium and its compounds are on the Community RghtTo-Know List. OSHA PEL: TWA 0.5 mg(Cr)/m3
C.I. ACID RED 114, DISODIUM SALT ACGIH TLV: TWA 0.025 ppm DFG MAK: Suspected Carcinogen NIOSH REL: (Chromium(VI)) TWA 0.001
mg(Cr(VI))/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Suspected carcinogen.
Probably a poison by various routes. Mutation data reported. Corrosive. A strong irritant. Hydrolyzes to form chromic and hydrochloric acids. A strong oxidner and chlorinating agent. Violent reaction with water. Reacts violently with alcohol, ether, acetone, turpentine. Ignites or explodes on contact with nonmetal halides (e.g., disulfur dichloride, phosphorus trichloride, and phosphorus tribromide), nonmetal hydrides (e.g., hydrogen sulfide and hydrogen phosphide), flowers of sulfur, moist phosphorus, sodium azide, and urea. During preparation can violently explode. Incompatible with ammonia, &sulfur dichloride, organic solvents, phosphorus, phosphorus trichloride, so&um azide, and sulfur. When heated to decomposition it emits toxic fumes of C1-. See also CHROMIUM COMPOUNDS. CML810 CAS: 218-01-9 HR: 3 CHRYSENE mf: C18H12 mw: 228.30 PROP: Plates from C6H6 or AcOH with reddish-violet fluorescence. Occurs in coal tar. Is formed during distillation of coal, in very small amount during dsullation or pyrolysis of many fats and oils. Orthorhombic bipyramidal plates from benzene. D: 1.274, mp: 255-256'. Sublimes easily in vacuum, bp: 448'. Sltly sol in alc, ether, carbon disulfide, and glacial acetic acid; moderately sol in boding benzene; insol in water. Chrysene is generally only sltly sol in cold org solvs, but fairly sol in these solvents when hot, includmg glacial acetic acid. SYNS: BENZO(a)PHENANTHRENE 0 1,Z-BENZOPHENAVTHRENE 0 BENZ(a)PHENANTHRENE 0 1,ZBENZPHENANTHRENE 0 1,2,5,6-DIBENZONAPHTHALENE 0 RCRA WASTE NUMBER U050
CMM330 367
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal hmited Evidence IMEMDT 32,247,83; Human No Adequate Data IMEMDT 32,247,83. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. OSHA PEL: 0.2 mg/m3 ACGIH TLV: Animal Carcinogen DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Chrysene) To be controlled as a carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data by skin contact. Human mutation data reported. When heated to decomposition it emits acrid smoke and fumes.
E
CMM330 CAS: 6459-94-5 HR: 3 C.I. ACID RED 114, DlSODlUM SALT mf: C37H28N4010S3*2Na mw: 830.85 SYNS: ACID LEATHERRED BG 0 ACID RED 114 0 AiMrZCID MILLING RED PRS 0 BENZYL FAST RED BG 0 BENZYL RED BR 0 CERVEN K Y S E U 114 0 C.I. 23635 0 C.I. ACID RED 114 0 ELCACID MILLING FAST RED RS 0 ERIONYL RED RS 0 FENAFOR RED PB 0 FOLAN RED B 0 INTRAZONE RED BR 0 KAYANOL hfILLIKG RED RS 0 LEATHER FAST RED B 0 LEVANOL RED GG 0 MIDLON RED PRS 0 MILLING FAST RED B 0 MILLING RED B 0 MILLING RED BB 0 MILLING RED SWB 0 1,3-NAPHTHALENEDISULFONIC ACID, 8-((3,3'-
DIMETHYL-4'-((4-(((4-METHYLPHENYL)SULFONYL)OXY) PHENYL)AZO)(l,l'-BIPHENYL)-4-\Z)AZO)-7HYDROXI-, DISODIUM SALT 0 NCI C61096 0 P O U R RED RS 0 SANDOLAN RED N-RS 0 SELLA FAST RED RS 0 SULPHONOL FAST RED R 0 SULPHONOL RED R 0 SUMINOL MILLING RED Rs 0 SUPRANOL FAST RED 3G 0 SUPRAXOL FAST RED GG 0 SUPRANOL RED PBX-CF 0 SUPRAiNOL RED R 0 TELON FAST RED G G 0 TETRACID MILLING RED B 0 TETRACID MILLING RED G 0 VONDAMOL FAST RED RS
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 57,247,93; Animal Sufficient Evidence IMEMDT 57,247,93; Human Inadequate Evidence IMEMDT 57,247,93. NTP Carcinogenesis Studies (drinhng); Clear Evidence: rat NTlTR* NTP-TR-405,91. Reported in EPA TSCA Inventory.
368
CMN750
C.I. DIRECT BLUE 1, TETRASODIUM SALT
SAFETY PROFILE: Confirmed carcinogen
with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic vapors of NO, and SO,.
CMN750 CAS: 2610-05-1 HR: D C.I. DIRECT BLUE 1, TETRASODIUM SALT mf: C34H2&0&*4Na mw: 996.88 SYNS: AIREDALE BLUE FFD 0 AMANIL SKY BLUE 6B 0 ATLhhjTIC RESIN FAST BLUE c1 BELhhlINE SKY BLUE FF 0 CALCODUR RESIN F24STBLUE 0 CHICAGO BLUE 6B 0 CHLORAZOL SKY BLUE FF 0 CHROME LEATHER SKY BLUE 0 C.I. 24410 0 C.I. DIRECT BLUE 1 0 DIACOTTON SKY BLUE 6B 0 DIPHENYL BRILLIANT BLUE FF 0 DIRECT BRILLIANT BLUE FF 0 ENWNIL BRILLIANT BLUE FF FENAMIN SKY BLUE 3F 0 HISPAMIN SKY BLUE 6B 0 KAYAKC DIRECT SKY BLUE 6B 0 LUhfICREASE BLUE 4GL 0 NAPHTAMINE SKY BLUE DD N C I - C ~ I I O ~PONTAMINE SKY BLUE PyRhZOL FAST BRILLIAiiT BLUE W 0 SHIKISO DIRECT SKY BLUE 6B 0 TERTRODIRECT BLUE FF 0 VONDACEL BLUE FF
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An experimental
teratogen. Other experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO,, Na20, and SO,.
CMOOOO CAS: 2602-46-2 HR: 3 C.I. DIRECT BLUE 6, TETRASODIUM SALT mf: C ~ ~ H ~ O N ~ O I ~ Smw: P ~932.78 N~ PROP: A dye. SYNS: AIREDALE BLUE 2BD 0 AIZEN DIRECT BLUE 2BH 0 MiANIL BLCE 2BX 0 ATLANTIC BLUE 2B 0 ATUL DIRECT BLUE 2B 0 AZOCARD BLUE 2B 0 AZOhlINE BLUE 2B 0 BELAMINE BLUE 2B 0 BENCIDAL BLUE 2B 0 BENZANIL BLUE 2B 0 BENZO BLCE GS 0 BLUE 2B 0 BRASILAMINA BLUE 2B 0 CALCOMINE BLUE 2B 0 CHLORAMINE BLUE 2B 0 CHLORAZOL BLUE B 0 CHROME LEATHER BLUE 2B 0 C.1 22610 0 CRESOTINE BLUE 2B 0 DIACO?TON BLUE BB 0 DWMINE BLUE 2B 0 DIAPHTAhIINE BLUE BB 0 DIAZINE BLUE 2B 0 DIAZOL BLUE 2B 0 DIPHENYL BLCE 2B 0 DIRECT BLUE 6 0 ENLWIL BLUE 2BN 0 FENAMIN BLUE 2B 0 FIXANOL BLUE 2B 0 HISPAMIN BLUE 2B INDIGO BLUE 2B 0 KAYAKU DIRECT 0 MITSUI DIRECT BLUE 2BN 0 NAPHTAMINE
BLUE 2B 0 NB2B 0 NCI-C54579 0 NIAGARA BLUE 2B 0 NIPPON BLUE BB 0 PARAMINE BLUE 2B 0 PHENAMINE BLUE BB 0 PHENO BLUE 2B 0 PONTAMINE BLUE BB 0 SODIUM DIPHE~YL4,4'-BIS-AZO-2"-8"hVINO-l"-NAPHTHOL-3",6 " DISULPHONATE 0 TERTRODIRECT BLUE 2B 0 VONDACEL BLUE 2B
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Animal Sufficient Evidence IMEMDT 29,311,82; Human Inadequate Evidence IMEMDT 29,311,82. NCI Carcinogenesis Bioassay (feed); Clear Evidence: rat NCITR* NCI-CG-TR-108,78; No Evidence: mouse NCITR* NCI-CG-TR-108,78. Reported in EPA TSCA Inventory. Community RightTo-Know List. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO,, Na20, and SO,.
CM0250 CAS: 72-57-1 HR: 3 C.I. DIRECT BLUE 14, TETRASODIUM SALT mf: C34H28N601.&*4Na mw: 964.88 PROP: Dark blue crystals or powder. Sol in H20 and acids. SYNS: AMANIL SKY BLUE 0 &MIDINE BLUE 4B 0 AZIDINE BLUE 3B 0 AZZURRO DIRETTO 3B 0 BENCIDAL BLUE 3B 0 BENZAMINE BLUE BENLO BLUE BLEU DIAMINE BLUE EMB n BRASILAMINA BLUE 3B 0 CENTRALINE BLUE 3B 0 CHLORAMINE BLUE 0 CHLORAZOL BLUE 3B CHROiME LEATHER BLUE 3B 0 C.I. 23850 0 C.I. DIRECT BLUE 14 0 C O N G O B U U 3B 0 CONGO BLUE 0 CRESOTINE BLUE 3B DILVINE BLUE 3B 0 DIhiUILBJAU 0 D I A " BLUE 0 DIAZINE BLUE 3B 0 DIPHENYL BLUE 3B 0 DIRECT BLUE 14 0 HISPAMIN BLC'E 3BX 0 NAPHTAMINE BLUE 2B 0 NAPHTHYLAMINE BLUE 0 NCIK61289 0 NIAGARA BLUE 0 ORION BLUE 3B 0 PARAMINE BLUE 3B 0 PARKIBLEU 0 PARKIPAN 0 PONTAMINE BLUE 3BX 0 PYRAZOL BLUE 3B 0 PYROTROPBLAU 0 RCRA WASTE NUMBER U236 0 RENOLBLAC 3B 0 SODIUM DITOLYLDIAZOBIS-8-AINO-1-NAPHTHOL-3,6DISULFONATE 0 SODIUM DITOLYLDIAZOBIS-8AMINO-I-NAPHTHOL-3,G-DISC'LPHONATE 0 TB 0 TRIANOL DIRECT BLUE 3B TRIPAN BLUE 0
CIGARETTE REFINED TAR TRWANBLAU (GERAWV) 0 TRYPAIU BLUE 0 TRYPAN BLUE SODIUM SALT
CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 8,267,75. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal, intravenous, and subcutaneous routes. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO,, NazO, and SO,.
CM0500 CAS: 2429-74-5 HR: 3 C.I. DIRECT BLUE 15, TETRASODIUM SALT mf: C34H28N6016S4*4Na mw: 996.88 SYNS: AIREDALE BLUE D 0 AIZEN DIRECT SKY BLUE 5BH 0 AMANIL SKY BLUE 0 ATLANTIC SKY BLUE A 0 ATUL DIRECT SKY BLUE 0 AZINE SKY BLUE 5B 0 BELAhfINE SKY BLUE A 0 BENZANIL SKY BLUE 0 BENZO SKY BLUE S 0 BENZO SKY BLUE A-CF 0 C H L O W I I N E SKY BLUE A 0 CHLORAhlINE SKY BLUE 4B 0 CHROME LEATHER PURE BLUE 0 C.I. 24400 0 C.I. DIRECT BLUE 15 0 CRESOTINE PURE BLUE 0 DIACOTTON SKY BLUE 5B 0 DIA,MINE SKY BLUE CI 0 DIAPHTrZlMINEPURE BLUE 0 DIAZOL PURE BLUE 4B 0 DIPHENYL BRILLIANT BLUE 0 DIPHENYL SKY BLUE 6B 0 DIRECT BLUE 10G 0 DIRECT BLUE 15 0 DIRECT BLUE H H 0 DIRECT PURE BLUE 0 DIRECT PURE BLUE M 0 DIRECT SKY BLUE A 0 ENIANIL PURE BLUE AN 0 FENAMIN SKY BLUE 0 HISPAMIN SKY BLUE 3B 0 KAYAKU DIRECT SKY BLUE 5B 0 MITSUI DIRECT SKY BLUE 5B 0 MODR PRIMA 15 NAPHTAMINE BLUE 10G 0 NCI C61290 0 NIAGARA BLUE 4B 0 NIAGARA SKY BLUE 0 NIPPON DIRECT SKY BLUE 0 N I P 0 DIRECT SKY BLUE 5B 0 PHENAMINE SKY BLUE A 0 PONTAMINE SKY BLUE 5BX 0 PONTACYL SKY BLUE 4BX 0 SHIKISO DIRECT SKY BLUE 5B 0 SKY BLUE 4B 0 SKY BLUE 5B 0 TERTRODIRECT BLUE F 0 VONDACEL BLUE H H CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 57,235,93; Animal Sufficient Evidence IMEMDT 57,235,93; Human Inadequate Evidence IMEMDT 57,235,93. Reported in EPA TSCA Inventory.
CMP800 369
SAFETY PROFILE: A confirmed
carcinogen with experimental carcinogenic data reported. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO,, NazO, and SO,.
CM0750 CAS: 16071-86-6 HR: 3 C.I. DIRECT BROWN mf: C ~ I H ~ O N ~ O ~ S * C Umw: * ~ N762.15 ~ SYNS: AIZEN PRIMULA BROWN BRLH 0 AMANIL SUPRA BROWN LBL 0 ATLANTIC RESIN FAST BROWN BRL 0 BENZAMIL SUPRA BROWN BRLL 0 CALCODUR BROWK BRL 0 CHLORAMINE FAST BROWW BRL 0 CHROME LEATHERBROWN BRLL 0 C.1.30145 0 DERMA FAST BROWN W-GL 0 DIPHENYL FAST BROWN BRL 0 DIRECT BROWN 95 0 NCI-C54568 0 SATURN BROWN LBR 0 SOLAR BROWN PL 0 TETRAMINE EAST BROWN BRS CONSENSUS REPORTS: IARC Cancer Review: Animal Limited Evidence IMEMDT 29,321,82; Human Lmited Evidence IMEMDT 29,321,82; NCI Carcinogenesis Bioassay (feed); Clear Evidence: rat NCITR* NCI-CG-TR-108,78; No Evidence: mouse NCITR" NCI-CGTR-108,78. Reported in EPA TSCA Inventory. Community Right-To-Know Llst. SAFETY PROFILE: Low toxicity by ingestion. Suspected carcinogen with experimental carcinogenic and neoplastigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of Na20, SO,, and NO,.
CMP800 CIGARETTE REFINED TAR
HR: 3
SYNS: CIGARETTE TAR 0 COLOMBIAN BLACK TOBACCO CIGARETTE REFINED TAR 0 TAR, from tobacco 0 TOBACCO REFINED TAR 0 TOBACCO TAR 0 US. BLENDED LIGHT TOBACCO CIGARETTE REFINED TAR DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROF ILE: Suspected carcinogen with experimental carcinogenic data. Experimental reproductive effects. Mutation
E
370
CMP969
CINNAMALDEHYDE
data reported. See also TOBACCO and NICOTINE. CMP969 CAS: 104-55-2 HR: 3 CINNAMALDEHYDE mf: C9H80 mw: 132.17 PROP: Found in Ceylon and Chmese cinnamon oils. Yellowish, oily liquid; strong odor of cinnamon. D: 1.048-1.052, mp: -7.5', bp: 246.0' (some decomp), d: 1.048-1.052 @ 25'/25", refr index: 1.619-1.623, flash p: 248'F. Very sltly sol in water; misc with alc, ether, chloroform, fixed oils. SYNS: BENZYLIDESEACETALDEHYDE 0 CASSIA ALDEHYDE 0 CINNAMAL 0 CINNAMYL ALDEHYDE 0 CINNIMIC ALDEHYDE 0 FElMA No. 2286 0 NCIC56111 0 PHENYLACROLEIN 0 3-PHENYLACROLEIN 0 3-PHENYLPROPENAL 0 3-PHENYL-2-PROPENAL 0 ZIBITALDEHYDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous
and parenteral routes. Moderately toxic by ingestion and intraperitoneal routes. A severe human skin irritant. Mutation data reported. Combustible liquid. May i p t e after a delay period in contact with NaOH. When heated to decomposition it emits acrid smoke and fumes. See also ALDEHYDES.
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and fumes.
CMQSlO CAS: 8015-91-6 HR: 2 CINNAMON LEAF OIL PROP: Extracted by steam &stillation of leaves from Cinnamomum wlanicum Nees. Light to dark brown liquid; spicy cinnamon, clove odor and taste. Sol in fixed oils, propylene glycol, mineral oil; insol in glycerin. SYNS: CEYLON CINNAhfON BARK OIL 0 CEYLONZIMT OEL 0 CIKNAMON LEAF OIL, CEYLON 0 CINNAMON OIL, CEYLON 0 OIL OF CINNAMON, CEYLON
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Low toxicity by skin contact. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
CMQ730 CAS: 103-54-8 HR: 2 CINNAMYL ACETATE mf: CllH1202 mw: 176.23 PROP: Colorless liquid; sweet floral odor. D: 1.047-1.051, refr index: 1.539-1.543, flash p: 244'F. Misc with chloroform, ether, fixed oils; insol in glycerin, water @ 264'. SYNS: ACETIC ACID, CINNAhWL ESTER 0 FEMh No.
CMP975 CAS: 621-82-9 HR: 3 ClNNAMlC ACID mf: C9H802 mw: 148.17 PROP: Occurs free and partly esterified in storax, balsam Peru or Tolu, oil of cinnamon, coca leaves. White monoclinic crystals; honey floral odor. D: (4'/4') 1.2475, mp: 133', bp: 300°, flash p: 212°F. One gram dissolves in about 2000 mL water at 25' (more sol in hot water), in 6 mL alc, 5 mL methanol, 12 mL chloroform. Freely sol in benzene, ether, acetone, glacial acetic acid, carbon disulfide, fured oils. SYNS: FEAM No 2288 0 PHENYLACRYLIC ACID 0
TSCA Inventory.
tert-P-PHENYLACRYLIC ACID 0 3-PHENYLACRYLIC ACID 0 3-PHENYLPROPENOIC ACID 0 3-PHENYL-2I'ROPENOIC ACID 0 ZIMTSAEURE (GERMAN)
CMQ740 CAS: 104-54-1 CINNAMYL ALCOHOL mf: C9HloO mw: 134.19
2293 0 y-PHENYLALLYL ACETATE 0 3-PHENYL-2PROPEN-1-YL ACETATE
CONSENSUS REPORTS: Reported in EPA SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. A skm irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and fumes. See also ALLYL COMPOUNDS.
HR: 2
C.I. SOLVENT RED PROP: Occurs (in the esterified form) in
storax and in balsam Peru, cinnamon leaves, hyacinth oil. Needles or crystalline mass; odor of hyacinth. Mp: 33', d: 1.0397, bp: 250.0', n: (20/D) 1.58190. Sol in water, glycerol, and propylene glycol; freely sol in alc, ether, other common org solvs. SYNS: CINNAMIC ALCOHOL 0 CINNAMYL ALCOHOL, SYNTHETIC 0 FEMA No. 2294 0 'yPHENYLALLYL ALCOHOL 0 3-PHENYLALLYL ALCOHOL 0 3-PHENYL-2-PROPEN-1-OL 0 STYROSE 0 STYRYL CARBINOL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A s h n irritant. Mutation data reported. When heated to decomposition it emits acrid smoke and fumes. See also ALCOHOLS and ALLYL COMPOUNDS.
CMQ800 CAS: 103-61-7 CINNAMYL BUTYRATE mf: C13H1602 mw: 204.29
HR: 1
SYNS: BUTYNOIC ACID, 3-PHENYL-2-PROPENYL ESTER 0 BUTYRIC ACID, CINNAMYL ESTER 0 PHENYLPROPESYL n-BUTYRATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A skin irritant. When
heated to decomposition it emits acrid smoke and irritating fumes. CMR500 CAS: 104-65-4 HR: 2 CINNAMYL FORMATE mf: C10H1002 mw: 162.20 PROP: Colorless liquid; balsamic odor. D: 1.077-1.082, refr index: 1.550-1.556, flash p: 212°F. Misc with alc, chloroform, ether, fixed oils; insol in water @ 250'. SYNS: CINNAMYL ALCOHOL, FORMATE 0 CINNAVYL hiETHANOATE 0 FEhlA KO.2299 0 FORMIC ACID, CIXXAMYL ESTER 0 3-PHEXYL-2PROPEN-1-YL FORMATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. See also ESTERS. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
CMS238 371
CMR800 HR: 2 CINNAMYL SOVALERATE mf: C14H1802 mw: 218.30 PROP: Colorless to sltly yellow liquid; spicy, floral, fruity odor. D: 0.991-0.996, refr index: 1.518-1.524, flash p: 212°F. Misc in alc, chloroform, ether, most oils; insol in glycerin, propylene glycol, and water @ 313". SYN: FEW,
No. 2302
SAFETY PROFILE: Combustible liquid.
When heated to decomposition it emits acrid smoke and irritating fumes. CMR850 CAS: 103-56-0 HR: 2 CINNAMYL PROPIONATE mf: C12H1402 mw: 190.24 PROP: Colorless to pale-yellow liquid; spicy, fruity, balsamic odor. D: 1.029-1.033, refr index: 1.523-1.537, flash p: 212'F. MISCin alc, chloroform, ether, most oils; insol in glycerin, propylene glycol, and water @ 289'. SYNS: FESLA No. 2301 0 3-PHENYL-2-PROPENYL PROPIONATE 0 3-PHENK-2-PROPEN-1 -YL PROPIONATE 0 PROPIONIC ACID, CINNAMYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
CMS212 CAS: 62865-26-3 C.I. PIGMENT YELLOW 35
HR: 3
SYNS: B-3-Zh 0 CADMIUM GOLDEN CADMIUM LEMON 0 CADMIUM PRIMROSE 0 CADMIUM SULFIDE rmxed wth ZINC SULFIDE (1:l) 0 C.I. 77205
OSHA PEL: TWA 5 kg(Cd)/m3 ACGIH TLV: TWA 0.01 mg(Cd)/m3;
Suspected Carcinogen NIOSH REL: (Cadmium) TWA reduce to lowest feasible level SAFETY PROFILE: Confirmed human carcinogen. When heated to decomposition it emits toxic fumes of Cd. CMS238 CAS: 1229-55-6 C.I. SOLVENT RED
HR: 1
E
372
CMS324
mf: C17H14N202
ClTRAL ETHYLENE GLYCOL ACETAL
mw: 278.33
SYNS: BRILLIANT FAT SCARLET R 0
CERES RED G 0 CERES RED G 102 0 C.I. 12150 0 C I FOOD RED 16 0 C RED 2 0 FAT RED BG 0 FAT RED G 0 FAT RED RS 0 FAT SOLUBLE RED S 0 FOOD RED 16 LACQUER RED V 2G 0 2-NAPHTWLENOL, L((2-METHOXYPHENYL)AZO)-(9CI) 0 OIL PINK 0 OIL RED 0 OIL RED 113 0 OIL RED O G 0 OIL SCARLET 389 0 OIL SOLUBLE RED S 0 OIL VERMILION 0 OIL VERMILION LP 0 OLEAL RED G 0 ORGANOL VERMILION 0 ORIENT OIL RED O G 0 PLASTORESIN RED FR 0 RESINOL RED G 0 SIC0 FAT RED BG NEW 0 SILOTRAS RED T G 0 SOLVENT RED 1 0 SOMALIA RED PG 0 SUDAS R 0 SUDAN RED 290 0 SUDAV RED G (6CI)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An eye irritant. When
heated to decomposition it emits toxic fumes of NO,. CMS324 CAS: 66408-78-4 HR: 1 CITRAL ETHYLENE GLYCOL ACETAL mf: C12H2002 mw: 196.32 SYNS: CITRACETAL 0 1,3-DIOXOLANE, 2-(2,6DIMETHYL-1 ,j-HEPTADIENYL)CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
CMS750 CAS: 77-92-9 HR: 3 CITRIC ACID mf: C~H807 mw: 192.14 PROP: Colorless, odorless crystals (crystals are monoclinic holohedra and crystallize from hot conc aq soh); acid taste. Mp: 135' (monohydrate), mp: 153' (anhydrous), bp: decomp, d: 1.665, flash p: 212'F. Very sol in H20 and EtOH; mod sol in Et2O. SYNS: ACILETTEN 0 CITRETTEN 0 CITRIC ACID, anhydrous 0 CITRO 0 FEhW No. 2306 0 2-HYDROXY1,2,3-PROPANETRICARBOXYLIC ACID 0 pHYDROXYTRICARBALLYLIC ACID 0 KYSELINA CITRONOVA (CZECH) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory.
ingestion. A severe eye and moderate s h n irritant. An irritating organic acid, some allergenic properties. Combustible liquid. Potentially explosive reaction with metal nitrates. When heated to decomposition it emits acrid smoke and fumes. CMS845 CAS: 106-23-0 HR: 2 CITRONELLAL mf: C10H180 mw: 154.25 PROP: Colorless to sltly yellow liquid; intense lemon-citronella-rose odor. D: 0.850-0.860, refr index: 1.446-1.456, flash p: 170'F. Sol in alc, most oils; sltly sol in propylene glycol; insol in glycerin and water. SYNS: 3,7-DIMETHYL-G-OCTENAL 0 FEMA No. 2307 SAFETY PROFILE: Combustible liquid.
When heated to decomposition it emits acrid smoke and irritating fumes. CMS850 CAS: 107-75-5 HR: 1 CITRONELLAL HYDRATE mf: C10H2002 mw: 172.30 PROP: Colorless liquid; sweet, floral, My odor. D: 0.91 8-0.923, refr index: 1.447-1.450, flash p: 212'F. Sol in fixed oils and propylene glycol; insol in glycerin. SYNS: CYCLALIA 0 CYCLOSIA 0 3,7-DIhfETHYL-7HYDROXYOCTANAL 0 FEMA No. 2583 0 FIXOL 0 HYDROXYCITRONELLAL (FCC) 0 7-HYDROXYCITROKELLAL 0 7-HMROXY-3,7-DISlETHYL OCTANAL 0 7-HYDROXY-3,7-DIblETHYL0CT24N-1-AL LAURINE L I L ~ A ~ E H MUSUET ~ E SYNTHETIC 0 MCSUETTINE PRINCIPLE 0 PHIXIrl CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A s h n irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.
CMTOSO CAS: 2436-90-0 HR: 1 CITRONELLENE mf: C1oH18 mw: 138.28 PROP: Bp: 154-155', d: 0.757 @ 20'/4'.
s:
SAFETY PROFILE: Poison by intravenous
SYN DIHYDROMYRCENE 0 3,7-DI5fETH\ZZ-1,6OCTADIEKE 0 1,6-OCT14DIENE, 3,7-DIMETHYL-
route. Moderately toxic by subcutaneous and intraperitoneal routes. Mildly toxic by
TSCA Inventory.
CONSENSUS REPORTS: Reported in EPA
CITRONELLYL PROPIONATE SAFETY PROFILE: A skin irritant. When
heated to decomposition it emits acrid smoke and irritating fumes. CMT250 CAS: 106-22-9 HR: 3 CITRONELLOL mf: CloHzoO mw: 156.30 PROP: Colorless oily liquid; rose odor. D: 0.850-0.860, refr index: 1.454-1.462, flash p: 215'F. Sol in fixed oils, propylene gl~7~0l; sltly sol in water; insol in glycerin @ 225'. SYNS: CEPHROL 0 2,6-DIhlETHYL-2-OCTEN'-8-OL 0 3,7-DIMETHYL-6-OCTEN-l-OL 0 FELL4 No. 2309 0 FEhM No. 2980 0 RHODINOL 0 RODINOL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Moderately toxic by ingestion, s h n contact, and intramuscular routes. A severe skin irritant. A combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALCOHOLS.
CMUlOO 373
0 FORMIC ACID, CITROKELLYL ESTER 0 FORMIC
ACID-3,7-DIMETHYL-G-OCTEN-l -YL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion. A human skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS and FORMIC ACID.
CMTSOO HR: 2 CITRONELLYL ISOBUTYRATE mf: C14H2602 mw: 226.36 PROP: Colorless liquid; rosy-fruity odor. D: 0.870-0.880, refr index: 1.440-1.448, flash p: 212'F. Wsc in alc, chloroform, ether, most oils; insol in water @ 249'. SYNs: 3,7-DISIETHYLhOCTEN-l-YL ISOBUTYRATE 0 FEMr\ No. 2313
SAFETY PROFILE: Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
CMUOSO CAS: 139-70-8 HR: 1 CITRONELLYL PHENYLACETATE mf: C18H2602 mw: 274.44
CMT6OO HR: 2 CITRONELLYL BUTYRATE mf: C14H2602 mw: 226.36 PROP: Colorless liquid; strong, fruity-rosy odor. D: 0.873-0.883, refr index: 1.444-1.448, flash p: 212'F. Misc in alc, ether, chloroform, most oils; insol in water @ 245'.
TSCA Inventory.
SYNS: 3.7-DI~~ETHYL-6-OCTEN-1-nBUTYRATE
SAFETY PROFILE: A skin irritant. When
FEMh No. 2312
heated to decomposition it emits acrid smoke and irritating fumes.
SAFETY PROFILE: Combustible liquid. When heated to decomposition it emits
acrid smoke and irritating fumes. CMT750 CAS: 105-85-1 HR: 1 CITRONELLYL FORMATE mf: C11H2002 mw: 184.31 PROP: Colorless liquid; strong, fruity odor. D: 0.890-0.93, refr index: 1.443-1.452, flash p: 197'F. Sol in alc, fixed oils; sltly sol in propylene glycol; insol in glycerin, water @ 235". SYNS: 3,7-DIMETHYL-6-OCTEN-l-OL FORMATE 0 2,6-DIMETHYL-2-OCTEN-8-TiL FORMATE 0 3,7DIMETHYL-6-OCTEN-1-YLFORTLATE 0 FEiMA No, 2314
SYNS: ACETIC ACID, PHENYL-, 3,7-DIMETHYL-GOCTENYL ESTER 0 BENZENEACETIC ACID, 3,7DIMETHYL-6-OCTENYLESTER (9CI) 0 3,7-DIMETHYL6-OCTEN-1-YL PHENYLACETATE
CONSENSUS REPORTS: Reported in EPA
CMU100 HR: 2 CITRONELLYL PROPIONATE mf: C13H2402 mw: 212.33 PROP: Colorless liquid; fruity-rosy odor. D: 0.877-0.886, refr index: 1.443-1.449, flash p: 212'F. Wsc in alc, most oils; insol in water @ 242". SYN: FEMA No. 2316 SAFETY PROFILE: Combustible liquid. When heated to decomposition it emits
acrid smoke and irritating fumes.
E
374
CMU475
C.I. VATBLACK8
CMU475 CAS: 2278-50-4 HR: 1 C.I. VAT BLACK 8 mf: C4jH19N304 mw: 665.67 SYNS: BENZADONE GREY M 0 IH-BENZ(6,7)INDAZ-
METHYLCHLOROPINDOL 0 METHYLCHLORPINDOL 0 METILCLORPINDOL
OSHA PEL: Total Dust: 15 mg/m3; Respirable Fraction: 5 mg/m3 OL0(2,3,4-fgh)NAPHTH(2",3":6',7')INDOL0(3',2':5,6)ANTHR ACGIH TLV: TWA 10 mg/m3; Not A(2,1,9-mna) ACRIDINE-5,8,13,25-TETRAONE0 CALEDClassifiable as a Human Carcinogen ON GREY M 0 CERN KYPOVA 8 0 C.I. 71000 0 INDSAFETY PROFILE: A nuisance dust. When ANTHREN GREY M 0 INDANTHREN GREY MG 0 heated to decomposition it emits very toxic MIKETHRENE GREY M 0 MIKETHRENE GREY MG 0 fumes of C1- and NO,. NIHONTHRENE GREY M 0 OSTANTHREN GREY M 0 PARADONE GREY M 0 PARADONE GREY MG 0 SED OSTANTHRENOVA M 0 VAT GRAY S 0 VAT GREY S
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by intraperitoneal and ingestion routes. An eye irritant.When heated to decomposition it emits toxic fumes of NO,.
CMU850 CAS: 542-46-1 HR: 1 cis-CIVETONE mf: C17H300 mw: 250.47 PROP: Crystals; strong musty odor. Mp: 31-32', bp: 342'. SYNS: CIVETONE 0 'XYCLOHEPTADECEN-I-ONE 0
I.C.I. LTD. COMPOUND NUiMBER 80996
SAFETY PROFILE: Experimental
reproductive effects. When heated to decomposition it emits toxic fumes of C1-. CMXOI0 HR: D CLORSULON SAFETY PROFILE: When heated to decomposition emits toxic fumes of C1-.
9-CYCLOHEPTADECEN-I-ONE, (Z)-(8CI,9CI)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
CMU9OO HR: D CLARY OIL PROP: From steam dsullation of flowering tops and leaves of Salvia sclarea L (Fam. Labiatae). Pale yellow liquid; herbaceous odor. Sol in fixed oils, mineral oil; insol in glycerin, propylene glycol. SYNS: CLARY SAGE OIL 0 OIL OF MUSCATEL SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. CMX850 CAS: 2971-90-6 HR: 1 CLOPIDOL mf: C7H7C12NO mw: 192.05 PROP: Insol in H20. SYNS: COCCIDIOSTAT C 0 COYDEN 0 3,5DICHLORO-2,6-DIMETHYL-4-PYRlDINOL 0 LERBEK
CMX880 CASE40665-92-7 HR: D CLOPROSTENOL mf: C22H29C106 mw: 424.96 SYNS: ESTRUMATE 0 ICI SO996 0 racemic-ICI 80,996 0
0
CMYSOO CAS: 8015-97-2 HR: 2 CLOVE LEAF OIL MADAGASCAR PROP: From steam distillation of leaves of Etrgenis caryopbyllata Thunberg (Ezigenia aromatics L. Bad.) (Fam. Mjrtaceae). Paleyellow liquid. Refr index: 1.527-1.538 @ 20'. Sol in propylene glycol, fixed oils; insol in glycerin, mineral oil. SYNS: CLOVE LEAF OIL 0 OILS, CLOVE LEAF CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and skin contact. A severe s h n irritant. When heated to decomposition it emits acrid smoke and fumes. CMY750 HR: 3 COAL CONVERSION MATERIALS, SRCII HEAVY DISTILLATE SYN: SRC-I1 HEAVY DISTILLATE SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data by s h n contact.
COAL TAR DISTILLATE
CMY760 COAL DUST PROP: Black powder or dust.
HR: 3
SYNS: ANTHMCITE PARTICLES 0 COAL FACINGS 0 COAL, GROUND BITUMINOUS (DOq 0 COAL-MILLED 0 COAL SLAG-MILLED SEA COAL
OSHA PEL: Respirable Quartz Fraction less
than 5% SiOz: TWA 2 mg/m3; Respirable Quartz Fraction greater than or equal to 5% SiOz: 0.1 mg/m3 ACGIH TLV: Bituminous: TWA 0.9 mg/m3; Not Classifiable as a Human Carcinogen; Anthracite: 0.4 mg/m3; Not Classifiable as a Human Carcinogen ACGIH TLV: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic data. Variable toxicity depending upon SiOz content. See also SILICA. Moderately flammable when exposed to heat, flame, or chemical reaction with oxidizers. Slightly explosive when exposed to flame. CMY800 COAL TAR
CAS: 8007-45-2
HR: 3
SYNS: CARBO-CORT C l COALTAR, AEROSOL 0 COAL TAR SOLUTION USP 0 CRUDE COAL TAR 0 ESTAR 0 IMPERVOTAR 0 LAV 0 LAVATAR 0 PICIS CARBONIS 0 PIXALBOL 0 PIX CARBONIS 0 PIX LITHANTHMCIS 0 POLYTAR BATH 0 SUPERTAH 0 SYNTAR 0 TAR 0 TAR, COAL 0 ZETAR
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 1 IMEMDT 7,175,87; Animal Sufficient Evidence IMEMDT 34,65,84; IMEMDT 35,83,85;IMEMDT 3,22,73; Human Sufficient Evidence IMEMDT 34,65,84;IMEMDT 3,22,73; Human Limited Evidence IMEMDT 35,83,85. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.2 mg/m3; Carcinogen DFG MAK: Human Carcinogen NIOSH REL: (Coal Tar Products) TWA 0.1 mdm3 DOT CLASSIFICATION: 3; Label: Flammable Lquid SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic
CMYSOO 375
and tumorigenic data. Mutation data reported. A human and experimental skin irritant. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes. CMY805 CAS: 8007-45-2 HR: 2 COAL TAR, AEROSOL OSHA PEL: TWA 0.2 mg/m3 NIOSH REL: TWA 0.1 mg/m3 CHE fraction CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits acrid smoke and irritating fumes. CMY825 CAS: 8001-58-9 COAL TAR CREOSOTE
HR: 3
SYNS: AWTA #I
0 BRICK OIL 0 COAL TAR OIL U COAL TAR OIL (DOT) 0 CREOSOTE 0 CREOSOTE, from COAL TAR 0 CREOSOTE OIL 0 CREOSOTE P1 0 CREOSOTUM 0 CRESYLIC CREOSOTE 0 HEAVY OIL 0 LIQUID PITCH OIL 0 NAPHTHALENE OIL 0 PRESERV-0-SOTE 0 R C M WASTE NUMBER U051 0 TAR OIL 0 WASH OIL
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 2A IMEMDT 7,177,87; Animal Sufficient Evidence, Human Limited Evidence IMEMDT 35,83,85; Animal Sufficient Evidence IMEMDT 3,22,73. Reported in EPA TSCA Inventory. NIOSH REL: (Coal Tar Products) TWA 0.1 mg/m3 CHE fraction DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion. Experimental reproductive effects. Mutation data reported. A flammable liquid. When heated to decomposition it emits acrid smoke and fumes. CMY9OO CAS: 65996-92-1 COAL TAR DISTILLATE DOT: UN 1136
HR: 3
376 CMY920 COAL TAR DYE SYNS: COAL TAR DISTILLATES 0 COAL TAR DISTILLATES, flammable (DOT) 0 DISTILLATES (COAL TAR) CONSENSUS REPORTS: Reported in NTP
10th Report on Carcinogens. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: A carcinogen. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating vapors. CMY920 HR: 3 COAL TAR DYE CONSENSUS REPORTS: Reported in NTP 10th Report on Carcinogens. SAFETY PROFILE: Confirmed carcinogen. When heated to decomposition it emits acrid smoke and irritating vapors. CMZ100 CAS: 65996-93-2 HR: 3 COAL TAR PITCH VOLATILES PROP: IDLH 80 mg/m3. SYNS: PITCH 0 PITCH, COAL TAR CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 7,174,87; Animal Sufficient Evidence, Human Sufficient Evidence IMEMDT 35,83,85; Human Sufficient Evidence IMEMDT 3,22,73. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.2 mg/m3; Carcinogen ACGIH TLV: TWA 0.2 mg/m3 (volatile), Confirmed Human Carcinogen NIOSH REL: (Coal Tar Products) TWA 0.1 mg/m3 CHE fraction DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data by skin contact. When heated to decomposition it emits acrid smoke and fumes. CNA250 CAS: 7440-48-4 HR: 3 COBALT af: Co aw: 58.93 PROP: Gray, hard, magnetic, lustrous, ducule, somewhat malleable, silvery-blue
metal. Mp: 1495O, bp: 28' @ 3100 mm, d 8.92, Brinell hardness: 125, latent heat of fusion: 62 cal/g, latent heat of vaporization: 1500 cal/g, specific heat (15-100O): 0.1056 cal/g/'C. Exists in two allotropic forms. At room temperature, the hexagonal form is more stable than the cubic form; both forms can exist at room temperature. Stable in air or toward water at ordinary temperatures. Ready sol in dd HNO3; very slowly attacked by HC1 or cold HzS04. The hydrated salts of cobalt are red, and the sol salts form red solns that become blue on adding conc HC1. IDLH 20 mg/m3 (as Co). SYNS: AQUACAT 0 C.I. 77320 0 COBALT-59 KOBALT (GERMAN, POLISH) 0 NCI-C60311 0 SUPER COBALT CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cobalt and its compounds are on the Community Right-To-Know List. OSHA PEL: TWA 0.05 mg/m3 ACGIH TLV: (metal, dust, and fume) TWA 0.02 mg(Co)/m'; Animal Carcinogen DFG MAK: DFG TRK. Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Cobalt) Insufficient evidence for recommending limit SAFETY PROFILE: Confirmed carcinogen with experimental neoplastigenic and tumorigenic data. Poison by intravenous, intratracheal, and intraperitoneal routes. Moderately toxic by ingestion. Inhalation of the dust may cause pulmonary damage. The powder may cause dermatitis. Ingestion of soluble salts produces nausea and vomiting by local irritation. Powdered cobalt igmtes spontaneously in air. Flammable when exposed to heat or flame. Explosive reaction with hydrazinium nitrate, ammonium nitrate + heat, and 1,3,4,7-tetramethylisoindole (at 39OOC). Ignites on contact with bromine pentafluoride. Incandescent reaction with acetylene or nitryl fluoride. See also COBALT COMPOUNDS.
CNASOO CAS: 6147-53-1 HR: 3 COBALT ACETATE TETRAHYDRATE mf: C ~ H ~ O ~ * C O * ~ Hmw: ~ O249.1 1
COBALT COMPOUNDS SYNS: ACETIC ACID, COBALT(2+) SALT, TETRAH M R A T E 0 COBALT DIACETATE TETRAHYDUTE 0 COBALTOUS ACETATE TETRAHYDRATE 0 OCTAhT KOBALTNATY (CZECH) CONSENSUS REPORTS: Cobalt and its compounds are on the Community kght-
To-Know List. IARC Cancer Review: Group 2B IMEMDT 52,363,91; Human Inadequate Evidence IMEMDT 52,363,91. SAFETY PROFILE: Moderately toxic by ingestion. Questionable carcinogen. A s h n and eye irritant. Human mutation data reported. See also C O B U T COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
CNBSOO CAS: 10210-68-1 HR: 3 COBALT CARBONYL mf: C8CozOs mw: 341.94 PROP: Air-sensitive orange-red platelets or crystals. D: 1.87, mp: 51', decomp above 52'. Decomp on exposure to air. Insol in water; sol in org solvs. SYNS: COBALT, DI-MUCARBONYLHEXACARBOPYLDI-, (CO-CO) 0 COBALT OCTACARBONYL 0 COBALT TETMCARBONYL 0 COBALT TETRACARBONYL DIMER 0 DI-MU-CARBONYLHEXACARBONYLDICOBALT 0 DICOBALT CARBONYL 0 DICOBALT OCTACARBONYL 0 OCTACARBONYLDICOBALT
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 52,363,91; Human Inadequate Evidence IMEMDT 52,363,91, Reported in EPA TSCA Inventory. Cobalt and its compounds are on the Community Right-To-Know List. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.1 mg(Co)/m3 ACGIH TLV: TWA 0.1 mg(Co)/m3 SAFETY PROFILE: Poison by inhalation and intraperitoneal routes. Questionable carcinogen. Decomposes in air to form a product that ignites spontaneously in air. " h e n heated to decomposition it emits acrid smoke and fumes. See also CARBONYLS and COBALT COMPOUNDS.
CNB850 377
CNB599 CAS: 7646-79-9 HR: 3 COBALT(I1) CHLORIDE mf: ClzCo mw: 129.83 PROP: Pale blue hygroscopic powder or crystals. Mp: 735", bp: 1049O, d: 3.348. Sol in Hz0 and polar org solvs. SYNS: COBALT DICHLORIDE 0 COBALT MURlATE 0 COBALTOUS CHLORIDE 0 COBALTOUS DICHLORIDE 0 KOBALT CHLORID (GERMAN)
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 52,363,91; Animal Limited Evidence IMEMDT 52,363,91; Human Inadequate Evidence IMEMDT 52,363,91. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Cobalt and its compounds are on the Community Right-To-Know List. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. Poison experimentally by ingestion, s h n contact, intraperitoneal, intravenous, and subcutaneous routes. Moderately toxic to humans by ingestion. Human systemic effects by ingestion: anorexia, goiter (increased thyroid size), and weight loss. Experimental teratogenic and reproductive effects. Human mutation data reported. Incompatible with metals (e.g., sodmm and potassium). See also COBALT. When heated to decomposition it emits toxic fumes of C1-.
CNB850 COBALT COMPOUNDS
HR: 3
CONSENSUS REPORTS: Cobalt and its compounds are on the Community Bght-
To-Know List. DFG MAK: DFG TRK. 0.5 mg/m3 calculated as cobalt in that portion of dust that can possibly be inhaled in the production of cobalt powder and catalysts; hard metal (tungsten carbide) and magnet production (processing of powder, m a c h e pressing, and mechanical processing of unsintered articles); other cobalt alloys and compounds: 0.1 mg/m3 calculated as cobalt in that portion of dust that can possibly be
378
CNCOOO
COBALT DIACETATE
inhaled. Animal Carcinogen, Suspected Human Carcinogen. SAFETY PROFILE: Confirmed carcinogen with experimental neoplastigenic and tumorigenic data. Cobalt has a low toxicity by ingestion. Ingestion of soluble salts produces nausea and vomiting by local irritation. In animals, administration of cobalt salts produces an increase in the total red cell mass of the blood. In humans, a single case of poisoning with liver and hdney damage has been attributed to cobalt. Locally, cobalt has been shown to produce dermatitis and investigators have been able to demonstrate a hypersensitivity of the skin to cobalt. There have been reports of hematologlc, digestive, and pulmonary changes in humans. See also specific compounds. CNCOOO CAS: 71-48-7 HR: 3 COBALT DIACETATE mf: C ~ H ~ O ~ C O mw: 177.03 PROP: Light-pink crystals. Very sol in H20; sol in EtOH. SYNS: ACETIC ACID, COBALT(2+) SALT 0 COBALT ACETATE 0 COBALT(2+) ACETATE 0 COBALTVI) ACETATE 0 COBALTOUS DIACETATE
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 52,363,91; Human Inadequate Evidence IMEMDT 52,363,91. Cobalt and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. NIOSH REL: (Cobalt Metal, Dust and Fume) TWA 0.05 mg/m3 SAFETY PROFILE: Poison by intravenous route. Moderately toxic by ingestion. Questionable carcinogen. Mutation data reported. See also COBALT COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
CNC100 CAS: 10026-17-2 COBALT(I1) FLUORIDE mf: CoF2 mw: 96.93
HR: 3
PROP: Small light-brown or reddsh-pink, hexagonal crystals. Bp: 1400'. Reacts with water. Sltly sol in water. SYNS: COBALT DIFLUORIDE 0 COBALTOUS FLUORIDE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shft. NIOSH REL: (Fluorides, Inorganic): 10H TWA 2.5 mg(F)/m3 SAFETY PROFILE: Poison by ingestion. When heated to decomposition it emits toxic fumes of Co and F-.
CNC230 CAS: 16842-03-8 HR: 3 COBALT HYDROCARBONYL mf: C4HCo04 mw: 171.98 PROP: Light-yellow liquid or gas. Unstable, but dstillable in current of CO. Mp: -33O, bp: 10'. Sol org solvs; spar sol in H20. CONSENSUS REPORTS: Cobalt and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA 0.1 mg(Co)/m3 ACGIH TLV: TWA 0.1 mg(Co)/m3 SAFETY PROFILE: Poison by inhalation. See also COBALT COMPOUNDS. CNC233 CAS: 1307-86-4 HR: 2 COBALT HYDROXIDE mf: CoH303 mw: 109.96 SYNS: COBALTPII) HYDROXIDE 0 COBALTIC HYDROXIDE 0 COBALT TRIHYDROXIDE
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 52,363,1991; Human Inadequate Evidence IMEMDT 52,363,1991. SAFETY PROFILE: Mutation data reported. Questionable carcinogen with experimental data reported. When heated to decomposition it emits toxic vapors of Co.
COBALT(I1) OXIDE
CNC245 HR: D COBALT LINOLEATE SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. CNC250 CAS: 13762-14-6 HR: D COBALT MOLYBDATE mf: CoMo04 mw: 218.87 PROP: Shmy black crystals or olive-green powder. Mp: 1040'. There is a high-pressure form with the wolframite structure. IDLH 1000 mg/m3 (as Mo). SYNS: COBALT(2+) MOLYBDATE 0 COBALT MOLYBDENUM OXIDE 0 COBALTOUS MOLYBDATE 0 HT-400 E 1/8'
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Cobalt and its compounds are on the Community fight-To-Know List. OSHA PEL: TWA 5 mg(Mo)/m3 ACGIH TLV: TWA Soluble Compounds: TWA 0.5 mg(Mo)/m3 Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Cobalt) Insufficient evidence for recommendmg limit SAFETY PROFILE: Mutation data reported. See also COBALT COMPOUNDS and MOLYBDENUM COMPOUNDS.
CNCSOO CAS: 10141-05-6 HR: 3 COBALT(I1) NITRATE mf: C O N Z O ~ mw: 182.95 PROP: Mp: 55O, d: 1.87. SYNS: COBALT BIS(N1TRATE) 0 COBALT DINITRATE 0 COBALT NITRATE 0 COBALT(Z+) NITRATE 0 COBALTOUS NITRATE 0 NITRIC ACID, COBrlLT(Z+) SALT
CONSENSUS REPORTS: IARC Cancer Review: Group 2B; Human Inadequate Evidence IMEMDT 52,36331. Reported in EPA TSCA Inventory. Cobalt and its compounds are on the Community RightTo-Know List. SAFETY PROFILE: Poison by ingestion, intramuscular, and subcutaneous routes. Experimental reproductive effects. Questionable carcinogen with experimental
CND125 379
tumorigenic data. Used in animal feed. Explosive reaction with ammonium hexacyanoferrate(I1) at 220OC. Potentially explosive reaction with carbon. When heated to decomposition it emits toxic fumes of NO,. See also COBALT COMPOUNDS and NITRATES. CNDl25 CAS: 1307-96-6 HR: 3 COBALT(I1) OXIDE mf: COO mw: 74.93 PROP: Powder, cubic, hexagonal crystals or solid. Color varies from olive green to red, depending on the particle size, but the commercial material is usually dark gray and contains about 76% Co. The color of anhydrous COO depends upon the degree of dispersion. It may be yellow, gray, brown, reddsh, bluish, or black. Mp: about 1935O, d: 5.7 to 6.7. Practically insol in water or alc; sol in acids or alkalies. Easily reduced to Co by C or CO. Reacts at high temperatures with silica, alumina, and zinc oxide to form pigments. SYNS: C.I. 77322 0 C.I. PIGMENT BLACK 13 0 COBALT B U C K COBALT MONOOXIDE 0 COBALT MONOXIDE 0 COBALTOUS OXIDE 0 COBALT OXIDE 0 COBALT@+)OXIDE 0 MONOCOBALT OXIDE 0 ZAFFRE
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 52,363,91; Animal Sufficient Evidence IMEMDT 52,363,91; Human Inadequate Evidence IMEMDT 52,36331. Cobalt and its compounds are on the Community fightTo-Know List. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion, subcutaneous, and intratracheal routes. Moderately toxic by intramuscular route. Violent reaction with hydrogen peroxide. See also COBALT. Note: The commercial oxides are usually not definite chemical compounds but mixtures of the cobalt oxides.
380 CND825 COBALT(///)OXIDE CND825 CAS: 1308-04-9 HR: 2 COBALT(II1) OXIDE mf: Co203 mw: 165.86 SYNS: C.I. 71323 0 COBALTIC OXIDE 0 COBALT OXIDE (8CI,9CI) 0 COBALTO+) OXIDE 0 COBALT PEROXIDE 0 COBALT SESQIOXIDE 0 COBALT SESQUIOXIDE 0 COBALT TRIOXIDE 0 DICOBALT OXIDE 0 DICOBALT TRIOXIDE
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 52,363,91; Human Inadequate Evidence IMEMDT 52,363,91. Reported in EPA TSCA Inventory. Cobalt compounds are on the Community Right-To-Know List. SAFETY PROFILE: Moderately toxic by intraperitoneal and subcutaneous routes. Questionable carcinogen. Violent reaction with hydrogen peroxide. The oxide increases the sensitivity of nitroalkanes (e.g., nitromethane, nitroethane, and 1nitropropane) to heat or detonation. See also COBALT COMPOUNDS.
CND9OO CAS: 13478-33-6 HR: 3 COBALT(I1) PERCHLORATE, HEXAHYDRATE mf: ClzO&o*6HzO mw: 365.95 SYNS: COBALT DIPERCHLORATE HEXAHYDRATE 0 COBALTOUS PERCHLORATE, HEXAHYDRATE 0 COBALT PERCHLORATE HEXAHYDRATE 0 PERCHLORIC ACID, COBALTVI) SALT, HEXAHYDRATE
DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: A poison by
intraperitoneal route. An oxidizer. When heated to decomposition it emits toxic vapors of Co and C1-. CNEOOO CAS: 68956-82-1 HR: 3 COBALT RESINATE, precipitated DOT: UN 1318 mf: Co(C~H6204)2 mw: 1368.81 PROP: Brown-red powder. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cobalt and its compounds are on the Community Right-To-Know List. DOT CLASSIFICATION: 4.1; Label: Flammable Solid SAFETY PROFILE: A dangerous fire hazard when exposed to heat, flame, oxidizers, or
air. Ignites spontaneously in air. See also COBALT COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
CNE125 CAS: 10124-43-3 HR: 3 COBALT(I1) SULFATE (1 :1) mf: 04S*Co mw: 154.99 PROP: Red to lavender or dark bluish solid or dimorphic, orthorhombic crystals. D: 3.71. Stable to 708'. Dissolves slowly in bohng water. SYNS: COBALTOUS SULFATE 0 COBALT SULFATE 0 COBALT SULFATE (1:l) 0 COBALT (2+) SULFATE 0 COBALTPI) SULPHATE 0 SULFLRIC ACID, COBALT(2+) SALT (1:l)
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 52,363,91; Human Inadequate Evidence IMEMDT 52,363,91. Cobalt and its compounds are on the Community Rght-To-Know List. EPA Genetic Toxicology Program.Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Moderately toxic by ingestion. Questionable carcinogen. When heated to decomposition it emits toxic fumes of SO,. See also COBALT COMPOUNDS.
CNE2OO CAS: 1317-42-6 HR: 3 COBALT(I1) SULFIDE mf: CoS mw: 90.99 PROP: Exists in two forms. a-CoS: black, amorphous powder. Sol in HC1. p-CoS: gray powder or reddish-silver octahedral crystals. Mp: above 1loo', d: 5.45. Practically insol in water; sol in acids. SYNS: COBALT MONOSULFIDE 0 COBALTOUS SULFIDE 0 COBALT SULFIDE 0 COBALT SULFIDE (amorphous)
CONSENSUS REPORTS: IARC Cancer
Review: Group 2B IMEMDT 52,363,91; Animal Lmited Evidence IMEMDT 52,363,91; Human Inadequate Evidence IMEMDT 52,363,91. Reported in EPA TSCA Inventory. Cobalt and its compounds are on the Community Rght-To-Know List.
COCONUT OIL ACID DIETHANOLAMINE CNF330 381 SAFETY PROFILE: Suspected carcinogen with experimental tumorigenic data. Mutation data reported. If dried at 300’C it igmtes spontaneously in air. See also COBALT COMPOUNDS and SULFIDES.
in fats and thus is used for ointments and oily solutions. For water-soluble applications, the sulfate or hydrochloride is used. See also ESTERS. When heated to decomposition it emits highly toxic fumes.
CNE240 HR: D COBALT TALLATE SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes.
CNFI 75 CAS: 61789-30-8 HR: D COCOA FATTY ACIDS, POTASSIUM SALTS SYN: SOAP CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes.
CNE750 CAS: 50-36-2 HR: 3 COCAINE mf: C17H~N04 mw: 303.39 PROP: Colorless to white crystals or prisms from alc. Mp: 98O, bp: 187-1 88’. Volatile, especially above 90’. Soluble in alcohol, chloroform, ether, oil turpentine, olive oil, liquid petrolatum, acetone, ethyl acetate, carbon disulfide. Sparingly soluble in water. SYNS: BENZOYLAfETHYLECGONINE 0 BERNICE 0 BERNIES 0 BURESE 0 2-p-CARBOMETHOXY-3-pBENZOXYTROPANE 0 “C” CARRIE 0 CECIL 0 CHOLLY 0 (-)-COCAINE 0 p-COCAINE 0 1-COCAINE 0 COKE 0 CORINE 0 ECGONINE, METHYL ESTER, BENZOATE (ESTER) 0 ERITROXILINA 0 ERYTROXYLIN 0 GIRL 0 GOLD DUST 0 HAPPY DUST 0 3-pHYDROXY-1-a-H,S-a-H-TROPANE-2-P-CARBOXYLK ACID METHYL ESTER, BENZOATE 0 KOKAIX 0 KOKAN 0 KOMYEEN 0 METHYL-3-P-HYDROXY-l-aH,5-a-H-TROPANE-2-P-CARBOXYLATE BENZOATE (ESTER) 0 NEUROCAINE 0 STAR DUST 0 2-pTROPANECARBOXYLIC ACID, 3-P-HYDROXY-,METHYL ESTER, BENZOATE (ESTER) 0 3-TROPANYLBENZOATE-2-CARBOXYLICACID METHYL ESTER
DOT CLASSIFICATION: Forbidden SAFETY PROFILE: A human poison by
ingestion and possibly other routes. Poison experimentally by ingestion, intraperitoneal, intravenous, subcutaneous, and parented routes. Human central nervous system effects by ingestion and possibly other routes: general anesthesia, hallucinations or distorted perceptions, and convulsions. An eye irritant. A widely abused, controlled substance. Abuse leads to habituation or addiction. In medcine, it is used as a local narcotic anesthetic applied topically to mucous membranes. The free base is soluble
CNF250 CAS: 104-61-0 HR: 2 COCONUT ALDEHYDE mf: C9H1602 mw: 156.25 PROP: Colorless to sltly yellow liquid; coconut odor. D: 0.958-0.966, refr index: 1.446-1.450, flash p: 212’F. Sol in alc, fixed oils, propylene glycol; insol in water. SYNS: ALDEHYDE C-18 0 y-NAMYLBUTYROLACTONE 0 FEMA No. 2781 0 4HYDROXYNOSAiiOIC ACID, y-LACTONE 0 yN O N U C T O N E (FCC) 0 1,CNONALOLIDE 0 PRCNOLIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.
CNF330 CAS: 68603-42-9 HR: 3 COCONUT OIL ACID DIETHANOLAMINE SYNS: AMIDES, COCO, N,N-BIS(HYDR0XYETHYL)0 CLINDROL 200CGN 0 CLINDROL 202CGN 0 CLIXDROL SUPERAMIDE lO0CG 0 COCAMIDE DEA 0 COCONUT DIETHAiiOLAMDE 0 COCOXCT DIETHANOLAMINE 0 COCONUT OIL ACID DIETHANOLAMINE 0 COCONUT OIL ACID DIETHANOLAMINE CONDENSATE 0 ETHYLAN LD 0 N,N-BIS(2-HYDROXYETHYL)COCOAMIDE 0 N,N-BIS(2-HYDROXYETHYL)COCONUT FATTY ACID AMIDE 0 N,N-BIS(2-HYDROXYETHYL)COCONUT OIL AMIDE 0 NCI-C55312 0 NINOL 2012E
E
382
CNG929 COKE OVEN EMISSIONS
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. EPA FIFRA 1988 pesticide subject to registration or registration. NCI Carcinogenesis Studies (derm). clear evidence: mouse; (derm). equivocal evidence: rat SAFETY PROFILE: A poison by ingestion. A moderate skin irritant. Questionable carcinogen with experimental Carcinogenic data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
CNG929 COKE OVEN EMISSIONS
HR: 3
SYN: COKE OVEN EMISSIONS (OSHA) CONSENSUS REPORTS: Reported in NTP
10th Report on Carcinogens. OSHA PEL: OSHA: Cancer Hazard NlOSH REL: 0.5-0.7 mg/m3 (total particulates) SAFETY PROFILE: Confirmed carcinogen. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
experimentally by most routes. Human systemic effects: aplastic anemia, blood pressure depression, body temperature decrease, changes in kidney tubules, dyspnea, flaccid paralysis without anesthesia, gastrointestinal effects, kidney damage and hemorrhaging, muscle contraction or spasticity, muscle weakness, nausea or vomiting, respiratory stimulation, and somnolence. An experimental teratogen. Experimental reproductive effects. A severe eye irritant. Human mutation data reported. Inhibits the formation of microtubules and thus impairs cell division. When heated to decomposition it emits toxic fumes of NO,.
CNH792 CAS: 8001-61-4 HR: 2 COPAIBA OIL PROP: From steam distillation of South American Copaifera L (Fam. Legaminosae) balsam. Colorless to yellow liquid; characteristic odor, aromatic, slightly bitter taste. D: 0.880-0.907, refr index: 1.493-1.500 @ 20". Sol in alc, fmed oils, mineral oil. SYNS: BALSAM CAPTIVI 0 BALSAMS, COPAIBA
CNG938 CAS: 64-86-8 HR: 3 COLCHICINE mf: C22H25NO6 mw: 399.48 PROP: Pale-yellow scales or powder. Mp: 155-1 57". Crystals from ethyl acetate, paleyellow needles. One gram dmolves in 22 mL water, 220 mL ether, 100 mL benzene; freely sol in alcohol or chloroform; practically insol in pet ether. SYNS: 7-ACETfiIIDO-6,7-DIHYDRO1,2,3,10TETRAhfETHOXY-BENZO(a)HEPTALEN-9(5H)-ONE 0 N-ACETYL TRIMETHYLCOLCHICINIC ACID METHYL. ETHER 0 COLCHICIN (GERMAN) 0 COLCHICINA (ITALIAN) 0 7-a-H-COLCHICINE 0 COLCHINEOS 0 COLCHISOL 0 COLCIN 0 COLSALOID 0 CONDYLON 0 NSC-757 0 N-(5,6,7,9-TETRAHYDR0-1,2,3,10TETRi%METHOXY-9-OXOBENZO(a)HEPTALEN-7-YL.)ACETAMIDE
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: A human poison by ingestion and intravenous routes. Poison
0
COPAIBA BALSAM 0 COPAIBA OLEORESIN 0JESUIT'S BALSAM
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: M d l y toxic by ingestion. Large doses cause vomiting and diarrhea. Can also cause dermatitis and hdney damage. When heated to decomposition it emits acrid smoke and irritating fumes.
CNIOOO CAS: 7440-50-8 HR: 2 COPPER af: Cu aw: 63.54 PROP: Reddish, malleable and ductile metal. Slowly weathers to green patina. Mp: 1083", bp: 25" @ 2595 mm, d: 8.92, vap press: 1 mm @ 1628'. IDLH 100 mg/m3 (as Cu). SYNS: ALLBRI NATURALCOPPER 0 ANAC 110 0 ARWOOD COPPER 0 BRONZE POWDER 0 CDA 101 0 CDA 102 0 CDA 110 0 CDA 122 0 C.I. 77400 0 C.I. PIGMENT METAL 2 0 COPPER-AIRBORNE 0 COPPER BRONZE 0 COPPER-MILLED 0 COPPER SLAG-
COPPER ALLOY AIRBORNE 0 COPPER SLAG-MILLED U 1721 GOLD 0 GOLD BRONZE 0 U F A R COPPER 0 M1 (COPPER) 0 M 2 (COPPER) 0 OFHC Cu 0 RANEY COPPER
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Copper and its compounds are on the Community RightTo-Know List. OSHA PEL: TWA (dust, mist) 1 mg(Cu)/m3; (fume and respirable particles) 0.1 mg/m3 ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3 DFG MAK: (dust) 1 mg/m3; (fume) 0.1 mg/m3 SAFETY PROFILE: Toxic by inhalation. Questionable carcinogen with experimental tumorigenic data. Experimental teratogenic and reproductive effects. Human systemic effects by ingestion: nausea and vomiting. See also COPPER COMPOUNDS. Liquid copper explodes on contact with water. Potentially explosive reaction with acetylenic compounds, 3-bromopropyne, ethylene oxide, lead azide, and ammonium nitrate. I p t e s on contact with chlorine, chlorine trifluoride, fluorine (above 121"), and hydrazinium nitrate (above 70'). Reacts violently with C2H2, bromates, chlorates, iodates, (Clz + OFz), dimethyl sulfoxide + trichloroacetic acid, ethylene oxide, H 2 0 2 , hydrazine mononitrate, hydrazoic acid, H 2 S + air, Pb(N3)2, K202, NaN3, Na202, sulfuric acid. Incandescent reaction with potassium &oxide. Incompatible with 1-bromo-2propyne.
CN1250 CAS: 142-71-2 HR: 3 COPPER ACETATE mfi C4H604.C~ mw: 181.64 PROP: Greenish-blue powder or small crystals. SYNS: ACETATE de CUIVRE (FRENCH) 0 ACETIC ACID, CUPRIC SALT COPPER(Z+) ACETATE COPPERQI) ACETATE 0 COPPER DIACETATE 0 COPPER(2+) DIACETATE 0 CRYSTALLIZED VERDIGRIS 0 CRYSTALS of VENUS 0 CUPRIC ACETATE 0 CUPRIC DIACETATE 0 NEUTRAL VERDIGFUS 0 OCThX MEDNATY (CZECH)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Copper and its
CNl600 383
compounds are on the Community RightTo-IGow List. ACGIH TLV: TWA 1 mg(Cu)/m3 SAFETY PROFILE: Poison by subcutaneous and intraperitoneal routes. Moderately toxic by ingestion. Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes. See also COPPER COMPOUNDS.
CN1500 CAS: 12540-13-5 HR: 3 COPPER ACETYLIDE mf: C2Cu mw: 87.56 PROP: A black or brown solid. SYN: COPPER CARBIDE CONSENSUS REPORTS: Copper and its compounds are on the Community &ghtTo-IGow List. ACGIH TLV: TWA 1 mg(Cu)/m' DOT CLASSIFICATION: Forbidden SAFETY PROFILE: Ignites and then explodes when heated to 100'C. Much more sensitive to impact, friction, and heat than copperp) acetylide (the red-brown form). See also COPPER COMPOUNDS and ACETYLIDES. CN1600 CAS: 11133-98-5 HR: 3 COPPER ALLOY, Cu, Be SYNS: BERYLLIUMCOPPER ALLOY 0 COPPERBERYLLIUM ALLOY
CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,4133; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Copper and its compounds, as well as beryllium and its compounds, are on the Community Right-To-Know List. OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002
384 CNJSOO COPPER CHLORATE mg(Be)/m3 (sensitizer) ( s h ) ; Confirmed Human Carcinogen) SAFETY PROFILE: Confirmed carcinogen. Cases of berylliosis have been reported from exposure to so-called low berylhum alloys. Human systemic effects by inhalation: dyspnea, fibrosing alveolitis, weight loss, or decreased weight gain. See also BERYLLIUM COMPOUNDS and COPPER COMPOUNDS. When heated to decomposition it emits very toxic fumes of BeO. CNJ9OO CAS: 26506-47-8 HR: 2 COPPER CHLORATE DOT: UN 2721 mf: HClOpxCu mw: 529.24 SYNS: CHLORIC ACID, COPPER SALT 0 COPPER CHLORATE (DOT)
ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust,
mist) 1 mg(Cu)/m3 DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: An oxidizer. When
heated to decomposition it emits toxic fumes of C1-. CNJ950 CAS: 1344-67-8 HR: 3 COPPER CHLORIDE DOT: UN 2802 SYNS: COPPER CHLORIDE (DO9 U KIRTICOPPER CONSENSUS REPORTS: Reported in EPA TSCA Inventory. ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A corrosive. A skin and eye irritant. When heated to decomposition it emits toxic vapors of Cu and C1-. CNKSOO CAS: 7447-39-4 HR: 3 COPPER(I1) CHLORIDE (1 :2) DOT: UN 2802 mf: C12Cu mw: 134.44 PROP: Yellowish-brown, hygroscopic powder. Mp: 498O, d: 3.054. SYNS: COPPER BICHLORIDE 0 COPPER(2+) CHLORIDE 0 COPPERPI) CHLORIDE 0 CUPRIC CHLORIDE 0 CUPRIC DICHLORIDE
CONSENSUS REPORTS: Copper and its
compounds are on the Community RtghtTo-Know List. Reported in EPA TSCA Inventory. ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3 DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Experimental reproductive effects. Mutation data reported. See also COPPER COMPOUNDS and CHLORIDES. Can react violently with K and Na. When heated to decomposition it emits toxic fumes of
c1-.
CNK625 CAS: 866-82-0 HR: 2 COPPER(1) CITRATE mf: C6H40~2Cu mw: 315.18 SYNS: CITRIC ACID, COPPER(2+) SALT (8CI) 0 COPPER CITRATE 0 COPPER SALT 2-HYDROXY-1,2,3PROPANETRICARBOXYLICACID (1:2) 0 CUPRIC CITRATE 0 CUPROCITROL 0 2-HYDROXY-l,2,3PROPANETRICARBOXYLIC ACID COPPER(2+) SALT (1:2) (9C9
CONSENSUS REPORTS: Copper and its
compounds are on the Community RightTo-Know List. Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Experimental reproductive effects. An experimental teratogen. See also COPPER COMPOUNDS. CNK700 CAS: 55158-44-6 HR: 3 COPPER-COBALT-BERYLLlUM SYNS: BERYLLIUM-COPPER-COBALT ALLOY 0 COPPER ALLOY, Cu, Be, Co
CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 58,41,93; Human Sufficient Evidence IMEMDT 58,41,93; Animal Sufficient Evidence IMEMDT 1,17,72; Animal Sufficient Evidence IMEMDT 23,143,80; Animal Sufficient Evidence IMEMDT 58,41,93. Copper, cobalt, and beryllium and their compounds are on the Community RightTo-Know List.
COPPER(II) CYANIDE OSHA PEL: TWA 0.002 mg(Be)/m3; STEL
0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3 ACGIH TLV: TWA 0.002 mg(Be)/m3; Confrmed Human Carcinogen; (Proposed: TWA 0.00005 mg(Be)/m3; STEL 0.0002 mg(Be)/m3 (sensitizer) (skin); Confirmed Human Carcinogen) NIOSH REL: (Beryllium) CL not to exceed 0.0005 mg(Be)/m3; (Cobalt) Insufficient evidence for recommendmg limit SAFETY PROFILE: Confirmed carcinogen. See COPPER, BERYLLIUM, and COBALT COMPOUNDS. When heated to decomposition it emits very toxic fumes of BeO. CNK750 HR: 3 COPPER COMPOUNDS CONSENSUS REPORTS: Copper and its compounds are on the Community fightTo-Know List. ACGIH TLV: Inorganic: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3 SAFETY PROFILE: As the sublimed oxide, copper may be responsible for one form of metal fume fever. In animals, inhalation of copper dust has caused hemolysis of the red blood cells, deposition of hemofuscin in the liver and pancreas, and injury to the lung cells; injection of the dust has caused cirrhosis of the liver and pancreas, and a condtion closely resembling hemochromatosis, or bronzed dabetes. However, considerable trial exposure to copper compounds has not resulted in such disease. As regards local effect, copper chloride and sulfate have been reported as causing irritation of the shn and conjunctiva, possibly on an allergic basis. Cuprous oxide is irritating to the eyes and upper respiratory tract. Discoloration of the skin is often seen in persons handhng copper, but t h s does not indicate any actual injury. There is an excess of cancer cases in the copper smelting industry. In humans the ingestion of a large quantity of copper sulfate has caused vomiting, gastric pain,
C N L ~385
dzziness, exhaustion, anemia, cramps, convulsions, shock, coma, and death. Symptoms attributed to damage to the nervous system and kidney have been recorded, jaundice has been observed, and, in some cases, the liver has been enlarged. Deaths have been reported to have occurred following the ingestion of as little as 27 g of the salt, while other victims have recovered after having taken up to 120 g. Many copper-containing compounds are used as fungcides. Many copper salts form highly unstable acetylides. Those formed in basic solutions from (Cu+ salts + CzHz) are less stable than those formed from Cuff salts. Copper salts + hydrazine react strongly, and with nitromethane these salts are explosive. CNLOOO CAS: 544-92-3 HR: 3 COPPER CYANIDE DOT: UN 1587 mf: CCuN mw: 89.56 PROP: Monoclinic, white prisms; whitecream powder; dark-green orthorhombic crystals; dark red monoclinic crystals. Mp: 474’ in N2, bp: decornp, d: 2.92. Sol in NH3 (ad;insol in HzO and alcohols. SYNS: COPPER@ CYANIDE 0 CUPRICIN 0 CUPROUS CYANIDE 0 RCRA WASTE NUMBER PO29
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds, as well as copper and its compounds, are on the Community RightTo-Know List. ACGIH TLV: TWA 1 mg(Cu)/m3 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: A poison. Reacts violently with magnesium. When heated to decomposition it emits very toxic CN- and NO,. See also CYANIDE and COPPER COMPOUNDS.
CNL250 CAS: 14763-77-0 HR: 3 COPPER(I1) CY ANlDE mf: C2CuNz mw: 115.58 PROP: Yellowish-green powder. Mp: decomp before melting.
386 CNMlOO COPPER GLUCONATE SYNS: COPPER CYANAMIDE 0 COPPER CYANIDE (DOT) 0 CUPRIC CYANIDE (DOT) 0 CYANURE de
CUIVRE (FRENCH)
CONSENSUS REPORTS: Copper and its compounds, as well as cyanide and its
compounds, are on the Community RightTo-Know List. ACGIH TLV: TWA 1 mg(Cu)/m3 DOT CLASSIFICATION: 6.1; Label: Poison, KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by intraperitoneal route. See also CYANIDE and COPPER COMPOUNDS. Incompatible with magnesium. When heated to decomposition it emits toxic fumes of NO, and CN-. CNM100 CAS: 527-09-3 HR: D COPPER GLUCONATE mf: Ct2H22CuOt4 mw: 453.84 PROP: Fine light blue powder. Sol in water; sltly sol in alc. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. CNM750 CASE3251-23-8 HR: 2 COPPER(I1) NITRATE mf: CuN206 mw: 187.55 PROP: Large, blue-green, deliquescent, orthorhombic crystals. D: 2.047, sublimes at 150-225', mp: 255-256'. Sol in water, ethyl acetate, dioxane; dlssolves in and reacts vigorously with ether. SYNS: COPPER DIXITRATE 0 COPPER(2+)NITRATE 0 CUPRIC DINITRATE 0 CUPRIC NITRATE (DOT,!
CONSENSUS REPORTS: Copper and its
compounds are on the Community &ghtTo-Know List. Reported in EPA TSCA Inventory. ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3 SAFETY PROFILE: Moderately toxic by ingestion. A severe eye and skin irritant. Potentially explosive reaction above 22OOC with ammonium or potassium hexacyanoferrate(I1).Reaction with ammonia + potassium amide gives explosive product. Violent reaction with acetic
anhydride. May ignite on prolonged contact with paper. Concentrated solutions may i p t e in contact with tin or aluminum foil. Used as a fungicide, herbicide, and as a catalyst component in solid rocket fuel. When heated to decomposition it emits toxic fumes of NO,. See also COPPER COMPOUNDS and NITRATES. CNNSOO CAS: 10290-12-7 HR: 3 COPPER ORTHOARSENITE DOT: UN 1586 mf: AsCuH03 mw: 187.47 PROP: Yellowish-green powder. Mp: decomp. SYNS: ACID COPPERARSENITE 0 AIR-FLO GREEN 0 ARSONIC ACID, COPPER(2+) SALT (1:l)(9CI) 0 COPPER ARSENITE, solid (DOT) 0 CUPRIC ARSENITE 0 CUPRIC GREEN 0 SCHEELES GREEN 0 SCHEELE'S MINERAL 0 SWEDISH GREEN
CONSENSUS REPORTS: Arsenic and its compounds, as well as copper and its compounds, are on the Community RightTo-Ihow List. OSHA PEL: OSHA: Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine; TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3 NlOSH REL: (Arsenic, Inorganic) CL 0.002 mg(As)/m3/15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen. Poison. When heated to decomposition it emits toxic fumes of As. See also ARSENIC COMPOUNDS and COPPER COMPOUNDS.
CNOOOO CAS: 1317-39-1 HR: 2 COPPER(1) OXIDE mf: CunO mw: 143.08 PROP: Octahedral, cubic, red or yellow crystals or powder. Mp: 1235O, bp: loses 0 2 @ 1800O (decomp), d: 6.0. Insol in water. SYNS: BROWN COPPEROXIDE 0 C.I. 77402 0 COPOX 0 COPPER NORDOX 0 COPPER SARDEX 0 CUPPER OXIDE (RUSSIAN) 0 CUPROUS OXIDE 0 DICOPPER MONOXIDE 0 FUNGIMAR 0
COPTISINE CNRlOO 387 KUPFEROXYDUL (GERMAN) 0 OLEOCUIVRE 0 OLEO NORDOX 0 RED COPPER OXIDE 0 YELLOW CUPROCIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. Copper and its compounds are on the Community RightTo-Know List. ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3 SAFETY PROFILE: Moderately toxic by ingestion. Experimental reproductive effects. A fungicide. Violent, potentially explosive reaction with concentrated peroxyformic acid. Violent reaction when heated with aluminum. See also COPPER COMPOUNDS.
CN0500 CAS: 17031-32-2 HR: 3 COPPER(I1) PERCHLORATE, DIHYDRATE mf: C1208*Cu*2H20 mw: 298.48 SYNS: CUPRIC DIPERCHLORATE TETRAHYDRATE 0 PERCHLORIC ACID, COPPER(II) SALT, DIHYDRATE (8CI,9CI) CONSENSUS REPORTS: Copper and its
compounds are on the Community RightTo-Know List. ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3 DOT CLASSIFICATION: 5.1; Label: Oxidizer SAFETY PROFILE: Poison by intraperitoneal route. See also COPPER COMPOUNDS and COPPER(I1) PERCHLORATE. An oxidzer. When heated to decomposition it emits toxic fumes of C1-.
SULFURIC ACID, COPPER(2+) SALT (1:l) 0 TNCS 53 0 TRIANGLE
CONSENSUS REPORTS: Copper and its compounds are on the Community RightTo-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3 SAFETY PROFILE: A human poison by ingestion. An experimental poison by ingestion, subcutaneous, parenteral, intravenous, and intraperitoneal routes. Human systemic effects by ingestion: gastritis, Qarrhea, nausea or vomiting, damage to kidney tubules, and hemolysis. Questionable carcinogen with experimental tumorigenic data. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Reacts violently with hydroxylamine, magnesium. See also COPPER COMPOUNDS and SULFATES. When heated to decomposition it emits toxic fumes of SO,.
CNROOO CAS: 8001-31-8 HR: 3 COPRA (OIL) DOT: UN 1363 PROP: From the kernel of the fruit of the coconut palm Cocos nzlc;fera. Fatty solid or liquid; sweet, nutty taste. Mp: 21-27'. SYNS: COCONUT BUTTER 0 COCONUT MEAL PELLETS, containing G-139'0 moisture and no more than 10% residual fat (DOT) 0 COCONUT OIL (FCC) 0 COCONUT PALM OIL 0 COPRA (DOT) 0 COPRA PELLETS (DOT) 0 FREE COCONUT OIL CONSENSUS REPORTS: Reported in EPA
CNP250 CAS: 7758-98-7 HR: 3 COPPER(I1) SULFATE (1:1) mf: O&Cu mw: 159.60 PROP: Blue or white rhombic crystals or crystalhe granules or hygroscopic powder. D: 2.284, mp: 200'. Very sol in H20; sol in MeOH or glycerol; sltly sol in EtOH. SYNS: BCS COPPER FUNGICIDE 0 BLUE COPPER 0 BLUE STONE 0 BLUE VITRIOL 0 COPPER MONOSULFATE 0 COPPER SULFATE 0 CP BASIC SULFATE 0 CUPRIC SULFATE 0 KUPFERSULFAT (GERMAN) 0 ROMAN VITRIOL 0 SULFATE de CUIVRE (FRENCH) 0
TSCA Inventory. DOT CLASSIFICATION: 4.2; Label: Spontaneously Combustible SAFETY PROFILE: Flammable solid when exposed to heat or flame. May spontaneously heat and ignite if stored wet and hot.
CNR100 CAS: 3486-66-6 COPTISINE mf: ClgH14N04 mw: 320.32
HR: 3
SYN: BIS(l,3)BENZODIOXOLO(5,G-A:4',5'-G)QUINOL IZINIUM, 6,7-DIHYDRO-
388
CNR735
CORIANDER OIL
SAFETY PROFILE: A poison by ingestion.
SAFETY PROFILE: When heated to
When heated to decomposition it emits toxic vapors of NO,.
decomposition it emits acrid smoke and irritating fumes.
CNR735 CAS: 8008-52-4 HR: 2 CORIANDER OIL PROP: From steam distillation of ripe fruit of Conandmm sah'vam L (Fam. Umbelhzrae). Colorless liquid; characteristic odor and taste, D: 0.863-0.875, refr index: 1.462 @ 20'.
CNS750 CAS: 50-23-7 HR: 3 CORTISOL mf: C Z I H ~ O N ~ O O ~mw: S 954.97 PROP: Striated blocks from 2-propanol. Mp: 220' (decomp).
SYNS: OIL OF CORIANDER 0 OILS, CORIANDER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
ingestion. Mutation data reported. A skin irritant. When heated to decomposition it emits acrid smoke and fumes. CNR850 HR: D CORN ENDOSPERM OIL PROP: Reddtsh-brown liquid. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. CNSOOO CASE8001-30-7 HR: 1 CORN OIL PROP: Light-yellow, clear, oily liquid; faint characteristic odor. Mp: -lo', flash p: 490'F (CC), d: 0.92, autoign temp: 740'F. From wet milling of Zea m q s (85DIA2 2,70,77). CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Human skin irritant. An experimental teratogen. May be an allergen. Combustible liquid when exposed to heat or flame. Dangerous spontaneous heating may occur during storage if leaks impregnate rags, waste, etc. To fight fire, use Con, dry chemical. CNS100 HR: D CORN SILK and CORN SILK EXTRACT PROP: Extracted from the fresh styles and stigmas of Zea mays L
SYNS: AEROSEB-HC 0 ANTI-INFLAR.liCLATORY HORMONE 0 BARSEB HC 0 CETACORT 0 COBADEX 0 COMPOUND F 0 CORT-DOME 0 CORTISOL ALCOHOL 0 CORTISPRAY 0 DERMACORT 0 EF CORLIN 0 GENACORT 0 HC 0 HEB-CORT 0 HIDROCOLISONA 0 11-P-HYDROCORTISONE 0 HYDROCORTISONE FREE ALCOHOL 0 HYDROCORTISYL 0 HYDROCORTONE 0 17-HYDROXYCORTICOSTERONE 0 11-P-HYDROXYCORTISONE 0 HYTONE LOTION 0 KENDALL'S COMPOUND F 0 NSC-10483 0 OPTEF 0 PERMICORT 0 4-PREGNENE-1 l-P,17-a,21-TRIOL 3,20DIONE 0 REICHSTEIN'S SUBSTAKE hf 0 SCHEROSON F 0 1l-P,17,21-TRIHYDROXYPREGN-4-ENE-3,20DIONE 0 1l-P,17-a-21-TRIHYDROXI-4-PREGNENE3,20-DIONE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by subcutaneous route. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. A steroid. When heated to decomposition it emits very toxic fumes of SO, and NO,. See also CORTISONE.
CNT250 HR: 3 CORUNDUM FUME PROP: Half finely divided alumina, half silica (JPBAA7 69,81,55). SAFETY PROFILE: Poison by intratracheal route. See also ALUMINUM OXIDE (2:3) and SILICA. CNT750 HR: 2 COTTON DUST PROP: IDLH 100 mg/m3. OSHA PEL: TWA 1 mg/m3 (raw dust); 0.2 mg/m3 (yarn manufacturing); 0.75 mg/m3 (slashing and weaving); 0.5 mg/m3 (other operations)
4-COUMARIC ACID
CNU825 389
ACGIH TLV: TWA 0.2 mg/m3 (raw dust) DFG MAK: 1.5 mg/m3 (raw cotton) NIOSH REL: (Cotton Dust) CL 0.200
a dangerous hazard due to spontaneous heating. To fight fire, use COa, dry chemical.
mg/m3 lint-free
CNU750 CAS: 56-72-4 HR: 3 COUMAPHOS mf: Ci4H16C105PS mw: 362.78 PROP: A solid. Mp: 95'. SYNS: AGRIDIP 0 ASUNTHOL 0 BAYER21/199 0
SAFETY PROFILE: Human pulmonary
effects. Causes a mild febrile condition of the lungs resembling metal fume fever. Coarser grades of cotton contain more dust than the finer varieties, and therefore constitute a greater hazard. It is considered an inert dust and indeed it is, within the meaning of the term. However, it can cause some Illness, due to the allergens or fungi in the cotton or on the dust. Workers in processing rooms may develop conjunctivitis or blepharitis from the burned products of the gassing of the double yarn. It is a mild allergen. Inhalation may produce bronchal asthma, sneezing, and eczema in sensitized persons. Moderate fire and explosion hazard when exposed to heat or flame; can react with oxidizing materials. CNT950 HR: D COTTONSEED, MODIFIED PRODUCTS PROP: Extracted from decorticated, partially defatted, cooked, ground cotton-seed kernels. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes. CNUOOO CAS: 8001-29-4 HR: 2 COTTONSEED OIL (unhydrogenated) PROP: Oily, pale-yellow, nearly odorless liquid from seeds of species of Gosypizlm hirszltzlm. Flash p: 486'F (CC), fp: 0-5', d: 0.915-0.921 @ 25'/25', autoign temp: 650'F. SYNS: DEODORIZED WINTERIZED COTTONSEED OIL 0 NCK50168
SAFETY PROFILE: Questionable
carcinogen with experimental tumorigenic data. Experimental teratogenic effects. An allergen. Combustible liquid when exposed to heat or flame. However, if allowed to impregnate rags or oily waste, it can become
BAYMIX 50 0 3-CHLORO-7-HYDROXY-4-METHYLCOUMARIN-0,O-DIETHYLPHOSPHOROTHIOATE 0 3-
CHLORO-7-HYDROXY-4-METHYL-COULMARIN-OESTER wth 0,O-DIETHYL PHOSPHOROTHIOATE 0 0-
~-CHLORO-~-IMETHYL-~-COUMARINYL-O,O-DIETHYL PHOSPHOROTHIOATE 0 3-CHLORO-4-METHYL-7COUMARINYL DIETHYL PHOSPHOROTHIOATE 0 3CHLORO-~-IMETHYL-~-HYDROXYCOUMARIN DIETHYL THIOPHOSPHORIC ACID ESTER 0 3-CHLORO-4METHYLUMBELLIFERONE-0-ESTERwith 0,ODIETHYL PHOSPHOROTHIOATE 0 CUMAFOS (DUTCH) 0 O,O-DIAETHYL-O-(3-CHLOR-4-METHYLCUIMARIN-~-YL)-~~ONOTHIOPHOSPHAT (GERMAN) 0
O,O-DIETHYL-O-(3-CHLOOR-4-METHYL-CUhfARIN-7YL)MONOTHIOFOSFAAT (DUTCH) 0 0,O-DIETHYLO(~-CHLORO-~-METHYJ-~-COUIMARINYL)PHOSPHOROTHIOATE 0 O,O-DIETHYL-O-(3-CHLORO-4METHYLCOUMARINYL-7)THIOPHOSPHATE 0 0,O-
DIETHYL-O-(3-CHLORO-4-METHYL-2HBENZOPYRAN-7-YL)PHOSPHOROTHIOATE 0 0,ODIETHYL-3-CHLORO-4-METHYL-7-UMBELLIFERONE THIOPHOSPHATE 0 O,O-DIETHYL-O-(3-CHLORO-4METHYLUMBELL1FERYL)PHOSPHOROTHIOATE 0
DIETHYL-3-CHLORO-4-METHYLUMBELLIFERYL THIONOPHOSPHATE 0 DIETHYL THIOPHOSPHORIC ACIDESTER of 3-CHLORO-4-METHYL-7-HYDROXYCOUMARIN 0 O,O-DIETILO-(3-CLORO-4-METIL CUIMARIN-~-IL-MONOTIOFOSFATO) (ITALIAN) 0 DIOLICE 0 E S T 17,956 0 MELDONE 0 NCI-CO8662 0 THIOPHOSPHATE de 0,O-DIETHYLE et de 0-(3CHLORO-4-METHYL-7-COUMARINYLE) (FRENCH) 0 UMBETHION
CONSENSUS REPORTS: NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* NCI-CGTR-96,79. EPA Extremely Hazardous Substances List. SAFETY PROFILE: Poison by ingestion, sktn contact, inhalation, and intraperitoneal routes. Mutation data reported. When heated to decomposition, it emits very toxic fumes of SO,, PO,, and C1-. See also COUMARIN.
CNU825 CAS: 7400-08-0 4-COUMARIC ACID mf: C9Hg03 mw: 164.17
HR: 2
390 CNVOOO COUMARIN PROP: Needles. Mp: 210-213'. Crystallizes in anhydrous form from conc hot aq soh, but as monohydrate from dilute aq s o h on slow cooling. Sltly sol in cold water; sol in
hot water, alc, and ether. Practically insol in benzene and ligroin. SYNS: p-COUXUUC ACID 0 p-CUbURIC ACID 0 pHYDROXYCINNAMIC ACID 0 4-HYDROXYCINNAMIC ACID 0 4'-HYDROXYCINNAMIC ACID 0 p-HYDROXYDHENYLACRYLIC ACID 0 P-(I.-HYDROXYPHENYL)ACRYLIC ACID 0 3-(4-HYDROXYPHESYL-2-PROPENOIC ACID
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderarely toxic by intraperitoneal route. Experimental reproductive effects. When heated to decomposition it emits acrid smoke and fumes. See also COUMARIN.
DOT: UN 2022 mfi C7HsO mw: 108.15 PROP: iMixture of isomeric cresols obtained from coal tar, colorless or yellowish to brown-yellow or pinhsh liquid; phenolic odor. Mp: 10.9-35.5', bp: 191-203', flash p: 178'F, d 1.030-1.038 @ 25'/25", vap press: 1 mm @ 38-53', vap d: 3.72. SYNS: ACIDE CRESYLIQUE (FRENCH) 0 BACILLOL 0 CRESOLI (ITALIAN) 0 CRESYLIC ACID 0 HYDROXYTOLUOLE (GERMAN) 0 KRESOLE (GERMAN) 0 KRESOLEN (DUTCH) 0 KREZOL (POLISH) 0 RCRA WASTE NUMBER U052 0 TEKRESOL 0 ar-TOLUENOL 0 TRICRESOL
CONSENSUS REPORTS: Community fight-To-Know List. OSHA PEL: TWA 5 pprn (skin) ACGIH TLV: TWA 5 pprn DFG MAK: (all isomers) 5 pprn (22 mg/m3) NIOSH REL: (Cresol) TWA 10 mg/m3 CNVOOO CAS: 91-64-5 HR: 3 DOT CLASSIFICATION: 6.1; Label: Poison COUMARI N SAFETY PROFILE: A poison by ingestion. mf: C9H602 mw: 146.15 Moderately toxic by s h n contact. Corrosive PROP: Rhombic crystals; fragrant, pleasant to skm and mucous membranes. Systemic odor; burning taste. Mp: 70°, bp: 291.0', vap poisoning has rarely been reported, but it is press: 1 mm @ 106.0'. Sol in EtOH, hot possible that absorption may result in HzO, and alkalies. damage to the kidneys, liver, and nervous SYNS: 2H-l-BENZOPYRAi%2-0NE 0 1,2-BENZOsystem. The main hazard accompanying its PYRONE 0 as-o-COCIMARINIC ACID LACTONE 0 use in industry lies in severe chemical burns COLMARISIC ANHYDRIDE 0 o-HYDROXYCINNAMIC and dermatitis. Flammable when exposed to ACID L4CTONE 0 o-HYDROXYZIMTSAEURE-LACTON heat or flame; can react vigorously with (GERhfAX) 0 NCI-C60297 0 2-OXO-l,2-BENZOPYRAN oxidzing materials. Slightly explosive in the 0 RATTEX 0 TONKA BL4N CAMPHOR form of vapor when exposed to heat or CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal flame. Explosive Range: 1.35% @ 300'F. Limited Evidence IMEMDT 10,113,76. Reacts violently with HN03, oleum, or EPA Genetic Toxicology Program. chlorosulfonic acid. When heated to Reported in EPA TSCA Inventory. decomposition it emits hghly toxic and irritating fumes. To fight fire, use foam, SAFETY PROFILE: Poison by ingestion, C02, dry chemical. See also other cresol intraperitoneal, and subcutaneous routes. entries and PHENOL. Questionable carcinogen with experimental tumorigenic data. Experimental teratogenic effects. Mutation data reported. CNW750 CAS: 108-39-4 HR: 3 Combustible when exposed to heat or m-CRESOL DOT: UN 2076 flame. When heated to decomposition it mf: C7HsO mw: 108.15 emits acrid smoke and fumes. See also PROP: Colorless to yellowish liquid; KETONES and ANHYDRIDES. phenolic odor. Mp: 10.9', bp: 202.8', lel: 1.1% @ 302'F, flash p: 202'F, d: 1.04 @ CNW500 CAS: 1319-77-3 HR: 3 CRESOL
p-CRESOL CNX250 391
22'/4', autoign temp: 1038'F, vap press: 1 mm @ 52.0°, vap d: 3.72. IDLH 250 ppm. SYNS: ~-CRESOLo m-CRESYIICACID 1HYDROXY-~-IMETHYLBENZENE m-HYDROXYTOLUENE 0 m-KRESOL 0 m-METHYLPHENOL 0 3METHYLPHENOL 0 m-OXYTOLUENE 0 RCRA WASTE NUME3ER U052 0 m-TOLUOL
CONSENSUS REPORTS: Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 5 ppm (skin) ACGIH TLV: TWA 5 ppm NIOSH REL: (Cresol) TWA 10 mg/m3 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion, intravenous, intraperitoneal, and subcutaneous routes. Moderately toxic by skin contact. Severe eye and skin irritant. An experimental teratogen. Human mutation data reported. Questionable carcinogen with experimental neoplastigenic data. Flammable when exposed to heat or flame. Moderately explosive in the form of vapor when exposed to heat or flame. See also other cresol entries and PHENOL.
CNXOOO CAS: 95-48-7 HR: 3 0-CRESOL DOT: UN 2076 mf: C7HsO mw: 108.15 PROP: Crystals or liquid darkening with exposure to air and light. Mp: 30°, bp: 191', flash p: 178'F, d: 1.05 @ 20°/4', autoign temp: 1110°F, vap press: 1 mm @ 38.2', vap d: 3.72, lel: 1.4% @ 300°F. IDLH 250 PPm.
SYNS: 2-CRESOL 0 0-CRESYLICACID 0 1-HYDROXY2-METHYLBENZENE 0 o-HYDROXYTOLUENE0 oKRESOL (GERMAN) 0 o-METHYLPHEXOL 0 2METHYLPHENOL 0 ORTHOCRESOL 0 oOXYTOLUENE RCRA WASTE NUIMBER U052 0 oTOLC'OL
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Community Right-To-Know List. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. OSHA PEL: TWA 5 ppm (shn)
ACGIH TLV: TWA 5 pprn NIOSH REL: (Cresol) TWA 10 mg/m3 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion,
inhalation, subcutaneous, intravenous, and intraperitoneal routes. Moderately toxic by skin contact. A severe eye and s h n irritant. Human mutation data reported. Questionable carcinogen with experimental neoplastigenic data. Flammable when exposed to heat, flame, or oxidants. To fight fire, water may be used to blanket fire; foam, fog, mist, dry chemical. See also other cresol entries and PHENOL.
CNX250 CAS: 106-44-5 HR: 3 p-CRESOL DOT: UN 2076 mf: C7H80 mw: 108.15 PROP: Found in a score of essential oils, includmg ylang-ylang and oil of jasmine (FCTXAV 12,385,74). Crystals; phenolic odor. Mp: 35.5', bp: 201.8', lel: 1.1% @ 302'F, flash p: 202'F, d: 1.0341 @ 20°/4', autoign temp: 1038'F, vap press: 1 mm @ 53.0', vap d: 3.72. IDLH 250 ppm. SYNS: 4-CRESOL 0 p-CRESYLIC ACID 0 I-HYDROXY4-METHYLBENZENE 0 p-HYDROXYTOLUENE 0 4HYDROXYTOLUENE 0 p-KRESOL 0 l-METHYI-4HYDROXYBENZENE 0 p-METHYLPHENOL 0 4METHYLPHENOL 0 p-OXYTOLUENE 0 PARAMETHYL PHENOL 0 RCRA WASTE NUMBER U052 0 p-TOLUOL 0 p-TOLYL ALCOHOL
CONSENSUS REPORTS: Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 5 pprn (shn) ACGIH TLV: TWA 5 ppm NIOSH REL: (Cresol) TWA 10 mg/m3 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion, s h n contact, subcutaneous, intravenous, and intraperitoneal routes. A severe s h n and eye irritant. Questionable carcinogen with experimental neoplastigenic data by itself and with 7,12-dirnethyl benz(a)anthracene. Combustible when exposed to heat or flame. Moderately explosive in the form of
392 COB250 CROTONALDEHYDE vapor when exposed to heat or flame. To fight fire, use CO2, dry chemical, alcohol foam. See also other cresol entries and PHENOL. COB250 CAS: 4170-30-3 HR: 3 CROTONALDEHYDE DOT: UN 1143 mf: C4H60 mw: 70.09 PROP: Water-white, mobile liquid; pungent suffocating odor. Bp: 104', fp: -76.0', lel: 2.1%, uel: 15.5%, flash p: 55'F, d: 0.853 @ 20'/20', vap d: 2.41, autoign temp: 405'F. IDLH 50 ppm. SYNS: 2-BUTENAL 0 CROTONALDEHYDE,stabilized (DOT) 0 CROTONIC ALDEHSDE 0 KROTONALDEHW (CZECH) 0 P-METHYLACROLEIN 0 RCRA WASTE NUMBER U053
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 2 ppm ACGlH TLV: STEL CL 0.3 ppm (skm); Animal Carcinogen DFG MAK: Suspected Carcinogen DOT CLASSIFICATION: 3; Label: Flammable Liquid, Poison SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. Poison by ingestion and inhalation. Mutation data reported. An eye, skin, and mucous membrane irritant. A lachrymating material that can cause corneal burns and is very dangerous to the eyes. Caution: Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Extremely irritating to eyes, slim, mucous membranes. When necessary, the lachrymatory effect of the vapors may be counteracted by ammonia fumes. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. Reacts violently with 1,3butadlene. Violent hypergolic reaction with concentrated nitric acid. When heated to decomposition it emits acrid smoke and fumes. See also ALDEHYDES.
COB260 CAS: 123-73-9 HR: 3 (E)-CROTONALDEHYDE mf: C4H1j0 mw: 70.10 PROP: Water-white, mobile liquid; pungent, suffocating odor. Mp: -69', bp: 102.2', fp: -76.0°, lel: 2.1%, uel: 15.5%, flash p: 55'F, d: 0.853 @ 2Oo/2O0, vap d: 2.41, autoign temp: 450'F. Moderately sol in H20. SYNS: ALDEHYDE CROTONIQUE (FRENCH) trans2-BUTENAL 0 @)-2-BUTENAL 0 CROTONAL 0 CROTONALDEHYDE 0 CROTONIC ALDEHYDE 0 1,2ETHANEDIOL DIPROPANOATE (9Cl) ETHYLENE GLYCOL DIPROPIONATE (8CI) 0 ETHYLENE PROPIONATE 0 P-METHYL ACROLEIN 0 NCI-C56279 0 PROPYLENE ALDEHYDE 0 RCR4 WASTE NUMBER U053 0 TOPANEL CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 2 ppm ACGIH TLV: TWA 2 ppm DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans SAFETY PROFILE: Suspected carcinogen. A poison by ingestion, subcutaneous, and intraperitoneal routes. Mutation data reported. A lachrymating material that is very dangerous to the eyes. Human respiratory system irritant by inhalation. Can cause corneal burns and is irritating to the skin. In case of contact, immediately flush the skin or eyes with water for at least 15 minutes and get medlcal attention. See also ALDEHYDES. Dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, Con, dry chemical. Incompatible with 1,3-butadiene and oxidizing materials. When heated to decomposition it emits acrid smoke and fumes.
COB500 CAS: 3724-65-0 HR: 3 CROTONIC ACID DOT: UN 2823 mf: C4H602 mw: 86.10 PROP: Colorless, needle-like crystals. Bp: 185', mp: 72O, flash p: 190'F (COC), d: 1.018 @ 15'/4', vap press: 0.19 mm @ Z O O , vap d: 2.97.
CRUDE SHALE OILS COD750 393 SYNS: a-BUTENOIC ACID 0 2-BUTENOIC ACID 0
CONSENSUS REPORTS: Reported in EPA
CROTONIC ACID, solid 0 a-CROTONIC ACID 0 3METHYLACRYLIC ACID 0 P-METHYLACRYLICACID
TSCA Inventory.
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Poison by
intraperitoneal route. Moderately toxic by ingestion, skin contact, and subcutaneous routes. A powerful corrosive and irritant. Flammable when exposed to heat or flame; can react with oxidizing materials. To fight fire, use alcohol foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. COB750 CAS: 623-70-1 HR: 3 a-CROTONIC ACID ETHYL ESTER DOT: UN 1862 mfi CGHIOOZ mw: 114.16 PROP: Colorless, monoclinic prisms or water-white liquid; pungent odor. Mp: 45" (solid), bp: 209" (solid), 137" @quid), flash p: 36.0°F, d: 0.9207 @ 2Oo/2O0, vap d: 3.93. SYNS: 2-BUTENOIC ACID, ETHYL ESTER, (E-(9CI,! 0 trans-2-BUTENOIC ACID ETHYL ESTER 0 CROTONATE d'ETHYLE (FRENCH) 0 ETHYL (E-2-BUTENOATE 0 ETHYLCROTONATE 0 ETHYL (E)-CROTONATE0 ETHYL trans-CROTONATE 0 ETHYL CROTONATE
SAFETY PROFILE: Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
COC500 CAS: 503-17-3 HR: 3 CROTONYLENE DOT: UN 1144 mf: CH3CCCH3 mw: 54.09 PROP: Liquid. Mp: -32.8", bp: 27", flash p: <-4'F, lel: 1.4%, d: 0.688 @ 25", vap d: 1.91. SYNS: 2-BUTYNE 0 DIMETHYLACETYLENE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: A simple asphyxiant. Very dangerous fire hazard when exposed to heat or flame; can react with oxidzing materials. Moderately explosive in the form of vapor when exposed to heat or flame. To fight fire, use foam, COZ,dry chemicals. See also ACETYLENE COMPOUNDS and ARGON (for a description of simple asphyxiants).
(DOT)
CONSENSUS REPORTS: Reported in EPA
HR: 3
DOT CLASSIFICATION: 3; Label:
COD750 CAS: 68308-34-9 CRUDE SHALE OILS DOT: UN 1288
Flammable Liquid
SYNS: BLUE OIL 0 GREEN OIL 0 RAW SHALE OIL 0
SAFETY PROFILE: Moderately toxic by ingestion and probably by inhalation. A shn,
SHALE OIL (DOT) 0 UNFINISHED LUBRICATING OIL
TSCA Inventory.
mucous membrane, and severe eye irritant. Very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. T o fight fire, use foam, C02, or dry chemical. See also ESTERS. When heated to decomposition it emits acrid smoke and fumes. COB900 CAS: 623-68-7 HR: 2 CROTONIC ANHYDRIDE mf: CsH1003 mw: 154.18 SYNS: ANHYDRID KYSELINY KROTONOVE 0 2BUTEXOIC ACID, AIVHYDRIDE (9Ca 0 CROTONIC ACID ANHYDRIDE
CONSENSUS REPORTS: IARC Cancer Review: Group 1 IMEMDT 7,339,87; Human Sufficient Evidence IMEMDT 35,161,85; Animal Lmited Evidence IMEMDT 35,161,85; Animal Sufficient Evidence IMEMDT 3,22,73. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mildly toxic by ingestion, skin contact, and intraperitoneal routes. A skin irritant. Experimental reproductive effects. Mutation
394 COEOOO CRYPTOHALITE data reported. Flammable when exposed to heat and flame. When heated to decomposition it emits acrid smoke and fumes. COEOOO CAS: 1309-32-6 HR: 3 CRYPTOHALITE DOT: UN 2854 mf: FbSi*2H4N mw: 178.19 PROP: Mp: subl, d: 2.01. SYNS: AMMONIUhI FLUOROSILICATE (DOT) 0 AMMONIUM FLUOSILICATE AMhIONIUhf HEXAFLUOROSILICL4TE 0 AMMONIUM SILICOFLUORIDE 0 ,%MMONIUM SILICON FLUORIDE 0 DL4hIMONIUM FLUOSILICATE 0 DIAMMOSIUM HEXAFLUOROSILICATE(2-) 0 DMMMONIURI SILICON HEXAFLUORIDE 17 FLUOSILICATE de AMMONIUM (FRENCH)
OSHA PEL: TWA 2.5 mg(F)/m3 ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3
mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift. NIOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m3 SAFETY PROFILE: Poison by ingestion and subcutaneous routes. See also HEXAFLUOROSILICATE (2-) DIHYDROGEN and FLUORIDES. When heated to decomposition it emits very toxic fumes of F-, NH3, and NO,. COE175 CAS: 8007-87-2 HR: 1 CUBEB OIL PROP: From steam disullation of mature, unripe fruit ofpiper cubeba L (Fam. Piperaceae). Colorless to light green liquid; spicy odor, slt acrid taste. D: 0.898-0.928, refr index: 1.492-1.502 @ 20'. Sol in fixed oils, mineral oil; insol in glycerin, propylene glycol. SYNS: OIL OF CUBEB 0 OILS, CUBEB CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes. COE500 CAS: 122-03-2 CUMALDEHYDE
HR: 2
mf: C I O H I ~ O mw: 148.22 PROP: Found in at least 50 essential oils, such as cumin, eucalyptus species, cinnamon, boldo, and rue, and as main constituent of oil of Pectispapposa ham and grq (FCTXAV 12,385,74).Colorless to paleyellow liquid; pungent odor of cumin. D: 0.976-0.980, refr index: 1.529-1.534, flash p: 199'F. Sol in alc, ether; insol in water. SYNS: p-CUMIC ALDEHYDE 0 CUMINALDEHYDE 0 CUhlINIC ALDEHYDE (FCC) 0 CUMINYL ALDEHYDE 0 FEW. No. 2341 0 p-ISOPROPYLBENZALDEHYDE 0 4-ISOPROPYLBENZALDEHYDE 0 p-ISOPROPYLBENZENECARBOXALDEHYDE 0 4-(1-METHYLETHYL)BENWLDEHYDE (9CI) CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and skin contact. A skm irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.
COE750 CAS: 98-82-8 HR: 3 CUMENE DOT: UN 1918 mf: C ~ H U mw: 120.21 PROP: Colorless liquid. Mp: -96.0°, bp: 152O, flash p: 11l'F, d: 0.864 @ 20'/4', vap press: 10 mm @ 38.3', autoign temp: 795'F, lel: 0.9%, uel: 6.5%, vap d: 4.1. IDLH 900 ppm [1O%LEL] . SYNS: BENZENE ISOPROPYL 0 CUM 0 CUbfEEN (DUTCH) 0 2-FENILPROPANO (ITALIAN) 0 2-FENYLP R O P M N (DUTCH) 0 ISOPROPILBENZENE (ITL4LMN) 0 ISOPROPYLBENZEEN (DUTCH) 0 ISOPROPYL BENZENE 0 ISOPROPYLBENZOL 0 ISOPROPYLBENZOL (GERMAN) 0 2-PHENYLPROPANE 0 RCR4 WASTE NUMBER U055
CONSENSUS RE PORTS: Community Eght-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 50 pprn (skin) ACGIH TLV: TWA 50 pprn DFG MAK: 50 pprn (250 mg/m3) DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by ingestion. M d l y toxic by inhalation and skm
CUPRIC ACETOARSENITE
contact. Human systemic effects by inhalation: an antipsychotic, unspecified changes in the sense of smell and respiratory system. An eye and skin irritant. Potential narcotic action. Central nervous system depressant. There is no apparent difference between the toxicity of natural cumene and that derived from petroleum. See also BENZENE and TOLUENE. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. Violent reaction with HN03, oleum, chlorosulfonic acid. To fight fKe, use foam, C02, dry chemical. COFOOO CAS: 93-53-8 HR: 2 CUMENE ALDEHYDE mf: C9HloO mw: 134.19 PROP: Colorless liquid; floral odor. D: 0.998-1.006, refr index: 1.515-1.520, flash p: 156'F. Sol in fixed oils; sltly sol in propylene glycol; insol in glycerin. SYNS: FEMA No. 2886 0 a-FORMYLETHYLBENZENE 0 HYACINTHAL 0 HYDRATROP ALDEHYDE 0 HYDRATROPIC ALDEHYDE 0 &METHYL PHENYLACETALDEHYDE 0 a-METHYL-Ct-TOLUICALDEHYDE 0 2-PHENYLPROPANAL 0 a-PHENYLPROPIONALDEHYDE 0 2-PHENYLPROPIONALDEHYDE(FCC)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.
COF325 CAS: 8014-13-9 HR: 2 CUMIN OIL PROP: From steam disdation of Cuminzrm qminum L Lght-yellow to brown liquid; strong odor. D: 0.905-0.925, refr index: 1.501 @ 20". Sol in fixed oils, mineral oil; very sol in glycerin, propylene glycol. SYNS: cumm 0 OILS, CUMIN CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion and s h n contact. A s h n irritant. Mutation data reported. When heated to
COF500 395
decomposition it emits acrid smoke and irritating fumes. COF350 CAS: 479-13-0 HR: D CUMOESTEROL mfi Cl&&Os mw: 268.23 PROP: Crystals. Mp: 385' (sublimes @ 325"). Sltly sol in alkaline water, methanol, chloroform, ether, carbon tet, and benzene. Insol in acidlfied water and pet ether. SYNS: 6H-BENZOFTiRO(3,2-c)(l)BENZOPYRAN-6ONE, 3,9-DIHDYROXY- 0 COUMESTROL 0 CUMOSTROL
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An experimental
teratogen. Other experimental reproductive effects. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. COF500 CAS: 12002-03-8 HR: 3 CUPRIC ACETOARSENITE mf: C4H&S6cU4016 mW: 1013.78 PROP: Emerald-green powder. SYNS: (ACETATO)(TRIMETAARSENITO)DICOPPER 0 ACETOARSENITE de CUIVRE (FRENCH) 0 BASLE GREEN 0 C.I. 77410 0 C.I. PIGMENT GREEN 21 (9CI) 0 COPPER ACETOARSENITE (DOT) 0 COPPER ACETOARSENITE, sohd (DOT) 0 EMERALD GREEN 0 ENT 884 0 FRENCH GREEN 0 GENCINE PARIS GREEN 0 IMPERIAL GREEN 0 KINGS GREEN 0 MEADOW GREEN 0 MINERAL GREEN 0 MITIS GREEN 0 MOSS GREEN 0 MOUNTAIN GREEN 0 NEUWIED GREEN 0 NEW GREEN 0 ORTHO P-G BAIT 0 PARIS GREEN PARROT GREEN 0 PATENT GREEN 0 POWDER GREEN 0 SCHW'EINFURTERGRUEN 0 SCHWEINFURT GREEN 0 SOWEiUG & CUTWORM BAIT 0 SWEDISH GREEN 0 VIENNA GREEN
CONSENSUS REPORTS: EPA Extremely Hazardous Substances List. Arsenic and its compounds, as well as copper and its compounds, are on the Community RightT o - K ~ o wL s t . OSHA PEL: TWA 0.5 mg(As)/m3 DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Poison by ingestion and possibly other routes. An insecticide. When heated to decomposition it emits very toxic fumes of As. See also ARSENIC
396 COF675 CUPRIZONE COMPOUNDS and COPPER COMPOUNDS. COF675 CAS: 370-81-0 HR: D CUPRIZONE mf: C14H2zN402 mw: 278.40 SYNS: BISCYCLOHEXANONE OXALDIHYDRAZONE CUPRIZASE 0 ETHANEDIOIC ACID BIS(CYCL0HEXYLIDENE HYDRAZIDE) 0
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also OXALATES.
COG000 CAS: 8024-37-1 HR: 2 CURCUMIN SYNS: C.I. 75300 0 CURCUMA OIL 0 CLRCUMINE 0 NCI-C60015 0 TURMERIC OIL 0 TURMERIC OLEORESIN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by intraperitoneal route. A skin irritant. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
COHO00 HR: 3 CUTTING OILS SAFETY PROFILE: Often carcinogenic. The cause of "cutting oil" dermatitis is generally due to an insoluble oil. However it can occasionally be caused by a soluble oil. Many have looked for a causative factor other than the oil itself. Bacteria have frequently been blamed, although insoluble oils are usually sterile, while the soluble oils may contain bacteria. The metal slivers that occur in these oils after use have also been blamed as well as the sulfur, chlorine, and inhibitors that they contain. The oil itself can plug the pores and form boils. Combustible when exposed to heat or flame. See also MINERAL OIL.
COH500 CAS: 420-04-2 HR: 3 CYANAM IDE mf: CHZNZ mw: 42.05 PROP: Deliquescent crystals. Mp: 45', bp: 260°, flash p: 285'F, d: 1.282, vap d: 1.45. SYNS: AMIDOCYANOGEN 0 CARBAhtONITRILE 0 CARBIMIDE 0 CYANOAMINE 0 CYANOGENAMIDE 0 CYANOGEN NITRIDE 0 HYDROGEN CYANAMIDE I3 UShF EK-1995
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community bghtT o - h o w List. OSHA PEL: TWA 2 mg/m3 ACGIH TLV: TWA 2 mg/m3 SAFETY PROFILE: Poison by ingestion, inhalation, and intraperitoneal routes. Moderately toxic by s h n contact. Experimental reproductive effects. Combustible when exposed to heat or flame. To fight fire, use COz, dry chemical. Thermally unstable. Contact with moisture (water), acids, or alkalies may cause a violent reaction above 40'. Concentrated aqueous solutions may undergo explosive polymerization. Mixture with 1,2phenylenediamine salts may cause explosive polymerization. When heated to decomposition or on contact with acid or acid fumes, it emits toxic fumes of CN- and NO,. See also CYANIDE and AMIDES.
C01250 CAS: 917-61-3 HR: 3 CYANIC ACID, SODIUM SALT DOT: UN 2207/UN 2478/UN 3080 mf: CNO*Na mw: 65.01 SYNS: CYANSAN 0 SAN-CYAN 0 SODIUM ISOCYAVATE 0 WEECON 0 ZASSOL
CONSENSUS REPORTS: Cyanide and its
compounds are on the Community fightTo-Know List. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD (UN 2207); DOT Class: 6.1; Label: Poison (UN 2206); DOT Class: 6.1; Label: Poison, Flammable Liquid (UN 3080); DOT Class: 3; Label: Flammable Liquid, Poison (UN 2478)
CYANIDE SAFETY PROFILE: Poison by ingestion, intraperitoneal, and intramuscular routes. Human systemic effects by ingestion: weight loss, changes in the visual field, and other eye effects. See also CYANATES. When heated to decomposition it emits very toxic fumes of CN- and Na2O.
co1500 CAS: 57-12-5 CYANIDE DOT: UN 1935 mf: CNmw: 26.02
HR: 3
SYNS: CARBON NITRIDE ION (CNl-) 0 CYANIDE(Chl ) 0 CYANIDE, dn (UN 1588) 0 CYANIDE -4NION 0 CYANIDE ION CYANIDE(CN~-)ION CYASIDE SOLUTIONS (DOT) 0 CYANURE 0 HYDROCYANIC ACID, IOY(CN~-) ISOCYANIDE NUMBER PO30
RCRA WASTE
CONSENSUS REPORTS: Cyanide and its compounds are on the Community &ghtTo-Ihow List. OSHA PEL: TWA 5 mg(CN)/m3 ACGIH TLV: CL 5 mg/m3 (skin) DFG MAK: 5 mg/m3 NlOSH REL: (Cyanide) TWA CL 5 mg/m3/ 1OM DOT CLASSIFICATION: 6.1; Label: Poison, KEEP AWAY FROM FOOD SAFETY PROFILE: Very poisonous by most routes. Cyanide directly stimulates the chemoreceptors of the carotid and aortic bodies with a resultant hyperpnea (increase in the depth and rate of respiration). Cardac irregularities are often noted, but the heart invariably outlasts the respirations. Death is due to respiratory arrest of central origm. It can occur withn seconds or minutes of the inhalation of htgh concentrations of HCN gas. Because of slower absorption, death may be more delayed after the ingestion of cyanide salts, but the critical events s d l occur within the first hour. Two other sources of cyanide have been responsible for human poisoning: the naturally occurring amygdalin and the drug nitroprusside. Amygdalin is a cyanogenic glycoside found in apricot, peach, and similar fruit pits and in sweet almonds (Sayre and Kaymakcalan,
C01500 397
1941). It is a chemical combination of glucose, benzaldehyde, and cyanide from which the latter can be released by the action of p-glucosidase or emulsion. Although these enzymes are not found in mammalian tissues, the human intestinal microflora appears to possess these or sirmlar enzymes capable of effecting cyanide release resulting in human poisoning. For this reason, amygdalin may be as much as 40 times more toxic by the oral route as compared with intravenous injection. Amygdalin is the major ingredient of Laetrile, and this alleged anticancer drug has also been responsible for human cyanide poisoning. An ethcal drug that may also cause cyanide poisoning in overdose is the potent vascular smooth-muscle relaxant sodlum nitropmsside. Although nitroprusside is related chemically to ferricpanide, unlike the latter it penetrates into erythrocytes and reacts with hemoglobin to release its cyanide (Smith and Kruszyna, 1974). Fortunately, the therapeutic margin for nitroprusside appears to be quite large. Cyanide is commonly found in certain rat and pest poisons, silver and metal polishes, photographic solutions, and fumigating products. Compounds such as potassium cyanide can also be readily purchased from chemical stores. Cyanide is r e a d y absorbed from all routes, including the skin, mucous membranes, and by inhalation, although alkali salts of cyanide are toxic only when ingested. Death may occur with ingestion of even small amounts of sodlum or potassium cyanide and can occur w i t h minutes or hours depending on route of exposure. Inhalation of toxic fumes represents a potentially rapidly fatal type of exposure. A blood cyanide level of greater than 0.2 pg/mL is considered toxic. Lethal cases have usually had levels above 1 pg/mL. Clinically, cyanide poisoning is reported to produce a bitter, almond odor on the breath of the patient; however, only a small proportion of the population is genetically
E
398 CON750 CYANO(4-FLUORO-3-PHENOXYPHENable to discern t h s characteristic odor. Typically, cyanide has a bitter, burning taste, and, following poisoning, symptoms of salivation, nausea without vomiting, anxiety, confusion, vertigo, giddiness, lower-jaw stiffness, convulsions, opisthotonos, paralysis, coma, cardac arrhythmias, and transient respiratory stimulation followed by respiratory failure may occur. Bradycardia is a common fm&ng, but in most cases heartbeat usually outlasts respiration (W‘exler et a/., 1947). A prolonged expiratory phase is considered to be characteristic of cyanide poisoning. (Casarett and Doull’s, Toxicology, The Basic Science of Poisons 2nd ed. Doull, Klaassen and Amdur (eds), Macmillan Pub. Co. Inc. New York, NY). The volatile cyanides resemble HCN physiologically, inhbiting tissue oxidation and causing death through asphyxia. Cyanogen is probably as toxic as HCN; the nitriles are generally considered somewhat less toxic, probably because of their lower volaulity. The non-volade cyanide salts appear to be relatively nontoxic systemically, so long as they are not ingested and care is taken to prevent the formation of HCN. Workers, such as electroplaters and picklers, who are dady exposed to cyanide solutions may develop a “cyanide” rash, characterized by itchng, and by macular, papular, and vesicular eruptions. Frequently there is secondary infection. Exposure to small amounts of cyanide compounds over long periods of time is reported to cause loss of appetite, headache, weakness, nausea, dizziness, and symptoms of irritation of the upper respiratory tract and eyes. See also specific cyanide compounds. Flammable by chemical reaction with heat, moisture, acid. Many cyanides rather easily evolve HCN, a flammable gas that is highly toxic. Carbon &oxide from the air is sufficiently acidic to liberate HCN from cyanide solutions. Reaction with hypochlorite solutions may be violent at pH 10.0-10.3. Cyanides explode if melted with nitrites or chlorates at about 450’. Violent
reaction with F2, Mg, nitrates, HN03, nitrites. Metal cyanides are easily oxidized and may be thermally unstable. N-cyano derivatives may be reactive or unstable. Many organic nitriles can be very reactive under the right conditions. When heated to decomposition or on contact with acid, acid fumes, water, or steam, cyanides emit toxic and flammable vapors of CN-. See also HYDROCYANIC ACID.
CON750 HR: D CYANO(4-FLUORO-3-PHENOXYPHENY L)-METHYL-3-(2,2-DICHLOROETHENYL)-P,P-DIMETHYLCYCLOPROPANE-CARBOXYLATE SAFETY PROFILE: When heated to decomposition emits toxic fumes of CN-, F-, and C1-. COO000 CAS: 460-19-5 HR: 3 CYANOGEN DOT: UN 1026 mf: C2Nz mw: 52.04 PROP: Colorless gas; pungent odor. Mp: -34.4’, bp: -21.0°, d: 0.866 @ 17’/4’, lel: 6.6%, uel: 32%, vap d: 1.8. SYNS: CARBON NITRIDE
0
CYANOGENE (FRENCH)
L3 CYAWOGEN GAS (DOq 0 DICYANOGEK 0
ETHANEDINITRILE 0 NITRILOACETONITRILE 0 OXALIC ACID DINITRILE 0 OXALONITRILE 0 OXALYL CYANIDE L3 PRUSSITE 0 RCRA WASTE NUR.IBER PO31
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community k g h t To-Know List. OSHA PEL: TWA 10 pprn ACGIH TLV: TWA 10 pprn DFG MAK: 10 pprn (22 mg/m3) DOT CLASSIFICATION: 2.3; Label: Poison Gas, Flammable Gas SAFETY PROFILE: A poison by subcutaneous and possibly other routes. Moderately toxic by inhalation. Human systemic effects by inhalation: damage to the olfactory nerves and irritation of the conjunctiva. A systemic irritant by inhalation and subcutaneous routes. A human eye
CYANOGEN IODIDE
irritant. Very dangerous fire hazard when exposed to heat, flames (sparks), or oxidizers. To fight fire, stop flow of gas. Potentially explosive reaction with powerful oxidants (e.g., dichlorine oxide, fluorine, oxygen, ozone). When heated to decomposition or on contact with acid, acid fumes, water, or steam will react to produce highly toxic fumes of NO, and CN-. See also other cyanogen entries and CYANIDE. COO500 CAS: 506-68-3 HR: 3 CYANOGEN BROMIDE DOT: UN 1889 mf: CBrN mw: 105.93 PROP: Colorless needles. Mp: 52O, bp: 61.6', d: 2.015 @ 2Oo/4O, vap press: 100 mm @ 22.6'. SYNS: BROMINE CYANIDE 0 BROMOCYAN 0 BROMOCYANOGEN 0 BROMURE de CYANOGEN (FRENCH) 0 CAMPILIT 0 CYANOBROMIDE 0 CYANOGEN rMONOBR0hIIDE 0 RCR4 WASTE NUiMBER U246 0 TL 822
CONSENSUS REPORTS: Cyanide and its compounds are on the Community kghtTo-Know List. EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison, Corrosive SAFETY PROFILE: A human and experimental poison by inhalation. Corrosive. When heated to decomposition it emits very toxic fumes of CN- and Br-. Possibly unstable. See also other cyanogen entries; CYANIDE; and BROMIDES.
COO750 CAS: 506-77-4 HR: 3 CYANOGEN CHLORIDE DOT: UN 1589 mf: CClN mw: 61.47 PROP: Colorless liquid or gas; lachrymatory and irritating odor. Mp: -6.5', bp: 13.1', d: 1.218 @ 4'/4O, vap press: 1010 mm @ 20°, vap d: 1.98. SYNS: CHLORCYAN 0 CHLORINE CYANIDE 0 CHLOROCYAN OCHLOROCYANIDEU CHLOROCYANOGEN 0 CHLORURE de CYANOGENE 0 CYANOGEN CHLORIDE (ACGIH,OSHA) 0 CYANOGEN
COPOOO 399
CHLORIDE, inhibited (DOT) 0 RCRA WASTE NUMBER PO33
CONSENSUS REPORTS: Cyanide and its compounds are on the Community kghtTo-Know List. Reported in EPA TSCA Inventory. OSHA PEL: CL 0.3 ppm ACGIH TLV: CL 0.3 ppm DOT CLASSIFICATION: 2.3; Label: Poison Gas, Flammable Gas SAFETY PROFILE: Poison by ingestion, subcutaneous, and possibly other routes. Toxic by inhalation. Human systemic effects by inhalation: lachrymation, conjunctiva irritation, and chronic pulmonary edema or congestion. A primary irritant. A severe human eye irritant. An insecticide. Flammable when exposed to heat or flame. When heated to decomposition or on contact with water or steam, it will react to produce highly toxic and corrosive fumes of C1-, CN-, and NO,. See also other cyanogen entries, CYANIDE, and CHLORIDES.
COPOOO CAS: 506-78-5 HR: 3 CYANOGEN IODIDE mf: CIN mw: 152.92 PROP: Colorless solid. Mp: 146.5', vap press: 1 mm @ 25.2'. SYNS: IODINE CYANIDE 0 JODCYAN CONSENSUS REPORTS: Cyanide and its compounds are on the Community RightTo-Ihow List. EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. ACGIH TLV: Proposed: (inhalable fraction) 0.1 mg/m3; Not Classifiable as a Human Carcinogen) DOT CLASSIFICATION: 6.1; Label: Poison, KEEP AWAY FROM FOOD SAFETY PROFILE: A poison by ingestion and subcutaneous routes. Violent reaction with P. See other cyanogen entries; CYANIDE and IODIDES. When heated to decomposition it emits very toxic fumes of NO,, CN-, and I-.
400
COP525 5-CYANO-3-INDOLYL ISOPROPYL KETONE
COP525 CAS: 17380-21-1 HR: 3 5-CYANO-3-INDOLYL ISOPROPYL KETONE mf: C13H12N20 mw: 212.27 SYNS: INDOLE-5-CARBONITRILE,3-(2-METHYLPROPI0NYL)- 0 3-(2-~~ETHYLPROPIONYL)-5INDOLECARBONITRILE
COR800 CAS: 1067-47-6 HR: 1 (3-CYANOPROPYL) TRIETHOXYSILANE mfi C10H21N03Si mw: 231.41 SYNS: BUTYRONITRILE, 4-(TRIETHOXYSILYL)-0 SILANE, (3-CYANOPR0PYL)TRIETHOXY- 0 SILANE, TRIETHOXY(3-CYANOPR0PYL))0 TRIETHOXY-3KYANPROPYLSILAN
DOT CLASSIFICATION: 3; Label:
CONSENSUS REPORTS: Reported in EPA
Flammable Lquid
TSCA Inventory.
SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
SAFETY PROFILE: Mddly toxic by ingestion. A skin irritant. When heated to decomposition it emits toxic fumes of NO, and Si.
COP550 CAS: 17380-19-7 HR: 3 5-CYANO-34NDOLYLMETHYLKETONE mf: CllH8N20 mw: 184.21 SYNS: 3-ACETYLINDOLE-5-CARBONITRILE 0 INDO-
COUOOO CAS: 14901-08-7 HR: 3 CYCASIN mf: C~Hi6N207 mw: 252.26 PROP: A solid. Mp: 154' (decomp) SYNS: CYCAS REVOLUTA GLUCOSIDE 0 CYKAZINE
LE-5-CARBONITRILE, 3-ACETYL
DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,.
COQ390 HR: D (+)CYANO(3-PHENOXY PHENYL)METHYL(f)-1-(DIFLUOROMETHOXY)-a-(l -METHYLETHYL)BENZENEACETATE SYN: FLUCYTHRINATE SAFETY PROFILE: When heated to decomposition emits toxic fumes of CN-,
F-. COR500 CAS: 1067-99-8 HR: 2 (3-CYANOPR0PYL)DIETHOXY(METHYL) SILANE mfi CsHt9NOzSi mw: 201.38 SYNS: BUTYRONITRILE, 4-(DIETHOXYMETHYLSIL X)-L3 DIETHOXY-3-KYANPROPYMETHYLSILAN 0 SIWVE, (3-CYANOPROPYL)DIETHOXY@ETHYL)-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A skin irritant. When heated to
decomposition it emits toxic fumes of NO, and Si.
0 P-d-GLUCOSYLOXYAZOXYMETHAPU'E 0 METHYLAZOXYMETHANOL GLUCOSIDE 0 METHYLAZOXYMETHANOL-P-d-GLUCOSIDE0 (METHYL-ONN-
AZOXY)METHYL~-d-GLUCOPYR4NOSIDE
CONSENSUS REPORTS: EPA Genetic Toxicology Program. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Human Inadequate Evidence IMEMDT 10,121,76; Animal Sufficient Evidence IMEMDT 10,121,76; IMEMDT 1,157,72. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. A poison by ingestion. An experimental teratogen. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
COU500 CAS: 103-95-7 HR: 2 CYCLAMEN ALDEHYDE mf: C13H180 mw: 190.31 PROP: Colorless liquid; strong, floral odor. D: 0.946-0.952, refr index: 1.503-1.508. Sol in fured oils; insol in propylene glycol, glycerin. SYNS: ALDEHYDE B 0 CYCLtlUL 0 FEMA No. 2743 0 p-ISOPROPYL-cch.fETHYLHYDROCI~~A~IC ALDEHYDE 0 p-ISOPROPYLa-METHYLPHENYLPROPYL ALDEHYDE 0 a-METHYL-p-ISOPROPYLHYDROCINNAMALDEHYDE 0 2-METHYL3-@-ISOPROPYLPHENYL)PROPIONALDEHYDE
CYCLOHEXANE CPBOOO 401 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A human skin irritant. See also ALDEHYDES. When heated to decomposition it emits acrid smoke and irritating fumes.
COU510 CAS: 7149-24-8 HR: 1 CYCLAMEN ALDEHYDE DIETHYL ACETAL mf: CI~HZEOZ mw: 264.45 SYNS: HYDROCINNAMALDEHYDE,p-ISOPROPYLaMETHYL-, DIETHYL ACETAL 0 a-METHYL-p-ISOPROPYL HYDROCINNAMIC ALDEHYDE DIETHYL ACETAL
heated to decomposition it emits acrid smoke and fumes.
COY100 CAS: 12125-77-8 HR: 3 CYCLOHEPTATRIENE MOLYBDENUM TRICARBONYL mf: C~oH&foOs mw: 272.12 PROP: Red hexagonal prisms from hexane. Mp: 95" decomp. IDLH 1000 mg/m3 (as Mo) . PROP: Mp: 1OO-10lo decomp. SYN: MOLYBDENUM, TRICARBONYL(l,3,5CYCLOHEPTATRIENE). OSHA PEL: TWA Total Dust: 10 mg/m3;
Respirable Fraction: 5 mg/m3
CONSENSUS REPORTS: Reported in EPA
ACGIH TLV: Insoluble Compounds:
TSCA Inventory.
inhalable fraction, 10 mg(Mo) /m3,3 mg(Mo)/m3, respirable fraction. SAFETY PROFILE: Poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits toxic fumes of Mo.
SAFETY PROFILE: A shn irritant. When heated to decomposition it emits acrid
smoke and irritating fumes.
COW780 CAS: 72117-72-7 HR: 1 U-CYCLOCITRYLIDENE-4-METHYLBUTAN-3-ONE mf: C15H240 mw: 220.39 SYNS: DIMETHYLIONONE 0 1,3-DIMETHYL-aIONONE 0 1-PENTEN-3-ONE,1-(2,6,6-TRIMETHYL-ZCYCLOHEXEN-1-YL)-2-METHYL
CPA775 CAS: 4998-76-9 HR: 3 CYCLOHEXANAMINE HYDROCHLORIDE mf: C6H13N°C1H mw: 135.66
TSCA Inventory.
SYNS: AMINOCYCLOHEXANEHYDROCHLORIDE 0 AMIN OHEMHYDROBENZENE HYDROCHLORIDE 0 HEXAHYDROANILIPU'EHYDROCHLORIDE
SAFETY PROFILE: A skin irritant. When
CONSENSUS REPORTS: EPA Genetic
heated to decomposition it emits acrid smoke and irritating fumes.
Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NO, and HC1.
CONSENSUS REPORTS: Reported in EPA
COY000 CAS: 544-25-2 HR: 3 1,3,5-CYCLOHEPTATRlENE DOT: UN 2603 mf: C7H8 mw: 92.14 PROP: A liquid. D: 0.888 @ 18.5"/4", bp: 117" @ 749 mm, flash p: 39.2"F. SYNS: CYCLOHEPTATRIENE 0
(DOT)
n TROPILIDENE
TROPILIDIN
DOT CLASSIFICATION: 3; Label:
Flammable Liquid, Poison SAFETY PROFILE: Poison by ingestion and shn contact. Mutation data reported. A very dangerous fire hazard when exposed to heat, flame, or oxidzers. Potentially violent reaction with nitrogen monoxide. When
CPBOOO CAS: 110-82-7 HR: 3 CYCLOHEXANE DOT: UN 1145 mf: C6H12 mw: 84.18 PROP: Colorless, mobile liquid; pungent odor. Mp: 6.5", bp: 81°, fp: 4.6", flash: p: 1.4"F, ULC: 90-95, lel: 1.3%, uel: 8.4%, d: 0.7791 @ 20°/4", autoign temp: 473"F, vap
402 CPBOSO CYCLOHEXANECARBOXAMIDE press: 100 mm @ 60.8', vap d: 2.90. Prac insol in H2O; sol in MeOH; misc in most org solvs. IDLH 1300 pprn [lO%LEL]. SYNS: CICLOESANO (ITALIAN) n CYCLOHEXhAN (DUTCH) 0 CYCLOHEXAN (GERMAN) 0 CYKLOHEKSAX POLISH) 0 HEXAHYDROBENZENE 0 HEXAMETHYLENE 0 HEXASAPHTHENE 0 RCRA WASTE NUhIBER U056
CONSENSUS REPORTS: Community hght-To-Know List. OSHA PEL: TWA 300 pprn ACGIH TLV: TWA 100 ppm DFG MAK: 200 ppm (720 mg/m3) DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Poison by intravenous route, Moderately toxic by ingestion. A systemic irritant by inhalation and ingestion. A s h n irritant. Mutation data reported. Flammable liquid. Dangerous fire hazard when exposed to heat or flame; can react with oxidming materials. Moderate explosion hazard in the form of vapor when exposed to flame. When mixed hot with liquid dinitrogen tetraoxide an explosion can result. To fight fire, use foam, CO2, dry chemical, spray, fog. When heated to decomposition it emits acrid smoke and fumes.
CPBOSO CAS: 1122-56-1 HR: 1 CYCLOHEXANECARBOXAMIDE mf: C ~ H I ~ N O mw: 127.21 PROP: Prisms from Hz0. Mp: 186-188'. Hygroscopic. Veq7 sol in EtOH, Et2O. SYNS: CYCLOHEXAMETHYLENE CARBAMIDE 0 CYCLOHEXANAMIDE CYCLOHEXANEFORMAMIDE 0 CYCLOHEXYLCARBOXAMIDE 0 CYCLOHEXYL CARBOXYhMIDE HEXAHYDROBEKZOIC ACID XVIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A shn irritant. When heated to decomposition it emits toxic fumes of NO,.
CPB625 CAS: 1569-69-3 CYCLOHEXANETHIOL DOT: UN 3054 mf: C6HizS mw: 116.24
HR: 3
PROP: Oil.D: 0.991, bp: 158-160". Sol in
EtOH, CHCL; insol in Hz0. SYNS: CYCLOHEXYL MERCAMAN (DO? 0 CYKLOHEXANTHIOL CYKLOHEXYLMERKAMAK (CZECH) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. NIOSH REL: (Cyclohexanethol) CL 0.5 ppm/ 15M DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: An eye and severe skin irritant. When heated to decomposition it emits toxic fumes of SO,. See also MERCAPTANS.
CPB750 CAS: 108-93-0 HR: 3 CYCLOHEXANOL mf: C6H12O mw: 100.16 PROP: Colorless needles or viscous liquid; hygroscopic, camphor-like odor. Mp: 24O, bp: 161.5', flash p: 154'F (CC), d: 0.9449 @ 25'/4O, vap press: 1 mm @ 21.0°, vap d: 3.45, autoign temp: 572OF. Sol in EtOH, EtzO; mod sol in HzO; misc in nonpolar solvents. IDLH 400 ppm. SYNS: ADRONAL 0 ANOL 0 CICLOESANOLO (ITALIAN) 0 CYCLOHEXYL ALCOHOL 0 CYKLOHEKSANOL (POLISW 0 HEXAHYDROPHENOL 0 HEXALIN HYDRALIN 0 HYDROPHENOL HYDROXYCYCLOHEXANE 0 NAXOL
CONSENSUS REPORTS: EPA Genetic Toxicology Program.Reported in EPA TSCA Inventory. OSHA PEL: TWA 50 pprn (skin) ACGIH TLV: TWA 50 ppm (skin) DFG MAK: 50 ppm (210 mg/m3) SAFETY PROFILE: Poison by intravenous route. Moderately toxic by ingestion, subcutaneous, and intramuscular routes. Mildly toxic by s h n contact. Human systemic effects by inhalation: conjunctiva irritation and changes in the olfactory and respiratory systems. Has caused damage to kidneys, liver, and blood vessels in experimental animals. Experimental reproductive effects. Human mutation data reported. A severe eye irritant. Narcotic-like action. Flammable when exposed to heat or
CYCLOHEXENE
CPC579 403
flame; can react with oxiduing materials. I p t e s on contact with chromium trioxide. Violent reaction with HN03. Incompatible with oxidants. To fight fire, use alcohol foam, foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also ALCOHOLS.
Explosive reaction with nitric acid at 75OC. Reaction with hydrogen peroxide + nitric acid forms an explosive peroxide. To fight fire, use alcohol foam, dry chemical, or COa. When heated to decomposition it emits acrid smoke and irritating fumes. See also KETONES and CYCLOHEXANE.
CPCOOO CAS: 108-94-1 HR: 3 CYCLOHEXANONE DOT: UN 1915 mf: CbHloO mw: 98.16 PROP: Colorless oily liquid; acetone-like odor. Mp: -45.0°, bp: 155O, ULC: 35-40, lel: 1.1% @ looo, flash p: l l l ° F , d: 0.9478 @ 2Oo/4O, autoign temp: 788'F, vap press: 10 mm @ 38.7', vap d: 3.4. Mod sol in H20. IDLH 700 ppm. SYNS: CICLOESANONE (ITALIAN) 0 CYCLOHEXAS
CPC300 CAS: 78-18-2 HR: 2 CYCLOHEXANONE PEROXIDE mf: C1zHz205 mw: 246.34 SYNS: CYCLOHEMNOL, 1-((I-HYDROPERO-
ON (DUTCH) 0 CYKLOHEKSANON (POLISH) 0 HEXAN-ON o KETOHEXQZETHYLENE NADONE 0 NCIK55005 0 PIMELIC KETONE 0 RCRA WASTE NUMBER U057 0 SEXTONE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 25 pprn (skin) ACGIH TLV: TWA 20 ppm, STEL 50 ppm (shn); Confirmed Animal Carcinogen DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Ketone (Cyclohexanone)) TWA 100 mg/m3 DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Suspected carcinogen. Moderately toxic by ingestion, inhalation, subcutaneous, intravenous, and intraperitoneal routes. A skin and severe eye irritant. Human systemic effects by inhalation: changes in the sense of smell, conjunctiva irritation, and unspecified respiratory system changes. Human irritant by inhalation. Mdd narcotic properties have also been ascribed to it. Human mutation data reported. Experimental reproductive effects. Flammable liquid when exposed to heat or flame; can react vigorously with oxidizing materials. Slight explosion hazard in its vapor form, when exposed to flame.
XYCYCL0HEXYL)DIOXY) 0 I-HYDROPEROXYCYCLOHEXYL-1-HYDROXI'CYCLOHEXYLPEROXIDE
1-HYDROXY-1-HYDROPEROXYDICYCLOHEXYL PEROXIDE 0 I-HWROXY-l'-HYDROPEROXYDICYCLOHEXYL PEROXIDE 0 PERO)(IDE, 1-HYDROPEROXYCYCLOHEXYL 1-HYDROXYCYCLOHEXYL
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DFG MAK: Strong Skin Effects SAFETY PROFILE: Slightly toxic by parenteral route. A severe eye and s h n irritant. When heated to decomposition it emits acrid smoke and irritating vapors.
CPC579 CAS: 110-83-8 HR: 3 CYCLOHEXENE DOT: UN 2256 mfi C6H10 mw: 82.15 PROP: Colorless liquid. Bp: 8 3 O , fp: -103.7', flash p: <21.2"F, d: 0.8102 @ 2Oo/4O, vap press: 160 mm @ 38", autoign temp: 590°F, vap d: 2.8, lel: 1.2%. IDLH 2000 ppm. SYNS: BENZESETETRAHYDRIDE 0 CYKLOHEKSEN (POLISH)
1,2,3,4-TETRAHYDROBENZENE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: 300 pprn ACGIH TLV: 300 pprn DFG MAK: 300 pprn (1000 mg/m3) DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by inhalation and ingestion. A very dangerous fire hazard when exposed to flame; can react with oxidizers. Dangerous; keep away from
404
CPDOOO CYCLOHEXENE OXIDE
heat and open flame. To fight fire, use foam, COz, dry chemical.
CPDOOO CAS: 286-20-4 HR: 3 CYCLOHEXENE OXIDE mf: CGH100 mw: 98.16 PROP: Clear liquid. Bp: 130-131°, flash p: 81'F, d: 0.9678 @ 25'/4', vap d: 3.5. SYNS: CCHO 0 CYCLOHEXhNE OXIDE 0 CYCLOHEXESE EPOXIDE 0 CYCLOHEXENE-1-OXIDE 0 1,2-CYCLOHEXENE OXIDE 0 CYCLOHEXYLEXE OXIDE 0 1,2-EPOXYCYCLOHEXANE 7-OXABICYCLO(4 1.O)HElTANE 0 TETWIETHYLENEOXIRANE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by ingestion, skin contact, intraperitoneal, and intramuscular routes. Mildly toxic by inhalation. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. A flammable liquid and dangerous fxe hazard when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritant fumes.
CPD250 CAS: 930-68-7 2-CYCLOHEXEN-1-ONE mf: C6HEO mw: 96.14 PROP: A liquid. Bp: 169-171'.
HR: 3
SYN: CYCLOHEXENONE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by ingestion, inhalation, intraperitoneal, and skin contact routes. Mutation data reported. When heated to decomposition it emits acrid smoke and irritant fumes. See also KETONES.
CPD750 CAS: 100-40-3 HR: 3 CYCLOHEXENYLETHYLENE mf: C8H12 mw: 108.20 PROP: Liquid. Bp: 128O, fp: -109O, flash p: GOOF (TOC), d: 0.832 @ 2Oo/4O, autoign temp: 517'F, vap press: 25.8 mm @ 38', vap d: 3.76.
SYNS: BUTADIENE DIMER 0 4-ETHENYL-lCYCLOHEXENE 0 NCLC54999 0 1,2,3,4-TETRA HYDROSTYRENE 0 1-VINYLCYCLOHEXENE-3 1VINYLCYCLOHEX-3-ENE 0 4-VINYLCYCLOHEXENE 0 4-VINYLCYCLOHEXENE-l 0 4-VINYL-1CYCLOHEXENE CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 11,277,76; Animal Limited Evidence IMEMDT 39,181,86. NTP Carcinogenesis Studes (gavage); Clear Evidence: mouse NTPTR* NTP-TR-303,86; Inadequate Studes: rat NTPTR" NTP-TR-303,86. Reported in EPA TSCA Inventory. ACGIH TLV: W A 0.1 ppm (skin); Animal Carcinogen DFG MAK: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic by ingestion and inhalation. M i l c U ~ 7toxic by skin contact. Experimental reproductive effects. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Can react with oxidizers. To fight fire, use foam, C02, dry chemical.
CPEBOO CAS: 10137-69-6 HR: 2 CYCLOHEXENYL TRICHLOROSILANE DOT: UN 1762 mf: C6H9CLSi mw: 215.59 PROP: Colorless, fuming liquid; HC1 odor. Bp: 202', d: 1.263 @ 25'/25O, flash p: 200'F (COC). SYNS: CYCLOHEXENE, 4-pNCHLOROS1LYL)- 0 CYCLOHEXENYLTRICHLOROSILANE(DOT) 0 TRICHLORO-3-CYCLOHEXENYLSILANE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: Moderately toxic by
ingestion and skin contact. An eye and severe skin irritant. A corrosive material. It fumes in moist air, releasing HC1. Combustible when exposed to heat or flame. When heated to decomposition it
4-(CYCLOHEXYLCARB0NYL)PYRlDlNE
emits toxic fumes of Cl-. See also CHLOROSILANES.
CPFOOO CAS: 622-45-7 HR: 3 CYCLOHEXYL ACETATE DOT: UN 2243 mf: CgH1402 mw: 142.22 PROP: Pale-yellow liquid; fruity odor. Bp: 177', d: 0.996, vap d: 4.9, flash p: 136'F, autoign temp: 633'F. SYNS: CYCLOHEXANOL ACETATE 0 CYCLOHEXANOLAZETAT (GERMAN) 0 CYCLOHEXANYL ACETATE 0 CYCLOHEXYLESTER KYSELINY OCTOVE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Moderately toxic by
subcutaneous route. Mildly toxic by ingestion and skin contact. Human systemic effects by inhalation: conjunctiva irritation and unspecified respiratory system changes. A systemic irritant to humans. A skin and eye irritant. Flammable liquid when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes.
CPF500 CAS: 108-91-8 HR: 3 CYCLOHEXYLAMINE DOT: UN 2357 mf: C6H13N mw: 99.20 PROP: Liquid; strong, fishy odor. Mp: -17.7', bp: 134.5', flash p: 69.8'F, d: 0.865 @ 25'/25', autoign temp: 560'F, vap d: 3.42. Mtsc in H20, org solvs. SYNS: ALMINOCYCLOHEXANE 0 AMINOHEXAHYDROBENZENE 0 CHA 0 CYCLOHEX ANAMINE 0 HEXAHYDROANILINE 0 HEXAHYDROBENZENAMINE CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,178,87; Animal Limited Evidence IMEMDT 7,178,87. EPA Extremely Hazardous Substances Lst. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. OSHA PEL: TWA 10 ppm
CP1375 405
ACGIH TLV: TWA 10 ppm; Not Classifiable
as a Human Carcinogen DFG MAK: 10 ppm (41 mg/m3) DOT CLASSIFICATION: 8; Label: Corrosive, Flammable Liquid SAFETY PROFILE: A poison by ingestion, skin contact, and intraperitoneal routes. Experimental teratogenic and reproductive effects. A severe human s h n irritant. Can cause dermatitis and convulsions. Human mutation data reported. Questionable carcinogen. Flammable liquid. Dangerous fire hazard when exposed to heat, flame, or oxidizers. To fight fire, use alcohol foam, COz, dry chemical. When heated to decomposition it emits toxic fumes of NO,.
CP1250 CAS: 95-33-0 HR: 3 N-CYCLOHEXYL-2-BENZOTHIAZOLESULFENAMIDE mf: C I ~ H I ~ N Z S Z mw: 264.43 PROP: Light tan or buff powder. Mp: 103-104', d: 1.27 @ 25'. SYNS: ACCELERATOR CZ 0 ACCICURE HBS 0 BENZOTHIAZYL2-CYCLOHEXYLSCLFENAMDE 0 CBS 0 CONAC A 0 CONAC S 0 CURAX 0 N-CYCLOHEX=-2-BENZOTHIAZOLESULFENAMIDE 0 NCYCLOHEXYL2-BENZOTHlAZYLSULFENAMIDE O DELAC S 0 DURAX 0 EKAGOM CBS 0 NOCCELER CZ 0 PENNAC CBS 0 RHODIFAX 16 0 ROYAL CBTS 0 SANCELER CM-PO 0 SANTOCURE 0 SANTOCURE VULCANIZATION ACCELERATOR 0 SOXINOL CZ 0 SULFENAMIDE TS 0 SULFENAX 0 SULFENAX CB 0 SULFENAX CB 30 0 SULFENAX CB/K 0 THIOHEXAM 0 VULCAFOR CBS 0 WLCAFOR HBS 0 WLKACIT C 0 WLKACIT CZ 0 VULKACIT CZ/C 0 VULKACIT CZ/K CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by intravenous route. Questionable carcinogen with experimental tumorigenic data. An experimental teratogen. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of SO, and NO,.
CP1375 CAS: 32921-23-6 HR: 3 4-(CYCLOHEXYLCARB0NYL)PYRlDlNE mf: CIzH15NO mw: 189.28
406 CPNSOO CYCLOHEXYL ISOCYANATE SYNS: CYCLOHEXYL 4-PYRIDYL KETONE 0 KETONE, CYCLOHEXYL 4-PYRIDYL 0 PYRIDINE, 4. (CYCLOHEXYLCARBONYL). DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: A poison by
intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of NO,. CPNSOO CAS: 3173-53-3 HR: 3 CYCLOHEXYLISOCYANATE DOT: UN 2488 mf: C ~ H I I N O mw: 125.19 PROP: Oil.Mp: 168-170'. SYNS: CYCLOHEXANE, ISOCYANATO-(9CI) 0 ISOCYANATOCYCLOHEXE 0 ISOCYANIC ACID, CYCLOHEXYL ESTER 0 NSC-87419
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: Poison; DOT Class: 6.1; Label: Poison, Flammable Liquid; DOT Class: 3; Label: Flammable Liquid, Poison SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Mutation data reported. A flammable liquid when exposed to heat or flame. When heated to decomposition it emits toxic fumes of NO,. See also CYANATES and ESTERS.
CPQ275 CAS: 6837-24-7 HR: 3 1-CYCLOHEXYL-2-PYRROLlDlNONE mf: CloH1;NO mw: 167.28 SYNS: N-CYCLOHEXYLPYRROLIDINOXE 0 NCYCLOHEXYLPYRROLIDONE U 2-PYRROLIDINONE, I-CYCLOHEXYL-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion. Moderately toxic by inhalation and slun contact. A severe skin and eye irritant. When heated to decomposition it emits toxic fumes of NO,.
CPQ625 CAS: 100-88-9 HR: 3 N-CYCLOHEXYLSULPHAMIC ACID mf: C G H I ~ N O ~ S mw: 179.26
PROP: Crystals; sweet-sour taste. Mp:
169-170'. Fairly strong acid. Very sparingly soluble in water. Slowly hydrolyzed by hot water. SYNS: CYCLAMATE 0 CYCLAMIC ACID
0 CYCLOHEXASESULPHAMIC ACID 0 CYCLOHEXYLAMIDOSULPHURIC ACID 0 CYCLOHEXYLASIINESULPHONIC ACID 0 CYCLOHEXYLSULFAMIC ACID (9CI) 0 CYCLOHEXYLSULPfiMIC ACID 0 HEXAMIC ACID 0 SUCARYL 0 SUCARYL ACID
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Suspected human carcinogen producing bladder tumors. Poison by intravenous route. LWdly toxic by ingestion. When heated to decomposition it emits toxic fumes of SO, and NO,.
CPR250 CAS: 98-12-4 HR: 3 CYCLOHEXYLTRICHLOROSILANE DOT: UN 1763 mf: C6H11C13Si mw: 217.61 PROP: A liquid. Bp: 198.6-200°. SYNS: CYCLOHEXANE, I-(TRICHLOROSILX). 0 SILhNE, TRICHLOROCYCLOHEXYL-
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A highly toxic and
corrosive material. When heated to decomposition it emits toxic fumes of C1-. See also CHLOROSILANES. CPR800 CAS: 121-82-4 HR: 3 CYCLONITE DOT: UN 0072/UN 0118/UN 0391/UN 0483 mf: C3H6N606 mW: 222.15 PROP: White, crystalline powder. Mp: 202'. SYNS: CYCLONITE, desensiuzed (UN 0483) (DOT) 0 CYCLONITE, wetted (CN0072) (DOT) 0 CYCLOTRIMETHYLENENITRAMNE 0 CYCLOTRIMETHYLENETRINITRhMINE 0 CYCLOTRIMETHYLENETRINITRAMINE, desensiuzed (UN0483) (DOT) 0 CYCLOTRIMETHYLENETRINITRAMINE, wetted (UN 0072) (DO?) 0 CYKLONIT 0 ESAIDRO-l,3,5-TRINITRO1,3,5-TRIAZINA PTALIAN) 0 HEKSOGEN (POLISH) 0 HEXAHYDRO-l,3,5-TRINITRO-I,3,5-TRIAZIN (GERWGi) 0 HEXIIHYDRO-l,3,5-TRINITRO-l,3,5-TRIAZINE 0 HEXOGEEN (DUTCH) 0 HEXOGEN 0 HEXOGEN, desensiuzed (UN 0483) (DOT) 0 HEXOGEN (Explosive) 0
1,3-CYCLOPENTADIENE CPUSOO 407 HEXOGEX 5\V 0 HEXOGEN, wetted (LTN 0072) (DOT) 0 HEXOLITE 0 HEXOLITE, dry or wetted with <15% water, by weight (CN 0118) (DOT) 0 PBX(AF) 108 0 PBXW lOS(E) RDX RDY desensiuzed (CN 0483) (DOT) 0 RDX and HMX MIXTURES, desensiuzed wth not
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 1.5 mg/m3 (skm) ACGIH TLV: TWA 0.5 mg/m3 (skin); Not Classifiable as a Human Carcinogen DOT CLASSIFICATION: EXPLOSIVE 1.1D; Label: EXPLOSIVE 1.1D SAFETY PROFILE: Poison by ingestion, intraperitoneal, and intravenous routes. An experimental teratogen. Other experimental reproductive effects. A corrosive irritant to skin, eyes, and mucous membranes. Cases of epileptifonn convulsions have been reported from exposure. It is one of the most powerful high explosives in use today. Has more shattering power than TNT and is often mixed with TNT as a bursting charge for aerial bombs, mines, and torpedoes. It is easily initiated by mercury fulrmnate, which may be used as a booster. When heated to decomposition it emits toxic fumes of NO,. See also M I N E S , NITRATES, and EXPLOSIVES, HIGH.
SAFETY PROFILE: Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh.
CPSOOO CAS: 115-25-3 HR: 1 CYCLOOCTAFLUOROBUTANE DOT: UN 1976 mf: C4Fg mw: 200.03 PROP: Colorless, odorless gas. Mp: -41.4", bp: -6.04', d (liquid): 1.513 @ -70'F. SYNS: FC-C 318 0 FREON C-318 0 HALOCARBON C138 0 OCTAFLUOROCYCLOBUTANE (DOT) 0 PERFLGOROCYCLOBUTANE 0 PROPELUVT C318 0 R-C 318
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 2.2; Label: Nonflammable Gas SAFETY PROFILE: M d l y toxic by ingestion and inhalation. Can cause slight transient effects at high concentrations. No anesthesia or central nervous system effects. Nonflammable gas. Mutation data reported. When heated to decomposition it emits hghly toxic fumes of F-.
CPU500 CAS: 542-92-7 HR: 3 1,3-CYCLOPENTADIENE mE CsH6 mw: 66.11 PROP: Colorless liquid. Mp: -85', bp: 41-42', d: 0.80475 @ 19'/4", flash p: 77'F. Misc in EtOH and C G H ~IDLH . 750 ppm. SYNS: CYCLOPENTADIENE 0 PENTOLE 0 PYROPENTYLENE 0 R-PENTINE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. CPR840 CAS: 12245-39-5 HR: 3 OSHA PEL: TWA 75 pprn (1,5-CYCLOOCTADIENE)(2,4-PENTAACGIH TLV: TWA 75 ppm NEDIONAT0)RHODIUM DFG MAK: 75 pprn (210 mg/m3) mf: C13H1902Rh mw: 310.23 SAFETY PROFILE: Low toxicity by PROP: Yellow crystals from pet ether. Mp: ingestion. A dangerous fire hazard when 125-128" decornp. Sol in hexane, CHCl3. exposed to heat or flame; can react with IDLH 100 mg/m3 (as Rh). SYNS: ACETYLACETONATE-l,5-CYCLOOCTADIENE oxidizing materials. Moderate explosion RHODIUM 0 RHODIUM, ((1,2,5,6-eta)-1,5-CYCLOOCTA- hazard in the form of gas when exposed to heat or by chemical reaction. It decomposes DIENE)(2,4-PENTANEDIONATO-O,0)- 0 RHOD-IUM, (1,5-CYCLOOCTADIENE)(2,4-PEiXT&~EDIONATO)violently at h g h temperatures and pressures. OSHA PEL: TWA 0.1 mg(Rh)/m3 Dimerization is highly exothermic. ACGIH TLV: TWA 1 mg(Rh)/m3 Explosive reaction with fuming nitric acid,
408
CPVOOO CYCLOPENTADIENYLMANGANESE
dinitrogen tetroxide, sulfuric acid. Reaction with nitrogen oxide + oxygen forms an explosive product. Reaction with oxygen forms a flame-sensitive explosive product. Ignites on contact with oxygen + ozone. Reacts vigorously on contact with potassium hydroxide. Incompatible with oxides of nitrogen, sulfuric acid. When heated to decomposition it emits acrid smoke and fumes. CPVOOO CAS: 12079-65-1 HR: 3 CYCLOPENTADIENYLMANGANESE TRICARBONYL mf: CsHsMnOj mw: 204.07 PROP: Pale-yellow crystals with camphoraceous odor. Mp: 76.8-77.1'. SYNS: ALANGANESE CYCLOPENTADIENYL TRICARBONYL 0 MCT
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Manganese and its compounds are on the Community RghtTo-Know List. OSHA PEL: TWA 0.1 mg(Mn)/m3 (skm) ACGIH TLV: TWA 0.1 mg(Mn)/m3 SAFETY PROFILE: A poison by ingestion, inhalation, intraperitoneal, and intravenous routes. A mild narcotic which can damage kidneys. When heated to decomposition it emits acrid smoke and irritating fumes. See also MANGANESE COMPOUNDS and CARBON MONOXIDE.
CPV750 CAS: 287-92-3 HR: 3 CYCLOPENTANE DOT: UN 1146 mf: C5HlO mw: 70.15 PROP: Colorless liquid. Bp: 49.3', fp: -93.7', flash p: 19.4'F7 autoign temp: 716'F, d: 0.745 @ 2Oo/4O, vap press: 400 mm @ 31.0°, vap d: 2.42. SYN: PESTAMETHYLENE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 600 ppm ACGIH TLV: TWA 600 ppm DOT CLASSIFICATION: 3; Label: Flammable Liquid
SAFETY PROFILE: Mildly toxic by ingestion and inhalation. High concentrations have narcotic action. A very dangerous fire hazard when exposed to heat or flame; can react with oxidizers. To fight fire, use foam, COZ,dry chemical. When heated to decomposition it emits acrid smoke and fumes.
CPW300 CAS: 1679-07-8 CYCLOPENTANETHIOL DOT: UN 1228/UN 3071 mf: CsHloS mw: 102.21 SYNS: CYCLOPENTYL MERCAPTAN 0
HR: 3
MERCAPTOCYCLOPENTANE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid, Poison (UN1228); DOT Class: 6.1; Label: Poison, Flammable Liquid (UN3071) SAFETY PROFILE: A human poison. A flammable liquid. When heated to decomposition it emits toxic vapors of SO,.
CPW500 CAS: 120-92-3 HR: 3 CYCLOPENTANONE DOT: UN 2245 mf: CjHsO mw: 84.13 PROP: Liquid with a pleasant odor. Mp: -58.2', bp: 130.6', flash p: 79'F, d: 0.9509 @ 18'/4', vap d: 2.3. Sparingly sol in H20. SYNS: ADIPIC KETONE 0 DULMASIN0 KETOCYCLOPENTAIE 0 KETOPEXTAMETHYLENE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label:
Flammable Liquid SAFETY PROFILE: Moderately toxic by intraperitoneal and subcutaneous routes. A skin and severe eye irritant. Dangerous fire hazard when exposed to heat or flame; can react with oxidizers. To fight fire, use alcohol foam, foam, C02, dry chemical. Potentially explosive reaction with hydrogen peroxide + nitric acid. When heated to decomposition it emits acrid smoke and fumes. See also KETONES.
CYCLOPHOSPHORAMIDE CQC650 409
CPX750 CAS: 142-29-0 HR: 3 CYCLOPENTENE DOT: UN 2246 mf: CjH8 mw: 68.13 PROP: A liquid. Mp: -135.3', bp: 44.242', flash p: -20'F, d: 0.77199 @ 20'. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by ingestion and s h n contact. A very dangerous fire hazard when exposed to flame or heat; can react with oxidning materials. Keep away from heat and open flame. To fight fire, use foam, C 0 2 , dry chemical.
Sufficient Evidence IMEMDT 9,135,75; Animal Sufficient Evidence IMEMDT 26,165,81. SAFETY PROFILE: Confirmed human carcinogen. Poison by ingestion and intravenous routes. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of C1-, PO,, and NO,.
E
CQC650 CAS: 50-18-0 HR: 3 CYCLOPHOSPHORAMIDE mf: C7H15Cl2N202P mw: 261.11 PROP: Crystals. Mp: 41-45', Water-sol; sltly sol in org solvs. SYNS: ASTA 0 ASTA B518 0 B 518 0 N,N-BIS-(PCHLORAETHYL-N',O-PROPYLEN-PHOSPHORSAEUREESTER-DIAhiID (GERMAS) 0 2-(BIS(2-CHLOROETHYL)-
AMINO)-2H-1,3,2-OXAAZAPHOSPHORINE 2-OXIDE 0 N,N-BIS(2-CHLOROETHYL))-N'-(3-HYDROXYPROPYL)-
CQCSOO CAS: 6055-19-2 HR: 3 PHOSPHORODIltzIDIC ACID muamol ESTER 0 BIS(2CYCLOPHOSPHAMIDE HYDRATE CHLOR0ETHYL)PHOSPHORIDE-CYCLIC PROPmf: C7HljC12N202P*H20 mw: 279.13 ANOLAhlIDE ESTER 0 N,N BIS(2-CHLOROETHYLSYNS: l-BIS(2-CHLOROETHYL)AINO-l-OXA-2-AZA-N',O-PROPYLENEPHOSPHORIC ACID ESTER DIAhlIDE 5-OXAPHOSPHORIDINEhiONOHMRATE 0 2-(BIS(2CHLOROETHYL)AMIXO)-l-OXA-3-AZA-2PHOSPHOCYCLOHEXANE 2-OXIDE hiONOHYDRATE 0 (BIS(CHLORO-2-ETHYL)AMIh0)-2-TETRAHYDRO-
0 N,X-BIS(2-CHLOROETHYL)TETRAHYDRO-2H-l,3,2OXAPHOSPHORIN-2-XhlINE-2-OXIDE 0 N,N-BE@CHLOR0ETHYL)-N',O-TRISlETHYLENEPHOSPHORIC
ACID ESTER DIAMIDE 0 CB 4564 0 CLAFEN 0 CLAPHENE 0 CP 0 CPA 0 CTX 0 CY 0 CYCLOPHOSPHAiiIDE 0 CYCLOPHOSPHAMIDUM 0 CYCLOASIIDE CYCLIC PROPAhOLkMIDE ESTER MOXOPHOSPHAN 0 CYCLOSTIN 0 CYTOPHOSPHAN 0 HYDRATE 0 N,N-BIS(P-CHL0ROETHYL)-N',OPROPYLENEPHOSPHORICACID ESTER AMINE CYTOXAN 0 N,N-DI(~-CHLOROETHYL)-N,O-PROPMONOHYDRATE 0 N,N-BIS(2-CHL0ROETHYL)YLENE-PHOSPHORICACID ESTER DIAMIDE 0 TETRAHYDRO-2H-l,3,2-OXAPHOSPHORIN-2-AMINE-2ENDOXAN 0 ENDOXAXAL 0 GENOXAL 0 OXIDE MONOHYDRATE 0 N,N-BIS(P-CHLOROETHHEXADRIN 0 MITOXAN 0 NCI-C04900 0 NEOSAR 0 n)-S1,0-TRI,21ETHnESEPHOSPHORIC ACID ESTER NSC-26271 0 2-H-1,3,2-OXAZAPHOSPHORINANE 0 DIAMIDE MONOHYDRATE 0 CB-4564 0 CLAFEN 0 PROCYTOX 0 RCRA WASTE KUMBER LO58 0 CYCLIC N',O-PROPYLENEESTER of N,N-BIS(2SEMDOmY 0 SENDUXAN 0 SK 20501 0 ZYKLOCHLOROETHYL)PHOSPHORODL4hlIDICACID MONOPHOSPHAMID (GERMAN) HYDRATE 0 CYCLOPHOSPHAMIDE MONOHYDRATE
3,4,5,6-OXAZAPHOSPHORINE-l,3,2-OXIDE-2MONOHYDRATE 0 BIS(2-CHLOR0ETHYL)PHOSPHOR-
0 CYCLOPHOSPHAhfIDUM 0 CYCLOPHOSPHAX 0 CYCLOPHOSPHANE 0 CYCLOPHOSPHANUhI 0 CYTOPHOSPHAN 0 CYTOXAN 0 2-(DI(2-CHLOROETHYLAS~INO)-l-OXA-3-AZA-2-PHOSPHACYCLOHE~~E-ZOXIDE MONOHYDRATE 0 N,N-DI(2-CHLOROETHYL)AMINO-N,O-PROPYLENEPHOSPHORIC ACID ESTER DIAMIDE MONOHYDRATE 0 ENDOXANA 0 ENDOXAN-ASTA 0 ENDOXAN MONOHYDRATE 0 ENDOXAS R 0 ESDUXAN 0 GENOXAL 0 LIITOXAX 0 NSC26271 0 PROCYTOX 0 SEMDOXAN 0 SEXDOXAh 0 SENDUMN
CONSENSUS REPORTS: IARC Cancer Review: Human Sufficient Evidence IMEMDT 26,165,81; Human Limited Evidence IMEMDT 9,135,75; Animal
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT 7,182,87; Human
Sufficient Evidence IMEMDT 26,165,81; Animal Sufficient Evidence IMEMDT 26,165,81; IMEMDT 9,135,75; Human Limited Evidence IMEMDT 9,135,75. NCI Carcinogenesis Studies (ipr); Clear Evidence: mouse, rat RRCRBU 52,1,75. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed human carcinogen producing leukemia, Hodgkin's dsease, gastrointestinal and bladder tumors.
410
CQD750
CYCLOPROPANE
Experimental carcinogenic, neoplastigenic, and teratogenic data. A human poison by ingestion and many other routes. Human systemic effects: hdney changes (hepatic dysfunction), leukopenia (reduced white blood cell count), nausea and alopecia (loss of hair), liver changes, agranulocytosis. Human reproductive and teratogenic effects by multiple routes: spermatogenesis, testicular changes, epiddymis and sperm duct changes, menstrual cycle changes, fetal developmental abnormahties of the craniofacial area, musculoskeletal and cardiovascular systems. Experimental reproductive effects. Human mutation data reported. A powerful skin irritant. Used as an immunosuppressive agent in nonmalignant diseases. When heated to decomposition it emits hghly toxic fumes of PO,, NO,, and C1-. CQD750 CAS: 75-19-4 HR: 3 CYCLOPROPANE DOT: UN 1027 mf: C3H6 mw: 42.09 PROP: Colorless gas with ethereal odor. Mp: -126.6', bp: -33.5', lel: 2.4%, uel: 10.4%, d: 1.879 g/L @ Oo, autoign temp: 932'F. Mod sol in H20; very sol in EtOH and Et2O. A minor constituent of MAPP gas. SYNS: CYCLOPROPANE, liquefied (DOT) 0 TRIMETHYLENE
CONSENSUS REPORTS: IARC Cancer Review: Animal No Adequate Data IMEMDT 7,93,87. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 2.1; Label: Flammable Gas SAFETY PROFILE: Mutation data reported. Questionable carcinogen. High concentrations are narcotic. Human reproductive effects. Very dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. Explosion Hazard: Moderate in the form of vapor when exposed to heat or flame. To fight fire, stop flow of gas, then use C02, dry
chemical, or water spray. When heated to decomposition it emits acrid smoke and fumes. CQH100 CAS: 59865-13-3 HR: 3 CYCLOSPORIN A mf: C62HlllN11012 mw: 1202.84 PROP: Needles from Me2CO. Mp: 148-1 51'. SYNS: ANTIBIOTIC S 7481F1 0 CICLOSPORIN 0 CYCLOSPORIN 0 CYCLOSPORINE 0 CYCLOSPORINE A 0 OL 27-400 0 S 7481F1 0 SANDIMMUN 0 SAlVDIMMCNE
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. SAFETY PROFILE: Confirmed carcinogen producing Hodghn's dlsease. Experimental reproductive effects. Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion. Human systemic effects by ingestion: increased body temperature, cyanosis. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
CQH250 CAS: 2691-41-0 HR: 3 CYCLOTETRAMETHYLENE TETRANITRAMINE DOT: UN 0226/UN 0484 mf: C4HsNsOs mw: 296.20 PROP: A solid. Mp: 286'. SYNS: CYCLOTETRrZIMETHYLENETETRANITRAMINE, desensiazed (UN 0483) (DOT) 0 CYCLOTETRAMETHYLENETETRANITRAMINE (dry or unphlegmauted) (DOT) 0 CYCLOTETF&iETHYLENETETRANITMMINE, wetted (UN 0226) (DOT) 0 HMX 0 HMX (dry or unphlegmauzed) (DOT) 0 HMX, wetted (UN 0226) (DOT) 0 beta HMY 0 HE'4 0 LX 14-0 0 OCTOGEN 0 OCTOGEN, desensiuzed (UN 0483) (DOT) 0 OCTOGEN, wetted with not <15% water, by weight (UN 0226) (DOT) 0 OKTOGEN 0 TETRAI&fETHYLENETETRAhITRAMINE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: Forbidden (dry or unphlegmatized); DOT Class: EXPLOSIVE 1.1D; Label: EXPLOSIVE 1.1D SAFETY PROFILE: A poison by ingestion and intravenous routes. An explosive. Decomposes violently at 279OC. When heated to decomposition it emits toxic
I-CYSTEINE
fumes of NO,. See also EXPLOSIVES, HIGH. CQH650 CAS: 13121-70-5 HR: 3 CY HEXATIN mf: CtsH340Sn mw: 385.21 PROP: White solid. Very sparingly sol in Hz0; sparingly sol in MezCO and MeOH; sol in CHCL. IDLH 80 mg/m3. SYNS: DOWCO-213 0 ENT 27,395-X 0 M 3180 0 PLICTRAN 0 PLYCTMN 0 TCTH 0 TRICYCLOHEXYLHYDROXYSTANNANE 0 TRICYCLOHEXYLHYDROXYTIN0 TRICYCLOHEXYLTIN HYDROXIDE 0 TRICYCLOHEXYLZINNHYDROXID (GERMAN) OSHA PEL: TWA 0.1 mg(Sn)/m3; TWA 5
mgh3 ACGlH TLV: TWA 5 mg/m3; TWA 0.1
mg(Sn)/m3; STEL 0.2 mg/m3 (skin); Not Classifiable as a Human Carcinogen NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion, inhalation, and intraperitoneal routes. Moderately toxic by s h n contact. Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes. See also TIN COMPOUNDS. CQIOOO CAS: 99-87-6 HR: 3 pCYMENE mf: CtoHt4 mw: 134.24 PROP: Colorless to pale-yellow liquid; odorless. Mp: -68.2", bp: 176", lel: 0.7% @ 100°, ULC: 30-35, flash p: 117°F (CC), d: 0.853, refr index: 1.489, autoign temp: 817"F, vap d: 4.62, vap press:-l m m @ 17.3", flash p (technical): 127"F, uel (technical): 5.6%. Found in nearly 100 volaule oils, including lemongrass, sage, thyme, coriander, star anise, and cinnamon (FCTXAV 12,385,74).Sol in alc, ether, acetone, benzene. SYNS: CAMPHOGEN 0 CYMENE 0 CYMOL 0 DOLCYhfENE 0 F E W No. 2356 0 4-ISOPROPYL-lMETHYLBENZENE 0 p-ISOPROPYLTOLUENE0 pMETHYL-CUMENE 0 p-METHYLISOPROPYL BENZENE 0 1-hlETHYL-4-ISOPROPYLBENZENE 0 PAMCYMENE 0 P>\MCYLlOL
CQKOOO 41 1
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion. Humans sustain central nervous system effects at low doses. A skin irritant. Flammable liquid. Explosion Hazard: Slight in the form of vapor. To fight fire, use foam, COz, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
CQJ750 CAS: 56-17-7 HR: 3 CYSTAMINE DIHYDROCHLORIDE mf: C ~ H I Z N Z S Z * ~ C ~mw: H 225.22 PROP: Prisms from EtOH. Mp: 212'. SYNS: AED 0 2-AMINOETHYLDISULFIDE DIHYDROCHLORIDE 0 2,2'-DITHIO-BIS(ETHYLAMINE) DIHYDROCHLORIDE 0 USAF CB-34 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A poison by
subcutaneous and intraperitoneal routes. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of HC1, SO,, and NO,. See also SULFIDES. CQKOOO CAS: 52-90-4 HR: 2 I-CYSTEINE mf: C ~ H ~ N O Z S mw: 121.17 PROP: A solid. Mp: 178". Sol in H20, AcOH, and NH3. An amino acid derived from cystine, occurring naturally in the 1form, which will be considered here. Colorless crystals; sol in water, ammonium hydroxide, and acetic acid; insol in ether, acetone, benzene, carbon &sulfide, and carbon tetrachloride. SYNS: CYSTEIN 0 CYSTEINE 0 1-(+)-CYSTEINE 0 HALF-CYSTEINE 0 HALF-CYSTINE 0 pMERCAMOAWNINE 0 THIOSERINE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by ingestion, intraperitoneal, and subcutaneous routes. Experimental reproductive effects. Human mutation data reported. When
E
41 2
CQK250 I-CYSTEINE HYDROCHLORIDE
heated to decomposition it emits very toxic fumes of SO, and NO,. CQK250 CAS: 52-89-1 HR: 2 I-CYSTEINE HYDROCHLORIDE mf: C3H,N02S*ClH mw: 157.63 PROP: m t e crystalline powder; characteristic acetic taste. Mp: 175' (decornp). Sol in water, alc. SYNS: CYSTEINE CHLORHYDRATE 0 CYSTEINE HYDROCHLORIDE 0 1-CYSTEINEHYDROCHLORIDE 0 I-CYSTEINE MONOHYDROCHLORIDE(FCC)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by intraperitoneal, intravenous, and possibly other routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO,, SO,, and C1-.
CQK325 CAS: 56-89-3 HR: 1 I-CYSTINE mf: C G H I ~ N Z O ~ S mw: ~ 240.30 PROP: Plates or prisms. Mp: 258-261' (decornp) (sealed tube). Sol in hot Hz0, mineral acids, and aq alkali. Naturally occurring levorotatory form. Colorless to white hexagonal tablets from water. Decomp 260-261'. d-Cystine: Crystals. Sltly sol in water. dl-Cystine, the synthetic racemic form: Crystals. Sltly sol in water. meso-Cystine, the internally compensated form: Crystals. Sltly sol in water. SYNS: CYSTEINE DISULFIDE 0 CYSTIN 0 (-)CYSTINE 0 CYSTINE ACID 0 DICYSTEINE 0 p,p'DITHIODIALANINE 0 GELUCYSTINE 0 OXIDIZED 1CYSTEINE
SAFETY PROFILE: Low toxicity by ingestion. When heated to decomposition it emits toxic fumes of PO, and SO,.
CQL250 CAS: 115-93-5 HR: 3 CYTHlOATE mf: CsH12NOjPS2 mw: 297.30 PROP: A solid. Insol in H20; SO^ in C&, MezCO, Et20, and EtOH. SYNS: AC 26,691 0 AMERICAN CG26691 0 AMERICAN CYANAMID CL-26,691 0 0-(4-(AMINOSULFONYL)PHENYL) 0,O-DIMETHYL PHOSPHOROTHIOATE 0 BENZENE-SULFONAMIDE,p-HYDROXY-, 0-ESTER with
0,O-DLMETHYL PHOSPHOROTHIOATE 0 CL 26691 0 CYFLEE 0 0,O-DIMETHYL 0-p-SULFAMOYLPHENYL PHOSPHOROTHIOATE 0 ENT 25,640 0 PHOSPHOROTHIOIC ACID, 0-(4-(AMINOSULFONYL)PHENYL) 0,ODIMETHYL ESTER (9CQ 0 PROBAN
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion. An insecticide. When heated to decomposition it emits very toxic fumes of NO,, PO,, and
so,.
CQM325 CAS: 9007-43-6 HR: D CYTOCHROME C PROP: Reduced form crystallizes as separate needles; oxidized form as rosettes. Mol wt about 13,000. Cytochrome c2: Needles changing to squares. Mol wt about 13,000. Cytochrome c3: Needles. Mol wt 11,300. SYNS: CROMOCI 0 CYTOREST 0 FERRICYTOCHROME C 0 FERROCYTOCHROME C 0 HEMATINPROTEIN 0 HORSE-CYTOCHROME C 0 HORSE HEART CYTOCHROME C 0 LANDRAX 0 MYOHEMATIN 0 NITROSYLFERRICYTOCHROME C
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY P ROFlLE: Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
CQNOOO CAS: 4465-94-5 HR: 3 CYTOXAL ALCOHOL mf: C ~ H I ~ C ~ Z N ~ O ~ P ~ Cmw: ~HI~N 378.33 SYNS: 2-(BIS(2-CHLOROETHYL)AINO)TETRAHYDROOXAZAPHOSPHORINECYCLOHEXYLAMINE SALT 0 N,NN-BIS(2-CHLOROETHYL)-N'-(3-HYDROXYPROPYL)PHOSPHORODIhbfIDATE,CYCLOHEXYLAMMONIUM SALT 0 N,N-BIS(2-CHLOROETHYL)-N'-3PHOSPHORODIAMIDICACID HYDROXYLPROPYLCYCLOHEXYLAhlINE SALT 0 CYTOXYL ALCOHOL CYCLOHEXlZAMMONIUMSALT 0 NCI-C04922 0 NSC52695
CONSENSUS REPORTS: NCI Carcinogenesis Studes (ipr); Clear Evidence: mouse, rat RRCRBU 52,1,75. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic and tumorigenic data. Poison by intravenous route. Moderately toxic by ingestion and
CYTOXAL ALCOHOL
subcutaneous routes. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to
CQNOOO 41 3
decomposition it emits very toxic fumes of NO,, NH3, PO,, and C1-. See also ALCOHOLS.
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SYNS: ANTIBIOTIC SF 2052 SULFATE 0 I-CHIROINOSITOL, 4-AMINO-1,~-DIDEOXY-~-O-(~,~-DIAMINO-
DAB600 CAS: 4342-03-4 HR: 3 DACARBAZINE mf: C6H10N60 mw: 182.22 PROP: Ivory microcrystals. Mp: 250-255' (decomp). SYNS: DETICENE
2,3,4,6,7-PENTADEOXY-p-l-LYXOHEITOPYRANOSYL)-6-o-hIETHn-I -(2(FOIlMIMIDOVLtLllINO)-N-METHYL-ACETAMIDO)-, SULFATE (1:2),HYDRATE 0 SF-2052 SULFATE
SAFETY PROFILE: A poison by
DIC 0 (DIMETHYLTRIAZEN0)intravenous and intramuscular route. IMIDAZOLECARBOXAMIDE 0 4-(DIMETHYLModerately toxic by subcutaneous route. TRIAZENO)-IhlIDAZOLE-5-CARBOXAMIDE 0 4-(3,3When heated to decomposition it emits DIMETHYL-1-TRIAZENO)IhlIDAZOLE-5-CARBOXAMIDE 0 4-(5)-(3,3-DIMETHYL-l-TRIAZENO)IMIDAZ-toxic vapors of NO, and SO,. OLE-5(4)-CARBOXAMIDE 0 5-(DIMETHYLTRIAZENO)IMIDAZOLE-4-CARBOXAMIDE 0 5-(3,3-DIMETHYLDAB879 CAS: 469-62-5 HR: 3 TRIAZENO)IMIDAZOLE-4-CARBOXIDE 0 5-(3,3DARVON DIMETHYL-1 -TRIAZENO)IhlIDAZOLE-4-CARBOXmf: C22H29N02 mw: 339.52 AMIDE 0 5-(3,3-DIMETHYL-l-TNAZENYL)-lHIMIDAZOLE-4-CARBO-XIDE 0 DTIC 0 DTIC-DOME PROP: Crystals from pet ether. Mp: 75-76' 0 NCI-C04717 0 NSC-45388 SYNS: DEXTROPROPOXYPHENE o a-(+)-40
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,184,87; Human Lmited Evidence IMEMDT 26,203,81; Animal Sufficient Evidence IMEMDT 26,203,81. NCI Carcinogenesis Studies (ipr); Clear Evidence: mouse, rat RRCRBU 52,1,75. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intraperitoneal and parenteral routes. Moderately toxic by ingestion and intravenous routes. Experimental teratogenic effects. Human systemic effects by intravenous route: nausea or vomiting, leukopenia (reduced white blood cell count), and changes in dehydrogenase enzymatic activity. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
DAB630 CAS: 73245-91-7 DACTlMlClN SULFATE mfi CisH36N606'2H204S'H20 614.72
HR: 3
mw:
DIMETHYLAMINO-l,2-DIPHENYI-3-METHYL-2BUTANOL PROPIONATE ESTER 0 DOLENE 0 DOLOXENE 0 (+)-PROPOXYPHENE 0 dPROPOXYPHENE 0 PROXAGESIC 0 SK 65
SAFETY PROFILE: Poison by ingestion, intraperitoneal, subcutaneous, and intravenous routes. Human systemic effects by ingestion: change in cardiac rate, respiratory depression, and coma. When heated to decomposition it emits toxic fumes of NO,.
DACOOO CAS: 20830-81-3 HR: 3 DAUNOMYCIN mf: C27H29N010 mw: 527.57 PROP: Thin, red needles. Mp: 190' (decomp). Isolated from cultures of a Streptomyces (CNREAS 32,1029,72). SYNS: ACETYLADRMiiCIN 0 CERUBIDIN 0 DAUNAMYCIN 0 DAUNORUBICIN 0 DAUNORUBICINE 0 DM 0 FI6339 0 LEUKAEMOMYCIN C 0 NCIC04693 0 NSC-82151 0 RCRA WASTE NUMBER U059 0 RP 13057 0 13,057 RP. 0 RUBIDOMYCIN 0 RUBIDOMYCINE 0 RUBOMYCIN C 0 RUBOMYCIN C 1 0 STREPTOMYCES PEUCETIUS
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT
415
41 6
DAC450
DA WSONITE
10,145,76. NCI Carcinogenesis Studies (ipr); Clear Evidence: rat CANCAR 40,1935,77; No Evidence: mouse CANCAR 40,1935,77. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Human poison by ingestion. Experimental poison by subcutaneous, intravenous, and intraperitoneal routes. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also DAUNOMYCIN HYDROCHLORIDE. DAC450 CAS: 12011-76-6 HR: 3 DAWSONITE mf: CH2AlOpNa mw: 144.00 SYN CRYSTALLINEDEHYDROXY SODIUM ALUMINUM, CARBONATE
DFG MAK: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Suspected carcinogen with experimental neoplastigenic data.
DAD200 CAS: 50-29-3 HR: 3 DDT mf: C14H9Clj mw: 354.48 PROP: Colorless crystals or whte to sltly off-white powder. Odorless or with slight aromatic odor. Mp: 108.5-109°. IDLH 500 mg/m3. SYNS: AGRITAN 0 ANOFEX 0 ARKOTINE 0 AZOTOX 0 a,a-BIS@-CHLOROPHENYL))-P,P,PTRICHLOROETHANE 0 1,l-BIS-@-CHLOR0PHENYL)2,2,2-TRICHLOROETHANE 0 2,2-BIS@-CHLOROPHENYL)-1,1,1-TRICHLOROETHANE 0 BOSAN SUPRA 0 BOVIDERMOL 0 CHLOROPHENOTHAN 0 CHLOROPHEN-OTHANE 0 CHLOROPHENOTOXUM 0 CITOX 0 CLOFENO-TANE 0 p,p'-DDT 0 DEDELO 0 DEOVAL 0 DETOX 0 DETOXAN 0 DIBOVAN 0 DICHLORODIPHENYLTRICHLORO-ETHANE0 DICHLORODIPHENYLTRICHLOROETHANE POT') 0 p,p'-DICHLORODIPHENYLTRICHLOROETHAXE0 4,C-DICHLORODIPHENYLTRICHLOROETHANE0 DICOPHANE 0 DIDIGAM 0 D I D I M C 0 DIPHENYLTRICHLOROETHANE 0 DODAT 0 DYKOL 0 ENT 1,506 0 ESTONATE 0 GENITOX 0 GESAFID 0 GESAPON 0 GESAREX 0 GESAROL 0 GUESAPON 0 GUESAROL 0 GYRON 0 HAVERO-EXTRA 0 HILDIT 0 IVORAN 0
IXODEX 0 KOPSOL 0 MICRO DDT 75 0 MUTOXIN 0 NCI-COO464 0 NEOCID 0 PARA-CHLOROCIDUM 0 PEBl 0 PENTACHLORIN 0 PENTECH 0 PPZEIDAN 0 R50 0 RCRA WASTE NUMBER U06l 0 RUKSEAM 0 SANTOBANE 0 TECH DDT 0 l,l,l-TRICHLOOR-2,2BIS(4-CHLOOR FENYL)-ETHAAN (DUTCH) 0 l,l,l-
TRICHLOR-2,2-BIS(4-CHLOR-PHENYL)-AETHAN (GERMAN) 0 TRICHLOROBIS (4-CHLOROPHENYL) ETHANE 0 1,l ,l-TRICHLORO-2,2-DI(4-CHLOROPHENYL)ETHANE 0 1,1'-(2,2,2-TRICHLOROETHYLIDENE)BIS(4-CHLOROBENZENE)0 1,l ,I-TRICLORO-2,2-BIS(4CLORO-FEN1L)-ETANO(ITALIAN) 0 ZEIDANE 0 ZERDANE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,186,87; Animal Sufficient Evidence IMEMDT 5,83,74; Human Inadequate Evidence IMEMDT 5,83,74. NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* NCICG-TR-131,78. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 1 mg/m3 (skin) ACGIH TLV: TWA 1 mg/m3; Animal Carcinogen NIOSH REL: (DDT) TWA 0.5 mg/m3; avoid skin contact DFG MAK: 1 mg/m3 SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic, and teratogenic data. Human poison by ingestion. Experimental poison by ingestion, skin contact, subcutaneous, intravenous, and intraperitoneal routes. Experimental reproductive effects. Human systemic effects by ingestion: anesthetic, convulsions, headache, analgesia, cardiac arrhythmias, nausea or vomiting, sweating, and unspecified pulmonary changes. Human mutation data reported. An insecticide. When heated to decomposition it emits toxic fumes of C1-. See also CHLORINATED HYDROCARBONS, AROiWTIC. A dose of 20 g has proved highly dangerous though not fatal to a human. This dose was taken by 5 persons who vomited an unknown portion of the material and even so recovered only incompletely after 5
trans,trans-2,4-DECADlENAL
weeks. Smaller doses produced less important symptoms with relatively rapid recovery. Experimental ingestion of 1.5 g resulted in great discomfort and moderate neurological changes including paresthesia, tremor, moderate ataxia, exaggeration of part of the reflexes, headache, and fatigue. Vomiting followed only after 11 hours. Recovery was complete on the following day. The fatal dose of DDT for humans is not known. Judgmg from the literature, no one has ever been killed by DDT in the absence of other insecticides and/or a variety of toxic solvents. However, these common solvent formulations are highly fatal when taken in small doses, partly because of the toxicity of the solvent, and perhaps because of the increased absorbabihty of the DDT; several fatal cases in humans have been reported. Little is known of the hazard of chronic DDT poisoning. Human volunteers have ingested up to 35 mg/day for 21 months with no dl effects. DDT and some of its degradation products, particularly DDE, are stored in fat. This storage effect leads to a concentration of DDT at higher levels of the food chain. DDT stored in the fat is at least largely inactive since a greater total dose may be stored in an experimental animal than is sufficient as a lethal dose for that same animal if given at one time. A study based on 75 human cases reported an average of 5.3 ppm of DDT stored in the fat. A higher content of DDT and its derivatives (up to 434 pprn of D D E and 648 ppm of DDT) was found in workers who had very extensive exposure. Without exception, the samples were taken from persons who were either asymptomatic or suffering from some disease completely unrelated to DDT. Careful hospital examination of workers who had been very extensively exposed and who had volunteered for examination revealed no abnormahty that could be attributed to DDT. Much higher levels have been found
DAE450 41 7
in humans than have been observed in the fat of experimental animals that were apparently asymptomatic. DDT stored in the fat is eluninated only very gradually when further dosage is discontinued. However, weight loss can speed the release of this stored DDT (and DDE) into the blood. After a single dose, the secretion of D D T in the milk and its excretion in the urine reach their height within a day or two and continue at a lower level thereafter.
DAE400 CAS: 17702-41-9 HR: 3 DECABORANE DOT: UN 1868 mf: B I O H I ~ mw: 122.24 PROP: Colorless needles or crystals. Solid by sublimation. Mp: 99.6", d: 0.94 (solid), d: 0.78 (liquid @ lOO"), bp: 213", vap press: 19 mm @ 100". Sol in CS2. IDLH 15 mg/m3. SYN: DECABORANE(14)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List. OSHA PEL: TWA 0.05 ppm; STEL 0.15 PPm (skin) ACGIH TLV: TWA 0.05 ppm; STEL 0.15 PP" (skin) DFG MAK: 0.05 pprn (0.25 mg/m3) DOT CLASSIFICATION: 4.1; Label: Flammable Solid, Poison SAFETY PROFILE: Poison by inhalation, ingestion, sktn contact, and intraperitoneal routes. Ignites in 0 2 at 100°C. Forms impact-sensitive explosive mixtures with ethers (e.g., dioxane) and halocarbons (e.g., carbon tetrachloride). Incompatible with dimethyl sulfoxide. When heated to decomposition it emits toxic fumes of boron oxides. See also BORON COMPOUNDS and BORANES.
DAE450 CAS: 25152-84-5 HR: 2 trans,trans-2,4-DECADlENAL mf: c10H160 mw: 152.23 PROP: Yellow liquid; chicken fat odor. D: 0.806-0.876, refr index: 1.514-1.516, bp:
41 8
DAE525
DECADRON PHOSPHATE
58-61' @ 0.05 mm, flash p: 212'F. Sol in alc, fixed oils; insol in water @ 104'. SYNS: (E,E)-2,4-DECADIENAL 0 (2E,4E)DECADIENAL 0 (2E,4E)-2,4-DECADIENAL 0 FEMA No. 3135 0 HEPTENYLACROLEIN SAFETY PROFILE: Combustible liquid.
When heated to decomposition it emits acrid smoke and irritating fumes. DAE525 CAS: 2392-39-4 HR: 3 DECADRON PHOSPHATE mf: C22HzaFOaP*2Na mw: 516.45 PROP: Crystals. Mp: 233-235'. SYNS: DEXACORT 0 DEXADRESON 0 DEXhGRO 0 DEXAMETHASONE DISODILX PHOSPHATE 0 DEWIETHASONE SODIUM PHOSPHATE 0 DEXAMETHXZONE SODIUM PHOSPHATE 0 DISODIUhl DEXAMETHASONE PHOSPHATE 0 9FLUORO-11-p,17,21-TRIHYDROXY-l6-a-METHYL-
to decomposition it emits very toxic fumes of PO,, Br-, and C1-. A pesticide. See also TIN COMPOUNDS. DAE800 CAS: 91-17-8 HR: 3 DECAHYDRONAPHTHALENE DOT: UN 1147 mf: C10H18 mw: 138.28 PROP: Water-white liquid with slight menthol odor. Mp: (cis) -43.3', mp: (trans) -30.7', bp: (cis) 195.6', bp: (trans) 187.3', flash p: 136'F, (CC), autoign temp: 482'F, vap press: (cis) 1 mm @ 22.5', (trans) 10 mm @ 47.2', d: (cis) 0.8963 @ 2 O o / 4 O , vap d: 4.76, lel: 0.7% @ 212'F, uel: 4.9% @ 212'F.
SYNS: BICYCLO(4.4.0)DECANE 0 DEC 0 DECALIN 0 DECALIN ( D O 9 0 DECALIN SOLVENT 0 DE-KhLIN 0 PREGNA-1,4-DIENE-3,20-DIONE-2l-(DIHYDROGEN DEKALINA (POLISH) 0 NAPHTHALANE 0 NAPHTHPHOSPHATE) DISODIUM SALT 0 MEGACORT 0 ANE 0 PERHMRONAPHTHALENE SODIUM DEXAMETHASONE PHOSPHATE 0 CONSENSUS REPORTS: Reported in EPA SOLDESAM 0 SOLU-DECADRON 0 SPERSADOX 0 TSCA Inventory. TURBINAIRE CONSENSUS REPORTS: Reported in EPA
DOT CLASSIFICATION: 3; Label:
TSCA Inventory.
Flammable Liquid
SAFETY PROFILE: Poison by intravenous
SAFETY PROFILE: Moderately toxic by inhalation and ingestion. Questionable carcinogen with experimental carcinogenic and neoplastigenic data. Mildly toxic by skin contact. Human systemic effects by inhalation: conjunctiva irritation, unspecified olfactory and pulmonary system changes. Can cause kidney damage. Mutation data reported. A skin and eye irritant. Flammable liquid when exposed to heat or flame, can react with oxidzing materials. T o fight fire, use foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
route. Moderately toxic by ingestion and intraperitoneal routes. Human systemic effects by intravenous route: peritonitis, central nervous system, and gastrointestinal changes. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of F-, PO,, and Na2O. DAE6OO CAS: 15652-38-7 HR: 3 DECAFENTIN mf: CzaHsPClaHlsBrClSn mw: 868.99 SYNS: A-36 0 CELAA-36 0 DECnTRIPHENYLPHOSPHONI~ BROMOCHLORO~~ TRIPHESYLSTANNATE 0 (DECYL-TRIPHENYLPHOSPHOSIU;10-TRIPHENYL-BRO~-CHLOR-STANNAT (GERMAN) 0 STANNOPLUS 0 STANNOWM 0 STAi\"PLOCS
DAF100 CAS: 10519-11-6 HR: 1 DECAHYDRO-PNAPHTHYL ACETATE mf: C12H2002 mw: 196.32
OSHA PEL: TWA 0.1 mg(Sn)/m' ( s h ) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
SYN : 2-NAPHTHOL, DECAHMRO-, ACETATE CONSENSUS REPORTS: Reported in EPA
0.2 mg(Sn)/m3 (skin). NlOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by skin contact. Moderately toxic by ingestion. When heated
TSCA Inventory. SAFETY PROFILE: A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
1-DECANEAMINE DAGGOO 41 9 DAF150 CAS: 10519-12-7 HR: 1 DECAHYDRO-kNAPHTHYL FORMATE mf: C11H1802 mw: 182.29 SYNS: DECALINK FORMATE D 2-NAPHTHALENOL,
Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.
DECAHYDRO-, FORMATE 0 2-NAPHTHOL, DECAHWRO-, FORMATE 0 SANTALOZOKE
DAG2OO CAS: 112-31-2 HR: 2 1-DECANAL (mixed isomers) SYN: FEMA No. 2362 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. A severe skin irritant. See also 1DECANAL. When heated to decomposition it emits acrid smoke and fumes.
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A s h n irritant. When
heated to decomposition it emits acrid smoke and irritating fumes. DAF200 CAS: 705-86-2 HR: 1 A-DECALACTONE mf: C10H1802 mw: 170.28 PROP: Colorless liquid; coconut, fruity odor, butterlike on dution. Refr index: 1.456-1.459. Very sol in alc and propylene glycol; insol in water @, 281'. SYNS: AMYL-A-VALEROLACTONE 0 DECANOLIDE1,5 0 FEMA NO. 2361
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A s h n and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
DAGOOO CAS: 112-31-2 HR: 2 1-DECANAL mf: CloHzoO mw: 156.30 PROP: Colorless to light-yellow liquid; floral, fatty odor. D: 0.830 @ 15'/4', bp: 208', flash p: 185'F, mp: -5' (approx). Found in over 50 sources including citrus oils, citronella, and lemongrass (FCTXAV 11,477,73). Sol in 80% alc, fEed oils, volatile oils, and mineral oils; insol in water and glycerol. SYNS: ALDEHYDE C-10 0 C-10 ALDEHYDE 0 CAPRALDEHYDE 0 CAPRIC ALDEHYDE 0 CAPRINALDEHYDE 0 CAPRINIC ALDEHYDE 0 DECALDEHYDE 0 n-DECALDEHYDE 0 DECANAL 0 nDECANAL 0 DECANALDEHYDE 0 DECYL. ALDEHYDE 0 n-DECYL ALDEHYDE 0 1-DECK ALDEHYDE 0 DECYLIC ALDEHYDE 0 F E U No. 2362
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by ingestion. Mildly toxic by skin contact. A severe s h n irritant. Mutation data reported.
DAG400 CAS: 124-18-5 HR: 3 DECANE DOT: UN 2247 mf: C10H22 mw: 142.29 PROP: Liquid. Mp: -30°, bp: 174', lel: O.8%, uel: 5.4%, flash p: 115'F (CC), d: 0.730 @, 20'/4', autoign temp: 410'F, vap press: 1 mm @, 16.5', vap d: 4.90. SYN: n-DECANE (DOT) CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Questionable carcinogen with experimental tumorigenic data. A simple asphyxiant. Narcotic in high concentrations, Flammable liquid when exposed to heat or flame. Can react with oxidizing materials. Moderately explosive in its vapor form. To fight fire, use foam, COz, dry chemical. Emitted from modern buildtng materials (CENEAR 69,22,91). See also ARGON for discussion of asphyxiants. DAGGOO CAS: 2016-57-1 HR: 3 1-DECANEAMINE DOT: UN 2733/UN 2734 mf: CIOHZ~N mw: 157.34 PROP: Liquid. Mp: 15.0°, bp: 218.0-218.5' @ 747 mm, flash p: 210'F, d: 0.79 @, 20°, vap d: 5.5. SYNS: 1-AMINODECANE0 DECYLAMINE
420
DAH400
DECANOIC ACID
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 8; Label: Corrosive, Flammable Liquid (UN 2734); DOT Class: 3; Label: Flammable Liquid, Corrosive (UN 2733) SAFETY PROFILE: Poison by ingestion and skm contact. A skin irritant. Flammable when exposed to heat or flame; can react with oxidizing materials. To fight fue, use alcohol foam, foam, dry chemical. When heated to decomposition it emits toxic fumes of NO,. See AMINES and AMINES, FATTY.
DAH400 CAS: 334-48-5 HR: 3 DECANOIC ACID mf: CloHzoOz mw: 172.30 PROP: White crystals or needles with an unpleasant odor. D: 0.8858 @ 4Oo/4O, bp: 270°, mp: 31.5'. Sol in EtOH, EtzO, MeKO, C6H6, CHCL, and alkalies. SYNS: CAPRIC ACID n n-CAPRIC ACID CAPRINIC ACID 0 CAPRYNIC ACID 0 n-DECANOIC ACID 0 nDECOIC ACID 0 DECYLIC ACID 0 n-DECYLIC ACID 0 HEXACID 1095 0 NEO-FAT 10 0 I-NONAXECARBOXYLIC ACID CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Mutation data reported. A moderate skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
DAH450 CAS: 10024-58-5 HR: 1 DECANOIC ACID, DIESTER with TRIETHYLENE GLYCOL (mixed isomers) mf: C26H5006 mw: 458.76 SYN: DIDECANOYLTRIETHYLENE GLYCOL ESTER (mlxed isomers)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Mildly toxic by ingestion and skin contact. When heated to decomposition it emits acrid smoke and irritating fumes.
DA1350 CAS: 3913-71-1 HR: 2 2-DECENAL mf: C10H180 mw: 154.28 PROP: Sltly yellow liquid; orange odor. D: 0.836-0.846, refr index: 1.452-1.457. Sol in alc, fured oils; insol in water. SYNS: trans-2-DECEN-1-AL 0 DECENALDEHYDE 0 FEhiA No. 2366 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by skin contact. Mildly toxic by ingestion. A
severe skin irritant. When heated to decomposition it emits acrid smoke and fumes. See also ALDEHYDES.
DA1360 CAS: 21662-09-9 HR: 1 cis-4-DECENAL mf: CloHlsO mw: 154.28 PROP: Colorless to sltly yellow liquid; fatty, orangelike odor. D: 0.847, refr index: 1.442-1.444. Sol in alc, fixed oils; insol in water. SYNS: cis-CDECEN-1-AL (FCC) 0 FEhMNo. 3264 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low toxicity by ingestion and skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
DA1450 CAS: 50816-18-7 HR: 1 9-DECENYL ACETATE mf: C12H2202 mw: 198.34 PROP: Bp: 95-97' @ 0.09 mm. SYNS: ACETIC ACID, 9-DECEXYL ESTER 0 9-DECENI-OL, ACETATE 0 DECENYL ACETATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Low toxicity by ingestion and skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
DA1495 CAS: 18507-89-6 DECOQUINATE mf: C Z ~ H ~ ~ N O mw: ~ 417.53 PROP: Crystals. Mp: 86-87'.
HR: D
DEH YDROSTILBES TROL DALGOO 421
SYNS: DECCOX 0 6-DECYLOXY-7-ETHOXY-4HYDROXY-3-QUINOLINECA4RBOXYLID ACID ETHYL ESTER 0 ETHYL 6-(N-DECYLOX~-7-ETHOXY-4HYDROXYQUINOLINE-3-CARBOXYLATE
SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes.
DA1600 CAS: 112-30-1 HR: 2 DECYL ALCOHOL mf: C10H220 mw: 158.32 PROP: Found in sweet orange and a few other essential oils (FCTXAV 11,95,73). Colorless, viscous, refractive liquid; floral fruity odor. Mp: 7', fp: 7', bp: 232-239" @ 700 mm, flash p: 180'F (OC), d: 0.8297 @ 20'/4', refr index: 1.435-1.439, vap press: 1 mm @ 69.5', vap d: 5.3. Sol in alc, ether, mineral oil, propplene glycol, fixed oils; ins01 in glycerin water @ 233'. SYNS: AGENT 504 0 ALCOHOL C-10 0 ANTAK 0 C I0 ALCOHOL 0 CAPRIC ALCOHOL 0 CAPRINIC ALCOHOL 0 DECANhL DIMETHYL ACETAL 0 DECANOL 0 n-DECANOL 0 1-DECANOL (FCC) 0 nDECATYL ALCOHOL 0 n-DECYL ALCOHOL 0 DECYLIC ALCOHOL 0 DYTOL S-91 0 EPAL 10 0 FEhfA No. 2365 0 LOROL 22 0 NONYLCARBINOL 0 PRIMARY DECYL ALCOHOL 0 ROYALTAC 0 SIPOL L10
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
skin contact. W d l y toxic by ingestion and inhalation. A severe human skin and eye irritant. Experimental reproductive effects. Questionable carcinogen with experimental tumorigenic data. Combustible when exposed to heat or flame; can react with oxidzing materials. To fight fire, use foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALCOHOLS.
SAFETY PROFILE: Poison by intravenous route. Moderately toxic by ingestion. A severe eye irritant. When heated to decomposition it emits toxic fumes of SO,. See also SULFONATES.
DAJ450 CAS: 6285-34-3 HR: 3 4-DECYLOXY-2-HYDROXYPHENYL 4DECYLOXYPHENYLKETONE mf: C33H5004 mw: 510.83 DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: A poison by intravenous route. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating vapors. DAL400 CAS: 23107-12-2 HR: 3 DEHYDRORETRONECINE mf: C8HllN02 mw: 153.20 SYNS: 3,s-DIDEHYDRORETRONECINE0 (R)-2,3DIHYDRO-1-HYDROXY-l H-PYRROLIZINE-7METHANOL
CONSENSUS REPORTS: IARC Cancer Review: Animal Sufficient Evidence IMEMDT 10,333,76. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Poison by intraperitoneal route. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
DAL6OO CAS: 84-17-3 HR: 3 DEHYDROSTILBESTROL mf: Ci8H1802 mw: 266.36 PROP: A solid. Mp: 121-122'. SYNS: 3,4-BIS@-HYDROXYPHENYL)-2,4-HEXhDIENE
DAJOOO CAS: 1322-98-1 HR: 3 DECYL BENZENE SODIUM SULFONATE mf: C1bH2503S*Na mw: 320.46 SYNS: SODIUM DECYLBENZENESULFONAMIDE0
0 3,4-BIS(4-HYDROXYPHENYL)-2,4-HEXADIENE 0 CYCLADIENE 0 DIENESTROL 0 DIENOESTROL 0 pDIENOESTROL 0 DIENOL 0 4,4'-(1,2-DIETHYLIDENE1,2-ETHANEDIYL)BISPHENOL0 p,p'-(DIETHYLIDENEETHYLENE)DIPHENOL 0 4,4'-(DIETHYLIDENEETHYLENE)DIPHENOL 0 DINOVEX 0 DI@OXYPHENYL)-2,4-HEXhDIENE 0 DV 0 ESTRAGARD 0 ESTRODIENOL 0 ESTRORAL 0 FOLLIDIENE 0 FOLLORMON 0 GYNEFOLLIN 0 HORMOFEMIN 0
SODIUM DECYLBENZENESULFONATE
4,4'-HYDROXY-'f,A-DIPHENYL-p,A-HEXADIENE 0
CONSENSUS REPORTS: Reported in EPA
ISODIENESTROL n OESTRASID C OESTRODIENE 0 OESTRODIENOL 0 OESTRORAL 0 PARA-DIEN 0
TSCA Inventory.
422
DAM700
DEMEROL HYDROCHLORIDE
RESTROL 0 RETALON 0 SEXADIEN 0 SYXESTROL 0 TESERENE 0 WILLNESTROL
CONSENSUS REPORTS: IARC Cancer Review: Animal Inadequate Evidence IMEMDT 21,161,79; Human Limited Evidence IMEMDT 21,161,79. SAFETY PROFILE: Suspected human carcinogen. Human mutation data reported. Experimental reproductive effects. Used as a drug for the treatment of postmenopausal symptoms. When heated to decomposition it emits acrid smoke and irritating fumes.
DAM700 CAS: 50-13-5 HR: 3 DEMEROL HYDROCHLORIDE mf: CljH21NOz*ClH mw: 283.83 PROP: Mmute crystals. Mp: 186-189'. Insol in C6H6 and EtsO. SYNS: ALGIL 0 ALODAN (GEROT) 0 ANTIDUROL 0 CENTRALGIN 0 CHLORBICYCLEhE (FREhCH) 0 DEMEROL 0 DISPADOL 0 DOL4NTAL 0 DOLANTIN 0 DOWNTIN HYDROCHLORIDE 0 DOLANTOL 0 DOLAREN 0 DOLARGAN 0 DOLCONTRAL 0 DOLENAL 0 DOLENOL 0 DOLESTINE 0 DOLIN 0 DOLOGAL 0 DOLONELRINE 0 DOLOPETHIN 0 DOLOSAL 0 DOLVANOL 0 ENDOLAT 0 ETHYL-1METHYL-4-PHENYLISONIPECOTXTE HYDROCHLORIDE 0 ETHYL-1-METHYL-4-PHENYL PIPERIDINE-4-CARBOXYWTEHYDROCHLORIDE 0 ETHYL-1-hlETHYL-4-PHENYLPIPERIDYL-4CARBOXYLhTE HYDROCHLORIDE 0 ISONIPECAINE HYDROCHLORIDE 0 LIDOL 0 LYDOL 0 MEFEDINA 0 MEPA4DIN0 MEPERIDINE HYDROCHLORIDE 0 MEPHEDINE 0 1-METHYL-4-CARBETHOXY-4PHENYLPIPERIDINE HYDROCHLORIDE 0 N -
METHYL-4-PHENYL-4-CARBETHOXYPIPERIDINE HYDROCHLORIDE 0 l-METHYL-4-PHEhYL-4CARBOETHOXYPIPERIDINEHYDROCHLORIDE 0 1METHYL-4-PHEhYLISONIPECOTIC ACID ETHYL ESTER HYDROCHLORIDE 0 OPERIDINE 0 PANTL4LGINE0 PENTANTIN 0 PENTANTIN HYDROCHLORIDE 0 PETHIDINE CHLORIDE 0 PETIDIN 0 PIRIDOSAL 0 S 140 0 SALTERALGYL 0 SPASMEDAL 0 SPASMODOL1;U 0 SYNELAVDINE 0 VCY 554
SAFETY PROFILE: Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Moderately toxic by parenteral route. Experimental teratogenic effects. Mutation data reported. An analgesic. When heated to decomposition it emits very toxic fumes of HC1 and NO,.
DAN100 CAS: 57852-57-0 HR: 3 4-DEMETHOXYDAUNORUBICIN HYDROCHLORIDE mf: C26H27N09*ClH mw: 534.00 SYN: DAUNOMYCIN, 4-DEXlETHOXI-, HYDROCHLORIDE SAFETY PROFILE: A poison by ingestion,
subcutaneous, intravenous, and intraperitoneal routes. When heated to decomposition it emits toxic vapors of NO,, HC1, and C1-. DA0800 CAS: 867-27-6 HR: 3 DEMETON-0-METHYL mf: C6Hi503PS2 mw: 230.30 PROP: Characterisitic odor. D: 1.2. Sol in water at 20'. SYNS: BAY 15203 0 DEMETON-0-METILE (ITXLMN) 0
O,O-DIMETHYL-O-(2-AETHYLTHIO-AETHYL)
IMONOTHIOPHOSPHAT (GERMAN) 0 0,O-DIMETHYL0-ETHYLMERCAPTOETHYLTHIOPHOSPHATE 0 0,ODIMETHYL 2-ETHYLMERCAPTOETHYLTHIOPHOSPHATE, THIONO ISOMER 0 O,O-DIMETHYLO-(2-ETHYLTHIO-ETHYL)-MONOTHIOFOSFAAT (DUTCH) 0 0,ODIMETHYL-O-2-(ETHYLTHIO)ETHYL PHOSPHOROTHIOATE 0 O,O-DIMETILO-(2-ETILTIO-ETIL)MONOTIOFOSFATO (ITALIAX) 0 ENT 18,862 0 pETHYLMERCAPTOETHYL DIMETHYL THIONOPHOSPHATE 0 0-(2-(ETHYLTHIO)ETHYL).O,ODIMETHYL PHOSPHOROTHIOATE 0 2-(ETHYLTHIO)ETHYL DIMETHYL PHOSPHOROTHIONATE 0 METHYL-DEiMETON-0 0 0-METHYLDEMETON 0 METHYLCISTOX 0 METHYLSYSTOX 0 METHYLSIERCAFTOPHOS 0 THIOPHOSPHATE de 0 , O DIMETHYLE et de 0-2-ETHYLTHIO-ETHYLE (FRENCH)
SAFETY PROFILE: Poison by ingestion,
skin contact, inhalation, and intravenous routes. Experimental teratogenic and reproductive effects. When heated to decomposition it emits very toxic fumes of PO, and SO,. See also DEMETON-0 + DEMETON-S and other DEMETON entries. DAPOOO CAS: 301-12-2 HR: 3 DEMETON-0-METHYL SULFOXIDE mf: C6H1503PSz mw: 230.30 PROP: Yellow liquid. D: 1.289 @ 20°/4', bp: 106' @ 0.01 mm. Sol in H20, most org solvs; ins01 in pet ether. SYNS: BAY 21097 0 DEMETON-S-METHYL-SULFOXD (GERMAN) 0 DEMETOX-S-METHYLSCLFOXIDE 0
DEMETON-S-METHYL DAP400 423 DEMETON-METHYLSULPHOXIDE 0 0,O-DIMETHYL-
SAFETY PROFILE: Poison by ingestion,
S-(2-AETHYLSCLFINYL-AETHYL)-THIOLPHOSPHL4T (GERXZeU) 0 O,O-DIMETHYL-S-(2-ETHTHIONYL-
intraperitoneal, and subcutaneous routes. When heated to decomposition it emits very ETHYL) PHOSPHOROTHIOATE 0 DIMETHYLA(2toxic fumes of PO, and SO,. See also ETHTHIONYLETHYL)THIOPHOSPHATE 0 0,ODIMETHYI-S-(2-ETHYLSULFINYJ-ETHYL)-MONO- DEMETON-0 + DEMETON-S and other THIOFOSFAAT (DUTCH) 0 O,O-DIMETHYL-S-(2demeton entries. (ETHYLSULF1NYL)ETHYL)PHOSPHOROTHIOATE 0
O,O-DIMETHYL-S-(2-ETHYLSULFINYL)ETHYL
DAP400 CAS: 919-86-8 HR: 3 DEMETON-S-METHYL DIMETHYL-S-(3-OXO-3-THIA-PENTYL)-MONOTHIO-mf: CbHlj03PS2 mw: 230.30 PHOSPHAT (GERMAN) 0 O,O-DIMETIL-S-(2-ETIL PROP: Pale-yellow oil. Bp: 89" @ 0.15 mm, SOLFINIL-ET1L)-MONOTIOFOSFATO (ITALIAN) 0 ENT @ 20"/4". Sltly sol in H20. d: 1.21 24,964 0 S-(2-(ETHYTSL'LFINYL)ETHYL))-O,O-DIMETHSYNS: BAY 18436 0 BAYER25/154 0 DEMETON-SYL PHOSPHOROTHIOATE 0 ISOMETHYLSYSTOX THIOPHOSPHATE 0 0,O-DIMETHYL-S-ETHYLSULPHINYLETHYLPHOSPHOROTHIOLATE 0 0,O-
SULFOXIDE 0 METAISOSYSTOXSULFOXIDE 0 METASYSTEMOX 0 METASYSTOX-R 0 METHYL DEMETON-0-SULFOXIDE 0 METILMERCAPTOFOSOKSID 0 OXYDEMETONMETHYL 0 OXYDEMETON-METILE (ITALIAN) 0 R 2170 0 THIOPHOSPHATE de 0,O-DIMETHYLE et de S-2-ETHYL SULFINYLETHYLE (FRENCH)
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by ingestion, skin contact, intravenous, and intraperitoneal routes. Human mutation data reported. When heated to decomposition it emits very toxic fumes of PO, and SO,. See also other demeton entries.
DAP200 CAS: 126-75-0 HR: 3 DEMETON-S mf: CaH1903PS2 mw: 258.36 PROP: Colorless oily liquid. Bp: 128" @ 0.1IQa. Sol in water.
METILE (ITALLAN) 0 O,O-DIMETHn-S-(2-AETHYLTHIO-AETHYL)-MONOTHIOPHOSPHAT (GERWGV) 0
O,O-DIMETHYL-S-(2-ETHTHIOETHYL)PHOSPHOROTHIOATE 0 DIMETHYL-S-(2-ETHTHIOETHYL)THIOPHOSPHATE 0 0,O-DIMETHYL-S-ETHYLMERCAPTOETHYL THIOPHOSPHATE I3 0,O-DIMETHYL-SETHYLMERCAPTOETHYL THIOPHOSPHATE, THIOLO ISOMER 0 O,O-DIMETHYLS-(2-ETHYLTHIO-ETHYL)MONOTHIOFOSFAAT (DUTCH) 0 O,O-DIhlETHYL-S-(2(ETHYLTHI0)ETHYL)PHOSPHOROTHIOATE 0 0,O-
DIMETHYL-S-(3-THIA-PENTYL)-MONOTHIOPHOSPHAT (GERMAN) 0 O,O-DIMETIL-S-(2-ETILITIO-ETIL)MONOTIOFOSFATO (ITALLW) 0 DUFUTOX 0 S-(2(ETHYLTHIO)ETHYL)-O,O-DIIMETHYL PHOSPHOROTHIOATE 0 S-(2-(ETHYLTHIO)ETHYL)DIMETHYL PHOSPHOROTHIOLATE 0 S-(2-(ETHYLTHIO)ETHYL)0,O-DIMETHYLTHIOPHOSPHATE 0 ISOMETASYSTOX 0 ISOMETHYLSYSTOX 0 METAISOSEMOX 0 METAISOSYSTOX 0 METASYSTOX FORTE 0 METHYL DEMETON THIOESTER 0 METHYL ISOSYSTOX 0 METHYL-MERCAPTOFOSTEOLOVY 0 THIOPHOSPHATE de 0,O-DIMETHYLE et de S-2-ETHYLTHIOETHYLE (FRENCH)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. EPA Extremely SYNS: O,O-DIAETHYL-S-(2-AETHYLTHIO-AETHYL)MONOTHIOPHOSPHAT (GERMAN) 0 DLAETHYLTHIOPHOSPHORSAECREESTERdes AETHYLTHIOGLYKOL (GERMAN) 0 DIETHYI-S-(2-ETHIOETHYL)THIOPHOSPHATE 0 O,O-DIETHYL-S-(2-ETHTHIOETHYL)PHOSPHOROTHIOATE0 0,O-DIETHYL-S-
Hazardous Substances List. ACGIH TLV: TWA 0.05 ppm
(shn)(sensitizer); Not Classifiable as a Human Carcinogen ETHYL-2-ETHYLMERCAPTOPHOSPHOROTHIOLATE 0 SAFETY PROFILE: Poison by ingestion, 0,O-DIETHYL-S-Q-ETHYLTHIO-ETHYL)-?\.IONO-inhalation, s h contact, intraperitoneal, and THIOFOSFAAT (DUTCH) 0 O,O-DIETHYLS-2intravenous routes. Mutation data reported. (ETHYLTHI0)ETHYLPHOSPHOROTHIOATE 0 0,OAn insecticide. When heated to DIETHYL-S-(2-(ETHYLTHIO)ETHYL) PHOSPHOROTHIOWTE (USDA) 0 O,O-DIETIL-S-(2-ETILTIO-ETIL)-decomposition it emits very toxic fumes of hlONOTIOFOSFATO (ITALIAN) 0 O,O-DIETYL-S-2PO, and SO,. See also DEMETON-0 + ETYLMERKAMOETYLTIOFOSFAT (CZECH) 0 2DEMETON-S and other demeton entries. (ETHYLTHI0)-ETHANETHIOL S-ESTER with 0,ODIETHYL PHOSPHOROTHIOATE 0 ISODEMETON 0 IZOSYSTOX (CZECH) 0 PO-SYSTOX 0 THIOLDEMETON 0 THIOL SYSTOX 0 THIOPHOSPHATE de 0,ODIETHYLE et de S-(2-ETHYLTHIO-ETHYLE)(FRENCH)
424 DAPGOO DEMETON-S-METHYL-SULPHONE DAP6OO CAS: 17040-19-6 HR: 3 DEMETON-S-METHYL-SULPHONE mf: CsH1505PSz mw: 262.30 PROP: Crystals. Mp: 60', bp: 120' (@, 0.03 mm. SYNS: BAYER 20315 0 DEhlETON-S-~~ETHnSULFON (GERMAN) 0 DEMETON-S-hiETHnSULFONE 0 0,O-
DIMETHYL-S-(2-AETHnSULFONn-AETHYL)THIOLPHOSPHAT (GERMAN) 0 O,O-DIMETHYL-S-(2-
reported. When heated to decomposition it emits acrid smoke and irritating fumes. DAQ850 CAS: 951-77-9 DEOXYCYTIDINE mf: C9H13N304 mw: 227.25 PROP: A solid. Mp: 207-210'.
HR: D
SYNS: CYTOSINE DEOXYRIBOSIDE 0 dCYD 0 2'-
DEOXYCYTIDINE 0 DEOXYRIBONUCLEOSIDE ETHSULF0NYLETHYL)PHOSPHOROTHIOATE0 CYTOSINE 0 DEOXYRIBOSE CYTIDINE 0 DIhfETHYL-S-(2-ETHSLLFONYLETHYL)THIOPHOSPHATE 0 O,O-DIR.IETHYLS-ETHY2-SULFONYLETH-DESOXYCYTIDIN (GERMAN) YL PHOSPHOROTHIOLATE 0 0,O-DIMETHYL-SETHYLSULPHONYLETHYLPHOSPHOROTHIOLATE 0 DIOXYDEMETON-S-METHYL 0 E 158 0 ISOMETASYSTOX SULFONE 0 ISOMETHYLSYSTOXSULFONE 0 M 3/158 0 METAISOSYSTOX-SOLFON 20 315
SAFETY PROFILE: Poison by ingestion, inhalation, intraperitoneal, and intravenous routes. Moderately toxic by skin contact. Mutation data reported. An insecticide. When heated to decomposition it emits very toxic fumes of PO, and SO,. See also DEMETON-0 + DEMETON-S and other demeton entries.
DAQ4OO CAS: 83-44-3 HR: 3 DEOXYCHOLATIC ACID mf: C24H4004 mw: 392.64 PROP: A white crystalline powder from EtOH. Mp: 187-189'. Sol in alc, acetone; sltly sol in ether and chloroform; insol in water. SYNS: CHOLEIC ACID 0 CHOLEREBIC 0
CONSENSUS REPORTS: EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
DAR400 CAS: 50-91-9 HR: 3 2'-DEOXY-5-FLUOROURIDlNE mf: C9HllFN205 mw: 246.22 PROP: Crystals from butyl acetate. Mp: 150-1 51'. SYNS: DEOXYFLUOROURIDINE 0 1-P-d-2'DEOXYRIBOFURANOSYL-5-FLUOROURACIL0 FDUR 0 FLOXURIDIN 0 FLOXURIDINE 0 FLUORODEOXY0 5URIDINE 0 P-5-FLUORO-2'-DEOXYURIDINE FLUORODEOXYURIDINE 0 5-FLUORO-2-DEOXYURIDINE 0 5-FLUORO-2'-DEOXnWDINE 0 5FLUOROURACIL DEOXYRIBOSIDE 0 5-FLUOROURACIL-2'-DEOXYRIBOSIDE 0 FLUORURIDINE DEOXYRIBOSE 0 FCDR 0 5-FUDR 0 NSC-27640 0 RO 5-0360
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by ingestion. Moderately toxic by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. Human systemic effects: hypermotitity, diarrhea, METHYL-3-CARBOXYPROPYL)-ETIOCHO~~E-3-a,12nausea, vomiting and other gastrointestinal a-DIOL 0 PYROCHOL 0 SEPTOCHOL effects, allergic dermatitis, and bone marrow CONSENSUS REPORTS: Reported in EPA changes. Human mutation data reported. TSCA Inventory. When heated to decomposition it emits very SAFETY PROFILE: Poison by toxic fumes of F- and NO,. intraperitoneal route. Moderately toxic by ingestion and intravenous routes. DAR6OO CAS: 154-17-6 HR: 3 Questionable carcinogen with experimental 2-DEOXYGLUCOSE tumorigenic data. Experimental mf: C~H1205 mw: 164.18 reproductive effects. Mutation data CHOLOREBIC 0 DEGALOL 0 DEOXYCHOLICACID (FCC) 0 7-a-DEOXYCHOLICACID 0 DESOXYCHOLIC ACID 0 DESOXYCHOLSAEURE (GERMAN) 0 3,12DIHYDROXYCHOLASICACID 0 3-a,l2-a-DIHYDROXYCHOLWIC ACID 0 3-a,l2-a-DIHYDROXY-j-PCHOL4NOIC ACID 0 3-a,l2-&DIHYDROXY-5-PCHOLILU-24-OICACID 0 3-a,l2-a-DIHYDROXYCHOLAXSAELRE (GERMAN) 0 DROXOLAN 0 17-P-(1-
DESOXYEPHEDRINE HYDRO-CHLORIDE PROP: Crystals from acetone or butanone. Mp: 142-144'. a-Form: Crystals from isopropanol. Mp: 134-136'. SYNS: 2-DEOXY-d-ARABINO-HEXOSE 0 2-DEOXY-3ARABINO-HEXOSE 0 d-2-DEOXYGLUCOSE0 2DEOXY-d-GLUCOSE0 2-DEOXY-d-GLUCOSE (FRENCH) 0 2-DG 0 NSC-15193 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous route. Moderately toxic by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits acrid smoke and fumes. DASOOO CAS: 54-42-2 HR: 2 2'-DEOXY-5-IODOURIDINE mf: CsHllINz05 mw: 354.12 PROP: Crystals from H20. Mp: 160'. SYNS: ALLERGAN 211 0 DENDRID
0 1-(2-DEOXY-P-
d-RIBOFURrWOSYL-5-IODOURACIL 0 1-P-d-2'DEOXYRIBOFURANOSX-5-IODOURACIL 0 EMANIL 0 HERPESIL 0 HERPIDU 0 HERPLEX 0 HERPLEX LIQUIFILM 0 IDEXUR 0 IDOXENE 0 IDOXURIDIN 0 IDOXURIDINE IDU 0 IDUCHER 0 IDULEA 0 IDUOCULOS 0 IDUR 0 IDURIDIN 0 5-IODODEOXYURIDINE 0 5-IODO-2'-DEOXYURIDINE 0 5IODOURACIL DEOXYRIBOSIDE 0 IUDR 0 5-IUDR 0 JODDEOXIURIDIN 0 KERECID 0 NSC-39661 0 OPHTHALMADINE 0 SK&F 14287 0 STOXIL 0 SYNMIOL
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Moderately toxic by intraperitoneal route. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic data. Human mutation data reported. When heated to decomposition it emits very toxic fumes of I- and NO,.
DAZ115 CAS: 313-06-4 HR: D DEPOFEMIN mf: C26H3603 mw: 396.62 PROP: Crystals from benzene + pet ether. Mp: 151-152'. Sol in ether, methanol, benzene, chloroform, peanut oil, cottonseed
DBABOO 425
oil, corn oil, and sesame oil. The limit of solubility in the oils is about 400 mg/mL. SYNS: DEPOESTRADIOL 0 DEPOESTRADIOL CYPIONATE 0 ECP 0 ESTRADEP 0 ESTRADIOL CYCLOPENTYLPROPIONATE0 ESTRADIOL-17CYCLOPENTYLPROPIONATE0 ESTRADIOL-17-PCYCLOPENTYLPROPIONATE0 ESTRADIOL CYPIONATE 0 ESTRADIOL-17-CYPIONATE0 ESTRADIOL-17-P-CYPIONATE 0 (17-P)-ESTRA1,3,5(1O)-TRIENE-3,17-DIOL 17CYCLOPENTANEPROPANOATE( 9 0 CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An experimental teratogen. Other experimental reproductive effects. A steroid. When heated to decomposition it emits acrid smoke and fumes.
DBA800 CAS: 300-42-5 HR: 3 DESOXYEPHEDRINE HYDROCHLORIDE mf: CloH15N*ClH mw: 185.72 PROP: Crystals from EtOH/Et2O. Mp: 135-136'. SYNS: A 884 0 AMDRAM 0 AMEDRINE 0 AMPHEDROXY 0 AMPHEDROXYN 0 APhVIINE 0 BOMBITA 0 C 6379 0 CORVITIN 0 DAROPERVAMIN 0 DEA 0 x 0 - 5 0 DEOFED 0 DEOXYEPHEDRINE 0 DEPOXIN 0 DESAMINE 0 DESFEDRIN 0 DESOSSIEFEDRINA 0 DES-OXA-D 0 DESOXEDRINE 0 DESOXIN 0 DESOXO-5 0 DESOXYFED 0 DESOXYN 0 DESOXYPHED 0 DESTIM 0 DETREX 0 DEXOPHRINE 0 DEXOVAL 0 N,a-DIMETHXP H E N E T H U M I N E HYDROCHLORIDE 0 DOPIDRIN 0 DOXEPHRIN 0 DOXYFED 0 DRINALFA 0 EFFROXINE 0 ESTIMULEX 0 EUPHODRIN 0 FENYPRIN 0 GEROBIT 0 GEROVIT 0 HEROPON 0 ISOPHEN 0 KEMODRIN 0 LANAZINE 0 MADRINE 0 METAMFETAbfINA 0 METAMPHEThbfIN 0 METANFETAhUNA 0 METHAMPHETAMINE HYDROCHLORIDE 0 METHEDRINE 0 METHEDRINE HYDROCHLORIDE 0 METHOXYN 0 METHYLAMPHETAMINE HYDROCHLORIDE 0 METHYLBENZEDRIN 0 METHYLISOMIN N-METHYL-P-PHENYLISOPROPYLAMINHYDROCHLORID(GERMAN) 0 METHYLPROPAMINE 0 NEODRINE 0 NEOPHARMEDRINE 0 NORODIN 0 OXYDRENE 0 OXYFED 0 PERVITIN 0 PHILOPON 0 PREMODRIN 0 SEMOXYDRINE 0 SPEED 0 STIMULEX 0 TONEDRIN 0 VONEDRINE SAFETY PROFILE: Poison by ingestion, intravenous, intraperitoneal, subcutaneous, and intramuscular routes. Human systemic
426 DBB200 2-DESOXYPHENOBARBITAL effects by ingestion: altered sleep patterns, anorexia, and change in heart rate. Experimental reproductive effects. An eye irritant, A powerful central nervous system stimulant. When heated to decomposition it emits very toxic fumes of NO, and HC1. See also BENZEDRINE. DBB2OO CAS: 125-33-7 HR: 3 2-DESOXYPHENOBARBITAL mf: C12H14N202 mw: 218.28 PROP: White crystalhe powder; odorless with slty bitter taste. Mp: 281'-282'. Sol in water <1 mg/mL @ 19'. SYNS: 5-i\ETHYL-5-PHENYL-HEXIHYDROPYRIMIDIi%4,6-DION (GERMAN) 0 CYRAL 0 2DEOXYPHENOBARBITAL 0 DESOXYPHENOBARBITONE 0 5-ETHYLDIHMRO-5-PHENYL4,6(1H,5H)-PYRILiIDINEDIONE 0 5-ETHYLHEXAHYDRO-4,6-DIOXO-5-PHENYLPHYIMIDINE 0 5ETHYLHEXAHMRO-j-PHENYLPYRIMIDINE-4,6DIONE 0 j-ETHYL-j-PHENnHEXAHMROPYRIMIDINE-4,6-DIONE 0 HEXADIONA 0 HEXAMIDINE 0 HEXAMIDINE (the anuspasmohc) 0 LEPIhiIDIN 0 LEPSIRAL 0 MAJSOLIN 0 MIDOXE 0 MILEPSIN 0 SIISODINE 0 MISOLYNE 0 MIZODIN 0 MIZOLIN 0 MYL.EPSIiS 0 hWLEPSINUM 0 MYSEDON 0 MYSOLINE 0 NCI-C5636@0 5-PHENYL-5-ETHYLHEXAHYDROPYRIMIDINE-4,6-DIONE 0 PRILEPSIN 0 PRIhfACIONE 0 PRIMACLONE 0 PRIMACONE 0 PRIhWKTON 0 PRIhfIDON 0 PRIhIIDOSE 0 PRYSOLINE 0 PYRIMIDONE MEDI-PETS 0 ROE 101 0 SERTAN
SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Human teratogenic effects include developmental abnormalities of the craniofacial area, s h n and s h n appendages, and cardlovascular system. Human reproductive effects: effects on newborn, including unusual growth statistics, drug dependence, physical and other neonatal changes. Experimental teratogenic and reproductive effects. Human mutation data reported. An addictive drug. When heated to decomposition it emits toxic fumes of NO,. See also BARBITURATES.
DBC400 CAS: 1177-87-3 DEXAMETHASONE ACETATE mf: C24H31F06 mw: 434.55
HR: D
SYNS: DECADRON-LA 0 DECTAN
0 9-FLUORO-11-
p,17,21-TRIHYDROXY-l6-a-METHYLPREGNA-l,4DIENE-3,2@-DIONE ACETATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Experimental
teratogenic and reproductive effects. A steroid. When heated to decomposition it emits toxic fumes of F-. DBC800 CAS: 9004-54-0 HR: 2 DEXTRAN 1 PROP: A linear water-sol polymer of average molecular weight 200,000 (ARPAAQ 6?,589,59). CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROF1LE: Questionable carcinogen with experimental neoplastigenic, tumorigenic, and teratogenic data. Other experimental reproductive effects. When heated to decomposition it emits acrid smoke and fumes. See also other dextrans. DBDOOO CAS: 9004-54-0 HR: 2 DEXTRAN 2 PROP: A linear, water-sol polymer of average molecular weight 100,000 (ARPAAQ 6?,589,59). CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits acrid smoke and fumes. See also other DEXTRANS. DBD2OO CAS: 9004-54-0 HR: 2 DEXTRAN 5 PROP: A highly branched, water-sol polymer (ARPAAQ 6?,589,59). CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits acrid smoke and fumes. See also other dextrans.
1,3-DIACETIN DBFGOO 427
DBD400 CASE9004-54-0 HR: 3 DEXTRAN 10 PROP: A branched, water-sol polymer of average molecular weight 89,400 (ARPAAQ 67,589,59). CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. When heated to decomposition it emits acrid smoke and fumes. See also other DEXTRANS. DBD6OO CAS: 9004-54-0 HR: 2 DEXTRAN 11 PROP: A highly branched, water-sol polymer of average molecular weight 71,400 (ARPAAQ 67,589,59). CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Questionable carcinogen with experimental neoplastigenic and tumorigenic data. When heated to decomposition it emits acrid smoke and fumes. See also other dextrans. DBD700 CAS: 9004-54-0 HR: 2 DEXTRAN 70 PROP: Chemical and physical properties of the dextrans vary with the methods of production. Native dextrans usually have high molecular weight; lower-molecularweight clinical dextrans are usually prepared by depolymerization of native dextrans or by synthesis. All dextrans are composed exclusively of a-d-glucopyranosyl units, differing only in degree of branching and chain length. SYNS: DEXTRAN 0 DEXTRAVEN 0 EXPANDEX 0 GENTRAN 0 HEMODEX 0 INTRADEX 0 X4CROSE 0 ONKOTIN 0 PLAVOLEX 0 POLYGLUCIN 0 PROMIT
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Human systemic effects by intravenous route: dermatitis and changes in the vascular and cardiac systems. Experimental reproductive effects. An
experimental teratogen. See also various dextrans. DBD800 CAS: 9004-53-9 HR: 1 DEXTRlNS mf: ( C ~ H I O ~ ~ ) ~ * X H Z ~ PROP: An intermediate product formed by the hydrolysis of starches. It describes a class of substances. Yellow or white powder or granules. Sol in b o h g water to give a gummy solution; insol in alc and ether; forms colloids. SYNS: ARTIFICIAL GUhl 0 DEXTRANS 0 STARCH GUM 0 TAPIOCA 0 VEGETABLE GUhl
SAFETY PROFILE: M d l y toxic by intravenous route. When heated to decomposition it emits acrid smoke and irritating fumes.
DBF200 CAS: 642-65-9 2-DI ACETAMIDOFLUOREN E mf: C17H15N02 mw: 265.33
HR: 3
SYNS: N-ACETn-~-9H-FLUOREN-2-YL-ACETh~IIDE 0 N-DMCETYL-2-ltlINOFLUORENEN,NDIhCETYL-2-A~~Ih'OFLUORENE 0 2-DIACETYLAMINOFLUOREXE 0 N,N-DIACETYL-2-FLUORENMlINE 0 F - U 0 2-FLUORENYLDIACETAMIDE0 NFLUOREN-2-YLDIhCEThMIDE O N-2-FLUORENYLDIACETAMIDE
SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. When heated to decomposition it emits toxic fumes of NO,.
DBF6OO CAS: 102-62-5 HR: 2 1,3-DIACETIN mf: C7H1205 mw: 176.19 PROP: Crystals. D: 1.178 @ 15"/15', bp: 280', mp: 40'. SYNS: 1,3-DIACETATEGLYCEROL 0 IJDIACETATE 1,2,3-PROPANETRIOL0 DIACETIN 0 1,2-DI-ACETIN 0 2,3-DMCETIN 0 DIACETYL GLYCERIKE 0 DIGLYCERIDE ACETIC ACID 0 GLYCEROL DIACETATE 0 GLYCERYI,1,3-DIACETATE 0 (HYDR0XYMETHYL)ETHYLENEACETATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Moderately toxic by
subcutaneous and intravenous routes. M d l y
428
DBF750
DIACETONE ALCOHOL
toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. DBF750 CAS: 123-42-2 HR: 3 DIACETONE ALCOHOL DOT: UN 1148 mf: C6H1202 mw: 116.18 PROP: Liquid; oily; faint pleasant odor. Mp: -47 to -54", bp: 164", flash p: 148"F, d: 0.9306 @ 25"/4", autoign temp: 1118"F, vap d: 4.00, vap press: 1.1 mm @ 20°, lel: 1.8'/0, uel: 6.9%, flash p: (acetone free) 136°F. Sol in water. IDLH 1800 ppm [l OYoLEL]. SYNS: DIACETONALCOHOL(DUTCH) 0 DIACETONALCOOL (ITALIAN) 0 DIACETONALKOHOL (GERMAS) 0 DIACETONE 0 DIACETONE-ALCOOL (FRESCH) 0 DIKETOKE ALCOHOL 0 4-HYDROXY-2KETO-4-METHYLPENTAKE0 4-HYDROXY-4-METHYL PESTAN-2-ON (GERMAN, DUTCH) 0 4-HYDROXY-4METHYLPENTA4NONE-20 4-HYDROXY-4-METHYL PENTAN-2-OSE 0 4-HYDROXY-4-hIETHYL2PENTAiiONE 0 4-IDROSSI-4-I\IETIL-PENTAN-2-ONE (ITALIAN) 0 2-METHYL-2-PENTANOL-4-ONE 0 PYRANTON 0 TYRANTON CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 50 pprn ACGIH TLV: TWA 50 ppm DFG MAK: 50 ppm (240 mg/m3) NIOSH REL: (Ketones) TWA 240 mg/m3 DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by ingestion and intraperitoneal routes. Mddly toxic by skm contact. Human systemic effects by inhalation: headache, nausea or vomiting, eye and pulmonary changes. A skin, mucous membrane, and severe eye irritant. Can cause anemia and damage to liver and hdneys. Narcotic in high concentration. Flammable liquid when exposed to heat or flame; can react with oxidzing materials. Explosive in the form of vapor when exposed to heat or flame. To fight fire, use alcohol foam, foam, COz, dry chemical. When heated to decomposition it
emits acrid smoke and irritating fumes. See also KETONES. DBF800 CAS: 1067-33-0 HR: 3 DIACETOXYDlBUTYL STANNANE mf: C12H2404Sn mw: 351.05 PROP: Clear, colorless oily liquid with a slight acetic acid odor. Bp: 144.5-145.5' @ 10 mm (decomp), mp: 8.5-10°, fp: 5-10', flash p: 290°F (OC), d: 1.31 @ 25", vap d: 12.1. Sol in org solvs. SYNS: BA 2126 0 B I S ( A C E T n 0 X Y ) D I B U T Y L S T A N ~ ~0EDIACETOXYBUTYLTIN 0 DUCETOXYDIBUTYLTIN 0 DIBUTYL TIN DIACETATE 0 FOhlREZ SUL-3 0 NCIC02028 0 T 1 (Catalyst) CONSENSUS REPORTS: NCI
Carcinogenesis Bioassay (feed); Inadequate Studies: mouse, rat NCITR* NCI-CG-TR183,79. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 ( s h ) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (shn). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion and intravenous routes. Experimental reproductive effects. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use water, foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also TIN COMPOUNDS. DBHOOO CAS: 95-45-4 HR: 3 DIACETYL DlOXlME mf: C~HENZOZ mw: 116.14 PROP: Triclinic crystals from EtOH (ad. Mp: 238-240". Sol in EtOH, MezCO, Et20, and alk soh; very sltly sol in H20 and CHCl3. SYNS: 2,3-DIISONITROSOBUTAiblE 0 DIMETHYLGLYOXIME
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
DIALLYLDIBROMO STANNANE DBJ400 429
DBH700 HR: D DIACETYL TARTARIC ACID ESTERS of MONO- and DIGLYCERIDES PROP: Vary from sticky, viscous liquid to waxy solid; faint acid odor. Sol in oil, methanol, acetone, acetic acid, water. SAFETY PROFILE: When heated to decomposition it emits acrid smoke and irritating fumes.
ALLYLE) (FRENCH) NUMBER U062
PYRADEX 0 RCRA WASTE
CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 30,235,83; Animal Sufficient Evidence IMEMDT 12,69,76. EPA Genetic Toxicology Program.Community Right-To-Know List. EPA Extremely Hazardous Substances List. SAFETY PROFILE: Poison by ingestion. DB1099 CAS: 10311-84-9 HR: 3 Moderately toxic by skin contact. DIALIFOR Questionable carcinogen with experimental mfi C14H17N04PS2 mw: 393.86 carcinogenic and tumorigenic data. Mutation PROP: Crystals from toluene/hexane. Mp: data reported. When heated to 67-69'. decomposition it emits very toxic fumes of SYNS: S-(2-CHLORO-l-(1,3-DIHYDRO-l,3-DIOXO-2HISOINDOL-2-YL)ETHYL)-O,O-DIETHYL PHOS-PHOROC1-, NO,, and SO,. See also DITHIOATE 0 S-(2-CHLORO-l-PHTHALIMIDOETHYL)CARBAMATES and ALLYL 0,O-DIETHYL PHOSPHORODITHIOATE 0 0,O-DIETHCOMPOUNDS. YL-S-(2-CHLORO-l-PHTHALIMIDOETHYL)PHOSPHORODITHIOATE 0 ENT 27,320 HERCULES 14503 U PHOSPHORODITHIOIC ACID-S-(2-CHLORO-1 -(1,3DB1600 CAS: 124-02-7 DIHYDRO-I,3-DIOX0-2H-ISOINDOL-2-YL))ETHYL-O,0DIALLYLAMINE DIETHYL ESTER 0 PHOSPHORODITHIOIC ACID-S-((2DOT: UN 2359 CHLORO-1-PHTHALIMIDOETHYL-0,)-DIETHYL ESTER 0 TORAK mf: C6H11N mw: 97.18
HR: 3
SAFETY PROFILE: Poison by ingestion and
PROP: Liquid, sol in water. D: 0.7889 @
skin contact. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of SO,, PO,, and NO,.
20', bp: 112', fp: -loo',
flash p: 69.8'F.
SYNS: DI-2-PROPENYLAMINE 0 N-2-PROPENYL-2PROPEN-1-AMINE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 3; Label: DB1200 CAS: 2303-16-4 HR: 3 Flammable Liquid DIALLATE SAFETY PROFILE: Poison by ingestion, mf: CIOHI~C~ZNOS mw: 270.24 s h n contact, and intraperitoneal routes. PROP: Brown liquid. Bp: 150" @ 9 mm, Moderately toxic by inhalation. Human mp: 25-30'. Sltly sol in water; sol in org systemic effects by inhalation route: eye solvs. lachrymation and changes in the trachea or SYNS: AVADEX 0 CP 15,336 0 DATC 0 2,3-DCDT 0 bronchi. A skin and severe eye irritant. A DIALLh4T (DUTCH) 0 DIALLAT (GERMAN) 0 2,3DICHLORALLYL-N,N-(DIISOPROPYL-THIOCARBXMAT dangerous fire hazard when exposed to heat (GERMAN) 0 S-(2,3-DICHLOR-ALLYL)-N,Nor flame. When heated to decomposition it DIISOPROPYL-MONOTHIOCARBAWT (DUTCH) 0 emits toxic fumes of NO,. See also DICHLOROALLYLDIISOPROPYLTHIOCARBAnIATE 0 AMINES and ALLYL COMPOUNDS. S-2,3-DICHLOROALLYLDIISOPROPYLTHIOCARBA?ATE 0 2,3-DICHLOROALLYL-N,N-DIISOPROPYLTHIOLCARBAMATE 2,3-DICHLORO-2-PROPENE-l-THIOL DBJ4OO CAS: 17381-88-3 HR: 3 DIISOPROPYLCARBAMATE 0 S-(2,3-DICHLORO-2DIALLYLDIBROMO STANNANE PROPEKYL)ESTER, BIS(1-METHYLETHYL)CARBAMOmf: CsHloBnSn mw: 360.67 THIOIC ACID 0 S-(2,3-DICLORO-ALLIL)-N,N-DIISOSYN: DIALLYLTIN DIBROMIDE PROPIL-MONOTIOCARBA,~~~TO (ITALIAN) 0 DIISOPROP1Z-THIOLOCARBARWTE de S-(2,3-DICHLOROOSHA PEL: TWA 0.1 mg(Sn)/m3 ( s h )
430 DBKOOO DlALLYL ETHER ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m' (shn). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of Br-. See also ALLYL COMPOUNDS, BROMIDES, and TIN COMPOUNDS. DBKOOO CAS: 557-40-4 HR: 3 DIALLYL ETHER DOT: UN 2360 mf: C6Ht00 mw: 98.16 PROP: Lquid; odor of radishes. Bp: 94.3', d: 0.805, vap d: 3.38, flash p: 20'F (OC). SYNS: ALLYLETHER 0 3,3'-0XYBIS(l-PROPENE) PROPENYL ETHER CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 3; Label: Flammable Liquid, Poison SAFETY PROFILE: Poison by ingestion. Moderately toxic by s h n contact. A skin and eye irritant. A dangerous fire hazard when exposed to heat, flame, or oxidzing materials. To fight fire, use alcohol foam. Reacts with air to form explosive peroxides. Violent explosions have occurred during distillation. When heated to decomposition it emits acrid smoke and fumes. See also ALLYL COMPOUNDS and ETHERS.
DBK2OO CAS: 999-21-3 DIALLYL MALEATE mf: Ct0H1204 mw: 196.22 PROP: Liquid. Vap d: 6.6.
HR: 3
SYNS: MALEIC ACID, DIALLYL ESTER 0 SIPOMER DAM
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion and
intraperitoneal routes. Moderately toxic by skin contact. A s h n and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS.
DBL2OO CAS: 131-17-9 HR: 3 DIALLYL PHTHALATE mf: C14H1404 mw: 246.28 PROP: Nearly colorless, oily liquid. Bp: 157', flash p: 330'F, d: 1.120 @ 2Oo/2O0, vap d: 8.3. SYNS: DAPON 35 0 DAPON R 0 DI-2-PROPENYL ESTER, 1,2-BENZENEDICARBOXYLICACID 0 NCIC50657 0 PHTHALIC ACID, DIALLYL ESTER 0 oPHTHALIC ACID, DIALLYL ESTER CONSENSUS REPORTS: NTP Carcinogenesis Studies (gavage); Equivocal Evidence: rat NTJ?TR* NTP-TR-284,85. Reported in EPA TSCA Inventory. SAFETY PROFILE: Suspected carcinogen with experimental carcinogenic data. Moderately toxic by ingestion, skin contact, intraperitoneal, and subcutaneous routes. An eye irritant. Mutation data reported. Combustible when exposed to heat or flame; can react with oxidzing materials. To fight fire, use C02 or dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS.
DBL300 CAS: 91297-11-9 DIALLYL SELENIDE mf: C6HtoSe mw: 184.11
HR: 3
SYN: SELENIDE, DIALLYLOSHA PEL: TWA 0.2 mg(Se)/m3 ACGIH TLV: TWA 0.2 mg(Se)/m3 SAFETY PROFILE: Poison by intravenc3us
route. When heated to decomposition it emits toxic fumes of Se. DBM800 CAS: 59-33-6 HR: 3 DIAMINIDE MALEATE mf: C I ~ H ~ ~ N ~ O * C ~mw: H ~401.51 O~ PROP: A solid. Mp: 100-101'. Very sol in H20. SYNS: AH 0 ANISOPYRADAMINE 0 ANTHISAN MALEATE 0 ANTIHIST 0 N - D I M E T H W I N O E T H Y L N-p-METHOXY-a-AMINOPYRIDINE MALEATE 2-((2(DIMETHYLAMINO)ETHYL)@-METHOXYBEN2YL)AMIN0)PYRIDINE BIMLEATE 0 2-((2-(DIMETHYL-
AMINO)ETHYL)@-METH0XYBENZYL)AMINO)PYRIDINE iMALEATE 0 N,N-DIhlETHYLN'-(C
METHOXYBENZYL)-Ki'-(2-PYRIDYL)ETHYLESEDIA M N E MALEATE 0 HISTATEX 0 MEPYRAMINE hIALEATE 0 N-p-hlETHOXYBENZYL-N'-N'-DIMETHn-
2,4-DIAMINOANISOLE SULPHATE 080400 431 N-a-PYRIDYLETHYLENEDI~~lI~E MALEATE 0 MINIHIST 0 NEOANTERGAN RIALEATE 0 PARAIIW 0 PAIWMINYL MALEATE 0 PYMAFED 0 PYRA MALEATE 0 PYRANILAMINE MALEATE 0 PYRANINYL 0 PYRANISARIINE MALEATE 0 PYRILAMINE MALEATE 0 RENSTAMIN 0 2786 RP. MALEATE 0 STANGEN MALEATE 0 STATOMIN MALEATE 0 THYLOGEN MALEATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: A human poison by ingestion. An experimental poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Experimental reproductive effects. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. An antihistamine. When heated to decomposition it emits toxic fumes of NO,.
DBN6OO CAS: 92-62-6 HR: 3 3,6-DIAMINOACRIDINIUM mf: C13HllN3 mw: 209.27 PROP: Yellow crystals. Mp: 284-286'. SYNS: 3,6-ACRIDINEDWIINE 0 2,g-DIAMINOACRIDINE 0 3,6-DIrtMINOACRIDINE 0 2,8-D&VINO0 ACRIDINIUM 0 3,7-DL451INO-5-hZAANTHRACENE ISOFLAV BASE 0 PROFLAVIN 0 PROFLAVINE 0 PROFOLIOL 0 PROFOR\UPHEN 0 PROFCNDOL 0 PROFURA 0 PROGARTMED 0 PRO-GEN 0 PROGESIC
CONSENSUS REPORTS: IARC Cancer Review: Animal Inadequate Evidence IMEMDT 24,195,80. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intravenous, intraperitoneal, and subcutaneous routes. Questionable carcinogen. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also other diaminoacridine entries.
DBOOOO CAS: 615-05-4 2,4-DIAMINOANISOLE mf: C ~ H I O N ~ O mw: 138.19 PROP: Needles. Mp: 68'.
HR: 3
SYNS: C.I. 76050 0 C.I. OXIDATION BASE 12 0 2,4D M 0 2,4-DIAlrllNEhNISOLE 0 2,4-DIAMINOANISOL 0 2,4-DIAMINOANISOLEBASE 0 m-DkMINOANISOLE 1,~-DIA~IINO-~-IMETHOXYBENZENE 0 2,4-DIAMINO-l-
METHOXYBENZENE 0 FURRO L 0 4-METHOXY-1,3BENZENEDIAMINE 0 p-METHOXY-m-PHENYLENEDIAMINE 0 4-RIETHOXY-m-PHENYLENEDIAMINE 0 4XMPD 0 PELAGOL DA 0 PELAGOL GREY L 0 PELAGOL L
CONSENSUS REPORTS: IARC Cancer Review: Group 2B IMEMDT 7,56,87; Human Limited Evidence IMEMDT 27,103,82. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (2,4-diaminoanisole) Reduce to lowest feasible level SAFETY PROFILE: Confirmed carcinogen. Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental reproductive effects. Human mutation data reported. A skin irritant. When heated to decomposition it emits toxic fumes of NO,. See also other diaminoanisole entries.
DB0400 CAS: 39156-41-7 HR: 3 2,4-DIAMINOANISOLE SULPHATE mf: C ~ H I O N ~ O * H ~ O ~ mw: S 236.27 PROP: Off white to violet powder. Sol in water and ethanol. SYNS: ANISOLE, 2,4-DIAMINO-,HYDROGEN SULFATE 0 ANISOLE, 2,4-DLAMINO-,SULFATE 0 1,3BENZENEDIAMINE, 4-METHOXY, SULFATE (1:1) (%I) 0 C.I. 76051 0 C.I. OXIDATION BASE 12A 0 2,4-DAA SULFATE 0 2,4-DIAMINOANISOLESULPHATE 0 2,4DIAIINO-ANSOL SULPHATE 0 2,4-DLWINO-1METHOXYBENZENE 0 1,3-D~VINO-4-hlETHOXYBENZENE SULPHATE 0 2,4-DIAMINO-l-;LIETHOXYBENZENE SULPHATE 0 2,4-DIAMINOSOLESULPHATE 0 DURAFUR BROWN haT 0 F O U M I N E BA FOURRINE 76 0 FOURRINE SLA 0 FURRO SLA 0 4METHOXY-1,3-BENZEXEDIAMIXE SULFATE 0 4METHOXY-1,3-BENZENEDJAMINE SULFATE (1:l) 0 4METHOXY-l,3-BENZENEDIARIINE SULPHATE 0 4METHOXY-m-PHENYLEXEDX\fIKESULFATE 0 pMETHOXY-m-PHENYLENEDL4MINE SULPHATE 0 4METHOXY-m-PHENYLENED&\lINE SULPHATE 0 4MMPD SULPHATE 0 NAKO TSA 0 NCI-C01989 0 OXIDATION BASE 12A 0 PELAGOL BA 0 PELAGOL GREY 0 PELAGOL GREY SLA 0 PELAGOL SLA 0 RENAL SLA 0 LRSOL SLA U ZOBA SLE CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Animal Sufficient Evidence IMEMDT
432 DBP909
1.5-DIAMINOANTHRARUFIN
27,103,82; Animal Inadequate Evidence IMEMDT 16,51,78. NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NCITR* NCI-CG-TR-84,78. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-ToKnow List. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal route. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and SO,. See also other diaminoanisole entries.
DBU800 CAS: 13426-91-0 HR: 2 1,2-DlAMINOETHANE COPPER COMPLEX DOT: UN 1761 mf: CzHtoNz*xCu mw: 506.92 PROP: Herbicide. SYNS: COPPER-ETHYLENEDIAMINECOMPLEX 0 CUPRIETHYLENE DIAMINE 0 CUPRIETHYLENEDIAMINE,solution (DOq 0 ETHANE, 1,2-DLAMINO-,COPPER COMPLEX 0 KOMEEN 0 KOPLEX AQUATIC HERBICIDE
DBP909 CAS: 145-49-3 HR: 3 1,5-DIAMINOANTHRARUFIN mf: C14H10N204 mw: 270.26 PROP: Dark red crystals or powder. Sol concentration in H2S04; sltly sol in Hz0 and EtOH.
CONSENSUS REPORTS: Copper and its compounds are on the Community RightTo-Know List. DOT CLASSIFICATION: 8; Label: Corrosive, Poison SAFETY PROFILE: Moderately toxic by ingestion. An irritating and corrosive material to the shn, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of NO,. See also COPPER COMPOUNDS.
SYNS: 4,8-DIAMINOANTHRARL!FIr\: 0 1,5-Dl;tMINO4,8-DIHYDROXY-9,10-A"EDIONEDIONE 0 1,5-
DBV400
CAS: 1239-45-8
HR: 3
DIASIINO-4,8-DIHYDROXYAKTHRAQUINONE 0 leuco2,7-DIAMINO-lO-ETHYL-9-PHENYL1,5-DL~hIINO-4,8-DIHYDROXYA~THRAQUINONE 0 PHENANTHRIDINIUM BROMIDE 4,8-DUhIINO-l,5-DIHYDROXYANTHRAQUINONE 0 mf: C Z I H Z O N ~ * B ~mw: 394.35 1,5-DIHMROXY-4,8-D~MINOANTHRACHINON (CZECH) 0 1,5-DIHYDROXY-4,8-DIfINOANTHRA- PROP: Dark-red crystals from EtOH. Mp: QUINONE
238-240'.
CONSENSUS REPORTS: Reported in EPA
SYNS: 3,8-DIAMINO-5-ETHYLG-PHENYLPHENAN-
TSCA Inventory.
THRIDINIUM BROMIDE 0 2,7-DIrZMINO-9-PHENYI-l0ETHYLPHENANTHRIDINIUMBROMIDE 0 2,7-DIAMINO-9-PHENYLPHENANTHRIDINE ETHOBROMIDE 0 DROMILAC 0 ETHIDIUM BROMIDE 0 HOMIDIUM BROMIDE 0 RD 1572
SAFETY PROFILE: Poison by intravenous
route. An eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. DBT2OO CAS: 92-26-2 HR: 3 3,6-DIAMINO-2,7-DIMETHYLACRlDlNE mf: C15H15N3 mw: 237.33 PROP: Crystals from PhNH2. Mp: 325'. SYNS: ACRIDINE YELLOW BASE 0 2,8-DLAMINO-3,7DIhfETHYLiCRIDINE CONSENSUS REPORTS: Reported in EPA
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intraperitoneal and subcutaneous routes. Human mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and Br-. See also BROMIDES.
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous route. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
DBX400 CAS: 8048-52-0 HR: 3 3,6-DIAMINO-lO-METHYLACRlDlNlUM CHLORIDE with 3,6-ACRIDINEDIAMINE mf: C I ~ H ~ ~ N ~ * C ~ * C I ~ mw: H I I 469.03 N~
2,5-DIAMlNOTOLUENE DIHYDRO-CHLORIDE SYNS: ACRIFLAVIN ACRIFLAVINE m n u e w ~ t h PROFLAVINE 0 ACRIFLAVINIUM CHLORIDE 0 ACRIFLAVINIUM CHLORIDUM 0 ACRIFLAVON 0 ANGIFLAN 0 ASSIFLAVINE 0 AVLON 0 BIALFLAVINA 0 BIOACRIDIN 0 BOVOFLAVIN 0 BURNOL 0 BUROFLAVIN 0 CHOLIFLAVIN 0 CHROMOFLAVINE 0 DIACRID 0 3,6-DIAMINOACRIDINEmutture wth 3,6-DIAMINO-I0-METHYLACRIDINIUMCHLORIDE 0 2,8-DIAMINO-lO-METHYLaCRIDINIUI\.I CHLORIDE m t u r e with 2,8-DIAMINOACRIDINE0 EUFLAVIKE 0 FLAVACRIDINUM HYDROCHLORICUM 0 FLAVINE 0 FLAVIOFORM 0 FLAVIPIN 0 FLAVISEPT 0 GLYCOFLAVINE 0 GONACRINE 0 ISRAVIN 0 MEDIFLAVIN 0 NEUTRAL ACRIFLAVINE 0 PANFLAVIN 0 PANTONSILETTEN 0 TRACHOSEPT 0 TRIPLA-ETILO 0 TRYPAFLAVINE 0 VETAFLAVIN 0 XANTHACRIDINUM 0 ZORIFLAVIN CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Inadequate Evidence IMEMDT 13,31,77. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by subcutaneous route. Questionable carcinogen with experimental tumorigenic data. Human mutation data reported. A topical antiseptic used in the treatment of gonorrhea. When heated to decomposition it emits very toxic fumes of NO, and C1-. See also 3,6-DIAMINO-10METHYLACRIDINIUM CHLORIDE.
DBY700 CAS: 82-33-7 HR: 2 1,4-DIAMINO-5-NITRO ANTHRAQUINONE mf: C14H9N304 mw: 283.26 PROP: Violet needles from EtOH. SYNS: 9,IO-ANTHRACENEDIONE,1,4-DM11N0-5NITRO-(9CI) 0 CELLITON FAST VIOLET B 0 CELLITON FAST VIOLET BA-CF 0 CELLITON VIOLET B 0 C.I. 62030 0 CIBACET BRILLIANT VIOLET 3B 0 C.I. DISPERSE VIOLET 8 0 CILLA FAST VIOLET B 0 DIACELLITON FAST VIOLET B 0 I,4-DIAMINO-5NITRO-9,lO-rtllTHRACENEDIONE DWNIX FAST VIOLET B 0 DISPERSE VIOLET 2s 0 DURANOL BRILLIANT BLUE VIOLET BR 0 DURANOL BRILLXVT VIOLET BR 0 FENACET FAST VIOLET B 0 KAYALON FAST VIOLET BR 0 MIKETON FAST VIOLET B 0 NITROCRESOLXVINE 0 PALANIL VIOLET 3B 0 PERLITON VIOLET B 0 SAMARON BRILLIANT VIOLET B 0 SERISOL FAST VIOLET B 0 SCPRACET FAST VIOLET B 0 TERASIL BRILLIANT VIOLET 3B 0 VIOLET 2s 0 VONTERYL VIOLET 2B
DCE200 433
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
DCC800 CAS: 141-86-6 HR: 3 2,6-DIAMINOPYRIDINE mf: CjH7N3 mw: 109.15 PROP: Crystals or leaflets. Mp: 121.5", bp: 148-150" @ 5 mm. CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. DCDOSO CAS: 25007-79-8 HR: 3 2,6-DIAMINO-4-(2-PYRlDYL)-s-TRIAZINE mf: CsHsN6 mw: 188.22 SYNS: A1 3-51408 0 s-TRIAZINE, 2,6-DIAMINO-4-(26-(2PYRIDYL)- 0 1,3,5-TRIAZINE-2,4-DIAMINE, PYRID1NYL)SAFETY PROFILE: A poison by intravenous route. When heated to decomposition it emits toxic vapors of NO,.
DCEOOO CAS: 636-23-7 HR: 3 2,4-DIAMINOTOLUENE DIHYDROCHLORIDE mf: C7HloNp2ClH mw: 195.11 SYN: METATOLYLENEDIAMINEDIHYDROCHLORIDE CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits very toxic fumes of NO, and HC1.
DCE2OO CAS: 615-45-2 HR: 3 SY5-DIAMINOTOLUENEDIHYDROCHLORIDE
434
DCEGOO 2,5-DIAMlNOTOLUENE SULFATE
mf: C7HloNp2ClH
mw: 195.11
SYNs: 2-METHYL-1,4-BENZENEDIAhZINE
DIHYDROCHLORIDE 0 p-TOLUENEDIh\IINE DIHYDROCHLOMDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by ingestion. Experimental teratogenic effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and HC1. See also CHLORIDES.
DCEGOO CAS: 615-50-9 HR: 3 2,5-DIAMINOTOLUENE SULFATE mf: C ~ H I ~ N ~ H ~ Omw: ~ S220.27 PROP: Pale purple powder. Mp: > 300". SYNS: C I. 76043 0 p-DIAMINOTOLUENE SULFATE 0 2,5-DL\MINOTOLUENE SULPHATE 0 2-METHYL-l,4BENZENEDIAMINE SULFATE 0 2-METHYL.-pPHENYLEKEDIAMINE SULPHATE 0 NCI-C01832 0 pTOLUENEDIMMINE SULFATE 0 2,5-TOLUENEDI,&MINE SULFATE 0 TOLUENE-2,5-DIAVINE, SULFATE (1:l) (8CI) 0 p-TOLUENEDItLZIINE SULPHATE 0 TOLUENE-2,5-DUI.IINE SULPHATE 0 p-TOLUYLENEDIAMINE SULPHATE 0 TOLUYLENE-2,5-DIAMINE SULPHATE 0 p-TOLYLENEDIAnlINE SULPHATE
CONSENSUS REPORTS: IARC Cancer Review: Animal Indefinite Evidence IMEMDT 16,97,78. NCI Carcinogenesis Bioassay Completed; Results Indefinite: mouse, rat NCITR* NCI-CG-TR-126,78. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and SO,. See also SULFATES.
DCF200 CAS: 1455-77-2 HR: 2 ~,~-DIAMINO-S-TRIAZOLE mf: C2HjNg mw: 99.12 PROP: Prisms from H20. Mp: 206". SYNS: GUANAZOLE 0 NCI-C04819 0 NSC-1895 CONSENSUS REPORTS: NCI
Carcinogenesis Studes (ipr); Equivocal Evidence: rat CANCAR 40,1935,77; No Evidence: mouse CANCAR 40,1935,77. Reported in EPA TSCA Inventory. SAFETY PROFILE: Human systemic effects by intravenous route: leukopenia (reduced
white blood cell count) and thrombocytopenia (reduced blood platelet count). Human mutation data reported. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NO,. DCGOOO HR: 3 DIAMMINEMALONATO PLATINUM (11) mf: C3HsN204Pt mw: 331.22 PROP: IDLH 4 mg/m3 (as Pt). CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also PLATINUM COMPOUNDS. DCG800 CAS: 7784-44-3 HR: 3 DIAMMONIUM HYDROGEN ARSENATE DOT: UN 1546 mf: AsH30~2H3N mw: 176.03 PROP: White powder or plate-like colorless crystals or prisms. Mp: decomp to yield NH3. SYNS: AXMONIUM ACID ARSENATE 0 AMMONIUM ARSENATE, sohd (DOT 0 DIAMMONIUM ARSENATE 0 DXMMONIUM MONOHYDROGEN ARSENATE DIBASIC AMMOXIUM ARSENATE 0 SECOADARY AMMONIUM ARSENATE CONSENSUS REPORTS: Arsenic and its compounds are on the Community RightTo-Ihow List. OSHA PEL: OSHA: Cancer Hazard ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 p (As)/L inorganic arsenic and methylated metabolites in urine NIOSH REL: (Inorganic Arsenic) CL 0.002 mg(As)/m3/ 15M DOT CLASSIFICATION: 6.1; Label: Poison SAFETY PROFILE: Confirmed human carcinogen. A poison. When heated to decomposition it emits very toxic fumes of As, NO,, and NH3. See also ARSENIC.
0-DIANISIDINE DCJ200 435
DCHOOO CAS: 3164-29-2 HR: 3 DIAMMONIUM TARTRATE mf: C4H606*2H3N mw: 184.18 PROP: White crystals. D: 1.60. Sol in water. SYNS: ALUMONIUMTARTRATE (DOT) 0 AhlMONIUbl-d-TARTRATE 0 2,3DIHYDROXYBUTANEDIOIC ACID, DIAMMONIUM SALT 0 1-TARTARICACID, AMMONIUM SALT 0 TARTARIC ACID, DJAMMONIUM SALT
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Moderately toxic by subcutaneous route. When heated to decomposition it emits very toxic fumes of NH3 and NO,.
DCH2OO CAS: 2050-92-2 HR: 3 DIAMYL AMINE DOT: UN 2841 mf: CloH23N mw: 157.34 PROP: Water-whte liquid. Bp: 210-211', flash p: 124'F, d: 0.777 @ 20°/200, vap d: 5.42. SYNS: D I - n - A i i I N E (DOT) 0 DIPENTYLAbfINE 0
PENTYL PENTYLAhlINE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by inhalation, ingestion, and skin contact. A severe skin irritant. See also AMINES. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use alcohol foam, foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of NO,.
DCIOOO CAS: 120-95-6 HR: 3 DI-tert-AMYLPHENOL mf: C16H260 mw: 234.42 PROP: Molten form. Mp: 23'. SYNS: 2,4-DI-tert-AMYLPHENOL 0 2,CDI-tertPENTYLPHENOL 0 PHENOL, 2,CDI-tert-PENTYL 0 PRODOX 156
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP
AWAY FROM FOOD
SAFETY PROFILE: Poison by ingestion. An eye irritant. When heated to decomposition
it emits acrid smoke and irritating fumes. See also PHENOL. DCJ2OO CAS: 119-90-4 HR: 3 0-DIANISIDINE mf: C14H16N202 mw: 244.32 PROP: Colorless leaflets or crystals. Mp: 137-138', flash p: 403'F, vap d: 8.5. Sol in C6H6 and AcOH; sldy sol in HzO. SYNS: ACETAMINE DMZO BLACK RD 0 AMACEL DEVELOPED NAVY SD 0 AZOENE FAST BLUE BASE 0 AZOFIX BLUE B SALT 0 AZOGNE FAST BLUE B 0 BLUE BN BALSE 0 BRENTAMINE FAST BLUE B BASE 0 CELLITAZOL B 0 C.I. 24110 0 C.I. AZOIC DIAZO COMPONENT 48 0 CIBACETE DIAZO NAVY BLUE 2B 0 C.I. DISPERSE BLACK 6 0 DIACELLITON FAST GREY G 0 DIACEL NAVY DC 0 o-DIANISIDIN (CZECH, GERMAN) 0 o-DIANISIDINA (ITALIAN) 0 0,O'DIANISIDINE 0 3,3'-DIANISIDINE 0 DIATO BLUE BASE B 0 3,3'-DIMETHOXYBENZIDlN (CZECH) 0 3,3'DIMETHOXYBENZIDINE 0 3,3'-DIhlETOSSIBENZODINA (ITALIAN) 0 FAST BLUE B BASE 0 HILTONIL FAST BLUE B BASE 0 HILTOSAL FAST BLUE B SALT 0 HINDASOL BLUE B SALT 0 KAKO BLUE B SALT 0 KAYAKU BLUE B BASE 0 LAKE BLUE B BASE 0 MEISEI TERYL DIAZO BLUE HR 0 MITSUI BLUE B BASE 0 NAPHTHANIL BLUE B BASE 0 NEUTROSEL NAVY BN 0 RCRA WASTE NUMBER U091 0 SAiVYO FAST BLUE SALT B 0 SETACYL DIAZO NAVY R 0 SPECTROLENE BLUE B
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,198,87; Animal Sufficient Evidence IMEMDT 4,41,74. EPA Genetic Toxicology Program. Community Right-To-Know List. Reported in EPA TSCA Inventory. DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (0-Dianisidine-Based Dyes) Reduce to lowest feasible concentration SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. Moderately toxic by ingestion. Mutation data reported. Combustible when exposed to heat or flame. When heated to decomposition it emits toxic fumes of NO,.
436 DCJ400
DlANlSlDlNE DIISOCYANATE
DCJ400 CAS: 91-93-0 HR: 3 DlANlSlDlNE DIISOCYANATE mf: C I ~ H I Z N Z O ~ mw: 296.30 SYNS: 4,4'-DIISOCYANATO-3,3'-DIMETHOXY-1,1'BIPHENYL 0 3,3'-DIhIETHOXYBENZIDINE-4,4'DIISOCYANATE 0 3,3'-DIMETHOXY-4,4'-BIPHENYLENE DIISOCYANATE 0 NCI-C02175
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,56,87; Animal Limited Evidence IMEMDT 39,279,86. NCI Carcinogenesis Bioassay (feed); No Evidence: mouse NCITR* NCI-CG-TR128,79; Clear Evidence: rat NCITR* NCICG-TR-128,79. NIOSH REL: (Diisocyanates) TWA 0.005 ppm; CL 0.02 ppm/lOM SAFETY PROFILE: Poison by intravenous route. A strong sensitizer. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits toxic fumes of NO,. See also CYANATES.
DCJ800 CAS: 61790-53-2 HR: 1 DIATOMACEOUS EARTH PROP: Composed of skeletons of small aquatic plants related to algae and contains as much as 88% amorphous shca (DTLVS* 4,120,80). White to buff-colored solid. Insol in water; sol in hydrofluoric acid. SYNS: AMORPHOUS SILICA 0 CELITE 0 D.E. 0 DIATOMACEOUS EARTH, NATURAL 0 DIATOMACEOUS SILICA 0 DIATOMITE 0 INFUSORIAL EARTH 0 KIESELGUHR 0 SILICA, AMORPHOUS-DMTOhWCEOUS EARTH (UNCALCINED) (ACGIH)
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,341,87; Animal Inadequate Evidence IMEMDT 42,39,87; Human Inadequate Evidence IMEMDT 42,39,87. Reported in EPA TSCA Inventory. OSHA PEL: TWA 6 mg/m3 ACGIH TLV: TWA (nuisance particulate) 10 mg/m3 of total dust (when toxic impurities are not present, e.g., quartz <1%) DFG MAK: 4 mg/m3 as fine dust SAFETY PROFILE: A nuisance dust that may cause fibrosis of the lungs. Roasting or calcining at h g h temperatures produces
cristobalite and tridymite, thus increasing the fibrogenicity of the material. A questionable carcinogen. DCK700 CAS: 283-66-9 HR: 3 1,6-DIAZA-3,4,8,9,12,13HEXAOXABICYCLO(4.4.4)TETRADE CANE mf: C1jHizN206 mw: 208.17 PROP: Crystals. SYN : HEXAhZETHYLENETRIPEROXYDIAMINE DOT CLASSIFICATION: Forbidden SAFETY PROFILE: The dry material is a powerful explosive that is heat- and shocksensitive. Explodes on contact with bromine or sulfuric acid. When heated to decomposition it emits toxic fumes of NO,. See also PEROXIDES. DCK759 CAS: 439-14-5 HR: 3 DIAZEPAM mf: C16H13ClN20 mw: 284.76 PROP: Plates or crystals from MezCO/pet ether. Mp: 125-126". SYNS: ALBORAL 0 AMIPROL 0 ANSIOLISINA 0 APAURIN 0 APOZEPAM 0 ATENSINE 0 ATILEN 0 BIALZEPAhi 0 CALhiOCITENE 0 CERCINE 0 7 -
CHLORO-1,3-DIHYDRO-l-hIETHYL-5-PHENYL-2H-l,4BENZODUZEPIN-2-09E 0 7-CHLORO-l-SIETHYl-53H-1,4-BENZODMZEPIN-Z(1H)-ONE 0 7-CHLORO-lMETHYL-2-0x0-5-PHENYL-3H-1 ,CBENZODIAZEPINE 0
7-CHLORO-l-?\IETHYI-5-PHENYL-2H-l,4-BENZODI-
AZEPIN-2-ONE 0 7-CHLORO-l-METHYL-5-PHENYL-1,3DIHYDRO-2H-l,4-BENZODIAZEPIN-2-ONE 0 CONDITION 0 DIACEPAN 0 DWPAh4 0 DIAZETARD 0 DIENPAX 0 DIPAM 0 DOhMLIUhZ 0 DUKSEN 0 EPAM 0 ERIDAN 0 FAUSTAN 0 FRUSTAN 0 GIHITAN 0 IUATRIUM 0 LEMBROL 0 LEVIUM 0 LIBERETAS 0 METHYL DIAZEPINONE 0 l-METHYL-5-PHEiVYL-7-
CHLORO-1,3-DIHYDRO-2H-1,4-BEXZODWZEPIN-2O N E 0 MOROSAN 0 NSC-77518 0 PACITRAN 0 PAXATE 0 PLIDAN 0 QUETINIL 0 QUIATRIL 0 RELAIviINAL 0 RELANIUM 0 RENBORIN 0 SAROMET 0 SEDIPhM 0 SEDUXEN 0 SERENACK 0 SERENZIN 0 SETONIL 0 SONACON 0 STESOLID 0 TENSOPAM 0 TRANIMUL 0 TRANQUIRIT 0 UMBRICM 0 UNISEDIL 0 VALE0 0 VALITRAN 0 VALIUM 0 VATRAN 0 VIVAL 0 ZIPAN
CONSENSUS REPORTS: IARC Cancer Review: Group 3 IMEMDT 7,189,87; Animal Inadequate Evidence IMEMDT 7,189,87; Human Inadequate Evidence
DlAZlNON
IMEMDT 7,189,87. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by ingestion, parenteral, subcutaneous, intravenous, and intraperitoneal routes. Moderately toxic by s h n contact. Questionable carcinogen with experimental tumorigenic data. Human systemic effects: dermatitis, effect on inflammation or mediation of inflammation, change in cardiac rate, somnolence, respiratory depression, and other respiratory changes, visual field changes, diplopia (double vision), change in motor activity, muscle contraction or spasticity, ataxia (loss of muscle coordination), an antipsychotic and general anesthetic. Human reproductive effects by ingestion and intravenous routes causing developmental abnormalities of the fetal cardiovascular (circulatory) system and postnatal effects. Experimental teratogenic and reproductive effects. Human mutation data reported. An allergen. A drug for the treatment of anxiety. When heated to decomposition it emits very toxic fumes of C1- and NO,. DCL125 CAS: 2294-47-5 HR: 3 1,4-DIAZIDOBENZENE mf: C G H ~ N ~ mw: 160.16 PROP: Yellow crystals from Et2O. Mp: 83'. SYNS: BENZENE, 1,4-DIAZIDO- 0 p-DIAZIDOBENZENE (DOV 0 1,4-DMZIDOBENZENE 0 pPHENYLENE DIAZIDE
DOT CLASSIFICATION: Forbidden SAFETY PROFILE: Explodes violently
when heated. When heated to decomposition it emits toxic fumes of NO,. See also AZIDES. DCL6OO CAS: 629-13-0 HR: 3 1,2-DIAZIDOETHANE mf: C2H4N6 mw: 112.09 PROP: Bp: 54-55' @ 11 mm. SYN: ETHAiiE, 1,2-DIAZIDODOT CLASSIFICATION: Forbidden SAFETY PROFILE: Explodes on heating or on contact with sulfuric acid. Upon
DCM750 437
decomposition it emits toxic fumes of NO,. See also AZIDES. DCM750 CAS: 333-41-5 HR: 3 DlAZlNON mf: C12H21N203PS mw: 304.38 PROP: Lquid with faint ester-like odor. Bp: 84' @ 0.002 mm, d: 1.116 @ 20'/4'. Mscible in org solvs. SYNS: ALFA-TOX 0 BASUDIN 0 BASUDIN 10 G 0 BAZUDEN 0 DAZZEL 0 O,O-DIAETHYLO-(2-
ISOPROPYL-4-hlETHYL-PYRIMIDIN-6-YL)MONOTHIOPHOSPHAT (GERhWN) 0 0,O-DWETHYL-
0-(2-1SOPROPYL-4-hlETHYL)-6-PYRIMIDnTHIONOPHOSPHAT (GERMAN) 0 D W O N 0 DIATERR-FOS 0 DIAZAJET 0 DWZATOL 0 DIAZIDE 0 DWZIKONE 0 DIAZITOL 0 DIALOL 0 0, O DIETHYL-O-(2-ISOPROPYL-4-METHn-PYRIhlIDIN-6YL)MONOTHIOFOSFAAT(DUTCH) 0 0,O-DIETHYL-O-
(2-ISOPROPYL-4-METHYL-6-PYRIR.IIDINYL)PHOSPHOROTHIOATE 0 O,O-DIETHYL-O-(2-ISOPROPYT-6METHYL-4-PYRIMIDINYL)PHOSPHOROTHIOATE 0 DIETHYL 4-(2-ISOPROPYL-6-METHYLPYRIIMIDINYL)PHOSPHOROTHIONATE 0 O,O-DIETHYL-O-(2ISOPROPYL-4-METHYL-6-PYRI~lIDYL)PHOSPHOROTHIOATE 0 O,O-DIETHYL-O-(2-ISOPROPYL,-4METHYL-6-PYRIMIDYL)THIONOPHOSPHATE 0 0,ODIETHYL-2-ISOPROPYL-4-~lETHYLP~~iIDYL6THIOPHOSPHATE 0 O,O-DIETHYL-O-6-METHYL-2ISOPROPYL-4-PYRIMIDINYLPHOSPHOROTHIOATE 0 O,O-DIETIL-O-(~-ISOPROPIL-~-METIL-PI~I~IDIN-~-IL)hlONOTIOFOSFAT0 (ITALIAN) 0 DIMPYLATE 0 DIPOFENE 0 DIZINON 0 DYZOL 0 ENT 19,507 0 G 301 0 G-24480 0 GARDENTOX 0 GEIGY 24480 0 0-2ISOPROPYL-4-METHYLP~PYRIMIDYL-0,O-DIETHYL PHOSPHOROTHIOATE 0 ISOPROPYLMETHYLPYRIMIDYL DIETHYL THIOPHOSPHATE 0 KAYAZINON 0 KAYAZOL 0 NCI-C08673 0 NEDCIDOL NEOCIDOL 0 NIPSAN 0 NUCIDOL 0 SAROLEX 0 SPECTRACIDE 0 THIOPHOSPHATE de 0,O-DIETHYLE et de o-2-ISOPROPYL-4-METHYL-G-PYRIMIDnE (FRENCH)
CONSENSUS REPORTS: NCI
Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* NCI-CGTR-137,79. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. OSHA PEL: TWA 0.1 mg/m3 (shn) ACGIH TLV: TWA 0.01 mg/m3 (shn); Not Classifiable as a Human Carcinogen DFG MAK: 1 mg/m3 SAFETY PROFILE: Poison by ingestion, skin contact, subcutaneous, intravenous, and
438 DCNBOO DIAZOACETIC ESTER intraperitoneal routes. Mildly toxic by inhalation. Human systemic effects by ingestion: changes in motor activity, muscle weakness, and sweating. Experimental teratogenic and reproductive effects. A skin and severe ej7e irritant. Human mutation data reported. When heated to decomposition it emits very toxic fumes of NO,, PO,, and SO,. DCN800 CAS: 623-73-4 HR: 3 DIAZOACETIC ESTER mf: C4H6N202 mw: 114.12 PROP: Yellow oil with pungent odor. Mp: -22O, bp: 141" @? 720 mm. SYNS: DtME 0 DIAZOACETIC ACID, ETHYL ESTER 0 DUZOESSIGSAEURE-AETHYLESTER (GERMAN) 0 EDA 0 ETHOXYCARBOSYLDIAZOhIETHANE 0 ETHYL DNZOACETATE
SAFETY PROFILE: Poison by ingestion and intravenous routes. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Can explode. Explodes on contact with tris(dimethy1amino) antimony. When heated to decomposition it emits toxic fumes of NO,. See also ESTERS.
DC0800 CAS: 820-75-7 HR: 3 N-(DIAZOACETYL)GLYCINE HYDRAZlNE mf: C4H~N502 mw: 157.16 SYNS: N-DMZOACETILGLICINA-IDMZIDE (ITALIAN) 0 DIAZOACETYLGLYCINE HYDRAZIDE 0 S-DIAZOACETYL GLYCYLHYDRAZIDE 0 NSC-58404
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intravenous route. Moderately toxic by ingestion, intraperitoneal, and subcutaneous routes. Questionable carcinogen with experimental carcinogenic and neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes including NO,.
DCP800 CAS: 334-88-3 DIAZOMETHANE mf: CH2N2 mw: 42.05
HR: 3
PROP: Yellow gas at ordmary temp which forms yellow solns in ethereal solvs. Mp: -145", bp: -23O, d: 1.45. IDLH 2 ppm. SYNS: AZIhfETHYLENE 0 DIAZIRIXE CONSENSUS REPORTS: IARC Cancer
Review: Group 3 IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 7,223,74. EPA Genetic Toxicology Program. Community &ght-To-I(now List. OSHA PEL: TWA 0.2 ppm ACGIH TLV: TWA 0.2 ppm; Suspected Human Carcinogen DFG MAK: Animal Carcinogen, Suspected Human Carcinogen SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. A poisonous irritant by inhalation. A powerful allergen. It can cause pulmonary edema and frequently causes hypersensitivity leading to asthmatic symptoms. Mutation data reported. Highly explosive when shocked, exposed to heat, or by chemical reaction. Undiluted liquid or gas may explode on contact with alkali metals, rough surfaces, heat (lOO°C), hgh-intensity light, or shock. When heated to decomposition or on contact with acid or acid fumes it emits highly toxic fumes of NO,. Incompatible with alkali metals; calcium sulfate. DCQ6OO CAS: 2435-76-9 HR: 3 DIAZOU RACI L mf: C4H2N402 mw: 138.10 PROP: Crystals from H2O. Mp: 198" (decomp). SYNS: 5-DIrizOPYRIMIDINE-2,4(3H)-DIONE 0
5-
DIAZO-2,4(1H,3H)-PYRISfIDINEDIONE 0 5DIAZOURACIL 0 2,4-DIOSSI-5-DIAZOPIRInlIDI" (ITALIAN) 0 2,6-DIOXO-5-DIAZOPYRIRI51IDISE0 DU 0 NSC-23519 0 (1,2,3)OXADIAZOL0(5,4-d)PYRIMIDIN5(4H)-ONE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by
subcutaneous and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,.
DIBENZ(a,h)ACRIDINE 3,4-DIOL- 1,P-EPOXIDE
DCQ800 CAS: 34493-98-6 HR: 3 DlBEKAClN mf: Ci8H37N508 mw: 451.60 PROP: A solid. SYNS: DEBECACIN 0 DIDEOXYKANAMYCIN B 0 3',4'-DIDEOXYKANAMYCIN B 0 DKB 0 ORBICIN
CONSENSUS REPORTS: EPA Genetic Toxicology Program. SAFETY PROFILE: Poison by intraperitoneal, subcutaneous, intramuscular, and intravenous routes. Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. An antibacterial agent. When heated to decomposition it emits toxic fumes of NO,.
DCR400 CAS: 203-20-3 HR: 3 DIBENZ(a,j)ACEANTHRYLENE mf: C24H14 mw: 302.38 PROP: Bright-yellow needles from C6H6. Mp: 181-181.3'. SYN: 15,16-BEKZDEHYDROCHOLAiYTHRENE SAFETY PROFILE: Poison by intravenous route. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. DCSPOO CAS: 1977-10-2 HR: 3 DIBENZACEPIN mf: C18H18ClN30 mw: 327.84 PROP: Pale-yellow cryst from pet ether. Mp: 109-110'. SYNS: 2-CHLORO-ll-(4-METHYL-l-PIPERAZINYL)DIBENZO(b,t)(l,4)OXAZEPINE 0 2-CHLORO-11-(4hfETHYL1-PIPERAZINYL-DIBENZO@,f)(l,4)0XOAZEPINE 0 CL-62362 0 CL-71563 0 CLOXAZEPINE 0 DIBENZOAZEPINE 0 HF3170 0 LOXAPINE 0 LW 3170 0 OXILAPINE 0 S-805 0 SUM 3170
SAFETY PROFILE: Poison by ingestion, intraperitoneal, subcutaneous, and intravenous routes. Experimental teratogenic and reproductive effects. A tranquilizer. Many dbenz-azepine compounds have central nervous system effects. When heated to decomposition it emits very toxic fumes of C1- and NO,.
DCS821 439
DIBENZ(a,h)ACRIDINE mfi C ~ I H I ~ N mw: 279.35 PROP: Yellow crystals. Mp: 228'. SYNS: 7-AZADIBENZ(a,h)ANTHRACENE 0 DB(a,h)AC DIBENZ(a,d)ACRIDINE 0 1,2,5,6-DIBENWCRIDINE 1,2,5,G-DIBENZOACRIDINE 0 1,2,5,6DINAPHTHACRIDINE 0 0
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 32,277,83; IMEMDT 3,247,73. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also ANTHRACENE.
DCS6OO CAS: 224-42-0 HR: 3 DIBENZ(a,j)ACRIDINE mf: C21H13N mw: 279.35 PROP: Yellow crystals. Mp: 216-217'. SYNS: 7-AWDIBENZ(a,j)A"HMCENE 0 DB(a,j)AC 0 DIBENZ(a,f)ACRIDINE 0 1,2,7,8-DIBENZACRIDINE 0 3,4,5,6-DIBENZACRIDINE 0 DIBENZO(a,j)ACRIDINE 0
3,4,6,7-DINAPHTHACRIDINE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 32,283,83; IMEMDT 3,254,73. EPA Genetic Toxicology Program. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also ANTHRACENE.
DCS821 CAS: 125276-72-4 HR: 2 DIBENZ(a,h)ACRIDINE3,4-DIOL-1,2EPOXIDE mf: C21H15N03 mw: 329.37 SYNS: BENZ@)OXIREN0(5,6)BENZ(1,2-A)ACRIDINE2,3-DIOL, lA,2,3,13C-TETMHYDRO-, (lA-a,2-P,3-a,13C-
DCS400
CAS: 226-36-8
HR: 3
a)-(+-)-0 (+/-)-3a,4P-DIHYDROXY-la,2a-EPOXY-1,2,3,4TETRAHYDRODIBEN-Z(a,h)ACRTDINE
440 DCTOSO DIBENZAMINE SAFETY PROFILE: Questionable
carcinogen with experimental carcinogenic data reported. Mutation data reported. When heated to decomposition it emits toxic vapors of NO,. DCT050 CAS: 51-50-3 DIBENZAMINE mf: C16H18ClN mw: 259.80
HR: 3
SYNS: N-(2-CHLOROETHYL)DIBENZYLAMINE 0 DIBEKZYL CHLORETHYLAMISE 0 N,N-DIBENZYL-PCHLOROETHYLXMINE 0 SYMPATHOLYTIN
SAFETY PROFILE: Poison by intravenous
and intraperitoneal routes. Moderately toxic by ingestion and subcutaneous routes. Experimental reproductive effects. Can cause leukopenia (reduced whte blood cell count). Mutation data reported. When heated to decomposition it emits very toxic fumes of C1- and NO,. See also AROMATIC M I N E S . DCT400 CAS: 53-70-3 HR: 3 DIBENZ(a,h)ANTHRACENE mf: C22H14 mw: 278.36 PROP: Silvery leaflets from AcOH. Mp: 266-26'7'. SYNS:
1,2:5,6-BENZANTHRACENE 0 DBA 0 DB(a,h)A 0 1,2,5,6-DBA 0 1,2,5,6-DIBENZANTHRACEEN (DUTCH) 0 1,2:5,6-DIBENZANTHRACENE 0 1,2:5,6-DIBENZ(a)ANTHRACENE 0 DIBEXZO(a,h)ANTHRACENE 0 1,2:5,6-DIBENZOANTHRCENE 0 RCRA WASTE NUMBER U063
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 2A IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 32,299,83; IMEMDT 3,178,73. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, tumorigenic, and neoplastigenic data. Poison by intravenous route. Human mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. DCYOOO CAS: 194-59-2 HR: 3 7H-DIBENZO(c,g)CARBAZOLE
mf: CZOHI~N mw: 267.34 PROP: Needles or crystals from alc. Mp: 158'. SYNS: 7-AZA-7H-DIBEKZO(c,g)FLUORENE 0 7HDB(c,g)C 0 3,4,5,6-DIBENZCARBAZOL 0 3,4,5,6DIBENZCARBAZOLE 0 3,4,5,6-DIBENZOCARBAZOLE 0
3,4,5,6-DINAPHTHACARBAZOLE
CONSENSUS REPORTS: NTP 10th Report
on Carcinogens. IARC Cancer Review: Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 32,315,83; IMEMDT 3,260,73. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of NO,. DCY2OO CAS: 189-64-0 HR: 3 DIBENZO(b,def)CHRYSENE mf: C24H14 mw: 302.38 PROP: Golden-orange plates from trichlorobenzene. Mp: 315'. SYNS: BD(a,h)P 0 DIBENZO(a,h)PYRENE 0 1,2,6,7DIBENZOPYRENE 0 3,4,8,9-DIBENZOPYRENE 0 3,4,8,9-DIBENZPYRENE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 32,331$3; IMEMDT 3,207,73. SAFETY PROFILE: Confirmed carcinogen with experimental carcinogenic and tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. Mutation data reported. DCY400 CAS: 191-30-0 DIBENZO(def,p)CHRYSENE mf: C24H14 mw: 302.38 PROP: Pale-yellow plates from CGHh/EtOH. Mp: 164-165'
HR: 3
SYNS: BA 51-090462 0 DB(a,l)P 0 DIBENZO(a,d)PYRENE 0 DIBENZO(a,l)PYRENE 0 1,2:3,4DIBEXZOPYRENE 0 1,2,9,10-DIBENZOPYRENE 0 2,3:4,5-DIBENZOPYRENE 0 1,2,3,4-DIBENZPYRENE 0 4,5,6,7-DIBENZPYRENE
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
DIBENZYLINE HYDROCHLORIDE
Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 32,343,83; Animal Limited Evidence IMEMDT 3,224,73. SAFETY PROFILE: Confirmed carcinogen with experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. DDC810 CAS: 153857-27-3 HR: 2 (+-)-DlBENZO(a,l)PYRENE-l1,12-DIHYDRODIOL mf: C24H1602 mw: 336.39 SYN: DIBENZO(def,p)CHRYSENE-11,12-DIOL, 11,12DIHYDRO-, (1lS,12S)-REL-
SAFETY PROF1LE: Questionable
carcinogen with experimental carcinogenic data reported. When heated to decomposition it emits acrid smoke and irritating vapors. DDE2OO CAS: 257-07-8 HR: 3 DIBENZ(b,f)(l,4)0XAZEPINE mf: C13H9NO mw: 195.23 S Y N S : CR EA 3547 CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion and inhalation. Experimental teratogenic and reproductive effects. A human skin and eye irritant. Questionable carcinogen with experimental carcinogenic and tumorigenic data. When heated to decomposition it emits toxic fumes of NO,. DDE300 CAS: 2743-38-6 HR: 1 DIBENZOYLTARTARIC ACID mfi C18H1408 mw: 358.32 PROP: Crystals. Mp: 89-92’. S Y N S : BUTANEDIOIC ACID, 2,3-BIS(BENZOYLOXY)-, (R-(R*,R*))-0 TARTARIC ACID, DIBENZOATE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: An eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
DDG800 441
DDGGOO CAS: 73926-81-5 HR: 3 DIBENZYLETHYLSULFONIUM IODIDE MERCURIC IODIDE PROP: IDLH 10 mg/m3 (as Hg). S Y N : DIBENZYLETHYLSULFONIUM IODIDE wlth MERCURY IODIDE (1:l)
CONSENSUS REPORTS: Mercury and its compounds are on the Community RightTo-Know List. ACGIH TLV: Proposed: (inhalable fraction) 0.1 mg/m3; Not Classifiable as a Human Carcinogen) DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: TWA 0.05 mg(Hg)/m3 SAFETY PROFILE: Poison by intravenous route. See also IODIDES and MERCURY IODIDE. When heated to decomposition it emits very toxic fumes of Hg, I- and SO,.
DDG800 CAS: 63-92-3 HR: 3 DIBENZYLINE HYDROCHLORIDE mf: ClsH22ClNOmClH mw: 340.32 PROP: Crystals from EtOH/EtaO. Mp: 137.5-140’. S Y N S : 688A 0 BENSYLYI 0 2-(N-BENZYL-2CHLOROETHYLAMIN0)-1-PHENOXYPROPANE HYDROCHLORIDE 0 BENZYL(2-CHLOROETHYL)(lMETHYL-2-PHEN0XYETHYL)AMINE HYDROCHLORIDE 0 N-BENZYLN-PHENOXYlSOPROPYI-~CHLORETHYLAiiINE HYDROCHLORIDE 0 BENZYLYT 0 BLOCADREN 0 N-(2-CHLOROETHYL-N(1-METHYLr2-PHENOXYETHYL)BENZENEMETHANAMINEHYDROCHLORIDE 0 N-(ZCHLOROETHYL)-N-(1-METHYL-2-PHEN0XYETHYL)BENZYLAMINE HYDROCHLORIDE 0 DIBENZYLENE 0 DIBENZYLIN 0 DIBENZYRAN 0 FENOXYBENZAMIN 0 NCI-CO1661 0 PHENOXYBENZAMIDE HYDROCHLORIDE 0 N-PHENOXYISOPROPYL-NBENZYL-p-CHLOROETHYINE HYDROCHLORIDE 0 P.*’-2-PHE~OXYlSOPROPYL-hT-BENZYLCHLOROETHYLAMINE HYDROCHLORIDE 0 SKF 688A
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 2B IMEMDT 7,56,87; Animal Sufficient Evidence IMEMDT 24,185,80. NCI Carcinogenesis Bioassay Completed; Results Positive: mouse, rat NCITR* NCICG-TR-72,78. SAFETY PROFILE: Confumed carcinogen with experimental carcinogenic and teratogenic data. Poison by intraperitoneal,
442
DDHOOO
DIBENZYLMERCURY
intravenous, and subcutaneous routes. Human systemic effects by ingestion: changes in tubules, including acute renal failure, acute tubular necrosis. Moderately toxic by ingestion. Other experimental reproductive effects. Mutation data reported. A long-acting adrenergic blocker. When heated to decomposition it emits very toxic fumes of NO, and C1-. DDHOOO CAS: 780-24-5 HR: 3 DIBENZYLMERCURY mf: C14H14Hg mw: 382.87 PROP: Colorless crystals or needles from alc. Mp: 111'. Insol in Et20, pet ether; sltly sol in EtOH and C6H6; sol in org s o h . IDLH 10 mg/m3 (as Hg). OSHA PEL: TWA 0.01 mg(Hg)/m3; STEL 0.03 mg/m3 (sku?) ACGIH TLV: TWA 0.01 mg(Hg)/m3; BEI: 35 pg/g creatinine total inorganic mercury in urine preshift; 15 pg/g creatinine total inorganic mercury in blood at end of shft at end of workweek. DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skin) SAFETY PROFILE: Poison by intravenous route. See also MERCURY COMPOUNDS, ORGANIC. When heated to decomposition it emits toxic fumes of Hg. DD1450 CAS: 19287-45-7 HR: 3 DIBORANE DOT: UN 1911/NA 1911 mf: B2Hb mw: 27.68 PROP: Colorless air- and moisture-sensitive gas; sickly-sweet odor. Mp: -165.5', bp: -92.5', d: 0.447 @quid @ -112'), 0.577 (solid @ -183'), vap press: 224 mm @ -112', autoign temp: 38-52", lel: 0.9%, uel: 98%, flash p: -90'F. Sol in THF as BH3THF complex. IDLH 15 ppm. SYNS: BOROETHANE 0 BORON HYDRIDE 0 DIBORAXE MIXTCRES (NA 1911) 0 DIBORON HEXAHYDRIDE
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances Lst. OSHA PEL: TWA 0.1 pprn ACGIH TLV: TWA 0.1 pprn DFG MAK: 0.1 ppm (0.1 mg/m3) DOT CLASSIFICATION: 2.1; Label: Flammable Gas (NA 1911); DOT Class: 2.3; Label: Poison Gas, Flammable Gas SAFETY PROFILE: Poison by inhalation. An irritant to skin, eyes, and mucous membranes comparable to chlorine, fluorine, arsine, and phosgene. The liquid causes local inflammation, blisters, redness, and swelling. Injuries to central nervous system, liver, and hdneys have also been produced in experimental animals. Sirmlar observations have been reported in humans, resulting at times in a reaction resembling metal fume fever. Human exposure to pentaborane has produced signs of severe central nervous system irritation such as drowsiness, dlzziness, visual disturbances, muscle twitching, and in severe cases, painful muscle spasm. Dangerously flammable when exposed to heat or flame or by chemical reaction. O n contact with moisture, hydrogen is usually evolved. Highly explosive when exposed to heat or flame. Explosive reaction with air, tetravinyllead, 0 2 above 165'C, octanol oxime + sodium hydroxide, benzene vapor, HN03C12. Violent reaction with halocarbon liquids. Other boron hydrides evolve H2 upon contact with moisture or can propagate a flame rapidly enough to cause an explosion. Heat can cause these materials to decompose violently or at least to evolve H2. They also react with water or steam to evolve hydrogen. Reaction with A1 or Li forms complex hydrides that may ignite spontaneously in air. Powerful oxidlzing agents, such as chlorine gas, etc., can react violently with boron hydrides. Pentaborane (stable) is spontaneously flammable in air. See also BORANES and HYDRIDES.
1,2-DIBROMO-3-CHLOROPROPANE DDLBOO 443
DDJOOO CAS: 10318-26-0 HR: 3 DIBROMODULCITOL mf: C6H12Br204 mw: 308.00 PROP: A solid. hip: 187-188'. SYNS: DBD 0 1,6-DIBRONODIDEOXYDULCITOL0 1,6-DIBROhiO-1,6-DIDEOXYDULCITOL 0 1,6DIBROMO-l,6-DIDEOXYGAL4CTITOL 0 1,6DIBROMO-l,6-DIDEOXY-d-GAUCTITOL 0 DIBROMODULCITOL 0 1,6-DIBROMODULCITOL0 ELOBROMOL 0 GAUCTICOL 0 MITOLAC 0 MITOLACTOL 0 NCI-C04795 0 NSC-104800
CONSENSUS REPORTS: NCI
Carcinogenesis Bioassay Completed; Results Positive: mouse, rat (RRCRBU 52,1,75). SAFETY PROFILE: Poison by ingestion. Moderately toxic by intraperitoneal route. Questionable carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Human mutation data reported. An anti-cancer agent taken orally. When heated to decomposition it emits very toxic fumes of Br-. DDJ400 CAS: 3252-43-5 HR: 3 DIBROMOACETONITRILE mf: C2HBrzN mw: 198.86 PROP: Water disinfection agent. CONSENSUS REPORTS: Cyanide and its compounds are on the Community fightTo-Know Lst. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intravenous route. Questionable carcinogen with experimental carcinogenic data. Experimental reproductive effects. Human mutation data reported. See also NITRILES and BROMIDES. When heated to decomposition it emits very toxic fumes of NO,, Br-, and CN-. DDJ8OO CAS: 624-61-3 HR: 3 DIBROMOACETYLENE mf: C2Br2 mw: 183.83 PROP: Heavy liquid with unpleasant odor. Mp: -25', bp: explodes, d: 2 (approx), vap d: 6.35. DOT CLASSIFICATION: Forbidden SAFETY PROFILE: Igmtes spontaneously in air. Explodes when heated. When heated
to decomposition it emits toxic fumes of Br-. See also ACETYLENE COMPOUNDS. DDJ9OO CAS: 26249-12-7 HR: 3 DIBROMOBENZENE DOT: UN 271 1 mf: c6H4B1-2 mw: 235.92 SYNS: BENZENE, DIBROMODOT CLASSIFICATION: 3; Label: Flammable Liquid CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Moderately toxic by intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic vapors of Br-. DDKGOO CAS: 6305-43-7 HR: 3 2,2'-DIBROMOBIACETYL mf: C4H4B1-202 mw: 243.90 PROP: Crystals from CHCL. Mp: 116-117'. SYN E,~'-DIBROMOBIACETYL CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by intravenous and intraperitoneal routes. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES. DDL800 CAS: 96-12-8 HR: 3 1,2-DIBROMO-3-CHLOROPROPANE DOT: UN 2872 mf: C3HjBr2C1 mw: 236.35 PROP: Bp: 196', flash p: 170'F (TOC). SYNS: BBC 12 0 l-CHLORO-2,3-DIBROMOPROPANE 0 3-CHLORO-1,2-DIBROhlOPROPANE 0 DBCP 0 DIBROMCHLORPROPAK (GERMAN) 0 1,2-DIBROM-3CHLOR-PROPrtU (GERMAN) 0 DIBROMOCHLOROPRO(ITALIAN) PANE 0 1,2-DIBROMO-3-CLORO-PROPANO 0 1,2-DIBROOW3-CHLOORPROPAAN (DUTCH) 0 FUMAGON 0 FUMAZONE 0 NCI-COO500 0 NEIMABROM 0 NEMAFUME 0 KELMAGON0 NEMAGONE 0 NEMAGON SOIL FUMIGANT 0 NELMANAX0 N E W PA2 0 NEhLASET 0 NEMhTOCIDE 0 NEMATOX 0 NELMAZON0 0s 1897 0 OXY DBCP 0 RCRA WASTE NUMBER U066 0 SD 1897
CONSENSUS REPORTS: NTP 10th Report on Carcinogens. IARC Cancer Review:
Group 2B IMEMDT 7,191,87; Animal
444
DDMOOO
~~-DIBROMO-~-CYANOACETAMlDE
Sufficient Evidence IMEMDT 15,139,??; Human Limited Evidence IMEMDT 20,83,79; Animal Sufficient Evidence IMEMDT 20,83,?9. NCI Carcinogenesis Bioassay Completed; Results Positive: mouse, rat NCITR* NCI-CG-TR-28,78. EPA Genetic Toxicology Program. Community fight-To-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.001 ppm; Cancer Hazard DFG MAK: Animal Carcinogen, Suspected Human Carcinogen NIOSH REL: (Dibromochloropropane) CL 0.01 ppm/30M DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Confirmed human carcinogen with experimental carcinogenic and teratogenic data. Poison by ingestion, inhalation, and subcutaneous routes. Moderately toxic by skin contact. An eye and severe skin irritant. Narcotic in high concentrations. Has been implicated in causing human sterihty in male factory workers. Human mutation data reported. A soil fumigant. Combustible. When heated to decomposition it emits toxic fumes of C1and Br-. See also CHLORIDES and BROLVIDES. DDMOOO CAS: 10222-01-2 HR: 3 a,a-DIBROMO-a-CYANOACETAMIDE mf: C3H2Br2NzO mw: 241.89 SYNS: DBSPA 0 DIBROMOCYANOACETAMIDE 0 2,2-DIBROMO-3-NITRILOPROPIONA~fIDE
CONSENSUS REPORTS: Cyanide and its compounds are on the Community RightTo-IOlow List. EPA FIFRA 1988 pesticide subject to regstration or re-regstration. Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intravenous routes. A severe skin and eye irritant. When heated to decomposition it emits very toxic fumes of Br- and NO,. See also NITRILES.
DDM400 CAS: 996-08-7 HR: 3 DIBROMODlBUTY LSTANNANE mf: CsHlsBrzSn mw: 392.77 PROP: Mp: 20'. SYNS: DIBROMODIBGTYLTIK 0 DIBUTYL TIN DIBROMIDE
OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion. Moderately toxic by sliln contact. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of Br-. DDM500 CAS: 35691-65-7 HR: D 1,2-DIBROMO-2,4-DICYANOBUTANE mf: C6HbBr2N2 mw: 265.96 SYNS: 2-BROhfO-2(BROM0METHYL)GLUTARONITRILE 0 GLUTARO0 METHYL NITRILE, 2-BROhiO-2-(BROhfOMETHYT-)DIBROMOGLUTARONITRILE n PENTAXEDINITRILE, 2-BROMO-2-(BROMOMETHYL)-
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFI LE: Experimental reproductive effects. When heated to decomposition it emits toxic fumes of NO, and Br-.
DDM820 CAS: 2361 1-68-9 HR: 3 6,8-DIBROMO-DIHYDRO-l,3-BENZOXAZI NE-2-THIONE-4-ONE mf: CsH3Br2N02S mw: 337.00 SYNS: 2H-1,3-BENZOXAZINE-2,4(3H)-DIONE, 6,8DIBROMO-2-THIO- 0 6,8-DIBROMO-2-THIO-2H-l,3BENZOXAZINE-2,4(3H)-DIONE
SAFETY PROFILE: A poison by ingestion. When heated to decomposition it emits toxic vapors of NO,, SO,, and Br-.
DD0200 CAS: 596-03-2 HR: D DIBROMOFLUORESCEIN mf: C2oH10Br205 mw: 490.12 PROP: Cosmetic colorant. SYNS: ACID ORANGE 11 0 C.I. 45370:l 0 C.I. SOLVENT RED 72 0 D&C ORANGE NO. 5 0 4',5'DIBROhfOFLUORORESCEI?N 0 FLUORESCEIN, 4',5'DIBROhfO- SOLVENT RED 72 0 SPIRO(ISOBESZ0-
n-DIBUTYLAMINE DDT800 445 FURAb-1(3H),9'-(9H)XI\IYTHEN)-3-ONE, 4',5'-DIBROMO3',6'-DIHYDROXI- (9CI)
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Br-.
DDPOOO CAS: 1689-84-5 HR: 3 3,5-DIBROMO-4-HYDROXYBENZONITRILE mf: C7H3Br2NO mw: 276.93 PROP: Needles. Mp: 187'. SYNS: BRITTOX 0 BROMIXAL 0 BROMINEX 0 BROMINIL 0 BROMOXYAIL 0 BROXYTIL 0 BUCTRIL 0 BUCTRIL INDUSTRIAL 0 BUTILCHLOROFOS 0 CHIPCO BUCTRIL 0 CHIPCO CRAB-KLEEN 0 2,6DIBROMO-4-CYANOPHENOL 0 3,5-DIBROhfO-4HYDROXYPHENYLCYAYIDE 0 E S T 20,852 0 4HYDROXY-3,5-DIBROh~OBE"ITRILE 0 LMB10064 0 iME4 BROMIXAL 0 XLLAW5S WEEDER 0 OXYTRIL 51
CONSENSUS REPORTS: Cyanide and its
compounds are on the Community kghtTo-Ihow List. SAFETY PROFILE: Poison by ingestion and intravenous routes. An herbicide. When heated to decomposition it emits highly toxic fumes of NO,, CN-, and Br-. See also NITRILES. DDP2OO CAS: 3562-84-3 HR: 3 3,5-DIBROMO-4-HYDROXYPHENYL-2ETHYL-3-BENZOFURANYL KETONE mfi C~H12Br203 mw: 424.11 PROP: Yellow prisms. Mp: 151'. SYNS: BENZBROhLARON 0 BEXZBROMARONE 0
the excretion of uric acid in the urine. A flammable liquid. When heated to decomposition it emits toxic fumes of Br-. See also KETONES. DDP800 CAS: 74-95-3 HR: 3 DIBROMOMETHANE DOT: UN 2664 mf: CH2Br2 mw: 173.85 PROP: Colorless, heavy liquid. Fp: -52.7', bp: 95.6-97.4', d: 2.485 @ 25'/25', vap d: 6.05. Sltly sol in water. SYNS: METHYLENE BROMIDE 0 METHYLENE DIBROMIDE 0 RCRA WASTE NCMBER U068
CONSENSUS REPORTS : Community kght-To-Know List. Reported in EPA TSCA Inventory. DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: A poison. Moderately toxic by subcutaneous route. M d l y toxic by inhalation. Mutation data reported. mxtures with potassium explode on light impact. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.
DDR200 CAS: 696-24-2 HR: 3 DIBROMOPHENYLARSINE mf: C6HsAsBr2 mw: 311.85 PROP: Bp: 285" (decomp), d: 2.103. SYNS: PHENYLARSONOUS DIBROMIDE 0 PHENYLDIBROMOARSINE
CONSENSUS REPORTS: Arsenic and its
compounds are on the Community kghtTo-Know List. OSHA PEL: TWA 0.5 mg(As)/m3 DESURIC 0 3-(3,5-DIBROhfO-4-HYDROXYBENZOn)-2SAFETY PROFILE: Poison by skin contact ETHYLBENZOFURAN 0 (3,5-DIBROMO-4-HYDROXYPHENYL)(2-ETHYL3-BENzOFURANn)METHAhTONE and intravenous routes. See also ARSENIC COMPOUNDS. When heated to 0 EXURATE 0 22214 0 MIXURIC 0 MJ 10061 0 URICOVAC decomposition it emits very toxic fumes of CONSENSUS REPORTS: Reported in EPA As and Br-. TSCA Inventory. DOT CLASSIFICATION: 3; Label: DDT800 CAS: 111-92-2 HR: 3 Flammable Liquid n-DIBUTYLAMlNE SAFETY PROFILE: Poison by ingestion, DOT: UN 2248 intravenous, and intraperitoneal routes. mf: C8H19N mw: 129.28 Moderately toxic by subcutaneous route. PROP: A liquid. Mp: -61.9'; bp: 159", flash Experimental teratogenic and reproductive p: 125'F (OC), d: 0.76, vap d: 4.46, vap effects. A uricosuric agent which promotes
446
DDUGOO 2-N-DIBUTYLAMINOETHANOL
press: 2 mm (@ 20'. Sol in water and alcohol. SYNS: n-BUTYL-1-BUTANAMINE 0 DI-nBUTYLhMINE 0 DI(n-BUT3'L)AMINE (DO? CONSENSUS REPORTS: Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. DOT CLASSIFICATION: 8; Label: Corrosive, Flammable Liquid SAFETY PROFILE: Poison by ingestion and subcutaneous routes. Moderately toxic by shn contact and inhalation. Corrosive. A severe s h n and eye irritant. Mutation data reported. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use alcohol foam, foam, COz, dry chemical. Exothermic reaction with cellulose nitrate does not proceed to ignition. When heated to decomposition it emits toxic fumes of NO,.
DDUGOO CAS: 102-81-8 HR: 3 2-N-DIBUTYLAMINOETHANOL DOT: UN 2873 mf: CloHz3NO mw: 173.34 PROP: Liquid. Bp: 222', flash p: 220'F (OC), d: 0.85, vap d: 6.0. SYNS: BU2AE 0 DIBUTYLAMINOETHANOL 0 2-
DDV225 CAS: 7128-68-9 HR: 3 DI-n-BUTYLAMMONIUM HEXAFLUOROARSENATE mf: CsH19NDAsF6H mw: 319.21 SYN : DIBUTYLKVINE, HEXAFLLiOROARSEKATE(1.) OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intravenous route. When heated to decomposition it emits toxic fumes of NO,, As, and F-. DDV250 CAS: 2850-61-5 HR: 3 DlBUTYLARSlNlC ACID mf: C8H19As02 mw: 222.19 PROP: Prisms from HzO or crystals from MezCO. Mp: 138'. Sol in EtOH; sltly sol in HzO. SYNS: ARSINE OXIDE, DIBUTYLHYDROXY- 0 ARSINIC ACID, DIBUTYI-(9CI)
OSHA PEL: TWA 0.5 mg(As)/m3 SAFETY PROFILE: Poison by intravenous
route. When heated to decomposition it emits toxic fumes of As.
DDVGOO CAS: 77-58-7 HR: 3 DlBUTYLBIS(LAUR0YL0XY)STANNANE mf: C3zH6404Sn mW: 631.65 PROP: Pale-yellow liquid to colorless solid (when pure). Mp: 23', bp: non-distillable @ DIBUTYIAW?U'OETHANOL 0 2-DI-n-BUTYIAMINOETHANOL 0 N,N-DI-n-BUTYLAhfINOETHANOL 10 mm, flash p: 455'F (OC), d: 1.066 (@ 2Oo/2O0, vap d: 21 23. (DOr) 0 P-N-DIBUTYLAMINOETHYLALCOHOL 0 SYNS: BIS(DODECANOYL0XI)DI-n-BGTYLN,r*j-DIBUTYLETHANOLAhfINE 0 N,N-DIBUTYLN-(2HYDR0XYETHYL)AiifINE
STANNANE 0 BIS(LAUROYL0XY)DIBUTYLSTAN"E
CONSENSUS REPORTS: Reported in EPA
0 BIS&AUROYLOXY)DI(n-BUTYL)STA"ANE 0
TSCA Inventory. OSHA PEL: TWA 2 ppm ACGIH TLV: TWA 0.5 ppm (shn) DOT CLASSIFICATION: 6.1; Label: KEEP AWAY FROM FOOD SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion and s h n contact. A severe eye and s h n irritant. Combustible; can react with oxidizing materials. To fight fire, use COZ, dry chemical. When heated to decomposition it emits toxic fumes of NO,. See also AMINES and ALCOHOLS.
BUTYNORATE 0 DBTL 0 DIBUTYLBIS(LAUROYL0W T I N 0 DI-n-BUTYLTIN DIpODECANOATE) 0 DIBUTYLTIN DILAURATE (USDA) 0 DIBUTYLTIN (GERMAN) 0 LAURATE 0 DIBUTYL-21"-DILAURAT FOMREZ SUL-4 0 LAUDRrtU DI-n-BUTYLCINICITY (CZECH) 0 LAURIC ACID, DIBUTYLSTANNYLENE derivaave 0 LAURIC ACID, DIBUTYLSTANNYLENE SALT 0 STABILIZER D-22 0 THERM CHEK 820 0 TIN DIBUTYL DILAURATE 0 TINOSTAT
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3
DIBUTYLDICHLOROSTANNANE SAFETY PROFILE: Poison by ingestion and
intraperitoneal routes. A skin and eye irritant. Avoid the vapor produced by heating. Combustible when exposed to heat or flame; reacts with oxidizers. When heated to decomposition it emits acrid smoke and fumes. See also TIN COMPOUNDS.
DDV800 CAS: 78-46-6 HR: 3 DIBUTYL BUTANEPHOSPHONATE mf: C12H2703P mw: 250.36 PROP: Colorless liquid with d d pleasant odor. Bp: 160-162' @ 20 mm, flash p: 311" (COC), d: 8.62. SYNS: DIBUTIZ BCTIZPHOSPHO~ATE0 NSC-2666 CONSENSUS REPORTS: Reported in EPA
DDY200 447
decomposition it emits acrid smoke and irritating fumes.
DDYOOO CAS: 4593-81-1 HR: 3 DIBUTYLDlCHLOROGER MANE mf: CsH18C12Ge mw: 257.75 SYNS: DI-n-BUTYLGERMANEDICHLORIDE0 DICHLORODIBUTYLGEIE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. SAFETY PROFILE: Poison by ingestion and intraperitoneal routes. Mutation data reported. See also GERMANIUM COMPOUNDS. When heated to decomposition it emits very toxic fumes of
c1-.
TSCA Inventory. SAFETY PROFILE: Poison by
intraperitoneal and intravenous routes. Combustible when exposed to heat or flame. It can react vigorously with oxidizing materials. To fight fire, use foam, CO2, or dry chemical. When heated to decomposition it emits toxic fumes of PO,.
DDW2OO CAS: 112-73-2 HR: 2 DIBUTYL CARBITOL mf: C12H2603 mw: 218.38 PROP: Practically colorless liquid, characteristic odor, sltl~7sol in water. D: 0.8853 @ 2Oo/2O0, bp: 256", fp: -60.2", flash p: 245°F (OC). SYNS: BIS(BUT0XETHYL) ETHER 0 BIS(2BUTOXYETHYL) ETHER 0 B U T n DIGLYME 0 2,2'DIBUTOXYETHYL ETHER 0 DIETHYLENEGLYCOL DIBUTYL ETHER 0 DIETHYLENEGLYCOLDI-n-BUTYL. ETHER 0 l,l'-(OXYBIS(2,l-ETHXWEDIYLOXY))BISBUTANE 0 5,8,11-TRIOXAPENTADECAWE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. Glycol ether compounds are on the Community Right-To-Know List. SAFETY PROFILE: Moderately toxic by ingestion. Mddly toxic by skin contact. Experimental reproductive effects. A s h n and eye irritant. See also GLYCOL ETHERS. Combustible when exposed to heat or flame. To fight fire, use foam or alcohol foam. When heated to
DDY2OO CAS: 683-18-1 HR: 3 DIBUTYLDICHLOROSTANNANE mf: CsHisC&l mW: 303.85 PROP: White, crystalline solid. Mp: 43', bp: 135' @ 10 mm, flash p: 335°F (OC), d: 1.36 @ 50', vap press: 2 mm @ loo", vap d: 10.5. SYNS: CHLORID DI-n-BUTYLCINICITY (CZECH) 0 D.B.T.C. 0 DIBUTYLDICHLOROTIN 0 DIBUTYLTIN CHLORIDE 0 DIBUTYLTIN DICHLORIDE 0 DI-nBUTYLTIN DICHLORIDE 0 DI-n-BUTYLZINNDICHLORID (GERMAN) 0 DICHLORODIBUTYLSTANNANE 0 DICHLORODIBUTYLTIN CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (shn). NlOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion, intravenous, and intraperitoneal routes. Moderately toxic by skin contact. A severe skin and eye irritant. Experimental reproductive effects. Mutation data reported. See also TIN COMPOUNDS. Combustible when exposed to heat or flame. A dangerous material; emits highly toxic fumes of HC1; wdl react with water or steam to produce heat and toxic fumes; can react vigorously with oxidizing materials. To
44% DD Y600
DIBUTYLDl(2-ETHYLHEXYLOXY
fight fue, use water, foam, C02, dry chemical. DDY6OO CAS: 10584-98-2 HR: 2 DlBUTYLDI(2-ETHYLHEXYLOXYCARBONYLMETHYLTHI0)STANNANE mf: C28H5604SzSn mW: 639.65 SYNS: BlS(2ETHYLHEXYLOXI'CARBONYETHYLTHI0)DIBUTYL STANNANE 0 BIS(2-ETHYLHEXYLTHIOGLYC0IATE)DIBUTYLTIN 0 DI-n-BUTYLTIN DI-2-ETHYLHEXYL THIOGLYCOLATE 0 DI-n-BUTYL-ZINNDI-2AETHYLHEXYL THIOGLYKOIAT (GERMAN)
CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m' ( s h ) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Moderately toxic by ingestion. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of SO,.
DDY800 CAS: 563-25-7 HR: 3 DIBUTYLDIFLUOROSTANNANE mf: CsHlsFzSn mw: 270.95 SYN: DIBUTYLTIN DIFLL'ORIDE CONSENSUS REPORTS: Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion. See also TIN COMPOUNDS and FLUORIDES. When heated to decomposition it emits toxic fumes of F-. DDZOOO CAS: 7392-96-3 HR: 3 DIBUTY L(DIFORMYL0XY)STANNANE mf: CloHzo04Sn mw: 322.99 SYNS: DI-n-BUTYLTIN DIFORMATE 0 MMVENCAN DI-n-BUTYLCISICITY(CZECH)
OSHA PEL: TWA 0.1 mg(Sn)/m3 ( s h ) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m3 (skin).
NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion. A severe skin and eye irritant. When heated to decomposition it emits acrid and irritating fumes. See also TIN COMPOUNDS.
DEA6OO CAS: 3465-74-5 HR: 3 DlBUTYLDIPENTANOYLOXYSTANNANE mf: ClsH3604Sn mw: 435.23 SYNS: DI-n-BUTYLTIN DIPENTANOATE 0 DI(PENTANOYLOX~D1BUTYLSTANNANE 0 VALERAN DI-n-BUTYLCINICITY (CZECH)
OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin) ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL
0.2 mg(Sn)/m3 (shn). NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3 SAFETY PROFILE: Poison by ingestion. A severe skin and eye irritant. See also TIN COMPOUNDS. When heated to decomposition it emits acrid and irritating fumes. DECOOO CAS: 625-22-9 HR: 3 DIBUTYL ESTER SULFURIC ACID mf: C8H1804S mw: 210.32 PROP: Lquid with sharp odor. Bp: 115-116' @ 6 mm. SYNS: DI-n-BUTYLSULFAT (GERMAN) 0 DIBUTYL SULFATE
SAFETY PROFILE: Poison by ingestion. Mildly toxic by subcutaneous route. Questionable carcinogen with experimental tumorigenic data. See also ESTERS and SULFATES. When heated to decomposition it emits toxic fumes of SO,.
DEC100 CAS: 4062-60-6 HR: 3 N,N-DI-tert-BUTYLETHYLENEDIAMINE mf: C I O H ~ ~ N Z mw: 172.36 SYNS: AR 81242 0 N,N'-BIS(l,l-DIMETHYLETHYL)-1,2ETHANEDIAMINE 0 1,2-ETHANEDIAMINE.N,N'BIS(1,I -DIMETHYLETHYL)-
SAFETY PROFILE: A poison by ingestion. Low toxicity by ingestion. A mild skin irritant. When heated to decomposition it emits toxic vapors of NO,.
DI-see-BUTYLMERCURY
DEC4OO CAS: 761-65-9 HR: 3 N,N-DI-n-BUTYLFORMAMIDE mf: C9H19NO mw: 157.29 PROP: Lquid. Bp: 235'. SYNS: DBF 0 DIBUTYLAhfID KYSELINY MRAVENCI 0
N,N-DI-n-BUTYLFOIMIDE
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. An experimental teratogen. When heated to decomposition it emits toxic fumes of NO,.
DEC6OO CAS: 105-75-9 HR: 3 DIBUTYL FUMARATE mf: C12H2004 mw: 228.32 PROP: Colorless, clear, mobile liquid; typical odor. Bp: 285.1', fp: -19', flash p: 300°F (OC), d: 0.986 @ 20'/20', vap d: 7.88. SYNS: DIBUTYLESTER KYSELINY FUMAROVE 0 FUSIARIC ACID, DIBUTYL ESTER
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Mildly toxic by ingestion and s h n contact. An eye, skn, and mucous membrane irritant. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, C02, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
DED6OO CAS: 105-76-0 HR: 3 DIBUTYL MALEATE mf: C12H2004 mw: 228.32 PROP: Liquid. Mp: -85' (sets to a glass), bp: 281', flash p: 285'F (OC), d: 0.9964 @ 20°/200, vap d: 7.9. SYNS: 2-BUTENEDIOIC ACID, DIBUTYL ESTER 0 DBM 0 MALEIC ACID, DIBUTYL ESTER 0 RC COhiONOMER DBM 0 STAFLEX DBhf
CONSENSUS REPORTS: Reported in EPA
TSCA Inventory. SAFETY PROFILE: Poison by intraperitoneal route. Moderately toxic by ingestion. Mddly toxic by skin contact. An eye and skin irritant. See also ESTERS and n-BUTYL ALCOHOL. Combustible when
DEE200 449
exposed to heat or flame; can react with oxilzing materials. To fight fire, use foam, C02, dry chemical, alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes. DEE000 CAS: 629-35-6 HR: 3 DIBUTYLMERCURY mf: CsHlsHg mw: 314.85 PROP: Lquid. Bp: 105" @ 10 mm, d: 1.779, vap d: 10.8. Sol in most org solvs; ins01 in H20. IDLH 10 mg/m3 (as Hg). SYN: DIBUTYLRTTT CONSENSUS REPORTS: Mercury and its compounds are on the Community RightTo-Know List. Reported in EPA TSCA Inventory. OSHA PEL: TWA 0.01 mg(Hg)/m3; STEL 0.03 mg/m3 (skin) 