European Agreement Concerning the International Carriage of Dangerous Goods by Inland Waterways (ADN) 2007

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ECElTRANSl190 (Vol. I)

ECONOMIC COMMISSION FOR EUROPE

Committee on Inland Transport

European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways (ADN) -

Final Act final of the Conference

-

Resolution on the Follow-up to the Conference

-

Agreement as adopted on 25 May 2000

-

Annexed Regulations, as revised as of 1 January 2007

UNITED NATIONS New York and Geneva, 2006

NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries.

I

ECE/TRANS/l90 (Vol. I)

1

Copyright O United Nations, 2006 AN right reserved. No part of this publication may be, for sales puiposes, be reproduced, stored in a retrieval system or transmitted in anyform or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, withoutprior permission in writing form from the United Nations

I

UNITED NATIONS PUBLICATIONS Sales No.: E.06.VIII.2 ISBN 92-1-1391 18-0 (Complete set of 2 volumes) ISBN 92- 1 - 139116-4 (Vol. I) Volumes I end I1 not to be sold separately.

FOREWORD The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways (ADN) was adopted on 25 May 2000 by a Diplomatic Conference held in Geneva from 22 to 26 May 2000 under the auspices of the United Nations Economic Commission for Europe (UNECE) and the Central Commission for the Navigation on the Rhine (CCNR). The ADN was elaborated jointly by the UNECE and the CCNR. The Agreement itself and the annexed Regulations in their original version, which form an integral part of it, as well as the Final Act of the Conference and the Resolution adopted by the Conference, were published in 200 1, under the symbol ECEITRANSII 50. The Final Act was signed on 26 May 2000 by the accredited representatives of the following fifteen countries: Austria, Belgium, Bulgaria, Croatia, Czech Republic, France, Germany, Hungary, Italy, Netherlands, Poland, Romania, Russian Federation, Slovakia and Switzerland. The Agreement was opened for signature from 26 May 2000 until 31 May 2001. It has been signed (subject to acceptance, approval or ratification) by the following States: Bulgaria, Croatia, Czech Republic, France, Germany, Italy, Luxembourg, Netherlands, Republic of Moldova and Slovakia. States which have not signed the Agreement may accede to it. The Agreement will enter into force one month after the date on which the number of States having signed it definitively, or having deposited their instruments of ratification, acceptance, approval or accession, has reached a total of seven. The Netherlands deposited an instrument of acceptance on 30 April 2003. Bulgaria deposited an instrument of ratification on 7 March 2006. The Russian Federation, Hungary and Austria acceded to the ADN on 10 October 2002,4 May 2004 and 9 November 2004 respectively. The annexed Regulations contain provisions concerning dangerous substances and articles, provisions concerning their carriage in packages and in bulk on board inland navigation vessels or tank vessels, as well as provisions concerning the construction and operation of such vessels. They also address requirements and procedures for inspections, issue of certificates of approval, recognition of classification societies, monitoring, and training and examination of experts. The annexed Regulations, in their original version, should apply twelve months after the entry into force of the Agreement (Article 11). However, in view of the delays for entry into force inherent to the processes of ratification and accession, the Resolution adopted by the Conference holds that the annexed Regulation will be updated on a regular basis by a Joint Meeting of Experts before the entry into force of the Agreement. It recommends that States interested in becoming Parties to the Agreement regularly implement these updates, at the national level, without waiting for the entry into force of the Agreement. On the entry into force of the Agreement, the most recent version of the annexed Regulations will be submitted for adoption to the ADN Administrative Committee (see Article 17) in order to ensure that the annexed Regulations, which will apply twelve months after the entry into force of the Agreement, are the updated version. Since the adoption of the Agreement in May 2000, sessions of the Joint Meeting of experts have been organized seven times jointly by the UNECE and the CCNR, and have adopted amendments to the original annexed Regulations (reports TRANSIWP. 15lAC.219, -11 1, -/l 3, -115, -1151Add.l , -117, -117lAdd.l and l7lAdd. llCorr. l, -119lAdd. l and -1211Add. l and 2). As a consequence, publications, including the text of the Final Act of the Conference held in May 2000, the Resolution adopted by the Conference, the Agreement itself and the updated version of the annexed Regulations as revised by the Joint Meeting for implementation as from 1 January 2003 and 1 January 2005 were issued under the symbols ECElTRANSl170 and ECElTRANSl182 respectively.

This publication contains a new updated version of the annexed Regulations, as adopted by the Joint Meeting for implementation as from 1 January 2007. Additional information on the status of the Agreement and the work of the Joint Meeting of Experts is available on the website of the UNECE Transport Division (http://www.unece.org/trans/danger/danger.htm).

TABLE OF CONTENTS VOLUME I Page FINAL ACT OF THE DIPLOMATIC CONFERENCE FOR THE ADOPTION OF A EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS (ADN).............................................................

xxi

RESOLUTION CONCERNING THE FOLLOW UP TO THE CONFERENCE ............................. xxiii EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS (ADN)............................................................. PART 1

GENERAL PROVISIONS ............................................................................................ Chapter 1.1 1.1.1 1.1.2 1.1.3 1.1.4

Scope and applicability Structure.......................................................................................... Scope............................................................................................... Exemptions ..................................................................................... Applicability of other regulations ...................................................

Chapter 1.2 1.2.1 1.2.2

Definitions and units of measurement Definitions ...................................................................................... Units of measurement .....................................................................

Chapter 1.3

Training of persons involved in the carriage of dangerous goods Scope and applicability ................................................................... Nature of the training ...................................................................... Documentation ................................................................................

1.3.1 1.3.2 1.3.3

Chapter 1.4 1.4.1 1.4.2 1.4.3

Safety obligations of the participants General safety measures ................................................................. Obligations of the main participants ............................................... Obligations of the other participants ...............................................

Chapter 1.5 1.5.1 1.5.2 1.5.3

Special rules. derogations Bilateral and multilateral agreements ............................................. Special authorizations concerning transport in tank vessels ........... Equivalents and derogations (Article 7. paragraph 3 of ADN) .......

Chapter 1.6 1.6.1 1.6.2 1.6.3

Transitional measures General ............................................................................................ Receptacles for Class 2 ................................................................... Fixed tanks (tank-vehicles and tank wagons). demountable tanks. battery vehicles and battery wagons ..................................... Tank.containers. portable tanks and MEGCs ................................. Vehicles and wagons....................................................................... Class 7 ............................................................................................. Transitional provisions concerning vessels .....................................

1.6.4 1.6.5 1.6.6 1.6.7

xxv 1

Table of contents (cont'd)

Chapter 1.7 1.7.1 1J . 2 1.7.3 1.7.4 1.7.5 1.7.6

General requirements concerning class 7 General ............................................................................................ Radiation protection programme .................................................... Quality assurance ............................................................................ Special arrangement ........................................................................ Radioactive material possessing other dangerous properties .......... Non.compliance ............................................................

Chapter 1.8

Checks and other support measures to ensure compliance with safety requirements Monitoring compliance with requirements ..................................... Administrative assistance during the checking of a foreign vessel ............................................................................................... Safety adviser .................................................................................. List of competent authorities and bodies designated by them ........ Notifications of occurrences involving dangerous goods ...............

Chapter 1.9

Transport restrictions by the competent authorities .................

Chapter 1.10 1.10.1 1.10.2 1.10.3

Security provisions General provisions .......................................................................... Security training .............................................................................. Provisions for high consequence dangerous goods .........................

Chapters 1.11 to 1.14 (Reserved)

PART 2

Chapter 1.15 1.15.1 1.15.2 1.15.3

Recognition of classification societies General ............................................................................................ Procedure for the recognition of classification societies................. Conditions and criteria for the recognition of a classification society applying for recognition under this Agreement .................. Obligations of recommended classification societies .....................

Chapter 1.16 1.16.1 1.16.2 1.16.3 1.16.4 1.16.5 1.16.6

Procedure for the issue of the certificate of approval Certificate of approval .................................................................... Issue and recognition of certificates of approval ............................ Inspection procedure ....................................................................... Inspection body ............................................................................... Application for the issue of a certificate of approval ...................... Particulars entered in the certificate of approval and amendments thereto ........................................................................ Presentation of the vessel for inspection......................................... First inspection................................................................................ Special inspection ........................................................................... Periodic inspection and renewal of the certificate of approval ....... Extension of the certificate of approval without an inspection ....... Official inspection........................................................................... Withholding and return of the certificate of approval..................... Duplicate copy ................................................................................ Register of certificates of approval .................................................

CLASSIFICATION ...................................................................................... (See Volume 11)

- vi -

Table of contents (cont'd) PART 3

PART 4 PART S

DANGEROUS GOODS LIST. SPECIAL PROVISIONS AND EXEMPTIONS RELATED TO DANGEROUS GOODS PACKED IN LIMITED QUANTITIES............................................................................................

99

Chapter 3.1

General ........................................................................... (See Volume I1

Chapter 3.2 3.2.1

List of dangerous goods List of dangerous goods in numerical Table A: order .......................................................... (See Volume 11) List of dangerous goods in alphabetical Table B: order ........................................................... See Volume 11) List of dangerous goods accepted for Table C: carriage in tank vessels in numerical order ............................................................................. 1 0 3

Chapter 3.3

Special provisions applicable to certain articles or substances ................................................................... See Volume 11)

Chapter 3.4

Exemptions related to dangerous goods packed in limited quantities .......................................................... (See Volume 11)

PROVISIONS CONCERNING THE USE OF PACKAGINGS. TANKS AND BULK TRANSPORT UNITS ..............................................................................

169

CONSIGNMENT PROCEDURES ..............................................................................

173

Chapter 5.1 5.1.1 5.1.2 5.1.3

General provisions Application and general provisions................................................. Use of overpacks............................................................................. Empty uncleaned packagings (including IBCs and large packagings). tanks. vehicles and containers for carriage in bulk ................................................................................................. Mixed packing ................................................................................ General provisions for Class 7 ........................................................

Chapter 5.2 5.2.1 5.2.2

Marking and labelling Marking of packages ....................................................................... Labelling of packages .....................................................................

Chapter 5.3

Placarding and marking of containers. MEGCs. tank.containers. portable tanks. vehicles and wagons Placarding ....................................................................................... Orange-coloured plate marking ...................................................... Mark for elevated temperature substances...................................... Marking for carriage in a transport chain including maritime transport ..........................................................................................

Chapter 5.4 5.4.1 5.4.2 5.4.3 5.4.4.

Documentation Dangerous goods transport document and related information ...... Container packing certificate .......................................................... Instructions in writing ..................................................................... Example of a multimodal dangerous goods form ........................... .vii .

Table of contents (cont'd) Chapter 5.5 5.5.1 5.5.2 PART 6

PART 7

Special provisions (Deleted) Special provisions for fumigated vehicles, wagons. containers and tanks ........................................................................

221

REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF PACKAGINGS (INCLUDING IBCS AND LARGE PACKAGINGS). TANKS AND BULK TRANSPORT UNITS ...............................................................

223

REQUIREMENTS CONCERNING LOADING. CARRIAGE. UNLOADING AND HANDLING OF CARGO ..........................................................

227

Chapter 7.1 7.1.0 7.1.1 7.1.2 7.1.3 7.1.4

Chapter 7.2 7.2.0 7.2.1 7.2.2 7.2.3 7.2.4

PART 8

Dry cargo vessels General requirements ...................................................................... Mode of carriage of goods .............................................................. Requirements applicable to vessels................................................. General service requirements.......................................................... Additional requirements concerning loading. carriage. unloading and other handling of the cargo.................................... Additional requirements concerning the operation of vessels ........ Additional requirements..................................................................

Tank vessels General requirements ...................................................................... Mode of carriage of goods .............................................................. Requirements applicable to vessels................................................. General service requirements......................................................... Additional requirements concerning loading, carriage, unloading and other handling of cargo ........................................... Additional requirements concerning the operation of vessels ........

229 229 230 231 234 248 251

255 255 255 257 263 273

PROVISIONS FOR VESSEL CREWS. EQUIPMENT. OPERATION AND DOCUMENTATION ..................................................................................................... 277 Chapter 8.1

General requirements applicable to vessels and equipment (Reserved) Documents ...................................................................................... (Reserved) . . Fire-extinguishing arrangements..................................................... Special equipment ........................................................................... Checking and inspection of equipment ........................................... Electrical installations..................................................................... Certificate of approval .................................................................... Provisional certificate of approval .................................................. Loading journal ............................................................................... Register of operations relating to the carriage of UN 1203 ............

Chapter 8.2 8.2.1 8.2.2

Requirements concerning training General requirements concerning training of experts ..................... Special requirements for the training of experts .............................

Table of contents (cont'd)

PART 9

Chapter 8.3

Miscellaneous requirements to be complied with by the crew of the vessel Persons authorized on board ........................................................... Portable lamps ................................................................................. Admittance on board ....................................................................... Prohibition on smoking, fire and naked light .................................. Risk of sparking ..............................................................................

Chapter 8.4

(Reserved) .......................................................................................

Chapter 8.5

(Reserved) .......................................................................................

Chapter 8.6 8.6.1 8.6.2

Documents Certificate of approval .................................................................... Certificate of special knowledge of ADN according to 8.2.1.2, 8.2.1.4 or 8.2.1.5 ................................................................ Checklist ADN ................................................................................ Discharge of residual quantities and stripping systems ..................

RULES FOR CONSTRUCTION ................................................................................. 325 Chapter 9.1 9.1.0

Rules for construction of dry cargo vessels Rules for construction applicable to dry cargo vessels ................... 327

Chapter 9.2

Rules for construction applicable to seagoing vessels which comply with the requirements of the SOLAS 74 Convention. Chapter 11.2. Regulation 19 or SOLAS 74. Chapter 11.2. Regulation 54

....................................................................................................... 341 Chapter 9.3 9.3.1 9.3.2 9.3.3

Rules for construction of tank vessels Rules for construction of type G tank vessels ................................. 347 Rules for construction of type C tank vessels ................................. 374 Rules for construction of type N tank vessels ................................. 405

FINAL ACT OF THE DIPLOMATIC CONFERENCE FOR THE ADOPTION OF A EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS (ADN) The Diplomatic Conference for the Adoption of a European Agreement concerning the International l. Carriage of Dangerous Goods by Inland Waterways (ADN) was convened jointly by the Executive Secretary of the United Nations Economic Commission for Europe (UNIECE) and the Secretary-General of the Central Commission for the Navigation of the Rhine (CCNR) pursuant to a decision of the UNIECE Inland Transport Committee at its fifty-eighth session (12- 16 January 1998) and CCNR Resolution 1994-11-6. 2.

The Conference was held at the Palais des Nations, Geneva, from 22 to 26 May 2000.

Representatives of the following States took part in the work of the Conference: Austria; Belgium; 3. Bulgaria; Croatia; Czech Republic; France; Germany; Hungary; Italy; Netherlands; Poland; Republic of Moldova; Romania; Russian Federation; Slovakia; Switzerland; Ukraine. 4.

Representatives of Turkey took part as observers.

5.

The European Commission also took part in the Conference.

6.

The following intergovernmental organization sent observers to the Conference: Danube Commission.

The following non-governmental organizations also sent observers to the Conference: European 7. Petroleum Industry Association (EUROPIA); International Association of Classification Societies (IACS); International Consortium of Rhine Inland Navigation (IAR); International Union for Inland Navigation (UrNF). 8.

Mr. R.J. van Dijk of the delegation of the Netherlands was elected President of the Conference.

9. The secretariat of UNJECE and the secretariat of CCNR acted jointly as the secretariat of the Conference.

10. The Conference adopted its draft agenda (ECE/TRANS/ADN/CONF/l-CCNR/MD/ADN/CONF/I and ECE/TRANS/ADN/CONF/l/Add. 1-CCNR/MD/ADN/CONF/l/Add. l). 11. The Conference adopted document ECE/TRANS/ADN/CONF/2- CCNR/MD/ADN/CONF/2proposed by the secretariat as its rules of procedure, with an amendment to rule 7 where the words "or alternate representatives" were inserted after "representatives". 12.

The Conference elected the following two Vice-Presidents: Mr. M. Rak (Czech Republic); Mr. G. Kafka (Austria).

13. In accordance with rule 5 of the rules of procedure of the Conference, the secretariat of the Conference examined the credentials and reported to the Conference. On the basis of this report, the Conference accepted the credentials of the States named in paragraph 3.

14.

The Conference based its proceedings on the following documents:

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Draft European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways (ECE/TRANS/ADN/CONF/3-CCNR/MD/ADN/CONF/3);

-

Annexes A, B.l and B.2 of the annexed Regulations (TRANS/WP.15/AC.2/5 and TRANStWP. 15/AC.2/5/Corr.1-CCNR/MD/ADN/CONF/A, B. 1, B.2);

-

Annex C of the CCNR/MD/ADN/CONF/4);

-

Annexes D. 1 and D.2 of the annexed Regulations

annexed

Regulations

(ECE/TRANS/ADN/CONF/4-

(ECEITRANSIADNICONFI5-CCNR/MD/ADN/CONF/S);

-

Draft Conference resolution (ECE/TRANS/ADN/CONF/6-CCNR/MD/ADN/CONF/6).

15. The Conference also had before it a number of documents containing proposals and observations by Governments or the secretariat concerning the above-mentioned draft texts:

-

-

-

-

ECE/TRANS/ADN/CONF/7-CCNR/MD/ADN/CONF/7 (France); ECE/TRANS/ADN/CONF/8-CCNlUMD/ADN/CONF/8 (Russian Federation); ECE/TRANS/ADN/CONF/2000/CRP. l -CCNR/MD/ADN/CONF/9 (Belgium); ECE/TRANS/ADN/CONF/2000/CRP.2-CCNlUMD/ADN/CONF/ 1 (France); ECE/TRANS/ADN/CONF/2000/CRP.3-CCNR/MD/ADN/CONF/ll (Germany and France); ECE/TRANS/ADN/CONF/2000/CRP.6-CCNR/MD/ADN/CONF/12 (Netherlands); ECE/TRANS/ADN/CONF/2000/CRP.7-CCNR/MD/ADN/CONF/l3 (Netherlands); ECE/TRANS/ADN/CONF/2000/CRP. 8-CCNR/MD/ADN/CONF/14 (Secretariat).

16. Following the debate, the Conference adopted the European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways (ADN) in English, French, German and Russian for the CRP. 10) and in French only for the annexed Agreement proper (document ECE/TRANS/ADN/CONF/2000/ Regulations (document TRANSIWP.15/AC.2/5 and -1Corr. l for annexes A, B. 1 and B.2 and document ECE/TRANS/ADN/CONF/2000/CRP. 11 for annexes C, D. l and D.2). 17. The Agreement will be deposited with the Secretary-General of the United Nations. It will be open for signature in the Office of the Executive Secretary of UNIECE in Geneva until 31 May 2001. Thereafter it will be open for accession. 18.

The Conference also adopted a resolution contained in the document annexed to this Final Act.

19.

Belgium made a declaration the text of which will be annexed to the Final ~ c t . *

I N WITNESS WHEREOF, the undersigned have signed this Final Act. DONE at Geneva, this twenty-sixth day of May two thousand, in a single original copy, in the English, French, German and Russian languages, which will be deposited with the Secretary-General of the United Nations.

*

This declaration was withdrawn by Note verbale No 1718 of 5 June 2000 sent to the UNECE secretariat by the Permanent Mission of Belgium to the United Nations OfJice and Specialized Agencies at Geneva. - xi -

RESOLUTION Follow up to the Conference

The Conference, Recognizing that the Regulations annexed to the European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways (ADN) meet the level of safety required for navigation on European waterways covered by the European Agreement on Main Inland Waterways of International Importance (AGN), particularly on the Rhine, at the time of adoption of this Agreement; Considering, however, that this level of safety might no longer be deemed suitable at the time of entry into force of the Agreement, depending on the evolution of safety and transport techniques; Recognizing; also the need for harmonization of the provisions of the Regulations annexed to this Agreement with those of other agreements governing other modes of transport for the purpose of facilitating multimodal transport; Aware of the request by the Central Commission for the Navigation of the Rhine that the level of safety at the time of entry into force of the Agreement should correspond to that applicable at that time on the Rhine; Aware also of the desire of the Central Commission for the Navigation of the Rhine and of the Danube Commission to remain closely associated in the regulating process;

m

that the United Nations Economic Commission for Europe, the Central Commission for the Navigation of the Rhine and the Danube Commission have bodies dealing with the transport of dangerous goods by inland waterways; Considering that, once the Agreement has entered into force, any proposal relating to the annexed Regulations should in principle, before submission to the Administrative Committee, be discussed at meetings of experts of the Contracting Parties and, if necessary, of the other States and international organizations mentioned in article 17, paragraph (2); l. Invites the United Nations Economic Commission for Europe, the Central Commission for the Navigation of the Rhine and the Danube Commission to establish a joint meeting of experts with the following mandate:

(a)

before entry into force of the Agreement:

(b)

to prepare the updates of the annexed Regulations in order to enable the Administrative Committee, once the Agreement has entered into force, to adapt them to the evolution of transport techniques and to the ongoing restructuring of the other European regulations governing the carriage of dangerous goods and to bring them into line with the level of safety required for navigation on European waterways covered by AGN, particularly on the Rhine; (ii) to recommend regular implementation, at national level, of the updated provisions of the relevant annexes by all countries interested in becoming parties to the Agreement; (iii) to appoint, amongst Contracting States and Signatory States, provisional committees of experts in accordance with Annex C, Chapter 2, paragraph2.2.2 of the annexed Regulations to consider on a preliminary basis requests from classification societies which wish to be recommended for recognition; after entry into force of the Agreement: (i)

to take the place of the Safety Committee referred to in article 18.

- xii -

Requests the Executive Secretary of the United Nations Economic Commission for Europe to convene 2. a meeting of the Administrative Committee as soon as possible after the entry into force of the Agreement with a view to: (a)

(b)

adopting proposals for the revision of the annexed Regulations as prepared in accordance with paragraphs 1 (a) (i) and 1 (b) above so that the Regulations will be applicable on the date scheduled in Article 11, paragraph 1; adopting a list of recommended classification societies on the basis of the preliminary work carried out in accordance with paragraph 1 (a) (iii) above, or appointing new committees of experts in accordance with Annex C, Chapter 2, paragraph 2.2.2 to consider requests from classification societies which wish to be recommended for recognition. Adopted on 25 May 2000

EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS (ADN)

THE CONTRACTING PARTIES, DESIRING to establish by joint agreement uniform principles and rules, for the purposes of: (a)

increasing the safety of international carriage of dangerous goods by inland waterways;

(b)

contributing effectively to the protection of the environment, by preventing any pollution resulting from accidents or incidents during such carriage; and

(c)

facilitating transport operations and promoting international trade,

CONSIDERING that the best means of achieving this goal is to conclude an agreement to replace the "European Provisions concerning the International Carriage of Dangerous Goods by Inland Waterways" annexed to resolution No. 223 of the Inland Transport Committee of the Economic Commission for Europe, as amended, HAVE AGREED as follows: CHAPTER I GENERAL PROVISIONS Article 1 Scope 1.

This Agreement shall apply to the international carriage of dangerous goods by vessels on inland waterways.

2.

This Agreement shall not apply to the carriage of dangerous goods by seagoing vessels on maritime waterways forming part of inland waterways.

3.

This Agreement shall not apply to the carriage of dangerous goods by warships or auxiliary warships or to other vessels belonging to or operated by a State, provided such vessels are used by the State exclusively for governmental and non-commercial purposes. However, each Contracting Party shall, by taking appropriate measures which do not impair the operations or operational capacity of such vessels belonging to or operated by it, ensure that such vessels are operated in a manner compatible with this Agreement, where it is reasonable in practice to do so.

- xiv -

Article 2

Regulations annexed to the Agreement 1.

The Regulations annexed to this Agreement shall form an integral part thereof. Any reference to this Agreement implies at the same time a reference to the Regulations annexed thereto.

2.

The annexed Regulations include: (a)

Provisions concerning the international carriage of dangerous goods by inland waterways;

(b)

Requirements and procedures concerning inspections, the issue of certificates of approval, recognition of classification societies, derogations, special authorizations, monitoring, training and examination of experts;

(c)

General transitional provisions;

(d)

Supplementary transitional provisions applicable to specific inland waterways. Article 3

Definitions For the purposes of this Agreement: "vessel'' means an inland waterway or seagoing vessel; "dangerous goods" means substances and articles the international carriage of which is prohibited by, or authorized only on certain conditions by, the annexed Regulations; "international carriage of dangerous goods" means any carriage of dangerous goods performed by a vessel on inland waterways on the territory of at least two Contracting Parties; "inland waterways" means the navigable inland waterways including maritime waterways on the territory of a Contracting Party open to the navigation of vessels under national law; "maritime waterways" means inland waterways linked to the sea, basically used for the traffic of seagoing vessels and designated as such under national law; "recognized classiJication society" means a classification society which is in conformity with the annexed Regulations and recognized, in accordance with the procedures laid down in these Regulations, by the competent authority of the Contracting Party where the certificate is issued; "competent authority" means the authority or the body designated or recognized as such in each Contracting Party and in each specific case in connection with these provisions; "inspection body" means a body nominated or recognized by the Contracting Party for the purpose of inspecting vessels according to the procedures laid down in the annexed Regulations.

CHAPTER I1 TECHNICAL PROVISIONS

Article 4

Prohibitions on carriage, conditions of carriage, monitoring Subject to the provisions of Articles 7 and 8, dangerous goods barred from carriage by the annexed Regulations shall not be accepted for international carriage. Without prejudice to the provisions of Article 6, the international carriage of other dangerous goods shall be authorized, subject to compliance with the conditions laid down in the annexed Regulations. Observance of the prohibitions and the conditions referred to in paragraphs 1 and 2 shall be monitored by the Contracting Parties in accordance with the provisions laid down in the annexed Regulations.

Article 5

Exemptions This Agreement shall not apply to the carriage of dangerous goods to the extent to which such carriage is exempted in accordance with the annexed Regulations. Exemptions may only be granted when the quantity of the goods exempted, or the nature of the transport operation exempted, or the packaging, ensure that transport is carried out safely.

Article 6

Sovereign right of States Each Contracting Party shall retain the right to regulate or prohibit the entry of dangerous goods into its territory for reasons other than safety during carriage. Article 7

Special regulations, derogations 1.

The Contracting Parties shall retain the right to arrange, for a limited period established in the annexed Regulations, by special bilateral or multilateral agreements, and provided safety is not impaired: (a)

that the dangerous goods which under this Agreement are barred from international carriage may, subject to certain conditions, be accepted for international carriage on their inland waterways; or

(b)

that dangerous goods which under this Agreement are accepted for international carriage only on specified conditions may alternatively be accepted for international carriage on their inland waterways under conditions different from those laid down in the annexed Regulations.

The special bilateral or multilateral agreements referred to in this paragraph shall be communicated immediately to the Executive Secretary of the Economic Commission for Europe, who shall communicate them to the Contracting Parties which are not signatories to the said agreements.

- xvi -

Each Contracting Party shall retain the right to issue special authorizations for the international carriage in tank vessels of dangerous substances the carriage of which in tank vessels is not permitted under the provisions concerning carriage in the annexed Regulations, subject to compliance with the procedures relating to special authorizations in the annexed Regulations. The Contracting Parties shall retain the right to authorize, in the following cases, the international carriage of dangerous goods on board vessels which do not comply with conditions established in the annexed Regulations, provided that the procedure established in the annexed Regulations is complied with: (a)

The use on a vessel of materials, installations or equipment or the application on a vessel of certain measures concerning construction or certain provisions other than those prescribed in the annexed Regulations;

(b)

Vessel with technical innovations derogating from the provisions of the annexed Regulations. Article 8 Transitional provisions

Certificates of approval and other documents prepared in accordance with the requirements of the Regulations for the Carriage of Dangerous Goods in the Rhine (ADNR), the Regulations for the Carriage of Dangerous Goods on the Danube (ADN-D) or national regulations based on the European Provisions concerning the International Carriage of Dangerous Goods by Inland Waterways as annexed to resolution No. 223 of the Inland Transport Committee of the Economic Commission for Europe or as amended, applicable at the date of application of the annexed Regulations foreseen in Article 11, paragraph 1, shall remain valid until their expiry date, under the same conditions as those prevailing up to the date of such application, including their recognition by other States. In addition, these certificates shall remain valid for a period of one year from the date of application of the annexed Regulations in the event that they would expire during that period. However, the period of validity shall in no case exceed five years beyond the date of application of the annexed Regulations. Vessels which, at the date of application of the annexed Regulations foreseen in Article 1 1, paragraph l , are approved for the carriage of dangerous goods on the territory of a Contracting Party and which conform to the requirements of the annexed Regulations, taking into account where necessary, their general transitional provisions, may obtain an ADN certificate of approval under the procedure laid down in the annexed Regulations. In the case of vessels referred to in paragraph 2 to be used exclusively for carriage on inland waterways where ADNR was not applicable under domestic law prior to the date of application of the annexed Regulations foreseen in Article 1 1, paragraph 1, the supplementary transitional provisions applicable to specific inland waterways may be applied in addition to the general transitional provisions. Such vessels shall obtain an ADN certificate of approval limited to the inland waterways referred to above, or to a portion thereof. If new provisions are added to the annexed Regulations, the Contracting Parties may include new general transitional provisions. These transitional provisions shall indicate the vessels in question and the period for which they are valid. Article 9

Applicability of other regulations The transport operations to which this Agreement applies shall remain subject to local, regional or international re&lations applicable in general to the carriage of goods by inland waterways.

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CHAPTER I11 FINAL PROVISIONS Article 10

Contracting Parties 1.

Member States of the Economic Commission for Europe whose territory contains inland waterways, other than those forming a coastal route, which form part of the network of inland waterways of international importance as defined in the European Agreement on Main Inland Waterways of International Importance (AGN) may become Contracting Parties to this Agreement: (a)

by signing it definitively;

(b)

by depositing an instrument of ratification, acceptance or approval after signing it subject to ratification, acceptance or approval;

(c)

by depositing an instrument of accession.

2.

The Agreement shall be open for signature until 3 1 May 2001 at the Office of the Executive Secretary of the Economic Commission for Europe, Geneva. Thereafter, it shall be open for accession.

3.

The instruments of ratification, acceptance, approval or accession shall be deposited with the Secretary-General of the United Nations. Article 11

Entry into force 1.

This Agreement shall enter into force one month after the date on which the number of States mentioned in Article 10, paragraph l , which have signed it definitively, or have deposited their instruments of ratification, acceptance, approval or accession has reached a total of seven. However, the annexed Regulations, except provisions concerning recognition of classification societies, shall not apply until twelve months after the entry into force of the Agreement.

2.

For any State signing this Agreement definitively or ratifying, accepting, approving or acceding to it after seven of the States referred to in Article 10, paragraph 1, have signed it definitively or have deposited their instruments of ratification, acceptance, approval or accession, this Agreement shall enter into force one month after the said State has signed it definitively or has deposited its instrument of ratification, acceptance, approval or accession. The annexed Regulations shall become applicable on the same date. In the event that the term referred to in paragraph l relating to the application of the annexed Regulations has not expired, the annexed Regulations shall become applicable after expiry of the said term.

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Article 12 Denunciation Any Contracting Party may denounce this Agreement by so notifying in writing the Secretary-General of the United Nations. Denunciation shall take effect twelve months after the date of receipt by the Secretary-General of the written notification of denunciation.

Article 13 Termination If, after the entry into force of this Agreement, the number of Contracting Parties is less than five during twelve consecutive months, this Agreement shall cease to have effect at the end of the said period of twelve months. In the event of the conclusion of a world-wide agreement for the regulation of the multimodal transport of dangerous goods, any provision of this Agreement, with the exception of those pertaining exclusively to inland waterways, the construction and equipment of vessels, carriage in bulk or tankers which is contrary to any provision of the said world-wide agreement shall, from the date on which the latter enters into force, automatically cease to apply to relations between the Parties to this Agreement which become parties to the world-wide agreement, and shall automatically be replaced by the relevant provision of the said world-wide agreement.

Article 14 Declarations Any State may, at the time of signing this Agreement definitively or of depositing its instrument of ratification, acceptance, approval or accession or at any time thereafter, declare by written notification addressed to the Secretary-General of the United Nations that this Agreement shall extend to all or any of the territories for the international relations of which it is responsible. The Agreement shall extend to the territory or territories named in the notification one month after it is received by the SecretaryGeneral. Any State which has made a declaration under paragraph 1 of this article extending this Agreement to any territory for whose international relations it is responsible may denounce the Agreement in respect of the said territory in accordance with the provisions of Article 12. (a)

In addition, any State may, at the time of signing this Agreement definitively or of depositing its instrument of ratification, acceptance, approval or accession or at any time thereafter, declare by written notification addressed to the Secretary-General of the United Nations that this Agreement shall not extend to certain inland waterways on its territory, provided that the waterways in question are not part of the network of inland waterways of international importance as defined in the AGN. If this declaration is made subsequent to the time when the State signs this Agreement definitively or when it deposits its instrument of ratification, acceptance, approval or accession, the Agreement shall cease to have effect on the inland waterways in question one month after this notification is received by the Secretary-General.

(b)

However, any State on whose territory there are inland waterways covered by AGN, and which are, at the date of adoption of this Agreement, subject to a mandatory regime under international law concerning the carriage of dangerous goods, may declare that the implementation of this -

xix -

Agreement on these waterways shall be subject to compliance with the procedures set out in the statutes of the said regime. Any declaration of this nature shall be made at the time of signing this Agreement definitively or of depositing its instrument of ratification, acceptance, approval or accession. Any State which has made a declaration under paragraphs 3 (a) or 3 (b) of this article may subsequently declare by means of a written notification to the Secretary-General of the United Nations that this Agreement shall apply to all or part of its inland waterways covered by the declaration made under paragraphs 3 (a) or 3 (b). The Agreement shall apply to the inland waterways mentioned in the notification one month after it is received by the Secretary-General.

Article 15

Disputes

Any dispute between two or more Contracting Parties concerning the interpretation or application of this Agreement shall so far as possible be settled by negotiation between the Parties in dispute. Any dispute which is not settled by direct negotiation may be referred by the Contracting Parties in dispute to the Administrative Committee which shall consider it and make recommendations for its settlement. Any dispute which is not settled in accordance with paragraphs 1 or 2 shall be submitted to arbitration if any one of the Contracting Parties in dispute so requests and shall be referred accordingly to one or more arbitrators selected by agreement between the Parties in dispute. If within three months from the date of the request for arbitration the Parties in dispute are unable to agree on the selection of an arbitrator or arbitrators, any of those Parties may request the Secretary-General of the United Nations to nominate a single arbitrator to whom the dispute shall be referred for decision. The decision of the arbitrator or arbitrators appointed under paragraph 3 of this article shall be binding on the Contracting Parties in dispute. Article 16

Reservations

Any State may, at the time of signing this Agreement definitively or of depositing its instrument of ratification, acceptance, approval or accession, declare that it does not consider itself bound by Article 15. Other Contracting Parties shall not be bound by Article 15 in respect of any Contracting Party which has entered such a reservation. Any Contracting State having entered a reservation as provided for in paragraph 1 of this article may at any time withdraw such reservation by notifying in writing the Secretary-General of the United Nations. Reservations other than those provided for in this Agreement are not permitted.

Article 17 Administrative Committee An Administrative Committee shall be established to consider the implementation of this Agreement, to consider any amendments proposed thereto and to consider measures to secure uniformity in the interpretation and application thereof. The Contracting Parties shall be members of the Administrative Committee. The Committee may decide that the States referred to in Article 10, paragraph 1 of this Agreement which are not Contracting Parties, any other Member State of the Economic Commission for Europe or of the United Nations or representatives of international intergovernmental or non-governmental organizations may, for questions which interest them, attend the sessions of the Committee as observers. The Secretary-General of the United Nations and the Secretary-General of the Central Commission for the Navigation of the Rhine shall provide the Administrative Committee with secretariat services. The Administrative Committee shall, at the first session of the year, elect a Chairperson and a ViceChairperson. The Executive Secretary of the Economic Commission for Europe shall convene the Administrative Committee annually, or at other intervals decided on by the Committee, and also at the request of at least five Contracting Parties. A quorum consisting of not less than one half of the Contracting Parties shall be required for the purpose of taking decisions. Proposals shall be put to the vote. Each Contracting Party represented at the session shall have one vote. The following rules shall apply: Proposed amendments to the annexed Regulations and decisions pertaining thereto shall be adopted in accordance with the provisions of Article 19, paragraph 2; Proposed amendment to the annexed Regulations and decisions pertaining thereto shall be adopted in accordance with the provisions of Article 20, paragraph 4; Proposals and decisions relating to the recommendation of agreed classification societies, or to the withdrawal of such recommendation, shall be adopted in accordance with the procedure of the provisions of Article 20, paragraph 4; Any proposal or decision other than those referred to in paragraphs (a) to (c) above shall be adopted by a majority of the Administrative Committee members present and voting. The Administrative Committee may set up such working groups as it may deem necessary to assist it in carrying out its duties. In the absence of relevant provisions in this Agreement, the Rules of Procedure of the Economic Commission for Europe shall be applicable unless the Administrative Committee decides otherwise.

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Article 18 Safety Committee A Safety Committee shall be established to consider all proposals for the amendment of the Regulations annexed to the Agreement, particularly as regards safety of navigation in relation to the construction, equipment and crews of vessels. The Safety Committee shall function within the framework of the activities of the bodies of the Economic Commission for Europe, of the Central Commission for the Navigation of the Rhine and of the Danube Commission which are competent in the transport of dangerous goods by inland waterways. Article 19 Procedure for amending the Agreement, excluding the annexed Regulations 1.

This Agreement, excluding its annexed Regulations, may be amended upon the proposal of a Contracting Party by the procedure specified in this article.

2.

Any proposed amendment to this Agreement, excluding the annexed Regulations, shall be considered by the Administrative Committee. Any such amendment considered or prepared during the meeting of the Administrative Committee and adopted by it by a two-thirds majority of the members present and voting shall be communicated by the Secretary-General of the United Nations to the Contracting Parties for their acceptance.

3.

Any proposed amendments communicated for acceptance in accordance with paragraph 2 shall come into force with respect to all Contracting Parties six months after the expiry of a period of twenty-four months following the date of communication of the proposed amendment if, during that period, no objection to the amendment in question has been communicated in writing to the Secretary-General of the United Nations by a Contracting Party. Article 20 Procedure for amending the annexed Regulations

1.

The annexed Regulations may be amended upon the proposal of a Contracting Party. The Secretary-General of the United Nations may also propose amendments with a view to bringing the annexed Regulations into line with other international agreements concerning the transport of dangerous goods and the United Nations Recommendations on the Transport of Dangerous Goods, as well as amendments proposed by a subsidiary body of the Economic Commission for Europe with competence in the area of the transport of dangerous goods.

2.

Any proposed amendment to the annexed Regulations shall in principle be submitted to the Safety Committee, which shall submit the draft amendments it adopts to the Administrative Committee.

3.

At the specific request of a Contracting Party, or if the secretariat of the Administrative Committee considers it appropriate, amendments may also be proposed directly to the Administrative Committee. They shall be examined at a first session and if they are deemed to be acceptable, they shall be reviewed at the following session of the Committee at the same time as any related proposal, unless otherwise decided by the Committee.

4.

Decisions on proposed amendments and proposed draft amendments submitted to the Administrative Committee in accordance with paragraphs 2 and 3 shall be made by a majority of the members present and voting. However, a draft amendment shall not be deemed adopted if, immediately after the vote, five members present declare their objection to it. Adopted draft amendments shall be communicated by the Secretary-General of the United Nations to the Contracting Parties for acceptance.

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5.

Any draft amendment to the annexed Regulations communicated for acceptance in accordance with paragraph 4 shall be deemed to be accepted unless, within three months from the date on which the Secretary-General circulates it, at least one-third of the Contracting Parties, or five of them if one-third exceeds that figure, have given the Secretary-General written notification of their objection to the proposed amendment. If the amendment is deemed to be accepted, it shall enter into force for all the Contracting Parties, on the expiry of a further period of three months, except in the following cases: In cases where similar amendments to other international agreements governing the carriage of dangerous goods have already entered into force, or will enter into force at a different date, the Secretary-General may decide, upon written request by the Executive Secretary of the Economic Commission for Europe, that the amendment shall enter into force on the expiry of a different period so as to allow the simultaneous entry into force of these amendments with those to be made to such other agreements or, if not possible, the quickest entry into force of this amendment after the entry into force of such amendments to other agreements; such period shall not, however, be of less than one month's duration. The Administrative Committee may specify, when adopting a draft amendment, for the purpose of entry into force of the amendment, should it be accepted, a period of more than three months= duration. Article 21 Requests, communications and objections

The Secretary-General of the UnitedNations shall inform all Contracting Parties and all States referred to in Article 10, paragraph 1 of this Agreement of any request, communication or objection under Articles 19 and 20 above and of the date on which any amendment enters into force. Article 22 Review conference 1.

Notwithstanding the procedure provided for in Articles 19 and 20, any Contracting Party may, by notification in writing to the Secretary-General of the United Nations, request that a conference be convened for the purpose of reviewing this Agreement. A review conference to which all Contracting Parties and all States referred to in Article 10, paragraph l, shall be invited, shall be convened by the Executive Secretary of the Economic Commission for Europe if, within a period of six months following the date of notification by the Secretary-General, not less than one fourth of the Contracting Parties notify him of their concurrence with the request.

2.

Notwithstanding the procedure provided for in Articles 19 and 20, a review conference to which all Contracting Parties and all States referred to in Article 10, paragraph 1, shall be invited, shall also be convened by the Executive Secretary of the Economic Commission for Europe upon notification in writing by the Administrative Committee. The Administrative Committee shall make a request if agreed to by a majority of those present and voting in the Committee.

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If a conference is convened in pursuance of paragraphs 1 or 2 of this article, the Executive Secretary of 3. the Economic Commission for Europe shall invite the Contracting Parties to submit, within a period of three months, the proposals which they wish the conference to consider. 4.

The Executive Secretary of the Economic Commission for Europe shall circulate to all the Contracting Parties and to all the States referred to in Article 10, paragraph 1, the provisional agenda for the conference, together with the texts of such proposals, at least six months before the date on which the conference is to meet. Article 23 Depositary The Secretary-General of the United Nations shall be the depositary of this Agreement.

IN WITNESS WHEREOF the undersigned, being duly authorized thereto, have signed this Agreement. DONE at Geneva, this twenty-sixth day of May two thousand, in a single copy, in the English, French, German and Russian languages for the text of the Agreement proper, and in the French language for the annexed Regulations, each text being equally authentic for the Agreement proper. The Secretary-General of the UnitedNations is requested to prepare a translation of the annexed Regulations in the English and Russian languages. The Secretary-General of the Central Commission for the Navigation of the Rhine is requested to prepare a translation of the annexed Regulations in the German language.

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PART I

General provisions

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CHAPTER 1.1 SCOPE AND APPLICABILITY Structure The Regulations annexed to ADN are grouped into nine parts. Each part is subdivided into chapters and each chapter into sections and subsections (see table of contents). Within each part the number of the part is included with the numbers of the chapters, sections and subsections, for example Part 2, Chapter 2, section 1 is numbered "2.2.1 ".

Scope For the purposes of Article 2 paragraph 2 (a) and Article 4 of ADN, the annexed Regulations specify: (a)

dangerous goods which are barred from international carriage;

(b)

dangerous goods which are authorized for international carriage and the conditions attaching to them (including exemptions) particularly with regard to: -

classification of goods, including classification criteria and relevant test methods;

-

use of packagings (including mixed packing);

-

use of tanks (including filling);

-

consignment procedures (including marking and labelling of packages and placarding and marking of means of transport embarked, the marking of vessels as well as documentation and information required);

-

provisions concerning the construction, testing and approval of packagings and tanks;

-

use of means of transport (including loading, mixed loading and unloading).

For the purposes of Article 5 of ADN, section 1.1.3 of this chapter specifies the cases in which the carriage of dangerous goods is partially or totally exempted from the conditions of carriage established by ADN. For the purposes of Article 7 of ADN, Chapter 1.5 of this part specifies the rules concerning the derogations, special authorizations and equivalences for which that article provides. For the purposes of Article 8 of ADN, Chapter 1.6 of this part specifies the transitional measures concerning the application of the Regulations annexed to ADN. The provisions of this part also apply to empty vessels or vessels which have been unloaded as long as the holds, cargo tanks or receptacles or tanks accepted on board are not free from dangerous substances or gases, except for the exemptions for which section 1.1.3 of this chapter provides.

1.1.3 1.1.3.1

Exemptions

Exemptions related to the nature of the transport operation The provisions laid down in ADN do not apply to: the carriage of dangerous goods by private individuals where the goods in question are packaged for retail sale and are intended for their personal or domestic use or for their leisure or sporting activities provided that measures have been taken to prevent any leakage of contents in normal conditions of carriage. Dangerous goods in IBCs, large packagings or tanks are not considered to be packaged for retail sale; the carriage of machinery or equipment not specified in these annexed Regulations and which happen to contain dangerous goods in their internal or operational equipment, provided that measures have been taken to prevent any leakage of contents in normal conditions of carriage; the carriage undertaken by enterprises which is ancillary to their main activity, such as deliveries to or returns from building or civil engineering sites, or in relation to surveying, repairs and maintenance, in quantities of not more than 450 litres per packaging and within the maximum quantities specified in 1.1.3.6. Measures shall be taken to prevent any leakage of contents in normal conditions of carriage. These exemptions do not apply to Class 7. Carriage undertaken by such enterprises for their supply or external or internal distribution does not fall within the scope of this exemption; the carriage undertaken by, or under the supervision of, the emergency services, insofar as such carriage is necessary in relation to the emergency response, in particular carriage undertaken to contain and recover the dangerous goods involved in an incident or accident and move them to a safe place; emergency transport under the supervision of the competent authorities intended to save human lives or protect the environment provided that all measures are taken to ensure that such transport is carried out in complete safety; the carriage of uncleaned empty static storage vessels which have contained gases of Class 2, groups A, 0 or F, substances of Class 3 or Class 9 belonging to packing group I1 or I11 or pesticides of Class 6.1 belonging to packing group I1 or 111, subject to the following conditions: All openings with the exception of pressure relief devices (when fitted) are hermetically closed; Measures have been taken to prevent any leakage of contents in normal conditions of carriage; and The load is fixed in cradles or crates or other handling devices or to the vehicle, container or vessel in such a way that they will not become loose or shift during normal conditions of carriage. This exemption does not apply to static storage vessels which have contained desensitized explosives or substances the carriage of which is prohibited by ADN. NOTE: For radioactive material see 2.2.7.1.2.

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Exemptions related to the carriage of gases The provisions laid down in ADN do not apply to the carriage of: (a)

(Reserved);

(b)

(Reserved);

(c)

gases of Groups A and 0 (according to 2.2.2.1), if the pressure of the gas in the receptacle or tank at a temperature of 15" C does not exceed 200 kPa (2 bar) and if the gas is completely in the gaseous state during carriage. This includes every kind of receptacle or tank, e.g. also parts of machinery and apparatus;

(d)

gases contained in the equipment used for the operation of the vessel;

(e)

(Reserved);

(f)

gases contained in foodstuffs or beverages.

Exemptions related to substances used for the propulsion of vessels, vehicles or wagons carried,for the operation of their special equipment,for their upkeep or for the safety. The requirements of ADN do not apply to substances used for the propulsion of vessels or the vehicles carried, for the operation of their special equipment, for their upkeep or to ensure safety, which are carried on board in the packaging, receptacle or tanks intended for use for this purpose. Exemptions related to special provisions or to dangerous goods packed in limited quantities NOTE: For radioactive material see 2.2.7.1.2. 1.1.3.4.1

Certain special provisions of Chapter 3.3 exempt partially or totally the carriage of specific dangerous goods from the requirements of ADN. The exemption applies when the special provision is referred to in Column (6) of Table A of Chapter 3.2 against the dangerous goods entry concerned.

1.1.3.4.2

Certain dangerous goods packed in limited quantities may be subject to exemptions provided that the conditions of Chapter 3.4 are met.

1.1.3.5

Exemptions related to empty uncleaned packagings Empty uncleaned packagings (including IBCs and large packagings) which have contained substances of Classes 2, 3, 4.1, 5.1, 6.1, 8 and 9 are not subject to the conditions of ADN if adequate measures have been taken to nullify any hazards. Hazards are nullified if adequate measures have been taken to nullify all hazards of Classes 1 to 9.

1.1.3.6

Exemptions related to quantities carried on board vessels

1.1.3.6.1

(a)

In the event of the carriage of dangerous goods in packages, the provisions of ADN other than those of 1.1.3.6.2 are not applicable when the gross mass of all the dangerous goods carried does not exceed 3,000 kg. This provision does not apply to the carriage of: (i)

substances and articles of Class 1;

(ii)

substances of Class 2, groups T, F, TF, TC, TO, TFC or TOC, according to 2.2.2.1.3 and aerosols of groups C, CO, F, FC, T, TF, TC, TO, TFC and TOC according to 2.2.2.1.6;

(iii) substances of Classes 4.1 or 5.2. for which a danger label of model No. 1 is required in column (5) of Table A of Chapter 3.2; (iv)

substances of Class 6.2, Group A;

(v)

substances of Class 7 other than UN Nos. 2908,2909,2910 and 291 1;

(vi) substances assigned to Packing Group I; (vii) substances carried in tanks; (b)

In the event of the carriage of dangerous goods in packages other than tanks (tankcontainers, tank vehicles, etc.), the provisions of ADN other than those of 1.1.3.6.2 are not applicable to the carriage of:

-

substances of Class 2 of group F in accordance with 2.2.2.1.3 or aerosols of group F according to 2.2.2.1.6; or

- substances assigned to Packing Group I, except substances of Class 6.1 when the gross mass of these goods does not exceed 300 kg. 1.1.3.6.2

The carriage of exempted quantities according to 1.1.3.6.1 is, however, subject to the following conditions: (a)

The obligation to report in accordance with 1.8.5 remains applicable;

(b)

Packages, except vehicles and containers (including swap bodies), shall comply with the requirements for packagings referred to in Parts 4 and 6 of ADR or RID; the provisions of Chapter 5.2 concerning marking and labelling are applicable;

(c)

The following documents shall be on board:

-

the transport documents (see 5.4.1.1); they shall concern all the dangerous goods carried on board;

- the stowage plan (see 7.1.4.1 1.1); (d)

The goods shall be stowed in the holds. This provision does not apply to goods loaded in:

- containers with complete spray-proof walls; -

(e)

vehicles with complete spray-proof walls;

Goods of different class shall be separated by a minimum horizontal distance of 3 m. They shall not be stowed on top of each other. This provision does not apply to:

- containers with complete metal walls; - vehicles with complete metal walls; (f)

For seagoing and inland navigation vessels, where the latter carry only containers, the above requirements under (d) and (e) shall be considered to have been met if the

provisions of the IMDG Code regarding stowage and separation are met and if this particular is recorded in the transport document. Applicability of other regulations General The following requirements are applicable to packages: (a)

in the case of packagings (including large packagings and intermediate bulk containers (IBCs), the applicable requirements of one of the international regulations shall be met (see also Part 4 and Part 6 of these Regulations);

(b)

in the case of containers, tank-containers, portable tanks and multiple element gas containers (MEGCs), the applicable requirements of ADR, RID or the IMDG Code shall be met (see also Part 4 and Part 6 of these Regulations);

c)

in the case of vehicles or wagons, the vehicles or wagons and their load shall meet the applicable requirements of ADR or of RID, as relevant.

NOTE: For the marking, labelling, placarding and orange plate marking, see also Chapters 5.2 and 5.3. 1.1.4.2

Carriage in a transport chain including maritime, road, rail or air carriage

1.1.4.2.1

Packages, containers, portable tanks and tank-containers, which do not entirely meet the requirements for packing, mixed packing, marking, labelling of packages or placarding and orange plate marking, of ADN, but are in conformity with the requirements of the IMDG Code or the ICAO Technical Instructions shall be accepted for carriage in a transport chain including maritime or air carriage subject to the following conditions: (a)

If the packages are not marked and labelled in accordance with ADR, they shall bear markings and danger labels in accordance with the requirements of the IMDG Code or the ICAO Technical Instructions;

(b)

The requirements of the IMDG Code or the ICAO Technical Instructions shall be applicable to mixed packing within a package;

(c)

For carriage in a transport chain including maritime carriage, if the containers, portable tanks or tank-containers are not marked and placarded in accordance with Chapter 5.3 of this Annex, they shall be marked and placarded in accordance with Chapter 5.3 of the IMDG Code. In such case, only 5.3.2.1.1 of this Annex is applicable to the marking of the vehicle itself. For empty, uncleaned portable tanks and tank-containers, this requirement shall apply up to and including the subsequent transfer to a cleaning station.

This derogation does not apply in the case of goods classified as dangerous goods in classes 1 to 9 of ADN and considered as non-dangerous goods according to the applicable requirements of the IMDG Code or the ICAO Technical Instructions. 1.1.4.2.2

When a maritime, road, rail or air transport operation follows or precedes carriage by inland waterway, the transport document used or to be used for the maritime, road, rail or air transport operation may be used in place of the transport document prescribed in 5.4.1 provided that the particulars it contains are in conformity with the applicable requirements of the IMDG Code, ADR, RID or the ICAO Technical Instructions, respectively except that,

when additional information is required by ADN, it shall be added or entered at the appropriate place. NOTE: For carriage in accordance with 1.1.4.2.1, see also 5.4.1.1.7. For carriage in containers, see also 5.4.2.

1.1.4.3

(Reserved).

1.1.4.4

(Reserved).

1.1.4.5

(Reserved).

1.1.4.6

Other regulations applicable to carriage by inland waterway

1.1.4.6.1

In accordance with article 9 of the Agreement, transport operations shall remain subject to the local, regional or international requirements generally applicable to the carriage of goods by inland waterway.

1.1.4.6.2

Where the requirements of these Regulations are in contradiction with the requirements referred to in 1.1.4.6.1, the requirements referred to in 1.1.4.6.1 shall not apply.

CHAPTER 1.2 DEFINITIONS AND UNITS OF MEASUREMENT Definitions

NOTE: This section contains all general or specific de$nitions. For the purposes of these regulations:

Accommodation means spaces intended for the use of persons normally living on board, including galleys, food stores, lavatories, washrooms, bathrooms, laundries, halls, alleyways, etc., but excluding the wheelhouse; ADR means the European Agreement concerning the International Carriage of Dangerous Goods by Road;

Aerosol, see Aerosol dispenser; Aerosol dispenser means any non-refillable receptacle meeting the requirements of 6.2.4 of ADR or of RID made of metal, glass or plastics, and containing a gas, compressed, liquefied or dissolved under pressure, with or without a liquid, paste or powder, and fitted with a release device allowing the contents to be ejected as solid or liquid particles in suspension in a gas, as a foam, paste or powder or in a liquid state or in a gaseous state; ASTM means the American Society for Testing and Materials (ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA, 19428-2959, United States of America); Auto-ignition temperature (EN 1127-1:1997, No. 331) means the lowest temperature determined under prescribed test conditions of a hot surface on which a flammable substance in the form of a gadair or vapoudair mixture ignites.

Bag means a flexible packaging made of paper, plastics film, textiles, woven material or other suitable material; Battery-vehicle means a vehicle containing elements which are linked to each other by a manifold and permanently fixed to a transport unit. The following elements are considered to be elements of a battery-vehicle: cylinders, tubes, bundles of cylinders (also known as frames), pressure drums as well as tanks destined for the carriage of gases of Class 2 with a capacity of more than 450 litres; Battery-wagon means a wagon containing elements which are linked to each other by a manifold and permanently fixed to a wagon. The following elements are considered to be elements of a battery wagon: cylinders, tubes, bundles of cylinders (also known as frames), pressure drums as well as tanks intended for gases of Class 2 with a capacity greater than 450 litres; BC Code means the Code of Safe Practice for Solid Bulk Cargoes of the International Maritime Organization (IMO);

Bilge water means oily water from the engine room bilges, the peak, the cofferdams and the double-hull spaces; Biological/technical name means a name currently used in scientific and technical handbooks, journals and texts. Trade names shall not be used for this purpose; Body (for all categories of IBC other than composite IBCs) means the receptacle proper, including openings and closures, but does not include service equipment; Box means a packaging with complete rectangular or polygonal faces, made of metal, wood, plywood, reconstituted wood, fibreboard, plastics or other suitable material. Small holes for purposes of ease of handling or opening or to meet classification requirements, are permitted as long as they do not compromise the integrity of the packaging during carriage; Breathing apparatus (ambient air-dependent) means an apparatus which protects the person wearing it when working in a dangerous atmosphere by means of a suitable filter; Bulk containers means containment systems (including any liner or coating) intended for the carriage of solid substances which are in direct contact with the containment system. Packagings, intermediate bulk containers (IBCs), large packagings and tanks are not included. Bulk containers are:

-

of a permanent character and accordingly strong enough to be suitable for repeated use; specially designed to facilitate the carriage of goods by one or more modes of carriage without intermediate reloading; fitted with devices permitting its ready handling; of a capacity of not less than 1.0 m3 Examples of bulk containers are containers, offshore bulk containers, skips, bulk bins, swap bodies, trough-shaped containers, roller containers, load compartments of wagons/vehicles;

Bulkhead means a metal wall, generally vertical, inside the vessel and which is bounded by the bottom, the side plating, a deck, the hatchway covers or by another bulkhead; Bulkhead (watertight) means -

in a tank vessel: a bulkhead constructed to withstand a water pressure of 1.00 metre above the deck;

-

in a dry cargo vessel: a bulkhead constructed so that it can withstand water pressure with a head of 1.00 metre above the deck but at least to the top of the hatchway coaming;

Bundle of cylinders frame) means an assembly of cylinders that are fastened together and are interconnected by a manifold and carried as a unit. The total water capacity shall not exceed 3,000 litres except that bundles intended for the carriage of toxic gases of Class 2 (groups starting with letter T according to 2.2.2.1.3) shall be limited to 1,000 litres water capacity.

Capacity of shell or shell compartment, for tanks, means the total inner volume of the shell or shell compartment expressed in litres or cubic metres. When it is impossible to completely fill the shell or the shell compartment because of its shape or construction, this reduced capacity shall be used for the determination of the degree of filling and for the marking of the tank; Cargo area means the whole of the following spaces (see figures below); Cargo area I

Cargo area above deck additional part

p p

Cofferdam vent openings

Cofferdam vent openings

-

.....................

Deck boundary of the cargo area part below deck

1

Deck boundary of the cargo area part below deck

Above deck cargo area for various tank vessel Tank vessels with deck formed by the top of tanks

Tank vessels with trunk-deck

Tank vessels with independant cargo tanks

/

Y Tank

Tank

Cargo area (additional part above deck) (When anti-explosion protection is required, comparable to zone I) means the spaces not included in the main part of cargo area above deck comprising 1.00 m radius spherical segments centred over the ventilation openings of the cofferdams and the service spaces located in the cargo area part below the deck and 2.00 m spherical segments centred over the ventilation openings of the cargo tanks and the opening of the pump-rooms; Cargo area (main part above deck) (When anti-explosion protection is required comparable to zone I) means the space which is bounded: -

at the sides, by the shell plating extending upwards from the decks sides;

-

fore and aft, by planes inclined at 45' towards the cargo area, starting at the boundary of the cargo area part below deck;

-

vertically, 3.00 m above the deck;

Cargo area (part below deck) means the space between two vertical planes perpendicular to the centre-line plane of the vessel, which comprises cargo tanks, hold spaces, cofferdams, double-hull spaces and double bottoms; these planes normally coincide with the outer cofferdam bulkheads or hold end bulkheads. Their intersection line with the deck is referred to as the boundary of the cargo area part below deck; Cargo piping, see Pipes for loading and unloading; Cargo pump-room (When anti-explosion protection is required, comparable to zone 1 - see Classijication of zones) means a service space where the cargo pumps and stripping pumps are installed together with their operational equipment; Cargo residues means liquid cargo which remain in the cargo tank or cargo piping after discharging or stripping; Cargo tank (When anti-explosion protection is required, comparable to zone 0) means a tank which is permanently attached to the vessel and the boundaries of which are either formed by the hull itself or by walls separate from the hull and which is intended for the carriage of dangerous goods; Cargo tank (condition) discharged : empty, but containing residual cargo; : dry, but not gas-free; empty gas-free : not containing any measurable concentration of dangerous gases or vapours; Carriage means the change of place of dangerous goods, including stops made necessary by transport conditions and including any period spent by the dangerous goods in vessels, vehicles, tanks and containers made necessary by traffic conditions before, during and after the change of place. This definition also covers the intermediate temporary storage of dangerous goods in order to change the mode or means of transport (transshipment). This shall apply provided that transport documents showing the place of dispatch and the place of reception are presented on request and provided that packages and tanks are not opened during intermediate storage, except to be checked by the competent authorities; Carriage in bulk means the carriage of an unpackaged solid which can be discharged; NOTE: Within the meaning of ADN, the carriage in bulk referred to in ADR is considered as carriage in packages.

Carrier means the enterprise which carries out the transport operation with or without a transport contract; Certijied safe type electrical apparatus means an electrical apparatus which has been tested and approved by the competent authority regarding its safety of operation in an explosive atmosphere, e.g. -

intrinsically safe apparatus;

-

flameproof enclosure apparatus;

-

apparatus protected by pressurization;

-

powder filling apparatus;

-

apparatus protected by encapsulation;

-

increased safety apparatus.

NOTE: Limited explosion risk apparatus is not covered by this definition. CEVNI means the UNECE European Code for Inland Waterways; CGA means the Compressed Gas Association (CGA, 4221 Walney Road, 5th Floor, Chantilly VA 2015 1-2923, United States of America); Classijication society (recognized) means a classification society which is recognized by the competent authorities in accordance with Chapter 1.15; ClassiJicationof zones (see IEC publication 79-10) Zone 0:

areas in which dangerous explosive atmospheres of gases, vapours or sprays exist permanently or during long periods;

Zone 1:

areas in which dangerous explosive atmospheres of gases, vapours or sprays are likely to occur occasionally;

Zone 2:

areas in which dangerous explosive atmospheres of gases, vapours or sprays are likely to occur rarely and if so for short periods only;

Closed container means a totally enclosed container having a rigid roof, rigid side walls, rigid end walls and a floor. The term includes containers with an opening roof where the roof can be closed during transport; Closed-type sampling device means a device penetrating through the boundary of the cargo tank but constituting a part of a closed system designed so that during sampling no gas or liquid may escape from the cargo tank. The device shall be of a type approved by the competent authority for this purpose; Closed vehicle means a vehicle having a body capable of being closed; Closure means a device which closes an opening in a receptacle; Cofferdam (when anti-explosion protection is required, comparable to zone 1) means an athwartship compartment which is bounded by watertight bulkheads and which can be inspected. The cofferdam shall extend over the whole area of the end bulkheads of the cargo tanks. The bulkhead not facing the cargo area shall extend from one side of the vessel to the other and from the bottom to the deck in one frame plane; Collective entry means an entry for a well-defined group of substances or articles (see 2.1.1.2, B, C and D); Combination packaging means a combination of packagings for transport purposes, consisting of one or more inner packagings secured in an outer packing in accordance with 4.1 . l .5 of ADR;

NOTE: The "inners" of "Combination packagings are always termed "inner packagings " and not "inner receptacles". A glass bottle is an example of such an "inner packaging ". "

Common vapourpiping means a pipe connecting two or more cargo tanks. This pipe is fitted with safety valves which protect cargo tanks against unacceptable internal overpressures or vacuums; it is intended to evacuate gases and vapours to the shore facility; Compensation piping means a pipe of the shore facility which is connected during the unloading to the vessel's common vapour pipe or gas return piping. This pipe is designed so as to protect the vessel against detonations or the passage of flames from the shore side; Competent authority means the authority or authorities or any other body or bodies designated as such in each State and in each specific case in accordance with domestic law; Compliance assurance (radioactive material) means a systematic programme of measures applied by a competent authority which is aimed at ensuring that the requirements of ADN are met in practice; Composite IBC with plastics inner receptacle means an IBC comprising structural equipment in the form of a rigid outer casing encasing a plastics inner receptacle together with any service or other structural equipment. It is so constructed that the inner receptacle and outer casing once assembled form, and are used as, an integrated single unit to be filled, stored, transported or emptied as such;

NOTE: Plastics, when used in connection with inner receptacles for composite IBCs, is taken to include other polymeric materials such as rubber, etc. Composite packaging (plastics material) is a packaging consisting of an inner plastics receptacle and an outer packaging (made of metal, fibreboard, plywood, etc.). Once assembled such a packaging remains thereafter an inseparable unit; it is filled, stored, despatched and emptied as such;

NOTE: See NOTE under Composite packagings (glass, porcelain or stoneware). Composite packaging (glass, porcelain or stoneware) is a packaging consisting of an inner glass, porcelain or stoneware receptacle and an outer packaging (made of metal, wood, fibreboard, plastics material, expanded plastics material, etc.). Once assembled, such a packaging remains thereafter an inseparable unit; it is filled, stored, despatched and emptied as such;

NOTE: The "inners" of "composite packagings " are normally termed "inner receptacles". For example, the "inner" of a 6HAI (composite packaging, plastics material) is such an "inner receptacle" since it is normally not designed to perform a containment function without its "outer packaging" and is not therefore an "inner packaging". Consignee means the consignee according to the contract for carriage. If the consignee designates a third party in accordance with the provisions applicable to the contract for carriage, this person shall be deemed to be the consignee within the meaning of ADN. If the transport operation takes place without a contract for carriage, the enterprise which takes charge of the dangerous goods on arrival shall be deemed to be the consignee; Consignment means any package or packages, or load of dangerous goods, presented by a consignor for carriage;

Consignor means the enterprise which consigns dangerous goods either on its own behalf or for a third party. If the transport operation is carried out under a contract for carriage, consignor means the consignor according to the contract for carriage. In the case of a tank vessel, when the cargo tanks are empty or have just been unloaded, the master is considered to be the consignor for the purpose of the transport document; Design pressure means the pressure on the basis of which the cargo tank or the residual cargo tank has been designed and built; Container means an article of transport equipment (lift van or other similar structure): -

of a permanent character and accordingly strong enough to be suitable for repeated use;

-

specially designed to facilitate the carriage of goods, by one or more means of transport, without breakage of load;

-

fitted with devices permitting its ready stowage and handling, particularly when being transloaded from one means of transport to another;

-

so designed as to be easy to fill and empty (see also Closed container, Large container, Open container, Sheeted container and Small container);

A swap body is a container which, in accordance with European Standard EN 283 (1991 edition) has the following characteristics: -

from the point of view of mechanical strength, it is only built for carriage on a wagon or a vehicle on land or by roll-on roll-off ship;

-

it cannot be stacked;

-

it can be removed from vehicles by means of equipment on board the vehicle and on its own supports, and can be reloaded;

NOTE: The term "container" does not cover conventional packagings, IBCs, tankcontainers or vehicles. Control temperature means the maximum temperature at which an organic peroxide or a self-reactive substance can be safely carried; Conveyance means, with respect to the carriage by inland waterway, any vessel, hold or defined deck area of any vessel; for carriage by road or by rail, it means a vehicle or a wagon; Crate means an outer packaging with incomplete surfaces; Critical temperature means the temperature above which the substance cannot exist in the liquid state; Cryogenic receptacle means a transportable thermally insulated receptacle for refrigerated liquefied gases of a water capacity of not more than 1,000 litres; CSC means the International Convention for Safe Containers (Geneva, 1972) as amended and published by the International Maritime Organization (IMO), London;

Cylinder means a transportable pressure receptacle of a water capacity not exceeding 150 litres (see also Bundle of cylinders Cframe));

Damage control plan means the plan indicating the boundaries of the watertight compartments serving as the basis for the stability calculations, in the event of a leak, the trimming arrangements for the correction of any list due to flooding and the means of closure which are to be kept closed when the vessel is under way; Damage stability plan means a plan indicating the water-tight subdivisions serving as the basis for the stability calculations, the arrangements necessary to offset a list caused by water penetration and all closing appliances which are to be kept closed during the voyage. These closing appliances shall be appropriately indicated; Dangerous goods means those substances and articles the carriage of which is prohibited by ADN, or authorized only under the conditions prescribed therein; Dangerous reaction means: (a)

combustion or evolution of considerable heat;

(b)

evolution of flammable, asphyxiate, oxidizing or toxic gases;

(c)

the formation of corrosive substances;

(d)

the formation of unstable substances; or

(e)

dangerous rise in pressure (for tanks only);

Dejlagration means an explosion which propagates at subsonic speed (see EN 1127-1:1997); Demountable tank means a tank, other than a fixed tank, a portable tank, a tank-container or an element of a battery-vehicle or a MEGC which has a capacity of more than 450 litres, is not designed for the carriage of goods without breakage of load, and normally can only be handled when it is empty; Detonation means an explosion which propagates at supersonic speed and is characterized by a shock-wave (see EN 1127-1:1997); Drum means a flat-ended or convex-ended cylindrical packaging made out of metal, fibreboard, plastics, plywood or other suitable materials. This definition also includes packagings of other shapes, e.g. round, taper-necked packagings or pail-shaped packagings. Wooden barrels andjerricans are not covered by this definition.

EC Directive means provisions decided by the competent institutions of the European Community and which are binding, as to the result to be achieved, upon each Member State to which it is addressed, but shall leave to the national authorities the choice of form and methods; Emergency temperature means the temperature at which emergency procedures shall be implemented in the event of loss of temperature control;

Electrical apparatus protected against water jets means an electrical apparatus so designed that water, projected by a nozzle on the enclosure from any direction, has no damaging effects. The test conditions are specified in the IEC publication 529, minimum degree of protection IP55; EN (standard) means a European standard published by the European Committee for Standardization (CEN) (CEN - 36 rue de Stassart B-1050 Brussels); Enterprise means any natural person, any legal person, whether profit-making or not, any association or group of persons without legal personality, whether profit-making or not, or any official body, whether it has legal personality itself or is dependent upon an authority that has such personality; Escape device (suitable) means a respiratory protection device, designed to cover the wearer's mouth, nose and eyes, which can be easily put on and which serves to escape from a danger area; Explosion means a sudden reaction of oxidation or decomposition with an increase in temperature or in pressure or both simultaneously (see EN 1127-1:1997); Explosion group (see IECpublication 79 and EN 50 014) means a grouping of flammable gases and vapours according to their maximum experimental safe gaps and minimum ignition currents, and of electrical apparatus which may be used in the corresponding potentially explosive atmosphere.

Fibreboard IBC means a fibreboard body with or without separate top and bottom caps, if necessary an inner liner (but no inner packagings), and appropriate service and structural equipment; Filler means any enterprise

(a)

which fills dangerous goods into a tank (tank-vehicle, demountable tank, portable tank or tank-container) or into a battery-vehicle or MEGC; or

(b)

which fills dangerous goods into a cargo tank; or

(c)

which fills dangerous goods into a vessel, a vehicle, a large container or small container for carriage in bulk;

Filling pressure means the maximum pressure actually built up in the tank when it is being filled under pressure; (see also Calculation pressure, Discharge pressure, Maximum working pressure (gauge pressure) and Test pressure); Filling ratio(cargo tank): Where a filling ratio is given for a cargo tank, it refers to the percentage of the volume of the cargo tank which may be filled with liquid during loading;; Fixed tank means a tank having a capacity of more than 1,000 litres which is permanently attached to a vehicle (which then becomes a tank-vehicle) or is an integral part of the frame of such vehicle; Flame arrester means a device mounted in the vent of part of an installation or in the interconnecting piping of a system of installations, the purpose of which is to permit flow but prevent the propagation of a flame front. This device shall be tested according to the European standard EN 12 874 (1999);

Flame arrester plate stack means the part of the flame arrester the main purpose of which is to prevent the passage of a flame front; Flame arrester housing means the part of a flame arrester the main purpose of which is to form a suitable casing for the flame arrester plate stack and ensure a mechanical connection with other systems; Flammable component (for aerosols and gas cartridges) means a gas which is flammable in air at normal pressure or a substance or a preparation in liquid form which has a flash-point less than or equal to 100 'C; Flammable gas detector means a device allowing measuring of any significant concentration of flammable gases given off by the cargo below the lower explosive limit and which clearly indicates the presence of higher concentrations of such gases. Flammable gas detectors may be designed for measuring flammable gases only but also for measuring both flammable gases and oxygen. This device shall be so designed that measurements are possible without the necessity of entering the spaces to be checked;

Flash-point means the lowest temperature of a liquid at which its vapours form a flammable mixture with air; Flexible IBC means a body constituted of film, woven fabric or any other flexible material or combinations thereof, and if necessary, an inner coating or liner, together with any appropriate service equipment and handling devices; Frame (Class 2), see Bundle of cylinders; Full load means any load originating from one consignor for which the use of a vehicle or of a large container is exclusively reserved and all operations for the loading and unloading of which are carried out in conformity with the instructions of the consignor or of the consignee; NOTE: The corresponding termfop. Class 7 is "exclusive use", see 2.2.7.2.

Gas (for the purposes of Class 2) means a substance which: (a)

at 50" C has a vapour pressure greater than 300 kPa (3 bar); or

(b)

is completely gaseous at 20" C under standard pressure of 101.3 kPa;

Otherwise, Gases means gases or vapours;

Gas cartridge means any non-refillable receptacle containing, under pressure, a gas or a mixture of gases. It may be fitted with a valve; Gas detection system means a fixed system capable of detecting in time significant concentrations of flammable gases given off by the cargoes at concentrations below the lower explosion limit and capable of activating the alarms;

Gas return piping means a pipe connecting a cargo tank to the shore facility during loading. This pipe is fitted with safety valves protecting the cargo tank against unacceptable internal overpressures or vacuums; it is intended to evacuate gases and vapours to the shore facility; GHS means the first revised edition of the Globally Harmonized System of Classification and Labelling of Chemicals, published by the United Nations as document STISGIAC.10/3O/Rev.1;

Handling device (for flexible IBCs) means any sling, loop, eye or frame attached to the body of the IBC or formed from the continuation of the IBC body material; Hermetically closed tank means a tank intended for the carriage of liquid substances with a calculation pressure of at least 4 bar or intended for the carriage of solid substances (powdery or granular) regardless of its calculation pressure, the openings of which are hermetically closed and which:

-

is not equipped with safety valves, bursting discs, other similar safety devices or vacuum valves, or

-

is not equipped with safety valves, bursting discs or other similar safety devices, but is equipped with vacuum valves, in accordance with the requirements of 6.8.2.2.3; of ADR; or

-

is equipped with safety valves preceded by a bursting disc according to 6.8.2.2.10 of ADR, but is not equipped with vacuum valves; or

-

is equipped with safety valves preceded by a bursting disc according to 6.8.2.2.10 of ADR and vacuum valves, in accordance with the requirements of 6.8.2.2.3 of ADR;

Highest class may be assigned to a vessel when: -

the hull, inclusive of rudder and steering gear and equipment of anchors and chains, complies with the rules and regulations of a recognized classification society and has been built and tested under its supervision;

-

the propulsion plant, together with the essential auxiliary engines mechanical and electrical installations, have been made and tested in conformity with the rules and regulations of this classification society, and the installation has been carried out under its supervision, and the complete plant was tested to its satisfaction on completion;

High velocity vent valve means a pressure-reducing valve with a nominal ejection speed greater than the speed of propagation of a flame, thus preventing the passage of a flame front. This type of installation shall be tested in accordance with European standard EN 12 874 (1999); Hold (when anti-explosion protection is required, comparable to zone 1 - see Classzfication of zones) means a part of the vessel which, whether covered by hatchway covers or not, is bounded fore and aft by bulkheads and which is intended to carry goods in packages or in bulk. The upper boundary of the hold is the upper edge of the hatchway coaming. Cargo extending above the hatchway coaming shall be considered as loaded on deck; Hold (condition) discharged:

empty, but containing residual cargo

- 19-

empty:

without residual cargo (swept clean);

Hold space (when anti-explosion protection is required, comparable to zone 1) means an enclosed part of the vessel which is bounded fore and aft by watertight bulkheads and which is intended only to carry cargo tanks independent of the vessel's hull.

IAEA means the International Atomic Energy Agency (IAEA), (IAEA, P.O. Box 100 - A1400 Vienna); IBC see Intermediate bulk container; ICAO means the International Civil Aviation Organization (ICAO, 999 University Street, Montreal, Quebec H3C 5H7, Canada); ICAO Technical Instructions means the Technical Instructions for the Safe Transport of Dangerous Goods by Air, which complement Annex 18 to the Chicago Convention on International Civil Aviation (Chicago 1944) published by the International Civil Aviation Organization (ICAO) in Montreal; Identification number means the number for identifying a substance to which no UN number has been assigned or which cannot be classified under a collective entry with a UN number. These numbers have four figures beginning with 9;

IEC means The International Electro technical Commission; IMDG Code means the International Maritime Dangerous Goods Code, for the implementation of Chapter VII, Part A, of the International Convention for the Safety of Life at Sea, 1974 (SOLAS Convention), published by the International Maritime Organization (IMO), London; IMO means the International Maritime Organization (IMO, 4 Albert Embankment, London SE l 7SR, United Kingdom); Independent cargo tank (when anti-explosion protection is required, comparable to zone 0) means a cargo tank which is permanently built in, but which is independent of the vessel's structure; Inner packaging means a packaging for which an outer packaging is required for carriage; Inner receptacle means a receptacle which requires an outer packaging in order to perform its containment function; Instruction means transmitting know-how or teaching how to do something or how to act. This transmission or teaching may be dispensed internally by the personnel; Intermediate bulk container (IBC) means a rigid, or flexible portable packaging, other than those specified in Chapter 6.1, that: (a)

has a capacity of (i)

not more than 3 m3 for solids and liquids of packing groups I1 and 111;

(ii)

not more than 1.5 m3 for solids of packing group I when packed in flexible, rigid plastics, composite, fibreboard and wooden IBCs;

(iii)

not more than 3 m3for solids of packing group I when packed in metal IBCs;

(iv)

not more than 3 m3for radioactive material of Class 7;

(b)

is designed for mechanical handling;

(c)

is resistant to the stresses produced in handling and transport as determined by the tests specified in Chapter 6.5 of ADR (see also Composite IBC with plastics inter receptacle, Fibreboard IBC, Flexible IBC, Metal IBC, Rigid plastics IBC and Wooden IBC);

NOTE 1: Portable tanks or tank-containers that meet the requirements of Chapter 6.7 or 6.8 of ADR respectively are not considered to be intermediate bulk containers (IBCs). NOTE 2: Intermediate bulk containers (IBCs) which meet the requirements of Chapter 6.5 of ADR are not considered to be containersfor the purposes of ADR. Intermediate packaging means a packaging placed between inner packagings or articles and an outer packaging; International regulations means ADR, BC Code, ICAO-TI, IMDG Code or RID. I S 0 (standard) means an international standard published by the International Organization for Standardization (ISO) (ISO-l , rue de Varembe - CH- 1204 Geneva 20);

Jerrican means a metal or plastics packaging of rectangular or polygonal cross-section with one or more orifices.

Large container means: (a)

a container having an internal volume of more than 3 m3;

(b)

in the meaning of the CSC, a container of a size such that the area enclosed by the four outer bottom corners is either

(i)

at least 14 m2 (150 square feet) or

(ii)

at least 7 m2 (75 square feet) if fitted with top corner fittings;

NOTE: For radioactive material see 2.2.7.1.2. Large packaging means a packaging consisting of an outer packaging which contains articles or inner packagings and which: (a)

is designed for mechanical handling;

(b)

exceeds 400 kg net mass or 450 litres capacity but has a volume of not more than 3 m3:

Light-gauge metal packaging means a packaging of circular, elliptical, rectangular or polygonal cross-section (also conical) and taper-necked and pail-shaped packaging made of metal, having a wall thickness of less than 0.5 mm (e.g. tinplate), flat or convex bottomed and with one or more orifices, which is not covered by the definitions for drums or jerricans; Limited explosion risk electrical apparatus means an electrical apparatus which, during normal operation, does not cause sparks or exhibits surface temperatures which are above the required temperature class, including e.g.: -

three-phase squirrel cage rotor motors;

-

brushless generators with contactless excitation;

-

fuses with an enclosed fuse element;

-

contactless electronic apparatus;

or means an electrical apparatus with an enclosure protected against water jets (degree of protection IP55) which during normal operation does not exhibit surface temperatures which are above the required temperature class;

Liner means a tube or bag inserted into a packaging, including large packagings or IBCs, but not forming an integral part of it, including the closures of its openings; Liquid means a substance which at 50" C has a vapour pressure of not more than 300 kPa (3 bar) which is not completely gaseous at 20" C and 101.3 kPa, and which: -

has a melting point or initial melting point of 20" C or less at a pressure of 101.3 kPa, or

-

is liquid according to the ASTM D 4359-90 test method or

-

is not pasty according to the criteria applicable to the test for determining fluidity (penetrometer test) described in 2.3.4;

NOTE: "Carriage in the liquid state" for the purpose of tank requirements means. -

Carriage of liquids according to the above definition, or

-

Solids handed over for carriage in the molten state;

Loader means any enterprise which loads dangerous goods into a vessel; Loading journal means a journal where all activities relating to loading, unloading, cleaning, gas-freeing, delivering washing water and taking in and discharging ballast water (in cargo tanks) are recorded.

Manual of Tests and Criteria means the fourth revised edition of the United Nations Model Regulations on the Transport of Dangerous Goods, Manual of Tests and Criteria, published by the UnitedNations Organization (ST/SGlAC.lO/11/Rev.4 as amended by document STISGIAC.1011liRev.4lAmend. l); Mass of package means gross mass of the package unless otherwise stated. The mass of containers and tanks used for the carriage of goods is not included in the gross mass;

Master means a person as defined in Article 1.02 of the European Code for Inland Waterways (CEVNI); Maximum capacity means the maximum inner volume of receptacles or packagings including intermediate bulk containers (IBCs) and large packagings expressed in cubic metres or litres; Maximum net mass means the maximum net mass of contents in a single packaging or maximum combined mass of inner packagings and the contents thereof expressed in kilograms; Maximum permissible gross mass, means (a)

(for all categories of IBCs other than flexible IBCs) means the mass of the IBC and any service or structural equipment together with the maximum net mass;

(b)

(for tanks) means the tare of the tank and the heaviest load authorized for carriage;

NOTE: For portable tanks, see Chapter 6.7 of ADR. Maximum permissible load (for flexible IBCs) means the maximum net mass for which the IBC is intended and which it is authorized to carry; Maximum working pressure means the maximum pressure occurring in a cargo tank or a residual cargo tank during operation. This pressure equals the opening pressure of high velocity vent valves; MEGC, see Multiple-element gas container; Metal IBC means a metal body together with appropriate service and structural equipment; Multiple-element gas container (MEGC) means a unit containing elements which are linked to each other by a manifold and mounted on a frame. The following elements are considered to be elements of a multiple-element gas container: cylinders, tubes, pressure drums and bundles of cylinders as well as tanks for the carriage of gases of Class 2 having a capacity of more than 450 litres.

NOTE: For UN MEGCs, see Chapter 6.7 of ADR.

Naked light means a source of light using a flame which is not enclosed in a flameproof enclosure. Nominal capacity of the receptacle means the nominal volume of the dangerous substance contained in the receptacle expressed in litres. For compressed gas cylinders the nominal capacity shall be the water capacity of the cylinder; N.O.S. entry (not otherwise specified entry) means a collective entry to which substances, mixtures, solutions or articles may be assigned if they: (a)

are not mentioned by name in Table A of Chapter 3.2, and

(b)

exhibit chemical, physical andfor dangerous properties corresponding to the Class, classification code, packing group and the name and description of the n.0.s. entry;

Not readilyflammable means a material which is not in itself readily flammable or whose outer surface at least is not readily flammable and limits the propagation of a fire to an appropriate degree. In order to determine flammability, the IMO procedure, Resolution A.653(16), or any equivalent requirements of a Contracting State are recognized;

Oflshore bulk container means a bulk container specially designed for repeated use for carriage to, from and between offshore facilities. An offshore bulk container is designed and constructed in accordance with the guidelines for the approval of offshore containers handled in open seas specified by the International Maritime Organization (IMO) in document MSCICirc.860; Oil separator vessel means an open type N tank-vessel with a dead weight of up to 300 tonnes, constructed and fitted to accept and carry oily and greasy wastes from the operation of vessels. Vessels without cargo tanks are considered to be subject to Chapters 9.1 or 9.2; Oily and greasy wastes from the operation of the vessel means used oils, bilge water and other oily or greasy wastes, such as used grease, used filters, used rags, and receptacles and packagings for such wastes; Open container means an open top container or a platform based container; Open vehicle means a vehicle the platform of which has no superstructure or is merely provided with side boards and a tailboard; Opening pressure means the pressure referred to in a list of substances at which the high velocity vent valves open. For pressure tanks the opening pressure of the safety valve shall be established in accordance with the requirements of the competent authority or a recognized classification society; Outer packaging means the outer protection of the composite or combination packaging together with any absorbent materials, cushioning and any other components necessary to contain and protect inner receptacles or inner packagings; Overpack means an enclosure used (by a single consignor in the case of Class 7 ) to contain one or more packages, consolidated into a single unit easier to handle and stow during carriage; Examples of overpacks: (a)

a loading tray such as a pallet, on which several packages are placed or stacked and secured by a plastics strip, shrink or stretch wrapping or other appropriate means; or

(b)

an outer protective packaging such as a box or a crate;

NOTE: For radioactive material, see the deJinition of containment system in 2.2.7.2.

Oxygen meter means a device allowing measuring of any significant reduction of the oxygen content of the air. Oxygen meters may either be a device for measuring oxygen only or part of a combination device for measuring both flammable gas and oxygen.

This device shall be so designed that measurements are possible without the necessity of entering the spaces to be checked.

Package means the complete product of the packing operation, consisting of the packaging or large packaging or IBC and its contents prepared for dispatch. The term includes receptacles for gases as defined in this section as well as articles which, because of their size, mass or configuration may be carried unpackaged or carried in cradles, crates or handling devices. On board vessels, the term also includes vehicles, containers (including swap bodies), tankcontainers, portable tanks, battery-vehicles, tank vehicles and multiple element gas containers (MECGs). The term does not apply to goods which are carried in bulk in the holds of vessels, nor to substances carried in tanks in tank vessels. NOTE: For radioactive material, see 2.2.7.2.

Packaging means the receptacle and any other components or materials necessary for the receptacle to perform its containment function (see also Combination packaging, Composite packaging (plastics material), Composite packaging (glass, porcelain or stoneware), Inner packaging, Intermediate bulk container (IBC), Intermediate packaging, Large packaging, Light-gauge metal packaging, Outer packaging, Reconditionedpackaging, Remanufactured packaging, Reused packaging, Salvagepackaging and Sift-proof packaging); NOTE: For radioactive material, see 2.2.7.2.

Packer means any enterprise which puts dangerous goods into packagings, including large packagings and intermediate bulk containers (IBCs) and, where necessary, prepares packages for carriage; Packing group means a group to which, for packing purposes, certain substances may be assigned in accordance with their degree of danger. The packing groups have the following meanings which are explained more fully in Part 2: Packing group I : Packing group I1 : Packing group I11 :

Substances presenting high danger; Substances presenting medium danger; and Substances presenting low danger;

NOTE: Certain articles containing dangerous goods are assigned to a packing group.

Partly closed sampling device means a device penetrating through the boundary of the cargo tank such that during sampling only a small quantity of gaseous or liquid cargo can escape into the open air. As long as the device is not used it shall be closed completely. The device shall be of a type approved by the competent authority for this purpose; Pipes for loading or unloading (cargo piping) means all pipes which may contain liquid or gaseous cargo, including the connected pumps, filters and closure devices; Portable tank means a multimodal tank having, when used for the carriage of Class 2 substances, a capacity of more than 450 litres in accordance with the definitions in Chapter 6.7 of ADR or the IMDG Code and indicated by a portable tank instruction (T-Code) in Column (10) of Table A of Chapter 3.2 of ADR;

Portable tank operator, see Tank-container/portable tank operator; Pressure drum means a welded, transportable pressure receptacle of a water capacity exceeding 150 litres and of not more than 1,000 litres (e.g. cylindrical receptacles equipped with rolling hoops, spheres on skids); Pressure relief device means a spring-loaded device which is activated automatically by pressure the purpose of which is to protect the cargo tank against unacceptable excess internal pressure; Pressure receptacle means a collective term that includes cylinders, tubes, pressure drums, closed cryogenic receptacles and bundles of cylinders; Pressures For tanks, all kinds of pressures (e.g. working pressure, opening pressure of the high velocity vent valves, test pressure) shall be expressed as gauge pressures in kPa (bar); the vapour pressure of substances, however, shall be expressed as an absolute pressure in kPa (bar); Pressure tank means a tank designated and approved for a working pressure 2 400 kPa (4 bar). Pressurized gas cartridge, see Aerosol dispenser; Protected area means (a)

the hold or holds (when anti-explosion protection is required, comparable to zone 1);

(b)

the space situated above the deck (when anti-explosion protection is required, comparable to zone 2), bounded: (i)

athwartships, by vertical planes corresponding to the side plating;

(ii)

fore and aft, by vertical planes corresponding to the end bulkheads of the hold; and

(iii)

upwards, by a horizontal plane 2.00 m above the upper level of the load, but at least by a horizontal plane 3.00 m above the deck.

Protected IBC (for metal IBCs) means an IBC provided with additional protection against impact, the protection taking the form of, for example, a multi-layer (sandwich) or doublewall construction, or a frame with a metal lattice-work casing.

Quality assurance means a systematic programme of controls and inspections applied by any organization or body which is aimed at providing confidence that the safety prescriptions in ADN are met in practice.

Receptacle (Class 1) includes boxes, cylinders, cans, drums, jars and tubes, including any means of closure used in the inner or intermediate packaging; Receptacle means a containment vessel for receiving and holding substances or articles, including any means of closing. This definition does not apply to shells (see also Cryogenic receptacle, Inner receptacle, Rigid inner receptacle and Gas cartridge);

- 26 -

NOTE: Receptacles for gases of Class 2 are cylinders, tubes, pressure drums, cryogenic receptacles and bundles of cylinders frames).

Recycled plastics material means material recovered from used industrial packagings that has been cleaned and prepared for processing into new packagings; Reel (Class 1 ) means a device made of plastics, wood, fibreboard, metal or other suitable material comprising a central spindle with, or without, side walls at each end of the spindle. Articles and substances can be wound on to the spindle and may be retained by side walls; Rescue winch means a device for hoisting persons from spaces such as cargo tanks, cofferdams and double-hull spaces. The device shall be operable by one person; Residual cargo means liquid cargo remaining in the cargo tank or cargo piping after unloading without the use of the stripping system; RID means Regulations concerning the International Carriage of Dangerous Goods by Rail, Appendix C of COTIF (Convention concerning International Carriage by Rail); Rigid inner receptacle (for composite IBCs) means a receptacle which retains its general shape when empty without its closures in place and without benefit of the outer casing. Any inner receptacle that is not rigid is considered to be flexible; Rigid plastics IBC means a rigid plastics body, which may have structural equipment together with appropriate service equipment;

Safety valve means a spring-loaded device which is activated automatically by pressure the purpose of which is to protect the cargo tank against unacceptable excess internal pressure or negative internal pressure (see also Pressure-relief device and Vacuum valve); SADT see Self-accelerating decomposition temperature; Salvage packaging means a special packaging into which damaged, defective or leaking dangerous goods packages, or dangerous goods that have spilled or leaked are placed for purposes of carriage for recovery or disposal; Sampling openings means opening with a diameter of not more than 0.30 m fitted with a flame arrester plate stack, capable of withstanding steady burning and so designed that the opening period will be as short as possible and that the flame arrester plate stack cannot remain open without external intervention. The flame arrester plate stack shall be of a type approved by the competent authority for this purpose; Self-accelerating decomposition temperature (SADT), means the lowest temperature at which self-accelerating decomposition may occur with substance in the packaging as used during carriage. Provisions for determining the SADT and the effects of heating under confinement are contained in Part I1 of the Manual of Tests and Criteria; Service space means a space which is accessible during the operation of the vessel and which is neither part of the accommodation nor of the cargo tanks, with the exception of the forepeak and after peak, provided no machinery has been installed in these latter spaces; Settled pressure means the pressure of the contents of a pressure receptacle in thermal and diffusive equilibrium;

- 27 -

Sheeted container means an open container equipped with a sheet to protect the goods loaded; Sheeted vehicle means an open vehicle provided with a sheet to protect the load; Sheeted wagon means an open wagon provided with a sheet to protect the load; Sift-proof packaging means a packaging impermeable to dry contents, including fine solid material produced during carriage; Slops means liquid cargo residues which cannot be removed from the cargo tank or cargo piping by discharging, draining or stripping; by extension, a mixture of cargo residues and washing water, rust, etc., which is either suitable or not suitable for pumping; Small container means a container having an internal volume of not less than 1 m3 and not more than 3 m3; NOTE: For radioactive material, see 2.2.7.2. Small receptacle containing gas, see Gas cartridge; SOLAS means the International Convention for the Safety of Life at Sea, 1974, as amended; Solid means: (a)

a substance with a melting point or initial melting point of more than 20 "C at a pressure of 101.3 kPa; or

(b)

a substance which is not liquid according to the ASTM D 4359-90 test method or which is pasty according to the criteria applicable to the test for determining fluidity (penetrometer test) described in 2.3.4;

Steady burning means (see EN 12 874: 1999);

combustion

stabilized

for

an

indeterminate

period

Stripping system (efjcient) means a system for draining the cargo tanks and stripping the cargo piping except for the cargo residues; Supply installation (bunkering system) means an installation for the supply of vessels with liquid fuels; Supply vessel means an open type N tank vessel with a dead weight of up to 300 tonnes, constructed and fitted for the carriage and delivery to other vessels of products intended for the operation of vessels; Swap-body, see Container

Tank means a shell, including its service and structural equipment. When used alone, the term tank means a tank-container, portable tank, demountable tank or fixed tank as defined in this part, including tanks forming elements of battery-vehicles or MEGCs (see also Demountable tank, Fixed tank, Portable tank and Multiple-element gas container); NOTE: For portable tanks, see 6.7.4.1 of ADR.

-28-

Tank-container means an article of transport equipment meeting the definition of a container, and comprising a shell and items of equipment, including the equipment to facilitate movement of the tank-container without significant change of attitude, used for the carriage of gases, liquid, powdery or granular substances and, when used for the carriage of Class 2 substances having a capacity of more than 0.45 m3 (450 litres);

NOTE: IBCs which meet the requirements of Chapter 6.5 of ADR are not considered to be tank-containers. Tank-container/portable tank operator means any enterprise in whose name the tankcontainerlportable tank is registered; "Tank record" means a file containing all the important technical information concerning a tank, a battery-vehicle or a MEGC, such as certificates referred to in 6.8.2.3, 6.8.2.4 and 6.8.3.4 of ADR; Tank swap body is considered to be a tank-container; Tank-vehicle means a vehicle built to carry liquids, gases or powdery or granular substances and comprising one or more fixed tanks. In addition to the vehicle proper, or the units of running gear used in its stead, a tank-vehicle comprises one or more shells, their items of equipment and the fittings for attaching them to the vehicle or to the running-gear units; Tank vessel means a vessel intended for the carriage of substances in cargo tanks; Tank wagon means a wagon intended for the carriage of liquids, gases, powdery or granular substances, comprising a superstructure, consisting of one or more tanks and their equipment and an underframe fitted with its own items of equipment (running gear, suspension, buffing, traction, braking gear and inscriptions).

NOTE: Tank wagon also includes wagons with demountable tanks. Technical name means a recognized chemical name, or a recognized biological name where relevant, or another name currently used in scientific and technical handbooks, journals and texts (see 3.1L 8 . l . 1); Temperature class (see IECpublication 79 and EN 50 014) means a grouping of flammable gases and vapours of flammable liquids according to their ignition temperature; and of the electrical apparatus intended to be used in the corresponding potentially explosive atmosphere according to their maximum surface temperature; Test pressure means the pressure at which a cargo tank, a residual cargo tank, a cofferdam or the loading and unloading pipes shall be tested prior to being brought into service for the first time and subsequently regularly within prescribed times; Toximeter means a device allowing measuring of any significant concentration of toxic gases given off by the cargo. This device shall be so designed that such measurements are possible without the necessity of entering the spaced to be checked. Training means teaching instruction, courses or apprenticeships dispensed by an organizer approved by the competent authority;

Transport unit means a vehicle according to article 1 (a) of ADR, a wagon according to the RID definition, a container, a tank-container, a portable tank or an MEGC; Transport unit means a motor vehicle without an attached trailer, or a combination consisting of a motor vehicle and an attached trailer; Transport unit (inland waterways) means, in carriage by inland waterways, a vessel, a hold, or a specific part of a vessel's deck; Tray (Class 1) means a sheet of metal, plastics, fibreboard or other suitable material which is placed in the inner, intermediate or outer packaging and achieves a close-fit in such packaging. The surface of the tray may be shaped so that packagings or articles can be inserted, held secure and separated from each other; Tube means a seamless transportable pressure receptacle of a water capacity exceeding 150 litres and of not more than 3,000 litres; Types ofprotection (see IEC Publication 79 and EN 50 014) EEx (d) EEx (e) EEx (ia) and EEx (ib) EEx (m) EEx (P) EEx (q)

:

flameproof enclosure (EN 50 018); increased safety (EN 50 019); intrinsic safety (EN 50 020); encapsulation (EN 50 028); pressurized apparatus (EN 50 0 16); powder filling (EN 50 017).

Type of vessel Type G

:

means a tank vessel intended for the carriage of gases. Carriage may be under pressure or under rehgeration.

Type C

:

means a tank vessel intended for the carriage of liquids. The vessel shall be of the flush-deckldouble-hull type with double-hull spaces, double bottoms, but without trunk. The cargo tanks may be formed by the vessel's inner hull or may be installed in the hold spaces as independent tanks.

Type N

:

means a tank vessel intended for the carriage of liquids.

Sketches (as example) Type G :

Type G Condition of cargo tank l , Type of cargo tanks 1 (also by flush-deck)

Type G Condition of cargo tank 1, Type of cargo tanks 1 (also by flush-deck)

Type G Condition of cargo tank 2 , Type of cargo tank 1 (also by flush-deck)

Type C :

Type C Condition of cargo tank 2, Type of cargo tank 2

Type C Condition of cargo tank l, Type of cargo tank l

Type C Condition of cargo tank 2 Type of cargo tank 1

Type N :

Type N Condition of cargo tank 2 , 3 or 4 Type of cargo tank 2

Type N Condition of cargo tank 2 , 3 or 4 Type of cargo tank 2

_ J

Type N Condition of cargo tank 2 , 3 or 4 Type of cargo tanks l (also by flush-deck)

Type N Condition of cargo tank 2 , 3 or 4 Type of cargo tank 1 (also by flush-deck)

Type N Condition of cargo tank 2 , 3 or 4 Type of cargo tank 3 (also by flush-deck)

UIC means the International Union of Railways (UIC, 16 rue Jean Rey, F-75015 Paris, France); Undertaking, see Enterprise; UNECE means the United Nations Economic Commission for Europe (UNECE, Palais des Nations, 8- l 4 avenue de la Paix, CH- 1211 Geneva 10, Switzerland); UN Model Regulations means the Model Regulations annexed to the fourteenth revised edition of the Recommendations on the Transport of Dangerous Goods published by the United Nations (STISGIAC.lO/l/Rev. 14); UN number means the four-figure identification number of the substance or article taken from the United Nations Model Regulations.

Vacuum design pressure means the vacuum pressure on the basis of which the cargo tank or the residual cargo tank has been designed and built; Vacuum-operated waste tank means a fixed or demountable tank primarily used for the carriage of dangerous wastes, with special constructional features andor equipment to facilitate the loading and unloading of wastes as specified in Chapter 6.10 of ADR. A tank which fully complies with the requirements of Chapter 6.7 or 6.8 of ADR is not considered to be a vacuum-operated waste tank; Vacuum valve means a spring-loaded device which is activated automatically by pressure the purpose of which is to protect the cargo tank against unacceptable negative internal pressure; Vehicle means any vehicle covered by the definition of the term vehicle in the ADR or wagon in RID (see Battery-vehicle, Closed vehicle, Open vehicle, Sheeted vehicle and Tankvehicle); Venting piping means a pipe of the shore facility which is connected during the loading to the vessel's common vapour pipe or gas return piping. This pipe is designed so as to protect the vessel against detonations or the passage of flames from the shoreside; Vessel means an inland navigation vessel or a seagoing vessel.

Wagon means a rail vehicle without its own means of propulsion that runs on its own wheels on railway tracks and is used for the carriage of goods; Wastes means substances, solutions, mixtures or articles for which no direct use is envisaged but which are transported for reprocessing, dumping, elimination by incineration or other methods of disposal; Wooden barrel means a packaging made of natural wood, of round cross-section, having convex walls, consisting of staves and heads and fitted with hoops; Wooden IBC means a rigid or collapsible wooden body, together with an inner liner (but no inner packaging) and appropriate service and structural equipment;

- 32 -

Workingpressure means the settled pressure of a compressed gas at a reference temperature of 15" C in a full pressure receptacle.

NOTE: For tanks, see Maximum working pressure. 1.2.2

Units of measurement

1.2.2.1

The following units of measurementa are applicable in ADN:

Measurement of Length Area Volume Time

m (metre) m2 (square metre) m3 (cubic metre) S (second)

Mass

kg (kilogram)

Mass density Temperature Temperature difference Force Pressure

kg/m3 K (kelvin) K (kelvin) N (newton) Pa (pascal)

Stress Work Energy Quantity of heat Power Kinematic viscosity Dynamic viscosity Activity Dose equivalent

Acceptable alternative unit

Relationship between units

l ' (litre) min. (minute) h (hour) d (day) g (gramme) t (ton) kg11 "C (degree Celsius) "C (degree Celsius) -

-

bar (bar) ~/rnm~ kWh (kilowatt hours) J (joule) eV (electronvolt) W (watt) m2/s Pas Bq (becquerel) Sv (sievert)

mm2/s mPa.s

1 l = 10" m3 1 min. = 60 S l h=36OOs 1d=86400s l g = 10" kg 1t=103kg l kg11 = 103kg/m3 0" C = 273.15 K 1°C=lK 1 N = l kg.m/s2 l ~ a 1=N/m2 1 bar = 105Pa = 1~MPa 1~ / m m 1 kWh = 3.6 MJ 1 J = l N.m= 1 W.s l eV = 0.1602 H 10-"J 1 W = 1 J/s= lN.m/s 1 mm2/s = 10-6m2/s l mPa.s = 10" Pa.s

" Thefollowing r o u n d m r e s are applicablefor the conversion of the units hitherto used into SI Units. Force lkg IN Pressure I Pa I bar Ikg/cm2 I torr

= =

= = =

=

9.807N 0.102kg

Stress I kg/mm2 I N/mm2

I~ / m ~ = lo5Pa = 9 . 8 0 7 ~ 1 0 " ~ a= 1.33 H I @PU =

Enerm. Work, Ouantitv o f heat = 1 N.m = IJ I kWh = 3 . 6 ~ 1 0 ~ ~= Ikgm = 9.807J = lkcal = 4.19Hld~ =

= 9.807 N/mm2 = 0.102 kg/mm2

10-5bar 1.02 kg/cm2 0.9807bar 1.33 HIO" bar

-

=

0.278 ~ 1 0k .m~ = 367H103kgm = 2.72 H I O -k~ ~ h= 1.16 H I O -k~ ~ h=

1.02 H 10.' kg/cm2 750 torr 736 torr 1.36 H I O -kg/cm2 ~

= 0.75 H

0.102 kgm 860 kcal 2.34 H I 0" kcal 42 7 kgm

=

1o - torr ~

0.239 HIO" kcal

Power l W l kgm/s Ikcal/h

= =

=

0.102 kgm/s 9.807 W 1.16W

Dynamic viscosity I Pas = I N.s/m2 = 0.1 P a s IP 1 kg.s/m2 = 9.807Pa.s

=

= =

= =

=

0.86 kcal/h 8.43 kcal/h 0.119 kgm/s

10 P (poise) 0.I ~ . s / m ~ 9.807N.s/m2

Kinematic viscosity I m2/s = l o4St (Stokes) 1 St = I o - m2/s ~

= =

=

0.102 kg.s/m2 1.02 H I kg.s/m2 98.07P

The International System of Units (S4 is the result of decisions taken at the General Conference on Weights and Measures (Address: Pavillon de Breteuil, Parc de St-Cloud, F-92 310 S2vres). The abbreviation "L" for litre may also be used in place of the abbreviation "l" when a typewriter cannot distinguish betweenfigure " I " and letter "l". The decimal multiples and sub-multiples of a unit may be formed by prefixes or symbols, having the following meanings, placed before the name or symbol of the unit: Prefix

Factor quintillion quadrillion trillion billion million thousand hundred ten tenth hundredth thousandth millionth billionth trillionth quadrillionth quintillionth

exa peta tera gigs mega kilo hecto deca deci centi milli micro nano pico femto atto

Symbol

E P T G M k h da d C

m

P n P f a

NOTE: l o 9 = 1 billion is United Nations usage in English. By analogy, so is I 0-9= I billionth. Unless expressly stated otherwise, the sign "%" in ADN represents: In the case of mixtures of solids or of liquids, and also in the case of solutions and of solids wetted by a liquid, a percentage mass based on the total mass of the mixture, the solution or the wetted solid; In the case of mixtures of compressed gases, when filled by pressure, the proportion of the volume indicated as a percentage of the total volume of the gaseous mixture, or, when filled by mass, the proportion of the mass indicated as a percentage of the total mass of the mixture; In the case of mixtures of liquefied gases and dissolved gases, the proportion of the mass indicated as a percentage of the total mass of the mixture.

Pressures of all kinds relating to receptacles (such as test pressure, internal pressure, safety valve opening pressure) are always indicated in gauge pressure (pressure in excess of atmospheric pressure); however, the vapour pressure of substances is always expressed in absolute pressure. Where ADN specifies a degree of filling for receptacles, this is always related to a reference temperature of the substances of 15" C, unless some other temperature is indicated.

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CHAPTER 1.3 TRAINING OF PERSONS INVOLVED IN THE CARRIAGE OF DANGEROUS GOODS Scope and applicability Persons employed by the participants referred to in Chapter 1.4, whose duties concern the carriage of dangerous goods, shall receive training in the requirements governing the carriage of such goods appropriate to their responsibilities and duties. Training requirements specific to security of dangerous goods in Chapter 1.10 shall also be addressed. NOTE l: With regard to the trainingfor the safety adviser, see 1.8.3.

NOTE 2: With regard to expert training, see Chapter 8.2.

Nature of the training The training shall take the following form, appropriate to the responsibility and duties of the individual concerned.

General awareness training Personnel shall be familiar with the general requirements of the provisions for the carriage of dangerous goods.

1.3.2.2

Function-specific training

1.3.2.2.1

Personnel shall receive detailed training, commensurate directly with their duties and responsibilities in the requirements of the regulations concerning the carriage of dangerous goods. Where the carriage of dangerous goods involves a multimodal transport operation, the personnel shall be made aware of the requirements concerning other transport modes.

1.3.2.2.2

The crew shall be familiarized with the handling of fire-extinguishing systems and fireextinguishers.

1.3.2.2.3

The crew shall be familiarized with the handling of the fire-extinguishing systems and fireextinguishers with the special equipment referred to in 8.1.5.

1.3.2.2.4

Persons wearing self-contained breathing apparatus shall be physically able to bear the additional constraints. They shall:

1.3.2.3.5

-

in the case of devices operating with pressurized air, be trained in their handling and maintenance;

-

in the case of devices supplied with pressurized air through a hose, be trained in their handling and maintenance.

The master shall bring the instructions in writing to the attention of the other persons on board to ensure that they are capable of applying them.

Safety training Commensurate with the degree of risk of injury or exposure arising from an incident involving the carriage of dangerous goods, including loading and unloading, personnel shall receive training covering the hazards and dangers presented by dangerous goods. The training provided shall aim to make personnel aware of the safe handling and emergency response procedures.

Trainingfor Class 7 For the purpose of Class 7, personnel shall receive appropriate training concerning radiation protection including the precautions to be observed in order to restrict their occupational exposure and the exposure of other persons who might be affected by their actions.

Documentation Details of all the training undertaken shall be kept by both the employer and the employee and shall be verified upon commencing a new employment. The training shall be periodically supplemented with refresher training to take account of changes in regulations.

CHAPTER 1.4 SAFETY OBLIGATIONS OF THE PARTICIPANTS General safety measures The participants in the carriage of dangerous goods shall take appropriate measures according to the nature and the extent of foreseeable dangers, so as to avoid damage or injury and, if necessary, to minimize their effects. They shall, in all events, comply with the requirements of ADN in their respective fields. When there is an immediate risk that public safety may be jeopardized, the participants shall immediately notify the emergency services and shall make available to them the information they require to take action. ADN may specify certain of the obligations falling to the various participants. If a Contracting Party considers that no lessening of safety is involved, it may in its domestic legislation transfer the obligations falling to a specific participant to one or several other participants, provided that the obligations of 1.4.2 and 1.4.3 are met. These derogations shall be communicated by the Contracting Party to the secretariat of the United Nations Economic Commission for Europe which will bring them to the attention of the Contracting Parties. The requirements of 1.2.1, 1.4.2 and 1.4.3 concerning the definitions of participants and their respective obligations shall not affect the provisions of domestic law concerning the legal consequences (criminal nature, liability, etc.) stemming from the fact that the participant in question is e.g. a legal entity, a self-employed worker, an employer or an employee. 1.4.2

Obligations of the main participants NOTE:

For radioactive material see also 1.7.6.

1.4.2.1

Consignor

1.4.2.1.1

The consignor of dangerous goods is required to hand over for carriage only consignments which conform to the requirements of ADN. In the context of 1.4.1, he shall in particular: ascertain that the dangerous goods are classified and authorized for carriage in accordance with ADN; furnish the carrier with information and data and, if necessary, the required transport documents and accompanying documents (authorizations, approvals, notifications, certificates, etc.), taking into account in particular the requirements of Chapter 5.4 and of the tables in Part 3; use only packagings, large packagings, intermediate bulk containers (IBCs) and tanks (tank-vehicles, demountable tanks, battery-vehicles, MEGCs, portable tanks, tankcontainers, tank wagons and battery wagons) approved for and suited to the carriage of the substances concerned and bearing the markings prescribed by one of the international Regulations, and to use only approved vessels or tank-vessels suitable for the carriage of the goods in question; comply with the requirements on the means of dispatch and on forwarding restrictions;

(e)

ensure that even empty uncleaned and not degassed tanks (tank-vehicles, demountable tanks, battery-vehicles, MEGCs, portable tanks, tank-containers, tank wagons and tank vehicles) or empty uncleaned vehicles, wagons and large and small bulk containers are appropriately marked and labelled and that empty uncleaned tanks are closed and present the same degree of leakproofness as if they were full.

1.4.2.1.2

If the consignor uses the services of other participants (packer, loader, filler, etc.), he shall take appropriate measures to ensure that the consignment meets the requirements of ADN. He may, however, in the case of 1.4.2.1.1 (a), (b), (c) and (e), rely on the information and data made available to him by other participants.

1.4.2.1.3

When the consignor acts on behalf of a third party, the latter shall inform the consignor in writing that dangerous goods are involved and make available to him all the information and documents he needs to perform his obligations.

1.4.2.2

Carrier

1.4.2.2.1

In the context of 1.4.1, where appropriate, the carrier shall in particular: ascertain that the dangerous goods to be carried are authorized for carriage in accordance with ADN; ascertain that the prescribed documentation is on board the vessel; ascertain visually that the vessels and loads have no obvious defects, leakages or cracks, missing equipment, etc.; (Reserved); verify that the vessels are not overloaded; (Reserved); ascertain that the equipment prescribed in the written instructions for the master is on board the vessel; ascertain that the marking requirements for the vessel have been met; ascertain that during loading, carriage, unloading and any other handling of the dangerous goods in the holds or cargo tanks, special requirements are complied with. Where appropriate, this shall be done on the basis of the transport documents and accompanying documents, by a visual inspection of the vessel or the containers and, where appropriate, the load.

1.4.2.2.2

The carrier may, however, in the case of 1.4.2.2.1 (a), (b) and (i), rely on information and data made available to him by other participants.

1.4.2.2.3

If the carrier observes an infringement of the requirements of ADN, in accordance with 1.4.2.2.1, he shall not forward the consignment until the matter has been rectified. (Reserved). (Reserved).

Consignee The consignee has the obligation not to defer acceptance of the goods without compelling reasons and to verify, before, during or after unloading, that the requirements of ADN concerning him have been complied with. In the context of 1.4.1, he shall in particular: carry out in the cases provided for by ADN the prescribed operations for the unloading of vessels; carry out in the cases provided for by ADN the prescribed cleaning and decontamination of the vessels; ensure that the containers, vehicles and wagons, once completely unloaded, cleaned and decontaminated, no longer bear danger markings conforming to Chapter 5.3; ascertain that provision has been made in the fore and aft sections of the vessel for its evacuation in the event of an emergency; ascertain that in the cases provided for by ADN a flame-arrester is installed in the gas discharge pipe or the compensation pipe to protect the vessel against detonations and flame-fronts from the landward side; ascertain that the seals he has put in place to ensure that the connections between the vessel's loading and discharging hoses are leakproof are made of a material which is not attacked by the cargo, which does not cause the decomposition of the cargo and does not cause a harmful or dangerous reaction with the cargo; ascertain that permanent and appropriate surveillance is ensured for the entire duration of loading or discharging. If the consignee makes use of the services of other participants (unloader, cleaner, decontamination facility, etc.) he shall take appropriate measures to ensure that the requirements of ADN have been complied with. If these verifications bring to light an infringement of the requirements of ADN, the consignee shall return a container or a vehicle to the carrier only after the infringement has been remedied. Obligations of the other participants

A non-exhaustive list of the other participants and their respective obligations is given below. The obligations of the other participants flow from section 1.4.1 above insofar as they know or should have known that their duties are performed as part of a transport operation subject to ADN;

Loader In the context of 1.4.1, the loader has the following obligations in particular: (a)

He shall hand the dangerous goods over to the carrier only if they are authorized for carriage in accordance with ADN;

(b)

He shall, when handing over for carriage packed dangerous goods or uncleaned empty packagings, check whether the packaging is damaged. He shall not hand over a -41 -

package the packaging of which is damaged, especially if it is not leakproof, and there are leakages or the possibility of leakages of the dangerous substance, until the damage has been repaired; this obligation also applies to empty uncleaned packagings; (c)

He shall, when loading dangerous goods in a vessel, a vehicle, a wagon, or a large or small container, comply with the special requirements concerning loading and handling;

(d)

He shall, after loading dangerous goods into a container comply with the requirements concerning danger markings conforming to Chapter 5.3;

(e)

He shall, when loading packages, comply with the prohibitions on mixed loading taking into account dangerous goods already in the vessel, vehicle, wagon or large container and requirements concerning the separation of foodstuffs, other articles of consumption or animal feedstuffs;

(Q

He shall ascertain that provision has been made in the fore and aft sections of the vessel for its evacuation in the event of an emergency;

(g)

He shall furnish the masters with the additional protection material and equipment required in the instructions in writing.

1.4.3.1.2

The loader may, however, in the case of 1.4.3.1.1 (a), (d) and (e), rely on information and data made available to him by other participants.

1.4.3.2

Packer In the context of 1.4.1, the packer shall comply with in particular: (a)

the requirements concerning packing conditions, or mixed packing conditions and,

(b)

when he prepares packages for carriage, the requirements concerning marking and labelling of the packages.

Filler In the context of 1.4.1, the filler has the following obligations in particular:

Obligations concerning the Jilling of tanks (tank-vehicles, battery-vehicles, demountable tanks,portable tanks, tank-containers, MEGCs, tank wagons and battev wagons): (a)

He shall ascertain prior to the filling of tanks that both they and their equipment are technically in a satisfactory condition;

(b)

He shall ascertain that the date of the next test for tank-vehicles, battery-vehicles, demountable tanks, portable tanks, tank-containers, MEGCs, tank wagons and battery wagons has not expired;

(c)

He shall only fill tanks with the dangerous goods authorized for carriage in those tanks;

(d)

He shall, in filling the tank, comply with the requirements concerning dangerous goods in adjoining compartments;

(e)

He shall, during the filling of the tank, observe the maximum permissible degree of filling or the maximum permissible mass of contents per litre of capacity for the substance being filled;

(f)

He shall, after filling the tank, check the leakproofness of the closing devices;

(g)

He shall ensure that no dangerous residue of the filling substance adheres to the outside of the tanks filled by him;

(h)

He shall, in preparing the dangerous goods for carriage, ensure that the orange plates and placards or labels prescribed are affixed in accordance with the requirements of chapter 5.3 concerning tanks.

Obligations concerning the bulk loading of dangerous solids in vehicles, wagons or containers: (i)

He shall ascertain, prior to loading, that the vehicles, wagons and containers, and if necessary their equipment, are technically in a satisfactory condition and that the carriage in bulk of the dangerous goods in question is authorized in these vehicles or containers;

(j)

He shall ensure after loading that the orange plates and placards or labels prescribed are affixed in accordance with the requirements of Chapter 5.3 applicable to such vehicles, wagons or containers;

(k)

He shall, when filling vehicles or containers with dangerous goods in bulk, ascertain that the relevant provisions of Chapter 7.3 of RID or ADR are complied with.

Obligations concerning thefilling of cargo tanks. (1)

He shall ascertain, prior to filling, that the additional protection material and equipment required in the instructions in writing have been provided to the master;

(m) He shall complete his section of the check list referred to in 7.2.4.10 prior to the loading of the cargo tanks of a tank vessel;

(n)

He shall only fill cargo tanks with the dangerous goods accepted in such tanks;

(0)

He shall, when necessary, issue a heating instruction in the case of the carriage of substances whose melting point is 0 "C or higher;

(p)

He shall ascertain that during loading the trigger for the automatic device for the prevention of overfilling switches off the electric line established and supplied by the on-shore installation and that he can take steps against overfilling;

(q)

He shall ascertain that provision has been made in the fore and aft sections of the vessel for appropriate means for its evacuation in the event of an emergency;

(r)

He shall ascertain that, when prescribed in 7.2.4.25.5. there is a flame-arrester in the gas discharge pipe or the compensation pipe to protect the vessel against detonations and flame-fronts from the landward side;

(S)

He shall ascertain that the loading flows conform to the loading instructions referred to in 9.3.2.25.9 or 9.3.3.25.9 and that the pressure at the crossing-point of the gas discharge pipe or the compensation pipe is not greater than the opening pressure of the high velocity vent valve;

- 43 -

(t)

He shall, after filling the tank, check the leakproofness of the closing devices;

(U)

He shall ensure that no dangerous residue of the filling substance adheres to the outside of the tanks filled by him.

Obligations concerning the bulk loading of dangerous solids in vessels: (v)

He shall ascertain, prior to loading, that the additional protection material and equipment required in the instructions in writing have been provided to the master;

(W)

He shall only load the vessel with dangerous goods the bulk carriage of which is authorized in that vessel;

(X)

He shall ascertain that provision has been made in the fore and aft sections of the vessel for appropriate means for its evacuation in the event of an emergency.

Tank-container/portable tank operator

In the context of 1.4.1, the tank-container/portable tank operator shall in particular: (a)

ensure compliance with the requirements for construction, equipment, tests and marking;

(b)

ensure that the maintenance of shells and their equipment is carried out in such a way as to ensure that, under normal operating conditions, the tank-containerlportable tank satisfies the requirements of ADR, RID or the IMDG Code until the next inspection;

(c)

have an exceptional check made when the safety of the shell or its equipment is liable to be impaired by a repair, an alteration or an accident.

(Reserved).

CHAPTER 1.5 SPECIAL RULES, DEROGATIONS Bilateral and multilateral agreements In accordance with Article 7, paragraph 1 of ADN, the competent authorities of the Contracting Parties may agree directly among themselves to authorize certain transport operations in their territories by temporary derogation from the requirements of ADN, provided that safety is not compromised thereby. The authority which has taken the initiative with respect to the temporary derogation shall notify such derogations to the Secretariat of the United Nations Economic Commission for Europe which shall bring them to the attention of the Contracting Parties.

NOTE: "Special arrangement" in accordance with 1.7.4 is not considered to be a temporary derogation in accordance with this section. The period of validity of the temporary derogation shall not be more than five years from the date of its entry into force. The temporary derogation shall automatically cease as from the date of the entry into force of a relevant amendment to these annexed Regulations. Transport operations on the basis of these agreements shall constitute transport operations in the sense of ADN.

Special authorizations concerning transport in tank vessels Special authorizations In accordance with paragraph 2 of Article 7, the competent authority shall have the right to issue special authorizations to a carrier or a consignor for the international carriage in tank vessels of dangerous substances, including mixtures, the carriage of which in tank vessels is not authorized under these Regulations, in accordance with the procedure set out below. The special authorization shall be valid, due account being taken of the restrictions specified therein, for the Contracting Parties and on whose territory the transport operation will take place, for not more than two years but unless it is repealed at an earlier date. With the approval of the competent authorities of these Contracting Parties, the special authorization may be renewed for a period of not more than one year. The special authorization shall include a statement concerning its repeal at an earlier date and shall conform to the model established by the Administrative Committee. Procedure The carrier or the consignor shall apply to the competent authority of a Contracting Party on whose territory the transport operation takes place for the issue of a special authorization. The application shall include the particulars mentioned in these Regulations. The applicant shall be responsible for the accuracy of the particulars. The competent authority shall consider the application from the technical and safety point of view. If it has no reservations, it shall draw up a special authorization in accordance with the criteria established by the Administrative Committee and immediately inform the other competent authorities involved in the carriage in question. The special authorization shall be issued only when the authorities concerned agree to it or have not expressed opposition within a period of two months after receiving the information. The applicant shall receive

the original of the special authorization and keep a copy of it on board the vessel(s) involved in the carriage in question. The competent authorities shall immediately communicate to the Administrative Committee the applications for special authorizations, the applications rejected and the special authorizations granted. 1.5.2.2.3

If the special authorization is not issued because doubts or opposition have been expressed, the Administrative Committee shall decide whether or not to issue a special authorization.

1.5.2.3

Update of the list of substances authorized for carriage in tank vessels

1.5.2.3.1

The Administrative Committee shall consider all the special authorizations and applications communicated to it and decide whether the substance is to be included in the list of substances in these Regulations, authorized for carriage in tank vessels.

1.5.2.3.2

If the Administrative Committee enters technical or safety reservations concerning the inclusion of the substance in the list of substances of these Regulations authorized for carriage in tank vessels or concerning certain conditions, the competent authority shall be so informed. The competent authority shall immediately withdraw or, if necessary, modify the special authorization. Equivalents and derogations (Article 7, paragraph 3 of ADN) Procedure for equivalents When the provisions of these Regulations prescribe for a vessel the use or the presence on board of certain materials, installations or equipment or the adoption of certain construction measures or certain fixtures, the competent authority may agree to the use or the presence on board of other materials, installations or equipment or the adoption of other construction measures or other fixtures for this vessel if, in line with recommendations established by the Administrative Committee, they are accepted as equivalent. Derogations on a trial basis The competent authority may, on the basis of a recommendation by the Administrative Committee, issue a trial certificate of approval for a limited period for a specific vessel having new technical characteristics departing from the requirements of these Regulations, provided that these characteristics are sufficiently safe. Particulars of equivalents and derogations The equivalents and derogations referred to in 1.5.3.1 and 1.5.3.2 shall be entered in the certificate of approval.

CHAPTER 1.6 TRANSITIONAL MEASURES General Unless otherwise provided, the substances and articles of ADN may be carried until 30 June 2007 in accordance with the requirements of ADN applicable up to 3 1 December 2006. (a)

The danger labels and placards which until 31 December 2004 conformed to models No. 7A, 7B, 7C, 7D or 7E prescribed up to that date may be used until 3 1 December 2010.

(b)

The danger labels and placards which until 31 December 2006 conformed to model No. 5.2 prescribed up to that date may be used until 3 1 December 20 10.

The transitional measures of 1.6.1.3 and 1.6.1.4 of ADR and RID, or falling within the scope of 4.1 S.19 of IMDG Code, concerning the packaging of substances and articles of Class 1, are also valid for carriage subject to ADN. 1.6.1.4-1.6.1.5 (Reserved). 1.6.1.6

The means of evacuation prescribed in 1.4.2.3.1 (d) with regard to the unloading of dry cargo vessels in 1.4.3.1.1 (Qand 1.4.3.3.1 (W)are mandatory only as from 1 January 2007.

1.6.1.7

(Reserved).

1.6.1.8

Existing orange-coloured plates which meet the requirements of sub-section 5.3.2.2 applicable up to 3 1 December 2004 may continue to be used.

1.6.1.9

(Reserved).

1.6.1.10

Lithium cells and batteries manufactured before 1 July 2003 which had been tested in accordance with the requirements applicable until 3 1 December 2002 but which had not been tested in accordance with the requirements applicable as from 1 January 2003, and appliances containing such lithium cells or batteries, may continue to be carried up to 30 June 20 13 if all the other applicable requirements are fulfilled. Receptacles for Class 2 The transitional measures of sections 1.6.2 of ADR and RID are also valid for transport operations subject to ADN. Fixed tanks (tank-vehicles and tank wagons), demountable tanks, battery vehicles and battery wagons The transitional measures of sections 1.6.3 of ADR and RID are also valid for transport operations subject to ADN. Tank-containers, portable tanks and MEGCs The transitional measures of sections 1.6.4 of ADR and RID or of section 4.2.0 of the IMDG Code, depending on the case, are also valid for transport operations subject to ADN.

Vehicles and wagons The transitional measures of sections 1.6.5 of ADR and RID are also valid for transport operations subject to ADN. Class 7 The transitional measures of sections 1.6.6 of ADR and RID or of section 6.4.24 of the IMDG Code are also valid for transport operations subject to ADN.

1.6.7

Transitional provisions concerning vessels

1.6.7.1

General

l .6.7.1. 1

For the purposes of Article 8 of ADN, section 1.6.7 sets out general transitional provisions in 1.6.7.2 (see Article 8, paragraphs 1, 2 and 4) and specific transitional provisions in 1.6.7.3 (see Article 8, paragraph 3).

1.6.7.1.2

In this section 1.6.7: (a)

"Vessel in service" means a vessel according to Article 8, paragraph 2 of the Agreement;

(b) "N.R.M." means that the requirement does not apply to vessels in service except where the parts concerned are replaced or modified, i.e. it applies only to vessels which are -new (as from the date indicated), or to parts which are ~eplacedor modified after the date indicated; where existing parts are replaced by spare or replacement parts of the same type and manufacture, this shall not be considered a replacement 'R' as defined in these transitional provisions. Modification shall also be taken to mean the conversion of an existing type of tank vessel, a type of cargo tank or a cargo tank design to another type or design at a higher level. (c)

"Renewal of the certificate of approval after the ..." means that the requirement shall be met at the next renewal of the certificate of approval following the date indicated. If the certificate of approval expires during the first year after the date of application of these Regulations, the requirement shall be mandatory only after the expiry of this first year.

1.6.7.2

General transitional provisions

1.6.7.2.1

General transitional provisions for dry cargo vessels

1.6.7.2.1.1

Vessels in service shall meet: (a)

the requirements of paragraphs mentioned in the table below within the period established therein;

(b)

the requirements of paragraphs not mentioned in the table below at the date of application of these Regulations.

The construction and equipment of vessels in service shall be maintained at least at the previous standard of safety.

- 48 -

p:2.1.1 Table 0; general transitional provisions Dry cargo Subiect Paragraphs Time limit and comments Ventilation of holds N.R.M. 9.1.0.12.1 The following requirements apply on board vessels in service: Each hold shall have appropriate natural or artificial ventilation; for the carriage of substances of Class 4.3, each hold shall be equipped with forced-air ventilation; the appliances used for this purpose must be so constructed that water cannot enter the hold. Ventilation of service maces N.R.M. Gas-tight openings facing N.R.M. The following requirements apply on board vessels holds in service: Openings of accommodation and the wheelhouse facing the holds must be capable of being tightly closed. N.R.M. Entrances and openings in the The following requirements apply on board vessels protected area in service: Openings of accommodation and the wheelhouse facing holds shall be capable of being tightly closed. N.R.M. 4ir intakes of engines N.R.M. Air pipes 50 cm above the deck N.R.M. Exhaust pipes N.R.M. Stripping pumps in the The following requirements apply on board vessels protected area in service: In the event of the carriage of substances of Class 4.1, 52", of all substances of Class 4.3 in bulk or unpackaged and polymeric beads, expandable, of Class 9, 4" (c), the stripping of the holds may only be effected using a stripping installation located in the protected area. The stripping installation located above the engine room must be clamped. N.R.M. Fire extinguishers, two pumps, Fire extinguishing systems permanently fixed in engine rooms

N.R.M.

Table of general transitional provisions: Dry cargo 1.6.7.2.1.1 Subject Time limit and comments Paragraphs Fire and naked light N.R.M. 3.1.0.41 The following requirements apply on board vessels in conjunction with in service: 7.1.3.41 The outlets of funnels shall be located not less than2.00 m from the nearest point on hold hatchways. Heating and cooking applimces shall be permitted only in metal-based accommodation and wheelhouses. However: Heating appliances fuelled with liquid fiiels having a flashpoint above 55 "C shall be permitted in engine rooms; Central-heating boilers fuelled with solid fuels shall be permitted in spaces situated below deck and accessible only from the deck. -Air intakes of engines 9.2.0.3 1.2 N.R.M. Position of exhaust pipes 3.2.0.34.1 N.R.M. Fire and naked light 9.2.0.41 The following requirements apply on board vessels .n conjunction with in service: 7.1.3.4.1 Outlets of funnels shall be located not less than 2.00 m from the nearest point on hold hatchways. Heating and cooking appliances shall be permitted only in metal-based accommodation and wheelhouses. However: Heating appliances fuelled with liquid fuels having a flashpoint above 55" C shall be permitted in engine rooms; Central-heating boilers fbelled by solid fuels shall be permitted in spaces situated below the deck and accessible only from the deck. 1.6.7.2.1.2

Vessels carrying only the dangerous goods referred to below in bulk are only required to meet the requirements of ADN as from l January 2005: Class 4.1

1350 3175

SULPHUR: SOLIDS or mixtures of solids (such as preparations and wastes) CONTAINING FLAMMABLE LIQUID N.O.S., having a flash point up to 6 1" C;

Class 4.2

1364 l365 1373

COTTON WASTE, OILY, in bulk; COTTON, WET FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC, N.O.S. with oil; IRON OXIDE, SPENT or IRON SPONGE, SPENT obtained from coal gas purification; PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper); MANEB or MANEB PREPARATION with not less than 60% maneb; SELF-HEATING SOLID, INORGANIC, N.O.S., Packing Group 111;

Class 9

2969

CASTOR BEANS

Vessels shall, however, meet the requirements of the following paragraphs of Part 7 below: 7.1.1.11 and7.1.3.51.4 1.6.7.2.2

General transitional provisions for tank vessels

1.6.7.2.2.1

Vessels in service shall meet: (a)

the requirements of paragraphs mentioned in the table below within the period established therein;

(b)

the requirements of paragraphs not mentioned in the table below at the date of application of these Regulations.

The construction and equipment of vessels in service shall be maintained at least at the previous standard of safety. 1.6.7.2.3

General transitional provisions for tank vessels

1.6.7.2.3.1

Table of general transitional provisions for tank vessels

1.6.7.2.3.1 Table 'general transitional provisions: 'ank vessels Time limit and comments Subject Paragraphs N.R.M. Limited explosion risk 1.2.1 The following requirements apply on board electrical apparatus vessels in service: Limited explosion risk electrical apparatus is: - Electrical apparatus which, during normal operation, does not cause sparks or exhibit surface temperatures exceeding 200 "C; or - Electrical apparatus with a spray-water protected housing which, during normal operation, does not exhibit surface temperatures above 200 "C. Not applicable to Type N open vessels whose Hold space hold spaces contain auxiliary appliances and which are carrying only substances of Class 8, with remark 30 in column (20) of Table C of Chapter 3.2. N.R.M. Flame arrester The following requirements are applicable on High velocity vent valve board vessels in service: according to standard Flame arresters and high velocity vent valves EN 12 874 (1999) shall be of a type approved by the competent authoritv for the use urescribed. I N.R.M. Approved gas detection system N.R.M. Vessels used for propulsion Use of cofferdams foi On board vessels in service, cofferdams may be filled with water during unloading to provide trim ballasting and to permit residue-free drainage if possible.

Table of general transitional provisions: Timnk vessels 1.6.7.2.3.1 Time limit and comments Paragraphs Subject Ballast water N.R.M. Prohibition against filling The following requirements apply on board vessels in service: cofferdams with water Cofferdams may be filled with ballast water only when cargo tanks are empty. -Proof of stabilization in the N.R.M. 7.2.3.20.1 event of a leak connected with ballast water for Type G vessels-Connections prohibited N.R.M. for oil-separator vessels 7.2.3.25.1 (c) between pipes for loading and unloading and pipes located outside the cargo area -N.R.M. Motor vehicles only outside the 7.2.3.3l .2 cargo area: Type N open

I

7.2.3.42.3 7.2.3.5 1.3 7.2.4.16.15

18.1.2.3 (c)

I

--

Use of the cargo heating system

I --open. N.R.M. ILive sockets for Type G and Type N vessels -Start of loading flow -Opening of openings lOn board vessels in service cargo tank hatches Type N open may be opened during loading for control and --sampling. N.R.M. I Damage control plan: Type G Documents concerning intact N.R.M. I stability -N.R.M. Loading and unloading instructions -Compliance of hoses and hose Hoses and hose assemblies on board at 1 January assemblies with standards 2007 which do not comply with the applicable standards may be used up to 3 1 December 2009 EN 121l5:l999, at the latest EN 13765:2003, EN I S 0 10380:2003 -Protection of vapour pipes against corrosion -Fire-resistant materials of accommodation and wheelhouse -N.R.M. Classification of Type N open vessels with flame arresters and Type N open vessels l

W

8.1.2.3 (c) 8.1.2.3 (i) 8.1.6.2

1

9.3.2.0.1 (c) 9.3.3.0.1 (c) 9.3.1.0.3 (d) 9.3.2.0.3 (d) 9.3.3.0.3 (d) 9.3.3.8.1

I

Table of general transitional provisions: ' 11.6.7.2.3.1 I Paragraphs Subject Continuation of class for 9.3.3.8.1 Type N open vessels with flame in conjunction with arresters and Type N open 7.2.2.8 vessels

Door coamings, etc.

1.3.1.10.3 1.3.2.10.3 3.3.3.10.3 3.3.1.11.1 (b)

Height of sills of hatches and ~peningsabove the deck

3.3.3.11.1 (d)

Limitation of length of cargo .anks

ank vessels Time limit and comments N.R.M. The following requirements apply on boarc vessels in service: Except where otherwise provided, the type o construction, the strength, the subdivision, th~ equipment and the gear of the vessel shal conform or be equivalent to the constructio~ requirements for classification in the highest clas of a recognized classification society. N.R.M. The following requirements apply on boarc vessels in service, with the exception of Type open vessels: This requirement may be met by fitting vertica protection walls not less than 0.50 m in height; On board vessels in service less than 50.00 n long, the height of 0.50 m may be reduce( to 0.30 m in passageways leading to the deck. N.R.M.

Ratio of length to diameter of Not applicable to Type G vessels whose keel! were laid before 1 January 1977. xessure cargo tanks N.R.M.

.6.7.2.3.1 Table Paragraphs 9.3.1.11.2 (a)

general transitional provisions: Tank vessels Subiect Time limit and comments Arrangement of cargo tanks N.R.M. Distance between cargo tanks Not applicable to Type G vessels whose keels and side walls were laid before l January 1977. Height of saddles, spacers

9.3.1.11.2 (b) 9.3.2.11.2 (b) 9.3.3.1 1.2 (a) 9.3.1.11.2 (c) 9.3.2.11.2 (c) 9.3.3.1 1.2 (b) 9.3.1.11.2 (d) 9.3.1.1 1.3 (a)

Cargo tank fastenings

N.R.M. The following requirements apply on board vessels in service: Where tank volume is more than 200 m3 or where the ratio of length to diameter is less than 7 but more than 5, the hull in the tank area shall be such that, in the event of a collision, the tanks remain intact as far as possible. This requirement shall be considered as having been met where, in the tank area, the vessel: - is double-hulled with a distance of at least 80 cm between the side plating and the longitudinal bulkhead, - or is designed as follows: (a) Between the gangboard and the top of the floorplates there shall be side stringers at regular intervals of not more than 60 cm; (b) The side stringers shall be supported by web frames spaced at intervals of not more than 2.00 m. The height of the web frames shall be not less than 10% of the depth and in any event not less than 30 cm. They shall be fitted with a face plate made of flat steel having a cross section of not less than 15 cm2; (c) The side stringers referred to in (a) shall have the same height as the web frames and be fitted with a face plate made of flat steel having a cross section of not less than 7.5 cm2. N.R.M.

Capacity of suction well

N.R.M.

Side stringers between the hull and the cargo tanks End bulkheads of cargo area with "A-60" insulation. Distance of 0.50 m from cargo tanks in hold spaces

N.R.M. N.R.M.

.6.7.2.3.1 Table of eeneral transitional ~rovisions:Tank vessels Subject Paragraphs Time limit and comments 9.3.2.1 1.3 (a) Width of cofferdams of 0.60 m N.R.M. 9.3.3.1 1.3 (a) Hold spaces with cofferdams or The following requirements apply on boarc "A-60" insulated bulkheads vessels in service: Distance of 0.50 m from cargo Type C: minimum width of cofferdams tanks in hold spaces 0.50 m; Type N: minimum width of cofferdams: 0.50 m, on board vessels with a deadweight of up to 150 t: 0.40 m: Type N open: cofferdams shall not be required with deadweight up to 150 t: The distance between cargo tanks and end bulkheads of hold spaces shall be at least 0.40 m. Passages through the end Shall not apply to Type N open vessels whose bulkheads of hold spaces keels were laid before 1 January 1977. Distance of piping in relation to N.R.M. :he bottom Form of cofferdam arranged as Shall not apply to Type N vessels whose keels 9.3.3.1 1.6 (a) were laid before 1 January 1977. I pump room 4rrangement of service spaces N.R.M. !ocated in the cargo area below iecks Distances in relation to the N.R.M. mter wall Hold spaces N.R.M. after 1 January 2007 'he following requirements are applicable tc essels with a certificate of approval valid prior tc January 2007: Yhere a vessel is constructed with hold space! ontaining cargo tanks which are independent o ie structure of the vessel, the space between tht {all of the hold space and the wall of the cargc inks shall be not less than 0.60 m. The spact etween the bottom of the hold space and tht ottom of the cargo tanks shall be not less thar .50 m. 'he space may be reduced to 0.40 m under tht ump sumps. 'he space between the suction well and the botton tructures shall be not less than 0.10 m. the above-mentioned spaces are not feasible, it hall be possible to remove the cargo tanks easily or ins~ections. N.R.M. limensions of openings for lccess to spaces within the :arizo area N.R.M. nterval between reinforcing :lements '

Y'entilation opening in hold ;paces

- 55

-

N.R.M.

.6.7.2.3.1 Table c,f general transitional provisions: Tank vessels Subiect Time limit and comments I Paragraphs Ventilation systems in doubleN.R.M. 9.3.1.12.2 lull spaces a i d double bottoms 9.3.3.12.2 N.R.M. ieight above the deck of the air 9.3.1.12.3 ntake for service spaces 9.3.2.12.3 ocated below deck 9.3.3.12.3 N.R.M. Iistance of ventilation inlets 3.3.1.12.6 tom cargo area 3.3.2.12.6 9.3.3.12.6 N.R.M. 'ermanently installed flame 3.3.1.12.6 xreens 9.3.2.12.6 9.3.3.12.6 Shall not apply to Type N vessels whose keels kpproval of flame arresters 9.3.3.12.7 were laid before 1 January 1977. N.R.M. Jeneral stability stability (general) :ntact stability 3.3.3.14 9.3.2.14.2 9.3.3.14.2 (b) and (c)

stability (intact) Stability (intact)

N.R.M. after 1 January 2007 N.R.M. N.R.M. N.R.M. after 1 Januarv 2007

N.R.M. after 1 January 2007 Stability (damaged condition) N.R.M. Iistance of openings of engine -ooms from the cargo area N.R.M. hternal combustion engines jutside the cargo area for Type \1 open vessels dinges of doors facing the Shall not apply to vessels whose keels were laid before 1 January l977 where alterations would :argo area obstruct other major openings. N.R.M. Engine rooms accessible from :he deck for Type N open ~ressels 4ccommodation and Shall not apply to vessels whose keels were laid wheelhouse outside the cargo before 1 January 1977, provided that there is no connection between the wheelhouse and other irea enclosed spaces. Shall not apply to vessels up to 50 m in length whose keels were laid before 1 January 1977 and whose wheelhouses are located in the cargo area even if it provides access to another enclosed space, provided that safety is ensured by appropriate service requirements of the competent authority. rype N open Arrangement of entrances and 3penings of forward uperstructures

N.R.M. N.R.M.

L

Table of general transitional provisions: T,ank vessels I Time limit and comments Paragraphs Subject Entrances facing the cargo area Shall not apply to vessels up to 50.00 m in length whose keels were laid before 1 January 1977, provided that gas screens are installed.

9.3.1.17.4 9.3.3.17.4 9.3.3.17.5 (b), (c)

Entrances and openings on Type N open vessels Entrances and openings must be capable of being closed type^ open Distance of openings from the 3arg0 area Approval of shaft passages and lisplaying of instructions Type N open Pump-room below deck

N.R.M. N.R.M.

N.R.M. N.R.M.

N.R.M. The following requirements apply on boarc vessels in service: Pump-rooms below deck shall meet tht requirements for service spaces:

- for Type G vessels: 9.3.1.12.3 for Type N vessels: 9.3.3.12.3; . be equipped with a gas detection system

Access and ventilation ~penings 0.50 m above the ieck [ntake valve Filling of cofferdams with PUP

9.3.3.21.1 (b)

referred to in 9.3.1.17.6 or 9.3.3.17.6. N.R.M.

N.R.M. N.R.M.

Type N open N.R.M. Filling of cofferdams within 30 minutes N.R.M. Liquid level gauge Type N apen with flame-arrester 3n board vessels in service fitted with gaugin ~penings,such openings shall: Type N open

. be arranged so that the degree of filling can be measured using a sounding rod;

9.3.3.21.1 (c) 9.3.1.21.1.(d) 9.3.2.21.1 (d) 9.3.3.21.1 (d)

- be fitted with an automatically-closing cover. Not applicable to open Type N vessels in servict permitted only to carry SULPHUR, MOLTEN UN No. 2448. Sensor for actuating the facility Applicable only to vessels to be loaded in 2 Contracting Party where the shore installation i: against overflowing equipped accordingly. Level alarm device

Table of " general transitional ~rovisions:Tank vessels 11.6.7.2.3.1 Subject Time limit and comments Paragraphs Alarm of the instrument for Renewal of certificate of approval after 1 January 9.3.2.21.1 (e) measuring the pressure in each 1999. cargo tank in the event of the carriage of substances for whichdeck spraying is required Instrument for measuring Renewal of the certificate of approval after 1 January 2001. Up to 3 1 December 2010 on pressure in the cargo tank board vessels in service which do not carry substances for which remarks 5, 6 or 7 are included in column (20) of Table C of Chapter3.2, the instrument for measuring pressure in the cargo tank conforms to requirements when the vapour pipe is equipped with such an instrument at its front and rear extremities. Installation of the instrument I Renewal of certificate of approval after 1 January 9.3.2.21.1 (f) for measuring the temperature 1999. 9.3.3.21.1 (f) N.R.M. Sampling opening Type N open 9.3.3.21.1 (g) Independent liquid-level alarm N.R.M. 9.3.1.21.4 device 9.3.2.21.4 9.3.3.21.4 N.R.M. Socket close to the shore 9.3.1.21.5 (a) connections and cut-out of 9.3.2.21.5 (a) vessel's pump 9.3.3.21.5 (a) Installation of on-board pump Renewal of the certificate of approval after 9.3.1.21.5 (b) switch-off from the shore 1 January 2007 9.3.2.21.5 (b) 9.3.3.21.5 (c) Sensor according- to l Renewal of the certificate of approval 9.3.3.21.5 (b) after 1 January 1999. 9.3.3.21.1 (d) Connecting nozzle according to Renewal of the certificate of approval after 9.3.3.21.5 (c) 3 1 December 2002 standard EN 12827 Device for rapid shutting off of Renewal of the certificate of approval after 9.3.3.21.5 (c) 3 1 December 2003 supply N.R.M. Vacuum or over-pressure alarms in cargo tanks for the carriage of substances without remark 5 in column (20) of Table C of Chapter 3.2. N.R.M. Vacuum or over-pressure alarms in cargo tanks for the Vessels furnished with a certificate of approval carriage of substances y i t J valid at 31 December 2000 shall meet these remark 5 in column (20) of requirements no later than 3 1 December 2010. Table C of Chapter 3.2. N.R.M. Temperature alarms in cargo 9.3.1.21.7 tanks 9.3.2.21.7 9.3.3.21.7 N.R.M. Self-closing lid 9.3.3.21.12 N.R.M. Distance of cargo tank 9.3.1.22.1 (b) openings above the deck Cargo tank openings 0.50 m Shall not apply to vessels whose keels were laid 9.3.3.22.1 (b) before l January 1977. above the deck N.R.M. Prevention of spark-formation by closure devices - -

Table of general transitional provisions: Tank vessels .6.7.2.3.1 Subject Time limit and comments Paragraphs Position of outlets of valves N.R.M. 9.3.1.22.3 above the deck 9.3.2.22.4 (b) 9.3.3.22.4 (b) Pressure setting of high l 9.3.2.22.4 (b) N.R.M. velocity vent valves 9.3.3.22.4 (b) Flame arrester or Valves or l 9.3.2.22.5 N.R.M. Individual gas discharge pipe or Vessels furnished with a certificate of approval 9.3.3.22.5 Shut-off devices valid at 31 December 1998 shall meet these requirements no later than 3 1 December 20 10 Fire-fighting installation 3 1 December 20 10 9.3.2.22.5 (a) Test pressure for cargo tanks Shall not apply to vessels whose keels were laid 9.3.3.23.2 1 before 1 January 1977, for which a test pressure of 15 kPa (0.15 bar) is required. A test pressure of 10 kPa (0.10 bar) shall be sufficient. Test pressure for pipes for On board oil-separator vessels in service I before 1 January 1999 a test pressure of 400 kPa loading- and unloading is sufficient. N.R.M. Shut-down of cargo pumps

I l

9.3.3.25.1 9.3.3.25.2 (a) 9.3.1.25.2 (d) 9.3.2.25.2 (d) 9.3.1.25.2 (e) 9.3.2.25.2 (e) 9.3.3.25.2 (e) 9.3.1.25.2 (i) 9.3.2.25.2.G) 9.3.3.25.2 (k) 9.3.2.25.8 (a)

Distance of pumps, etc. from accommodation, etc.

N.R.M.

Pipes for loading and unloading located in the below-deck area Position of loading and unloading pipes on deck Distance of shore connections from accommodation, etc.

N.R.M. for oil-separator vessels N.R.M. N.R.M. I

Position of cargo piping

N.R.M.

Ballasting suction pipes located within the cargo area but outside the cargo tanks Loading and unloading flow

N.R.M.

N.R.M. As from 1 January 2003, the loading flows mentioned in the certificate of approval shall be checked if necessary when the certificate of approval is renewed. N.R.M. 9.3.3.25.1 (a) and (c), 9.3.3.25.2 (e), 9.3.3.25.3 and This time limit concerns only Type N open 9.3.3.25.4 (a) are not applicable vessels carrying corrosive substances (see with the exception of Type N I Chapter 3.2, Table C, column ( 9 , hazard 8). open carrying corrosive substances (see Chapter 3.2, Table C, column (5), hazard 8) I N.R.M. Refrigeration system List i f 12" instead of 10" Water-spray installation 'This transitional requirement is valid only f o ~ required in Table C of substances accepted for carriage in tank vessels before 1 January 1995. Chapter 3.2

1.6.7.2.3.l Table of general transitional provisions: Tank vessels Paragraphs Subject Time limit and comments Distance of engine air intakes 9.3.1.31.2 N.R.M. from the cargo area

I

Temperature of outer parts of N.R.M. engines, etc. The following requirements apply on board vessels in service: The temperature of outer parts shall not exceed 300" C. Temperature in the engine N.R.M. room The following requirements apply on board vessels in service:

l The

temperature in the engine room shall not exceed 45 "C. Openings of air pipes 0.50 m N.R.M. above the deck

I

Exhaust pipes Stripping and ballast pumps in the cargo area I Suction pipes for ballasting located within the cargo area but outside the cargo tanks Stripping installation of the pump-room outside the pumproom Fire extinguishing systems, two pumps, etc. Fixed fire extinguishing system in engine room

9.3.2.41.3 9.3.3.41.2 in conjunction wit1

N.R.M. N.R.M. N.R.M.

N.R.M.

N.R.M.

N.R.M.

Outlets of funnels located not Not applicable to vessels whose keels were laid less than 2 m from the cargo before 1 January 1977. area Outlets of funnels N.R.M. for oil-separator vessels N.R.M. Heating, cooking and refrigerating appliances

N.R.M. The following requirements apply on board vessels in service: This can be achieved by an oil separator fitted to the condensed water return pipe. N.R.M.

Cargo heating system: Type N open

Visual and audible alarm

Temperature class explosion group

and

N.R.M.

general transitional provisions: Subject ~lectricalinstallations:

3nk

vessels Time limit and comments N.R.M.

Electrical installations of the Shall not apply to vessels whose keels were laic "certified safe" type in the before l January 1977. The following condition: shall be met during loading, unloading anc cargo area gas-freeing on board vessels having non-gastigh wheelhouse openings (e.g. doors, windows, etc.: giving on to the cargo area: (a) All electrical installations designed to be usec shall be of a limited explosion-risk type, i.e they shall be so designed that there is nc sparking under normal operating condition: and the temperature of their outer surface5 does not rise above 200" C, or be of a type protected against water spray the temperature of whose outer surfaces does no1 exceed 200" C under normal operating conditions; (b) Electrical installations which do not meet thc requirements of (a) above shall be marked ir red and it shall be possible to switch them ofi bv means of a central switch. N.R.M. Accumulators located outside the cargo area Electrical installations used Shall not apply to the following installation? during loading, unloading or on vessels whose keels were laid before 1 Januarq 1977: gas-freeing Lighting installations in accommodation, with the exception of switches near the entrances tc accommodation; Radio telephone installations in accommodation and wheelhouses and combustion engine control appliances. All other electrical installations shall meet the following requirements: (a) Generators, engines, etc. P 13 protection mode (b) Control panels, lamps, etc. IP23 protection mode (C) Appliances, etc. IP55 protection mode. N.R.M. Type N open N.R.M. Electrical installations used during loading, unloading and On board vessels in service, paragraph (3) (a) 9.3.2.52.3 (b) shall not apply to: gas-freeing 9.3.3.52.3 (b) Lighting installations in accommodation, with in conjunction with the exception of switches near entrances to accommodation; Radiotelephone installations in accommodation and wheelhouses.

'1.6.7.2.3.1 Table of general transitional provisions: ' 'ank vessels Paragraphs Subject Time limit and comments 9.3.1.52.4 Disconnection of such N.R.M. 9.3.2.52.4 installations from a centralized 9.3.3.52.4 location last sentence 9.3.3.52.4 Red mark on electrical N.R.M. installations Type N open Cut-out switch for continuously N.R.M. driven generator: Type N open Permanently fitted sockets: 9.3.3.52.6 N.R.M.

I Metallic sheaths for all cables

9.3.1.56.1 9.3.3.56.1 9.3.3.56.1 9.3.1.56.3

Shall not apply to vessels whose keels were laid I

Metallic sheath Movable cables in the cargo

1.6.7.2.3.2

Transitional provisions concerning the application of the requirements of Table C of Chapter 3.2 to the carriage of goods in tank vessels.

1.6.7.2.3.2.1

The goods for which Type N closed with a minimum valve setting of 10 kPa (0.10 bar) is required in Table C of Chapter 3.2, may be carried in tank-vessels in service of Type N closed with a minimum valve setting of 6 kPa (0.06 bar) (cargo tank test pressure of 10 kPa (0.10 bar)).

1.6.7.2.3.2.2

(Remark 5) On board tank vessels in service, the dismantling of the fixed plate stacks of flame arresters is permitted in the event of the carriage of substances for which remark 5 is included in column (20) of Table C of Chapter 3.2. This transitional provision is valid until 3 1 December 20 10.

1.6.7.2.3.2.3

(Remarks 6 and 7) On board tank vessels in service vapour pipes and pressure/vacuum valves do not need to be heated in the event of the carriage of substances for which remarks 6 or 7 are included in column (20) of Table C of Chapter 3.2. This transitional provision is valid until 30 December 2010. On board vessels equipped with flame arresters with fixed plate stacks, the latter may be dismantled in the event of the carriage of the above-mentioned substances. This transitional provision is valid until 3 1 December 20 10.

1.6.7.3

Supplementary transitionalprovisions applicable to specific inland waterways

1.6.7.3.1

Vessels in service to which the transitional provisions of this subsection are applied shall meet: -

the requirements of paragraphs and subparagraphs mentioned in the table below and in the table of general transitional provisions (see 1.6.7.2.l . l and 1.6.7.2.3.1) within the period established therein;

-

the requirements of paragraphs and subparagraphs not mentioned in the table below or in the table of general transitional provisions at the date of application of these Regulations.

The construction and equipment of vessels in service shall be maintained at least at the previous standard of safety.

Paragraph 9.1.0.11.1 (b)

9.1.0.95.1 (c)

9.3.1.11.1 (a) 9.3.2.1 1.1 (a) 9.3.3.1 1.1 (a)

able of supplementary transitional 1 wisions Subject Time limit and comments Holds, common bulkheads with N.R.M. oil fuel tanks The following requirements apply on board vessels in service: Holds may share a common bulkhead with the oil fuel tanks, provided that the cargo or its packaging does not react chemically with the fuel. Emergency exit N.R.M. The following requirements apply on board vessels in service: Spaces the entrances or exits of which are partly or fully immersed in damaged condition shall be provided with an emergency exit not less than 0.075 m above the damage waterline. Height of openings above N.R.M. damage waterline The following requirements apply on board vessels in service: The lower edge of any nonwatertight openings (e.g. doors, windows, access hatchways) shall, at the final stage of flooding, be not less than 0.075 m above the damage waterline. Extent of the stability diagram N.R.M. (damaged condition) The following requirements apply on board vessels in service: At the final stage of flooding the angle of heel shall not exceed: 20" before measures to right the vessel; 12" following measures to right the vessel. Classification of Type N open N.R.M. vessels Maximum capacity of cargo N.R.M. tanks. The following requirements apply on board vessels in service: The maximum permissible capacity of a cargo tank shall be 760 m3.

T; Le of supplementary transitional p Paragraph 9.3.1.12.3 9.3.2.12.3 9.3.3.12.3

9.3.2.1 1.1 (d)

9.3.3.8.1 9.3.2.15.1 (c)

Time limit and comments N.R.M. The following requirements apply on board vessels in service: The air inlets to be positioned at least 5.00 m from the safety-valve outlets N.R.M. Length of cargo tanks The following requirements apply on board vessels in service: The length of a cargo tank may exceed 10 m and 0.2 L. N.R.M. Classification of Type N open vessels N.R.M. Height of openings above The following requirements apply damage waterline on board vessels in service: The lower edge of any non-watertight openings (e.g. doors, windows, access hatchways) shall, at the final stage of flooding, be not less than 0.075 m above the damage waterline. N.R.M. Filling of cofferdams with water The following requirements apply on board vessels in service: Cofferdams shall be fitted with a system for filling with water or inert gas. N.R.M. Emergency Exit The following requirements apply on board vessels in service: Spaces the entrances or exits of which are partly or fully immersed in damaged condition shall be provided with an emergency exit not less than 0.075 m above the damage waterline. Subject Position of air inlets

CHAPTER 1.7 GENERAL REQUIREMENTS CONCERNING CLASS 7 1.7.1

General

1.7.1.1

ADN establishes standards of safety which provide an acceptable level of control of the radiation, criticality and thermal hazards to persons, property and the environment that are associated with the carriage of radioactive material. These standards are based on the IAEA Regulations for the Safe Transport of Radioactive Material, 2005 edition, Safety Standards Series No. TS-R-1, IAEA, Vienna (2005). Explanatory material can be found in the "Advisory Material for the IAEA Regulations for the Safe Transport of Radioactive Material", Safety Standard Series No. TS-G- l. 1 (ST-2), IAEA, Vienna (2002).

1.7.1.2

The objective of ADN is to protect persons, property and the environment from the effects of radiation during the carriage of radioactive material. This protection is achieved by requiring: (a)

Containment of the radioactive contents;

(b)

Control of external radiation levels;

(c)

Prevention of criticality; and

(d)

Prevention of damage caused by heat.

These requirements are satisfied firstly by applying a graded approach to contents limits for packages and vehicles and to performance standards applied to package designs depending upon the hazard of the radioactive contents. Secondly, they are satisfied by imposing requirements on the design and operation of packages and on the maintenance of packagings, including a consideration of the nature of the radioactive contents. Finally, they are satisfied by requiring administrative controls including, where appropriate, approval by competent authorities. 1.7.1.3

ADN applies to the carriage of radioactive material by inland waterways including carriage which is incidental to the use of the radioactive material. Carriage comprises all operations and conditions associated with and involved in the movement of radioactive material; these include the design, manufacture, maintenance and repair of packaging, and the preparation, consigning, loading, carriage including in-transit storage, unloading and receipt at the final destination of loads of radioactive material and packages. A graded approach is applied to the performance standards in ADN that is characterized by three general severity levels: (a)

Routine conditions of carriage (incident free);

(b)

Normal conditions of carriage (minor mishaps);

(c)

Accident conditions of carriage.

1.7.2

Radiation protection programme

1.7.2.1

The carriage of radioactive material shall be subject to a Radiation protection programme which shall consist of systematic arrangements aimed at providing adequate consideration of radiation protection measures.

1.7.2.2

The nature and extent of the measures to be employed in the programme shall be related to the magnitude and likelihood of radiation exposures. The programme shall incorporate the

- 65 -

requirements in 1.7.2.3, 1.7.2.4 and CV33 (1.1) of 7.5.1 1 of ADR and applicable emergency response procedures. Programme documents shall be available, on request, for inspection by the relevant competent authority. Doses to persons shall be below the relevant dose limits. Protection and safety shall be optimized in order that the magnitude of individual doses, the number of persons exposed, and the likelihood of incurring exposure shall be kept as low as reasonably achievable, economic and social factors being taken into account, within the restriction that the doses to individuals be subject to dose constraints. A structured and systematic approach shall be adopted and shall include consideration of the interfaces between carriage and other activities. For occupational exposures arising from transport activities, where it is assessed that the effective dose: (a)

is likely to be between 1 mSv and 6 mSv in a year, a dose assessment programme via work place monitoring or individual monitoring shall be conducted;

(b)

is likely to exceed 6 mSv in a year, individual monitoring shall be conducted.

When individual monitoring or work place monitoring is conducted, appropriate records shall be kept.

Quality assurance Quality assurance programmes based on international, national or other standards acceptable to the competent authority shall be established and implemented for the design, manufacture, testing, documentation, use, maintenance and inspection of all special form radioactive material, low dispersible radioactive material and packages and for carriage and in-transit storage operations to ensure compliance with the relevant provisions of ADN. Certification that the design specification has been fully implemented shall be available to the competent authority. The manufacturer, consignor or user shall be prepared to provide facilities for competent authority inspection during manufacture and use and to demonstrate to any cognizant competent authority that: (a)

the manufacturing methods and materials used are in accordance with the approved design specifications; and

(b)

all packagings are periodically inspected and, as necessary, repaired and maintained in good condition so that they continue to comply with all relevant requirements and specifications, even after repeated use.

Where competent authority approval is required, such approval shall take into account and be contingent upon the adequacy of the quality assurance programme.

Special arrangement Special arrangement shall mean those provisions, approved by the competent authority, under which consignments of radioactive material which do not satisfy all the applicable requirements of ADN may be transported. NOTE: Special arrangement is not considered to be a temporary derogation in accordance with 1.5.1. Consignments for which conformity with any provision applicable to Class 7 is impracticable shall not be transported except under special arrangement. Provided the

competent authority is satisfied that conformity with the Class 7 provisions of ADN is impracticable and that the requisite standards of safety established by ADN have been demonstrated through alternative means the competent authority may approve special arrangement transport operations for single or a planned series of multiple consignments. The overall level of safety in carriage shall be at least equivalent to that which would be provided if all the applicable requirements had been met. For international consignments of this type, multilateral approval shall be required.

Radioactive material possessing other dangerous properties In addition to the radioactive and fissile properties, any subsidiary risk of the contents of the package, such as explosiveness, flammability, pyrophoricity, chemical toxicity and corrosiveness, shall also be taken into account in the documentation, packing, labelling, marking, placarding, stowage, segregation and carriage, in order to be in compliance with all relevant provisions for dangerous goods of ADN.

In the event of a non-compliance with any limit in ADN applicable to radiation level or contamination, (a)

(b)

The consignor shall be informed of the non-compliance (i)

by the carrier if the non-compliance is identified during carriage; or

(ii)

by the consignee if the non-compliance is identified at receipt;

The carrier, consignor or consignee, as appropriate shall: (i)

take immediate steps to mitigate the consequences of the non-compliance;

(ii)

investigate the non-compliance and its causes, circumstances and consequences;

(iii) take appropriate action to remedy the causes and circumstances that led to the non-compliance and to prevent a recurrence of similar circumstances that led to the non-compliance; and (iv) communicate to the competent authority(ies) on the causes of the noncompliance and on corrective or preventive actions taken or to be taken; and (c)

The communication of the non-compliance to the consignor and competent authority(ies), respectively, shall be made as soon as practicable and it shall be immediate whenever an emergency exposure situation has developed or is developing.

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CHAPTER 1.8 CHECKS AND OTHER SUPPORT MEASURES TO ENSURE COMPLIANCE WITH SAFETY REQUIREMENTS Monitoring compliance with requirements General In accordance with Article 4, paragraph 3 of ADN, Contracting Parties shall ensure that a representative proportion of consignments of dangerous goods carried by inland waterways is subject to monitoring in accordance with the provisions of this Chapter, and including the requirements of 1.10.1.5. Participants in the carriage of dangerous goods (see Chapter 1.4) shall, without delay, in the context of their respective obligations, provide the competent authorities and their agents with the necessary information for carrying out the checks. Monitoring procedure In order to carry out the checks provided for in Article 4, paragraph 3 of ADN, the Contracting Parties shall use the checklist to be developed by the Administrative Committee. A copy of this checklist or a certificate showing the result of the check drawn up by the competent authority which carried it out shall be given to the master of the vessel and presented on request in order to simplify or avoid, where possible, subsequent checks. This paragraph shall not prejudice Contracting Parties' right to carry out specific measures for detailed checks. The checks shall be random and shall as far as possible cover an extensive portion of the inland waterway network. When exercising the right to monitor, the authorities shall make all possible efforts to avoid unduly detaining or delaying a vessel. Infringements of the requirements Without prejudice to other penalties which may be imposed, vessels in respect of which one or more infringements of the rules on the transport of dangerous goods by inland waterways are established may be detained at a place designated for this purpose by the authorities carrying out the check and required to be brought into conformity before continuing their journey or may be subject to other appropriate measures, depending on the circumstances or the requirements of safety. Checks in companies and atplaces of loading and unloading Checks may be carried out at the premises of undertakings, as a preventive measure or where infringements which jeopardize safety in the transport of dangerous goods have been recorded during the voyage. The purpose of such checks shall be to ensure that safety conditions for the transport of dangerous goods by inland waterways comply with the relevant laws.

Sampling Where appropriate and provided that this does not constitute a safety hazard, samples of the goods transported may be taken for examination by laboratories recognized by the competent authority. 1.8.1.4.4

Cooperation of the competent authorities

1.8.1.4.4.1

Contracting Parties shall assist one another in order to give proper effect to these requirements.

1.8.1.4.4.2

Serious or repeated infringements jeopardizing the safety of the transport of dangerous goods committed by a foreign vessel or undertaking shall be reported to the competent authority in the Contracting Party where the certificate of approval of the vessel was issued or where the undertaking is established.

1.8.1.4.4.3

The competent authority of the Contracting Party where serious or repeated infringements have been recorded may ask the competent authority of the Contracting Party where the certificate of approval of the vessel was issued or where the undertaking is established for appropriate measures to be taken with regard to the offender or offenders.

1.8.1.4.4.4

The latter competent authority shall notify the competent authorities of the Contracting Party where the infringements were recorded of any measures taken with regard to the offender or offenders.

Administrative assistance during the checking of a foreign vessel If the findings of a check on a foreign vessel give grounds for believing that serious or repeated infringements have been committed which cannot be detected in the course of that check in the absence of the necessary data, the competent authorities of the Contracting Parties concerned shall assist one another in order to clarify the situation.

Safety adviser Each undertaking, the activities of which include the carriage, or the related packing, loading, filling or unloading, of dangerous goods by inland waterways shall appoint one or more safety advisers, hereinafter referred to as "advisers", for the carriage of dangerous goods, responsible for helping to prevent the risks inherent in such activities with regard to persons, property and the environment. The competent authorities of the Contracting Parties may provide that these requirements shall not apply to undertakings: (a)

the activities of which concern quantities in each transport unit smaller than those referred to in 1.1.3.6,2.2.7.1.2 and in Chapters 3.3 and 3.4; or

(b)

the main or secondary activities of which are not the carriage or the related loading or unloading of dangerous goods but which occasionally engage in the national carriage or the related loading or unloading of dangerous goods posing little danger or risk of pollution.

The main task of the adviser shall be, under the responsibility of the head of the undertaking, to seek by all appropriate means and by all appropriate action, within the limits of the relevant activities of that undertaking, to facilitate the conduct of those activities in accordance with the requirements applicable and in the safest possible way.

With regard to the undertaking's activities, the adviser has the following duties in particular: -

monitoring compliance with the requirements governing the carriage of dangerous goods;

-

advising his undertaking on the carriage of dangerous goods;

-

preparing an annual report to the management of his undertaking or a local public authority, as appropriate, on the undertaking's activities in the carriage of dangerous goods. Such annual reports shall be preserved for five years and made available to the national authorities at their request.

The adviser's duties also include monitoring the following practices and procedures relating to the relevant activities of the undertaking: the procedures for compliance with the requirements governing the identification of dangerous goods being transported; the undertaking's practice in taking account, when purchasing means of transport, of any special requirements in connection with the dangerous goods being transported; the procedures for checking the equipment used in connection with the carriage, loading or unloading of dangerous goods; the proper training of the undertaking's employees and the maintenance of records of such training; the implementation of proper emergency procedures in the event of any accident or incident that may affect safety during the carriage, loading or unloading of dangerous goods; investigating and, where appropriate, preparing reports on serious accidents, incidents or serious infringements recorded during the carriage, loading or unloading of dangerous goods; the implementation of appropriate measures to avoid the recurrence of accidents, incidents or serious infringements; the account taken of the legal prescriptions and special requirements associated with the carriage of dangerous goods in the choice and use of sub-contractors or third parties; verification that employees involved in the carriage, loading or unloading of dangerous goods have detailed operational procedures and instructions, the introduction of measures to increase awareness of the risks inherent in the carriage, loading and unloading of dangerous goods; the implementation of verification procedures to ensure the presence on board, means of transport of the documents and safety equipment which must accompany transport and the compliance of such documents and equipment with the regulations; the implementation of verification procedures to ensure compliance with the requirements governing loading and unloading; the existence of the security plan indicated in 1.10.3.2.

The safety adviser may also be the head of the undertaking, a person with other duties in the undertaking, or a person not directly employed by that undertaking, provided that that person is capable of performing the duties of adviser. Each undertaking concerned shall, on request, inform the competent authority or the body designated for that purpose by each Contracting Party of the identity of its adviser. Whenever an accident affects persons, property or the environment or results in damage to property or the environment during carriage, loading or unloading carried out by the undertaking concerned, the safety adviser shall, after collecting all the relevant information, prepare an accident report to the management of the undertaking or to a local public authority, as appropriate. That report shall not replace any report by the management of the undertaking which might be required under any other international or national legislation.

A safety adviser shall hold a vocational training certificate, valid for transport by inland waterways. That certificate shall be issued by the competent authority or the body designated for that purpose by each Contracting Party. To obtain a certificate, a candidate shall undergo training and pass an examination approved by the competent authority of the Contracting Party. The main aims of the training shall be to provide candidates with sufficient knowledge of the risks inherent in the carriage of dangerous goods, of the laws, regulations and administrative provisions applicable to the modes of transport concerned and of the duties listed in 1.8.3.3. 1.8.3.10

The examination shall be organized by the competent authority or by an examining body designated by the competent authority. The examining body shall not be a training provider. The examining body shall be designated in writing. This approval may be of limited duration and shall be based on the following criteria:

1.8.3.1 1

-

competence of the examining body;

-

specifications of the form of the examinations the examining body is proposing;

-

measures intended to ensure that examinations are impartial;

-

independence of the body from all natural or legal persons employing safety advisers.

The aim of the examination is to ascertain whether candidates possess the necessary level of knowledge to carry out the duties incumbent upon a safety adviser as listed in 1A.3.3, for the purpose of obtaining the certificate prescribed in subsection 1.8.3.7, and it shall cover at least the following subjects: (a)

Knowledge of the types of consequences which may be caused by an accident involving dangerous goods and knowledge of the main causes of accidents;

(b)

Requirements under national law, international conventions and agreements, with regard to the following in particular:

-

classification of dangerous goods (procedure for classifying solutions and mixtures, structure of the list of substances, classes of dangerous goods and principles for their classification, nature of dangerous goods transported, physical, chemical and toxicological properties of dangerous goods);

-

general packing provisions, provisions for tanks and tank-containers (types, code, marking, construction, initial and periodic inspection and testing);

-

marking and labelling, placarding and orange plates marking (marking and labelling of packages, placing and removal of placards and orange plates);

-

particulars in transport documents (information required);

-

method of consignment and restrictions on dispatch (full load, carriage in bulk, carriage in intermediate bulk containers, carriage in containers, carriage in fixed or demountable tanks);

-

transport of passengers;

-

prohibitions and precautions relating to mixed loading;

-

segregation of goods;

-

limitation of the quantities carried and quantities exempted;

-

handling and stowage (loading and unloading segregation);

-

cleaning andlor degassing before loading and after unloading;

-

crews, vocational training;

-

vehicle documents (transport document, instructions in writing, vessel approval certificate, ADN dangerous goods training certificate, copies of any derogations, other documents);

-

instructions in writing (implementation of the instructions and crew protection equipment);

-

supervision requirements (parking);

-

traffic regulations and restrictions;

-

operational discharges or accidental leaks of pollutants;

-

requirements relating to equipment for transport by vessel.

-

filling ratios -, stowage and

1.8.3.12

Examinations

1.8.3.12.1

The examination shall consist of a written test which may be supplemented by an oral examination.

1.8.3.12.2

The use in the written test of documentation other than international or national regulations is not permitted.

1.8.3.12.3

Electronic media may be used only if provided by the examining body. There shall be no means of a candidate introducing further data to the electronic media provided; the candidate may only answer to the questions posed.

1.8.3.12.4

The written test shall consist of two parts: (a)

(b)

1.8.3.13

Candidates shall receive a questionnaire. It shall include at least 20 open questions covering at least the subjects mentioned in the list in 1.8.3.11. However, multiple choice questions may be used. In this case, two multiple choice questions count as one open question. Amongst these subjects particular attention shall be paid to the following subjects: -

general preventive and safety measures;

-

classification of dangerous goods;

-

general packing provisions, including tanks, tank-containers, tank-vehicles, etc.;

-

danger markings and labels;

-

information in transport document;

-

handling and stowage;

-

crew, vocational training;

-

vehicle documents and transport certificates;

-

instructions in writing;

-

requirements concerning equipment for transport by vessel;

Candidates shall undertake a case study in keeping with the duties of the adviser referred to in 1.8.3.3, in order to demonstrate that they have the necessary qualifications to fulfil the task of adviser.

The Contracting Parties may decide that candidates who intend working for undertakings specializing in the carriage of certain types of dangerous goods need only be questioned on the substances relating to their activities. These types of goods are: -

Class 1;

-

Class 2;

-

Class 7; Classes 3,4.1,4.2,4.3, 5.1, 5.2, 6.1, 6.2, 8 and 9; UN Nos. 1202, 1203 and 1223.

The certificate prescribed in 1.8.3.7 shall clearly indicate that it is only valid for one type of the dangerous goods referred to in this subsection and on which the adviser has been questioned under the conditions defined in 1.8.3.12. 1.8.3.14

The competent authority or the examining body shall keep a running list of the questions that have been included in the examination.

1.8.3.15

The certificate prescribed in 1.8.3.7 shall take the form laid down in 1.8.3.18 and shall be recognized by all Contracting Parties.

1.8.3.16

Validity and renewal of certifiates

1.8.3.16.1

The certificate shall be valid for five years. The period of the validity of a certificate shall be extended from the date of its expiry for five years at a time where, during the year before its expiry, its holder has passed an examination. The examination shall be approved by the competent authority.

1.8.3.16.2

The aim of the examination is to ascertain that the holder has the necessary knowledge to carry out the duties set out in 1.8.3.3. The knowledge required is set out in 1.8.3.1 1 (b) and shall include the amendments to the regulations introduced since the award of the last certificate. The examination shall be held and supervised on the same basis as in 1.8.3.10 and 1.8.3.12 to 1.8.3.14. However, holders need not undertake the case study specified in 1.8.3.12.4 (b).

1.8.3.17

The requirements set out in 1.8.3.1 to 1.8.3.16 shall be considered to have been fulfilled if the relevant conditions of Council Directive 96/35/EC of 3 June 1996 on the appointment and vocational qualification of safety advisers for the transport of dangerous goods by road, rail and inland waterway1 and of Directive 2000/18/EC of the European Parliament and of the Council of 17 April 2000 on minimum examination requirements for safety advisers for the transport of dangerous goods by road, rail or inland waterway are applied.

OfJicial Journal of the European Communities, No. L1 45 of 19 June 1996, page 10. 2

Official Journal of the European Communities, No. L118 of 19 May 2000, page 41.

- 75 -

Form of certificate Certificate of training as safety adviser for the transport of dangerous goods Certificate No: .......................................................................................................................................... Distinguishing sign of the State issuing the certificate: ............................................................................ Surname: ...................................................................................................................................................

Date and place of birth: ............................................................................................................................ Nationality: ................................................................................................................................................ Signature of holder: .................................................................................................................................. Valid until ................for undertakings which transport dangerous goods and for undertakings which carry out related loading or unloading: by road

by rail

by inland waterway

Issued by: .................................................................................................................................................. Date: ....................................................

Signature: .........................................................

Extended until: ....................................

By: ....................................................................

Date: ...................................................

Signature: .........................................................

List of competent authorities and bodies designated by them The Contracting Parties shall communicate to the secretariat of the UnitedNations Economic Commission for Europe the addresses of the authorities and bodies designated by them which are competent in accordance with national law to implement ADN, referring in each case to the relevant requirement of ADN and giving the addresses to which the relevant applications should be made. The secretariat of the United Nations Economic Commission for Europe shall establish a list on the basis of the information received and shall keep it up-to-date. It shall communicate this list and the amendments thereto to the Contracting Parties.

Notifications of occurrences involving dangerous goods If a serious accident or incident takes place during loading, filling, carriage or unloading of dangerous goods on the territory of a Contracting Party, the loader, filler, carrier or consignee, respectively, shall ascertain that a report is made to the competent authority of the Contracting Party concerned. The Contracting Party shall in turn, if necessary, make a report to the secretariat of the United Nations Economic Commission for Europe with a view to informing the other Contracting Parties. An occurrence subject to report in accordance with 1.8.5.1 has occurred if dangerous goods were released or if there was an imminent risk of loss of product, if personal injury, material or environmental damage occurred, or if the authorities were involved and one or more of the following criteria hashave been met: Personal injury means an occurrence in which death or injury directly relating to the dangerous goods carried has occurred, and where the injury (a)

requires intensive medical treatment,

(b)

requires a stay in hospital of at least one day, or

(c)

results in the inability to work for at least three consecutive days.

Loss ofproduct means the release of dangerous goods (a)

substances of Classes 1 or 2 or packing group I in quantities of 50 kg or 50 litres or more, or other substances not assigned to a packing group;

(b) substances of packing group I1 in quantities of 333 kg or 333 litres or more; or (c)

substances of packing group 111 in quantities of 1,000 kg or 1,000 litres or more.

The loss of product criterion also applies if there was an imminent risk of loss of product in the above-mentioned quantities. As a rule, this has to be assumed if, owing to structural damage, the means of containment is no longer suitable for further carriage or if, for any other reason, a sufficient level of safety is no longer ensured (e.g. owing to distortion of tanks or containers, overturning of a tank or fire in the immediate vicinity). If dangerous goods of Class 6.2 are involved, the obligation to report applies without quantity limitation. In occurrences involving Class 7 material, the criteria for loss of product are:

Any release of radioactive material from the packages; Exposure leading to a breach of the limits set out in the regulations for protection of workers and members of the public against ionizing radiation (Schedule I1 of IAEA Safety Series No. 115 - "International Basic Safety Standards for Protection Against Ionizing Radiation and for Safety of Radiation Sources"); or Where there is reason to believe that there has been a significant degradation in any package safety function (containment, shielding, thermal protection or criticality) that may have rendered the package unsuitable for continued carriage without additional safety measures. NOTE: See the provisions of 7.5.11 CV33 (6) of ADR or of 7.5.11 CW33 (6) of RID for undeliverable consignments. Material damage or environmental damage means the release of dangerous goods, irrespective of the quantity, where the estimated amount of damage exceeds 50,000 Euros. Damage to any directly involved means of carriage containing dangerous goods and to the modal infrastructure shall not be taken into account for this purpose. Involvement of authorities means the direct involvement of the authorities or emergency services during the occurrence involving dangerous goods and the evacuation of persons or closure of public traffic routes (roadslrailways) for at least three hours owing to the danger posed by the dangerous goods. If necessary, the competent authority may request further relevant information. The Contracting Parties may establish a standard format for these reports.

CHAPTER 1.9 TRANSPORT RESTRICTIONS BY THE COMPETENT AUTHORITIES In accordance with Article 6, paragraph l of ADN, the entry of dangerous goods into the territory of Contracting Parties may be subject to regulations or prohibitions imposed for reasons other than safety during carriage. Such regulations or prohibitions shall be published in an appropriate form. Subject to the provisions of 1.9.3, a Contracting Party may apply to vessels engaged in the international camage of dangerous goods by inland waterways on its territory certain additional provisions not included in ADN, provided that those provisions do not conflict with Article 4, paragraph 2 of the Agreement, and are contained in its domestic legislation applying equally to vessels engaged in the domestic carriage of dangerous goods by inland waterways on the territory of that Contracting Party. Additional provisions falling within the scope of 1.9.2 are as follows: (a)

Additional safety requirements or restrictions concerning vessels using certain structures such as bridges or tunnels, or vessels entering or leaving ports or other transport terminals;

(b)

Requirements for vessels to follow prescribed routes to avoid commercial or residential areas, environmentally sensitive areas, industrial zones containing hazardous installations or inland waterways presenting severe physical hazards;

(c)

Emergency requirements regarding routeing or parking of vessels canying dangerous goods resulting from extreme weather conditions, earthquake, accident, industrial action, civil disorder or military hostilities;

(d)

Restrictions on movement of vessels carrying dangerous goods on certain days of the week or year.

The competent authority of the Contracting Party applying on its territory any additional provisions within the scope of 1.9.3 (a) and (d) above shall notify the secretariat of the United Nations Economic Commission for Europe of the additional provisions, which secretariat shall bring them to the attention of the Contracting Parties.

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CHAPTER 1.10 SECURITY PROVISIONS NOTE: For the purposes of this Chapter, "security" means measures or precautions to be taken to minimise theft or misuse of dangerous goods that may endanger persons, property or the environment.

General provisions All persons engaged in the carriage of dangerous goods shall consider the security requirements set out in this Chapter commensurate with their responsibilities. Dangerous goods shall only be offered for carriage to carriers that have been appropriately identified. Holding areas in trans-shipment zones for dangerous goods shall be secured, well lit and, where possible and appropriate, not accessible to the general public. For each crew member of a vessel carrying dangerous goods, means of identification, which includes a photograph, shall be on board during carriage. Safety checks in accordance with 1.8.1 shall also concern the implementation of security measures. The competent authority shall maintain up-to-date registers of all valid certificates for experts stipulated in 8.2.1 issued by it or by any recognized organization.

Security training The training and the refresher training specified in Chapter 1.3 shall also include elements of security awareness. The security refresher training need not be linked to regulatory changes only. Security awareness training shall address the nature of security risks, recognising security risks, methods to address and reduce such risks and actions to be taken in the event of a security breach. It shall include awareness of security plans (if appropriate) commensurate with the responsibilities and duties of individuals and their part in implementing security plans.

Provisions for high consequence dangerous goods NOTE: "High consequence dangerous goods" are those which have the potential for misuse in a terrorist incident and which may, as a result, produce serious consequences such as mass casualties or mass destruction. The list of high consequence dangerous goods is provided in Table 1.10.5. Security plans

1.10.3.2.1

Carriers, consignors and other participants specified in 1.4.2 and 1.4.3 engaged in the carriage of high consequence dangerous goods (see Table 1.10.5) shall adopt, implement and comply with a security plan that addresses at least the elements specified in 1.10.3.2.2.

l . 10.3.2.2

The security plan shall comprise at least the following elements:

specific allocation of responsibilities for security to competent and qualified persons with appropriate authority to carry out their responsibilities; records of dangerous goods or types of dangerous goods concerned; review of current operations and assessment of security risks, including any stops necessary to the transport operation, the keeping of dangerous goods in the vessel, tank or container before, during and after the journey and the intermediate temporary storage of dangerous goods during the course of intermodal transfer or transshipment between units; clear statement of measures that are to be taken to reduce security risks, commensurate with the responsibilities and duties of the participant, including:

-

training;

-

security policies (e.g. response to employee/employment verification, etc.);

-

operating practices (e.g. choiceluse of routes where known, access to dangerous goods in intermediate temporary storage (as defined in (c)), proximity to vulnerable infrastructure etc.);

-

equipment and resources that are to be used to reduce risks;

higher

threat

conditions,

new

effective and up to date procedures for reporting and dealing with security threats, breaches of security or security incidents; procedures for the evaluation and testing of security plans and procedures for periodic review and update of the plans; measures to ensure the physical security of transport information contained in the security plan; and measures to ensure that the distribution of information relating to the transport operation contained in the security plan is limited to those who need to have it. Such measures shall not preclude the provision of information required elsewhere in ADN. NOTE: Carriers, consignors and consignees should co-operate with each other and with competent authorities to exchange threat information, apply appropriate security measures and respond to security incidents. 1.10.3.3

Operational or technical measures shall be taken on vessels carrying high consequence dangerous goods referred to in 1.10.5 in order to prevent the improper use of the vessel and of the dangerous goods. The application of these protective measures shall not jeopardize emergency response. NOTE: When appropriate and already fitted, the use of transport telemetry or other tracking methods or devices should be used to monitor the movement of high consequence dangerous goods (see Table I .I 0.5). The requirements of 1.10.1, 1.10.2 and 1.10.3 do not apply when the quantities carried in packages on a vessel do not exceed those referred to in 1.1.3.6.1. High consequence dangerous goods are those listed in the table below and carried in quantities greater than those indicated therein.

Table 1.10.5: List of high consequence dangerous goods

Substance or article

Zlass Division

Quantity Goods in ~ulk-?! packages (kg) (kg)

Tank or cargo tank (litres)

1

a

a

a

a

a

a

0 3000

a

0 0 0 0

I

1.3 1.5 2

3

I

Compatibility group C explosives Explosives Flammable gases (classification codes including only letter F) Toxic gases (classification codes including letter(s) T, TF, TC, TO, TFC or TOC) excluding aerosols Flammable liquids of packing groups I and I1 Desensitized explosives Desensitized explosives Packing group I substances Packing group I substances Oxidizing liquids of packing group I Perchlorates, ammonium nitrate and ammonium nitrate fertilizers Toxic substances of packing group I Infectious substances of Category A (UN Nos. 28 l 4 and 2900) Radioactive material

Corrosive substances of packing group 1

0

3000

l

a

l

a

l

a

a

0 0

3000 3000 3000 3000

a

b

a

b

a

b

3000

b

0

a

a

0

0 0

3000 AI (special form) or 3000 AZ,as applicable, in Type B(U), B(M) or C packages a b 3000

1

*/ -

Bulk means bulk in the vessel, or bulk in a vehicle or a container.

a b

Not relevant. The provisions of 1.10.3 do not apply, whatever the quantity is.

For radioactive material, the provisions of this Chapter are deemed to be complied with when the provisions of the Convention on Physical Protection of Nuclear Material and of IAEA INFCIRCl225 (Rev.4) are applied.

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CHAPTERS 1.11 to 1.14

(Reserved)

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CHAPTER 1.15 RECOGNITION OF CLASSIFICATION SOCIETIES General In the event of the conclusion of an international agreement concerning more general regulations or the navigation of vessels on inland waterways and containing provisions relating to the full range of activities of classification societies and their recognition, any provision of this Chapter in contradiction with any of the provisions of the said international agreement would, in the relations among Parties to this Agreement which had become parties to the international agreement and as from the day of the entry into force of the latter, automatically be deleted and replaced ipso facto by the relevant provision of the international agreement. This Chapter would become null and void once the international agreement came into force if all Parties to this Agreement became Parties to the international agreement.

1.15.2

Procedure for the recognition of classification societies

1.15.2.1

A classification society which wishes to be recommended for recognition under this Agreement shall submit its application for recognition, in accordance with the provisions of this Chapter, to the competent authority of a Contracting Party. The classification society shall prepare the relevant information in accordance with the provisions of this Chapter. It shall produce it in, at least, an official language of the State where the application is submitted and in English. The Contracting Party shall forward the application to the Administrative Committee unless in its opinion the conditions and criteria referred to in 1.15.3 have manifestly not been met.

1.15.2.2

The Administrative Committee shall appoint a Committee of Experts and determine its composition and its rules of procedure. This Committee of Experts shall consider the proposal; it shall determine whether the classification society meets the criteria set out in 1.15.3 and shall make a recommendation to the Administrative Committee within a period of six months.

1.15.2.3

The Administrative Committee shall examine the report of the experts. It shall decide in accordance with the procedure set out in Article 17,7(c), within one year maximum, whether or not to recommend to the Contracting Parties that they should recognize the classification society in question. The Administrative Committee shall establish a list of the classification societies recommended for recognition by the Contracting Parties.

1.15.2.4

Each Contracting Party may or may not decide to recognize the classification societies in question, only on the basis of the list referred to in 1.15.2.3. The Contracting Party shall inform the Administrative Committee and the other Contracting Parties of its decision. The Administrative Committee shall update the list of recognitions issued by Contracting Parties.

1.15.2.5

If a Contracting Party considers that a classification society no longer meets the conditions and criteria set out in 1.15.3, it may submit a proposal to the Administrative Committee for withdrawal from the list of recommended societies. Such a proposal shall be substantiated by convincing evidence of a failure to meet the conditions and criteria.

The Administrative Committee shall set up a new Committee of Experts following the procedure set out under 1.15.2.2 which shall report to the Administrative Committee within a period of six months. The Administrative Committee may decide, according to Article 17, 7 (c), to withdraw the name of the society in question from the list of societies recommended for recognition. In such a case the society in question shall immediately be so informed. The Administrative Committee shall also inform all the Contracting Parties that the classification society in question no longer meets the requirements to act as a recognized classification society in the context of the Agreement and shall invite them to take the necessary steps in order to remain in conformity with the requirements of the Agreement.

Conditions and criteria for the recognition of a classification society applying for recognition under this Agreement A classification society applying for recognition under this Agreement shall meet all the following conditions and criteria: A classification society shall be able to demonstrate extensive knowledge of and experience in the assessment of the design and construction of inland navigation vessels. The society should have comprehensive rules and regulations for the design, construction and periodical inspection of vessels. These rules and regulations shall be published and continuously updated and improved through research and development programmes. Registers of the vessels classified by the classification society shall be published annually The classification society shall not be controlled by shipowners or shipbuilders, or by others engaged commercially in the manufacture, fitting out, repair or operation of ships. The classification society shall not be substantially dependent on a single commercial enterprise for its revenue. The headquarters or a branch of the classification society authorized and entitled to give a ruling and to act in all areas incumbent on it under the regulations governing inland navigation shall be located in one of the Contracting Parties. The classification society and its experts shall have a good reputation in inland navigation; the experts shall be able to provide proof of their professional abilities. The classification society: -

shall have sufficient professional staff and engineers for the technical tasks of monitoring and inspection and for the tasks of management, support and research, in proportion to the tasks and the number of vessels classified and sufficient to keep regulations up to date and develop them in the light of quality requirements;

-

shall have experts in at least two Contracting Parties.

The classification society shall be governed by a code of ethics. The classification society shall have prepared and implemented and shall maintain an effective system of internal quality based on the relevant aspects of internationally recognized quality standards and conforming to the standards EN: 45004: 19% (control mechanisms) and IS0 9001 or EN 29001:1997. The classification society is subject to certification of its quality system by an independent body of auditors recognized by the administration of the State in which it is located.

1.15.4

Obligations of recommended classification societies

1.15.4.1

Recommended classification societies shall undertake to cooperate with each other so as to guarantee the equivalence of their technical standards and their implementation.

1.15.4.2

Recommended classification societies shall undertake to bring their requirements into line with the present and future provisions of this Agreement.

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CHAPTER 1.16 PROCEDURE FOR THE ISSUE OF THE CERTIFICATE OF APPROVAL Certificate of approval General Dry cargo vessels carrying dangerous goods in quantities greater than exempted quantities, the vessels referred to in 7.1.2.19. 1, tank vessels carrying dangerous goods and the vessels referred to in 7.2.2.19.3 shall be provided with an appropriate certificate of approval. The certificate of approval shall be valid for not more than five years, subject to the provisions of 1.16.11.

Format of the certificate of approval, particulars to be included The certificate of approval shall conform to the model 8.6.1.1 or 8.6.1.3 and include the required particulars, as appropriate. It shall include the date of expiry of the period of validity. The certificate of approval shall attest that the vessel has been inspected and has its construction and equipment comply with the applicable provisions of Part 9 of ADN. All particulars for amendments to the certificate of approval provided for in these Regulations and in the other regulations drawn up by mutual agreement by the Contracting Parties may be entered in the certificate by the competent authority. The competent authority shall include the following particulars in the certificate of approval of double-hull vessels meeting the additional requirements of 9.1.0.80 to 9.1.0.95 or 9.2.0.80 to 9.2.0.95: "The vessel meets the additional requirements for double-hull vessels of 9.1.0.80 to 9.1.0.95" or "The vessel meets the additional requirements for double-hull vessels of 9.2.0.80 to 9.2.0.95." For tank vessels, the certificate of approval must be supplemented by a list of all the dangerous goods accepted for carriage in the tank vessel, drawn up by the recognized classification society which has classified the vessel. When the competent authority issues a certificate of approval for tank vessels, it shall also issue a first loading journal.

Provisional certificate of approval For a vessel which is not provided with a certificate of approval, a provisional certificate of approval of limited duration may be issued in the following cases, subject to the following conditions: (a)

The vessel complies with the applicable provisions of these Regulations, but the normal certificate of approval could not be issued in time. The provisional certificate of approval shall be valid for an appropriate period but not exceeding three months;

(b)

The vessel does not comply with every applicable provision of these Regulations after sustaining damage. In this case the provisional certificate of approval shall be valid

only for a single specified voyage and for a specified cargo. The competent authority may impose additional conditions. The provisional certificate of approval shall conform to the model in 8.6.1.2 or 8.6.1.4 or a single model certificate combining a provisional certificate of inspection and the provisional certificate of approval provided that the single model certificate contains the same information as the model in 8.6.1.2 or 8.6.1.4 and is approved by the competent authority.

Issue and recognition of certificates of approval The certificate of approval referred to in 1.16.1 shall be issued by the competent authority of the Contracting Party where the vessel is registered, or in its absence, of the Contracting Party where it has its home port or, in its absence, of the Contracting Party where the owner is domiciled or in its absence, by the competent authority selected by the owner or his representative. The other Contracting Parties shall recognize such certificates of approval. The period of validity shall not exceed five years subject to the provisions of 1.16.10. The competent authority of any of the Contracting Parties may request the competent authority of any other Contracting Party to issue a certificate of approval in its stead. The competent authority of any of the Contracting Parties may delegate the authority to issue the certificate of approval to an inspection body as defined in 1.16.4. The provisional certificate of approval referred to in 1.16.1.3 shall be issued by the competent authority of one of the Contracting Parties for the cases and under the conditions referred to in these Regulations. The other Contracting Parties shall recognize such provisional certificates of approval.

Inspection procedure The competent authority of the Contracting Party shall supervise the inspection of the vessel. Under this procedure, the inspection may be performed by an inspection body designated by the Contracting Party or by a recognized classification society. The inspection body or the recognized classification society shall issue an inspection report certifying that the vessel conforms partially or completely to the provisions of these Regulations. This inspection report shall be drawn up in a language accepted by the competent authority and shall contain all the necessary information to enable the certificate to be drawn up.

Inspection body Inspection bodies shall be subject to recognition by the Contracting Party administration as expert bodies on the construction and inspection of inland navigation vessels and as expert bodies on the transport of dangerous goods by inland waterway. They shall meet the following criteria: -

Compliance by the body with the requirements of impartiality;

-

Existence of a structure and personnel that provide objective evidence of the professional ability and experience of the body;

-

Compliance with the material contents of standard EN 45004:1995 supported by detailed inspection procedures.

Inspection bodies may be assisted by experts (e.g. an expert in electrical installations) or specialized bodies according to the national provisions applicable (e.g. classification societies). The Administrative Committee shall maintain an up-to-date list of the inspection bodies appointed.

Application for the issue of a certificate of approval The owner of a vessel, or his representative, who requests a certificate of approval, shall deposit an application with the competent authority referred to in 1.16.2.1. The competent authority shall specify the documents to be submitted to it. In order to obtain a certificate of approval a valid vessel certificate shall accompany the request.

Particulars entered in the certificate of approval and amendments thereto The owner of a vessel, or his representative, shall inform the competent authority of any change in the name of the vessel or change of official number or registration number and shall transmit to it the certificate of approval for amendment. All amendments to the certificate of approval provided for in these Regulations and in the other regulations drawn up by mutual agreement by the Contracting Parties may be entered in the certificate by the competent authority. When the owner of the vessel, or his representative, has the vessel registered in another Contracting Party, he shall request a new certificate of approval from the competent authority of that Contracting Party. The competent authority may issue the new certificate for the remaining period of validity of the existing certificate without making a new inspection of the vessel, provided that the state and the technical specifications of the vessel have not undergone any modification.

Presentation of the vessel for inspection The owner, or his representative, shall present the vessel for inspection unladen, cleaned and equipped; he shall be required to provide such assistance as may be necessary for the inspection, such as providing a suitable launch and personnel, and uncovering those parts of the hull or installations which are not directly accessible or visible. In the case of a first, special or periodical inspection, the inspection body or the recognized classification society may require a dry-land inspection.

First inspection If a vessel does not yet have a certificate of approval or if the validity of the certificate of approval expired more than six months ago, the vessel shall undergo a first inspection.

Special inspection If the vessel's hull or equipment has undergone alterations liable to diminish safety in respect of the carriage of dangerous goods, or has sustained damage affecting such safety, the vessel shall be presented without delay by the owner or his representative for further inspection.

Periodic inspection and renewal of the certificate of approval To renew the certificate of approval, the owner of the vessel, or his representative, shall present the vessel for a periodic inspection. The owner of the vessel or his representative may request an inspection at any time. If the request for a periodic inspection is made during the last year preceding the expiry of the validity of the certificate of approval, the period of validity of the new certificate shall commence when the validity of the preceding certificate of approval expires. A periodic inspection may also be requested during a period of six months after the expiry of the certificate of approval. The competent authority shall establish the period of validity of the new certificate of approval on the basis of the results of the inspection.

Extension of the certificate of approval without an inspection By derogation from 1.16.10, at the substantiated request of the owner or his representative, the competent authority may grant an extension of the validity of the certificate of approval of not more than one year without an inspection. This extension shall be granted in writing and shall be kept on board the vessel. Such extensions may be granted only once every two validity periods.

Official inspection If the competent authority of a Contracting Party has reason to assume that a vessel which is in its territory may constitute a danger in relation to the transport of dangerous goods, for the persons on board or for shipping or for the environment, it may order an inspection of the vessel in accordance with 1.16.3. When exercising this right to inspect, the authorities will make all possible efforts to avoid unduly detaining or delaying a vessel. Nothing in this Agreement affects rights relating to compensation for undue detention or delay. In any instance of alleged undue detention or delay the burden of proof shall lie with the owner or operator of the vessel.

Withholding and return of the certificate of approval The certificate of approval may be withdrawn if the vessel is not properly maintained or if the vessel's construction or equipment no longer complies with the applicable provisions of these Regulations. The certificate of approval may only be withdrawn by the authority by which it has been issued. Nevertheless, in the cases referred to in 1.16.2.1 to 1.16.9 above, the competent authority of the State in which the vessel is staying may prohibit its use for the carriage of those dangerous goods for which the certificate is required. For this purpose it may withdraw the certificate until such time as the vessel again complies with the applicable provisions of these Regulations. In that case it shall notify the competent authority which issued the certificate. Notwithstanding 1.l6.2.2 above, any competent authority may amend or withdraw the certificate of approval at the request of the vessel's owner, provided that it so notifies the competent authority which issued the certificate.

1.16.13.4

When an inspection body or a classification society observes, in the course of an inspection, that a vessel or its equipment suffers from serious defects in relation to dangerous goods which might jeopardize the safety of the persons on board or the safety of shipping, or constitute a hazard for the environment, it shall immediately notify the competent authority to which it answers with a view to a decision to withhold the certificate. If this authority which decided to withdraw the certificate is not the authority which issued the certificate, it shall immediately inform the latter and, where necessary, return the certificate to it if it presumes that the defects cannot be eliminated in the near future.

1.16.13.5

When the inspection body or the classification society referred to in 1.16.13.1 above ascertains, by means of a special inspection according to 1.16.9, that these defects have been remedied, the certificate of approval shall be returned by the competent authority to the owner or to his representative. This inspection may be made at the request of the owner or his representative by another inspection body or another classification society. In this case, the certificate of approval shall be retuned through the competent authority to which the inspection body or the classification society answers.

1.16.13.6

When a vessel is finally immobilized or scrapped, the owner shall send the certificate of approval back to the competent authority which issued it.

1.16.14

Duplicate copy In the event of the loss, theft or destruction of the certificate of approval or when it becomes unusable for other reasons, an application for a duplicate copy, accompanied by appropriate supporting documents, shall be made to the competent authority which issued the certificate. This authority shall issue a duplicate copy of the certificate of approval, which shall be designated as such.

1.16.15

Register of certificates of approval

1.16.15.1

The competent authorities shall assign a serial number to the certificates of approval which they issue. They shall keep a register of all the certificates issued.

1.16.15.2

The competent authorities shall keep copies of all the certificates which they have issued and enter all particulars and amendments in them, as well as cancellations and replacements of certificates.

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PART 2 Classification (See Volume 11)

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PART 3 Dangerous goods list, special provisions and exemptions related to dangerous goods packed in limited quantities

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CHAPTER 3.1 GENERAL

(See Volume 11)

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CHAPTER 3.2 LIST OF DANGEROUS GOODS Table A: List of dangerous goods in numerical order See Volume I1

Table B: List of dangerous goods in alphabetical order See Volume I1

Table C:List of dangerous goods accepted for carriage in tank vessels in numerical order Explanations concerning Table C: As a rule, each row of Table C of this Chapter deals with the substance(s) covered by a specific UN number or identification number. However, when substances belonging to the same UN number or identification number have different chemical properties, physical properties andfor carriage conditions, several consecutive rows may be used for that UN number or identification number. Each column of Table C is dedicated to a specific subject as indicated in the explanatory notes below. The intersection of columns and rows (cell) contains information concerning the subject treated in that column, for the substance(s) of that row: -

The first four cells identify the substance(s) belonging to that row;

-

The following cells give the applicable special provisions, either in the form of complete information or in coded form. The codes cross-refer to detailed information that is to be found in the numbers indicated in the explanatory notes below. An empty cell means either that there is no special provision and that only the general requirements apply, or that the carriage restriction indicated in the explanatory notes is in force.

The applicable general requirements are not referred to in the corresponding cells. Explanatory notes for each column: Column (1)

"UN number/identification number"

Contains the UN number or identification number:

Column (2)

-

of the dangerous substance if the substance has been assigned its own specific UN number or identification number, or

-

of the generic or n.0.s. entry to which the dangerous substances not mentioned by name shall be assigned in accordance with the criteria ("decision trees") of Part 2.

"Name and description" Contains, in upper case characters, the name of the substance, if the substance has been assigned its own specific UN number or identification

number or of the generic or n.0.s. entry to which the dangerous substances have been assigned in accordance with the criteria ("decision trees") of Part 2. This name shall be used as the proper shipping name or, when applicable, as part of the proper shipping name (see 3.1.2 for firther details on the proper shipping name). A descriptive text in lower case characters is added after the proper shipping name to clarify the scope of the entry if the classification or carriage conditions of the substance may be different under certain conditions. Column (3a)

"Class" Contains the number of the Class, whose heading covers the dangerous substance. This Class number is assigned in accordance with the procedures and criteria of Part 2.

Column (3b)

"Classification code" Contains the classification code of the dangerous substance. -

For dangerous substances of Class 2, the code consists of a number and one or more letters representing the hazardous property group, which are explained in 2.2.2.1.2 and 2.2.2.1.3.

-

For dangerous substances or articles of Classes 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 8 and 9, the codes are explained in 2.2.x. 1.2.

'

Column (4)

"Packing group" Contains the packing group number(s) (I, I1 or 111) assigned to the dangerous substance. These packing group numbers are assigned on the basis of the procedures and criteria of Part 2. Certain substances are not assigned to packing groups.

Column (5)

"Danger" This column contains information concerning the hazards inherent in the dangerous substance. They are included on the basis of the danger labels of Table A, column (5). In the case of a chemically unstable substance the code "unst." is added to the information.

Column (6)

"Type of tank vessel" Contains the type of tank vessel: G, C or N.

Column (7)

"Cargo tank design" Contains information concerning the design of the cargo tank:

*

x

1

Pressure cargo tank

2

Closed cargo tank

= the Class number of the dangerous substance

-

or article, without dividing point ifapplicable.

104 -

Column (8)

3

Open cargo tank with flame arrester

4

Open cargo tank

"Cargo tank type7' Contains information concerning the cargo tank type.

Column (9)

1

Independent cargo tank

2

Integral cargo tank

3

Cargo tank with walls distinct from the outer hull

"Cargo tank equipment" Contains information concerning the cargo tank equipment.

Column (10)

1

Refrigeration system

2

Heating system

3

Water-spray system

"Opening pressure of high-velocity vent valve in kPa" Contains information concerning the opening pressure of the highvelocity vent valve in kPa.

Column ( l l )

"Maximum degree of filling ( %)" Contains information concerning the maximum degree of filling of cargo tanks as a percentage.

Column (12)

"Relative density" Contains information concerning the relative density of the substance at 20" C. Data concerning the density are for information only.

Column (13)

"Type of sampling device" Contains information concerning the prescribed type of sampling device. 1

Closed sampling device

2

Partly closed sampling device

3

Open sampling device

Column (14)

"Pump-room below deck permitted" Contains an indication of whether a pump-room is permitted below deck. Yes pump-room below deck permitted No

Column (15)

pump-room below deck not permitted

"Temperature class" Contains the temperature class of the substance.

Column (16)

"Explosion group7' Contains the explosion group of the substance.

Column (1 7)

"Anti-explosion protection required Contains a code referring to protection against explosions.

Column (1 8)

Yes

anti-explosion protection required

No

anti-explosion protection not required

"Equipment required This column contains the alphanumeric codes for the equipment required for the carriage of the dangerous substance (see 8.1.5).

Column (19)

"Number of coneshlue lights" This column contains the number of conesllights which should constitute the marking of the vessel during the carriage of this dangerous substance or article.

Column (20)

"Additional requirementsIRemarks" This column contains the additional requirements or remarks applicable to the vessel. These additional requirements or remarks are: 1.

Anhydrous ammonia is liable to cause stress crack corrosion in cargo tanks and cooling systems constructed of carbon-manganese steel or nickel steel. In order to minimize the risk of stress crack corrosion the following measures shall be taken: (a)

Where carbon-manganese steel is used, cargo tanks, pressure vessels of cargo refrigeration systems and cargo piping shall be constructed of fine-grained steel having a specified ~. minimum yield stress of not more than 355 ~ l m mThe actual yield stress shall not exceed 440 ~ l m m In ~ addition, . one of the following construction or operational measures shall be taken:

.l

Material with a low tensile strength (R, < 410 ~ / m m shall ~ ) be used; or

.2

Cargo tanks, etc., shall undergo a post-weld heat treatment for the purpose of stress relieving; or

.3

The transport temperature shall preferably be maintained close to the evaporation temperature of the cargo of -33" C, but in no case above -20" C; or

.4

Ammonia shall contain not less than 0.1 % water, by mass.

When carbon-manganese steel with yield stress values higher than those referred to in (a) above is used, the completed tanks, pipe sections, etc., shall undergo a postweld heat treatment for the purpose of stress relieving. Pressure vessels of the cargo refrigeration systems and the piping systems of the condenser of the cargo refrigeration system constructed of carbon-manganese steel or nickel steel shall undergo a post-weld heat treatment for the purpose of stress relieving. The yield stress and the tensile strength of welding consumables may exceed only by the smallest value possible the corresponding values of the tank and piping material. Nickel steels containing more than 5 % nickel and carbon-manganese steel which are not in compliance with the requirements of (a) and (b) above may not be used for cargo tanks and piping systems intended for the transport of this substance. Nickel steels containing not more than 5 % nickel may be used if the transport temperature is within the limits referred to in (a) above. The concentration of oxygen dissolved in the ammonia shall not exceed the values given in the table below: t in "C -30 and below -20 -10 0 10 20 30

2.

O2 in %, by volume 0.90 0.50 0.28 0.16 0.10 0.05 0.03

Before loading, air shall be removed and subsequently kept away to a sufficient extent from the cargo tanks and the accessory cargo piping by the means of inert gas (see also 7.2.4.18).

3.

Arrangements shall be made to ensure that the cargo is sufficiently stabilized in order to prevent a reaction at any time during carriage. The transport document shall contain the following additional particulars: (a)

Name and amount of inhibitor added;

(b)

Date on which inhibitor was added and expected duration of effectiveness under normal conditions;

(c)

Any temperature limits having an effect on the inhibitor.

When stabilization is ensured solely by blanketing with an inert gas it is sufficient to mention the name of the inert gas used in the transport document. When stabilization is ensured by another measurement, e.g. the special purity of the substance, this measurement shall be mentioned in the transport document. 4.

The substance shall not be allowed to solidify; the transport temperature shall be maintained above the melting point. In instances where cargo heating installations are required, they must be so designed that polymerisation through heating is not possible in any part of the cargo tank. Where the temperature of steamheated coils could give rise to overheating, lower-temperature indirect heating systems shall be provided.

5.

This substance is liable to clog the vapour pipe and its fittings. Careful surveillance should be ensured. If a close-type tank vessel is required for the carriage of this substance the vapour pipe shall conform to 9.3.2.22.5 (a) (i), (ii), (iv), (v), (b), (c) or (d) or to 9.3.3.22.5 (a) (i), (ii), (iv), (b), (c) or (d). This requirement does not apply when the cargo tanks are inerted in accordance with 7.2.4.18 nor when protection against explosions is not required in column (17) and when flame-arresters have not been installed.

6.

When external temperatures are below or equal to that indicated in column (20), the substance may only be carried in tank vessels meeting the following conditions: The tank vessels shall be equipped with a cargo heating system conforming to 9.3.2.42 or 9.3.3.2. The arrangement of heating coils inside the cargo tanks instead of a cargo heating system may be sufficient (possibility of heating the cargo). In addition, in the event of carriage in a closed-type vessel, if the tank vessel: -

is fitted out in accordance with 9.3.2.22.5 (a) (i) or (d) or9.3.3.22.5 (a) (i) or (d), it shall be equipped with pressure/vacuum valves capable of being heated; or

-

is fitted out in accordance with 9.3.2.22.5 (a) (ii), (v), (b) or (C) or 9.3.3.22.5 (a) (ii), (v), (b) or (c), it shall be equipped

with heatable vapour pipes and heatable pressure/vacuum valves; or -

is fitted out in accordance with 9.3.2.22.5 (a) (iii) or (iv) or 9.3.3.22.5 (a) (iii) or (iv), it shall be equipped with heatable vapour pipes and with heatable pressure/vacuum valves and heatable flame-arresters.

The temperature of the vapour pipes, pressure/vacuum valves and flame-arresters shall be kept at least above the melting point of the substance. If a closed-type tank vessel is required to carry this substance or if the substance is carried in a closed-type tank vessel, if this vessel: -

is fitted out in accordance with 9.3.2.22.5 (a) (i) or (d) or 9.3.3.22.5 (a) (i) or (d), it shall be equipped with heatable pressure/vacuum valves, or

-

is fitted out in accordance with 9.3.2.22.5 (a) (ii), (v), (b) or (C)or 9.3.3Z . 5 (a) (ii), (v), (b) or (c), it shall be equipped with heatable vapour pipes and heatable pressure/vacuum valves, or

-

is fitted out in accordance with 9.3.2.22.5 (a) (iii) or (iv) or 9.3.3.22.5 (a) (iii) or (iv), it shall be equipped with heatable vapour pipes and with heatable pressure/vacuum valves and heatable flame-arresters.

The temperature of the vapour pipes, pressure/vacuum valves and flame-arresters shall be kept at least above the melting point of the substance. Double-hull spaces, double bottoms and heating coils shall not contain any water. (a)

While the vessel is underway, an inert-gas pad shall be maintained in the ullage space above the liquid level.

(b)

Cargo piping and vent lines shall be independent of the corresponding piping used for other cargoes.

(c)

Safety valves shall be made of stainless steel.

(Reserved). (a)

Stainless steel of type 416 or 442 and cast iron shall not be used for cargo tanks and pipes for loading and unloading.

(b)

The cargo may be discharged only by deep-well pumps or pressure inert gas displacement. Each cargo pump shall be arranged to ensure that the substance does not heat significantly if the pressure discharge line from the pump is shut off or otherwise blocked.

(c)

The cargo shall be cooled and maintained at temperatures below 30" C.

(d)

The safety valves shall be set at a pressure of not less than 550 kPa (5.5 bar) gauge pressure. Special authorization is required for the maximum setting pressure.

(e)

While the vessel is underway, a nitrogen pad shall be maintained in the ullage space above the cargo (see also 7.2.4.18). An automatic nitrogen supply system shall be installed to prevent the pressure from falling below 7 kPa (0.07 bar) gauge within the cargo tank in the event of a cargo temperature fall due to ambient temperature conditions or to some other reason. In order to satisfy the demand of the automatic pressure control a sufficient amount of nitrogen shall be available on board. Nitrogen of a commercially pure quality of 99.9 %, by volume, shall be used for padding. A battery of nitrogen cylinders connected to the cargo tanks through a pressure reduction valve satisfies the intention of the expression "automatic" in this context. The required nitrogen pad shall be such that the nitrogen concentration in the vapour space of the cargo tank is not less than 45 % at any time.

12.

(Q

Before loading and while the cargo tank contains this substance in a liquid or gaseous form, it shall be inerted with nitrogen.

(g)

The water-spray system shall be fitted with remote-control devices which can be operated from the wheelhouse or from the control station, if any.

(h)

Transfer arrangements shall be provided for emergency transfer of ethylene oxide in the event of an uncontrollable self-reaction.

(a)

The substance shall be acetylene free.

(b)

Cargo tanks which have not undergone appropriate cleaning shall not be used for the carriage of these substances if one of the previous three cargoes consisted of a substance known to promote polymerisation, such as: .l

mineral acids (e.g. sulphuric acid, hydrochloric acid, nitric acid);

.2

carboxylic acids and anhydrides (e.g. formic acid, acetic acid);

.3

halogenated carboxylic acids (e.g. chloroacetic acid);

.4

sulphonic acids (e.g. benzene sulphonic acid);

.5

caustic alkalis (e.g. sodium hydroxide, potassium hydroxide);

.6

ammonia and ammonia solutions;

.7

amines and amine solutions;

.S

oxidizing substances.

Before loading, cargo tanks and their piping shall be efficiently and thoroughly cleaned so as to eliminate all traces of previous cargoes, except when the last cargo was constituted of propylene oxide or a mixture of ethylene oxide and propylene oxide. Special precautions shall be taken in the case of ammonia in cargo tanks built of steel other than stainless steel. In all cases the efficiency of the cleaning of cargo tanks and their piping shall be monitored by means of appropriate tests or inspections to check that no trace of acid or alkaline substance remains that could present a danger in the presence of these substances. The cargo tanks shall be entered and inspected prior to each loading of these substances to ensure freedom from contamination, heavy rust deposits or visible structural defects. When these cargo tanks are in continuous service for these substances, such inspections shall be performed at intervals of not more than two and a half years. Cargo tanks which have contained these substances may be reused for other cargoes once they and their piping have been thoroughly cleaned by washing and flushing with an inert gas. Substances shall be loaded and unloaded in such a way that there is no release of gas into the atmosphere. If gas is returned to the shore installation during loading, the gas return system connected to the tank containing that substance shall be independent from all other cargo tanks. During discharge operations, the pressure in the cargo tanks shall be maintained above 7 kPa (0.07 bar) gauge. The cargo shall be discharged only by deep-well pumps, hydraulically operated submerged pumps or pressure inert gas displacement. Each cargo pump shall be arranged to ensure that the substance does not heat significantly if the pressure discharge line from the pump is shut off or otherwise blocked. Each cargo tank carrying these substances shall be ventilated by a system independent from the ventilation systems of other cargo tanks carrying other substances.

Loading pipes used for these substances shall be marked as follows:

"To be used only for the transfer of alkylene oxide." Cargo tanks, cofferdams, double-hull spaces, double bottoms, cargo tank spaces adjacent to a cargo tank carrying this substance shall either contain compatible cargo (the substances mentioned under (b) are examples of substances considered to be incompatible) or be inerted with an appropriate inert gas. Spaces so inerted shall be monitored for these substances and oxygen. The oxygen content shall be maintained below 2 %, by volume. Portable measuring devices are permitted. No air shall be allowed to enter the cargo pumps and cargo piping system while these substances are contained within the system. Before the shore connections are disconnected, piping containing liquids or gas shall be depressurised at the shore link by means of appropriate devices. The piping system for cargo tanks to be loaded with these substances shall be separate from piping system for all other cargo tanks, including empty cargo tanks. If the piping system for the cargo tanks to be loaded is not independent, separation shall be accomplished by the removal of spool pieces, shut-off valves, other pipe sections and by fitting blank flanges at these locations. The required separation applies to all liquid pipes and vapour vent lines and any other connections which may exist such as common inert gas supply lines. These substances may be carried only in accordance with cargo handling plans that have been approved by a competent authority. Each loading arrangement shall be shown on a separate cargo handling plan. Cargo handling plans shall show the entire cargo piping system and the locations for installations of blank flanges needed to meet the above piping separation requirements. A copy of each cargo handling plan shall be kept on board. Reference to the approved cargo handling plans shall be included in the certificate of approval. Before loading of these substances and before carriage is resumed a qualified person approved by the competent authority shall certify that the prescribed separation of the piping has been effected; this certificate shall be kept on board. Each connection between a blank flange and a shutoff valve in the piping shall be fitted with a sealed wire to prevent the flange from being disassembled inadvertently. During the voyage, the cargo shall be covered with nitrogen. An automatic nitrogen make-up system shall be installed to

prevent the cargo tank pressure from falling below 7 kPa (0.07 bar) gauge in the event of a cargo temperature fall due to ambient temperature conditions or to some other reason. Sufficient nitrogen shall be available on board to satis@ the demand of automatic pressure control. Nitrogen of commercially pure quality of 99.9 %, by volume, shall be used for padding. A battery of nitrogen cylinders connected to the cargo tanks through a pressure reduction valve satisfies the intention of the expression "automatic" in this context. The vapour space of the cargo tanks shall be checked before and after each loading operation to ensure that the oxygen content is 2 %, by volume, or less. Loading flow The loading flow (LR) of cargo tank shall not exceed the following value:

In this formula: U = the free volume (m3) during loading for the activation of the overflow prevention system;

T = the time (S) required between the activation of the overflow prevention system and the complete stop of the flow of cargo into the cargo tank; The time is the sum of the partial times needed for successive operations, e.g. reaction time of the service personnel, the time needed to stop the pumps and the time needed to close the shut-off valves; The loading flow shall also take account of the design pressure of the piping system. 13.

If no stabilizer is supplied or if the supply is inadequate, the oxygen content in the vapour phase shall not exceed 0.1 %. Overpressure must be constantly maintained in cargo tanks. This requirement applies also to voyages on ballast or empty with uncleaned cargo tanks between cargo transport operations.

14.

The following substances may not be carried under these conditions: -

substances with self-ignition temperatures L 200 "C;

-

mixtures containing halogenated hydrocarbons;

-

mixtures containing more than 10 % benzene;

-

substances and mixtures carried in a stabilized state.

Provision shall be made to ensure that alkaline or acidic substances such as sodium hydroxide solution or sulphuric acid do not contaminate this cargo. If there is a possibility of a dangerous reaction such as polymerisation, decomposition, thermal instability or evolution of gases resulting from local overheating of the cargo in either the cargo tank or associated piping system, this cargo shall be loaded and carried adequately segregated from other substances the temperature of which is sufficiently high to initiate such reaction. Heating coils inside cargo tanks carrying this substance shall be blanked off or secured by equivalent means. The melting point of the cargo shall be shown in the transport documents.

(Reserved). Provision shall be made to ensure that the cargo does not come into contact with water. The following additional requirements apply: Carriage of the cargo is not permitted in cargo tanks adjacent to slop tanks or cargo tanks containing ballast water, slops or any other cargo containing water. Pumps, piping and vent lines connected to such tanks shall be separated from similar equipment of tanks carrying these substances. Pipes from slop tanks or ballast water pipes shall not pass through cargo tanks containing this cargo unless they are encased in a tunnel. The maximum permitted transport temperature given column (20) shall not be exceeded.

in

(Reserved). The relative density of the cargo shall be shown in the transport document. The instrument for measuring the pressure of the vapour phase in the cargo tank shall activate the alarm when the internal pressure reaches 40 H a . The water-spray system shall immediately be activated and remain in operation until the internal pressure drops to 30 H a . Substances having a flash-point above 61 "C which are handed over for carriage or which are carried heated within a limiting range of 15 K below their flash-point shall be carried under the conditions of substance number 9001. Type 3 cargo tank may be used for the carriage of this substance provided that the construction of the cargo tank has been accepted by a recognized classification society for the maximum permitted transport temperature. Type 2 cargo tank may be used for the carriage of this substance provided that the construction of the cargo tank has been accepted

by a recognized classification society for the maximum permitted transport temperature. 27.

The requirements of 3.1.2.8.1 are applicable.

28.

(a)

When this substance is carried, the forced ventilation of the cargo tanks shall be brought into service at latest when the concentration of hydrogen sulphide reaches 1.0 %, by volume.

(b)

When during the carriage of this substance, the concentration of hydrogen sulphide exceeds 1.85 %, the boat master shall immediately notify the nearest competent authority. When a significant increase in the concentration of hydrogen sulphide in a hold space leads it to be supposed that the sulphur has leaked, the cargo tanks shall be unloaded as rapidly as possible. A new load may only be taken on board once the authority which issued the certificate of approval has carried out a further inspection.

29.

(c)

When this substance is carried, the concentration of hydrogen sulphide shall be measured in the vapour phase of the cargo tanks and concentrations of sulphur dioxide and hydrogen sulphide in the hold spaces.

(d)

The measurements prescribed in (c) shall be made every eight hours. The results of the measurements shall be recorded in writing.

When particulars concerning the vapour pressure or the boiling point are given in column (2), the relevant information shall be added to the proper shipping name in the transport document, e.g. UN 1224 KETONES, LIQUID, N.O.S., 110 kPa< vp 5O< 175 kPaor UN 2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S., boiling point < 60" C

30.

When these substances are carried, the hold spaces of open type N tank vessels may contain auxiliary equipment.

31.

When these substances are carried, the vessel shall be equipped with a rapid blocking valve placed directly on the shore connection.

32.

In the case of transport of this substance, the following additional requirements are applicable: (a)

The outside of the cargo tanks should be equipped with insulation of low flammability. This insulation should be strong enough to resist shocks and vibration. Above deck, the insulation should be protected by a covering.

The outside temperature of this covering should not exceed 70 "C. The spaces containing the cargo tanks should be provided with ventilation. Connections for forced ventilation should be fitted. The cargo tanks should be equipped with forced ventilation installations which, in all transport conditions, will reliably keep the concentration of hydrogen sulphide above the liquid phase below 1.85 % by volume. The ventilation installations should be fitted in such a way as to prevent the deposit of the goods to be transported. The exhaust line of the ventilation should be fitted in such a way as not to present a risk to personnel. The cargo tank and the hold spaces should be fitted with outlets and piping to allow gas sampling. The outlets of the cargo tanks should be situated at a height such that for a trim of 2" and a list of 10°, no sulphur can escape. All the outlets should be situated above the deck in the open air. Each outlet should be equipped with a satisfactory fixed closing mechanism. One of these mechanisms should be capable of being opened for slight overpressure within the tank. The pipes for loading and unloading should be equipped with adequate insulation. They should be capable of being heated. The heat transfer fluid should be such that in the event of a leak into a tank, there is no risk of a dangerous reaction with the sulphur. following provisions are applicable to transport of this substance: Construction requirements:

Hydrogen peroxide solutions may be transported only in cargo tanks equipped with deep-well pumps. Cargo tanks and their equipment should be constructed of solid stainless steel of a type appropriate to hydrogen peroxide solutions (for example, 304, 304L, 316, 316L or 316 Ti). None of the non-metallic materials used for the system of cargo tanks should be attacked by hydrogen peroxide solutions or cause the decomposition of the substance. The temperature sensors should be installed in the cargo tanks directly under the deck and at the bottom. Remote

temperature read-outs and monitoring should be provided for in the wheelhouse. (d)

Fixed oxygen monitors (or gas-sampling lines) should be provided in the areas adjacent to the cargo tanks so that leaks in such areas can be detected. Account should be taken of the increased flammability arising from the increased presence of oxygen. Remote read-outs, continuous monitoring (if the sampling lines are used, intermittent monitoring will suffice) and visible and audible alarms similar to those for the temperature sensors should also be located in the wheelhouse. The visible and audible alarms should be activated if the oxygen concentration in these void spaces exceeds 30 % by volume. Two additional oxygen monitors should also be available.

(e)

The cargo tank venting systems which are equipped with filters should be fitted with pressure/vacuum relief valves appropriate to closed-circuit ventilation and with an extraction installation should cargo tank pressure rise rapidly as a result of an uncontrolled breakdown (see under m). These air supply and extraction systems should be so designed that water cannot enter the cargo tanks. In designing the emergency extraction installation account should be taken of the design pressure and the size of the cargo tanks.

(f)

A fixed water-spray system should be provided for diluting and washing away any hydrogen peroxide solutions spilled onto the deck. The area covered by the jet of water should include the shore connections and the deck containing the cargo tanks designated for carrying hydrogen peroxide solutions. The following minimum requirements should be complied with:

.l

The product should be diluted from the original concentration to a 35 % concentration within five minutes from the spillage on the deck;

.2

The rate and estimated size of the spill should be determined in the light of the maximum permissible loading or unloading rates, the time required to halt the spillage in the event of tank overfill or a piping/hose failure, and the time necessary to begin application of dilution water with actuation at the cargo control location or in the wheelhouse.

(g)

The outlets of the pressure valves should be situated at least 2.00 metres from the walkways if they are less than 4.00 metres from the walkway.

(h)

A temperature sensor should be installed by each pump to make it possible to monitor the temperature of the cargo

during unloading and detect any overheating due to defective operation of the pump.

Servicing requirements: Shipper

(i)

Hydrogen peroxide solutions may only be carried in cargo tanks which have been thoroughly cleaned and passivated, in accordance with the procedure described under (j), of all traces of previous cargoes, their vapours or their ballast waters. A certificate stating that the procedure described under (j) has been duly complied with must be carried on board. Particular care in this respect is essential to ensure the safe carriage of hydrogen peroxide solutions:

(j)

1

When a hydrogen peroxide solution is being carried, no other cargo may be carried simultaneously;

.2

Tanks which have contained hydrogen peroxide solutions may be reused for other cargoes after they have been cleaned by persons or companies approved for this purpose by the competent authority;

.3

In the design of the cargo tanks, efforts must be made to keep to a minimum any internal tank structure, to ensure free draining, no entrapment and ease of visual inspection.

Procedures for inspection, cleaning, passivation and loading for the transport of hydrogen peroxide solutions with a concentration of 8-60 per cent in cargo tanks which have previously carried other cargoes. Before their reuse for the transport of hydrogen peroxide solutions, cargo tanks which have previously carried cargoes other than hydrogen peroxide must be inspected, cleaned and passivated. The procedures described in paragraphs .l to .7 below for inspection and cleaning apply to stainless steel cargo tanks. The procedure for passivating stainless steel is described in paragraph .8. Failing any other instructions, all the measures apply to cargo tanks and to all their structures which have been in contact with other cargoes.

.l

After offloading of the previous cargo, the cargo tank must be degassed and inspected for any remaining traces, carbon residues and rust.

.2

The cargo tanks and their equipment must be washed with clear filtered water. The water used must be at least of the same quality as drinking water and have a low chlorine content.

.3

Traces of the residues and vapours of the previous cargo must be removed by the steam cleaning of the cargo tanks and their equipment.

.4

The cargo tanks and their equipment must then be rewashed with clear water of the quality specified in paragraph 2 above and dried in filtered, oil-free air.

.5

Samples must be taken of the atmosphere in the cargo tanks and these must be analysed for their content of organic gases and oxygen.

.6

The cargo tank must be reinspected for any traces of the previous cargo, carbon residues or rust or odours of the previous cargo.

.7

If the inspection and the other measures point to the presence of traces of the previous cargo or of its gases, the measures described in paragraphs .2 to .4 above must be repeated.

.8

Stainless steel cargo tanks and their structures which have contained cargoes other than hydrogen peroxide solutions and which have been repaired must, regardless whether or not they have previously been passivated, be cleaned and passivated in accordance with the following procedure: The new weld seams and other repaired parts must be cleaned and scrubbed with stainless steel brushes, graving tools, sandpaper and polishers. Rough surfaces must be made smooth and a final polishing must be carried out; Fatty and oily residues must be removed with the use of organic solvents or appropriate cleaning products diluted with water. The use of chlorinated products should be avoided because these might seriously interfere with the passivation procedure;

3.3

(k)

Any residues of the product that have been removed must be eliminated and the tanks must then be washed.

During the transfer of the hydrogen peroxide solutions, the related piping system must be separated from all other systems. Cargo hoses used for the transfer of hydrogen peroxide solutions must be marked as follows: "Uniquement pour le transbordement de peroxydes d'hydrog6ne en solution" "For Hydrogen Peroxide Solution Transfer only"

(1)

If the temperature in the cargo tanks rises above 35 "C, visible and audible alarms should activate on the navigating bridge.

Master

(m)

If the temperature rise exceeds 4 "C for 2 hours or if the temperature in the cargo tanks exceeds 40 "C, the master must contact the consignor directly, with a view to taking any action that might be necessary.

Filler

(n)

(0)

Hydrogen peroxide solutions must be stabilized to prevent decomposition. The manufacturer must provide a stabilization certificate which must be carried on board and must specify: .l

The disintegration date of the stabilizer and the duration of its effectiveness;

.2

Actions to be taken should the product become unstable during the voyage.

Only those hydrogen peroxide solutions which have a maximum decomposition rate of 1.0 per cent per year at 25 "C may be carried. A certificate from the shipper stating that the product meets this standard must be presented to the master and kept on board. An authorized representative of the manufacturer must be on board to monitor the transfer operations and to test the stability of the hydrogen peroxide solutions to be transported. He should certify to the master that the cargo has been loaded in a stable condition.

34. For type N carriage, the flanges and stuffing boxes of the loading and unloading hoses must be fitted with a protection device to protect against splashing. 35. A direct system for the cargo refrigerating system is not permitted for this substance. 36. Only an indirect system for the cargo refrigerating system is permitted for this substance. 37. For this substance, the cargo tank system shall be capable of resisting the vapour pressure of the cargo at higher ambient temperatures whatever the system adopted for the boil-off gas. 38. When the initial melting point of these mixtures in accordance with standard ASTM D86-01 is above 60" C, the transport requirements for packing group I1 are applicable.

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Ldditional requirements1Remarl

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of tilling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

idditional requirements/Remarl

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

n

C

E 2 g 2

$

Z

6'

;

z

z

3 %

8

--.?

a

rr

5; 0

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2

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(1 ) 1134

I CHLOROBENZENE C (phenyl & & chloride)

1135

(2- CHLOROETHANOL)

1145

CROTONALDEHYDE or CROTONALDEHYDE. STABILIZED CYCLOHEXANE

1146

CYCLOPENTANE

3

F1

1150

3

F1

3

F1

3

F1

1 I54

1,2-D1CHLOROETHYLENE( a s 1,2-D1CHLOROETHYLENE) 1,2-DICHLOROETHYLENE (trans-l,2DICHLOROETHYLENE) ETHYLENE GLYCOL DIETHYL ETHER DIETHYLAMINE

3

FC

1155

DIETHYL ETHER

3

F1

1157

DIISOBUTYL KETONE

3

F1

I159

DIISOPROPYL ETHER

3

FI

1160

DIMETHYLAMINE AQUEOUS SOLUTION DIMETHYLHYDRAZINE, UNSYMMETRICAL

3

FC

61

TFC

F1

1143

,

6.1

TFI

3

FI

I

I

1150

I153

1163

1165

DIOXANE

3

(18)

'P, EX, A 'P, EP, EX, 'OX, A 'P, EP, EX, 'OX, A 'P,EX, A 'P,EX, A 'P,EX, A 'P, EX, A 'P, EX, A 'P, EP, EX, A 'P, EX, A 'P, EX, A 'P, EX, A 'P, EP, EX, A

(19) 0 2

2

3; 5; 15

1

5: +11 'C;

1 1

13

1

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DIVINYL ETHER, STABILIZED

3

F1

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2

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EX, 'OX, A 'P,EX,

1

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:=.

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$

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-

rn 3

3 (b) F1

(4)

3

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111

F1

111

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3

3

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2

97

0.87 0.96

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97

0.93

gP ID

g. g =

E

g yz

B

$ m.

3

I 173

MONOETHYL ETHER ETHYLENE GLYCOL MONOETHYL ETHER ACETATI ETHYL ACETATE

I175

F1

3

111

3

2

97

0.98

3 Y

g.

(16) I1 B

(17)

I1 B

yes

IIB

yes

IIA

yes

I1 A

yes

yes

I I170

k

9

4'

8

3

s (11)

or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) aqueous solution with more than 70 % alcohol by volume I ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION), aqueous solution with more than 24 % and not more than 7 0 O/o alcohol by volume

"P

3

3

3

-

F1

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3

2

2

97

0.9

ETHYLBENZENE

FI

I1

3

2

2

97

0.87

II B

yes

I177

2-ETHYLBUTYL ACETATE

F1

111

3

3

2

91

0.88

IIA

yes

I 1 84

ETHYLENE DICHLORIDE (1,2-dichIoroethane)

FTI

I1

3+6.1

2

2

95

1.25

I1 A

yes

F1

111

3

3

2

97

0.97

IIB

yes

F1

111

3

2

2

95

0.82

I1 A

yes

F1

111

3

3

2

97

0.82

I1 B4)

yes

F1

I1

3

2

2

97

0.8

I1 A

yes

FC

111

3+8

3

2

97

1.09

IIB

yes

I1 B

yes

3

no

E 'P, EX A

'P, EX A

'P, EX A 'P, EX A 'P, EX A 'P, EX A 'P, EX A PP, EP, EX,

0

0 1

1 0

TOX,A I188

I 19 1

I191 I193 IIYh

ETHYLENE GLYCOL MONOMETHYL ETHER OCTYL ALDEHYDES (2- ETHYLCAPRONALDEHYDE I OCTYL ALDEHYDES (n- OCTALDEHYDE) I ETHYL METHYL KETONE (METHYL ETII\'L KFTOhTj I FORMALDEIIYDE SOI.UTIOK. FLAMMABLE

I I I

I I

3

3

3

6.1

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-

TFI

I1

6.1+3

2

2

95

1.16

3

2

'P, EX A 'P, EX A 'P, EX A 'P, EX A 'P, EP, EX, A 'P, EP, EX, rox, A

14 L5

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density a t 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

rdditional requirementslRemark

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

dditional requirementsIRemarks

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 O C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of fdling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

l+

Number of conesiblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment p ~

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

S

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W

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S S':

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g

5

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Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted

Type of sampling device

l X B-. a

$?m< a

E-*

X^

I-

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26

h

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a-

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2

m

L

-

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m

l II+ Iz

1

c Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

UN No. or substance identification No.

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

idditional requirementdRemarks

Number of cones/blue lights

Equipment required

. " OU F N C

I& IN

3

E-8

8

8

10

w

w

8

: m

5%

1%

Anti- explosion protection required

Explosion group

I+ I

I

Temperature class

g8 N

Pump room below deck permitted

2N

h

Type of sampling device

2 O\

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m

5 2

Relative density at 20 OC

-

I&

4;

I+ ;;;w

g

-

v fi

Y

o v= w

s zz

v)

z

0

s?i 8% 22

w

zE gE

' Y

3-

142 12

w

I+ IN

14' 1' : 1

Maximum degree of filling in % Z Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code Class

Name and description

UN No. or substance identification No.

- 136 -

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

lHO

l$ 6

V1 W C

gg

C

55 2 W

oo m

h

2

-

Maximum degree of filling in % 2 Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type -r

l'-

h

Cargo tank design

SZ

1

14. l$ I

Sm m

5

S

P

V

i

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Qdditional requirements1Remark

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

--

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

idditional requirements1Remark

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

UN No. or substance identification No.

$4

ga 6 < a

xLa

e

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 O C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of conesiblue lights

Additional requirements/Remarks

1 I Equipment required

gm

4:I

e

S

G

N

0

2

S N

W E

zK N

c

IE-

h

h

2

z

S % N

-

8

ss

N C

2

+

L Anti- explosion protection required

Class

Classification code

Packing group

Dangers

Type of tank vessel

Cargo tank design

Cargo tank type

C a r p tank equipment

Opening pressure of the high-velocity vent valve in kPa

Maximum degree of filling in %

Relative density at 20 O C

Type of sampling device

Pump room below deck permitted

Temperature class

Explosion group

r-

/

l I I Name and description

P -

UN No. or substance identification No.

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa

pp

Cargo tank equipment

Cargo tank type

Cargo tank design

Packing group

Dangers

Type of tank vessel

p

Classification code

Class

Name and description

UN No. or substance identification No.

Number of cones/blue lights

Anti- explosion protection

Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C P -

Maximum degree of tilling in %

Ir Ig

l I- I14

m

0

19

1 1;;1 2

14: :I W

N

o m

N

g

N

N

-

C

oom

N

Opening pressure of the high-velocity vent valve in W a

-

*

Cargo tank type

P. W

U

Cargo tank equipment

Cargo tank design

U

2

m

*

LL

- -

E

5+ +3 m

ci

g2

m

=m m

m

Type of tank vessel

Dangers

Packing group

Classification code

Class

UN No. or substance identification No.

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

&

4

W

E m l-

"

g

&

X"

14- 1- I5 m

2 %

1 1; 14. 1~ IF:

2

N

m m

m

I 1 11 1 1% g2

N

Relative density at 20 ' C

-

Maximum degree of filling in %

00 N

N

Cargo tank equipment

Opening pressure of the high-velocity vent valve in kPa

Cargo tank type

c m

U U

N

Cargo tank design

z

n

Type of tank vessel

p p

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa

p

Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

3

EB

B

e

2B

1 . 3

c d

d

-I

5.

$

x

v)

I

m

jit

z

U”

P

z

$

0 N

K (1)

I

2528

(2) ISOBUTYL ISOBUTYRATE

I

2531

2564

I METHACRYLIC ACID.

I STABILIZED

I TRICHLOROACETIC ACID

-

30

Isl

3

(10)

2

-

c12

8

-

2

(11)

97

4

25

95

8

95

8

97

SOLUTION SOLUTION TRICRESYL PHOSPHATE with

-

CIZ

6.1

2s

95 95 97 97

I

c ul

0 I

2608

LIQUID or ARLSULFONIC ACIDS, LIQUID with not more I than 5 % free sulphuric acid NITROPROPANES

VINYLTOLUENES, STABILIZE1

N

3

1

N

2

1+unst.

4,4’-DIAMINODIPHENYL-

5.1

I METHANE 2672

1

I AMMONIA SOLUTION (relative

3

density between 0.880 and0.957 at 15 “C in water, with mote than 10 % but not more than 35 % ammonia)

2

25

2

25

10

97 95

95 97

E

0

0.86

1.02

3; 4; 5; 17

1.62”’ 1.62”’ 1.18 0.9 1.45 -

7; 17; 22; 3

no

0.73 0.92

yes

1

-1

m

2

3

<+3+6.1

8

3

1

97

0.87

no

I

PP, EX

3

--

0 I

3; 5 0 0 7 ; 17 0

34

2 15; 16

2

3

2

0 0 0

TOX, P

-

22; 34

* T

1

-

PP, EP. EX, A PP, EP. TOX, P

PP, EP

-

+ 10

e

AIL

0.96’O)

SOLUTION

SOLUTION, N.O.S.

C

97

3

TOX, P

0 27; 34 0 -

Qdditionalrequirements1Remark

Number of coneslblue lights Equipment required Anti- explosion protection required Explosion group Temperature class Pump room below deck permitted Type of sampling device Relative density a t 20 OC Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment Cargo tank type

Cargo tank design Type of tank vessel

Dangers

Packing group Classification code Class

Name and description

UN No. or substance identification No.

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

-

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

rdditional requirements1Remark

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

'I) S\

Relative density at 20 'C

Maximum degree of filling in %

= 'I)

Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Ldditional requirements/RemarE

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. o r substance identification No.

Explosion group

Anti- explosion protection

Equipment required

Number of coneslblue lights

F I Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Dangers

Type of tank vessel

I-I Packing group

Classification code

Class

UN No. or substance identification No.

Name and description

L== l

Number of cones/blue lights

Additional

I Ido .I PI

xa

Equipment required Anti- explosion protection required

12

A

..

.I I

I m

k

d

I-

m

6

I--

:1

142

2

14-

3

Explosion group

K

W

2 Q

Temperature class Pump room below deck permitted

2

Type of sampling device

Relative density at 20 OC

14,

l

Maximum degree of filing in %

n

Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

m

Z

Cargo tank type

I--

Z

n

Cargo tank design

g2

W

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

K

m

m

a"

m

K

Equipment required

3

\O

h

3 m

K

v

PI m

W

)

N m

v W

)

\

D N m

m

i

1 1 1 1

m

5$ m

,X

m

N

s sm

m

14: I P I B 10 1:

1

Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 'C

Cargo tank type

Type of tank vessel

UN No. or substance identification No.

K

m

m

W

D

PI m

idditional requirementslRemark ~

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

I

L

ttI_

I

- 164-

4dditional requirementslRemarks

Number of cones/blue lights

Equipment required Anti- explosion protection required Explosion group

g

N r‘

N

m

tN

3. "

-

m N .-

.-

N P N m

o

6, a

d

aa

-

."

N t-

N m

o

d

a

n

tPI

.

m

o

~1

k

m

R

f

m

-

M

Efl

-

m

W

-J

S -7

.*

Y + N d

Cargo tank equipment

-

00 N

..

-m

X

d M

4

W ,

X

0

% m

m

X

N

m

X

N

N

m r-

4

P!

m V)

m V)

N

z

ir,

m

,-.

W

m

E X

m

M

.-,a f

?..

m

h

m

N

.r

R

.-

X-

a

-

W

h*

gg :-$

A-

Temperature class

2

g,

Pump room below deck permitted

g 2

h

h

Type of sampling device

Relative density at 20 OC m V)

V)

m

5

Maximum degree of filling in % 2 g

m

m

Cargo tank type h

h

YL

V)

Vr

N

N

Dangers

0

N

N

Z

0 v,

N

N

U

m 'Ci

N

N

U

CO

SE

N

V

m

Opening pressure of the high-velocity vent valve in kPa

cm U

m

C H (

Y,

m d

2

2 g

V1

W

c

M

m

4

M

L

W

4

W

LL

-

LL

m

m

V)

m

N

m

N

m

V)

m

m N

m

m

, a

m

V)

N

m

V)

m

.-.

m

Cargo tank design

SU

m

3

Type of tank vessel

m

$E h

p 2, m

N m

22

W

m

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Ldditional reqnirements1Remark

Number of coneslblue lights

Equipment required Anti- explosion protection required Explosion group

Temperature class Pump room below deck permitted Type of sampling device

Relative density at 20 OC

Maximum degree of filling in % Opening pressure of the high-velocity vent valve in kPa Cargo tank equipment

Cargo tank type

Cargo tank design

Type of tank vessel

Dangers

Packing group

Classification code

Class

Name and description

UN No. or substance identification No.

Footnotes related to the list of substances The ignition temperature has not been determined in accordance with IEC 79-4; therefore, provisional assignment has been made to temperature class T2 which is considered safe. The ignition temperature has not been determined in accordance with IEC 79-4; therefore, provisional assignment has been made to temperature class T3 which is considered safe. The ignition temperature has not been determined in accordance with IEC 79-IA; therefore, provisional assignment has been made to temperature class T4 which is considered safe. No maximum experimental safe gap (MESG) has been measured in accordance with IEC 791A; therefore, provisional assignment has been made to explosion group IIB which is considered safe. No maximum experimental safe gap (MESG) has been measured in accordance with IEC 791A; therefore, provisional assignment has been made to explosion group IIC which is considered safe. The maximum experimental safe gap (MESG) is within the marginal range between explosion group IIA and IIB. No maximum experimental safe gap (MESG) has been measured in accordance with IEC-791A; therefore, assignment has been made to the explosion group which is considered safe. No maximum experimental safe gap (MESG) has been measured in accordance with IEC 791A; therefore, assignment has been made to the explosion group in compliance with EN 50014. Assignment in accordance with IMO (International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk) (IBC Code). Relative density at 15 OC. Relative density at 25 "C. Relative density at 37 "C. Indications related to the pure substance.

PART 4 Provisions concerning the use of packagings, tanks and bulk transport units

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CHAPTER 4.1

GENERAL PROVISIONS

Packagings and tanks shall be used in accordance with the requirements of one of the international Regulations, bearing in mind the indications given in the list of substances of these international Regulations, namely: -

For packagings (including IBCs and large packagings): columns (9a) and (9b) of Chapter 3.2, Table A of RID or ADR, or the list of substances in Chapter 3.2 of the IMDG Code or the ICAO Technical Instructions;

-

For portable tanks: columns (10) and (1 1) of Chapter 3.2, Table A of RID or ADR or the list of substances in the IMDG Code;

-

For RID or ADR tanks: columns (12) and (13) of Chapter 3.2, Table A of RID or ADR.

The requirements to be implemented are as follows: -

For packagings (including IBCs and large packagings): Chapter 4.1 of RID, ADR, the IMDG Code or the ICAO Technical Instructions;

-

For portable tanks: Chapter 4.2 of RID, ADR or the IMDG Code;

-

For RID or ADR tanks: Chapter 4.3 of RID or ADR, and, where applicable, sections 4.2.5 or 4.2.6 of the IMDG Code;

-

For fibre-reinforced plastics tanks: Chapter 4.4 of ADR;

-

For vacuum-operated waste tanks: Chapter 4.5 of ADR.

For carriage in bulk of solids in vehicles, wagons or containers, the following requirements of the international Regulations shall be complied with: -

Chapter 4.3 of the IMDG Code; or

-

Chapter 7.3 of ADR, taking account of indications in columns (10) or (17) of Table A of Chapter 3.2 of ADR, except that sheeted vehicles and containers are not allowed;

-

Chapter 7.3 of RID, taking account of indications in columns (10) or (17) of Table A of Chapter 3.2 of RID, except that sheeted wagons and containers are not allowed.

Only packagings and tanks which meet the requirements of Part 6 may be used.

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PART 5 Consignment procedures

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CHAPTER 5.1 GENERAL PROVISIONS Application and general provisions This Part sets forth the provisions for dangerous goods consignments relative to marking, labelling, and documentation, and, where appropriate, authorisation of consignments and advance notifications.

Use of overpacks (a)

An overpack shall be: (i)

marked with the word "OVERPACK"; and

(ii)

marked with the UN number preceded by the letters "UN", and labelled as required for packages in 5.2.2, for each item of dangerous goods contained in the overpack,

unless the markings and the labels representative of all dangerous goods contained in the overpack are visible. If the same marking or the same label is required for different packages, it only needs to be applied once. The marking of the word "OVERPACK", which shall be readily visible and legible, shall be in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise. (b)

Orientation arrows illustrated in 5.2.1.9 shall be displayed on two opposite sides of the following overpacks:

-

overpacks containing packages which shall be marked in accordance with 5.2.1.9.1, unless the marking remains visible, and

-

overpacks containing liquids in packages which need not be marked in accordance with 5.2.1.9.2. unless the closures remain visible.

Each package of dangerous goods contained in an overpack shall comply with all applicable provisions of ADN. The intended function of each package shall not be impaired by the overpack. The prohibitions on mixed loading also apply to these overpacks. Each package bearing package orientation markings as prescribed in 5.2.1.9 and which is overpacked or placed in a large packaging shall be oriented in accordance with such markings.

Empty uncleaned packagings (including IBCs and large packagings), tanks, vehicles and containers for carriage in bulk Empty uncleaned packagings (including IBCs and large packagings), tanks (including tankvehicles, battery-vehicles, demountable tanks, portable tanks, tank-containers, MEGCs), vehicles and containers for carriage in bulk having contained dangerous goods of the different classes other than Class 7, shall be marked and labelled as if they were full.

NOTE: For documentation, see Chapter 5.4.

Tanks and IBCs used for the carriage of radioactive material shall not be used for the storage or carriage of other goods unless decontaminated below the level of 0.4 ~ ~ / for c m beta~and gamma emitters and low toxicity alpha emitters and 0.04 ~ ~ / for c m all other ~ alpha emitters. Mixed packing

When two or more dangerous goods are packed within the same outer packaging, the package shall be labelled and marked as required for each substance or article. If the same label is required for different goods, it only needs to be applied once. 5.1.5

General provisions for Class 7

5.1.5.1

Requirements before shipments

5.1.5.1.1

Requirements before thefirst shipment of a package Before the first shipment of any package, the following requirements shall be fulfilled:

5.1.5.1.2

(a)

If the design pressure of the containment system exceeds 35 kPa (gauge), it shall be ensured that the containment system of each package conforms to the approved design requirements relating to the capability of that system to maintain its integrity under that pressure;

(b)

For each Type B(U), Type B(M) and Type C package and for each package containing fissile material, it shall be ensured that the effectiveness of its shielding and containment and, where necessary, the heat transfer characteristics and the effectiveness of the confinement system, are within the limits applicable to or specified for the approved design;

(c)

For packages containing fissile material, where, in order to comply with the requirements of 6.4.1 1.1 of ADR, neutron poisons are specifically included as components of the package, checks shall be performed to confirm the presence and distribution of those neutron poisons.

Requirements before each shipment of a package Before each shipment of any package, the following requirements shall be fulfilled: (a)

For any package it shall be ensured that all the requirements specified in the relevant provisions of ADN have been satisfied;

(b)

It shall be ensured that lifting attachments which do not meet the requirements of 6.4.2.2 of ADR have been removed or otherwise rendered incapable of being used for lifting the package, in accordance with 6.4.2.3 of ADR;

(c)

For each package requiring competent authority approval, it shall be ensured that all the requirements specified in the approval certificates have been satisfied;

(d)

Each Type B(U), Type B(M) and Type C package shall be held until equilibrium conditions have been approached closely enough to demonstrate compliance with the requirements for temperature and pressure unless an exemption from these requirements has received unilateral approval;

(e)

For each Type B(U), Type B(M) and Type C package, it shall be ensured by inspection andlor appropriate tests that all closures, valves, and other openings of the containment system through which the radioactive contents might escape are properly closed and, where appropriate, sealed in the manner for which the demonstrations of compliance with the requirements of 6.4.8.7 of ADR were made;

(f)

For each special form radioactive material, it shall be ensured that all the requirements specified in the approval certificate and the relevant provisions of ADN have been satisfied;

(g)

For packages containing fissile material the measurement specified in 6.4.1 1.4 (b) of ADR and the tests to demonstrate closure of each package as specified in 6.4.1 1.7 of ADR shall be performed where applicable;

(h)

For each low dispersible radioactive material, it shall be ensured that all the requirements specified in the approval certificate and the relevant provisions of ADN have been satisfied.

5.1 S.2

Approval of shipments and notification

5.1.5.2.1

General

In addition to the approval for package designs described in Chapter 6.4 of ADR, multilateral shipment approval is also required in certain circumstances (5.1.5.2.2 and 5.1 S.2.3). In some circumstances it is also necessary to notify competent authorities of a shipment (5.1.5.2.4). 5.1S.2.2

Shipment approvals

Multilateral approval shall be required for: (a)

the shipment of Type B(M) packages not conforming with the requirements of 6.4.7.5 of ADR or designed to allow controlled intermittent venting;

(b)

the shipment of Type B(M) packages containing radioactive material with an activity greater than 3000 A, or 3000 AZ,as appropriate, or 1000 TBq, whichever is the lower;

(c)

the shipment of packages containing fissile materials if the sum of the criticality safety indexes of the packages in a single wagon/vehicle or container or in a single conveyanceexceeds 50;

except that a competent authority may authorise carriage into or through its country without shipment approval, by a specific provision in its design approval (see 5.1S.3.l). 5.1.5.2.3

Shipment approval by special arrangement

Provisions may be approved by a competent authority under which a consignment, which does not satisfy all of the applicable requirements of ADN may be carried under special arrangement (see 1.7.4).

Notification to competent authorities is required as follows: (a)

Before the first shipment of any package requiring competent authority approval, the consignor shall ensure that copies of each applicable competent authority certificate

applying to that package design have been submitted to the competent authority of each country through or into which the consignment is to be carried. The consignor is not required to await an acknowledgement from the competent authority, nor is the competent authority required to make such acknowledgement of receipt of the certificate; (b)

For each of the following types of shipments: (i)

Type C packages containing radioactive material with an activity greater than 3000 A, or 3000 A2, as appropriate, or l000 TBq, whichever is the lower;

(ii)

Type B(U) packages containing radioactive material with an activity greater than 3000 AI or 3000 A2, as appropriate, or 1000 TBq, whichever is the lower;

(iii)

Type B(M) packages;

(iv)

Shipment under special arrangement.

The consignor shall notify the competent authority of each country through or into which the consignment is to be carried. This notification shall be in the hands of each competent authority prior to the commencement of the shipment, and preferably at least 7 days in advance; (c)

The consignor is not required to send a separate notification if the required information has been included in the application for shipment approval;

(d)

The consignment notification shall include: sufficient information to enable the identification of the package or packages including all applicable certificate numbers and identification marks; information on the date of shipment, the expected date of arrival and proposed routeing; the name(s) of the radioactive material(s) or nuclide(s); descriptions of the physical and chemical forms of the radioactive material, or whether it is special form radioactive material or low dispersible radioactive material; and the maximum activity of the radioactive contents during carriage expressed in becquerels (Bq) with an appropriate S1 prefix symbol (see 1.2.2.1). For fissile material, the mass of fissile material in grams (g), or multiples thereof, may be used in place of activity.

5.1.5.3

Certificates issued by the competent authority

5.1.5.3.1

Certificates issued by the competent authority are required for the following: (a)

Designs for: (i)

special form radioactive material;

(ii)

low dispersible radioactive material;

(iii)

packages containing 0.1 kg or more of uranium hexafluoride;

- 178 -

(iv)

all packages containing fissile material unless excepted by 6.4.1 1.2 of ADR;

(v)

Type B(U) packages and Type B(M) packages;

(vi)

Type C packages;

(b)

Special arrangements;

(c)

Certain shipments (see 5.1S.2.2).

The certificates shall confirm that the applicable requirements are met, and for design approvals shall attribute to the design an identification mark. The package design and shipment approval certificates may be combined into a single certificate. Certificates and applications for these certificates shall be in accordance with the requirements in 6.4.23 of ADR. 5.1.5.3.2

The consignor shall be in possession of a copy of each applicable certificate. The consignor shall also have a copy of any instructions with regard to the proper closing of the package and any preparation for shipment before making any shipment under the terms of the certificates.

5.1.5.3.3

For package designs where a competent authority issued certificate is not required, the consignor shall, on request, make available for inspection by the competent authority, documentary evidence of the compliance of the package design with all the applicable requirements.

5.1.5.4

Summary of approval and prior notification requirements NOTE l : Before first shipment of any package requiring competent authority approval of the design, the consignor shall ensure that a copy of the approval certificate for that design has been submitted to the competent authority of each country en route (see 5.1.5.2.4 (a)). NOTE 2: NotiJication required ifcontents exceed 3 x 1o3A,, or 3 X 1o3AA or 1000 TBq (see 5.1.5.2.4 (b)). NOTE 3: Multilateral approval of shipment required i f contents exceed 3 X lo3 A,, or 3 x 10" AZ,or 1000 TBq, or ifcontrolled intermittent venting is allowed (see 5.1.5.2). NOTE 4: See approval and prior notification provisions for the applicable package for carrying this material.

I Subject

1

I

I Number

Competent Authority

I

Consignor ( required to notify the competent authorities of the Country Countries country of origin and of the of origin en routea 1 ( countries en routea ( beforeeach shi ment

Reference

I

Tiq--+

Calculation of unlisted A, and A2 values Excepted packages - package design - shipment LSA materialb and S C O ~ Industrial packages types 1 , 2 or 3, non fissile and fissile excepted - package design - shipment Type A packages,b non fissile and fissile excepted - package design - shipment

5.1.5.2.4 (b), 5.1.5.3.1 (a) 5.4.22.2 :ADR)

Type B(U) packages,b non fissile and fissile excepted

- package design - shipment Type B(M) packages,b non fissile and fissile excepted - package design - shipment

Yes No

Yes See Note 3

See Note 1 See Note 2

Yes See Note 3

No Yes

5.1.5.2.4 (b), 5.1.5.3.1 (a) 5.4.22.2 of \DR

rype C packages,b non fissile and fissile excepted

- package design - shipment

5.1.5.2.4 (b), 5.1.5.3.1 (a), 5.1S.2.2. 3.4.22.3 ADR)

Yes No

No No

See Note 1 See Note 2

Consignor required to notify the competent authorities of the Country Countrie! country of origin and of the of origin en routea countries en route' before each shipment Authority

Subject

UN Number

Packages for fissile material - package design - shipment: - sum of criticality safety indexes not more than 50 - sum of criticality safety indexes greater than 50 Special form radioactive material - design - shipment

See Note 4

5.1.5.3.1 (a), 5.1S.2.2, 5.4.22.4 :ADR)

Yesc

Yesc

NO^

NO^

See Note 2

Yes

Yes

See Note 2

Yes See Note 4

No See Note 4

No See Note 4

design shipment

packages containing 0.1 kg or more of uranium hexafluoride - design - shipment

1.6.6.3 ADR), 5.1.5.3.1 (a) 5.4.22.5 ADR) i.1.5.3.1 (a), 5.4.22.5 of IDR

radioactive material

-

Reference

See Note 4

Yes See Note 4

No See Note 4

No See Note 4

i.1.5.3.1 (a), 5.4.22.1 of 4DR See Note 4

Yes See Note 4

No See Note 4

No See Note 4

Yes

Yes

Yes

.7.4.2,

- shipment

i.1.5.3.1 (b),

i.1.5.2.4 (b)

I a

Approved packages designs subjected to transitional measures

See 1.6.6

See 1.6.6

See Note 1

.6.6.1, .6.6.2 ADR), i.1.5.2.4 (b), i.1.5.3.1 (a), i.1.5.2.2.

Countriesfrom, through or into which the consignment is carried.

If the radioactive contents are fissile

material which is not excepted from the provisions for packages containingJissile material, then the provisions for fissile material packages apply (see 6.4.11 of ADR).

Designs ofpackages forfissile material may also require approval in respect of one of the other items in the table. Shipments may, however, require approval in respect of one of the other items in the table.

CHAPTER 5.2 MARKING AND LABELLING Marking of packages

NOTE: For markings related to the construction, testing and approval of packagings, large packagings, gas receptacles and IBCs, see Part 6 ofADR. Unless provided otherwise in ADN, the UN number corresponding to the dangerous goods contained, preceded by the letters "UN" shall be clearly and durably marked on each package. In the case of unpackaged articles the marking shall be displayed on the article, on its cradle or on its handling, storage or launching device. All package markings required by this Chapter: (a)

shall be readily visible and legible;

(b)

shall be able to withstand open weather exposure without a substantial reduction in effectiveness.

Salvage packagings shall additionally be marked with the word "SALVAGE". Intermediate bulk containers of more than 450 litres capacity and large packagings shall be marked on two opposite sides. Additional provisions for goods of Class 1 For goods of Class 1, packages shall, in addition, bear the proper shipping name as determined in accordance with 3.1.2. The marking, which shall be clearly legible and indelible, shall be in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German unless any agreements concluded between the countries concerned in the transport operation provide otherwise. Additional provisions for goods of Class 2 Refillable receptacles shall bear the following particulars in clearly legible and durable characters: (a)

the UN number and the proper shipping name of the gas or mixture of gases, as determined in accordance with 3.1.2. In the case of gases classified under an N.O.S. entry, only the technical name' of the gas has to be indicated in addition to the UN number.

'

Instead of the proper shipping name or , if applicable, of the proper shipping name of the n.o.s. entry followed by the technical name, the use of the following names is permitted: for UN No. 1078 refrigerant gas, n.0.s: mixture F l , mixture F2, mixture F3; for UN No. 1060 methylacetylene andpropadiene mixtures, stabilized: mixture P1, mixture P2; for UN No. 1965 hydrocarbon gas mixture, liquefied, n.0.s: mixture A or butane, mixture A01 or butane, mixture A02 or butane, mixture A0 or butane, mixture A l , mixture BI, mixture B2, mixture B, mixture C or propane. The names customary in the trade and mentioned in 2.2.2.3, ClasslJication code 2F, UN No. 1965, Note l may be used only as a complement; for UN No. 1010 Butadienes, stabilized: 1,2-Butadiene, stabilized, 1,3-Butadiene, stabilized.

In the case of mixtures, not more than the two constituents which most predominantly contribute to the hazards have to be indicated; (b)

for compressed gases filled by mass and for liquefied gases, either the maximum filling mass and the tare of the receptacle with fittings and accessories as fitted at the time of filling, or the gross mass;

(c)

the date (year) of the next periodic inspection.

These marks can either be engraved or indicated on a durable information disk or label attached on the receptacle or indicated by an adherent and clearly visible marking such as by printing or by any equivalent process. NOTE 1: See also 6.2.1.7 of ADR.. NOTE 2: For non refillable receptacles, see 6.2.1.8 of ADR.. 5.2.1.7

Special marking provisions for goods of Class 7

5.2.1.7.1

Each package shall be legibly and durably marked on the outside of the packaging with an identification of either the consignor or consignee, or both.

5.2.1.7.2

For each package, other than excepted packages, the UN number preceded by the letters " U N and the proper shipping name shall be legibly and durably marked on the outside of the packaging. In the case of excepted packages only the UN number, preceded by the letters "UN", is required.

5.2.1.7.3

Each package of gross mass exceeding 50 kg shall have its permissible gross mass legibly and durably marked on the outside of the packaging.

5.2.1.7.4

Each package which conforms to:

5.2.1.7.5

'

(a)

a Type IP-1 package, a Type IP-2 package or a Type IP-3 package design shall be legibly and durably marked on the outside of the packaging with "TYPE IP-l", "TYPE IP-2" or "TYPE IP-3" as appropriate;

(b)

a Type A package design shall be legibly and durably marked on the outside of the packaging with "TYPE A";

(c)

a Type 1P-2 package, a Type IP-3 package or a Type A package design shall be legibly and durably marked on the outside of the packaging with the international vehicle registration code (VRI code)' of the country of origin of design and either the name of the manufacturer or other identification of the packaging specified by the competent authority of the country of origin of design.

Each package which conforms to a design approved by the competent authority shall be legibly and durably marked on the outside of the packaging with: (a)

the identification mark allocated to that design by the competent authority;

(b)

a serial number to uniquely identify each packaging which conforms to that design;

Distinguishing sign for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 184 -

5.2.1.7.6

(c)

in the case of a Type B(U) or Type B(M) package design, with "TYPE B(U)" or "TYPE B(M)"; and

(d)

in the case of a Type C package design, with "TYPE C"

Each package which conforms to a Type B(U), Type B(M) or Type C package design shall have the outside of the outermost receptacle which is resistant to the effects of fire and water plainly marked by embossing, stamping or other means resistant to the effects of fire and water with the trefoil symbol shown in the figure below. Basic trefoil symbol with proportions based on a central circle of radius X. The minimum allowable size of X shall be 4 mm.

5.2.1.7.7

Where LSA-I or SCO-I material is contained in receptacles or wrapping materials and is carried under exclusive use as permitted by 4.1.9.2.3 of ADR, the outer surface of these receptacles or wrapping materials may bear the marking "RADIOACTIVE LSA-I" or "RADIOACTIVE SCO-I", as appropriate.

5.2.1.7.8

In case of international carriage of packages requiring competent authority design or shipment approval, for which different approval types apply in the different countries concerned, marking shall be in accordance with the certificate of the country of origin of the design.

5.2.1.8

(Reserved).

5.2.1.9

Orientation arrows

5.2.1.9.1

Except as provided in 5.2.1.9.2:

-

combination packagings having inner packagings containing liquids;

-

single packagings fitted with vents; and

-

cryogenic receptacles intended for the carriage of refrigerated liquefied gases,

shall be legibly marked with package orientation arrows which are similar to the illustration shown below or with those meeting the specifications of I S 0 780:1985. The orientation arrows shall appear on two opposite vertical sides of the package with the arrows pointing in the correct upright direction. They shall be rectangular and of a size that is clearly visible commensurate with the size of the package. Depicting a rectangular border around the arrows is optional.

Two black or red arrows on white or suitable contrasting background. The rectangular border is optional. Orientation arrows are not required on packages containing: pressure receptacles except for closed cryogenic receptacles; dangerous goods in inner packagings of not more than 120 m1 which are prepared with sufficient absorbent material between the inner and outer packagings to completely absorb the liquid contents; Class 6.2 infectious substances in primary receptacles of not more than 50 ml; Class 7 radioactive material in Type IP-2, IP-3, A, B(U), B(M) or C packages; or articles which are leak-tight in all orientations (e.g. alcohol or mercury in thermometers, aerosols, etc.). Arrows for purposes other than indicating proper package orientation shall not be displayed on a package marked in accordance with this sub-section. Labelling of packages Labelling provisions

For each article or substance listed in Table A of Chapter 3.2, the labels shown in Column (5) shall be affixed unless otherwise provided for by a special provision in Column (6). Indelible danger markings corresponding exactly to the prescribed models may be used instead of labels. (Reserved). Except as provided in 5.2.2.2.1.2, each label shall:

(a)

be affixed to the same surface of the package, if the dimensions of the package allow; for packages of Class 1 and 7, near the mark indicating the proper shipping name;

(b)

be so placed on the package that it is not covered or obscured by any part or attachment to the packaging or any other label or marking; and

(c)

be displayed next to each other when more than one label is required.

Where a package is of such an irregular shape or small size that a label cannot be satisfactorily affixed, the label may be attached to the package by a securely affixed tag or other suitable means. 5.2.2.1.7

Intermediate bulk containers of more than 450 litres capacity shall be labelled on two opposite sides.

5.2.2.1.8

(Reserved).

5.2.2.1.9

Special provisions for the labelling of self-reactive substances and organic peroxides (a)

the label conforming to model No. 4.1 also implies that the product may be flammable and hence no label conforming to model No. 3 is required. In addition, a label conforming to model No. 1 shall be applied for self-reactive substances Type B, unless the competent authority has permitted this label to be dispensed with for a specific packaging because test data have proven that the self-reactive substance in such a packaging does not exhibit explosive behaviour.

(b)

the label conforming to model No. 5.2 also implies that the product may be flammable and hence no label conforming to model No. 3 is required. In addition, the following labels shall be applied: (i)

a label conforming to model No. 1 for organic peroxides type B, unless the competent authority has permitted this label to be dispensed with for a specific packaging because test data have proven that the organic peroxide in such a packaging does not exhibit explosive behaviour;

(ii)

a label conforming to model No. 8 is required when Packing Group I or I1 criteria of Class 8 are met.

For self-reactive substances and organic peroxides mentioned by name, the labels to be affixed are indicated in the list found in 2.2.41.4 and 2.2.52.4 respectively. 5.2.2.1.10

Special provisions for the labelling of infectious substances packages In addition to the label conforming to model No. 6.2, infectious substances packages shall bear any other label required by the nature of the contents.

5.2.2.1.1 1

Special provisions for the labelling of radioactive material

5.2.2.1.1 1.1

Except as provided for large containers and tanks in accordance with 5.3.1.1.3, each package, overpack and container containing radioactive material shall bear at least two labels which conform to the models Nos. 7A, 7B, and 7C as appropriate according to the category (see 2.2.7.8.4) of that package, overpack or container. Labels shall be affixed to two opposite sides on the outside of the package or on the outside of all four sides of the container. Each overpack containing radioactive material shall bear at least two labels on opposite sides of the outside of the overpack. In addition, each package, overpack and container containing fissile material, other than fissile material excepted under 6.4.1 1.2 of ADR shall bear labels

which conform to model No. 7E; such labels, where applicable shall be affixed adjacent to the labels for radioactive material. Labels shall not cover the markings specified in 5.2.1. Any labels which do not relate to the contents shall be removed or covered. 5.2.2.1.11.2

Each label conforming to models Nos. 7A, 7B, and 7C shall be completed with the following information: (a)

Contents: (i)

except for LSA-I material, the name(s) of the radionuclide(s) as taken from Table 2.2.7.7.2.1, using the symbols prescribed therein. For mixtures of radionuclides, the most restrictive nuclides shall be listed to the extent the space on the line permits. The group of LSA or SCO shall be shown following the name(s) of the radionuclide(s). The terms "LSA-II","LSA-111", "SCO-I" and "SCO-11" shall be used for this purpose;

(ii)

for LSA-I material, only the term "LSA-I" is necessary; the name of the radionuclide is not necessary;

(b)

Activity: The maximum activity of the radioactive contents during carriage expressed in becquerels (Bq) with the appropriate S1 prefix symbol (see 1.2.2.1). For fissile material, the mass of fissile material in grams (g), or multiples thereof, may be used in place of activity;

(c)

For overpacks and containers the "contents" and "activity" entries on the label shall bear the information required in (a) and (b) above, respectively, totalled together for the entire contents of the overpack or container except that on labels for overpacks or containers containing mixed loads of packages containing different radionuclides, such entries may read "See Transport Documents";

(d)

Transport index (TI): see 2.2.7.6.1.1 and 2.2.7.6.1.2 (no transport index entry is required for category I-WHITE).

5.2.2.1.11.3

Each label conforming to the model No. 7E shall be completed with the criticality safety index (CSI) as stated in the certificate of approval for special arrangement or the certificate of approval for the package design issued by the competent authority.

5.2.2.1.1 1.4

For overpacks and containers, the criticality safety index (CSI) on the label shall bear the information required in 5.2.2.1.1 1.3 totalled together for the fissile contents of the overpack or container.

5.2.2.1.1 1.5

In case of international carriage of packages requiring competent authority design or shipment approval, for which different approval types apply in the different countries concerned, labelling shall be in accordance with the certificate of the country of origin of design.

5.2.2.2

Provisions for labels

5.2.2.2.1

Labels shall satisfy the provisions below and conform, in terms of colour, symbols and general format, to the models shown in 5.2.2.2.2. NOTE: Where appropriate, labels in 5.2.2.2.2 are shown with a dotted outer boundary as provided for in 5.2.2.2.1.1. This is not required when the label is applied on a background of contrasting colour.

5.2.2.2.1.1

Labels shall be in the form of a square set at an angle of 45" (diamond-shaped) with minimum dimensions of 100 mm by 100 mm. They have a line of the same colour as the symbol, 5 mm inside the edge and running parallel with it. Labels shall be displayed on a background of contrasting colour, or shall have either a dotted or solid outer boundary line.

5.2.2.2.1.2

Gas cylinders for Class 2 may, on account of their shape, orientation and securing mechanisms for carriage, bear labels representative of those specified in this section, which have been reduced in size, according to the dimensions outlined in IS0 7225:1994, "Gas cylinders - Precautionary labels ", for display on the non-cylindrical part (shoulder) of such cylinders. Notwithstanding the provisions of 5.2.2.1.6, labels may overlap to the extent provided for by IS0 7225. However, in all cases, the primary risk label and the figures appearing on any label shall remain fully visible and the symbols recognizable. Empty uncleaned pressure receptacles for gases of Class 2 may be carried with obsolete or damaged labels for the purposes of refilling or inspection as appropriate and the application of a new label in conformity with current regulations or for the disposal of the pressure receptacle.

5.2.2.2.1.3

Labels are divided into halves. With the exception of Divisions 1.4, 1.5 and 1.6, the upper half of the label is reserved for the pictorial symbol and the lower half for texts and the class number and the compatibility group letter as appropriate.

NOTE: For the labels of Classes 1, 2, 3, 5.1, 5.2, 7, 8 and 9, the respective class number shall be shown in the bottom corner. For the labels of Classes 4.1, 4.2 and 4.3 and of Classes 6.1 and 6.2 only figures 4 and 6 respectively shall be shown in the bottom corner (see 5.2.2.2.2). 5.2.2.2.1.4

Except for Divisions 1.4, 1.5 and 1.6, labels for Class 1 show in the lower half the division number and compatibility group letter for the substance or article. Labels for Divisions 1.4, 1.5 and 1.6 show in the upper half the division number and in the lower half the compatibility group letter.

5.2.2.2.1.5

On labels other than those for material of Class 7, the optional insertion of any text (other than the class number) in the space below the symbol shall be confined to particulars indicating the nature of the risk and precautions to be taken in handling.

5.2.2.2.1.6

The symbols, text and numbers shall be clearly legible and indelible and shall be shown in black on all labels except for:

5.2.2.2.1.7

(a)

the Class 8 label, where the text (if any) and class number shall appear in white;

(b)

labels with entirely green, red or blue backgrounds where they may be shown in white: and

(c)

labels conforming to model No. 2.1 displayed on cylinders and gas cartridges for gases of UN Nos. 1011, 1075, 1965 and 1978, where they may be shown in the background colour of the receptacle if adequate contrast is provided.

All labels shall be able to withstand open weather exposure without a substantial reduction in effectiveness.

5.2.2.2.2 Specimen labels

CLASS l HAZARD Explosive substances or articles

(No. 1) Divisions 1.1, 1.2 and 1.3 Symbol (exploding bomb): black; Background: orange; Figure 'l' in bottom corner

(No. 1.5) (No. 1.6) (No. 1.4) Division 1.5 Division 1.6 Division 1.4 Background: orange; Figures: black; Numerals shall be about 30 mm in height and be about 5 mm thick (for a label measuring 100 mm X 100 mm); Figure ' 1' in bottom corner

** Place for division - to be left blank if explosive is the subsidiary risk * Place for compatibility group - to be left blank if explosive is the subsidiary risk CLASS 2 HAZARD Gases

Flammable gases Symbol (flame): black or white; (except as provided for in 5.2.2.2.1.6 (c)) Background: red; Figure '2' in bottom corner

(No. 2.3) Toxic gases Symbol (skull and crossbones): black; Background: white; Figure '2' in bottom corner

Non flammable, non-toxic gases Symbol (gas cylinder): black or white; Background: green; Figure '2' in bottom comer

(No. 3) Symbol (flame): black or white; Background: red; Figure '3' in bottom comer

CLASS 4.1 HAZARD Flammable solids, self-reactive substances and desensitized explosives

(No. 4.1) Symbol (flame): black; Background: white with seven vertical red stripes; Figure '4' in bottom corner

CLASS 4.2 HAZARD Substances liable to spontaneous combustion

(No. 4.2) Symbol (flame): black; Background: upper half white, lower half red; Figure '4' in bottom corner

CLASS 4.3 HAZARD Substances which, in contact with water, emit flammable gases

(No. 4.3) Symbol (flame): black or white; Background: blue; Figure '4' in bottom corner

CLASS 5.2 HAZARD Organic peroxides

CLASS 5.1 HAZARD Oxidizing substances

(No. 5.1) Symbol (flame over circle): black; Background: yellow; Figure '5.1' in bottom corner

(No. 5.2) Symbol (flame): black or white; Background: upper half red; lower half yellow; Figure '5.2' in bottom corner

CLASS 6.1 HAZARD Toxic substances

WO.6.1) Symbol (skull and crossbones): black; Background: white; Figure '6' in bottom corner

CLASS 6.2 HAZARD Infectious substances

(No. 6.2) The lower half of the label may bear the inscriptions: 'INFECTIOUS SUBSTANCE' and 'In the case of damage or leakage immediately notify Public Health Authority'; Symbol (three crescents superimposed on a circle) and inscriptions: black; Background: white; Figure '6' in bottom corner

CLASS 7 HAZARD Radioactive material

(No. 7A) (No 7B) (No 7C) Category I11 - Yellow Category I1 - Yellow Category I - White Symbol (trefoil): black; Symbol (trefoil): black; Background: upper half yellow with white border, lower half white; Background: white; Text (mandatory): black in lower half of label: Text (mandatory): black in lower half of label: 'RADIOACTIVE' 'RADIOACTIVE' 'CONTENTS .......' 'CONTENTS .......' 'ACTIVITY ......' 'ACTIVITY ......' In a black outlined box: 'TRANSPORT INDEX'; One red bar shall Three red vertical bars shall Two red vertical bars shall follow the word 'RADIOACTIVE'; follow the word 'RADIOACTIVE'; follow the word 'RADIOACTIVE'; Figure '7' in bottom corner. Figure '7' in bottom corner.

(No. 7E) Class 7 fissile material Background: white; Text (mandatory): black in upper half of label: 'FISSILE'; In a black outlined box in the lower half of the label: 'CRITICALITY SAFETY INDEX' Figure '7' in bottom corner.

CLASS 8 HAZARD Corrosive substances

,

(No. 8) Symbol (liquids, spilling from two glass vessels and attacking a hand and a metal): black; Background: upper half white; lower half black with white border; Figure '8' in bottom corner

CLASS 9 HAZARD Miscellaneous dangerous substances and articles

(No. 9) Symbol (seven vertical stripes in upper halt): black; Background: white; Figure '9' underlined in bottom corner

CHAPTER 5.3 PLACARDING AND MARKING OF CONTAINERS, MEGCs, TANK-CONTAINERS, PORTABLE TANKS, VEHICLES AND WAGONS For marking and placarding of containers, MEGCs, tank-containers and NOTE l : portable tanks for carriage in a transport chain including a maritime journey, see also 1.1.4.2.1. 1f the provisions of 1.1.4.2.1 (c) are applied, only 5.3.1.3 and 5.3.2.1.1 of this Chapter are applicable.

NOTE 2: For the purposes of this subsection, "transport unit" means a motor vehicle without an attached trailer or a combination consisting of a motor vehicle and an attached trailer. 5.3.1

Placarding

5.3.1.1

General provisions

5.3.1.1.1

As and when required in this section, placards shall be affixed to the exterior surface of containers, MEGCs, tank-containers, portable tanks, vehicles and wagons. Placards shall correspond to the labels required in Column (5) and, where appropriate, Column (6) of Table A of Chapter 3.2 for the dangerous goods contained in the container, MEGC, tank-container, portable tank, vehicle or wagon and shall conform to the specifications given in 5.3.1.7. Placards shall be displayed on a background of contrasting colour, or shall have either a dotted or solid outer boundary line.

5.3.1.1.2

For Class 1, compatibility groups shall not be indicated on placards if the vehicle or wagon or container is carrying substances or articles belonging to two or more compatibility groups. Vehicles or wagons or containers carrying substances or articles of different divisions shall bear only placards conforming to the model of the most dangerous division in the order: 1.1 (most dangerous), 1.5, 1.2, 1.3, 1.6, 1.4 (least dangerous). When 1.5D substances are carried with substances or articles of Division 1.2, the vehicle, wagon or container shall be placarded as Division 1.1. Placards are not required for the carriage of explosives of Division 1.4, Compatibility Group S.

5.3.1.1.3

For Class 7, the primary risk placard shall conform to model No. 7D as specified in 5.3.1.7.2. This placard is not required for vehicles, wagons or containers carrying excepted packages and for small containers. Where both Class 7 labels and placards would be required to be affixed to vehicles, wagons, containers, MEGCs, tank-containers or portable tanks, an enlarged label corresponding to the label required may be displayed instead of placard No. 7D to serve both purposes.

5.3.1.1.4

Containers, MEGCs, tank-containers, portable tanks, vehicles or wagons containing goods of more than one class need not bear a subsidiary risk placard if the hazard represented by that placard is already indicated by a primary or subsidiary risk placard.

5.3.1.1.5

Placards which do not relate to the dangerous goods being carried, or residues thereof, shall be removed or covered.

Placarding of containers, MEGCs, tank-containers andportable tanks NOTE: This subsection does not apply to swap-bodies, except tank swap bodies carried on vehicles bearing the orange markings stipulated in 5.3.2.

The placards shall be affixed to both sides and at each end of the container, MEGC, tank-container or portable tank. When the tank-container or portable tank has multiple compartments and carries two or more dangerous goods, the appropriate placards shall be displayed along each side at the position of the relevant compartments and one placard of each model shown on each side at both ends. Placarding of vehicles carrying containers, MEGCs, tank-containers or portable tanks NOTE: This subsection does not apply to swap-bodies, except tank swap bodies carried on vehicles bearing the orange markings stipulated in 5.3.2.

If the placards affixed to the containers, MEGCs, tank-containers or portable tanks are not visible from outside the carrying vehicles, the same placards shall also be affixed to both sides and at the rear of the vehicle. Otherwise, no placard need be affixed on the carrying vehicle. Placarding of vehicles for carriage in bulk, wagons for carriage in bulk, tank-vehicles, tank-wagons, battery vehicles, battery-wagons, vehicles with demountable tanks and wagons with demountable tanks

Placards shall be affixed to both sides and at the rear of the vehicle, or, for wagons, to both sides. When the tank-vehicle, tank-wagon, the demountable tank carried on the vehicle or the demountable tank carried on the wagon has multiple compartments and carries two or more dangerous goods, the appropriate placards shall be displayed along each side at the position of the relevant compartments and (vehicles only) one placard of each model shown on each side at the rear of the vehicle. However, in such case, if all compartments have to bear the same placards, these placards need be displayed only once along each side and (vehicles only) at the rear of the vehicle. Where more than one placard is required for the same compartment, these placards shall be displayed adjacent to each other. NOTE: When, a tank semi-trailer is separated from its tractor to be loaded on board a ship or a vessel, placards shall also be displayed at thefront of the semi-trailer. Placarding of vehicles carrying packages only NOTE: This sub-section applies also to vehicles or wagons carving swap-bodies loaded with packages. 5.3.1 S. 1

For vehicles carrying packages containing substances or articles of Class 1 (other than of Division 1.4, Compatibility Group S), placards shall be affixed to both sides and at the rear of the vehicle.

5.3.1.5.2

For vehicles carrying radioactive material of Class 7 in packagings or IBCs (other than excepted packages), placards shall be affixed to both sides and at the rear of the vehicle.

NOTE: If a vehicle carrying packages containing dangerous goods of classes other than Classes l and 7 is loaded on board a vessel for an ADN journey preceding a voyage by sea, placards shall be afJixed to both sides and at the rear of the vehicle. Such placards may remain affixed to a vehiclefor an ADN journey following a sea voyage. 5.3.1.5.3

For wagons carrying packages, placards corresponding to the goods carried shall be affixed to both sides.

5.3.1.6

Placarding of empty tank-vehicles, tank-wagons, vehicles with demountable tanks, wagons with demountable tanks, battery-vehicles, battery-wagons, MEGCs, tank-containers, portable tanks and empty vehicles, wagons and containers for carriage in bulk

5.3.1.6.1

Empty tank-vehicles, tank-wagons, vehicles with demountable tanks, wagons with demountable tanks, battery-vehicles, battery-wagons, MEGCs, tank-containers and portable tanks uncleaned and not degassed, and empty vehicles, wagons and containers for carriage in bulk, uncleaned, shall continue to display the placards required for the previous load.

5.3.1.7

Specifications for placards

5.3.1.7.1

Except as provided in 5.3.1.7.2 for the Class 7 placard, a placard shall: be not less than 250 mm by 250 mm, with a line of the same colour as the (a) symbol running 12.5 mm inside the edge and parallel with it; correspond to the label required for the dangerous goods in question with (b) respect to colour and symbol (see 5.2.2.2); and display the numbers (and for goods of Class l, the compatibility group letter) (C) prescribed for the dangerous goods in question in 5.2.2.2 for the corresponding label, in digits not less than 25 mm high.

5.3.1.7.2

The Class 7 placard shall be not less than 250 mm by 250 mm with a black line running 5 mm inside the edge and parallel with it and is otherwise as shown below (Model No. 7D). The number "7" shall not be less than 25 mm high. The background colour of the upper half of the placard shall be yellow and of the lower half white, the colour of the trefoil and the printing shall be black. The use of the word "RADIOACTIVE" in the bottom half is optional to allow the use of this placard to display the appropriate UN number for the consignment.

Placard for radioactive material of Class 7

(No.7D) Symbol (trefoil): black; Background: upper half yellow with white border, lower half white; The lower half shall show the word "RADIOACTIVE" or alternatively, when required, the appropriate UN Number (see 5.3.2.1.2) and the figure "7" in the bottom corner. 5.3.1.7.3

For tanks with a capacity of not more than 3 m3 and for small containers, placards may be replaced by labels conforming to 5.2.2.2.

5.3.1.7.4

For Classes 1 and 7, if the size and construction of the vehicle are such that the available surface area is insufficient to affix the prescribed placards, their dimensions may be reduced to 100 mm on each side.

5.3.2

Orange-coloured plate marking

5.3.2.1

General orange-coloured plate marking provisions

5.3.2.1 . l

Transport units carrying dangerous goods shall display two rectangular orange-coloured plates conforming to 5.3.2.2.1, set in a vertical plane. They shall be affixed one at the front and the other at the rear of the transport unit, both perpendicular to the longitudinal axis of the transport unit. They shall be clearly visible. When a hazard identification number is indicated,in Column (20) of Table A of Chapter 3.2 of ADR, tank-vehicles, battery vehicles or transport units having one or more tanks carrying dangerous goods shall in addition display on the sides of each tank, each tank compartment or each element of battery-vehicles, clearly visible and parallel to the longitudinal axis of the vehicle, orange-coloured plates identical with those prescribed in 5.3.2.1.1. These orange-coloured plates shall bear the hazard identification number and the UN number prescribed respectively in Columns (20) and (1) of Table A of Chapter 3.2 of ADR for each of the substances carried in the tank, in a compartment of the tank or in an element of a battery-vehicle. The provisions of this paragraph are also applicable to tank-wagons, battery-wagons and wagons with movable tanks.

5.3.2.1.3

For tank-vehicles or transport units having one or more tanks carrying substances with UN Nos. 1202, 1203 or 1223, or aviation fuel classed under UN Nos. 1268 or 1863, but no other dangerous substance, the orange-coloured plates prescribed in 5.3.2.1.2 need not be affixed if the plates affixed to the front and rear in accordance with 5.3.2.1.1 bear the hazard

identification number and the UN number prescribed for the most hazardous substance carried, i.e. the substance with the lowest flashpoint. 5.3.2.1.4

When a hazard identification number is indicated in Column (20) of Table A of Chapter 3.2 of ADR, transport units and containers carrying dangerous solid substances in bulk or packaged radioactive material with a single UN number under exclusive use and no other dangerous goods shall in addition display on the sides of each transport unit or container, clearly visible and parallel to the longitudinal axis of the vehicle, orange-coloured plates identical with those prescribed in 5.3.2.1.1. These orange-coloured plates shall bear the hazard identification number and the UN number prescribed respectively in Columns (20) and (1) of Table A of Chapter 3.2 of ADR for each of the substances carried in bulk in the transport unit or in the container or for the packaged radioactive material carried under exclusive use in the transport unit or in the container. The provisions of this paragraph are also applicable to wagons for carriage in bulk and full wagon loads comprising packages containing only one substance. In the latter case the hazard identification number to be used is that indicated in Column (20) of Table A of Chapter 3.2 of RID.

5.3.2.1.5

If the orange-coloured plates prescribed in 5.3.2.1.2 and 5.3.2.1.4 affixed to the containers, tank-containers, MEGCs or portable tanks are not clearly visible from outside the carrying vehicle or wagon, the same plates shall also be affixed to both sides of the vehicle or wagon.

5.3.2.1.6

For transport units carrying only one substance, the orange-coloured plates prescribed in 5.3.2.1.2, 5.3.2.1.4 and 5.3.2.1.5 shall not be necessary provided that those displayed at the front and rear in accordance with 5.3.2.1.1 bear the hazard identification number and the UN number prescribed respectively in Columns (20) and (1) of Table A of Chapter 3.2 of ADR.

5.3.2.1.7

The requirements of 5.3.2.1.1 to 5.3.2.1.5 are also applicable to empty fixed or demountable tanks, battery-vehicles, tank-containers, portable tanks , MEGCs, tank-wagons, batterywagons and wagons with demountable tanks, uncleaned, not degassed or not decontaminated as well as to empty vehicles, wagons and containers for carriage in bulk, uncleaned or not decontaminated.

5.3.2.1.8

Orange-coloured marking which does not relate to dangerous goods carried, or residues thereof, shall be removed or covered. If plates are covered, the covering shall be total and remain effective after 15 minutes' engulfment in fire.

5.3.2.2

Specificationsfor the orange-colouredplates

5.3.2.2.1

The orange-coloured plates shall be reflectorized and shall be of 40 cm base and of 30 cm high; they shall have a black border of 15 mm wide. The material used shall be weatherresistant and ensure durable marking. The plate shall not become detached from its mount in the event of a 15 minutes' engulfment in fire. The orange-coloured plates may be separated in their middle with a black horizontal line of 15 mm thickness. If the size and construction of the vehicle are such that the available surface area is insufficient to affix these orange-coloured plates, their dimensions may be reduced to 300 mm for the base, 120 mm for the height and 10 mm for the black border. A non-reflectorized colour is permitted for wagons. For containers carrying dangerous solid substances in bulk and for tank-containers, MEGCs and portable tanks, the plates prescribed in 5.3.2.1.2, 5.3.2.1.4 and 5.3.2.1.5 may be replaced by a self-adhesive sheet, by paint or by any other equivalent process.

This alternative marking shall conform to the specifications set in this sub-section except for the provisions concerning resistance to fire mentioned in 5.3.2.2.1 and 5.3.2.2.2. NOTE: The colour of the orange plates in conditions of normal use should have chromaticity coordinates lying within the area on the chromaticity diagram formed by joining thefollowing coordinates:

x Y

Chromaticity coordinates ofpoints at the corners of the area on the chromaticity diagram 0.52 0.52 0.578 0.40 0.422 0.38

0.618 0.38

Luminance factor of reflectorized colour: P > 0.12. Luminance factor of non-reflectorized colour (wagons): P? 0.22 Reference centre E, standard illuminant C, normal incidence 4-59 viewed at 0'. CoefJicient of reflex luminous intensity at an angle of illumination of -59 viewed at 0.2': not less than 20 candelas per lux per m2 (not requiredfor wagons). 5.3.2.2.2

The hazard identification number and the UN number shall consist of black digits 100 mm high and of 15 mm stroke thickness. The hazard identification number shall be inscribed in the upper part of the plate and the UN number in the lower part; they shall be separated by a horizontal black line, 15 mm in stroke width, extending from side to side of the plate at mid-height (see 5.3.2.2.3). The hazard identification number and the UN number shail be indelible and shall remain legible after 15 minutes engulfment in fire.

5.3.2.2.3

Example of orange-colouredplate with hazard identijication number and UN number

Hazard identification number (2 or 3 figures preceded where appropriate by the letter X, see 5.3.2.3)

UN number (4 figures)

Background orange. Border, horizontal line and figures black, 15 mm thickness. 5.3.2.2.4

The permitted tolerances for dimensions specified in this sub-section are k 10%.

5.3.2.3

Meaning of hazard identiJication numbers

5.3.2.3.1

The hazard identification number consists of two or three figures. In general, the figures indicate the following hazards:

2 3 4 5 6 7 8 9

Emission of gas due to pressure or to chemical reaction Flammability of liquids (vapours) and gases or self-heating liquid Flammability of solids or self-heating solid Oxidizing (fire-intensifying) effect Toxicity or risk of infection Radioactivity Corrosivity Risk of spontaneous violent reaction

NOTE: The risk of spontaneous violent reaction within the meaning offigure 9 includes the possibility following from the nature of a substance of a risk of explosion, disintegration and polymerization reaction following the release of considerable heat or flammable and/or toxic gases. Doubling of a figure indicates an intensification of that particular hazard. Where the hazard associated with a substance can be adequately indicated by a single figure, this is followed by zero. The following combinations of figures, however, have a special meaning: 22, 323, 333, 362, 382,423,44,446,462,482, 539,606,623,642, 823, 842,90 and 99 (see 5.3.2.3.2 below). If a hazard identification number is prefixed by the letter "X", this indicates that the substance will react dangerously with water. For such substances, water may only be used by approval of experts. For substances of Class l, the classification code in accordance with Column (3 b) of Table A of Chapter 3.2, shall be used as the hazard identification number. The classification code consists of:

5.3.2.3.2

-

the division number in accordance with 2.2.1.1 S; and

-

the compatibility group letter in accordance with 2.2.1.1.6.

The hazard identification numbers listed in Column (20) of Table A of Chapter 3.2 have the following meanings: asphyxiant gas or gas with no subsidiary risk refrigerated liquefied gas, asphyxiant refrigerated liquefied gas, flammable refrigerated liquefied gas, oxidizing (fire-intensifying) flammable gas flammable aerosols, corrosive flammable gas, which can spontaneously lead to violent reaction oxidizing (fire-intensifying) gas toxic gas toxic gas, flammable toxic gas, oxidizing (fire-intensifying) toxic gas, corrosive aerosols, corrosive aerosols, corrosive, oxidizing 30

flammable liquid (flashpoint between 23 "C and 60 "C, inclusive) or flammable liquid or solid in the molten state with a flashpoint above 60 "C, heated to a temperature equal to or above its flashpoint, or self-heating liquid

- 199 -

flammable liquid which reacts with water, emitting flammable gases flammable liquid which reacts dangerously with water, emitting flammable gases1 highly flammable liquid (flashpoint below 23 "C) pyrophoric liquid pyrophoric liquid which reacts dangerously with water1 highly flammable liquid, toxic highly flammable liquid, corrosive highly flammable liquid, corrosive, which reacts dangerously with water' highly flammable liquid which can spontaneously lead to violent reaction flammable liquid (flashpoint between 23 "C and 60 "C, inclusive), slightly toxic, or self-heating liquid, toxic flammable liquid, toxic, which reacts with water, emitting flammable gases flammable liquid, toxic, which reacts dangerously with water, emitting flammable gases1 flammable liquid, toxic, corrosive flammable liquid (flashpoint between 23 "C and 60 "C, inclusive), slightly corrosive or self-heating liquid, corrosive flammable liquid, corrosive, which reacts with water, emitting flammable gases flammable liquid, corrosive, which reacts dangerously with water, emitting flammable gases' flammable liquid, which can spontaneously lead to violent reaction flammable solid, or self-reactive substance, or self-heating substance solid which reacts with water, emitting flammable gases flammable solid which reacts dangerously with water, emitting flammable gases1 spontaneously flammable (pyrophoric) solid flammable solid, in the molten state at an elevated temperature flammable solid, toxic, in the molten state, at an elevated temperature flammable or self-heating solid, toxic toxic solid which reacts with water, emitting flammable gases solid which reacts dangerously with water, emitting toxic gases1 flammable or self-heating solid, corrosive corrosive solid which reacts with water, emitting flammable gases solid which reacts dangerously with water, emitting corrosive gases1 oxidizing (fire-intensifying) substance flammable organic peroxide strongly oxidizing (fire-intensifying) substance strongly oxidizing (fire-intensifying) substance, toxic strongly oxidizing (fire-intensifying) substance, corrosive strongly oxidizing (fire-intensifying) substance, which can spontaneously lead to violent reaction oxidizing substance (fire-intensifying), toxic oxidizing substance (fire-intensifying), toxic, corrosive oxidizing substance (fire-intensifying), corrosive oxidizing substance (fire-intensifying), which can spontaneously lead to violent reaction toxic or slightly toxic substance infectious substance toxic liquid, which reacts with water, emitting flammable gases 1

Water not to be used except by approval of experts. - 200 -

toxic substance, flammable (flashpoint between 23 "C and 60 "C, inclusive) toxic substance, flammable (flashpoint between 23 "C and 60 "C, inclusive), corrosive toxic substance, flammable (flashpoint not above 60 "C) which can spontaneously lead to violent reaction toxic solid, flammable or self-heating toxic solid, which reacts with water, emitting flammable gases toxic substance, oxidizing (fire-intensifying) highly toxic substance highly toxic substance, flammable (flashpoint not above 60 "C) highly toxic solid, flammable or self-heating highly toxic substance, oxidizing (fire-intensifying) highly toxic substance, corrosive highly toxic substance which can spontaneously lead to violent reaction toxic substance, corrosive toxic or slightly toxic substance, which can spontaneously lead to violent reaction radioactive material radioactive material, corrosive corrosive or slightly corrosive substance corrosive or slightly corrosive substance, which reacts dangerously with water' corrosive liquid which reacts with water, emitting flammable gases corrosive or slightly corrosive substance, flammable (flashpoint between 23 "C and 60 "C, inclusive) corrosive or slightly corrosive substance, flammable, (flashpoint between 23 "C and 60 "C, inclusive), which reacts dangerously with water1 corrosive or slightly corrosive substance, flammable (flashpoint between 23 "C and 60 "C inclusive) which can spontaneously lead to violent reaction corrosive or slightly corrosive substance, flammable (flashpoint between 23 "C and 60 "C inclusive), which can spontaneously lead to violent reaction and which reacts dangerously with water' corrosive solid, flammable or self-heating corrosive solid which reacts with water, emitting flammable gases corrosive or slightly corrosive substance, oxidizing (fire-intensifying) corrosive or slightly corrosive substance, oxidizing (fire-intensifying) and toxic corrosive or slightly corrosive substance, toxic highly corrosive substance highly corrosive substance, which reacts dangerously with water' highly corrosive substance, flammable (flashpoint between 23 "C and 60 "C inclusive) highly corrosive solid, flammable or self-heating highly corrosive substance, oxidizing (fire-intensifying) highly corrosive substance, toxic highly corrosive substance, toxic, which reacts dangerously with water1 corrosive or slightly corrosive substance, which can spontaneously lead to violent reaction environmentally hazardous substance; miscellaneous dangerous substances miscellaneous dangerous substance carried at an elevated temperature.

'

Water not to be used except by approval of experts. - 201 -

Mark for elevated temperature substances Tank-vehicles, tank-wagons, tank-containers, portable tanks, special vehicles, special wagons or special containers or especially equipped vehicles, especially equipped wagons or especially equipped containers for which a mark for elevated temperature substances is required according to special provision 580 in Column (6) of Table A of Chapter 3.2 shall bear on both sides for wagons, on both sides and at the rear for vehicles, and on both sides and at each end for containers, tank-containers and portable tanks, a triangular shaped mark with sides of at least 250 mm, to be shown in red, as reproduced below.

Marking for carriage in a transport chain including maritime transport For carriage in a transport chain including maritime transport, containers, portable tanks and MEGCs are not required to carry the orange-coloured plate marking according to sections 5.3.2 and 5.3.3 if they carry the marking prescribed in section 5.3.2 of the IMDG Code, where: (a)

(b)

The proper shipping name of the contents is durably marked on at least two sides: -

of portable tanks and MEGCs;

-

of containers for carriage in bulk;

-

of containers containing dangerous goods in packages constituting only one substance for which the IMDG Code does not require a placard or the marine pollutant mark;

The UN number for the goods is displayed in black digits not less than 65 mm high: -

either on a white background in the lower half of the placards affixed to the transport unit;

-

or on an orange rectangular panel not less than 120 mm high and 300 mm wide, with a 10 mm black border, to be placed immediately adjacent to the placard or the marine pollutant marks of the IMDG Code, or, if no placard or marine pollutant mark is prescribed, adjacent to the proper shipping name.

Example of marking for a tank-container carrying acetal, Class 3, UN No 1088, according to the IMDG Code

FIRST VARIANT black flame on red background

SECOND VARIANT

black flame on red background

orange background border and digits in black If portable tanks, MEGCs or containers marked in accordance with 5.3.4.1 are carried on board a vessel loaded on vehicles, only paragraph 5.3.2.1.1 of section 5.3.2 applies to the carrying vehicle. In addition to the placards, orange-coloured plate marking and marks prescribed or permitted by ADN, transport units may carry additional marks, placards and other markings prescribed where appropriate by the IMDG Code, for example, the marine pollutant mark or the "LIMITED QUANTITIES" mark.

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CHAPTER 5.4 DOCUMENTATION Any carriage of goods governed by ADN shall be accompanied by the documentation prescribed in this Chapter, as appropriate, unless exempted under 1.1.3.1 to 1.1.3.5. NOTE l : For the list of documentation to be carried on board vessels, see 8.1.2. NOTE 2: The use of electronic data processing (EDP) or electronic data interchange (EDI) techniques as an aid to or instead of paper documentation is permitted, provided that the procedures used for the capture, storage and processing of electronics data meet the legal requirements as regards the evidential value and availability of data during transport in a manner at least equivalent to that ofpaper documentation.

5.4.1

Dangerous goods transport document and related information

5.4.1.1

General information required in the transport document

5.4.1.1.1

General information required in the transport document for carriage in bulk or in packages The transport document(s) shall contain the following information for each dangerous substance, material or article offered for carriage: (a)

the UN number, preceded by the letters "UN";

(b)

the proper shipping name supplemented, when applicable (see 3.1.2.8.1) with the technical name in brackets (see 3.1.2.8.1. l), as determined in accordance with 3.1.2.

(c)

-

For substances and articles of Class 1: Column (3 b) of Table A of Chapter 3.2.

the classification code given in

When, in Column (5) of Table A of Chapter 3.2, label model numbers are given other than 1, 1.4, 1.5 and 1.6, these label model numbers, in brackets, shall follow the classification code; -

For radioactive material of Class 7: the Class number: "7"; NOTE: For radioactive material with a subsidiary risk, see also special provision 172.

-

(d)

For substances and articles of other classes: the label model numbers given in Column (5) of Table A of Chapter 3.2 or applicable according to a special provision referred to in Column (6). When more than one label model number is given, the numbers following the first one shall be given in brackets. For substances and articles for which no label model is given in Column (5) of Table A in Chapter 3.2, their class according to Column (3a) shall be given instead;

where assigned, the packing group for the substance which may be preceded by the letters " P G (e.g. "PG II"), or the initials corresponding to the words "Packing Group'' in the languages used according to 5.4.1.4.1 ; NOTE: For radioactive material of Class 7 with subsidiary risks, see special provision 172 (b) in Chapter 3.3.

the number and a description of the packages when applicable. UN packaging codes may only be used to supplement the description of the kind of package (e.g. one box (4G)); the total quantity of each item of dangerous goods bearing a different UN number, proper shipping name (as a volume or as a gross mass, or as a net mass as appropriate); NOTE: In the case of intended application of 1.1.3.6, the total quantity of dangerous goods for each transport category shall be indicated in the transport document in accordance with 1.1.3.6.3. the name and address of the consignor; the name and address of the consignee(s); a declaration as required by the terms of any special agreement. The location and order in which the elements of information required appear in the transport document is left optional, except that (a), (b), (c) and (d) shall be shown in the order listed above (i.e. (a), (b), (c), (d)) with no information interspersed, except as provided in ADN. Examples of such permitted dangerous goods descriptions are:

"UN 1098 ALLYL ALCOHOL, 6.1 (3), I" or "UN1098, ALLYL ALCOHOL, 6.1 (3), PG I" The information required on a transport document shall be legible. Although upper case is used in Chapter 3.1 and in Table A of Chapter 3.2 to indicate the elements which shall be part of the proper shipping name, and although upper and lower case are used in this Chapter to indicate the information required in the transport document, the use of upper or of lower case for entering the information in the transport document is left optional. 5.4.1.1.2

General information required in the transport documentfor carriage in tank vessels The transport document(s) shall contain the following information for each dangerous substance or article offered for carriage: the UN number preceded by the letters "UN" or the substance identification number; the proper shipping name given in Column (2) of Table C of Chapter 3.2, supplemented, when applicable, by the technical name; the data contained in column (5) of Table C of Chapter 3.2. If several data are given, those following the first bracket should be included; where assigned, the packing group for the substance, which may be preceded by the letters 'PG' (e.g. 'PG 11'), or the initials corresponding to the words 'Packing Group' in the languages used in accordance with 5.4.1.4.1 ; the mass in tonnes; the name and address of the consignor;

(g)

the name and address of the consignee(s).

The location and order in which the elements of information required appear in the transport document is left optional, except that (a), (b), (c) and (d) shall be shown in the order listed above (i.e. (a), (b), (c), (d)) with no information interspersed, except as provided in ADN. Examples of such permitted dangerous goods descriptions are:

"UN 1230 METHANOL, 3 (6.1), II", or "UN 1230 METHANOL, 3 (6.1), PG 117' The information required on a transport document shall be legible. Although upper case is used in Chapter 3.1 and in Chapter 3.2 to indicate the elements which shall be part of the proper shipping name, and although upper and lower case are used in this Chapter to indicate the information required in the transport document, the use of upper or of lower case for entering the information in the transport document is left optional. Special provisions for wastes If waste containing dangerous goods (other than radioactive wastes) is being carried, the UN number and the proper shipping name shall be preceded by the word "WASTE", unless this term is part of the proper shipping name, e.g.:

"WASTE, UN 1230 METHANOL, 3 (6.1), 11", or "WASTE, UN 1230 METHANOL, 3 (6.1), PG 11", or "WASTE, UN 1993 FLAMMABLE LIQUID, N.O.S., (toluene and ethyl alcohol), 3, 1I"or " WASTE, UN 1993 FLAMMABLE LIQUID, N.O.S. (toluene and ethyl alcohol), 3, PG 11". Special provisions for dangerous goods packed in limited quantities No information is required in the transport document, if any, for carriage of dangerous goods packed in limited quantities according to Chapter 3.4. Special provisions for salvage packagings When dangerous goods are carried in a salvage packaging, the words "SALVAGE PACKAGE" shall be added after the description of the goods in the transport document. Special provision for empty means of containment and for empty cargo tanks of tank

vessels For empty means of containment, uncleaned, which contain the residue of dangerous goods of classes other than Class 7, the words "EMPTY, UNCLEANED" or "RESIDUE, LAST CONTAINED" shall be indicated before or after the proper shipping name required in 5.4.1.1.1 (b). Moreover, 5.4.1.1.1 (f) does not apply. The special provision of 5.4.1.1.6.1 may be replaced with the provisions of 5.4.1.1.6.2.1, 5.4.1.1.6.2.2 or 5.4.1.1.6.2.3, as appropriate. For empty packagings, uncleaned, which contain the residue of dangerous goods of classes other than Class 7, including empty uncleaned receptacles for gases with a capacity of not more than 1000 litres, the particulars according to 5.4.1.1.1 (a), (b), (c), (d), (e) and (f) are

- 207 -

replaced with "EMPTY PACKAGING", "EMPTY RECEPTACLE", "EMPTY IBC" or "EMPTY LARGE PACKAGING", as appropriate, followed by the information of the goods last loaded, as described in 5.4.1.1.1 (c). Example: "EMPTY PACKAGING, 6.1 (3)".

In addition, in such a case, if the dangerous goods last loaded are goods of Class 2, the information prescribed in 5.4.1.1.1 (c) may be replaced by the number of the class "2". 5.4.1.1.6.2.2

For empty means of containment other than packagings, uncleaned, which contain the residue of dangerous goods of classes other than Class 7 and for empty uncleaned receptacles for gases with a capacity of more than 1000 litres, the particulars according to 5.4.1.1.1 (a) to (d) are preceded by "EMPTY TANK-WAGON", "EMPTY TANK-VEHICLE", "EMPTY DEMOUNTABLE TANK", "EMPTY TANK-CONTAINER", "EMPTY PORTABLE TANK", "EMPTY BATTERY-WAGON", "EMPTY BATTERY-VEHICLE", "EMPTY MEGC", "EMPTY WAGON", "EMPTY VEHICLE", "EMPTY CONTAINER" or "EMPTY RECEPTACLE", as appropriate, followed by the words "LAST LOAD:". Moreover, paragraph 5.4.1.1.1 (Qdoes not apply. See example as follows: "EMPTY TANK-CONTAINER, LAST LOAD: UN 1098 ALLYL ALCOHOL, 6.1 (3), I" or " EMPTY TANK-CONTAINER, LAST LOAD: UN 1098 ALLYL ALCOHOL, 6.1 (3), PG I".

5.4.1.1.6.2.3

When empty means of containment, uncleaned, which contain the residue of dangerous goods of classes other than Class 7, are returned to the consignor, the transport documents prepared for the full-capacity carriage of these goods may also be used. In such cases, the indication of the quantity is to be eliminated (by effacing it, striking it out or any other means) and replaced by the words "EMPTY, UNCLEANED RETURN".

5.4.1.1.6.3

(a)

If empty tanks, battery-vehicles and MEGCs, uncleaned, are carried to the nearest place where cleaning or repair can be carried out in accordance with the provisions of 4.3.2.4.3 of ADR, the following additional entry shall be made in the transport document: "Carriage in accordance with 4.3.2.4.3 of ADR".

(b)

If empty vehicles and containers, uncleaned, are carried to the nearest place where cleaning or repair can be carried out in accordance with the provisions of 7.5.8.1 of ADR, the following additional entry shall be made in the transport document: "Carriage in accordance with 7.5.8.1 of ADR".

5.4.1.1.6.4

For tank vessels with empty cargo tanks or cargo tanks that have been discharged, the master is deemed to be the consignor for the purpose of the transport documents required. In this case, the following particulars shall be entered on the transport document for each empty cargo tank or cargo tank that has been discharged: (a)

the number of the cargo tank;

(b)

the UN number preceded by the letters "UN" or the substance identification number;

(c)

the proper shipping name of the last substance carried, the class and, if applicable, the packing group in accordance with 5.4.1.1.2.

Special provisions for carriage in a transport chain including maritime, road, rail or air carriage For carriage in accordance with 1.1.4.2.1, a statement shall be included in the transport document, as follows: "Carriage in accordance with 1.1.4.2.1".

(Reserved). Special provisions for exemptions related to quantities carriedper transport unit In the case of exemptions provided for in 1.1.3.6, the transport document shall bear the following inscription: "Load not exceeding the exemption limits prescribed in 1.1.3.6." Where consignments from more than one consignor are carried in the same transport unit, the transport documents accompanying these consignments need not bear the inscription mentioned in 5.4.1.1.10. l .

Special provisions for the carriage of IBCs after the date of expiry of the last periodic test inspection For carriage in accordance with 4.1.2.2 of ADR or of RID, a statement to this effect shall be included in the transport document, as follows: "Carriage in accordance with 4.1.2.2"

(Reserved). Special provisions for the carriage of substances carried under elevated temperature If the proper shipping name of a substance which is carried or offered for carriage in a liquid state at a temperature equal to or exceeding 100 "C, or in a solid state at a temperature equal to or exceeding 240' C, does not convey the elevated temperature condition (for example, by using the term "MOLTEN" or "ELEVATED TEMPERATURE" as part of the proper shipping name), the word "HOT" shall immediately precede the proper shipping name.

Special provisions for the carriage of substances stabilized by temperature control If the word "STABILIZED" is part of the proper shipping name (see also 3.1.2.6), when stabilization is by means of temperature control, the control and emergency temperatures (see 2.2.41 . l .17) shall be indicated in the transport document, as follows: "Control temperature:

... OC

Emergency temperature:

... 'C".

Information required in accordance with special provision 640 in Chapter 3.3 Where it is required by special provision 640 of Chapter 3.3, the transport document shall bear the inscription "Special provision 640X" where "X" is the capital letter appearing after the pertinent reference to special provision 640 in Column (6) of Table A of Chapter 3.2.

Special provisions for the carriage of solids in bulk containers conforming to 6.11.4 ofADR When solid substances are carried in bulk containers conforming to 6.1 1.4 of ADR, the following statement shall be shown on the transport document (see NOTE at the beginning of 6.1 1.4 of ADR): "Bulk container BK(x) approved by the competent authority of.. ."".

Special provisions for carriage in oil separator vessels and supply vessels 5.4.1.1.2 and 5.4.1.1.6.3 are not applicable to oil separator vessels or supply vessels.

Additional or special information required for certain classes Special provisions for Class I The transport document shall indicate, in addition to the requirements in 5.4.1.1.1

(0:

1

the total net mass, in kg, of explosive contents for each substance or article identified by its UN number; -

1

the total net mass, in kg, of explosive contents for all substances and articles covered by the transport document.

For mixed packing of two different goods, the description of the goods in the transport document shall include the UN numbers and names printed in capitals in Columns (1) and (2) of Table A of Chapter 3.2 of both substances or articles. If more than two different goods are contained in the same package in conformity with the mixed packing provisions given in 4.1.10 of ADR special provisions MP 1, MP2 and MP20 to MP24, the transport document shall indicate under the description of the goods the UN numbers of all the substances and articles contained in the package, in the form, "Goods of UN Nos. ...". For the carriage of substances and articles assigned to an n.0.s. entry or the entry "0 190 SAMPLES, EXPLOSIVE" or packed conforming to packing instruction P l 0 l of 4.1.4.1 of ADR, a copy of the competent authority approval with the conditions of carriage shall be attached to the transport document. It shall be in an official language of the forwarding country and also, if that language is not English, French or German, in English, French or German unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise. If packages containing substances and articles of compatibility groups B and D are loaded together in the same vehicle or wagon in accordance with the requirements of 7.5.2.2 or ADR or RID, the approval certificate of the protective compartment or containment system in accordance with 7.5.2.2, note a under the table of ADR or RID, shall be attached to the transport document. When explosive substances or articles are carried in packagings conforming to packing instruction P101 of ADR, the transport document shall bear the inscription "Packaging approved by the competent authority of ..." (see 4.1.4.1, packing instruction P10 1).

For articles, "explosive contents" means the explosive substance contained in the article.

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NOTE: The commercial or technical name of the goods may be entered additionally to the proper shipping name in the transport document.

(0

(Reserved).

(g)

When fireworks of UN Nos. 0333, 0334, 0335, 0336 and 0337 are carried, the transport document shall bear the inscription: "Classification recognized by the competent authority of (State referred to in special provision 645 of 3.3.1).

...

5.4.1.2.2

Additional provisions for Class 2 (a)

For the carriage of mixtures (see 2.2.2.1.1) in tanks (demountable tanks, fixed tanks, portable tanks, tank-containers or elements of battery-vehicles or batteries-wagons or of MEGCs), the composition of the mixture as a percentage of the volume or as a percentage of the mass shall be given. Constituents below 1% need not be indicated (see also 3.1.2.8.1.2).

(b)

For the carriage of cylinders, tubes, pressure drums, cryogenic receptacles and bundles of cylinders under the conditions of 4.1.6.10 of ADR, the following entry shall be included in the transport document: "Carriage in accordance with 4.1.6.10 of ADR".

5.4.1.2.3

Additional provisions for self-reactive substances of Class 4.1 and organic peroxides of Class 5.2

5.4.1.2.3.1

For self-reactive substances of Class 4.1 and for organic peroxides of Class 5.2 that require temperature control during carriage (for self-reactive substances see 2.2.41.1.17; for organic peroxides, see 2.2.52.1.15 to 2.2.52.l.l7), the control and emergency temperatures shall be indicated in the transport document, as follows: "Control temperature:

...'C

Emergency temperature:

...'C"

5.4.1.2.3.2

When for certain self-reactive substances of Class 4.1 and certain organic peroxides of Class 5.2 the competent authority has permitted the label conforming to model No. 1 to be dispensed with for a specific packaging (see 5.2.2.1.9), a statement to this effect shall be included in the transport document, as follows: "The label conforming to model No. 1 is not required".

5.4.1.2.3.3

When organic peroxides and self-reactive substances are carried under conditions where approval is required (for organic peroxides see 2.2.52.1.8, 4.1.7.2.2 and special provision TA2 of 6.8.4 of ADR; for self-reactive substances see 2.2.4 1.1.13 and 4.1.7.2.2, a statement to this effect shall be included in the transport document, e.g. "Carriage in accordance with 2.2.52.1.g". A copy of the approval of the competent authority with the conditions of carriage shall be attached to the transport document.

5.4.1.2.3.4

When a sample of an organic peroxide (see 2.2.52.1.9) or a self-reactive substance (see 2.2.41.1.15) is carried, a statement to this effect shall be included in the transport document, e.g. "Carriage in accordance with 2.2.52.1.9".

5.4.1.2.3.5

When self-reactive substances type G (see Manual of Tests and Criteria, Part 11, paragraph 20.4.2 (g)) are carried, the following statement may be given in the transport document: "Not a self-reactive substance of Class 4.1".

When organic peroxides type G (see Manual of Tests and Criteria, Part 11, paragraph 20.4.3 (g)) are carried, the following statement may be given in the transport document: "Not a substance of Class 5.2". 5.4.1.2.4

Additional provisions for Class 6.2 In addition to the information concerning the consignee (see 5.4.1.1.1 (h)), the name and telephone number of a responsible person shall be indicated.

5.4.1.2.5

Additional provisions for Class 7

5.4.1.2.5.1

The following information shall be inserted in the transport document for each consignment of Class 7 material, as applicable, in the order given and immediately after the information required under 5.4.1.1.1 (a) to (c):

5.4.1.2.5.2

(a)

The name or symbol of each radionuclide or, for mixtures of radionuclides, an appropriate general description or a list of the most restrictive nuclides;

(b)

A description of the physical and chemical form of the material, or a notation that the material is special form radioactive material or low dispersible radioactive material. A generic chemical description is acceptable for chemical form. For radioactive material with a subsidiary risk, see last sentence of special provision 172 of Chapter 3.3;

(c)

The maximum activity of the radioactive contents during carriage expressed in becquerels (Bq) with an appropriate S1 prefix symbol (see 1.2.2.1). For fissile material, the mass of fissile material in grams (g), or appropriate multiples thereof, may be used in place of activity;

(d)

The category of the package, i.e. I-WHITE, 11-YELLOW, 111-YELLOW;

(e)

The transport index (categories 11-YELLOW and 111-YELLOW only);

(Q

For consignments including fissile material other than consignments excepted under 6.4.1 1.2 of ADR, the criticality safety index;

(g)

The identification mark for each competent authority approval certificate (special form radioactive material, low dispersible radioactive material, special arrangement, package design, or shipment) applicable to the consignment;

(h)

For consignments of more than one package, the information required in 5.4.1.1.1 and in (a) to (g) above shall be given for each package. For packages in an overpack, container, or conveyance, a detailed statement of the contents of each package within the overpack, container, or conveyance and, where appropriate, of each overpack, container, or conveyance shall be included. If packages are to be removed from the overpack, container, or conveyance at a point of intermediate unloading, appropriate transport documents shall be made available;

(i)

Where a consignment is required to be shipped under exclusive use, the statement "EXCLUSIVE USE SHIPMENT"; and

(j)

For LSA-I1 and LSA-111 substances, SCO-I and SCO-11, the total activity of the consignment as a multiple of A2.

The consignor shall provide in the transport documents a statement regarding actions, if any, that are required to be taken by the carrier. The statement shall be in the languages deemed

necessary by the carrier or the authorities concerned, and shall include at least the following information: (a)

Supplementary requirements for loading, stowage, carriage, handling and unloading of the package, overpack or container including any special stowage provisions for the safe dissipation of heat (see 7.1.4.14.7.3.2), or a statement that no such requirements are necessary;

(b)

Restrictions on the mode of carriage or vehicle and any necessary routeing instructions;

(c)

Emergency arrangements appropriate to the consignment.

In case of international carriage of packages requiring competent authority design or shipment approval, for which different approval types apply in the different countries concerned, the UN number and proper shipping name required in 5.4.1.1.1 shall be in accordance with the certificate of the country of origin of design. The applicable competent authority certificates need not necessarily accompany the consignment. The consignor shall make them available to the carrier(s) before loading and unloading. (Reserved).

Format and language The document containing the information in 5.4.1.1 and 5.4.1.2 may be that already required by other regulations in force for carriage by another mode of carriage. In case of multiple consignees, the name and address of the consignees and the quantities delivered enabling the nature and quantities carried to be evaluated at any time, may be entered in other documents which are to be used or in any other documents made mandatory according to other specific regulations and which shall be on board the vehicle. The particulars to be entered in the document shall be drafted in an official language of the forwarding country, and also, if that language is not English, French or German, in English, French or German, unless agreements concluded between the countries concerned in the transport operation, provide otherwise. If by reason of the size of the load, a consignment cannot be loaded in its entirety on a single transport unit, at least as many separate documents, or copies of the single document, shall be made out as transport units loaded. Furthermore, in all cases, separate transport documents shall be made out for consignments or parts of consignments which may not be loaded together on the same vehicle by reason of the prohibitions set forth in 7.5.2 of ADR. The information relative to the hazards of the goods to be carried (as indicated in 5.4.1.1) may be incorporated in, or combined with, an existing transport or cargo handling document. The layout of the information in the document (or the order of transmission of the corresponding data by electronic data processing (EDP) or electronic data interchange (EDI) techniques) shall be as provided in 5.4.1.1.1 or 5.4.1.1.2 as relevant. When an existing transport document or cargo handling document cannot be used for the purposes of dangerous goods documentation for multimodal transport, the use of documents 2 corresponding to the example shown in 5.4.4 is considered advisable. 2

If used, the relevant recommendations of the UNECE Working Party on Facilitation of International Trade Procedures may be consulted, in particular Recommendation No. I (United Nations - 213 -

Non-dangerous goods

When goods mentioned by name in Table A of Chapter 3.2, are not subject to ADN because they are considered as non-dangerous according to Part 2, the consignor may enter in the transport document a statement to that effect, e.g.: "Not goods of Class

..."

NOTE: This provision may be used in particular when the consignor considers that, due to the chemical nature of the goods (e.g. solutions and mixtures) carried or to the fact that such goods are deemed dangerous for other regulatory purposes the consignment might be subject to control during the journey.

Container packing certificate

If the carriage of dangerous goods in a large container precedes a voyage by sea, a container packing certificate conforming to section 5.4.2 of the IMDG code3 shall be provided with 4 the transport document. Lay-out Key for Trade Documents) (ECE/TRADE/I 3 7, edition 96. l ) , Recommendation No. I I (Documentary Aspects of the International Transport of Dangerous Goods) ECE/TRADE/204, edition 96.1) and Recommendation No. 22 (Lay-out Key for standard Consignment Instructions) (ECE/TRADE/168, edition 96.1). Refer to the Trade Data Elements Directory, Volume 111, Trade Facilitation Recommendations (ECE/TRADE/200) (United Nations publication Sales No. E. 96.11.E. 13). 3 Guidelines for use in practice and in training for loading goods in transport units have also been drawn up by the International Maritime Organization (IMO), the International Labour Organization (ILO) and the United Nations Economic Commission for Europe (UNECE) and have been published by IMO ("IMO/ILO/UNECE Guidelinesfor Packing of Cargo Transport Units ( C T U S ) ' ~ . 4 Section 5.4.2 of the IMDG Code requires the following: "5.4.2

Container/vehicle packing certificate

5.4.2.1

When dangerous goods are packed or loaded into any container or vehicle, those responsible for packing the container or vehicle shall provide a "container/vehicle packing certificate" speczfiing the container/vehicle identification number(s) and certiJSing that the operation has been carried out in accordance with the following conditions:

.I

The container/vehicle was clean, dry and apparentlyJit to receive the goods;

.2

Packages, which need to be segregated in accordance with applicable segregation requirements, have not been packed together onto or in the container/vehicle (unless approved by the competent authority concerned in accordance with 7.2.2.3 (of the IMDG Code));

.3

All packages have been externally inspected for damage, and only sound packages have been loaded:

.4

Drums have been stowed in an upright position, unless otherwise authorised by the competent authority, and all goods have been properly loaded, and, where necessary, adequately braced with securing material to suit the mode(s) of transport for the intendedjourney;

.5 .6

Goods loaded in bulk have been evenly distributed within the container/vehicle; For consignments including goods of class I, other than division 1.4, the container/vehicle is structurally serviceable in conformity with 7.4.6 (of the IMDG Code); - 214 -

The functions of the transport document required under 5.4.1 and of the container packing certificate as provided above may be incorporated into a single document; if not, these documents shall be attached one to the other. If these functions are incorporated into a single document, the inclusion in the transport document of a statement that the loading of the container has been carried out in accordance with the applicable modal regulations together with the identification of the person responsible for the container packing certificate shall be sufficient. NOTE: The container packing certzjicate is not requiredfor portable tanks, tank-containers and MEGCs.

Instructions in writing As a precaution against any accident or emergency that may occur or arise during carriage, the master shall be given instructions in writing, specifying concisely for each dangerous substance or article carried or for each group of goods presenting the same dangers to which the substance(s) or article(s) carried belong(s): (a)

-

the name of the substance or article or group of goods;

-

the Class; and

-

the UN number, or for a group of goods, the UN numbers

(b)

the nature of the danger inherent in these goods as well as the measures to be taken by the master and the personal protection equipment to be used by the master;

(c)

the action to be taken and the treatment to be given in the event of any person coming into contact with the goods being carried or with any substances which might be expelled from them;

(d)

the general actions to be taken, e.g. to warn other users of the waterway and passers-by and call the emergency services;

.7

The container/vehicle and packages are properly marked, labelled, and placarded, as appropriate;

.8

When solid carbon dioxide (COZ-dry ice) is used for cooling purposes, the container/vehicle is externally marked or labelled in a conspicuous place, such as, at the door end, with the words: "DANGEROUS C 0 2 GAS (DRY ICE) INSIDE. VENTILATE THOROUGHLY BEFORE ENTERING"; and

.9

A dangerous goods transport document, as indicated in 5.4.1 (of fhe IMI)G Code) has been received .for each dangerous goods consignment loaded in the containev/vehicle.

NOTE: The container/vehicle packing certzjicate is not required for tanks. 5.4.2.2 The information required in the dangerous goods transport document and the container/vehicle packing certzjicate may be incorporated into a single document; if not, these documents shall be attached one to the other. I f the information is incorporated into a single document, the document shall a signed declaration such as "It is declared that the packing of the goods into the container/vehicle has been carried out in accordance with the applicable provisionsrf. This declaration shall be dated and the person signing this declaration shall be identified on the document. ". - 215 -

(e)

the measures to be taken in case of breakage or other deterioration of the packagings or of the dangerous goods being carried, in particular where such dangerous goods have spilled;

(f)

the special actions to be taken for certain goods, if applicable;

(g)

the necessary equipment for additional andlor special actions, if applicable, if the equipment referred to in 8.1S.is not sufficient.

These instructions shall be provided by the consignor and shall be handed out to the master at the latest when the dangerous goods are loaded on the vessel. Information on the content of the instructions shall be supplied to the carrier at the latest when the carriage order is given, so as to enable him to take the necessary steps to ensure that the employees concerned are aware of these instructions and are capable of carrying them out properly and to ensure that the necessary equipment is on board the vessel. The consignor shall be responsible for the content of these instructions. They shall be provided in a language the master(s) taking over the dangerous goods is (are) able to read and to understand, and in all languages of the countries of origin, transit and destination. In the case of countries with more than one official language, the competent authority shall specify the official language or languages applicable throughout the territory or in each region or part of the territory. These instructions shall be kept readily at hand in the wheelhouse. This requirement does not apply to oil separator vessels. Instructions in writing according to 5.4.3 which are on board but which do not concern the goods on board shall be kept separate from the applicable instructions in such a way as to prevent confusion. The master shall bring the instructions to the attention of the persons on board to enable them to understand them and carry them out properly. In case of mixed loads of packaged goods including dangerous goods which belong to different groups of goods presenting the same dangers, the instructions in writing may be restricted to one instruction per class of dangerous goods carried on board of the vehicle. In such case no name of goods, or UN number has to be mentioned in the instructions. These instructions shall be drafted according to the following format:

LOAD Mention of the following details concerning the goods for which these instructions are intended or applicable:

-

-

the name of the substance or article, or group of goods presenting the same dangers;

-

the Class; and

-

the UN number or, for a group of goods the, UN numbers.

Description shall be restricted to e.g. the physical state with indication of any colour and mention of any odour, to aid identification of leakages or spillages.

NATURE OF DANGER Short enumeration of dangers: -

-

Main danger; Additional dangers including possible delayed effects and dangers for the environment;

-

Behaviour under fire or heating (decomposition, explosion, development of toxic fumes, etc.);

-

If applicable, it shall be mentioned here that the goods carried react dangerously with water.

PERSONAL PROTECTION Mention of the personal protection intended for the crew in accordance with the requirements of 8.1.5. GENERAL ACTIONS TO BE TAKEN BY THE CREW Mention of the following instructions: -

Inform the competent authority;

-

No naked lights. No smoking;

-

Remove people from the danger zone;

-

Remain upwind;

-

Notify the emergency services as soon as possible.

ADDITIONAL ANDIOR SPECIAL ACTIONS TO BE TAKEN BY THE CREW Appropriate instructions shall be included here as well as the list of equipment necessary for the crew to perform the additional andor special actions according to the class(es) of the goods being carried. It is considered that the crew should be instructed and trained to take additional actions with minor leakages or spillages to prevent their escalation, provided that this can be achieved without personal risk. It is considered that any special action recommended by the consignor requires a special training of the crew. If applicable, appropriate instructions shall be included here as well as the list of equipment needed for these special actions. FIRE Information for the crew in case of fire: Crew members should be instructed during training to deal with minor vessel fires. They shall not attempt to deal with any fire involving the load.

FIRST AID Information for the crew in case of contact with the carried good(s).

ADDITIONAL INFORMATION Example of a multimodal dangerous goods form

Example of a form which may be used as a combined dangerous goods declaration and container packing certificate for multimodal carriage of dangerous goods.

MULTIMODAL DANGEROUS GOODS FORM 12. Transport document number

13.

Page 1 of

14.Shipper's reference Pages 5. Freight Forwarder's reference I

7. Carrier (to be completed by the carrier)

. Consignee

SHIPPER'S DECLARATION I hereby declare that the contents of this consignment are fully and accurately described below by the proper shipping name, and are classified, packaged, marked and lahelledplacarded and are in all respects in proper condition for transport according to the applicable international and national governmentalregulations. . This shipment is within the limitations pre.~cribedfor:(Delete non-applicable)

9. Additional handling information

CARGO AIRCRAFT ONLY

PASSENGER AND CARGO AIRCRAFT 0. Vessel/ flight No. and date

11. Portlplace of loading

2. Portiplace of discharge

13. Destination

4. Shipping marks

* Number and kind of packages; description of goods

5. Container identification No./

16. Seal number (S)

Gross mass (kg)

Net mass

17. Containerlvehiclesize &type

vehicle registration No.

CONTAINERNEHICLE PACKING CERTIFICATE hereby declare that the goods described above have been ackedloaded into the containerlvehicle identified above in ccordance with the applicable provisions **

18. Tare (kg)

Cube (m')

19. Total gross mass (including tare) (kg)

2I.RECEIVING ORGANIZATION RECEIPT Received the above number of packageslcontainersltrailersin apparent good order and condition unless stated hereon: RECEIVING ORGANIZATION REMARKS:

lUST BE COMPLETED AND SIGNED FOR ALL 'ONTAINERNEHICLE LOADS BY PERSON .ESPONSIBLE FOR PACKINGILOADING

Haulier's name

22. Name of company (OF SHIPPER PREPARING THIS NOTE)

IameiStatus of declarant

Vehicle reg. No.

NameiStatus of declarant

lace and date

Signature and date

ignature of declarant

DRIVER'S SIGNATURE

0. Name of company -

I

Signature of dedannt

BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCH BLACK

CHAPTER 5.5 SPECIAL PROVISIONS (Deleted).

Special provisions for fumigated vehicles, wagons, containers and tanks For the carriage of UN No. 3359 FUMIGATED UNIT (vehicle, wagon, container or tank) the transport document shall show the information required in 5.4.1.1.1, the date of fumigation and the type of the fumigant used. These particulars shall be drafted in an official language of the forwarding country and also, if the language is not English, French or German, in English, French or German, unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise. In addition, instructions for disposal of any residual fumigant including fumigation devices (if used) shall be provided. A warning sign as specified in 5.5.2.3 shall be placed on each fumigated vehicle, wagon, container or tank in a location where it will be easily seen by persons attempting to enter the interior of the container or vehicle. The particulars concerning the warning sign shall be drafted in a language considered appropriate by the consignor. The fumigation warning sign shall be rectangular and shall not be less than 300 mm wide and not less than 250 mm high. The markings shall be black print on a white background with lettering not less than 25 mm high. An illustration of this sign is given in the figure below.

Fumigation warning sign

DANGER

THIS UNIT IS UNDER FUMlGaTIDN WITH I fumigant name" ] APPLIED ON [ the date * ] thetime" j [ DO NOT ENTER

* Insan details as appropriate Matle?m than 36El m m

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PART 6 Requirements for the construction and testing of packagings (including IBCs and large packagings), tanks and bulk transport units

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CHAPTER 6.1 GENERAL REQUIREMENTS Packaging (including IBCs and large packagings) and tanks shall meet the following requirements of ADR in respect of construction and testing: Chapter 6.1 :

Requirements for the construction and testing of packagings;

Chapter 6.2:

Requirements for the construction and testing of pressure receptacles, aerosol dispensers and small receptacles containing gas (gas cartridges);

Chapter 6.3:

Requirements for the construction and testing of packagings for Class 6.2 substances;

Chapter 6.4:

Requirements for the construction, testing and approval of packages and material of Class 7;

Chapter 6.5

Requirements for the construction and testing of intermediate bulk containers (IBCs);

Chapter 6.6

Requirements for the construction and testing of large packagings;

Chapter 6.7

Requirements for the design, construction, inspection and testing of portable tanks and UN multiple-element gas containers (MEGCs);

Chapter 6.8

Requirements for the construction, equipment, type approval, inspections and tests, and marking of fixed tanks (tank-vehicles), demountable tanks and tank-containers and tank swap bodies, with shell made of metallic materials and battery-vehicles and multiple element gas containers (MEGCs);

Chapter 6.9

Requirements for the design, construction, equipment, type approval, testing and marking of fibre-reinforced plastics (FRP) fixed tanks (tank-vehicles), demountable tanks, tank-containers and tank swap bodies;

Chapter 6.10

Requirements for the construction, equipment, type approval, inspection and marking of vacuum-operated waste tanks.

Chapter 6.1 1

Requirements for the design, construction, inspection and testing of bulk containers

Portable tanks may also meet the requirements of Chapter 6.7 or, if appropriate, Chapter 6.9 of the IMDG Code. Tank-vehicles may also meet the requirements of Chapter 6.8 of the IMDG Code. Tank wagons, with fixed or removable tanks and battery-wagons shall meet the requirements of Chapter 6.8 of the IMDG Code. Bodies of vehicles for bulk carriage shall, if necessary, meet the requirements of Chapter 6.1 1 or of Chapter 9.5 of ADR. When the provisions of 7.3.1.1 (a) of RID or ADR are applied, the bulk containers shall meet the requirements of Chapter 6.1 1 of RID or ADR.

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PART 7 Requirements concerning loading, carriage, unloading and handling of cargo

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CHAPTER 7.1 DRY CARGO VESSELS

General requirements The provisions of 7.1.0 to 7.1.6 are applicable to dry cargo vessels.

(Reserved). Mode of carriage of goods (Reserved). Carriage of packages Unless otherwise specified, the masses given for packages shall be the gross masses. When packages are carried in containers or vehicles, the mass of the container or vehicle shall not be included in the gross mass of such packages. Carriage in bulk Carriage of dangerous goods in bulk shall be prohibited except where this mode of carriage is explicitly authorized in column (8) of Table A of Chapter 3.2. The code "B" shall then appear in this column. Ventilation The ventilation of holds is required only if it is prescribed in 7.1.4.12 or by an additional requirement "VE ..." in column (10) of Table A of Chapter 3.2. Measures to be taken prior to loading Additional measures to be taken prior to loading are required only if prescribed in 7.1.4.13 or by an additional requirement "L0 ..." in column (l l ) of Table A of Chapter 3.2 (see also 7.1.6.13). Handling and stowage of cargo During the handling and stowage of cargo additional measures are required only if prescribed in 7.1.4.14 or by an additional requirement "HA ..." in column (1 1) of Table A of Chapter 3.2.

(Reserved). Measures to be taken during loading, carriage, unloading and handling of cargo The additional measures to be taken prior to loading are required only if prescribed in 7.1.4.16 or by an additional requirement "IN ..." in column ( l l ) of Table A of Chapter 3.2.

(Reserved).

Carriage in containers, in intermediate bulk containers (IBCs) and in large packagings, in MEGCs, in portable tanks and in tank-containers The carriage of containers, IBCs, large packagings, MEGCs portable tanks and tankcontainers shall be in accordance with the provisions applicable to the carriage of packages. Vehicles and wagons The carriage of vehicles and wagons shall be in accordance with the provisions applicable to the carriage of packages.

(Reserved). Carriage in cargo tanks The carriage of dangerous goods in cargo tanks in dry-cargo vessels is prohibited.

(Reserved).

Requirements applicable to vessels Permitted vessels Dangerous goods may be carried in quantities not exceeding those indicated in 7.1.4.1.1, or, if applicable, in 7.1.4.1.2: -

In dry cargo vessels conforming to the applicable construction requirements of 9.1.0.0 to 9.1.0.79; or

-

In seagoing vessels conforming to the applicable construction requirements of 9.1.0.0 to 9.1.O.79, or otherwise to the requirements of 9.2.0 to 9.2.0.79.

Dangerous goods of classes 2, 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 7, 8 or 9, with the exception of those for which a No. 1 model label is required in column (5) of table A of Chapter 3.2, may be carried in quantities greater than those indicated in 7.1.4.1.1 and 7.1.4.1.2: -

In double-hull dry cargo vessels conforming to the applicable construction requirements of 9.1.0.80 to 9.1.0.95; or

-

In double-hull seagoing vessels conforming to the applicable construction requirements of 9.1.0.80 to 9.1.0.95, or otherwise to the requirements of 9.2.0 to 9.2.0.95.

(Reserved). Instructionsfor the use of devices and installations Where specific safety rules have to be complied with when using any device or installation, instructions for the use of the particular device or installation shall be readily available for consultation at appropriate places on board in the language normally spoken on board and also if that language is not English, French or German, in English, French or German unless agreements concluded between the countries concerned in the transport operation provide otherwise.

(Reserved).

Pushed convoys and side-by-side formations Where at least one vessel of a convoy or side-by-side formation is required to be in possession of a certificate of approval, all vessels of such convoy or side-by-side formation shall be provided with an appropriate certificate of approval. Vessels not carrying dangerous goods shall comply with the requirements of the following paragraphs: 7.1.2.5, 8.1.5, 8.1.6.1, 8.1.6.3, 8.1.7, 8.1.8, 8.1.9, 9.1.0.0, 9.1.0.12.3, 9.1.0.17.2, 9.1.0.17.3, 9.1.0.31, 9.1.0.32,9.1.0.34, 9.1.0.41, 9.1.0.52.2, 9.1.0.52.3,9.1.0.56, 9.1.0.71 and 9.1.0.74. For the purposes of the application of the provisions of this Part with the exception of 7.1.4.1.1 and 7.1.4.1.2, the entire pushed convoy or the side-by-side formation shall be deemed to be a single vessel. (Reserved).

General service requirements Access to holds, double-hull spaces and double bottoms; inspections Access to the holds is not permitted except for the purpose of loading or unloading and carrying out inspections or cleaning work. Access to the double-hull spaces and the double bottoms is not permitted while the vessel is under way. If the concentration of gases or the oxygen content of the air in holds, double-wall spaces or double bottoms has to be measured before entry the results of these measurements shall be recorded in writing. The measurement may only be effected by persons equipped with suitable breathing apparatus for the substance carried. Entry into the spaces is not permitted for the purpose of measuring. In case of suspected damage to packages, the gas concentration in holds containing dangerous goods of Classes 2, 3, 5.2, 6.1 and 8 for which EX andor TOX appears in column (9) of Table A of Chapter 3.2, shall be measured before any person enters these holds. The gas concentration in holds and in adjacent holds containing dangerous goods carried in bulk or without packaging for which EX andor TOX appears in column (9) of Table A of Chapter 3.2, shall be measured before any person enters these holds. Entry into holds where damage is suspected to packages in which dangerous goods of Classes 2, 3, 5.2, 6.1 and 8 are carried as well as entry into double-hull spaces and double bottoms is not permitted except where: -

there is no lack of oxygen and no measurable amount of dangerous substances in a dangerous concentration; or

-

the person entering the space wears a self-contained breathing apparatus necessary protective and rescue equipment and is secured by a line. Entry spaces is only permitted if this operation is supervised by a second person the same equipment is readily at hand. Another two persons capable assistance in an emergency shall be on the vessel within calling distance.

and other into these for whom of giving

Entry into holds where dangerous goods are carried in bulk or without packaging as well as entry into double-hull space and double bottoms is not permitted except where: -

there is no lack of oxygen and no measurable amount of dangerous substances in a dangerous concentration; or

-

the person entering the space wears a self-contained breathing apparatus and other necessary protective and rescue equipment and is secured by a line. Entry into these spaces is only permitted if this operation is supervised by a second person for whom the same equipment is readily at hand. Another two persons capable of giving assistance in an emergency shall be on the vessel within calling distance.

(Reserved).

Dangerous goods training When dangerous goods are carried an expert shall be on board the vessel. (Reserved).

Water ballast Double-hull spaces and double bottoms may be used for water ballast. (Reserved).

Opening of holds Dangerous goods shall be protected against the influences of weather and against spray water except during loading and unloading or during inspection. This provision does not apply when dangerous goods are loaded in sprayproof containers, IBCs, or large packagings, or in MEGCs, portable tanks, tank-containers, vehicles or wagons which are covered or sheeted. Where dangerous goods are carried in bulk, the holds shall be covered with hatch covers. (Reserved).

Engines The use of engines running on fbels having a flashpoint below 55" C (e.g. petrol engines) is prohibited. This requirement does not apply to the petrol-operated outboard motors of lifeboats.

Oilfuel tanks Double bottoms with a height of at least 0.6 m may be used as oil fuel tanks provided that they have been constructed in accordance with Chapters 9.1 or 9.2.

(Reserved). Fire and naked light The use of fire or naked light is prohibited. This provision does not apply to the accommodation and the wheelhouse. Heating, cooking and refrigerating appliances shall not be fuelled with liquid fuels, liquid gas or solid fuels. Cooking and refrigerating appliances may only be used in the accommodation and in the wheelhouse. Heating appliances or boilers fuelled with liquid fbels having a flashpoint above 55" C which are installed in the engine room or in another suitable space may, however, be used.

Heating of holds The heating of holds or the operation of a heating system in the holds is prohibited.

(Reserved). Cleaning operations The use of liquids having a flashpoint below 55" C for cleaning purposes is prohibited.

(Reserved). Electrical installations The electrical installations shall be properly maintained. The use of movable electric cables is prohibited in the protected area. This provision does not apply to: -

intrinsically safe electric circuits;

-

electric cables for connecting signal lights or gangway lighting, provided the socket is permanently fitted to the vessel close to the signal mast or gangway;

-

electric cables for connecting containers;

-

electric cables for electrically operated hatch cover gantries;

-

electric cables for connecting submerged pumps;

-

electric cables for connecting hold ventilators.

The sockets for connecting the signal lights and gangway lighting and for connecting containers, submerged pumps, hatch cover gantries, or hold fans shall not be live except when the signal lights or the gangway lighting are switched on or when the containers or the submerged pumps or the hatch cover gantries or hold fans are in operation. In the protected area, connecting or disconnecting shall not be possible except when the sockets are not live. The electrical installations in the holds shall be kept switched off and protected against unintentional connection. This provision does not apply to permanently installed cables passing through the holds, to movable cables connecting containers, or to electrical apparatus of a "certified safe type".

(Reserved).

Aerials, lightning conductors, wire cables and masts No part of an aerial for electronic apparatus, no lightning conductor and no wire cable shall be situated above the holds. No part of aerials for radiotelephones shall be located within 2.00 m from substances or articles of Class 1.

(Reserved). Additional requirements concerning loading, carriage, unloading and other handling of the cargo

Limitation of the quantities carried Subject to 7.1.4.1.3, the following gross masses shall not be exceeded on any vessel. For pushed convoys and side-by-side formations this gross mass applies to each unit of the convoy or formation.

Class 1 A11 substances and articles of Division 1 . 1 of compatibility group A All substances and articles of Division 1 . 1 of compatibility groups B, C, D. E, F, G, J or L All substances and articles of Division 1.2 of compatibility groups B, C, D, E, F, G, H, J or L All substances and articles of Division 1.3 of compatibility groups C, G, H, J or L All substances and articles of Division 1.4 of compatibility groups B, C, D, E, F, G or S All substances of Division 1.5 of compatibility group D All articles of Division 1.6 of compatibility group N Empty packagings, uncleaned

Note: In not less than three batches of a maximum of 30 kg each, distance between batches not less than 10.00 m. In not less than three batches of a maximum of 5 000 kg each, distance between batches not less than 10.00 m. A wooden partition is permitted for subdividing a hold Class 2 All goods for which label No. 2.3 is required in column (5) of Table A of Chapter 3.2: total All goods for which label No. 2.1 is required in column (5) of Table A of Chapter 3.2: total Other goods

300 000 kg No limitation

Class 3 All goods for which label No. 6.1 is required in column (5) of Table A of Chapter 3.2: total Other goods Class 4.1 U N Nos. 322 1,3222,323 1 and 3232, total All goods of packing group I; all goods of packing group I1 for which label No. 6.1 is required in column (5) of Table A of Chapter 3.2; selfreactive substances of types C, D, E and F (UN Nos. 3223 to 3230 and 3233 to 3240); other substances of classification code SR1 or SR2 (UN Nos. 2956,3241,3242 and 325 1); and desensitized explosive substances of packing group I1 (UN Nos. 2907,3319 and 3344): total

120 000 kg No limitation

Other goods Class 4.2 All goods of packing groups I or I1 for which label No. 6.1 is required in column (5) of Table A of Chapter 3.2: total Other goods

- 235 -

300 000 kg No limitation

Class 4.3 All goods of packing groups I or I1 for which label No. 3, 4.1 or 6.1 is required in column (5) of Table A of Chapter 3.2: total Other goods

Class 5.1 All goods of packing groups I or I1 for which label No. 6.1 is required in column (5) of Table A of Chapter 3.2: total Other goods

300 000 kg No limitation

300 000 kg No limitation

Class 5.2 UNNos. 3101, 3102,3111 and 3112: total All other goods: total Class 6.1 All goods of packing group I All goods of packing group I1 Other goods Class 7 UN Nos. 2912,2913,2915,2917,2919,2977,2978 and 3321 to 3333 Other goods Class 8 All goods of packing group I; goods of packing group I1 for which label No. 3 or 6.1 is required in column (5) of the table in Chapter 3.2: total Other goods Class 9 All goods of packing group I1 Other goods

120 000 kg 300 000 kg No limitation

0 kg No limitation

300 000 kg No limitation 300 000 kg No limitation

Subject to 7.1.4.1.3, the maximum quantity of dangerous goods permitted on board a vessel or on board each unit of a pushed convoy or side-by-side formation is 1,100,000 kg. The limitations of 7.1.4.1.1 and 7.1.4.1.2 shall not apply in the case of transport of dangerous goods of classes 2, 3,4.1,4.2, 4.3, 5.1, 5.2, 6.1, 7, 8 and 9, except of those for which a label of Model No l is required in column (5) of Table A of Chapter 3.2, on board double-hull vessels complying with the additional requirements of 9.1.0.88 to 9.1.OM or 9.2.0.88 to 9.2.0.95. Where substances and articles of different divisions of Class 1 are loaded in a single vessel in conformity with the provisions for prohibition of mixed loading of 7.1.4.3.3 or 7.1.4.3.4, the entire load shall not exceed the smallest maximum net mass given in 7.1.4.1.1 above for the goods of the most dangerous division loaded, the order of precedence being 1.1, 1S , 1.2, 1.3, 1.6, 1.4. Where the total net mass of the explosive substances contained in the explosive substances and articles carried is not known, the table in 7.1.4.1.1 above shall apply to the gross mass of the cargo.

7.1.4.1.6

For activity limits, transport index (TI) limits and criticality safety indices (CSI) in the case of the carriage of radioactive material, see 7.1.4.14.7.

7.1.4.2

Prohibition of mixed loading (bulk) Vessels carrying substances of Class 5.1 in bulk shall not carry any other goods.

7.1.4.3

Prohibition of mixed loading fpackages in holds)

7.1.4.3.1

Goods of different classes shall be separated by a minimum horizontal distance of 3.00 m. They shall not be stowed one on top of the other.

7.1.4.3.2

Irrespective of the quantity, dangerous goods for which marking with three blue cones or three blue lights is prescribed in column (12) of Table A of Chapter 3.2 shall not be stowed in the same hold together with flammable goods for which marking with one blue cone or one blue light is prescribed in column (12) of Table A of Chapter 3.2.

7.1.4.3.3

Packages containing substances or articles of Class 1 and packages containing substances of Classes 4.1 or 5.2 for which marking with three blue cones or three blue lights is prescribed in column (12) of Table A of Chapter 3.2 shall be separated by a distance of not less than 12 m from goods of all other classes.

7.1.4.3.4

Substances and articles of Class 1 shall not be stowed in the same hold, except as indicated in the following table:

“X” indicates that explosive substances of corresponding compatibility groups in accordance with Part 2 of these Regulations may be stowed in the same hold. Packages containing substances or articles assigned to Compatibility groups B and D may be loaded together in the same hold provided that they are carried in containers or vehicles or wagons with complete metal walls. Different categories of articles of Division 1.6, compatibility group N, may be carried together as articles of Division I . 6, compatibility group N, only when it is proven by testing or analogy that there is no additional risk of sympathetic detonation between the articles. Otherwise they should be treated as hazard Division I . I . When articles of compatibility group N are carried with substances or articles of compatibility groups C, D or E, the articles of Compatibility group N should be considered as having the characteristics of compatibility group D. Packages with substances or articles of Compatibility group L may be stowed in the same hold with packages containing the same type of substances or articles of the same compatibility group.

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For the carriage of material Class 7 (UN Nos. 2916, 2917, 3323, 3328, 3329 and 3330) in Type B(U) or Type B(M) or Type C packages, the controls, restrictions or provisions specified in the competent authority approval certificate shall be complied with. For the carriage of material of Class 7 (UN Nos. 2919 and 333 1) under special arrangement, the special provisions specified by the competent authority shall be met. In particular, mixed loading shall not be permitted unless specifically authorized by the competent authority.

Prohibition of mixed loading (containers, vehicles, wagons) 7.1.4.3 shall not apply to packages stowed in containers, vehicles or wagons in accordance with international regulations. 7.1.4.3 shall not apply to: -

closed containers with complete metal walls;

-

vehicles and wagons with closed body having complete metal walls;

-

tank-containers, portable tanks and MEGCs;

-

tank-vehicles and tank-wagons.

For containers other than those referred to in paragraph 7.1.4.4.1 and 7.1.4.4.2 above the separation distance required by 7.1.4.3.1 may be reduced to 2.4 m (width of container).

Prohibition of mixed loading (seagoing vessels) For seagoing vessels and inland waterway vessels, where the latter only carry containers, the prohibition of mixed loading shall be deemed to have been met if the stowage and segregation requirements of the IMDG Code have been complied with.

(Reserved). Places of loading and unloading The dangerous goods shall be loaded or unloaded only at the places designated or approved for this purpose by the competent authority. When substances or articles of Class 1 and substances of Classes 4.1 or 5.2 for which marking with three blue cones or three blue lights is prescribed in column (12) of Table A of Chapter 3.2 are on board, no goods of any kind may be loaded or unloaded except at the places designated or permitted for this purpose by the competent local authority.

Time and duration of loading and unloading operations Loading and unloading operations of substances or articles of Class l and substances of Classes 4.1 or 5.2 for which marking with three blue cones or three blue lights is prescribed in column (12) of Table A of Chapter 3.2 shall not start without permission in writing from the competent authority. This provision also applies to loading or unloading of other goods when substances or articles of Class 1 or substances of Classes 4.1 or 5.2 for which marking with three blue cones or three blue lights is prescribed in column (12) of Table A of Chapter 3.2 are on board.

Loading and unloading operations of substances or articles of Class 1 and substances of Classes 4.1 or 5.2, for which marking with three blue cones or three blue lights is prescribed in column (12) of Table A of Chapter 3.2, shall be suspended in the event of a storm. Cargo transfer operations Partial or complete cargo transfer into another vessel without permission from the competent authority is prohibited outside a cargo transfer place approved for this purpose.

Precautions with respect to foodstuffs, other articles of consumption and animal feeds When special provision 802 is indicated for a dangerous good in column (6) of Table A of Chapter 3.2, precautions shall be taken as follows with respect to foodstuffs, other articles of consumption and animal feeds: Packages, including intermediate bulk containers (IBCs), and uncleaned empty packagings, including uncleaned empty intermediate bulk containers (IBCs), bearing labels conforming to models Nos. 6.1 or 6.2, and those bearing labels of Class 9, containing substances of Class 9, UN Nos. 2212, 2315, 2590, 3151, 3152 or 3245, shall not be stacked on or loaded in immediate proximity to packages known to contain foodstuffs, other articles of consumption or animal feeds in the same hold and at places of loading and unloading or trans-shipment. When these packages, bearing the said labels, are loaded in immediate proximity of packages known to contain foodstuffs, other articles of consumption or animal feeds, they shall be kept apart from the latter: (a)

by complete partitions which should be as high as the packages bearing the said labels, or

(b)

by packages not bearing labels conforming to models Nos. 6.1, 6.2 or 9 or packages bearing labels of Class 9 but not containing substances of that class, UN Nos. 2212, 2315,2590,3151,3152 or3245, or

(c)

by a space of at least 0.8 m,

unless the packages bearing said labels are provided with an additional packaging or are completely covered (e.g. by a sheeting, a fibreboard cover or other measures). Stowage plan The master shall enter on a stowage plan the dangerous goods stowed in the individual holds or on deck. The goods shall be described as in the transport document in accordance with 5.4.1.1.1 (a), (b), (c) and (d). Where the dangerous goods are transported in containers, the number of the container shall suffice. In this case, the stowage plan shall contain as an annex a list of all containers with their numbers and the description of the goods contained therein in accordance with 5.4.1.1.1 ( 4 , (b), (c) and ( 4 . Ventilation During loading or unloading of road vehicles into or from the holds of ro-ro-vessels, there shall be not less than five changes of air per hour based upon the total volume of the empty hold.

On board vessels carrying dangerous goods only in containers placed in open holds, ventilators do not require to be incorporated but must be on board. Where damage is suspected, the holds shall be ventilated so as to reduce the concentration of gases given off by the cargo to less than 10% of the lower explosive limit or in the case of toxic gases to below any significant concentration. If tank-containers, portable tanks, MEGCs, road tank vehicles or tank wagons are carried in closed holds, such holds shall be permanently ventilated for ensuring five air changes per hour.

Measures to be taken before loading The holds and cargo decks shall be cleaned prior to loading. The holds shall be ventilated.

Handling and stowage of the cargo The various components of the cargo shall be stowed such as to prevent them from shifting in relation to one another or to the vessel and such that no damage can be caused by other cargo. Packages containing dangerous substances and unpackaged dangerous articles shall be secured by suitable means capable of restraining the goods (such as fastening straps, sliding slatboards, adjustable brackets) in a manner that will prevent any movement during carriage which would change the orientation of the packages or cause them to be damaged. When dangerous goods are carried with other goods (e.g. heavy machinery or crates), all goods shall be securely fixed or packed so as to prevent the release of dangerous goods. Movement of packages may also be prevented by filling any voids by the use of dunnage or by blocking and bracing. Where restraints such as banding or straps are used, these shall not be overtightened to cause damage or deformation of the package. Packages shall not be stacked unless designed for that purpose. Where different design types of packages that have been designed for stacking are to be loaded together, consideration shall be given to their compatibility for stacking with each other. Where necessary, stacked packages shall be prevented from damaging the package below by the use of load-bearing devices. During loading and unloading, packages containing dangerous goods shall be protected from being damaged.

Particular attention shall be paid to the handling of packages during their NOTE: preparation for carriage, the type of vessel on which they are to be carried and to the method of loading or unloading, so that accidental damage is not caused through dragging or mishandling the packages. When orientation arrows are required, packages shall be oriented in accordance with such markings.

NOTE: Liquid dangerous goods shall be loaded below dry dangerous goods whenever practicable. Dangerous goods shall be stowed at a distance of not less than l m from the accommodation, the engine rooms, the wheelhouse and any sources of heat. When the accommodation or wheelhouse is situated above a hold, dangerous goods shall in no case be stowed beneath such accommodation or wheelhouse.

7.1.4.14.3

Packages shall be protected against heat, sunlight and the effects of the weather. This provision does not apply to vehicles, wagons, tank-containers, portable tanks, MEGCs and containers. Where packages are not enclosed in vehicles, wagons or containers but loaded on deck, they shall be covered with tarpaulins that are not readily flammable. The ventilation shall not be obstructed.

7.1.4.14.4

The dangerous goods shall be stowed in the holds. However, dangerous goods packed or loaded in: -

containers having complete sprayproof walls;

-

vehicles having complete sprayproof walls;

-

tank-containers or portable tanks;

-

tank vehicles or tank wagons;

may be carried on deck in the protected area. 7.1.4.14.5

Packages containing dangerous goods of Classes 3,4.1,4.2, 5.1 or 8 may be stowed on deck provided that drums are used or that they are contained in containers with complete walls or vehicles or wagons with complete walls. Substances of Class 2 may be stowed on deck in the protected area, provided they are contained in cylinders.

7.1.4.14.6

For seagoing vessels, the stowage requirements set out in 7.1.4.14.1 to 7.1.4.14.5 above and 7.1.4.14.7 below shall be deemed to have been met, if the relevant stowage provisions of the IMDG Code and, in the case of carriage in bulk, those set out in subsection 9.3 of the BC Code have been complied with.

7.1.4.14.7

Handling and stowage of radioactive material

NOTE I: "Critical group" means a group of members of the public which is reasonably homogeneous with respect to its exposure for a given radiation source and given exposure pathway and is typical of individuals receiving the highest effective dose by the given exposure pathway from the given source. NOTE 2: "Members of the public" means in a general sense, any individuals in the population except when subject to occupational or medical exposure. NOTE 3: "Workers" are any persons who work, whether full time, part-time or temporarily, for an employer and who have recognized rights and duties in relation to occupational radiation protection. 7.1.4.14.7.1

Segregation

7.1.4.14.7.1.1 Packages, overpacks, containers, tanks and vehicles containing radioactive material and unpackaged radioactive material shall be segregated during carriage: (a)

from workers in regularly occupied working areas;

(i)

in accordance with Table A below; or

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by distances calculated using a dose criterion of 5 mSv in a year and conservative model parameters;

(ii)

NOTE: Workers subject to individual monitoring for the purposes of radiation protection shall not be consideredfor the purposes of segregation.

(b)

(c)

from members of the critical group of the public, in areas where the public has regular access; (i)

in accordance with Table A below; or

(ii)

by distances calculated using a dose criterion of 1 mSv in a year and conservative model parameters;

from undeveloped photographic film and mailbags; (i)

in accordance with Table B below; or

(ii)

by distances calculated using a radiation exposure criterion for undeveloped photographic film due to the transport of radioactive material for 0.1 mSv per consignment of such film; and

NOTE: Mailbags - shall be assumed to contain undeveloped film and plates and therefore be separated from radioactive material in the same way. (d)

from other dangerous goods in accordance with 7.1.4.3.

Table A: Minimum distances between packages of category 11-YELLOW or of category 111-YELLOW and persons Exposure time per year (hours) Sum of transport indexes not more than

2 4 8 12 20 30 40 50

Areas where members of the public have regular access 50

250

Regularly occupied working areas 50

250

Segregation distance in metres, no shielding material intervening, from: l 0.5 3 1 1.5 0.5 4 1.5 2.5 1.O 6 2.5 1.o 3 7.5 3 4 1.5 9.5 4 2 5 12 5 5.6 13.5 2.5 5.5 6.5 3 15.5 6.5

Table B: Minimum distances between packages of category 11-YELLOW or of category 111-YELLOW and packages bearing the word "FOTO", or mailbags Total number of packages not more than Cate, ,ry 111-yellow IIyellow

Sum of transport indexes not more than

Journey or storage duration, in hours 1

I

2

1

4

1

10

[

24

1

48

1120

1240

Minimum distances in metres

1 2 4 8 10 20 30 40 50

Category 11-YELLOW or 111-YELLOW packages or overpacks shall not be carried in compartments occupied by passengers, except those exclusively reserved for couriers specially authorized to accompany such packages or overpacks. No persons other than the master of the vessel or the vehicle embarked and the other members of the crew shall be permitted in vessels carrying packages, overpacks or containers bearing category 11-YELLOW or 111-YELLOW labels. Activity limits

The total activity in a single hold or compartment of vessel, or in another conveyance, for carriage of LSA material or SCO articles in Type IP-l, Type IP-2, Type IP-3 or unpackaged, shall not exceed the limits shown in Table C below:

Table C: Conveyance activity limits for LSA material and SCO in industrial packages or unpackaged Nature of material or articles LSA-I LSA-I1 and LSA-I11 non-combustible solids

Activity limit for conveyances other than by vessel No limit No limit

LSA-I1 and LSA-I11 combustible solids, and all liquids and gases SCO 7.1.4.14.7.3

Stowage during carriage and storage in transit

7.1.4.14.7.3.1 Consignments shall be securely stowed.

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Activity limit for a hold or compartment of vessel No limit

7.1.4.14.7.3.2 Provided that its average surface heat flux does not exceed 15W/MLand that the immediately surrounding cargo is not in bags, a package or overpack may be carried or stored among packaged general cargo without any special stowage provisions except as may be specifically required by the competent authority in an applicable approval certificate. 7.1.4.14.7.3.3 Loading of containers and accumulation of packages, overpacks and containers shall be controlled as follows: (a)

Except under the conditions of exclusive use, and for consignments of LSA-I material, the total number of packages, overpacks and containers aboard a single conveyance shall be so limited that the total sum of the transport indexes aboard the conveyance does not exceed the values shown in Table D below;

(b)

The radiation level under routine conditions of carriage shall not exceed 2 mSvh at any point on, and 0.1 mSvh at 2 m from, the external surface of the conveyance, except for consignments carried under exclusive use, for which the radiation limits around the conveyance are set forth in 7.1.4.14.7.3.5 (b) and (c);

(c)

The total sum of the criticality safety indexes in a container and aboard a conveyance shall not exceed the values shown in Table E below.

Table D: Transport Index limits for containers and conveyances not under exclusive use Type of container or conveyance Small container Large container Vehicle or wagon

Limit on total sum of transport indexes in a container or aboard a convevance 50 50 50

Table E: Criticality Safety Index for containers and vehicles containing fissile material Type of container or conveyance Small container Large container Vehicle or wagon Vessel

Limit on total sum of criticality safety indexes Under exclusive use Not under exclusive use n.a. 50 50 100 100 50 100 50

7.1.4.14.7.3.4 Any package or overpack having either a transport index greater than 10, or any consignment having a criticality safety index greater than 50, shall be carried only under exclusive use. 7.1.4.14.7.3.5 For consignments under exclusive use in vehicles or wagons, the radiation level shall not exceed: (a)

10 mSV/h at any point on the external surface of any package or overpack, and may only exceed 2 mSv/h provided that: (i)

the vehicle or wagon is equipped with an enclosure which, during routine conditions of carriage, prevents the access of unauthorized persons to the interior of the enclosure;

(ii)

provisions are made to secure the package or overpack so that its position within the vehicle or wagon enclosure remains fixed during routine conditions of carriage; and

(iii) there is no loading or unloading during the shipment;

(b)

2 mSvh at any point on the outer services of the vehicle or wagon, including the upper and lower surfaces, or, in the case of an open vehicle or wagon, at any point on the vertical planes projected from the outer edges of the vehicle or wagon, on the upper surface of the load, and on the lower external surface of the vehicle or wagon; and

(c)

0.1 mSv/h at any point 2 m from the vertical planes represented by the outer lateral surfaces of the vehicle or wagon, or, if the load is carried in an open vehicle or wagon, at any point 2 m from the vertical planes projected from the outer edges of the vehicle or wagon.

7.1.4.14.7.3.6 Packages or overpacks having a surface radiation area greater than 2 mSv/h, unless being carried in or on a vehicle or wagon under exclusive use and unless they are removed from the vehicle or wagon when on board the vessel shall not be transported by vessel except under special arrangement. 7.4.1.14.7.3.7

The transport of consignments by means of a special use vessel which, by virtue of its design, or by reason of its being chartered, is dedicated to the purpose of carrying radioactive material, shall be excepted from the requirements specified in 7.1.4.14.7.3.3 provided that the following conditions are met: (a)

A radiation protection programme for the shipment shall be approved by the competent authority of the flag state of the vessel and, when requested, by the competent authority at each port of call of the transit countries;

(b)

Stowage arrangements shall be predetermined for the whole voyage including any consignments to be loaded at ports of call en route; and

(c)

The loading, carriage and unloading of the consignments shall be supervised by persons qualified in the transport of radioactive material.

7.1.4.14.7.4

Segregation of packages containingfissile material during carriage and storage in transit

7.1.4.14.7.4.1

Any group of packages, overpacks, and containers containing fissile material stored in transit in any one storage area shall be so limited that the total sum of the criticality safety indexes in the group does not exceed 50. Each group shall be stored so as to maintain a spacing of at least 6 m from other such groups.

7.1.4.14.7.4.2

Where the total sum of the criticality safety indexes on board a vehicle or in a container exceeds 50, as permitted in Table E above, storage shall be such as to maintain a spacing of at least 6 m from other groups of packages, overpacks or containers containing fissile material or other vehicles carrying radioactive material. The space between such groups may be used for other dangerous goods of ADN. The carriage of other goods with consignments under exclusive use is permitted provided that the pertinent provisions have been taken by the consignor and that carriage is not prohibited under other requirements.

7.1.4.14.7.5

Damaged or leaking packages, contaminatedpackagings

7.1.4.14.7.5.1 If it is evident that a package is damaged or leaking, or if it is suspected that the package may have leaked or been damaged, access to the package shall be restricted and a qualified

person shall, as soon as possible, assess the extent of contamination and the resultant radiation level of the package. The scope of the assessment shall include the package, the vehicle, the wagon, the adjacent loading and unloading areas, and, if necessary, all other material which has been carried in the vessel. When necessary, additional steps for the protection of persons property and the environment, in accordance with provisions established by the competent authority, shall be taken to overcome and minimize the consequences of such leakage or damage. Packages damaged or leaking radioactive contents in excess of allowable limits for normal conditions of carriage may be removed to an acceptable interim location under supervision, but shall not be forwarded until repaired or reconditioned and decontaminated. Vehicles, wagons, vessels and equipment used regularly for the carriage of radioactive material shall be periodically checked to determine the level of contamination. The frequency of such checks shall be related to the likelihood of contamination and the extent to which radioactive material is carried. Except as provided in paragraph 7.1.4.14.7.5.6, any vessel, or equipment or part thereof which has become contaminated above the limits specified in 7.1.4.14.7.5.5 in the course of carriage of radioactive material, or which shows a radiation level in excess of 5 pSvh at the surface, shall be decontaminated as soon as possible by a qualified person and shall not be re-used unless the non-fixed contamination does not exceed the limits specified in 7.1.4.14.7.5.5, and the radiation level resulting from the fixed contamination on surfaces after decontamination is less than 5 pSvlh at the surface. For the purposes of 7.1.4.14.7.5.4, non-fixed contamination shall not exceed: -

4 ~ ~ l for c beta m ~and gamma emitters and low toxicity alpha emitters;

-

0.4 ~ ~ l for c all m other ~ alpha emitters.

These are average limits applicable to any area of 300 cm2on any part of the surface. Vessels dedicated to the carriage of radioactive material under exclusive use shall be excepted from the requirements of the previous paragraph 7.1.4.14.7.5.4 solely with regard to its internal surfaces and only for as long as it remains under that specific exclusive use.

Limitation of the effect of temperature If the temperature of the accessible outer surfaces of a Type B (U) or Type B (M) package could exceed 50" C in the shade, carriage is permitted only under exclusive use. As far as practicable, the surface temperature shall be limited to 85" C. Account may be taken of barriers or screens intended to give protection to transport workers without the barriers or screens being subject to any test. If the average heat flux from the external surfaces of a Type B (U) or B (M) package could exceed 15 w/m2, the special stowage requirements specified in the competent authority package design approval certificate shall be met.

Other provisions If neither the consignor nor the consignee can be identified or if the consignment cannot be delivered to the consignee and the carrier has no instructions from the consignor the consignment shall be placed in a safe location and the competent authority shall be informed as soon as possible and a request made for instructions on further action.

Measures to be taken a@ unloading After unloading the holds shall be inspected and cleaned if necessary. In the case of carriage in bulk, this requirement does not apply if the new cargo comprises the same goods as the previous cargo. For material of Class 7 see also 7.1.4.14.7.5. A transport unit or hold space which has been used to cany infectious substances shall be inspected for release of the substance before re-use. If the infectious substances were released during carriage, the transport unit or hold space shall be decontaminated before it is re-used. Decontamination may be achieved by any means which effectively inactivates the released infectious substance. Measures to be taken during loading, carriage, unloading and handling ofthe cargo The filling or emptying of receptacles, road tank vehicles tank wagons, intermediate bulk containers (IBCs), large packagings, MEGCs, portable tanks or tank-containers on board the vessel is prohibited without special permission from the competent local authority.

(Reserved). Fire and naked light The use of fire or naked light is prohibited while substances or articles of Divisions 1.1, 1.2, 1.3, 1.5 or 1.6 are on board and the holds are open or the goods to be loaded are located at a distance of less than 50 m from the vessel.

(Reserved). Electrical equipment The use of radiotelephone or radar transmitters is not permitted, while substances or articles of Divisions 1.1, 1.2, 1.3, 1.5 or 1.6 are being loaded or unloaded. This shall not apply to VHF-transmitters of the vessel, in cranes or in the vicinity of the vessel, provided the power of the VHF-transmitter does not exceed 25 W and no part of its aerial is located at a distance less than 2.00 m from the substances or articles mentioned above.

(Reserved). Lighting If loading, or unloading is performed at night or in conditions of poor visibility, effective lighting shall be provided. If provided from the deck, it shall be effected by properly secured electric lamps which shall be positioned in such a way that they cannot be damaged. Where these lamps are positioned on deck in the protected area, they shall be of limited explosion risk type.

(Reserved).

Risk of sparking All electrically continuous connections between the vessel and the shore as well as appliances used in the protected area shall be so designed that they do not present a source of ignition.

Synthetic ropes During loading or unloading operations, the vessel may be moored by means of synthetic ropes only when steel cables are used to prevent the vessel from going adrift. Steel cables sheathed in synthetic material or natural fibres are considered as equivalent when the minimum tensile strength required in accordance with the Regulations referred to in 1.1.4.6 is obtained from the steel strands. However, during loading or unloading of containers, vessels may be moored by means of synthetic ropes.

(Reserved). Additional requirements concerning the operation of vessels

Marking Vessels carrying dangerous goods listed in Table A of Chapter 3.2 shall, in accordance with Chapter 3 of the European Code for Inland Waterways (CEVNI), display the markings prescribed in this table. Vessels carrying the dangerous goods listed in Table A of Chapter 3.2 in packages placed exclusively in containers shall display the number of blue cones or blue lights indicated in column (12) of Table A of Chapter 3.2 where: -

three blue cones or three blue lights are required, or

-

two blue cones or two blue lights are required, a substance of Class 2 is involved or packing group I is indicated in column (4) of Table A of Chapter 3.2 and the total gross mass of these dangerous goods exceeds 30,000 kg, or

-

one blue cone or one blue light is required, a substance of Class 2 is involved or packing group I is indicated in column (4) of Chapter 3.2 and the total gross mass of these dangerous goods exceeds 130,000 kg.

Vessels carrying empty, uncleaned tanks, battery vehicles, battery wagons or MEGCs shall display the marking referred to in column (12) of Table A of Chapter 3.2 if these units have contained dangerous goods for which this table prescribes marking. Where more than one marking could apply to a vessel, only the marking which includes the greatest number of blue cones or blue lights shall apply, i.e. in the following order of precedence: -

three blue cones or three blue lights; or

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-

two blue cones or two blue lights; or

--

one blue cone or one blue light.

7.1.5.0.5

By derogation from paragraph 7.1.5.0.1, and in accordance with the footnotes to article 3.14 of the European Code for Inland Waterways (CEVNI), the competent authority of a Contracting Party may authorize seagoing vessels temporarily operating in an inland navigation area on the territory of this Contracting Party, the use of the day and night signals prescribed in the Recommendations on the Safe Transport of Dangerous Cargoes and Related Activities in Port Areas adopted by the Maritime Safety Committee of the International Maritime Organization (by night an all-round fixed red light and by day flag "B" of the International Code of Signals), instead of the signals prescribed in 7.1.5.0.1. Contracting Parties which have taken the initiative with respect to the derogation granted shall notify the Executive Secretary of the United Nations Economic commission for Europe, who shall bring this derogation to the attention of the Administrative Committee.

7.1.5.1

Mode of navigation

7.1 S.1.1

The competent authorities may impose restrictions on the inclusion of tank vessels in pushed conveys of large dimension.

7.1.5.1.2

When vessels carry substances or articles of Class l , or substances of Classes 4.1 or 5.2 for which marking with three blue cones or three blue lights is prescribed in column (12) of Table A of Chapter 3.2, or material of Class 7 of UN Nos. 2912, 2913, 2915, 2916, 2917, 2919, 2977, 2978 or 3321 to 3333, the competent authority may impose restrictions on the dimensions of convoys or side-by-side formations. Nevertheless, the use of a motorized vessel giving temporary towing assistance is permitted.

Vessels under way Vessels carrying substances or articles of Class 1, or substances of Classes 4.1 or 5.2 for which marking with three blue cones or three blue lights is prescribed in column (12) of Table A of Chapter 3.2, when under way shall keep not less than 50 m away from any other vessel, if possible.

Mooring Vessels shall be moored securely, but in such a way that they can be released quickly in an emergency. 7.1.5.4

Berthing

7.1S.4.1

The distances to be kept by vessels carrying dangerous goods at berth from other vessels shall not be less than the distance prescribed by the European Code for Inland Waterways.

7.1S.4.2

An expert in accordance with 7.1.3.15 shall be permanently on board berthed vessels carrying dangerous goods for which marking is prescribed in column (12) of Table A of Chapter 3.2. The competent authority may, however, exempt from this obligation those vessels which are berthed in a harbour basin or in an accepted berthing position.

7.1 S.4.3

Outside the berthing areas specifically designated by the competent authority, the distances to be kept by berthed vessels shall not be less than:

from residential areas, civil engineering structures or storage tanks, if the vessel is required to be marked with one blue cone or one blue light in accordance with the requirements of column (12) of Table A of Chapter 3.2; from civil engineering structures and storage tanks and 300 m from residential areas if the vessel is required to be marked with two blue cones or two blue lights in accordance with the requirements of column (12) of Table A of Chapter 3.2; from residential areas, civil engineering structures and storage tanks if the vessel is required to be marked with three blue cones or three blue lights inaccordance with the requirements of column (12) of Table A of Chapter 3.2. While waiting in front of locks or bridges, vessels are allowed to keep distances different from and lower than those given above. In no case shall the distance be less than 100 m. 7. l .5.4.4

The competent authority may prescribe distances lower than those given in 7.1S.4.3 above, especially taking local conditions into account.

7.1.5.5

Stopping of vessels If navigation of a vessel carrying substances and articles of Class 1 or substances of Class 4.1 or 5.2 for which marking with three blue cones or three blue lights is prescribed in column (12) of Table A of Chapter 3.2 threatens to become dangerous owing either to: -

external factors (bad weather, unfavourable conditions of the waterway, etc.), or

-

the condition of the vessel itself (accident or incident),

the vessel shall be stopped at a suitable berthing area as far away as possible from residential areas, harbours, civil engineering structures or storage tanks for gas or flammable liquids, regardless of the provisions set out in 7.1.5.4. The competent authority shall be notified without delay. 7.1.5.67.1.5.7

(Reserved).

7.1.5.8

Reporting duty

7.1.5.8.1

In the States where the reporting duty is in force, the master of a vessel for which marking in accordance with 7.1.5.0 is required shall, prior to the start of any voyage, report the following particulars to the competent authority of the State in which the voyage has started: -

name of the vessel;

-

official number;

-

dead-weight tonnage;

-

description of the dangerous goods carried as given in the transport document (UN number or identification number, proper shipping name, class and, where applicable, packing group andlor classification code) together with the quantity in each case;

NOTE: The gross mass of the packages containing substances or articles of Class I shall be declared in addition to the net mass of explosive substances and of explosive substances contained in the articles. -

number of persons on board;

-

port of destination; and

-

planned shipping route.

This reporting duty shall apply in each State territory once to both passages upstream and downstream so far as the competent authorities so require. The information may be given orally (e.g. by radio-telephone, where appropriate by automatic wireless message service) or in writing. When passing the other traffic control stations designated by the competent authority, the following particulars shall be reported: -

name of the vessel;

-

official number;

-

dead-weight tonnage.

Changes to any of the particulars referred to in 7.1 S.8.1 shall be reported to the competent authority without delay. The information is confidential and shall not be passed on to third parties by the competent authority. The competent authority may, however, in the event of an accident, inform the emergency services of the relevant particulars required for organizing emergency action. (Reserved). Additional requirements (Reserved). Carriage in bulk

The following additional requirements shall be met when they are indicated in column (l l ) of Table A of Chapter 3.2: C001:

The surfaces of holds shall be coated or lined such that they are not readily flammable and not liable to impregnation by the cargo.

C002:

Any part of the holds and of the hatchway covers which may come into contact with this substance shall consist of metal or of wood having a specific density of not less than 0.75 kgidm3 (seasoned wood).

C003:

The inner surfaces of holds shall be lined or coated so as to prevent corrosion.

STOl:

The substances shall have been stabilized in accordance with the requirements applicable to ammonium nitrate fertilizers set out in the BC Code. Stabilizing shall be certified by the consignor in the transport document. In those States where this is required, these substances may be carried in bulk only with the approval of the competent national authority.

ST02:

These substances may be carried in bulk if the results of the trough test according to Appendix D.4 of the BC Code show that the self-sustaining decomposition rate is not greater than 25 c d h .

RA01 :

The materials may be carried in bulk provided that:

RA02:

RA03:

(a)

for materials other than natural ores, carriage is under exclusive use and there is no escape of contents out of the vessel and no loss of shielding under normal conditions of transport; or

(b)

for natural ores, carriage is under exclusive use.

The materials may be carried in bulk provided that: (a)

they are carried in a vessel so that, under normal conditions of transport, there is no escape of contents or loss of shielding;

(b)

they are carried under exclusive use if the contamination on the accessible and inaccessible surfaces is greater than 4 ~ ~ / (c1 m 0 ci/cm2) ~ ~~ for beta and gamma emitters and low toxicity alpha emitters or 0.4 ~ ~ / (1c 0-5 my ~~i i c r n ~ ) for all other alpha emitters;

(c)

measures are taken to ensure that radioactive material is not released into the vessel, if it is suspected that non-fixed contamination exists on inaccessible surfaces of more than 4 Bqlcm2 (10.~p~i/cm2)for beta and gamma emitters and low toxicity alpha emitters or 0.4 Bq/cmZ (10-5 yCiicm2) for all other alpha emitters.

Surface Contaminated Objects (SCO-11) shall not be carried in bulk.

The following additional requirements shall be met when they are indicated in column (10) of Table A of Chapter 3.2: VEO1 :

Holds containing these substances shall be ventilated with the ventilators operating at full power, where after measurement it has been established that the concentration of gases given off by the cargo exceeds 10% of the lower explosive limit. The measurement shall be carried out immediately after loading. The meast~rementshall be repeated after one hour for monitoring purposes. The results of the measurement shall be recorded in writing.

VE02:

Holds containing these substances shall be ventilated with the ventilators operating at full power, where after measurement it has been established that the holds are not free from gases given off by the cargo. The measure~nentshall be carried out immediately after loading. The measurement shall be repeated after one hour for monitoring purposes. The results of the measurement shall be recorded in writing.

VE03:

Spaces such as holds, accommodation and engine rooms, adjacent to holds containing these goods shall be ventilated. After unloading holds shall undergo forced ventilation. After ventilation, the concentration of gases in the holds shall be measured. The results of the measurement shall be recorded in writing.

VE04

7.1.6.13

When aerosols are carried for the purposes of reprocessing or disposal under special provision 327, provisions of VEO1 and VE02 are applied.

Measures to be taken before loading The following additional requirements shall be met when they are indicated in column (l l ) of Table A of Chapter 3.2:

LOOI:

Before these substances or articles are loaded, it shall be ensured that there are no metal objects in the hold which are not an integral part of the vessel.

L002:

These substances may be loaded in bulk only if their temperature is not above 55" C.

L003:

Before loading these substances in bulk or unpackaged, holds should be made as dry as possible.

L004:

Any loose organic material shall be removed from holds before loading these substances in bulk.

L005: Prior to carriage of pressure receptacles it shall be ensured that the pressure

has not risen due to potential hydrogen generation. 7.1.6.14

Handling and stowage of cargo The following additional requirements shall be met when they are indicated in column (l I) of Table A of Chapter 3.2: These substances shall be stowed at a distance of not less than 3.00 m from the accommodation, engine rooms, the wheelhouse and from any sources of heat. These substances or articles shall be stowed at a distance of not less than 2.00 m from the sides of the vessel. Any friction, impact, jolting, overturning or dropping shall be prevented during handling of these substances or articles. All packages loaded in the same hold shall be stowed and wedged as to prevent any jolting or friction during transport. Stacking of non-dangerous goods on top of packages containing these substances or articles is prohibited. Where these substances or articles are loaded together with other goods in the same hold, these substances or articles shall be loaded after, and unloaded before, all the other goods.

This provision does not apply if the substances or articles of Class l are contained in containers. While these substances or articles are being loaded or unloaded, no loading or unloading operations shall take place in the other holds and no filling or emptying of fuel tanks shall be allowed. The competent authority may, however, permit exemptions from this provision. It is prohibited to load or unload these substances in bulk or unpackaged if there is a danger that they may get wet because of the prevailing weather conditions. If the packages with these substances are not contained in a container, they shall be placed on grating and covered with waterproof tarpaulins arranged in such a way that the water drains off to the outside and the air circulation is not hindered. If these substances are carried in bulk they shall not be loaded in the same hold together with flammable substances. These substances shall be stowed on deck in the protected area. For seagoing vessels, the stowage requirements are deemed to be met if the provisions of the IMDG Code are complied with. 7.1.6.15

(Reserved).

7.1.6.16

Measures to be taken during loading, carriage, unloading and handling The following additional requirements shall be met when they are indicated in column (1 1) of Table A of Chapter 3.2: IN01 :

After loading and unloading of these substances in bulk or unpackaged and before leaving the cargo transfer site, the concentration of gases in the accommodation, engine rooms and adjacent holds shall be measured by the consignor or consignee using a flammable gas detector. Before any person enters a hold and prior to unloading, the concentration of gases shall be measured by the consignee of the cargo. The hold shall not be entered or unloading started until the concentration of gases in the airspace above the cargo is below 50% of the lower explosive limit. If significant concentrations of gases are found in these spaces, the necessary safety measures shall be taken immediately by the consignor or the consignee.

IN02:

If a hold contains these substances in bulk or unpackaged, the gas concentration shall be measured in all other spaces of the vessel which are used by the crew at least once every eight hours with a toximeter. The results of the measurements shall be recorded in writing.

IN03:

If a hold contains these substances in bulk or unpackaged, the master shall make sure every day by checking the bilge wells or pump ducts that no water has entered the bilges. Water which has entered the bilges shall be removed immediately.

7.1.6.177.1.9.99

(Reserved).

CHAPTER 7.2

TANK VESSELS General requirements The provisions of 7.2.0 to 7.2.5 are applicable to tank vessels.

(Reserved). Mode of carriage of goods (Reserved).

Carriage in cargo tanks Substances, their assignment to the various types of tank vessels and the special conditions for their carriage in these tank vessels, are listed in Table C of Chapter 3.2. Substances, which according to column (6) of Table C of Chapter 3.2, have to be carried in a tank vessel of type N, open, may also be carried in a tank vessel of type N, open, with flamearresters; type N, closed; types C or G provided that all conditions of carriage prescribed for tank vessels of type N, open, as well as all other conditions of carriage prescribed in the list of substances of Table C are met. Substances which, according to column (6) of Table C of Chapter 3.2 have to be carried in a tank vessel of type N, open, with flame-arresters, may also be carried in tank vessels of type N, closed, and types C or G provided that all conditions of carriage prescribed for tank vessels of type N, open, with flame arresters, as well as all other conditions of carriage prescribed in the list of substances of Table C are met. Substances which, according to column (6) of Table C of Chapter 3.2 have to be carried in a tank vessel of type N, closed, may also be carried in tank vessels of type C or G provided that all conditions of carriage prescribed for tank vessels of type N, closed, as well as all other conditions of carriage prescribed in the list of substances of Table C are met. Substances which, according to column (6) of Table C of Chapter 3.2 have to be carried in tank vessels of type C may also be carried in tank vessels of type G provided that all conditions of carriage prescribed for tank vessels of type C as well as all other conditions of carriage prescribed in the list of substances of Table C are met. Oily and greasy wastes resulting from the operation of the vessel may only be carried in fireresistant receptacles, fitted with a lid, or in cargo tanks.

(Reserved). Requirements applicable to vessels

Permitted vessels

NOTE I : The reliefpressure of the safety valves or of the high-velocity vent valves shall be itzdicated in the certzficate of approval (see 8.6.1.3).

NOTE 2: The design pressure and the test pressure of cargo tanks shall be indicated in the certificate of the classzjkation society prescribed in 9.3.1.8.1 or 9.3.2.8.l or 9.3.3.8.1. NOTE 3: Where a vessel carries cargo tanks with diJfferent valve-relief pressures, the relief pressure o f each tank shall be indicated in the certificate of approval and the design and test pressures of each tank shall be indicated in the certzjkate of the class~jicationsociety.

Dangerous substances may be carried in tank vessels of Types N, C or G in accordance with the requirements of Chapters 9.2, 9.3 or 9.4 respectively. The type of tank vessel to be used is specified in column (6) of Table C of Chapter 3.2 and in 7.2.1.21. NOTE: The substances accepted for carriage in the vessel are indicated in the certificate to be drawn up by the classification socieh, (se 1.16.1J.5).

(Resewed).

Instructions for the use of devices and installations Where specific safety mles have to be complied with when using any device or installation, instructions for the use of the particular device or installation shall be readily available for consultation at appropriate places on board in the language normally spoken on board, and also, if that language is not English, French or German, in English, French or German unless agreements concluded between the countries concerned in the transport operation provide otherwise.

Gas detection system The sensors of the gas detection system shall be set at not more than 20% of the lower explosive limit of the substances allowed for carriage in the vessel. The system shall have been approved by the competent authority or a recognized classification society.

(Reserved).

Pushed convoys and side-by-sideformations Where at least one vessel of a convoy or side-by-side formation is required to be in possession of a certificate of approval, all vessels of such convoy or side-by-side formation shall be provided with an appropriate certificate of approval. Vessels not carrying dangerous goods shall comply with the provisions of 7.1.2.19. For the purposes of the application of this Part, the entire pushed convoy or side-by-side formation shall be deemed to be a single vessel. When a pushed convoy or a side-by-side formation comprises a tank vessel carrying dangerous substances, vessels used for propulsion shall meet the requirements of the following paragraphs: 7.2.2.5, 8.1.4, 8.1.5, 8.1.6.1, 8.1.6.3, 8.1.7, 8.1.8, 8.1.9, 9.3.3.0.1, 9.3.3.0.3 (d), 9.3.3.0.5, 9.3.3.10.1, 9.3.3.10.2, 9.3.3.12.4, 9.3.3.12.6, 9.3.3.16, 9.3.3.17.1 to 9.3.3.17.4, 9.3.3.31.1 to 9.3.3.3 1.5, 9.3.3.32.2, 9.3.3.34.1, 9.3.3.34.2, 9.3.3.40.1 (however, one single fire or ballast

pump shall be sufficient), 9.3.3.40.2, 9.3.3.41, 9.3.3.50.1 (c), 9.3.3.50.2, 9.3.3.51, 9.3.3.52.3, 9.3.3.52.4 to 9.3.3.52.6, 9.3.3.56.5, 9.3.3.71 and 9.3.3.74. (Reserved).

Safe@ and control equbment It shall be possible to interrupt loading or unloading of substances of Class 2 and substances assigned to UN Nos. 1280 and 2983 of Class 3 by means of switches installed at two locations on the vessel (fore and aft) and at two locations ashore (directly at the access to the vessel and at an appropriate distance on the quay). Entemption of loading and unloading shall be effected by the means of a quick action stop valve which shall be directly fitted to the flexible connecting hose between the vessel and the shore facility. The system of disconnection shall be designed in accordance with the closed circuit principle.

Cargo tank openings When substances for which a type C vessel is required in column (6) of Table C of Chapter 3.2 are carried, the high-velocity vent valves shall be set so that blowing-off does not normally occur while the vessel is under way. (Reserved).

General service requirements Access to cargo tanks, residual cargo tanks, cargo pump-rooms below deck, cofferdams, double-hull spaces, double bottoms and hold spaces; inspections The cofferdams shall be empty. They shall be inspected once a day in order to ascertain that they are dry (except for condensation water). Access to the cargo tanks, residual cargo tanks, cofferdams, double-hull spaces, double bottoms and hold spaces is not permitted except for carrying out inspections or cleaning operations. Access to the double-hull spaces and the double bottoms is not permitted while the vessel is under way. When the gas concentration or oxygen content has to be measured before entry into cargo tanks, residual cargo tanks, cargo pump-rooms below deck, cofferdams, double-hull spaces, double bottoms or hold spaces, the results of these measurements shall be recorded in writing. The measurement may only be effected by persons equipped with breathing apparatus suited to the substance carried. Entry into these spaces is not permitted for the purpose of measuring. Before any person enters cargo tanks, the cargo pump-rooms below deck, cofferdams, double-hull spaces, double bottoms or hold spaces: (a)

When dangerous substances of Classes 2,3,4.1,6.1, 8 or 9 for which a flammable gas detector is required in column (l 8) of Table C of Chapter 3.2 are carried on board the

vessel, it shall be estabiished, by means of this device that the gas concentration in these cargo tanks, cargo pump-rooms below deck, cofferdams, double-hull spaces, double bottoms or hold spaces is not more than 50% of the lower explosive limit of the cargo. For the cargo pump-rooms below deck this may be determined by means of the permanent gas detection system; (b)

When dangerous substances of Classes 2, 3, 4.1, 6.1, 8 or 9 for which a toximeter is required in column (18) of Table C of Chapter 3.2 are carried on board the vessel, it shall be established, by means of this device that the cargo tanks, cargo pump-rooms below deck, cofferdams, double-hull spaces, double bottoms or hold spaces do not contain any significant concentration of toxic gases.

Entry into empty cargo tanks, the cargo pump-rooms below deck, cofferdams, double-hull spaces, double bottoms and hold spaces is not permitted, except where: -

there is no lack of oxygen and no measurable amount of dangerous substances in dangerous concentrations; or

-

the person entering the spaces wears a self-contained breathing apparatus and other necessary protective and rescue equipment, and is secured by a line. Entry into these spaces is only permitted if this operation is supervised by a second person for whom the same equipment is readily at hand. Another two persons capable of giving assistance in an emergency shall be on the vessel within calling distance. If a rescue winch has been installed, only one other person is sufficient.

Cargopump-rooms below deck When carrying dangerous substances of classes 3, 4.1, 6.1, 8 or 9, the cargo pump-rooms below deck shall be inspected daily so as to ascertain that there are no leaks. The bilges and the drip pans shall be kept clean and free from products. When the gas detection system is activated, the loading and unloading operations shall be stopped immediately. AI1 shut-off devices shall be closed and the cargo pump-rooms shall be evacuated immediately. All entrances shall be closed. The loading or unloading operations shall not be continued except when the damage has been repaired or the fault eliminated.

Gas detection system The gas detection system shall be maintained and calibrated in accordance with the instructions of the manufacturer.

Gas-freeing of empty cargo tanks Gas-freeing of empty or unloaded cargo tanks is permitted under the conditions below but only if it is not prohibited on the basis of international or domestic legal requirements. Empty or unloaded cargo tanks having previously contained dangerous substances of Class 2, Class 3, with classification code "T" in column (3b) of Table C of Chapter 3.2, Class 6.1 or packing group I of Class 8, may only be gas-freed at the locations designated or approved for such purpose by the competent authority. Gas-freeing may be carried out only by competent persons or companies approved for that purpose.

7.2.3.7.2

Gas-freeing of empty or unloaded cargo tanks having contained dangerous goods other than those referred to under 7.2.3.7.1 above, may be carried out while the vessel is under way by means of suitable venting equipment with the tank lids closed and by leading the gadair mixtures through flame-arresters capable of withstanding steady burning. In normal conditions of operation, the gas concentration in the vented mixture at the outlet shall be less than 50% of the lower explosive limit. The suitable venting equipment may be used for gas-freeing by extraction only when a flame-arrester is fitted immediately before the ventilation fan on the extraction side. The gas concentration shall be measured once each hour during the two first hours after the beginning of the gas-freeing operation by forced ventilation or by extraction, by an expert referred to in 7.2.3.15. The results of these measurements shall be recorded in writing. Gas-freeing is, however, prohibited within the area of locks including their lay-bys.

7.2.3.7.3

Where gas-freeing of cargo tanks having previously contained the dangerous goods referred to in 7.2.3.7.1 above is not practicable at the locations designated or approved for this purpose by the competent authority, gas-freeing may be carried out while the vessel is under way, provided that: -

the requirements of 7.2.3.7.2 are complied with; the concentration of dangerous substances in the vented mixture at the outlet shall, however, be not more than 10% of the lower explosive limit;

-

there is no risk involved for the crew;

-

any entrances or openings of spaces connected to the outside are closed; this provision does not apply to the air supply openings of the engine room;

-

any member of the crew working on deck is wearing suitable protective equipment;

-

it is not carried out within the area of locks including their lay-bys, under bridges or within densely populated areas.

7.2.3.7.4

Gas-freeing operations shall be intempted when, due to unfavourable wind conditions, dangerous concentrations of gases are to be expected outside the cargo area in front of accommodation, the wheelhouse and service spaces. The critical state is reached as soon as concentrations of more than 20% of the lower explosive limit have been detected in those areas by measurements by means of portable equipment.

7.2.3.7.5

The marking prescribed in column (19) of Table C of Chapter 3.2 may be withdrawn when, after gas-freeing of the cargo tanks, it has been ascertained, using the equipment described in column (18) of Table C of Chapter 3.2, that the cargo tanks no longer contain flammable gases in concentrations of more than 20% of the lower explosive limit or do not contain any significant concentration of toxic gases. Repair and maintenance work

No repair or maintenance work liable to cause sparks or requiring the use of an open flame or electric current shall be undertaken unless permission has been given by the competent authority or a certificate attesting gas-free condition has been issued for the vessel. In the service spaces outside the cargo area repair and maintenance work may be undertaken, provided the doors and openings are closed and the vessel is not being loaded, unloaded or gas-freed.

The use of chromium vanadium steel screwdrivers and wrenches or screwdrivers and wrenches of equivalent material from the point of view of spark formation is permitted.

Ventilation While the machinery in the service spaces is opcrating, the extension ducts connected to the air inlets, if any, shall be in the upright position; otherwise the inlets shall be closed. This provision does not apply to air inlets of service spaces outside the cargo area, provided the inlets without extension duct are located not less than 0.50 m above the deck. The ventilation of pump rooms shall be in operation: -

at least 30 minutes before entry and during occupation;

-

during loading, unloading and gas-freeing; and

-

after the gas detection system has been activated.

(Reserved).

Expert on board the vessel When dangerous substances are carried, an expert, referred to in 8.2.1 shall be on board the vessel. In addition, -

when dangerous substances are carried, for which a type G tank vessel is prescribed in column (6) of Table C of Chapter 3.2, this expert shall be the expert referred to in 8.2.1.5; and

-

when dangerous substances are carried, for which a type C tank vessel is prescribed in column (6) of Table C of Chapter 3.2, this expert shall be the expert referred to in 8.2.1.7.

During the carriage of goods for which a type C vessel is prescribed in column (6) of Table C of Chapter 3.2 and cargo tank type 1 in column (7), an expert holding the certificate referred to in 8.2.1.5 for carriage in type G vessels is sufficient. (Reserved).

Cofferdams and hold spaces containing insulated cargo tanks shall not be filled with water. Double-hull spaces, double bottoms and hold spaces may be filled with ballast water provided the cargo tanks have been discharged. If the cargo tanks are not empty, double-hull spaces and double bottoms may be filled with ballast water provided this has been taken into account in the damage-control plan and the ballast tanks are not filled to more than 90% of their capacity and provided this is not prohibited in column (20) of Table C of Chapter 3.2.

Where ballast water is discharged from cargo tanks, an appropriate entry shall be made in the loading journal.

(Reserved). Entrances to hold spaces, cargo pump-rooms below deck, cofferdams, opening of cargo tanks and residual cargo tanks; closing devices The cargo tanks, residual cargo tanks and entrances to cargo pump-rooms below deck, cofferdams and hold spaces shall remain closed. This requirement shall not apply to cargo pump-rooms on board oil separator and supply vessels or to the other exceptions set out in this Part.

(Reserved). Connections between pipes Connecting two or more of the following groups of pipes is prohibited: (a)

pipes for loading and unloading;

(b)

pipes for ballasting and draining cargo tanks, cofferdams, hold spaces, double-hull spaces and double bottoms;

(c)

pipes located outside the cargo area.

The provision of 7.2.3.25.1 above does not apply to removable pipe connections between cofferdam pipes and -

pipes for loading and unloading;

-

pipes located outside the cargo area while the cofferdams have to be filled with water .

In these cases the connections shall be designed so as to prevent water from being drawn from the cargo tanks. The cofferdams shall be emptied only by means of educators or an independent system within the cargo area. The provisions of 7.2.3.25.1 (b) and (c) above do not apply to: -

pipes intended for ballasting and draining double-hull spaces and double bottoms which have not common boundary with the cargo tanks;

-

pipes intended for ballasting hold spaces where the pipes of the fire-fighting system within the cargo area are used for this purpose. Double-hull and double bottom spaces and hold spaces shall be stripped only by means of educators or an independent system within the cargo area.

(Reserved). Refrigeration system For the carriage of refrigerated substances, an instruction shall be on board mentioning the permissible maximum loading temperature in relation to the capacity of the refrigeration system and the insulation design of the cargo tanks.

The lifeboat required in accordance with the Regulations referred to in 1.1.4.6 shall be stowed outside the cargo area. The lifeboat may, however, be stowed in the cargo area provided an easily accessible collective life-saving appliance conforming to the Regulations referred to in 1.1.4.6 is available within the accommodation area. 7.2.3.29.1 above does not apply to oil separator or supply vessels. (Resewed). Engines The use of engines running on fuels having a flashpoint below 55" C (e.g. petrol engines) is prohibited. This requirement does not apply to the outboard motors of lifeboats. The carriage of power-driven conveyances such as passenger cars and motor boats in the cargo area is prohibited. Oil fuel tanks Double bottoms with a height of at least 0.6 m may be used as oil fuel tanks, provided they have been constructed in accordance with Part 9. (Resewed).

Fire and naked light The use of fire or naked light is prohibited. This provision does not apply to the accommodation and the wheelhouse. Heating, cooking and refrigerating appliances shall not be fuelled with liquid fuels, liquid gas or solid fuels. Cooking and refrigerating appliances may only be used in the accommodation and in the wheelhouse. Heating appliances or boilers fuelled with liquid fuels having a flashpoint above 55' C which are installed in the engine room or in another suitable space may, however, be used. Cargo heating system Heating of the cargo is not permitted except where there is risk of solidification of the cargo or where the cargo, because of its viscosity, cannot be unloaded in the usual manner. In general, a liquid shall not be heated up to a temperature above its flashpoint. Special provisions are included in column 20 of Table C of Chapter 3.2. Cargo tanks containing substances which are heated during transport shall be equipped with devices for measuring the temperature of the cargo.

During unloading, the cargo heating system may be used provided that the space where it has been installed meets in all respects the provisions of 9.3.2.52.3 (b) or 9.3.3.52.3 (b). The provisions of 7.2.3.42.3 above do not apply when the cargo heating system is supplied with steam from shore and only the circulation pump is in operation, as well as when the flashpoint of the cargo being unloaded is not less than 60" C. (Reserved). Cleaning operations

The use of liquids having a flashpoint below 55" C for cleaning purposes is permitted only in the cargo area. (Reserved).

Electrical installations

The electrical installations shall be properly maintained in a faultless condition. The use of movable electric cables is prohibited in the cargo area. This provision does not apply to: -

intrinsically safe electric circuits;

-

electric cables for connecting signal lights or gangway lighting, provided the socket is permanently fitted to the vessel close to the signal mast or gangway;

-

electric cables for connecting submerged pumps on board oil separator vessels.

The sockets for connecting the signal lights and gangway lighting or for submerged pumps on board oil separator vessels shall not be live except when the signal lights or the gangway lighting or the submerged pumps on board oil separator vessels are switched on. Connecting or disconnecting shall not be possible except when the sockets are not live. (Reserved). Additional requirements concerning loading, carriage, unloading and other handling of cargo

Limitation of the quantities carried

The carriage of packages in the cargo area is prohibited. This prohibition does not apply to: -

residual cargo, cargo residues and slops in approved intermediate bulk containers (IBCs), tank-containers or portable tanks having a maximum individual capacity of not more than 2.00 m3; not more than six such intermediate bulk containers, tank-containers or portable tanks, however, shall be carried. These intermediate bulk containers, tank-containers or portable tanks shall meet the requirements of international regulations applicable to the substance concerned and shall comply with the provisions of 9.3.2.26.4 or 9.3.3.26.4 for the reception of residual cargo, cargo residues or slops;

-

to cargo samples, up to a maximum of 30, of substances accepted for carriage in the tank vessel, where the maximum contents are 500 m1 per receptacle. Receptacles shall meet the packing requirements referred to in Part 4 and shall be placed on board, at a specific point in the cargo area, such that under normal conditions of carriage they cannot break or be punctured and their contents cannot spill in the hold space. Fragile receptacles shall be suitably padded.

On board oil separator vessel receptacles with a maximum capacity of 2.00 m3 oily and greasy wastes resulting from the operation of vessels may be placed in the cargo area provided that these receptacles are properly secured. On board supply vessel packages of dangerous goods may be carried in the cargo area up to a gross quantity of 5,000 kg provided that this possibility is mentioned in the certificate of approval. The packages shall be properly secured and shall be protected against heat, sun and bad weather. On board supply vessels or other vessels delivering products for the operation of vessels, the number of cargo samples referred to in 7.2.4.1.1 may be increased from 30 to a maximum of 500.

Reception of oily and greasy wastes resulting from the operation of vessels and delivery of products for the operation of vessels The reception of unpackaged liquid oily and greasy wastes resulting from the operation of vessels may only be effected by suction. The landing and reception of oily and greasy wastes may not take place during the loading and unloading of substances for which protection against explosion is required column (16) of Table C of Chapter 3.2 nor during the gas-freeing of tank vessels. This requirement does not apply to oil separator vessels provided that the provisions for protection against explosion applicable to the dangerous substance are complied with. Berthing and handing over of products for the operation of vessels shall not take place during the loading or unloading of substances for which protection against explosions is required column (16) of Table C of Chapter 3.2 nor during the gas-freeing of tank vessels. This requirement does not apply to supply vessels provided that the provisions for protection against explosion applicable to the dangerous substance are complied with. The competent authority may issue derogations to the requirements of 7.2.4.2.1 and 7.2.4.2.2 above. During unloading it may also issue derogations to 7.2.4.2.3 above. (Reserved).

Places of loadkg and unloadilzg Tank vessels shall be loaded, unloaded or gas-freed only at the places designated or approved for this purpose by the competent authority. The reception of unpackaged oily and greasy liquid wastes resulting from the operation of vessels and the handing over of products for the operation of vessels shall not be taken to be loading or unloading within the meaning of 7.2.4.7.1 above. (Reserved).

7.2.4.9

Cargo transfer operations Partial or complete cargo transfer without permission fi-om the competent authority is prohibited outside a cargo transfer place approved for this purpose.

Checklist Loading or unloading shall not be started before a check list for the cargo in question has been completed and questions 1 to 18 of the list have been checked off with an "X". Irrelevant questions should be deleted. The list shall be completed in duplicate and signed by the master or a person mandated by himself and the person responsible for the handling at the shore facilities. If a positive response to all the questions is not possible loading or unloading is only permitted with the consent of the competent authority. The list shall conform to the model in 8.6.3. The checklist shall be printed at least in languages understood by the master and the person responsible for the handling at the shore facilities. The provisions of 7.2.4.10.1 to 7.2.4.10.3 above shall not apply to the reception of oily and greasy wastes by oil separator vessels nor to the handing over of products for the operation of vessels by supply vessels.

Loading journal; loading plan The master shall record without delay in a loading journal all activities relating to loading, unloading, cleaning, gas-freeing, discharge of washing water and reception or discharge of ballast water (in cargo tanks). The goods shall be described as in the transport document (UN number or substance identification number, proper shipping name, class, and, where applicable classification code andior packing group).]' The master shall enter on a cargo stowage plan the goods carried in the individual cargo tanks. The goods shall be described as in the transport document (UN number or substance identification number, proper shipping name, class and, where applicable, packing group).

Registration during the voyage The following particulars shall immediately be entered in the register referred to in 8.1.1 1: Loading: Place of loading and loading berth, date and time, UN number or identification number of the substance, including the class and packing group if it exists; Unloading: Place of unloading and unloading berth, date and time; Gas-freeing of UN No. 1203 petrol: Gas-freeing place and facility or sector, date and time. These particulars shall be provided for each cargo tank. Measures to be taken before loading

When residues of the previous cargo may cause dangerous reactions with the next cargo, any such residues shall be properly removed.

' it is not necessary to apply thisparagraph. The date of application will be defined later. - 265 -

Substances which react dangerously with other dangerous goods shall be separated by a cofferdam, an empty space, a pump-room, an empty cargo tank or a cargo tank loaded with a substance which does not react with the cargo. Where an empty, uncleaned cargo tank, or a cargo tank containing cargo residues of a substance liable to react dangerously with other dangerous goods, this separation is not required if the master has taken appropriate measures to avoid a dangerous reaction. If the vessel is equipped with piping for loading and unloading below the deck passing through the cargo tanks, the mixed loading or carriage of substances likely to react dangerously with each other is prohibited. Before the start of loading operations, any prescribed safety and control devices and any items of equipment shall, if possible, be checked and controlled for the proper hnctioning. Before the start of loading operations the overflow control device switch shall be connected to the shore installation. Cargo handling and stowage Dangerous goods shall be loaded in the cargo area in cargo tanks, in cargo residue tanks or in packages permitted under 7.2.4.1.1. Measures to be taken after unloading After each unloading operating the cargo tanks and the cargo piping shall be emptied by means of the stripping system in accordance with the conditions laid down in the testing procedure. This provision need not be complied with if the new cargo is the same as the previous cargo. Residual cargo shall be discharged ashore by means of the equipment provided to that effect or shall be stored in the vessel's own residual cargo tank or stored in intermediate bulk containers (IBCs) or tank-containers or portable tanks permitted according to 7.2.4.1.1, 9.3.2.26.3 or 9.3.3.26.3. During the filling of permitted residual cargo tanks, intermediate bulk containers (IBCs), tank-containers or portable tanks, gases shall be safely evacuated. After additional stripping, cargo tanks and pipes for loading and unloading shall, if necessary, be cleaned and gas-freed by persons or companies approved for this purpose by the competent authority in places approved for this purpose. Measures to be taken during loading, carriage, unloading and handling The loading rate and the maximum operational pressure of the cargo pumps shall be determined in agreement with the personnel at the shore installation. All safety or control devices required in the cargo tanks shall remain switched on. During carriage this provision is only applicable for the installations mentioned in 9.3.1.2 1.1 (e) and (ff,9.3.2.21.1 (e) and (Q or 9.3.3.21.1 (e) and (0. In the event of a failure of a safety or control device, loading or unloading shall be suspended immediately. When a cargo pump-room is located below deck, the prescribed safety and control devices in the cargo pump-room shall remain permanently switched on.

- 266 -

Any failure of the gas detection system shall be immediately signalled in the wheelhouse and on deck by a visual and audible warning. The shut-off devices of the cargo piping as well as of the pipes of the stripping systems shall remain closed except during loading, unloading, stripping, cleaning or gas-freeing operations. If the vessel is fitted with a transverse bulkhead according to 9.3.1.25.3, 9.3.2.25.3 or 9.3.3.25.3, the doors in this bulkhead shall be closed during loading and unloading. Receptacles intended for recovering possible liquid spillage shall be placed under connections to shore installations used for loading and unloading. This requirement shall not apply to the carriage of substances of Class 2. In case of recovery of the gas-air mixture from shore into the vessel, the pressure at the connection point shall not be more than the operating pressure of the high velocity vent valve. When a tank vessel conforms to 9.3.2.25.5 (d) or 9.3.3.22.5 (d), the individual cargo tanks shall be closed off during transport and opened during loading, unloading and gas-freeing. Persons entering the premises located in the below deck cargo area during loading or unloading shall wear the PP equipment referred to in 8.1.5 if this equipment is prescribed in column (18) of Table C of Chapter 3.2. Persons connecting or disconnecting the loading and unloading pipes or the vapour pipes or gas discharge pipes, or taking samples, carrying out measurements, replacing the flame arrester plate stack or relieving pressure in cargo tanks shall wear the PP equipment referred to in 8.1.5. If this equipment is prescribed in column (18) of Table C of Chapter 3.2. They shall also wear protective equipment A if a toximeter (TOX) is prescribed in column (18) of Table C of Chapter 3.2. During loading or unloading in a closed tank vessel of substances for which an open type N vessel or an open type N vessel with a flame arrester is sufficient according to columns (6) and (7) of Table C of Chapter 3.2, the cargo tanks may be opened using the safe pressure-relief device referred to in 9.3.2.22.4 (a) or 9.3.3.22.4 (a). 7.2.4.16.9 shall not apply when the cargo tanks contain gases or vapour from substances for the carriage of which a closed-type tank vessel is required in columns (6) and (7) of Table C of Chapter 3.2. The nozzle closure referred to in 9.3.1.21.l (g), 9.3.2.2 1.1 (g) or 9.3.3.21.l (g) can be opened only after a gastight connection has been made to the closed or partly closed sampling device. For substances requiring protection against explosions according to column (17) of Table C of Chapter 3.2, the connection of the vapour pipe or the gas discharge piping to the shore installation shall be such that the vessel is protected against detonations and the passage of flames from the shore. The protection of the vessel against detonations and the passage of flames from the shore is not required when the cargo tanks are inerted in accordance with 7.2.4.19. The bulwark ports, openings in the foot rail, etc., shall not be capable of being closed off.

If supervision is required in column (20) of Table C of Chapter 3.2 for substances of Classes 2 or 6.1, loading and unloading shall be carried out under the supervision of a person who is not a member of the crew and has been mandated for the task by the consignor or the consignee. The initial cargo throughput established in the loading instructions shall be such as to ensure that no electrostatic charge exists at the start of loading. Closing of windows and doors During loading, unloading and gas-freeing operations, all entrances or openings of spaces which are accessible from the deck and all openings of spaces facing the outside shall remain closed. This provision does not apply to: air intakes of running engines; -

ventilation inlets of engine rooms while the engines are running;

-

air intakes of the overpressure ventilation system referred to in 9.3.1.52.3 (b), 9.3.2.52.3 (b) or 9.3.3.52.3 (b);

-

air intakes of air conditioning in installations if these openings are fitted with a gas detection system referred to in 9.3.1S2.3. (b), 9.3.2.52.3 (b) or 9.3.3S2.3 (b).

These entrances and openings may only be opened when necessary and for a short time, after the master has given his permission. After the loading, unloading and gas-freeing operations, the spaces which are accessible from the deck shall be ventilated. The provisions of 7.2.4.17.1 and 7.2.4.17.2 above shall not apply to the reception of oily and greasy wastes resulting from the operation of vessels nor to the handing over of products for the operation of vessels. Monitoring of gaseous phases in cargo tanks and adjacent empty spaces For the gaseous phases of tanks, inerting or blanketing may be necessary. These are defined as follows: -

inerting: cargo tanks and their piping and other spaces for which this process is prescribed are filled with gases or vapours which prevent combustion, do not react with the cargo and maintain this state;

-

blanketing: cargo tanks and their piping are filled with a liquid, gas or vapour which separates the cargo from the air and maintains this situation.

For certain substances the requirements for the monitoring of the gaseous phases in cargo tanks and in adjacent empty spaces are given in column (20) of Table C of Chapter 3.2.

When anti-explosion protection is required in colttmn (l 7) of Table C of Chapter 3.2, cargo tanks and their piping shall be purged in an appropriate form of any air that may be present using inert gas and maintained in an air-free state.

7.2.4.1 8.4

Inerting or blanketing of flammable cargoes shall be carried out in such a way as to reduce the electrostatic charge as far as possible when the inerting agent is added.

7.2.4.19

Inerting of tank vessels The cargo tanks of a closed tank vessel, loaded or empty, which have not been cleaned of substances for which the use of a closed tank vessel of type C or type N with anti-explosion protection is prescribed in columns (6) and (7) of Table C of Chapter 3.2 shall be inerted in accordance with 7.2.4.18. The inerting shall be performed so as to ensure that the oxygen content is less than 8% in volume. Inerting is not prescribed when the tank vessel is in conformity with 9.3.2.22.5 or 9.3.3.22.5.

7.2.4.20

(Reserved).

7.2.4.21

Filling of cargo tanks

7.2.4.2 1.1

The degree of filling given in column (11) of Table C of Chapter 3.2 or calculated in accordance with 7.2.4.21.3 below shall not be exceeded.

7.2.4.21.2

The provisions of 7.2.4.2 1.1 above do not apply to cargo tanks the contents of which are maintained at the filling temperature during carriage by means of heating equipment. In this case calculation of the degree of filling at the beginning of carriage and control of the temperature shall be such that, during carriage, the maximum allowable degree of filling is not exceeded.

7.2.4.21.3

For carriage of substances having a relative density higher than that stated in the certificate of approval, the degree of filling shall be calculated in accordance with the following formula. a Permitted degree of filling (%) = - X 100 b a = relative density stated in the certificate of approval b = relative density of the substance. The degree of filling given in column (1 1) of Table C of Chapter 3.2 shall, however, not be exceeded.

7.2.4.21.4

If the degree of filling of 97.5% is exceeded a technical installation shall be authorized to pump off the overflow, During such an operation an automatic visual alarm shall be activated on deck.

7.2.4.22

Opening of openings of cargo tanks

7.2.4.22.1

Opening of cargo tanks apertures shall be permitted only after the tanks have been relived of pressure.

7.2.4.22.2

Opening of sampling outlets and ullage openings and opening of the housing of the flame arrester shall not be permitted except for the purpose of inspecting or cleaning empty cargo tanks. When in column (17) of Table C of Chapter 3.2 anti-explosion protection is required, the opening of cargo tank covers or of the housing of the flame arrester for the purpose of mounting or removing the flame arrester plate stack in unloaded cargo tanks shall be permitted only if the cargo tanks in question have been gas-freed and the concentration of fla~ninablegases in the tanks is less than 10% of the lower explosive limit. - 269 -

7.2.4.22.3

Sampling shall be permitted only if a device prescribed in column (13) of Table C of Chapter 3.2 or a device ensuring a higher level of safety is used. Opening of sampling outlets and ullage openings of cargo tanks loaded with substances for which marking with two blue cones or blue lights is prescribed in column (19) of Table C of Chapter 3.2 shall be permitted only when loading has been interrupted for not less than 10 minutes.

7.2.4.22.4

The sampling receptacles including all accessories such as ropes, etc., shall consist of electrostatically conductive material and shall, during sampling, be electrically connected to the vessel's hull.

7.2.4.22.5

The duration of opening shall be limited to the time necessary for control, cleaning, gauging or sampling.

7.2.4.22.6

Pressure relief of cargo tanks is permitted only when carried out by means of the device for safe pressure relief prescribed in 9.3.2.22.4 (a) or 9.3.3.22.4 (a).

7.2.4.22.7

The provisions of 7.2.4.22.1 to 7.2.4.22.6 above shall not apply to oil separator or supply vessels.

7.2.4.23

(Reserved).

7.2.4.24

Sipnultaneoccs loading and lcnloading

During loading or unloading of cargo tanks, no other cargo shall be loaded or unloaded. The competent authority may grant exceptions during unloading. 7.2.4.25

Cargo piping

7.2.4.25.1

Loading and unloading as well as stripping of cargo tanks shall be carried out by means of the fixed cargo piping of the vessel. The metal fittings of the connections to the shore piping shall be electrically earthed so as to prevent the accumulation of electrostatic charges.

7.2.4.25.2

The cargo piping shall not be extended by rigid or flexible pipes fore or aft beyond the cofferdams. This requirement shall not apply to hoses used for the reception of oily and greasy wastes resulting from the operation of vessels and the delivery of products for the operation of vessels.

7.2.4.25.3

The shut-off devices of the cargo piping shall not be open except as necessary during loading, unloading or gas-freeing operations.

7.2.4.25.4

The liquid remaining in the piping shall be completely drained into the cargo tanks, if possible, or safely removed. This requirement shall not apply to supply vessels.

7.2.4.25.5

The gasiair mixtures shall be returned ashore through a gas recovery or compensation pipe during loading operations when a closed type vessel is required in column (7) of Table C of Chapter 3.2.

When substances of Class 2 are carried the requirements of 7.2.4.25.4 shall be deemed to have been satisfied if the pipes for loading and unloading have been purged with the cargo gas or with nitrogen.

(Resewed).

Water-spraysystem If a water-spray system is required in column (9) of Table C of Chapter 3.2, it shall be kept ready for operation during loading or unloading operations and during the voyage. When water-spraying is required in column (9) of Table C of Chapter 3.2 and the pressure of the gaseous phase in the cargo tanks may reach 80% of the relief pressure of the high velocity vent valves, the master shall take all measures compatible with safety to prevent the pressure from reaching that value. He shall in particular activate the water-spray system. If a water-spray system is required in column (9) of Table C of Chapter 3.2 and remark 23 is indicated in column (20) of Table C of Chapter 3.2, the instrument measuring the internal pressure shall activate an alarm when the internal pressure reaches 40 kPa. The water-spray system shall immediately be activated and remain in operation until the internal pressure drops to 30 kPa.

(Reserved).

Fire-extinguishing arrangements During loading and unloading, the fire extinguishing systems, the hoses and spray nozzles shall be kept ready for operation in the cargo area on deck.

Fire or naked light During loading, unloading or gas-freeing operations fires and naked lights are prohibited on board the vessel. However, the provisions of 7.2.3.42.3 and 7.2.3.42.4 are applicable.

Cargo heating system The maximum allowable temperature for carriage indicated in column (20) of Table C of Chapter 3.2 shall not be exceeded.

(Reserved).

Electrical installations During loading, unloading or gas-freeing operations, only electrical equipment c o n f o ~ n g to the rules for construction in Part 9 or which are installed in spaces complying with the conditions of 9.3.1.52.3, 9.3.2.52.3 or 9.3.3.52.3, may be used. All other electrical equipment marked in red shall be switched off. Electrical equipment which has been switched off by the device referred to in 9.3.1 S2.3 (b), 9.3.2.52.3 (b) or 9.3.3.52.3 (b) shall only be switched on after the gas-free condition has been established in these spaces.

Equipment for electric corrosion protection against external currents shall be disconnected before berthing and may not be re-connected until after the departure of the vessel, at earliest.

Lighting If loading or unloading is performed at night or in conditions of poor visibility, effective lighting shall be provided. If provided from the deck, it shall be effected by properly secured electric lamps which shall be positioned in such a way that they cannot be damaged. Where these lamps are positioned in the cargo area, they shall be of the "certified safe" type.

Special equipment The shower and the eye and face bath prescribed in the rules for construction shall be kept ready in all weather conditions for use during loading and unloading operations and cargo transfer operations by pumping. (Reserved). Prohibition of smoking,fire and naked light The prohibition of smoking does not apply in accommodation or wheelhouses conforming to the provisions of 9.3.1S2.3 (b), 9.3.2.52.3 (b) or 9.3.3 SZ.3 (b). Risk of sparking All electrical connections between the vessel and the shore shall be so designed that they do not present a source of ignition. Synthetic ropes During loading and unloading operations, the vessel may be moored by means of synthetic ropes only when steel cables are used to prevent the vessel from going adrift. Steel cables sheathed in synthetic material or natural fibres are considered as equivalent when the minimum tensile strength required in accordance with the Regulations referred to in 1.1.4.6 is obtained from the steel strands. Oil separator vessels may, however, be moored by means of synthetic ropes during the reception of oily and greasy wastes resulting from the operation of vessels, as may supply vessels during the delivery of products for the operation of vessels.

Additional requirements concerning the operation of vessels

Marking Vessels carrying dangerous goods listed in Table C of Chapter 3.2 shall display the number of blue cones or blue lights indicated in column (19) and in accordance with CEVNI. When because of the cargo carried no marking with blue cones or blue lights is prescribed but the concentration of flammable gases in the cargo tanks is 20% higher than the lower explosion limit, the number of blue cones or blue lights to be carried is determined by the fast cargo for which this marking was required. Where more than one marking could apply to a vessel, only the marking which includes the greatest number of blue cones or blue lights shall apply, i.e. in the following order of precedence:

-

two blue cones or two blue lights; or

-

one blue cone or one blue light.

By derogation from 7.2.5.0.1 above, and in accordance with the footnotes to article 3.14 of the CEVNI, the competent authority of a Contracting Party may authorize seagoing vessels temporarily operating in an inland navigation area on the territory of this Contracting Party, the use of the day and night signals prescribed in the Recommendations on the Safe Transport of Dangerous Cargoes and Related Activities in Port Areas adopted by the Maritime Safety Committee of the International Maritime Organization (by night an all-round fixed red light and by day flag "B" of the International Code of Signals), instead of the signals prescribed in 7.2.5.0.1. The competent authority which has taken the initiative with respect to the derogation granted shall notify the Executive Secretary of the United Nations Economic Commission for Europe, who shall bring this derogation to the attention of the Administrative Committee.

Mode of navigation The competent authorities may impose restrictions on the inclusion of tank vessels in pushed convoys of large dimension.

Mooring Vessels shall be moored securely, but in such as way that electrical power cables and flexible hoses are not subject to tensile strain and the vessels can be released quickly in an emergency.

Berthing The distances from other vessels to be kept by vessels carrying dangerous goods shall be not less than those prescribed by the Regulations referred to in 1.1.4.6. An expert, as required by 7.2.3.15 shall be permanently on board berthed vessels carrying dangerous substances. The competent authority may, however, exempt from this obligation those vessels which are berthed in the harbour basin or in a permitted berthing position. Outside the berthing areas specifically designated by the local competent authority, the distances to be kept by berthed vessels shall not be less than: -

273 -

-

100 m

from residential areas, civil engineering structures or storage tanks, if the vessel is required to be marked with one blue cone or blue light in accordance with column (19) of Table C of Chapter 3.2;

100 m

from civil engineering structures and storage tanks; and 300 m from residential areas if the vessel is required to be marked with two blue cones or two blue lights in accordance with column (19) of Table C of Chapter 3.2.

While waiting in front of locks or bridges, vessels are allowed to keep distances less than those given above. In no case shall the distance be less than 100 m. 7.2.5.4.4

The local competent authority may prescribe distances less than those given in 7.1.5.4.3 above.

7.2.5.8

Reporting duty

7.2.5.8.1

In the States where the reporting duty is in force, the master of a vessel for which marking in accordance with 7.2.5.0 is required shall, prior to the start of any voyage, report the following particulars to the competent authority of the State in which the voyage has started: -

name of the vessel;

-

official number;

-

dead-weight tonnage;

-

description of the dangerous substances carried as given in the transport document (UN number or identification number, proper shipping name, class and, where applicable, packing group andor classification code) together with the quantity in each case;

-

nuxnber of persons on board;

-

port of destination; and

-

planned shipping route.

This reporting duty shall apply in each State territory once to both passages upstream and downstream so far as the competent authorities so require. The information may be given orally (e.g. by radio-telephone, where appropriate by autoxnatic wireless message service) or in writing. 7.2.5.8.2

When passing the other traffic control stations designated by the competent authority, the following particulars shall be reported: name of the vessel; official number; -

7.2.5.8.3

dead-weight tonnage.

Changes to any of the particulars referred to in 7.2.5.8.1 shall be reported to the competent authority without delay.

- 274 -

7.2.5.8.4

The information is confidential and shall not be passed on to third parties by the competent authority. The competent authority may, however, in the event of an accident, inform the emergency services of the relevant particulars required for organizing emergency action.

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PART 8 Provisions for vessel crews, equipment, operation and documentation

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CHAPTER 8.1 GENERAL REQUIREMENTS APPLICABLE TO VESSELS AND EQUIPMENT (Resewe4.

Documents In addition to the documents required by other regulations, the following documents shall be kept on board: The vessel's certificate of approval referred to in 8.1.8; Transport documents referred to in 5.4.1 for all dangerous goods on board and, where necessary the container packing certificate (see 5.4.2); The instructions in writing prescribed in 5.4.3 for all dangerous goods on board; A copy of the ADN with its annexed Regulations which may be a copy which can be consulted by electronic means at any time; The inspection certificate of the insulation resistance of the electrical installations prescribed in 8.1.7; The inspection certificate of the fire-extinguishing equipment and fire-hoses prescribed in 8.1.6. l; A book in which all required measurement results are recorded;

A copy of the relevant text of the special authorizations referred to in 1.5 if the transport operation is performed under thisithese special authorization(s); Means of identification, which include a photograph, for each crew member, in accordance with 1.10.1.4; the checklist or a certificate showing the result of the check drawn up by the competent authority which carried it out, referred to in 1.8.12. This list or certificate shall be kept on board; for the carriage of refrigerated substances, the instruction required in 7.2.3.28; the certificate concerning the refrigeration system, prescribed in 9.3.1.27.10. In addition to the documents prescribed in 8.1.2.1, the following documents shall be carried on board dry cargo vessels: (a)

The loading plan prescribed in 7.1.4.1 1;

(b)

The ADN specialized knowledge certificate prescribed in 8.2.12;

(c)

For vessels which have to conform to the conditions of datnage-control (see 9.1.0.95) -

a damage-control plan;

-

the documents concerning intact stability as well as all conditions of intact stability taken into account for the damaged stability calculation in a form the master understands;

-

the certificate of the classification society (see 9.1 .OM or 9.2.0.88).

In addition to the documents prescribed in 8.1.2.1, the following documents should be carried on board tank vessels: The loading journal prescribed in 7.2.4.1 l;]' The ADN specialized knowledge certificate prescribed in 7.2.3.15; For vessels which have to conform to the conditions of damage-control (see 9.3.1.15 or 9.3.2.15) -

-

a damage-control plan; the documents concerning intact stability as well as all conditions of intact stability taken into account for the damaged stability calculation in a form the master understands;

The documents concerning the electrical installations prescribed in 9.3.1.50, 9.3.2.50 or 9.3.3.50; The classification certificate prescribed in 9.3.1.8, 9.3.2.8 or 9.3.3.8; The flammable gas detector certificate prescribed in 9.3.1.8.3, 9.3.2.8.2 or 9.3.3.8.3; The certificate listing all dangerous goods accepted for carriage in the vessel, referred to in 1.11.1.2.5; The inspection certificate for the pipes for loading and unloading prescribed in 8.1.6.2; The instructions relating to the loading and unloading flows prescribed in 9.3.2.25.9 or 9.3.3.25.9. The inspection certificate for the stripping installation prescribed in 8.6.4.2;11 In the event of the carriage of goods having a melting point 3 0" C, heating instructions; The inspection certificate for the pressure relief and vacuum relief valves prescribed in 8.1.6.5; The registration document referred to in 8.1.1 1. The instructions in writing referred to in 5.4.3 shall be handed to the master before loading. They shall be kept readily at hand in the wheelhouse. On board dry cargo vessels, the transport documents shall be handed to the master before loading and on board tank vessels they shall be handed to him after loading.

1

It is not necessary to apply this subpavagraph . The date of application will be dejned later.

- 280 -

The instructions in writing which are not applicable to the dangerous goods on board the vessel shall be kept separate from those which are applicable so as to avoid any confusion. The presence on board of the certificate of approval is not required in the case of pusher barges which are not carrying dangerous goods, provided that the following additional particulars are indicated, in identical lettering, on the metal plate furnished by CEVNI: Number of the certificate of approval: issued by: . .. valid until: ...

...

The barge-owner shall thereafter keep the certificate of approval in his possession. The similarity of the particulars on the plate and those contained in the certificate of approval shall be certified by a competent authority which shall affix its stamp to the plate. The presence on board of the certificate of approval is not required in the case of dry cargo barges or tank barges carrying dangerous goods provided that the metal plate furnished by CEVNI is supplemented by a second metal plate reproducing by photo-optical means a copy of the entire certificate of approval. The barge-owner shall thereafter keep the certificate of approval in his possession. The similarity of the particulars on the metal plate and the certificate of approval shall be certified by an inspection commission which shall affix its stamp to the plate. All documents shall be drawn up in a language the master is able to read and understand and if that language is not English, French or German, in English, French or German unless agreements concluded between the countries concerned in the transport operation provide otherwise. They shall also be drawn up in one of these languages. 8.1.2.1 (b), 8.1.2.1 (g), 8.1.2.4 and 8.1.2.5 do not apply to oil separator vessels or supply vessels. 8.1.2.1 (c) does not apply to oil separator vessels. (Reserved).

Fire-extinguishing arrangements In addition to the fire-extinguishing appliances prescribed in the Regulations referred to in 1.1.4.6, each vessel shall be equipped with at least two additional hand fire-extinguishers having the same capacity. The fire-extinguishing agent contained in these additional hand fire-extinguishers shall be suitable and sufficient in quantity for fighting fires involving the dangerous goods carried.

Special equipment Insofar as the provisions of Chapter 3.2, Tables A or C require, the following equipment shall be available on board:

PP:

for each member of the crew, a pair of protective goggles, a pair of protective gloves, a protective suit and a suitable pair of protective shoes (or protective boots, if necessary). On board tank vessels, protective boots are required in all cases;

EP:

a suitable escape device for each person on board;

EX: a flammable gas detector with the instructions for its use;

- 281 -

TOX: a toximeter with the instructions for its use; A:

a breathing apparatus ambient air-dependent;

Materials and special additional protective equipment specified by the consignor in the instructions in writing shall be provided by the consignor or by the filler of cargo tanks or holds. This requirement is not applicable when, in a transport chain the instructions in writing for carriage by road or the corresponding copies of the IMDG Code Ems safety data sheets are used in accordance with 1.1.4.2.2 and the materials and additional protective equipment expressly refer to a transport mode other than inland navigation. For pushed convoys or side-by-side formations under way, it shall be sufficient, however, if the pusher tug or the vessel propelling the fornation is equipped with the special equipment referred to in 8.1.5.1 above, when this is required in Chapter 3.2, Tables A or C.

Checking and inspection of equipment The fire-extinguishing appliances and hoses shall be inspected at least once every two years by persons authorized for this purpose by the competent authority. Proof of inspection shall be affixed to the fire-extinguishing appliances. A certificate concerning this inspection shall be carried on board. Hoses and hose assemblies used for loading, unloading or delivering products shall comply with European standard EN 12115:1999 (Rubber and thermoplastics hoses and hose assemblies) or EN 13765:2003 (Thermoplastic multilayer (non-vulcanized) hoses and hose assemblies) or EN IS0 10380:2003 (Corrugated metal hoses and hose assemblies). They shall be checked and inspected in accordance with table 6 of standard EN 12115:1999 or table K.1 of standard EN 13765:2003 or paragraph 7 of standard EN I S 0 10380:2003 at least once a year, according to the manufacturer's instructions, by persons authorized for this purpose by the competent authority. A certificate concerning this inspection shall be carried on board. The special equipment referred to in 8.1.5.1 and the gas detection system shall be checked and inspected in accordance with the instructions of the manufacturer concerned by persons authorized for this purpose or by the competent authority. A certificate concerning this inspection shall be carried on board. The measuring instruments prescribed in 8.1.5.1 shall be checked each time before use by the user in accordance with the instructions for use. The pressure relief and vacuum relief valves prescribed in 9.3.1.22, 9.3.2.22, 9.3.2.26.4, 9.3.3.22 and 9.3.3.26.4 shall be inspected on each renewal of the certificate of approval by the manufacturer or by a firm approved by the manufacturer. A certificate concerning this inspection shall be carried on board. The stripping system referred to in 9.3.2.25.10 or 9.3.3.25.10 shall be subjected to a water test before its first use or after a modification. The test and the establishment of the residual quantities shall be carried out in accordance with the provisions of 8.6.4.2. The certificate concerning the test referred to in 8.6.4.3 shall be carried on board.

Electrical installations

The insulation resistance of the electrical installations, the earthing and the certified safe type electrical equipment and the conformity of the documents required in 9.3.1SO.1, 9.3.2.50.1 or 9.3.3.50.1 with the circumstances on board shall be inspected whenever the certificate of approval is renewed and, in addition, within the third year from the date of issue of the certificate of approval by a person authorized for this purpose by the competent authority. An appropriate inspection certificate shall be kept on board. Certificate of approval Dry cargo vessels carrying dangerous goods in quantities greater than exempted quantities, the vessels referred to in 7.1.2.19.1, tank vessels carrying dangerous goods and the vessels referred to in 7.2.2.19.3 shall be provided with an appropriate certificate of approval.

The certificate of approval shall attest that the vessel has been inspected and that its construction and equipment comply with the requirements of these Regulations. The certificate of approval shall be issued in accordance with the requirements and procedures set out in Chapter 1.16. It shall conform to the model in 8.6.1.1 or 8.6.1.3. For tank vessels, the relief pressure of the safety valves or of the high-velocity vent valves shall be entered in the certificate of approval.

If a vessel has cargo tanks with different valve opening pressures, the opening pressure of each tank shall be entered in the certificate of approval. NOTE: For procedures concerning: -

the issue of certijicates: see 1.16.2,

-

the applicationfor issue of certzjicates: see 1.16.5;

-

the amendments to be made to the certijicabe of approval: see 1.16.6;

-

the presentation of the vessel for inspection: see I. 16.7;

-

theJirst inspection (ifthe vessel does not yet have the certzjicate of approval or if the validity of the certzjicate of approval expired more than six months ago): see 1.16.8;

-

the special inspection (f the vessel's hull or equipment has undergone alterations liable to diminish safety in respect of the carriage of dangerous goods or has sustained damage affecting such safety): see 1.16.9;

-

the periodic inspectionfor the renewal of the certificate o f approval: see 1.16.10;

-

the extension of the certificate of approval without an inspection: see 1. l 6.11;

-

the right of qfJieial inspection by the competent authority of a Contracting Party: see 1.16.12;

-

the withholding and return of the certzjkate of approval: see 1.16.13;

-

the issue of a duplicate copy: see 1.16.14;

- 283 -

The certificate of approval shall be valid for not more than five years. The date on which the period of validity expires shall be shown on the certificate. The competent authority which issued the certificate may, without inspection of the vessel, extend the validity of the certificate by not more than one year. Such extension may be granted only once within two periods of validity (see 1.16.11). If the vessel's hull or equipment has undergone alterations liable to reduce the safety as regards the carriage of dangerous goods or has sustained damage affecting such safety, the vessel shall undergo a further inspection in (see 1.16.9). The certificate of approval may be withdrawn if the vessel is not properly maintained or if the vessel's construction or equipment no longer complies with the applicable provisions of these Regulations (see 1.16.13). The certificate of approval may only be withdrawn by the authority by which it has been issued. Nevertheless, in the cases referred to in 8.1.8.5 and 8.1.8.6 above, the competent authority of the State in which the vessel is staying may prohibit its use for the carriage of those dangerous goods for which the certificate is required. For this purpose it may withdraw the certificate until such time as the vessel again complies with the applicable provisions of these Regulations. In that case it shall notify the competent authority which issued the certificate. Notwithstanding 8.1.8.7 above, any competent authority may amend or withdraw the certificate of approval at the request of the vessel's owner, provided that it so notifies the competent authority which issued the certificate.

Provisional certificate of approval NOTE: For procedures concerning the issue o f certificates, see Chapter 1.16. For a vessel which is not provided with a certificate of approval, a provisional certificate of approval of limited duration may be issued in the following cases, subject to the following conditions: (a)

The vessel complies with the applicable provisions of these Regulations, but the normal certificate of approval could not be issued in time. The provisional certificate of approval shall be valid for an appropriate period but not exceeding three months;

(b)

The vessel does not comply with every applicable provisions of these Regulations after sustaining damage. In this case the provisional certificate of approval shall be valid only for a single specified voyage and for a specified cargo. The competent authority may impose additional conditions.

The provisional certificate of approval shall conform to the model in 8.6.1.2 or 8.6.1.4 of these Regulations or a single model certificate combining a provisional certificate of inspection and the provisional certificate of approval provided that the single model certificate contains the same information as 8.6.1.2 or 8.6.1.4 and is approved by the competent authority.

Loading journal

All tank vessels shall be provided with a loading journal in accordance with the provisions of the CEVNI. The original of the loading journal shall be kept on board for not less than 12 months after the last entry is made. The first loading journal shall be issued by the authority which issued the certificate of approval. Subsequent journals may be issued by authorities competent to do so.l1

Register of operations relating to the carriage of UN 1203 Tank vessels accepted for the carriage of UN No. 1203 petrol shall have on board a register of operations during the voyage. This register may consist of other documents containing the information required. This register or these other documents shall be kept on board for not less than three months and cover at least the last three cargoes.

*

- 285 It is not necessary to amly this subparagi-apbz. The date ofapplicafion will be defined Eater.

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CHAPTER 8.2 mQUIREMENTS CONCERNING TRAINING

General requirements concerning training of experts An expert shall not be less than 18 years of age. An expert is a person who has a special knowledge of the ADN. Proof of this knowledge shall be furnished by means of a certificate from a competent authority or from an agency recognized by the competent authority. This certificate shall be issued to persons who, after training, have passed a qualifying ADN examination. The experts referred to in 8.2.1.2 shall take part in a basic training course. Training shall take place in the context of classes approved by the competent authority. The primordial objective of the training is to make the experts aware of the hazards of the carriage of dangerous goods and provide them with the necessary basic knowledge to reduce the dangers of an incident to a minimum, to enable them to take the necessary measures to ensure their own safety, general safety and the protection of the environment and to limit the consequences of the incident. This training, which shall include individual practical exercises, takes the form of a basic course; it shall cover at least the objectives referred to in 8.2.2.3.1.1 and in 8.2.2.3.1.2 or 8.2.2.3.1.3. Experts for the carriage of gases shall take part in an advanced course covering at least the objectives referred to in 8.2.2.3.3.1. Training shall take place in the context of classes approved by the competent authority. An expert certificate shall be issued to persons who, after training, have successfully passed an examination concerning the carriage of gases and have produced evidence of not less than one year's work on board a type G vessel during a period of two years prior to or following the examination. Experts for the carriage of chemicals shall take part in an advanced course covering at least the objectives referred to in 8.2.2.3.3.2. Training shall take place in the context of classes approved by the competent authority. An expert certificate shall be issued to persons who, after training, have successfully passed an examination concerning the carriage of chemicals and have produced evidence of not less than one year's work on board a type C vessel during a period of two years prior to or following the examination. After five years the expert shall furnish proof, in the form of relevant particulars entered in the certificate by the competent authority or by a body recognized by it, of participation in a refresher or advanced course taken in the last year prior to the expiry of the certificate, covering at least the objectives referred to in 8.2.2.3.1.1 and in 8.2.2.3.1.2 or 8.2.2.3.1.3 and comprising current new developments in particular. The new period of invalidity shall begin on the expiry date of the certificate; in other cases it shall begin on the date of the certificate of participation in the course. After five years, the expert for the carriage of gases shall furnish proof, in the form of relevant particulars entered in the certificate by the competent authority or by a body recognized by it, -

that during the year preceding the expiry of the certificate, he has participated in a refresher or advanced course covering at least the objectives referred to in 8.2.2.3.3.1 and comprising current new developments in particular, or

-

that during the previous two years he has performed a period of work of not less than one year on board a type G tank vessel.

When the refresher or advanced training course is taken in the year preceding the date of expiry of the certificate, the new period of validity shall begin on the expiry date of the preceding certificate, but in other cases it shall begin on the date of certification of participation in the course. After five years, the expert for the carriage of chemicals shall hrnish proof, in the form of relevant particulars entered in the certificate by the competent authority or by a body recognized by it, -

that during the year preceding the expiry of the certificate, he has participated in a refresher or advanced course covering at least the objectives referred to in 8.2.2.3.3.2 and comprising current new developments in particular, or

-

that during the previous two years he had performed a period of work of not less than one year on board a type C tank vessel.

When the refresher or advanced training course is taken in the year preceding the date of expiry of the certificate, the new period of validity shall begin on the expiry date of the preceding certificate, but in other cases it shall begin on the date of certification of participation in the course. The document attesting training and experience in accordance with the requirements of Chapter V of the STCW Code on Training and Qualifications of Masters, Officers and Ratings of Tankers carrying LPGLNG shall be equivalent to the certificate referred to in 8.2.1.4, provided it has been recognized by a competent authority. No more than five years shall have passed since the date of issue or renewal of such a document. 8.2.1.10

The document attesting training and experience in accordance with Chapter V of the STCW Code for officers concerning personnel in charge of cargo on tank vessels carrying chemicals in bulk shall be equivalent to the certificate referred to in 8.2.1.5, provided it has been recognized by a competent authority. No more than five years shall have passed since the date of issue or renewal of such a document.

8.2.1.11

The certificate shall conform to the model in 8.6.2

8.2.2

Special requirements for the training of experts

8.2.2.1

Theoretical knowledge and practical abilities shall be acquired as a result of training in theory and practical exercises. The theoretical knowledge shall be tested by an examination. During the refresher and advanced courses exercises and tests shall ensure that the participant takes an active role in the training. The training organizer shall ensure that participants have a good knowledge of the subject and shall take into account the latest developments concerning the Regulations and the requirements for training in the transport of dangerous goods. Teaching shall relate closely to practice. In accordance with the approval, the teaching syllabus shall be drawn up on the basis of the objectives referred to in 8.2.2.3.1.1 to 8.2.2.3.1.3 and in 8.2.2.3.3.1 or 8.2.2.3.3.2. Basic training and the refresher and advanced courses shall comprise individual practical exercises (see 8.2.2.3.1.1).

Organization oftrai~ing Basic training and the refresher and advanced courses shall be organized in the context of basic courses (see 8.2.2.3.1) and if necessary specialization courses (see 8.2.2.3.3). The courses referred to in 8.2.2.3.1 may comprise three variants: transport of dry cargo, transport in tank vessels and combined transport of dry cargo and transport in tank vessels. 8.2.2.3.1

Basic course Basic course on the transport of dry cargo Prior training: Knowledge: Authorized for: Training:

none ADN in general, except Chapter 3.2, Table C, Chapters 7.2 and 9.3 dry cargo vessel general 8.2.2.3.1.1 and dry cargo vessels 8.2.2.3.1.2

Basic course on transport by tank vessels Prior training: Knowledge: Authorized for: Training:

none ADN in general, except Chapter 3.2, Tables A and B, Chapters 7.1, 9.1, 9.2 and sections 9.3.1 and 9.3.2 tank vessels for the transport of substances for which a type N tank vessel is prescribed general 8.2.2.3.1.1 and tank vessels 8.2.2.3.1.3

Combined basic course on dry cargo and tank vessels Prior training: Knowledge: Authorized for: Training: 8.2.2.3.1.l

none ADN in general, except sections 9.3.1 and 9.3.2 dry cargo vessels and tank vessels for the transport of substances for which a type N tank vessel is prescribed general 8.2.2.3.1.1, dry cargo vessels 8.2.2.3.1.2 and tank vessels 8.2.2.3.1.3

The general part of the basic training course shall comprise at least the following objectives: General:

-

Objectives and structure of ADN.

Construction and equipment: Construction and equipment of vessels subject to ADN. Measurement techniques: Measurements of toxicity, oxygen content, explosivity. Knowledge of products: Classification and hazard characteristics of the dangerous goods. Loading, unloading and transport: Loading, unloading, general service requirements and requirements relating to transport.

Documents:

-

Documents which must be on board during transport.

Hazards and measures of prevention:

-

General safety measures.

Practical exercises: Practical exercises, in particular with respect to entry into spaces, use of fire-extinguishers, fire-fighting equipment and personal protective equipment as well as flammable gas detectors, oxygen meters and toximeters. 8.2.2.3.1.2

The "dry cargo vessels" part of the basic training course shall comprise at least the following objectives: Construction and equipment:

-

Construction and equipment of dry cargo vessels.

Treatment of holds and adjacent spaces: degassing, cleaning, maintenance, ventilation of holds and spaces outside the cargo area. Loading, unloading and transport: loading, unloading, general service and transport requirements, labelling of packages. Documents:

-

documents which must be on board during transport.

Hazards and measures of prevention: general safety measures, personal protective and safety equipment. 8.2.2.3.1.3

The "tank vessel" part of the basic training course shall comprise at least the following objectives: Construction and equipment: construction and equipment of tank vessels, ventilation, loading and unloading systems. Treatment of cargo tanks and adjacent spaces:

-

degassing, cleaning, maintenance, heating and cooling of cargo, handling of residual cargo tanks.

Measurement and sampling techniques: measurements of toxicity, oxygen content and explosivity, sampling. Loading, unloading and transport: loading, unloading, general service and transport requirements. Documents: documents which must be on board during transport. Hazards and measures of prevention:

8.2.2.3.2

prevention and general safety measures, spark formation, personal protective and safety equipment, fires and fire-fighting.

Refresher and advanced training courses Refresher and advanced training course on Pansport ofdry cargo

Prior training: Knowledge: Authorized for: Training:

valid ADN "dry cargo vessels" or combined "dry cargo vessels/tank vessels" certificate ADN in general, except Chapter 3.2, Table C, Chapters 7.2 and 9.3 dry cargo vessel general 8.2.2.3.1.1 and dry cargo vessels 8.2.2.3.1.2

Refresher and amianced training course on PayEsport in tank vessels

Prior training: howledge: Authorized for: Training:

valid ADN "tank vessels" or combined "dry cargo vessels/tank vessels" certificate ADN in general, except Chapter 3.2, Tables A and B, Chapters 7.1, 9.1 and 9.2 and sections 9.3.1 and 9.3.2 tank vessels for the transport of substances for which a type N tank vessel is prescribed general 8.2.2.3.1.1 and tank vessels 8.2.2.3.1.3

Refresher and advanced training course on combined transport in "dry cargo vessels/tank vessels "

Prior training: Knowledge: Authorized for: Training: 8.2.2.3.3

valid ADN combined "dry cargo vessels and tank vesse1s"certificate ADN in general, including sections 9.3.1 and 9.3.2 dry cargo vessels and tank vessels for the transport of substances for which a type N tank vessel is prescribed general 8.2.2.3.1.1, dry cargo vessels 8.2.2.3.1.2 and tank vessels 8.2.2.3.1.3

Specialization courses Specialization course on gases

Prior training:

valid ADN "tank vessels" or combined "dry cargo vesselsltank vessels" certificate

- 291 -

Knowledge: Authorized for:

Training:

ADN, in particular knowledge relating to loading, transport, unloading and handling of gases tank vessels for the transport of substances for which a type G tank vessel is required and transport in type G of substances for which a type C is required in cargo tank type l in column (7) of Table C of Chapter 3.2 gases 8.2.2.3.3.1

Specialization course on chemicals Prior training: Knowledge: Authorized for: Training: 8.2.2.3.3.1

valid ADN "tank vessels" or combined "dry cargo vessels/tank vessels" certificate ADN, in particular knowledge relating to loading, transport, unloading and handling of chemicals tank vessels for the transport of substances for which a type C tank vessel is required chemicals 8.2.2.3.3.2

The specialization course on gases shall comprise at least the following objectives: Knowledge ofphysics and chemistry:

-

-

laws of gases, e.g. Boyle, Gay-Lussac and fundamental law partial pressures and mixtures, e.g. definitions and simple calculations, pressure increase and gas release from cargo tanks Avogadro's number and calculation of masses of ideal gas and application of the mass formula density and volume of liquids, e.g. density, volume in terms of temperature increase and maximum degree of filling critical pressure and temperature polymerization, e.g. theoretical and practical questions, conditions of carriage vaporization, condensation, e.g. definition, liquid volume and vapour volume ratio mixtures, e.g. vapour pressure, composition and hazard characteristics chemical bonds and formulae.

Practice:

-

-

flushing of cargo tanks, e.g. flushing in the event of a change of cargo, addition of air to the cargo, methods of flushing (degassing) before entering cargo tanks sampling danger of explosion health risks gas concentration measures, e.g. which apparatus to use and how to use it monitoring of closed spaces and entry to these spaces certificates for degassing and permitted work degree of filling and over-filling safety installations pumps and compressors.

Emergencj~measures:

-

physical injury, e.g. liquefied gases on the skin, breathing in gas, assistance irregularities relating to the cargo, e.g. leak in a connection, over-filling, polymerization and hazards in the vicinity of the vessel.

8.2.2.3.3.2

The specialization course on chemicals shall comprise at least the following objectives: Knowledge ofphysics and chemistry: chemical products, e.g. molecules, atoms, physical state, acids, bases, oxidation density, pressure and volume of liquids, e.g. density, volume and pressure in terms of temperature increase, maximum degree of filling critical temperature polymerization, e.g. theoretical and practical questions, conditions of carriage mixtures, e.g. vapour pressure, composition and hazard characteristics chemical bonds and formulae. Practice: cleaning of cargo tanks, e.g. degassing, washing, residues, cargo residues loading and unloading, e.g. vapour pipes systems, rapid closing devices, effects of temperature sampling danger of explosion health risks gas concentration measures, e.g. which apparatus to use and how to use it monitoring of closed spaces and entry to these spaces certificates for degassing and permitted work degree of filling and over-filling safety installations pumps and compressors. Emergency measures: physical injury, e.g. liquefied gases on the skin, breathing in gas, assistance irregularities relating to the cargo, e.g. leak in a connection, over-filling, polymerization and hazards in the vicinity of the vessel. Refresher and advanced training courses Refresher and advanced training course on gases Prior training: Knowledge: Authorization for:

Training:

valid ADN 'gases' and 'tank vessels' certificate or combined 'dry cargo and tank vessels' certificate; ADN, in particular, loading, transport, unloading and handling of gases; tank vessels for the transport of substances for which a type G tank vessel is required and transport in type G of substances for which a type C is required in cargo tank type l in column (7) of Table C of Chapter 3.2; gases 8.2.2.3.3.1.

Refresher and advanced training course on chemicals Prior training: Knowledge: Authorization for: Training:

valid ADN "chemicals" and "tank vessels" certificate or combined "dry cargo and tank vessels" certificate; ADN, in particular, loading, transport, unloading and handling of gases; tank vessels for the transport of substances for which a type C tank vessel is required; chemicals 8.2.2.3.3.2.

Planning of refresher and specialization courses The following minimum periods of training shall be observed: Basic "dry cargo vessels course" Basic "tank vessels" course Basic combined course Specialization course on gases Specialization course on chemicals

24 lessons of 45 minutes each 24 lessons of 45 minutes each 32 lessons of 45 minutes each 16 lessons of 45 minutes each 16 lessons of 45 minutes each

Each day of training may comprise not more than eight lessons. If the theoretical training is by correspondence, equivalences to the above-mentioned lessons shall be determined. Training by correspondence shall be completed within a period of nine months. Approximately 30% of basic training shall be devoted to practical exercises. Practical exercises shall, where possible, be undertaken during the period of theoretical training; in any event, they shall be completed not later than three months following the completion of theoretical training. Planning of refresher and advanced training courses The refresher and advanced training courses shall take place before the expiry of the deadline referred to in 8.2.1.4, 8.2.1.6 or 8.2.1.8. The following minimum periods of training shall be observed: Basic refresher course:

-

dry cargo vessels tank vessels combined dry cargo vessels and tank vessels

16 lessons of 45 minutes each 16 lessons of 45 minutcs each 16 lessons of 45 minutes each

Specialization refresher course on gases

8 lessons of 45 minutes each

Specialization refi-esher course on chemicals

8 lessons of 45 minutes each

Each day of training may comprise not more than eight lessons. Approximately 50% of basic training shall be devoted to practical exercises. Practical exercises shall, where possible, be undertaken during the period of theoretical training; in any event, they shall be completed not later than three months following the completion of theoretical training. 8.2.2.6

Approval of training courses

8.2.2.6.1

Training courses shall be approved by the competent authority.

8.2.2.6.2

Approval shall be granted only on written application.

8.2.2.6.3

Applications for approval shall be accompanied by: (a)

the detailed course curriculum showing the course topics and the length of time to be devoted to them, as well as the teaching methods envisaged;

- 294 -

(b)

the roster of teaching staff, listing their qualifications and the subjects to be taught by each one;

(c)

information on classrooms and teaching materials, as well as on the facilities available for practical exercises;

(d)

enrolment requirements, e.g. the number of participants.

The competent authority shall be responsible for monitoring training courses and examinations. The approval comprises the following conditions, inter alia: (a)

training courses shall conform to the information accompanying the application for approval;

(b)

the competent authority may send inspectors to attend training courses and examinations;

{c)

the timetables for the various training courses shall be notified in advance to the competent authority.

Approval shall be granted in writing. It may be withdrawn in the event of failure to comply with the conditions of approval. The approval document shall indicate whether the course in question is a basic training course, a specialization course or a refresher and advanced training course. If, after approval is granted, the training body wishes to change conditions affecting the approval, he shall seek the prior agreement of the competent authority. This provision shall apply in particular to amendments to syllabuses. Training courses shall take account of the current developments in the various subjects taught. The course organizer shall be responsible for ensuring that recent developments are brought to the attention of, and properly understood by, teachers.

Examinations Busk training courses After initial training, including practical exercises, and ADN basic training examination shall be taken. This examination shall be held either immediately after the training courses or within six months following the completion of such courses. In the examination the candidate shall furnish evidence that, in accordance with the basic training course, he has the knowledge, understanding and capabilities required of an expert on board a vessel. The Administrative Committee shall establish a list of questions comprising the objectives set out in 8.2.2.3.1.1 to 8.2.2.3.1.3. The examination questions shall be selected from this list. The candidate shall not have advance knowledge of the questions selected. The model attached to the list of questions is to be used to compile the examination questions.

8.2.2.7.1.5

The examination shall be written. Candidates shall be asked 30 questions. The examination shall last 60 minutes. It is deemed to have been passed if at least 25 of the 30 questions have been answered correctly. During the examination, candidates may consult the texts of regulations on dangerous goods and CEVNI.

8.2.2.7.2

Specialization course on gases and chemicals

8.2.2.7.2.1

Candidates who are successful in the ADN basic training examination may apply for enrolment in a "gases" andor "chemicals" specialization course, to be followed by an examination. The examination shall be based on the Administrative ~ommittee's' list of questions.

8.2.2.7.2.2

During the examination the candidate shall furnish proof that, in accordance with the "gases" andlor "chemicals" specialization course, he has the knowledge, understanding and capabilities required of the expert on board vessels carrying gases or chemicals, respectively.

8.2.2.7.2.3

The Administrative Committee shall prepare a list of questions for the examination, comprising the objectives set out in 8.2.2.3.3.1 or 8.2.2.3.3.2. The examination questions shall be selected from the list. The candidate shall not have advance knowledge of the questions selected.

8.2.2.7.2.4

In the event of multiple training courses a single examination may be organized.

8.2.2.7.2.5

The examination shall be written. The candidate is to be asked 30 multiple-choice questions and one substantive question. The examination shall last a total of 120 minutes, of which 60 minutes for the multiple-choice questions and 60 minutes for the substantive question. The examination shall be marked out of a total of 60, of which 30 marks will go to the multiple-choice questions (one mark per question) and 30 to the substantive question (the distribution of marks is left to the appreciation of the Administrative Committee). A total of 44 marks must be achieved to pass. However, not less than 20 marks must be obtained in each subject. If the candidate obtains 44 but does not achieve 20 in one subject, the subject in question may be set in a resit. The texts of regulations and technical literature are permitted during the examination.

ADN specialized knowledge certificate The issue and renewal of the ADN specialized knowledge certificate confoming to 8.6.2, shall be the responsibility of the competent authority. Certificates shall be issued to: -

candidates who have attended a basic training course and have passed the ADN examination;

-

candidates who have taken part in a refresher or advanced training course.

Before the entry into force of the Agreement, or until the Administrative Committee adopts the list of questions, this list of questions shall be drajled by the competent authori&. i t is recommended that the competent aznthority shozcld use the lists of questions drawn up by the Central Commissionfor the Navigation of the Rhine or the Danube Commission. - 296 -

The validity of the basic training certificate shall be five years as from the date of the examination. The validity of the 'gases' andlor 'chemicals' specialized training certificate shall be brought into line with the validity of the basic training certificate. If the refresher and advanced training course was not fully completed before the expiry of the period of validity of the certificate, a new certificate shall not be issued until the candidate has completed a further initial basic training course and passed an examination referred to in 8.2.2.7 above.

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CHAPTER 8.3 MISCELLANEOUS REQUIREMENTS TO BE COMPLIED WITH BY THE CREW OF THE VESSEL Persons authorized on board Only the following persons are authorized to be on board: (a)

members of the crew;

(b)

persons who, although not being members of the crew, normally live on board; and

(c)

persons who are on board for official reasons.

The persons referred to in 8.3.1 (b) are not authorized to remain in the protected area of dry cargo vessels or in the cargo area of tank vessels except for short periods. When the vessel is required to carry two blue cones or two blue lights in accordance with column (19) of Table C of Chapter 3.2, persons under 14 years of age are not permitted on board.

Portable lamps On board dry cargo vessels, the only portable lamps permitted in the protected area are lamps having their own source of power. On board tank vessels, the only portable lamps permitted in the cargo area are lamps having their own source of power. They shall be of the certified safe type.

Admittance on board No unauthorized person shall be permitted on board. This prohibition shall be displayed on notice boards at appropriate places.

Prohibition on smoking, fire and naked light Smoking on board the vessel is prohibited. This prohibition shall be displayed on notice boards at appropriate places. This prohibition does not apply to the accommodation or the wheelhouse provided their windows, doors, skylights and hatches are closed.

Danger caused by work on board No repair or maintenance work requiring the use of an open flame or electric current or liable to cause sparks may be carried out

-

on board dry cargo vessels in the protected area or on the deck less than 3m forward or aft of that area; on board tank vessels.

This requirement does not apply:

when dry cargo vessels are furnished with an authorization from the competent local authority or a certificate attesting to the totally gas-free condition of the protected area; when tank vessels are krnished with an authorization from the competent local authority or a certificate attesting to the totally gas-free condition of the vessel;

-

to berthing operations.

Such work on board tank vessels may be undertaken without permission in the service spaces outside the cargo area, provided the doors and openings are closed and the vessel is not being loaded, unloaded or gas-freed. The use of chromium vanadium steel screwdrivers and wrenches or screwdrivers and wrenches of equivalent material from the point of view of spark formation is permitted.

CHAPTER 8.4 (Reserved)

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CHAPTER 8.5 (Reserved)

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CHAPTER 8.6 DOCUMENTS 8.6.1

Certificate of approval

8.6.1.1

Model for a certificate of approval for dry cargo vessels

Competent authority: ...................................................................................... Space reserved for the emblem and name of the State

Certificate of approval No.: Name of vessel ................................................................................................................ Official number ................................................................................................................ Type of vessel .................................................................................................................. vessel referred to in 7.1.2.19.1' Additional requirements: vessel referred to in 7.2.2.19.3' The vessel complies with the additional rules of construction referred to in 9.1.O.80 to 9.1.O.95/ 9.2.0.80 to 9.2.0.95 for double hull vessels1 Permitted derogations:

..........................................................................................

......................................................................................................................................... The validity of this certificate of approval expires on ..........................................(date) The previous certificate of approval No. ..............was issued on .................................. by ................................................................................................ (competent authority) The vessel is approved for the carriage of dangerous goods following: - inspection on' ....................................................................................................(date) - certification by a recognized classification society1 Name of the classification society1 .......................................... (date) ......................... Subject to permitted equivalence:I ..............................................................................

........................................................................................................................................ Subject to special authorizations:l ................................................................................. ........................................................................................................................................ Issued at: ........................................................on ...................................................... (place) (date) (Stamp)

.................................................... (competent authority)

.................................................... (signature)

' Delete as appropriate

2

Extension of the validity of the certificate of approval 13.

The validity of this certificate is extended under Chapter 1.l6 of ADN until ................................................... (date)

14.

................................................................................... on .................................................. (place)

(date)

........................................................ 15.

(Stamp)

(competent authority)

(signature)

Model for a provisional certificate of approvalfor dry cargo vessels

8.6.1.2

Competent authority: .................................................................................... Space reserved for the emblem and name of the State

Provisional certificate of approval No: ............................................................. Name of vessel ...................................................................................... Official number ...................................................................................... Type of vessel ....................................................................................... Additional requirements: vessel subject to 7.1 .2.19.11 vessel subject to 7.2.2.19.3' The vessel complies with the additional requirements of 9.1 .O.8O to 9.1 .O.95/9.2.0.80. to 9.2.0.95 for double hull vessels1

Permitted derogations: ......................................................................................................

........................................................................................................................................... ........................................................................................................................................... The provisional certificate of approval is valid1 ............................................... 6.1 until ....................................................................................... 6.2

for a single journey from .................to

.........................................

Issued at ............................................. on .......................................... (place) (date)

............................................. (competent authority)

............................................ (signature)

.........................................................................................................

' Delete as appropriate. NOTE: This model provisional cert~jicateof appvoval m q be replaced by a single certiJicate model combining a provisional certiJicate of inspection and the provisional certiJicate of approval, provided that this single certzjicate model contains the same particulars as the model above and is approved by the competent authorities.

Model for a cerh'flcate of approvalfor tank vessels

8.6.1.3

Competent authority: ................................................................................................................... Space reserved for the emblem and name of the State

Certificate of approval No.: Name of vessel ................................................................................................................. Official number ................................................................................................................ Type of vessel ................................................................................................................... Type of tank vessel ........................................................................................................... 1. Pressure cargo tanks1 Types of cargo tanks 2. Closed cargo tanks1 3. Open cargo tanks with flame arresters1* 4. Open cargo tanks1

Types of cargo tanks

1. 2. 3.

Independent cargo tanks" Integral cargo tanks1 Cargo tank wall distinct from the hull1

Opening pressure of high-velocity vent valveslsafety valves ................................ W P ~ ' Additional equipment:

* o

Sampling device closed .................................................... yeslno1 2 partly closed ........................................ yeslno1 2 sampling opening .................................. yeslno1 2 Water-spray system ..................................... yeslno1 2 Cargo heating system: possibility of cargo heating from shore ..... yeslnol cargo heating installation on board ........... yeslno' Cargo refrigeration system ......................... yeslno1 2 Cargo pump-room below deck ................... yesino1 2 Pressure relief device ................................. yeslno' in .................................... Gas supplylreturn line according to ........... piping and installation heated .................... yes/nol

Electrical equipment: o Temperature class: .................................... * Explosion group: ....................................... Loading rate: .................................................... m 3 h (see loading instructions)

1

Delete as appropriate. If the tanks are not all of the same condition, see page 3. -

308 -

Permitted relative density: ................................................................................................ Additional observations ...........................................................................................

............................................................................................................................................ The validity of this certificate of approval expires on ............................................ (date) The previous certificate of approval No. .................. was issued on ................................ by .................................................................................................. (competent authority) The vessel is approved for the carriage of dangerous goods listed in the attestation attached to this certificate following: inspection on1 (date)............................................................................................. certification by a recognized classification society' Name of the classification society1............................................ (date) ................ Subjected to permitted equivalence:'

............................................................................................................................................ ............................................................................................................................................ Subject to special authorizations:'

............................................................................................................................................. ............................................................................................................................................. Issued at: ..................................................... on ................................................... (place)

(date)

........................................................ (competent authority)

....................................................... (signature) Delete as appropriate

Extension of the validity of the certificate of approval 20.

The validity of this certificate is extended under Chapter 1.16 of ADN Untii ................................................... (date)

21.

............................................................ (place)

22.

(Stamp)

on ......................................................... (date)

......................................................... (competent authority)

........................................................ (signature)

If the cargo tanks of the vessel are not all of the same condition or the equipment is not the same, their condition and their equipment should be indicated below:

8.6.1.4

Model for a certificate of approval for tank vessels

Competent authority: .................................................................................... Space reserved for the emblem and name of the State Provisional certificate of approval No: ............................................................. Name of vessel ...................................................................................... Official number ...................................................................................... Type of vessel ....................................................................................... Type of tank vessel .................................................................

Types of cargo tanks

1. 2. 3.

Independent cargo tanks Integral cargo tanks Cargo tank wall distinct from the hull

Types of cargo tanks

1. 2. 3. 4.

Pressure cargo tanks Closed cargo tanks Open cargo tanks with flame arresters Open cargo tanks

Opening pressure of high-velocity vent valves/safety valves ...........kPa Additional equipment: Sampling device closed .................................................. partly closed .......................................... sampling opening .................................... * Water-spray system ....................................... Cargo heating system: possibility of cargo heating from shore .......... cargo heating installation on board ............... cargo refrigeration system ............................. cargo pump-room below deck .......................... Electrical equipment: Temperature class: ....................................... e Explosion group: ......................................... Loading rate ...................................................

m?h

Permitted relative density: ......................................................................... Additionnal observations: ................................................................................

......................................................................................................... L

"f

Delete as appropriate. the tanks are not all of the same type, see page 3

13.

13.1

certificate of approval is valid' ............................................... until .......................................................................................

13.2

for a single jouney from .................to ..........................................

ÿ he provisional

14.

Issued at ............................................. on .......................................... (place) (date)

15.

(Stamp)

............................................. (competent authority)

............................................ (signature) 1

Delete as appropriate.

NOTE: This model provisional certificate of approval may be replaced by a single certificate model combining a provisional certificate of inspection and the provisional certzjicate of approval, provided that this single certzjicate model contains the same particulars as the model above and is approved by the competent authorities.

3 If the cargo tanks of the vessel are not all of the same condition or the equipment is not the same. their condition and their equipment should be indicated below: Cargo tank number pressure cargo tank closed cargo tank open cargo tank with flame arrester open cargo tank

water-spray system internal pressure alarm 40 kPa ........ possibility of cargo heating from shore cargo heating installation cargo refrigeration installation gas supplylretum line according to 9.3.2.22.5 gas supply line and heated installation

1

2

3

4

5

6

7

8

9

Certificate of special knowledge of ADN according to 8.2.1.2,8.2.1.4 or 8.2.1.5

8.6.2

(Format: A6, Colour: orange) No. of certificate: (Space reserved for the emblem of State, competent authority)

.......................................

Name First name(s): ............................................ Born on: .................................................

ADN certificate of special knowledge of ADN

Nationality: ............................................. Signature of holder: ................................... The holder of this certificate has special knowledge of ADN The certificate is valid for special knowledge ofADN according to 8.2.1.2 (dry cargo vessels)" 8.2.1.2 (tanks vessels)* 8.2.l.4* 8.2.1.5" until: ...................................................... Issued by: ................................................ Date: ......................................................

Signature: .......................................

* (Recto)

Delete as appropriate. ( Verso)

Checklist ADN

8.6.3

1

Checklist ADN

concerning the observance of safety provisions and the implementation of the necessary measures for 1oadingJunloading

Particulars of vessel

.................................................. (name of vessel)

No. ...................... (official number)

.................................................. (vessel type)

Particulars of loading or unloading operations

...................................................

...a.......................

(shore loading or unloading installation)

(place)

(date)

(time)

Particulai of the cargo Name of product

Quantity m3

Identification number

Class

...............

-

............... ...............

l

Particulars of last cargo* Name of product

*

To be-filled in on& if vessel is to be loaded.

Identification number

Class

Loading rate (not to be filled in if vessel is to be loaded with gas) Name of substance Cargo tank agreed rate of loadin~/unloa~1g number start half wav rate quantity m31h m3

end

........ ........

........ I I y ; Will the cargo piping be drained afte loading or unloading quantities to the shore installatiodto the vessel?*

stripping or by blow

residual

by blowing* by stripping* If drained by blowing, how?

.................................................................................................................. (e.g. air, inert gas, sleeve)

........................................ kPa (permissible maximum pressure in the cargo tank)

........................................litres (estimated residual quantity) Questions to the master or the person mandated by him and the person in charge at the loadinglunloading place Loadinglunloading may only be started after all questions on the checklist have been checked off by "X", i.e. answered with YES and the list has been signed by both persons. Non-applicable questions have to be deleted. If not all questions can be answered with YES, loadinglunloading is only allowed with consent of the competent authority.

* Delete as appropviate.

vessel

1. 2.

Is the vessel permitted to carry this cargo? Did the master or the person mandated by him receive the instructions

3.

Is the vessel well moored in view of local circumstances? Have suitable means been provided at the fore and at the aft of the vessel, for boarding or leaving, including in cases of emergency? Are the escape routes and the loadinglunloading place adequately lighted? Vessellshore connection

m 4. 5.

6.

6.1

Are the cargo hoses between vessel and shore in satisfactory condition? Are these hoses correctly connected?

6.2

Are all the connecting flanges fitted with suitable gaskets?

6.3

Are all the connecting bolts fitted and tightened?

Are the shoreside loading arms free to move in all directions and do the hoses have enough room for easy movement? Are all flanges of the connections of the pipes for loading and unloading and of the vapour pipe not in use, correctly blanked off? Are suitable means of collecting leakages placed under the pipe connections which are in use? Are the movable connecting pieces between the ballast and bilge piping on the one hand and the pipes for loading and unloading on the other hand disconnected? Is continuous and suitable supervision of loadinglunloading ensured for the whole period of the operation? Is coinmunication between vessel and shore ensured? 6.4

7. 8. 9.

10.

It.

3 loading1 unloading place 0"

vessel

For the loading of the vessel, is the vapour pipe, where required, or if it exists, connected with the shore gas return line? Is it ensured that the shore installation is such that the pressure at the connecting point cannot exceed the opening pressure of the high-velocity vent valves'? When anti-explosion protection is required in Chapter 3.2,Table C, column (1 7) does the shore installation ensure that its venting pipe or pressure compensation pipe is such that the vessel is protected against detonations and flame fronts from the shore. Is it know what actions are to be taken in the event of an "Emergency-stop" and an "Alarm"? Check on the most important operational requirements: -

Are the required fire extinguishing systems and appliances operational?

- Have all valves and other closing devices been checked for correct open - or closed position? - Has smoking been generally prohibited? -

Are the flame-operated heating, cooking and cooling applications on board turned off?

-

Are the liquefied gas installations shut off at the main check valve?

- Is the voltage cut off from the radar installations? - Is all electrical equipment marked red switched off? Are all windows and doors closed? Has the starting working pressure of the vessels cargo discharge pump been adjusted to the permissible working pressure of the shore installation? Has the starting working pressure of the shore pump been adjusted to the permissible working pressure of the on board installation? Is the liquid level alarm-installation operational? Is the level control device activating the overflow prevention system plugged in, in working order and tested? -

4 Ioadingi unloading place 0

0" 0

vessel

18.

loadingl unloading place

To be filled in only in the case of loading or unloading of substances for the carriage of which a vessel of the closed type or a vessel of the open type with flame arrester is required.

Are the cargo tank hatches and cargo tank inspection, gauging and sampling openings closed or protected by flame arresters in good condition? Checke filled in and signed

-

for the vessel:

for the installation of loading and unloading

.........................................................

....................................................

name (in capital letters)

......................................................... (signature)

name (in capital letters)

...................................................... (signature)

Explanation Question 3 "Well moored" means that the vessel is fastened to the pier or the cargo transfer station in such a way that, without intervention of a third person, movements of the vessel in any direction that could hamper the operation of the cargo transfer gear will be prevented. Established or predictable variations of the water-level at that location and special factors have to be taken into account.

Question 4 It must be possible to board or escape from the vessel at any time. If there is none or only one protected escape route available at the shoreside for a quick escape from the vessel in case of emergency, a suitable means of escape has to be provided on the vessel side (e.g. a lowered dinghy).

Question 6 A valid inspection certificate for the loadingiunloading hoses must be available on board. The material of the hoses must be able to withstand the expected loads and be suitable for cargo transfer of the respective substances. The term cargo hoses includes hoses as well as the shoreside loadingldischarging arms. The cargo transfer hoses between vessel and shore must be placed so that they cannot be damaged by variations of the water-level, passing vessels andor loadinglunloading operations. All flange con~lections are to be fitted with appropriate gaskets and sufficient bolt connections in order to exclude the possibility of leakage.

Question 10 Loadinghnloading must be supervised on board and ashore so that dangers which may occur in the vicinity of cargo hoses can be recognized immediately. When supervision is effected by additional technical means it must be agreed between the shore installation and the vessel how it is to be ensured.

Question 11

For a safe loadingiunloading operation good communications between vessel and shore are required. For this purpose telephone and radio equipment may be used only if of an explosion protected type and located within reach of the supervisor. Question 13

Before the start of the loading/unloading operation the representative of the shore installation and the master or the person mandated by him must agree on the applicable procedure. The specific properties of the substances to be loadedlunloaded have to be taken into account.

Discharge of residual quantities and stripping systems Device for the discharge of residual quantities

vessel' s side Connection for the discharge of residual quantities Connection of the shore installation intended for blowing residual quantities to the short installation by means of a gas

8.6.4.2

Test of the stripping system

8.6.4.2.1

Before the start of the test, the cargo tanks and their piping shall be clean. The cargo tanks shall be safe for entry.

8.6.4.2.2

During the test, the trim and list of the vessel shall not exceed normal operating values.

8.6.4.2.3

During the test, a back pressure of not less than 300 kPa (3 bar) shall be maintained at the device for discharge of residual quantities fitted on the pipe for unloading.

8.6.4.2.4

The test shall comprise (a)

The filling of the cargo tank with water until the suction intake inside the tank is submerged;

(b)

The pumping out of the water and the emptying of the cargo tank and the corresponding piping by means of the tank's stripping system;

(c)

The collection of the remaining water at the following points: -

The cargo tank suction intake;

-

The bottom of the cargo tank where water has collected;

-

The lowest point drain of the cargo pump;

-

At all the lowest points of the piping associated with the cargo tank up to the device for the discharge of residual quantities.

8.6.4.2.5

The quantity of water collected as described in 8.6.4.2.4 (c) shall be measured precisely and noted in the test certificate referred to in 8.6.4.3.

8.6.4.2.6

The competent authority or the recognized classification society shall set out all the operations required for the test in the test certificate. This certificate shall include at least the following data: -

trim of the vessel during the test;

-

list of the vessel during the test;

-

tank unloading order;

-

back pressure at the device for the discharge of residual quantities;

-

residual quantity per tank;

-

residual quantity per piping system; duration of the stripping operation;

-

cargo tank plan, duly completed.

8.6.4.3

Certificatefor the test of the stripping system

Certificate for the test of the stripping system Name of vessel: .....................................................................................

Official number: .................................................................................... Type of tank vessel: ................................................................................. Number of certificate of approval: ................................................................ Date of test: .......................................................................................... Place of test: ......................................................................................... Number of cargo tanks: ............................................................................ The following residual quantities were measured during the test Tank 1: ............................. ..litres Tank 3: ...............................litres Tank 5: ............................. ..litres Tank 7: ...............................litres Tank 9: ...............................litres Tank 11: ..............................litres Slop tank 1: ..........................litres Slop tank 3: ........................ litres Piping system 1: ....................litres Piping system 2: ....................litres

Tank 2: .......................... ..litres Tank 4: ............................litres Tank 6: .......................... ..litres Tank 8: ........................... .litres Tank 10: .........................litres Tank 12: ...........................litres Slop tank 2 : .....................litres

During the test, the back pressure at the device for the discharge of residual quantities was .............................. ..kPa. The tanks were discharged in the following order: tank.. ., tank ....,

tank.. ., tank ...,

tank.. ., tank.. .,

tank.. ., tank.. .,

tank. .., tank.. .,

During the test, the trim of the vessel was ...................................................... and the list of the vessel was ...................................................................... The total duration of the stripping operation was.. .......................................... h.

............................................................................................. (date)

(signature)

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PART 9 Rules for construction

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CHAPTER 9.1 RULES FOR CONSTRUCTION OF DRY CARGO VESSELS Rules for construction applicable to dry cargo vessels Provisions of 9.1.0.0 to 9.1.0.79 apply to dry cargo vessels. Materials of construction

The vessel's hull shall be constructed of shipbuilding steel or other metal, provided that this metal has at least equivalent mechanical properties and resistance to the effects of temperature and fire. (Reserved).

Holds (a)

Each hold shall be bounded fore and aft by watertight metal bulkheads.

(b)

The holds shall have no common bulkhead with the oil fuel tanks.

The bottom of the holds shall be such as to permit them to be cleaned and dried. The hatchway covers shall be spraytight and weathertight or be covered by waterproof tarpaulins. Tarpaulins used to cover the holds shall not readily ignite. No heating appliances shall be installed in the holds. Ventilation

Ventilation of each hold shall be provided by means of two mutually independent extraction ventilators having a capacity of not less than five changes of air per hour based on the volume of the empty hold. The ventilator fan shall be designed so that no sparks may be emitted on contact of the impeller blades with the housing and no static electricity may be generated. The extraction ducts shall be positioned at the extreme ends of the hold and extend down to not more than 50 mm above the bottom. The extraction of gases and vapours through the duct shall also be ensured for carriage in bulk. If the extraction ducts are movable they shall be suitable for the ventilator assembly and capable of being firmly fixed. Protection shall be ensured against bad weather and spray. The air intake shall be ensured during ventilation. The ventilation system of a hold shall be arranged so that dangerous gases cannot penetrate into the accommodation, wheelhouse or engine rooms. Ventilation shall be provided for the accommodation and for service spaces. (Reserved).

Accommodation and service spaces The accommodation shall be separated from the holds by metal bulkheads having no openings. Gastight closing appliances shall be provided for openings in the accommodation and wheelhouse facing the holds. No entrances or openings of the engine rooms and service spaces shall face the protected area.

(Reserved). Water ballast The double-hull spaces and double bottoms may be arranged for being filled with water ballast.

(Reserved).

Engines Only internal combustion engines running on fuel having a flashpoint above 55 "C are allowed. The air vents in the engine rooms and the air intakes of the engines which do not take air in directly from the engine room shall be located not less than 2.00 m from the protected area. Sparking shall not be possible in the protected area. Oilfuel tanks Double bottoms within the hold area may be arranged as oil fuel tanks provided their depth is not less than 0.6 m. Oil fuel pipes and openings to such tanks are not permitted in the holds. The air pipes of all oil fuel tanks shall be led to 0.50 m above the open deck. Their open ends and the open ends of the overflow pipes leaking to the deck shall be fitted with a protective device consisting of a gauze grid or by a perforated plate.

(Resewed). Exhaust pipes Exhausts shall be evacuated from the vessel into the open air either upwards through an exhaust pipe or through the shell plating. The exhaust outlet shall be located not less than 2.00 m from the hatchway openings. The exhaust pipes of engines shall be arranged so that the exhausts are led away from the vessel. The exhaust pipes shall not be located within the protected area. Exhaust pipes shall be provided with a device preventing the escape of sparks, e.g. spark arresters.

Stripping installation The stripping pumps intended for the holds shall be located in the protected area. This requirement shall not apply when stripping is effected by eductors. (Reserved).

Fire-extinguishing arrangements A fire-extinguishing system shall be installed on the vessel. This system shall comply with the following requirements: -

It shall be supplied by two independent fire or ballast pumps one of which shall be ready for use at any time. These pumps and their means of propulsion and electrical equipment shall not be installed in the same space;

-

It shall be provided with a water main fitted with at least three hydrants in the protected area above deck. Three suitable and sufficiently long hoses with spray nozzles having a diameter of not less than 12 mm shall be provided. It shall be possible to reach any point of the deck in the protected area simultaneously with at least two jets of water which do not emanate from the same hydrant. A spring-loaded non-return valve shall be fitted to ensure that no gases can escape through the fireextinguishing system into the accommodation or service spaces outside the protected area;

-

The capacity of the system shall be at least sufficient for a jet of water to reach a distance of not less than the vessel's breadth from any location on board with two spray nozzles being used at the same time.

A single fire or ballast pump shall suffice on board pushed barges without their own means of propulsion. In addition, the engine rooms shall be provided with a permanently fixed fire-extinguishing system meeting the following requirements: Extinguishing agents For the protection of spaces in engine rooms, boiler rooms and pump rooms, only permanently fixed fire-extinguishing systems using the following extinguishing agents are permitted: (a)

CO2 (carbon dioxide);

(b)

HFC 227 ea (heptafluoropropane);

(c)

IG-541 (52% nitrogen, 40% argon, 8% carbon dioxide).

Other extinguishing agents are permitted only on the basis of recommendations by the Administrative Committee. Ventilation, air extraction (a)

The combustion air required by the combustion engines which ensure propulsion should not come from spaces protected by permanently fixed fire-extinguishing systems. This requirement is not mandatory if the vessel has two independent main

engine rooms with a gastight separation or if, in addition to the main engine room, there is a separate engine room installed with a bow thruster that can independently ensure propulsion in the event of a fire in the main engine room. All forced ventilation systems in the space to be protected shall be shut down automatically as soon as the fire-extinguishing system is activated. All openings in the space to be protected which permit air to enter or gas to escape shall be fitted with devices enabling them to be closed rapidly. It shall be clear whether they are open or closed. Air escaping from the pressure-relief valves of the pressurised air tanks installed in the engine rooms shall be evacuated to the open air. Overpressure or negative pressure caused by the diffusion of the extinguishing agent shall not destroy the constituent elements of the space to be protected. It shall be possible to ensure the safe equalisation of pressure. Protected spaces shall be provided with a means of extracting the extinguishing agent. If extraction devices are installed, it shall not be possible to start them up during extinguishing. 9.1 .O.40.2.3

Fire alarm system The space to be protected shall be monitored by an appropriate fire alarm system. The alarm signal shall be audible in the wheelhouse, the accommodation and the space to be protected.

9.1 .O.40.2.4

9.1.0.40.2.5

Piping system (a)

The extinguishing agent shall be routed to and distributed in the space to be protected by means of a permanent piping system. Piping installed in the space to be protected and the reinforcements it incorporates shall be made of steel. This shall not apply to the connecting nozzles of tanks and compensators provided that the materials used have equivalent fire-retardant properties. Piping shall be protected against corrosion both internally and externally.

(b)

The discharge nozzles shall be so arranged as to ensure the regular diffusion of the extinguishing agent.

Triggering device (a)

Automatically activated fire-extinguishing systems are not permitted.

(b)

It shall be possible to activate the fire-extinguishing system from a suitable point located outside the space to be protected.

(c)

Triggering devices shall be so installed that they can be activated in the event of a fire and so that the risk of their breakdown in the event of a fire or an explosion in the space to be protected is reduced as far as possible. Systems which are not mechanically activated shall be supplied from two energy sources independent of each other. These energy sources shall be located outside the space to be protected. The control lines located in the space to be protected shall be so designed as to remain capable of operating in the event of a fire for a minimum of 30 minutes. The electrical installations are deemed to meet this requirement if they conform to the IEC 6033 1-21:1999 standard.

- 330 -

When the triggering devices are so placed as not to be visible, the component concealing them shall carry the "Fire-fighting system" symbol, each side being not less than 10 cm in length, with the following text in red letters on a white ground:

Fire-extinguishing system (d)

If the fire-extinguishing system is intended to protect several spaces, it shall comprise a separate and clearly-marked triggering device for each space;

(e)

The instructions shall be posted alongside all triggering devices and shall be clearly visible and indelible. The instructions shall be in a language the master can read and understand and if this language is not English, French or German, they shall be in English, French or German. They shall include information concerning:

(Q

9.1.O.40.2.6

(i)

the activation of the fire-extinguishing system;

(ii)

the need to ensure that all persons have left the space to be protected;

(iii)

the correct behaviour of the crew in the event of activation;

(iv)

the correct behaviour of the crew in the event of the failure of the fire-extinguishing system to function properly.

The instructions shall mention that prior to the activation of the fire-extinguishing system, combustion engines installed in the space and aspirating air from the space to be protected, shall be shut down.

Alarm device

Permanently fixed fire-extinguishing systems shall be fitted with an audible and visual alarm device; The alarm device shall be set off automatically as soon as the fire-extinguishing system is first activated. The alarm device shall function for an appropriate period of time before the extinguishing agent is released; it shall not be possible to turn it off; Alarm signals shall be clearly visible in the spaces to be protected and their access points and be clearly audible under operating conditions corresponding to the highest possible sound level. It shall be possible to distinguish them clearly from all other sound and visual signals in the space to be protected; Sound alarms shall also be clearly audible in adjoining spaces, with the communicating doors shut, and under operating conditions corresponding to the highest possible sound level; If the alarm device is not intrinsically protected against short circuits, broken wires and drops in voltage, it shall be possible to monitor its operation; A sign with the following text in red letters on a white ground shall be clearly posted at the entrance to any space the extinguishing agent may reach:

Warning, fire-extinguishing system! Leave this space immediately when the (description) alarm is activated!

...

Pressurised tanks, Jittings and piping (a)

Pressurised tanks, fittings and piping shall conform to the requirements of the competent authority.

(b)

Pressurised tanks shall be installed in accordance with the manufacturer's instructions.

(c)

Pressurised tanks, fittings and piping shall not be installed in the accommodation.

(d)

The temperature of cabinets and storage spaces for pressurised tanks shall not exceed 50 "C.

(e)

Cabinets or storage spaces on deck shall be securely stowed and shall have vents so placed that in the event of a pressurised tank not being gastight, the escaping gas cannot penetrate into the vessel. Direct connections with other spaces are not permitted.

Quantity of extinguishing agent If the quantity of extinguishing agent is intended for more than one space, the quantity of extinguishing agent available does not need to be greater than the quantity required for the largest of the spaces thus protected. Installation, maintenance, monitoring and documents The mounting or modification of the system shall only be performed by a company specialised in fire-extinguishing systems. The instructions (product data sheet, safety data sheet) provided by the manufacturer of the extinguishing agent or the system shall be followed. The system shall be inspected by an expert: (i)

before being brought into service;

(ii)

each time it is put back into service after activation;

(iii)

after every modification or repair;

(iv)

regularly, not less than every two years.

During the inspection, the expert is required to check that the system conforms to the requirements of 9.1.0.40.2. The inspection shall include, as a minimum: (i)

an external inspection of the entire system;

(ii)

an inspection to ensure that the piping is leakproof;

(iii)

an inspection to ensure that the control and activation systems are in good working order;

(iv)

an inspection of the pressure and contents of tanks;

(v)

an inspection to ensure that the means of closing the space to be protected are leakproof;

- 332 -

(vi)

an inspection of the fire alarm system;

(vii) an inspection of the alarm device.

9.1.0.40.2.10

(e)

The person performing the inspection shall establish, sign and date a certificate of inspection.

(Q

The number of permanently fixed fire-extinguishing systems shall be mentioned in the inspection certificate.

Fire-extinguishing system operating with CO2 In addition to the requirements contained in 9.1.0.40.2.1 to 9.1.0.40.2.9, fire-extinguishing systems using CO2 as an extinguishing agent shall conform to the following provisions: Tanks of CO2 shall be placed in a gastight space or cabinet separated from other spaces. The doors of such storage spaces and cabinets shall open outwards; they shall be capable of being locked and shall carry on the outside the symbol "Warning: danger," not less than 5 cm high and "CO2" in the same colours and the same size; Storage cabinets or spaces for CO2 tanks located below deck shall only be accessible from the outside. These spaces shall have an artificial ventilation system with extractor hoods and shall be completely independent of the other ventilation systems on board; The level of filling of C02 tanks shall not exceed 0.75 kg/l. The volume of depressurised CO2 shall be taken to be 0.56 m3/kg; The concentration of C02 in the space to be protected shall be not less than 40% of the gross volume of the space. This quantity shall be released within 120 seconds. It shall be possible to monitor whether diffusion is proceeding correctly; The opening of the tank valves and the control of the diffusing valve shall correspond to two different operations; The appropriate period of time mentioned in 9.1.0.40.2.6 (b) shall be not less than 20 seconds. A reliable installation shall ensure the timing of the diffusion of CO2.

9.1.0.40.2.1 1

Fire-extinguishing system operating with HFC-227 ea (heptafluoropropane) In addition to the requirements of 9.1 .O.40.2.l to 9.1 .O.40.2.9, fire-extinguishing systems using HFC-227 ea as an extinguishing agent shall conform to the following provisions: Where there are several spaces with different gross volumes, each space shall be equipped with its own fire-extinguishing system; Every tank containing HFC-227 ea placed in the space to be protected shall be fitted with a device to prevent overpresswe. This device shall ensure that the contents of the tank are safely diffused in the space to be protected if the tank is subjected to fire, when the fire-extinguishing system has not been brought into service; Every tank shall be fitted with a device permitting control of the gas pressure; The level of filling of tanks shall not exceed 1.15 kg/l. The specific volume of depressurised HFC-227 ea shall be taken to be 0.1374 m3/kg;

The concentration of HFC-227 ea in the space to be protected shall be not less than 8% of the gross volume of the space. This quantity shall be released within 10 seconds; Tanks of HFC-227 ea shall be fitted with a pressure monitoring device which triggers an audible and visual alarm in the wheelhouse in the event of an unscheduled loss of propellant gas. Where there is no wheelhouse, the alarm shall be triggered outside the space to be protected; After discharge, the concentration in the space to be protected shall not exceed 10.5% (volume); The fire-extinguishing system shall not comprise aluminium parts.

Fire-extinguishing system operating with IG-541 In addition to the requirements of 9.1 .0.40.2.l to 9.1 .O.40.2.9, fire-extinguishing systems using IG-541 as an extinguishing agent shall conform to the following provisions: Where there are several spaces with different gross volumes, every space shall be equipped with its own fire-extinguishing system; Every tank containing IG-541 placed in the space to be protected shall be fitted with a device to prevent overpressure. This device shall ensure that the contents of the tank are safely diffused in the space to be protected if the tank is subjected to fire, when the fire-extinguishing system has not been brought into service; Each tank shall be fitted with a device for checking the contents; The filling pressure of the tanks shall not exceed 200 bar at a temperature of + 15 "C; The concentration of IG-541 in the space to be protected shall be not less than 44% and not more than 50% of the gross volume of the space. This quantity shall be released within 120 seconds.

Fire-extinguishing system for physical protection In order to ensure physical protection in the engine rooms, boiler rooms and pump rooms, fire-extinguishing systems are accepted solely on the basis of recommendations by the Administrative Committee. The two hand fire-extinguishers referred to in 8.1.4 shall be located in the protected area. The fire-extinguishing agent in the permanently fixed fire-extinguishing system shall be suitable and sufficient for fighting fires.

Fire and naked light The outlets of funnels shall be located not less than 2 m from the hatchway openings. Arrangements shall be provided to prevent the escape of sparks and the entry of water. Heating, cooking and refrigerating appliances shall not be fuelled with liquid fuels, liquid gas or solid fuels. The installation in the engine room or other separate space of heating appliances fuelled with liquid fuel having a flashpoint above 55 "C is, however, permitted.

Cooking and refrigerating appliances are permitted only in wheelhouses with metal floor and in the accommodation. Electric lighting appliances only are permitted outside the accommodation and the wheelhouse.

(Reserved). Type and location of electrical equipment It shall be possible to isolate the electrical equipment in the protected area by means of centrally located switches except where: -

in the holds it is of a certified safe type corresponding at least to temperature class T4 and explosion group I1 B; and

-

in the protected area on the deck it is of the limited explosion risk type.

The corresponding electrical circuits shall have control lamps to indicate whether or not the circuits are live. The switches shall be protected against unintended unauthorized operation. The sockets used in this area shall be so designed as to prevent connections being made except when they are not live. Submerged pumps installed or used in the holds shall be of the certified safe type at least for temperature class T4 and explosion group I1 B. Electric motors for hold ventilators which are arranged in the air flow shall be of the certified safe type. Sockets for the connection of signal lights and gangway lighting shall be solidly fitted to the vessel close to the signal mast or the gangway. Sockets intended to supply the submerged pumps, hold ventilators and containers shall be permanently fitted to the vessel in the vicinity of the hatches. Accumulators shall be located outside the protected area.

(Reserved). Electric cables Cables and sockets in the protected area shall be protected against mechanical damage. Movable cables are prohibited in the protected area, except for intrinsically safe electric circuits or for the supply of signal lights and gangway lighting, for containers, for submerged pumps, hold ventilators and for electrically operated cover gantries. For movable cables permitted in accordance with 9.1.0.56.2 above, only rubber-sheathed cables of type H07 RN-F in accordance with 245 IEC 66 or cables of at least equivalent design having conductors with a cross-section of not less than 1.5 mm2, shall be used. These cables shall be as short as possible and installed so that damage is not likely to occur.

(Reserved).

Metal wires, masts All metal wires passing over the holds and all masts shall be earthed, unless they are electrically bonded to the metal hull of the vessel through their installation. Admittance on board The notice boards displaying the prohibition of admittance in accordance with 8.3.3 shall be clearly legible from either side of the vessel. (Reserved).

Prohibition of smoking, fire and naked light The notice boards displaying the prohibition of smoking in accordance with 8.3.4 shall be clearly legible from either side of the vessel. Notice boards indicating the circumstances under which the prohibition applies shall be fitted near the entrances to the spaces where smoking or the use of fire or naked light is not always prohibited. Ashtrays shall be provided close to each exit of the accommodation and the wheelhouse. (Reserved).

Additional rules applicable to double-hull vessels The rules of 9.1.0.88 to 9.1.0.99 are applicable to double-hull vessels intended to carry dangerous goods of Classes 2, 3, 4. l , 4.2, 4.3, 5.1, 5.2, 6.1, 7, 8 or 9, except those for which label No. 1 is prescribed in column (5) of Table A of Chapter 3.2, in quantities exceeding those of 7.1.4.1.1. (Reserved). Classification Double-hull vessels intended to carry dangerous goods of Classes 2, 3, 4.1, 4.2,4.3, 5.1, 5.2, 6.1, 7, 8 or 9 except those for which label No. 1 is prescribed in column (5) of Table A of Chapter 3.2, in quantities exceeding those referred to in 7.1.4.1.1 shall be built or transformed under survey of a recognised classification society in accordance with the rules established by this classification society to its highest class. This shall be confirmed by the classification society by the issue of an appropriate certificate. Continuation of class is not required. Future conversions and major repairs to the hull shall be carried out under survey of this classification society. (Reserved).

9.1.0.91

Holds

9.1.0.91.1

The vessel shall be built as a double-hull vessel with double-hull spaces and double bottom within the protected area.

9.1.0.91.2

The distance between the sides of the vessel and the longitudinal bulkheads of the hold shall be not less than 0.80 m. Regardless of the requirements relating to the width of walkways on deck, a reduction of this distance to 0.60 m is permitted, provided that, compared with the scantlings specified in the rules for construction published by a recognised classification society, the following reinforcements have been made: (a)

Where the vessel's sides are constructed according to the longitudinal framing system, the frame spacing shall not exceed 0.60 m. The longitudinals shall be supported by web frames with lightening holes similar to the floors in the double bottom and spaced not more than 1.80 m apart;

(b)

Where the vessel's sides are constructed according to the transverse framing system, either: -

two longitudinal side shell stringers shall be fitted. The distance between the two stringers and between the uppermost stringer and the gangboard shall not exceed 0.80 m. The depth of the stringers shall be at least equal to that of the transverse frames and the cross-section of the face plate shall be not less than 15 cm2. The longitudinal stringers shall be supported by web frames with lightening holes similar to plate floors in the double bottom and spaced not more than 3.60 m apart. The transverse shell frames and the hold bulkhead vertical stiffeners shall be connected at the bilge by a bracket plate with a height of not less than 0.90 m and thickness equal to the thickness of the floors; or

-

(c)

web frames with lightening holes similar to the double bottom plate floors shall be arranged on each transverse frame;

The gangboards shall be supported by transverse bulkheads or cross-ties spaced not more than 32 m apart.

As an alternative to compliance with the requirements of (c) above, a proof by calculation, issued by a recognised classification society confirming that additional reinforcements have been fitted in the double-hull spaces and that the vessel's transverse strength may be regarded as satisfactory. 9.1.O.9l.3

The depth of the double bottom shall be not less than 0.50 m. The depth below a suction well may however be locally reduced to 0.40 m, provided that the suction well has a capacity of not more than 0.03 m3.

9.1.0.92

Emergency exit Spaces the entrances or exits of which are partly or fully immersed in damaged condition shall be provided with an emergency exit not less than 0.10 m above the waterline. This does not apply to forepeak and afterpeak.

9.1 . O S

Stability (general)

9.1.0.93.1

Proof of sufficient stability shall be furnished including stability in the damaged condition.

- 337 -

The basic values for the stability calculation - the vessel's lightweight and the location of the centre of gravity - shall be determined either by means of an inclining experiment or by detailed mass and moment calculation. In the latter case the lightweight shall be checked by means of a lightweight test with a resulting difference of not more than 5% between the mass determined by the calculation and the displacement determined by the draught readings.

*

Proof of sufficient intact stability shall be furnished for all stages of loading and unloading and for the final loading condition. Floatability after damage shall be proved for the most unfavourable loading condition. For this purpose calculated proof of sufficient stability shall be established for critical intermediate stages of flooding and for the final stage of flooding. Negative values of stability in intermediate stages of flooding may be accepted only if the continued range of curve of righting lever in damaged condition indicates adequate positive values of stability. Stability (intact)

The requirements for intact stability resulting from the damaged stability calculation shall be fully complied with. For the carriage of containers, proof of sufficient stability shall also be furnished in accordance with the provisions of the Regulations referred to in 1.1.4.6. The most stringent of the requirements of 9.1.0.94.1 and 9.1.0.94.2 above shall prevail for the vessel. Stability (damaged condition)

The following assumptions shall be taken into consideration for the damaged condition: The extent of side damage is as follows: longitudinal extent: transverse extent: vertical extent:

at least 0.10 L, but not less than 5.00 m; 0.59 m; from the baseline upwards without limit;

The extent of bottom damage is as follows: longitudinal extent: transverse extent: vertical extent:

at least 0.10 L, but not less than 5.00 m; 3.00 m; from the base 0.49 m upwards, the sump excepted;

Any bulkheads within the damaged area shall be assumed damaged, which means that the location of bulkheads shall be chosen so as to ensure that the vessel remains afloat after the flooding of two or more adjacent compartments in the longitudinal direction. The following provisions are applicable: -

For bottom damage also two adjacent athwartships compartments shall be assumed as flooded;

-

The lower edge of any openings that cannot be closed watertight (e.g. doors, windows, access hatchways) shall, at the final stage of flooding, be not less than 0.10 m above the damage waterline;

- 338 -

-

In general, permeability shall be assumed to be 95%. Where an average permeability of less than 95% is calculated for any compartment, this calculated value may be used.

However, the following minimum values shall be used: -

engine rooms:

-

accommodation:

-

double bottoms, oil fuel tanks, ballast tanks, etc., depending on whether, according to their function, they have to be assumed as full or empty for the vessel floating at the maximum permissible draught:

0% or 95%

For the main engine room only the one-compartment standard needs to be taken into account, i.e. the end bulkheads of the engine room shall be assumed as not damaged. 9.1.0.95.2

At the stage of equilibrium (final stage of flooding) the angle of heel shall not exceed 12". Non-watertight openings shall not be immersed before reaching the stage of equilibrium. If such openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purpose of stability calculation. The positive range of the righting lever curve beyond the position of equilibrium shall have a righting lever of L 0.05 m in association with an area under the curve of L 0.0065 m.rad. The minimum values of stability shall be satisfied up to immersion of the first nonweathertight opening and in any event up to an angle of heel < 27". If non-weathertight openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purposes of stability calculation.

.

I/

9.1.0.95.3

uiliirium position (Final buoyancy position)

'-First

floodable non-weathemat however 27'

Inland navigation vessels carrying containers which have not been secured shall satisfy the following damage stability criteria:

- 339 -

At the stage of equilibrium (final stage of flooding) the angle of heel shall not exceed 5". Non-watertight openings shall not be immersed before reaching the stage of equilibrium. If such openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purpose of stability calculation; The positive range of the righting lever curve beyond the position of equilibrium shall have an area under the curve of > 0.0065 m.rad. The minimum values of stability shall be satisfied up to immersion of the first non-weathertight opening and in any event up to an angle of heel 5 10". If non-weathertight openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purposes of stability calculation.

i;l

(Final buoyancy position)

non-weathertight however S 10"

9.1.0.95.4

If openings through which undamaged compartments may become additionally flooded are capable of being closed watertight, the closing devices shall be appropriately marked.

9.1.0.95.5

Where cross- or down-flooding openings are provided for reduction of unsymmetrical flooding, the time for equalisation shall not exceed 15 minutes if during the intermediate stages of flooding sufficient stability has been proved.

9.1.0.969.1 .O.99

(Reserved).

CHAPTER 9.2 RULES FOR CONSTRUCTION APPLICABLE TO SEAGOING VESSELS WHICH COMPLY WITH THE REQUIREMENTS OF THE SOLAS 74 CONVENTION, CHAPTER 11-2, REGULATION 19 OR SOLAS 74, CHAPTER 11-2, REGULATION 54 The requirements of 9.2.0.0 to 9.2.0.79 are applicable to seagoing vessels which comply with the following requirements:

-

SOLAS 74, Chapter 11-2, Regulation 19 in its amended version; or

-

SOLAS 74, Chapter 11-2, Regulation 54 in its amended version in accordance with the resolutions mentioned in Chapter 11-2, Regulation l , paragraph 2.1, provided that the vessel was constructed before 1 July 2002.

Seagoing vessels which do not comply with the above-mentioned requirements of the SOLAS 74 Convention shall meet the requirements of 9.1.0.0 to 9.1.0.79. Materials of construction The vessels hull shall be constructed of shipbuilding steel or other metal, provided that this metal has at least equivalent mechanical properties and resistance to the effects of temperature and fire. (Reserved).

Water ballast The double-hull spaces and double bottoms may be arranged for being filled with water ballast. (Reserved).

Engines Only internal combustion engines running on a fuel having a flashpoint above 60 "C, are allowed. Air intakes of the engines shall be located not less than 2.00 m from the protected area. Sparking shall not be possible in the protected area. (Reserved).

Exhaust pipes Exhausts shall be evacuated from the vessel into the open-air either upwards through an exhaust pipe or through the shell plating. The exhaust outlet shall be located not less than 2.00 m from the hatchway openings. The exhaust pipes of engines shall be arranged so that the exhausts are led away from the vessel. The exhaust pipes shall not be located within the protected area.

Exhaust pipes shall be provided with a device preventing the escape of sparks, e.g. spark arresters. (Reserved).

Fire and naked light The outlets of funnels shall be located not less than 2.00 m from the hatchway openings. Arrangements shall be provided to prevent the escape of sparks and the entry of water. Heating, cooking and refrigerating appliances shall not be fuelled with liquid fuels, liquid gas or solid fuels. The installation in the engine room or other separate space of heating appliances fuelled with liquid fuel having a flashpoint above 55 "C shall, however, be permitted. Cooking and refrigerating appliances are permitted only in wheelhouses with metal floor and in the accommodation. Electric lighting appliances only are permitted outside the accommodation and the wheelhouse. (Reserved).

Admittance on board The notice boards displaying the prohibition of admittance in accordance with 8.3.3 shall be clearly legible from either side of the vessel. (Reserved).

Prohibition of smoking, fire and naked light The notice boards displaying the prohibition of smoking in accordance with 8.3.4 shall be clearly legible from either side of the vessel. Notice boards indicating the circumstances under which the prohibition applies shall be fitted near the entrances to the spaces where smoking or the use of fire or naked light is not always prohibited. Ashtrays shall be provided close to each exit of the wheelhouse. (Reserved,). Additional rules applicable to double-hull vessels The rules of 9.2.0.88 to 9.2.0.99 are applicable to double-hull vessels intended to carry dangerous goods of Classes 2, 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 7, 8 or 9, except those for which label No. 1 is prescribed in column (5) of Table A of Chapter 3.2, in quantities exceeding those of 7.1.4.1.1. (Reserved,).

9.2.0.88

Classification

Double-hull vessels intended to carry dangerous goods of Classes 2, 3, 4.1,4.2,4.3, 5.1, 5.2, 6.1, 7, 8 or 9 except those for which label No. l is prescribed in column (5) of Table A of Chapter 3.2, in quantities exceeding those referred to in 7.1.4.1, shall be built under survey of a recognised classification society in accordance with the rules established by that classification society to its highest class. This shall be confirmed by the classification society by the issue of an appropriate certificate. The vessel's class shall be continued.

(Reserved). Holds

The vessel shall be built as a double-hull vessel with double-wall spaces and double bottom within the protected area. The distance between the sides of the vessel and the longitudinal bulkheads of the hold shall be not less than 0.80 m. A locally reduced distance at the vessel's ends shall be permitted, provided the smallest distance between vessel's side and the longitudinal bulkhead (measured perpendicular to the side) is not less than 0.60 m. The sufficient structural strength of the vessel (Longitudinal, transverse and local strength) shall be confirmed by the class certificate. The depth of the double bottom shall be not less than 0.50 m. The depth below the suction wells may however be locally reduced to 0.40 m, provided the suction well has a capacity of not more than 0.03 m3.

(Reserved). Stability (general)

Proof of sufficient stability shall be h i s h e d including stability in the damaged condition. The basic values for the stability calculation - the vessel's lightweight and the location of the centre of gravity - shall be determined either by means of an inclining experiment or by detailed mass and moment calculation. In the latter case the lightweight shall be checked by means of a lightweight test with a resulting difference of not more than h 5% between the mass determined by the calculation and the displacement determined by the draught readings. Proof of sufficient intact stability shall be furnished for all stages of loading and unloading and for the final loading condition. Floatability after damage shall be proved for the most unfavourable loading condition. For this purpose calculated proof of sufficient stability shall be established for critical intermediate stages of flooding and for the final stage of flooding. Negative values of stability in intermediate stages of flooding may be accepted only if the continued range of curve of righting lever in damaged condition indicates adequate positive values of stability.

Stability (intact) The requirements for intact stability resulting from the damaged stability calculation shall be fully complied with. For the carriage of containers, additional proof of sufficient stability shall be furnished in accordance with the requirements of the Regulations referred to in 1.1.4.6. The most stringent of the requirements of 9.2.0.94.1 and 9.2.0.94.2 shall prevail for the vessel. For seagoing vessels the provisions of 9.2.0.94.2 above may be regarded as having been complied with if the stability conforms to Resolution A.749 (18) from the International Maritime Organization and the stability documents have been checked by the competent authority. This applies only when all containers are secured as usual on seagoing vessels and a relevant stability document has been approved by the competent authority. Stability (damaged condition) The following assumptions shall be taken into consideration for the damaged condition: The extent of side damage is as follows: longitudinal extent: transverse extent: vertical extent:

at least 0.10 L, but not less than 5.00 m; 0.59 m; from the baseline upwards without limit;

The extent of bottom damage is as follows: longitudinal extent: transverse extent: vertical extent:

at least 0.10 L, but not less than 5.00 m; 3.00 m; from the base 0.49 m upwards, the sump excepted;

Any bulkheads within the damaged area shall be assumed damaged, which means that the location of bulkheads shall be chosen so that the vessel will remain afloat after flooding of two or more adjacent compartments in the longitudinal direction. The following provisions are applicable: -

For bottom damage, adjacent athwartship compartments shall also be assumed as flooded;

-

The lower edge of any openings that cannot be closed watertight (e.g. doors, windows, access hatchways) shall, at the final stage of flooding, be not less than 0.10 m above the damage waterline;

-

In general, permeability shall be assumed to be 95%. Where an average permeability of less than 95% is calculated for any compartment, this calculated value may be used.

However, the following minimum values shall be used: -

engine rooms

-

accommodation

double bottoms, oil fuel tanks, ballast tanks, etc., depending on whether according to their function, they have to be assumed as full or empty for the vessel floating at the maximum permissible draught

0% or 95%

For the main engine room only the one-compartment standard needs to be taken into account. (Consequently, the end bulkheads of the engine room shall be assumed as not damaged.) 9.2.0.95.2

At the stage of equilibrium (final stage of flooding) the angle of heel shall not exceed 12". Non-watertight openings shall not be immersed before reaching the stage of equilibrium. If such openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purpose of stability calculation. The positive range of the righting lever curve beyond the position of equilibrium shall have a righting lever of 2 0.05 m in association with an area under the curve of > 0.0065 m.rad. The minimum values of stability shall be satisfied up to immersion of the first nonweathertight opening and in any event up to an angle of heel 127". If non-weathertight openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purposes of stability calculation.

Equilibrium position (Final buoyancy position)

non-weathertight however 27"

9.2.0.95.3

If openings through which undamaged compartments may become additionally flooded are capable of being closed watertight, the closing devices shall be appropriately marked.

9.2.0.95.4

Where cross- or down-flooding openings are provided for reduction of unsymmetrical flooding, the time for equalisation shall not exceed 15 minutes if during the intermediate stages of flooding sufficient stability has been proved.

9.2.0.969.2.0.99

(Reserved).

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CHAPTER 9.3 RULES FOR CONSTRUCTION OF TANK VESSELS Rules for construction of type G tank vessels The provisions of 9.3.1.0 to 9.3.1.99 apply to type G tank vessels.

9.3.1.0

Materials of construction

9.3.1.O. 1

(a)

The vessel's hull and the cargo tanks shall be constructed of shipbuilding steel or other at least equivalent metal. The independent cargo tanks may also be constructed of other materials, provided these have at least equivalent mechanical properties and resistance against the effects of temperature and fire.

(b)

Every part of the vessel including any installation and equipment which may come into contact with the cargo shall consist of materials which can neither be dangerously affected by the cargo nor cause decomposition of the cargo or react with it so as to form harmful or hazardous products.

9.3.1.0.2

Except where explicitly permitted in 9.3.1.0.3 below or in the certificate of approval, the use of wood, aluminium alloys or plastic materials within the cargo area is prohibited.

9.3.1.0.3

(a)

(b)

The use of wood, aluminium alloys or plastic materials within the cargo area is only permitted for: -

gangways and external ladders;

-

movable items of equipment;

-

chocking of cargo tanks which are independent of the vessel's hull and chocking of installations and equipment;

-

masts and similar round timber;

-

engine parts;

-

parts of the electrical installation;

-

lids of boxes which are placed on the deck.

The use of wood or plastic materials within the cargo area is only permitted for: -

(c)

supports and stops of any kind.

The use of plastic materials or rubber within the cargo area is only permitted for: -

all kinds of gaskets (e.g. for dome or hatch covers);

-

electric cables:

-

hoses for loading and unloading;

-

insulation of cargo tanks and of hoses for loading and unloading.

- 347 -

(d)

All permanently fitted materials in the accommodation or wheelhouse, with the exception of furniture, shall not readily ignite. They shall not evolve fumes or toxic gases in dangerous quantities, if involved in a fire.

The paint used in the cargo area shall not be liable to produce sparks in case of impact. The use of plastic material for vessel's boats is permitted only if the material does not readily ignite. (Reserved).

Classification The tank vessel shall be built under survey of a recognised classification society in accordance with the rules established by that classification society for its highest class, and the tank vessel shall be classed accordingly. The vessel's class shall be continued. The classification society shall issue a certificate certifying that the vessel is in conformity with the rules of this section. The design pressure and the test pressure of cargo tanks shall be entered in the certificate. If a vessel has cargo tanks with different valve opening pressures, the design and test pressures of each tank shall be entered in the certificate. The classification society shall draw up a certificate mentioning all the dangerous goods accepted for carriage by the vessel (see also 1.16.1.2.5). The cargo pump-rooms shall be inspected by a recognised classification society whenever the certificate of approval has to be renewed as well as during the third year of validity of the certificate of approval. The inspection shall comprise at least: -

-

an inspection of the whole system for its condition, for corrosion, leakage or conversion works which have not been approved; a checking of the condition of the gas detection system in the cargo pump-rooms.

Inspection certificates signed by the recognised classification society with respect to the inspection of the cargo pump-rooms shall be kept on board. The inspection certificates shall at least include particulars of the above inspection and the results obtained as well as the date of the inspection. The condition of the gas detection system referred to in 9.3.1.52.3 (b) shall be checked by a recognised classification society whenever the certificate of approval has to be renewed and during the third year of validity of the certificate of approval. A certificate signed by the recognised classification society shall be kept on board. (Reserved).

9.3.1.10

Protection against the penetration of gases

9.3.1.10.1

The vessel shall be designed so as to prevent gases from penetrating into the accommodation and the service spaces.

9.3.1.10.2

Outside the cargo area, the lower edges of door-openings in the sidewalls of superstructures and the coamings of access hatches to under-deck spaces shall have a height of not less than 0.50 m above the deck This requirement need not be complied with if the wall of the superstructures facing the cargo area extends from one side of the ship to the other and has doors the sills of which have a height of not less than 0.50 m. The height of this wall shall not be less than 2.00 m. In this case, the lower edges of door-openings in the sidewalls of superstructures and the coamings of access hatches behind this wall shall have a height of not less than 0.10 m. The sills of engine room doors and the coamings of its access hatches shall, however, always have a height of not less than 0.50 m.

9.3.1.10.3

In the cargo area, the lower edges of door-openings in the sidewalls of superstructures shall have a height of not less than 0.50 m above the deck and the sills of hatches and ventilation openings of premises located under the deck shall have a height of not less than 0.50 m above the deck. This requirement does not apply to access openings to double-hull and double bottom spaces.

9.3.1.10.4

The bulwarks, foot-rails, etc shall be provided with sufficiently large openings which are located directly above the deck.

9.3.1.11

Hold spaces and cargo tanks

9.3.1.11.1

(a)

The maximum permissible capacity of a cargo tank shall be determined in accordance with the following table:

In the table above L x B X H is the product of the main dimensions of the tank vessel in metres (according to the measurement certificate), where: L B H

=

= =

overall length of the hull; extreme breadth of the hull; shortest vertical distance between the top of the keel and the lowest point of the deck at the side of the vessel (moulded depth) within the cargo area;

For trunk vessels, H shall be replaced by H', where H' shall be obtained from the following formula:

where:

9.3.1.1 1.2

ht

=

bt It

= =

trunk height (distance between trunk deck and main deck measured on trunk side at Ll2); trunk breadth; trunk length;

(b)

Pressure cargo tanks whose ratio of length to diameter exceeds 7 are prohibited.

(c)

The pressure cargo tanks shall be designed for a cargo temperature of + 40 "C

(a)

In the cargo area, the hull shall be designed as follows:' -

as a double-hull and double bottom vessel. The internal distance between the sideplatings of the vessel and the longitudinal bulkheads shall not be less than 0.80 m, the height of the double bottom shall be not less than 0.60 m, the cargo tanks shall be supported by saddles extending between the tanks to not less than 20" below the horizontal centreline of the cargo tanks. Refrigerated cargo tanks shall be installed only in hold spaces bounded by double-hull spaces and double-bottom. Cargo tank fastenings shall meet the requirements of a recognised classification society; or

-

as a single-hull vessel with the sideplatings of the vessel between gangboard and top of floor plates provided with side stringers at regular intervals of not more than 0.60 m which are supported by web frames spaced at intervals of not more than 2.00 m. The side stringers and the web frames shall have a height of not less than 10% of the depth, however, not less than 0.30 m. The side stringers and web frames shall be fitted with a face plate made of flat steel and having a cross-section of not less that 7.5 cm2 and 15 cm2,respectively. The distance between the sideplating of the vessel and the cargo tanks shall be not less than 0.80 m and between the bottom and the cargo tanks not less than 0.60 m. The depth below the suction wells may be reduced to 0.50 m. The lateral distance between the suction well of the cargo tanks and the bottom structure shall be not less than 0.10 m.

The cargo tank supports and fastenings shall be as follows: -

the cargo tanks shall be supported by saddles extending between the tanks to not less than 10" below the horizontal centreline of the tanks; and

-

for adjacent cylindrical cargo tanks, a spacer of 500 mmx 450 mm shall be provided at the saddles, and a spacer of 2,000 mmx 450 mm shall be provided midway between the saddles. The spacers shall fit the adjacent cargo tanks closely. The spacers shall consist of an energy-absorbing material.

(b)

1

The cargo tanks shall be fixed so that they cannot float.

For a different design of the hull in the cargo area, proof shall be furnished by way of calculation that in the event of a lateral collision with another vessel having a straight bow, an energy of 22 MJ can be absorbed without any rupture of the cargo tanks and the piping leading to the cargo tanks. - 350 -

9.3.1.1 1.3

(c)

The capacity of a suction well shall be limited to not more than 0.10 m3. For pressure cargo tanks, however, the capacity of a suction well may be of 0.20 m3.

(d)

Side-stringers linking or supporting the load-bearing components of the sides of the vessel with the load-bearing components of the longitudinal walls of cargo tanks and side-stringers linking the load-bearing components of the vessel's bottom with the tank-bottom are prohibited.

(a)

The hold spaces shall be separated from the accommodation and service spaces outside the cargo area below deck by bulkheads provided with a Class A-60 fire protection insulation according to SOLAS 74, Chapter 11-2, Regulation 3. A space of not less than 0.20 m shall be provided between the cargo tanks and the end bulkheads of the hold spaces. Where the cargo tanks have plane end bulkheads this space shall be not less than 0.50 m.

(b)

The hold spaces and cargo tanks shall be capable of being inspected.

(c)

All spaces in the cargo area shall be capable of being ventilated. Means for checking their gas-free condition shall be provided.

9.3.1.1 1.4

The bulkheads bounding the hold spaces shall be watertight. The cargo tanks and the bulkheads bounding the cargo area shall have no openings or penetrations below deck. The bulkhead between the engine room and the service spaces within the cargo area or between the engine room and a hold space may be fitted with penetrations provided that they conform to the requirements of 9.3.1.17.5.

9.3.1.11.5

Double-hull spaces and double bottoms in the cargo area shall be arranged for being filled with ballast water only. Double bottoms may, however, be used as oil fuel tanks, provided they comply with the requirements of 9.3.1.32.

9.3.1.11.6

(a)

A space in the cargo area below deck may be arranged as a service space, provided that the bulkhead bounding the service space extends vertically to the bottom and the bulkhead not facing the cargo area extends from one side of the vessel to the other in one frame plane. This service space shall only be accessible from the deck.

(b)

The service space shall be watertight with the exception of its access hatches and ventilation inlets.

(c)

No pipes for loading or unloading shall be fitted within the service space referred to under (a) above. Pipes for loading and unloading may be fitted in the cargo pump-rooms below deck only when they conform to the provisions of 9.3.1.17.6.

9.3.1.1 1.7

Where service spaces are located in the cargo area under deck, they shall be arranged so as to be easily accessible and to permit persons wearing protective clothing and breathing apparatus to safely operate the service equipment contained therein. They shall be designed so as to allow injured or unconscious personnel to be removed from such spaces without difficulty, if necessary by means of fixed equipment.

9.3.1. l 1.8

Hold spaces and other accessible spaces within the cargo area shall be arranged so as to ensure that they may be completely inspected and cleaned in an appropriate manner. The dimensions of openings, except for those of double-hull spaces and double bottoms which do not have a wall adjoining the cargo tanks, shall be sufficient to allow a person wearing breathing apparatus to enter or leave the space without difficulty. These openings shall have a minimum cross-sectional area of 0.36 m2 and a minimum side length of 0.50 m.

They shall be designed so as to allow injured or unconscious personnel to be removed from the bottom of such spaces without difficulties, if necessary by means of fixed equipment. In these spaces the distance between the reinforcements shall not be less than -0.50m. In double bottoms this distance may be reduced to 0.45 m. Cargo tanks may have circular openings with a diameter of not less than 0.68 m. Ventilation Each hold space shall have two openings the dimensions and location of which shall be such as to permit effective ventilation of any part of the hold space. If there are no such openings, it shall be possible to fill the hold spaces with inert gas or dry air. Double-hull spaces and double bottoms within the cargo area which are not arranged for being filled with ballast water and cofferdams between engine rooms and pump-rooms, if they exist, shall be provided with ventilation systems. Any service spaces located in the cargo area below deck shall be provided with a system of forced ventilation with sufficient power for ensuring at least 20 changes of air per hour based on the volume of the space. The ventilation exhaust ducts shall extend down to 50 mm above the bottom of the service space. The air shall be supplied through a duct at the top of the service space. The air inlets shall be located not less than 2.00 m above the deck, at a distance of not less than 2.00 m from tank openings and 6.00 m from the outlets of safety valves. The extension pipes, which may be necessary, may be of the hinged type. Ventilation of accommodation and service spaces shall be possible. Ventilators used in the cargo area shall be designed so that no sparks may be emitted on contact of the impeller blades with the housing and no static electricity may be generated. Notice boards shall be fitted at the ventilation inlets indicating the conditions when they shall be closed. All ventilation inlets of accommodation and service spaces leading outside shall be fitted with fire flaps. Such ventilation inlets shall be located not less than 2.00 m from the cargo area. Ventilation inlets of service spaces in the cargo area below deck may be located within such area. Stability (general) Proof of sufficient stability shall be furnished including for stability in damaged condition. The basic values for the stability calculation - the vessel's lightweight and location of the centre of gravity - shall be determined either by means of an inclining experiment or by detailed mass and moment calculation. In the latter case the lightweight of the vessel shall be checked by means of a lightweight test with a tolerance limit of 5% between the mass determined by calculation and the displacement determined by the draught readings.

*

Proof of sufficient intact stability shall be furnished for all stages of loading and unloading and for the final loading condition. Floatability after damage shall be proved for the most unfavourable loading condition. For this purpose, calculated proof of sufficient stability shall be established for critical

- 352 -

intermediate stages of flooding and for the final stage of flooding. Negative values of stability in intermediate stages of flooding may be accepted only if the continued range of curve of righting lever in damaged condition indicates adequate positive values of stability. 9.3.1.14

Stability (intact)

The requirements for intact stability resulting from the damaged stability calculation shall be fully complied with. 9.3.1.15

Stability (damaged condition)

9.3.1.15.1

The following assumptions shall be taken into consideration for the damaged condition: (a)

The extent of side damage is as follows: longitudinal extent: transverse extent: vertical extent:

(b)

The extent of bottom damage is as follows: longitudinal extent: transverse extent: vertical extent:

(c)

at least 0.10 L, but not less than 5.00 m; 0.79 m; from the base line upwards without limit;

at least 0.10 L, but not less than 5.00 m; 3.00 m; from the base 0.59 m upwards, the well excepted;

Any bulkheads within the damaged area shall be assumed damaged, which means that the location of bulkheads shall be chosen so as to ensure that the vessel remains afloat after the flooding of two or more adjacent compartments in the longitudinal direction. The following provisions are applicable: -

For bottom damage, adjacent athwartship compartments shall also be assumed as flooded; The lower edge of any non-watertight openings (e.g. doors, windows, access hatchways) shall, at the final stage of flooding, be not less than 0.10 m above the damage waterline;

-

In general, permeability shall be assumed to be 95%. Where an average permeability of less than 95% is calculated for any compartment, this calculated value obtained may be used.

However, the following minimum values shall be used: -

engine rooms:

85%;

-

accommodation:

95%;

-

double bottoms, oil fuel tanks, ballast tanks, etc., depending on whether, according to their function, they have to be assumed as full or empty for the vessel floating at the maximum permissible draught:

0% or 95%.

For the main engine room only the one-compartment standard need be taken into account, i.e. the end bulkheads of the engine room shall be assumed as not damaged.

- 3.53 -

At the stage of equilibrium (final stage of flooding), the angle of heel shall not exceed 12". Non-watertight openings shall not be flooded before reaching the stage of equilibrium. If such openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purpose of stability calculation. The positive range of the righting lever curve beyond the stage of equilibrium shall have a righting level of L 0.05 m in association with an area under the curve of > 0.0065 m.rad. The minimum values of stability shall be satisfied up to immersion of the first non-weathertight opening and in any event up to an angle of heel 5 27". If non-watertight openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purpose of stability calculation.

Equiliiriium position (Final buoyancy position)

non-weathertight opening, however 27"

If openings through which undamaged compartments may additionally become flooded are capable of being closed watertight, the closing appliances shall be marked accordingly. When cross- or down-flooding openings are provided for reduction of unsymmetrical flooding, the time for equalisation shall not exceed 15 minutes, if during the intermediate stages of flooding sufficient stability has been proved. Engine rooms Internal combustion engines for the vessel's propulsion as well as internal combustion engines for auxiliary machinery shall be located outside the cargo area. Entrances and other openings of engine rooms shall be at a distance of not less than 2.00 m from the cargo area. The engine room shall be accessible from the deck; the entrances shall not face the cargo area. When the doors are not located in a recess whose depth is at least equal to the door width, the hinges shall face the cargo area. Accommodation and sewice spaces Accommodation spaces and the wheelhouse shall be located outside the cargo area forward of the fore vertical plane or abaft the aft vertical plane bounding the part of cargo area below deck. Windows of the wheelhouse which are located not less than 1.00 m above the bottom of the wheelhouse may tilt forward. - 354 -

9.3.1.17.2

Entrances to spaces and openings of superstructures shall not face the cargo area. Doors opening outward and not located in a recess the depth of which is at least equal to the width of the doors shall have their hinges facing the cargo area.

9.3.1.l 7.3

Entrances from the deck and openings of spaces facing the weather shall be capable of being closed. The following instruction shall be displayed at the entrance of such spaces: Do not open during loading and unloading without the permission of the master. Close immediately.

9.3.1.17.4

Entrances and windows of superstructures and accommodation spaces which can be opened as well as other openings of these spaces shall be located not less than 2.00 m from the cargo area. No wheelhouse doors and windows shall be located within 2.00 m from the cargo area, except where there is no direct connection between the wheelhouse and the accommodation.

9.3.1.17.5

(a)

Driving shafts of the bilge or ballast pumps may penetrate through the bulkhead between the service space and the engine room, provided the arrangement of the service space is in compliance with 9.3.1.1 1.6.

(b)

The penetration of the shaft through the bulkhead shall be gastight and shall have been approved by a recognised classification society.

(c)

The necessary operating instructions shall be displayed.

(d)

Penetrations through the bulkhead between the engine room and the service space in the cargo area, and the bulkhead between the engine room and the hold spaces may be provided for electrical cables, hydraulic lines and piping for measuring, control and alarm systems, provided that the penetrations have been approved by a recognised classification society. The penetrations shall be gastight. Penetrations through a bulkhead with an "A-60" fire protection insulation according to SOLAS 74, Chapter 11-2, Regulation 3, shall have an equivalent fire protection.

(e)

Pipes may pass through the bulkhead between the engine room and the service space in the cargo area provided that these are pipes between the mechanical equipment in the engine room and the service space which do not have any openings within the service space and which are provided with shut-off devices at the bulkhead in the engine room.

(f)

Notwithstanding 9.3.1.1 1.4, pipes from the engine room may pass through the service space in the cargo area or a cofferdam or a hold space or a double-hull space to the outside provided that within the service space or cofferdam or hold space or doublehull space they are of the thick-walled type and have no flanges or openings.

(g)

Where a driving shaft of auxiliary machinery penetrates through a wall located above the deck the penetration shall be gastight.

9.3.1.17.6

A service space located within the cargo area below deck shall not be used as a cargo pumproom for the vessel's own gas discharging system, e.g. compressors or the compressorlheat exchangerlpump combination, except where: -

the pump-room is separated from the engine room or from service spaces outside the cargo area by a cofferdam or a bulkhead with an "A-60" fire protection insulation according to SOLAS 74, Chapter 11-2, Regulation 3, or by a service space or a hold space;

-

the "A-60" bulkhead required above does not include penetrations referred to in 9.3. I. 17.5 (a);

-

ventilation exhaust outlets are located not less than 6.00 m from entrances and openings of the accommodation and service spaces;

-

the access hatches and ventilation inlets can be closed from the outside;

-

all pipes for loading and unloading (at the suction side and delivery side) are led through the deck above the pump-room. The necessary operation of the control devices in the pump-room, starting of pumps or compressors and control of the liquid flow rate shall be effected from the deck;

-

the system is fully integrated in the gas and liquid piping system;

-

the cargo pump-room is provided with a permanent gas detection system which automatically indicates the presence of explosive gases or lack of oxygen by means of direct-measuring sensors and which actuates a visual and audible alarm when the gas concentration has reached 20% of the lower explosive limit. The sensors of this system shall be placed at suitable positions at the bottom and directly below the deck. Measurement shall be continuous. The audible and visual alarms are installed in the wheelhouse and in the cargo pump-room and, when the alarm is actuated, the loading and unloading system is shut down. Failure of the gas detection system shall be immediately signalled in the wheelhouse and on deck by means of audible and visual alarms;

-

9.3.1.17.7

the ventilation system prescribed in 9.3.1.12.3 has a capacity of not less than 30 changes of air per hour based on the total volume of the service space.

The following instruction shall be displayed at the entrance of the cargo pump-room:

Before entering the cargo pump-room check whether it is free from gases and contains sufficient oxygen. Do not open doors and entrance openings without the permission of the master. Leave immediately in the event of alarm.

9.3.1.18

Inerting facility In cases in which inerting or blanketing of the cargo is prescribed, the vessel shall be equipped with an inerting system. This system shall be capable of maintaining a permanent minimum pressure of 7 kPa (0.07 bar) in the spaces to be inerted. In addition, the inerting system shall not increase the pressure in the cargo tank to a pressure greater than that at which the pressure valve is regulated. The set pressure of the vacuum-relief valve shall be 3.5 kPa. A sufficient quantity of inert gas for loading or unloading shall be carried or produced on board if it is not possible to obtain it on shore. In addition, a sufficient quantity of inert gas to offset normal losses occurring during carriage shall be on board.

The premises to be inerted shall be equipped with connections for introducing the inert gas and monitoring systems so as to ensure the correct atmosphere on a permanent basis. When the pressure or the concentration of inert gas in the gaseous phase falls below a given value, this monitoring system shall activate an audible and visible alarm in the wheelhouse. When the wheelhouse is unoccupied, the alarm shall also be perceptible in a location occupied by a crew member. (Reserved).

Safety and control installations Cargo tanks shall be provided with the following equipment: (a)

(Resewed);

(b)

a level gauge;

(c)

a level alarm device which is activated at the latest when a degree of filling of 86% is reached;

(d)

a high level sensor for actuating the facility against overflowing at the latest when a degree of filling of 97.5% is reached;

(e)

an instrument for measuring the pressure;

(f)

an instrument for measuring the temperature of the cargo;

(g)

a connection for a closed sampling device.

When the degree of filling in per cent is determined, an error of not more than 0.5% is permitted. It shall be calculated on the basis of the total cargo tank capacity including the expansion trunk. The level gauge shall allow readings from the control position of the shut-off devices of the particular cargo tank. The permissible maximum filling level of the cargo tank shall be marked on each level gauge. Permanent reading of the overpressure and vacuum shall be possible from a location from which loading or unloading operations may be interrupted. The permissible maximum overpressure and vacuum shall be marked on each level gauge. Readings shall be possible in all weather conditions. The level alarm device shall give a visual and audible warning on board when actuated. The level alarm device shall be independent of the level gauge. (a)

The high level sensor referred to in 9.3.1.2 1.1 (d) shall give a visual and audible alarm on board and at the same time actuate an electrical contact which in the form of a binary signal interrupts the electric current loop provided and fed by the shore facility, thus initiating measures at the shore facility against overflowing during loading operations.

The signal shall be transmitted to the shore facility via a watertight two-pin plug of a connector device in accordance with standard EN 60309-2: 1999 for direct current of 40 to 50 volts, identification colour white, position of the nose 10 h. The plug shall be permanently fitted to the vessel close to the shore connections of the loading and unloading pipes. The high level sensor shall also be capable of switching off the vessel's own discharging pump. The high level sensor shall be independent of the level alarm device, but it may be connected to the level gauge. (b)

9.3.1.21.6

During discharging by means of the on-board pump, it shall be possible for the shore facility to switch it off. For this purpose, an independent intrinsically safe power line, fed by the vessel, shall be switched off by the shore facility by means of an electrical contact. It shall be possible for the binary signal of the shore facility to be transmitted via a watertight two-pole socket or a connector device in accordance with standard EN 60309-2: 1999, for direct current of 40 to 50 volts, identification colour white, position of the nose 10 h. This socket shall be permanently fitted to the vessel close to the shore connections of the unloading pipes.

The visual and audible signals given by the level alarm device shall be clearly distinguishable from those of the high level sensor. The visual alarm shall be visible at each control position on deck of the cargo tank stop valves. It shall be possible to easily check the functioning of the sensors and electric circuits or these shall be of the "failsafe" design.

9.3.1.2 1.7

When the pressure or the temperature exceeds a set value, the instruments for measuring the pressure and the temperature of the cargo shall activate a visual and an audible alarm in the wheelhouse. When the wheelhouse is unoccupied the alarm shall also be perceptible in a location occupied by a crew member. When the pressure exceeds a set value during loading or unloading, the instrument for measuring the pressure shall simultaneously initiate an electrical contact which, by means of the plug referred to in 9.3.1.2 1.5 above, enables measures to be taken to interrupt the loading operation. When the vessel's own discharge pump is used, it shall be switched off automatically. The sensor for the alarms referred to above may be connected to the alarm installation.

9.3.1.21.8

Where the control elements of the shut-off devices of the cargo tanks are located in a control room, it shall be possible to stop the loading pumps and read the level gauges in the control room, and the visual and audible warning given by the level alarm device, the high level sensor referred to in 9.3.1.21.1 (d) and the instruments for measuring the pressure and temperature of the cargo shall be noticeable in the control room and on deck. Satisfactory monitoring of the cargo area shall be ensured from the control room.

9.3.1.21.9

The vessel shall be so equipped that loading or unloading operations can be interrupted by means of switches, i.e. the quick-action stop valve located on the flexible vessel-to-shore connecting line must be capable of being closed. The switches shall be placed at the two points on the vessel (fore and aft).

The interruption systems shall be designed according to the quiescent current principle. When refrigerated substances are carried the opening pressure of the safety system shall be determined by the design of the cargo tanks. In the event of the transport of substances that must be carried in a refrigerated state the opening pressure of the safety system shall be not less than 25 kPa greater than the maximum pressure calculated according to 9.3.1.27. Cargo tank openings (a)

Cargo tank openings shall be located on deck in the cargo area.

(b)

Cargo tank openings with a cross-section greater than 0.10 m2 shall be located not less than 0.50 m above the deck.

Cargo tank openings shall be fitted with gastight closures capable of withstanding the test pressure in accordance with 9.3.1.23.1. The exhaust outlets of the pressure relief valves shall be located not less than 2.00 m above the deck at a distance of not less than 6.00 m from the accommodation and from the service spaces located outside the cargo area. This height may be reduced when within a radius of 1.00 m round the pressure relief valve outlet there is no equipment, no work is being carried out and signs indicate the area. The closing devices normally used in loading and unloading operations shall not be capable of producing sparks when operated. Each tank in which refrigerated substances are carried shall be equipped with a safety system to prevent unauthorized vacuum or overpressure. Pressure test Cargo tanks and pipes for loading and unloading shall comply with the provisions concerning pressure vessels which have been established by the competent authority or a recognised classification society for the substances carried. Any cofferdams shall be subjected to initial tests before being put into service and thereafter at the prescribed intervals. The test pressure shall be not less than 10 kPa (0.10 bar) gauge pressure. The maximum intervals for the periodic tests referred to in 9.3.1.23.2 above shall be l l years. Regulation of cargo pressure and temperature Unless the entire cargo system is designed to resist the full effective vapour pressure of the cargo at the upper limits of the ambient design temperatures, the pressure of the tanks shall be kept below the permissible maximum set pressure of the safety valves, by one or more of the following means: (a)

a system for the regulation of cargo tank pressure using mechanical refrigeration;

(b)

a system ensuring safety in the event of the heating or increase in pressure of the cargo. The insulation or the design pressure of the cargo tank, or the combination of these two elements, shall be such as to leave an adequate margin for the operating

period and the temperatures expected; in each case the system shall be deemed acceptable by a recognized classification society; (c)

other systems deemed acceptable by a recognized classification society.

The systems prescribed in 9.3.1.24.1 shall be constructed, installed and tested to the satisfaction of the recognized classification society. The materials used in their construction shall be compatible with the cargoes to be carried. For normal service, the upper ambient design temperature limits shall be: air:

+30° C;

water: +20° C. The cargo storage system shall be capable of resisting the full vapour pressure of the cargo at the upper limits of the ambient design temperatures, whatever the system adopted to deal with the boil-off gas. This requirement is indicated by remark 37 in column (20) of Table C of Chapter 3.2. Pumps and piping Pumps, compressors and accessory loading and unloading piping shall be placed in the cargo area. Cargo pumps and compressors shall be capable of being shut down from the cargo area and, in addition, from a position outside the cargo area. Cargo pumps and compressors situated on deck shall be located not less than 6.00 m from entrances to, or openings of, the accommodation and service spaces outside the cargo area. Pipes for loading and unloading shall be independent of any other piping of the vessel. No cargo piping shall be located below deck, except those inside the cargo tanks and in the service spaces intended for the installation of the vessel's own gas discharging system.

(Reserved). Pipes for loading and unloading shall be clearly distinguishable from other piping, e.g. by means of colour marking. The pipes for loading and unloading on deck, the vapour pipes with the exception of the shore connections but including the safety valves, and the valves shall be located within the longitudinal line formed by the outer boundaries of the domes and not less than one quarter of the vessel's breadth from the outer shell. This requirement does not apply to the relief pipes situated behind the safety valves. If there is, however, only one dome athwartships, these pipes and their valves shall be located at a distance not less than 2.70 m from the shell. Where cargo tanks are placed side by side, all the connections to the domes shall be located on the inner side of the domes. The external connections may be located on the fore and aft centre line of the dome. The shut-off devices shall be located directly at the dome or as close as possible to it. The shut-off devices of the loading and unloading piping shall be duplicated, one of the devices being constituted by a remotecontrolled quick-action stop device. When the inside diameter of a shut-off device is less than 50 mm this device may be regarded as a safety device against bursts in the piping.

(e)

The shore connections shall be located not less than 6.00 m from the entrances to or openings of, the accommodation and service spaces outside the cargo area.

(Q

Each shore connection of the vapour pipe and shore connections of the pipes for loading and unloading, through which the loading or unloading operation is carried out, shall be fitted with a shut-off device and a quick-action stop valve. However, each shore connection shall be fitted with a blind flange when it is not in operation.

The distance referred to in 9.3.1.25.1 and 9.3.1.25.2 (e) may be reduced to 3.00 m if a transverse bulkhead complying with 9.3.1.10.2 is situated at the end of the cargo area. The openings shall be provided with doors. The following notice shall be displayed on the doors: Do not open during loading and unloading without the permission of the master. Close immediately. Every component of the pipes for loading and unloading shall be electrically connected to the hull. The stop valves or other shut-off devices of the pipes for loading and unloading shall indicate whether they are open or shut. The pipes for loading and unloading shall have, at the test pressure, the required elasticity, leakproofness and resistance to pressure. The pipes for loading and unloading shall be fitted with pressure gauges at the inlet and outlet of the pump. Reading of the pressure gauges shall be possible from the control position of the vessel's own gas discharging system. The maximum permissible overpressure or vacuum shall be indicated by a red mark. Readings shall be possible in all weather conditions. Use of the cargo piping for ballasting purposes shall not be possible. (Reserved).

Refrigeration system The refrigeration system referred to in 9.3.1.24.1 (a) shall be composed of one or more units capable of keeping the pressure and temperature of the cargo at the upper limits of the ambient design temperatures at the prescribed level. Unless another means of regulating cargo pressure and temperature deemed satisfactory by a recognized classification society is provided, provision shall be made for one or more stand-by units with an output at least equal to that of the largest prescribed unit. A stand-by unit shall include a compressor, its engine, its control system and all necessary accessories to enable it to operate independently of the units normally used. Provision shall be made for a stand-by heat-exchanger unless the system's normal heat-exchanger has a surplus capacity equal to at least 25% of the largest prescribed capacity. It is not necessary to make provision for separate piping. Cargo tanks, piping and accessories shall be insulated so that, in the event of a failure of all cargo refrigeration systems, the entire cargo remains for at least 52 hours in a condition not causing the safety valves to open.

- 361 -

The security devices and the connecting lines from the refrigeration system shall be connected to the cargo tanks above the liquid phase of the cargo when the tanks are filled to their maximum permissible degree of filling. They shall remain within the gaseous phase, even if the vessel has a list up to 12 degrees. When several refrigerated cargoes with a potentially dangerous chemical reaction are carried simultaneously, particular care shall be given to the refrigeration systems so as to prevent any mixing of the cargoes. For the carriage of such cargoes, separate refrigeration systems, each including the full stand-by unit referred to in 9.3.1.27.1, shall be provided for each cargo. When, however, refrigeration is ensured by an indirect or combined system and no leak in the heat exchangers can under any foreseeable circumstances lead to the mixing of cargoes, no provision need be made for separate refrigeration units for the different cargoes. When two or more refrigerated cargoes are not soluble in each other under conditions of carriage such that their vapour pressures are added together in the event of mixing, particular care shall be given to the refrigeration systems to prevent any mixing of the cargoes. When the refrigeration systems require water for cooling, a sufficient quantity shall be supplied by a pump or pumps used exclusively for the purpose. This pump or pumps shall have at least two suction pipes, if possible leading from two water intakes, one to port, the other to starboard. Provision shall be made for a stand-by pump with a satisfactory flow; this may be a pump used for other purposes provided that its use for supplying water for cooling does not impair any other essential service. The refrigeration system may take one of the following forms: (a)

Direct system: the cargo vapours are compressed, condensed and returned to the cargo tanks. This system shall not be used for certain cargoes specified in column (20) of Table C of Chapter 3.2. This requirement is indicated by remark 35 in column (20) of Table C of Chapter 3.2;

(b)

Indirect system: the cargo or the cargo vapours are cooled or condensed by means of a coolant without being compressed;

(c)

Combined system: the cargo vapours are compressed and condensed in a cargo/coolant heat-exchanger and returned to the cargo tanks. This system shall not be used for certain cargoes specified in Table C of Chapter 3.2. This requirement is indicated by remark 36 in column (20) of Table C of Chapter 3.2.

All primary and secondary coolant fluids shall be compatible with each other and with the cargo with which they may come into contact. Heat exchange may take place either at a distance from the cargo tank, or by using cooling coils attached to the inside or the outside of the cargo tank. When the refrigeration system is installed in a separate service space, this service space shall meet the requirements of 9.3.1.17.6. For all cargo systems, the heat transmission coefficient shall be determined by calculation. The correctness of the calculation shall be checked by means of a refrigeration test (heat balance test). This test shall be performed in accordance with the rules set up by a recognised classification society.

A certificate from a recognised classification society stating that 9.3.1.27.1 and 9.3.1.27.4 above have been complied with shall be submitted together with the application for issue or renewal of the certificate of approval.

Water-spraysystem When water-spraying is required in column (9) of Table C of Chapter 3.2 a water-spray system shall be installed in the cargo area on deck for the purpose of reducing gases given off by the cargo by spraying water over the whole surface. The system shall be fitted with a connection device for supply from the shore. The spray nozzles shall be so installed that released gases are precipitated safely. The system shall be capable of being put into operation from the wheelhouse and from the deck. The capacity of the water-spray system shall be such that when all the spray nozzles are in operation, the outflow is of 50 litres per square metre of cargo deck area and per hour. (Reserved).

Engines Only internal combustion engines running on fuel with a flashpoint of more than 55 "C are allowed. Ventilation inlets of the engine room and, when the engines do not take in air directly fi-om the engine room, the air intakes of the engines shall be located not less than 2.00 m from the cargo area. Sparking shall not be possible within the cargo area. The surface temperature of the outer parts of engines used during loading or unloading operations, as well as that of their air inlets and exhaust ducts shall not exceed the allowable temperature according to the temperature class. This provision does not apply to engines installed in service spaces provided the provisions of 9.3.1.52.3 (b) are fully complied with. The ventilation in the closed engine room shall be designed so that, at an ambient temperature of 20 "C, the average temperature in the engine room does not exceed 40 "C. Oilfuel tanks When the vessel is fitted with hold spaces and double bottoms, double bottoms within the cargo area may be arranged as a liquid oil fuel tanks, provided their depth is not less than 0.60 m. Liquid oil fuel pipes and openings of such tanks are not permitted in the hold space. Open ends of air pipes of all liquid oil fuel tanks shall extend to not less than 0.5 m above the open deck. The open ends and the open ends of overflow pipes leading on the deck shall be fitted with a protective device consisting of a gauze diaphragm or a perforated plate. (Reserved). Exhaust pipes Exhausts shall be evacuated from the vessel into the open air either upwards through an exhaust pipe or through the shell plating. The exhaust outlet shall be located not less

- 363 -

than 2 m from the cargo area. The exhaust pipes of engines shall be arranged so that the exhausts are led away from the vessel. The exhaust pipes shall not be located within the cargo area. Exhaust pipes shall be provided with a device preventing the escape of sparks, e.g. spark arresters. Bilge pumping and ballasting arrangements

Bilge and ballast pumps for spaces within the cargo area shall be installed within such area. This provision does not apply to: -

double-hull spaces and double bottoms which do not have a common boundary wall with the cargo tanks; cofferdams and hold spaces where ballasting is carried out using the piping of the firefighting system in the cargo area and bilge-pumping is performed using educators.

Where the double bottom is used as a liquid oil fuel tank, it shall not be connected to the bilge piping system. Where the ballast pump is installed in the cargo area, the standpipe and its outboard connection for suction of ballast water shall be located within the cargo area. It shall be possible for an under-deck pump-room to be stripped in an emergency using a system located in the cargo area and independent of any other system. This stripping system shall be located outside the pump-room.

(Reserved). Fire-extinguishing arrangements A fire-extinguishing system shall be installed on the vessel.

This system shall comply with the following requirements: It shall be supplied by two independent fire or ballast pumps, one of which shall be ready for use at any time. These pumps and their means of propulsion and electrical equipment shall not be installed in the same space; -

It shall be provided with a water main fitted with at least three hydrants in the cargo area above deck. Three suitable and sufficiently long hoses with spray nozzles having a diameter of not less than 12 mm shall be provided. It shall be possible to reach any point of the deck in the cargo area simultaneously with at least two jets of water which do not emanate from the same hydrant. A spring-loaded non-return valve shall be fitted to ensure that no gases can escape through the fire-extinguishing system into the accommodation or service spaces outside the cargo area;

-

The capacity of the system shall be at least sufficient for a jet of water to have a minimum reach of not less than the vessel's breadth from any location on board with two spray nozzles being used at the same time.

In addition the engine rooms, the cargo pump-room and all spaces containing special equipment (switchboards, compressors, etc.) for the refrigerant equipment if any, shall be provided with a permanently fixed fire-extinguishing system meeting the following requirements: Extinguishing agents For the protection of spaces in engine rooms, boiler rooms and pump rooms, only permanently fixed fire-extinguishing systems using the following extinguishing agents are permitted: (a)

CO2 (carbon dioxide);

(b)

HFC 227 ea (heptafluoropropane);

(c)

IG-541 (52% nitrogen, 40% argon, 8% carbon dioxide).

Other extinguishing agents are permitted only on the basis of recommendations by the Administrative Committee. Ventilation, air extraction The combustion air required by the combustion engines which ensure propulsion should not come from spaces protected by permanently fixed fire-extinguishing systems. This requirement is not mandatory if the vessel has two independent main engine rooms with a gastight separation or if, in addition to the main engine room, there is a separate engine room installed with a bow thruster that can independently ensure propulsion in the event of a fire in the main engine room. All forced ventilation systems in the space to be protected shall be shut down automatically as soon as the fire-extinguishing system is activated. All openings in the space to be protected which permit air to enter or gas to escape shall be fitted with devices enabling them to be closed rapidly. It shall be clear whether they are open or closed. Air escaping from the pressure-relief valves of the pressurised air tanks installed in the engine rooms shall be evacuated to the open air. Overpressure or negative pressure caused by the diffusion of the extinguishing agent shall not destroy the constituent elements of the space to be protected. It shall be possible to ensure the safe equalisation of pressure. Protected spaces shall be provided with a means of extracting the extinguishing agent. If extraction devices are installed, it shall not be possible to start them up during extinguishing. Fire alarm system The space to be protected shall be monitored by an appropriate fire alarm system. The alarm signal shall be audible in the wheelhouse, the accommodation and the space to be protected. Piping system (a)

The extinguishing agent shall be routed to and distributed in the space to be protected by means of a permanent piping system. Piping installed in the space to be protected

- 365 -

and the reinforcements it incorporates shall be made of steel. This shall not apply to the connecting nozzles of tanks and compensators provided that the materials used have equivalent fire-retardant properties. Piping shall be protected against corrosion both internally and externally. (b) 9.3.1.40.2.5

The discharge nozzles shall be so arranged as to ensure the regular diffusion of the extinguishing agent.

Triggering device (a)

Automatically activated fire-extinguishing systems are not permitted.

(b)

It shall be possible to activate the fire-extinguishing system from a suitable point located outside the space to be protected.

(c)

Triggering devices shall be so installed that they can be activated in the event of a fire and so that the risk of their breakdown in the event of a fire or an explosion in the space to be protected is reduced as far as possible. Systems which are not mechanically activated shall be supplied from two energy sources independent of each other. These energy sources shall be located outside the space to be protected. The control lines located in the space to be protected shall be so designed as to remain capable of operating in the event of a fire for a minimum of 30 minutes. The electrical installations are deemed to meet this requirement if they conform to the IEC 6033 1-21:1999 standard. When the triggering devices are so placed as not to be visible, the component concealing them shall carry the "Fire-fighting system" symbol, each side being not less than 10 cm in length, with the following text in red letters on a white ground:

Fire-extinguishing system (d)

If the fire-extinguishing system is intended to protect several spaces, it shall comprise a separate and clearly-marked triggering device for each space.

(e)

The instructions shall be posted alongside all triggering devices and shall be clearly visible and indelible. The instructions shall be in a language the master can read and understand and if this language is not English, French or German, they shall be in English, French or German. They shall include information concerning:

(0

(i)

the activation of the fire-extinguishing system;

(ii)

the need to ensure that all persons have left the space to be protected;

(iii)

the correct behaviour of the crew in the event of activation;

(iv)

the correct behaviour of the crew in the event of the failure of the fire-extinguishing system to function properly.

The instructions shall mention that prior to the activation of the fire-extinguishing system, combustion engines installed in the space and aspirating air from the space to be protected, shall be shut down.

Alarm device Permanently fixed fire-extinguishing systems shall be fitted with an audible and visual alarm device. The alarm device shall be set off automatically as soon as the fire-extinguishing system is first activated. The alarm device shall function for an appropriate period of time before the extinguishing agent is released; it shall not be possible to turn it off. Alarm signals shall be clearly visible in the spaces to be protected and their access points and be clearly audible under operating conditions corresponding to the highest possible sound level. It shall be possible to distinguish them clearly from all other sound and visual signals in the space to be protected. Sound alarms shall also be clearly audible in adjoining spaces, with the communicating doors shut, and under operating conditions corresponding to the highest possible sound level. If the alarm device is not intrinsically protected against short circuits, broken wires and drops in voltage, it shall be possible to monitor its operation.

A sign with the following text in red letters on a white ground shall be clearly posted at the entrance to any space the extinguishing agent may reach: Warning, fire-extinguishing system! Leave this space immediately when the ... (description) alarm is activated! Pressurised tanks, jttings and piping Pressurised tanks, fittings and piping shall conform to the requirements of the competent authority. Pressurised tanks shall be installed in accordance with the manufacturer's instructions. Pressurised tanks, fittings and piping shall not be installed in the accommodation. The temperature of cabinets and storage spaces for pressurised tanks shall not exceed 50 "C. Cabinets or storage spaces on deck shall be securely stowed and shall have vents so placed that in the event of a pressurised tank not being gastight, the escaping gas cannot penetrate into the vessel. Direct connections with other spaces are not permitted. Quantity of extinguishing agent If the quantity of extinguishing agent is intended for more than one space, the quantity of extinguishing agent available does not need to be greater than the quantity required for the largest of the spaces thus protected. Installation, maintenance, monitoring and documents (a)

The mounting or modification of the system shall only be performed by a company specialised in fire-extinguishing systems. The instructions (product data sheet, safety data sheet) provided by the manufacturer of the extinguishing agent or the system shall be followed.

(b)

The system shall be inspected by an expert: (i)

before being brought into service;

(ii)

each time it is put back into service after activation;

(iii)

after every modification or repair;

(iv)

regularly, not less than every two years.

(c)

During the inspection, the expert is required to check that the system conforms to the requirements of 9.3.1.40.2.

(d)

The inspection shall include, as a minimum: (i)

an external inspection of the entire system;

(ii)

an inspection to ensure that the piping is leakproof;

(iii)

an inspection to ensure that the control and activation systems are in good working order;

(iv)

an inspection of the pressure and contents of tanks;

(v)

an inspection to ensure that the means of closing the space to be protected are leakproof;

(vi)

an inspection of the fire alarm system;

(vii) an inspection of the alarm device.

9.3.1.40.2.10

(e)

The person performing the inspection shall establish, sign and date a certificate of inspection.

(f)

The number of permanently fixed fire-extinguishing systems shall be mentioned in the inspection certificate.

Fire-extinguishing system operating with CO2 In addition to the requirements contained in 9.3.1.40.2.1 to 9.3.1.40.2.9, fire-extinguishing systems using CO2 as an extinguishing agent shall conform to the following provisions: Tanks of CO2 shall be placed in a gastight space or cabinet separated from other spaces. The doors of such storage spaces and cabinets shall open outwards; they shall be capable of being locked and shall carry on the outside the symbol "Warning: danger", not less than 5 cm high and "CO2" in the same colours and the same size; Storage cabinets or spaces for C02 tanks located below deck shall only be accessible from the outside. These spaces shall have an artificial ventilation system with extractor hoods and shall be completely independent of the other ventilation systems on board; The level of filling of CO2 tanks shall not exceed 0.75 kgll. The volume of depressurised CO2 shall be taken to be 0.56 m3/kg;

9.3.1.40.2.1 1

(d)

The concentration of CO2 in the space to be protected shall be not less than 40% of the gross volume of the space. This quantity shall be released within 120 seconds. It shall be possible to monitor whether diffusion is proceeding correctly;

(e)

The opening of the tank valves and the control of the diffusing valve shall correspond to two different operations;

(f)

The appropriate period of time mentioned in 9.3.1.40.2.6 (b) shall be not less than 20 seconds. A reliable installation shall ensure the timing of the diffusion of COz.

Fire-extinguishing system operating with HFC-227 ea (heptajluoropropane) In addition to the requirements of 9.1 .O.40.2.1 to 9.1 .O.40.2.9, fire-extinguishing systems using HFC-227 ea as an extinguishing agent shall conform to the following provisions: Where there are several spaces with different gross volumes, each space shall be equipped with its own fire-extinguishing system; Every tank containing HFC-227 ea placed in the space to be protected shall be fitted with a device to prevent overpressure. This device shall ensure that the contents of the tank are safely diffused in the space to be protected if the tank is subjected to fire, when the fire-extinguishing system has not been brought into service; Every tank shall be fitted with a device permitting control of the gas pressure; The level of filling of tanks shall not exceed 1.15 kg/l. The specific volume of depressurised HFC-227 ea shall be taken to be 0.1374 m3/kg; The concentration of HFC-227 ea in the space to be protected shall be not less than 8% of the gross volume of the space. This quantity shall be released within 10 seconds; Tanks of HFC-227 ea shall be fitted with a pressure monitoring device which triggers an audible and visual alarm in the wheelhouse in the event of an unscheduled loss of propellant gas. Where there is no wheelhouse, the alarm shall be triggered outside the space to be protected; After discharge, the concentration in the space to be protected shall not exceed 10.5% (volume); The fire-extinguishing system shall not comprise aluminium parts.

9.3.1.40.2.12

Fire-extinguishing system operating with IG-541 In addition to the requirements of 9.3.1.40.2.1 to 9.3.1.40.2.9, fire-extinguishing systems using IG-541 as an extinguishing agent shall conform to the following provisions: (a)

Where there are several spaces with different gross volumes, every space shall be equipped with its own fire-extinguishing system;

(b)

Every tank containing IG-541 placed in the space to be protected shall be fitted with a device to prevent overpressure. This device shall ensure that the contents of the tank are safely diffused in the space to be protected if the tank is subjected to fire, when the fire-extinguishing system has not been brought into service;

(c)

Each tank shall be fitted with a device for checking the contents;

- 369 -

9.3.1.40.2.13

(d)

The filling pressure of the tanks shall not exceed 200 bar at a temperature of + l 5 "C;

(e)

The concentration of IG-541 in the space to be protected shall be not less than 44% and not more than 50% of the gross volume of the space. This quantity shall be released within 120 seconds.

Fire-extinguishing system for physicalprotection In order to ensure physical protection in the engine rooms, boiler rooms and pump rooms, fire-extinguishing systems are accepted solely on the basis of recommendations by the Administrative Committee. The two hand fire-extinguishers referred to in 8.1.4 shall be located in the cargo area. The fire-extinguishing agent and the quantity contained in the permanently fixed fireextinguishing system shall be suitable and sufficient for fighting fires. Fire and naked light

The outlets of funnels shall be located not less than 2.00 m from the cargo area. Arrangements shall be provided to prevent the escape of sparks and the entry of water. Heating, cooking and refrigerating appliances shall not be fuelled with liquid fuels, liquid gas or solid fuels. The installation in the engine room or in another separate space of heating appliances fuelled with liquid fuel having a flash-point above 55 "C is, however, permitted. Cooking and refrigerating appliances are permitted only in the accommodation. Only electrical lighting appliances are permitted.

(Reserved).

Documents concerning electrical installations

In addition to the documents required by the Regulations referred to in 1.1.4.6, the following documents shall be on board: (a)

a drawing indicating the boundaries of the cargo area and the location of the electrical equipment installed in this area;

(b)

a list of the electrical equipment referred to in (a) above including the following particulars: machine or appliance, location, type of protection, type of protection against explosion, testing body and approval number;

(c)

a list of or general plan indicating the electrical equipment outside the cargo area which may be operated during loading, unloading or gas-freeing. All other electrical equipment shall be marked in red. See 9.3.1 S2.3 and 9.3.1S2.4.

The documents listed above shall bear the stamp of the competent authority issuing the certificate of approval.

- 370 -

Electrical installations Only distribution systems without return connection to the hull are permitted. This provision does not apply to:

-

electric corrosion protection against external currents;

-

local installations outside the cargo area (e.g. connections of starters of diesel engines);

-

the device for checking the insulation level referred to in 9.3.1.5 1.2 below.

Every insulated distribution network shall be fitted with an automatic device with a visual and audible alarm for checking the insulation level. For the selection of electrical equipment to be used in zones presenting an explosion risk, the explosion groups and temperature classes assigned to the substances carried in the list of substances shall be taken into consideration (See columns (15) and (16) of Table C of Chapter 3.2). Type and location of electrical equipment Only the following equipment may be installed in cargo tanks and pipes for loading and unloading (comparable to zone 0): -

measuring, regulation and alarm devices of the EEx (ia) type of protection.

Only the following equipment may be installed in the cofferdams, double-hull spaces, double bottoms and hold spaces (comparable to zone 1): -

measuring, regulation and alarm devices of the certified safe type;

-

lighting appliances of the "flame-proof enclosure" or "apparatus protected by pressurization" type of protection;

-

hermetically sealed echo sounding devices the cables of which are led through thick-walled steel tubes with gastight connections up to the main deck;

-

cables for the active cathodic protection of the shell plating in protective steel tubes such as those provided for echo sounding devices.

Only the following equipment may be installed in the service spaces in the cargo area below deck (comparable to zone 1): -

measuring, regulation and alarm devices of the certified safe type;

-

lighting appliances of the "flame-proof enclosure" or "apparatus protected by pressurization" type of protection;

-

motors driving essential equipment such as ballast pumps; they shall be of the certified safe type.

The control and protective equipment of the electrical equipment referred to in (a), (b) and (c) above shall be located outside the cargo area if they are not intrinsically safe.

- 371 -

(e)

The electrical equipment in the cargo area on deck (comparable to zone 1) shall be of the certified safe type.

9.3.1S2.2

Accumulators shall be located outside the cargo area.

9.3.1S2.3

(a)

Electrical equipment used during loading, unloading and gas-heeing during berthing and which are located outside the cargo area (comparable to zone 2) shall be at least of the "limited explosion risk" type.

(b)

This provision does not apply to: (i)

lighting installations in the accommodation, except for switches near entrances to accommodation;

(ii)

radiotelephone installations in the accommodation or the wheelhouse;

(iii)

mobile and fixed telephone installations in the accommodation or the wheelhouse;

(iv)

electrical installations in the accommodation, the wheelhouse or the service spaces outside the cargo areas if: 1.

These spaces are fitted with a ventilation system ensuring an overpressure of 0.1 kPa (0.001 bar) and none of the windows is capable of being opened; the air intakes of the ventilation system located as far away as possible, however, not less than 6.00 m from the cargo area and not less than 2.00 m above the deck;

2.

The spaces are fitted with a gas detection system with sensors: -

at the suction inlets of the ventilation system;

-

directly at the top edge of the sill of the entrance doors of the accommodation and service spaces;

3.

The gas concentration measurement is continuous;

4.

When the gas concentration reaches 20% of the lower explosive limit, the ventilators shall be switched off. In such a case and when the overpressure is not maintained or in the event of failure of the gas detection system, the electrical installations which do not comply with (a) above, shall be switched off. These operations shall be performed immediately and automatically and activate the emergency lighting in the accommodation, the wheelhouse and the service spaces, which shall comply at least with the "limited explosion risk" type. The switching-off shall be indicated in the accommodation and wheelhouse by visual and audible signals;

5.

The ventilation system, the gas detection system and the alarm of the switch-off device fully comply with the requirements of (a) above;

6.

The automatic switch-off device is set so that no automatic switching-off may occur while the vessel is under way.

The electrical equipment which does not meet the requirements set out in 9.3.1S2.3 above together with its switches shall be marked in red. The disconnection of such equipment shall be operated from a centralised location on board. An electric generator which is permanently driven by an engine and which does not meet the requirements of 9.3.1.52.3 above, shall be fitted with a switch capable of shutting down the excitation of the generator. A notice board with the operating instructions shall be displayed near the switch. Sockets for the connection of signal lights and gangway lighting shall be permanently fitted to the vessel close to the signal mast or the gangway. Connecting and disconnecting shall not be possible except when the sockets are not live. The failure of the power supply for the safety and control equipment shall be immediately indicated by visual and audible signals at the locations where the alarms are usually actuated. Earthing

The metal parts of electrical appliances in the cargo area which are not live as well as protective metal tubes or metal sheaths of cables in normal service shall be earthed, unless they are so arranged that they are automatically earthed by bonding to the metal structure of the vessel. The provisions of 9.3.1.53.1 above apply also to equipment having service voltages of less than 50 V. Independent cargo tanks shall be earthed. Metal intermediate bulk containers (IBCs) and tank-containers, used as residual cargo tanks or slop tanks, shall be capable of being earthed. (Reserved).

Electrical cables

All cables in the cargo area shall have a metallic sheath. Cables and sockets in the cargo area shall be protected against mechanical damage. Movable cables are prohibited in the cargo area, except for intrinsically safe electric circuits or for the supply of signal lights and gangway lighting. Cables of intrinsically safe circuits shall only be used for such circuits and shall be separated from other cables not intended for being used in such circuits (e.g. they shall not be installed together in the same string of cables and they shall not be fixed by the same cable clamps). For movable cables intended for signal lights and gangway lighting, only sheathed cables of type H 07 RN-F in accordance with IEC publication 60 245-4 (1994) or cables of at least equivalent design having conductors with a cross-section of not less than 1.5 mm2 shall be used. These cables shall be as short as possible and installed so that damage is not likely to occur.

The cables required for the electrical equipment referred to in 9.3.1.52.1 (b) and (c) are accepted in cofferdams, double-hull spaces, double bottoms, hold spaces and service spaces below deck. (Reserved).

Special equipment

A shower and an eye and face bath shall be provided on the vessel at a location which is directly accessible from the cargo area. (Reserved). Admittance on board

The notice boards displaying the prohibition of admittance in accordance with 8.3.3 shall be clearly legible from either side of the vessel. (Reserved). Prohibition of smoking, fire or naked light

The notice boards displaying the prohibition of smoking in accordance with 8.3.4 shall be clearly legible from either side of the vessel. Notice boards indicating the circumstances under which the prohibition is applicable shall be fitted near the entrances to the spaces where smoking or the use of fire or naked light is not always prohibited. Ashtrays shall be provided close to each exit of the accommodation and the wheelhouse. (Reserved). Emergency exit

Spaces the entrances or exits of which are likely to become partly or completely immersed in the damaged condition shall have an emergency exit which is situated not less than 0.10 m above the damage waterline. This does not apply to forepeak and afterpeak. (Reserved). Rules for construction of type C tank vessels

The rules for construction of 9.3.2.0 to 9.3.2.99 apply to type C tank vessels. Materials of construction

(a)

The vessel's hull and the cargo tanks shall be constructed of shipbuilding steel or other at least equivalent metal.

The independent cargo tanks may also be constructed of other materials, provided these have at least equivalent mechanical properties and resistance against the effects of temperature and fire. (b)

Every part of the vessel including any installation and equipment which may come into contact with the cargo shall consist of materials which can neither be dangerously affected by the cargo nor cause decomposition of the cargo or react with it so as to form harmful or hazardous products.

(c)

Inside vapour pipes and gas discharge pipes shall be protected against corrosion.

9.3.2.0.2

Except where explicitly permitted in 9.3.2.0.3 below or in the certificate of approval, the use of wood, aluminium alloys or plastic materials within the cargo area is prohibited.

9.3.2.0.3

(a)

The use of wood, aluminium alloys or plastic materials within the cargo area is only permitted for: -

gangways and external ladders;

-

movable items of equipment (aluminium gauging rods are, however permitted, provided that they are fitted with brass feet or protected in another way to avoid sparking);

-

chocking of cargo tanks which are independent of the vessel's hull and chocking of installations and equipment; masts and similar round timber;

(b)

-

engine parts;

-

parts of the electrical installation;

-

loading and unloading appliances;

-

lids of boxes which are placed on the deck.

The use of wood or plastic materials within the cargo area is only permitted for: -

(c)

(d)

supports and stops of any kind.

The use of plastic materials or rubber within the cargo area is only permitted for: -

coating of cargo tanks and of pipes for loading and unloading;

-

all kinds of gaskets (e.g. for dome or hatch covers);

-

electric cables;

-

hoses for loading and unloading;

-

insulation of cargo tanks and of hoses for loading and unloading.

All permanently fitted materials in the accommodation or wheelhouse, with the exception of furniture, shall not readily ignite. They shall not evolve fumes or toxic gases in dangerous quantities, if involved in a fire.

The paint used in the cargo area shall not be liable to produce sparks in case of impact. The use of plastic material for vessel's boats is permitted only if the material does not readily ignite. (Reserved).

Classification

The tank vessel shall be built under survey of a recognised classification society in accordance with the rules established by that classification society for its highest class, and the tank vessel shall be classed accordingly. The vessel's class shall be continued. The classification society shall issue a certificate certifying that the vessel is in conformity with the rules of this section. The design pressure and the test pressure of cargo tanks shall be entered in the certificate. If a vessel has cargo tanks with different valve opening pressures, the design and test pressures of each tank shall be entered in the certificate. The classification society shall draw up a certificate mentioning all the dangerous goods accepted for carriage by the vessel (see also 1.16.1.2.5). The cargo pump-rooms shall be inspected by a recognised classification society whenever the certificate of approval has to be renewed as well as during the third year of validity of the certificate of approval. The inspection shall comprise at least: -

an inspection of the whole system for its condition, for corrosion, leakage or conversion works which have not been approved;

-

a checking of the condition of the gas detection system in the cargo pump-rooms.

Inspection certificates signed by the recognised classification society with respect to the inspection of the cargo pump-rooms shall be kept on board. The inspection certificates shall at least include particulars of the above inspection and the results obtained as well as the date of the inspection. The condition of the gas detection system referred to in 9.3.2.52.3 (b) shall be checked by a recognised classification society whenever the certificate of approval has to be renewed and during the third year of validity of the certificate of approval. A certificate signed by the recognised classification society shall be kept on board. (Reserved). Protection against the penetration of gases

The vessel shall be designed so as to prevent gases from penetrating into the accommodation and the service spaces. Outside the cargo area, the lower edges of door-openings in the sidewalls of superstructures and the coamings of access hatches to under-deck spaces shall have a height of not less than 0.50 m above the deck.

This requirement need not be complied with if the wall of the superstructures facing the cargo area extends from one side of the ship to the other and has doors the sills of which have a height of not less than 0.50 m. The height of this wall shall be not less than 2.00 m. In this case, the lower edges of door-openings in the sidewalls of superstructures and of coamings of access hatches behind this wall shall have a height of not less than 0.10 m. The sills of engine-room doors and the coamings of its access hatches shall, however, always have a height of not less than 0.50 m. 9.3.2.10.3

In the cargo area, the lower edges of door-openings in the sidewalls of superstructures shall have a height of not less than 0.50 m above the deck and the sills of hatches and ventilation openings of premises located under the deck shall have a height of not less than 0.50 m above the deck. This requirement does not apply to access openings to double-hull and double bottom spaces.

9.3.2.10.4

The bulwarks, foot-rails, etc. shall be provided with sufficiently large openings which are located directly above the deck.

9.3.2.11

Hold spaces and cargo tanks

The maximum permissible capacity of a cargo tank shall be determined in accordance with the following table: LXBXH(~~)

Maximum permissible capacity of a cargo tank (m3)

up to 600

LxBxHx0.3

600 to 3 750

180+ ( L x B x H - 600) x0.0635

> 3 750

380

In the table above L X B X H is the product of the main dimensions of the tank vessel in metres (according to the measurement certificate), where:

L B H

=

= =

overall length of the hull; extreme breadth of the hull; shortest vertical distance between the top of the keel and the lowest point of the deck at the side of the vessel (moulded depth) within the cargo area.

The relative density of the substances to be carried shall be taken into consideration in the design of the cargo tanks. The maximum relative density shall be indicated in the certificate of approval. When the vessel is provided with pressure cargo tanks, these tanks shall be designed for a working pressure of 400 kPa (4 bar). For vessels with a length of not more than 50.00 m, the length of a cargo tank shall not exceed 10.00 m; and For vessels with a length of more than 50.00 m, the length of a cargo tank shall not exceed 0.20 L. This provision does not apply to vessels with independent built-in cylindrical tanks 7. having a length to diameter ratio I 9.3.2.1 1.2

(a)

In the cargo area (except cofferdams) the vessel shall be designed as a flush-deck double-hull vessel, with double-hull spaces and double bottoms, but without a trunk. - 377 -

Cargo tanks independent of the vessels' hull and refrigerated cargo tanks may only be installed in a hold space which is bounded by double-hull spaces and double bottoms in accordance with 9.3.2.1 1.7 below. The cargo tanks shall not extend beyond the deck. The cargo tanks independent of the vessel's hull shall be fixed so that they cannot float. The capacity of a suction well shall be limited to not more than 0.10 m3. Side-stringers linking or supporting the load-bearing components of the sides of the vessel with the load-bearing components of the longitudinal walls of cargo tanks and side-stringers linking the load-bearing components of the vessel's bottom with the tank-bottom are prohibited. The cargo tanks shall be separated by cofferdams of at least 0.60 m in width from the accommodation, engine room and service spaces outside the cargo area below deck or, if there are no such accommodation, engine room and service spaces, from the vessel's ends. Where the cargo tanks are installed in a hold space, a space of not less than 0.50 m shall be provided between such tanks and the end bulkheads of the hold space. In this case an insulated end bulkhead meeting at least the definition for Class "A-60" according to SOLAS 74, Chapter 11-2, Regulation 3, shall be deemed equivalent to a cofferdam. For pressure cargo tanks, the 0.50 m distance may be reduced to 0.20 m. Hold spaces, cofferdams and cargo tanks shall be capable of being inspected. All spaces in the cargo area shall be capable of being ventilated. Means for checking their gas-free condition shall be provided. 9.3.2.1 1.4

The bulkheads bounding the cargo tanks, cofferdams and hold spaces shall be watertight. The cargo tanks and the bulkheads bounding the cargo area shall have no openings or penetrations below deck. The bulkhead between the engine room and the cofferdam or service space in the cargo area or between the engine room and a hold space may be fitted with penetrations provided that they conform to the provisions of 9.3.2.1.7.5. The bulkhead between the cargo tank and the cargo pump-room below deck may be fitted with penetrations provided that they conform to the provisions of 9.3.2.1.7.6. The bulkheads between the cargo tanks may be fitted with passages provided that the unloading pipes are fitted with shut-off devices in the cargo tank from which they come.

9.3.2.1 1.5

Double-hull spaces and double bottoms in the cargo area shall be arranged for being filled with ballast water only. Double bottoms may, however, be used as oil fuel tanks, provided they comply with the provisions of 9.3.2.32.

9.3.2.1 1.6

(a)

A cofferdam, the centre part of a cofferdam or another space below deck in the cargo area may be arranged as a service space, provided the bulkheads bounding the service space extend vertically to the bottom. This service space shall only be accessible from the deck.

(b)

The service space shall be watertight with the exception of its access hatches and ventilation inlets.

(c)

No pipes for loading and unloading shall be fitted within the service space referred to under (a) above. Pipes for loading and unloading may be fitted in the cargo pump-rooms below deck only when they conform to the provisions of 9.3.2.17.6.

9.3.2.1 1.7

For double-hull construction with the cargo tanks integrated in the vessel's structure, the distance between the side wall of the vessel and the longitudinal bulkhead of the cargo tanks shall be not less than 1.OO m. A distance of 0.80 m may however be permitted, provided that, compared with the scantling requirements specified in the rules for construction of a recognised classification society, the following reinforcements have been made: (a)

25% increase in the thickness of the deck stringer plate;

(b)

15% increase in the side plating thickness;

(c)

Arrangement of a longitudinal framing system at the vessel's side, where depth of the longitudinals shall be not less than 0.15 m and the longitudinals shall have a face plate with the cross-sectional area of at least 7.0 cm2.

(d)

The stringer or longitudinal framing systems shall be supported by web frames, and like bottom girders fitted with lightening holes, at a maximum spacing of 1.80 m. These distances may be increased if the longitudinals are strengthened accordingly.

When a vessel is built according to the transverse framing system, a longitudinal stringer system shall be arranged instead of (c) above. The distance between the longitudinal stringers shall not exceed 0.80 m and their depth shall be not less than 0.15 m, provided they are completely welded to the frames. The cross-sectional area of the facebar or faceplate shall be not less than 7.0 cm2 as in (c) above. Where cut-outs are arranged in the stringer at the connection with the frames, the web depth of the stringer shall be increased with the depth of cut-outs. The mean depth of the double bottoms shall be not less than 0.70 m. It shall, however, never be less than 0.60 m. The depth below the suction wells may be reduced to 0.50 m. 9.3.2.1 1.8

When a vessel is built with cargo tanks located in a hold space or refrigerated cargo tanks, the distance between the double walls of the hold space shall be not less than 0.80 m and the depth of the double bottom shall be not less than 0.60 m.

9.3.2.11.9

Where service spaces are located in the cargo area under deck, they shall be arranged so as to be easily accessible and to permit persons wearing protective clothing and breathing apparatus to safely operate the service equipment contained therein. They shall be designed so as to allow injured or unconscious personnel to be removed from such spaces without difficulties, if necessary by means of fixed equipment.

9.3.2.1 1.10

Cofferdams, double-hull spaces, double bottoms, cargo tanks, hold spaces and other accessible spaces within the cargo area shall be arranged so that they may be completely inspected and cleaned in an appropriate manner. The dimensions of openings except for those of double-hull spaces and double bottoms which do not have a wall adjoining the cargo tanks shall be sufficient to allow a person wearing breathing apparatus to enter or leave the space without difficulties. These openings shall have a minimum cross-sectional area of 0.36 m2 and a minimum side length of 0.50 m. They shall be designed so as to allow injured or unconscious personnel to be removed from the bottom of such a space without difficulties, if necessary by means of fixed equipment. In these spaces the distance between

the reinforcements shall not be less than 0.50 m. In double bottoms this distance may be reduced to 0.45 m. Cargo tanks may have circular openings with a diameter of not less than 0.68 m. Ventilation

Each hold space shall have two openings the dimensions and location of which shall be such as to permit effective ventilation of any part of the hold space. If there are no such openings, it shall be possible to fill the hold spaces with inert gas or dry air. Double-hull spaces and double bottoms within the cargo area which are not arranged for being filled with ballast water, hold spaces and cofferdams shall be provided with ventilation systems. Any service spaces located in the cargo area below deck shall be provided with a system of forced ventilation with sufficient power for ensuring at least 20 changes of air per hour based on the volume of the space. The ventilation exhaust ducts shall extend down to 50 mm above the bottom of the service space. The air shall be supplied through a duct at the top of the service space. The air inlets shall be located not less than 2.00 m above the deck, at a distance of not less than 2.00 m from tank openings and 6.00 m from the outlets of safety valves. The extension pipes, which may be necessary, may be of the hinged type. Ventilation of accommodation and service spaces shall be possible. Ventilators used in the cargo area shall be designed so that no sparks may be emitted on contact of the impeller blades with the housing and no static electricity may be generated. Notice boards shall be fitted at the ventilation inlets indicating the conditions when they shall be closed. Any ventilation inlets of accommodation and service spaces leading outside shall be fitted with fire flaps. Such ventilation inlets shall be located not less than 2.00 m from the cargo area. Ventilation inlets of service spaces in the cargo area below deck may be located within such area. The flame-arresters prescribed in 9.3.2.20.4, 9.3.2.22.4, 9.3.2.22.5 and 9.3.2.26.4 shall be of a type approved for this purpose by the competent authority. Stability (general)

Proof of sufficient stability shall be furnished including for stability in damaged condition. The basic values for the stability calculation - the vessel's lightweight and location of the centre of gravity - shall be determined either by means of an inclining experiment or by detailed mass and moment calculation. In the latter case the lightweight of the vessel shall be checked by means of a lightweight test with a tolerance limit of 5% between the mass determined by calculation and the displacement determined by the draught readings.

*

Proof of sufficient intact stability shall be furnished for all stages of loading and unloading and for the final loading condition.

Floatability after damage shall be proved for the most unfavourable loading condition. For this purpose, calculated proof of sufficient stability shall be established for critical intermediate stages of flooding and for the final stage of flooding. Negative values of stability in intermediate stages of flooding may be accepted only if the continued range of curve of righting lever in damaged condition indicates adequate positive values of stability. 9.3.2.14

Stability (intact)

9.3.2.14.1

The requirements for intact stability resulting from the damage stability calculation shall be fully complied with. 9.3.2.14.2 For vessels with cargo tanks of more than 0.70 B in width, proof shall be hrnished that the following stability requirements have been complied with: (a)

In the positive area of the righting lever curve up to immersion of the first nonwatertight opening there shall be a righting lever (GZ) of not less than 0.10 m;

(b)

The surface of the positive area of the righting lever curve up to immersion of the first non-watertight opening and in any event up to an angle of heel 5 27" shall not be less than 0.024 m.rad;

The metacentric height (GM) shall be not less than 0.10 m. (c) These conditions shall be met bearing in mind the influence of all free surfaces in tanks for all stages of loading and unloading. 9.3.2.14.3

The most stringent requirement of 9.3.2.14.1 and 9.3.2.14.2 is applicable to the vessel.

9.3.2.15

Stability (damaged condition)

9.3.2.15.1

The following assumptions shall be taken into consideration for the damaged condition: The extent of side damage is as follows: longitudinal extent: transverse extent: vertical extent:

at least 0.10 L, but not less than 5.00 m; 0.79 m; from the base line upwards without limit.

The extent of bottom damage is as follows: longitudinal extent: transverse extent: vertical extent:

at least 0.10 L, but not less than 5.00 m; 3.00 m; from the base 0.59 m upwards, the sump excepted.

Any bulkheads within the damaged area shall be assumed damaged, which means that the location of bulkheads shall be chosen so as to ensure that the vessel remains afloat after the flooding of two or more adjacent compartments in the longitudinal direction. The following provisions are applicable: -

For bottom damage, adjacent athwartship compartments shall also be assumed as flooded;

-

The lower edge of any non-watertight openings (e.g. doors, windows, access hatchways) shall, at the final stage of flooding, be not less than 0.10 m above the damage waterline;

-

In general, permeability shall be assumed to be 95%. Where an average permeability of less than 95% is calculated for any compartment, this calculated value obtained may be used.

However, the following minimum values shall be used:

-

-

engine rooms:

85%;

accommodation:

95%;

double bottoms, oil fuel tanks, ballast tanks, etc., depending on whether, according to their function, they have to be assumed as full or empty for the vessel floating at the maximum permissible draught:

0% or 95%.

For the main engine room only the one-compartment standard need be taken into account, i.e. the end bulkheads of the engine room shall be assumed as not damaged. 9.3.2.15.2

At the stage of equilibrium (final stage of flooding), the angle of heel shall not exceed 12". Non-watertight openings shall not be flooded before reaching the stage of equilibrium. If such openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purpose of the stability calculation. The positive range of the righting lever curve beyond the stage of equilibrium shall have a righting lever of > 0.05 m in association with an area under the curve of > 0.0065 m.rad. The minimum values of stability shall be satisfied up to immersion of the first non-watertight opening and in any event up to an angle of heel 5 27". If non-watertight openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purposes of stability calculation.

V'

Equihiriurn position (Final buoyancy position)

y ~ i r s floodable t non-weathertight however 27"

9.3.2.15.3

If openings through which undamaged compartments may additionally become flooded are capable of being closed watertight, the closing appliances shall be marked accordingly.

9.3.2.15.4

Where cross- or down-flooding openings are provided for reduction of unsymmetrical flooding, the time for equalisation shall not exceed 15 minutes, if during the intermediate stages of flooding sufficient stability has been proved. - 382 -

Engine rooms Internal combustion engines for the vessel's propulsion as well as internal combustion engines for auxiliary machinery shall be located outside the cargo area. Entrances and other openings of engine rooms shall be at a distance of not less than 2.00 m from the cargo area. The engine rooms shall be accessible from the deck; the entrances shall not face the cargo area. Where the doors are not located in a recess whose depth is at least equal to the door width, the hinges shall face the cargo area. Accommodation and service spaces Accommodation spaces and the wheelhouse shall be located outside the cargo area forward of the fore vertical plane or abaft the aft vertical plane bounding the part of cargo area below deck. Windows of the wheelhouse which are located not less than 1.00 m above the bottom of the wheelhouse may tilt forward. Entrances to spaces and openings of superstructures shall not face the cargo area. Doors opening outward and not located in a recess the depth of which is at least equal to the width of the doors shall have their hinges face the cargo area. Entrances from the deck and openings of spaces facing the weather shall be capable of being closed. The following instruction shall be displayed at the entrance of such spaces: Do not open during loading and unloading without the permission of the master. Close immediately.

Entrances and windows of superstructures and accommodation spaces which can be opened as well as other openings of these spaces shall be located not less than 2.00 m from the cargo area. No wheelhouse doors and windows shall be located within 2.00 m from the cargo area, except where there is no direct connection between the wheelhouse and the accommodation. (a)

Driving shafts of the bilge or ballast pumps in the cargo area may penetrate through the bulkhead between the service space and the engine room, provided the arrangement of the service space is in compliance with 9.3.2.1 1.6.

(b)

The penetration of the shaft through the bulkhead shall be gastight and shall have been approved by a recognised classification society.

(c)

The necessary operating instructions shall be displayed.

(d)

Penetrations through the bulkhead between the engine room and the service space in the cargo area and the bulkhead between the engine room and the hold spaces may be provided for electrical cables, hydraulic and piping for measuring, control and alarm systems, provided that the penetration have been approved by a recognised classification society. The penetrations shall be gastight. Penetrations through a bulkhead with an "A-60" fire protection insulation according to SOLAS 74, Chapter 11-2, Regulation 3, shall have an equivalent fire protection.

(e)

Pipes may penetrate the bulkhead between the engine room and the service space in the cargo area provided that these are pipes between the mechanical equipment in the engine room and the service space which do not have any openings within the service space and which are provided with shut-off devices at the bulkhead in the engine room.

9.3.2.17.6

(f)

Notwithstanding 9.3.2.11.4, pipes from the engine room may pass through the service space in the cargo area or a cofferdam or a hold space or a double-hull space to the outside provided that within the service space or cofferdam or hold space or doublehull space they are of the thick-walled type and have no flanges or openings.

(g)

Where a driving shaft of auxiliary machinery penetrates through a wall located above the deck the penetration shall be gastight.

A service space located within the cargo area below deck shall not be used as a cargo pumproom for the loading and unloading system, except where: -

the pump room is separated from the engine room or from service spaces outside the cargo area by a cofferdam or a bulkhead with an "A-60 fire protection insulation according to SOLAS 74, Chapter 11-2, Regulation 3, or by a service space or a hold space;

-

the "A-60" bulkhead required above does not include penetrations referred to in 9.3.2.17.5 (a);

-

ventilation exhaust outlets are located not less than 6.00 m from entrances and openings of the accommodation and service spaces outside the cargo area;

-

the access hatches and ventilation inlets can be closed from the outside;

-

all pipes for loading and unloading as well as those of stripping systems are provided with shut-off devices at the pump suction side in the cargo pump-room immediately at the bulkhead. The necessary operation of the control devices in the pump-room, starting of pumps and control of the liquid flow rate shall be effected from the deck;

-

the bilge of the cargo pump-room is equipped with a gauging device for measuring the filling level which activates a visual and audible alarm in the wheelhouse when liquid is accumulating in the cargo pump-room bilge;

-

the cargo pump-room is provided with a permanent gas-detection system which automatically indicates the presence of explosive gases or lack of oxygen by means of direct-measuring sensors and which actuates a visual and audible alarm when the gas concentration has reached 20% of the lower explosive limit. The sensors of this system shall be placed at suitable positions at the bottom and directly below the deck. Measurement shall be continuous. The audible and visual alarms are installed in the wheelhouse and in the cargo pump-room and, when the alarm is actuated, the loading and unloading system is shut down. Failure of the gas detection system shall be immediately signalled in the wheelhouse and on deck by means of audible and visual alarms;

-

9.3.2.17.7

the ventilation system prescribed in 9.3.9.12.3 has a capacity of not less than 30 changes of air per hour based on the total volume of the service space.

The following instruction shall be displayed at the entrance of the cargo pump-room:

Before entering the cargo pump-room check whether it is free from gases and contains sufficient oxygen. Do not open doors and entrance openings without the permission of the master.

Leave immediately in the event of alarm.

Inerting facility In cases in which inerting or blanketing of the cargo is prescribed, the vessel shall be equipped with an inerting system. This system shall be capable of maintaining a permanent minimum pressure of 7 kPa (0.07 bar) in the spaces to be inerted. In addition, the inerting system shall not increase the pressure in the cargo tank to a pressure greater than that at which the pressure valve is regulated. The set pressure of the vacuum-relief valve shall be 3.5 kPa. A sufficient quantity of inert gas for loading or unloading shall be carried or produced on board if it is not possible to obtain it on shore. In addition, a sufficient quantity of inert gas to offset normal losses occurring during carriage shall be on board. The premises to be inerted shall be equipped with connections for introducing the inert gas and monitoring systems so as to ensure the correct atmosphere on a permanent basis. When the pressure or the concentration of inert gas in the gaseous phase falls below a given value, this monitoring system shall activate an audible and visible alarm in the wheelhouse. When the wheelhouse is unoccupied, the alarm shall also be perceptible in a location occupied by a crew member.

(Reserved). Arrangement of COfferdams Cofferdams or cofferdam compartments remaining once a service space has been arranged in accordance with 9.3.2.1 1.6 shall be accessible through an access hatch. If, however, the cofferdam is connected to a double-hull space, it is sufficient for it to be accessible from that space. For openings giving access to double-hull spaces on deck the last sentence of 9.3.2.10.3 remains applicable. In this case an arrangement shall be made for possible monitoring in order to ascertain from the deck whether the cofferdam is empty. Cofferdams shall be capable of being filled with water and emptied by means of a pump. Filling shall be effected within 30 minutes. These requirements are not applicable when the bulkhead between the engine room and the cofferdam comprises fire-protection insulation "A-60" in accordance with SOLAS 74, Chapter 11-2, Regulation 3, or has been fitted out as a service space. The cofferdams shall not be fitted with inlet valves. No fixed pipe shall permit connection between a cofferdam and other piping of the vessel outside the cargo area. The ventilation openings of cofferdams shall be fitted with a flame-arrester withstanding a deflagration. Safety and control installations Cargo tanks shall be provided with the following equipment: (a)

a mark inside the tank indicating the liquid level of 95%;

(b)

a level gauge;

(c)

a level alarm device which is activated at the latest when a degree of filling of 90% is reached;

(d)

a high level sensor for actuating the facility against overflowing at the latest when a degree of filling of 97.5% is reached;

(e)

an instrument for measuring the pressure of the vapour phase inside the cargo tank;

(Q

an instrument for measuring the temperature of the cargo, if in column (9) of Table C of Chapter 3.2 a heating installation is required, or if a maximum temperature is indicated in column (20) of that list;

(g)

a connection for a sampling device, closed or partially closed, andlor at least one sampling opening as required in column (13) of Table C of Chapter 3.2.

9.3.2.21.2

When the degree of filling in per cent is determined, an error of not more than 0.5% is permitted. It shall be calculated on the basis of the total cargo tank capacity including the expansion trunk.

9.3.2.21.3

The level gauge shall allow readings from the control position of the shut-off devices of the particular cargo tank. The permissible maximum filling level of the cargo tank shall be

marked on each level gauge. Permanent reading of the overpressure and vacuum shall be possible from a location from which loading or unloading operations may be interrupted. The permissible maximum overpressure and vacuum shall be marked on each level gauge. Readings shall be possible in all weather conditions. 9.3.2.21.4

The level alarm device shall give a visual and audible warning on board when actuated. The level alarm device shall be independent of the level gauge.

9.3.2.21.5

(a)

The high level sensor referred to in 9.3.2.21.1 (d) above shall give a visual and audible alarm on board and at the same time actuate an electrical contact which in the form of a binary signal interrupts the electric current loop provided and fed by the shore facility, thus initiating measures at the shore facility against overflowing during loading operations. The signal shall be transmitted to the shore facility via a watertight two-pin plug of a connector device in accordance with standard EN 60309-2: 1999 for direct current of 40 to 50 volts, identification colour white, position of the nose l 0 h. The plug shall be permanently fitted to the vessel close to the shore connections of the loading and unloading pipes. The high level sensor shall also be capable of switching off the vessel's own discharging pump. The high level sensor shall be independent of the level alarm device, but it may be connected to the level gauge.

(b)

During discharging by means of the on-board pump, it shall be possible for the shore facility to switch it off. For this purpose, an independent intrinsically safe power line, fed by the vessel, shall be switched off by the shore facility by means of an electrical contact. It shall be possible for the binary signal of the shore facility to be transmitted via a watertight two-pole socket or a connector device in accordance with standard EN

60309-2: 1999, for direct current of 40 to 50 volts, identification colour white, position of the nose 10 h. This socket shall be permanently fitted to the vessel close to the shore connections of the unloading pipes. 9.3.2.21.6

The visual and audible signals given by the level alarm device shall be clearly distinguishable from those of the high level sensor. The visual alarm shall be visible at each control position on deck of the cargo tank stop valves. It shall be possible to easily check the functioning of the sensors and electric circuits or these shall be "intrinsically safe apparatus".

9.3.2.21.7

When the pressure or temperature exceeds a set value, instruments for measuring the vacuum or overpressure of the gaseous phase in the cargo tank or the temperature of the cargo, shall activate a visual and audible alarm in the wheelhouse. When the wheelhouse is unoccupied the alarm shall also be perceptible in a location occupied by a crew member. When the pressure exceeds the set value during loading, the instrument for measuring the pressure shall, by means of the plug referred to in 9.3.2.21.5 above, initiate immediately an electrical contact which shall put into effect measures to interrupt the loading operation. If the vessel's own discharge pump is used, it shall be switched off automatically. The instrument for measuring the overpressure or vacuum shall activate the alarm at latest when an overpressure equal to 1.15 times the opening pressure of the pressure relief device, or a vacuum pressure equal to the construction vacuum pressure but not exceeding 5 kPa. The maximum allowable temperature is indicated in column (20) of Table C of Chapter 3.2. The sensors for the alarms mentioned in this paragraph may be connected to the alarm device of the sensor. When it is prescribed in column (20) of Table C of Chapter 3.2, the instrument for measuring the overpressure of the gaseous phase shall activate a visible and audible alarm in the wheelhouse when the overpressure exceeds 40 kPa during the voyage. When the wheelhouse is unoccupied, the alarm shall also be perceptible in a location occupied by a crew member.

9.3.2.21.8

Where the control elements of the shut-off devices of the cargo tanks are located in a control room, it shall be possible to stop the loading pumps and read the level gauges in the control room, and the visual and audible warning given by the level alarm device, the high level sensor referred to in 9.3.2.21.1 (d) and the instruments for measuring the pressure and temperature of the cargo shall be noticeable in the control room and on deck. Satisfactory monitoring of the cargo area shall be ensured from the control room.

9.3.2.21.9

The vessel shall be so equipped that loading or unloading operations can be interrupted by means of switches, i.e. the quick-action stop valve located on the flexible vessel-to-shore connecting line must be capable of being closed. The switch shall be placed at two points on the vessel (fore and aft). This provision applies only when prescribed in column (20) of Table C of Chapter 3.2. The interruption system shall be designed according to the quiescent current principle.

9.3.2.22

Cargo tank openings

9.3.2.22.1

(a)

Cargo tank openings shall be located on deck in the cargo area.

(b)

Cargo tank openings with a cross-section of more than 0.10 m* and openings of safety devices for preventing overpressures shall be located not less than 0.50 m above deck.

9.3.2.22.2

Cargo tank openings shall be fitted with gastight closures capable of withstanding the test pressure in accordance with 9.3.2.23.1.

9.3.2.22.3

Closures which are normally used during loading or unloading operations shall not cause sparking when operated.

9.3.2.22.4

(a)

Each cargo tank or group of cargo tanks connected to a common vapour pipe shall be fitted with: -

safety devices for preventing unacceptable overpressures or vacuums. When anti-explosion protection is required in column (17) of Table C of Chapter 3.2, the vacuum valve shall be fitted with a flame arrester capable of withstanding a deflagration and the pressure-relief valve with a high-velocity vent valve capable of withstanding steady burning. The gases shall be discharged upwards. The opening pressure of the high-velocity vent valve and the opening pressure of the vacuum valve shall be indelibly indicated on the valves;

9.3.2.22.5

-

a connection for the safe return ashore of gases expelled during loading;

-

a device for the safe depressurisation of the tanks consisting of at least a fire-resistant flame-arrester and a stop valve which clearly indicates whether it is open or shut.

(b)

The outlets of high-velocity vent valves shall be located not less than 2.00 m above the deck and at a distance of not less than 6.00 m from the accommodation and from the service spaces outside the cargo area. This height may be reduced when within a radius of 1.00 m round the outlet of the high-velocity vent valve, there is no equipment, no work is being carried out and signs indicate the area. The setting of the high-velocity vent valves shall be such that during the transport operation they do not blow off until the maximum permissible working pressure of the cargo tanks is reached.

(a)

Insofar as anti-explosion protection is prescribed in column (17) of Table C of Chapter 3.2, a vapour pipe connecting two or more cargo tanks shall be fitted, at the connection to each cargo tank, with a flame arrester with a fixed or spring-loaded plate stack, capable of withstanding a detonation. This equipment may consist of: (i)

a flame arrester fitted with a fixed plate stack, where each cargo tank is fitted with a vacuum valve capable of withstanding a deflagration and a high-velocity vent valve capable of withstanding steady burning;

(ii)

a flame arrester fitted with a spring-loaded plate stack, where each cargo tank is fitted with a vacuum valve capable of withstanding a deflagration;

(iii)

a flame arrester with a fixed plate stack;

(iv)

a flame arrester with a fixed plate stack, where the pressure-measuring device is fitted with an alarm system in accordance with 9.3.2.21.7;

(v)

a flame arrester with a spring-loaded plate stack, where the pressure-measuring device is fitted with an alarm system in accordance with 9.3.2.21.7.

When a fire-fighting installation is permanently mounted on deck in the cargo area and can be brought into service from the deck and from the wheelhouse, flame arresters need not be required for individual cargo tanks. Only substances which do not mix and which do not react dangerously with each other may be carried simultaneously in cargo tanks connected to a common vapour pipe;

Insofar as anti-explosion protection is prescribed in column (17) of Table C of Chapter 3.2, a vapour pipe connecting two or more cargo tanks shall be fitted, at the connection to each cargo tank, with a pressure/vacuum relief valve incorporating a flame arrester capable of withstanding a detonationldeflagration. Only substances which do not mix and which do not react dangerously with each other may be carried simultaneously in cargo tanks connected to a common vapour pipe;

Insofar as anti-explosion protection is prescribed in column (17) of Table C of Chapter 3.2, an independent vapour pipe for each cargo tank, fitted with a pressure/vacuum valve incorporating a flame arrester capable of withstanding a deflagration and a high velocity vent valve incorporating a flame arrester capable of withstanding steady burning. Several different substances may be carried simultaneously;

Insofar as anti-explosion protection is prescribed in column (17) of Table C of Chapter 3.2, a vapour pipe connecting two or more cargo tanks shall be fitted, at the connection to each cargo tank, with a shut-off device capable of withstanding a detonation, where each cargo tank is fitted with a vacuum valve capable of withstanding a deflagration and a high-velocity vent valve capable of withstanding steady burning. Only substances which do not mix and which do not react dangerously with each other may be carried simultaneously in cargo tanks connected to a common vapour pipe. Pressure tests The cargo tanks, residual cargo tanks, cofferdams, pipes for loading and unloading shall be subjected to initial tests before being put into service and thereafter at prescribed intervals. Where a heating system is provided inside the cargo tanks, the heating coils shall be subjected to initial tests before being put into service and thereafter at prescribed intervals. The test pressure for the cargo tanks and residual cargo tanks shall be not less than 1.3 times the construction pressure. The test pressure for the cofferdams and open cargo tanks shall be not less than 10 kPa (0.10 bar) gauge pressure. The test pressure for pipes for loading and unloading shall be not less than 1,000 kPa (10 bar) gauge pressure. The maximum intervals for the periodic tests shall be 11 years.

9.3.2.23.5

The procedure for pressure tests shall comply with the provisions established by the competent authority or a recognised classification society.

9.3.2.24

(Reserved).

9.3.2.25

Pumps and piping

9.3.2.25.1

Pumps, compressors and accessory loading and unloading piping shall be placed in the cargo area. Cargo pumps shall be capable of being shut down from the cargo area and, in addition, from a position outside the cargo area. Cargo pumps situated on deck shall be located not less than 6.00 m from entrances to, or openings of, the accommodation and service spaces outside the cargo area. Pipes for loading and unloading shall be independent of any other piping of the vessel. No cargo piping shall be located below deck, except those inside the cargo tanks and inside the cargo pump-room. The pipes for loading and unloading shall be arranged so that, after loading or unloading operations, the liquid remaining in these pipes may be safely removed and may flow either into the vessel's tanks or the tanks ashore. Pipes for loading and unloading shall be clearly distinguishable from other piping, e.g. by means of colour marking. The pipes for loading and unloading located on deck, with the exception of the shore connections, shall be located not less than a quarter of the vessel's breadth from the outer shell. The shore connections shall be located not less than 6.00 m from the entrances to, or openings of, the accommodation and service spaces outside the cargo area. Each shore connection of the vapour pipe and shore connections of the pipes for loading and unloading, through which the loading or unloading operation is carried out, shall be fitted with a shut-off device. However, each shore connection shall be fitted with a blind flange when it is not in operation. Each shore connection of the pipes for loading and unloading through which the loading or unloading operation is carried out shall be fitted with the device intended for the discharge of residual cargo described in 8.6.4.1. The vessel shall be equipped with an additional stripping system. The flanges and stuffing boxes shall be provided with a spray protection device.

9.3.2.25.3

The distance referred to in 9.3.2.25.1 and 9.3.2.25.2 (e) may be reduced to 3.00 m if a transverse bulkhead complying with 9.3.2.10.2 is situated at the end of the cargo area. The openings shall be provided with doors. The following notice shall be displayed on the doors: Do not open during loading and unloading without the permission of the master. Close immediately.

9.3.2.25.4

(a)

Every component of the pipes for loading and unloading shall be electrically connected to the hull. -

390 -

(b)

The pipes for loading shall extend down to the bottom of the cargo tanks.

9.3.2.25.5

The stop valves or other shut-off devices of the pipes for loading and unloading shall indicate whether they are open or shut.

9.3.2.25.6

The pipes for loading and unloading shall have, at the test pressure, the required elasticity, leakproofness and resistance to pressure.

9.3.2.25.7

The permissible maximum overpressure or vacuum value shall be indicated on each installation. Readings shall be possible in all weather conditions.

9.3.2.25.8

(a)

When pipes for loading and unloading are used for supplying the cargo tanks with washing or ballast water, the suctions of these pipes shall be located within the cargo area but outside the cargo tanks. Pumps for tank washing systems with associated connections may be located outside the cargo area, provided the discharge side of the system is arranged in such a way that the suction is not possible through that part. A spring-loaded non-return valve shall be provided to prevent any gases from being expelled from the cargo area through the tank washing system.

(b) 9.3.2.25.9

A non-return valve shall be fitted at the junction between the water suction pipe and the cargo loading pipe.

The permissible loading and unloading flows shall be calculated. Calculations concern the permissible maximum loading and unloading flow for each cargo tank or each group of cargo tanks, taking into account the design of the ventilation system. These calculations shall take into consideration the fact that in the event of an unforeseen cut-off of the gas return piping or the compensation piping of the shore facility, the safety devices of the cargo tanks will prevent pressure in the cargo tanks from exceeding the following values: over-pressure:

1 15% of the opening pressure of the high-velocity vent valve;

vacuum pressure: not more than the construction vacuum pressure but not exceeding 5 kPa (0.05 bar). The main factors to be considered are the following: 1.

Dimensions of the ventilation system of the cargo tanks;

2.

Gas formation during loading: multiply the largest loading flow by a factor of not less than 1.25;

3.

Density of the vapour mixture of the cargo based on 50% volume vapour of 50% volume air:

4.

Loss of pressure through ventilation pipes, valves and fittings. Account will be taken of a 30% clogging of the mesh of the flame-arrester;

5.

Chocking pressure of the safety valves.

The permissible maximum loading and unloading pressure for each cargo tank or for each group of cargo tanks shall be given in an on-board instruction. 9.3.2.25.10

The stripping system shall be subjected to initial tests before being put into service or thereafter if any alteration has been made to it, using water as test medium. The test and the determination of the residual quantities shall be carried out in accordance with the requirements of 8.6.4.2. In this test, the following residual quantities shall not be exceeded: (a)

5 1 for each cargo tank;

(b)

15 1for each pipe system.

The residual quantities obtained in the test shall be entered in the certificate for the test of the stripping system referred to in 8.6.4.3. 9.3.2.25.1 1

If the vessel is carrying several dangerous substances liable to react dangerously with each other, a separate pump with its own piping for loading and unloading shall be installed for each substance. The piping shall not pass through a cargo tank containing dangerous substances with which the substance in question is liable to react.

9.3.2.26

Residual cargo tanks and slop tanks

9.3.2.26.1

The vessel shall be provided with at least one residual cargo tank and with slop tanks for slops which are not suitable for pumping. These tanks shall be located only in the cargo area. Intermediate bulk containers or tank-containers or portable tanks in accordance with 7.2.4.1 may be used instead of a fixed residual cargo tank. During filling of these intermediate bulk containers or tank-containers or portable tanks, means for collecting any leakage shall be placed under the filling connections.

9.3.2.26.2

Slop tanks shall be fire resistant and shall be capable of being closed with lids (e.g. drums with lever closing ring lids). The tanks shall be marked and easy to handle.

9.3.2.26.3

The maximum capacity of a residual cargo tank is 30 m3.

9.3.2.26.4

The residual cargo tank shall be equipped with: -

pressure-relief and *vacuum relief valves. The high velocity vent valve shall be so regulated as not to open during carriage. This condition is met when the opening pressure of the valve meets the conditions set out in column (109) of Table C of Chapter 3.2; When anti-explosion protection is required in column (17) of Table C of Chapter 3.2, the vacuum-relief valve shall be capable of withstanding deflagrations and the highvelocity vent valve shall withstand steady burning; a level indicator;

-

connections with shut-off devices, for pipes and hoses.

Intermediate bulk containers (IBCs), tank containers and portable tanks intended to collect cargo remains, cargo residues or slops shall be equipped with:

-

a connection enabling gases released during filling to be evacuated safely;

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-

a possibility of indicating the degree of filling;

-

connections with shut-off devices, for pipes and hoses.

Residual cargo tanks, intermediate bulk containers (IBCs), tank containers and portable tanks shall be connected to the vapour pipe of cargo tanks only for the time necessary to fill them in accordance with 7.2.4.15.2. Residual cargo tanks, intermediate bulk containers (IBCs), tank-containers and portable tanks placed on the deck shall be located at a minimum distance from the hull equal to one quarter of the vessel's breadth. (Resewed).

Water-spray system When water-spraying is required in column (9) of Table C of Chapter 3.2, a water-spray system shall be installed in the cargo area on deck to enable gas emissions from loading to be precipitated and to cool the tops of cargo tanks by spraying water over the whole surface so as to avoid safely the activation of the high-velocity vent valve at 50 kPa. The gas precipitation system shall be fitted with a connection device for supply from a shore installation. The spray nozzles shall be so installed that the entire cargo deck area is covered and the gases released are precipitated safely. The system shall be capable of being put into operation from the wheelhouse and from the deck. Its capacity shall be such that when all the spray nozzles are in operation, the outflow is not less than 50 litres per square metre of deck area and per hour. (Reserved).

Engines Only internal combustion engines running on fuel with a flashpoint of more than 55" C are allowed. Ventilation inlets of the engine room, and when the engines do not take in air directly from the engine room, air intakes of the engines shall be located not less than 2.00 m from the cargo area. Sparking shall not be possible within the cargo area. The surface temperature of the outer parts of engines used during loading or unloading operations, as well as that of their air inlets and exhaust ducts shall not exceed the allowable temperature according to the temperature class. This provision does not apply to engines installed in service spaces provided the provisions of 9.3.2.52.3 (b) are fully complied with. The ventilation in the closed engine room shall be designed so that, at an ambient temperature of 20 "C, the average temperature in the engine room does not exceed 40" C.

Oilfuel tanks Where the vessel is provided with hold spaces, the double bottoms within these spaces may be arranged as a liquid oil fuel tanks, provided their depth is not less than 0.60 m. Liquid oil fuel pipes and openings of such tanks are not permitted in the hold space. The open ends of the air pipes of all liquid oil fuel tanks shall extend to not less than 0.50 m above the open deck. Their open ends and the open ends of overflow pipes leading to the deck shall be fitted with a protective device consisting of a gauze diaphragm or a perforated plate.

(Reserved). Exhaust pipes Exhausts shall be evacuated from the vessel into the open air either upwards through an exhaust pipe or through the shell plating. The exhaust outlet shall be located not less than 2.00 m from the cargo area. The exhaust pipes of engines shall be arranged so that the exhausts are led away from the vessel. The exhaust pipes shall not be located within the cargo area. Exhaust pipes shall be provided with a device preventing the escape of sparks, e.g. spark arresters.

Bilge pumping and ballasting arrangements Bilge and ballast pumps for spaces within the cargo area shall be installed within such area. This provision does not apply to: -

double-hull spaces and double bottoms which do not have a common boundary wall with the cargo tanks;

-

cofferdams, hold spaces and double bottoms where ballasting is carried out using the piping of the fire-fighting system in the cargo area and bilge-pumping is performed using educators.

Where the double bottom is used as a liquid oil fuel tank, it shall not be connected to the bilge piping system. Where the ballast pump is installed in the cargo area, the standpipe and its outboard connection for suction of ballast water shall be located within the cargo area but outside the cargo tanks. A cargo pump-room below deck shall be capable of being drained in an emergency by an installation located in the cargo area and independent from any other installation. This installation shall be provided outside the cargo pump-room.

(Reserved).

Fire-extinguishing arrangements A fire-extinguishing system shall be installed on the vessel. This system shall comply with the following requirements: -

It shall be supplied by two independent fire or ballast pumps, one of which shall be ready for use at any time. These pumps and their means of propulsion and electrical equipment shall not be installed in the same space.;

-

It shall be provided with a water main fitted with at least three hydrants in the cargo area above deck. Three suitable and sufficiently long hoses with spray nozzles having a diameter of not less than 12 mm shall be provided. It shall be possible to reach any point of the deck in the cargo area simultaneously with at least two jets of water which do not emanate from the same hydrant.

A spring-loaded non-return valve shall be fitted to ensure that no gases can escape through the fire-extinguishing system into the accommodation or service spaces outside the cargo area; -

The capacity of the system shall be at least sufficient for a jet of water to have a minimum reach of not less than the vessel's breadth from any location on board with two spray nozzles being used at the same time.

In addition, the engine rooms, the pump-room and all spaces containing essential equipment (switchboards, compressors, etc.) for the refrigeration equipment, if any, shall be provided with a permanently fixed fire-extinguishing system meeting the following requirements: Extinguishing agents

For the protection of spaces in engine rooms, boiler rooms and pump rooms, only permanently fixed fire-extinguishing systems using the following extinguishing agents are permitted: (a)

COz (carbon dioxide);

(b)

HFC 227 ea (heptafluoropropane);

(c)

IG-541 (52% nitrogen, 40% argon, 8% carbon dioxide).

Other extinguishing agents are permitted only on the basis of recommendations by the Administrative Committee. Ventilation, air extraction

(a)

The combustion air required by the combustion engines which ensure propulsion should not come from spaces protected by permanently fixed fire-extinguishing systems. This requirement is not mandatory if the vessel has two independent main engine rooms with a gastight separation or if, in addition to the main engine room, there is a separate engine room installed with a bow thruster that can independently ensure propulsion in the event of a fire in the main engine room.

(b)

All forced ventilation systems in the space to be protected shall be shut down automaticallv as soon as the fire-extineuishin~svstem is activated.

All openings in the space to be protected which permit air to enter or gas to escape shall be fitted with devices enabling them to be closed rapidly. It shall be clear whether they are open or closed. Air escaping from the pressure-relief valves of the pressurised air tanks installed in the engine rooms shall be evacuated to the open air. Overpressure or negative pressure caused by the diffusion of the extinguishing agent shall not destroy the constituent elements of the space to be protected. It shall be possible to ensure the safe equalisation of pressure. Protected spaces shall be provided with a means of extracting the extinguishing agent. If extraction devices are installed, it shall not be possible to start them up during extinguishing.

Fire alarm system The space to be protected shall be monitored by an appropriate fire alarm system. The alarm signal shall be audible in the wheelhouse, the accommodation and the space to be protected.

Piping system (a)

The extinguishing agent shall be routed to and distributed in the space to be protected by means of a permanent piping system. Piping installed in the space to be protected and the reinforcements it incorporates shall be made of steel. This shall not apply to the connecting nozzles of tanks and compensators provided that the materials used have equivalent fire-retardant properties. Piping shall be protected against corrosion both internally and externally.

(b)

The discharge nozzles shall be so arranged as to ensure the regular diffusion of the extinguishing agent.

Triggering device (a)

Automatically activated fire-extinguishing systems are not permitted.

(b)

It shall be possible to activate the fire-extinguishing system from a suitable point located outside the space to be protected.

(c)

Triggering devices shall be so installed that they can be activated in the event of a fire and so that the risk of their breakdown in the event of a fire or an explosion in the space to be protected is reduced as far as possible. Systems which are not mechanically activated shall be supplied from two energy sources independent of each other. These energy sources shall be located outside the space to be protected. The control lines located in the space to be protected shall be so designed as to remain capable of operating in the event of a fire for a minimum of 30 minutes. The electrical installations are deemed to meet this requirement if they conform to the IEC 6033 1-21:1999 standard. When the triggering devices are so placed as not to be visible, the component concealing them shall carry the "Fire-fighting system" symbol, each side being not less than 10 cm in length, with the following text in red letters on a white ground:

Fire-extinguishing system

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(d)

If the fire-extinguishing system is intended to protect several spaces, it shall comprise a separate and clearly-marked triggering device for each space.

(e)

The instructions shall be posted alongside all triggering devices and shall be clearly visible and indelible. The instructions shall be in a language the master can read and understand and if this language is not English, French or German, they shall be in English, French or German. They shall include information concerning:

(Q

9.3.2.40.2.6

(i)

the activation of the fire-extinguishing system;

(ii)

the need to ensure that all persons have left the space to be protected;

(iii)

the correct behaviour of the crew in the event of activation;

(iv)

the correct behaviour of the crew in the event of the failure of the fire-extinguishing system to function properly.

The instructions shall mention that prior to the activation of the fire-extinguishing system, combustion engines installed in the space and aspirating air from the space to be protected, shall be shut down.

Alarm device (a)

Permanently fixed fire-extinguishing systems shall be fitted with an audible and visual alarm device.

(b)

The alarm device shall be set off automatically as soon as the fire-extinguishing system is first activated. The alarm device shall function for an appropriate period of time before the extinguishing agent is released; it shall not be possible to turn it off.

(c)

Alarm signals shall be clearly visible in the spaces to be protected and their access points and be clearly audible under operating conditions corresponding to the highest possible sound level. It shall be possible to distinguish them clearly from all other sound and visual signals in the space to be protected.

(d)

Sound alarms shall also be clearly audible in adjoining spaces, with the communicating doors shut, and under operating conditions corresponding to the highest possible sound level.

(e)

If the alarm device is not intrinsically protected against short circuits, broken wires and drops in voltage, it shall be possible to monitor its operation.

(f)

A sign with the following text in red letters on a white ground shall be clearly posted at the entrance to any space the extinguishing agent may reach:

Warning, fire-extinguishing system! Leave this space immediately when the (description) alarm is activated!

...

9.3.2.40.2.7

Pressurised tanks, fittings and piping (a)

Pressurised tanks, fittings and piping shall conform to the requirements of the competent authority.

(b)

Pressurised tanks shall be installed in accordance with the manufacturer's instructions.

9.3.2.40.2.8

(c)

Pressurised tanks, fittings and piping shall not be installed in the accommodation.

(d)

The temperature of cabinets and storage spaces for pressurised tanks shall not exceed 50 "C.

(e)

Cabinets or storage spaces on deck shall be securely stowed and shall have vents so placed that in the event of a pressurised tank not being gastight, the escaping gas cannot penetrate into the vessel. Direct connections with other spaces are not permitted.

Quantity of extinguishing agent

If the quantity of extinguishing agent is intended for more than one space, the quantity of extinguishing agent available does not need to be greater than the quantity required for the largest of the spaces thus protected. 9.3.2.40.2.9

Installation, maintenance, monitoring and documents

(a)

The mounting or modification of the system shall only be performed by a company specialised in fire-extinguishing systems. The instructions (product data sheet, safety data sheet) provided by the manufacturer of the extinguishing agent or the system shall be followed.

(b)

The system shall be inspected by an expert: (i)

before being brought into service;

(ii)

each time it is put back into service after activation;

(iii)

after every modification or repair;

(iv)

regularly, not less than every two years.

(c)

During the inspection, the expert is required to check that the system conforms to the requirements of 9.3.2.40.2.

(d)

The inspection shall include, as a minimum: (i)

an external inspection of the entire system;

(ii)

an inspection to ensure that the piping is leakproof;

(iii)

an inspection to ensure that the control and activation systems are in good working order;

(iv)

an inspection of the pressure and contents of tanks;

(v)

an inspection to ensure that the means of closing the space to be protected are leakproof;

(vi)

an inspection of the fire alarm system;

(vii) an inspection of the alarm device. (e)

The person performing the inspection shall establish, sign and date a certificate of inspection.

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(Q 9.3.2.40.2.10

The number of permanently fixed fire-extinguishing systems shall be mentioned in the inspection certificate.

Fire-extinguishing system operating with CO2 In addition to the requirements contained in 9.3.2.40.2.1 to 9.3.2.40.2.9, fire-extinguishing systems using C02 as an extinguishing agent shall conform to the following provisions: Tanks of CO2 shall be placed in a gastight space or cabinet separated from other spaces. The doors of such storage spaces and cabinets shall open outwards; they shall be capable of being locked and shall carry on the outside the symbol "Warning: danger", not less than 5 cm high and "CO? in the same colours and the same size; Storage cabinets or spaces for CO2 tanks located below deck shall only be accessible from the outside. These spaces shall have an artificial ventilation system with extractor hoods and shall be completely independent of the other ventilation systems on board; The level of filling of C02 tanks shall not exceed 0.75 kg/l. The volume of depressurised CO2 shall be taken to be 0.56 m3/kg; The concentration of CO2 in the space to be protected shall be not less than 40% of the gross volume of the space. This quantity shall be released within 120 seconds. It shall be possible to monitor whether diffusion is proceeding correctly; The opening of the tank valves and the control of the diffusing valve shall correspond to two different operations; The appropriate period of time mentioned in 9.3.2.40.2.6 (b) shall be not less than 20 seconds. A reliable installation shall ensure the timing of the diffusion of CO2.

9.3.2.40.2.1 1

Fire-extinguishing system operating with HFC-227 ea (heptaJuoropropane) In addition to the requirements of 9.3.2.40.2.1 to 9.3.2.40.2.9, fire-extinguishing systems using HFC-227 ea as an extinguishing agent shall conform to the following provisions: Where there are several spaces with different gross volumes, each space shall be equipped with its own fire-extinguishing system; Every tank containing HFC-227 ea placed in the space to be protected shall be fitted with a device to prevent overpressure. This device shall ensure that the contents of the tank are safely diffused in the space to be protected if the tank is subjected to fire, when the fire-extinguishing system has not been brought into service; Every tank shall be fitted with a device permitting control of the gas pressure; The level of filling of tanks shall not exceed 1.15 kg/l. The specific volume of depressurised HFC-227 ea shall be taken to be 0.1374 m3/kg; The concentration of HFC-227 ea in the space to be protected shall be not less than 8% of the gross volume of the space. This quantity shall be released within 10 seconds; Tanks of HFC-227 ea shall be fitted with a pressure monitoring device which triggers an audible and visual alarm in the wheelhouse in the event of an unscheduled loss of

propellant gas. Where there is no wheelhouse, the alarm shall be triggered outside the space to be protected; (g)

After discharge, the concentration in the space to be protected shall not exceed 10.5% (volume);

(h)

The fire-extinguishing system shall not comprise aluminium parts.

Fire-extinguishing system operating with IG-541 In addition to the requirements of 9.3.2.40.2.1 to 9.3.2.40.2.9, fire-extinguishing systems using IG-541 as an extinguishing agent shall conform to the following provisions: (a)

Where there are several spaces with different gross volumes, every space shall be equipped with its own fire-extinguishing system;

(b)

Every tank containing IG-541 placed in the space to be protected shall be fitted with a device to prevent overpressure. This device shall ensure that the contents of the tank are safely diffused in the space to be protected if the tank is subjected to fire, when the fire-extinguishing system has not been brought into service;

(c)

Each tank shall be fitted with a device for checking the contents;

(d)

The filling pressure of the tanks shall not exceed 200 bar at a temperature of + l 5 "C;

(e)

The concentration of IG-541 in the space to be protected shall be not less than 44% and not more than 50% of the gross volume of the space. This quantity shall be released within 120 seconds.

Fire-extinguishing systemfor physical protection In order to ensure physical protection in the engine rooms, boiler rooms and pump rooms, fire-extinguishing systems are accepted solely on the basis of recommendations by the Administrative Committee. The two hand fire-extinguishers referred to in 8.1.4 shall be located in the cargo area. The fire-extinguishing agent and the quantity contained in the permanently fixed fire-extinguishing system shall be suitable and sufficient for fighting fires. Fire and naked light

The outlets of funnels shall be located not less than 2.00 m from the cargo area. Arrangements shall be provided to prevent the escape of sparks and the entry of water. Heating, cooking and refrigerating appliances shall not be fuelled with liquid.fuels, liquid gas or solid fuels. The installation in the engine room or in another separate space of heating appliances fuelled with liquid fuel having a flash-point above 55 "C is, however, permitted. Cooking and refrigerating appliances are permitted only in the accommodation. Only electrical lighting appliances are permitted.

Cargo heating system Boilers which are used for heating the cargo shall be fielled with a liquid fuel having a flashpoint of more than 55 "C. They shall be placed either in the engine room or in another separate space below deck and outside the cargo area, which is accessible from the deck or from the engine room. The cargo heating system shall be designed so that the cargo cannot penetrate into the boiler in the case of a leak in the heating coils. A cargo heating system with artificial draught shall be ignited electrically. The ventilation system of the engine room shall be designed taking into account the air required for the boiler. Where the cargo heating system is used during loading, unloading or gas-freeing, the service space which contains this system shall fully comply with the requirements of 9.3.2.52.3 (b). This requirement does not apply to the inlets of the ventilation system. These inlets shall be located at a minimum distance of 2.00 m from the cargo area and 6.00 m from the openings of cargo tanks or residual cargo tanks, loading pumps situated on deck, openings of high velocity vent valves, pressure relief devices and shore connections of loading and unloading pipes and must be located not less than 2.00 m above the deck. The requirements of 9.3.2.52.3 (b) are not applicable to the unloading of substances having a flash point of 60 "C or more when the temperature of the product is at least 15 K lower at the flash point. (Reserved). Documents concerning electrical installations In addition to the documents required in accordance with the Regulations referred to in 1.1.4.6, the following documents shall be on board: (a)

a drawing indicating the boundaries of the cargo area and the location of the electrical equipment installed in this area;

(b)

a list of the electrical equipment referred to in (a) above including the following particulars: machine or appliance, location, type of protection, type of protection against explosion, testing body and approval number;

(c)

a list of or general plan indicating the electrical equipment outside the cargo area which may be operated during loading, unloading or gas-freeing. All other electrical equipment shall be marked in red. See 9.3.2.52.3 and 9.3.2.52.4.

The documents listed above shall bear the stamp of the competent authority issuing the certificate of approval. Electrical installations Only distribution systems without return connection to the hull are permitted: This provision does not apply to:

-

electric corrosion protection against external currents;

-

local installations outside the cargo area (e.g. connections of starters of diesel engines);

-

the device for checking the insulation level referred to in 9.3.2.5 1.2 below.

9.3.2.51.2

Every insulated distribution network shall be fitted with an automatic device with a visual and audible alarm for checking the insulation level.

9.3.2.5 1.3

For the selection of electrical equipment to be used in zones presenting an explosion risk, the explosion groups and temperature classes assigned to the substances carried in accordance with columns (15 ) and (1 6) of Table C of Chapter 3.2 shall be taken into consideration.

9.3.2.52

Type and location of electrical equipment

9.3.2.52.1

(a)

Only the following equipment may be installed in cargo tanks, residual cargo tanks and pipes for loading and unloading (comparable to zone 0): -

(b)

(c)

9.3.2.52.2

measuring, regulation and alarm devices of the EEx (ia) type of protection.

Only the following equipment may be installed in the cofferdams, double-hull spaces, double bottoms and hold spaces (comparable to zone 1): -

measuring, regulation and alarm devices of the certified safe type;

-

lighting appliances of the "flame-proof enclosure" or "pressurised enclosure" type of protection;

-

hermetically sealed echo sounding devices the cables of which are led through thick-walled steel tubes with gastight connections up to the main deck;

-

cables for the active cathodic protection of the shell plating in protective steel tubes such as those provided for echo sounding devices.

Only the following equipment may be installed in the service spaces in the cargo area below deck (comparable to zone 1): -

measuring, regulation and alarm devices of the certified safe type;

-

lighting appliances of the "flame-proof enclosure" or "apparatus protected by pressurization" type of protection;

-

motors driving essential equipment such as ballast pumps; they shall be of the certified safe type.

(d)

The control and protective equipment of the electrical equipment referred to in paragraphs (a), (b) and (c) above shall be located outside the cargo area if they are not intrinsically safe.

(e)

The electrical equipment in the cargo area on deck (comparable to zone 1) shall be of the certified safe type.

Accumulators shall be located outside the cargo area.

9.3.2.52.3

(a)

Electrical equipment used during loading, unloading and gas-freeing during berthing and which are located outside the cargo area shall (comparable to zone 2) be at least of the "limited explosion risk" type.

(b)

This provision does not apply to: (i)

lighting installations in the accommodation, except for switches near entrances to accommodation;

(ii)

radiotelephone installations in the accommodation or the wheelhouse;

(iii)

mobile and fixed telephone installations in the accommodation or the wheelhouse;

(iv)

electrical installations in the accommodation, the wheelhouse or the service spaces outside the cargo areas if 1.

These spaces are fitted with a ventilation system ensuring an overpressure of 0.1 kPa (0.001 bar) and none of the windows is capable of being opened; the air intakes of the ventilation system shall be located as far away as possible, however, not less than 6.00 m from the cargo area and not less than 2.00 m above the deck;

2.

The spaces are fitted with a gas detection system with sensors: -

at the suction inlets of the ventilation system;

-

directly at the top edge of the sill of the entrance doors of the accommodation and service spaces;

3.

The gas concentration measurement is continuous;

4.

When the gas concentration reaches 20% of the lower explosive limit, the ventilators are switched off. In such a case and when the overpressure is not maintained or in the event of failure of the gas detection system, the electrical installations which do not comply with (a) above, shall be switched off. These operations shall be performed immediately and automatically and activate the emergency lighting in the accommodation, the wheelhouse and the service spaces, which shall comply at least with the "limited explosion risk" type. The switching-off shall be indicated in the accommodation and wheelhouse by visual and audible signals;

5.

The ventilation system, the gas detection system and the alarm of the switch-off device fully comply with the requirements of (a) above;

6.

The automatic switching-off device is set so that no automatic switch off may occur while the vessel is under way.

9.3.2.52.4

The electrical equipment which does not meet the requirements set out in 9.3.2.52.3 above together with its switches shall be marked in red. The disconnection of such equipment shall be operated from a centralised location on board.

9.3.2.52.5

An electric generator which is permanently driven by an engine and which does not meet the requirements of 9.3.2.52.3 above, shall be fitted with a switch capable of shutting down the excitation of the generator. A notice board with the operating instructions shall be displayed near the switch.

Sockets for the connection of signal lights and gangway lighting shall be permanently fitted to the vessel close to the signal mast or the gangway. Connecting and disconnecting shall not be possible except when the sockets are not live. The failure of the power supply for the safety and control equipment shall be immediately indicated by visual and audible signals at the locations where the alarms are usually actuated. Earthing The metal parts of electrical appliances in the cargo area which are not live as well as protective metal tubes or metal sheaths of cables in normal service shall be earthed, unless they are so arranged that they are automatically earthed by bonding to the metal structure of the vessel. The provisions of 9.3.2.53.1 above apply also to equipment having service voltages of less than 50 V. Independent cargo tanks, metal intermediate bulk containers and tank-containers shall be earthed. Metal intermediate bulk containers (IBCs) and tank-containers, used as residual cargo tanks or slop tanks, shall be capable of being earthed. (Reserved).

Electrical cables All cables in the cargo area shall have a metallic sheath. Cables and sockets in the cargo area shall be protected against mechanical damage. Movable cables are prohibited in the cargo area, except for intrinsically safe electric circuits or for the supply of signal lights and gangway lighting. Cables of intrinsically safe circuits shall only be used for such circuits and shall be separated from other cables not intended for being used in such circuits (e.g. they shall not be installed together in the same string of cables and they shall not be fixed by the same cable clamps). For movable cables intended for signal lights and gangway lighting, only sheathed cables of type H 07 RN-F in accordance with IEC publication 60 245-4 (1994) or cables of at least equivalent design having conductors with a cross-section of not less than 1.5 mm2 shall be used. These cables shall be as short as possible and installed so that damage is not likely to occur. The cables required for the electrical equipment referred to in 9.3.2.51.1 (b) and (c) are accepted in cofferdams, double-hull spaces, double bottoms, hold spaces and service spaces below deck. (Reserved).

Special equipment

A shower and an eye and face bath shall be provided on the vessel at a location which is directly accessible from the cargo area. (Reserved).

Admittance on board

The notice boards displaying the prohibition of admittance in accordance with 8.3.3 shall be clearly legible from either side of the vessel. (Reserved). Prohibition of smoking, fire or naked light

The notice boards displaying the prohibition of smoking in accordance with 8.3.4 shall be clearly legible from either side of the vessel. Notice boards indicating the circumstances under which the prohibition is applicable shall be fitted near the entrances to the spaces where smoking or the use of fire or naked light is not always prohibited. Ashtrays shall be provided close to each exit of the accommodation and the wheelhouse. (Reserved).

Emergency exit

Spaces the entrances or exits of which are likely to become partly or completely immersed in the damaged condition shall have an emergency exit which is situated not less than 0.10 m above the damage waterline. This requirement does not apply to forepeak and afterpeak. (Reserved).

Rules for construction of type N tank vessels The rules for construction of 9.3.3.0 to 9.3.3.99 apply to type N tank vessels. Materials of construction

(a)

The vessel's hull and the cargo tanks shall be constructed of shipbuilding steel or other at least equivalent metal. The independent cargo tanks may also be constructed of other materials, provided these have at least equivalent mechanical properties and resistance against the effects of temperature and fire.

(b)

Every part of the vessel including any installation and equipment which may come into contact with the cargo shall consist of materials which can neither be dangerously

affected by the cargo nor cause decomposition of the cargo or react with it so as to form harmful or hazardous products. (c)

Inside vapour pipes and gas discharge pipes shall be protected against erosion.

9.3.3.0.2

Except where explicitly permitted in 9.3.3.03 below or in the certificate of approval, the use of wood, aluminium alloys or plastic materials within the cargo area is prohibited.

9.3.3.0.3

(a)

The use of wood, aluminium alloys or plastic materials within the cargo area is only permitted for: -

(b)

-

movable items of equipment (aluminium gauging rods are, however, permitted provided that they are fitted with brass feet or protected in another way to avoid sparking);

-

chocking of cargo tanks which are independent of the vessel's hull and chocking of installations and equipment;

-

masts and similar round timber;

-

engine parts;

-

parts of the electrical installation;

-

loading and unloading appliances;

-

lids of boxes which are placed on the deck.

The use of wood or plastic materials within the cargo area is only permitted for: -

(c)

(d)

gangways and external ladders;

supports and stops of any kind.

The use of plastic materials or rubber within the cargo area is only permitted for: -

coating of cargo tanks and of hoses for loading and unloading;

-

all kinds of gaskets (e.g. for dome or hatch covers);

-

electric cables;

-

hoses for loading and unloading;

-

insulation of cargo tanks and of hoses for loading and unloading.

All permanently fitted materials in the accommodation or wheelhouse, with the exception of furniture, shall not readily ignite. They shall not evolve fumes or toxic gases in dangerous quantities, if involved in a fire.

9.3.3.0.4

The paint used in the cargo area shall not be liable to produce sparks in case of impact.

9.3.3.0.5

The use of plastic material for vessel's boats is permitted only if the material does not readily ignite.

(Reserved).

Classification The tank vessel shall be built under survey of a recognised classification society in accordance with the rules established by that classification society for its highest class, and the tank vessel shall be classed accordingly. The vessel's class shall be continued. The classification society shall issue a certificate certifying that the vessel is in conformity with the rules of this section. The design pressure and the test pressure of cargo tanks shall be entered in the certificate. If a vessel has cargo tanks with different valve opening pressures, the design and test pressures of each tank shall be entered in the certificate. The classification society shall draw up a certificate mentioning all the dangerous goods accepted for carriage by the vessel (see also 1.16.1.2.5). The cargo pump-rooms shall be inspected by a recognised classification society whenever the certificate of approval has to be renewed as well as during the third year of validity of the certificate of approval. The inspection shall comprise at least: -

an inspection of the whole system for its condition, for corrosion, leakage or conversion works which have not been approved;

-

a checking of the condition of the gas detection system in the cargo pump-rooms.

Inspection certificates signed by the recognised classification society with respect to the inspection of the cargo pump-rooms shall be kept on board. The inspection certificates shall at least include particulars of the above inspection and the results obtained as well as the date of the inspection. The condition of the gas detection system referred to in 9.3.3.52.3 (b) shall be checked by a recognised classification society whenever the certificate of approval has to be renewed and during the third year of validity of the certificate of approval. A certificate signed by the recognised classification society shall be kept on board. 9.3.3.8.2 and 9.3.3.8.3, checking of the condition of the gas detection system, do not apply to open type N.

Protection against the penetration of gases The vessel shall be designed so as to prevent gases from penetrating into the accommodation and the service spaces. Outside the cargo area, the lower edges of door-openings in the sidewalls of superstructures and the coaming of access hatches to under-deck spaces shall have a height of not less than 0.50 m above the deck.

This requirement need not be complied with if the wall of the superstructures facing the cargo area extends from one side of the ship to the other and has doors the sills of which have a height of not less than 0.50 m above the deck. The height of this wall shall be not less than 2.00 m. In this case, the lower edges of door-openings in the sidewalls of superstructures and the coamings of access hatches behind this wall shall have a height of not less than 0.10 m above the deck. The sills of engine room doors and the coamings of its access hatches shall, however, always have a height of not less than 0.50 m. 9.3.3.10.3

In the cargo area, the lower edges of door-openings in the sidewalls of superstructures shall have a height of not less than 0.50 m above the deck and the sills of hatches and ventilation openings of premises located under the deck shall have a height of not less than 0.50 m above the deck. This requirement does not apply to access openings to double-hull and double bottom spaces.

9.3.3.10.4

The bulwarks, foot-rails etc. shall be provided with sufficiently large openings which are located directly above the deck.

9.3.3.10.5

9.3.3.10.1 to 9.3.3.10.4 above do not apply to open type N.

9.3.3.11

Hold spaces and cargo tanks

9.3.3.1 1.1

(a)

The maximum permissible capacity of a cargo tank shall be determined in accordance with the following table: L X B X H(m3)

Maximum permissible capacity of a cargo tank (m3)

up to 600

LxBxHx0.3

600 to 3 750 3 750

180 + ( L x B x H - 600) ~ 0 . 0 6 3 5 380

In the table above L x B x H is the product of the main dimensions of the tank vessel in metres (according to the measurement certificate), where:

L B H

=

= =

overall length of the hull; extreme breadth of the hull; shortest vertical distance between the top of the keel and the lowest point of the deck at the side of the vessel (moulded depth) within the cargo area.

For trunk vessels, H shall be replaced by H', where H' shall be obtained from the following formula:

where: ht

=

bt It

= =

trunk height (distance between trunk deck and main deck measured on trunk side at L/2); trunk breadth; trunk length.

The relative density of the substances to be carried shall be taken into consideration in the design of the cargo tanks. The maximum relative density shall be indicated in the certificate of approval. When the vessel is provided with pressure cargo tanks, these tanks shall be designed for a working pressure of 400 kPa (4 bar). For vessels with a length of not more than 50.00 m, the length of a cargo tank shall not exceed 10.00 m; and For vessels with a length of more than 50.00 m, the length of a cargo tank shall not exceed 0.20 L. This provision does not apply to vessels with independent built-in cylindrical tanks having a length to diameter ratio I 7. The cargo tanks independent of the vessel's hull shall be fixed so that they cannot float. The capacity of a suction well shall be limited to not more than 0.10 m3. The cargo tanks shall be separated by cofferdams of at least 0.60 m in width from the accommodation, engine room and service spaces outside the cargo area below deck or, if there are no such accommodation, engine room and service spaces, from the vessel's ends. Where the cargo tanks are installed in a hold space, a space of not less than 0.50 m shall be provided between such tanks and the end bulkheads of the hold space. In this case an insulated end bulkhead meeting the definition for Class "A-60" according to SOLAS 74, Chapter 11-2, Regulation 3, shall be deemed equivalent to a cofferdam. For pressure cargo tanks, the 0.50 m distance may be reduced to 0.20 m. Hold spaces, cofferdams and cargo tanks shall be capable of being inspected. All spaces in the cargo area shall be capable of being ventilated. Means for checking their gas-free condition shall be provided. The bulkheads bounding the cargo tanks, cofferdams and hold spaces shall be watertight. The cargo tanks and the bulkheads bounding the cargo area shall have no openings or penetrations below deck. The bulkhead between the engine room and the cofferdam or service space in the cargo area or between the engine room and a hold space may be fitted with penetrations provided that they conform to the provisions of 9.3.3.17.5. The bulkhead between the cargo tank and the cargo pump-room below deck may be fitted with penetrations provided that they conform to the provisions of 9.3.3.17.6. The bulkheads between the cargo tanks may be fitted with passages provided that the unloading pipes are fitted with shut-off devices in the cargo tank from which they come. The shut-off devices shall be capable of being activated from the deck. Double-hull spaces and double bottoms in the cargo area shall be arranged for being filled with ballast water only. Double bottoms may, however, be used as oil fuel tanks, provided they comply with the provisions of 9.3.3.32. (a)

A cofferdam, the centre part of a cofferdam or another space below deck in the cargo area may be arranged as a service space, provided the bulkheads bounding the service

space extend vertically to the bottom. This service space shall only be accessible from the deck. (b)

The service space shall be watertight with the exception of its access hatches and ventilation inlets.

(c)

No pipes for loading and unloading shall be fitted within the service space referred to under 9.3.3.1 1.4 above. Pipes for loading and unloading may be fitted in the cargo pump-rooms below deck only when they conform to the provisions of 9.3.3.17.6.

9.3.3.1 1.7

For double-hull construction with the tanks integrated in the vessel's structure or where hold spaces contain cargo tanks which are independent of the structure of the vessel, or where independent cargo tanks are used, or for double-hull construction where the cargo tanks are integrated in vessel's structure, the space between the wall of the vessel and wall of the cargo tanks shall be not less than 0.60 m. The space between the bottom of the vessel and the bottom of the cargo tanks shall be not less than 0.50 m. The space may be reduced to 0.40 m under the pump sumps. The vertical space between the suction well of a cargo tank and the bottom structures shall be not less than 0.10 m. When a hull is constructed in the cargo area as a double hull with independent cargo tanks located in hold spaces, the above values are applicable to the double hull. If in this case the minimum values for inspections of independent tanks referred to in 9.3.3.1 1.9 are not feasible, it must be possible to remove the cargo tanks easily for inspection.

9.3.3.1 1.8

Where service spaces are located in the cargo area under deck, they shall be arranged so as to be easily accessible and to permit persons wearing protective clothing and breathing apparatus to safely operate the service equipment contained therein. They shall be designed so as to allow injured or unconscious personnel to bc removed from such spaces without difficulties, if necessary by means of fixed equipment.

9.3.3.11.9

Cofferdams, doubIe-hull spaces, double bottoms, cargo tanks, hold spaces and other accessible spaces within the cargo area shall be arranged so that they may be completely inspected and cleaned. The dimensions of openings except for those of double-hull spaces and double bottoms which do not have a wall adjoining the cargo tanks shall be sufficient to allow a person wearing breathing apparatus to enter or leave the space without difficulties. These openings shall have a minimum cross-section of 0.36 m2 and a minimum side length of 0.50 m. They shall be designed so as to allow injured or unconscious personnel to be removed from the bottom of such a space without difficulties, if necessary by means of fixed equipment.. In these spaces the free penetration width shall not be less than 0.50 m in the sector intended for the penetration. In double bottoms this distance may be reduced to 0.45 m. Cargo tanks may have circular openings with a diameter of not less than 0.68 m.

9.3.3.11.10

9.3.3.11.6 (c) above does not apply to open type N.

9.3.3.12

Ventilation

9.3.3.12.1

Each hold space shall have two openings the dimensions and location of which shall be such as to permit effective ventilation of any part of the hold space. If there are no such openings, it shall be possible to fill the hold spaces with inert gas or dry air.

Double-hull spaces and double bottoms within the cargo area which are not arranged for being filled with ballast water, hold spaces and cofferdams shall be provided with ventilation systems. Any service spaces located in the cargo area below deck shall be provided with a system of forced ventilation with sufficient power for ensuring at least 20 changes of air per hour based on the volume of the space. The ventilation exhaust ducts shall be located up to 50 mm above the bottom of the service space. The fresh air inlets shall be located in the upper part; they shall be not less than 2.00 m above the deck, not less than 2.00 m from the openings of the cargo tanks and not less than 6.00 m from the outlets of safety valves. The extension pipes which may be necessary may be of the hinged type. On board open type N vessels other suitable installations without ventilator fans shall be sufficient. Ventilation of accommodation and service spaces shall be possible. Ventilators used in the cargo area shall be designed so that no sparks may be emitted on contact of the impeller blades with the housing and no static electricity may be generated. Notice boards shall be fitted at the ventilation inlets indicating the conditions when they shall be closed. Any ventilation inlets of accommodation and service spaces leading outside shall be fitted with fire flaps. Such ventilation inlets shall be located not less than 2.00 m from the cargo area. Ventilation inlets of service spaces in the cargo area below deck may be located within such area. Flame-arresters prescribed in 9.3.3.20.4, 9.3.3.22.4, 9.3.3.22.5 and 9.3.3.26.4 shall be of a type approved for this purpose by the competent authority. 9.3.3.12.5, 9.3.3.12.6 and 9.3.3.12.7 above do not apply to open type N. Stability (general) Proof of sufficient stability shall be furnished. This proof is not required for vessels with cargo tanks the width of which is not more than 0.70 B. The basic values for the stability calculation - the vessel's lightweight and location of the centre of gravity - shall be determined either by means of an inclining experiment or by detailed mass and moment calculation. In the latter case the lightweight of the vessel shall be checked by means of a lightweight test with a tolerance limit of 5% between the mass determined by calculation and the displacement determined by the draught readings.

*

Proof of sufficient intact stability shall be furnished for all stages of loading and unloading and for the final loading condition. For vessels with independent cargo tanks and for double-hull constructions with cargo tanks integrated in the frames of the vessel, floatability after damage shall be proved for the most unfavourable loading condition. For this purpose, calculated proof of sufficient stability shall be established for critical intermediate stages of flooding and for the final stage of flooding. Negative values of stability in intermediate stages of flooding may be accepted

only if the continued range of curve of the righting lever in damaged condition indicates adequate positive values of stability. 9.3.3.14

Stability (intact)

9.3.3.14.1

For vessels with independent cargo tanks and for double-hull constructions with cargo tanks integrated in the frames of the vessel, the requirements for intact stability resulting from the damage stability calculation shall be fully complied with.

9.3.3.14.2

For vessels with cargo tanks of more than 0.70 B in width, proof shall be furnished that the following stability requirements have been complied with: (a) In the positive area of the righting lever curve up to immersion of the first nonwatertight opening there shall be a righting lever (GZ) of not less than 0.10 m; (b) The surface of the positive area of the righting lever curve up to immersion of the first non-watertight opening and in any event up to an angle of heel 5 27" shall not be less than 0.024 m.rad; (c) The metacentric height (GM) shall be not less than 0.10 m. These conditions shall be met bearing in mind the influence of all free surfaces in tanks for all stages of loading and unloading.

9.3.3.15

Stability (damaged condition)

9.3.3.15.1

For vessels with independent cargo tanks and for double-hull constructions with cargo tanks integrated in the frames of the vessel, the following assumptions shall be taken into consideration for the damaged condition: The extent of side damage is as follows: longitudinal extent: at least 0.10 L, but not less than 5.00 m; transverse extent: 0.59 m; vertical extent: from the base line upwards without limit. The extent of bottom damage is as follows: longitudinal extent:

at least 0.10 L, but not less than 5.00 m;

transverse extent: vertical extent:

3.00 m; from the base 0.49 m upwards, the sump excepted.

Any bulkheads within the damaged area shall be assumed damaged, which means that the location of bulkheads shall be chosen so as to ensure that the vessel remains afloat after the flooding of two or more adjacent compartments in the longitudinal direction. The following provisions are applicable: -For bottom damage, adjacent athwartship compartments shall also be assumed as flooded; -The lower edge of any non-watertight openings (e.g. doors, windows, access hatchways) shall, at the final stage of flooding, be not less than 0.10 m above the damage waterline;

-

In general, permeability shall be assumed to be 95%. Where an average permeability of less than 95% is calculated for any compartment, this calculated value obtained may be used.

However, the following minimum values shall be used: - engine rooms:

85%; - accommodation: 95%; - double bottoms, oil fuel tanks, ballast tanks, etc., depending on whether, according to their function, they have to be assumed as full or empty for the vessel floating at the maximum permissible draught: 0% or 95%. For the main engine room only the one-compartment standard need be taken into account, i.e. the end bulkheads of the engine room shall be assumed as not damaged. 9.3.3.15.2

At the stage of equilibrium (final stage of flooding), the angle of heel shall not exceed 12". Non-watertight openings shall not be flooded before reaching the stage of equilibrium. If such openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purpose of the stability calculation. The positive range of the righting lever curve beyond the stage of equilibrium shall have a righting lever of 3 0.05 m in association with an area under the curve of > 0.0065 m.rad. The minimum values of stability shall be satisfied up to immersion of the first non-watertight opening and in any event up to an angle of heel < 27". If non-watertight openings are immersed before that stage, the corresponding spaces shall be considered as flooded for the purposes of stability calculation.

II / / / I

K F i r s t floodable non-weathertight opening, however 5 27" Equilibrium position (Final buoyancy position)

I

I

9.3.3.15.3

If openings through which undamaged compartments may additionally become flooded are capable of being closed watertight, the closing appliances shall be marked accordingly.

9.3.3.15.4

Where cross- or down-flooding openings are provided for reduction of unsymmetrical flooding, the time for equalization shall not exceed 15 minutes, if during the intermediate stages of flooding sufficient stability has been proved.

Engine rooms Internal combustion engines for the vessel's propulsion as well as internal combustion engines for auxiliary machinery shall be located outside the cargo area. Entrances and other openings of engine rooms shall be at a distance of not less than 2.00 m from the cargo area. The engine rooms shall be accessible from the deck; the entrances shall not face the cargo area. Where the doors are not located in a recess whose depth is at least equal to the door width, the hinges shall face the cargo area. The last sentence of 9.3.3.16.2 does not apply to oil separator or supply vessels. Accommodation and service spaces Accommodation spaces and the wheelhouse shall be located outside the cargo area forward of the fore vertical plane or abaft the aft vertical plane bounding the part of cargo area below deck. Windows of the wheelhouse which are located not less than 1.00 m above the bottom of the wheelhouse may tilt forward. Entrances to spaces and openings of superstructures shall not face the cargo area. Doors opening outward and not located in a recess whose depth is at least equal to the width of the doors shall have their hinges face the cargo area. Entrances from the deck and openings of spaces facing the weather shall be capable of being closed. The following instruction shall be displayed at the entrance of such spaces:

Do not open during loading and unloading without the permission of the master. Close immediately. Entrances and windows of superstructures and accommodation spaces which can be opened as well as other openings of these spaces shall be located not less than 2.00 m from the cargo area. No wheelhouse doors and windows shall be located within 2.00 m from the cargo area, except where there is no direct connection between the wheelhouse and the accommodation. Driving shafts of the bilge or ballast pumps may penetrate through the bulkhead between the service space and the engine room, provided the arrangement of the service space is in compliance with 9.3.3.1 1.6. The penetration of the shaft through the bulkhead shall be gastight and shall have been approved by a recognised classification society. The necessary operating instructions shall be displayed. Penetrations through the bulkhead between the engine room and the service space in the cargo area and the bulkhead between the engine room and the hold spaces may be provided for electrical cables, hydraulic lines and piping for measuring, control and alarm systems, provided that the penetrations have been approved by a recognised classification society. The penetrations shall be gastight. Penetrations through a bulkhead with an "A-60 fire protection insulation according to SOLAS 74, Chapter 11-2, Regulation 3, shall have an equivalent fire protection. Pipes may penetrate the bulkhead between the engine room and the service space in the cargo area provided that these are pipes between the mechanical equipment in the engine room and the service space which do not have any openings within the service

space and which are provided with shut-off devices at the bulkhead in the engine room.

9.3.3.17.6

(Q

Notwithstanding 9.3.3.11.4, pipes from the engine room may pass through the service space in the cargo area or a cofferdam or a hold space or a double-hull space to the outside provided that within the service space or cofferdam or hold space or doublehull space they are of the thick-walled type and have no flanges or openings.

(g)

Where a driving shaft of auxiliary machinery penetrates through a wall located above the deck the penetration shall be gastight.

A service space located within the cargo area below deck shall not be used as a cargo pumproom for the loading and unloading system, except where: -

the cargo pump-room is separated from the engine room or from service spaces outside the cargo area by a cofferdam or a bulkhead with an "A-60" fire protection insulation according to SOLAS 74, Chapter 11-2, Regulation 3, or by a service space or a hold space;

-

the "A-60" bulkhead required above does not include penetrations referred to in 9.3.3.17.5 (a);

-

ventilation exhaust outlets are located not less than 6.00 m from entrances and openings of the accommodation and service spaces outside the cargo area;

-

the access hatches and ventilation inlets can be closed from the outside;

-

all pipes for loading and unloading as well as those of stripping systems are provided with shut-off devices at the pump suction side in the cargo pump-room immediately at the bulkhead. The necessary operation of the control devices in the pump-room, starting of pumps and control of the liquid flow rate shall be effected from the deck;

-

the bilge of the cargo pump-room is equipped with a gauging device for measuring the filling level which activates a visual and audible alarm in the wheelhouse when liquid is accumulating in the cargo pump-room bilge; the cargo pump-room is provided with a permanent gas detection system which automatically indicates the presence of explosive gases or lack of oxygen by means of direct-measuring sensors and which actuates a visual and audible alarm when the gas concentration has reached 20% of the lower explosive limit. The sensors of this system shall be placed at suitable positions at the bottom and directly below the deck. Measurement shall be continuous. The audible and visual alarms are installed in the wheelhouse and in the cargo pumproom and, when the alarm is actuated, the loading and unloading system is shut down. Failure of the gas detection system shall be immediately signalled in the wheelhouse and on deck by means of audible and visual alarms;

-

9.3.3.17.7

the ventilation system prescribed in 9.3.3.12.3 has a capacity of not less than 30 changes of air per hour based on the total volume of the service space.

The following instruction shall be displayed at the entrance of the cargo pump-room: Before entering the cargo pump-room check whether it is free from gases and contains sufficient oxygen. - 415 -

Do not open doors and entrance openings without the permission of the master. Leave immediately in the event of alarm. 9.3.3.17.5 (g), 9.3.3.17.6 and 9.3.3.17.7 do not apply to open type N. 9.3.3.17.2, last sentence, 9.3.3.17.3, last sentence and 9.3.3.17.4 do not apply to oil separator and supply vessels.

Inerting facility In cases in which inerting or blanketing of the cargo is prescribed, the vessel shall be equipped with an inerting system. This system shall be capable of maintaining a permanent minimum pressure of 7 kPa (0.07 bar) in the spaces to be inerted. In addition, the inerting system shall not increase the pressure in the cargo tank to a pressure greater than that at which the pressure valve is regulated. The set pressure of the vacuum-relief valve shall be 3.5 kPa.

A sufficient quantity of inert gas for loading or unloading shall be carried or produced on board if it is not possible to obtain it on shore. In addition, a sufficient quantity of inert gas to offset normal losses occurring during carriage shall be on board. The premises to be inerted shall be equipped with connections for introducing the inert gas and monitoring systems so as to ensure the correct atmosphere on a permanent basis. When the pressure or the concentration of inert gas in the gaseous phase falls below a given value, this monitoring system shall activate an audible and visible alarm in the wheelhouse. When the wheelhouse is unoccupied, the alarm shall also be perceptible in a location occupied by a crew member. (Reserved).

Arrangement of cofferdams Cofferdams or cofferdam compartments remaining once a service space has been arranged in accordance with 9.3.3.1 1.6 shall be accessible through an access hatch. If, however, the cofferdam is connected to a double-hull space, it is sufficient for it to be accessible from that space. For openings giving access to double-hull spaces on deck the last sentence of 9.3.2.10.3 remains applicable. In this case an arrangement shall be made for possible monitoring in order to ascertain from the deck whether the cofferdam is empty. Cofferdams shall be capable of being filled with water and emptied by means of a pump. Filling shall be effected within 30 minutes. These requirements are not applicable when the bulkhead between the engine room and the cofferdam has an "A-16" fire protection insulation according to SOLAS 74, Chapter 11-2, Regulation 3. The cofferdams shall not be fitted with inlet valves. No fixed pipe shall permit connection between a cofferdam and other piping of the vessel outside the cargo area. The ventilation openings of cofferdams shall be fitted with a flame-arrester.

9.3.3.20.5

9.3.3.20.4 above does not apply to open type N. 9.3.3.20.2 above does not apply to oil separator and supply vessels.

9.3.3.21

Safety and control installations

9.3.3.2 1.1

Cargo tanks shall be provided with the following equipment: (a)

a mark inside the tank indicating the liquid level of 97%;

(b)

a level gauge;

(c)

a level alarm device which is activated at the latest when a degree of filling of 90% is reached;

(d)

a high level sensor for actuating the facility against overflowing when a degree of filling of 97.5% is reached;

(e)

an instrument for measuring the pressure of the vapour phase inside the cargo tank;

(0

an instrument for measuring the temperature of the cargo if in column (9) of Table C of Chapter 3.2 a heating installation is required or if in column (20) a possibility of heating the cargo is required or if a maximum temperature is indicated;

(g)

a connection for a sampling device, closed or partially closed, andor at least one sampling opening as required in column (13) of Table C of Chapter 3.2.

9.3.3.21.2

When the degree of filling in per cent is determined, an error of not more than 0.5% is permitted. It shall be calculated on the basis of the total cargo tank capacity including the expansion trunk.

9.3.3.21.3

The level gauge shall allow readings from the control position of the shut-off devices of the particular cargo tank. The permissible maximum filling level of the cargo tank shall be

marked on each level gauge. Permanent reading of the overpressure and vacuum shall be possible from a location from which loading or unloading operations may be interrupted. The permissible maximum overpressure and vacuum shall be marked on each level gauge. Readings shall be possible in all weather conditions. 9.3.3.21.4

The level alarm device shall give a visual and audible warning on board when actuated. The level alarm device shall be independent of the level gauge.

9.3.3.21.5

(a)

The high level sensor referred to in 9.3.3.21.1 (d) above shall give a visual and audible alarm on board and at the same time actuate an electrical contact which in the form of a binary signal interrupts the electric current loop provided and fed by the shore facility, thus initiating measures at the shore facility against overflowing during loading operations. The signal shall be transmitted to the shore facility via a watertight two-pin plug of a connector device in accordance with standard EN 60309-2:1999 for direct current of 40 to 50 volts, identification colour white, position of the nose 10 h. The plug shall be permanently fitted to the vessel close to the shore connections of the loading and unloading pipes.

The high level sensor shall also be capable of switching off the vessel's own discharging pump. The high level sensor shall be independent of the level alarm device, but it may be connected to the level gauge. On board oil separator vessels the sensor referred to in 9.3.3.21.1 (d) shall activate a visual and audible alarm and switch off the pump used to evacuate bilge water. Supply vessels and other vessels which may be delivering products required for operation shall be equipped with a transshipment facility compatible with European standard EN 12 827:1996 and a rapid closing device enabling refuelling to be interrupted. It shall be possible to actuate this rapid closing device by means of an electrical signal from the overflow prevention system. The electrical circuits actuating the rapid closing device shall be secured according to the quiescent current principle or other appropriate error detection measures. The state of operation of electrical circuits which cannot be controlled using the quiescent current principle shall be capable of being easily checked. It shall be possible to actuate the rapid closing device independently of the electrical signal. The rapid closing device shall actuate a visual and an audible alarm on board. During discharging by means of the on-board pump, it shall be possible for the shore facility to switch it off. For this purpose, an independent intrinsically safe power line, fed by the vessel, shall be switched off by the shore facility by means of an electrical contact. It shall be possible for the binary signal of the shore facility to be transmitted via a watertight two-pole socket or a connector device in accordance with standard EN 60309-2: 1999, for direct current of 40 to 50 volts, identification colour white, position of the nose 10 h. This socket shall be permanently fitted to the vessel close to the shore connections of the unloading pipes. 9.3.3.21.6

The visual and audible signals given by the level alarm device shall be clearly distinguishable from those of the high level sensor. The visual alarm shall be visible at each control position on deck of the cargo tank stop valves. It shall be possible to easily check the functioning of the sensors and electric circuits or these shall be intrinsically safe apparatus.

9.3.3.21.7

When the pressure or temperature exceeds a set value, instruments for measuring the vacuum or overpressure of the gaseous phase in the cargo tank or the temperature of the cargo, shall activate a visual and audible alarm in the wheelhouse. When the wheelhouse is unoccupied, the alarm shall also be perceptible in a location occupied by a crew member. When the pressure exceeds the set value during loading, the instrument for measuring the pressure shall, by means of the plug referred to in 9.3.3.21S, initiate simultaneously an electrical contact which shall put into effect measures to interrupt the loading operation. If the vessel's own discharge pump is used, it shall be switched off automatically. The instrument for measuring the overpressure or vacuum shall activate the alarm at latest when an overpressure equal to 1.15 times the opening pressure of the pressure relief device, or a vacuum pressure equal to the construction vacuum pressure but not exceeding 5 kPa. The maximum allowable temperature is indicated in column (20) of Table C of

Chapter 3.2. The sensors for the alarms mentioned in this paragraph may be connected to the alarm device of the sensor. When it is prescribed in column (20) of Table C of Chapter 3.2 the instrument for measuring the overpressure of the gaseous phase shall activate a visible and audible alarm in the wheelhouse when the overpressure exceeds 40 kPa during the voyage. When the wheelhouse is unoccupied, the alarm shall also be perceptible in a location occupied by a crew member. 9.3.3.21.8

Where the control elements of the shut-off devices of the cargo tanks are located in a control room, it shall be possible to stop the loading pumps and read the level gauges in the control room, and the visual and audible warning given by the level alarm device, the high level sensor referred to in 9.3.3.21.1 (d) and the instruments for measuring the pressure and temperature of the cargo shall be noticeable in the control room and on deck. Satisfactory monitoring of the cargo area shall be ensured from the control room.

9.3.3.21.9

9.3.3.21.1 (e), 9.3.3.2 1.7 as regards measuring the pressure, do not apply to open type N with flame-arrester and to open type N. 9.3.3.21. l (b), (c) and (g), 9.3.3.21.3 and 9.3.3.21.4 do not apply to oil separator and supply vessels. Screens in sampling openings are not required on board open type N tank vessels. 9.3.3.21.1 (Qand 9.3.3.21.7 do not apply to supply vessels. 9.3.3.21.5 (a) does not apply to oil separator vessels.

9.3.3.22

Cargo tank openings

9.3.3.22.1

(a)

Cargo tank openings shall be located on deck in the cargo area.

(b)

Cargo tank openings with a cross-section of more than 0.10 m2 and openings of safety devices for preventing overpressures shall be located not less than 0.50 m above deck.

9.3.3.22.2

Cargo tank openings shall be fitted with gastight closures capable of withstanding the test pressure in accordance with 9.3.3.23.1.

9.3.3.22.3

Closures which are normally used during loading or unloading operations shall not cause sparking when operated.

9.3.3.22.4

(a)

Each cargo tank or group of cargo tanks connected to a common vapour pipe shall be fitted with safety devices for preventing unacceptable overpressures or vacuums. These safety devices shall be as follows: for the open N type: -

safety devices designed to prevent any accumulation of water and its penetration into the cargo tanks;

for the open N type with flame-arresters: -

safety equipment fitted with flame-arresters capable of withstanding steady burning and designed to prevent any accumulation of water and its penetration into the cargo tank;

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for the closed N type: -

safety devices for preventing unacceptable overpressure or vacuum. Where antiexplosion protection is required in column (17) of Table C of Chapter 3.2, the vacuum valve shall be fitted with a flame arrester capable of withstanding a deflagration and the pressure relief valve with a high-velocity vent valve acting as a flame arrester capable of withstanding steady burning. Gases shall be discharged upwards. The opening pressure of the high-velocity vent valve and the opening pressure of the vacuum valve shall be permanently marked on the valves.

-

a connection for the safe return ashore of gases expelled during loading; a device for the safe depressurisation of the cargo tanks consisting of at least a flame-arresters and a stop valve the position of which shall clearly indicate whether it is open or shut.

9.3.3.22.5

(b)

The outlets of high-velocity vent valves shall be located not less than 2.00 m above the deck and at a distance of not less than 6.00 m from the accommodation and from the service spaces outside the cargo area. This height may be reduced when within a radius of 1.00 m round the outlet of the high-velocity vent valve, there is no equipment, no work is being carried out and signs indicate the area. The setting of the high-velocity vent valves shall be such that during the transport operation they do not blow off until the maximum permissible working pressure of the cargo tanks is reached.

(a)

Insofar as anti-explosion protection is prescribed in column (17) of Table C of Chapter 3.2, a vapour pipe connecting two or more cargo tanks shall be fitted, at the connection to each cargo tank, with a flame arrester with a fixed or spring-loaded plate stack, capable of withstanding detonation. This equipment may consist of: (i)

a flame arrester fitted with a fixed plate stack, where each cargo tank is fitted with a vacuum valve capable of withstanding a deflagration and a high-velocity vent valve capable of withstanding steady burning;

(ii)

a flame arrester fitted with a spring-loaded plate stack, where each cargo tank is fitted with a vacuum valve capable of withstanding a deflagration;

(iii)

a flame arrester with a fixed plate stack;

(iv)

a flame arrester with a fixed plate stack, where the pressure measurement device is fitted with an alarm system in accordance with 9.3.3.21.7;

(v)

a flame arrester with a spring-loaded plate stack, where the pressure measurement device is fitted with an alarm system in accordance with 9.3.3.21.7.

Only substances which do not mix and which do not react dangerously with each other may be carried simultaneously in cargo tanks connected to a common vapour pipe;

(b)

Insofar as anti-explosion protection is prescribed in column (17) of Table C of Chapter 3.2, a vapour pipe connecting two or more cargo tanks shall be fitted, at the

connection to each cargo tank, with a pressure/vacuum valve incorporating a flame arrester capable of withstanding a detonationldeflagration. Only substances which do not mix and which do not react dangerously with each other may be carried simultaneously in cargo tanks connected to a common vapour pipe;

Insofar as anti-explosion protection is prescribed in column (17) of Table C of Chapter 3.2, an independent vapour pipe for each cargo tank, fitted with a pressure/vacuum valve incorporating a flame arrester capable of withstanding a deflagration and a high-velocity vent value incorporating a flame arrester capable of withstanding steady burning. Several difference substances may be carried simultaneously;

Insofar as anti-explosion protection is prescribed in column (17) of Table C of Chapter 3.2, a vapour pipe connecting two or more cargo tanks shall be fitted, at the connection to each cargo tank, with a shut-off device capable of withstanding a detonation, where each cargo tank is fitted with a vacuum valve capable of withstanding a deflagration and a high-velocity vent valve capable of withstanding steady burning. Only substances which do not mix and which do not react dangerously with each other may be carried simultaneously in cargo tanks connected to a common vapour pipe. 9.3.3.22.2, 9.3.3.22.4 (b) and 9.3.3.22.5 do not apply to open type N with flame-arrester and to open type N. 9.3.3.22.3 does not apply to open type N. Pressclre tests

The cargo tanks, residual cargo tanks, cofferdams, pipes for loading and unloading, with the exception of discharge hoses shall be subjected to initial tests before being put into service and thereafter at prescribed intervals. Where a heating system is provided inside the cargo tanks, the heating coils shall be subjected to initial tests before being put into service and thereafter at prescribed intervals. The test pressure for the cargo tanks and residual cargo tanks shall be not less than 1.3 times the design pressure. The test pressure for the cofferdams and open cargo tanks shall be not less than 10 kPa (0.10 bar) gauge pressure. The test pressure for pipes for loading and unloading shall be not less than 1,000 kPa (10 bar) gauge pressure. The maximum intervals for the periodic tests shall be 11 years. The procedure for pressure tests shall comply with the provisions established by the competent authority or a recognised classification society. (Reserved,).

9.3.3.25

Pumps and piping

Pumps and accessory loading and unloading piping shall be located in the cargo area. Cargo pumps shall be capable of being shut down from the cargo area and from a position outside the cargo area. Cargo pumps situated on deck shall be located not less than 6.00 m from entrances to, or openings of, the accommodation and service spaces outside the cargo area. 9.3.3.25.2

(a)

Pipes for loading and unloading shall be independent of any other piping of the vessel. No cargo piping shall be located below deck, except those inside the cargo tanks and inside the cargo pump-room. The pipes for loading and unloading shall be arranged so that, after loading or unloading operations, the liquid remaining in these pipes may be safely removed and may flow either into the vessel's cargo tanks or the tanks ashore. Pipes for loading and unloading shall be clearly distinguishable from other piping, e.g. by means of colour marking. (Reserved). The shore connections shall be located not less than 6.00 m from the entrances to, or openings of, the accommodation and service spaces outside the cargo area. Each shore connection of the vapour pipe and shore connections of the pipes for loading and unloading, through which the loading or unloading operation is carried out, shall be fitted with a shut-off device. However, each shore connection shall be fitted with a blind flange when it is not in operation. Each shore connection of the pipes for loading and unloading through which the loading or unloading operation is carried out shall be fitted with the device intended for the discharge of residual cargo described in the model in 8.6.4.1. The vessel shall be equipped with a stripping system.

9.3.3.25.3

The distance referred to in 9.3.3.25.1 (c) and (e) and 9.3.3.25.2 (e) may be reduced to 3.00 m if a transverse bulkhead complying with 9.3.3.10.2 is situated at the end of the cargo area. The openings shall be provided with doors. The following notice shall be displayed on the doors: Do not open during loading and unloading without the permission of the master. Close immediately.

9.3.3.25.4

9.3.3.25.5

(a)

Every component of the pipes for loading and unloading shall be electrically connected to the hull.

(b)

The pipes for loading shall extend down to the bottom of the cargo tanks.

The stop valves or other shut-off devices of the pipes for loading and unloading shall indicate whether they are open or shut.

9.3.3.25.6

The pipes for loading and unloading shall have, at the test pressure, the required elasticity, leakproofness and resistance to pressure.

9.3.3.25.7

The permissible maximum overpressure or vacuum value shall be indicated on each installation. Readings shall be possible in all weather conditions.

9.3.3.25.8

(a)

When pipes for loading and unloading are used for supplying the cargo tanks with washing or ballast water, the suctions of these pipes shall be located within the cargo area but outside the cargo tanks. Pumps for tank washing systems with associated connections may be located outside the cargo area, provided the discharge side of the system is arranged in such a way that suction is not possible through that part. A spring-loaded non-return valve shall be provided to prevent any gases from being expelled from the cargo area through the tank washing system.

(b) 9.3.3.25.9

A non-return valve shall be fitted at the junction between the water suction pipe and the cargo loading pipe.

The permissible loading and unloading flows shall be calculated. For open type N with flame-arrester and open type N the loading and unloading flows depend on the total crosssection of the exhaust ducts. Calculations concerning the permissible maximum loading and unloading flows for each cargo tank or each group of cargo tanks, taking into account the design of the ventilation system. These calculations shall take into consideration the fact that in the event of an unforeseen cut-off of the gas return piping or the compensation piping of the shore facility, the safety devices of the cargo tanks will prevent pressure in the cargo tanks from exceeding the following values: over pressure:

115% of the opening pressure of the high velocity vent valve

vacuum pressure: not more than the construction vacuum pressure but not exceeding 5 kPa (0.05 bar) The main factors to be considered are the following: 1.

Dimensions of the ventilation system of the cargo tanks;

2.

Gas formation during loading: multiply the largest loading flow by a factor of not less than 1.25;

3.

Density of the vapour mixture of the cargo based on 50% volume vapour of 50% volume air;

4.

Loss of pressure through ventilation pipes, valves and fittings. Account will be taken of a 30% clogging of the mesh of the flame-arrester;

5.

Chocking pressure of the safety valves.

The permissible maximum loading and unloading pressure for each cargo tank or for each group of cargo tanks shall be given in an on-board instruction. 9.3.3.25.10

The stripping system shall be subjected to initial tests before being put into service or thereafter if any alteration has been made to it, using water as test medium. The test and the

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determination of the residual quantities shall be carried out in accordance with the requirements of 8.6.4.2. In this test, the following residual quantities shall not be exceeded: (a)

5 1 for each cargo tank;

(b)

15 1 for each pipe system.

The residual quantities obtained in the test shall be entered in the certificate in 8.6.4.3. 9.3.3.25.1 1

If the vessels is carrying several dangerous substances liable to react dangerously with each other, a separate pump with its own piping for loading and unloading shall be installed for each substance. The piping shall not pass through a cargo tank containing dangerous substances with which the substance in question is liable to react.

9.3.3.25.12

9.3.3.25.1 (a) and (c), 9.3.3.25.2 (a), last sentence and (e), 9.3.3.25.3 and 9.3.3.25.4 (a) do not apply to type N open unless the substance carried has corrosive properties (see column (5) of Table C of Chapter 3.2, hazard 8). 9.3.3.25.4 (b) does not apply to open type N. 9.3.3.25.2 (Q,last sentence, 9.3.3.25.2 (g), 9.3.3.25.8 (a), last sentence and 9.3.3.25.10 do not apply to oil separator and supply vessels. 9.3.3.25.9 does not apply to oil separator vessels. 9.3.3.25.2 (h) does not apply to supply vessels.

9.3.3.26

Residual cargo tanks and slop tanks

9.3.3.26.1

The vessel shall be provided with at least one residual cargo tank and with at least one tank for slops. These tanks shall be located only in the cargo area. Intermediate bulk containers or tank-containers or portable tanks in accordance with 7.2.4.1 may be used instead of a fixed residual cargo tank. During filling of intermediate bulk containers or tank-containers or portable tanks, means for collecting any leakage shall be placed under the filling connections.

9.3.3.26.2

Slop tanks shall be fire resistant and shall be capable of being closed with lids (e.g. drums with lever closing ring lids). The tanks shall be marked and easy to handle.

9.3.3.26.3

The maximum permissible capacity of a residual cargo tank is 30 m3.

9.3.3.26.4

The residual cargo tanks shall be equipped with: -

-

in the case of an open system: -

a device for ensuring pressure equilibrium;

-

an ullage opening;

-

connections, with stop valves, for pipes and hoses;

in the case of a protected system:

-

-

a device for ensuring pressure equilibrium, fitted with a flame-arrester capable of withstanding steady burning;

-

an ullage opening;

-

connections, with stop valves, for pipes and hoses;

in the case of a closed system: -

a vacuum valve and a high-velocity vent valve. The high-velocity vent valve shall be so regulated that it does not open during carriage. This condition is met when the opening pressure of the valve meets the conditions required in column (10) of Table C of Chapter 3.2 for the substance to be carried. When anti-explosion protection is required in column (17) of Table C of Chapter 3.2, the vacuum valve shall be capable of withstanding deflagrations and the high-velocity vent valve steady burning;

-

a device for measuring the degree of filling;

-

connections, with stop valves, for pipes and hoses.

Intermediate bulk containers (IBCs), tank containers and portable tanks intended to collect cargo remains, cargo residues or slops shall be equipped with:

-

a connection enabling gases released during filling to be evacuated safely;

-

a possibility of indicating the degree of filling;

-

connections with shut-off devices, for pipes and hoses.

Residual cargo tanks, intermediate bulk containers (IBCs), tank containers and portable tanks shall be connected to the vapour pipe of cargo tanks only for the time necessary to fill them in accordance with 7.2.4.15.2. Residual cargo tanks, intermediate bulk containers (IBCs), tank containers and portable tanks placed on the deck shall be located at a minimum distance from the hull equal to one quarter of the vessel's breadth. 9.3.3.26.5

9.3.3.26.1 and 9.3.3.26.3 above do not apply to oil separator vessels.

9.3.3.27

(Reserved).

9.3.3.28

Water-spray system

When water-spraying is required in column (9) of Table C of Chapter 3.2, a water-spray system shall be installed in the cargo area on deck for the purpose of cooling the tops of cargo tanks by spraying water over the whole surface so as to avoid safely the activation of the high-velocity vent valve at 10 kPa or as regulated. The spray nozzles shall be so installed that the entire cargo deck area is covered and the gases released are precipitated safely. The system shall be capable of being put into operation from the wheelhouse and from the deck. Its capacity shall be such that when all the spray nozzles are in operation, the outflow is not less than 50 litres per square metre of deck area and per hour.

(Reserved).

Engines Only internal combustion engines running on fuel with a flashpoint of more than 55 "C are allowed. Ventilation inlets of the engine room and, when the engines do not take in air directly from the engine room, air intakes of the engines shall be located not less than 2.00 m from the cargo area. Sparking shall not be possible within the cargo area. The surface temperature of the outer parts of engines used during loading or unloading operations, as well as that of their air inlets and exhaust ducts shall not exceed the allowable temperature according to the temperature class. This provision does not apply to engines installed in service spaces provided the provisions of 9.3.3.52.3 (b) are fully complied with. The ventilation in the closed engine room shall be designed so that, at an ambient temperature of 20 "C, the average temperature in the engine room does not exceed 40 "C. 9.3.3.3 1.2 above does not apply to oil separator or supply vessels. Oil fuel tanks Where the vessel is provided with hold spaces, the double bottoms within these spaces may be arranged as liquid oil fuel tanks, provided their depth is not less than 0.60 m. Liquid oil fuel pipes and openings of such tanks are not permitted in the hold space. The open ends of the air pipes of each liquid oil fuel tank shall extend to 0.5 m above the open deck. These open ends and the open ends of overflow pipes leading to the deck shall be provided with a protective device consisting of a gauze diaphragm or a perforated plate. (Reserved). Exhaust pipes Exhaust shall be evacuated from the vessel into the open air either upwards through an exhaust pipe or through the shell plating. The exhaust outlet shall be located not less than 2.00 m from the cargo area. The exhaust pipes of engines shall be arranged so that the exhausts are led away from the vessel. The exhaust pipes shall not be located within the cargo area. Exhaust pipes shall be provided with a device preventing the escape of sparks, e.g. spark arresters. The distance prescribed in 9.3.3.34.1 above does not apply to oil separator or supply vessels. Bilge pumping and ballasting arrangements Bilge and ballast pumps for spaces within the cargo area shall be installed within such area. This provision does not apply to:

-

double-hull spaces and double bottoms which do not have a common boundary wall with the cargo tanks;

-

cofferdams, double-hull, double bottom and hold spaces where ballasting is carried out using the piping of the fire-fighting system in the cargo area and bilge-pumping is performed using eductors.

Where the double bottom is used as a liquid oil fuel tank, it shall not be connected to the bilge piping system. Where the ballast pump is installed in the cargo area, the standpipe and its outboard connection for suction of ballast water shall be located within the cargo area but outside the cargo tanks. A cargo pump-room below deck shall be capable of being drained in an emergency by an installation located in the cargo area and independent from any other installation. The installation shall be provided outside the cargo pump-room.

(Resewed).

Fire-extinguishing arrangements A fire-extinguishing system shall be installed on the vessel. This system shall comply with the following requirements: -

It shall be supplied by two independent fire or ballast pumps, one of which shall be ready for use at any time. These pumps and their means of propulsion and electrical equipment shall not be installed in the same space.;

-

It shall be provided with a water main fitted with at least three hydrants in the cargo area above deck. Three suitable and sufficiently long hoses with spray nozzles having a diameter of not less than 12 mm shall be provided. It shall be possible to reach any point of the deck in the cargo area simultaneously with at least two jets of water which do not emanate from the same hydrant; A spring-loaded non-return valve shall be fitted to ensure that no gases can escape through the fire-extinguishing system into the accommodation or service spaces outside the cargo area;

-

The capacity of the system shall be at least sufficient for a jet of water to have a minimum reach of not less than the vessel's breadth from any location on board with two spray nozzles being used at the same time.

In addition the engine room, the pump-room and all spaces containing essential equipment (switchboards, compressors, etc.) for the refrigeration equipment, if any, shall be provided with a fixed fire-extinguishing system meeting the following requirements: Extinguishing agents For the protection of spaces in engine rooms, boiler rooms and pump rooms, only permanently fixed fire-extinguishing systems using the following extinguishing agents are permitted: (a)

COz (carbon dioxide);

(b)

HFC 227 ea (heptafluoropropane);

(c)

IG-541 (52% nitrogen, 40% argon, 8% carbon dioxide).

Other extinguishing agents are permitted only on the basis of recommendations by the Administrative Committee. Ventilation, air extraction The combustion air required by the combustion engines which ensure propulsion should not come from spaces protected by permanently fixed fire-extinguishing systems. This requirement is not mandatory if the vessel has two independent main engine rooms with a gastight separation or if, in addition to the main engine room, there is a separate engine room installed with a bow thruster that can independently ensure propulsion in the event of a fire in the main engine room. All forced ventilation systems in the space to be protected shall be shut down automatically as soon as the fire-extinguishing system is activated. All openings in the space to be protected which permit air to enter or gas to escape shall be fitted with devices enabling them to be closed rapidly. It shall be clear whether they are open or closed. Air escaping from the pressure-relief valves of the pressurised air tanks installed in the engine rooms shall be evacuated to the open air. Overpressure or negative pressure caused by the diffusion of the extinguishing agent shall not destroy the constituent elements of the space to be protected. It shall be possible to ensure the safe equalisation of pressure. Protected spaces shall be provided with a means of extracting the extinguishing agent. If extraction devices are installed, it shall not be possible to start them up during extinguishing. Fire alarm system The space to be protected shall be monitored by an appropriate fire alarm system. The alarm signal shall be audible in the wheelhouse, the accommodation and the space to be protected. Piping system (a)

The extinguishing agent shall be routed to and distributed in the space to be protected by means of a permanent piping system. Piping installed in the space to be protected and the reinforcements it incorporates shall be made of steel. This shall not apply to the connecting nozzles of tanks and compensators provided that the materials used have equivalent fire-retardant properties. Piping shall be protected against corrosion both internally and externally.

(b)

The discharge nozzles shall be so arranged as to ensure the regular diffusion of the extinguishing agent.

Triggering device (a)

Automatically activated fire-extinguishing systems are not permitted.

It shall be possible to activate the fire-extinguishing system from a suitable point located outside the space to be protected. Triggering devices shall be so installed that they can be activated in the event of a fire and so that the risk of their breakdown in the event of a fire or an explosion in the space to be protected is reduced as far as possible. Systems which are not mechanically activated shall be supplied from two energy sources independent of each other. These energy sources shall be located outside the space to be protected. The control lines located in the space to be protected shall be so designed as to remain capable of operating in the event of a fire for a minimum of 30 minutes. The electrical installations are deemed to meet this requirement if they conform to the IEC 6033 1-21:1999 standard. When the triggering devices are so placed as not to be visible, the component concealing them shall carry the "Fire-fighting system" symbol, each side being not less than 10 cm in length, with the following text in red letters on a white ground: Fire-extinguishing system If the fire-extinguishing system is intended to protect several spaces, it shall comprise a separate and clearly-marked triggering device for each space. The instructions shall be posted alongside all triggering devices and shall be clearly visible and indelible. The instructions shall be in a language the master can read and understand and if this language is not English, French or German, they shall be in English, French or German. They shall include information concerning: (i)

the activation of the fire-extinguishing system;

(ii)

the need to ensure that all persons have left the space to be protected;

(iii)

the correct behaviour of the crew in the event of activation;

(iv)

the correct behaviour of the crew in the event of the failure of the fire-extinguishing system to function properly.

The instructions shall mention that prior to the activation of the fire-extinguishing system, combustion engines installed in the space and aspirating air from the space to be protected, shall be shut down. 9.3.3.40.2.6

Alarm device

Permanently fixed fire-extinguishing systems shall be fitted with an audible and visual alarm device. The alarm device shall be set off automatically as soon as the fire-extinguishing system is first activated. The alarm device shall hnction for an appropriate period of time before the extinguishing agent is released; it shall not be possible to turn it off; Alarm signals shall be clearly visible in the spaces to be protected and their access points and be clearly audible under operating conditions corresponding to the highest possible sound level. It shall be possible to distinguish them clearly from all other sound and visual signals in the space to be protected.

Sound alarms shall also be clearly audible in adjoining spaces, with the communicating doors shut, and under operating conditions corresponding to the highest possible sound level. If the alarm device is not intrinsically protected against short circuits, broken wires and drops in voltage, it shall be possible to monitor its operation. A sign with the following text in red letters on a white ground shall be clearly posted at the entrance to any space the extinguishing agent may reach:

Warning, fire-extinguishing system! Leave this space immediately when the (description) alarm is activated!

...

Pressurised tanks, Jittings and piping (a)

Pressurised tanks, fittings and piping shall conform to the requirements of the competent authority.

(b)

Pressurised tanks shall be installed in accordance with the manufacturer's instructions.

(c)

Pressurised tanks, fittings and piping shall not be installed in the accommodation.

(d)

The temperature of cabinets and storage spaces for pressurised tanks shall not exceed 50 "C.

(e)

Cabinets or storage spaces on deck shall be securely stowed and shall have vents so placed that in the event of a pressurised tank not being gastight, the escaping gas cannot penetrate into the vessel. Direct connections with other spaces are not permitted.

Quantity of extinguishing agent If the quantity of extinguishing agent is intended for more than one space, the quantity of extinguishing agent available does not need to be greater than the quantity required for the largest of the spaces thus protected. Installation, maintenance, monitoring and documents The mounting or modification of the system shall only be performed by a company specialised in fire-extinguishing systems. The instructions (product data sheet, safety data sheet) provided by the manufacturer of the extinguishing agent or the system shall be followed. The system shall be inspected by an expert: (i)

before being brought into service;

(ii)

each time it is put back into service after activation;

(iii)

after every modification or repair;

(iv)

regularly, not less than every two years.

During the inspection, the expert is required to check that the system conforms to the requirements of 9.3.3.40.2.

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(d)

The inspection shall include, as a minimum: (i)

an external inspection of the entire system;

(ii)

an inspection to ensure that the piping is leakproof;

(iii)

an inspection to ensure that the control and activation systems are in good working order;

(iv)

an inspection of the pressure and contents of tanks;

(v)

an inspection to ensure that the means of closing the space to be protected are leakproof;

(vi)

an inspection of the fire alarm system;

(vii) an inspection of the alarm device.

9.3.3.40.2.10

(e)

The person performing the inspection shall establish, sign and date a certificate of inspection.

(Q

The number of permanently fixed fire-extinguishing systems shall be mentioned in the inspection certificate.

Fire-extinguishing system operating with COz In addition to the requirements contained in 9.3.3.40.2.1 to 9.3.3.40.2.9, fire-extinguishing systems using CO2 as an extinguishing agent shall conform to the following provisions: Tanks of CO2 shall be placed in a gastight space or cabinet separated from other spaces. The doors of such storage spaces and cabinets shall open outwards; they shall be capable of being locked and shall carry on the outside the symbol "Warning: danger", not less than 5 cm high and "CO2" in the same colours and the same size; Storage cabinets or spaces for C02 tanks located below deck shall only be accessible from the outside. These spaces shall have an artificial ventilation system with extractor hoods and shall be completely independent of the other ventilation systems on board; The level of filling of C02 tanks shall not exceed 0.75 kgll. The volume of depressurised COz shall be taken to be 0.56 m3/kg; The concentration of CO2 in the space to be protected shall be not less than 40% of the gross volume of the space. This quantity shall be released within 120 seconds. It shall be possible to monitor whether diffusion is proceeding correctly; The opening of the tank valves and the control of the diffusing valve shall correspond to two different operations; The appropriate period of time mentioned in 9.3.3.40.2.6 (b) shall be not less than 20 seconds. A reliable installation shall ensure the timing of the diffusion of COz.

9.3.3.40.2.1 1

Fire-extinguishing system operating with HFC-22 7 ea fheptaflzdovopvopane) In addition to the requirements of 9.3.0.40.2.1 to 9.3.0.40.2.9, fire-extinguishing systems using HFC-227 ea as an extinguishing agent shall conform to the following provisions: Where there are several spaces with different gross volumes, each space shall be equipped with its own fire-extinguishing system; Every tank containing HFC-227 ea placed in the space to be protected shall be fitted with a device to prevent overpressure. This device shall ensure that the contents of the tank are safely diffused in the space to be protected if the tank is subjected to fire, when the fire-extinguishing system has not been brought into service; Every tank shall be fitted with a device permitting control of the gas pressure; The level of filling of tanks shall not exceed 1.15 kg/l. The specific volume of depressurised HFC-227 ea shall be taken to be 0.1374 m3/kg; The concentration of HFC-227 ea in the space to be protected shall be not less than 8% of the gross volume of the space. This quantity shall be released within 10 seconds; Tanks of HFC-227 ea shall be fitted with a pressure monitoring device which triggers an audible and visual alarm in the wheelhouse in the event of an unscheduled loss of propellant gas. Where there is no wheelhouse, the alarm shall be triggered outside the space to be protected; After discharge, the concentration in the space to be protected shall not exceed 10.5% (volume); The fire-extinguishing system shall not comprise aluminium parts.

9.3.3.40.2.12

Fire-extinguishing system operating with IG-541 In addition to the requirements of 9.3.3.40.2.1 to 9.3.3.40.2.9, fire-extinguishing systems using IG-541 as an extinguishing agent shall conform to the following provisions: Where there are several spaces with different gross volumes, every space shall be equipped with its own fire-extinguishing system; Every tank containing IG-541 placed in the space to be protected shall be fitted with a device to prevent overpressure. This device shall ensure that the contents of the tank are safely diffused in the space to be protected if the tank is subjected to fire, when the fire-extinguishing system has not been brought into service; Each tank shall be fitted with a device for checking the contents; The filling pressure of the tanks shall not exceed 200 bar at a temperature of +l 5 "C; The concentration of IG-541 in the space to be protected shall be not less than 44% and not more than 50% of the gross volume of the space. This quantity shall be released within 120 seconds.

9.3.3.40.2.13

Fire-extinguishing systemfor physical protection In order to ensure physical protection in the engine rooms, boiler rooms and pump rooms, fire-extinguishing systems are accepted solely on the basis of recommendations by the Administrative Committee. The two hand fire-extinguishers referred to in 8.1.4 shall be located in the cargo area. The fire-extinguishing agent and the quantity contained in the permanently fixed fire-extinguishing system shall be suitable and sufficient for fighting fires. 9.3.3.40 and 9.3.3.40.2 above do not apply to oil separator or supply vessels. Fire and naked light The outlets of funnels shall be located not less than 2.00 m from the cargo area. Arrangements shall be provided to prevent the escape of sparks and the entry of water. Heating, cooking and refrigerating appliances shall not be fuelled with liquid fuels, liquid gas or solid fuels. The installation in the engine room or in another separate space of heating appliances fuelled with liquid fuel having a flashpoint above 55 "C is, however, permitted. Cooking and refrigerating appliances are permitted only in the accommodation. Only electrical lighting appliances are permitted. Cargo heating system Boilers which are used for heating the cargo shall be fuelled with a liquid fuel having a flashpoint of more than 55 "C. They shall be placed either in the engine room or in another separate space below deck and outside the cargo area, which is accessible from the deck or from the engine room. The cargo heating system shall be designed so that the cargo cannot penetrate into the boiler in the case of a leak in the heating coils. A cargo heating system with artificial draught shall be ignited electrically. The ventilation system of the engine room shall be designed taking into account the air required for the boiler. Where the cargo heating system is used during loading, unloading or gas-freeing, the service space which contains this system shall fdly comply with the requirements of 9.3.3.52.3 (b). This requirement does not apply to the inlets of the ventilation system. These inlets shall be located at a minimum distance of 2.00 m from the cargo area and 6.00 m from the openings of cargo tanks or residual cargo tanks, loading pumps situated on deck, openings of high-velocity vent valves, pressure relief devices and shore connections of loading and unloading pipes and must be located not less than 2.00 m above the deck. The requirements of 9.3.3.52.3 (b) are not applicable to the unloading of substances having a flashpoint of 60 "C or more when the temperature of the product is at least 15 K lower at the flashpoint. (Reserved.

Documents concerning electrical installations

In addition to the documents required in accordance with the Regulations referred to in 1.1.4.6, the following documents shall be on board: (a)

a drawing indicating the boundaries of the cargo area and the location of the electrical equipment installed in this area;

(b)

a list of the electrical equipment referred to in (a) above including the following particulars: machine or appliance, location, type of protection, type of protection against explosion, testing body and approval number;

(c)

a list of or general plan indicating the electrical equipment outside the cargo area which may be operated during loading, unloading or gas-freeing. All other electrical equipment shall be marked in red. See 9.3.3.52.3 and 9.3.3.52.4.

The documents listed above shall bear the stamp of the competent authority issuing the certificate of approval. Electrical installations

Only distribution systems without return connection to the hull are permitted. This provision does not apply to:

-

electric corrosion protection against external currents;

-

certain limited sections of the installations situated outside the cargo area (e.g. connections of starters of diesel engines);

-

the device for checking the insulation level referred to in 9.3.3.51.2 below.

Every insulated distribution network shall be fitted with an automatic device with a visual and audible alarm for checking the insulation level. For the selection of electrical equipment to be used in zones presenting an explosion risk, the explosion groups and temperature classes assigned to the substances carried in columns (15) and (16) of Table C of Chapter 3.2 shall be taken into consideration. Type and location of electrical equipment

(a)

Only the following equipment may be installed in cargo tanks, residual cargo tanks, and pipes for loading and unloading (comparable to zone 0): -

(b)

measuring, regulation and alarm devices of the EEx (ia) type of protection.

Only the following equipment may be installed in the cofferdams, double-hull spaces, double bottoms and hold spaces (comparable to zone 1): -

measuring, regulation and alarm devices of the certified safe type;

-

lighting appliances of the "flame-proof enclosure" or "apparatus protected by pressurization" type of protection;

- 434 -

(c)

-

hermetically sealed echo sounding devices the cables of which are led through thick-walled steel tubes with gastight connections up to the main deck;

-

cables for the active cathodic protection of the shell plating in protective steel tubes such as those provided for echo sounding devices.

Only the following equipment may be installed in the service spaces in the cargo area below deck (comparable to zone 1): -

measuring, regulation and alarm devices of the certified safe type;

-

lighting appliances of the "flame-proof enclosure" or "apparatus protected by pressurization" type of protection;

-

motors driving essential equipment such as ballast pumps; they shall be of the certified safe type.

(d)

The control and protective equipment of the electrical equipment referred to in paragraphs (a), (b) and (c) above shall be located outside the cargo area if they are not intrinsically safe.

(e)

The electrical equipment in the cargo area on deck (comparable to zone 1) shall be of the certified safe type.

9.3.3.52.2

Accumulators shall be located outside the cargo area.

9.3.3.52.3

(a)

Electrical equipment used during loading, unloading and gas-freeing during berthing and which are located outside the cargo area shall (comparable to zone 2) be at least of the "limited explosion risk" type.

(b)

This provision does not apply to: (i)

lighting installations in the accommodation, except for switches near entrances to accommodation;

(ii)

radiotelephone installations in the accommodation or the wheelhouse;

(iii)

mobile and fixed telephone installations in the accommodation or the wheelhouse;

(iv)

electrical installations in the accommodation, the wheelhouse or the service spaces outside the cargo areas if: 1.

These spaces are fitted with a ventilation system ensuring an overpressure of 0.1 kPa (0.001 bar) and none of the windows is capable of being opened; the air intakes of the ventilation system shall be located as far away as possible, however, not less than 6.00 m from the cargo area and not less than 2.00 m above the deck;

2.

The spaces are fitted with a gas detection system with sensors: -

at the suction inlets of the ventilation system;

-

directly at the top edge of the sill of the entrance doors of the accommodation and service spaces;

3.

The gas concentration measurement is continuous;

4.

When the gas concentration reaches 20% of the lower explosive limit, the ventilators are switched off. In such a case and when the overpressure is not maintained or in the event of failure of the gas detection system, the electrical installations which do not comply with (a) above, shall be switched off. These operations shall be performed immediately and automatically and activate the emergency lighting in the accommodation, the wheelhouse and the service spaces, which shall comply at least with the "limited explosion risk" type. The switching-off shall be indicated in the accommodation and wheelhouse by visual and audible signals;

5.

The ventilation system, the gas detection system and the alarm of the switch-off device fully comply with the requirements of (a) above;

6.

The automatic switch-off device is set so that no automatic switching-off may occur while the vessel is under way.

The electrical equipment which does not meet the requirements set out in 9.3.3.52.3 above together with its switches shall be marked in red. The disconnection of such equipment shall be operated from a centralised location on board. An electric generator which is permanently driven by an engine and which does not meet the requirements of 9.3.3.52.3 above, shall be fitted with a switch capable of shutting down the excitation of the generator. A notice board with the operating instructions shall be displayed near the switch. Sockets for the connection of signal lights and gangway lighting shall be permanently fitted to the vessel close to the signal mast or the gangway. Connecting and disconnecting shall not be possible except when the sockets are not live. The failure of the power supply for the safety and control equipment shall be immediately indicated by visual and audible signals at the locations where the alarms are usually actuated. Earthing

The metal parts of electrical appliances in the cargo area which are not live as well as protective metal tubes or metal sheaths of cables in normal service shall be earthed, unless they are so arranged that they are automatically earthed by bonding to the metal structure of the vessel. The provisions of 9.3.3.53.1 above apply also to equipment having service voltages of less than 50 V. Independent cargo tanks, metal intermediate bulk containers and tank-containers shall be earthed. Metal intermediate bulk containers (IBCs) and tank-containers, used as residual cargo tanks or slop tanks, shall be capable of being earthed. (Reserved).

Electrical cables All cables in the cargo area shall have a metallic sheath. Cables and sockets in the cargo area shall be protected against mechanical damage. Movable cables are prohibited in the cargo area, except for intrinsically safe electric circuits or for the supply of signal lights, gangway lighting and submerged pumps on board oil separator vessels. Cables of intrinsically safe circuits shall only be used for such circuits and shall be separated from other cables not intended for being used in such circuits (e.g. they shall not be installed together in the same string of cables and they shall not be fixed by the same cable clamps). For movable cables intended for signal lights, gangway lighting, and submerged pumps on board oil separator vessels, only sheathed cables of type H 07 RN-F in accordance with IEC publication-60 245-4 (1994) or cables of at least equivalent design having conductors with a cross-section of not less than 1.5 mm2 shall be used. These cables shall be as short as possible and installed so that damage is not likely to occur. The cables required for the electrical equipment referred to in 9.3.3.52.1 (b) and (c) are accepted in cofferdams, double-hull spaces, double bottoms, hold spaces and service spaces below deck. When the vessel is only authorized to carry substances for which no antiexplosion protection is required in column (17) of Table C in Chapter 3.2, cable penetration is permitted in the hold spaces. (Reserved).

Special equipment A shower and an eye and face bath shall be provided on the vessel at a location which is directly accessible from the cargo area.

This requirement does not apply to oil separator and supply vessels. (Reserved). Admittance on board The notice boards displaying the prohibition of admittance in accordance with 8.3.3 shall be clearly legible from either side of the vessel. (Reserved). Prohibition of smoking,fire or naked light The notice boards displaying the prohibition of smoking in accordance with 8.3.4 shall be clearly legible from either side of the vessel. Notice boards indicating the circumstances under which the prohibition is applicable shall be fitted near the entrances to the spaces where smoking or the use of fire or naked light is not always prohibited.

- 437 -

9.3.3.74.3

Ashtrays shall be provided close to each exit in the accommodation and the wheelhouse.

9.3.3.759.3.3.91

(Reserved).

9.3.3.92

On board of tank vessels referred to in 9.3.3.11.7, spaces the entrances or exits of which are likely to become partly or completely immersed in the damaged condition shall have an emergency exit which is situated not less than 0.10 m above the damage waterline. This requirement does not apply to forepeak and afterpeak.

9.3.3.939.3.3.99

(Reserved).

ECElTRANSl190 (Vol. 11)

ECONOMIC COMMISSION FOR EUROPE Committee on Inland Transport

European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways (ADN) Annexed Regulations, as revised as of 1 January 2007 (cont 'd)

UNITED NATIONS New York and Geneva, 2006

NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries.

I ECElTRANSl190 (Vol. 11)

(

Copyright O United Nations, 2006 All right reserved No part ofthzs publication may be, for sales purposes, be reproduced stored in a retrieval system or transmitted in anyform or by any weans, electronic, electrostatic, magnetic tape, mechanical, photocopying or ofhenrise, wi/hout prior permission m ivritingform from the United Nations

PUBLICATION DES NATIONS UNIES Sales No.: E.06.VIII.2

ISBN 92-1-1391 18-0 (Complete set of 2 volumes) ISBN 92-1 -1 391 17-2 (Vol. 11) Volumes I end I1 not to be sold separately.

TABLE OF CONTENTS VOLUME I1

Page PART l

GENERAL PROVISIONS............................................................................(See Volume I)

PART 2

CLASSIFICATION.......................................................................................................

1

Chapter 2.1 2.1.1 2.1.2 2.1.3

General provisions Introduction..................................................................................... 3 Principles of classification ............................................................. 4 Classification of substances. including solutions and mixtures 5 (such as preparations and wastes). not mentioned by name ............ Classification of samples ................................................................ 11

Chapter 2.2 2.2.1 2.2.2 2.2.3 2.2.41

Class specific provisions Class 1 Explosive substances and articles...................................... Class 2 Gases ................................................................................. Class 3 Flammable liquids ............................................................. Class 4.1 Flammable solids. self-reactive substance and solid desensitised explosives ................................................................... Class 4.2 Substances liable to spontaneous combustion ................ Class 4.3 Substances which. in contact with water. emit flammable gases ............................................................. Class 5.1 Oxidizing substances ...................................................... Class 5.2 Organic peroxides .......................................................... Class 6.1 Toxic substances ............................................................ Class 6.2 Infectious substances ...................................................... Class 7 Radioactive material .......................................................... Class 8 Corrosive substances ......................................................... Class 9 Miscellaneous dangerous substances and articles .............

Chapter 2.3 2.3.0 2.3.1 2.3.2 2.3.3 2.3.4 2.3.5

Test methods General............................................................................................ 163 Exudation test for blasting explosives of Type A ........................... 163 Tests relating to nitrated cellulose mixtures of Class 4.1 ................ 165 Tests relating to flammable liquids of Classes 3. 6.1 and 8 ............ 166 Test for determining fluidity ........................................................... 169 Test for determining the ecotoxicity, persistence and bioaccumulation of substances in the aquatic environment for assignment to Class 9 ...................................................................... 171 Classification of organometallic substances in Classes 4.2 and4.3 ............................................................................................. 175

PART 3

DANGEROUS GOODS LIST. SPECIAL PROVISIONS AND EXEMPTIONS RELATED TO DANGEROUS GOODS PACKED IN LIMITED QUANTITIES ........................................................................................ 177 Chapter 3.1 3.1.1

General Introduction..................................................................................... 179

Table of contents (cont'd) 3.1.2

Proper shipping name ..................................................................... 179

Chapter 3.2 3.2.1

List of dangerous goods List of dangerous goods in numerical Table A: order .......................................................................... 183 List of dangerous goods in alphabetical Table B: order ........................................................................... 403 List of dangerous goods accepted for Table C: carriage in tank vessels in numerical order ...........................................................(See Volume I)

3.2.2 3.2.3

Chapter 3.3

Special provisions applicable to certain articles or substances ...................................................................................... 489

Chapter 3.4

Exemptions related to dangerous goods packed in limited quantities ........................................................................................ 5 17

PART 4

PROVISIONS CONCERNING THE USE OF PACKAGINGS, TANKS AND BULK TRANSPORT UNITS ........................................(See Volume I)

PART 5

CONSIGNMENT PROCEDURES ..............................................................

PART 6

REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF PACKAGINGS (INCLUDING IBCS AND LARGE PACKAGINGS), TANKS AND BULK TRANSPORT UNITS ........................................(See Volume I)

PART 7

REQUIREMENTS CONCERNING LOADING, CARRIAGE, UNLOADING AND HANDLING OF CARGO...................................(See Volume I)

PART 8

PROVISIONS FOR VESSEL CREWS, EQUIPMENT, OPERATION AND DOCUMENTATION .................................................(See Volume I)

PART 9

RULES FOR CONSTRUCTION ................................................................(See Volume I)

(See Volume I)

PART 2 Classification

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CHAPTER 2.1 GENERAL PROVISIONS

Introduction The classes of dangerous goods according to ADN are the following: Class 1 Class 2 Class 3 Class 4.1 Class 4.2 Class 4.3 Class 5.1 Class 5.2 Class 6.1 Class 6.2 Class 7 Class 8 Class 9

Explosive substances and articles Gases Flammable liquids Flammable solids, self-reactive substances and solid desensitized explosives Substances liable to spontaneous combustion Substances which, in contact with water, emit flammable gases Oxidizing substances Organic peroxides Toxic substances Infectious substances Radioactive material Corrosive substances Miscellaneous dangerous substances and articles

Each entry in the different classes has been assigned a UN number. The following types of entries are used: A.

Single entries for well defined substances or articles including entries for substances covering several isomers, e.g.: UN No. 1090 UN No. 1 104 UN No. 1194

B.

Generic entries for a well defmed group of substances or articles, which are not n.0.s. entries, e.g.:

UN No. 1133 UN No. 1266 UN No. 2757 UN No. 3 101 C.

ADHESIVES PERFUMERY PRODUCTS CARBAMATE PESTICIDE, SOLID, TOXIC ORGANIC PEROXIDE TYPE B, LIQUID

Specific n.0.s. entries covering a group of substances or articles of a particular chemical or technical nature, not otherwise specified, e.g.: UN No. 1477 UN No. 1987

D.

ACETONE AMYL ACETATES ETHYL NITRITE SOLUTION

NITRATES, INORGANIC, N.O.S. ALCOHOLS, N.O.S.

General n.0.s. entries covering a group of substances or articles having one or more dangerous properties, not otherwise specified, e.g.: UN No. 1325 UN No. 1993

FLAMMABLE SOLID, ORGANIC, N.O.S. FLAMMABLE LIQUID, N.O.S.

The entries defmed under B., C. and D. are defmed as collective entries.

For packing purposes, substances other than those of Classes 1, 2, 5.2, 6.2 and 7, and other than self-reactive substances of Class 4.1 are assigned to packing groups in accordance with the degree of danger they present: Packing group I: Substances presenting high danger; Packing group 11: Substances presenting medium danger; Packing group 111: Substances presenting low danger. The packing group(s) to which a substance is assigned is (are) indicated in Table A of Chapter 3.2. For the purpose of carriage in tank vessels, some substances may be further subdivided. Principles of classification

The dangerous goods covered by the heading of a class are defined on the basis of their properties according to sub-section 2.2.x.1 of the relevant class. Assignment of dangerous goods to a class and a packing group is made according to the criteria mentioned in the same sub-section 2.2.x.1. Assignment of one or several subsidiary risk(s) to a dangerous substance or article is made according to the criteria of the class or classes corresponding to those risks, as mentioned in the appropriate sub-section(s) 2.2.x. 1. All dangerous goods entries are listed in Table A of Chapter 3.2 in the numerical order of their UN Number. This table contains relevant information on the goods listed, such as name, class, packing group(s), label(s) to be affixed, packing and carriage provisionsa. NOTE: An alphabetical list ofthese entries can be found in Chapter 3.2, Table B.

Dangerous goods which are listed or defined in sub-section 2.2.x.2 of each class are not to be accepted for carriage. Goods not mentioned by name, i.e. goods not listed as single entries in Table A of Chapter 3.2 and not listed or defined in one of the above-mentioned sub-sections 2.2.x.2 shall be assigned to the relevant class in accordance with the procedure of section 2.1.3. In addition, the subsidiary risk (if any) and the packing group (if any) shall be determined. Once the class, subsidiary risk (if any) and packing group (if any) have been established the relevant UN number shall be determined. The decision trees in sub-sections 2.2.x.3 (list of collective entries) at the end of each class indicate the relevant parameters for selecting the relevant collective entry (UN number). In all cases the most specific collective entry covering the properties of the substance or article shall be selected, according to the hierarchy indicated in 2.1.1.2 by the letters B, C and D respectively. If the substance or article cannot be classified under entries of type B or C according to 2.1.1.2, then, and only then shall it be classified under an entry of type D. On the basis of the test procedures of Chapter 2.3 and the criteria set out in subsections 2.2.x.1 of classes when it is so specified, it may be determined that a substance, solution or mixture of a certain class, mentioned by name in Table A of Chapter 3.2, does not meet the criteria of that class. In such a case, the substance, solution or mixture is deemed not to belong to that class. For the purposes of classification, substances with a melting point or initial melting point of 20 "C or lower at a pressure of 101.3 kPa shall be considered to be liquids. A viscous substance for which a specific melting point cannot be determined shall be subjected to the a

Note by the Secretariat: An alphabetic list of these entries has been prepared by the secretariat and is reproduced in Table B of Chapter 3.2. This table is not an ofJicia1part of the ADN. -4-

ASTM D 4359-90 test or to the test for determining fluidity (penetrometer test) prescribed in 2.3.4. Classification of substances, including solutions and mixtures (such as preparations and wastes), not mentioned by name Substances including solutions and mixtures not mentioned by name shall be classified according to their degree of danger on the basis of the criteria mentioned in subsection 2.2.x.1 of the various classes. The danger(s) presented by a substance shall be determined on the basis of its physical and chemical characteristics and physiological properties. Such characteristics and properties shall also be taken into account when such experience leads to a more stringent assignment. A substance not mentioned by name in Table A of Chapter 3.2 presenting a single hazard shall be classified in the relevant class under a collective entry listed in sub-section 2.2.x.3 of that class. A solution or mixture containing only one dangerous substance mentioned by name in Table A of Chapter 3.2, together with one or more non-dangerous substance(s), shall be regarded as the dangerous substance listed by name, unless: (a)

the solution or mixture is specifically mentioned by name in Table A of Chapter 3.2; or

(b)

it is quite clear from the entry for the dangerous substance that it is applicable only to the pure or technically pure substance; or

(c)

the class, physical state or packing group of the solution or mixture is different from that of the dangerous substance.

In the cases referred to under (b) or (c) above, the solution or mixture shall be classified as a substance not mentioned by name in the relevant class under a collective entry listed in subsection 2.2.x.3 of that class taking account of the subsidiary risks presented by that solution or mixture, if any, unless the solution or mixture do not meet the criteria of any class, in which case they are not subject to ADN. 2.1.3.4

Solutions and mixtures containing a substance belonging to one of the entries mentioned in 2.1.3.4.1 or 2.1.3.4.2 shall be classified in accordance with the provisions of these paragraphs.

2.1.3.4.1

Solutions and mixtures containing one of the following substances mentioned by name shall always be classified under the same entry as the substance they contain, provided they do not have the hazard characteristics as indicated in 2.1.3.5.3: -

Class 3 UN No. 1921 PROPYLENEIMINE, STABILIZED; UN No. 2481 ETHYL ISOCYANATE; UN No. 3064 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin;

-

Class 6.1

UN No. 105l HYDROGEN CYANIDE, STABILIZED, containing less than 3% water; UN No. l 185 ETHYLENEIMINE, STABILIZED; UN No. 1259 NICKEL CARBONYL:

UN No. 1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION);

UN No. 1614 HYDROGEN CYANIDE, STABILIZED, containing not more than 3% water and absorbed in a porous inert material; UN No. 1994 IRON PENTACARBONYL; UN No. 2480 METHYL ISOCYANATE:

UN No. 3294 HYDROGEN CYANIDE, SOLUTION M ALCOHOL, with not more than 45% hydrogen cyanide;

Class 8 UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS; UN No. 1744 BROMlNE or UN No. 1744 BROMINE SOLUTION;

UN No. 1790 HYDROFLUORIC ACID with more than 85% hydrogen fluoride; UN No. 2576 PHOSPHORUS OXYBROMIDE, MOLTEN.

2.1.3.4.2

Solutions and mixtures containing a substance belonging to one of the following entries of Class 9: UN No. 23 15 POLYCHLORINATED BIPHENYLS, LIQUID; UN No. 3 151 POLYHALOGENATED BIPHENYLS, LIQUID;

UN No. 3 151 POLYHALOGENATED TERPHENYLS, LIQUID; UN No. 3 152 POLYHALOGENATED BIPHENYLS, SOLID; UN No. 3 152 POLYHALOGENATED TERPHENYLS, SOLID; or

UN No. 3432 POLYCHLORINATED BIPHENYLS, SOLID

shall always be classified under the same entry of Class 9 provided that:

2.1.3.5

-

they do not contain any additional dangerous component other than components of packing group I11 of classes 3, 4.1, 4.2,4.3, 5.1, 6.1 or 8; and

-

they do not have the hazard characteristics as indicated in 2.1.3.5.3.

Substances not mentioned by name in Table A of Chapter 3.2, having more than one hazard characteristic and solutions or mixtures containing several dangerous substances shall be classified under a collective entry (see 2.1.2.4) and packing group of the appropriate class in -6-

accordance with their hazard characteristics. Such classification according to the hazard characteristics shall be carried out as follows: 2.1.3.5.1

The physical and chemical characteristics and physiological properties shall be determined by measurement or calculation and the substance, solution or mixture shall be classified according to the criteria mentioned in sub-section 2.2.x. 1 of the various classes.

2.1.3.5.2

If this determination is not possible without disproportionate cost or effort (as for some kinds of wastes), the substance, solution or mixture shall be classified in the class of the component presenting the major hazard.

2.1.3.5.3

If the hazard characteristics of the substance, solution or mixture fall within more than one class or group of substances listed below then the substance, solution or mixture shall be classified in the class or group of substances corresponding to the major hazard on the basis of the following order of precedence: Material of Class 7 (apart from radioactive material in excepted packages where the other hazardous properties take precedence); Substances of Class 1; Substances of Class 2; Liquid desensitized explosives of Class 3; Self-reactive substances and solid desensitized explosives of Class 4.1; Pyrophoric substances of Class 4.2; Substances of Class 5.2; Substances of Class 6.1 or Class 3 which, on the basis of their inhalation toxicity, are to be classified under Packing group I (Substances meeting the classification criteria of Class 8 and having an inhalation toxicity of dust and mist (LCSo)in the range of Packing group I and a toxicity through oral ingestion or dermal contact only in the range of Packing group I11 or less, shall be allocated to Class 8); Infectious substances of Class 6.2.

2.1.3.5.4

If the hazard characteristics of the substance fall within more than one class or group of substances not listed in 2.1.3.5.3 above, the substance shall be classified in accordance with the same procedure but the relevant class shall be selected according to the precedence of hazards table in 2.1.3.10. The most specific applicable collective entry (see 2.1.2.4) shall always be used, i.e. a general n.0.s. entry shall only be used if a generic entry or a specific n.0.s. entry cannot be used. Solutions and mixtures of oxidizing substances or substances with an oxidizing subsidiary risk may have explosive properties. In such a case they are not to be accepted for carriage unless they meet the requirements for Class 1. For the purposes of ADN, substances, solutions and mixtures (such as preparations and wastes) which cannot be assigned to Classes 1 to 8 or Class 9 entries other than UN Nos 3077 and 3082, but which may be assigned to UN Nos. 3077 or 3082 on the basis of the test methods and criteria of section 2.3.5 shall be considered to be pollutant to the aquatic environment.

Wastes which do not meet the criteria for classification in classes 1 to 9 but are covered by the Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal may be carried under UN Nos. 3077 or 3082.

1.3,III 5.1, I

S.1,II

1.31

SOL LIQ S.l,I 3,I

SOL LIQ SOL LIQ 3,1 5.1,I 3 , I 5.1,I 3,I

3, I

3, I

1.3,I1

SOL LIQ 5.1.1 3,1

SOL LIQ SOL LIQ 3, I 5.1.11 3.11 5.1.11 3,11

3, I

3, I1

I

5.1.111

I

6.1.1 DERMAL

I

1.3.111 SOL LIQ SOL LIQ SOL LIQ 6.1, I 5.1,I 3,1 l 5.1.11 3,II 1S.l,III3,III 1 l 1.3, I1 15.1, I 14.1, I1 14.1,I1 16.1, I

6.1.1 6.1.11 ORAL

I

I

6.1,I 1

16.1,1

6.1,II l

SOL

LIQ

SOL LIQ 6.1,II 6 , l , I 8.1

6.1,II

6.1, I1

SOL LIQ SOL LIQ 6.1, I1 6 1 , I 8 , I 6.1.118.11

6.1, I1

I

I

Solid substances and mixtures Liquid substances, mixtures and solutions = Dermal toxicity = Oral toxicity ORAL Inhalation toxicity INHAL = *l Clms 6.l for pesticides = =

I

8, I

l

8.1

SOL LIQ 6.1, I1 6.1, I1 8, I1

6.1, I1

8. 1

8. I1

6.1.111

8,111

NOTE 1: Examples to explain the use of the table Classification of a single substance Description of the substance to be classzjied: An amine not mentioned by name meeting the criteria for Class 3, packing group II as well as those for Class 8, packing group I. Procedure: The intersection of line 3 I1 with column 8 I gives 8 I. This amine has therefore to be classified in Class 8 under: UN No. 2734 AMINES LIQUID, CORROSIVE, FLAMMBLE, N.O.S. or UN No. 2734 POL YAMINES, LIQUID, CORROSIVE, FLAMMj2 BL E, N. 0.8. packing group I

Description of the mixture to be classiJied: Mixture consisting of a flammable liquid classzjied in Class 3, packing group III, a toxic substance in Class 6.1, packing group II and a corrosive substance in Class 8, packing group I. Procedure The intersection of line 3 III with column 6.1 II gives 6.1 II. The intersection of line 6.1 II with column 8 Igives 8 I LIQ. This mixture not further defined has therefore to be classz3ed in Class 8 under: UN No. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. packing group I.

NOTE 2: Examples for the classification of mrjctures and solutions under a class and a packing group: A phenol solution of Class 6.1, (II), in benzene of Class 3, (11) is to be classzjied in Class 3, (11); this solution is to be classzjied under UN No. 199.2 FLAMMABLE LIQUID, TOXIC, N.O.S., Class 3, (II), by virtue of the toxicity of the phenol. A solid mixture of sodium arsenate of Class 6.1, (11) and sodium hydroxide of Class 8, (11') is to be classzjied under UN No. 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S., in Clms 6. I (14. A solution of crude or refined naphthalene of Class 4.1, (I14 in petrol of Class 3, (II), is to be classifed under UN No. 3295 HYDROCARBONS, LIQUID, N.O.S. in Class 3, (11). A mixture of hydrocarbons of Class 3, (Ill), and of polychlorinated biphenyls (PCB) of Class 9, (14, is to be classzj?ed under UN No. 2315 POLYCHLORINATED BIPHENYLS, LIQUID or UN No. 3432 POLYCHLORINATED BIPHENYLS, SOLID in Class 9, (11). A mixture of propyleneimine of Class 3, and polychlorinated biphenyls (PCB) of Class 9, (I.., is to be classz3ed under UN No. I921 PROPYLENEIMINE, INHIBITED in Class 3.

Classification of samples When the class of a substance is uncertain and it is being carried for further testing, a tentative class, proper shipping name and UN number shall be assigned on the basis of the consignor's knowledge of the substance and application of: (a)

the classification criteria of Chapter 2.2; and

(b)

the requirements of this Chapter.

The most severe packing group possible for the proper shipping name chosen shall be used. Where this provision is used the proper shipping name shall be supplemented with the word "SAMPLE" (e.g., "FLAMMABLE LIQUID, N.O.S., SAMPLE"). In certain instances, where a specific proper shipping name is provided for a sample of a substance considered to meet certain classification criteria (e.g., GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, UN No. 3167) that proper shipping name shall be used. When an N.O.S. entry is used to carry the sample, the proper shipping name need not be supplemented with the technical name as required by special provision 274 of Chapter 3.3. Samples of the substance shall be carried in accordance with the requirements applicable to the tentative assigned proper shipping name provided: (a)

the substance is not considered to be a substance not accepted for carriage by sub-sections 2.2.x.2 of Chapter 2.2 or by Chapter 3.2;

(b)

the substance is not considered to meet the criteria for Class 1 or considered to be an infectious substance or a radioactive material;

(c)

the substance is in compliance with 2.2.41.1.15 or 2.2.52.1.9 if it is a self-reactive substance or an organic peroxide, respectively;

(d)

the sample is carried in a combination packaging with a net mass per package not exceeding 2.5 kg; and

(e)

the sample is not packed together with other goods.

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CHAPTER 2.2 CLASS SPECIFIC PROVISIONS 2.2.1

Class 1

Explosive substances and articles

2.2.1.1

Criteria

2.2.1.1.1

The heading of Class 1 covers: Explosive substances: solid or liquid substances (or mixtures of substances) capable by chemical reaction of producing gases at such a temperature and pressure and at such a speed as to cause damage to the surroundings. Pyrotechnic substances: substances or mixtures of substances designed to produce an effect by heat, light, sound, gas or smoke or a combination of these as the result of non-detonating self-sustaining exothermic chemical reactions. NOTE l : Substances which are not themselves explosive but which may form an explosive mixture of gas, vapour or dust are not substances of Class I . NOTE 2: Also excludedj-om Class I are: water- or alcohol-wetted explosives of which the water or alcohol content exceeds the limits specified and those containing plasticizers - these explosives are assigned to Class 3 or Class 4.1 - and those explosives which, on the basis of their predominant hazard, are assigned to Class 5.2. Explosive articles: articles containing one or more explosive or pyrotechnic substances. NOTE: Devices containing explosive or pyrotechnic substances in such small quantity or of such a character that their inadvertent or accidental ignition or initiation during carriage would not cause any manifestation external to the device by projection, fire, smoke, heat or loud noise are not subject to the requirements of Class I . Substances and articles not mentioned above which are manufactured with a view to producing a practical effect by explosion or a pyrotechnic effect. substance or article having or suspected of having explosive properties shall be considered for assignment to Class 1 in accordance with the tests, procedures and criteria prescribed in Part I, Manual of Tests and Criteria. A substance or article assigned to Class 1 can only be accepted for carriage when it has been assigned to a name or n.0.s. entry listed in Table A of Chapter 3.2 and meets the criteria of the Manual of Tests and Criteria.

2.2.1.1.3

The s~lbstancesand articles of Class 1 shall be assigned to a UN Number and a name or n.0.s. entry listed in Table A of Chapter 3.2. Interpretation of the names of substances and articles in Table A of Chapter 3.2 shall be based upon the glossary in 2.2.1 .l.& Samples of new or existing explosive substances or articles carried for purposes including: testing, classification, research and development quality control, or as a commercial sample, other than initiating explosive, may be assigned to UN No. 0190 SAMPLES, EXPLOSIVE. The assignment of explosive substances and articles not mentioned by name as such in TableA of Chapter 3.2 to an n.0.s entry of Class 1 or UN No. 0190 SAMPLES, EXPLOSIVE as well as the assignment of certain substances the carriage of which is subject

to a specific authorization by the competent authority according to the special provisions referred to in Column (6) of Table A of Chapter 3.2 shall be made by the competent authority of the country of origin. This competent authority shall also approve in writing the conditions of carriage of these substances and articles. If the country of origin is not a Contracting Party to ADN, the classification and the conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADN reached by the consignment. 2.2.1.1.4

Substances and articles of Class 1 shall have been assigned to a division in accordance with 2.2.1.1.5 and to a compatibility group in accordance with 2.2.1.1.6. The division shall be based on the results of the tests described in section 2.3.1 applying the definitions in 2.2.1.1.5. The compatibility group shall be determined in accordance with the definitions in 2.2.1.1.6. The classification code shall consist of the division number and the compatibility group letter.

2.2.1.1.5

Definition of divisions Division 1.1

Substances and articles which have a mass explosion hazard (a mass explosion is an explosion which affects almost the entire load virtually instantaneously).

Division 1.2

Substances and articles which have a projection hazard but not a mass explosion hazard.

Division 1.3

Substances and articles which have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but not a mass explosion hazard: (a)

combustion of which gives rise to considerable radiant heat; or

(b)

which burn one after another, producing minor blast or projection effects or both.

Division 1.4

Substances and articles which present only a slight risk of explosion in the event of ignition or initiation during carriage. The effects are largely confined to the package and no projection of fragments of appreciable size or range is to be expected. An external fire shall not cause virtually instantaneous explosion of almost the entire contents of the package.

Division 1.5

Very insensitive substances having a mass explosion hazard which are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of carriage. As a minimum requirement they must not explode in the external fire test.

Division 1.6

Extremely insensitive articles which do not have a mass explosion hazard. The articles contain only extremely insensitive detonating substances and demonstrate a negligible probability of accidental initiation or propagation.

NOTE: The riskfiom articles of Division 1.6 is limited to the explosion of a single article.

2.2.1.1.6

Definition of compatibility groups of substances and articles

Primary explosive substance. Article containing a primary explosive substance and not having two or more effective protective features. Some articles, such as detonators for blasting, detonator assemblies for blasting and primers, cap-type, are included, even though they do not contain primary explosives. Propellant explosive substance or other deflagrating explosive substance or article containing such explosive substance. Secondary detonating explosive substance or black powder or article containing a secondary detonating explosive substance, in each case without means of initiation and without a propelling charge, or article containing a primary explosive substance and having two or more effective protective features. Article containing a secondary detonating explosive substance, without means of initiation, with a propelling charge (other than one containing a flammable liquid or gel or hypergolic liquids). Article containing a secondary detonating explosive substance with its own means of initiation, with a propelling charge (other than one containing a flammable liquid or gel or hypergolic liquids) or without a propelling charge. Pyrotechnic substance, or article containing a pyrotechnic substance, or article containing both an explosive substance and an illuminating, incendiary, tear- or smoke-producing substance (other than a water-activated article or one which contains white phosphorus, phosphides, a pyrophoric substance, a flammable liquid or gel or hypergolic liquids). Article containing both an explosive substance and white phosphorus. Article containing both an explosive substance and a flammable liquid or gel. Article containing both an explosive substance and a toxic chemical agent. Explosive substance or article containing an explosive substance and presenting a special risk (e.g. due to water activation or the presence of hypergolic liquids, phosphides or a pyrophoric substance) necessitating isolation of each type. Articles containing only extremely insensitive detonating substances. Substance or article so packed or designed that any hazardous effects arising from accidental functioning are confined within the package unless the package has been degraded by fire, in which case all blast or projection effects are limited to the extent that they do not significantly hinder or prevent fire-fighting or other emergency response efforts in the immediate vicinity of the package. NOTE 1: Each substance or article, packed in a speciJied packaging, may be assigned to one compatibility group only. Since the criterion of compatibility group S is empirical, assignment to this group is necessarily linked to the tests for assignment of a classiJication code. NOTE 2: Articles of compatibility groups D and E may be fitted or packed together with their own means of initiation provided that such means have at least two effective protective

features designed to prevent an explosion in the event of accidentalfunctioning of the means of initiation. Such packages shall be assigned to compatibility groups D or E. NOTE 3: Articles of compatibility groups D and E may be packed together with their own means of initiation, which do not have two effective protective features (i.e. means of initiation assigned to compatibility group B), provided that they comply with mixed packing provision MP 21 of Section 4.1.10 of ADR.. Such packages shall be assigned to compatibility groups D or E. NOTE 4: Articles may be fitted or packed together with their own means of ignition provided that the means of ignition cannotfunction during normal conditions of carriage. NOTE 5: Articles of compatibility groups C, D and E may be packed together. Such packages shall be assigned to compatibility group E. 2.2.1.1.7

Assignment offireworks to divisions

2.2.1.1.7.1

Fireworks shall normally be assigned to divisions 1.1, 1.2, 1.3, and 1.4 on the basis of test data derived from Test Series 6 of the Manual of Tests and Criteria. However, since the range of such articles is very extensive and the availability of test facilities may be limited, assignment to divisions may also be made in accordance with the procedure in 2.2.1.1.7.2.

2.2.1.1.7.2

Assignment of fireworks to UN No. 0333, 0334, 0335 or 0336 may be made on the basis of analogy, without the need for Test Series 6 testing, in accordance with the default fireworks classification table in 2.2.1.1.7.5. Such assignment shall be made with the agreement of the competent authority. Items not specified in the table shall be classified on the basis of test data derived from Test Series 6. NOTE l : The addition of other types offireworks to column l of the table in 2.2.1.1.7.5 shall only be made on the basis of full test data submitted to the UN Sub-Committee of Experts on the Transport of Dangerous Goodsfor consideration. NOTE 2: Test data derived by competent authorities which validates, or contradicts the assignment of fireworks specijied in column 4 of the table in 2.2.1.1.7.5 to divisions in column 5 should be submitted to the UN Sub-Committee of Experts on the Transport of Dangerous Goodsfor information.

2.2.1. l .7.3

Where fireworks of more than one division are packed in the same package they shall be classified on the basis of the highest division unless test data derived from Test Series 6 indicate otherwise.

2.2.1.1.7.4

The classification shown in the table in 2.2.1.1.7.5 applies only for articles packed in fibreboard boxes (4G).

2.2.1.1.7.5

Defaultfireworks classijkation table

'

NOTE l : References to percentages in the table, unless otherwise stated, are to the mass of all pyrotechnic composition (e.g. rocket motors, lifting charge, bursting charge and effect charge). NOTE 2: "Flash composition" in this table refers to pyrotechnic compositions containing an oxidizing substance, or black powder, and a metal powder fuel that are used to produce an aural report effect or used as a bursting charge infireworks devices.

1

This table contains a list offirework classzjkations which may be used in the absence of Test Series 6 data (see 2.2.1.1.7.2). - 16-

NOTE 3:

Dimensions in mm refer to:

- for spherical andpeanut shells the diameter of the sphere of the shell; - for cylinder shells the length of the shell; - for a shell in mortar, Roman candle, shot tube firework or mine the inside diameter of the tube comprising or containing the jrework; - for a bag niine or cylinder mine, the inside diameter of the mortar intended to contain the mine.

Type

Includes: / Synonym:

Definition

Specification

Shell. spherical or cylindrical

Spherical display shell: aerial shell, colour shell, dye shell, multi-break shell, multi-effect shell, nautical shell, parachute shell, smoke shell. star shell; report shell: maroon, salute, sound shell, thunderclap, aerial shell kit

Device with or without propellant charge, with delay h s e and bursting charge. pyrotechnic unit(s) or loose pyrotechnic composition and designed to be projected fkom a mortar

All report shells

Classification

Colour shell: 2 180 mm Colour shell: < 180 mm with > 25% flash composition, as loose powder andor report effects Colour shell: < l80 mm with 125% flash composition, as loose powder andor report effects Colour shell: 1 50 mm, or I 60 g pyrotechnic composition, with 1 2% flash composition as loose powder andor report effects

Peanut shell

Device with two or more spherical aerial shells in a common wrapper propelled by the same propellant charge with separate external delay hses

The most hazardous spherical aerial shell determines the classification

Preloaded mortar, shell in mortar

Assembly comprising a spherical or cylindrical shell inside a mortar from which the shell is designed to be projected

All report shells

1.1G

Colour shell: 2 180 mm

1.1G

Colour shell: > 50 mm and < 180 mm

1.2G

Colour shell: I 50 mm, or I 60 g pyrotechnic composition, with 125% flash composition as loose powder andor report effects

1.3G

Definition

Type Shell, spherical or cylindrical

(cont U)

Shell of shells (spherical)

(Reference to percentages for shell of shells are to the gross mass of the $reworks article)

Specification

Classification

Device without propellant charge, with delay fuse and bursting charge, containing report shells and inert materials and designed to be projected from a mortar Device without propellant charge, with delay fuse and bursting charge, containing report shells 1 2 5 g flash composition per report unit, with 133% flash composition and 2 60% inert materials and designed to be projected from a mortar Device without propellant charge, with delay fuse and bursting charge, containing colour shells andor pyrotechnic units and designed to be proiected from a mortar Device without propellant charge, with delay fuse and bursting charge, containing colour shells 5 70mm andor pyrotechnic units, with 5 25% flash composition and 5 60% pyrotechnic composition and designed to be projected from a mortar

> 200 mm and 5 300 mm

Device with propellant charge, with delay fuse and bursting charge, containing colour shells 5 70 mm andor pyrotechnic units, with 5 25% flash composition and 5 60% pyrotechnic composition and designed to be projected from a mortar Battery1 combination

Barrage, bombardos, cakes, finale box, flowerbed, hybrid, multiple tubes, shell cakes, banger batteries, flash banger batteries

Assembly including several elements either containing the same type or several types each corresponding to one of the types of fireworks listed in this table, with one or two points of ignition

The most hazardous firework type determines the classification

Type

Includes: / Synonym:

Definition

Roman candle

Exhibition candle, candle, bombettes

Tube containing a series of pyrotechnic units consisting of alternate pyrotechnic composition, propellant charge, and transmitting fuse

Specificstion 1 50 mm inner diameter, containing flash composition, or < 50 mm with > 25% flash composition

2 50 mm inner diameter, containing no flash composition

< 50 mm inner diameter and 5 25% flash com~osition 1 30 mm inner diameter, each pyrotechnic unit I 25 g and I 5% flash composition -

Shot tube

Single shot Roman candle, small preloaded mortar

Tube containing a pyrotechnic unit consisting of pyrotechnic composition, propellant charge with or without transmitting fuse

1 30 mm inner diameter and pyrotechnic unit > 25 g, or > 5% and 5 25% flash composition 1 30 mm inner diameter, pyrotechnic unit 5 25 g and I 5% flash composition

Rocket

Avalanche rocket, signal rocket, whistling rocket, bottle rocket, sky rocket, missile type rocket, table rocket

Tube containing pyrotechnic composition andor pyrotechnic units, equipped with stick(s) or other means for stabilization of flight, and designed to be propelled into the air

Flash composition effects only Flash composition > 25% of the pyrotechnic composition > 20 g pyrotechnic composition and flash composition 5 25% 1 20 g pyrotechnic composition,

black powder bursting charge and 1 0.13 g flash composition per report and 5 1 g in total

Classification

FYP~ Mine

Fountain

Sparkler

Bengal stick

Includes: 1 Synonym:

Definition

Specification

I Classification

Pot-a-feu, ground mine, bag mine, cylinder mine

Tube containing propellant charge and pyrotechnic units and designed to be placed on the ground or to be fixed in the ground. The principal effect is ejection of all the pyrotechnic units in a single burst producing a widely dispersed visual andor aural effect in the air or:

> 25% flash composition, as loose powder and/ or report effects

I

l.1G

Cloth or paper bag or cloth or paper cylinder containing propellant charge and pyrotechnic units, designed to be placed in a mortar and to function as a mine

< 180 mm and I: 25% flash composition, as loose powder and/ or report effects

1

1.36

Non-metallic case containing pressed or Volcanos, gerbs, showers, lances, Bengal fire, flitter sparkle, cylindrical consolidated pyrotechnic composition producing sparks and flame fountains, cone fountains, illuminating torch Handheld sparklers, non-handheld sparklers, wire sparklers

Dipped stick

Rigid wire partially coated (along one end) with slow burning pyrotechnic composition with or without an ignition tip

Non-metallic stick partially coated (along one end) with slow-burning pyrotechnic composition and designed to be held in the hand

2 180 mm and 5 25% flash

composition, as loose powder and/ or report effects

I 150 g pyrotechnic composition, containing I5% flash composition as loose powder and/ or report effects. Each pyrotechnic unit 5 25 g, each report effect < 2g; each whistle, if any, 5 3 g

2 1 kg pyrotrchnic cornpusition

< 1 kg pyrotechnic composition Perchlorate based sparklers: > 5 g per item or > 10 items per pack 5g Perchlorate based sparklers: I per item and 5 10 items per pack; Nitrate based sparklers: 1 30 g per item Perchlorate based items: > 5 g per item or > 10 items per pack Perchlorate based items: I 5 g per item and 1 10 items per pack; nitrate based items: 5 30 g per item

1.4G

Type Low hazard fireworks and novelties

Includes: 1 Synonym: Table bombs, throwdowns, crackling granules, smokes, fog, snakes, glow worm, serpents, snaps, party poppers

Definition Device designed to produce very limited visible a n d or audible effect which contains small amounts of pyrotechnic andor explosive composition.

Spinner

Aerial spinner, helicopter, chaser, ground spinner

Non-metallic tube or tubes containing gas- or spark-producingpyrotechnic composition, with or without noise producing composition, with or without aerofoils attached

Wheels

Catherine wheels, Saxon

Assembly including drivers containing pyrotechnic composition and provided with a means of attaching it to a support so that it can rotate

Aerial wheel

Flying Saxon, UFO's, rising crown

Tubes containing propellant charges and sparksflame- andor noise producing pyrotechnic compositions, the tubes being fixed to a supporting ring

Specification Throwdowns and snaps may contain up to 1.6 mg of silver fklminate; snaps and party poppers may contain up to 16 mg of potassium chloratelred phosphorous mixture; other articles may contain up to 5 g of pyrotechnic composition, but no flash composition Pyrotechnic composition per item > 20 g, containing 5 3% flash composition as report effects, or whistle composition I5 g Pyrotechnic composition per item 1 20 g, containing 3% flash composition as report effects, or whistle composition 5 5 g 2 1 kg total pyrotechnic composition, no report effect, each whistle (if any) I25 g and f 50 g whistle composition per wheel < 1 kg total pyrotechnic composition, no report effect, each 10 g whistle (if any) I 5 g and I whistle composition per wheel > 200 g total pyrotechnic composition or > 60 g pyrotechnic composition per driver, 1 3% flash composition as report effects, each whistle (if any) I 25 g and f 50 g whistle composition per wheel

Classification

Includes: 1 Svnonvm:

Definition

Classification

Specification 1200 g total pyrotechnic composition and 5 60 g

pyrotechnic composition per driver, I3% flash composition as report effects, each whistle (if any) 5 5 g and 5 10 g whistle composition per wheel Selection pack

Display selection box, display selection pack, garden selection box, indoor selection box; assortment

A pack of more than one type each corresponding to one of the types of fireworks listed in this table

The most hazardous firework type determines the classification

Firecracker

Celebration cracker, celebration roll, string cracker

Assembly of tubes (paper or cardboard) linked by a pyrotechnic fuse, each tube intended to produce an aural effect

Each tube 5 140 mg of flash composition or 5 1 g black powder

Banger

Salute, flash banger, lady cracker

Non-metallic tube containing report composition intended to produce an aural effect

> 2 g flash composition per item 1 2 g flash composition per item and 5 10 g per inner packaging 5 1 g flash composition per item and I 10 g per inner packaging or I 10 g black powder per item

1.4G

I 1.1G

Glossary of names NOTE 1: The descriptions in the glossary are not intended to replace the test procedures, nor to determine the hazard classzjkation of a substance or article of Class I . Assignment to the correct division and a decision on whether Compatibility Group S is appropriate shall be based on testing of the product in accordance with the Manual of Tests and Criteria, Part I or by analogy with similar products which have already been tested and assigned in accordance with the procedures of the Manual of Tests and Criteria. NOTE 2: Thefigures given after the names refer to the relevant UN numbers (Column (2) of Table A of Chapter 3.2). For the classification code, see 2.2.1.1.4. AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT PRETENSIONERS: UN No. 0503 Articles which contain pyrotechnic substances and are used as life-saving vehicle airbags or seat-belts. AMMUNITION, ILLUMINATING, with or without burster, expelling charge or propelling charge: UN Nos. 0171,0254,0297 Ammunition designed to produce a single source of intense light for lighting up an area. The term includes illuminating cartridges, grenades and projectiles; and illuminating and target identification bombs. NOTE: The following articles: CARTRIDGES, SIGNAL; SIGNAL DEVICES HAND; SIGNALS, DISTRESS; FLARES, AERIAL; FLARES, SURFACE are not included in this definition. They are listed separately. AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge: UN No. 0247 Ammunition containing liquid or gelatinous incendiary substance. Except when the incendiary substance is an explosive per se, it also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge: UN Nos. 0243,0244 Ammunition containing white phosphorus as incendiary substance. It also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge: UN Nos. 0009,0010,0300 Ammunition containing incendiary composition. Except when the composition is an explosive per se, it also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, PRACTICE: UN Nos. 0362,0488 Ammunition without a main bursting charge, containing a burster or expelling charge. Normally it also contains a fuze and a propelling charge.

NOTE: GRENADES, PRACTICE are not included in this de$nition. They are listed separately. AMMUNITION, PROOF: UN No. 0363 Ammunition containing pyrotechnic substances, used to test the performance or strength of new ammunition, weapon components or assemblies. AMMUNITION, SMOKE, WHITE PHOSPHORUS, with burster, expelling charge or propelling charge: UN Nos. 0245, 0246 Ammunition containing white phosphorus as a smoke-producing substance. It also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. The term includes grenades, smoke. AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge: UN Nos. 0015,0016,0303 Ammunition containing a smoke-producing substance such as chlorosulphonic acid mixture or titanium tetrachloride; or a smoke-producing pyrotechnic composition based on hexachloroethane or red phosphorus. Except when the substance is an explosive per se, the ammunition also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. The term includes grenades, smoke. NOTE: SIGNALS, SMOKE are not included in this definition. They are listed separately. AMMUNITION, TEAR-PRODUCING, with burster, expelling charge or propelling charge: UN Nos. 001 8,0019,0301 Ammunition containing a tear-producing substance. It also contains one or more of the following: a pyrotechnic substance; a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES EEI): UN No. 0486 Articles containing only extremely insensitive detonating substances (EIDS) which demonstrate a negligible probability of accidental initiation or propagation under normal conditions of transport, and which have passed Test Series 7. ARTICLES, PYROPHORIC: UN No. 0380 Articles which contain a pyrophoric substance (capable of spontaneous ignition when exposed to air) and an explosive substance or component. The term excludes articles containing white phosphorus. ARTICLES, PYROTECHNIC, for technical purposes: UN Nos. 0428, 0429, 0430, 0431, 0432 Articles which contain pyrotechnic substances and are used for technical purposes such as heat generation, gas generation, theatrical effects, etc. NOTE: The following articles: all ammunition; CARTRIDGES, SIGNAL; CUTTERS, CABLE, EXPLOSIVE; FIRE WORKS; FLARES, AERIAL; FLARES, SURFACE; RELEASE DEVICES, EXPLOSIVE; RIVETS, EXPLOSIVE; SIGNAL DEVICES, HAND; SIGNALS,

DISTRESS; SIGNALS, RAIL WAY TRACK, EXPLOSIVES; SIGNALS, SMOKE are not included in this definition. They are listed separately. BLACK POWDER (GUNPOWDER), COMPRESSED (GUNPOWDER), IN PELLETS: UN No. 0028

or

BLACK

POWDER

Substance consisting of a pelletized form of black powder. BLACK POWDER (GUNPOWDER), granular or as meal: UN No. 0027 Substance consisting of an intimate mixture of charcoal or other carbon and either potassium nitrate or sodium nitrate, with or without sulphur. BOMBS, WITH FLAMMABLE LIQUID, with bursting charge: UN Nos. 0399,0400 Articles which are dropped from aircraft, consisting of a tank filled with inflammable liquid and bursting charge. BOMBS. PHOTO-FLASH: UN NO. 0038 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a charge of detonating explosive without means of initiation or with means of initiation containing two or more effective protective features. BOMBS, PHOTO-FLASH: UN NO. 0037 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a charge of detonating explosive with means of initiation not containing two or more effective protective features. BOMBS, PHOTO-FLASH: UN Nos. 0039,0299 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a photo-flash composition. BOMBS with bursting charge: UN Nos. 0034; 0035 Explosive articles which are dropped from aircraft, without means of initiation or with means of initiation containing two or more effective protective features. BOMBS with bursting charge: UN Nos. 0033, 0291 Explosive articles which are dropped from aircraft, with means of initiation not containing two or more effective protective features. BOOSTERS WITH DETONATOR: UN Nos. 0225,0268 Articles consisting of a charge of detonating explosive with means of initiation. They are used to increase the initiating power of detonators or detonating cord. BOOSTERS without detonator: UN Nos. 0042, 0283 Articles consisting of a charge of detonating explosive without means of initiation. They are used to increase the initiating power of detonators or detonating cord.

BURSTERS, explosive: UN No. 0043 Articles consisting of a small charge of explosive used to open projectiles or other ammunition in order to disperse their contents. CARTRIDGES, FLASH: UN Nos. 0049,0050 Articles consisting of a casing, a primer and flash powder, all assembled in one piece ready for firing. CARTRIDGES FOR WEAPONS, BLANK: UN Nos. 0326,0413,0327,0338,0014 Ammunition consisting of a closed cartridge case with a centre or rim fire primer and a charge of smokeless or black powder but no projectile. It produces a loud noise and is used for training, saluting, propelling charge, starter pistols, etc. The term includes ammunition, blank. CARTRIDGES FOR WEAPONS, INERT PROJECTILE: UN Nos. 0328,0417,0339,0012 Ammunition consisting of a projectile without bursting charge but with a propelling charge with or without a primer. The articles may include a tracer, provided that the predominant hazard is that of the propelling charge. CARTRIDGES FOR WEAPONS with bursting charge: UN Nos. 0006,0321,041 2 Ammunition consisting of a projectile with a bursting charge without means of initiation or with means of initiation containing two or more effective protective features; and a propelling charge with or without a primer. The term includes fixed (assembled) ammunition, semi-fixed (partially assembled) ammunition and separate loading ammunition when the components are packed together. CARTRIDGES FOR WEAPONS with bursting charge: UN Nos. 0005,0007,0348 Ammunition consisting of a projectile with a bursting charge with means of initiation not containing two or more effective protective features; and a propelling charge with or without a primer. The term includes fixed (assembled) ammunition, semi-fixed (partially assembled) ammunition and separate loading ammunition when the components are packed together. CARTRIDGES, OIL WELL: UN Nos. 0277,0278 Articles consisting of a thin casing of fibreboard, metal or other material containing only propellant powder which projects a hardened projectile to perforate an oil well casing. NOTE: CHARGES, SHAPED are not included in this dejinition. They are listed separately.

CARTRIDGES, POWER DEVICE: UN Nos. 0275,0276,0323,0381 Articles designed to accomplish mechanical actions. They consist of a casing with a charge of deflagrating explosive and a means of ignition. The gaseous products of the deflagration produce inflation, linear or rotary motion or activate diaphragms, valves or switches or project fastening devices or extinguishing agents. CARTRIDGES, SIGNAL: UN Nos. 0054,03 12,0405 Articles designed to frre coloured flares or other signals from signal pistols, etc.

CARTRIDGES, SMALL ARMS: UN Nos. 0417,0339,0012 Ammunition consisting of a cartridge case fitted with a centre or rim fire primer and containing both a propelling charge and solid projectile. They are designed to be fired in weapons of calibre not larger than 19.1 mm. Shot-gun cartridges of any calibre are included in this description. NOTE: CARTRIDGES, SMALL ARMS, BLANK, are not included in this definition. They are listed separately. Some military snzall arms cartridges are not included in this definition. They are listed under CARTRIDGES FOR WEAPONS, INERT PROJECTILE.

CARTRIDGES, SMALL ARMS, BLANK: UN Nos. 0014,0327,0338 Ammunition consisting of a closed cartridge case with a centre or rim fire primer and a charge of smokeless or black powder. The cartridge cases contain no projectiles. The cartridges are designed to be fired from weapons with a calibre of at most 19.1 mm and serve to produce a loud noise and are used for training, saluting, propelling charge, starter pistols, etc. CASES, CARTRIDGE, EMPTY, WITH PRIMER: UN Nos. 0379; 0055 Articles consisting of a cartridge case made from metal, plastics or other non-inflammable material, in which the only explosive component is the primer. CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER: UN Nos. 0447,0446 Articles consisting of a cartridge case made partly or entirely from nitrocellulose. CHARGES, BURSTING, PLASTICS BONDED: UN Nos. 0457,0458,0459,0460 Articles consisting of a charge of detonating explosive, plastics bonded, manufactured in a specific form without a casing and without means of initiation. They are designed as components of ammunition such as warheads. CHARGES, DEMOLITION: UN No. 0048 Articles containing a charge of a detonating explosive in a casing of fibreboard, plastics, metal or other material. The articles are without means of initiation or with means of initiation containing two or more effective protective features. NOTE: The following articles: BOMBS; MINES; PROJECTILES are not included in this dejkition. They are listed separately.

CHARGES, DEPTH: UN No. 0056 Articles consisting of a charge of detonating explosive contained in a drum or projectile without means of initiation or with means of initiation containing two or more effective protective features. They are designed to detonate under water. CHARGES, EXPLOSIVE, COMMERCIAL without detonator: UN Nos. 0442, 0443, 0444, 0445 Articles consisting of a charge of detonating explosive without means of initiation, used for explosive welding, jointing, forming and other metallurgical processes.

CHARGES, PROPELLING, FOR CANNON: UN Nos. 0242,0279,0414 Charges of propellant in any physical form for separate-loading ammunition for cannon. CHARGES, PROPELLING: UN Nos. 0271,0272,041 5,0491 Articles consisting of a charge of a propellant charge in any physical form, with or without a casing, as a component of rocket motors or for reducing the drag of projectiles. CHARGES, SHAPED, without detonator: UN Nos. 0059,0439,0440, UN 0441 Articles consisting of a casing containing a charge of detonating explosive with a cavity lined with rigid material, without means of initiation. They are designed to produce a powerful, penetrating jet effect. CHARGES, SHAPED, FLEXIBLE, LINEAR: UN Nos. 0237,0288 Articles consisting of a V-shaped core of a detonating explosive clad by a flexible sheath. CHARGES, SUPPLEMENTARY, EXPLOSIVE: UN No. 0060 Articles consisting of a small removable booster placed in the cavity of a projectile between the fuze and the bursting charge. COMPONENTS, EXPLOSIVE TRAIN, N.O.S.: UN Nos. 0382,0383,0384,0461 Articles containing an explosive designed to transmit detonation or deflagration within an explosive train. CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge: UN Nos. 0248,0249 Articles whose functioning depends upon physico-chemical reaction of their contents with water. CORD, DETONATING, flexible: UN Nos. 0065,0289 Article consisting of a core of detonating explosive enclosed in spun fabric and a plastics or other covering. The covering is not necessary if the spun fabric is sift-proof. CORD (FUSE) DETONATING, metal clad: UN Nos. 0102,0290 Article consisting of a core of detonating explosive clad by a soft metal tube with or without protective covering. CORD (FUSE) DETONATING, MILD EFFECT, metal clad: UN No. 0104 Article consisting of a core of detonating explosive clad by a soft metal tube with or without a protective covering. The quantity of explosive substance is so small that only a mild effect is manifested outside the cord. CORD, IGNITER: UN No. 0066 Article consisting of textile yarns covered with black powder or another fast burning pyrotechnic composition and of a flexible protective covering; or it consists of a core of

black powder surrounded by a flexible woven fabric. It burns progressively along its length with an external flame and is used to transmit ignition from a device to a charge or primer. CUTTERS, CABLE, EXPLOSIVE: UN No. 0070 Articles consisting of a knife-edged device which is driven by a small charge of deflagrating explosive into an anvil. DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting: UN Nos. 0360,0361,0500 Non-electric detonators assembled with and activated by such means as safety fuse, shock tube, flash tube or detonating cord. They may be of instantaneous design or incorporate delay elements. Detonating relays incorporating detonating cord are included. DETONATORS, ELECTRIC for blasting: UN Nos. 0030,0255,0456 Articles specially designed for the initiation of blasting explosives. These detonators may be constructed to detonate instantaneously or may contain a delay element. Electric detonators are activated by an electric current. DETONATORS FOR AMMUNITION: UN Nos. 0073,0364,0365,0366 Articles consisting of a small metal or plastics tube containing explosives such as lead azide, PETN or combinations of explosives. They are designed to start a detonation train. DETONATORS, NON-ELECTRIC for blasting: UN Nos. 0029,0267,0455 Articles specially designed for the initiation of blasting explosives. These detonators may be constructed to detonate instantaneously or may contain a delay element. Non-electric detonators are activated by such means as shock tube, flash tube, safety fuse, other igniferous device or flexible detonating cord. Detonating relays without detonating cord are included. EXPLOSIVE, BLASTING, TYPE A: UN No. 0081 Substances consisting of liquid organic nitrates such as nitroglycerine or a mixture of such ingredients with one or more of the following: nitrocellulose; ammonium nitrate or other inorganic nitrates; aromatic nitro-derivatives, or combustible materials, such as wood-meal and aluminium powder. They may contain inert components such as kieselguhr, and additives such as colouring agents and stabilizers. Such explosives shall be in powdery, gelatinous or elastic form. The term includes dynamite; gelatine, blasting and gelatine dynamites. EXPLOSIVE, BLASTING, TYPE B: UN Nos. 0082,033 1 Substances consisting of (a)

a mixture of ammonium nitrate or other inorganic nitrates with an explosive such as trinitrotoluene, with or without other substances such as wood-meal and aluminium powder; or

(b)

a mixture of ammonium nitrate or other inorganic nitrates with other combustible substances which are not explosive ingredients. In both cases they may contain inert components such as kieselguhr, and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine, similar liquid organic nitrates or chlorates.

EXPLOSIVE, BLASTING, TYPE C: UN No. 0083 Substances consisting of a mixture of either potassium or sodium chlorate or potassium, sodium or ammonium perchlorate with organic nitro-derivatives or combustible materials such as wood-meal or aluminium powder or a hydrocarbon. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine or similar liquid organic nitrates. EXPLOSIVE, BLASTING, TYPE D: UN No. 0084 Substances consisting of a mixture of organic nitrated compounds and combustible materials such as hydrocarbons and aluminium powder. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine, similar liquid organic nitrates, chlorates and ammonium nitrate. The term generally includes plastic explosives. EXPLOSIVES, BLASTING, TYPE E: UN Nos. 0241,0332 Substances consisting of water as an essential ingredient and high proportions of ammonium nitrate or other oxidizers, some or all of which are in solution. The other constituents may include nitro-derivatives such as trinitrotoluene, hydrocarbons or aluminium powder. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. The term includes explosives, emulsion, explosives, slurry and explosives, watergel. FIREWORKS: UN Nos. 0333,0334,0335,0336,0337 Pyrotechnic articles designed for entertainment. FLARES, AERIAL: UN Nos. 0093,0403,0404,0420,0421; Articles containing pyrotechnic substances which are designed to be dropped from an aircraft to illuminate, identify, signal or warn. FLARES, SURFACE: UN Nos. 0092,041 8,0419 Articles containing pyrotechnic substances which are designed for use on the surface to illuminate, identify, signal or warn. FLASH POWDER: UN Nos. 0094.0305 Pyrotechnic substance which, when ignited, produces an intense light. FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells: UN No. 0099 Articles consisting of a charge of detonating explosive contained in a casing without means of initiation. They are used to fracture the rock around a drill shaft to assist the flow of crude oil from the rock. FUSE, IGNITER, tubular, metal clad: UN No. 0103 Article consisting of a metal tube with a core of deflagrating explosive.

FUSE, NON-DETONATING: UN No. 0 101 Article consisting of cotton yarns impregnated with fine black powder (quickmatch). It burns with an external flame and is used in ignition trains for fireworks, etc. FUSE, SAFETY: UN No. 0105 Article consisting of a core of fine grained black powder surrounded by a flexible woven fabric with one or more protective outer coverings. When ignited, it burns at a predetermined rate without any external explosive effect. FUZES, DETONATING: UN Nos. 0106,0107,0257,0367 Articles with explosive components designed to produce a detonation in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to initiate the detonation. They generally incorporate protective features. FUZES, DETONATING with protective features: UN Nos. 0408, 0409,0410 Articles with explosive components designed to produce a detonation in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to initiate the detonation. The detonating fuze must incorporate two or more effective protective features. FUZES, IGNITING: UN Nos. 03 16,0317,0368 Articles with primary explosive components designed to produce a deflagration in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to start the deflagration. They generally incorporate protective features. GRENADES, hand or rifle, with bursting charge: UN Nos. 0284,0285 Articles which are designed to be thrown by hand or to be projected by a rifle. They are without means of initiation or with means of initiation containing two or more effective protective features. GRENADES, hand or rifle, with bursting charge: UN Nos. 0292,0293 Articles which are designed to be thrown by hand or to be projected by a rifle. They are with means of initiation not containing two or more effective protective features. GRENADES, PRACTICE, hand or rifle: UN Nos. 0 110,0372,0318,0452 Articles without a main bursting charge which are designed to be thrown by hand or to be projected by a rifle. They contain the priming device and may contain a spotting charge. HEXOTONAL: UN No. 0393 Substance consisting of an intimate mixture of cyclotrimethylenetrinitramine (RDX), trinitrotoluene (TNT) and aluminium. HEXOLITE (HEXOTOL), dry or wetted with less than 15 % water, by mass: UN No. 01 18 Substance consisting of an intimate mixture of cyclotrimethylenetrinitramine (RDX) and trinitrotoluene (TNT). The term includes "Composition B".

IGNITERS: UNNos. 0121,0314,0315, 0325,0454 Articles containing one or more explosive substances designed to produce a deflagration in an explosive train. They may be actuated chemically, electrically or mechanically. NOTE: The following articles: CORD, IGNITER; FUSE, IGNITER; FUSE, NON-DETONATING; FUZES, IGNITING; LIGHTERS, FUSE; PRIMERS, CAP TYPE; PRIMERS, TUBULAR are not included in this definition. They are listed separately.

JET PERFORATING GUNS, CHARGED, oil well, without detonator: UN Nos. 0124,0494 Articles consisting of a steel tube or metallic strip, into which are inserted shaped charges connected by detonating cord, without means of initiation. LIGHTERS, FUSE: UN No. 0 131 Articles of various design actuated by friction, percussion or electricity and used to ignite safety fuse. MINES with bursting charge: UN Nos. 0137,0138 Articles consisting normally of metal or composition receptacles filled with a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be operated by the passage of ships, vehicles or personnel. The term includes "Bangalore torpedoes". MINES with bursting charge: UN Nos. 0136,0294 Articles consisting normally of metal or composition receptacles filled with a detonating explosive, with means of initiation not containing two or more effective protective features. They are designed to be operated by the passage of ships, vehicles or personnel. The term includes "Bangalore torpedoes". OCTOLITE (OCTOL), dry or wetted with less than 15 % water, by mass: UN No. 0266 Substance consisting of an intimate mixture of cyclotetramethylenetetranitramine (HMX) and trinitrotoluene (TNT). OCTONAL: UN No. 0496 Substance consisting of an intimate mixture of cyclotetramethylenetetranitramine (HMX), trinitrotoluene (TNT) and aluminium. PENTOLITE, dry or wetted with less than 15 % water, by mass: UN No. 0151 Substance consisting of an intimate mixture of pentaerythrite tetranitrate (PETN) and trinitrotoluene (TNT). POWDER CAKE (POWDER PASTE), WETTED with not less than 17 % alcohol, by mass; POWDER CAKE (POWDER PASTE), WETTED with not less than 25 % water, by mass: UN Nos. 0433,0159 Substance consisting of nitrocellulose impregnated with not more than 60 % of nitroglycerine or other liquid organic nitrates or a mixture of these.

POWDER, SMOKELESS: UN Nos. 0160,O 161 Substance based on nitrocellulose used as propellant. The term includes propellants with a single base (nitrocellulose (NC) alone), those with a double base (such as NC and nitroglycerine (NG)) and those with a triple base (such as NC/NG/nitroguanidine).

NOTE: Cast, pressed or bag-charges of smokeless powder are listed under CHARGES, PROPELLING or CHARGES, PROPELLING, FOR CANON. PRIMERS, CAP TYPE: UN Nos. 0044,0377,0378 Articles consisting of a metal or plastics cap containing a small amount of primary explosive mixture that is readily ignited by impact. They serve as igniting elements in small arms cartridges and in percussion primers for propelling charges. PRIMERS, TUBULAR: UN Nos. 0319,0320,0376 Articles consisting of a primer for ignition and an auxiliary charge of deflagrating explosive such as black powder used to ignite the propelling charge in a cartridge case for cannon, etc. PROJECTILES, inert with tracer: UN Nos. 0345,0424,0425 Articles such as a shell or bullet, which are projected from a cannon or other gun, rifle or other small arm. PROJECTILES with burster or expelling charge: UN Nos. 0346,0347 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are without means of initiation or with means of initiation containing two or more effective protective features. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with burster or expelling charge: UN Nos. 0426,0427 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are with means of initiation not containing two or more effective protective features. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with burster or expelling charge: UN Nos. 0434,0435 Articles such as a shell or bullet, which are projected from a cannon or other gun, rifle or other small arm. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with bursting charge: UN Nos. 0168, 0169,0344 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are without means of initiation or with means of initiation containing two or more effective protective features. PROJECTILES with bursting charge: UN Nos. 0167,0324 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are with means of initiation not containing two or more effective protective features. PROPELLANT, LIQUID: UN Nos. 0495,0497 Substance consisting of a deflagrating liquid explosive, used for propulsion.

PROPELLANT, SOLID: UN Nos. 0498,0499,0501 Substance consisting of a deflagrating solid explosive, used for propulsion. RELEASE DEVICES, EXPLOSIVE: UN No. 0173 Articles consisting of a small charge of explosive with means of initiation and rods or links. They sever the rods or links to release equipment quickly. RIVETS, EXPLOSIVE: UN No. 0174 Articles consisting of a small charge of explosive inside a metallic rivet. ROCKET MOTORS: UN Nos. 0186,0280,0281 Articles consisting of a charge of explosive, generally a solid propellant, contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKET MOTORS, LIQUID FUELLED: UN Nos. 0395,0396 Articles consisting of a liquid fuel within a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge: UN Nos. 0322,0250 Articles consisting of a hypergolic fuel contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKETS, LINE THROWING: UN Nos. 0238,0240,0453 Articles consisting of a rocket motor which is designed to extend a line. ROCKETS, LIQUID FUELLED with bursting charge: UN Nos. 0397,0398 Articles consisting of a liquid fuel within a cylinder fitted with one or more nozzles and fitted with a warhead. The term includes guided missiles. ROCKETS with bursting charge: UN Nos. 0181,0182 Articles consisting of a rocket motor and a warhead without means of initiation or with means of initiation containing two or more effective protective features. The term includes guided missiles. ROCKETS with bursting charge: UN Nos. 01 80,0295 Articles consisting of a rocket motor and a warhead with means of initiation not containing two or more effective protective features. The term includes guided missiles. ROCKETS with expelling charge: UN Nos. 0436,0437,0438 Articles consisting of a rocket motor and a charge to expel the payload from a rocket head. The term includes guided missiles.

ROCKETS with inert head: UN Nos. 0183,0502 Articles consisting of a rocket motor and an inert head. The term includes guided missiles. SAMPLES, EXPLOSIVE, other than initiating explosive UN No. 0190 New or existing explosive substances or articles, not yet assigned to a name in Table A of Chapter 3.2 and carried in conformity with the instructions of the competent authority and generally in small quantities, inter alia, for the purposes of testing, classification, research and development, or quality control, or as commercial samples. NOTE: Explosive substances or articles already assigned to another name in Table A of Chapter 3.2 are not included in this definition.

SIGNAL DEVICES, HAND: UN Nos. 0191,0373 Portable articles containing pyrotechnic substances which produce visual signals or warnings. The term includes small surface flares such as highway or railway flares and small distress flares. SIGNALS, DISTRESS, ship: UN Nos. 0194,0195 Articles containing pyrotechnic substances designed to produce signals by means of sound, flame or smoke or any combination thereof. SIGNALS, RAILWAY TRACK, EXPLOSIVE: UN Nos. 0192,0193,0492,0493 Articles containing a pyrotechnic substance which explodes with a loud report when the article is crushed. They are designed to be placed on a rail. SIGNALS, SMOKE: UN Nos. 0196,0197,03 13,0487 Articles containing pyrotechnic substances which emit smoke. In addition they may contain devices for emitting audible signals. SOUNDING DEVICES, EXPLOSIVE: UN Nos. 0374,0375 Articles consisting of a charge of detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are dropped from ships and function when they reach a predetermined depth or the sea bed. SOUNDING DEVICES, EXPLOSIVE: UN Nos. 0204,0296 Articles consisting of a charge of detonating explosive with means of initiation not containing two or more effective protective features. They are dropped from ships and function when they reach a predetermined depth or the sea bed. SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (Substances, EVI), N.O.S.: UN No. 0482 Substances presenting a mass explosion hazard but which are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of transport, and which have passed Test Series 5.

TORPEDOES, LIQUID FUELLED with inert head: UN No. 0450 Articles consisting of a liquid explosive system to propel the torpedo through the water, with an inert head. TORPEDOES, LIQUID FUELLED with or without bursting charge: UN No. 0449 Articles consisting of either a liquid explosive system to propel the torpedo through the water, with or without a warhead; or a liquid non-explosive system to propel the torpedo through the water, with a warhead. TORPEDOES with bursting charge: UN No. 045 1 Articles consisting of a non-explosive system to propel the torpedo through the water, and a warhead without means of initiation or with means of initiation containing two or more effective protective features. TORPEDOES with bursting charge: UN No. 0329 Articles consisting of an explosive system to propel the torpedo through the water, and a warhead without means of initiation or with means of initiation containing two or more effective protective features. TORPEDOES with bursting charge: UN No. 0330 Articles consisting of an explosive or non-explosive system to propel the torpedo through the water, and a warhead with means of initiation not containing two or more effective protective features. TRACERS FOR AMMUNITION: UN Nos. 02 12,0306 Sealed articles containing pyrotechnic substances, designed to reveal the trajectory of a projectile. TFUTONAL: UN No. 0390 Substance consisting of trinitrotoluene (TNT) mixed with aluminium. WARHEADS, ROCKET with burster or expelling charge: UN No. 0370 Articles consisting of an inert payload and a small charge of detonating or deflagrating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a rocket motor to scatter inert material. The term includes warheads for guided missiles. WARHEADS, ROCKET with burster or expelling charge: UN No. 0371 Articles consisting of an inert payload and a small charge of detonating or deflagrating explosive, with means of initiation not containing two or more effective protective features. They are designed to be fitted to a rocket motor to scatter inert material. The term includes warheads for guided missiles.

WARHEADS, ROCKET with bursting charge: UN Nos. 0286,0287 Articles consisting of a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a rocket. The term includes warheads for guided missiles. WARHEADS, ROCKET with bursting charge: UN No. 0369 Articles consisting of a detonating explosive, with means of initiation not containing two or more effective protective features. They are designed to be fitted to a rocket. The term includes warheads for guided missiles. WARHEADS, TORPEDO with bursting charge: UN No. 0221 Articles consisting of a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a torpedo.

2.2.1.2

Substances and articles not acceptedfor carriage

2.2.1.2.1

Explosive substances which are unduly sensitive according to the criteria of the Manual of Tests and Criteria, Part I, or are liable to spontaneous reaction, as well as explosive substances and articles which cannot be assigned to a name or n.0.s. entry listed in Table A of Chapter 3.2, shall not be accepted for carriage.

2.2.1.2.2

Articles of compatibility group K shall not be accepted for carriage (1.2K, UN No. 0020 and 1.3K, UN No. 002 1).

List of collective entries

2.2.1.3

Classification code (see 2.2.1.1.4) 1.1A 1.1B 1.1C

I UN

1.1D

1

No 0473 0461 0474 0497 0498 0462 0475 0463 0464 0465 0476 0357 0354 0382 0466 0467 0468 0469 0358 0248

0355 0132 0477 0495 0499 0470 0478 0359 0249

1.4D 1.4E 1.4F 1.4G 1.4s

1.5D

0356 0350 0383 0479 035 1 0501 0480 0352 0471 0472 0485 0353 0481 0349 0384 0482

Name of the substance or article

SUBSTANCES, EXPLOSIVE, N.O.S. COMPONENTS, EXPLOSIVE TRAIN, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. PROPELLANT, LIQUID PROPELLANT, SOLID ARTICLES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. COMPONENTS, EXPLOSIVE TRAIN, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge ARTICLES, EXPLOSIVE, N.O.S. DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. PROPELLANT, LIQUID PROPELLANT, SOLID ARTICLES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. COMPONENTS, EXPLOSIVE TRAIN, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. ARTICLES. EXPLOSIVE. N.O.S. PROPELLANT, SOLID SUBSTANCES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. COMPONENTS, EXPLOSIVE TRAIN, N.O.S. SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI) N.O.S.

- 39 -

Classification code ( UN (see 2.2.1.1.4) No 0486 1.6N 0190

Name of the substance or article ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI) SAMPLES, EXPLOSIVE other than initiating explosive NOTE: Division and Compatibility Group shall be defined as directed bv the competent authority and according to the principles in 2.2.1.1.4.

2.2.2

Class 2

2.2.2.1

Criteria

2.2.2.1.1

The heading of Class 2 covers pure gases, mixtures of gases, mixtures of one or more gases with one or more other substances and articles containing such substances.

Gases

A gas is a substance which: (a)

at 50 "C has a vapour pressure greater than 300 kPa (3 bar); or

(b)

is completely gaseous at 20" C at the standard pressure of 101.3 kPa

.

NOTE l : UN No. 105.2 HYDROGEN FLUORIDE ANHYDROUS is nevertheless classified in Class 8. NOTE 2: A pure gas may contain other components deriving from its production process or added to preserve the stability of the product, provided that the level of these components does not change its classification or its conditions of carriage, such as filling ratio, filling pressure, test pressure. NOTE 3: N. O.S. entries in 2.2.2.3 may cover pure gases as well as mixtures. NOTE 4: Carbonated beverages are not subject to the provisions of ADN. 2.2.2.1.2

The substances and articles of Class 2 are subdivided as follows:

Compressed gas: a gas which when packaged under pressure for carriage is entirely gaseous at -50 "C; this category includes all gases with a critical temperature less than or equal to -50 "C; Liquefied gas: a gas which when packaged under pressure for carriage is partially liquid at temperatures above -50 "C. A distinction is made between: High pressure liquefied gas: a gas with a critical temperature above -50 "C and equal to or below +65 "C; and Low pressure liquefied gas: a gas with a critical temperature above +65 "C; Refrigerated liquefied gas: a gas which when packaged for carriage is made partially liquid because of its low temperature;

Dissolved gas: a gas which when packaged under pressure for carriage is dissolved in a liquid phase solvent; Aerosol dispensers and receptacles, small, containing gas (gas cartridges); Other articles containing gas under pressure; Non-pressurized gases subject to special requirements (gas samples). 2.2.2.1.3

Substances and articles (except aerosols) of Class 2 are assigned to one of the following groups according to their hazardous properties, as follows: A

asphyxiant;

0

oxidizing;

F

flammable;

T

toxic;

TF

toxic, flammable;

TC

toxic, corrosive;

TO

toxic, oxidizing;

TFC toxic, flammable, corrosive; TOC toxic, oxidizing, corrosive. For gases and gas mixtures presenting hazardous properties associated with more than one group according to the criteria, the groups designated by letter T take precedence over all other groups. The groups designated by letter F take precedence over the groups designated by letters A or 0. NOTE l : Zn the UN Model Regulations, the ZMDG Code and the ICAO Technical Instructions, gases are assigned to one of the following three divisions, based on the primary hazard:

Division 2.1:

flammable gases (corresponding to the groups designated by the capital letter F);

Division 2.2:

non-flammable, non-toxic gases (corresponding to the groups designated by the capital letters A or 0);

Division 2.3:

toxic gases (corresponding to the groups designated by the capital letter T (i.e. T, TF, TC, TO, TFC and TOC).

NOTE 2: Receptacles, small containing gas (UN No. 2037) shall be assigned to the groups A to TOC according to the hazard of the contents. For aerosols (UN No. 1950), see 2.2.2.1.6. NOTE 3: Corrosive gases are considered to be toxic, and are therefore assigned to the group TC, TFC or TOC. NOTE 4: Mixtures containing more than 21% oxygen by volunze shall be classiJied as oxidizing. 2.2.2.1.4

If a mixture of Class 2 mentioned by name in Table A of Chapter 3.2 meets different criteria as mentioned in 2.2.2.1.2 and 2.2.2.1.5, this mixture shall be classified according to the criteria and assigned to an appropriate N.O.S. entry.

2.2.2.1.5

Substances and articles (except aerosols) of Class 2 which are not mentioned by name in Table A of Chapter 3.2 shall be classified under a collective entry listed in 2.2.2.3 in accordance with 2.2.2.1.2 and 2.2.2.1.3. The following criteria shall apply: Asphyxiant gases Gases which are non-oxidizing, non-flammable and non-toxic and which dilute or replace oxygen normally in the atmosphere.

Flammable gases Gases which at 20 OC and a standard pressure of 101.3 kPa: (a)

are ignitable when in a mixture of 13% or less by volume with air; or

(b)

have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit.

Flammability shall be determined by tests or by calculation, in accordance with methods adopted by I S 0 (see I S 0 10156:1996). Where insufficient data are available to use these methods, tests by a comparable method recognized by the competent authority of the country of origin may be used. If the country of origin is not a Contracting Party to ADN these methods shall be recognized by the competent authority of the first country Contracting Party to ADN reached by the consignment.

Oxidizing gases Gases, which may, generally by providing oxygen, cause or contribute to the combustion of other material more than air does. Oxidizing ability is determined either by tests or by calculation methods adopted by I S 0 (see I S 0 10156: l996 and I S 0 10156-2:2005).

Toxic gases NOTE: Gases meeting the criteria for toxicity in part or completely owing to their corrosivity are to be classiJied as toxic. See also the criteria under the heading "Corrosive gases" for a possible subsidiary corrosivity risk. Gases which: (a)

are known to be so toxic or corrosive to humans as to pose a hazard to health; or

(b)

are presumed to be toxic or corrosive to humans because they have a LC5o value for acute toxicity equal to or less than 5 000 ml/m3 (ppm) when tested in accordance with 2.2.61.1.

In the case of gas mixtures (including vapours of substances from other classes) the following formula may be used:

L C Toxic ~ ~ (mixture) =

where

l

-

fi

=

mole fraction of the ithcomponent substance of the mixture;

Ti

=

toxicity index of the i~ component substance of the mixture. The Ti equals the LC50value as found in packing instruction P200 of 4.1.4.1 of ADR. When no LC50 value is listed in packing instruction P200 of 4.1.4.1 value available in scientific literature shall be used. of ADR, a LC5@

When the LC50 value is unknown, the toxicity index is determined by using the lowest LCS0 value of substances of similar physiological and chemical effects, or through testing if this is the only practical possibility. Corrosive gases

Gases or gas mixtures meeting the criteria for toxicity completely owing to their corrosivity are to be classified as toxic with a subsidiary corrosivity risk. A gas mixture that is considered to be toxic due to the combined effects of corrosivity and toxicity has a subsidiary risk of corrosivity when the mixture is known by human experience to be destructive to the skin, eyes or mucous membranes or when the LCSovalue of the corrosive components of the mixture is equal to or less than 5 000 ml/m3 (ppm) when the LCsois calculated by the formula:

1 LCso Corrosive (mixture) = + i

where

2.2.2.1.6

fci

=

mole fraction of the ith corrosive component substance of the mixture;

Tci

=

toxicity index of the ith corrosive component substance of the mixture. The Tci equals the LC50 value as found in packing instruction P200 of 4.1.4.1 of ADR. When no LCS0value is listed in packing instruction P200 of 4.1.4.1 of ADR, a LC5o value available in scientific literature shall be used. When the LCSo value is unknown the toxicity index is determined by using the lowest LCSo value of substances of similar physiological and chemical effects, or through testing if this is the only practical possibility.

Aerosols

Aerosols (UN No. 1950) are assigned to one of the following groups according to their hazardous properties, as follows:

A

asphyxiant;

0

oxidizing;

F

flammable;

T

toxic;

C

corrosive;

CO

corrosive, oxidizing;

FC

flammable, corrosive;

TF

toxic, flammable;

TC

toxic, corrosive;

TO

toxic, oxidizing;

TFC

toxic, flammable, corrosive

TOC

toxic, oxidizing, corrosive.

The classification depends on the nature of the contents of the aerosol dispenser. NOTE: Gases, which meet the deJinition of toxic gases according to 2.2.2.1.5 or of pyrophoric gases according to packing instruction P200 in 4.1.4.1 of ADR, shall not be used as a propellant in an aerosol dispenser. Aerosols with contents meeting the criteria for packing group I for toxicity or corrosivity shall not be accepted for carriage (see also 2.2.2.2.2).

The following criteria shall apply: Assignment to group A shall apply when the contents do not meet the criteria for any other group according to sub-paragraphs (b) to (f) below; Assignment to group 0 shall apply when the aerosol contains an oxidizing gas according to 2.2.2.1.5; Assignment to group F shall apply if the contents include 85% by mass or more flammable components and the chemical heat of combustion is 30 kJ/g or more. It shall not apply if the contents contain 1% by mass or less flammable components and the heat of combustion is less than 20 kJ/g. Otherwise the aerosol shall be tested for flammability in accordance with the tests described in the Manual of Tests and Criteria, Part 111, section 31. Extremely flammable and flammable aerosols shall be assigned to group F; Flammable components are jlammable liquids, jlammable solids or NOTE: flammable gases and gas mixtures as deJined in Notes l to 3 of sub-section 31.1.3 of Part 111 of the Manual of Tests and Criteria. This designation does not cover pyrophoric, self-heating or water-reactive substances. The chemical heat of combustion shall be determined by one of the following methods ASTMD 240, ISO/FDIS 13943: 1999 (E/F) 86.1 to 86.3 or NFPA 30B.

Assignment to group T shall apply when the contents, other than the propellant of aerosol dispensers to be ejected, are classified as Class 6.1, packing groups I1 or 111; Assignment to group C shall apply when the contents, other than the propellant of aerosol dispensers to be ejected, meet the criteria for Class 8, packing groups I1 or 111; When the criteria for more than one group amongst groups 0, F, T, and C are met, assignment to groups CO, FC, TF, TC TO, TFC or TOC shall apply, as relevant. 2.2.2.2

Gases not accepted for carriage

2.2.2.2.1

Chemically unstable substances of Class 2 shall not be accepted for carriage, unless the necessary steps have been taken to prevent all possibility of a dangerous reaction e.g. decomposition, dismutation or polymerisation under normal conditions during transport.

To this end particular care shall be taken to ensure that receptacles and tanks do not contain any substances liable to promote these reactions. 2.2.2.2.2

The following substances and mixtures shall not be accepted for carriage: -

UN No. 2186 HYDROGEN CHLORIDE, REFRIGERATED LIQUID;

-

UN NO.242 1 NITROGEN TRIOXIDE;

-

UN NO. 2455 METHYL NITRITE;

-

Refi-igerated liquefied gases which cannot be assigned to classification codes 3A, 3 0 or 3F;

-

Dissolved gases which cannot be classified under UN Nos. 1001,2073 or 33 18;

-

Aerosols where gases which are toxic according to 2.2.2.1.5 or pyrophoric according to packing instruction P200 in 4.1.4.1 of ADR are used as propellants;

-

Aerosols with contents meeting the criteria for packing group I for toxicity or corrosivity (see 2.2.61 and 2.2.8);

-

Receptacles, small, containing gases which are very toxic lower than 200 ppm) or pyrophoric according to packing instruction P200 in 4.1.4.1 of ADR.

2.2.2.3

List of collective entries Compressed gases

Classification code 1A 1 0 1F

1T 1 TF 1 TC 1 TO 1 TFC 1 TOC

UN No 1956 3 156 1964 1954 1955 1953 3304 3303 3305 3306

Name and description

COMPRESSED GAS, N.O.S. COMPRESSED GAS, OXIDIZING, N.O.S. HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. COMPRESSED GAS, FLAMMABLE, N.O.S. COMPRESSED GAS, TOXIC, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S.

Liquefied gases Classification code 2A

UN No

Name and description

LIQUEFIED GASES, non-flammable, charged with nitrogen, carbon dioxide or air REFRIGERANT GAS, N.O.S. such as mixtures of gases, indicated by the letter R, which as: Mixture F 1, have a vapour pressure at 70 'C not exceeding 1.3 MPa ( l 3 bar) and a density at 50 'C not lower than that of dichlorofluoromethane (1.30 kgll); Mixture F2, have a vapour pressure at 70 'C not exceeding 1.9 MPa (19 bar) and a density at 50 'C not lower than that of dichlorodifluoromethane (1.21 kgll); Mixture F3, have a vapour pressure at 70 'C not exceeding 3 MPa (30 bar) and a density at 50 'C not lower than that of chlorodifluoromethane (1.O9 kgll).

NOTE: Trichlorofluoronzethane (Refrigerant R II), 1,1,2-trichloro-1,2,2trzjluoroethane (Refrigerant R 113), 1,l ,l -trichloro-2,2,2-trijluoroethane (Refrigerant R 113a), I-chloro-1,2,2-trzjluoroethane (Refrigerant R 133) and 1chloro-1,1,2-trzjluoroethane(Refrigerant R 133b) are not substances of Class 2. They nzay, however, enter into the composition of mixtures F1 to F3. 3 l63 3 157

INSECTICIDE GAS, N.O.S. LIQUEFIED GAS, N.O.S. LIQUEFIED GAS, OXIDIZING, N.O.S.

Liquefied gases (cont'd) Classification code

UN No 1010

Name and description

BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 "C not exceeding 1.1 MPa ( l l bar) and a density at 50% not lower than 0.525 kgll. NOTE: Butadienes, stabilized are also classij?ed under UNNo. 1010, see Table A of Chapter 3.2.

METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED such as mixtures of methylacetylene and propadiene with hydrocarbons, which as: Mixture PI, contain not more than 63% methylacetylene and propadiene by volume and not more than 24% propane and propylene by volume, the percentage of C4- saturated hydrocarbons being not less than 14% by volume; and as Mixture P2, contain not more than 48% methylacetylene and propadiene by volume and not more than 50% propane and propylene by volume, the percentage of C4-saturated hydrocarbons being not less than 5% by volume, as well as mixtures of propadiene with 1 to 4% methylacetylene. HYDROCARBON GAS MIXTURE, LIQUEFIED, N.0.S such as mixtures, which as: Mixture A, have a vapour pressure at 70 "C not exceeding 1.1 MPa (1 1 bar) and a density at 50 'C not lower than 0.525 kg/l; Mixture A01, have a vapour pressure at 70 "C not exceeding 1.6 MPa (16 bar) and a relative density at 50 "C not lower than 0.5 16 kgll; Mixture A02, have a vapour pressure at 70 "C not exceeding 1.6 MPa (16 bar) and a relative density at 50 'C not lower than 0.505 kg/l; Mixture AO, have a vapour pressure at 70 "C not exceeding 1.6 MPa (16 bar) and a density at 50 "C not lower than 0.495 kgll; Mixture Al, have a vapour pressure at 70 "C not exceeding 2.1 MPa (21 bar) and a density at 50 "C not lower than 0.485 kgll; Mixture B1 have a vapour pressure at 70 "C not exceeding 2.6 MPa (26 bar) and a relative density at 50 "C not lower than 0.474 kgll; Mixture B2 have a vapour pressure at 70 OC not exceeding 2.6 MPa (26 bar) and a relative density at 50 "C not lower than 0.463 kgll; Mixture B, have a vapour pressure at 70 "C not exceeding 2.6 MPa (26 bar) and a density at 50 "C not lower than 0.450 kgll; Mixture C, have a vapour pressure at 70 "C not exceeding 3.1 MPa (3 1 bar) and a relative density at 50 'C not lower than 0.440 kgll; NOTE 1: In the case of the foregoing mixtures, the use of the following names customary in the trade is permitted for describing these substances: for mixture AOI, A02 and AO: BUTANE; for mixture C: PROPANE. NOTE 2: UN No. 1075 PETROLEUM GASES, LIQUEFIED may be used as an alternative entry for UN No. 1965 HYDROCARBON GAS MLWURE LIQUEFIED, N.O.S. for carriage prior to or following maritime or air carriage.

3161

INSECTICIDE GAS, FLAMMABLE, N.O.S. LIQUEFIED GAS, FLAMMABLE, N.O.S.

- 48 -

I Classification

Liquefied gases (cont'd) UN No 1967 3 162 3355 3 l60 3308 3307 3309 33 10

code 2T 2 TF 2 TC 2 TO 2 TFC 2 TOC

Name and description

INSECTICIDE GAS, TOXIC, N.O.S. LIQUEFIED GAS, TOXIC, N.O.S. INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S.

Refrigerated liquefied gases Classification code 3A 30 3F

UN No 3 158 33 1 1 33 12

Classification code 4

UN No

Name and description

GAS, REFRIGERATED LIQUID, N.O.S. GAS, REFRIGERATED LIQUID, OXIDIZING, N-0.S. GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S.

I

Dissolved ~ a s e s Name and description

Only substances listed in Table A of Chapter 3.2 are to be accepted for carriage.

Aerosols and receptacles, small, containing gas Classification

UN No 1950 2037

code

5

Name and description

AEROSOLS RECEPTACLES, SMALL CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable

Other articles containing gas under pressure UN No 2857

Classification code 6A

3 164 3 164 3 150 3150

6F

Name and description

REFRIGERATING MACHINES containing non-flammable, non-toxic gases or ammonia solutions (UN 2672) ARTICLES, PRESSURIZED, PNEUMATIC (containing non-flammable gas) or ARTICLES, PRESSURIZED, HYDRAULIC (containing non-flammable gas) DEVICES, SMALL, HYDROCARBON GAS POWERED or HYDROCARBON GAS REFILLS FOR SMALL DEVICES, with release device

~~-

Gas samples

1

Classification code 7F

UN No 3 167

7T 7 TF

3 169 3 168

1

1

Name and description

GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S., not refrigerated liquid GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid

- 49 -

I

2.2.3

Class 3 Flammable liquids

2.2.3.1

Criteria

2.2.3.1.1

The heading of Class 3 covers substances and articles containing substances of this Class which: -

are liquids according to subparagraph (a) of the definition for "liquid" in 1.2.1;

-

have at 50 "C a vapour pressure of not more than 300 kPa (3 bar) and are not completely gaseous at 20 "C and at standard pressure of 101.3 kPa; and

-

have a flash-point of not more than 60 "C (see 2.3.3.1 for the relevant test).

The heading of Class 3 also covers liquid substances and molten solid substances with a flash-point of more than 60°C and which are carried or handed over for carriage whilst heated at temperatures equal to or higher than their flash-point. These substances are assigned to UN No. 3256. The heading of Class 3 also covers liquid desensitized explosives. Liquid desensitized explosives are explosive substances which are dissolved or suspended in water or other liquid substances, to form an homogeneous liquid mixture to suppress their explosive properties. Such entries in Table A of Chapter 3.2 are UN Nos. 1204, 2059, 3064, 3343, 3357 and 3379. For the purpose of carriage in tank vessels, the heading of Class 3 also covers the following substances which: -

have a flash-point above 60" C and which are carried or handed over for carriage at a temperature within a range of 15 K below the flash-point;

-

have an auto-ignition temperature of 200" C or below and which are not mentioned elsewhere.

NOTE l : Substances having aflash-point above 35 "C, non-toxic and non-corrosive, which, do not sustain combustion according to the criteria of 32.2.5 of Part 111 of the Manual of Tests and Criteria are not substances of Class 3; if; however, these substances are handed over for carriage and carried whilst heated at temperatures equal to or higher than their $ash-point, they are substances of Class 3. NOTE 2: By derogation from paragraph 2.2.3.1.1 above, diesel fuel, gasoil, heating oil (light) having a flash-point above 60 "C and not more than 100 'C shall be deemed substances of Class 3, UN No. 1202. NOTE 3: Liquids which are highly toxic on inhalation, having a flash-point below 23 "C and toxic substances, having a $ash-point of 23 "C or above are substances of Class 6.1 (see 2.2.61.1). NOTE 4: Flammable liquid substances and preparations used as pesticides, which are highly toxic, toxic or slightly toxic and have aflash-point of 23 "C or above are substances of Class 6.1 (see 2.2.61.1). NOTE 5: For the purpose of carriage in tank vessels, substances having a flash-point above 60' C and not more than 100" C are substances of Class 9 (identification number 9003).

2.2.3.1.2

The substances and articles of Class 3 are subdivided as follows: F

Flammable liquids, without subsidiary risk: F1 F2 F3 F4

FT

Flammable liquids having a flash-point of or below 60 "C; Flanunable liquids having a flash-point above 60 "C which are carried or handed over for carriage at or above their flash-point (elevated temperature substances); Substances having a flash-point above 60" C which are carried or handed over for carriage at a temperature within a range of 15 K below the flash-point; Substances having an auto-ignition temperature of 200" C or below and which are not mentioned elsewhere.

Flammable liquids, toxic: FT1 Flammable liquids, toxic; FT2 Pesticides;

FC

Flammable liquids, corrosive;

FTC Flammable liquids, toxic, corrosive;

D 2.2.3.1.3

Liquid desensitized explosives.

Substances and articles classified in Class 3 are listed in Table A of Chapter 3.2. Substances not mentioned by name in Table A of Chapter 3.2 shall be assigned to the relevant entry of 2.2.3.3 and the relevant packing group in accordance with the provisions of this section. Flammable liquids shall be assigned to one of the following packing groups according to the degree of danger they present for carriage:

"

See also 2.2.3.1.4

For a liquid with (a) subsidiary risk(s), the packing group determined in accordance with the table above and the packing group based on the severity of the subsidiary risk(s) shall be considered; the classification and packing group shall then be determined in accordance with the table of precedence of hazards in 2.1.3.10. 2.2.3.1.4

Liquid or viscous mixtures and preparations, including those containing no more than 20% nitrocellulose with a nitrogen content not exceeding 12.6% (by dry mass), shall be assigned to packing group I11 only if the following requirements are met: (a)

the height of the separated layer of solvent is less than 3 % of the total height of the sample in the solvent-separation test (see Manual of Tests and Criteria, Part 111, subsection 32.5.1); and

(b)

the viscosityZand flash-point are in accordance with the following table:

Viscositv determination: Where the substance concerned is non-Newtonian, or where a flow cup method of viscosity determination is otherwise unsuitable, a variable shear-rate viscometer shall be used to determine the dynamic viscosity coefJicient of the substance, at 23 "C, at a number of shear rates. The values obtained are plotted against shear rate and then extrapolated to zero shear rate. The dynamic viscosity thus obtained, divided by the density, gives the apparent kinematic viscosity at near-zero shear rate. - 51 -

Kinematic viscosity (extrapolated) v (at near-zero shear rate) mm2/sat 23 "C 20 80 135 220 300 700

< v l 80
Flow time t in accordance with I S 0 243 1:1993 Jet diameter in mm ins 4 20
above 17 above 10 above 5 above - 1 above -5 -5 and below

NOTE: Mixtures containing more than 20% but not more than 55% nitrocellulose with a nitrogen content not exceeding 12.6% by dry mass are substances assigned to UN No. 2059. Mixtures having aflash-point below 23 "C and containing: -

more than 55 % nitrocellulose, whatever their nitrogen content; or

-

not more than 55 % nitrocellulose with a nitrogen content above 12.6 % by dry mass,

are substances of Class l (UN Nos. 0340 or 0342) or of Class 4.1 (UN Nos. 2555, 2556 or 2557).

2.2.3.1.5

2.2.3.1.6

Non-toxic and non-corrosive solutions and homogeneous mixtures having a flash-point of 23 "C or above (viscous substances, such as paints or varnishes, excluding substances containing more than 20 %nitrocellulose) packed in receptacles of less than 450 litres capacity, are not subject to ADN if, in the solvent-separation test (see Manual of Tests and Criteria, Part 111, sub-section 32.5.1), the height of the separated layer of solvent is less than 3 % of the total height, and if the substances at 23 "C have, in the flow cup conforming to I S 0 243 1:1993 having a jet 6 mm in diameter, a flow time of: (a)

not less than 60 seconds, or

(b)

not less than 40 seconds and contain not more than 60 % of substances of Class 3.

If substances of Class 3, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes) see also 2.1.3.

2.2.3.1.7

On the basis of the test procedures in accordance with 2.3.3.1 and 2.3.4, and the criteria set out in 2.2.3.1.1, it may also be determined whether the nature of a solution or a mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the provisions for this Class (see also 2.1.3).

2.2.3.2

Substances not acceptedfor carriage

2.2.3.2.1

Substances of Class 3 which are liable to form peroxides easily (as happens with ethers or with certain heterocyclic oxygenated substances) shall not be accepted for carriage if their peroxide content, calculated as hydrogen peroxide (H202), exceeds 0.3%. The peroxide content shall be determined as indicated in 2.3.3.2.

2.2.3.2.2

The chemically unstable substances of Class 3 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall be ensured in particular that receptacles and tanks do not contain any substance liable to promote these reactions.

2.2.3.2.3

Liquid desensitized explosives other than those listed in Table A of Chapter 3.2 shall not be accepted for carriage as substances of Class 3.

List of collective entries 1133 ADHESIVES containing flammable liquid COAL TAR DISTILLATES, FLAMMABLE COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle undercoating. drum or barrel lining) EXTRACTS, AROMATIC. LIQUID EXTRACTS. FLAVOURING, LIQUID PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink tlhning or reducing compound), flammable PAINT (including paint. lacquer. enamel, stain. shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) PERFUMERY PRODUCTS with flammable solvents TINCTURES, MEDICINAL WOOD PRESERVATIVES. LIQUID RESIN SOLUTION, flammable TARS. LIQUID, including road asphalt and oils, bitumen and cut backs ALCOHOLIC BEVERAGES POLYESTER RESIN KITS KETONES, LIQUID, N.O.S. PETROLEUM DISTILLATES. N.O.S. or PETROLEUM PRODUCTS, N.O.S. ALCOHOLS, N.O.S. ALDEHYDES, N.O.S. TERPENE HYDROCARBONS, N.O.S. ETHERS, N.O.S. ESTERS, N.O.S. HYDROCARBONS, LIQUID, N.O.S. MERCAPTANS. LIQUID, FLAMMABLE, N.O.S. or MERCAPTANS MIXTURE, LIQUID, FLAMMABLE, N.O.S. 1993 FLAMMABLE LIQUID, N.O.S.

Flammable iquids

Without ,ubsidiary .isk elevated temperature

F2

3256

ELEVATED TEMPERATURE LIQUID, FLAMMABLE. N.O.S., with flash-point above 60 "C. at or above its flash-point

9001

SUBSTANCES HAVING A FLASH-POINT ABOVE 60 'C carried or handed over for carriage at a TEMPERATURE WITHIN A RANGE OF 15 K BELOW THE FLASH-POINT

9002

SUBSTANCES WITH A SELF-IGNITION TEMPERATURE OF 200 "C AND BELOW. n.0.s. MERCAPTANS, LIQUID. FLAMMABLE, TOXIC. N.O.S. or MERCAPTAN MIXTURE. LIQUID, FLAMMABLE, TOXIC, N.O.S. ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. ISOCYANATES, FLAMMABLE. TOXIC. N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE. TOXIC, N.O.S. MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. NITRILES, FLAMMABLE, TOXIC, N.O.S. FLAMMABLE LIQUID, TOXIC. N.O.S.

(cont'd)

2.2.3.3

List of collective entries (cont'd) 2758

l Pesticide (f.pC23 'C)

m2

CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC ARSENICAL PESTICIDE, LIQUID. FLAMMABLE, TOXIC ORGANOCHLOLUNE PESTICIDE. LIQUID, FL-LE, TOXIC TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC SUBSTITUTED NTTROPHENOL PESTICIDE, LIQUID. FLAMMABLE, TOXIC BIPYRIDILIUM PESTICIDE. LIQUID, FLAMMABLE, TOXIC ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC ORGANOTM PESTICIDE. LIQUID, FLAMMABLE, TOXIC COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC PYRETHROID PESTICIDE, LIQUID, FLAMMABLE TOXIC 3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S. NOTE : The classification of a pesticide under an entw shall be effected on the basis of the active ingredient, of the physical state ofthe pesticide and any subsidiaiy risks it may exhibit.

PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer. enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or 3469 PAINT RELATED MATERIAL, FLAMMABLE. CORROSIVE (including paint thinning or reducing compound) 2733 AMINES, FLAMMABLE, CORROSIVE. N.O.S. or 2733 POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 2985 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. 3274 ALCOHOLATES SOLUTION, N.O.S., in alcohol 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 3469

Corrosive

FC

Toxic, corrosive

FTC

3286 3343

Liquid

FLAMMABLE LIQUTD, TOXIC, CORROSIVE, N.O.S.

NITROGLYCERIN MIXTURE. DESENSITIZED. LIQUID. FLAMMABLE, N.O.S. with not more than 30% nitroglycerin by mass 3357 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID. N.O.S. with not more than 30% nitroglycerin by mass 3379 DESENSITIZED EXPLOSIVE, LIQUID, N.O.S.

Flammable solids, self-reactive substance and solid desensitized explosives

2.2.41

Class 4.1

2.2.41.1

Criteria

2.2.4 1.1.1

The heading of Class 4.1 covers flammable substances and articles, desensitized explosives which are solids according to subparagraph (a) of the definition "solid" in 1.2.1 and self-reactive liquids or solids. The following are assigned to Class 4.1 :

2.2.41.1.2

-

readily flammable solid substances and articles (see paragraphs 2.2.41.1.3 to 2.2.41.1.8);

-

self-reactive solids or liquids (see paragraphs 2.2.4 1.1.9 to 2.2.4 1.1.17);

-

solid desensitized explosives (see 2.2.4 1.1.18);

-

substances related to self-reactive substances (see 2.2.4 1.1.19).

The substances and articles of Class 4.1 are subdivided as follows: Flammable solids, without subsidiary risk: F1 F2 F3

Organic; Organic, molten; Inorganic;

Flammable solids, oxidizing; Flammable solids, toxic: FT 1 Organic, toxic; FT2 Inorganic, toxic; Flammable solids, corrosive: FC l Organic, corrosive; FC2 Inorganic, corrosive; Solid desensitized explosives without subsidiary risk; Solid desensitized explosives, toxic; Self-reactive substances: SRI Not requiring temperature control; SR2 Requiring temperature control.

Flammable solids Definition and properties

2.2.41.1.3

Flammable solids are readily combustible solids and solids which may cause fire through friction. Readily conzbustible solids are powdered, granular, or pasty substances which are dangerous if they can be easily ignited by brief contact with an ignition source, such as a burning match, and if the flame spreads rapidly. The danger may come not only from the fire but also from toxic combustion products. Metal powders are especially dangerous because of the difficulty of extinguishing a fire since normal extinguishing agents such as carbon dioxide or water can increase the hazard.

Substances and articles classified as flammable solids of Class 4.1 are listed in Table A of Chapter 3.2. The assignment of organic substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of sub-section 2.2.41.3 in accordance with the provisions of Chapter 2.1 can be based on experience or on the results of the test procedures in accordance with Part 111, sub-section 33.2.1 of the Manual of Tests and Criteria. The assignment of inorganic substances not mentioned by name shall be based on the results of the test procedures in accordance with Part 111, sub-section 33.2.1 of the Manual of Tests and Criteria; experience shall also be taken into account when it leads to a more stringent assignment. 2.2.41.1.5

When substances not mentioned by name are assigned to one of the entries listed in 2.2.41.3 on the basis of the test procedures in accordance with the Manual of Tests and Criteria, Part 111, sub-section 33.2.1, the following criteria apply: (a)

With the exception of metal powders or powders of metal alloys, powdery, granular or pasty substances shall be classified as readily flammable substances of Class 4.1 if they can be easily ignited by brief contact with an ignition source (e.g. a burning match), or if, in the event of ignition, the flame spreads rapidly, the burning time is less than 45 seconds for a measured distance of 100 mm or the rate of burning is greater than 2.2 mmls.

(b)

Metal powders or powders of metal alloys shall be assigned to Class 4.1 if they can be ignited by a flame and the reaction spreads over the whole length of the sample in 10 minutes or less.

Solids which may cause fire through friction shall be classified in Class 4.1 by analogy with existing entries (e.g. matches) or in accordance with any appropriate special provision. 2.2.41.1.6

On the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part 111, Section 33.2.1 and the criteria set out in 2.2.41.1.4 and 2.2.41.1.5, it may also be determined whether the nature of a substance mentioned by name is such that the substance is not subject to the provisions for this Class.

2.2.41.1.7

If substances of Class 4.1, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classzjkation of solutions and mixtures (such as preparations and wastes), see also 2.1.3.

Assignment of packing groups 2.2.41.1 .8

Flammable solids classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I1 or 111 on the basis of test procedures of the Manual of Tests and Criteria, Part 111, sub-section 33.2.1, in accordance with the following criteria: (a)

Readily flammable solids which, when tested, have a burning time of less than 45 seconds over a measured distance of l00 mm shall be assigned to: Packing group 11: if the flame passes the wetted zone; Packing group 111: if the wetted zone stops the flame for at least four minutes;

(b)

Metal powders or powders of metal alloys shall be assigned to: Packing group 11: if, when tested, the reaction spreads over the whole length of the sample in five minutes or less; Packing group 111: if, when tested, the reaction spreads over the whole length of the sample in more than five minutes.

For solids which may cause fire through friction, the packing group shall be assigned by analogy with existing entries or in accordance with any special provision. Self-reactive substances Definitions 2.2.41.1.9

For the purposes of ADN, self-reactive substances are thermally unstable substances liable to undergo a strongly exothennic decomposition even without participation of oxygen (air). Substances are not considered to be self-reactive substances of Class 4.1, if: (a)

they are explosives according to the criteria of Class 1;

(b)

they are oxidizing substances according to the classification procedure for Class 5.1 (see 2.2.51.1) except that mixtures of oxidizing substances which contain 5.0% or more of combustible organic substances shall be subjected to the classification procedure defined in Note 2;

(c)

they are organic peroxides according to the criteria of Class 5.2 (see 2.2.52.1);

(d)

their heat of decomposition is less than 300 J/g; or

(e)

their self-accelerating decomposition temperature (SADT) (see NOTE 2 below) is greater than 75 "C for a 50 kg package.

NOTE l: The heat of decomposition can be determined using any internationally recognised method e.g. differential scanning calorimety and adiabatic calorimety.

NOTE 2: Mixtures of oxidizing substances meeting the criteria of Class 5.1 which contain 5.0% or more of combustible organic substances, which do not meet the criteria mentioned in (a), (c), (4 or (e) above, shall be subjected to the self-reactive substance classzjication procedure. A mixture showing the properties of a self-reactive substance, type B to F, shall be classzjied as a self-reactive substance of Class 4.1.

A mixture showing the properties of a self-reactive substance, type G, according to the principle given in 20.4.3 (g) of Part 11 of the Manual of Tests and Criteria shall be consideredfor classzjkation as a substance of Class 5.1 (see 2.2.51.1). NOTE 3: The self-accelerating decomposition temperature (SADT) is the lowest temperature at which self-accelerating decomposition may occur with a substance in the packaging as used during carriage. Requirements for the determination of the SADT are given in the Manual of Tests and Criteria, Part 11, Chapter 20 and section 28.4. NOTE 4: Any substance which shows the properties of a self-reactive substance shall be classzjied as such, even if this substance gives a positive test result according to 2.2.42.1.5 for inclusion in Class 4.2. Properties

The decomposition of self-reactive substances can be initiated by heat, contact with catalytic impurities (e.g. acids, heavy-metal compounds, bases), friction or impact. The rate of decomposition increases with temperature and varies with the substance. Decomposition, particularly if no ignition occurs, may result in the evolution of toxic gases or vapours. For certain self-reactive substances, the temperature shall be controlled. Some self-reactive substances may decompose explosively, particularly if confined. This characteristic may be modified by the addition of diluents or by the use of appropriate packagings. Certain selfreactive substances burn vigorously. Self-reactive substances are, for example, some compounds of the types listed below: aliphatic azo compounds (-C-N=N-C-); organic azides (-C-N3); diazonium salts (-CN,' Z-); N-nitroso compounds (-N-N=O); and aromatic sulphohydrazides(-SO2-NH-NH2). This list is not exhaustive and substances with other reactive groups and some mixtures of substances may have similar properties.

Self-reactive substances are classified into seven types according to the degree of danger they present. The types of self-reactive substances range from type A, which is not accepted for carriage in the packaging in which it is tested, to type G, which is not subject to the provisions for self-reactive substances of Class 4.1. The classification of types B to F is directly related to the maximum quantity allowed in one packaging. The principles to be applied for classification as well as the applicable classification procedures, test methods and criteria and an example of a suitable test report are given in Part I1 of the Manual of Tests and Criteria. Self-reactive substances which have already been classified and are already permitted for carriage in packagings are listed in 2.2.41.4, those already permitted for carriage in IBCs are listed in 4.1.4.2 of ADR, packing instruction IBC520 and those already permitted for carriage in tanks according to Chapter 4.2 of ADR are listed in 4.2.5.2 of ADR, portable tank instruction T23. Each permitted substance listed is assigned to a generic entry of Table A of Chapter 3.2 (UN Nos. 322 1 to 3240), and appropriate subsidiary risks and remarks providing relevant transport information are given. The collective entries specify: -

self-reactive substances types B to F, see 2.2.4 1.1.11 above;

-

physical state (liquid/solid); and

-

temperature control (when required), see 2.2.4 1.1.17 below.

The classification of the self-reactive substances listed in 2.2.41.4 is based on the technically pure substance (except where a concentration of less than 100% is specified). 2.2.41.1.13

Classification of self-reactive substances not listed in 2.2.41.4, 4.1.4.2 of ADR, packing instruction IBC520 or 4.2.5.2 of ADR, portable tank instruction T23 and assignment to a collective entry shall be made by the competent authority of the country of origin on the basis of a test report. The statement of approval shall contain the classification and the relevant conditions of carriage. If the country of origin is not a Contracting Party to ADN, the classification and the conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADN reached by the consignment.

2.2.41.1.14

Activators, such as zinc compounds, may be added to some self-reactive substances to change their reactivity. Depending on both the type and the concentration of the activator, this may result in a decrease in thermal stability and a change in explosive properties. If either of these properties is altered, the new formulation shall be assessed in accordance with the classification procedure.

2.2.41.1.15

Samples of self-reactive substances or formulations of self-reactive substances not listed in 2.2.41.4, for which a complete set of test results is not available and which are to be carried for further testing or evaluation, shall be assigned to one of the appropriate entries for selfreactive substances type C provided the following conditions are met:

2.2.41.1.16

-

the available data indicate that the sample would be no more dangerous than selfreactive substances type B;

-

the sample is packaged in accordance with packing method 0 P 2 of 4.1.4.1 of ADR and the quantity per transport unit is limited to 10 kg;

-

the available data indicate that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation.

In order to ensure safety during carriage, self-reactive substances are in many cases desensitized by use of a diluent. Where a percentage of a substance is stipulated, this refers to the percentage by mass, rounded to the nearest whole number. If a diluent is used, the selfreactive substance shall be tested with the diluent present in the concentration and form used in carriage. Diluents which may allow a self-reactive substance to concentrate to a dangerous extent in the event of leakage from a packaging shall not be used. Any diluent shall be compatible with the self-reactive substance. In this regard, compatible diluents are those solids or liquids which have no detrimental influence on the thermal stability and hazard type of the self-reactive substance. Liquid diluents in formulations requiring temperature control (see 2.2.4 1.1.14) shall have a boiling point of at least 60 "C and a flash-point not less than 5 "C. The boiling point of the liquid shall be at least 50 "C higher than the control temperature of the self-reactive substance. Temperature control requirements

2.2.4 1.1.17

Certain self-reactive substances may only be carried under temperature controlled conditions. The control temperature is the maximum temperature at which the self-reactive

substance can be safely carried. It is assumed that the temperature of the immediate surroundings of a package only exceeds 55 "C during carriage for a relatively short time in a 24 hour period. In the event of loss of temperature control, it may be necessary to implement emergency procedures. The emergency temperature is the temperature at which such procedures shall be implemented. The control and emergency temperatures are derived from the SADT (see table 1). The SADT shall be determined in order to decide whether a substance shall be subjected to temperature control during carriage. Provisions for the determination of the SADT are given in the Manual of Tests and Criteria, Part 11, Chapter 20 and Section 28.4. Table 1 Type of receptacle

Single

packagings

Derivation of control and emergency temperatures SADT a

20 "C or less

Control temperature 20 "C below SADT

Emergency temperature 10 "C below SADT

over 20 "C to 35 "C

15 "C below SADT

10 "C below SADT

over 35 "C

10 "C below SADT

5 "C below SADT

not greater than 50 "C

10 "C below SADT

5 "C below SADT

J

Tanks a

SADT of the substance as packaged for carriage.

Self-reactive substances with an SADT not greater than 55 "C shall be subject to temperature control during carriage. Where applicable, control and emergency temperatures are listed in 2.2.41.4. The actual temperature during carriage may be lower than the control temperature but shall be selected so as to avoid dangerous separation of phases. Solid desensitized explosives 2.2.41.1.18

Solid desensitized explosives are substances which are wetted with water or alcohols or are diluted with other substances to suppress their explosive properties. Such entries in Table A of Chapter 3.2 are: UN Nos. 1310, 1320, 1321, 1322, 1336, 1337, 1344, 1347, 1348, 1349, 1354, 1355, 1356, 1357, 1517, 1571,2555,2556,2557,2852,2907,3317,3319,3344,3364, 3365,3366,3367,3368,3369,3370,3376 and 3380. Substances related to self-reactive substances

2.2.41.1.19

Substances that: (a)

have been provisionally accepted into Class 1 according to Test Series 1 and 2 but exempted from Class 1 by Test Series 6;

(b)

are not self-reactive substances of Class 4.1 ;and

(c)

are not substances of Classes 5.1 or 5.2

are also assigned to Class 4.1. UN Nos. 2956, 3241, 3242 and 3251 are such entries. 2.2.41.2

Substances not acceptedfor carriage

2.2.41.2.1

The chemically unstable substances of Class 4.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization - 61 -

during carriage. To this end, it shall in particular be ensured that receptacles and tanks do not contain any substance liable to promote these reactions. 2.2.41.2.2

Flammable solids, oxidizing, assigned to UN No. 3097 shall not be accepted for carriage unless they meet the requirements for Class 1 (see also 2.1.3.7).

2.2.41.2.3

The following substances shall not be accepted for carriage:

-

Self-reactive substances of type A (see Manual of Tests and Criteria, Part 11, paragraph 20.4.2 (a));

-

Phosphorus sulphides which are not free from yellow and white phosphorus;

-

Solid densitized explosives other than those listed in Table A of Chapter 3.2;

-

Lnorganic flammable substances in the molten form other than UN No. 2448 SULPHUR, MOLTEN;

-

Barium azide with a water content less than 50% (mass).

List of collective entries

2.2.41.3

3175 SOLIDS CONTAINING FLAMMABLE LIQUID, N O.S. 1353 FIBRES IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. or 1353 FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 1325 FLAMMABLE SOLID, ORGANIC, N.O.S.

r rganic

F1

rganic

1

3 l76 FLAMMABLE SOLID, ORGANIC, MOLTEN. N.O. S.

ubsidiary

3089 3 181 3182 - 3178

b , 1

lammable )lids xidizin

1 corrosive

F0

organic

H i n o r g a n i c

3097 FLAMMABLE SOLID, OXIDIZING, N.O.S. (not allowed, see Para. 2.2.41.2.2)

FC1

1 2926 1 31 79 1 2925

FC?

1

D iolid lesen-

LI !X

1

FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. FLAMMAE3I.E SOLID, TOXIC. INORGANIC, N O S FLA'M.MAB1.E SOLID, CORROSI\'E. OKGAhIC, K 0 S

I

3180 FLAMMAB1.E SOLID. COKROSIVE. INORGAN[C. N.0.S 3319 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin by mass 3344 PENTAERYTHRITE TETRANITRATE MIXTURE, DESENSITIZED. SOLID, N.O.S. with more than 10% but not more than 20% PETN by mass 3380 DESENSITIZED EXPLOSIVE, SOLID, N.O.S.

losives

Selfreactive substance SR

toxic

DT

not requiring temperature control

SRI

Only those listed in Table A of Chapter 3.2 are to be accepted for carriage as substances of Class 4.1

SELF-REACTIVE SOLID TYPE G

I

requiring temperature

a

METAL POWDER, FLAMMABLE, N.O.S. a METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. METAL HYDRIDES, FLAMMABLE.N.0.S. c FLAMMABLE SOLID, INORGANIC, N.O.S.

3231 3232 3233 3234 3235 3236 3237 3238 3239 3240

1

Class 4.1, see 2.2.41.1 11

SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED

Metals and metal alloys in powdered or other flammable form, liable to spontaneous combustion, are substances of Class 4.2. Metals and metal alloys in powdered or other jlammable form, which in contact with water, emit flammable gases, are substances of Class 4.3. Metals hydrides which, in contact with water, emit flammable gases, are substances of Class 4.3. Aluminium borohydride or aluminium borohydride in devices are substances of Class 4.2, UN No. 2870. - 63 -

2.2.41.4

List of currently assigned self-reactive substances in packagings

In the column "Packing Method" codes "OP1" to "OP8" refer to packing methods in 4.1.4.1 of ADR, packing instruction P520 (see also 4.1.7.1 of ADR). Self-reactive substances to be carried shall hlfil the classification and the control and emergency temperatures (derived from the SADT) as listed. For substances permitted in IBCs, see 4.1.4.2 of ADR, packing instruction IBC520 and, for those permitted in tanks according Chapter 4.2 of ADR, see 4.2.5.2 of ADR, portable tank instruction T23.

NOTE: The classzj?cation given in this table is based on the technically pure substance (except where a concentration of less than 100 % is specified). For other concentrations, the substance may be classzfied differentlyfollowing the procedures given in Part II of the Manual of Tests and Criteria and in 2.2.41.1.17.

SELF-REACTIVE SUBSTANCE

Concentration (%)

Packing method

Control temperature ("C)

Emergency temperature ("C)

UN generic entry

ACETONE-PYROGALLOL COPOLYMEE 100 2-DIAZO- l-NAPHTHOL-5-SULPHONATE

OP8

3228

AZODICARBONAMIDE FORMULATION TYPE B, TEMPERATURE CONTROLLED

< 100

OP5

3232

AZODICARBONAMIDE FORMULATION TYPE C

< 100

OP6

3224

AZODICARBONAMIDE FORMULATION TYPE C, TEMPERATURE CONTROLLED

< 100

OP6

3234

AZODICARBONAMIDE FORMULATION TYPE D

< 100

OP7

3226

AZODICARBONAMIDE FORMULATION TYPE D, TEMPERATURE CONTROLLED

< 100

OP7

3236

2.2' -AZODI(2,4-DIMETHYL4-METHOXYVALERONITRILE)

100

OP7

15

3236

2,2' -AZODI(2,4-DIMETHYLVALERONITRILE)

100

OP7

F15

3236

2,2' -AZODI(ETHYL2-METHYLPROPIONATE)

100

OP7

125

3235

1.1-AZODI(HEXAHYDROBENZ0NITRlLE)100

0P7

2.2' -AZODI(ISOBUTYRONITRILE

100

OP6

2,2' -AZODI(ISOBUTYROMTRlLE) as a water based paste

5 50

OP6

2,2' -AZODI(2-METHYLBUTYR0NITRILE)

100

OP7

BENZENE- 13-DISULPHONYL KYDRAZIDE, as a paste

52

OP7

3226

BENZENE SULPHONYL HYDRAZIDE

100

OP7

3226

t-(BENZYL(ETHYL)AMINO)-3-ETHOXY- 100

OP7

3226

3226 -45

3234 3224

-40

3236

BENZENEDIAZONIUM ZINC CHLORIDE

I-(BENZYL(METFIYL)AMINO)-3-

100

OP7

3-CHLORO-4-DIETmAMINOBENE- 100 DIAZONIUM ZINC CHLORIDE

OP7

-45

3236

ETHOXYBENZENEDIAZONIUM ZINC CHLORtDE

- 64 -

3226

Remarks

2.2.41.4

List of currently assigned self-reactive substances in packagings fcont '4

SELF-REACTIVE SUBSTANCE 2-DIAZO- 1-NAPHTHOL-4-SULPHONYL CHLORIDE

ConcenControl Emergency UN generic Packing tration temperature temperature entry method ("C) ("C) (Yo) 3222 100 OP5

Remarks 2)

OP5

3222

2)

2-DIAZO-I-NAPHTHOL SULPHONIC ACID < 100 ESTER MIXTURE, TYPE D

OP7

3226

9)

2,5-DIBUTOXY-4-(4-MORPH0LINYL)- 100

OP8

3228

67-100

OP7

3236

66

OP7

3236

100

OP7

3236

2.5-DIETHOXY-4-(4-MORPH0LINYL)- 100

OP7

3226

OP7

3236

OP8

3237

79

OP7

3236

100

OP8

3228

I-DIMETHYLAMINO-6-(2-DIMETHYL- 100

OP7

3236

72

OP6

3224

82

OP6

3224

100

OP7

3226

IDIPROPYLAMINOBENZENEDIAZONIUM ZINC CHLORIDE

100

OP7

3226

2-(N,N-ETHOXYCARBONYL-

63-92

OP7

3236

62

OP7

3236

2-DIAZO-l-NAPHTHOL-5-SULPHONYL CHLORlDE

100

BENZENEDIAZONIUM, TETRACHLOROZINCATE (2: 1)

2.5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE

2.5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE

2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM TETRAFLUOROBORATE BENZENEDIAZONKJM SULPHATE

2,5-DIETHOXY-4-(PHENYLSULPH0NYL)-67 BENZENEDIAZONIUM ZINC CHLORIDE DIETHYLENEGLYCOL BIS (ALLYL CARBONATE) + DI-

ISOPROPYLPEROXYDICARBONATE 2,5-DIMETHOXY-4-(4-METHYLPHENYLSULPH0NYL)BENZENE-

2 88 +

I12

DIAZONIUM ZINC CHLORIDE 4-(DIMETHYLAMIN0)BENZENEDIAZONIUM

AMINOETHOXY) TOLUENE2-DIAZONIUM ZINC CHLORIDE N,N'-DINITROSO-N,N- DIMETHYL TEREPHTHALAMIDE. as a paste

DIPHENYLOXIDE-4,4'-DISULPHONYL HYDRAZIDE

PHENYLAMIN0)-3-METHOXY-4(N-METHYL-N-CYCLOHEXYLAMINO) BENZENEDIAZONIUM ZINC CHLORIDE 2-(N,N-ETHOXYCARBONYLPHENYLMN0)-3-METHOXY-4(N-METHYL-N-CYCLOHEXYLAMINO) BENZENEDIAZONIUM ZINC CHLORIDE

- 65 -

7)

2.2.41.4

1

List of currently assigned self-reactive substances in packagings (cont'd)

SELF-REACTIVE SUBSTANCE

2-(2-HYDROXYETH0XY)-1(PYRROLIDIN-1-YL)BENZENE-4DIAZONIUM ZINC CHLORIDE

Concentration ("h) LOO

Control temperature

Emergency UN generic temperature entry ("C) t50 3236

100

t 50

3236

100

t45

3236

>6

t50

3236

Remarks

(PYRROLIDIN-1-YL)BENZENE DIAZONIUM ZINC CHLORIDE

2-(N,N-METHYLAMINOETHYLCARB0NYL)-4-(3.4-DIMETHYLPHENYLSULPH0NYL)BENZENEDIAZONIUM HYDROGEN SULPHATE

4-METHYLBENZENESULPHONYL-

LOO

3226

HYDRAZIDE

3-METHYL-4-(PYRROLIDIN-l-YL)

)5

k50

3234

L 00

k40

3236

BENZENEDIAZONIUM TETRAFLUOROBORATE

/

4-NITROSOPHENOL SELF-REACTIVE LIQUID. SAMPLE

3223

SELF-REACTIVE LIQUID, SAMPLE, TEMPERATURE CONTROLLED

3233

I SELF-REACTIVE SOLID, SAMPLE

3224 3234

SELF-REACTIVE SOLID, SAMPLE, TEMPERATURE CONTROLLED SODIUM 2-DIAZO-I -NAPHTHOL4-SULPHONATE

LOO

3226

SODIUM 2-DIAZO- 1-NAPHTHOL5-SULPHONATE

LOO

3226

LOO

k35

3234

Remarks

Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (b) of the Manual of Tests and Criteria. The control and emergency temperatures shall be determined by the procedure given in 2.2.41.1.17.

"EXPLOSIVE" subsidiary risk label required (Model No. l , see 5.2.2.2.2). Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (c) of the Manual of Tests and Criteria. Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (c) of the Manual of Tests and Criteria. The control and emergency temperatures shall be determined by the procedure given in 2.2.4 1.1.17. Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (d) of the Manual of Tests and Criteria. Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (d) of the Manual of Tests and Criteria. The control and emergency temperatures shall be determined by the procedure given in 2.2.41.1.17.

(7)

With a compatible diluent having a boiling point of not less than 150 "C.

(8)

See 2.2.4 1.1.15.

(9)

This entry applies to mixtures of esters of 2-diazo- l-naphthol-4-sulphonic acid and 2-diazo-l-naphthol-5-sulphonic acid which fulfil the criteria of paragraph 20.4.2 (d) of the Manual of Test and Criteria.

2.2.42

Class 4.2

Substances liable to spontaneous combustion

Criteria The heading of Class 4.2 covers: -

Pyrophoric substances which are substances, including mixtures and solutions (liquid or solid), which even in small quantities ignite on contact with air within five minutes. These are the Class 4.2 substances the most liable to spontaneous combustion; and

-

Self-heating substances and articles which are substances and articles, including mixtures and solutions, which, on contact with air, without energy supply, are liable to self-heating. These substances will ignite only in large amounts (kilogrammes) and after long periods of time (hours or days).

The substances and articles of Class 4.2 are subdivided as follows: Substances liable to spontaneous combustion, without subsidiary risk: S1 S2 S3 S4 S5

Organic, liquid; Organic, solid; Inorganic, liquid; Inorganic, solid; Organometallic;

Substances liable to spontaneous combustion, which, in contact with water, emit flammable gases; Substances liable to spontaneous combustion, oxidizing; Substances liable to spontaneous combustion, toxic: STI ST2 ST3 ST4

Organic, toxic, liquid; Organic, toxic, solid; Inorganic, toxic, liquid; Inorganic, toxic, solid;

Substances liable to spontaneous combustion, corrosive: SC 1 SC2 SC3 SC4

Organic, corrosive, liquid; Organic, corrosive, solid; Inorganic, corrosive, liquid; Inorganic, corrosive, solid.

Properties

2.2.42.1.3

Self-heating of these substances, leading to spontaneous combustion, is caused by reaction of the substance with oxygen (in the air) and the heat developed not being conducted away rapidly enough to the surroundings. Spontaneous combustion occurs when the rate of heat production exceeds the rate of heat loss and the auto-ignition temperature is reached.

Classification

2.2.42.1.4

Substances and articles classified in Class 4.2 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant specific N.O.S. entry of 2.2.42.3 in accordance with the provisions of Chapter 2.1 can be based on experience or the results of the test procedures in accordance with the Manual of Tests and Criteria, Part 111, Section 33.3. Assignment to general N.O.S. entries of Class 4.2 shall be based on the results of the test procedures in accordance with the Manual of Tests and Criteria, Part 111, section 33.3; experience shall also be taken into account when it leads to a more stringent assignment.

2.2.42.1.5

When substances or articles not mentioned by name are assigned to one of the entries listed in 2.2.42.3 on the basis of the test procedures in accordance with the Manual of Tests and Criteria, Part 111, section 33.3, the following criteria shall apply: Solids liable to spontaneous combustion (pyrophoric) shall be assigned to Class 4.2 when they ignite on falling fi-om a height of 1 m or within five minutes; Liquids liable to spontaneous combustion (pyrophoric) shall be assigned to Class 4.2 when: (i)

on being poured on an inert carrier, they ignite within five minutes, or

(ii)

in the event of a negative result of the test according to (i), when poured on a dry, indented filter paper (Whatman No. 3 filter), they ignite or carbonize it within five minutes;

Substances in which, in a 10 cm sample cube, at 140 'C test temperature, spontaneous combustion or a rise in temperature to over 200 "C is observed within 24 hours shall be assigned to Class 4.2. This criterion is based on the temperature of the spontaneous combustion of charcoal, which is at 50 "C for a sample cube of 27 m3. Substances with a temperature of spontaneous combustion higher than 50 "C for a volume of 27 m3 are not to be assigned to Class 4.2. NOTE I : Substances carried in packages with a volume of not more than 3 rn3 are exempted j?om Class 4.2 iJ; tested with a 10 cm sample cube at 120 "C, no spontaneous combustion nor a rise in temperature to over 180 OC is observed within 24 hours. NOTE 2: Substances carried in packages with a volunie of not more than 450 litres are exempted from Class 4.2 iJ; tested with a 10 cm sample cube at l00 "C, no spontaneous combustion nor a rise in temperature to over 160 "C is observed within 24 hours. NOTE 3: Since organometallic substances can be classified in Class 4.2 or 4.3 with additional subsidiary risks, depending on their properties, a speczjic classzJication jlow chart for these substances is given in 2.3.6.

.42.1.6

If substances of Class 4.2, as a result of admixtures, come into different categories of risk fi-om those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3.

2.2.42.1.7

On the basis of the test procedure in the Manual of Tests and Criteria, Part 111, section 33.3 and the criteria set out in 2.2.42.1.5, it may also be determined whether the nature of a substance mentioned by name is such that the substance is not subject to the provisions for this Class. Assignment of packing groups

2.2.42.1.8

2.2.42.2

Substances and articles classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, I1 or 111 on the basis of test procedures of the Manual of Tests and Criteria, Part 111, section 33.3, in accordance with the following criteria: (a)

Substances liable to spontaneous combustion (pyrophoric) shall be assigned to packing group I;

(b)

Self-heating substances and articles in which, in a 2.5 cm sample cube, at 140 'C test temperature, spontaneous combustion or a rise in temperature to over 200 'C is observed within 24 hours, shall be assigned to packing group 11; Substances with a temperature of spontaneous combustion higher than 50 "C for a volume of 450 litres are not to be assigned to packing group 11;

(c)

Slightly self-heating substances in which, in a 2.5 cm sample cube, the phenomena referred to under (b) are not observed, in the given conditions, but in which in a 10 cm sample cube at 140 'C test temperature spontaneous combustion or a rise in temperature to over 200 "C is observed within 24 hours, shall be assigned to packing group 111.

Substances not accepted for carriage The following substances shall not be accepted for carriage:

-

UN No. 3255 tert-BUTYL HYPOCHLORITE; and

-

Self-heating solids, oxidizing, assigned to UN No. 3127 unless they meet the requirements for Class 1 (see 2.1.3.7).

2.2.42.3

List of collective entries

Substances liable to spontaneous combustion

l

2845 3183

PYROPHORIC LIQUID. ORGANIC, N.O.S. SELF-HEATING LIOUTD. ORGANIC. N.O.S.

1373

FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC, N.O.S. with oil PLASTICS, NITROCELLULOSE-BASED. SELF-HEATING, N.O.S. ORGANIC PIGMENTS, SELF HEATING

organic

L

S2

solid

Without subsidiary isk

r liquid

7 nor anic

1 solid

organometallic

2006 33 13 2846 3088

PYROPHORK SOLID, ORGANIC. N.O.S. SELF-HEATING SOLID. ORGANIC, N.O.S.

S3

3 194 3 186

PYROPHORIC LIQUID, INORGANIC, N.O.S. SELF-HEATING LIQUID, INORGANIC, N.O.S.

S4

1383 1383 1378 288 1 3189~ 3205 3200 3190

PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. METAL CATALYST, WETTED with a visible excess of liquid METAL CATALYST, DRY METAL POWDER, SELF-HEATING, N.O.S. ALKALINE EARTH METAL ALCOHOLATES, N.O.S. PYROPHORIC SOLID, INORGANIC, N.O.S. SELF-HEATJNG SOLID, INORGANIC, N.O.S.

3392 3391

ORGANOMETALLIC SUBSTANCE, LIQUID. PYROPHORIC ORGANOMETALLIC SUBSTANCE. SOLID, PYROPHORIC

1 3400

ORGANOMETALLIC SUBSTANCE, SOLID, SELF-HEATING

SS

3394 3393

I

ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC. WATER-REACTIVE --

3127

13184

l

Organic

I l

inorganic

l

solid

ST2 [3128

v

SELF-HEATING see 2.2.42.2)

SOLID, OXIDIZING, N.O.S. (not allowed,

SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S.

ST3 [3l87

SELFHEATING LIQUID. TOXIC. INORGANIC, N.O.S.

solid

ST4 13191

SELF-HEATING SOLID. TOXIC. INORGANIC, N.O.S.

liquid

SC1 [3 185

SELF-HEATING LIQUID, CORROSIVE, ORGANIC. N.O.S.

solid

SC2 13126

SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S.

liquid

SC3 13188

SELF-HEATING LIQUID. CORROSIVE. INORGANIC. N.O.S.

solid

SC4

organic :orrosive iC

1

I I

inorganic

3206 3192

a

ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S.

Dust and powder of metals, non toxic in a non-spontaneous combustible form which nevertheless, in contact with water, emit flammable gases, are substances of Class 4.3. - 71 -

2.2.43

Class 4.3

Substances which, in contact with water, emit flammable gases

2.2.43.1

Criteria

2.2.43.1.1

The heading of Class 4.3 covers substances which react with water to emit flammable gases liable to form explosive mixtures with air, and articles containing such substances.

2.2.43.1.2

Substances and articles of Class 4.3 are subdivided as follows: Substances which, in contact with water, emit flammable gases, without subsidiary risk, and articles containing such substances: W1 W2 W3

Liquid; Solid; Articles;

Substances which, in contact with water, emit flammable gases, liquid, flammable; Substances which, in contact with water, emit flammable gases, solid, flammable; Substances which, in contact with water, emit flammable gases, solid, self-heating; Substances which, in contact with water, emit flammable gases, oxidizing, solid; Substances which, in contact with water, emit flammable gases, toxic: WTI Liquid; WT2 Solid; Substances which, in contact with water, emit flammable gases, corrosive: WC1 Liquid; WC2 Solid; W C Substances which, in contact with water, emit flammable gases, flammable, corrosive. Properties

2.2.43.1.3

Certain substances in contact with water may emit flammable gases that can form explosive mixtures with air. Such mixtures are easily ignited by all ordinary sources of ignition, for example naked lights, sparking handtools or unprotected light bulbs. The resulting blast wave and flames may endanger people and the environment. The test method referred to in 2.2.43.1.4 below is used to determine whether the reaction of a substance with water leads to the development of a dangerous amount of gases which may be flammable. This test method shall not be applied to pyrophoric substances. Classzjkation

2.2.43.1.4

Substances and articles classified in Class 4.3 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of 2.2.43.3 in accordance with the provisions of Chapter 2.1 shall be based on the results of the test procedure in accordance with the Manual of Tests and Criteria, Part 111, Section 33.4; experience shall also be taken into account when it leads to a more stringent assignment.

When substances not mentioned by name are assigned to one of the entries listed in 2.2.43.3 on the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part 111, Section 33.4, the following criteria shall apply: A substance shall be assigned to Class 4.3 if:

(a)

spontaneous ignition of the gas emitted takes place in any step of the test procedure; or

(b)

there is an evolution of flammable gas at a rate greater than 1 litre per kilogram of the substance to be tested per hour.

NOTE: Since organometallic substances can be classiJied in Classes 4.2 or 4.3 with additional subsidiary risks, depending on their properties, a speczjk class ijkation flow chart for these substances is given in 2.3.6.

If substances of Class 4.3, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classtjkation of solutions and mixtures (such as preparations and wastes) see also 2.1.3.

On the basis of the test procedures in accordance with the Manual of Tests and Criteria, Part 111, Section 33.4, and the criteria set out in paragraph 2.2.43.1.5, it may also be determined whether the nature of a substance mentioned by name is such that the substance is not subject to the provisions for this Class. Assignment of packing groups

Substances and articles classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, I1 or I11 on the basis of test procedures of the Manual of Tests and Criteria, Part 111, section 33.4, in accordance with the following criteria: Packing group I shall be assigned to any substance which reacts vigorously with water at ambient temperature and generally demonstrates a tendency for the gas produced to ignite spontaneously, or one which reacts readily with water at ambient temperatures such that the rate of evolution of flammable gas is equal to or greater than 10 litres per kilogram of substance over any one minute period; Packing group I1 shall be assigned to any substance which reacts readily with water at ambient temperature such that the maximum rate of evolution of flammable gas is equal to or greater than 20 litres per kilogram of substance per hour, and which does not meet the criteria of packing group I; Packing group I11 shall be assigned to any substance which reacts slowly with water at ambient temperature such that the maximum rate of evolution of flammable gas is greater than 1 litre per kilogram of substance per hour, and which does not meet the criteria of packing groups I or 11.

2.2.43.2

Substances not acceptedfor carriage

Water-reactive solids, flammable, assigned to UN No. 3 132, water-reactive solids, oxidizing, assigned to UN No. 3133 and water-reactive solids, self-heating, assigned to UN No.3135 shall not be accepted for carriage unless they meet the requirements for Class l (see also 2.1.3.7).

2.2.43.3

List of collective entries

iubstances which, in ontact with water, emit lammable gases

r Without subsidiary risk

liquid

W1

solid

wza

articles

W3

W

iquid, flammable

ALKALI METAL AMALGAM, LIQUID ALKALI METAL DISPERSION having a flash-point above 60 "C or ALKALINE EARTH METAL DISPERSION having a flash-point above 60 "C ALKALINE EARTH METAL AMALGAM, LIQUID POTASSIUM METAL ALLOYS, LIQUID ALKALI METAL ALLOY, LIQUID. N.O.S. POTASSIUM SODIUM ALLOYS, LIQUID ORGANOMETALLIC SUBSTANCE. LIQUID, WATER-REACTIVE WATER-REACTIVE LIQUID, N.O.S.

1390 3401 3402 3 170 3 170 3403 3404 1393 1409 3208 3395 2813

ALKALI METAL AMlDES ALKALI METAL A M A L G M SOLID ALKALINE EARTH METAL AMALGAM, SOLID ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS POTASSIUM METAL ALLOYS. SOLID POTASSIUM SODIUM ALLOYS, SOLID ALKALINE EARTH METAL ALLOY, N 0 S METAL HYDRIDES, WATER-REACTIVE,N 0 S METALLIC SUBSTANCE, WATER-REACTIVE, N 0 S ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE WATER-REACTIVE SOLID, N 0 S

3292 BATTERIES, CONTAINING SODIUM or 3292 CELLS, CONTAINING SODIUM 13% ALKALI METAL DISPERSION having a flashpoint of not more than 60 "C or 1391 ALKALINE EARTH METAL DISPERSION having a flash-point of not more than 60 "C 3399 ORGANOMETALLIC SUBSTANCE. LIQUID, WATER-REACTIVE, FLAMMABLE

W1

Solid, flammable

1389 1391 1391 1392 1420 1421 1422 3398 3148

11

W 2

ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, 3396 FLAMMABLE 3132 WATER-REACTIVE SOLID. FLAMMABLE. N O S (not allowed. see 2.2.43.2)

I

I I

3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, SELFHEATING 3209 METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. 3135 WATER-REACTIVE SOLID, SELF-HEATING,N.O.S. (not allowed, see 2.2.43.2)

Solid, self-beating

ws

Solid, oxidizing

WO

1 3133

liquid

W

13130 WATER-REACTIVE LIQUID, TOXIC, N.O.S.

solid

W 2

1 3134

WATER-REACTIVE SOLID, TOXIC, N.O.S.

liquid

WC1

1 3129

WATER-REACTIVE LIQUID, CORROSIVE, N.O.S.

solid

WC2

13 131

WATER-REACTIVE SOLID, CORROSIVE, N.O.S.

1

WATER-REACTIVE SOLID, OXIDIZING, N.O.S. (not allowed, see 2.2.43.2)

roxic

W

Zorrosive WC

~lammable,corrosive

WC

c

1

2988 CHLOROSILANES, WATER-REACTIVE, FLAMMABLE. CORROSIVE, NOS. (No other collective entrv with this classification code available. if need be. classification Ader a collective entry with a classification code to be determined according to the table of precedence of hazard in 2.1.3.10.)

a

Metals and metal alloys which, in contact with water, do not emit flammable gases and are not pyrophoric or self-heating, but which are readily flammable, are substances of Class 4.1. Alkaline-earth metals and alkaline-earth metal alloys in pyrophoric form are substances of Class 4.2. Dust and powders of metals in pyrophoric form are substances of Class 4.2. Metals and metal alloys in pyrophoric form are substances of Class 4.2. Compounds of phosphorus with heavy metals such as iron, copper, etc. are not subject to the provisions of ADN. Metals and metal alloys in pyrophoric form are substances of Class 4.2. c Chlorosilanes, having aflash-point of less than 23 'C and which, in contact with water, do not emit flammable gases, are substances of Class 3. Chlorosilanes, having a flash-point equal to or greater than 23 "C and which, in contact with water, do not emit flammable gases, are substances of Class 8. - 75 -

2.2.51

Class 5.1 Oxidizing substances

2.2.5 1.1.1

The heading of Class 5.1 covers substances which, while in themselves not necessarily combustible, may, generally by yielding oxygen, cause or contribute to the combustion of other material, and articles containing such substances.

2.2.51.1.2

The substances of Class 5.1 and articles containing such substances are subdivided as follows:

0

Oxidizing substances without subsidiary risk or articles containing such substances: 01 02 03

Liquid; Solid; Articles;

OF

Oxidizing substances, solid, flammable;

OS

Oxidizing substances, solid, self-heating;

OW Oxidizing substances, solid which, in contact with water, emit flammable gases; OT

Oxidizing substances, toxic: OT1 Liquid; 0 T 2 Solid;

OC

Oxidizing substances, corrosive: OC1 Liquid; 0C2 Solid:

OTC Oxidizing substances, toxic, corrosive. 2.2.5 1.1.3

Substances and articles classified in Class 5.1 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of 2.2.5 1.3 in accordance with the provisions of Chapter 2.1 can be based on the tests, methods and criteria in paragraphs 2.2.51.1.6 to 2.2.51.1.9 below and the Manual of Tests and Criteria, Part 111, Section 34.4. In the event of divergence between test results and known experience, judgement based on known experience shall take precedence over test results.

2.2.5 1.1.4

If substances of Class 5.1, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classzjkation of solutions and mixtures (such as preparations and wastes), see also Section 2.1.3.

2.2.51.1.5

On the basis of the test procedures in the Manual of Tests and Criteria, Part 111, Section 34.4 and the criteria set out in 2.2.5 1.1.6-2.2.5 1.1.9 it may also be determined whether the nature of a substance mentioned by name in Table A of Chapter 3.2 is such that the substance is not subject to the provisions for this class.

Oxidizing solids ClassiJication

2.2.51.1.6

When oxidizing solid substances not mentioned by name in Table A of Chapter 3.2 are assigned to one of the entries listed in 2.2.51.3 on the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part 111, sub-section 34.4.1, the following criteria shall apply: A solid substance shall be assigned to Class 5.1 if, in the 4: 1 or the 1:1 sample-to-cellulose ratio (by mass) tested, it ignites or burns or exhibits mean burning times equal to or less than that of a 3:7 mixture (by mass) of potassium bromate and cellulose. Assignment of packing groups

2.2.51.1.7

Oxidizing solids classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, I1 or 111 on the basis of test procedures of the Manual of Tests and Criteria, Part 111, sub-section 34.4.1, in accordance with the following criteria: (a)

Packing group I: any substance which, in the 4: 1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time less than the mean burning time of a 3:2 mixture, by mass, of potassium bromate and cellulose;

(b)

Packing group 11: any substance which, in the 4: 1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 2:3 mixture (by mass) of potassium bromate and cellulose and the criteria for packing group 1 are not met;

(c)

Packing group 111: any substance which, in the 4: 1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 3:7 mixture (by mass) of potassium bromate and cellulose and the criteria for packing groups I and I1 are not met.

Oxidizing liquids Classification

2.2.51.1.8

When oxidizing liquid substances not mentioned by name in Table A of Chapter 3.2 are assigned to one of the entries listed in sub-section 2.2.5 1.3 on the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part 111, sub-section 34.4.2, the following criteria shall apply: A liquid substance shall be assigned to Class 5.1 if, in the 1:l mixture, by mass, of substance and cellulose tested, it exhibits a pressure rise of 2070 H a gauge or more and a mean pressure rise time equal to or less than the mean pressure rise time of a 1:1 mixture, by mass, of 65% aqueous nitric acid and cellulose. Assignment of packing groups

2.2.51.1.9

Oxidizing liquids classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, I1 or 111 on the basis of test procedures of the Manual of Tests and Criteria, Part 111, section 34.4.2, in accordance with the following criteria:

Packing group I: any substance which, in the 1:1 mixture, by mass, of substance and cellulose tested, spontaneously ignites; or the mean pressure rise time of a 1:1 mixture, by mass, of substance and cellulose is less than that of a 1:1 mixture, by mass, of 50% perchloric acid and cellulose; Packing group 11: any substance which, in the 1:l mixture, by mass, of substance and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture, by mass, of 40% aqueous sodium chlorate solution and cellulose; and the criteria for packing group I are not met; Packing group 111: any substance which, in the 1:1 mixture, by mass, of substance and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a l : 1 mixture, by mass, of 65% aqueous nitric acid and cellulose; and the criteria for packing groups I and I1 are not met. Substances not acceptedfor carriage

The chemically unstable substances of Class 5.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end it shall in particular be ensured that receptacles and tanks do not contain any material liable to promote these reactions. The following substances and mixtures shall not be accepted for carriage: -

oxidizing solids, self-heating, assigned to UN No. 3 100, oxidizing solids, water-reactive, assigned to UN No. 3 121 and oxidizing solids, flammable, assigned to UN No. 3 137, unless they meet the requirements for Class 1 (see also 2.1.3.7);

-

hydrogen peroxide, not stabilized or hydrogen peroxide, aqueous solutions, not stabilized containing more than 60 % hydrogen peroxide;

-

tetranitromethane not free from combustible impurities;

-

perchloric acid solutions containing more than 72 % (mass) acid, or mixtures of perchloric acid with any liquid other than water;

-

chloric acid solution containing more than 10 % chloric acid or mixtures of chloric acid with any liquid other than water;

-

halogenated fluor compounds other than UN Nos. 1745 BROMINE PENTAFLUORIDE; 1746 BROMINE TRIFLUORIDE and 2495 IODINE PENTAFLUORIDE of Class 5.1 as well as UN Nos. 1749 CHLORINE TRIFLUORIDE and 2548 CHLORNE PENTAFLUORIDE of Class 2;

-

ammonium chlorate and its aqueous solutions and mixtures of a chlorate with an ammonium salt;

-

ammonium chlorite and its aqueous solutions and mixtures of a chlorite with an ammonium salt;

-

mixtures of a hypochlorite with an ammonium salt;

-

ammonium bromate and its aqueous solutions and mixtures of a bromate with an ammonium salt;

-

ammonium permanganate and its aqueous solutions and mixtures of a permanganate with an ammonium salt;

-

ammonium nitrate containing more than 0.2 % combustible substances (including any organic substance calculated as carbon) unless it is a constituent of a substance or article of Class 1;

-

fertilizers having an ammonium nitrate content (in determining the ammonium nitrate content, all nitrate ions for which a molecular equivalent of ammonium ions is present in the mixture shall be calculated as ammonium nitrate) or a content in combustible substances exceeding the values specified in special provision 307 except under the conditions applicable to Class 1;

-

ammonium nitrite and its aqueous solutions and mixtures of an inorganic nitrite with an ammonium salt;

-

mixtures of potassium nitrate, sodium nitrite and an ammonium salt.

2.2.51.3

List of collective entries

3xidizing substances

liquid

01

3210 321 1 3213 3214 3216 3218 3219 3139

CHLORATES. INORGANIC, AQUEOUS SOLUTION, N.O.S. PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. BROMATES. INORGANIC. AQUEOUS SOLUTION, N.O.S. PERMANGANATES, INORGANIC, AQUEOUS SOLUTION. N.O.S. PERSULPHATES. INORGANIC. AQUEOUS SOLUTION, N.O.S. NITRATES. lNORGANIC, AQUEOUS SOLUTION, N.O.S. NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. OXIDIZING LIQUID. N.O.S.

1450 1461 I462 1477 1481 1482 1483 2627 32 12 3215 1479

BROMATES, INORGANIC, N.0.S CHLORATES, INORGANIC. N.O.S. CHLORITES, INORGANIC, N.O.S. NITRATES, INORGANIC, N.0.S PERCHLORATES, INORGANIC, N.O.S. PERMANGANATES, INORGANIC, N.O.S. PEROXIDES, INORGANIC, N.0.S NITRITES. INORGANIC, N.O.S. HYPOCHLORITES, INORGANIC, N.O.S. PERSULPHATES, INORGANIC, N.O.S. OXIDIZING SOLID, N.O.S.

1 3356

OXYGEN GENERATOR. CHEMICAL

Solid, flammable

OF

(3137 OXIDIZING SOLID, FLAMMABLE, N.O.S. (not allowed, see 2.2.51.2)

Solid, self-heating

OS

1 3 100

Solid, water reactive

1-

OW

OXIDIZING SOLID, SELF-HEATING, N.O.S. (not allowed. see 2.2.5 1.2)

3121 OXIDIZING SOLID, WATER REACTIVE, N.O.S. see 2.2.51.2)

l liquid

OT1 13099 OXIDIZING LIQUID. TOXIC, N.O.S.

I solid

0 T 2 13087 OXIDIZING SOLID, TOXIC, N.O.S.

l liquid

OC1 13098 OXIDIZING LIQUID. CORROSIVE. N.O.S.

solid

0 C 2 13085 OXIDIZING SOLID. CORROSIVE, N.O.S.

(not

1

allowed.

Toxic

41 Corrosive

Toxic, corrosive

1

OTC (No collective entry with this classification code available: if need be. classification I under a collective entry with a classification code to be determined according to the table of ~recedenceof hazard in 2.1 -3.10.)

Class 5.2

Organic peroxides

Criteria

The heading of Class 5.2 covers organic peroxides and formulations of organic peroxides. The substances of Class 5.2 are subdivided as follows: P1 P2

Organic peroxides, not requiring temperature control; Organic peroxides, requiring temperature control.

Definition Organic peroxides are organic substances which contain the bivalent -0-0-structure and may be considered derivatives of hydrogen peroxide, where one or both of the hydrogen atoms have been replaced by organic radicals. Properties

Organic peroxides are liable to exothermic decomposition at normal or elevated temperatures. The decomposition can be initiated by heat, contact with impurities (e.g. acids, heavy-metal compounds, amines), friction or impact. The rate of decomposition increases with temperature and varies with the organic peroxide formulation. Decomposition may result in the evolution of harmful, or flammable, gases or vapours. For certain organic peroxides the temperature shall be controlled during carriage. Some organic peroxides may decompose explosively, particularly if confmed. This characteristic may be modified by the addition of diluents or by the use of appropriate packagings. Many organic peroxides burn vigorously. Contact of organic peroxides with the eyes is to be avoided. Some organic peroxides will cause serious injury to the cornea, even after brief contact, or will be corrosive to the skin. NOTE: Test methods for determining thejlanzmability of organic peroxides are set out in the Manual of Tests and Criteria, Part III, sub-section 32.4. Because organic peroxides may react vigorously when heated, it is recommended to determine their flash-point using snzall sample sizes such as described in I S 0 3679:1983.

Any organic peroxide shall be considered for classification in Class 5.2 unless the organic peroxide formulation contains: (a)

not more than 1.0 % available oxygen from the organic peroxides when containing not more than 1.0 % hydrogen peroxide;

(b)

not more than 0.5 % available oxygen from the organic peroxides when containing more than 1.0 % but not more than 7.0 % hydrogen peroxide.

NOTE: The available oxygen content (%) of an organic peroxide formulation is given by the formula 16 X 3 ( n , X c,/mJ where: = n1 Cl

mi

= =

number ofperoxygen groups per molecule of organic peroxide i; concentration (mass %) of organic peroxide i; and molecular mass of organic peroxide i.

2.2.52.1.6

Organic peroxides are classified into seven types according to the degree of danger they present. The types of organic peroxide range from type A, which is not accepted for carriage in the packaging in which it is tested, to type G, which is not subject to the provisions of Class 5.2. The classification of types B to F is directly related to the maximum quantity allowed in one packaging. The principles to be applied to the classification of substances not listed in 2.2.52.4 are set out in the Manual of Tests and Criteria, Part 11.

2.2.52.1.7

Organic peroxides which have already been classified and are already permitted for carriage in packagings are listed in 2.2.52.4, those already permitted for carriage in IBCs are listed in 4.1.4.2 of ADR, packing instruction IBC520 and those already permitted for carriage in tanks in accordance with Chapters 4.2 and 4.3 are listed in 4.2.5.2 of ADR, portable tank instruction T23. Each permitted substance listed is assigned to a generic entry of Table A of Chapter 3.2 (UN Nos. 3101 to 3 120) and appropriate subsidiary risks and remarks providing relevant transport information are given. These generic entries specify: -

the type (B to F) of organic peroxide (see 2.2.52.1.6 above);

-

physical state (liquid/solid); and

-

temperature control (when required), see 2.2.52.1.15 to 2.2.52.1.18.

Mixtures of these formulations may be classified as the same type of organic peroxide as that of the most dangerous component and be carried under the conditions of carriage given for this type. However, as two stable components can form a thermally less stable mixture, the self-accelerating decomposition temperature (SADT) of the mixture shall be determined and, if necessary, the control and emergency temperatures derived from the SADT in accordance paragraph 2.2.52.1 .l 6. 2.2.52.1.8

Classification of organic peroxides, formulations or mixtures of organic peroxides not listed in 2.2.52.4, 4.1.4.2 of ADR, packing instruction IBC520 or 4.2.5.2 of ADR, portable tank instruction T23, and assignment to a collective entry shall be made by the competent authority of the country of origin. The statement of approval shall contain the classification and the relevant conditions of carriage. If the country of origin is not a Contracting Party to ADN, the classification and conditions of carriage shall be recognized by the competent authority of the fxst country Contracting Party to ADN reached by the consignment.

2.2.52.1.9

Samples of organic peroxides or formulations of organic peroxides not listed in 2.2.52.4, for which a complete set of test results is not available and which are to be carried for further testing or evaluation, shall be assigned to one of the appropriate entries for organic peroxides type C provided the following conditions are met: -

the available data indicate that the sample would be no more dangerous than organic peroxides type B;

-

the sample is packaged in accordance with packing method 0 P 2 of 4.1.4.1 of ADR and the quantity per transport unit is limited to 10 kg;

-

the available data indicate that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation.

Desensitization of organic peroxides

2.2.52.1 . l 0

In order to ensure safety during carriage, organic peroxides are in many cases desensitized by organic liquids or solids, inorganic solids or water. Where a percentage of a substance is stipulated, this refers to the percentage by mass, rounded to the nearest whole number. In general, desensitization shall be such that, in case of spillage, the organic peroxide will not concentrate to a dangerous extent.

2.2.52.1.11

Unless otherwise stated for the individual organic peroxide formulation, the following defmition(s) shall apply to diluents used for desensitization: -

diluents type A are organic liquids which are compatible with the organic peroxide and which have a boiling point of not less than 150 "C. Type A diluents may be used for desensitizing all organic peroxides.

-

diluents type B are organic liquids which are compatible with the organic peroxide and which have a boiling point of less than 150 "C but not less than 60 "C and a flash-point of not less than 5 "C.

Type B diluents may be used for desensitization of all organic peroxides provided that the boiling point of the liquid is at least 60 "C higher than the SADT in a 50 kg package. 2.1.52.1 . l 2

Diluents, other than type A or type B, may be added to organic peroxide formulations as listed in 2.2.52.4 provided that they are compatible. However, replacement of all or part of a type A or type B diluent by another diluent with differing properties requires that the organic peroxide formulation be re-assessed in accordance with the normal acceptance procedure for Class 5.2.

2.2.52.1.13

Water may only be used for the desensitization of organic peroxides which are listed in 2.2.52.4 or in the competent authority decision according to 2.2.52.1.8 as being "with water" or "as a stable dispersion in water". Samples of organic peroxides or formulations of organic peroxides not listed in 2.2.52.4 may also be desensitized with water provided the requirements of 2.2.52.1.9 are met.

2.2.52.1.14

Organic and inorganic solids may be used for desensitization of organic peroxides provided that they are compatible. Compatible liquids and solids are those which have no detrimental influence on the thermal stability and hazard type of the organic peroxide formulation. Temperature control requirements

2.2.52.1 .l 5

Certain organic peroxides may only be carried under temperature-controlled conditions. The control temperature is the maximum temperature at which the organic peroxide can be safely carried. It is assumed that the temperature of the immediate surroundings of a package only exceeds 55 "C during carriage for a relatively short time in a 24 hour period. h the event of loss of temperature control, it may be necessary to implement emergency procedures. The emergency temperature is the temperature at which such procedures shall be implemented.

2.2.52.1.16

The control and emergency temperatures are derived from the SADT which is defined as the lowest temperature at which self-accelerating decomposition may occur with a substance in the packaging as used during carriage (see Table 1). The SADT shall be determined in order to decide whether a substance shall be subjected to temperature control during carriage. Provisions for the determination of the SADT are given in the Manual of Tests and Criteria, Part 11, Sections 20 and 28.4.

Table 1: Derivation of control and emergency temperatures Type of receptacle Single packagings and IBCs

Tanks a

SADT a

Control temperature

Emergency temperature

20 "C or less

20 "C below SADT

10 "C below SADT

over 20 "C to 35 "C

15 "C below SADT

10 "C below SADT

over 35 "C

10 "C below SADT

5 "C below SADT

Not greater than 50 "C

10 "C below SADT

5 "C below SADT

SADT of the substance as packaged for carriage.

2.2.52.1.17

The following organic peroxides shall be subject to temperature control during carriage: -

organic peroxides types B and C with an SADT I 50 "C;

-

organic peroxides type D showing a medium effect when heated under confinement 50 "C or showing a low or no effect when heated under confinement with an SADT I 45 "C; and with an SADT I

-

organic peroxides types E and F with an SADT 1 45 "C.

NOTE: Provisions for the determination of the effects of heating under confinement are given in the Manual of Tests and Criteria, Part 11, Section 20 and Sub-section 28.4. 2.2.52.1 .l 8

Where applicable, control and emergency temperatures are listed in 2.2.52.4. The actual temperature during carriage may be lower than the control temperature but shall be selected so as to avoid dangerous separation of phases.

2.2.52.2

Substances not accepted for carriage Organic peroxides, type A, shall not be accepted for carriage under the provisions of Class 5.2 (see Manual of Tests and Criteria, Part 11, paragraph 20.4.3 (a)).

2.2.52.3

List of collective entries

Organic peroxides

Not requiring temperature control

P1

Requiring temperature control p2

2.2.52.4

3 101 3102 3103 3104 3 105 3106 31 07 3108 3 109 3 110

l

31 11 31 12 3 1 13 31 14 3 115 31 16 3 117 3 118 31 19 3120

ORGANIC PEROXIDE TYPE A, LIQUID ORGANIC PEROXIDE TYPE A. SOLID ORGANIC PEROXIDE TYPE B, LIQUID ORGANIC PEROXIDE TYPE B, SOLID ORGANIC PEROXIDE TYPE C, LIQUID ORGANIC PEROXIDE TYPE C, SOLID ORGANIC PEROXIDE TYPE D, LIQUID ORGANIC PEROXIDE TYPE D, SOLID ORGANIC PEROXIDE TYPE E, LIQUID ORGANIC PEROXIDE TYPE E, SOLID ORGANIC PEROXIDE TYPE F, LIQUID ORGANIC PEROXIDE TYPE F. SOLID ORGANIC PEROXIDE TYPE G, LIQUID ORGANIC PEROXIDE TYPE G, SOLID

1

)

Not accepted for carriage, see 2 2 52 2

Not subject to the provlslons appl~cableto Class 5 2, see 2 2 52 1 6

ORGANIC PEROXIDE TYPE B, LIQUID. TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE D. LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE D, SOLID. TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE E. SOLID. TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE F. LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED

List of currently assigned organic peroxides in packagings In the column "Packing Method", codes "OP1" to "OP8" refer to packing methods in 4.1.4.1 of ADR packing instruction P520 (see also 4.1.7.1 of ADR). Organic peroxides to be carried shall fulfil1 the classification and he control and emergency temperatures (derived from the SADT) as listed. For substances permitted in IBCs, see 4.1.4.2 of ADR, packing instruction IBC520 and, for those permitted in tanks according to Chapters 4.2 and 4.3 of ADR, see 4.2.5.2 of ADR, portable tank instruction T23.

ORGANIC PEROXIDE

Concentration (%)

ACETYL ACETONE PEROXIDE

4 42 4 32 as a paste

ACETYL CYCLOHEXANESLJLPHONYL PEROXIDE

5 82 i 32 tert-AMYL HYDROPEROXIDE 488 tert-AMYL PEROXYACETATE 5 62 tert-AMYL PEROXYBENZOATE 5 100 tert-AMYL PEROXY-2-ETHYLHEXANOATE 5 100 tert-AMYL PEROXY-2-ETHYLHEXYL CARBONATE 5 100 tert-AMYLPEROXY ISOPROPYL CARBONATE 177 tert-AMYL PEROXYNEODECANOATE 5 77 tert-AMYL PEROXYPIVALATE 5 77 tert-AMYLPEROXY-3,5,5-TMMETHYLHEXANOATE4 100 tert-BUTYL CUMYL PEROXIDE > 42 - 100 It 152 > 52 100

-

tert-BUTYL HYDROPEROXIDE

tert-BUTYL HYDROPEROXIDE + DI-tert-BUTYLPEROXIDE

152 >79 - 90 1so 5 79 5 72 <82+>9

tert-BUTYL MONOPEROXYMALEATE

> 52 - 100 4 52 152 i 52 as a paste

tert-BUTYL PEROXYACETATE

> 52 - 77 > 32 - 52 5 32

Diluent type A (%)

Diluent Inert type B l ) solid ("h) (Vo)

Water

Packing Method

Control temperature ("c)

Emergency temperature

("c)

Number (Generic entry)

Subsidiary risks and remarks

ORGANIC PEROXIDE

Concentration (%)

tert-BUTYL PEROXYBENZOATE

> 77 - 100

Diluent type A (Oh)

11

P,

tert-BUTYL PEROXYBUTYL FUMARATE

1.6-Di-(tert-BUTYLPEROXY-CARBONYLOXY) HEXANE tert-BUTYL PEROXYCROTONATE tert-BUTYL PEROXYDIETHYLACETATE tert-BUTYL PEROXY-2-ETHYLHEXANOATE

!, I,

I

W l . I

tert-BUTYL PEROXY-2-ETHYLHEXYLCARBONATE tert-BUTYL PEROXMSOBUTYRATE I,

tert-BUTYLPEROXY ISOPROPYLCARBONATE l-(2-tert-BUTYLPEROXY 1SOPROPYL)-3ISOPROPENYLBENZENE v,

tert-BUTYL PEROXY-2-METHYLBENZOATE tert-BUTYL PEROXYNEODECANOATE 1,

tert-BUTYL PEROXYNEOHEPTANOATE 11

5 42 5 100 > 77 - l00 5 77 L 23 5 52 as a stable dispersion in water 5 42 as a stable dispersion in water 5 32 2 68 177 2 23 1 42 as a stable dispersion in water

Diluent Inert type B 1) solid (?h) (Yo)

Water

Packing Method

Control Emergency temperature temperature ("c) ("C)

Number (Generic entry)

Subsidiary risks and remarks

ORGANIC PEROXIDE

Concentration

W)

Diluent type A ("h) > 23

> 67 - 77 >27-67 5 27 tert-BUTYLPEROXY STEARYLCARBONATE 5 100 tert-BUTYL PEROXY-3.5.5-TRIMETHYLHEXANOATE > 32 - 100 t 132 3-CHLOROPEROXYBENZOIC ACID > 57 - 86 (8 5 57 I, 5 77 CUMYL HYDROPEROXIDE > 90 - 98 510 , i 90 1 10 C U M PEROXYNEODECANOATE ~ 5 77 11 i 52 as a stable dispersion in water

tert-BUTYL PEROXYPIVALATE 11

I

00 I

c u M n PEROXYNEOHEPTANOATE CUMYL PEROXYPIVALATE CYCLOHEXANONE PEROXIDE@) I#

DIACETONE ALCOHOL PEROXIDES DIACETYL PEROXIDE DI-tert-AMYL PEROXIDE 1,l -DI-(tert-AMYLPER0XY)CYCLOHEXANE

5 77 5 77 i 91 5 72 i 72 as a paste 5 32 5 57 - 27 5 100 5 82

2 23

? 28

? 18

Diluent Inert type B 1) solid (?h) ("h)

Water

L 33 173

1 68 2 14 >3 >6

> 23

240 L17

Packing Method OP5 OP7 OP8 OP7 OP7 OP8 OP 1 OP7 OP7 OP8 OP8 OP7 OP8

Control temperature ("c) 0 0 +30

-10 -10

Emergency temperature ("C) +l0 +l0 +35

Number (Generic entry) 3113 3115 3119 3 106 3105 3 109 3102 3106 3106 3107 3109 3115 3119

3115 3115 3104 3 105 3106 Exempt 3115 3115 3107 3103

Subsidiary risks and remarks

ORGANIC PEROXIDE

Concentration ("h)

DIBENZOYL. PEROXIDE

> 51 - 100 > 77 - 94

Diluent type A (%)

!l

177 5 62 > 52 - 62 as a paste > 35 - 52 > 36 - 42 5 56.5 as a paste < 52 as a paste 142 as a stable dispersion in water 5 35 DI-(4-tert-BUTYLCYCLOHEXYL) PEROXYDICARBONATE

00 \O I

DI-tert-BUTYL PEROXIDE l1

DI-tert-BUTYL. PEROXYAZELATE

2.2-DI-(tert-BUTYLPER0XY)BUTANE 1,l-DI-(tert-BUTYLPEROXY) CYCLOHEXANE t,

DI-n-BUTYL PEROXYDICARBONATE I

5 42 as a stable dispersion in water > 52 100 152 5 52 5 52 > 80 - 100 > 52 - 80 >42 - 52 5 42 5 27 < 42 113 > 27 52 5 27 5 42 as a stable dispersion in water (frozen)

-

-

Diluent Inert type B l ) solid (Yo) (Yo)

Water

Packing Method

Control Emergency temperature temperature ("C) ("C)

Number (Generic entry)

Subsidiary risks and remarks

Exempt

29)

ORGANIC PEROXIDE

Concentration

DI-sec-BUTYL PEROXYDICARBONATE

> 52 - 100

,

5 52 DI-(2-tert-BUTYLPEROXYISOPROPYL)BENZENE(S) > 42 - 100 5 42 DI-(tert-BUTYLPEROXY) PHTHALATE > 42 - 52 5 52 as a paste 5 42 L52 5 42 l ,l-DI-(tert-BUTYLPER0XY)-3,3.51 9 0 - 100 11

11

Diluent type A (Oh)

Diluent Inert type B 1) solid (Yo) (Yo)

Water

Packing Method

Control temperature ("C)

Emergency temperature ("C) .l0 .5

Number (Generic entry) 3113 3115 3 l06 Exempt 3105 3106 3107 3105 3106 3101

TRIMETHYLCYCLOHEXANE It

l

a 0

DICETYL PEROXYDICARBONATE I,

l

DI-4-CHLOROBENZOYL PEROXIDE S,

DICUMYL PEROXIDE 11

DICYCLOHEXYL PEROXYDICARBONATE t, It

DIDECANOYL PEROXIDE 2,2-DI-(4,4-D1(ten-BUTYLPEROXY) CYCLOHEXYL) PROPANE DI-2,4-DICHLOROBENZOYL PEROXIDE I,

DI-(2-ETHOXYETHYL) PEROXYDICARBONATE 1 -(2-ETHYLHEXANOYL-PER0XY)- 1.3DIMETHYLBUTYL PEROXYPIVALATE

> 57 - 90 5 77 5 57 5 57 5 32 5 100 5 42 as a stable dispersion in water 5 77 L 52 as a paste 5 32 > 52 - 100 5 52 > 91 - 100 5 91 1 42 as a stable dispersion in water 5 l00 5 42

122 L 77 152 as a paste with silicon oil 152 152

3102 3 l06 Exempt 3110 Exempt 31 12 3114 3119

Subsidiary risks and remarks

ORGANIC PEROXIDE

Concentration ("h)

DI-(2-ETHYLHEXYL) PEROXYDICARBONATE

> 77 - 100 < 77 < 62 as a stable dispersion in water

2.2-DIHYDROPEROXYPROPANE DI-(1-HYDROXYCYCLOHEXYL) PEROXIDE DIISOBUTYRYL PEROXIDE

DI-ISOPROPYLBENZENE DIHYDROPEROXIDE DIISOPROPYL PEROXYDICARBONATE I

2 I

DILAUROYL PEROXIDE

DI-(3-METHOXYBUTYL) PEROXYDICARBONATE DI-(2-METHYLBENZOYL) PEROXIDE DI-(3-METHYLBENZOYL) PEROXIDE + BENZOYL (3-METHYLBENZOYL) PEROXIDE + DIBENZOYL PEROXIDE DI-(4-METHYLBENZOYL) PEROXIDE

Diluent type A (Yo)

5 52 as a stable dispersion in water < 52 as a stable dispersion in water (frozen) 5 27 < l00 > 32 52 5 32 < 82 >5 > 52-100 5 52 < 28 1 72 < 100 < 42 as a stable dispersion in water < 52 < 87 <20+< 18+<4

-

5 52 as a paste with silicon oil > 82-100

Diluent Inert type B l ) solid (?h) (?h)

Water

Packing Method

Control Emergency temperature temperature ("c) ("c)

Number (Generic entry)

Subsidiary risks and remarks

ORGANIC PEROXIDE

Concentration

('W

Diluent type A (Oh)

5 47 as a paste 5 52 5 77 >52-86

2 48 2 14

2.5-DIMETHYL-2.5-DIHYDROPEROXYHEXAq 2.5-DIMETHYL-2.5-DI-(3,5,5TRIMETHYLHEXANOYLPER0XY)HEXANE l ,l-DIMETHYL-3-HYDROXYBUTYL I

W

h,

PEROXYNEOHEPTANOATE DIMYRISTYL PEROXYDICARBONATE I!

I

DI-(2-NEODECANOYLPEROXYISOPROPYL) BENZENE DI-n-NONANOYL PEROXIDE DI-n-OCTANOYL PEROXIDE DI-(2-PHENOXYETHYL) PEROXYDICARBONATE DIPROPIONYL PEROXIDE DI-n-PROPYL PEROXYDICARBONATE

5 100 5 42 as a stable dispersion in water 552 ? 48

Diluent Inert type B l ) solid (Yo) (%)

Water

Packing Method

Control Emergency temperature temperature ("c) ("C)

Number (Generic entry)

Subsidiary risks and remarks

ORGANIC PEROXIDE

Concentration (%)

DISUCCINIC ACID PEROXIDE

> 72-100

DI-(3.5,5-TRIMETHYLHEXANOYL) PEROXIDE

ETHYL 3.3-DI-(tert-AMYLPER0XY)BUTYRATE ETHYL 3.3-DI-(tert-BUTYLPER0Xy)BUTYRATE

I

E3 t

tert-HEXYL PEROXYNEODECANOATE tert-HEXYL PEROXYPIVALATE lSOPROPYL sec-BUTYL PEROXYDICARBONATE +DI-sec-BUTYL PEROXYDICARBONATE +DI-ISOPROPYL PEROXYDICARBONATE

Diluent type A (Vo)

Diluent Inert type B l ) solid (%) (Yo)

5 72 > 38-82 5 52 as a stable dispersion in water i38 i 67 > 77 - 100 5 77 i 52 5 52 5 52 5 71 5 72

ISOPROPYL sec-BUTYL PEROXYDICARBONATE + DI-sec-BUTYL PEROXYDICARBONATE + DI-ISOPROPYL PEROXYDICARBONATE ISOPROPYLCUMYL HYDROPEROXIDE p-MENTHYL HYDROPEROXIDE METHYLCYCLOHEXANONE PEROXIDE(S) METHYL ETHYL KETONE PEROXIDE(S)

METHYL ISOBUTYL KETONE PEROXIDE(S) ORGANIC PEROXIDE, LIQUID, SAMPLE ORGANIC PEROXIDE, LIQUID, SAMPLE, TEMPERATURE CONTROLLED ORGANIC PEROXIDE, SOLID, SAMPLE ORGANIC PEROXIDE, SOLID, SAMPLE, TEMPERATURE CONTROLLED PEROXYACETIC ACID, DISTILLED, TYPE F,

stabilized PEROXYACETIC ACID, TYPE D, stabilized

L 72 > 72 - 100 < 72 5 67 (see remark 8) (see remark 9) (see remark 10) 5 62

> 28

> 28 2 33

L 48 2 55 > 60 1 19

Water

Packing Method

Control Emergency temperature temperature ("c) ("C)

Number (Generic entry)

Subsidiary risks and remarks

ORGANIC PEROXIDE

Concentration (%)

PEROXYACETIC ACID, TYPE E, stabilized PEROXYACETIC ACID, TYPE F, stabilized PEROXYLAURIC ACID PINANYL HYDROPEROXIDE

5 43

Diluent type A (%)

1,l ,3.3- TETRAMETHYLBUTYL PEROXYNEODECANOATE

l ,l .3,3-TETRAMETHYL-BUTYLPEROXYPIVALATE I

a

P

3,6,9-TRIETHYL-3,6,9-TRIMETHYL

- 1,4,7 TRIPEROXONANE

Water

Packing Method OP8

POLYETHER POLY-tert-BUTYLPEROXYCARBONATE 1,l ,3.3-TETRAMETHYLBUTYL HYDROPEROXIDE l ,1,3,3-TETRAMETHYLBUTYL PEROXY-2 ETHYLHEXANOATE

5 52 as a stable dispersion in water < 77

Diluent Inert type B 1) solid (%) (Oh)

t 23

Control Emergency temperature temperature ("C) ("C)

Number (Generic entry)

Subsidiary risks and remarks

3107

13) 14) 19)

Remarks (refer to the last column of the Table in 2.2.52.4): Diluent type B may always be replaced by diluent t p e A. The boiling point of diluent type B shall be at least 60°C higher than the SADT of the organic peroxide. Available oxygen 14.7%. ffEXPLOSIVE"subsidialyrisk label required (Model No.1, see 5.2.2.2.2). Diluent may be replaced by di-tert-butyl peroxide. Available oxygen 19%. With 1 9 % hydrogen peroxide; available oxygen _(l0%. Only non-metallic packagings allowed. Available oxygen > 10% and 1 10.7%, with or without water. Available oxygen 5 1 0%, with or without water. Available oxygen 18.2%, with or without water. See 2.2.52.1.9. Up to 2000 kgper receptacle assigned to ORGANIC PEROXIDE TYPE F on the basis of large scale trials. "CORROSIVE"subsidiary risk label required (Model No. 8, see 5.2.2.2.2). Peroxyacetic acid formulations which fulfil the criteria of the Manual of Tests and Criteria, paragraph 20.4.3 (d). Peroxyacetic acid formulations which fulfil the criteria of the Manual of Tests and Criteria, paragraph 20.4.3 (e). Peroxyacetic acid formulations which fulfil the criteria of the Manual of Tests and Criteria, paragraph 20.4.3

m.

Addition of water to this organic peroxide will decrease its thermal stability. No 'CORROSIVE" subsidiary risk label (Model No.8, see 5.2.2.2.2) required for concentrations below 80%. Mixtures with hydrogen peroxide, water and acid(s). With diluent type A, with or without water. With 225% diluent type A by mass, and in addition ethylbenzene. With 2 19% diluent type A by mass, and in addition methyl isobutyl ketone. With < 6% di-tert-butylperoxide. With 1 8 % 1-isopropylhydroperoxy-4-isopropylhydroxybenzene. Diluent type B with boiling point > 110 'C. With < 0.5% hydroperoxides content. For concentrations more than 56%, "CORROSIVE" subsidiary risk label required (Model No. 8, see 5.2.2.2.2). Available active oxygen 17.6% in diluent type A having a 95% boil-offpoint in the range of 200 - 260 'C. Not subject to the requirements of ADN for Class 5.2.

2.2.61

Class 6.1

2.2.61.1

Criteria

2.2.61.1.1

The heading of Class 6.1 covers substances of which it is known by experience or regarding which it is presumed from experiments on animals that in relatively small quantities they are able by a single action or by action of short duration to cause damage to human health, or death, by inhalation, by cutaneous absorption or by ingestion.

2.2.61 .l .2

Substances of Class 6.1 are subdivided as follows: T

Toxic substances without subsidiary risk: T1 T2 T3 T4 T5 T6 T7 T8 T9

TF

Toxic substances

Organic, liquid; Organic, solid; Organometallic substances; Inorganic, liquid; Inorganic, solid; Liquid, used as pesticides; Solid, used as pesticides; Samples; Other toxic substances;

Toxic substances. flammable: TFI Liquid; TF2 Liquid, used as pesticides; TF3 Solid;

TS

Toxic substances, self-heating, solid;

TW

Toxic substances, which, in contact with water, emit flammable gases: TW1 Liquid; TW2 Solid;

TO

Toxic substances, oxidizing: TO1 Liquid; TO2 Solid;

TC

Toxic substances, corrosive: TC l TC2 TC3 TC4

Organic, liquid; Organic, solid; Inorganic, liquid; Inorganic, solid;

TFC Toxic substances, flammable, corrosive. Definitions

2.2.61 .l .3

For the purposes of ADN: LDjO(median lethal dose) for acute oral toxicity is the statistically derived single dose of a substance that can be expected to cause death within 14 days in 50 per cent of young adult

albino rats when administered by the oral route. The LDSo value is expressed in terms of mass of test substance per mass of test animal (mg/kg);

LDjo for acute dermal toxicity is that dose of the substance which, administered by continuous contact for 24 hours with the bare skin of albino rabbits, is most likely to cause death within 14 days in one half of the animals tested. The number of animals tested shall be sufficient to give a statistically significant result and be in conformity with good pharmacological practice. The result is expressed in milligrams per kg body mass;

Leso for acute toxicity on inhalation is that concentration of vapour, mist or dust which, administered by continuous inhalation to both male and female young adult albino rats for one hour, is most likely to cause death within 14 days in one half of the animals tested. A solid substance shall be tested if at least 10% (by mass) of its total mass is likely to be dust in a respirable range, e.g. the aerodynamic diameter of that pa~-ticle-fractionis 10 pm or less. A liquid substance shall be tested if a mist is likely to be generated in a leakage of the transport containment. Both for solid and liquid substances more than 90% (by mass) of a specimen prepared for inhalation toxicity shall be in the respirable range as defined above. The result is expressed in milligrams per litre of air for dusts and mists or in millilitres per cubic metre of air (parts per million) for vapours. Classzjkation and assignment of packing groups 2.2.61.1.4

Substances of Class 6.1 shall be classified in three packing groups according to the degree of danger they present for carriage, as follows: highly toxic substances toxic substances slightly toxic substances.

Packing group I: Packing group 11: Packing group 111: 2.2.61 .1.5

Substances, mixtures, solutions and articles classified in Class 6.1 are listed in Table A of Chapter 3.2. The assignment of substances, mixtures and solutions not mentioned by name in Table A of Chapter 3.2 to the relevant entry of sub-section 2.2.61.3 and to the relevant packing group in accordance with the provisions of Chapter 2.1, shall be made according to the following criteria in 2.2.61.1.6 to 2.2.61.1.1 1.

2.2.6 1.1.6

To assess the degree of toxicity, account shall be taken of human experience of instances of accidental poisoning, as well as special properties possessed by any individual substances: liquid state, high volatility, any special likelihood of cutaneous absorption, and special biological effects.

2.2.61.1.7

In the absence of observations on humans, the degree of toxicity shall be assessed using the available data from animal experiments in accordance with the table below:

I

Oral toxicity LDso (mg/kg) 55

Dermal toxicity LDso (mg/kg) 10.2

Inhalation toxicity by dusts and mists LCso(mgll) 10.2

I1

> 5 and I 50

> 50 and 5 200

> 0.2 and I 2

Packing group Highly toxic Toxic I

I a

Slightly toxic

I

1

I11 a

1

I

> 5 0 a n d 5 300

1

I

> 200 and I l 000

I

Tear gas substances shall be included in packing group 11 even their toxicity correspond to packing group IIZ criteria.

>2andI4

J

if data concerning

2.2.61 .l .7.1

Where a substance exhibits different degrees of toxicity for two or more kinds of exposure, it shall be classified under the highest such degree of toxicity.

2.2.61.1.7.2

Substances meeting the criteria of Class 8 and with an inhalation toxicity of dusts and mists (LCSo)leading to packing group I shall only be accepted for an allocation to Class 6.1 if the toxicity through oral ingestion or dermal contact is at least in the range of packing groups I or 11. Otherwise an assignment to Class 8 shall be made if appropriate (see footnote in 2.2.8.1.4).

2.2.61.1.7.3

The criteria for inhalation toxicity of dusts and mists are based on LCSO data relating to l-hour exposure, and where such information is available it shall be used. However, where only LCso data relating to 4-hour exposure are available, such figures can be multiplied by four and the product substituted in the above criteria, i.e. LCso value multiplied by four (4 hour) is considered the equivalent of LCSo(1 hour). Inhalation toxicity of vapours

2.2.61.1.8

Liquids giving off toxic vapours shall be classified into the following groups where "V" is the saturated vapour concentration (in ml/m3 of air) (volatility) at 20 'C and standard atmospheric pressure:

I Highly toxic I Toxic Slightly toxic "

Packing group 1

I1 IIIa

I Where

V 2 10 LCIo and LCSO5 1 000 ml/m3

Where V L LCso and LCso I 3 000 ml/m3 and the criteria for packing group I are not met Where V 2 115 LCso and LCso 5 5 000 ml/m3 and the criteria for ~ackincrgroutx I and I1 are not met

I '

Tear gas substances shall be included in packing group 11 even if data concerning their toxicity correspond to packing group 111 criteria.

These criteria for inhalation toxicity of vapours are based on LCS0 data relating to l-hour exposure, and where such information is available, it shall be used.

However, where only LCS0data relating to 4-hour exposure to the vapours are available, such figures can be multiplied by two and the product substituted in the above criteria, i.e. LCso (4 hour) X 2 is considered the equivalent of LC50 (1 hour).

Group borderlines inhalation toxicity of vapours

10

100

1.ooo

10.000

100.000

Volatility ml/m3 In this figure, the criteria are expressed in graphical form, as an aid to easy classification. However, due to approximations inherent in the use of graphs, substances falling on or near group borderlines shall be checked using numerical criteria.

Mixtures of liquids

2.2.61.1.9

Mixtures of liquids which are toxic on inhalation shall be assigned to packing groups according to the following criteria:

2.2.61.1.9.1

If LCso is known for each of the toxic substances constituting the mixture, the packing group may be detennined as follows: (a)

calculation of the LCSOof the mixture:

,,

LC (mixture)=

1

t-LCsoi fi

i=1

where

f,

=

LCSOi= (b)

average lethal concentration of constituent i in ml/m3.

calculation of volatility of each mixture constituent:

where

2.2.61.1.9.2

molar fraction of constituent i of the mixture;

Pi

=

partial pressure of constituent i in kPa at 20 'C and at standard atmospheric pressure.

(c)

calculation of the ratio of volatility to LCSO:

(d)

the values calculated for LC50 (mixture) and R are then used to determine the packing group of the mixture: Packing group I

R 2 l 0 and LCS0(mixture) l 1 000 ml/m3;

Packing group I1

R > 1 and LC50 (mixture) 5 3 000 ml/m3, if the mixture does not meet the criteria for packing group I;

Packing group 111

R 2 115 and LC50 (mixture) I 5 000 ml/m3, if the mixture does not meet the criteria of packing groups I or 11.

In the absence of LC50 data on the toxic constituent substances, the mixture may be assigned to a group based on the following simplified threshold toxicity tests. When these threshold tests are used, the most restrictive group shall be determined and used for carrying the mixture.

2.2.61.1.9.3

2.2.61.1.9.4

2.2.61.1.9.5

A mixture is assigned to packing group I only if it meets both of the following criteria: (a)

A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of l000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LC50 equal to or less than 1000 ml/m3;

(b)

A sample of vapour in equilibrium with the liquid mixture is diluted with 9 equal volumes of air to form a test atmosphere. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have a volatility equal to or greater than 10 times the mixture LC5,.

A mixture is assigned to packing group I1 only if it meets both of the following criteria, and does not meet the criteria for packing group I:

(a)

A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 3000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LCsOequal to or less than 3000 ml/m3;

(b)

A sample of the vapour in equilibrium with the liquid mixture is used to form a test atmosphere. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have a volatility equal to or greater than the mixture LC50.

A mixture is assigned to packing group 111 only if it meets both of the following criteria, and does not meet the criteria for packing groups I or 11:

(a)

A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 5000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LCsoequal to or less than 5000 ml/m3;

(b)

The vapour concentration (volatility) of the liquid mixture is measured and if the vapour concentration is equal to or greater than 1000 ml/m3, the mixture is presumed to have a volatility equal to or greater than 115 the mixture LC5,.

Methods for determining oral and dermal toxicity of'mixtures

2.2.61.1.10

When classifying and assigning the appropriate packing group to mixtures in Class 6.1 in accordance with the oral and dermal toxicity criteria (see 2.2.61.1.3), it is necessary to determine the acute LDS, of the mixture.

2.2.6l.l.lO.l

of that constituent is known, in If a mixture contains only one active substance, and the the absence of reliable acute oral and dermal toxicity data on the actual mixture to be carried, the oral or dermal LD5, may be obtained by the following method: LD,, value of preparation =

LD,, value of active substance X l00 percentage of active substance by mass

2.2.61.1.10.2

If a mixture contains more than one active constituent, there are three possible approaches that may be used to determine the oral or dermal LDsoof the mixture. The preferred method is to obtain reliable acute oral and dermal toxicity data on the actual mixture to be carried. If reliable, accurate data are not available, then either of the following methods may be performed: (a)

Classify the formulation according to the most hazardous constituent of the mixture as if that constituent were present in the same concentration as the total concentration of all active constituents: or

(b)

Apply the formula:

5+-+...+--c, c, TA

TB

Tz

- 100

TM

where: C

=

the percentage concentration of constituent A, B, ... Z in the mixture;

T

=

the oral

TM

=

the oral LD50value of the mixture.

values of constituent A, B, ... Z;

NOTE: This formula can also be used for dermal toxicities provided that this information is available on the same species for all constituents. The use of this formula does not take into account any potentiation or protective phenomena. Classzjication of pesticides

2.2.6 1.1.1 1

All active pesticide substances and their preparations for which the LC50 andlor LDso values are known and which are classified in Class 6.1 shall be classified under appropriate packing groups in accordance with the criteria given in 2.2.61.1.6 to 2.2.61.1.9. Substances and preparations which are characterized by subsidiary risks shall be classified according to the precedence of hazard Table in 2.1.3.1 0 with the assignment of appropriate packing groups.

2.2.61.1.1 1.1

If the oral or dermal LDS0value for a pesticide preparation is not known, but the LDS0value of its active substance(s) is known, the LDso value for the preparation may be obtained by applying the procedures in 2.2.61.1.10. NOTE: LD5" toxicity data for a number of common pesticides may be obtained from the most current edition of the document "The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classzjication" availablefrom the International Programme on Chemical Safety, World Health Organisation (WHO), 1211 Geneva 27, Switzerland. While that document may be used as a source of LDS" data for pesticides, its classzjication system shall not be used for purposes of transport classzjication oJ or assignment ofpacking groups to, pesticides, which shall be in accordance with the requirements of ADN.

2.2.61.1.1 1.2

The proper shipping name used in the carriage of the pesticide shall be selected on the basis of the active ingredient, of the physical state of the pesticide and any subsidiary risks it may exhibit (see 3.1.2).

2.2.61.1.12

If substances of Class 6.1, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classijkation of solutions and mixtures (such as preparations and wastes), see also 2.1.3.

2.2.61.1.13

On the basis of the criteria of 2.2.61.1.6 to 2.2.61.1.11, it may also be determined whether the nature of a solution or mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the requirements for this Class.

2.2.61.1.14

Substances, solutions and mixtures, with the exception of substances and preparations used as pesticides, which do not meet the criteria of Directives 671548EEC or 881379EEC as amended and which are not therefore classified as highly toxic, toxic or harmful according to these directives, as amended, may be considered as substances not belonging to Class 6.1.

2.2.61.2

Substances not acceptedfor carriage

2.2.61.2.1

Chemically unstable substances of Class 6.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall in particular be ensured that receptacles and tanks do not contain any substance(s) likely to cause such a reaction.

2.2.61.2.2

The following substances and mixtures shall not be accepted for carriage: -

Hydrogen cyanide, anhydrous or in solution, which do not meet the descriptions of UN Nos. 1051, 1613, 1614 and 3294;

-

Metal carbonyls, having a flash-point below 23 "C, other than UN Nos. 1259 NICKEL CARBONYL and 1994 IRON PENTACARBONYL;

-

2,3,7,8-TETRACHLORODIBENZO-p-DIOXINE(TCDD)

in considered highly toxic in accordance with the criteria in 2.2.6 1.1.7;

-

UN NO. 2249 DICHLORODIMETHYL ETHER, SYMMETRICAL;

-

Preparations of phosphides without additives inhibiting the emission of toxic flammable gases.

concentrations

Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L l 9 6 of 16.08.1967,page l). Council Directive 88/379/EEC on the approximation of laws, regulations and administrative provisions relating to the classzjkation, packaging and labelling of dangerous preparations (OfJicial Journal of the European Communities No. L 187 of 16.07.2988, page 14). - 103 -

List of collective entries

2.2.61.3

Toxic substances without subsidiary risk(s)

quid "

T1

2810

CHLOROPICRIN MIXTURE, N.O.S. DYE, LIQUID, TOXIC, N.O.S., or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. TEAR GAS SUBSTANCE, LIQUID, N.O.S. MEDICINE, LIQUID, TOXIC, N.O.S. ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. DISINFECTANT, LIQUID, TOXIC, N.O.S. NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. NITRILES, TOXIC, LIQUID, N.0.S ORGANOPHOSPHORUS COMPOUND, TOXIC, LIQUID, N.O.S. TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LCsn TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 L C ~ O TOXIC LIQUID, ORGANIC, N.O.S.

1544 1544 1601 1655 1655 3448 3143 3143 3462 3249 3464 3439 2811

ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. DISINFECTANT, SOLID, TOXIC, N.O.S. NICOTINE COMPOUND, SOLID, N.O.S., or NICOTINE PREPARATION. SOLID. N.O.S. TEAR GAS SUBSTANCE, SOLID, N.O.S. DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. MEDICINE, SOLID, TOXIC, N.O.S. ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S. NITRILES, TOXIC, SOLID, N.O.S. TOXIC SOLID, ORGANIC, N.O.S.

12026 2788 3146 3280 3465 3281 3466 3282 3467

PHENYLMFRCURIC COMPOUND. N.O.S. ORGANOTM COMPOUND, LIQUID, N.O.S. ORGANOTIN COMPOUND. SOLID, N.O.S. ORGANOARSEMC COMPOUND, LIQUID, N.O.S. ORGANOARSENIC COMPOUND. SOLID, N.O.S. METAL CARBONYLS, LIQUID, N.O.S. METAL CARBONYLS. SOLID. N.O.S. ORGANOMETALLIC COMPOUND, TOXIC, LIQUID, N.O.S. ORGANOMETALLIC COMPOUND. TOXIC, SOLID. N.O.S.

3140 3142 3144 3144 3172 3276 3278 3381 3382

)rganometallic

'. *

T3

:on/'d on next page)

a

Substances and preparations containing alkaloids or nicotine used as pesticides shall be classijied under UN No. 2588 PESTICIDES, SOLID, TOXIC, N.O.S., UN No. 2902 PESTICIDES, LIQUID, TOXIC, N. O.S. or UN No. 2903 PESTICIDES, LIQUID, TOXIC, FLA M M BLE, N. O.S. b

Active substances and triturations or mixtures of substances intendedfor laboratories and experiments and for the manufacture of pharmaceutical products with other substances shall be classiJied according to their toxicity (see 2.2.61.1.7 to 2.2.61.1.1I). c

Self-heating substances, slightly toxic and spontaneously combustible organometallic compounds, are substances of Class 4.2. Water-reactive substances, slightly toxic, and water-reactive organometatIic compounds, are substances of Class 4.3.

2.2.61.3

List of collective entries (cont'd)

Toxic substances without subsidiary risk(s) (contfd)

iqoide

T4

norganic

olids " g

T5

ARSENIC COMPOUND, LIQUID, N.O.S., inorganic including: Arsenates, n.o.s., Arsenites, n.0.s.;and Arsenic sulphides, n.0.s. CYANIDE SOLUTION, N.O.S. MERCURY COMPOUND. LIQUID, N.O.S. ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. SELENIUM COMPOUND, LIQUID, N.O.S. TOXIC BY INHALATION LIQUID, N.O.S. with an Inhalation toxicity lower than or equal to 200 d i m 3 and saturated vapour concentration greater than or equal to 500 LCSO TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 1000 d i m 3 and saturated vapour concentration greater than or equal to 10 LCSO TOXIC LIQUID, INORGANIC, N.O.S. ANTIMONY COMPOUND, INORGANIC, SOLID, N.0.S ARSENIC COMPOUND. SOLID, N.O.S., including: Arsenates, n.0.s.; Arsenites, n.0.s.; and Arsenic sulphides, n.0.s. BARIUM COMPOUND, N.O.S. BERYLLIUM COMPOUND, N.O.S. CYANIDES, INORGANIC, SOLID. N.O.S. THALLIUM COMPOUND, N.O.S. MERCURY COMPOUND, SOLID, N.O. S. LEAD COMPOUND, SOLUBLE, N.O.S. CADMIUM COMPOUND SELENATES or SELENITES FLUOROSILICATES,N.O.S. SELENIUM COMPOUND. SOLID, N.O.S. TELLURIUM COMPOUND, N.O.S. VANADIUM COMPOUND. N.O.S. TOXIC SOLID, INORGANIC, N.O.S. 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC ARSENICAL PESTICIDE, LIQUID. TOXIC ORGANOCHLORINE PESTICIDE, LIQUID. TOXIC TRIAZINE PESTICIDE, LIQUID, TOXIC THIOCARBAMATE PESTICIDE, LIQUID, TOXIC COPPER BASED PESTICIDE, LIQUID, TOXIC MERCURY BASED PESTICIDE, LIQUID, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC ORGANOTIN PESTICIDE, LIQUID. TOXIC COUMARIN DERIVATIVE PESTICIDE, LIQUID. TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC PYRETHROID PESTICIDE, LIQUID, TOXIC

'esticides

PESTICIDE, LIQUID, TOXIC. N.0.S

ront 'd on next page) e

Mercury fulminate, wetted with not less than 20% water, or mixture of alcohol and water by mass is a substance of Class l , UN No. 0135. Ferricyanides,ferrocyanides, alkaline thiocyanates and ammonium thiocyanates are not subject to the provisions of ADN. g

Lead salts and lead pigments which, when mixed in a ratio of 1:1,000 with O.07M hydrochloric acid and stirred for one hour at a temperature of 23 "C 2 "C, exhibit a solubility of 5% or less, are not subject to the provisions of ADN.

*

h

Articles impregnated with this pesticide, such as fibreboard plates, paper strips, cotton-wool balls, sheets ofplastics material, in hermetically closed wrappings, are not subject to the provisions of ADN.

- 105 -

2.2.61.3

List of collective entries (cont'd)

Toxic substances without subsidiary risk(s) (cont'd) 'esticides (cont'd) 2757 2759 2761 2763 2771 2775 2777

amples

T8

Mher toxic substances

'

T9

Toxic substances & y

Liquid

CARBAMATE PESTICIDE, SOLID, TOXIC ARSENICAL PESTICIDE. SOLID, TOXIC ORGANOCHLORINE PESTICIDE, SOLID, TOXIC TRIAZINE PESTICIDE, SOLID, TOXIC THIOCARBAMATE PESTICIDE. SOLID, TOXIC COPPER BASED PESTICIDE, SOLID, TOXIC MERCURY BASED PESTICIDE, SOLID, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC BIPYRIDILIUM PESTICIDE, SOLID, TOXIC ORGANOPHOSPHORUS PESTICIDE. SOLID. TOXIC ORGANOTIN PESTICIDE, SOLID, TOXIC COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC ALUMINIUM PHOSPHIDE PESTICIDE PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC PYRETHROID PESTICIDE, SOLID, TOXIC PESTICIDE, SOLID. TOXIC, N 0 S

l33 l 5 CHEMICAL SAMPLE, TOXIC

3243 SOLIDS CONTAINING TOXIC LIQUID, N.O.S.

subsidiary risk(s)

'.

TF1

MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. ISOCYANATES. TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION, TOXIC. FLAMMABLE. N.O.S. MTRILES, TOXIC. FLAMMABLE, N.O.S. ORGANOPHOSPHORUS COMPOUND. TOXIC. FLAMMABLE, N.O.S. TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 d i m 3and saturated vapour concentration greater than or equal to 500 LCXI TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an Inhalation toxicity lower than or equal to 1000 d i d and saturated vapour concentration greater than or equal to 10 LCso TOXlC LIQUID. FLAMMABLE, ORGANIC, N.O.S.

con/ 'd on next page,

h

Articles impregnated with this pesticide, such as fibreboard plates, paper strips, cotton-wool balls, sheets ofplastics material, in hermetically closed wrappings, are not subject to the provisions ofADN. i

Mixtures of solids which are not subject to the provisions of ADN and of toxic liquids may be carried under UN No. 3243 without first applying the classiJication criteria of Class 6.1, provided there is no JFee liquid visible at the time the substance is loaded or at the time the packaging, container or transport unit is closed. Each packaging shall correspond to a design type that has passed a leakproofness test at the packing group 11level. This entry shall not be used for solids containing apacking group I liquid. Highly toxic or toxic, flammable liquids having aflash-point below 23 "C excluding substances which are highly toxic on inhalation, i.e. UN Nos. 1051, 1092, 1098, 11 43, 11 63, 1182, 11 85, 1238, 1239, 1244, 1251, 1259, l61 3, l61 4, 1695, 1994, 2334, 2382, 2407, 2438, 2480,2482, 2484, 2485, 2606, 2929, 3279 and 3294 are substances of Class 3. k

Flammable liquids, slightly toxic, with the exception of substances and preparations used as pesticides, having aflash-point between 23 "C and 60 'C inclusive, are substances of Class 3.

2.2.61.3

List of collective entries (cont 'd)

Toxic substances

subsidiary risk(s) (cont 'd)

2991 2993 2995 2997 3005 3009 301 1 3013 3015 3017 3019 3025 3347 3351 2903

pesticides,

point not less than

1700 2930 iolid, self-heating '

l+

r

CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE MERCURY BASED PESTICIDE. LIQUID. TOXIC. FLAMMABLE SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N 0 S TEAR GAS CANDLES TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S.

3124 TOXIC SOLID, SELF-HEATING, N.O.S.

1

3385 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an inhalation toxiciq lower than or equal to 200 ml/m3and saturated vapour concentration greater than or equal ta 500 LCso 3386 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an inhalation toxicit4 lower than or equal to 1000 d i m 3 and saturated vapour concentration greater than or equal to 10 LC5o 3123 TOXIC LIQUID, WATER-REACTIVE,N.O.S.

liquid

TW1

solid"

TW2

13125 TOXIC SOLID, WATER-REACTIVE, N.O.S.

iquid

TO1

3387 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/rn3and saturated vapour concentration greater than or equal to 500 LCSo 3388 TOXIC BY INHALATION LIQUID, OXIDIZING. N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3and saturated vapour concentration greater than or equal to 10 LCSo 3122 TOXIC LIQUID, OXIDIZING, N.O.S.

TO2

13086 TOXIC SOLID, OXIDIZING, N.O.S.

Ixidizin solid

J

1

I

I liquid

:orroive "

TC1

3277 CHLOROFORMATES, TOXIC, CORROSIVE. N.O.S. 3361 CHLOROSILANES. TOXIC, CORROSIVE. N.O.S. 3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 mlid and saturated vapour concentration greater than or equal to 500 LC5n 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 dim' and saturated vapour concentration greater than or equal to 10 LC5o 2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S.

:c 12928

TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S.

1

cont 'd on next page)

C

Self-heating substances, slightly toxic and spontaneously combustible organometallic compounds, are substances of Class 4.2. Water-reactive substances, slightly toxic, and water-reactive organometallic compounds, are substances of Class 4.3.

'

Oxidizing substances, slightly toxic, are substances of Class 5.1.

"

Substances slightly toxic and slightly corrosive, are substances of Class 8.

Metal phosphides assigned to UN Nos. 1360, 1397, 1432, 1714, 2011 and 2013 are substances of Class 4.3. - 107 -

List of collective entries (cont 'd)

2.2.61.3

i subsidiary risk(s) (cont 'd) Toxic substances y&

Corrosive " TC (cun/'ciy organic (con/'dl solid

TC2

12928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S.

liquid

TC3

3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an Inhalation toxicity lower than or equal to 200 d i m 3 and saturated vapour concentration greater than or equal to 500 LCSo 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LCx 3289 TOXIC LIQUID, CORROSIVE, INORGANIC. N.O.S.

TCI

13290 TOXIC SOLID. CORROSIVE. INORGANIC. N O.S.

iuorganic lsoUd Flammable, corrosive TFC

m

12742 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 3362 CHLOROSILANES. TOXIC, CORROSIVE, FLAMMABLE, N.O.S. (No other collective entry available; if need be, classification under a collective entry with a classification code to be determined according to the table of precedence of hazards in 2.1.3.10)

Substances slightly toxic and slightly corrosive, are substances of Class 8.

- 108 -

I I

2.2.62

Class 6.2

Infectious substances

2.2.62.1

Criteria

2.2.62.1.1

The heading of Class 6.2 covers infectious substances. For the purposes of ADN, infectious substances are substances which are known or are reasonably expected to contain pathogens. Pathogens are defined as micro-organisms (including bacteria, viruses, rickettsiae, parasites, fungi) and other agents such as prions, which can cause disease in humans or animals. NOTE l : Genetically modified micro-organisms and organisms, biological products, diagnostic specimens and infected live animals shall be assigned to this Class ifthe?, meet the conditionsfor this Class. NOTE 2: Toxinsfiom plant, animal or bacterial sources which do not contain any infectious substances or organisms or which are not contained in them are substances of Class 6.1, UN No. 31 72 or 3462.

2.2.62.1.2

Substances of Class 6.2 are subdivided as follows: I1

Infectious substances affecting humans;

I2

Infectious substances affecting animals only;

I3

Clinical waste;

I4

Biological substances.

Definitions

2.2.62.1.3

For the purposes of ADN, "Biological products" are those products derived from living organisms which are manufactured and distributed in accordance with the requirements of appropriate national authorities, which may have special licensing requirements, and are used either for prevention, treatment, or diagnosis of disease in humans or animals, or for development, experimental or investigational purposes related thereto. They include, but are not limited to, finished or unfinished products such as vaccines; "Czrltures" are the result of a process by which pathogens are intentionally propagated. This definition does not include human or animal patient specimens as defmed in this paragraph; "Genetically modz9ed micro-organisms and organisms " are micro-organisms and organisms in which genetic material has been purposely altered through genetic engineering in a way that does not occur naturally; "Medical or clinical wastes" are wastes derived from the medical treatment of animals or humans or from bio-research: "Patient specimens" are human or animal materials, collected directly from humans or animals, including, but not limited to, excreta, secreta, blood and its components, tissue and tissue fluid swabs, and body parts being carried for purposes such as research, diagnosis, investigational activities, disease treatment and prevention.

Classijication

2.2.62.1.4

Infectious substances shall be classified in Class 6.2 and assigned to UN Nos 2814, 2900, 3291 or 3373, as appropriate. Infectious substances are divided into the following categories:

2.2.62.1.4.1

Category A: An infectious substance which is carried in a form that, when exposure to it occurs, is capable of causing permanent disability, life-threatening or fatal disease in otherwise healthy humans or animals. Indicative examples of substances that meet these criteria are given in the table in this paragraph. NOTE : An exposure occurs when an infectious substance is released outside of the protective packaging, resulting in physical contact with humans or animals.

(a)

Infectious substances meeting these criteria which cause disease in humans or both in humans and animals shall be assigned to UN No. 2814. Infectious substances which cause disease only in animals shall be assigned to UN No. 2900;

(b)

Assignment to UN No. 2814 or UN No. 2900 shall be based on the known medical history and symptoms of the source human or animal, endemic local conditions, or professional judgement concerning individual circumstances of the source human or animal.

NOTE l : The proper shipping name for UN No. 2814 is "INFECTIOUS SUBSTANCE, AFFECTING HUMANS". The proper shipping name for UN No. 2900 is "INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only". NOTE 2: The following table is not exhaustive. Infectious substances, including new or emergingpathogens, which do not appear in the table but which meet the same criteria shall be assigned to Category A. In addition, ifthere is doubt as to whether or not a substance meets the criteria it shall be included in Category A. NOTE 3: In the following table, the micro-organisms written in italics are bacteria, mycoplasmas, rickettsia orfungi.

INDICATIVE EXAMPLES OF INFECTIOUS SUBSTANCES INCLUDED IN CATEGORY A IN ANY FORM UNLESS OTHERWISE INDICATED (2.2.62.1.4.1)

Micro-organism Bacillus anthracis (cultures only) Brucella abortus (cultures only) Brucella melitensis (cultures only) Brucella suis (cultures only) Burkholderia mallei - Pseudomonas mallei - Glanders (cultures only) Burkholderia pseudomallei - Pseudomonas pseudomallei (cultures only) Chlarnydia psittaci - avian strains (cultures only) Clostridium botulinum (cultures only) Coccidioides immitis (cultures only) Coxiella burnetii (cultures only) Crimean-Congo haemorrhagic fever virus Dengue virus (cultures only) Eastern equine encephalitis virus (cultures only) Escherichia coli, verotoxigenic (cultures only)* Ebola virus Flexal virus Francisella tularensis (cultures only) Guanarito virus Hantaan virus Hantaviruses causing haeinorrhagicfever with renal syndrome Hendra virus Hepatitis B virus (cultures only) Herpes B virus (cultures only) Human immunodeficiency virus (cultures only) Highly pathogenic avian influenza virus (cultures only) Japanese Encephalitis virus (cultures only) Junin virus Kyasanur Forest disease virus Lassa virus Machupo virus Marburg virus Monkeypox virus Mycobacteriurn tuberculosis (cultures only)* Nipah virus Olnsk haemorrhagic fever virus Poliovirus (cultures only) Rabies virus (cultures only) Rickettsia prowazekii (cultures only) Rickettsia rickettsii (cultures only) Rift Valley fever virus (cultures only) Russian spring-summer encephalitis virus (cultures only) Sabia virus Shigella dysenteriae type I (cultures only)* Tick-borne encephalitis virus (cultures only) Variola virus Venezuelan equine encephalitis virus (cultures only) West Nile virus (cultures only) Yellow fever virus (cultures only) Yersinia pestis (cultures only)

- 111 -

]

INDICATIVE EXAMPLES OF INFECTIOUS SUBSTANCES INCLUDED IN CATEGORY A IN ANY FORM UNLESS OTHERWISE INDICATED (2.2.62.1.4.1)

UN Number and name UN No. 2900 Infectious substances affecting animals only

Micro-organism African swine fever virus (cultures only) Avian paramyxovirus Type 1 - Velogenic Newcastle disease virus (cultures only) Classical swine fever virus (cultures only) Foot and mouth disease virus (cultures only) Lumpy skin disease virus (cultures only) Mycoplasma mycoides - Contagious bovine pleuropneumonia (cultures only) Peste des petits ruminants virus (cultures only) Rinderpest virus (cultures only) Sheep-pox virus (cultures only) Goatpox virus (cultures only) Swine vesicular disease virus (cultures only) Vesicular stomatitis virus (cultures only)

-*/Nevertheless, when the cultures are intendedfor diagnostic or clinical purposes, they may be classz~edas infectious substances of Category B.

Category B: An infectious substance which does not meet the criteria for inclusion in Category A. Infectious substances in Category B shall be assigned to UN No. 3373. NOTE: The proper shipping name of UN No. 3373 is CATEGORY B".

"BIOLOGICAL SUBSTANCE,

Exemptions

Substances which do not contain infectious substances or substances which are unlikely to cause disease in humans or animals are not subject to the provisions of ADN unless they meet the criteria for inclusion in another class. Substances containing microorganisms which are non-pathogenic to humans or animals are not subject to ADN unless they meet the criteria for inclusion in another class. Substances in a form that any present pathogens have been neutralized or inactivated such that they no longer pose a health risk are not subject to ADN unless they meet the criteria for inclusion in another class. Substances where the concentration of pathogens is at a level naturally encountered (including foodstuff and water samples) and which are not considered to pose a significant risk of infection are not subject to ADN unless they meet the criteria for inclusion in another class. Dried blood spots, collected by applying a drop of blood onto absorbent material, or faecal occult blood screening tests and blood or blood components which have been collected for the purposes of transfusion or for the preparation of blood products to be used for transfusion or transplantation and any tissues or organs intended for use in transplantation are not subject to the provisions of ADN. Human or animal specimens for which there is minimal likelihood that pathogens are present are not subject to ADN if the specimen is carried in a packaging which will prevent any

leakage and which is marked with the words "Exempt human specimen" or "Exempt animal specimen", as appropriate. The packaging is deemed to comply with the above requirements if it meets the following conditions: (a)

The packaging consists of three components: (i)

a leak-proof primary receptacle(s);

(ii)

a leak-proof secondary packaging; and

(iii)

an outer packaging of adequate strength for its capacity, mass and intended use, and with at least one surface having minimum dimensions of 100 mm X 100 mm;

(b)

For liquids, absorbent material in sufficient quantity to absorb the entire contents is be placed between the primary receptacle(s) and the secondary packaging so that, during carriage, any release or leak of a liquid substance will not reach the outer packaging and will not compromise the integrity of the cushioning material;

(c)

When multiple fragile primary receptacles are placed in a single secondary packaging, they are either individually wrapped or separated to prevent contact between them.

NOTE: An element of professional judgment is required to determine if a substance is exempt under this paragraph. Thatjudgment should be based on the known medical history, symptoms and individual circumstances of the source, human or animal, and endemic local conditions. Examples of specimens which may be carried under this paragraph include the blood or urine tests to monitor cholesterol levels, blood glucose levels, hormone levels, or prostate speczjk antibodies (PSA); those required to monitor organ function such as heart, liver or kidney function for humans or animals with non-infectious diseases, or for therapeutic drug monitoring; those conducted for insurance or employment purposes and are intended to determine the presence of drugs or alcohol; pregnancy test; biopsies to detect cancer; and antibody detection in humans or animals. 2.2.62.1.62.2.62.1.8

(Reserved).

2.2.62.1.9

Biological products

For the purposes of ADN, biological products are divided into the following groups: (a)

those which are manufactured and packaged in accordance with the requirements of appropriate national authorities and carried for the purposes of final packaging or distribution, and use for personal health care by medical professionals or individuals. Substances in this group are not subject to the provisions of ADN;

(b)

those which do not fall under paragraph (a) and are known or reasonably believed to contain infectious substances and which meet the criteria for inclusion in Category A or Category B. Substances in this group shall be assigned to UN No. 28 14, UN No. 2900 or UN No. 3373, as appropriate.

NOTE: Some licensed biological products may present a biohazard only in certain parts of the world. In that case, competent authorities nzciy require these biological products to be in compliance with local requirements for infectious substances or may impose other restrictions. - 113-

Genetically modzj?ed micro-organisms and organisms

Genetically modified micro-organisms not meeting the definition of infectious substance shall be classified according to section 2.2.9. Medical or clinical wastes

Medical or clinical wastes containing Category A infectious substances shall be assigned to UN No. 2814 or UN No. 2900 as appropriate. Medical or clinical wastes containing infectious substances in Category B shall be assigned to UN No. 3291. NOTE: Medical or clinical wastes assigned to number 18 01 03 (Wastes from human or animal health care and/or related research - wastes fiom natal care, diagnosis, treatment or prevention of disease in humans - wastes whose collection and disposal is subject to special requirement in order to prevent infection) or 18 02 02 (Wastesj-om human or animal health care and/or related research - wastes from research, diagnosis, treatment or prevention of disease involving animals - wastes whose collection and disposal is subject to special requirements in order to prevent infection) according to the list of wastes annexed to the Commission Decision 2000/532/~C"5as amended, shall be classiJied according to the provisions set out in this paragraph, based on the medical or veterinary diagnosis concerning the patient or the animal.

Medical or clinical wastes which are reasonably believed to have a low probability of containing infectious substances shall be assigned to UN No. 3291. NOTE l : The proper shipping name for UN No. 3291 is "CLINICAL WASTE, UNSPECIFIED, N. O.S. " or "(BIO) MEDICAL WASTE, N. 0.S ''. or "REGULATED MEDICAL WASTE, N. 0.S.': NOTE 2: Notwithstanding the classzj?cation criteria set out above, medical or clinical wastes assigned to number 18 01 04 (Wastes fiom human or animal health care and/or related research - wastes from nata,?care, diagnosis, treatment or prevention of disease in humans - wastes whose collection and disposal is not subject to special requirements in order to prevent infection) or 18 02 03 (Wastes fiorn human or animal health care and/or related research - wastes fiom research, diagnosis, treatment or prevention of disease involving animals - wastes whose collection and disposal is not subject to special requirements in order to prevent infection) according to the list of wastes annexed to the Commission Decision 2 0 0 0 / 5 3 2 / ~ eas amended, are not subject to the provisions of ADN.

Decontaminated medical or clinical wastes which previously contained infectious substances are not subject to the provisions of ADN unless they meet the criteria for inclusion in another class. Medical or clinical wastes assigned to UN No. 3291 are assigned to packing group 11. Infected animals

Unless an infectious substance cannot be consigned by any other means, live animals shall not be used to consign such a substance. A live animal which has been intentionally infected 5

Commission Decision 2000/532/EC of 3 May 2000 replacing Decision 94/3/EC establishing a list of wastes pursuant to Article ](a) of Council Directive 75/442/EEC on waste and Council Decision 94/904/EC establishing a list of hazardous waste pursuant to Article 1(4) of Council Directive 91/689/EEC on hazardous waste ( O f f i a l Journal of the European Communities No. L 226 of 6 September 2000, Page 3). - 114-

and is known or suspected to contain an infectious substance shall only be carried under terms and conditions approved by the competent authority6. Animal carcasses affected by pathogens of Category A or which would be assigned to Category A in cultures only, shall be assigned to UN 2814 or UN 2900 as appropriate. Other animal carcasses affected by pathogens included in Category B shall be carried in accordance with provisions determined by the competent authority7. Substances not acceptedfor carriage

Live vertebrate or invertebrate animals shall not be used to carry an infectious agent unless the agent cannot be carried by other means or unless this carriage has been approved by the competent authority (see 2.2.62.1.12.1). List of collective entries

Effects on humans

I1

Effects on animals on1

I2

I3

14

2814

INFECTIOUS SUBSTANCE, AFFECTING HUMANS

2900

INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only

3291 3291 3291

CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BI0)MEDICAL WASTE, N O.S. or REGULATED MEDICAL WASTE, N.O.S.

3373

BIOLOGICAL SUBSTANCE, CATEGORY

Biological substances

6

Such regulations are contained in, e.g. Directive 91/628/EEC (Oficial Journal of the European Comniunities No. L 340 of I1 December 1991, p. 17) and in the Recommendations of the Council of Europe (Ministerial Committee) on the carriage of certain animal species. Regulations for dead infected animals are contained e.g. in Regulation (EC) No. 1774/2002 of the European Parliament and of the Council of 3 October 2002 laying down health rules concerning animal byproducts not intended for human consumption (Official Journal of the European Communities, No. L 273 of 10.10.2002, p. I). - 115 -

'

2.2.7

Class 7

Radioactive material

2.2.7.1

Definition of Class 7

2.2.7.1 .l

Radioactive material means any material containing radionuclides where both the activity concentration and the total activity in the consignment exceed the values specified in 2.2.7.7.2.1 to 2.2.7.7.2.6.

2.2.7.1.2

The following radioactive materials are not included in Class 7 for the purposes of ADN: Radioactive material that is an integral part of the means of transport; (Reserved); Radioactive material implanted or incorporated into a person or live animal for diagnosis or treatment; Radioactive material in consumer products which have received regulatory approval, following their sale to the end user; Natural material and ores containing naturally occurring radionuclides which are either in their natural state, or have only been processed for purposes other than for extraction of the radionuclides, and which are not intended to be processed for use of these radionuclides provided the activity concentration of the material does not exceed 10 times the values specified in 2.2.7.7.2.1 (b), or calculated in accordance with 2.2.7.7.2.2 to 2.2.7.7.2.6; Non-radioactive solid objects with radioactive substances present on any surfaces in quantities not in excess of the limit set out in the definition for "contamination" in 2.2.7.2. Definitions

A, means the activity value of special form radioactive material which is listed in Table 2.2.7.7.2.1 or derived in 2.2.7.7.2 and is used to determine the activity limits for the requirements of ADN. A? means the activity value of radioactive material, other than special form radioactive material, which is listed in Table 2.2.7.7.2.1 or derived in 2.2.7.7.2 and is used to determine the activity limits for the requirements of ADN. Approval Multilateral approval means approval by the relevant competent authority of the country of origin of the design or shipment, as applicable and also, where the consignment is to be carried through or into any other country, approval by the competent authority of that country. Unilateral approval means an approval of a design which is required to be given by the competent authority of the country of origin of the design only. If the country of origin is not a Contracting Party to ADN, the approval shall require validation by the competent authority of the first country Contracting Party to ADN reached by the consignment (see 6.4.22.6).

Confinement system means the assembly of fissile material and packaging components specified by the designer and agreed to by the competent authority as intended to preserve criticality safety. Containment system means the assembly of components of the packaging specified by the designer as intended to retain the radioactive material during carriage. Containination: Contamination means the presence of a radioactive substance on a surface in quantities in excess of 0.4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 0.04 Bq/cm2 for all other alpha emitters. Non-fixed contamination means contamination that can be removed from a surface during routine conditions of carriage. Fixed contamination means contamination other than non-fixed contamination. Criticality safety index (CS0 assigned to a package, overpack or container containing fissile material means a number which is used to provide control over the accumulation of packages, overpacks or containers containing fissile material. Design means the description of special form radioactive material, low dispersible radioactive material, package or packaging which enables such an item to be hlly identified. The description may include specifications, engineering drawings, reports demonstrating compliance with regulatory requirements, and other relevant documentation. Exclusive use means the sole use, by a single consignor, of a vehicle or of a large container, in respect of which all initial, intermediate and final loading and unloading is carried out in accordance with the directions of the consignor or consignee. Fissile material means uranium-233, uranium-23 5, plutonium-239, plutonium-24 1, or any combination of these radionuclides. Excepted from this definition is:

(a)

natural uranium or depleted uranium which is unirradiated, and

(b)

natural uranium or depleted uranium which has been irradiated in thermal reactors only.

Large container means a container which is not a small container according to the definitions of this Sub-section. Low dispersible radioactive material means either a solid radioactive material or a solid radioactive material in a sealed capsule, that has limited dispersibility and is not in powder form.

NOTE: Low dispersible radioactive material may be carried by air in Type B(U) or B(M) packages in quantities as authorisedfor the package design as specz9ed in the certzjkate of approval. This definition is included here since such packages carrying low dispersible radioactive material may also be carried by inland waterways. Low specific activity (LSA) material, see 2.2.7.3. Low toxicity alpha emitters are: natural uranium; depleted uranium; natural thorium; uranium-235 or uranium-238; thorium-232; thorium-228 and thorium-230 when contained in ores or physical and chemical concentrates; or alpha emitters with a half-life of less than 10 days.

Maximum normal operating pressure means the maximum pressure above atmospheric pressure at mean sea-level that would develop in the containment system in a period of one year under the conditions of temperature and solar radiation corresponding to environmental conditions in the absence of venting, external cooling by an ancillary system, or operational controls during carriage. Package in the case of radioactive material means the packaging with its radioactive contents as presented for carriage. The types of packages covered by ADN, which are subject to the activity limits and material restrictions of 2.2.7.7 and meet the corresponding requirements, are:

(a)

Excepted package;

(b)

Industrial package Type 1 (Type IP- 1 package);

(c)

Industrial package Type 2 (Type IP-2 package);

(d)

Industrial package Type 3 (Type IP-3 package);

(e)

Type A package;

(f)

Type B(U) package;

(h)

Type C package.

Packages containing fissile material or uranium hexafluoride are subject to additional requirements (see 2.2.7.7.1.7 and 2.2.7.7.1.8). NOTE: For '>ackages" for other dangerous goods see definitions under 1.2.1. Packaging in the case of radioactive material means the assembly of components necessary to enclose the radioactive contents completely. It may, in particular, consist of one or more receptacles, absorbent materials, spacing structures, radiation shielding and service equipment for filling, emptying, venting and pressure relief; devices for cooling, absorbing mechanical shocks, handling and tie-down, thermal insulation; and service devices integral to the package. The packaging may be a box, drum or similar receptacle, or may also be a container, tank or intermediate bulk container (IBC).

NOTE: For "packagings" for other dangerous goods see definitions under 1.2.1 Radiation level means the corresponding dose rate expressed in millisieverts per hour. Radioactive contents mean the radioactive material together with any contaminated or activated solids, liquids, and gases within the packaging. ShQment means the specific movement of a consignment from origin to destination. Small container means a container which has either any overall outer dimension less than 1.5 m, or an internal volume of not more than 3 m3. Special form radioactive material, see 2.2.7.4.1.

Specific activity of a radionuclide means the activity per unit mass of that nuclide. The specific activity of a material shall mean the activity per unit mass of the material in which the radionuclides are essentially uniformly distributed. Surface contaminated object (SCO), see 2.2.7.5. Transport index (TI) assigned to a package, overpack or container, or to unpackaged LSA-I or SCO-I, means a number which is used to provide control over radiation exposure. Unirradiated thorium means thorium containing not more than 10-' g of uranium-233 per gram of thorium-232. Unirradiated uranium means uranium containing not more than 2 X 103Bq of plutonium per gram of uranium-235, not more than 9 X 106Bq of fission products per gram of uranium-235 and not more than 5 X 10" g of uranium-236 per gram of uranium-235. Uranium - natural, depleted, enriched means the following: Natural uranium means uranium (which may be chemically separated) containing the naturally occurring distribution of uranium isotopes (approximately 99.28% uranium-238, and 0.72% uranium-235 by mass). Depleted uranium means uranium containing a lesser mass percentage of uranium-235 than in natural uranium. Enriched uranium means uranium containing a greater mass percentage of uranium-235 than 0.72%.

In all cases, a very small mass percentage of uranium-234 is present.

2.2.7.3

Low specific activity (LSA) material, determination of groups

2.2.7.3.1

Radioactive material which by its nature has a limited specific activity, or radioactive material for which limits of estimated average specific activity apply, is termed low specific activity or LSA material. External shielding materials surrounding the LSA material shall not be considered in determining the estimated average specific activity.

2.2.7.3.2

LSA material shall be in one of three groups: (a)

LSA-I uranium and thorium ores and concentrates of such ores, and other ores containing naturally occurring radionuclides which are intended to be processed for the use of these radionuclides; natural uranium, depleted uranium, natural thorium or their compounds or mixtures, providing they are unirradiated and in solid or liquid form; radioactive material for which the A? value is unlimited, excluding fissile material in quantities not excepted under 6.4.11.2 of ADR; or other radioactive material in which the activity is distributed throughout and the estimated average specific activity does not exceed 30 times the values for activity concentration specified in 2.2.7.7.2.1 to 2.2.7.7.2.6, excluding fissile material in quantities not excepted under 6.4.1 1.2 of ADR.

(b)

(c)

LSA-I1 (i)

water with tritium concentration up to 0.8 TBqIl; or

(ii)

other material in which the activity is distributed throughout and the estimated average specific activity does not exceed 1 0 - Az/g ~ for solids and gases, and 10-* A2/gfor liquids;

LSA-I11 - Solids (e.g. consolidated wastes, activated materials), excluding powders, in which: (i)

the radioactive material is distributed throughout a solid or a collection of solid objects, or is essentially uniformly distributed in a solid compact binding agent (such as concrete, bitumen, ceramic, etc.);

(ii)

the radioactive material is relatively insoluble, or it is intrinsically contained in a relatively insoluble matrix, so that, even under loss of packaging, the loss of radioactive material per package by leaching when placed in water for seven days would not exceed 0.1 A2; and

(iii) the estimated average specific activity of the solid, excluding any shielding material, does not exceed 2 X 1 A2/g. 2.2.7.3.3

LSA-I11 material shall be a solid of such a nature that if the entire contents of a package were subjected to the test specified in 2.2.7.3.4 the activity in the water would not exceed 0.1 A*.

2.2.7.3.4

LSA-I11 material shall be tested as follows: A solid material sample representing the entire contents of the package shall be immersed for 7 days in water at ambient temperature. The volume of water to be used in the test shall be sufficient to ensure that at the end of the 7 day test period the free volume of the unabsorbed and unreacted water remaining shall be at least 10% of the volume of the solid test sample itself. The water shall have an initial pH of 6-8 and a maximum conductivity of 1 mS/m at 20 "C. The total activity of the free volume of water shall be measured following the 7 day immersion of the test sample.

2.2.7.3.5

Demonstration of compliance with the performance standards in 2.2.7.3.4 shall be in accordance with 6.4.12.1 and 6.4.12.2 of ADR.

2.2.7.4

Requirements for special form radioactive material

2.2.7.4.1

Specialform radioactive material means either: (a)

an indispersible solid radioactive material; or

(b)

a sealed capsule containing radioactive material that shall be so manufactured that it can be opened only by destroying the capsule.

Special form radioactive material shall have at least one dimension not less than 5 mm. 2.2.7.4.2

Special form radioactive material shall be of such a nature or shall be so designed that if it is subjected to the tests specified in 2.2.7.4.4 to 2.2.7.4.8, it shall meet the following requirements: (a)

It would not break or shatter under the impact, percussion and bending tests 2.2.7.4.5 (a)(b)(c), 2.2.7.4.6 (a) as applicable;

- 120 -

(b)

It would not melt or disperse in the applicable heat test 2.2.7.4.5 (d) or 2.2.7.4.6 (b) as applicable; and

(c)

The activity in the water from the leaching tests specified in 2.2.7.4.7 and 2.2.7.4.8 would not exceed 2 kBq; or alternatively for sealed sources, the leakage rate for the volumetric leakage assessment test specified in I S 0 9978: 1992 "Radiation Protection Sealed Radioactive Sources - Leakage Test Methods", would not exceed the applicable acceptance threshold acceptable to the competent authority.

2.2.7.4.3

Demonstration of compliance with the performance standards in 2.2.7.4.2 shall be in accordance with 6.4.12.1 and 6.4.12.2 of ADR.

2.2.7.4.4

Specimens that comprise or simulate special form radioactive material shall be subjected to the impact test, the percussion test, the bending test, and the heat test specified in 2.2.7.4.5 or alternative tests as authorized in 2.2.7.4.6. A different specimen may be used for each of the tests. Following each test, a leaching assessment or volumetric leakage test shall be performed on the specimen by a method no less sensitive than the methods given in 2.2.7.4.7 for indispersible solid material or 2.2.7.4.8 for encapsulated material.

2.2.7.4.5

The relevant test methods are: Impact test: The specimen shall drop onto the target from a height of 9 m. The target shall be as defined in 6.4.14 of ADR; Percussion test: The specimen shall be placed on a sheet of lead which is supported by a smooth solid surface and struck by the flat face of a mild steel bar so as to cause an impact equivalent to that resulting from a free drop of 1.4 kg through 1 m. The lower part of the bar shall be 25 mm in diameter with the edges rounded off to a radius of (3.0 0.3) mm. The lead, of hardness number 3.5 to 4.5 on the Vickers scale and not more than 25 mm thick, shall cover an area greater than that covered by the specimen. A fresh surface of lead shall be used for each impact. The bar shall strike the specimen so as to cause maximum damage;

*

Bending test: The test shall apply only to long, slender sources with both a minimum length of 10 cm and a length to minimum width ratio of not less than 10. The specimen shall be rigidly clamped in a horizontal position so that one half of its length protrudes from the face of the clamp. The orientation of the specimen shall be such that the specimen will suffer maximum damage when its free end is struck by the flat face of a steel bar. The bar shall strike the specimen so as to cause an impact equivalent to that resulting from a free vertical drop of 1.4 kg through 1 m. The lower part of the bar shall be 25 mm in diameter with the edges rounded off to a radius of (3.0 0.3) mm;

*

Heat test: The specimen shall be heated in air to a temperature of 800°C and held at that temperature for a period of 10 minutes and shall then be allowed to cool. 2.2.7.4.6

Specimens that comprise or simulate radioactive material enclosed in a sealed capsule may be excepted from: The tests prescribed in 2.2.7.4.5 (a) and (b) provided the mass of the special form (a) radioactive material: (i)

is less than 200 g and they are alternatively subjected to the Class 4 impact test prescribed in IS0 29 19:1999 "Radiation protection - Sealed radioactive sources - General requirements and classification"; or

(ii)

(b)

is less than 500 g and they are alternatively subjected to the Class 5 impact test prescribed in I S 0 2919:1999 "Radiation protection - Sealed Radioactive Sources - General requirements and Classification; and

The test prescribed in 2.2.7.4.5 (d) provided they are alternatively subjected to the Class 6 temperature test specified in IS0 2919:1999 " Radiation protection - Sealed radioactive sources - General requirements and classification ".

For specimens which comprise or simulate indispersible solid material, a leaching assessment shall be performed as follows: The specimen shall be immersed for 7 days in water at ambient temperature. The volume of water to be used in the test shall be sufficient to ensure that at the end of the 7 day test period the free volume of the unabsorbed and unreacted water remaining shall be at least 10 % of the volume of the solid test sample itself. The water shall have an initial pH of 6-8 and a maximum conductivity of 1 mS/m at 20 'C; The water with specimen shall then be heated to a temperature of (50 maintained at this temperature for 4 hours;

* 5) "C and

The activity of the water shall then be determined; The specimen shall then be kept for at least 7 days in still air at not less than 30 "C and relative humidity not less than 90%; The specimen shall then be immersed in water of the same specification as in (a) above and the water with the specimen heated to (50 h 5) "C and maintained at this temperature for 4 hours; The activity of the water shall then be determined. For specimens which comprise or simulate radioactive material enclosed in a sealed capsule, either a leaching assessment or a volumetric leakage assessment shall be performed as follows: (a)

The leaching assessment shall consist of the following steps: (i)

the specimen shall be immersed in water at ambient temperature. The water shall have an initial pH of 6-8 with a maximum conductivity of 1 mS/m at 20 'C;

(ii)

the water and specimen shall be heated to a temperature of (50 maintained at this temperature for 4 hours;

* 5) "C and

(iii) the activity of the water shall then be determined;

(b)

(iv)

the specimen shall then be kept for at least 7 days in still air at not less than 30 "C and relative humidity of not less than 90%;

(v)

the process in (i), (ii) and (iii) shall be repeated;

The alternative volumetric leakage assessment shall comprise any of the tests prescribed in I S 0 9978:1992 "Radiation Protection - Sealed radioactive sources Leakage test methods", which are acceptable to the competent authority.

Surface contaminated object (SCO), determination of groups Surface contaminated object (SCO) means a solid object which is not itself radioactive but which has radioactive material distributed on its surfaces. SCO is classified in one of two groups:

(a)

(b)

SCO-I: A solid object on which: (i)

the non-fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm') does not exceed 4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 0.4 Bq/cm2 for all other alpha emitters; and

(ii)

the fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm') does not exceed 4 X 1o4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 4 X 103Bq/cm2 for all other alpha emitters; and

(iii)

the non-fixed contamination plus the fixed contamination on the inaccessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 4 X 104 ~ q / c m 'for beta and gamma emitters and low toxicity alpha emitters, or 4 X 103Bq/cm2for all other alpha emitters;

SCO-11: A solid object on which either the fixed or non-fixed contamination on the surface exceeds the applicable limits specified for SCO-I in (a) above and on which: (i)

the non-fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm') does not exceed 400 Bq/cm2for beta and gamma emitters and low toxicity alpha emitters, or 40 Bq/cm2 for all other alpha emitters; and

(ii)

the fixed contamination on the accessible surface, averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 8 X 105Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 8 X 104Bq/cm2 for all other alpha emitters; and

(iii)

the non-fixed contamination plus the fixed contamination on the inaccessible surface averaged over 300 cm' (or the area of the surface if less than 300 cm2) does not exceed 8 X 105Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 8 X 1o4Bq/cm2for all other alpha emitters.

2.2.7.6

Determination of transport index (TI) and criticality safety index (CSI)

2.2.7.6.1

Determination of transport index

2.2.7.6.1.1

The transport index (TI) for a package, overpack or container, or for unpackaged LSA-I or SCO-I, shall be the number derived in accordance with the following procedure: (a)

Determine the maximum radiation level in units of millisieverts per hour (mSv/h) at a distance of 1 m from the external surfaces of the package, overpack, container, or unpackaged LSA-I and SCO-I. The value determined shall be multiplied by 100 and the resulting number is the transport index. For uranium and thorium ores and their concentrates, the maximum radiation level at any point l m from the external surface of the load may be taken as: 0.4 mSv/h

for ores and physical concentrates of uranium and thorium;

- 123 -

0.3 mSv/h

for chemical concentrates of thorium;

0.02 mSvih

for chemical concentrates of uranium, other than hexafluoride;

uranium

(b)

For tanks, containers and unpackaged LSA-I and SCO-I, the value determined in step (a) above shall be multiplied by the appropriate factor from Table 2.2.7.6.1 .l;

(C)

The value obtained in steps (a) and (b) above shall be rounded up to the first decimal place (e.g. 1.13 becomes 1.2), except that a value of 0.05 or less may be considered as zero. Table 2.2.7.6.1.1 Multiplication factor for tanks, containers and unpackaged LSA-I and SCO-I

Size of load a size of load I 1 m2 < size of load I 5 m' 1 m' 5 m' < size of load I 20 m2 20 m2 < size ofload a

Multiplication factor 1 2 3 10

Largest cross-sectional area of the load being measured.

The transport index for each overpack, container, vehicle shall be determined as either the sum of the TIs of all the packages contained, or by direct measurement of radiation level, except in the case of non-rigid overpacks for which the transport index shall be determined only as the sum of the TIs of all the packages. Determination of criticality safety index (CSI)

The criticality safety index (CSI) for packages containing fissile material shall be obtained by dividing the number 50 by the smaller of the two values of N derived in 6.4.1 1.11 and 6.4.11.12 of ADR (i.e. CS1 = 50/N). The value of the criticality safety index may be zero, provided that an unlimited number of packages is subcritical (i.e. N is effectively equal to infinity in both cases). The criticality safety index for each overpack or container shall be determined as the sum of the CSIs of all the packages contained. The same procedure shall be followed for determining the total sum of the CSIs in a consignment or aboard a conveyance. Activily limits and material restrictions Contents limits for packages

General The quantity of radioactive material in a package shall not exceed the relevant limits for the package type as specified below.

Excepted packages For radioactive material other than articles manufactured of natural uranium, depleted uranium or natural thorium, an excepted package shall not contain activities greater than the following: (a)

Where the radioactive material is enclosed in or is included as a component part of an instrument or other manufactured article, such as a clock or electronic apparatus, the limits specified in columns 2 and 3 of Table 2.2.7.7.1.2.1 for each individual item and each package, respectively; and

(b)

Where the radioactive material is not so enclosed in or is not included as a component of an instrument or other manufactured article, the package limits specified in column 4 ofTable2.2.7.7.1.2.1. Table 2.2.7.7.1.2.1 Activity limits for excepted packages

Physical state of contents

I

lnstruments or article

Materials

I

Package limits

Item limits a

Package limits a

Solids

special form other form Liquids Gases

tritium special form other forms a

For mixtures of radionuclides, see 2.2.7.7.2.4to 2.2.7.7.2.6.

For articles manufactured of natural uranium, depleted uranium or natural thorium, an excepted package may contain any quantity of such material provided that the outer surface of the uranium or thorium is enclosed in an inactive sheath made of metal or some other substantial material. Industrial packages The radioactive contents in a single package of LSA material or in a single package of SCO shall be so restricted that the radiation level specified in 4.1.9.2.1 of ADR shall not be exceeded, and the activity in a single package shall also be so restricted that the activity limits for a vehicle specified in 7.5.11, CV33 (2) of ADR shall not be exceeded. Type A packages Type A packages shall not contain activities greater than the following: (a)

For special form radioactive material - A,; or

For all other radioactive material - A?.

(b) 2.2.7.7.1.4.2

For mixtures of radionuclides whose identities and respective activities are known, the following condition shall apply to the radioactive contents of a Type A package:

where B(i) is the activity of radionuclide i as special form radioactive material and Al(i) is the AI value for radionuclide i; and C(j) is the activity of radionuclide j as other than special form radioactive material and A2(j) is the A2 value for radionuclide j. 2.2.7.7.1.5

Type B(U) and Type B(M) packages

2.2.7.7.1.5.1

Type B(U) and Type B(M) packages shall not contain: (a)

activities greater than those authorized for the package design;

(b)

radionuclides different from those authorized for the package design; or

(c)

contents in a form, or a physical or chemical state different from those authorized for the package design;

as specified in their certificates of approval. 2.2.7.7.1.6

Type C packages

NOTE: Type C packages may be transported by air carrying radioactive material in quantities exceeding either 3 OOOAI or 100 000A2 ,whichever is the lower for special form radioactive material, or 3 000A2for all other radioactive material. Whilst Type C packages are not required for carriage of radioactive material by inland waterways in such quantities (Type B(U) or Type B(M) packages szcffice), the following requirements are presented since such packages may also be carried by inland waterways. Type C packages shall not contain: (a)

activities greater than those authorized for the package design;

(b)

radionuclides different from those authorized for the package design; or

(c)

contents in a form, or physical or chemical state different from those authorized for the package design;

as specified in their certificates of approval. 2.2.7.7.1.7

Packages containing fissile material Unless excepted by 6.4.11.2 of ADR, packages containing fissile material shall not contain: (a)

A mass of fissile material different from that authorized for the package design;

(b)

Any radionuclide or fissile material different from those authorized for the package design; or - l26 -

(c)

Contents in a form or physical or chemical state, or in a spatial arrangement, different from those authorized for the package design;

as specified in their certificates of approval where appropriate. 2.2.7.7.1.8

Packages containing uranium hexafluoride

(a)

Packages containing uranium hexafluoride shall not contain: a mass of uranium hexafluoride different from that authorized for the package design;

(b)

a mass of uranium hexafluoride greater than a value that would lead to an ullage smaller than 5 % at the maximum temperature of the package as specified for the plant systems where the package shall be used; or

(c)

uranium hexafluoride other than in solid form or at an internal pressure above atmospheric pressure when presented for carriage.

2.2.7.7.2

Activity levels

2.2.7.7.2.1

The following basic values for individual radionuclides are given in Table 2.2.7.7.2.1: (a)

AlandA2inTBq;

(b)

Activity concentration for exempt material in Bqlg; and

(c)

Activity limits for exempt consignments in Bq.

Table 2.2.7.7.2.1 Radionuclide (atomic number)

Actinium (89) Ac-225 (a) Ac-227 (a)

Activity concentration for exempt material

I

I I

(W

(WR)

I 9~10-lI 8~10-l

6 ~ 1 0 - ~ 9 ~ 1 0 - ~

6 H 10-'

5 H 10-'

2 H 10'

6 H 10-'

1 H 10-'

1 X 10-'

Am-24 1

1 X 10'

1 X IO-~

Am-242m (a)

1 X lol

1 X 10"

Am-243 (a)

5 X 10'

1 X 10"

10'

2 X 10'

Ac-228

Activity limit for an exempt consignment

Silver (47)

Ag- l 1Om (a) Ag-l l l Aluminium ( 13) AI-26 Americium (95)

Argon ( l 8)

Ar-39

4

Ar-4 1

3 X 10-'

3

X

10-'

As-72

3 X 10-'

3

X

10~'

As-73

4 X 10'

4

X

10'

As-74

1 X 10'

9

X

10-I

As-76

3 X 10-'

3 X 10-I

2 X 10'

5 X 10~'

X

Arsenic (33)

Astatine (85) At-2 l l (a)

X

10' (b)

1 X loO(b)

X

1o4(b)

1 X 103(b)

Radionuclide (atomic number)

Activity concentration for exempt material (Wg)

Activity limit for an exempt consignment (Jw

2 X loo

1 X 10'

1 X 107

1 X 10'

1 X 10'

1 X 10'

1 X 106

Au- 195

1 X 10'

6 X 10'

1 X 10'

1 X lo7

Au- 199

l

10'

6 X 10-'

1 X 102

1 X 106

A1

A2

(TW

(TW

AU-l93

7 X loo

Au- l94

Gold (79)

X

Barium (56) Ba-131 (a)

2 X 10'

2 X 10'

1 X 102

1 X 106

Ba- 133

3

3

1 X 102

1 X 106

Ba-133m

2 X 10'

6 X 10-'

Ba- 140 (a)

5 X 10-'

3 X 10-'

1 X 10' (b)

1 X lo5 (b)

X

10'

X

10'

l

X

10'

1 X 106

Beryllium (4) Be-7

2

10'

2 X 10'

1 X lo3

1 X lo7

Be- l 0

4 X 10'

6 X 10-'

1 X lo4

1 X 106

Bi-205

7 X 10-I

7 X 10-'

1 X lol

1 X 106

Bi-206

3 X 10"

3 X 10-'

1 X 10'

1 X lo5

Bi-207

7 X 10-I

7 X 10-'

1 X 10'

1 X 106

Bi-2 10

1 X 10'

6 X 10-'

1 X lo3

1 X 106

Bi-2l0m (a)

6

10-'

2 X 10-'

1 X 10'

1 X lo5

Bi-2 12 (a)

7 X 10-I

6 X 10-'

1 X lol(b)

1 X lo5 (b)

Bk-247

8 X 10'

8 X lo4

1 X 10'

1 X lo4

Bk-249 (a)

4

10'

3 X 10-'

1 X 103

1 X 106

C-l l

1 X 10'

6 X 10-'

1 X 10'

1 X 106

C-14

4

10'

3 X 100

1 X 104

1 X 107

X

Bismuth (83)

X

Berkelium (97)

X

Bromine (35)

Carbon (6)

X

l I

Radionuclide (atomic number)

l

AI

A2

Unlimited

Unlimited

Activity concentration for exempt material

Activity limit for an exempt consignment ( W

Calcium (20) Ca-4 1 Ca-45

4

Ca-47 (a)

3 X loo

X

10'

I

X

loo

3 X 10-l

1 X 105 1 X 104 1 X 10'

Cadmium (48) Cd- 109 Cd-113m

4 X 10'

Cd- 115 (a)

3 X loo

Cd-1 15m

5 X 10-l

Cerium (58)

Ce- 143 Ce-144 (a)

I

9x10-' 2 X 10“

Californium (98) Cf-248

4

Cf-249

3 X loo

Cf-250

2 X 10'

Cf-25 1

7 X loo

Cf-252

1 X 10-'

X

10'

Cf-253 (a) Cf-254

1 X 10"

Chlorine (17) Cl-36

l

Cl-3 8

2 X 10-'

X

10'

1 X lo5 (b)

Activity concentration for exempt material (Bqk)

Curium (96)

Cm-24 1

2 X loo

1 X loo

Cm-242

4

lol

1 X 10-'

Cm-243

9 X loo

1 X 10"

Cm-244

2

10'

2 X 10"

Cm-245

9 X loo

9 X 10"

Cm-246

9 X loo

9 X 10"

Cm-247 (a)

3 X loo

1 X 10"

CO-55

5 X 10-'

5 X 10-'

CO-56

3 X 10-'

3

CO-57

I

10'

1 X 10'

CO-58

1 X loo

1 X loo

CO-58m

4

X

10'

4 X 10'

CO-60

4

X

10-'

4

X

X

Cobalt (27)

Chromium (24)

X

X

X

10-'

10-'

I 3 X 10'

3 X 10'

CS-129

4

loo

4 X loo

CS-131

3 X 10'

3 X 10'

CS-132

1 X loo

1 X loo

CS-134m

4

10'

6 X 10-'

CS-135

4 X 10'

1 X loo

CS-136

5 X 10-l

5 X 10-'

CS-137 (a)

2 X loo

6 X 10-'

Cr-5 1 Caesium (55)

X

X

1 X 10' (b)

Activity limit for an exempt consignment ( W

Radionuclide (atomic number)

Copper (29)

Activity concentration for exempt material

I 1 X 10'

7 X 10-l

Dy-159

2 X 10'

2 X 10'

Dy-165

9 X 10-'

6 X 10-'

Cu-67 Dysprosium (66)

Dy- 166 (a) Erbium (68) Er- 169

I

I

I

4 X lol

I

I

l

X

loo

I

Europium (63)

Eu- l50(short lived) Eu- 15O(long lived)

I

7 X 10-I

I

I

7 X 10-l

I

Eu-1 55

2 X 10'

3 X loo

Eu- 156

7 X 10-l

7 X 10-l

Fe-52 (a)

3 X 10-l

3

Fe-55

4 X 10'

4 X 10'

Fe-59

9 X 10-l

9 X 10-'

Fe-60 (a)

4 X 10'

2 X 10"

Fluorine (9)

Iron (26) X

10-'

Activity limit for an exempt consignment ( W

Radionuclide (atomic number)

A1

A2

(TBq) Gallium (3 1)

Ga-68

5 X 10-'

5

Ga-72

4

4 X 10-'

X

10-'

X

10-'

Gadolinium (64) Gd- 146 (a)

5 X 10-'

5

Gd- 148

2

2 X 10‘~

Gd- 153

1 X 10'

1 Germanium (32) 1 Ge-68 (a)

I I

X

10'

X

10-'

9 X 10'

5x10.'

3 X 10-'

3 X 10-l

Hf- 172 (a)

6 X 10-'

6 X 10-'

Hf- 175

3 X 10'

3 X 10'

Ge-77 Hafnium (72)

1 Hf-182

I Unlimited

Unlimited

Hg- 194 (a)

1 X 10'

1 X 10'

Hg- 195m (a)

3

10'

7 X 10"

Hg- 197

2 X 10'

1 X 10'

Hg- l 97m

1 X 10'

4 X 10-I

4

4

X

Holmium (67) Ho- l66 Ho- l66m

X

10-'

16x10-l

X

10-l

15x10-I

Activity concentration for exempt material (Bqk)

Activity limit for an exempt consignment (W)

Activity concentration for exempt material (Wg)

Radionuclide (atomic number)

Unlimited 3 X loo 4 X 10-l

1-135 (a) Indium (49) In-l l l In-1 l3m In- 114m (a)

1 Iridium (77) 1 Ir- l 89 (a) Ir- 192 Ir- 194 Potassium ( 19)

Unlimited

Activity limit for an exempt consignment ( W

Radionuclide (atomic number)

Activity concentration for exempt material (Bqk)

(TW Lanthanum (57)

La- 140 Lutetium (7 1)

Lu- 174

9 X 10'

9 X 10'

Lu- l 74m

2 X 10'

1 X 10'

Lu-1 77

3 X 10'

7 X 10-l

3

3 X 10"

Magnesium ( 12) Mg-28 (a)

X

10-'

Manganese (25)

I Unlimited Mn-54

1 X 10'

Mn-56

3

X

-- -

Unlimited

10-'

Molybdenum (42) MO-93

4 X 10'

MO-99(a)

1 X 10'

Nitrogen (7)

Sodium (1 1) Na-22

5 X 10-'

5 X 10-'

Na-24

2 X 10-'

2

Niobium (4 1)

X

10-l

Activity limit for an exempt consignment (Bq)

Radionuclide (atomic number)

AI

A2

(TB4

(TB4

Activity concentration for exempt material (Wg)

Activity limit for an exempt consignment (Bq)

Nd- 147

1 Nickel (28)

I

Unlimited

Osmium (76)

OS-191

1 OS-194 (a)

1 Phosphorus ( l 5) Protactinium (9 1) Pa-230 (a)

I

I

Unlimited

I

I

l

X

lo4

1 X 108

I

1

Radionuclide (atomic number)

A1

A2

/'PR-\

Activity concentration for exempt material

Activity lim for an exem consign me^

Lead (82)

Pb-2 10 (a)

4 X loo

3 X loo

1 X 10'

1 X 106

Unlimited

Unlimited

1 X lo4

1 X 10'

1 X 100

5 X 10"

1 X 10' (b)

1 X 104(b)

7 X 10-'

2 X 10-l

1 X 10' (b)

1 1o5 (b)

Unlimited

I Unlimited I

1 Palladium (46) 1 ~ d103- (a) Promethium (6 1) Pm-143 Pm- 144

1 Pm-148m (a) Polonium (84)

Praseodymium (59)

I

X

lo5

I

l

X

10'

Radionuclide (atomic number)

Activity concentration for exempt material

A2

Activity limit for an exempt consignment ( W

Platinum (78) Pt-188 (a)

Pt- 193m Pt- l95m

Pt- 1971~1 Plutonium (94)

PU-240

1 X 10'

1 X 10"

1 X loo

Pu-241 (a)

4

10'

6 X 10"

1 X 102

Pu-242

1 X 10'

1 X 10"

1 X loo

Pu-244 (a)

4

1 X 10‘~

1 X loo

X

X

10-'

Radium (88) Ra-223 (a)

4 X 10-I

7 X 10"

1 X 10' (b)

Ra-224 (a)

4

2

1 X lol(b)

Ra-225 (a) Ra-226 (a) Ra-228 (a)

I

I

I

X

10-'

X

10-~

2x10~' 2x10-I

1 X lo4 (b)

6 X 10-l

1 X lo5 (b)

I

Rubidium (37) Rb-8 1

2

X

loo

8 X 10-'

1 X 10'

Rb-83 (a)

2

X

loo

2 X loo

1 X 102

Rb-84

1 X loo

1 X loo

1 X 10'

Rb-86

5 X 10-I

5 X 10-'

1 X 10'

Unlimited

Unlimited

1 X lo4

I

1 X lo5 (b)

Unlimited

I

Unlimited

1

Radionuclide (atomic number)

AI

Activity concentration for exempt material

Activity limit for an exempt consignment

Rhenium (75) Re- 184

1 X loo

Re- l 84m

3 X loo

1 X loo

1 X 10'

1 X 106

Re- 186

2 X loo

6 X 10-'

1 X lo3

1 X 106

Re-1 87

Unlimited

Unlimited

1 X 106

1 X lo9

1 X 10'

1 X los

Re- 188 Re- 189 (a) Re(nat)

4

I I

X

10-'

3x10' Unlimited

1

Unlimited

Rhodium (45)

m-101

4 X loo

3 X loo

1 X 10'

1 X 107

Rh- 102

5 X 10-'

5 X 10-'

1 X 10'

1 X 106

Rh- 102m

2 X loo

2 X loo

1 X 10'

1 X 106

Rh-103m

4 X 10'

4 X 10'

1 X lo4

1 X 108

lxlol(b)

1 X 108(b)

Rh- 105 Radon (86) 3x10-l

Rn-222 (a) Ruthenium (44)

Ru- 103 (a)

Ru- 106 (a) Sulphur ( 16)

Antimony (5 1) Sb-122 Sb- 124

I I

2x104

I

4x10"

I

Radionuclide (atomic number)

I

I

I

(TW

(TB4

Activity concentration for exempt material (Bqlg)

Sc-46

5 X 10-'

5 X 10-'

1 X 10'

Sc-47

1 X 10'

7 X 10-'

1 X 10'

Sc-48

3 X 10-'

3 X 10-'

1 X 10'

6 X 10-'

6 X 10-'

1 X lo3

Sm-145

1 X 10'

1 X 10'

1 X 102

Sm-147

Unlimited

Unlimited

1 X 10'

1 X 10'

1 X 104

A2

Scandium (2 1)

Selenium (34)

Silicon (14) Si-3 1

Samarium (62)

sm-151 Sm- 153

4

I

X

10'

9x10'

1

6x10-l

1

Tin (50) I

Sn- 113 (a)

4

Sn-1 17m

2

X

10'

I

7 X loo

4

X

10-'

1 X 10"

Sn-12lm (a)

4

10'

9 X 10-'

1

Sn- 123

8 X 10-'

6 X 10-'

1 X lo3

Sn- 125

4

4

1 X 102

Sn-126 (a)

I

X

X

X

10'

10-'

6x10-'

I

X

10-'

4x10~'

I

X

lo3

lo3

1x10'

Activity limit for an exempt consignment 0%)

Radionuclide (atomic number)

Activity concentration for exempt material (Bqk)

Activity limit for an exempt consignment (Bq)

Sr-90 (a)

1 X 1o2 (b)

1 X lo4 (b)

Sr-91 (a)

1 X 10'

Strontium (38) Sr-82 (a)

Sr-92 (a) Tritium ( 1) T(H-3) Tantalum (73) Ta- 178(long-lived) Ta- 179 Ta- 182 Terbium (65)

Tb- l60 p P

Technetium (43) Tc-95m (a)

Tc-96m (a)

4 X 10-'

4 X 10-'

Unlimited

Unlimited

4 X 10'

l

X

loo

Radionuclide (atomic number)

A2

A1

I

Activity concentration for exempt material

Activity limit for an exempt consignment (Bq)

Tellurium (52)

Te-121m

5 X loo

3 X loo

1 X 10'

Te- l23m

8 X loo

1 X loo

1 X 10'

Te-125m

2 X 10'

9 X 10-'

1 X lo3

Te- 127

2 X 10'

7 X 10-'

1 X lo3

1 X lo3

Te-127m (a)

I

2 X 10'

Te-129m (a)

8 X 10-'

4

Te-131m (a)

7 X 10-l

5 X 10~'

Te- 132 (a)

5 X 10-'

4

10-l

1 X 10'

Th-227

1 X 10'

5 X 10"

1 X 10'

Th-228 (a)

5 X 10"

1 X 10"

1 X 10' (b)

Th-229

5 X loo

5 X 10"

1 X loO(b)

Th-230

1 X 10'

1 X 10"

1 X loo

Th-232

Unlimited

Unlimited

1 X 10'

3 X 10-'

3 X 10-'

1 X 103(b)

Unlimited

Unlimited

1 X loO(b)

X

X

10-'

1 X 10'

Thorium (90)

Th-234 (a)

Titanium (22) Ti-44 (a) Thallium (8 1)

Tl-20 1

1 X 10'

T1-202

2 X loo

T1-204

1 X 10'

Thulium (69) Tm- 167

7 X loo

Tm- 170

3 X loo

Tin- 17 1

1 X lo3 (b)

1 X lo3 (b)

Radionuclide (atomic number)

A1

1 Uranium (92) 1 U-230 (fast lung absorption) (a)(d)

I

4 X 10'

1

l

X

4 X 10"

U-230 (slow lung absorption) (a)(f)

3 X 10'

3 X 10"

U-232 (fast lung absorption) (d)

4 X 10'

1 X 10-'

U-232 (medium lung absorption) (e)

4 X 10'

7 X 10"

U-232 (slow lung absorption) (f)

l

10'

1 X 10"

U-233 (fast lung absorption) (d)

4 X 10'

9 X 10"

U-233 (medium lung absorption) (e)

4 X 10'

2 X 10"

U-233 (slow lung absorption) (f)

4 X 10'

6 X 10"

U-234 (fast lung absorption) (d)

4 X 10'

9 X 10"

I

I

X

4x10'

I

U-234 (slow lung absorption) (f)

1 U-236 (fast lung absorption) (d)

I

I

1 X 103(b)

2x10"

I

4x10'

I

U-235 (all lung absorption types) (a)(d)(e)(f)

Activity limit for an exempt consignment (B¶)

10-I

4 X 10'

U-234 (medium lung absorption) (e)

Activity concentration for exempt material (Bqk)

7

U-230 (medium lung absorption) (a)(e)

r

11

I 1

A2

6x10-l

I

Unlimited

Unlimited

I Unlimite; 1 Unlimited

U-236 (medium lung absorption) (e)

4 X 10'

2 X 10"

U-236 (slow lung absorption) (f)

4 X 10'

6 X 10"

U-238 (all lung absorption types)

I Unlimited I Unlimited

1 X loO(b)

1 X 103(b)

U (enriched to 20% or less) ( g )

I

I

Unlimited

1 X 100

1

U (dep)

I Unlimited I

Unlimited

1 X 100

1 X 103

Unlimited

I

Vanadium (23) V-48

4 X 10-'

4 X 10-'

9 X loo

5 X loo

Tungsten (74) W-1 78 (a)

103

Radionuclide (atomic number)

Al

A2

Activity concentration for exempt material (Bqlg)

('m)

(TBq)

4 X 10-'

3

X

10-'

1 X 10'

Xe- 122 (a)

4 X 10"

4

X

10-l

1 X 10'

Xe- l23

2 X loo

7 X 10-'

l

Xe- 127

4 X loo

2 X loo

1 X lo3

~e-13lm

4 X 10'

4

10'

1 X 104

Xe-133

2 X 10'

1 X 10'

1 X lo3

Xe-135

3 X loo

2 X loo

1 X lo3

Y-87 (a)

1 X loo

1 X loo

1 X 10'

Y-88

4 X 10-'

4

X

10-l

1 X 10'

Y-90

3 X 10-1

3

X

10-1

1 X 103

Y-91

6 X 10"

6

X

10-'

1 X lo3

Y-91m

2 X loo

2

X

loo

1 X 102

Y-92

2 X 10-'

2 X 10-'

1 X 10'

Y-93

3 X 10-I

3

10-l

1 X 10'

Yb- 169

4 X loo

1 X loo

1 X 10'

~b-175

3 X 10'

9

Zn-65

2 X loo

2 X loo

1 X 10'

Zn-69

3 X loo

6 X 10-l

1 X lo4

Zn-69m (a)

3 X loo

6 X 10-'

1 X 10'

Zr-88

3 X loo

3 X loo

1 X 10'

Zr-93

Unlimited

Unlimited

1 X 103(b)

Zr-95 (a)

2 X loo

8 X 10-'

1 X 10'

Zr-97 (a)

4 X 10-'

4

W-188 (a)

Activity limit for an exempt consignment ( W

Xenon (54)

X

X

10'

Yttrium (39)

X

Ytterbium (70)

X

10-1

1 X 103

Zinc (30)

Zirconium (40)

(a)

X

10-l

l

X

10' (b)

1 X lo7 (b)

1 X lo5 (b)

Al andor A' values for these parent radionuclides include contributions from daughter radionuclides with half-lives less than 10 days, as listed in the following:

- 144 -

Mg-28 Ar-42 Ca-47 Ti-44 Fe-52 Fe-60 Zn-69m Ge-68 Rb-83 Sr-82 Sr-90 Sr-9 1 Sr-92 Y-87 Zr-95 Zr-97 MO-99 Tc-95m Tc-96m RU-103 RU-106 Pd- 103 Ag- l O8m Ag- l l Om Cd-115 In- 114m Sn-1 l 3 Sn-121m Sn- l26 Te-118 Te- l27m Te-129m Te-13 l m Te-132 1-135 Xe- 122 (3-137 Ba-131 Ba- 140 Ce- 144 Pm-148m Gd- l46 Dy- l 66 Hf- 172 W-178 W-188 Re-189 OS-194 Ir- 189 Pt-188 Hg- 194 Hg- 195m Pb-2 10 Pb-2 12 Bi-2 1Om Bi-2 12

A1-28 K-42 Sc-47 Sc-44 Mn-52m Co-6Om Zn-69 Ga-68 Kr-83m Rb-82 Y-90 Y-91m Y-92 Sr-87m Nb-95m Nb-97m, Nb-97 Tc-99m TC-95 TC-96 Rh-103m Rh- l06 Rh- 1O3m Ag- 108 Ag-l 10 In- 115m In-1 l 4 In-1 l3m Sn- 121 Sb-126m Sb-118 Te- 127 Te-129 Te-13 1 1-132 Xe-135m 1-122 Ba-137m CS-131 La- 140 Pr- 144m, Pr- 144 Pm-148 EU-l46 HO-166 LU-172 Ta-178 Re-188 Os- l89m Ir- 194 Os- l89m Ir-188 AU-194 Hg- 195 Bi-2 10 Bi-212, T1-208, Po-212 T1-206 T1-208, PO-212

- 145 -

(b)

Parent nuclides and their progeny included in secular equilibrium are listed in the following: Sr-90 Zr-93 Zr-97 Ru- l06 Ag- 108m CS-137 Ce- 144 Ba- 140 Bi-2 12 Pb-2 10 Pb-2 12 Rn-222 Ra-223 Ra-224 Ra-226 Ra-228 Th-228 Th-229 Th-nat

Y-90 Nb-93m Nb-97 Rh- 106 Ag- l08 Ba-137m Pr- 144 La- 140 T1-208 (0.36), PO-212(0.64) Bi-2 10, PO-210 Bi-2 12, T1-208 (0.36), PO-212 (0.64) PO-218, Pb-2 14, Bi-2 14, PO-214 Rn-2 19, PO-215, Pb-2 11, Bi-2 11, T1-207 Rn-220, PO-216, Pb-212, Bi-2 12, T1-208 (0.36), PO-212 (0.64) Rn-222, PO-218, Pb-2 14, Bi-2 14, PO-214, Pb-2 10, Bi-2 10, PO-210 Ac-228 Ra-224, Rn-220, PO-216, Pb212, Bi-212, T1208 (0.36), PO-212(0.64) Ra-225, Ac-225, Fr-22 1, At-2 17, Bi-2 13, PO-213, Pb-209 Ra-228, Ac-228, Th-228, Ra-224, Rn-220, PO-216, Pb-2 12, Bi-212, 1208(0.36), PO-212(0.64) Th-234 Pa-234m U-230 Th-226, Ra-222, Rn-2 18, PO-214 U-232 Th-228, Ra-224, Rn-220, PO-216, Pb-212, Bi-212, T1-208 (0.36), PO-212 (0.64) U-235 Th-23 1 U-238 Th-234, Pa-234m U-nat Th-234, Pa-234m, U-234, Th-230, Ra-226, Rn-222, PO-218, Pb-2 14, Bi-2 14, PO-214, Pb-2 10, Bi-2 10, PO-210 Np-237 Pa-233 Am-242m Am-242 Am-243 Np-23 9 - 146 -

The quantity may be determined from a measurement of the rate of decay or a measurement of the radiation level at a prescribed distance from the source. These values apply only to compounds of uranium that take the chemical form of UF6, U02F2and UO2(N0& in both normal and accident conditions of carriage. These values apply only to compounds of uranium that take the chemical form of U03, UF4, UC14 and hexavalent compounds in both normal and accident conditions of carriage. These values apply to all compounds of uranium other than those specified in (d) and (e) above. These values apply to unirradiated uranium only. 2.2.7.7.2.2

For individual radionuclides which are not listed in Table 2.2.7.7.2.1 the determination of the basic radionuclide values referred to in 2.2.7.7.2.1 shall require, multilateral approval. It is permissible to use an A? value calculated using a dose coefficient for the appropriate lung absorption type as recommended by the International Commission on Radiological Protection, if the chemical forms of each radionuclide under both normal and accident conditions of carriage are taken into consideration. Alternatively, the radionuclide values in Table 2.2.7.7.2.2 may be used without obtaining competent authority approval. Table 2.2.7.7.2.2 Basic radionuclide values for unknown radionuclides or mixtures A1

A2

TBq

TBq

0.1

0.02

0.2

9 X 10"

Activity concentration for exempt material Bq/g 1 X 10'

Radioactive contents

Only beta or gamma emitting nuclides are known to be present

Activity limit for an exempt consignment Bq 1 X lo4

neutron emitters are known to be present

gnidime-

nuclides are known to be present or no relevant data are available

1

0.001

1

I

9 X 10"

1

1

1 X 10-I

1

lxld

1

In the calculations of AI and A2 for a radionuclide not in Table 2.2.7.7.2.1, a single radioactive decay chain in which the radionuclides are present in their naturally occurring proportions, and in which no daughter nuclide has a half-life either longer than 10 days or longer than that of the parent nuclide, shall be considered as a single radionuclide; and the activity to be taken into account and the AI or A2 value to be applied shall be those corresponding to the parent nuclide of that chain. In the case of radioactive decay chains in which any daughter nuclide has a half-life either longer than 10 days or greater than that of the parent nuclide, the parent and such daughter nuclides shall be considered as mixtures of different nuclides. For mixtures of radionuclides, the determination of the basic radionuclide values referred to in 2.2.7.7.2.1 may be determined as follows:

f(i)

is the fraction of activity or activity concentration of radionuclide i in the mixture;

X(i) is the appropriate value of Al or A?, or the activity concentration for exempt material or the activity limit for an exempt consignment as appropriate for the radionuclide i; and X,

is the derived value of Al or A2, or the activity concentration for exempt material or the activity limit for an exempt consignment in the case of a mixture.

2.2.7.7.2.5

When the identity of each radionuclide is known but the individual activities of some of the radionuclides are not known, the radionuclides may be grouped and the lowest radionuclide value, as appropriate, for the radionuclides in each group may be used in applying the formulas in 2.2.7.7.2.4and 2.2.7.7.1.4.2.Groups may be based on the total alpha activity and the total betalgamma activity when these are known, using the lowest radionuclide values for the alpha emitters or betalgamma emitters, respectively.

2.2.7.7.2.6

For individual radionuclides or for mixtures of radionuclides for which relevant data are not available, the values shown in Table 2.2.7.7.2.2 shall be used.

2.2.7.8

Limits on transport index (TI), criticality safety index (CSI), radiation levels for packages and overpacks

2.2.7.8.1

Except for consignments under exclusive use, the transport index of any package or overpack shall not exceed 10, nor shall the criticality safety index of any package or overpack exceed 50.

2.2.7.8.2

Except for packages or overpacks carried under exclusive use by rail or by road under the conditions specified in 7.1.4.14.7.3.5 a), the maximum radiation level at any point on any external surface of a package or overpack shall not exceed 2 mSv/h.

2.2.7.8.3

The maximum radiation level at any point on any external surface of a package or overpack under exclusive use shall not exceed 10 mSv/h.

2.2.7.8.4

Packages and overpacks shall be assigned to either category I-WHITE, 11-YELLOW or 111-YELLOW in accordance with the conditions specified in Table 2.2.7.8.4 and with the following requirements: (a)

For a package or overpack, both the transport index and the surface radiation level conditions shall be taken into account in determining which is the appropriate category. Where the transport index satisfies the condition for one category but the surface radiation level satisfies the condition for a different category, the package or overpack shall be assigned to the higher category. For this purpose, category I-WHITE shall be regarded as the lowest category;

(b)

The transport index shall be determined following the procedures specified in 2.2.7.6.1.1 and 2.2.7.6.1.2;

(c)

If the surface radiation level is greater than 2 mSv/h, the package or overpack shall be carried under exclusive use and under the provisions of 7.5.1 1, CV33 (3.5) (a);

2.2.7.8.5

(d)

A package carried under a special arrangement shall be category 111-YELLOW except under the provisions of 2.2.7.8.5;

assigned to

(e)

An overpack which contains packages carried under special arrangement shall be assigned to category 111-YELLOW except under the provisions of 2.2.7.8.5.

In case of international carriage of packages requiring competent authority design or shipment approval, for which different approval types apply in the different countries concerned by the shipment, assignment to the category as required in 2.2.7.8.4 shall be in accordance with the certificate of the country of origin of design. Table 2.2.7.8.4 CATEGORIES OF PACKAGES AND OVERPACKS Conditions Transport index (TI)

Maximum radiation level at any point on external surface Not more than 0.005 mSvih

0"

I

More than 0 but not more than l a More than I but not more than 10 More than 10

I

More than 0.005 mSvih but not more than 0.5 mSvh More than 0.5 mSvh but not more than 2 mSvh More than 2 mSvh but not more than 10 mSvih

Category

I-WHITE

I

11-YELLOW

I

111-YELLOW 111-YELLOW

a

If the measured TI is not greater than 0.05, the value quoted may be zero in accordance with 2.2.7.6.1. I (c).

b

Shall also be carried under exclusive use.

2.2.7.9

Requirements and controlsfor carriage of exceptedpackages

2.2.7.9.1

Excepted packages which may contain radioactive material in limited quantities, instruments, manufactured articles as specified in 2.2.7.7.1.2 and empty packagings as specified in 2.2.7.9.6 may be carried under the following conditions: (a)

The applicable requirements specified in 2.2.7.9.2, 3.3.1 (special provision 290, if relevant), 4.1.9.1.2 of ADR, 5.2.1.2, 5.2.1.7.1, 5.2.1.7.2, 5.2.1.7.3, 5.4.1.1.1 (a), 7.1.4.14.7.5.2, and, as applicable 2.2.7.9.3 to 2.2.7.9.6;

(b)

The requirements for excepted packages specified in 6.4.4 of ADR;

(c)

If the excepted package contains fissile material, one of the fissile exceptions provided by 6.4.1 1.2 of ADR shall apply and the requirement of 6.4.7.2 of ADR shall be met.

2.2.7.9.2

The radiation level at any point on the external surface of an excepted package shall not exceed 5 pSvih.

2.2.7.9.3

Radioactive material which is enclosed in or is included as a component part of an instrument or other manufactured article, with activity not exceeding the item and package limits specified in columns 2 and 3 respectively of Table 2.2.7.7.1.2.1, may be carried in an excepted package provided that:

(a)

the radiation level at 10 cm from any point on the external surface of any unpackaged instrument or article is not greater than 0.1 mSv/h; and

(b)

each instrument or manufactured article bears the marking "RADIOACTIVE" except: (i) (ii)

(c)

2.2.7.9.4

radioluminescent time-pieces or devices; consumer products that either have received regulatory approval according to 2.2.7.1.2 (d) or do not individually exceed the activity limit for an exempt consignment in column (5) of Table 2.2.7.7.2.1, provided such products are carried in a package that bears the marking "RADIOACTIVE" on an internal surface in such a manner that warning of the presence of radioactive material is visible on opening the package; and

the active material is completely enclosed by non-active components (a device performing the sole function of containing radioactive material shall not be considered to be an instrument or manufactured article).

Radioactive material in forms other than as specified in 2.2.7.9.3, with an activity not exceeding the limit specified in column 4 of Table 2.2.7.7.1.2.1, may be carried in an excepted package provided that: (a)

the package retains its radioactive contents under routine conditions of carriage; and

(b)

the package bears the marking "RADIOACTIVE" on an internal surface in such a manner that a warning of the presence of radioactive material is visible on opening the package.

2.2.7.9.5

A manufactured article in which the sole radioactive material is unirradiated natural uranium, unirradiated depleted uranium or unirradiated natural thorium may be carried as an excepted package provided that the outer surface of the uranium or thorium is enclosed in an inactive sheath made of metal or some other substantial material.

2.2.7.9.6

An empty packaging which had previously contained radioactive material may be carried as an excepted package provided that:

2.2.7.9.7

(a)

It is in a well maintained condition and securely closed;

(b)

The outer surface of any uranium or thorium in its structure is covered with an inactive sheath made of metal or some other substantial material; and

(c)

The level of internal non-fixed contamination does not exceed one hundred times the levels specified in 4.1.9.1.2 of ADR.

The following provisions do not apply to excepted packages and the controls for carriage of excepted packages: Chapter 1.10, 2.2.7.4.1, 2.2.7.4.2, 4.1.9.1.3 of ADR, 4.1.9.1.4 of ADR, 5.1.3.2, 5.1.5.1.1, 5.1.5.1.2, 5.2.2.1.11.1, 5.4.1.1.1 except (a), 5.4.1.2.5.1, 5.4.1.2.5.2, 5.4.3, 6.4.6.1 of ADR, 7.1.4.14.7 with the exception of 7.1.4.14.7.5.2.

2.2.7.10

(Reserved).

2.2.8

Class 8

2.2.8.1

Criteria

2.2.8.1.1

The heading of Class 8 covers substances and articles containing substances of this class which by chemical action attack epithelia1 tissue - of skin or mucous membranes - with which they are in contact, or which in the event of leakage are capable of damaging or destroying other goods, or means of transport. The heading of this class also covers other substances which form a corrosive liquid only in the presence of water, or which produce corrosive vapour or mist in the presence of natural moisture of the air.

2.2.8.1.2

Substances and articles of Class 8 are subdivided as follows: C l -C 10

Corrosive substances

Corrosive substances without subsidiary risk: Cl-C4

Acid substances: C1 Inorganic, liquid; C2 Inorganic, solid; C3 Organic, liquid; C4 Organic, solid;

CS-C8

Basic substances: C5 Inorganic, liquid; C6 Inorganic, solid; C7 Organic, liquid; C8 Organic, solid;

C9-C 10

Other corrosive substances: C9 Liquid; C10 Solid;

Articles; Corrosive substances, flammable: CFl Liquid; CF2 Solid: Corrosive substances, self-heating: CS1 Liquid; CS2 Solid; Corrosive substances which, in contact with water, emit flammable gases: CWI Liquid; CW2 Solid; Corrosive substances, oxidizing: C01 Liquid; C 0 2 Solid; Corrosive substances, toxic: CT1 Liquid; CT2 Solid; CFT COT

Corrosive substances, flammable, liquid, toxic; Corrosive substances, oxidizing, toxic.

Classzjkation and assignment of packing groups

Substances of Class 8 shall be classified in three packing groups according to the degree of danger they present for carriage, as follows: Packing group 1: Packing group 11: Packing group 111:

highly corrosive substances corrosive substances slightly corrosive substances.

Substances and articles classified in Class 8 are listed in Table A of Chapter 3.2. Allocation of substances to packing groups I, I1 and 111has been made on the basis of experience taking into account such additional factors as inhalation risk (see 2.2.8.1.5) and reactivity with water (including the formation of dangerous decomposition products). A substance or preparation meeting the criteria of Class 8 having an inhalation toxicity of dusts and mists (LC50) in the range of packing group I, but toxicity through oral ingestion or dermal contact only in the range of packing group I11 or less, shall be allocated to Class 8.

Substances, including mixtures, not mentioned by name in Table A of Chapter 3.2 can be assigned to the relevant entry of sub-section 2.2.8.3, and to the relevant packing group on the basis of the length of time of contact necessary to produce full thickness destruction of human skin in accordance with the criteria of (a) to (c) below. Liquids, and solids which may become liquid during carriage, which are judged not to cause full thickness destruction of human skin shall still be considered for their potential to cause corrosion to certain metal surfaces. In assigning the packing group, account shall be taken of human experience in instances of accidental exposure. In the absence of human experience, the grouping shall be based on data obtained from experiments in accordance with OECD Guideline 404

'.

8

(a)

Packing group 1 is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 60 minutes starting after the exposure time of 3 minutes or less.

(b)

Packing group I1 is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 3 minutes but not more than 60 minutes.

(c)

Packing group 111 is assigned to substances that: -

cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 60 minutes but not more than 4 hours; or

-

are judged not to cause full thickness destruction of intact skin tissue, but which exhibit a corrosion rate on steel or aluminium surfaces exceeding 6.25 mm a year at a test temperature of 55 "C. For the purposes of testing steel, type S235JR+CR (1.OO37 resp. St 37-2), S275J2G3+CR (1-0144 resp. St 44-3), I S 0 3574, Unified Numbering System (UNS) G10200 or SAE 1020, and for testing aluminium, non-clad, types 7075-T6 orAZ5GU-T6 shall be used. An acceptable test is prescribed in the Manual of Tests and Criteria, Part 111, Section 37.

OECD guidelines for Testing of Chemicals, No. 404 "Acute Dermal Irritation/CorrosionU(1992).

- 152-

2.2.8.1.7

If substances of Class 8, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong, on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3.

2.2.8.1 .8

On the basis of the criteria set out in paragraph 2.2.8.1.6, it may also be determined whether the nature of a solution or mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the provisions for this class.

2.2.8.1.9

Substances, solutions and mixtures, which -

do not meet the criteria of Directives 6 7 1 5 4 8 or ~ 8~ 8~ 1~ 3 7 9 ~as~ amended ~ and therefore are not classified as corrosive according to these directives, as amended; and

-

do not exhibit a corrosive effect on steel or aluminium,

may be considered as substances not belonging to Class 8. NOTE: UN No. 1910 calcium oxide and UN No. 2812 sodium aluminate, listed in the UN Model Regulations, are not subject to the provisions of ADN. 2.2.8.2

Substances not acceptedfor carriage

2.2.8.2.1

The chemically unstable substances of Class 8 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end it shall in particular be ensured that receptacles and tanks do not contain any substance liable to promote these reactions.

2.2.8.2.2

The following substances shall not be accepted for carriage: -

UN No. 1798 NITROHYDROCHLORIC ACID;

-

chemically unstable mixtures of spent sulphuric acid;

-

chemically unstable mixtures of nitrating acid or mixtures of residual sulphuric and nitric acids, not denitrated;

-

perchloric acid aqueous solution with more than 72 % pure acid, by mass, or mixtures of perchloric acid with any liquid other than water.

Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L l96 of 16.08.1967, page I). 4 Council Directive 88/379/EEC on the approximation of laws, regulations and administrative provisions relating to the classzjication,packaging and labelling of dangerous preparations (Official Journal of the European Communities No. L. 187 of 16.07.1988,page 14).

2.2.8.3

List of collective entries

Corrosive substances without subsidiary risk liquid

l

C1

2584 2584 2693 2837 3264

ALKYLSULPHONIC ACIDS. LIQUID w ~ t hmore than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid BISULPHITES, AQUEOUS SOLUTION, N.O.S. BISULPHATES. AQUEOUS SOLUTION CORROSIVE LIQUID, ACIDIC, INORGANIC. N.O.S.

1740 2583 2583 3260

HYDROGENDIFLUORIDES, SOLID, N.O.S. ALKYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.

2586 2586 2987 3 145 3265

ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS. LIQUID with not more than 5% free sulphuric acid CHLOROSILANES, CORROSIVE, N.O.S. ALKYLPHENOLS, LIQUID, N.O.S. (including C2-CIIhomologues) CORROSIVE LIQUID, ACIDIC, ORGANIC. N.0.S

2430 2585 2585 3261

ALKYLPHENOLS, SOLID, N.O.S. (includmg C2-CI2homologues) ALKYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, SOLID wlth not more than 5% free sulphuric acid CORROSIVE SOLID, ACIDIC, ORGANIC. N.O.S.

inorganic

l solid liquid

c2

C3

i organic

l solid

C4

r liquid

C5

1719 CAUSTIC ALKALI LIQUID, N.O.S. 2797 BATTERY FLUID, ALKALI 13266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 13262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S.

273s POLYAMIN~S,LIQUID. CORROSIVE. N.O.S. 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.

l solid liquid

CS

C9

Mher corrosive substances 39-C10

3259 AMINES, SOLID, CORROSIVE, N.O.S., or 3259 POLYAMINES, SOLID, CORROSIVE, N.O.S. 1 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 1903 2801 2801 3066

DISINFECTANT, LIQUID, CORROSIVE, N.0.S DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE. N.O.S. PAINT (including paint, enamel. stain, shellac. varnish. polish, liquid filler and lacquer base) or 3066 PAINT RELATED MATERIAL (including paint thinning or reducing compound) 1760 CORROSIVE LIQUID, N.O.S. 3147 3147 3244 1759

1 2794 Lrticles

C11

I

DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE. SOLID, CORROSIVE, N.O.S. SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. CORROSIVE SOLID, N.O.S.

BATTERIES. WET. FILLED WITH ACID. electric storage 2795 BATTERIES, WET; FILLED WITH ALKALI. electric &age 2800 BATTERIES. WET, NON-SPILLABLE, electric storage 3028 BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE SOLID, electric storage

I

cont'd on next page)

a

Mixtures of solids which are not subject to the provisions of ADR and of corrosive liquids may be carried under UN No. 3244 without being subject to the classification criteria of Class 8, provided there is no fiee liquid visible at the time the substance is loaded or at the time the packaging, container or transport unit is closed. Each packaging shall correspond to a design type which has passed the leakproofness test for Packing group II level.

Corrosive substances y i t J

subsidiary risk(s) 3470 PAINT, CORROSIVE, FLAMMABLE (inciuding paint, enamel, stain, shellac, vam~sh, polish. liquid filler and lacquer base) or 3470 PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE (including palnt thinning or reducing compound) 2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE. N.O.S. or 2734 POLYAMINES. LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 2986 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. 2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S.

Liquid

3301

1

CORROSIVE LIQUID, SELF-HEATING, N.O.S.

Self-heating

l

CS

solid

I

13095

liquid Water-reactive CW

CT

CORROSIVE LIQUID, WATER-REACTIVE, N.O.S.

1

I

1 3096

CORROSIVE SOLID, WATER-REACTIVE, N.O.S.

1

liquid

I

1 3093

CORROSIVE LIQUID, OXIDIZING, N.O.S.

1

solid

I

1 3084

CORROSIVE SOLID. OXIDIZING, N.O.S.

I

r liquid

Toxic

3094

solid

Oxidizing CO

l

CORROSIVE SOLID, SELF-HEATMG, N.0 S.

--

solid

CTl

I

3471 2922

HYDROGENDIFLUORIDES SOLUTION, N 0 S. CORROSIVE LIQUID, TOXIC. N . 0 S

2923

CORROSIVE SOLID, TOXIC. N.O.S.

1

Flammable, Liquid, toxic

CFT

No collective entry with this classification code available: if need be, classification under a collective entry with a classification code to be determined according to table of precedence of hazard in 2.1.3.10.

Oxidizing, toxic d, e

COT

No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to table of precedence of hazard in 7 1 710

Chlorosilanes which, in contact with water or moist air, emit flammable gases, are substances of Class 4.3. Chloroformates havingpredominantly toxic properties are substances of Class 6.1. Corrosive substances which are highly toxic by inhalation, as deJined in 2.2.61.1.4 to 2.2.61.1.9 are substances of Class 6.1. UN No. 2505 AMMONIUM FLUORIDE, UN No. 1812 POTASSIUM FLUORIDE, UN No. 1690 SODIUM FLUORIDE, SOLD, UN No. 2674 SODIUM FLUOROSILICATE, UN No. 2856 FL UOROSILZCATES, N. O.S. , UN No. 3415 SODIUM FLUORIDE SOLUTION and UN No. 3422 POTASSIUM FL UORIDE SOL UTZON are substances of Class 6.1.

2.2.9

Class 9 Miscellaneous dangerous substances and articles

2.2.9.1

Criteria

2.2.9.1.1

The heading of Class 9 covers substances and articles which, during carriage, present a danger not covered by the heading of other classes.

2.2.9.1.2

The substances and articles of Class 9 are subdivided as follows: M1

Substances which, on inhalation as fine dust, may endanger health;

M2

Substances and apparatus which, in the event of fire, may form dioxins;

M3

Substances evolving flammable vapour;

M4

Lithium batteries;

M5

Life-saving appliances;

M6-MS

Environmentally hazardous substances: M6 M7 MS

M9-M10

Pollutant to the aquatic environment, liquid; Pollutant to the aquatic environment, solid; Genetically modified micro-organisms and organisms;

Elevated temperature substances: M9 Liquid; M10 Solid;

M1 1 Other substances presenting a danger during carriage, but not meeting the definitions of another class. Definitions and classification

2.2.9.1.3

Substances and articles classified in Class 9 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of that Table or of sub-section 2.2.9.3 shall be done in accordance with 2.2.9.1.4 to 2.2.9.1.14 below. Substances which, on inhalation asfine dust, may endanger health

2.2.9.1.4

Substances which, on inhalation as fine dust, may endanger health include asbestos and mixtures containing asbestos. Substances and apparatus which, in the event offire, may form dioxins

2.2.9.1.5

Substances and apparatus which, in the event of fire, may form dioxins include polychlorinated biphenyls (PCBs) and terphenyls (PCTs) and polyhalogenated biphenyls and terphenyls and mixtures containing these substances, as well as apparatus such as transformers, condensers and apparatus containing those substances or mixtures. NOTE: Mixtures with a PCB or PCT content of not more than 50 mg/kg are not subject to the provisions of ADN.

Substances evolvingJlammable vapour

2.2.9.1.6

Substances evolving flammable vapour include polymers containing flammable liquids with a flash-point not exceeding 55 "C. Lithium batteries

2.2.9.1.7

Lithium cells and batteries may be assigned to Class 9 if they meet the requirements of special provision 230 of Chapter 3.3. They are not subject to the provisions of ADN if they meet the requirements of special provision 188 of Chapter 3.3. They shall be classified in accordance with the procedures of Section 38.3 of the Manual of Tests and Criteria. Life-saving appliances

2.2.9.1 .8

Life-saving appliances include life-saving appliances and motor vehicle components which meet the descriptions of special provisions 23 5 or 296 of Chapter 3.3. Environmentally hazardous substances

2.2.9.1.9

Environmentally hazardous substances include liquid or solid substances pollutant to the aquatic environment and solutions and mixtures of such substances (such as preparations and wastes), which cannot be classified in the other classes or under any other entry of Class 9 listed in Table A of Chapter 3.2. It also includes genetically modified micro-organisms and organisms. Pollutants to the aquatic environment

2.2.9.1.10

Assignment of a substance to the entries UN No. 3082 ENVIROMLlENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.0.S and UN No. 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. as pollutant to the aquatic environment shall be as indicated in 2.3.5. Notwithstanding the provisions of 2.3.5, substances which cannot be assigned to other classes of ADN or to other entries of Class 9, and which are not identified in Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances9,as amended, as substances to which letter N "Environmentally hazardous" (R50; R50153; R51153) has been allocated, are not subject to ADN. Notwithstanding the provisions of 2.1.3.8, solutions and mixtures (such as preparations and wastes) of substances to which letter N "Environmentally hazardous" (R50; R50153; R5 1/53) has been allocated in Directive 67/548/EEC, as amended, need only be assigned to UN Nos. 3077 or 3082 if, according to Directive 1999145lEC of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations10, as amended, they are also allocated letter N "Environmentally hazardous" (R50; R50153; R51153) and they cannot be assigned to one of classes 1 to 8 or to any other entry of Class 9.

9

'O

Official Journal of the European Communities No. 196, of 16 August 1967, pp. 1 - 5. Oflcial Journal of the European Communities No. L 200, of 30 July 1999, pp. I - 68.

- 157 -

Genetically modzjied micro-organisms or organisms

2.2.9.1.1 1

Genetically modified micro-organisms (GMMOs) and genetically modified organisms (GMOs) are micro-organisms and organisms in which genetic material has been purposely altered through genetic engineering in a way that does not occur naturally. They are assigned to Class 9 (UN No. 3245) if they do not meet the definition of infectious substances, but are capable of altering animals, plants or microbiological substances in a way not normally the result of natural reproduction. NOTE 1: 2900).

GMMOs which are infectious are substances of Class 6.2 (UN Nos. 2814 and

NOTE 2: GMMOs or GMOs are not subject to the provisions of ADN when authorized for use by the competent authorities of the countries of origin, transit and destination". NOTE 3: Live animals shall not be used to carry genetically modified micro-organisms classified in Class 9 unless the substance can be carried no other way. 2.2.9.1.12

Genetically modified organisms, which are known or suspected to be dangerous to the environment shall be carried in accordance with conditions specified by the competent authority of the country of origin. Elevated temperature substances

2.2.9.1.13

Elevated temperature substances include substances which are carried or handed over for carriage in the liquid state at or above 100 "C and, in the case of those with a flash-point, below their flash-point. They also include solids which are carried or handed over for carriage at or above 240 "C. NOTE I : Elevated temperature substances may be assigned to Class 9 only meet the criteria of any other class.

if they do not

NOTE 2: Substances having aflash-point above 60 'C which are carried or handed over for carriage within a range of 15 K below the flash-point are substances of Class 3, identijkation number 9001. Other substances presenting a danger during carriage but not meeting the definitions of another class.

2.2.9.1.14

The following other miscellaneous substances not meeting the definitions of another class are assigned to Class 9: Solid ammonia compounds having a flash-point below 60 "C Low hazard dithionites Highly volatile liquids Substances emitting noxious fumes Substances containing allergens Chemical kits and first aid kits

See in particular Part C of Directive 2001/18/EC of the European Parliament and of the Council on the deliberate release into the environment of genetically mod~jiedorganisms and repealing Council Directive 90/220/EEC (OfJiciial Journal of the European Communities, No. L 106, of 17 April 2001, pp. 814), which sets out the authorization procedures for the European Community.

- 158 -

The following miscellaneous substances not meeting the definition of another class are assigned to Class 9 when they are carried in bulk or in tank vessels: -

UN 2071 AMMONIUM NITRATE FERTILIZERS: uniform non-segregating mixtures of nitrogen phosphate or nitrogen potash types or complete fertilizers of nitrogen phosphate potash type, with not more than 70% ammonium nitrate and not more than 0.4% total combustible material, or with not more than 45% ammonium nitrate irrespective of their content of combustible material;

NOTE I : In determining the anzmoniurn nitrate content, all nitrate ions for which a molecular equivalent of ammonium ions is present in the mixture shall be calculated as anzmonium nitrate mass. NOTE 2: Ammonium nitratefertilizers of Class 9 are not subject to ADN

if.

-

the results of the trough test (see Manual of Tests and Criteria, Part Ill, sub-section 38.2) show that they are not capable of undergoing self-sustaining decomposition; and

-

the calculation referred to in NOTE l does not give an excess of nitrate greater than 10% by mass, calculated in KN03.

-

UN 2216 FISH MEAL, STABILIZED (humidity between 5% by mass and 12% by mass with not more than 15% fat by mass); or

-

UN 2216 FISH SCRAP, STABILIZED (humidity between 5% by mass and 12% by mass with not more than 15% fat by mass);

-

Identification No. 9003 SUBSTANCES HAVING A FLASH-POINT ABOVE 60" C AND NOT MORE THAN 100" C which cannot be assigned to another class or another entry of Class 9;

-

Identification No. 9004,4,4' DIPHENYLMETHANE DIISOCYANATE.

NOTE: UN No. 1845 carbon dioxide, solid (dry ice), UN No. 2807 magnetized material, UN No. 3166 engine, internal combustion or vehicle, flanzmable gas powered or vehicle, flanzmable liquid powered, UN No. 31 71 battery-powered vehicle or 31 71 battery-powered equipment (wet battery), UN No. 3334 aviation regulated liquid, n.o.s., UN No. 3335 aviation regulated solid, n.0.s. and UN No. 3363 dangerous goods in niachinery or dangerous goods in apparatus, listed in the UN Model Regulations, are not subject to the provisions of ADN. Assignment of the packing groups

2.2.9.1.15

The substances and articles of Class 9 listed as such in Table A of Chapter 3.2 shall be assigned to one of the following packing groups according to their degree of danger: Packing group 11:

substances presenting medium danger

Packing group 111:

substances presenting low danger.

Substances and articles not acceptedfor carriage The following substances and articles shall not be accepted for carriage: -

Lithium batteries which do not meet the relevant conditions of special provisions 188, 230 or 636 of Chapter 3.3;

-

Uncleaned empty containment vessels for apparatus such as transformers, condensers and hydraulic apparatus containing substances assigned to UN Nos. 23 15, 3 151, 3 152 or 3432..

2.2.9.3

List of collective entries

I Substances which, on inhalation as fine dust, may endanger health

r2212 BLUE ASBESTOS (crocidolite) or M1 2212 BROWN ASBESTOS (amosite, mysorite) 2590 WHITE ASBESTOS (chrysotile, actlnolite, anthophyllite,tremolite)

Substances and apparatus which, in the event of fire, may form dioxins

23 15 POLYCHLORINATED BIPHENYLS. LIQUID 3432 POLYCHLORINATED BIPHENYLS, SOLID 3 151 POLYHALOGENATED BIPHENYLS, LIQUID or M2 3 151 POLYHALOGENATED TERPHENYLS, LIQUID 3 152 POLYHALOGENATED BIPHENYLS, SOLID or 3 152 POLYHALOGENATED TERPHENYLS, SOLID

I

I Substances evolviue flammable vapour

I

221 1 POLYMEFUC BEADS, EXPANDABLE, evolvlng flammable vapour 3314 PLASTICS MOULDING COMPOUND m dough, sheet or extruded rope form evolving flammable vapour

3090 LITHIUM BATTERIES M4 3091 LlTHllJM BATTERIES CONTAINED IN EQLTIPMENl' or 3091 LlTHlUM BATTERIES PACKED WlTH EQUIPMENT

Lithium batteries

I I

2990 LIFE-SAVING APPLIANCES, SELF-INFLATING 3072 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment 3268 AIR BAG INFLATORS or 3268 AIR BAG MODULES or 3268 SEAT-BELT PRETENSIONERS

aquatic environment, liquid

1

/

M6 3082 ENVIRONMENTALLY HAZARWUS SUBSTANCE. LIQUID. N.O.S.

1 aquatic pollutant to the Environmentally hazardous substances

environment, solid

3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE. SOLID. N.O.S.

genetically modified microorganisms and

3245 GENETICALLY MODIFIED MICROORGANISMS or 3245 GENETICALLY MODIFLED ORGANISMS

3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 "C and below its flash-point (includmg molten metal, molten salts, etc.)

)

solid

Other substances or articles presenting a danger during carriage, but not meeting the definitions of another class

1

MII) 3258 ELEVATED TEMPEUTURE SOLID, N O S . . at or above 240 ^C

subject to the provisions for Class 9 under this classificationcode, as follows: 1841 ACETALDEHYDE AMMONIA 1931 ZINC DITHIONITE (ZINC HYDROSULPHITE) 1941 DIBROMODIFLUOROMETHANE 1990 BENZALDEHYDE 2969 CASTOR BEANS, or M1l 2969 CASTOR MEAL, or 2969 CASTOR POMACE, or 2969 CASTOR FLAKE 3316 CHEMICAL KIT, or 33 l 6 FIRST AID KIT 3359 FUMIGATED UNIT

]

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CHAPTER 2.3 TEST METHODS General

Unless otherwise provided for in Chapter 2.2 or in this Chapter, the test methods to be used for the classification of dangerous goods are those described in the Manual of Tests and Criteria. Exudation test for blasting explosives of Type A

Blasting explosives of type A (UN No. 0081) shall, if they contain more than 40 % liquid nitric ester, in addition to the testing specified in the Manual of Tests and Criteria, satisfy the following exudation test. The apparatus for testing blasting explosive for exudation (figs. 1 to 3) consists of a hollow bronze cylinder. This cylinder, which is closed at one end by a plate of the same metal, has an internal diameter of 15.7 mm and a depth of 40 mm. It is pierced by 20 holes 0.5 mm in diameter (four sets of five holes) on the circumference. A bronze piston, cylindrically fashioned over a length of 48 mm and having a total length of 52 mm, slides into the vertically placed cylinder. The piston, whose diameter is 15.6 mm, is loaded with a mass of 2 220 g so that a pressure of 120 kPa (1.20 bar) is exerted on the base of the cylinder. A small plug of blasting explosive weighing 5 to 8 g, 30 mm long and 15 mm in diameter, is wrapped in very fine gauze and placed in the cylinder; the piston and its loading mass are then placed on it so that the blasting explosive is subjected to a pressure of 120 kPa (1.20 bar). The time taken for the appearance of the first signs of oily droplets (nitroglycerine) at the outer orifices of the cylinder holes is noted.

The blasting explosive is considered satisfactory if the time elapsing before the appearance of the liquid exudations is more than five minutes, the test having been carried out at a temperature of 15 "C to 25 'C.

Test of blasting explosive for exudation

Fig. l : Bell-fonn charge, mass 2220 g, capable of being suspended from a bronze piston

Fig.2: Cylindrical bronze piston, dimensions in mm

0

'"

Fig.3: Hollow bronze cylinder, closed at one end; Plan and cut dimensions in mm

Fig. 1 to 3 (1) 4 series of 5 holes at 0.5 N (2) copper (3) iron plate with centre cone at the inferior face (4) 4 openings, approximately 46x56, set at even intervals on the periphery

Tests relating to nitrated cellulose mixtures of Class 4.1 Nitrocellulose heated for half an hour at 132 "C shall not give off visible yellowish-brown nitrous fumes (nitrous gases). The ignition temperature shall be above 180 "C. See 2.3.2.3 to 2.3.2.8, 2.3.2.9 (a) and 2.3.2.10 below. 3 g of plasticized nitrocellulose, heated for one hour at 132 "C, shall not give off visible yellowish-brown nitrous fumes (nitrous gases). The ignition temperature shall be above 170 "C. See 2.3.2.3 to 2.3.2.8, 2.3.2.9 (b) and 2.3.2.10 below. The test procedures set out below are to be applied when differences of opinion arise as to the acceptability of substances for carriage by road. If other methods or test procedures are used to verify the conditions of stability prescribed above in this section, those methods shall lead to the same findings as could be reached by the methods specified below. In carrying out the stability tests by heating described below, the temperature of the oven containing the sample under test shall not deviate by more than 2 "C from the prescribed temperature; the prescribed duration of a 30-minute or 60-minute test shall be observed to within two minutes. The oven shall be such that the required temperature is restored not more than five minutes after insertion of the sample. Before undergoing the tests in 2.3.2.9 and 2.3.2.10, the samples shall be dried for not less than 15 hours at the ambient temperature in a vacuum desiccator containing fused and granulated calcium chloride, the sample substance being spread in a thin layer; for this purpose, substances which are neither in powder form nor fibrous shall be ground, or grated, or cut into small pieces. The pressure in the desiccator shall be brought below 6.5 kPa (0.065 bar). Before being dried as prescribed in 2.3.2.6 above, substances conforming to 2.3.2.2 shall undergo preliminary drying in a well-ventilated oven, with its temperature set at 70 "C, until the loss of mass per quarter-hour is less than 0.3 % of the original mass. Weakly nitrated nitrocellulose conforming to 2.3.2.1 shall first undergo preliminary drying as prescribed in 2.3.2.7 above; drying shall then be completed by keeping the nitrocellulose for at least 15 hours over concentrated sulphuric acid in a desiccator. Test of chemical stability under heal (a)

Test of the substance listed in paragraph 2.3.2.1 above.

(i)

In each of two glass test tubes having the following dimensions: length internal diameter thickness of wall

350 16 1.5

mm mm mm

is placed 1 g of substance dried over calcium chloride (if necessary the drying shall be carried out after reducing the substance to pieces weighing not more than 0.05 g each). Both test tubes, completely covered with loose-fitting closures, are then so placed in an oven that at least four-fifths of their length is visible, and are kept at a constant temperature of 132 "C for 30 minutes. It is observed whether nitrous gases in the form of yellowish-brown fumes clearly visible against a white background are given off during this time.

(ii) (b)

In the absence of such fumes the substance is deemed to be stable.

Test of plasticized nitrocellulose (see 2.3.2.2)

(i)

3 g of plasticized nitrocellulose are placed in glass test tubes, similar to those referred to in (a), which are then placed in an oven kept at a constant temperature of 132 "C.

(ii)

The test tubes containing the plasticized nitrocellulose are kept in the oven for one hour. During this time no yellowish-brown nitrous fwnes (nitrous gases) shall be visible. Observation and appraisal as in (a).

Ignition temperature (see 2.3.2.1 and 2.3.2.2)

The ignition temperature is determined by heating 0.2 g of substance enclosed in a glass test tube immersed in a Wood's alloy bath. The test tube is placed in the bath when the latter has reached 100 "C. The temperature of the bath is then progressively increased by 5 "C per minute; The test tubes must have the following dimensions: length internal diameter thickness of wall

125 mm 15 mm 0.5 mm

and shall be immersed to a depth of 20 mm; The test shall be repeated three times, the temperature at which ignition of the substance occurs, i.e., slow or rapid combustion, deflagration or detonation, being noted each time; The lowest temperature recorded in the three tests is the ignition temperature. Tests relating to flammable liquids of Classes 3,6.1 and 8 Testfor determiningflash-point

The flash-point shall be determined by means of one of the following types of apparatus: (a)

Abel;

(b)

Abel-Pensky;

(c)

Tag;

(d)

Pensky-Martens;

(e)

Apparatus in accordance with I S 0 3679:1983 or I S 0 3680:1983.

To determine the flash-point of paints, gums and similar viscous products containing solvents, only apparatus and test methods suitable for determining the flash-point for viscous liquids shall be used, in accordance with the following standards: (a)

International Standard IS0 3679: 1983;

(b)

International Standard IS0 3680: 1983;

(c)

International Standard IS0 1523:1983;

(d)

German Standard DIN 53213:1978, Part 1.

2.3.3.1.3

The test procedure shall be either according to an equilibrium method or according to a non-equilibrium method.

2.3.3.1.4

For the procedure according to an equilibrium method, see:

2.3.3.1.5

(a)

International Standard IS0 1516:l98 1;

(b)

International Standard I S 0 3680: 1983;

(c)

International Standard IS0 1523:1983;

(d)

International Standard IS0 3679: 1983.

The procedure according to a non-equilibrium method shall be: (a)

(b)

for the Abel apparatus, see: (i)

British Standard BS 2000 Part 170:1995;

(ii)

French Standard NF M07-011: 1988;

(iii)

French Standard NF T66-009: 1969;

for the Abel-Pensky apparatus, see: (i)

German Standard DIN 51755, Part 1:1974 (for temperatures from 5 "C to 65 "C);

(ii)

German Standard DIN 5 1755, Part 2: 1978 (for temperatures below 5 "C);

(iii)

French Standard NF M07-036:1984;

(c)

for the Tag apparatus, see American Standard ASTM D 56:1993;

(d)

for the Pensky-Martens apparatus, see: (i)

International Standard I S 0 2719: 1988;

(ii)

European Standard EN 22719 in each of its national versions (e.g. BS 2000, part 404/EN 227 19):1994;

(iii)

American Standard ASTM D 93: 1994;

(iv)

Institute of Petroleum Standard IP 34: 1988.

2.3.3.1.6

The test methods listed in 2.3.3.1.4 and 2.3.3.1.5 shall only be used for flash-point ranges which are specified in the individual methods. The possibility of chemical reactions between the substance and the sample holder shall be considered when selecting the method to be used. The apparatus shall, as far as is consistent with safety, be placed in a draught-free position. For safety, a method utilizing a small sample size, around 2 ml, shall be used for organic peroxides and self-reactive substances (also known as "energetic" substances), or for toxic substances.

2.3.3.1.7

When the flash-point, determined by a non-equilibrium method in accordance with 2.3.3.1.5 is found to be 23 2 "C or 60 2 "C, it shall be confirmed for each temperature range by an equilibrium method in accordance with 2.3.3.1.4.

*

*

2.3.3.1.8

In the event of a dispute as to the classification of a flammable liquid, the classification proposed by the consignor shall be accepted if a check-test of the flash-point, yields a result not differing by more than 2 "C from the limits (23 "C and 60 "C respectively) stated in 2.2.3.1. If the difference is more than 2 "C, a second check-test shall be carried out, and the lowest figure of the flash-points obtained in either check-test shall be adopted.

Testfor determining peroxide content To determine the peroxide content of a liquid, the procedure is as follows: A quantity p (about 5 g, weighed to the nearest 0.01 g) of the liquid to be titrated is placed in an Erlenmeyer flask; 20 cm3 of acetic anhydride and about 1 g of powdered solid potassium iodide are added; the flask is shaken and, after 10 minutes, heated for 3 minutes to about 60 "C. When it has been left to cool for 5 minutes, 25 cm3 of water are added. After this, it is left standing for half an hour, then the liberated iodine is titrated with a decinormal solution of sodium thiosulphate, no indicator being added; complete discoloration indicates the end of the reaction. If n is the number of cm3 of thiosulphate solution required, the percentage of peroxide (calculated as H202)present in the sample is obtained by the formula: 17n

Test for determining fluidity To determine the fluidity of liquid, viscous or pasty substances and mixtures, the following test method shall be used. Test apparatus Commercial penetrometer conforming to I S 0 2 137:1985, with a guide rod of 47.5 g 0.05 g; sieve disc of duralumin with conical bores and a mass of 102.5 g k 0.05 g (see Figure 1); penetration vessel with an inside diameter of 72 mm to 80 mm for reception of the sample. Test procedure The sample is poured into the penetration vessel not less than half an hour before the measurement. The vessel is then hermetically closed and left standing until the measurement. The sample in the hermetically closed penetration vessel is heated to 35 "C + 0.5 "C and is placed on the penetrometer table immediately prior to measurement (not more than two minutes). The point S of the sieve disc is then brought into contact with the surface of the liquid and the rate of penetration is measured. Evaluation of test results A substance is pasty if, after the centre S has been brought into contact with the surface of the sample, the penetration indicated by the dial gauge:

* 0.1 S, is less than 15.0 mm * 0.3 mm; or

(a)

after a loading time of 5 S

(b)

after a loading time of 5 S 0.1 S, is greater than 15.0 mm h 0.3 mm, but the additional penetration after another 55 s 0.5 S is less than 5.0 mm 0.5 mm.

*

*

NOTE: In the case of samples having aflow point, it is often impossible to produce a steady level surface in the penetration vessel and, hence, to establish satisfactog, initial measuring conditions for the contact of the point S. Furthermore, with some samples, the impact of the sieve disc can cause an elastic deformation of the surface and, in the first few seconds, simulate a deeper penetration. In all these cases, it may be appropriate to make the evaluation in paragraph (b) above.

Figure 1 - Penetrometer

Adjust mass to 102.5gI- 0.05%

1 . , ,

"S

\

hess fit

*

Tolerances not specified are 0.1 mm.

Test for determining the ecotoxicity, persistence and bioaccumulation of substances in the aquatic environment for assignment to Class 9

NOTE: The test methods used shall be those adopted by the Organization for Economic Cooperation and Development (OECD) and the European Commission (EC). If other methods are used, they shall be internationally recognized, be equivalent to the OECD/EC tests and be referenced in test reports. Acute toxicity forfish

The object is to determine the concentration which causes 50% mortality in the test species; this is the (LCSo)value, namely, the concentration of the substance in water which will cause the death of 50% of a test group of fish during a continuous period of testing of at least 96 hours. Appropriate types of fish include: striped brill (Brachvdanio rerio), fathead minnow (Pimephales vromelas) and rainbow trout (Oncorhvnchus mykiss). The fish are exposed to the test substance added to the water in varying concentrations (+l control). Observations are recorded at least every 24 hours. At the end of the 96-hour activity and, if possible, at each observation, the concentration causing the death of 50% of the fish is calculated. The no observed effect concentration (NOEC) at 96 hours is also determined. Acute toxicity for daphnia

The object is to determine the effective concentration of the substance in water which renders 50% of the daphnia unable to swim (EC5o). The appropriate test organisms are daphnia mama and daphnia vulex. The daphnia are exposed for 48 hours to the test substance added to the water in varying concentrations. The no observed effect concentration (NOEC) at 48 hours is also determined. Algal growth inhibition

The object is to determine the effect of a chemical on the growth of algae under standard conditions. The change in biomass and the rate of growth with algae under the same conditions, but without the presence of the test chemical, are compared over 72 hours. The results are expressed as the effective concentration which reduces the rate of algal growth by 50%, ICSOr,and also the formation of the biomass, ICSOb. Testsfor ready biodegradability

The object is to determine the degree of biodegradation under standard aerobic conditions. The test substance is added in low concentrations to a nutrient solution containing aerobic bacteria. The progress of degradation is followed for 28 days by determining the parameter specified in the test method used. Several equivalent test methods are available. The parameters include reduction of dissolved organic carbon (DOC), carbon dioxide (CO?) generation of oxygen (02) depletion. A substance is considered to be readily biodegradable if within not more than 28 days the following criteria are satisfied - within 10 days from when degradation first reaches 10%:

Reduction of DOC: Generation of CO*: Depletion of 05

70% 60% of theoretical COz production 60% of theoretical 0 2 requirement.

The test may be continued beyond 28 days if the above criteria are not satisfied, but the result will represent the inherent biodegradability of the test substance. For assignment purposes, the "ready" result is normally required.

Where only COD and BOD5 data are available, a substance is considered to be readily biodegradable if: BOD, 20.5 COD BOD (Biochemical Oxygen Demand) is defined as the mass of dissolved oxygen required by a specific volume of solution of the substance for the process of biochemical oxidation under prescribed conditions. The result is expressed as grams of BOD per gram of test substance. The normal test period is five days (BOD5)using a national standard test procedure. COD (Chemical Oxygen Demand) is a measure of the oxidizability of a substance, expressed as the equivalent amount in oxygen of an oxidizing reagent consumed by the substance under fixed laboratory conditions. The results are expressed in grams of COD per gram of substance. A national standard procedure may be used.

2.3.5.5

Testsfor bioaccurnulation potential

2.3.5.5.1

The object is to determine the potential for bioaccumulation either by the ratio at equilibrium of the concentration (c) of a substance in a solvent to that in water or by the bioconcentration factor (BCF).

2.3.5.5.2

The ratio at equilibrium of the concentration (c) of a substance in a solvent to that in water is normally expressed as a loglo.The solvent and water shall have negligible miscibility and the substance shall not ionize in water. The solvent normally used is n-octanol. In the case of n-octanol and water, the result is:

where P,, is the partition coefficient obtained by dividing the concentration of the substance in n-octanol (c,) by the concentration of the substance in water (C,). If log P,, 2 3.0 then the substance has a potential to bioaccumulate. 2.3.5.5.3

The bioconcentration factor (BCF) is defmed as the ratio of the concentration of the test substance in the test fish (cf) to the concentration in the test water (c,) at steady state: BCF = (cf) / (c,). The principle of the test involves exposing fish to a solution or dispersion at known concentrations of the test substance in water. Continuous flow, static or semi-static procedures may be used according to the test procedure selected, based on the properties of the test substances. Fish are exposed to the test substances over a given period of time, followed by a period of no further exposure. During the second period, measurements are made of the rate of increase in the water of the test substance (i.e. the rate of excretion or depuration). (Full details of the various test procedures and the calculation method for the BCF are given in the OECD Guidelines for Testing of Chemicals, methods 305A to 305E, 12 May 1981).

2.3.5.5.4

A substance may have a log P,, greater than 3 and a BCF less than 100 which would indicate little or no potential to bioaccumulate. In cases of doubt, the BCF value takes precedence over log P , , as indicated in the flow chart of the procedure in 2.3.5.7.

Criteria A substance may be regarded as a pollutant to the aquatic environment if it satisfies one of the following criteria:

The lowest of the values of the 96-hour LCSofor fish, the 48-hour EC50 for daphnia or the 72-hour ICSOfor algae -

is less than or equal to I mg/l;

-

is greater than 1 mg/l but less than or equal to 10 mg/l, and the substance is not biodegradable;

-

is greater than 1 mg/l but less than or equal to 10 mg/l, and the log P,, is greater than or equal to 3.0 (unless the experimentally determined BCF is less than or equal to 100).

Procedure to be followed of acute for fish, daphnia or algae

toxicity

Yes l

i

Substance degradable

readily

Yes I

1

Log P,, 2 3,O (unless the experimentally determined BCF I 100) Yes

(

* Lowest value of 96-hour LC50, 48-hour ECsoor 72-hour ICsoas appropriate. BCF = bioconcentration factor

Classification of organometallic substances in Classes 4.2 and 4.3

Depending on their properties as determined in accordance with tests N.l to N.5 of the Manual of Tests and Criteria, Part 111, section 33, organometallic substances may be classified in Classes 4.2 or 4.3, as appropriate, in accordance with the flowchart scheme given in Figure 2.3.6. NOTE l : Depending on their other properties and on the precedence of hazard table (see 2.1.3.101, organometallic substances may have to be classiJied in other classes as appropriate.

NOTE 2: Flammable solutions with organometallic compounds in concentrations which are not liable to spontaneous combustion or, in contact with water, do not emit flammable gases in dangerous quantities, are substances of Class 3.

Figure 2.3.6

Flowchart scheme for the classification of organometallic substances in Classes 4.2 and 4.3

Organometallic

Organometallic substance, solid, pyrophoric

Organometallic substance. l

Liquid

Is the

Solid

I

Yes

liquid, pyrophoric UN 3392 -+

I

Organometallic substance. solid, pyrophoric, water-reactive UN 3393 Organometallic substance,

Liquid

liquid pyrophoric, water-reactive , UN 3394

Organometallic substance, solid, water-reactive UN 3395 Organometallic substance, solid, water-reactive, flammable UN 3396

Substance does not have to be classified in Class 4.2

a

If applicable and testing is relevant, taking into account reactivity properties, class 6.1 and 8 properties should be considered according to the precedence of hazard table of 2.1.3.10. b Test methods N. I to N.5 can be found in the Manual of Tests and Criteria, Part III, Section 33.

PART 3

Dangerous goods list, special provisions and exemptions related to dangerous goods packed in limited quantities

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CHAPTER 3.1

GENERAL Introduction

In addition to the provisions referred to or given in the tables of this Part, the general requirements of each Part, Chapter andlor Section are to be observed. These general requirements are not given in the tables. When a general requirement is contradictory to a special provision, the special provision prevails. Proper shipping name

NOTE: For proper shipping names usedfor the carriage of samples, see 2.1.4.1 The proper shipping name is that portion of the entry most accurately describing the goods in Table A or Table C in Chapter 3.2, which is shown in upper case characters (plus any numbers, Greek letters, "sec", "tert", and the letters "m", "n", "of', "p", which form an integral part of the name). Particulars concerning the vapour pressure (vp) and the boiling point (bp) in column (2) of Table C in chapter 3.2 are part of the proper shipping name. An alternative proper shipping name may be shown in brackets following the main proper shipping name. In Table A, it is shown in upper case characters (e.g., ETHANOL (ETHYL ALCOHOL)). In Table C, it is shown in lower case characters (e.g. ACETONITRILE (methyl cyanide)). Portions of an entry appearing in lower case need not be considered as part of the proper shipping name unless otherwise stated above. When conjunctions such as "and" or "or" are in lower case or when segments of the name are punctuated by commas, the entire name of the entry need not necessarily be shown in the transport document or package markings. This is the case particularly when a combination of several distinct entries are listed under a single UN Number. Examples illustrating the selection of the proper shipping name for such entries are: (a)

UN 1057 LIGHTERS or LIGHTER REFILLS - The proper shipping name is the most appropriate of the following possible combinations: LIGHTERS LIGHTER REFILLS;

(b)

UN 2793 FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to self-heating. The proper shipping name is the most appropriate of the following combinations:

FERROUS METAL BORINGS FERROUS METAL SHAVINGS FERROUS METAL TURNINGS FERROUS METAL CUTTINGS. Proper shipping names may be used in the singular or plural as appropriate. In addition, when qualifying words are used as part of the proper shipping name, their sequence on documentation or package markings is optional. For instance, "DIMETHYLAMINE AQUEOUS SOLUTION" may alternatively be shown "AQUEOUS SOLUTION OF DIMETHYLAMINE". Commercial or military names for goods of Class 1 which contain the proper shipping name supplemented by additional descriptive text may be used.

Many substances have an entry for both the liquid and solid state (see definitions for liquid and solid in 1.2.1), or for the solid and solution. These are allocated separate UN numbers which are not necessarily adjacent to each other'. Unless it is already included in capital letters in the name indicated in Table A or Table C in Chapter 3.2, the qualifying word "MOLTEN" shall be added as part of the proper shipping name when a substance, which is a solid in accordance with the definition in 1.2.1, is offered for carriage in the molten state (e.g. ALKYLPHENOL, SOLID, N.O.S., MOLTEN). Except for self-reactive substances and organic peroxides and unless it is already included in capital letters in the name indicated in Column (2) of Table A of Chapter 3.2, the word "STABILIZED" shall be added as part of the proper shipping name of a substance which without stabilization would be forbidden from carriage in accordance with paragraphs 2.2.X.2 due to it being liable to dangerously react under conditions normally encountered in carriage (e.g.: "TOXIC LIQUID, ORGANIC, N.O.S., STABILIZED"). When temperature control is used to stabilize such substances to prevent the development of any dangerous excess pressure, then: (a)

For liquids: where the SADT is less than or equal to 50 OC, the provisions of 2.2.41.1.1 7, the special provision V8 of Chapter 7.2, the special provision S4 of Chapter 8.5 and the requirements of Chapter 9.6 shall apply; for carriage in IBCs and tanks, all the provisions applicable to UN No. 3239 apply (see in particular 4.1.7.2 of ADR, packing instruction IBC520 and 4.2.1.13 of ADR);

(b)

For gases: the conditions of carriage shall be approved by the competent authority.

3.1.2.7

Hydrates may be carried under the proper shipping name for the anhydrous substance.

3.1.2.8

Generic or "not otherwise specified" (N.O.S.) names Generic and "not otherwise specified" proper shipping names that are assigned to special provision 274 in Column (6) of Table A in Chapter 3.2 or remark 27 in column (20) of Table C in Chapter 3.2 shall be supplemented with the technical name of the goods unless a national law or international convention prohibits its disclosure if it is a controlled substance. For explosives of Class 1, the dangerous goods description may be supplemented by additional descriptive text to indicate commercial or military names. Technical names shall be entered in brackets immediately following the proper shipping name. An appropriate modifier, such as "contains" or "containing" or other qualifying words such as "mixture", "solution", etc. and the percentage of the technical constituent may also be used. For example: "UN 1993 FLAMMABLE LIQUID, N.O.S. (CONTAINS XYLENE AND BENZENE), 3,II".

3.1.2.8.1.1

1

The technical name shall be a recognized chemical name, if relevant a biological name, or other name currently used in scientific and technical handbooks, journals and texts. Trade names shall not be used for this purpose. In the case of pesticides, only I S 0 common name(s), other name(s) in the World Health Organization (WHO) Recommended Classification of Pesticides by Hazard and Guidelines to Classification, or the name(s) of the active substance(s) may be used.

Details are provided in the alphabetical index (Table B of Chapter 3.2), e.g.: NITROXYLENES, LIQUID 6.1 1665 NITROXYLENES, SOLID 6.1 3447 - 180 -

When a mixture of dangerous goods is described by one of the "N.O.S." or "generic" entries to which special provision 274 has been allocated in Column (6) of Table A in Chapter 3.2, or remark 27 has been allocated in column (20) of Table C in Chapter 3.2, not more than the two constituents which most predominantly contribute to the hazard or hazards of a mixture need to be shown, excluding controlled substances when their disclosure is prohibited by national law or international convention. If a package containing a mixture is labelled with any subsidiary risk label, one of the two technical names shown in parentheses shall be the name of the constituent which compels the use of the subsidiary risk label. NOTE: see 5.4.1.2.2. 3.1.2.8.1.3

Examples illustrating the selection of the proper shipping name supplemented with the technical name of goods for such N.O.S. entries are: UN 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. (drazoxolon); UN 3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATERREACTIVE (trimethylgallium).

3.1.2.8.1.4

Examples illustrating how the proper shipping name is supplemented in the indication of the vapour pressure or the boiling-point for N.0.S entries for carriage in tank vessels are: UN No. 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S., l l 0 kPa < pv5O 5 150 kpa;

UN No. 1993 FLAMMABLE LIQUID, N.O.S. (ACETONE with more than 10% BENZENE), pv 50 5 l l 0 kPa, 85" C < bp 5 115" C. Mixtures and solutions containing one dangerous substance

When mixtures and solutions have to be regarded as the dangerous substance mentioned by name in accordance with the classification requirements of 2.1.3.3, the qualifying word "SOLUTION" or "MIXTURE", as appropriate, shall be added as part of the proper shipping name, e.g. "ACETONE SOLUTION". In addition, the concentration of the solution or mixture may also be indicated, e.g. "ACETONE 75% SOLUTION".

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CHAPTER 3.2 DANGEROUS GOODS LIST

List of dangerous goods in numerical order Explanations concerning Table A: As a rule, each row of Table A of this Chapter deals with the substance(s) or article(s) covered by a specific UN number or an identification number. However, when substances or articles belonging to the same UN number have different chemical properties, physical properties andlor carriage conditions, several consecutive rows may be used for that UN number or identification number. Each column of Table A is dedicated to a specific subject as indicated in the explanatory notes below. The intersection of columns and rows (cell) contains information concerning the subject treated in that column, for the substance(s) or article(s) of that row: -

The first four cells identify the substance(s) or article(s) belonging to that row (additional information in that respect may be given by the special provisions referred to in Column (6));

-

The following cells give the applicable special provisions, either in the form of complete information or in coded form. The codes cross-refer to detailed information that is to be found in the numbers indicated in the explanatory notes below. An empty cell means either that there is no special provision and that only the general requirements apply, or that the carriage restriction indicated in the explanatory notes is in force.

The applicable general requirements are not referred to in the corresponding cells. Explanatory notes for each column: Column (1 )

"UN numberlidentification number". Contains the UN number or the identification number:

Column (2)

-

of the dangerous substance or article if the substance or article has been assigned its own specific UN number or identification number, or

-

of the generic or n.0.s. entry to which the dangerous substances or articles not mentioned by name shall be assigned in accordance with the criteria ("decision trees") of Part 2.

"Name and description" Contains, in upper case characters, the name of the substance or article, if the substance or article has been assigned its own specific UN number or identification number, or of the generic or n.0.s. entry to which it has been assigned in accordance with the criteria ("decision trees") of Part 2. This name shall be used as the proper shipping name or, when applicable, as part of the proper shipping name (see 3.1.2 for further details on the proper shipping name).

A descriptive text in lower case characters is added after the proper shipping name to clarify the scope of the entry if the classification and/or carriage conditions of the substance or article may be different under certain conditions. Column (3a)

"Class" Contains the number of the Class, whose heading covers the dangerous substance or article. This Class number is assigned in accordance with the procedures and criteria of Part 2.

Column (3b)

"Classification code" Contains the classification code of the dangerous substance or article.

-

For dangerous substances or articles of Class 1, the code consists of a division number and compatibility group letter, which are assigned in accordance with the procedures and criteria of 2.2.1.1.4.

-

For dangerous substances or articles of Class 2, the code consists of a number and one or more letters representing the hazardous property group, which are explained in 2.2.2.1.2 and 2.2.2.1.3.

-

For dangerous substances or articles of Classes 3, 4.1,4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 8 and 9, the codes are explained in 2.2.x. 1.2.

'

-

Column (4)

Dangerous substances or articles of Class 7 do not have a classification code.

"Packing group" Contains the packing group number(s) (I, I1 or 111) assigned to the dangerous substance. These packing group numbers are assigned on the basis of the procedures and criteria of Part 2. Certain articles and substances are not assigned to packing groups.

Column (5)

"Labels" Contains the model number of the labels/placards (see 5.2.2.2 and 5.3.1.1.7) that have to be affixed to packages, containers, tank-containers, portable tanks, MEGCs and vehicles. However: -

For substances or articles of Class 7, 7X means label model No. 7A, 7B or 7C as appropriate according to the category (see 2.2.7.8.4 and 5.2.2.1.11.1) or placard No. 7D (see 5.3.1.1.3 and 5.3.1 .l .7.2).

The general provisions on labellinglplacarding (e.g. number of labels, their location) are to be found in 5.2.2.1 for packages, and in 5.3.1, for containers, tank-containers, MEGCs, portable tanks and vehicles.

x

= the

Class number of the dangerous substance or article, without dividing point if applicable.

- l84 -

NOTE: Special provisions, indicated in Column (6), may change the above labelling provisions. Column (6)

"Special provisions" Contains the numeric codes of special provisions that have to be met. These provisions concern a wide array of subjects, mainly connected with the contents of Columns (1) to (5) (e.g. carriage prohibitions, exemptions from requirements, explanations concerning the classification of certain forms of the dangerous goods concerned and additional labelling or marking provisions), and are listed in Chapter 3.3 in numerical order. If Column (6) is empty, no special provisions apply to the contents of Columns (1) to (5) for the dangerous goods concerned. Special provisions specific to inland navigation begin at 800.

Column (7)

"Limited quantities" Contains an alphanumeric code with the following meaning: "LQO" signifies that no exemption from the provisions of ADN exists for the dangerous goods packed in limited quantities; -

Column (8)

All the other alphanumeric codes starting with the letters " L Q sign@ that the provisions of ADN are not applicable if the conditions indicated in Chapter 3.4 are fulfilled (general conditions of 3.4.1 and conditions of 3.4.3, 3.4.4, 3.4.5 and 3.4.6, as appropriate, for the relevant code).

"Carriage permitted" This column contains the alphanumeric codes concerning the permitted form of carriage in inland navigation vessels. If column (8) is empty, the substance or article may only be carried in packages. If column (8) contains code "B", carriage is permitted in packages or in bulk (see 7.1.1.1 1). If column (8) contains code "TV, carriage is permitted in packages and in tank vessels. In the event of carriage in tank vessels, the requirements of Table C are applicable (see 7.2.1.21). If "carriage prohibited" appears in column (8), carriage is not permitted. If "free" appears in column (S), the substance is not subject to the requirements of ADN.

Column (9)

"Equipment required" This column contains the alphanumeric codes for the equipment required for the carriage of the dangerous substance or article (see 8.1 S).

Column (10)

"Ventilation"

- l85 -

This column contains the alphanumeric codes of the special requirements concerning ventilation applicable to carriage with the following meaning: -

Column (1 1)

alphanumeric codes starting with the letters "VE" mean that special additional conditions are applicable to carriage. These can be found in 7.1.6.12 and establish special requirements.

"Provisions concerning loading, unloading and carriage" This column contains the alphanumeric codes of the special requirements applicable to carriage with the following meaning:

Column (12)

-

alphanumeric codes starting with the letters " C O , "ST" and "RA" mean that special additional conditions are applicable to carriage in bulk. These can be found in 7.1.6.11 and establish special requirements.

-

alphanumeric codes starting with the letters "LO" mean that special additional conditions are applicable prior to loading. These can be found in 7.1.6.13 and establish special requirements.

-

alphanumeric codes starting with the letters "HA" mean that special additional conditions are applicable to the handling and stowage of the cargo. These can be found in 7.1.6.14 and establish special requirements.

-

alphanumeric codes starting with the letters "M" mean that special additional conditions are applicable to the inspection of holds during carriage. These can be found in 7.1.6.16 and establish special requirements.

"Number of cones/blue lights" This column contains the number of conesllights which should constitute the marking of the vessel during the carriage of this dangerous substance or article (see 7.1S).

Column (13)

"Additional requirements/Remarksfl This column contains additional requirements or observations concerning the carriage of this dangerous substance or article

iiN No. or ID No.

Name and description

Class

lassifi. 'acking cation Code group

2.2

0

0 D004

1.1D

wetted with less than 10% water, by nass

0005

1.1F with bursting charge

0006

ZARTRIDGES FOR WEAPONS with bursting charge

1

1.1E

-

0007

1.2F

with bursting charge

3009

1.2G with or without burster, expelling ;harge or propelling charge

3010

1.3G with or without burster, expelling :harge or propelling charge

Labels

Special provisions

Limited quantities

Equipment required

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

(2)

ZARTRIDGES FOR WEAPONS, NERT PROJECTILE or XRTRIDGES, SMALL ARMS ZARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK QMMUNITION, SMOKE with or without burster, expelling charge or xopelling charge

Class

lassifi cation Code

2.2

2.2

00

Labels

5.2.2 (5)

1

1.4s

1.4

1

1.4s

1.4

1.2G

Equipment Ventilation required

8.1.5

Provisions concerning loading, unloading and carriage

7.1.6

7.1.5

0 0

0

PP

0

PP

0

PP HA03, HA04, ha05,

4MhWNITION. SMOKE with or without burster, expelling charge or xopelling charge, containing :orrosive substances

1.2G

PP

IZMMUNITION, SMOKE with or without burster, expelling charge or ~ropellingcharge

1.3G

PP

OMUNITION, SMOKE with or without burster, expelling charge or ~ropeilingcharge, containing mrrosive substances

1.3G

PP

4MMUNITION, TEARPRODUCING with burster, :xpelling charge or propelling :harge

1.2G

PP

Number of cones, blue lights

HA06 LOO1 HAOI, HA03, HA04, HA05, HA06 LOOl HAO1, HA03, HA04. HA05. HA06 LOO1 HAo1. HA03. HA04. HA05

E LOOl HAo1.

Remarks

U N No

or ID No.

Name and description

J2.L

3.1.2 (2) AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge

0020

AMMUNITION, TOXIC with burster, expelling charge or propelling charge AMMUNITION, TOXIC with bunter, expelling charge or . propelling charge BLACK POWDER (GUNPOWDER), granular or as a meal

0019

0021

-

0027

0028

-

Limited Carriage Equipment quantities permitted required

Provisions concerning loading, unloading and carriage

7.1.6 (11) LOO1 HAOI, HA03, HA04, HA05, HA06

I

Number of cones, blue lights

7.1.5 (12) 3

c CARRIAGEPROHIBITED CARRIAGEPROHIBITED

BLACK POWDER (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS

0029

DETONATORS, NON-ELECTRI( for blasting

0030

DETONATORS. ELECTRIC for blasting

HAo5, HA06 HAO1, HA02, HA03, HA04, HAO5, HA06 HAOI, HA02, HA03, HA04, HAo5, HA06

3

3

1

Remarks

3.2.1 (13)

UN No

or ID No.

Name and description

-

3.1.2 (2)

0 0033

BOMBS with bursting charge

Class

Ilassifi cation Code

2.2

2.2

0 m 1 1.1F

Labels

5.2.2 (5) 1

Special provisions

3.3 (6)

Limited quantities

3.4.6

0 LQO

Equipment Ventilation required

8.1.5

Provisions concerning loading, unloading and carriage

7.1.6

Number of cones, blue lights

7.1.5 (12) 3

0 0 PP

HA02. HA03, HA04. HA05 HA06 0034

BOMBS with bursting charge

1.1D

LQO

PP

ha01,

3

HA02, HA03, HA04, HA05, HA06 0035

-

30MBS with bursting charge

0037

BOMBS, PHOTO-FLASH

0038

SOMBS. PHOTO-FLASH

0039

BOMBS, PHOTO-FLASH

1.2D

1.lF

LQO

PP

LQO

PP

1.1D

LQO

PP

1.2G

LQO

PP

-

-

ha01,

HA03. HA04, HA05, HA06 LOO l ha01, HA02, HA03, HA04, HA0.5, - HA06 LOO1 HAOI, HA02, HA03, HA04, HA0.5, HA06 LOO1 ha01, HA03, HA04, HA05, HA06

3

3

3

3

Remarks

UN No or ID No.

Name and description

0

\-,

0042

BOOSTERS without detonator

0043

BURSTERS, explosive

0044

PRIMERS, CAP TYPE

0048

0049

0050

Class

lassie cation Code

acking group

Labels

2.2

2.2

1.1.1.3

5.2.2

Special provisions

00 (4) 0

3.3 (6)

Limited quantities

3.4.6

0

1

1.lD

l

1.1D

LQO

1.4s

LQO

CHARGES. DEMOLITION

1.lD

LQO

CARTRIDGES, FLASH

1.1G

LQO

CARTRIDGES, FLASH

1.3G

LQO

1

1

brriage Equipment Ventilation iermitted required

LQO

Provisions concerning loading, unloading and carriage

7.1.6 (10)

Number of cones, blue lights

7.1.5

LOO1 HAo1, HA02, HA03. HA04, HA05, - HA06 LOO1 HAOI, HA02, HA03, HA04, HA05, HA06 LOO1 HAo1, HA03, HA04, HA05, HA06 LOO1 HAOI, HA02, HA03, HA04, HA05, - HA06 LOO1 HAOI, HA02, HA03, H.404, HA05, HA06 LOO l HAOI, HA03, HA04, HA05, HA06

0 3

Remarks

UN No or ID No.

Name and description

Class

3.1.2

:lassiii cation Code

2.2

m 1.3G

CARTRIDGES, SIGNAL

1.4s

Special provisions

Limited Carriag, Equipmen quantities permitte required

Provisions concerning loading, unloading and carriage

8.1.5

0

7.1.5 (12)

PP

LOO1

PP

LOO l

PP

LOO l

WITH PRIMER

P CHARGES, DEPTH

1.1D

1.1D

LOO1

detonator

l

CHARGES, SUPPLEMENTARY, EXPLOSIVE

1

CORD, DETONATING, flexible

1

1.1D

1.lD

Number of cones, blue lights

LOO1

LOO1

3

Remarks

UN No or ID No.

111 0066

0070

-

Name and description

(2) IORD, IGNITER

:UTTERS, CABLE, EXPLOSIVE

Class

Xassifi. cation Code

Limited quantities

2.2

2.2

3.4.6

00 1

1

0072

ZYCLOTRZMETHYLENErRINITRAMINE (CYCLONITE; IEXOGEN; RDX), WETTED wit1 lot less than 15% water, by mass

1

0073

IETONATORS FOR MMUNITION

1

XAZODINITROPHENOL, WETTED with not less than 40% at er, or mixture of alcohol and at er, by mass

1

XETHYLENEGLYCOL IINITRATE, DESENSITIZED ~ i t hnot less than 25% non-volatile. at er-insoluble phlegmatizer, by nass

1

0074

0075

1.4G

0

1.1D

7.1.6

0 HA03, HA04, HA05, HA06 -

LQO

LQO

1.1B

Provisions concerning loading, unloading and carriage

LQO

1.4s

Carriage Equipment Ventilation ~ermitted required

ha01,

HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 -

LQO

ha01,

1.1A

LQO

HA02, HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HA05, HA06

1.1D

LQO

ha01,

HA02, HA03, HA04, HA05, HA06

Number of cones, blue lights

Remarks

LJNNo

or ID No.

Name and description

3.1.2

111 0076

0077

-

(2) DINITROPHENOL, dry or wetted with less than 15% water, by mass

DINITROPHENOLATES, alkali metals, dry or wetted with less than 15% water. by mass

Class

lassif catior Code

2.2

2.2

00 l

1.1D

Labels

5.2.2 (5) 1+6.1

1+6.1

Special provisions

Limited Carriage Equipment Ventilatior quantities permittec required

3.2.1 (8)

8.1.5 (9) PP

PP

0078

DMITRORESORCINOL, dry or wetted with less than 15% water, b) mass

PP

0079

HEXANITRODIPHENYLAMINE (DIPICRYLAMINE; HEXYL)

PP

0081

EXPLOSIVE, BLASTING, TYPE A

PP

EXPLOSIVE, BLASTNG, TYPE B

PP

0082

Provisions concerning loading, unloading and carriage

7.1.6

0

0 HA0 l , HA02, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04. HA05, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 HAOI, H.402, HA03, HA04, H.405, HA06

Number of cones, blue lights

Remarks

UN No. or m NO.

Name and description

3.1.2 (2) EXPLOSIVE, BLASTING, TYPE C

EXPLOSIVE, BLASTING, TYPE D

Class

2.2

lassifi. 'acking cation Code POUP

2.2

00 1

1

1.1D

1.1D

Labels

Special provisions

Limited quantities

.required

Ventilation

3.3

3.4.6

8.1.5

7.1.6

0 0

0

267 617

LQO

617

LQO

PP

PP

FLARES, SURFACE

1.3G

LQO

PP

FLARES, AERIAL

1.3G

LQO

PP

FLASH POWDER

1.1G

LQO

PP

LQO

PP

FRACTURING DEVICES, EXPLOSIVE without detonator, fo~ oil wells

1.1D

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.5

(10)

LOO1 HA02, HA03, HA04, HA05, HA06 -LOO1 HAOI, HA02, HA03, HA04, HAOS, HA06 LOO1 HAo1, HA03, HA04, HAOS, HA06 LOO1 HAOI, HA03, HA04. HA05, HA06 -LOO l HAOl, HA02, HA03, HA04, HA05, HA06 LOO1 HAo1, HA02, HA03, HA04, HA05, HA06 -

(12) 3

Remarks

JN No or ID No.

Name and description

3.1.2 (2) FUSE, NON-DETONATING

CORD (FUSE), DETONATING, metal clad

Class

2.2

m 1 1

7assi6 cation Code

m 2.2

1.3G

1.2D

FUSE, IGNITER, tubular, metal clad

1.4G

CORD (FUSE). DETONATING. MILD EFFECT. metal clad

1.4D

FUSE, SAFETY

1.4s

FUZES, DETONATING

1.1B

FUZES, DETONATING

1.2B

'acking BOUP

Labels

Special provisions

Limited quantities

Equipment required

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

I : ' 7.1.6

7.1.5

UN No

or ID No.

Name and description

Class

3.1.2

Xassiti cation Code

2.2 -

a 0110 GRENADES, PRACTICE. hand or

0 1.4s

Labels

Special provisions

Limited quantities

5.2.2

3.3

3.4.6

1.4

PP

266

LQO

PP

266

LQO

PP

1.1D

LQO

PP

1.1G

LQO

PP

1.lA

GUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass

1.1A

GUANYLTETRAZENE (TETRAZENE), WETTED with no less than 30% water, or mixture of alcohol and water, by mass 0118

KEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass

0121

D124

1

1.lD CHARGED, oil well, without ietonator

Provisions concerning loading, unloading and carriage

8.1.5

LQO

-

0114

3.2.1

0 (6) 0 _(8L 0

rifle

0113

Carriag Equipment ~ermitte required

PP

Number of cones, blue lights

7.1.5

0 HAo1. HA03. HA04. HA05. HA06 HAo1. HA02. HA03. HA04. HA05. HA06 HAOI. HA02. HA03. HA04. HA05, HA06 HAOI, HA02, H.403, HA04, HAOS, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 HAOI, HA02, HA03. HA04, HA05, HA06

0 0

3

Remarks

mNo Name and description

or ID No.

0 0129

GTTED

LEAD AZIDE, with not less than 20% water, or mixture of alcohol and water, by mass

Class

lassifi :ation Code

2.2

2.2

00 1

1.lA

Labels

Special provisions

Limited quantities

3arriage ermittec

Provisions concerning loading, unloading and carriage

3.2.1

0 HA02, H.403, HA04, HAOS,

0130

LEAD STYF'HNATE (LEAD TRINTRORESORCINATE), WETTED with not less than 20% water, or mixture of alcohol and water, by mass

1

1.1A

0131

LIGHTERS, FUSE

1

1.4s

0132

DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES, N.O.S.

1

1.3C

0133

MANNITOL HEXANITRATE (NITROMANNITE), WETTED with not less than 40% water, or mixture of alcohol and water, by mass

l

1.1D

0135

MERCURY FULMINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass

1.1A

Number of cones, blue lights

Remarks

UN No or ID No.

Name and description

2.2

-

0 0136

Class

\-,

WNES with bursting charge

0 1

Xassifi cation Code

m 2.2

1.1F

Labels

Special provisions

Limited quantities

Eqniprnent red requi~

.

8.1. 5-l 0 --

PP

p -

0137

-

MINES with bursting charge

l

1.lD

PP

1

1.2D

PP

1

1.1D

PP

-

Provisions concerning loading, unloading and carriage

--

0138

MINES with bursting charge

0143

OITROGLYCERIN, )ESENSITIZED with not less than 10% non-volatile water-insoluble ~hlegmatizer,by mass

0144

OITROGLYCERIN SOLUTION N ALCOHOL with more than 1% )ut not more than 10% nitroglycerit

1.1D

PP

0146

JITROSTARCH, dry or wetted with less than 20% water, by mass

1.1D

PP

--

--

p -

HA02, HA03, HA04, HA05, HA06 HAOI, HA02, HA03. HA04, HA05, HA06 ha01, HA03, HA04, HA05, HA06 H.401, HA02, HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 ha01,

-

HA02, HA03, HA04, HA05, HA06 -

Number of cones, blue lights

Remarks

Name and description

Class

llassifi cation Code

Labels

3.1.2 (2)

2.2 (3a) l

2.2

5.2.2

0

NITRO UREA

PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN), WETTED with not less than 25% water, by mass. or DESENSITIZED with not less than 15% phlegmatizer, by mass PENTOLITE, dry or wetted with less than 15% water, by mass

1.1D

l

1.1D

1

1.1D

Special provisions

3.3 0 (6) 1

266

Limited quantities

3.4.6 LQO

LQO

PP

1.1D

LQO

PP

1.1D

LQO

PP

LQO

PP

1.1D

Provisions concerning loading, unloading and carriage

7.1.6

Nu mber of cones, blue lights

7.1.5

0

PP

PP

(PICRYL CHLORIDE)

8.1.5

LQO

(PICRAMIDE)

1

3.2.1

Ventilation

0000

-

TRINITROPHENOL (PICRIC ACID), dry or wetted with less than 30% water, by mass

larriage Equipment ermittec required

3

HA02, HA03, HA04, HA05, HA06 HAOI, HA02, H.403, HA04, HA05, HA06

HAOI, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06

3

Remarks

UN No or ID No.

Name and description

Class

ClassifiPacking cation Code group

Labels

Special Iprovisions

Limited quantities

Equipment required

Ventilation

Provisions concerning loading, unloading and carriage

2.2 (2) POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass POWDER, SMOKELESS

0 1

LOO1

1

LOO1

POWDER, SMOKELESS

1

LOO l

PROJECTILES with bursting charge

1

PROJECTILES with bursting charge

1

LOO l

PROJECTILES with bursting charge

1

LOO1

AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge

LOO1

1

LOO1

Number of cones, blue lights

Remarks

UN No. or m NO.

Name and description

Class

2.2

I

(2) 0173 1 RELEASE DEVICES, (1)

-I

0174

RIVETS, EXPLOSIVE

:lassifi 'acking cation Code group

ROCKETS with bursting cha

-I -I----T--

Limited quantities

Equipment required

Provisions concerning loading, unloading and carriage

2.2

1

1.4s

LOO1

1

1.4s

LOO1

1

1.1F

LOO1

1

1.1E

LOO l

0181

ROCKETS with bursting cha

0182

ROCKETS with bursting cha

1.2E

0183

ROCKETS with inert head

1.3C

-I

ROCKET MOTORS

1.3C

0186

Special provisions

00

I--0180

Labels

LOO1

LOO1

LOO1

Number of cones, blue lights

Remarks

UN No.

or ID No.

Name and description

3.1.2 (2) SAMPLES, EXPLOSIVE, other han initiating explosive

SIGNAL DEVICES, HAND

Class

lassifi. cation Code

2.2

2.2

0@L 1

1

-

Labels

Special provisions

5.2.2 3.3 (5) (6) 16 274

Limited quantities

3.4.6

0 LQO

Equipment Ventilation required

8.1.5

PP

LQO

PP

1

LQO

PP

SIGNALS, RAILWAY TRACK, EXPLOSIVE

LQO

PP

SIGNALS, DISTRESS, ship

LQO

PP

SIGNALS, DISTRESS, ship

LQO

PP

SIGNALS, RAILWAY TRACK, EXPLOSIVE

7.1.6

Number of cones, blue lights

7.1.S

0 0

1.4

1.4G

Provisions concerning loading, unloading and carriage

LOO1

HA02, HA03, HA04, HA05, HA06 LOO1 HAo1, HA03, HA04, HAOS, - HA06 LOO1 HAo1, HA02, HA03, HA04, HAOS, HA06 LOO1 HAo1, HA03, HA04, HAOS, HA06 LOO1 HAO1, HA02, HA03, HA04, HA05, - HA06 LOO l HAOI, HA03, HA04, HAOS, HA06 -

(12) 3

Remarks

LJNNo or ID No.

Name and description

Class

Jassifi cation Code

2.2

2.2

J.30196

3.1.2 (2) SIGNALS, SMOKE

0m

0197

SIGNALS, SMOKE

- l 1.4G

0204

SOUNDING DEVICES, EXPLOSIVE

0207

TETRANITROANILINE

0208

TRINITROPHENYLMETHYLMTRAMINE (TETRYL)

0209

TRINITROTOLUENE (TNT), dry or wetted with less than 30% water. by mass

Special provisions

5.2.2

3.3

0(6)

Limited Carriage Equipment quantities permittec required

8.1.5

Provisions concerning Jentilation loading, unloading and carriage

7.1.6

0(10) PP

LOO1

PP

LOO1

1.2F

PP

L 0 0l

1 1.1D

PP

L 0 0l

1.1D

PP

LOO1

PP

LOO l

1

1

1.1G

Labels

1

1.4

Number of cones, blue lights

7.1.5 (12) 3

Remarks

Name and description

3.1.2 (2) TRACERS FOR AMMUNITION

Class

:lassifi cation Code

2.2

2.2 -

0 (3b) 1

1.3G

Labels

Special provisions

Limited quantities

5.2.2

3.3

3.4.6

8.1.5

7.1.6

Number of cones, blue lights

LOO1

PP

LOO l

3

LQO

PP

LOO1

3

LQO

PP

LOO1

LQO

PP

LOO1

LQO

PP

LOO1

0 (10)

LQO

PP

1.1D

LQO

TRINITROBENZENE, dry or wetted with less than 30% water, b! mass

1.1D

TRINITROBENZOIC ACID, dry o wetted with less than 30% water, b! mass

1.1D

TRINITRONAPHTHALENE

Provisions concerning loading, unloading and carriage

7.1.5 (12) 3

000 1

Equipment Ventilatior required

-

Remarks

UN No. or LD No.

Name and description

3.1.2 (2) TRINITROPHENETOLE

(1)

0218

Class

2.2

lassifi cation Code

2.2

m

0 1

1.1D

1

1.1D

1

1.1D

Labels

Special provisions

5.2.2

0 1

Limited quantities

Equipmen required

Provisions concerning loading, unloading and carriage

8.1.5

0 PP

7.1.5

LOO1

PP

LOO l

1.1D

PP

LOO1

1.1D

PP

LOO1

PP

LOO1

(STYPHNIC ACID), dry or wetted with less than 20% water, or mixture of alcohol and water, by

T UREA NITRATE, dry or wetted with less than 20% water, by mass

0220

I

0221

1 WARHEADS, TORPEDO with

1

-

bursting charge

0222

0224

AMMONIUM NITRATE with more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance BARIUM AZIDE, dry or wetted with less than 50% water, by mass

1

0

LOO1

PP

1

Number of cones, blue lights

3

HA02, HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, H.405, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HAo5, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 -

Remarks

UN No. or ID No.

Name and description

Class

3.1.2

0 0225

0226

Labels

Special provisions

Limited quantities

5.2.2

3.3

3.4.6

0 (6) 0

BOOSTERS WITH DETONATOR

1

Equipment required

Provisions concerning loading, unloading and carriage

8.1.5

0

LQO

PP

7.1.5 (12)

LOO1

I

-

SODIUM DINITRO-0CRESOLATE, dry or wetted with less than 15% water, by mass

LQO

PP

LOO1

CYCLOTETRAMETHYLENETETRANITRAMINE (HMX; OCTOGEN), WETTED with not less than 15% water, by mass

266

LQO

PP

LOO1

-

0235

! SODIUM PICRAMATE, dry or wetted with less than 20% water, bj mass

LQO

PP

0236

ZIRCONIUM PICRAMATE, dry o

LQO

PP

0237

CHARGES, SHAPED, FLEXIBLE, LINEAR

LQO

PP

LOO1

LQO

PP

LOO l

0234

0238

1

1 ROCKETS, LINE-THROWING

Number of cones, blue lights

LOO1

LOO1

3

3

3

Remarks

LJNNo.

or ID No.

Name and description

Class

lassifi cation Code

2.2

m 1.3G I

I

0241

1 EXPLOSIVE, BLASTING,

0242

1 CHARGES, PROPELLING, FOR I

1

1

1

1.1D

1.3C

Labels

Special provisions

Limited Carriage Equipment Ventilatio~ quantities permittec required

8.1.5

7.1.6

(9) PP

(10)

PP

PP

CANNON

I

0243

I

1 AMMUNITION, INCENDIARY, I

1

1.2H

PP

WHITE PHOSPHORUS with burster, expelling charge or propelling charge

1.3H

PP

WHITE PHOSPHORUS with burster, expelling charge or propelling charge l

l

0245

1 AMMUNITION, SMOKE. WHITE 1

1

1.2H

PP

1.3H

PP

PHOSPHORUS with burster, expelling charge or propelling charge PHOSPHORUS with burster, expelling charge or propelling charge

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No.

or ID No.

Name and description

Class

3.1.2 (2) AMMUNITION, INCENDIARY, liquid or gel, with bnrster, expelling charge or propelling charge

2.2 (3a) 1

0 0247

0248

Classifi cation 'acking Code gr'"'p

2.2 (3b) 1.35

Labels

Special provisions

Provisions concerning Limited Carriagq Equipment quantities permitte~ required Ventilation loading, unloading and carriage

3.3

0

8.1.5

0 PP

CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge

1

1.2L

274

PP

CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge

1

1.3L

274

PP

0250

ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge

1

1.3L

PP

0254

AMMUNITION, ILLUMINATINC with or without burster, expelling charge or propelling charge

1

1.3G

PP

0255

DETONATORS, ELECTRIC for blasting

1

1.4B

PP

0257

FUZES, DETONATING

1

1.4B

PP

0249

-

HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

(2) OCTOLITE (OCTOL), dry or wetted with less than 15%~water,bj mass

Class

Iassifi cation Code

2.2

2.2 -

m 1

DETONATORS, NON-ELECTRIC for blasting

1

BOOSTERS WITH DETONATOR

0 1.1D

1.4B

Labels

Special provisions

5.2.2

3.3

0 (6) 1

Limited quantities

Carriage Equipmen1 ~ermitted required

Ventilatior

3.4.6 3.2.1 8.1.5 7.1.6 (7) 00 (10) PP LQO

Provisions concerning loading, unloading and carriage

LOO l

1.4

LQO

PP

l

l

LQO

PP

CHARGES. PROPELLING

1

1

LQO

PP

CHARGES, PROPELLING

1

LQO

PP

LOO1

CARTRIDGES, POWER DEVICE

I

LQO

PP

LOO1

LOO l

LOO1

LOO1

Number of cones, blue lights

Remarks

UN No.

or ID No.

Name and description

Class

:lassifi cation Code

2.2

m 1.4C

Labels

5.2.2 (5) 1.4

Special provisions

Limited Carriage Equipment Ventilation quantities permittec required

3.3 (6)

Provisions concerning loading, unloading and carriage

8.1.5

Number of cones, blue lights

Remarks

7.1.5 (12) 1

0 PP

HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA0.5, HA06 HAo1, HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA0.5, HA06

----lCARTRIDGES, OIL WELL

1.3C

1

PP

3

----lCARTRIDGES, OIL WELL

1.4C

1.4

PP

1.1C

1

PP

I

CHARGES, PROPELLING, FOR CANNON

1

1

i ROCKET MOTORS

1.1C

T ROCKET MOTORS

NITROGUANIDINE (PICRITE), k y or wetted with less than 20% water, by mass

1.2C

1.1D

1

PP

PP

PP

Name and description

3.1.2 (2) BOOSTERS without detonator

Class

llassifi cation Code

2.2

2.2

(3a) 0 1

GRENADES, hand or rifle, with bursting charge

1

GRENADES, hand or rifle, with

1

1.2D

1.1D

bursting charge

5.2.2

0 1

Limited Carriag quantities bermitte

3.4.6

LQO

LQO

LQO

1

1.1D

LQO

1

1.2D

LQO

-

3.2.1

Equipmenl required

fentilation

Provisions concerning loading, unloading and carriage

8.1.5

CHARGES, SHAPED, FLEXIBLE LINEAR

LQO

CORD, DETONATING, flexible

LQO

Number of cones, blue lights

7.1.5

0(8) 0

1.2D

bursting charge

WARHEADS, ROCKET with

Special orovisions

-

bursting charge

WARHEADS, ROCKET with

Labels

0

PP

3

HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HAOS, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HAOS, HA06 HAOI, HA03, HA04, HA05, HA06

3

3

3

Remarks

Name and description

3.1.2 (2) CORD (FUSE), DETONATING,

Class

3assifi cation Code

2.2

2.2

00 1

1.1D

Labels

Special provision!

5.2.2 (5) 1

3.3 (6)

Limited quantities

Equipment required

3.4.6

8.1.5 (9)

0 LQO

PP

metal clad

BOMBS with bursting charge

1

1.2F

PP

GRENADES, hand or rifle, with bursting charge

1

1.1F

PP

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.5 (12) 3

LOO1 HA02, HA03, HA04, HA05, HA06 LOO l HAOI, HA02. HA03, HA04, HA05, HA06 LOO1 HAOI, HA02, H.403, HA04,

3

3

ha05,

GRENADES, hand or rifle, with

1

1.2F

PP

MINES with bursting charge

1.2F

PP

ROCKETS with bursting charge

1.2F

PP

bursting charge

HA06 LOO1 HAOI. HA02, HA03, HA04. HA05, - HA06 LOO1 HAOI, HA02, HA03, HA04, HA05, HA06 LOO1 HAOI, HA02, H.403, HA04, HA05, HA06

3

Remarks

UN No.

or ID No.

Name and description

3.1.2 (2) _(II 0296 SOUNDING DEVICES, EXPLOSIVE

0297

AMMUNITION, ILLUMINATIN( with or without burster, expelling charge or propelling charge

0299

BOMBS, PHOTO-FLASH

0300

AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge AMMUNITION, TEARPRODUCNG with burster, expelling charge or propelling charge AhENUNITION, SMOKE with or without burster, expelling charge o: propelling charge AMhfUNITION, SMOKE with or without burster, expelling charge o propelling charge, containing corrosive substances

Class

lassifi. cation Code

2.2

2.2

m m 1 1.1F

Labels

Special provisions

Limited Carriage Equipmen) Ventilation quantities permittec required

3.4.6 (7) LQO

1.4G

LQO

1.3G

LQO

1.4G

LQO

3.2.1 (8)

7.1.6 (10)

Provisions concerning loading, unloading and carriage

7.1.6 (11) LOO1 HAOI. HA02, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA0.5, HA06

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

3.1.2 (2) 'LASH POWDER

Class

:lassifi cation Code

2.2

2.2

group

Labels

Special

Limited Carriagc Equipment Ventilation quantities permitte~ required

8.1.5

Provisions concerning loading, unloading and carriage

7. l.6

Number of cones, blue lights

PP

7.1.5 (12) 3

1.4G

PP

1

1

1.4G

PP

1

1

1.2G

PP

3

GNITERS

1.2G

PP

3

GNITERS

1.3G

PP

3

'UZES, IGNITING

1.3G

PP

RACERS FOR AMMUNITION

SARTRIDGES, SIGNAL

XGNALS, SMOKE

l%?l. m l

1

-

1.3G

0 0

Remarks

Name and description

Class

:lassifi cation Code

2.2

2.2

0m 1

1.4G

Special provisions

Limited quantities

5.2.2 (5) 1.4

3.3 (6)

0 00 0

3.4.6

LQO

Carriage Equipment Ventilation wmittec required

3.2.1

8.1.5

PP

GRENADES, PRACTICE, hand or rifle

1

1.3G

1

LQO

PP

PRIMERS, TUBULAR

1

1.3G

1

LQO

PP

1.4G

LQO

PP

CARTRIDGES FOR WEAPONS with bursting charge

1.2E

LQO

PP

ROCKET MOTORS WITH HYPERGOLIC LIQULDS with or without expelling charge

1.2L

LQO

PP

CARTRIDGES, POWER DEVICE

1.4s

LQO

PP

PRIMERS. TUBULAR

Provisions concerning loading, unloading and carriage

Labels

-

7.1.6

LOO1

HA031 HA04, HA05, HA06 LOO1 HAOI, HA03, HA04, HAOS, - HA06 LOO1 HAOI. HA03, HA04, HAOS, HA06 LOO1 ha01, HA03, HA04, HAOS, HA06 LOO l HAOI, HA03, HA04, HA05, - HA06 LOO1 HA0 l, HA03, HA04, HA05, HA06 LOO1 ha01, HA03, HA04, HA05, HA06

Number of cones, blue lights

Remarks

LJNNa or ID No

Name and description

Class

Iassift cation Code

2.2

2.2

3.1.2 (2) _(11 0324 PROJECTILES with bursting charge

00

D325 IGNITERS

1 1.4G

1

1.2F

Labels

Special provisions

Limited quantities

5.2.2

3.3

3.4.6

Carriage Equipment Ventilation ~ermittec required

3.2.1

8.1.5

Provisions concerning loading, unloading and carriage

7.1.6

0 (6) 000 0 l

1.4

LQO

PP

LOO1

LQO

PP

LOO1

D326

CARTRIDGES FOR WEAPONS, BLANK

1

1.1C

LQO

PP

LOO1

3327

CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK

1

1.3C

LQO

PP

LOO l

3328

CARTRIDGES FOR WEAPONS, INERT PROJECTILE

1

1.2C

LQO

PP

LOO l

3329

TORPEDOES with bursting charge

1

1.1E

LQO

PP

LOO1

HA02, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HA05. HA06 HAo1, HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 -

Number of cones, blue lights

Remarks

Name and description

3.1.2 (2) TORPEDOES with bimting chargc

EXPLOSIVE, BLASTING, TYPE B (AGENT, BLASTING, TYPE B

EXPI.OSIVE. BLASTING. TYPE E (AGENT, BLASTING, TYPE B

FIREWORKS

Class

lassifi :ation Code

2.2

2.2

00 1

1.1F

1 1.5D

Labels

Special provisions

5.2.2 (5) 1

0

1.5

Provisions concerning loading, unloading and carriage

3.3

7.1.5

0

617

HA02, HA03, HA04, HA05, HA06 ha01,

HA03. HA04, HA05, HA06 1

1.5D

1.5

617

ha01,

HA03, HA04, HA05, HA06 1.1G

1

645

ha01,

HA02, HA03, HA04, HA05, HA06 HAOl, HA03, HA04, HA05, HA06 -

1.2G

645

FIREWORKS

1.3G

645

1.4G

Number of cones, blue lights

3

FIREWORKS

FIREWORKS

Limited Carriag~ Equipment Ventilation quantities permitte required

645 65 1

ha01.

HA03, H.04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06

3

Remarks

LJN No or ID No.

Name and description

3.1.2 (2)

FIREWORKS

CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK

Class

3assifi cation Code

2.2 2.2 0 0

1

1

1.4s

1.4C

CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS

1.4C

NITROCELLULOSE, dry or wette with less than 25% water (or alcohol), by mass

1.1D

NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass

1.1D

NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass

1.3C

NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance, by mas

1.3C

Labels

Special provisions

Limited quantities

Carriage Equipmenl Ventilation ~rmittec required

Provisions concerning lording, unloading and carriage

3.2.1 (8)

LOO1 HA03, HA04. HAo5, HA06 -LOO l HAo1, HA03, HA04, HAo5, HA06 LOO1 HAo1, HA03. HA04, HAo5, HA06 -LOO1 HAOI, HA02, HA03, HA04, HAo5, - HA06 LOO l HAOI, HA02, HA03, HA04, HAo5, HA06 LOO1 HAOI, HA03, HA04, HAo5, HA06 LOO l HAOI, HA03, HA04, HAo5, HA06

Number of cones, blue fights

Remarks

UN No or ID No.

Name and description

Class

Rassifi cation Code

2.2

0

0 0344

1.4D

charge

lacking group

Labels

Special provisions

Limited quantities

3.3 (6)

0

3.4.6

LQO

Equipmen required

8.1.5

CS)

Ventilation

Provisions concerning loading, unloading and carriage

7.1.6 (10)

7.1.5

0

PP

1

0345

PROJECTILES, inert with tracer

1

1.4s

LQO

PP

HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06

0346

PROJECTILES with burster or expelling charge

1

1.2D

LQO

PP

ha01,

0347

0348

i

PROJECTILES with burster or expelling charge

1.4D

LQO

PP

1.4F

LQO

PP

1.4s

LQO

PP

with bursting charge

0349

0350

ARTICLES, EXPLOSIVE, N.O.S.

1

S ARTICLES, EXPLOSIVE, N.O.S.

1.4B

LQO

Number of cones, blue lights

HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 ha01,

HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HA05, HA06

Remarks

UN No or ID No.

Name and description

3.1.2 (2)

mTICLES, EXPLOSIVE, N.O.S.

Class

2.2

m l

3assifi cation Code

2.2

(3b) 1.4C

Labels

5.2.2 (-5)

1.4

Special provisions

Limited quantities

3.3 3.4.6 (6) (7) 178 LQO 274

Equipmen required

Ventilatior

8.1.5

7.1.6

00 PP

mTICLES, EXPLOSIVE, N.O.S.

1.40

178 274

PP

IRTICLES, EXPLOSIVE, N.O.S.

1.4G

178 274

PP

YRTICLES, EXPLOSIVE, N.O.S.

1.IL

178 2 74

PP

IRTICLES, EXPLOSIVE, N.O.S.

1.2L

l78 274

PP

IRTICLES, EXPLOSIVE, N.O.S.

1.3L

l78 274

PP

XJBSTANCES, EXPLOSIVE, 4.0s.

1.1L

l78 274

PP

-

Provisions concerning loading, unloading and carriage

0 HA01 HA03. HA04. HA05 HA06 HAOI. H.403. HA04. HA05 HA06 HAOI. HA03. HA04. HA05 HA06 HAOI. HA02, HA03, HA04. HA05 HA06 HAo1, HA03, HA04, HA05, HA06 HAo1, HA03, HA04. HAo5, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 -

Number of cones, blue lights

7.1.5 (12)

1

1

Remarks

UN No or ID No.

Name and description

I I Class

Classifi cation Code

0 0358

Labels

Special provisions

5.2.2 (5) l

0

1

0359 V.O.S.

-

Limited Carriagt quantities permittec

3.3

l78 274

l78 274

Equipmenl Ventilation required

8.1.5

PP

1

PP

0361

IETONATOR ASSEMBLIES, \TON-ELECTRIC for blasting

1.4

PP

0362

4MMUNITION, PRACTICE

1.4

PP

1.4

PP

0364

Si TT 4MMUNITION, PROOF

DETONATORS FOR 4MMUNITION

PP

Number of cones, blue lights

7.1.5

(12) 3

PP

IETONATOR ASSEMBLIES, VON-ELECTRIC for blasting

0363

7.1.6

00

0360

-

Provisions concerning loading, unloading and carriage

HA03, HA04, HAo5, HA06 HAOI, HA03, HA04, HAo5, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, H.403, HA04, HAo5, HA06 HAo1, HA03, HA04, HA05, HA06 HAOl, HA03, HA04, HA05, HA06 HAOl, HA02, HA03, HA04, HA05, HA06 -

Remarks

UN No or ID No.

Name and description

Class

2.2

0366

-

2.2

Labels

Special provisions

Limited quantities

Carriage Equipment Ventilation ~ermittec required

Provisions concerning loading, unloading and carriage

3.2.1 (8)

(2) DETONATORS FOR AMMUNITION

m 1

0

DETONATORS FOR AMMUNITION

1

1.4s

LOO l

0 0365

3assif cation Code

1.4B

0367

FUZES, DETONATING

1.4s

LOO1

0368

FUZES, IGNITING

1.4s

LOO1

0369

WARHEADS, ROCKET with bursting charge

1.1F

,001

0370

WARHEADS, ROCKET with burster or expelling charge

1.4D

0371

WARHEADS, ROCKET with burster or expelling charge

1.4F

-

Number of cones, blue lights

Remarks

LJN No.

or ID No.

Name and description

Class

3.1.2 (2) GRENADES, PRACTICE, hand or rifle

W

0 0372

0373

SIGNAL DEVICES, HAND

03 74

2.2

1

lassifiPackio cation Code uOUp

Labels

Special provisions

5.2.2 (5) 1

3.3 (6)

1.4

Limited Carriage Equipment Ventilatior quantities permitted required

3.4.6 (7) LQO

3.2.1 (8)

8.1.5 (9) PP

LQ0

PP

SOUNDRVG DEVICES, EXPLOSIVE

LQ0

PP

0375

SOUNDING DEVICES, EXPLOSIVE

LQO

PP

D376

PRIMERS. TUBULAR

D377

PRIMERS. CAP TYPE

0378

PRIMERS. CAP TYPE

7.1.6

(10)

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.5

0 3

Remarks

--

Name and description

3.1.2 (2) CASES, CARTRIDGE?EMPTY, WITH PRIMER

Class

2.2

m 1

Special provisions

Limited quantities

3.3

3.4.6

0 0 LQO

ARTICLES, PYROPHORIC

1

LQO

CARTRIDGES, POWER DEVICE

1

LQO

COMPONENTS, EXPLOSIVE TRAIN, N.O.S.

LQO

COMPONENTS, EXPLOSIVE TRAIN, N.O.S.

LQO

COMPONENTS, EXPLOSIVE TRAIN, N.O.S.

LQO

LQO

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.5

0 1

3

Remarks

Class

3assifi cation Code

2.2

2.2 -

UN No.

or ID No.

111 0386

0387

-

Name and description

3.1.2 (2) TRINITROBENZENEIULPHONIC ACID

NNITROFLUORENONE

00 1

1

0388

MNITROTOLUENE (TNT) AN1 MNITROBENZENE MIXTURE br TRINITROTOLUENE (TNT) iND HEXANITROSTILBENE VlIxTURE

1

0389

rRINITROTOLUENE (TNT) v~IXTURECONTAINING rRINITROBENZENE AND IEXANITROSTILBENE

1

0390

1

1.1D

Labels

Special provisions

5.2.2

3.3

Limited Carriage Equipmen quantities permittec required

1

3.4.6 (7) LQO

1

0(6)

3.2.1 (8)

8.1.5

Ventilation

Provisions concerning loading, unloading and carriage

7.1.6

00 PP

LOO1

LQO

PP

LOO l

LQO

PP

LOO1

1.1D

PP

LOO1

1.1D

PP

LOO1

1.1D

1.lD

Number of cones, blue lights

7.1.5 (12)

3

Remarks

JN No or [DNo.

Name and description

Class

2 ) 0( )391

Classiti cation Code

Labels

Special provisions

Limited quantities

:arriag ermitte

5.2.2

3.3

3.4.6

3.2.1

0 0 0 (8)

)392

CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX) AND CYCLOTETRAMETHYLENETETRANITRAMmE (HMX; OCTOGEN) MIXTURE, WETTEI with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegnatiser by mas HEXANITKOSTILBENE

)393

HEXOTONAL

LQO

)394

TRINITRORESORCMOL (STYPHNIC ACID), WETTED with not less than 20% water, or mixture of alcohol and water, by

LQO

1

266

LQO

LQO

mass

1395

ROCKET MOTORS, LIQUID FUELLED

LQO

)396

ROCKET MOTORS, LIQUID FUELLED

LQO

Equipment Ventilation required

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

LJNNo,

or ID No.

Name and description

3.1.2 (2) 111 0397 ROCKETS, LIQUID FUELLED with bursting charge

-

Class

lassifi cation Code

2.2

2.2 -

m 1

Labels

Special provisions

Limited quantities

Equipment required

Provisions concerning loading, unloading and carriage

0 1.1J

HA02, HA03, HA04. HAOS. HA06 HAo1, HA03, HA04, HAOS, HA06 HAo1, HA02, HA03, HA04, HAOS, HA06 HAO1, HA03, HA04, HAOS, HA06

0398

ROCKETS, LIQUID FUELLED with bursting charge

1.2.l

0399

BOMBS WITH FLAMMABLE LIQUID with bursting charge

l.lJ

0400

BOMBS WITH FLAMMABLE LIQUID with bursting charge

1.25

040 1

DIPICRYL SULPHIDE, dry or wetted with less than 10% water, b, mass

1.1D

HAO1,

AMMONIUM PERCHLORATE

1.lD

HA02, HA03, HA04, HAOS, HA06 HAo1, HA02, HA03, HA04, HAOS, HA06

0402

Number of cones, blue lights

Remarks

UN No or ID No.

Class

lassif cation Code

3.1.2 2.2 ( I ) ( 2 )0 0403 FLARES. AERIAL 1

0

-

Name and description

2.2 1.4G

0404

FLARES, AERIAL

1.4s

0405

CARTRIDGES, SIGNAL

1.4s

0406

DINITROSOBENZENE

1.3C

0407

TETRAZOL-1-ACETIC ACID

1.4C

D408

FUZES, DETONATING with ~rotectivefeatures

1.1D

FUZES, DETONATING with xotective features

1.2D

-

3409

lacking POUP

Labels

Special provisions

Limited quantities

Carriage Equipment Ventilation ~ermittec required

Provisions concerning loading, unloading and carriage

3.2.1 (8) HA03, HA04, HA05, HA06 ha01, HA03, HA04, HAOS, HA06 HAOI, HA03, H.404. HAOS, HA06 ha01, HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HAOS, HA06 ha01,

HA02, HA03, HA04, HA05, HA06 ha01,

HA03, HA04, HA0.5, HA06

Number of cones, blue lights

Remarks

UN No or ID No.

Name and description

3.1.2

Class

2.2

:lassif cation Code

2.2

( 1 ) (2) 0410 EUZES, DETONATING with protective features

00

-

-

1

1

1.4D

Labels

5.2.2

Special provisions

Limited quantities

3.3

3.4.6

0 0(7) 1.4

LQO

041 1

PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) with no less than 7% wax, by mass

0412

CARTRIDGES FOR WEAPONS with bursting charge

1.4E

LQO

0413

CARTRIDGES FOR WEAPONS, BLANK

1.2C

LQO

0414

CHARGES, PROPELLING, FOR CANNON

1.2C

LQO

0415

CHARGES, PROPELLING

1.2C

LQO

0417

CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS

1.3C

LQO

1.1D

1

131

LQO

Equipmen required

Provisions concerning

Ventilation

I loading, unloading a i d carriage

8.1.5

7.1.5

0

0

PP

PP

Number of cones, blue lights

1

HA03, HA04, HA05, HA06 HAOl, HA02, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 -

Remarks

UN No or ID No.

Name and description

Class

Zlassiti. cation Code

Labels

Special provisions

Limited quantities

Equipment required

Ventilation

Provisions concerning loading, unloading and carriage

3.1.2 (2)

FLARES, SURFACE

FLARES, SURFACE

FLARES, AERIAL

FLARES, AERIAL

PROJECTILES, inert with tracer

PROJECTILES, inert with tracer

PROJECTILES with burster or expelling charge

HAo1. HA02. HA03. HA04. HA05. HA06 HAOI. HA03. HA04. HA05. HA06 HAOI. HA02. HA03. HA04. HA05. HA06 HAo1. HA03. HA04. HA05. HA06 HAOI. HA03. HA04. HA05. HA06 HAOI, HA03, HA04, HA05. HA06 HAo1, HA02, HA03, HA04. HA05,

UN No or ID No.

Name and description

Class

2.2 (2) PROJECTILES with burster or :xpelling charge

0 1

Labels

Special provisions

5.2.2

3.3

Limited Carriage Equipment Ventilatior quantities ~ermitted required

3.4.6

0 (6) 0 1.4

LQO

4RTICLES, PYROTECHNIC for .eclmical purposes

1

1

LQO

aTICLES, PYROTECHNIC for echnical purposes

1

1

LQO

4RTICLES, PYROTECHNIC for :ethnical purposes

LQO

4RTICLES, PYROTECHNIC for technical purposes

LQO

ARTICLES, PYROlTCHhW for technical purposes

LQO

POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass

LQO

7.1.6 (10)

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or DD No.

Name and description

Class

:lassiti cation Code

2.2 -

a 0434 PROJECTILES with burster or

0 1.2G

zxpelling charge

-

Special provisions

Limited quantities

3.4.6 (7) LQO

-

043 5

Equipment required

Provisions concerning loading, unloading and carriage

8.1.5 LOO1

1.4G

LQO

PP

LOO l

1.2C

LQO

PP

LOO1

LQO

PP

LOO l

LQO

PP

LOO l

sxpelling charge

I

0436

ROCKETS with expelling charge

1

0437

ROCKETS with expelling charge

1

0438

3439

3440

l ROCKETS with expelling charge

I

"RGES, letonator

7.1.5 (12) 3

0 PP

SHAPED, without

1

LQO

PP

LOO1

ZHARGES, SHAPED, without letonator

1

LQO

PP

LOO1

Number of cones, blue lights

HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06 HAo1. HA03, HA04, HA05, HA06 HAO1, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HAo5, HA06 HAOI, HA03, HA04, HA05, HA06 HAOl, HA03, HA04, HA05, HA06 -

1

3

Remarks

Name and description

-

CHARGES, SHAPED, without

Class

7lassifi cation Code

2.2

2.2 -

00 1

1.4s

Labels

Special provisions

5.2.2 (5) 1.4

3.3 (6)

detonator

CHARGES, EXPLOSIVE, COMMERCIAL without detonator

1

CHARGES, EXPLOSIVE, COMMERCIAL without detonator

1

CHARGES, EXPLOSIVE, COMMERCIAL without detonator

l

1.1D

-

1

1.2D

l

1.4D

1.4

Limited Carriage Equipment Ventilation quantities permitted required

Provisions concerning loading, unloading and carriage

7.1.6 (10)

7.1.5 (12) 0

LOO1 HA03, HA04, HA05, HA06 LOO1 HAOI, HA02, HA03, HA04, HA05, HA06 LOO1 HAOI, HA03, HA04, HA05, HA06 LOO1 HAOI, H.403, HA04,

-I

1.4s

1.4

CASES, COMBUSTIBLE, EMPTY. WITHOUT PRIMER

1

1.4C

1.4

CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER

1

CHARGES, EXPLOSIVE, COMMERCIAL without detonator

1.3C

Number of cones, blue lights

H.405, HA06 LOO1 HAO1. HA03, HA04, HA05, HA06 LOO1 HAo1, HA03, HA04, HA05, HA06 LOO l HAOI, HA03, HA04, HA05, HA06

Remarks

UN No. or ID No.

Name and description

Class

2.2

m 1 ACETIC ACID

'lassifiPackin :ation Code

Limited quantities

3.4.6

0 LQO

l

LQO

1

LQO

with or without bursting charge

-C-0450

TORPEDOES, LIQUID FUELLED

with inert head

W 0451

TORPEDOES with bursting charge

LQO

i C 0452

GRENADES, PRACTICE, hand or

Provisions concerning loading, unloading and carriage

LQO

rifle

I

0453

ROCKETS, LINE-THROWING

LQO

0454

IGNITERS

LQO

Number of cones, blue lights

7.1.5

LOO1 HA03, HA04, HA05, HA06 LOO1 HAOI, HA02, HA03, HA04, HA05, - HA06 LOO l HAo1, HA03, HA04, HA05, - HA06 LOO1 HAo1, HA02, HA03, HA04, HA05, HA06 LOO1 HAOI, HA03, HA04, HA05, HA06 LOO1 HAOI, HA03, HA04, HA05, HA06 LOO1 HAOI, HA03, HA04, HA05,

0 1

3

Remarks

UN No. or ID No.

Name and description

3.1.2

0 0455

-

(2)

IETONATORS. NON-ELECTRIC o r blasting

Class

2.2

'lassifiPackin :ation Code

2.2

0 13b) 1

1.4s

0456

DETONATORS, ELECTRIC for Aasting

1

1.4s

0457

ZHARGES, BURSTING, PLASTICS BONDED

1

1.1D

0458

ZHARGES, BURSTING, PLASTICS BONDED

1.2D

0459

CHARGES. BURSTING. PLASTICS BONDED

1.4D

0460

CHARGES, BURSTING, PLASTICS BONDED

1.4s

-

0461

COMPONENTS, EXPLOSIVE TRAIN, N.O.S.

2.1.1.: (4)

Labels

Special provisions

Limited quantities

Zarriage Equipment Ventilation ermitted required

::

Provisions concerning loading, unloadin carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

Class

Classif cation Code

Labels

Special provisions

Limited Carriagc Equipment quantities permitte~ required

Provisions concerning loading, unloading and carriage

0462

3.1.2 (2) GRTICLES, EXPLOSIVE, N.O.S.

LOO1

0463

ARTICLES, EXPLOSIVE, N.O.S.

LOO1

0464

ARTICLES, EXPLOSIVE, N.O.S.

LOO1

0465

ARTICLES, EXPLOSIVE, N.O.S.

LOO1

0466

ARTICLES, EXPLOSIVE, N.O.S.

LOO l

0467

ARTICLES, EXPLOSIVE, N.O.S.

LOO1

0

-

-

Number of cones, blue lights

Remarks

3lassili cation Code

Name and description

Class

3.1.2 (2) 4RTICLES, EXPLOSIVE, N.O.S.

2.2 1

1.2E

5.2.2 (5) 1

4RTlCLES, EXPLOSIVE. N.O.S.

1

1.2F

1

4RTICLES, EXPLOSIVE, N.O.S.

2.2

0

Labels

Ventilation

Provisions concerning loading, unloading and carriage

7.1.6

0

1

:::l l HA03,

UTICLES, EXPLOSIVE, N.O.S.

4RTICLES, EXPLOSIVE, N.O.S.

SUBSTANCES, EXPLOSIVE, N.O.S.

Number of cones, blue lights

Remarks

UN No.

(1) 0474

0475

3.1.2 (2) SUBSTANCES, EXPLOSIVE, N.O.S.

1 SUBSTANCES, EXPLOSIVE,

2.2 (34 1

I

1

lassifiPacking cation Code

Labels

2.2 2.1.1.3 (3b) (4) 1.1C

5.2.2 (5) 1

Special provisions

Limited quantities

larriage Equipment Ventilation crmitted required

Provisions concerning loading, unloading and carriage

7.1.6 (10) LOO1

1.1D

1

LOO l

1.1G

1

LOO l

1.3C

1

LOO1

1.3G

1

LOO1

1.4C

1.4

LOO1

N.O.S.

N.O.S.

N.O.S.

N.O.S.

0479

SUBSTANCES, EXPLOSIVE, N.O.S.

N.O.S.

1

HA02, HA03, HA04, HA05, HA06 HAOI, HA02, H.403, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06 HAo1, HA03, HA04, HA05,

LOO1 HAOI, HA03, HA04, HA05, HA06 -

UN No

or ID No.

-

111 0481

Name and description

3.1.2 (2) SUBSTANCES, EXPLOSIVE, N.O.S.

Class

lassif cation Code

2.2

2.2

0m 1

1.4s

SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI), N.O.S.

1.5D

0483

CYCLOTRIMETHYLENETRINITRAMME (CYCLONITE; HEXOGEN; RDX), DESENSITIZED

1.1D

0484

CYCLOTETRAMETHYLENETETRANITRAMINE (HMX; OCTOGEN), DESENSITIZED

1.1D

0482

-

-

-

0485

SUBSTANCES, EXPLOSIVE. N.O.S.

0486

ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI)

1.6N

0487

SIGNALS, SMOKE

1.3G

1.4G

Provisions concerning loading, unloading and carriage

(11) ha01, HA03, HA04, HA05, HA06 ha01, HA03, HA04, HA05, HA06 ha01, HA02, HA03, HA04, HA05, HA06 HAOI, HA02, HA03, HA04, HA05, HA06 ha01, HA03, HA04, HA05, HA06 ha01, HA03, HA04, HA05, HA06 HAOI, HA03, HA04, HA05, HA06

Number of cones, blue lights

Remarks

7.1.5

3.2.1

(12) 0

(13)

3

3

3

Name and description

3.1.2 (2)

4MMUNITION. PRACTICE

Class

Iassifi cation Code

2.2

2.2

00 1

1.3G

DMITROGLYCOLURIL

1.1D

NITROTRIAZOLONE (NTO)

1.1D

P

CHARGES, PROPELLING

1.4C

SIGNALS, RAILWAY TRACK, EXPLOSIVE

1.3G

SIGNALS, RAILWAY TRACK, EXPLOSIVE

1.4G

E T PERFORATING GUNS, CHARGED, oil well, without ietonator

1.4D

Labels

Special provisions

Limited quantities

Carriage Equipment ~ermittec required

Provisions concerning loading, unloading and carriage

3.2.1

(8) LOO1 HA03, HA04, HA05, - HA06 LOO1 HAo1, HA02, HA03, HA04, HA05, HA06 LOO1 HAOI, HA02, HA03, HA04, HA05, HA06 LOO1 H.401, HA03, HA04, HA05, HA06 LOO1 HAo1, HA03, HA04, HA05, HA06 LOO l HAOI, HA03, HA04, HA05, HA06 LOO1 HAo1, HA03, HA04, HA05, HA06

Number of cones, blue lights

Remarks

3assiti cation Code

Labels

Ventilation

2.2 -

5.2.2

7.1.6

1

1.3C

(5) 1

(10)

OCTONAL

1

1.1D

PROPELLANT, LIQUID

1

1.1C

PROPELLANT, SOLID

1

PROPELLANT, SOLID

1

DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting

1

1.4s

PROPELLANT, SOLID

l

1.4C

Name and description

3.1.2 (2) PROPELLANT, LIQUID

Class

2.2

0(3b)

1.1C

1.3C

Provisions concerning loading, unloading and carriage

0 HAOI, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 HAo1, HA02, HA03, HA04, HA05, HA06 LOO l HAOI, HA03, HA04, HA05, HA06 LOO1 HAo1, HA03, H.404, HA05, HA06 LOO1 HAo1, HA03, HA04, HA05, HA06

Number of cones, blue lights

7.1.5 (12) 3

3

3

3

3

Remarks

UN No or ID No.

Name and description

Labels

Special provisions

Limited quantities

Equipment required

Ventilation

PP, EX, A

VEOl

3.1.2 (2) ROCKETS with inert head

0 0502

0503

AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT PRETENSIONERS

0504

1H-TETRAZOLE

1001 ACETYLENE, DISSOLVED 1002 AIR, COMPRESSED 1003 1005

AIR, REFRIGERATED LIQUlD AMMONIA, ANHYDROUS

- -

PP, EP, TOX, A

W02

1006 1008 1009 1010

1011

BROMOTRIFLUOROMETHANE (REFRIGERANT GAS R 13R 1) BU'I'ADIENES. STABILIZED or BUTADIENES'AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 "C not exceeding 1.1 MPa ( l l bar) and a density at

TOX, A PP PP, EX, A

VEO l

PP. EX. A

VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

Limited Carriage Equipment Ventilation quantities permitted required

TRANS-2-BUTYLENE CARBON DIOXIDE CARBON MONOXIDE, COMPRESSED CHLORINE

1

2

1 2 A I

1

2.2

1

2

1

I

1

2.3+2.1

1

I

2 I

CHLORODIFLUOROMETHANE 1 2 (REFRIGERANT GAS R 22) CHLOROPENTAFLUORO1 2 ETHANE (REFRIGERANT GAS I

1TF 2TC

I

1

2A

1

I

PP, EP, EX TOX, A PP, EP, TOX, A

I

1

2.2

1

1

1

1

2.2

1

I

(REFRIGERANT GAS R 124) CHLOROTRIFLUORO-

1

2

1 2 A I

1

2.2

1

R 13) COAL GAS, COMPRESSED

1

2

1

1

2.3+2.1

1

1TF

584 653

2.3+8

/ 2 A I

1

I 1 1

I

CYANOGEN

2

2TF

2.3+2.1

CYCLOPROPANE DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) DICHLOROFLUORO-METHANE (REFRIGERANT GAS R 21) 1,l -DIFLUOROETHANE (REFRIGERANT GAS R 152a) DIMETHYLAMINE, ANHYDROUS DIMETHYL ETHER ETHANE

2 2

2F 2A

2.1 2.2

2

2A

2.2

2

2F

2.1

2

2F

2.1

2 2

2F 2F

2.1 2.1

LQO

PP, EP, EX TOX, A PP, EP, EX TOX, A PP, EX, A

VEOl.

VEOl LQO

PP, EX, A PP, EX, A

VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

Name and description

3.1.2 (2) ETHYLAMINE ETHYL CHLORIDE ETHYLENE, REFRIGERATED LIQUID ETHYL METHYL ETHER ETHYLENE OXIDE

ETHYLENE OXIDE WITH XITROGEN up to a total pressure 3f 1 MPa ( l 0 bar) at 50 "C ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide FERTILIER AMMONIATINGSOLUTION with free ammonia FIRE EXTINGUISHERS with :ompressed or liquefied gas

Class

Xassifi cation Code

2.2

2.2

m m 2 2F 2 2

2F 3F

2 2

2F 2TF 2TF

2

2

2F

2

4A

2

6.4

2

ITOC

HELIUM, COMPRESSED HYDROGEN BROMIDE, 4NHYDROIJS HYDROGEN. COMPRESSED HYDROGEN CHLORIDE, 4NHYDROUS l IYDROGEN CYANIDE. STABILIZED containing less than 3% water FFYDROGEN FLUORIDE, 4NHYDROUS HYDROGEN SULPHIDE

2 -

1A 2TC

[SOBUTYLENE KRYPTON, COMPRESSED 1.ICiHTERS or LIGHTtK REFILLS containing flammable gal

FLUORINE, COMPRESSED

2 2 2

-

Labels

Special provisions

Limited Carriage Equipment Ventilation quantities permittec required

8.1.5

7.1.6

0 0 PP. EX. A PP, EX, A PP, EX, A 7

,

VEOl m01 VEOl

TOX. A

VEOl VEo1, VE02 VEOI, VE02

PP, EX, A

VEOl

,

,

PP, EP, TOX, A PP PP. EP.

1F 2TC

6.1

TF l

TOX, A >P,EP, EX TOX, A

8

CT l

PP, EP,

2

2TF

2

2F 1A 6F

2 2

Provisions concerning loading, unloading and carriage

VEOI, VE02

VE02 VEOl VEOl

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

SiJf

11

Equipment required Ventilation

Code

2.2.)

LIQUEFIED GASES, nonBammable, charged with nitrogen, I :arbon dioxide or air METHYLACETYLENEAND 1 2 PROPADIENE MIXTURE, 3TABILIZED such as mixture P1 )r mixture P2 METHYLAMINE, ANHYDROUS 2 2 METHYL BROMIDE with not nore than 2% chloropicrin METHYL CHLORlDE 1 2 REFRIGERANT GAS R 40) 2 METHYL MERCAPTAN

I

12.ti.3 2A

L 0

1

1 2 F I

1

2F 2T

Yi"i PP, EP, TOX, A

1 2 F I

]

2TF

I

WON, COMPRESSED VITROGEN, COMPRESSED JINITROGEN TETROXIDE NITROGEN DIOXIDE) VITROSYL CHLORIDE

2 2 2

1A 1A 2TOC

2.2 2.2 2.3+5.1+8

LQ 1 LQl LOO

2

2TC

2.3+8

LQO

VITROUS OXIDE 3IL GAS, COMPRESSED

2 2

20 ITF

2.2+5.1 2.3+2.1 I

3XYGEN, COMPRESSED IXYGEN, REFRIGERATED LIQUID PETROLEUM GASES, LIQUEFIED PHOSGENE

1 1

2 2

1

2

I

2

I

.

584

1 1

2.2+5.1 2.2+5.1

1 1

1 2 F I

1

2.1

1

I

2TC

I

LQo LQO I

I

1 1 0 1 1 3 0 1

I

274 1 5 8 3 639

2.3+8

I

I I

LQO LQO

I I

1

LOO

I

1

I

LQO

2 2

2F 2A

2

2TC

2.1 2.2

274

LQO L01

I

1

VE02

PP, EP, EX,^ TOX, A PP PP PP, EP, TOX, A PP, EP, TOX, A PP PP, EP, EX, TOX,A PP PP

VEO1, W02

I

VE02

PP, EP, TOX, A

l

PROPYLENE REFRIGERANT GAS, N.O.S.. ;uch as mixture F1, mixture ~2or nixture F3 SULPHUR DIOXIDE

Number of cones, blue lights

7.1.5

1 1 1

1

Provisions concerning loading, unloading and carriage

VE02 VE02

VEOl, VE02

T

PP, EP, TOX. A

WO2

1 2 1 2

Remarks

UN No. 1 or ID No.

Name and description

Class

ClassifiPacking cation Code

Labels

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

7.1.6

(1) l080 1081

(2) SULPHUR HEXAFLUORIDE TETRAFLUOROETHYLENE, STABILIZED 1082 I TRIFLUOROCHLOROETHYLENE, STABILIZED 1083 I TRIMETHYLAMINE,

(10) VEOl

l

I

I

---

.

-

I

I

LQO

I

I

LQO

T

I VINYL BROMIDE, STABILIZED

1087

1 VINYL METHYL ETHER,

I VINYL CHLORIDE.

l STABILIZED

=pqT+GG LQo

STABILIZED

LQO

ACRYLONITRILE, STABILIZED I

1098

ALLYL ALCOHOL I

1099

1100

ALLYL CHLORIDE

I

1106 1107 1108 1109 1110

( AMYLAMME AMYL CHLORIDE 1-PENTENE (n-AMYLENE) AMYL FORMATES n-AMYL METHYL KETONE

PP, EX, A

VEOl VEOl

PP, EX, A

VEOl

PP, EX, A PP, EX, A PP, EP, EX ( TOX, A ]PP. EP. EX TOX, A

/ 802

1

ALLYL BROMIDE

,

VEo1, VE02 VEOl

~

1085 1086

1093

IPP, EP, EX TOX, A PP, EX, A

LOO

I

T

LOO 802

1

LQO

T

LQ7 LQ4 LQ7 LQ4

T T

LQ7

LQ7 LQ7

1

TOX, A PP, EP. EX TOX, A PP, EP,EX TOX, A PP, EX, A PP, EX, A PP, EX,A PP, EP, EX I A !PP, EP, EX

PP, EX, A PP, EX, A

VEOl VEOl VEOl VEOl VEO1, VE02 VEO1, W02 VEo1, W02 VEo1, VE02 W01, VE02 VEOl VEOl VEOl VEO l VEOl VEOl VEOl VEOl VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

Classification Code

JN No. or m NO.

Name and description

Class

p~~??s

Labels "OUp

Provisions concerning Limited Carriage Equipment Ventilation loading, unloading and quantities permittec required camage

Number of cones, blue lights

7.1.5

0 1 0 1 1 1 0 1 0 1

1-BROMOBUTANE CHLOROBUTANES n-BUTYL FORMATE BUTYRALDEHYDE CAMPHOR OIL CARBON DISULPHIDE

3 3 3 3 3 3 I

ADHESIVES containing flammable1 liquid (vapour pressure at 50 "C more than l l 0 kPa) ADHESIVES containing flammable liquid (vapour pressure at 50 'C not mire thai I 10 k ~ a ) ADHESIVES containing flammable1 liquid ADHESIVES containing flanmable( liquid (having a flash-point below 23 'C and viscous according to 2.2.3.1.4) ( boiling point not more than 35" C)

F1 F1 F1 F1 F1 FT1 I

I

3

1

I1 I1 I1 I1 I11 I

F1

1

3 3 3 3 3 3+6.1 I

I

I

1 1 1 1 0 2

802 TOX, A PP, EX, A

W02 VEOl

PP, EX, A

VEOl

640D

PP,EX,A

VEOl

PP, EX,A

VEOl

I

3

I

I

3

1

I

3

I

640E

3

( F1 ( 111 (

3

1

640F

F1

I11

Remarks

JN No

or ID No.

Classifi. cation Code group

Name and description

Class

3.1.2 (2) ADHESIVES containing flammablc liquid (having a flash-point below 23 'C and viscous according to 2.2.3.1.4) (vapour pressure at 50 'C more than l l 0 kPa , boiling point o more than 35' C) ADHESIVES containing flammablc liquid (having a f l a s ~ ~ - ~ dbelow int 23 'C and viscous according to 2.2.3.1.4) (vapour pressure at 50 ' C not more than l10 k ~ a ) CHLOROBENZENE ETHYLENE CHLOROHYDRIN

2.2 (3a) 3

2.2 (3b) F1

3

COAL TAR DISTILLATES, FLAMMABLE COAL TAR DISTILLATES, FLAMMABLE COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes sucl as vehicle under coating. drum or barrel lining) COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes sucl as vehicle under coating, drum or barrel lining) (vapour pressure at 50 'C more than l l 0 kPa) COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes snd as vehicle under coating, drum or barrel lining) (vapour pressure at 50 "C not more than 110 kPa)

Labels

Special ororisions

Limited quantities

3.4.6

0

Equipment Ventilatior required

8.1.5

7.1.6

(10) 0

LQ7

PP, EX, A

VEOl

F1

LQ7

PP, EX, A

VEO l

3 6.1

F1 TF1

LQ7 LQO

3

F1

LQ4

PP, EX, A 'P, EP, EX TOX, A PP, EX, A

VEOl VEo1, W02 VEOl

3

F1

LQ7

PP, EX, A

VEOl

3

F1

LQ3

PP, EX, A

VEO l

3

F1

LQ6

PP, EX, A

VEO l

3

F1

LQ6

PP, EX, A

VEOl

W ,

Provisions concerning loading. -, unloading and carriage

-

Number of cones, blue lights

7.1.5

0 0

Remarks

m No or ID No.

111 1139

l139

1139

1139

L 143 l144

1145 1147 -

Name and description

Class

:lassifi cation Code

3.1.2 (2)

2.2 (3a) 3

m

COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) COATING SOLUTION (includes 3 surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) ( boiling point not more than 35' C) COATING SOLUTION (includes surface treatments or coatings used ( for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at 50 "C, boiling point of more than 35" C) COATING SOLUTION (includes 3 surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drwn or barrel lining) (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at 50 "C not more than l l 0 kPa) CROTONALDEHYDE or 6.1 CROTONALDEHYDE, STABILIZED CROTONYLENE 3 CYCLOHEXANE 3 CYCLOPENTANE 3 DECAHYDRO-NAPHTHALENE 3

2.2

F1

F1

F1

F1

TF1

Labels

Special provisions

5.2.2 3.3 (5) (6) 3 640E

Limited quantities

3.4.6

0

F1

F1 F1

8.1.5

7.1.6

(10) 0

LQ7

PP, EX, A

VEOl

640F

LQ7

PP, EX, A

VEOl

640G

LQ7

PP, EX, A

VEOl

640H

LQ7

PP, EX, A

VEOl

324 802

LQO

'P, EP, EX TOX, A

VEo1, W 02

LQ3 LQ4 LQ4 LQ7

PP, EX, A PP, EX, A PP, EX, A PP, EX, A

VEOl VEOl VEOl VEOl

F1 -

Provisions concerning Equipment Ventilation loading, unloading and required carriage

Number of cones, blue lights

Remarks

UN No, or ID No.

Name and description

I

class

:lassification Packing Code

Labels

3.3

-

0

1l48 1l48 1149 1150 1152 1153 ETHYLENE GLYCOL DETHYL ETHER 1153 ETHYLENE GLYCOL DIETHYL ETHER 1154 DlETHYLAMINE

1155

1156 1157 1158

1l61 1162

1163

3.4.6

1

3

LQ4 LQ7 LQ7 LQ4 LQ7 LQ4

1

3

LQ7

3.2.1 (8)

LQ4

3

DIMETHYLHYDRAZN, UNSYMMETRKAL DIMETHYL SULPHIDE DIOXANE DIOXOLANE DNINYL ETHER, STABILIZED EXTRACTS, AROMATIC, LIQUID EXTRACTS, AROMATIC, LIQUID (vapour pressure at 50 'C more than 110 kPa) EXTRACTS. AROMATIC, 3 LIQUID (vapour pressure at 50 'C not more than 110 kPa)

VEO l

T

IPP, EP, EX

WO1

* L04

3

3 3

3

PP, EX, A I

m

3 3

3 3 3 3 3

VEOl VEO l WO l VEOl VEOl VEOl

T

I

I

6.1

PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A

T

I

0

VEOl

1 3

DIMETHYLAMINE AQUEOUS SOLUTION DIMETHYL CARBONATE DIMETHYLDICHLORO-SILANE

(9)

TFC

I

I

1

6.1+3+8

LQO

I

1

I PP. EX. A PP, EP, EX

VEOl VEOl WO1

PP, EP, EX

VEOl m01

PP, EX, A PP, EP, EX A (PP, EP,EX

1 T

PP, EX, A

LQ3

PP, EX, A PP, EX, A PP, EX, A

T LQ6

Provisions concerning loading,carriage unloading and

7.1.6

8.1.5

T

I

I

DIETHYL ETHER (ETHYL ETHER) DlETHYL KETONE DIISOBUTYL KETONE DIISOPROPYLAMINE

Limited Carriage Equipment Ventilation quantities permitted required

0 (7)

1159 DIISOPROPYL ETHER 1160

Special provisions

VEO l m01 VEO1, m02 VEOl VEO l VEOl VEOl VEO l

PP, EX, A

VEOl

PP, EX, A

VEO l

Number of cones, blue lights

7.1.5 (12) 1 0 0 1 0 1

Remarks

UN No.

or ID No.

Name and description

3.1.2 (2) EXTRACTS, AROMATIC,

(1) 1169

Class

Classifi cation Code

2.2

2.2

00 3

-

3 LIQUID (having a flash-point below 23 "C and viscous according not to 2.2.3.1.4) ( boiling-point . more than 35' C) 1l69 1 EXTRACTS. AROMATIC. 3 LIQUID (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at 50 "C more than 110 kPa ,boiling point of more than 35" C) 1169 EXTRACTS, AROMATIC, 3 LIQUID (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vavour vressure at ihan i l 0 kPa) (ETHYL ALCOHOL) 3 I or ETHANOL SOLUTION I (ETHYL ALCOHOL SOLUTION) 1170 1 ETFIANOL SOLUTION (ETHYL 3 ALCOHOL SOLUTION)

F1

Labels

Special provisions

Limited quantities

Provisions concerning 3arriage Equipment Ventilation loading, unloading and ermitted required carriage

Si2;

1 1 PP, EX, A

7.1.6 (lo) VEOl

I

m&

I

3 3 3 3 3

3 3 3 3 6.1

m PP, EX, A

Number of cones, blue lights

Remarks

lassifi-

Special provisions

Name and description Code

[D No.

2.2 L182

TFC

2.1.1.3

5.2.2 6.1+3+8

3.3 (6) 802

3.4.6 (7) LQO

ETHYL CHLOROFORMATE

6.1

ETHYLDICHLOROSILANE

4.3

LQO

3

LQo

6.1

LQO

I

L 183 I

3.2.1 (8)

ETHYLENE DICHLORIDE

T

I

L 185

ETHYLENEIMINE, STABILIZED

8.1.5

(9) PP. EP. EX. TOX; A ]PP, E P , E x ~ A PP, EP, EX, TOX, A PP, EP, EX, TOX, A PP, EX, A

I

I

I

1184

LQ7

T

LQ7

1 1190 1191 1192 1193 1191

I

1

1195 1196 I

1197

[

1

/ HA08 I

I

I

VEOl

PP, EX, A

ETHYL PROPIONATE ETHYLTRICHLOROSILANE

3 3

LQ4 LQ4

PP, EP, EX, TOX, A PP,EX,A PP, EP, EX,

1 3

LQ3

PP, EX, A

WO1

LQ6

PP, EX, A

VEOl

LQ6

PP, EX, A

WO1

PP, EX, A LQ4 LQo

VEOI, VE02 VEOl WO1

A

I

LIQUID 1197 EXTRACTS, FLAVOURING, 3 LIQUID (vapour pressure at 50 "C more than l10 kPa) 3 1197 1 EXTRACTS. FLAVOURING, LIQUID (vapour pressure at 50 'C

7.1.6 (11)

VEOI, VE02 VEO1, VE02 VEOl

3 3 3 3

1 EXTRACTS, FLAVOURING,

I

'1

7.1.6 (10) VEO1. VE02 VEOl

MONOMETHYL ETHER ACETATE ET^ FORMATE OCTYL ALDEHYDES ETHYL LACTATE ETHYL METHYL KETONE (METHYL ETHYL KETONE) ETHYL NITRITE SOLUTION

-b

Provisions concerning loading, unloading and carriage

Limited Carriage Equipment Ventilation quantities permitted required

I

LQ7

I

l

PP, EX,A

VEOl

I

Number of cones, blue lights

Remarks

UN No. or ID No.

(1) 1197

1197

1197

Name and description

I

(2) IEXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) ( boiling point not more than 35" C) EXTRACTS, FLAVOURNG, LIQUID (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at 50 "C more than l l 0 kPa , boiling point of more than 35" C) EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 'C and viscous according to 2.2.3.1.4) (vapour pressure at 50 "C not more than l l 0 kPa) 1 FORMALDEHYDE SOLUTION. FLAMMABLE FURALDEHYDES

I 1198 1199

I HEATING OIL, LIGHT (flash-

Class

Zlassifi cation Code

2.2

2.2

00 3

3

3

F1

F1

F1

FC

TF1

Labels

Special provisions

Limited Carriage quantities permittec

-.

required

8.1.5

Ventilation

7.1.6

0 0 PP, EX, A

VEOl

PP, EX, A

VEOl

PP, EX, A

PP, EP, EX A PP. EP. EX

PP, EX, A

VEOl m01 m01

PP, EX, A

VEOl

PP, EX, A

VEOl

PP, EX, A

VEOl

I point not more than 60 "C)

1202

1 DIESEL FUEL. comdvinr with

standard EN 5 9 0 : 2 0 0 4 o r E ~OIL ~ or HEATING OIL, LIGHT with a flash-point as specified in EN 1 590:2-004 1202 1 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flashpoint more than 60 "C and not mon ihan 100 "C) 1203 1 MOTOR SPIRIT or GASOLINE 01 PETROL

1

l

Provisions concerning loading, unloading and camage

Number of cones, blue lights

Remarks

1 class

lassif cation Code

(2) I (3a) NITROGLYCERIN SOLUTION 1 3 IN ALCOHOL with not more than 1% nitroglycerin HEPTANES 3 3 HEXALDEHYDE HEXANES 3 3 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable PRINTING INK, flammable or 3 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (vapour pressure at 50 "C more than l l0 kPa) PRINTING INK, flannnable or 3 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (vapour pressure at 50 'C not more than l l 0 kPa) PRINTING INK, flammable or 3 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable PRINTING INK, flammable or 3 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) ( boiling point not more than 35" C)

Name and description

- -

'acking g'-"'P

Labels

Special provisions

m D

!.1.1.3 (4) I1

5.2.2 (5) 3

(6)

F1 F1 Fl F1

I1 III I1 I

3 3 3 3

LQ4 LQ7 LQ4 LQ3

F1

I1

3

I1

2.2

3.3

Limited Carriag quantities permitte

3.4.6

3.2.1

..

Eauiomeu required

Ventilatio~

8.1.5

Provisions concerning loading, unloading anc carriage

Number of cones, blue light

(12)

PP, EX, P

7.1.6 (10) VEOl

PP, EX, P PP, EX, P PP, EX, P PP, EX, P

VEOl VEOl VEOl VEOl

1 0 1 1

LQ6

PP, EX, A

VEOl

3

LQ6

PP, EX, A

VEOl

m1

3

LQ7

PP, EX, A

VEOl

111

3

LQ7

PP, EX, A

VEO l

0(8) 0 LQO

T T

7.1.5

1

Remarks

Class

Name and description

'lassifi cation Code

2.2

3.1.2

0

PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at 50 "C more than l l 0 kPa , boiling point of more than 35" C) PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at 50 'C not more than 110 kPa) ISOBUTANOL (ISOBUTYL ALCOHOL) ISOBUTYL ACETATE ISOBUTYLAMINE 1 1

1

ISOPROPYL NITRATE KEROSENE KETONES. LIQUID, N.O.S. (vavow vressure at 50 "C more than1 l16 k ~ a j KETONES, LIQUID, N.O.S. 1 (vapour pressure at 50 "C not more than l l 0 kPa)

Labels

Special provisions

Limited quantities

.

L

required

Ventilation

8.1.5

0

F1

PP, EX, A

VEOl

3

F1

PP, EX, A

VEOl

3

PP, EX, A

VEOl

3 3

F1 F1 FC

3 3 3

F1 F1 F1

PP, EX, A 'P, EP, EX A PP, EX, A PP, EX, A PP, EX, A

VEOl VEOl VEOl

F1 FC

PP, EX, A 'P, EP, EX

VEOl WO1

I

TSOOCTENES .-.ISOPRENt, SI'ABIIMFD ISOPROPANOL (ISOPROPYL ALCOHOL) ISOPROPYL ACETATE ISOPROPYLAMINE

Zroup

VEOl

F1 F1 F1

3

PP, EX, A

VEO l

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

mNo. or m No.

Name and description

Class

Xassifi. Packing cation Code group

2.2 F1 FT1 FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIOUID. FLAMMABLE. TOXIC,

3

FT1

F1 FT1 METHYL ACETATE METHYLAMYL ACETATE rnTHYLAL

F1 F1 F1 -

SOLUTION WETHYL BUTYRATE METHYL CHLOROFORMATE

F1 -

Labels

Special provisions

3.3 (6) 274 274 802

274 802

279 802

Limited Carriage Equipment Ventilation quantities permitted required

3.4; LQ7 LQO

11 T

TT

FC

3 6.1 I

METHYL CHLORO-METHYL ETHER METHYLDICHLOROSILANE

1

6.1

4.3

METHYL FORMATE METHYLHYDRAZINE

LQO

I

WFC

LQo

1

F1 TFC

LOO

F1 F1

LQ4

TF 1

-

PP. EP. EX

0 2

PP, EX, A PP, EX, A PP, EP, EX

1 0 1 1

I

PP, EX, A

VEOl VEo1, m02 VEOl VEOl

PP, EX, A

m01

PP. EP. EX

I

METHYL ISOBUTYL KETONE 1 3 METHYL ISOPROPENYL 1 3 KETONE. STABILIZED METHYL ME'I'HACKY LA'I'E

-A- F1

F1 -

F1

I I

LQ4

0

PP, EX, A PP, EP, EX I TOX,A ]PP, EP, EX TOX, A IPP, EP, EX

TFC

I

T

Number of cones, blue lights

7.1.5 (12) 0 2

8; PP, EX, A PP, EP, EX TOX, A

PP, EP, EX TOX, A

LOO

Provisions concerning loading, unloading and carriage

PP, EX, A PP, EX, A

Remarks

JN No. or ID No.

Name and description

3.1.2 (2) METHYLTRICHLOROSILANE

0 1250 1251 1259

METHYL VINYL KETONE, STABILIZED NICKEL CARBONYL

MTROMEWANE 1261 OCTANES 1262 - .- 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (vapour pressure at 50 'C more thar l l 0 kPa) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (vapour pressure at 50 'C not more - than l l d k ~ a ) 1263 PAINT (including - paint, - lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) - --

-

Class

Classifi cation Code

2.2

2.2

00 3

FC

TFC

TF1

Labels

Special provisions

Provisions concerning Limited Carriagc Equipment Ventilation loading, unloading and quantities permitte, required carriage

8.1.5

0 'P, EP, EX A 'P, EP, EX TOX, A 'P, EP, EX

F1 F1 -

.

Fl

F1

F1

F1

VEOl

PP, EX, A

VEOl

PP, EX, A

VEO l

PP, EX, A

VEOl

Number of cones, blue lights

Remarks

JN No. or [D No.

Name and description

3.1.2 (2) 0 1263 PAINT (includimg paint, lacquer, enamel, stain, sliellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flash-point below 23 "C and viscous according to 2.2.3.1 ( boiling point not more than 35" C). L263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flash-point below 23 "C and viscous according to 2.2.3.1) (vapour pressure at 50 'C more thar 110 kPa ,boiling point of more thar 35" - C). 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATEC MATERIAL (including paint thinning and reducing compound) (having a flash-point below 23 "C and viscous according to 2.2.3.1) (vapour pressure at 50 "C not more

Class

2.2 -

lassifi :ation Code

acking ;roup

Labels

2.2

.1.1.3

5.2.2

00 0 (5)

3.3 (6) l63 640F 650

:arriage ermittec

3.2.1 3.4.6 (7) (8) LQ7

:quipmetit required

Jentilation

0 'P, EX, A

7.1.6 (10) VEOl

8.1.5

3

F1

111

3

3

F1

111

3

163 640G 650

LQ7

'P, EX, A

VEOl

3

Fl

111

3

l63 640H 650

LQ7

'P, EX, A

VEO l

3

F1

111 I

LQ7 LQ3 LQ4 LQ3

PP, EX, A PP, EX, A PP, EX, A PP, EX, A

WO1 VEOl VEOl VEOl

-

F1 3 3 3

flammable solvents

Limited Special ~rovisions quantities

F1 F1

-

11

I

Provisions concerning loading, unloading and carriage

Number of cones, due lights

Remarks

7.1.5

3.2.1

0 0

0

(13)

LrN No.

or ID No.

Name and description

Class

2.2

Labels

Special provisions

Limited Carriage Equipment quantities permittec required

v'entilation

3

F1

3

F1

I1

F1

111

PP, EX, A

VEOl

F1

111

PP, EX, A

VEOl

F1

111

PP, EX, A

VEOl

F1

111

PP, EX, A

VEO l

F1 F1

I I1

PP, EX, A PP, EX, A

VEOl VEOl

~1

n

PP, EX, A

VEOl

F1

111

PP, EX, A

VEO l

0 (3b)

5.2.2

1 1

2.1.1.3 (4) I1

2.2

(2) PERFUMERY PRODUCTS with flammable solvents (vapour pressure at 50 'C more than l l 0 Wa) PERFUMERY PRODUCTS with tlammable solvents (vapour pressure at 50 "C not more than 110 kPa) PERFUMERY PRODUCTS with flammable solvents PERFUMERY PRODUCTS with flammable solvents (having a flashpoint below 23 "C and viscous according to 2.2.3.1.4) ( boiling point not more than 35" C) PERFUMERY PRODUCTS with flammable solvents (having a flashpoint below 23 'C and viscous according to 2.2.3.1.4) (vapour pressure at 50 "C more than 110 W a , boiling point of more thar 35' C) PERFUMERY PRODUCTS with flammable solvents (having a flashpoint below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at 50 "C not more than l l 0 kPa) PETROLEUM CRUDE OIL PETROLEUM CRUDE OIL (vapour pressure at 50 'C more thar l l 0 kPa) PETROLEUM CRUDE OIL (vavour vressure at 50 'C not more than 110k ~ a ) PETROLEUM CRUDE OIL

'lassifiPacking :ation Code "OUp

0 3

3

8.1.5

7.1.6

PP, EX, A

VEOl

PP, EX, A

VEOl

Provisions concerning loading, unloading and carriage

0 0

Number of cones, blue lights

Remarks

JN No. Name and description

or [D No.

3.1.2

(2) ( I ) 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (vapour pressure at 50 OC more than - 110 kPa) 1268 PETROLEUM DISTILLATES. N.O.S. or PETROLEUM PRODUCTS, N.O.S. (vapour Dressure at 50 'C not more than 110 kPa) 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 1272 PINE OIL 1274 n-PROPANOL (PROPYL - ALCOlIOL. NORMAL) 1274 11-PROPANOI. (PROPYL ALCOHOL, NORMAL) 1275 PROPIONALDEHYDE 1276 n-PROPYL ACETATE 1277 PROPYLAMINE

1278 1279 1280 1281 1282 l286 1286 1286

1286 -

1-CHLOROPROPANE 1,2-DICHLOROPROPANE PROPYLENE OXIDE PROPYL FORMATES PYRIDINE ROSIN OIL ROSIN OIL (vapour pressure at 50 "C more tl& 110 kPa) ROSIN OIL (vavour pressure at 50 "C not more illan i l 0 kPa) ROSIN OIL ~

Class

1

Classifi. 'acking cation Code E'"-'UP

Special provisions

Limited Carriagc Equipment Ventilation quantities permitte~ required

8.1.5

Provisions concerning loading, unloading and carriage

7.1.6

0 0 PP, EX, A

VEO l

PP, EX, A

VEO l

PP, EX, A

VEOl

PP, EX, A

VEOl

PP, EX, A PP, EX, A

VEOl VEOl

PP, EX, A

VEOl

PP, EX, A PP, EX, A PP, EP, EX A PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A

VEOl VEOl VEOl

PP, EX, A

VEOl

PP, EX, A

VEOl

VEOl VEOl VEOl VEOl VEOl VEO l VEOl

~~

Number of cones, blue lights

7.1.5 (12) l

Remarks

IN No or ID No.

Name and description

Class

2.2

111 1286

\-I

ROSIN OIL (having a flash-point below 23 "C and viscous accordine to 2.2.3.1.4) ( boiling point not more than 35" C) ROSIN OIL (havine a flash-voint . below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at 50 'C more than 110 kPa , boiling point of more than 35" C) ROSIN OIL (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at ~

1286

1286

:lassifi. 'acking cation Code group

2.2

m m 3 F1

Labels

Special provisions

Limited quantities

Equipment Ventilation required

8.1.5

0 PP, EX, A

-

-

1287 1287

3

3

\

F1

F1

-

PP, EX, A

VEOl

PP, EX, A

VEOl

F1 F1

PP, EX, A PP, EX, A

F1

PP, EX, A

VEOl

PP, EX, A PP, EX, A

VEO l VEOl

F1

PP, EX, A

VEOl

3

F1

PP, EX, A

VEOl

3

F1

PP, EX, A

VEOl

3 3

pressure at 50 "C more than 110 kPa) 1287 RUBBER SOLUTION (vapour pressure at 50 "C not more than 110 kPa1 -. -p. 1287 RUBBER SOLUTION 1287 RUBBER SOLUTION (having a flash-point below 23 "C and visco~ according to 2.2.3.1.4) ( boiling point not more than 35" C) 1287 RUBBER SOLUTION (having a flash-point below 23 "C and visco~ according to 2.2.3.1.4) (vapour pressure at 50 "C more than l l 0 kPa , boiling point of more tha 35O C) 1287 RUBBER SOLUTION (having a flash-point below 23 'C and visco~ according to 2.2.3.1.4) (vapour vressure at 50 "C not more than - l l 0 kPa) 1288 SHALE OIL

-

3 3 3

3

F1 F1

-

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

:lassifi-

JN No. or m NO.

Name and description

Code

2.2

-

111

-

L288

SHALE OIL SODIUM METHYLATE - SOLUTION in alcohol 1289 SODIUM METHYLATE 1289

1292 1293 1294 1295

TINCTURES, MEDICINAL TOLUENE TRICHLOROSILANE

l296

-

TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% - trimethylmine, by mass 1297 TWETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass l298 TRIMETHYLCHLORO-SILANE 1297

-

1299 1300 1300 1301 1302 VINYL ETHYL ETHER, STABILIZED 1303 VINYLIDENE CHLORIDE, - STABILIZED 1304 VINYL ISOBUTYL ETHER, STABILIZED 1305 VMYLTRICHLOROSILANE, STABILIZED P

Special provisions

Class

2.2

2.1.1.3

Carriage Equipment Limited Ventilation quantities ~ermitted required

5.2.2

(3b) (4) @ ?(5) l

3 3

F1 FC

111 I1

3 3+8

3

FC

111

3+8

3 3 3 3 4.3

F1 F1 F1 F1 WFC

III I1 I11 I1 I

3 3 3 3 4.3+3+8

3

FC

I1

3+8

FC

I

3+8

1 T

T

A (PP, EP, EX A PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EP, EX

VEO l PP, EP, EX

VEO l

PP, EP, EX

VEOl

PP, EP, EX

VEOl

PP, EP, EX PP, EX, A PP, EX, A

PP, EX, A

VEOl VEOl VEOl VEOl VEOl

PP, EX, A

VEOl

P

P

P

VEO l VEOl VEOl VEO l VEOl

VEOl

IIIL PP, EP, EX

VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

JN No. or [D No.

Name and description

3.1.2 (2) WOOD PRESERVATIVES, LIQUID (vapour pressure at 50 "C more than l10 k g ) WOOD PRESERVATIVES. LIQUID (vapour pressure at 50 'C not more than 110 kPa) WOOD PRESERVATIVES, LIQUID WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) ( boiling point not more than 35" C) WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at 50 "C more than l10 kPa , boiling point of more than 35" C) WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at 50 'C not more than l l 0 kPa) XYLENES XYLENES ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID (vapour pressure at 50 "C more than 110 kPa) ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID (vapour pressure at 50 "C not more than l l 0 kPa)

Class

Classifi. 'acking cation Code BOUP

Labels

5.2.2 (4) (5) I1 3

-

Special provisions

Limited Carriagc Equipment quantities permitte~ required

3.3

0 640C

8.1.5

0 PP, EX, A

I1

640D

PP, EX, A

I11

640E

PP, EX, A

640F

PP, EX, A

III

640G

PP, EX, A

111

640H

PP, EX, A

111

-

I1 111 I

I1

I1

Ventilation

PP, EX, A PP, EX, A PP, EX, A PP, EX, A

PP, EX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.5 (12) 1

Remarks

I JN No. or [D No.

Name and description

Class

ClassifiPacking cation Code group

'Pecia' provisions

Labels

Limited Carriage Equipment Ventilation quantities permitted required

3.1.2 (2) ZIRCONIUM SUSPENDED IN A FLAMMAB1.E LIQUID ALUMINIUM POWDER. COATED ALUMINIUM POWDER, COATED AMMONIUM PICRATE, WETTED with not less than 10% water, by mass BORNEOL CALCIUM RESINATE CALCIUM RESINATE, FUSED COBALT RESINATE. PRECIPITATED DINITROPHENOL, WETTED with not less than 15% water, by mass DINITROPHENOLAES, WETTED with not less than 15% water, by mass DINITRORESORCINOL, WETTED with not less than 15%

8.1.5

0 PP, EX, A PP PP PP

PP PP PP PP PP

BASE, gelatin coated, except scrap FLAMMABLE SOLID. ORGANIC, N.O.S. FLAMMABLE SOLID, ORGANIC, N.O.S. HAFNIUM POWDER. WETTED with not less than 25% water Hay, Straw or Bhusa HEXAMETHYLENE-

PP l

4.1

l

l

F1

111

I

4.1

274

PP PP I

NOT SUBJECT 0 ADN PP

I

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.5 (12) 0

Remarks

UN No. or ID No.

Name and description

3.1.2 (2) 1331 MATCHES, 'STRIKE ANYWHERE' 1332 METALDEHYDE 1333 CElUUM, slabs, ingots or rods 1334 NAPHTHALENE, CRUDE or - NAPHTHALENE, REFlNED 1336 NITROGUANIDINE (PICRITE), WETTED with not less than 20% water, by mass 1337 NITROSTARCH, WETTED with not less than 20% water, by mass 1338 PHOSPHORUS, AMORPHOUS 1339 PHOSPHORUS HEPTASULPHIDE, free from yellow and white phospl~orus 1340 PHOSPHORUS PENTASULPHIDE, free from yellow and white phosphorus 1341 PHOSPHORUS SESQUISULPHIDE, free from and white phosphorus 1343 PHOSPHORUS TRISULPHIDE, free from yellow and white phosphorus 1344 TRINITROPHENOL, WETTED with not less than 30% water, by mass 1345 RUBBER SCRAP or RUBBER SHODDY. powdered or granulated 1346 SILICON POWDER. AMORPHOUS 1347 SILVER PICRATE, WETTED wit1 not less than 30% water, by mass 1348 SODIUM DINITRO-0CRESOLATE, WETTED with not less than 15% water, by mass

Class

Classifi cation

Labels

Special orovisions

Limited quantities

Iarriage Equipmenl ermitted required

fentilation

Provisions concerning loading, unloading and carriage

0

COO l

l PP, EX, A

Number of cones, blue lights

Remarks

JN No Name and description

or ID No.

Class

3.1.2 (2) SODIUM PICRAMATE, WETTEI ~ i t not h less than 20% water, by

2.2 -

nas

-

SULPHUR TITANIUM POWDER WETTED with not less than 25% water FIBRES or FABRICS [MPREGNATEDWITH W E A W VITRATED NITROCELLULOSE, N.O.S. TRINITROBENZENE. WETTED with not less than 30% water, by mass ~RINITROBENZOICACID, WETTED with not less than 30% water, by mass RINITROTOLUENE (TNT), WETTED with not less than 30% water, by mass UREA NITRATE, WETTED with not less than 20% water, by mass ZIRCONIUM POWDER, WETTED with not less than 25% water CALCIUM PHOSPHIDE CARBON, animal or vegetable origin CARBON, animal or vegetable origin CARBON, ACTIVATED COPRA

COTTON WASTE, OILY

Limited Carriage Equipment Ventilation quantities permitted required

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

7.1.6 (10)

0 4.1 4.1 4.1 4.1

4.1

4.1 4.1 4.1 4.1 l

4.3

LQO

4.2

LQO

I

I

IPP, EP, EX TOX, A PP

4.2

4.2 4.2

4.2

LQO

I

B

1

NO1 and m02 apply only when !his substance is zarried in bulk or without packaging

PP

LTN No.

or m No.

Name and description

3.1.2

i

cation Code

Labels

Special provisions

Provisions concerning Limited Carriage Equipment quantities permitted required Ventilation loading, unloading and carriage

Number of cones, blue lights

3.3

(6)

l ANILINE 1372

1 Fibres, animal or fibres, vegetable 1 burnt, wet or damp FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC. N.O.S. with oil

1373

4.2

NOT SUBJECT TO ADN

s2

nr

4.2

274

LQO

S2

I1

4.2

300

LQO

S4

111

4.2

592

LQO

4.2

S4

I1

4.2

274

LQo

4.2

S2

111

4.2

ST3

I

4.2+6.1

802

LQO

ST3

I

4.2+6.1

503 802

LQo

ST4

I

4.2+6.1

LQO

PP, EP

2

S4

I1

4.2

503 802 5 04

LQO

PP

0

S4

I

4.2

274

LQO

PP

0

S4

I1

4.2

LQo

PP

0

S4

I1

4.2

LQO

PP

0

4.2

UNSTABILIZED SPONGE, SPENT obtained from coal gas purification 1378 METAL CATALYST, WETTED I with a visible excess of liquid 1379 1 PAPER. UNSATURATED OIL TREATED, incompletely dried

1381 1381

1

1

PHOSPHORUS, WHITE or 4.2 YELLOW, UNDER WATER or IN ~ T I O ' N PHOSPHORUS, WHITE or YELLOW, DRY POTASSIUM SULPHIDE, ANHYDROUS or POTASSIUM SULPHIDE with less than 30% water of c stallization PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. 1 SODIUM DITHIONITE (SODIUM I 4.2

r 1382

1383 1384

I

1

ANHYDROUS or SODIUM SULPHIDE with less than 30%

LQO

504

B

B

B

PP

o

PP

0

PP

0

PP

0

PP

0

PP, EP, TOX, A PP, EP, TOX, A

VE02

2

VE02

2

Remarks

Name and description

3.1.2 (2) SEED CAKE with more than 1.5% oil and not more than 11% moisture.

Wool waste, wet ALKALI METAL AMALGAM, LIQUID ALKALI METAL AMIDES

Class

:lassifi. cation Code

2.2

2.2 -

3.2.1

4.2

S2

IN01 and IN02 apply only when this substance is carried in bulk or without packaging

Provisions concerning loading, unloading and carriage

Limited Carriage Equipment Ventilation quantities permitted required

Special provisions

0m

4.2 4.3 4.3

S2 W1

W2

-W1

4.3

WF1

4.3

W1

ALKALINE EARTH METAL ALLOY, N.O.S.

4.3

W2

ALUMINIUM CARBIDE ALUMINIUM FERROSILICON POWDER ALUMINIUM POWDER UNCOATED ALUMINIUM POWDER, UNCOATED ALUMINIUM PHOSPHIDE

4.3 4.3

W2 WT2

505 182

506 183

1 1

LOO

1 )

LQO

1

I

PP,EX, A

VEOl

HA08

PP, EX, A

VEOl

HA08

1 PP, EX, A l

4.3 4.3

W2

W2

PP, EX, A 1 VEOl PP, EP, EX.( VEOl, TOX, A VE02 PP, EX, A VEOl

WT2

I

l

1

I HA08 I

I

l

I HA08 I HA08 I

PP, EX, A

VEOl l

4.3

Number of cones, blue lights

Remarks

(13)

-

4.3

ALKALI METAL DISPERSION o ALKALINE EARTH METAL DISPERSION having a flash-point above 60 "C ALKALI METAL DISPERSION OR ALKALINE EARTH METAL DISPERSION having a flash-point of not more than 60 'C ALKALINE EARTH METAL AMALGAM, LIQUID

Labels

PP, EP, EX, TOX, A

HA08 l

VEO1, VE02

1

l

HA08

M No. or [D No.

Name and description

3.1.2 (2) ALUMINIUM SILICON POWDER, UNCOATED

RARTIJM

Class

'lassif ;ation Code

Labels

2.2

2.2

5.2.2

00 4.3

W2

(5)

4.3

Special provisions

Limited quantities

3.3 (6) 37

3.4.6 (7) LQ12

:arriagc Equipment ermittei required

3.2.1

8.1.5

Ventilation

Provisions concerning loading, unloading and carriage

7.1.6

00 0 B

PP, EX, A

VEO1, VE03

Number of cones, blue lights

7.1.5

0 0

HA07, IN01 and IN03 apply only when this substance is carrie in bulk or without packaging

PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A

VEOl VEOl VEOl VEOl VEOl

0 0 0 0 0

PP, EX, A PP, EX, A PP, EX, A PP, EX, A 'P. EP, EX TOX, A

VEOl VEOl VEOl VEOl VEo1, VE02, W03

0 0 0

PP, EX, A

VEOl

PP, EX, A

VEOl

W2

PP, EX, A

VEOl

WF1

PP, EX, A

VEOl

W2 W2 W2 W2

PP, EX, A PP, EX, A PP, EX, A PP, EX, A

VEOl VEOl VEOl VEOl

W2 W2 W2 4.3 4.3 W2 W2 4.3 4.3

CALCIUM CALCIUM CARBIDE CALCIUM CARBIDE CALCIUM CYANAMIDE with more than 0.1% calcium carbide CALCIUM HYDRIDE CALCIUM SILICIDE CALCIUM SILICIDE CAESIUM FERROSILICON with 30% or more but less than 90% silicon

4.3 -

4.3 4.3 4.3 4.3 4.3

W2 W2 W2 W2 WT2

METAL HYDRIDES, WATERREACTIVE, N.O.S. METAL HYDRIDES. WATERREACTIVE, N.O.S. LITHIUM ALUMINIUM HYDRIDE LITHIUM ALUMINIUM HYDRIDE. ETHEREAL LITHIUM BOROHYDRIDE LITHIUM HYDRIDE LITHIUM LITHIUM SILICON

4.3

W2

P

4.3

LQl l LQ12

4.3 4.3 4.3 4.3 4.3+6.1

LQO LQll LQ12 LQO LQ12

Remarks

P

W2

39 802

274

LQl l

LQO LQll

n

VE03, L003, HA07, M01, INO: and IN03 apply only when this substance is carrie in bulk or without packaging

JN No. or ID No.

Name and description

-

3.1.2 (2)

111

Class

lassifi :ation Code

2.2

2.2

00

acking TOUP

.1.1.3

(4) I

1427 1428 1431 1432

MAGNESIUM POWDER or 4.3 WS MAGNESIUM ALLOYS POWDER n 4.3 WS MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER I11 WS 4.3 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER I WT2 4.3 MAGNESIUM ALUMINIUM PHOSPHIDE I W1 4.3 PO.I.ASSIIIM METAL ALLOYS. LIQUID I W1 4.3 ALKALI METAL ALLOY, LIQUID, N.O.S. I W1 4.3 POTASSIUM SODIUM ALLOYS LIQUID I W2 4.3 RUBIDIUM I 4.3 W2 SODIUM BOROHYDRIDE I 4.3 W2 SODIUM HYDRIDE I W2 4.3 SODIUM 4.2 I1 SC4 SODIUM METHYLATE I 4.3 WT2 SODIUM PHOSPHIDE

1433

STANNIC PHOSPHIDES

4.3

WT2

1

1435

ZINC ASHES

4.3

W2

111

1418

1418 1418

1419 1420 1421

l422

1423 1426 -

1436 1436 1436 1437

WS WS WS F3

Labels

Special provisions

Provisions concerning loading, unloading and carriage

Limited Carriag~ Equipment quantities permitte required

8.1.5

Number of cones, blue lights

Remarks

7.1.6

0 (10) PP, EX, A

VEOl

PP, EX, A

VEO l

PP, EX, A

VEOl

'P, EP, EX TOX, A PP, EX, A

VE01, VE02 VEOl

PP, EX, A

VEOl

PP, EX, A

VEOl

PP. EX. A

TOX, A 'P, EP, E 3 TOX, A PP, EX, A

W02 VEO 1, VE03

VEOl VEOl VEOl

VE03, L003, HA07, IN01 and IN03 apply only when this substance is canie in bulk or without packaging

UN No or ID No.

-

Name and description

3.1.2 (2) ALUMINIUM NITRATE

0 1438

1439 AMMONIUM DICHROMATE 1442 AMMOSKY PPERCIILORI\TE 1444 AMMONIUM PERSULPHATE 1445 l446 1447 1448 1449 1450 1451

BROMATES, INORGANIC, N.O.S. CAESIUM NITRATE

1452 -

Class

llassifi cation Code

2.2

2.2

Labels

Special provisions

Limited quantities

3.2.1

00 5.1

02

0 B

5.1

5.1 5.1 5.1 5.1 5.1 5.1

LQll LQl l L012 LQl l LQll LQl l

5.1 5.1 5.1

LQl l LQll LQl l

P

Remarks

3.2.1 (13)

C002 and LOO4 apply only when this substance is carried in bulk or without packaging

C002 and L004 apply only when this substance is carried in bulk or without packaging LQll LQll LQl l LQl l

MIXTURE CHLORATE AND BORATE MIXTURE CHLORATE AND MAGNESIUM CHLORIDE MSXTURE, SOLID

Number of cones, blue lights

C002 and L004 apply only when this substance is carried in bulk or without packaging

5.1

5.1 5.1 5.1

1453 1454

Provisions concerning Jarriage Equipment Ventilation loading, unloading and ~ermitted required carriage

LQll

JN No. or ID No.

Special provisions

Name and description

Class

3.1.2 (2) CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID CHLORATES, INORGANIC, N.O.S. CHLORITES, INORGANIC, N.O.S.

2.2 (34 5.1

52.2 (5) 5.1

3.3 (6)

5.1

5.1

274 605 274 509 606 510

5.1 I

CHROMIUM TRIOXIDE, ANHYDROUS DIDYMIUM NITRATE

1

5.1

Labels

Limited Carriage Equipment quantities permitted required

PP

LQll I

1

LQll

PP

LQl l

PP

PP

LQ12

B

PP

GUANIDINE NITRATE

LQ12

B

PP

LEAD NITRATE 1 5.1 LEAD PERCIILORATE, SOLID 1 5.1 LITHJIJM HYPOCHLORITF.. 1 5.1 DRY or LITHIUM HYPOCHLORITE MIXTURE LITHIUM PEROXIDE MAGNESIUM BROMATE MAGNESIUM NITRATE

LQl l LQl l LQll

M I

MAGNESIUM PERCHLORATE

1

5.1

Remarks

0

B

5.1

Number of cones, blue lights

7.1.5 (12)

LQ12

FERRIC NITRATE

Provisions concerning loading, unloading and carriage

C002 and L004 apply only when this substance is xrried in bulk or without packagin~ C002 and L004 apply only when ;his substance is :arried in bulk or without packaginp C002 and L004 lpply only when :his substance is :arried in bulk or without packaging

PP PP PP

2002 and L004 apply only when :his substance is :arried in bulk or without packaginp

LJNNo. l

or ID No.

Name and description

(1) 1476 1477

(2) MAGNESIUM PEROXIDE NITRATES, INORGANIC, N.O.S.

1477

NITRATES, INORGANIC, N.O.S.

Class

2.2

1479 1479 1479 1481

OXIDIZING SOLID, N.O.S. OXIDIZING SOLID, N.O.S. OXIDIZING SOLID, N.O.S. PERCHLORATES, INORGANIC, N.O.S. 1481 PERCHLORATES. INORGANIC. N.O.S. 1482 I PERMANGANATES, INORGANIC, N.O.S. 1182 I PERMANGANATES.

I I

'lassifi lacking cation Code grouP

5.1 5.1

02 02

(4) I1 I1

5.1

02

111

5.1

5.1 5.1 5.1

-

Special provisions

Limited quantities

Equipment required

Ventilation

Provisions concerning loading,carriage unloading and

Number of cones, blue lights

Remarks

2.2

00

-

Labels

02 02 02 02

5.1

02

5.1

02

5.1

02

5.1

02

LQll LQll

& C002 and L004 apply only when this substance is carried in bulk or

LQ12 LQll

N.O.S.

apply only when this substance is carried in bulk or without acka in 1487 1488 1489 1490 1491 1492

POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE POTASSIUM NITRITE POTASSIUM PERCHLORATE POTASSIUM PERMANGANATE POTASSIUM PEROXIDE POTASSIUM PERSULPHATE

UN No. or ID No.

Name and description

3.1.2

1493 1494 1495 1496 1498

5.1 5.1 5.1 5.1 5.1

SODIUM NITRATE AND 'OTASSIUM NITRATE MIXTURE

1500 SODIUM NITRITE 1502 SODIUM PERCHLORATE 1503 SODIUM PERMANGANATE 1504 1505 1506 1507 STRONTIUM NITRATE - --

-

1508 ITRONTIL'M PF.RC1IL.OKATE 1509 il'RONTIUM PEROXIDE 1510

-

1511 JREA HYDROGEN PEROXIDE 1512 ZINC AMMONIUM NITRITE 1513 CINC CHLORATE. 1514 CINC NITRATE 1515 - ZINC PERMANGANATE 1516 ZINC PF.ROXlDE -

- - -

- - - --

Labels

Special provisions

Limited quantities

Equipment Ventilation required

Provisions concerning loading, unloadiig and carriage

Number of cones, blue lights

Remarks

2.2

0

0

1499

Class

(7) LQll LQll LQl l LQll LQ12

3002 and L004 rpply only when his substance is ;arried in bulk or without packaging :002 and L004 rpply only when his substance is :arried in bulk or without packaging

5.1

5.1 5.1 5.1 5.1 5.1 5.1 5.1

5.1

5.1 5.1

LQ12 LQll LQll LQO LQ12 LQll LQ12

LQll LQl l LQO LQ12 LQll LQll LQ1 1 LQll LQl l

ZOO2 and L004 rpply only when his substance is :arried in bulk or vithout packaging PP PP PP, EP, TOX, A PP PP PP PP PP PP

UN No. or ID No.

Name and description

Class

(2)

2.2 (3a) 4.1

-

l ! L

ZIRCONIUM PICRAMATE. WETTED with not less than 20% water, by mass 1541 4CETONE CYANOHYDRIN, STABILIZED 1544 4LKALOIDS. SOLID. N.O.S. or ALKALOID SALTS. SOLID. N.O.S. 1544 ALKALOIDS, SOLID, N.O.S. or 4LKALOID SALTS, SOLID, - N.O.S. 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 1545 ALLYL ISOTHIOCYANATE, STABILIZED 1546 AMMONIUM ARSENATE 1547 ANILINE 1517

l548 ANILINE HYDROCHLORIDE 1549

1550 1551 1553 1554 1555 1556

ANTIMONY COMPOUND. INORGANIC, SOLID, N.O.S. AN'TIMONY LACTATE ANTIMONY POTASSIUM TARTRATE ARSENIC ACID, LIQUlD

ARSENIC ACID, SOLID ARSENIC BROMIDE ARSENIC COMPOUND. LIQUID N.O.S., inorganic, including: Arsenates, n.0.s.. Arsenites, n.0.s.; uld Arsenic sulphides, n.0.s.

6.1 6.1

6.1

Xassifi. cation Code W0"P

Labels

Special

Limited

Carriage Equipment Ventilation required

p r o ~ d o n s quantities permitted

2.2 -

4.k D

T1

T2

PP, EP, TOX, A PP, EP

T2

PP, EP

T2

PP, EP

TF 1

'P, EP, EX TOX, A PP, EP PP, EP,

T5 T1

T2 T5

T5 T5

T4

PP, EP,

T5

T5 T4

TOX, A

Provisions concerning loading, unloading and camage

Number of cones, blue lights

Remarks

UN No.

Classifi. Packing cation Code group

or

Name and description

-

3.1.2 (2)

2.1.1.3

ARSENIC COMPOUND, LIQUID. N.O.S., inorganic, including: 4rsenates, n o s . , Arsenites, n.0.s.; and Arsenic sulphides, n.0.s. ARSENIC COMPOUND. LIOUID. N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.0.s.; and Arsenic sulphides, n.0.s. ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.0.s.; Arsenites, n.0.s.; and Arsenic sulphides, n.0.s. ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.0.s.; Arsenites, n.0.s.; and Arsenic sulphides, n.0.s. ARSENIC COMPOUND. SOLID. N.O.S., inorganic, including: Arsenates, n.0.s.: Arsenites. n.0.s.: and ~ r s e n i sulphides, c n.0.s. ARSENIC ARSENIC PENTOXILIE ARSENIC TRICHLORIDE

I1

m NO.

111 1556

1556

1557

1557

1557

1558 1559 1560

-

~

1561 l562 1564

1564

BARIUM COMPOUND. N.O.S.

1565 BARIUM CYANIDE -

Class

Labels

Special provisions

5.2.2

Limited Carriage Equipment Ventilation quantities permittec required

Provisions concerning loading, unloading and camage

Number of cones, blue lights

3.2.1

8.1.5

7.1.5

(8)

(9) PP, EP, TOX, A

(12) 2

I11

PP, EP, TOX, A

0

I

PP, EP

00 6.1

PP, EP

PP, EP

PP, EP PP, EP PP, EP, TOX, A PP, EP PP, EP PP, EP

PP, EP

PP, EP

Remarks

JN No. or [D No.

Name and description

I I Class

Classifi cation Code

Special provisions

I

I

Limited Carriage Equipment Ventilation quantities permitted required

3.3

0 l566

N.O.S.

I

I

l566

BERYLLIUM COMPOUND, N.O.S.

6.1

T5

1567 1569

BERYI.LIUM POWI)I:R BROMOACETONE

6.1 6.1

TF3 TFl

1570

BRUCINE

1571

BARIUM AZIDE, WETTED with not less than 50% water, by mass CACODYLIC ACID CALCIUM ARSENATE CALCIUM ARSENATE AND CALCIUM ARSENITE MIXTURE, SOLID CALCIUM CYANIDE CHLORODINITRO-BENZENES, LIQUID CHLORONITROBENZENES, SOLID 4-CHLORO-0-TOLUIDINE HYDROCHLORIDE, SOLID CHLOROPICRIN

1572 1573 1574

1575 1577 1578 1579 1580

1581

CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more

1582

CHLOROPICRIN AND METHYL

- CHLORIDE MIXTURE 1583

CHLOROPICRIN MIXTURE. N.O.S.

1

6.1

1

T2

(6) 274 5l 4 802 274 514 802 802 802 43 802 568 802 802 802 802

4.1

DT

6.1 6.1 6.1

T5 T5 T5

6.1 6.1

T5 T1

6.1

T1

6.1

T2

802 279 802 279 802 802

6.1

T1

802

LOI PP, EP

LQO

I

PP, EP PP, EP, EX I TOX, A I PP,EP

PP, EP PP, EP, TOX, A

LQ17

TOX, A I

LOO

1

I

I

I

I

16.1

1

T1

PP. EP. TOX, A PP, EP, PP, EP, TOX, A PP, EP, TOX, A

Provisions concerning loading, unloading and carriage

UN No.

or ID No.

-

111 1583

Name and description

(2) "OROPICRIN MIXTURE,

Class

:lassifi. Packing cation Code group

2.2

I

1

(34 6.1

0 T1

Special provisions

Limited Carriage Equipment Ventilation quantities permittec required

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

3.2.1

0 TOX, A

1583

XLOROPICRIN MIXTURE, V.O.S.

6.1

1586

1588

1588

T1

T5 EYANIDES, NORGANIC, SOLID, N.O.S.

6.1

XANIDES, INORGANIC, SOLID, N.O.S.

6.1

CYANIDES, INORGANIC, SOLID, N.O.S.

6.1

T5 T5

T5

PP, EP

T5

PP, EP

1.590

l XANOGEN CHLORIDE. 1 2 STABILIZED 6.1 DICJILOROANILINES. LIQUID

1591

1-DICHLOROBENZENE

T1

1593

DICHLOROMETHANE

T1

1594

DIETHYL SULPHATE

1595

DIMETHYL SULPHATE

1589

! 1

6.1 6.1

l598

-

T1

T1 TC 1 T2 T1

l

-

2TC

-

-

1596 1597 1597

PP, EP, TOX, A

T5

1585

1587 1588

-

DINITROBENZENES, LIQUID

6.1

T1

T2

PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX, A PP, EP PP, EP, TOX, A PP, EP, TOX, A PP, EP

Name and description

Class

3.1.2

2.2

:lassifi. 'acking cation Code group

2.2

Labels

Special provisions

Limited quantities

P

DISINFECTANT, SOLID, TOXIC N.O.S. DISINFECTANT, SOLID, TOXIC N.O.S. DISINFECTANT, SOLID, TOXIC N.O.S. DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. DYE. I-IOUID. TOXIC. N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. ETHYL BROMOACETATE ETHYLENEDIAMINE ETHYLENE DIBROMIDE FERRIC ARSENATE FERRIC ARSENITE FERROUS ARSENATE HEXAETHYL TETRAPHOSPHATE HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE

Tl T1 T1

0

T2

PP, EP, A PP., EP., A PP, EP, TOX, A PP, EP

11 111 I1

T2

PP, EP

T2

PP, EP

T1

PP, EP, TOX, A

T1

PP, EP, TOX, A

-

PP, EP, TOX, A

T1

P

TFl CF1 T1

T5 T5 T5 Tl

P

IT

Ventilation

8.1.5

!.1.1.3

l?% 00 6.1 6.1 6.1

Equipment required

802 802 802 802

LQl8 LQlS LQlS LQ17

'P, EP, EX TOX, A 'P, EP, EX A PP, EP, TOX, A PP, EP PP, EP PP, EP PP, EP, TOX, A PP, EP, TOX. A

hovisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

a 1613 WROCYANIC ACID, -

Class

Classification Packing Code

Labels

Special provisions

Limited Carriage Equipment quantities permitted required Ventilation

7.1.6 (10)

I

LQO

IQUEOUS SOLUTION HYDROGEN CYANIDE, IQUEOUS SOLUTION) with not - nore than 20% hydrogen' cyanide 1614 3YDROGEN CYANIDE, STABILIZED, containing less than I% water and absorbed in a porous

PP, EP, EX

TOX, A

1616

1617 B A D ARSENATES 1618 1620 1621

E A D ARSENITES -EAD CYANIDE ,ONDON PURPLE

1622 WGNESIUM ARSENATE 1623 - !4ERCURIC ARSENATE 1624 !4ERCURIC CHLORIDE 1625 vIERCURIC NITRATE l626 vIERCURIC POTASSIUM .- - - -

--

6.1 6.1 6.1

6.1 6.1 6.1 6.1 6.1

T5 T5 T5 T5 T5

I1 I1 I1 I

6.1 6.1 6.1 6.1 6.1

6.1 6.1 6.1

T5 T5 T5

I1 I1 I1

6.1 6.1 6.1

I1

802 802 43

LQl 8

802 802 802 802 802 802

PP, EP PP, EP PP, EP PP, EP PP, EP

802 802 802

PP, EP PP, EP PP, EP

-

1627 vlERCUROUS NITRATE 1629 1630

6.1

PP, EP PP, EP PP, EP PP, EP PP, EP

@ERCURY ACETATE vIERCURY AMMONIUM

LQl8 LQl8 LQl8 LQ18 LQl8 LQ18 LQl8 LQl8 LQlS IESENSITIZED vIERCURY POTASSIUM IODIDE vIERCURY SALICYLATE

6.1 6.1

T5 T5

I1 I1

6.1 6.1

802 802

PP, EP PP, EP PP, EP PP, EP PP, EP PP, EP PP, EP PP, EP PP, EP PP, EP PP, EP

VEOI, W02

VEo1, VE02

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

LJNNo.

or ID No.

Name and description

3.1.2 (2) ( I ) 1645 MERCURY SULPHATE l646 MERCURY THIOCYANATE 1647 METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID 1648 ACETONITRILE 1649 MOTOR FUEL ANTI-KNOCK MIXTURE having a flash-point - above 60 "C l649 MOTOR FUEL ANTI-KNOCK MMTURE having a flash-point of not more than 60 'C 1650 beta-NAPHTHYLAMINE, SOLID 1651 NAPHTHYLTHIOUREA

1652 1653 1654

Special provisions

Limited quantities

3arriage Equipment ventilation ermitted required

7.1.6

3.2.1 (8)

PP, EP, TOX, A

T

I LJ-L PP, EP, TOX. A

VE02

'P, EP, EX,

VEO1,

PP, EP

NAPHTHYLUREA NICKEL CYANIDE NICOTINE

p

NICOTINE COMPOUND, SOLID N.O.S. or NICOTINE - PREPARATION, SOLID, N.O.S. 1655 NICOTINE COMPOUND, SOLID N.O.S. or NICOTINE PREPARATION, SOLID. N.O.S. 1655 NICOTINE COMPOIJND, SOLID N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 1656 NICOTINE HYDROCHLORIDE, - LIQUID or SOLUTION 1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 1657 NICOTINE SALICYLATE 1658 NICOTINE SULPHATE, SOLUTION 1658 NICOTINE SULPHATE, SOLUTION

Provisions concerning loading, unloading and carriage

1655

-F PP, EP

TOX, A PP, EP

Number of cones, blue ligbts

Remarks

Name and description

Class

Classifi. cation Code

Labels

Special provisions

LQ18 LQO

11

LQ9

T

3.1.2

(2) NICOTINE TARTRATE NITRIC OXIDE, COMPRESSED

3iAii

Ventilation

Si2f

NITROANILINJ3 (0-, m-, p-)

PP, EP PP, EP, TOX, A PP, EP

NITROBENZENE NITROPHENOLS (0-, m-, p-)

TOX, A PP, EP

NITROTOLUENES, LIQUID NITROXYLENES. LIQUID PENTACHLOROETHANE

LQ17

PERCHLOROMETHYL MERCAPTAN PHENOL, SOLID

LQO

PHENYLCARBYLAMINE CHLORIDE PHENYLENEDIAMINES(0-, m-, p-) PHENYLMERCURICACETATE POTASSIUM ARSENATE POTASSIUM ARSENI'IT

,

.

SOLUTION SODIUM ARSENITE, AQUEOUS SOLUTION SODIUM AZIDE

I

LQ18

I

I

LQO

I

I

LQ9

LQl8 L018 LQO LQ18 L018

'

TOX, A PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX, A PP,EP PP, EP, TOX, A PP, EP PP, EP, TOX, A PP, EP PP, EP PP. EP PP, EP PP, EP PP. EP PP, EP PP, EP PP, EP PP, EP

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

Class

:lassifi. Packing cation Code BOUP

2.2 2.1.1.3 3.1.2 2.2 (2) 0 00 SODIUM CACODYLATE 6.1 T5 I1 SODIUM CYANIDE, SOLID I T5 6.1 SODIUM FLUORIDE. SOLID T5 6.1 m STRONTIUM ARSENITE T5 I1 6.1 STRYCItNINE or S rRYCHNINE T2 I 6.1 SALTS rEAR GAS SUBSTANCE, Tl I 6.1 LIQUID, N.O.S. rEAR GAS SUBSTANCE, T1 I1 6.1 LIQUID, N.O.S. BROMOBENZYL CYANIDES, T1 I 6.1 LIQUID EHLOROACETONE, TFC I 6.1 STABILIZED CHLOROACETOPHENONE, 6.1 I1 SOLID DIPHENYLAMME 6.1 2HLOROARSINE DIPHENYLCHLOROARSINE. LIQUID rEAR GAS CANDLES WLYL BROMIDE, LIQUID -

Labels

Special provisions

Limited quantities

Carriage Equipment Ventilation ermittec required

3.2.1

0

--

PP, EP,

p

DITHIOPYROPHOSPI IA'I'E THALLIUM COMPOUND. N.0.S TOLUIDINES, LIQUID 2,4-TOLUYLENEDLAMINE, SOLID rRICHLOROETHYLENE

TOX, A 'P. EP. EX

TOX, A PP, EP, TOX, A PP, EP PP, EP, TOX, A PP, EP, TOX, A PP, EP PP, EP PP. EP. TOX, A PP, EP PP, EP, TOX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No.

or ID No.

Name and description

class

I

Classifi cation lacking Code group

1 1711

XYLIDINES, LIQUID

Labels

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

3;

3.4;

1

LQ17

PP, EP,

ARSENITE or ZINC ARSENATE AND ZINC ARSENITE MIXTURE PP, EP, EX I

1715

1718 1719

ACETIC ANHYDRIDE

1 BUTYL ACI1) PHOSPHATE 1 CAUSI'IC ALKALI LIQUID, N.O.S.

jl

%$p%

PP, EP PP, EP, EX

PP, EP

PP, EP, E3 TOX, A PP, EP, E3

TFC

I

1723

ALLYL IODIDE

1724

ALLYLTRICHLOROSILANE, STABILIZED 1725 A L m I U M BROMIDE, ANHYDROUS 1726 ALUMINIUM CHLORIDE, ANHYDROUS 1727 ( AMMONIUM HYDROGENDIFLUORIDE,

l

LQ22

I

LQ23 I

LQ23

/PP, EP, E3 A PP, EP I

PP, EP PP, EP

LQ22

PP, EP PP, EP PP, EP

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

JN No or ID No.

1731 1731 1732 1733

1736 1737

Name and description

3.1.2 (2) 4NTIMONY PENTACHLORlDE 30LUTlON 4NTIMONY PENTACHLORIDE SOLUTION 4NTIMONYPENTAFLUORIDE

1743 1744 1745

1

4NTIMONY TRICHLORIDE B E N Z O n CHLORIDE BENZYL BROMIDE

1738 BENZYL CHLORIDE 1739 BENZYLCHLOROFORMATF. 1740 HYDROGENDIFLUORIDES. SOLID, N.O.S. 1740 HYDROGENDIFLUORIDES. SOLID, N.O.S. 1741 BORON TRICHLORIDE 1742

I I Class

Classifi. cation Code

2.2 (3a) 8

2.2 (3b) C1

8

6.1

TCl

6.1 8 1 8

1747

BUTYLTRICHLOROSILANE

1748 DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available

LQ22

PP, EP

zLJ= PP, EP

PP, EP,

TOX, A PP, EP PP, EP

1

S I C 2

2

LQ23 LQ24

PP, EP I

2

2TC

LQO

8

C3

LQ22

8

C3

8

CT1

5.1

8

(

I T

PP, EP, TOX, A PP,EP

IO?I PP, EP

LOO

1

OTC

LQO

I

OTC

LOO

I

CFl

LQ22

(

I

5.1

I

I

I

1

0

TC1 C9 1 ~

Provisions concerning loading, unloading and carriage

7.1.6

I

1

1

Limited Carriage Equipment Ventilation quantities permitted required

3.3 (6)

C1 CTI

I

BROMINE TRIFLUORIDE

1

8

I

BORON TRIFLUORIDE ACETIC 4CID COMPLEX, LIQUID BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID BROMINE or BROMINE SOLUTION BROMINE PENTAFLUORIDE

l746

I

Special provisions

I

PP, EP, TOX, A I PP, EP, I TOX, A I PP. EP, TOX, A (PP, EP, EX

I I

Number of cones, blue lights

7.1.5 (12) 0

Remarks

UN No. or ID No.

Name and description

3.1.2 (2) ZALCIUM HYPOCHLORITE, IRY or CALCIUM 3YPOCHLORITE MIXTURE, IRY with more than 39% available :Ihrine (8.8%available oxygen) LIILORINE TRJFL.UORIDE

XILOROACETIC ACID >

- - . A

XLOROACETIC ACID, SOLID "OROACETYL CHLORIDE

Class

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

2.2 2.2 -

7.1.6

00 5.1

2 6.1

(10)

02

PP, EP, TOX, A

2TOC

-

6.1

TOX, A PP, EP PP, EP, TOX, A PP, EP

8

TC 1 C3

LQ22

C1

I

I

LQo

PP, EP

:with or without sulphur trioxide)

ZHROMIC ACID SOLUTION ZHROMIC ACID SOLUTION CHROMIC FLUORIDE, SOLID ZHROMIC FLUORIDE SOLUTION CHROMIC FLUORIDE SOLUTION

CORROSIVE SOLID, N.O.S.

SOLUTION CUPRIETHYLENEDIAMINE SOLUTION CYCLOHEXENYLTRICHLOROSILANE

8

C1

8 C1 8 8 8

-

-8 C1 C10 8 C10 8 8 C10 8 C9 C9 8 C9 8 8 CTl 8 8

PP, EP PP, EP PP, EP

C2 C1 C1

I I

LQ7 LQO LQO LQ23 LQ24 LQo LQ22 LQ7 LQ22

l

PP, EP

T T T

PP, EP PP, EP PP, EP PP, EP PP,EP PP,EP PP,EP PP, EP, A

CT1

LQ7

PP, EP, A

C3

LQ22

PP, EP

-

m02 m02

TC l

-6.1 TC2 8

rRICHLOROSILANE ZHLOROSULPHONIC ACID

lassifi. acking cation Code group

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

(1)

1763

Name and description

Class

Classifi cation Code

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

I (2) l CYCLOHEXYLTRICHLORO---

-

DICHLOROACETIC ACID DICHLOROACETYL CHLORIDE DICHLOROPHENYLTRICHLOROSILANE DIETHYLDICHLOROSILANE

PP, EP, E 3

/ DIFLUOROPHOSPHORIC ACID,

PP, EP

1764 1765 1766 1767

PP, EP PP, EP

I

1768

PP, EP PP. EP PP, EP PP, EP

l ANHYDROUS 1774

1 FIRE EXTINGUISHER PP, EP PP, EP

1 85% acid bv mass

PP, EP PP, EP PP, EP, E3

LQ22

- -

1780 1781

1 FUMARYL CHLORIDE

PP, EP PP, EP

l HEXADECYLTRICHLORO-

l

SILANE 1782 [ HEXAFLUORO-PHOSPHORIC ACID 1783 HEXAMETHYLENE-DIAMINE SOLUTION 1783 HEXAMETHYLENE-DIAMINE SOLUTION 1784 HEXYLTRICHLOROSILANE 1786 HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE 1787 1 HYDRIODIC ACID

I

I

I

1

l

LQ22 LQ22

PP, EP

I

T

Trf-Tj-

PP, EP PP, EP

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

JN No. or m NO.

Name and description

Class

I

Classili Packing cation group Code

[ more than 85% hydrofluoric acid 1790 1790 1791 1791 1792 1793 1794 1796 1796

1 HYDROFLUORIC ACID with

I more than 60% but not more than ( 85% hydrofluoric acid 1 HYDROFLUORIC ACID with not more than 60% hydrofluoric acid HYPOCHLORITE SOLUTION HYPOCHLORITE SOLUTION IODINE MONOCHLORIDE ISOPROPYL ACID PHOSPHATE LEAD SULPHATE with more thar 1 3% free acid 1 NITRATING ACID MIXTURE with more than 50% nitric acid 1 NITRATING ACID MLXTURE -

1

I

1

8+6.1

1

8+6.1

/

l 11

1

I1 111 11 I11 I1

8 8 8 8 8

I

8+5.1

Limited Carriage Equipment Ventilation quantities permitted required

1 1

802

1

521 521

59 1

LQ22

I 1

l

I

I

I

LQ22 L07 LQ22 LQ7 LQ23 LQO

PP, EP

I

I

PP, EP

I

1 PEKCHLORIC ACII) with not

I1 H

8 8+5.1

1 PHENOLSULPHONIC ACID,

L1

8

LQ22

I1 111 I1

8 8 8

LQ22 LQ7 LQ23

I

~

I more than 50% acid, by mass

I

I

11 I1

I

I

8 8

LQ22 LQ22

1

I

I

PP, EP PP, EP I

LQ23

I L022

I

PP, EP PP, EP PP,EP PP, EP

T

(

1

I

Number of cones, blue lights

Remarks

4

CARRIAGI PROHIBITED PP, EP PP, EP

LQ22 LQ22

522

Provisions concerning loading, unloading and carriage

TOX, A PP, EP, PP, EP, TOX, A PP, EP PP. EP PP, EP PP, EP PP, EP

8 8

l SILANE 1 OCTYLTRlCHLOROSlLANE

I

LQ22

8

I1

LQO

I1 I1

~

1803

6405

l

l

1801 1802

Special provisions

Labels

PP, EP

1 PP.EP

UN No. or ID No.

Name and description

3.1.2 (2) PHOSPHORUS TRICHLORIDE

0 1809 1810 1811 1812 1813 1814 1814 1815

PHOSPHORUSOXYCHLORIDE POTASSIUM HYDROGENDIFLUORIDE, SOLID POTASSIUM FLUORIDE, SOLID POTASSIUM HYDROXIDE, SOLID POTASSIUM HYDROXIDE 1 SOLUTION 1 POTASSIUM HYDROXIDE SOLUTION PROPIONYL CHLORIDE

class

Classification Packing Code

Labels

Special provisions

2.2 (3a) 6.1

2.2 2.1.1.3 (36) (4) TC3 I

5.2.2 (5) 6.1+8

3.3 (6) 802

3.4.6 (7) LQ0

8 8

C1 CT2

I1 I1

8 8+6.1

802

LQ22 LQ23

6.1 8

T5 C6

111 I1

6.1 8

8

l C 5 I I I I

8

8

( C5

I

8

3

I

1816

FC I

I11

I

I1

Provisions concerning Limited Carriage Equipment Ventilation loading, unloading and quantities permitted required carriage

802

3.2.1 (8)

8.1.5 (9) PP, EP, TOX, A PP, EP PP, EP

LQ9 LQ23

B

PP, EP PP, EP

LQ7

T

PP, EP

3+8

PP, EP, EX

I

I

PROPYLTRICHLOROSILANE

8

CF1

I1

8+3

PYROSULPHURYL CHLORIDE SILICON TETRACHLORIDE SODIUM ALUMINATE SOLUTION SODIUM ALUMINATE SOLUTION SODIUM HYDROXIDE, SOLID SODIUM HYDROXIDE SOLUTION SODIUM HYDROXIDE SOLUTION SODIUM MONOXIDE NITRATMG ACID MIXTURE,

8 8 8

Cl C1 C5

I1 I1 I1

8 8 8

LQ22

PP, EP, EX

P

1817 1818 1819 1819 l823 l824 1824 1825 1826 1826

1

8

1

8

1

8

1

8 8 8

C5

I

C6 C5

1

C5 C6 C01

I11

I

I1 I1

I

I11 I1 I

I

PP, EP PP, EP PP, EP I

I

8

LQ7

8 8

LQ23 LQ22 I

I

8

I

PP, EP

T T I

LQ7

1

PP, EP PP,EP I

T

I

8 8+5.1

PP, EP PP, EP PP, EP

113

LQ22

PP, EP

SPENT, with not more than 50% nitric acid P

1827

STANNIC CHLORIDE, ANHYDROUS

I

I

LQ22

I

PP, EP

Number of cones, blue lights

7.1.S (12) 2

Remarks

UNorNo.

m NO.

(1) 1828 1829

1830

l

l /

1831 1833 1834 1835

Name and description

I

3.1.2 2.2 (2) (3a) SULPHUR CHLORIDES 8 SULPHUR TRIOXDE, 8 STABILIZED SULPHURIC ACID with more thanl 8 51% acid SULPHURIC ACID, FUMING 8

SULPHUROUS ACID SULPHURYL CHLORIDE TETRAMETHYL-AMMONIUM HYDROXIDE, SOLUTION TETRAMETHYLAMMONIUM HYDROXIDE SOLUTION THIONYL CHLORIDE THIOPHOSPHORYL CHLORIDE TITANIUM TETRACHLORIDE TRICHLOROACETIC ACID ZlNC CHLORIDE SOLUTION

1835 1836 1837 1838 1839 1840

Class

1843 1 AMMONIUM DINITRO-oCRESOLATE, SOLID 1845 Carbon dioxide, solid (Dry ice)

I

Classifi cation Code

2.2 (3b) C1 C1

1

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

3.3 (6)

623

PP, EP PP, EP

LQO

C1 CTI

LQO

T T

C7

LQ22 LQ22 LQO LQ22

C7

LQ7

I

PP,EP, TOX, A PP,EP PP, EP PP, EP PP, EP I

PP, EP A

C1

8

1 6.1 1 T2 9

M11

LQO LQ22 LQ22 LQ23 L07

PP, EP PP, EP PP, EP PP, EP PP. EP

T PP, EP

m NOT SUBJECT TO ADN

1846

I 1

1847

I CARBON TETRACHLORIDE

I 6.1

I

POTASSIUM SULPHIDE, HYDRATED with not less than 30% water of crystallization 1848 1 PROPIONIC ACIDwithnot less 1 than 10% and less than 90% acid by\ mass 1849 SODIUM SULPHIDE, HYDRATED with not less than 30% water

8

1

I

T1

TOX, A

I

8 8

C6

1

1

C3 C6

PP, EP

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No or ID No.

Name and description

3.1.2

(2) a 1851 MEDICINE, LIQUID, TOXIC,

Class

Iassifi cation Code

2.2

2.2

acking group

6.1

T1

!.1.1.3 (4) I1

6.1

T1

111

00

N.O.S. 1851

1854 1855

1856 1857 1858 1859 l860 l862 l863 1863

MEDICINE, LIQUID, TOXIC, N.O.S.

Limited quantities

3i2f

1

l863

1863

Number of cones, blue lights

Remarks

PP, EP, TOX, A

TOX, A

BARIUM ALLOYS, PYROPHORIC CALCNM. PYROPHORIC or CALCIUM'ALLOYS, PYROPHORIC Rags, oily Textile waste, wet HEXAFLUOROPROPYLENE (REFRIGERANT GAS R 1216) SILICON TETRAFLUORIDE

4.2

S4

I

4.2

4.2 4.2 2

VINYL FLUORIDE. STABILIZE ETHYL CROTONATE FUEL, AVIATION, TURBINE ENGINE FUEL, AVIATION, TURBINE ENGINE (vapour pressure at 50 more than l l 0 k ~ i ) FUEL. AVIATION, TURBINE ENGINE (vapour pressure at 50 O( not more than 110 kPa) FUEL, AVIATION, TURBINE

PP, EP, TOX. A PP, EX, A PP, EX, A PP, EX, A

m01 VEOl VEOl

PP, EX, A

VEOl

1865 1866 1866 (vapour pressure at 50 "C more th; l l 0 kPa)

1 1 1 1

O(

-

Provisions concerning loading, unloading and carriage

larriage Equipment Ventilation ermitted required

PP, EX, A PP, EX, A

I

I

I

I

I

1

3assifi-

JN No. Name and description

or U) No.

Code

3.1.2 (2)

-

111 1866

RESIN SOLUTION, flammable (vaoour vressure at 50 "C not more

1866 1866

1866

1866

Class

(having a flash-point below 23 "C and viscous according to 2.2.3.1.4) boiling point not more than 35' C) RESIN SOLUTION, flammable (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) (vapour pressure at50 "C more than 110 kPa , boiling point of more thiu 35" C) RESIN SOLUTION, flammable (having a flash-point below 23 'C and viscous according to 2.2.3.1.4) (vapour pressure at 50 "C not more

2.2

0

P

PP, EX, A PP, EX, A

VEOl VEOl

640G

PP, EX, A

VEO l

640H

PP, EX, A

VEO l

802 59

PP PP

ALLOYS with more than 50% magnesium in pellets, turnings or

-

-

rihhnnc

4.3

1870 POTASSIUM BOROHYDRIDE 1871 1872 LEAD DIOXIDE l873 PERCHLORIC ACID with more than 50% but not more than 72%

4.1 5.1 -

-

-

l884 1885 1886

5.1

6.1

6.1 -

6.1

-

7.1.6

640E 640F

3

3

8.1.5

0 (10)

VEOl

3 3

-

Limited Carriagc Equipment Ventilation quantities permittec required

PP, EX, A

640D

4.1 4.1

1868 l869

3.3 (6)

3

-

-

Special provisions

PP, EX, A PP PP PP, EP PP, EP PP, EP PP, EP, TOX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.6 (11)

7.1.S (12)

1

Remarks

UN No or ID No.

Name and description

3.1.2

111 1887

(2) BROMOCHLOROMETHANE

Special provisions

Class

CHLOROFORM

3i2f

6.1

T1

I

III

1891

6.1

ETHYLDICHLOROARSINE

1894

PHENYLMERCURIC

PP, EP,

PP, EP, TOX, A PP, EP,

- HYDROXIDE 18%

PHENYLMERCURIC NITRATE

1897

TETRACHLOROETHYLENE

1898 1902

ACETYL IODIDE DIISOOCTYL ACID PHOSPHATE DISINFECTANT, LIQUID, CORROSIVE, N.O.S. DISINFECTANT, LIQUID, CORROSIVE, N.O.S. DISINFECTANT, LIQUID, CORROSIVE, N.O.S. SELENIC ACID SLUDGE ACID SODA LIME with more than 4%

P

1903

1903

1903

1905 1906 1907

PP, EP, TOX, A TOX, A

ETHYL BROMIDE

1892

1

Ventilation

I PP, EP

PP, EP

1908 1908 1910 1911

- Calcium oxide 1912

1913

+

DIBORANE

TOX, A

METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE NEON, REFRIGERATED LIQUII

Provisions concerning loading, unloading and carriage

,

6.1

BROMIDE 1889 CYANOGEN -

.'arriage Equipmen! ~ermitted required

2.2

0 I

1888

Limited quantities

1

593

1

LQl

Number of cones, blue lights

Remarb

JN No.

or LD No.

Name and description

(2) BUTYL PROPIONATES CYCLOHEXANONE 2,2'-DICHLORODIETHYL ETHER ETHYLACRYLATE, STABILIZED ISOPROPYLBENZENE m T H Y L ACRYLATE, STABILIZED NONANES PROPYLENEIMME. STABILIZED PYRROLIDINE CALCIUM DITHIONITE (CALCIUM HYDROSULPHITE) METHYL MAGNESIUM BROMIDE IN ETlNI. E7'tIER POTASSIUM DlTHlONlTE (POTASSIUM ~WDROSULPHITE) ZINC DITHIONITE (ZINC HYDROSULPHITE) ZIRCONIUM SCRAP

Class

Iassification Code

2.2 (3a) 3 3 6.1

2.2 (3b) F1 F1 TFl

Labels

2.1.1.3 (4)

111 111 I1

5.2.2 (5) 3 3 6.1+3

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

3.3 (6)

*

7.1.6

0

TOX, A

3

:_:: WFl

4.3+3

S4

4.2

PP, EP, EX

LQO

l

L90

1

PP, EX, A

TOX, A

CYANIDE SOLUTION, N.O.S. BROMOACETIC ACID. SOLUTION

VEOl VEO l VEOI, W02 VEOl

"T PP, EP, TOX, A

PP, EP, TOX, A PP, EP

Number of cones, blue lights

7.1.5 (12) 0 0 2 1

VEO l VEOl

0 1

VEO l VEo1, W02 VEOl

0 2

l

CYANIDE SOLUTION, N.O.S. CYANIDE SOLUTION, N.O.S.

Provisions concerning loading, unloading and carriage

VEOl

1

Remarks

UN No

or Il)No.

Name and description

3.1.2

(2) BROMOACETIC ACID SOLUTION PHOSPHORUS OXYBROMIDE THIOGLYCOLIC ACID DIBROMODIFLUOROMETHANE AMMONIUM NITRATE with not more than 0.2% total combustible material, including any organic substance calculated as carbon. to the exclusion of any other added substance MATCHES. SAFETY (book. \ . card or strike on box) MATCHES, WAX 'VESTA' AEROSOLS, asphyxiant

Class

2.2 -

m 8

lassifi. cation Code

2.2

0 C3 C2 C3 -

M11

Labels

Special provisions

Limited quantities

Provisions concerning Equipment Ventilation loading, unloading and required carriage

Remarks

8.1.5

0 PP, EP

PP, EP PP, EP PP ZOO2 and HA09 pply only when his substance is :arried in bulk or without packaging

AEROSOLS, corrosive

PP, EP

AEROSOLS, corrosive, oxidizing

PP, EP

AEROSOLS, flammable

PP, EX, A

AEROSOLS, flammable, corrosive

PP, EX, A

AEROSOLS, oxidizing AEROSOLS, toxic

Number of cones, blue lights

PP, EP, TOX, A

LIN No.

or ID No.

Name and description

1

Class

1950

AEROSOLS, toxic, flammable

2

1950

AEROSOLS, toxic, flammable, corrosive

2

1950

AEROSOLS, toxic, oxidizing

2

1950

AEROSOLS, toxic, oxidizing, corrosive

2

I

l

1951

I ARGON, REFRIGERATED

1952

1 ETHYLENE OXIDE AND

1953 1954 1955 1956

l LIQUID

2

1 (REFRIGERANT GAS R 114)

1

I (REFRIGERANT GAS R 1132a)

[

1 1.1-DIFLUOROETHYLENE

1

Labels

2.2

2

1TF

2.3+2.1

2

1F

2.1

2

1T

2.3

2

1A

2.2

1F 2A

2.1 2.2

2F

2.1

2

Special provisions

2.2 2.1.1.3 5.2.2 3.3 (3b) (4) 0 (6) 5TC 2.2+6.1+8 190 327 625 5TF 2.1+6.1 190 327 625 5TFC 2.1+6.1+8 190 327 625 5T0 .2+6.1+5. 190 327 625 5TOC .2+6.1+5. 190 +8 327 625 3A 2.2 593 2A

2

CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. COMPRESSED GAS, FLAMMABLE, N.O.S. COMPRESSED GAS, TOXIC, N.O.S. COMPRESSED GAS, N.O.S.

TETRAFLUOROETHANE

1959

I

IlassifiPacking cation Code

Limited Carriage Equipment Ventilation quantities permitted required

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

m No or ID No.

Name and description

-

3.1.2

ALL 1961

ETHANE, REFRIGERATED

l962 1963 1964

1965

l966

1967

1968 -

LIQUID HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. such as mixtures A, A01, A02, AO, Al. B1, R2, R or C HYDROGEN. REFRIGERATED LIQUID INSECTICIDE GAS, TOXIC, N.O.S.

1973

1974

2.2

METHANE. COMPRESSED or NATURAL GAS, COMPRESSED with high methane content METHANE, REFRIGERATED LIQUID or NATURAL GAS, REFRIGERATED LIQUID with high methane content CHLORODIFLUORO-METHANE AND CHLOROPENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502) CHLORODIFLUOROBROMOMETHANE (REFRIGERANT GA! R 12Bll

1.1.1.3 (4)

Labels

Special provisions

Limited Carriage Equipmenl Ventilation quantities 3errnitted required

3.2.1

m 2

0

2 2

2F 3A

PP, EX, A PP

VEOl

2

1F

PP, EX, A

VEO l

2F

PP, EX, A

VEOl

3F

PP, EX, A

VEO l

PP, EP, TOX, A PP PP, EX, A PP

m02

3F

2T

2A 2F 3A

- LIQUID 1972

2.2

lassifi. acking cation Code %ronP

P

1969 1970 1971

Class

-

00 PP, EX, A

VEOl

IF

PP, EX, A

VEOl

3F

PP, EX, A

VEOl

2A

2A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or [D No.

Name and description

0 1975

(2)

I

NITRIC OXIDE AND 1 DINITROGEN TETROXIDE MIXTURE (NITRIC OXIDE AND NITROGEN DIOXIDE

Class

Zlassifi. cation Code

(34

0

2.2

2

1976 1977 1978 1982

1983

1984

l986

1986 1986

1987

LIQUID PROPANE TETRAFLUOROMETHANE (REFRIGERANT GAS R 14) 1-CHLORO-2.2.2T F L U O R O E T (REFRIGERANT GAS R 133a) TRIFLUOROMETHANE (REFRIGERANT GAS R 23) ALCOHOLS. FLAMMABLE. TOXIC, N.O.S. ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. ALCOHOLS. FLAMMABLE. TOXIC, N.O.S. ALCOHOLS, N.O.S. (vapour pressure at 50 "C more than l l0 kPa)

1

I

2

Labels

Special provisions

2TOC

5.2.2 (5) !.3+5.1+8

2A

2.2

PP

2.2

PP

2.1 2.2

PP, EX, A PP

2.2

PP

2.2

PP ?P, EP, EX TOX, A 'P, EP, EX TOX, A 'P, EP, EX TOX, A PP, EX, A

I

3

3+6.1

1

3

3+6.1

1

3

3+6.1

1

3

3

3.3

Limited Carriage Equipment Ventilation quantities permitted required

(6)

8.1.5

0 PP, EP, TOX, A

PP, EX, A

1987 pressure at 50 'C not more than l l 0 kPa)

1987

1988

ALCOHOLS, N.O.S.

3

PP, EX, A PP, EP, EX TOX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

U N No.

or m NO.

Name and description

Class

3.1.2 (2) ( I ) 1988 4LDEHYDES, FLAMMABLE, - TOXIC, N.O.S. 1988 4LDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1989 4LDEHYDES, N.O.S.

2.2 -

-

-

1989 1990 1991

4LDEHYDES. N.O.S. (vapour Jressure at 50 "C more than l l 0 kPa) 4LDEHYDES, N.O.S. (vapour sressure at 50 "C not more than 110 kPa) 4LDEHYDES, N.O.S. BENZALDEHYDE FHLOROPRENE, STABILIZED

1992

FLAMMABLE LIQUID, TOXIC,

1989

1989

V.O.S.

1992 1992

1993

-

FLAMMABLE LIOUID. TOXIC. V.O.S. FLAMMABLE LIQUID, TOXIC. FLAMMABLE LIQUID, N.O.S.

m 3

3

3 3

-

lassifiPacking cation Code BOuP

Labels

Special provisions

Limited quantities

Carriage Equipment Ventilation ~ermittec required

3.2.1

8.1.5

00 ?P, EP, EX TOX, A PP, EP, EX TOX, A PP, EX, A

PP, EX, A

3

PP, EX, A

3 -

3

PP, EX, A PP PP, EP, EX TOX, A PP, EP, EX TOX, A 'P, EP, EX TOX, A >P,EP, EX TOX, A PP, EX, A

3

PP, EX, A

9 3

3

3 3

-

1993

FLAMMABLE LIQUID, N.O.S. :vapour pressure at 50 "C more thlu l10 kPa)

1993

FLAMMABLE LIQUID, N.O.S. :vapour pressure at 50 "C not more han 110 kPa)

PP, EX, A

1993

FLAMMABLE LIQUID, N.O.S.

PP, EX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

Class

2.2

(2) FLAMMABLE LIQUID, N.O.S. :having a flash-point below 23 "C md viscous according to 2.2.3.1.4) >oilingpoint not more than 35' C) FLAMMABLE LIQUID, N.O.S. :having a flash-point below 23 "C md viscous according to 2.2.3.1.4) :vapour pressure at 50 'C more thru 110 kPa , boiling point of more thru 35' C) FLAMMABLE LIQULD, N.O.S. :having a flash-point below 23 "C md viscous according to 2.2.3.1.4) :vapour pressure at 50 'C not more : h illdk~a) [RON PENTACARBONYL TARS, LIQUID, including road asphalt and oils, bitumen and cut lacks (vapour pressure at 50 'C nore than 110 kPa) TARS, LIQUID, including road asphalt and oils, bitumen and cut lacks (vapour pressure at 50 "C not nore than l l0 kPa) TARS, LIQUID, including road asphalt and oils, bitumen and cut lacks TARS, LIQUID, including road 3sphalt and oils, bitumen and cut lacks (having a flash-point below 23 "C and viscous according to 2.2.3.1.4) ( boiling point not more han 35" C)

llassifi cation Packing Code group

2.2

Labels

F1

2.1.1.3 (4) 111

5.2.2 (5) 3

3

F1

111

3

3

F1

111

3

6.1

TFl

0m 3

-

3

3 3

3.3 (6) 274 330 601 640F 274 330 601 640G

Limited quantities

3.4.6

Carriag Equipment Ventilation ~ermittc required

3.2.1

8.1.5

7.1.6

000 (10) LQ7

T

PP, EX, A

VEO l

LQ7

T

PP, EX, A

VEOl

PP, EX, A

VEOl

VEo1, W02 VEO l

-

274 330 601 640H

LQ7

802

LQO

640C

LQ6

'P, EP, EX TOX, A PP, EX, A

F1

640D

LQ6

PP, EX, A

VEOl

F1

640E

LQ7

PP, EX, A

VEO l

PP, EX, A

VEOl

-3

Special provisions

F1

-

F1

640F

T

-

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.5 (12) 0

Remarks

JN No or [D No.

lassifi. 'acking cation Code

Special provisions

Limited quantities

3

m F1

3.3 (6) 640G

3.4.6 (7) LQ7

3

F1

640H

LQ7

PP, EX, A

4.1

F1

502

LQ9

PP

F3

LQ9

PP

S2

LQO

PP

4.2

S4 S2

LQO LQO

PP PP

4.2

S4

LQO

PP

ZIRCONIUM POWDER, DRY

4.2

S4

LQO

PP

ZIRCONIUM POWDER, DRY ZIRCONIUM, DRY, finished

4.2 4.2

S4 S4

LQO LQO

PP PP

W2 WT2

LQO LQO

PP, EX, A 'P, EP, EX TOX, A

Name and description

Class

3.1.2

2.2

2.2

( 2 )0 TARS, LIQUID, including road asphalt and oils, bitumen and cut backs (having a flash-point below 23 'C and viscous according to 2.2.3.1.4) (vapour pressure at 50 'C not more than 110 kPa) (vapour pressure at 50 'C more than 110 kPa , boiling point of more thiu 35" C) TARS, LIQUID, including road asphalt and oils, bitumen &d cut backs (having a flash-point below 23 'C and viscous according to 2.2.3.1.4) (vapour pressure at 50 'C not more than 110 kPa) (vapour vressure at 50 'C not more than 110 kPa) CELLULOID in block, rods, rolls, sheets, tubes, etc., except scrap COBALT NAPHTHENATES, POWDER CELLULOID, SCRAP MAGNESIUM DIAMIDE PLASTICS, NITROCELLULOSEBASED. SE1.F-IIEATING, N.O.S. ZlRCONlUM POWDER. DRY

Labels

-4.1

4.2

4.2 -

4.3 4.3

Carriage Equipment lermittec required

3.2.1 (8)

lentilation

8.1.5

7.1.6 0 (10) PP, EX, A VEO l

VEOl

VEOl VEOI, W02

Provisions concerning loading, unloading and carriage

Number of cones, blue Lights

7.1.5

(12) 0

Remarks

UN No, or ID No.

Name and description

Class

Classiti. cation group Code

Labels

Special provisions

Limited quantities

Provisions concerning loading, unloading and carriage

Zarriage Equipment ermitted required

3.1.2

2012

(2) POTASSIUM PHOSPHIDE

PP, EP, EX,

VEO1,

2013

STRONTIUM PHOSPHIDE

PP, EP, EX,

VEO1,

2014

2018 2019

HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 70% hydrogen peroxide HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 60% hydrogen peroxide and not more tlian 5%hydrogen peroxide AMMIJNITION. TOXIC. NONEXPLOSIVE without burster or expelling charge, non-fuzed AMMUNITION, TEARPRODUCING, NON-EXPLOSTVE without bluster or expelling . - charge non- fuzed CHLOROANILINES, SOLID CHLOROANILINES, LIQUID

2020

CHLOROPHENOLS, SOLID

2021

CHLOROPHENOLS, LIQUID

0

2015

2015

2016 2017

LQlO

II PP, EP

PP, EP PP, EP, TOX, A PP, EP

P

2022

2023

CRESYLIC ACID EPICHLOROHYDRIN

TOX, A PP, EP, TOX,A IPP. EP. EX.^

I

T

VE02

l VEOI.

Number of cones, blue lights

Remarks

J N No. or D No.

Name and description

Class

2.2

0 !024

(2) MERCURY COMPOUND, LIQUID, N.O.S.

lassitiacking :ation group Code

Labels

Special provisions

,.1.1.3

5.2.2

3.3

2.2

3.4.6

3.2.1

8.1.5

7.1.1

00(4) (5) 0 0 00(10 6.1

T4

I

6.1

I1

6.1

to24

MERCURY COMPOUND, LIQUID, N.O.S.

6.1

T4

1024

MERCURY COMPOUND, LIQUID, N.O.S.

6.1

T4

l025

MERCURY COMPOUND, SOLII N.O.S.

6.1

T5

2025

MERCURY COMPOUND, SOLII N.O.S.

6.1

T5

2025

MERCURY COMPOUND, SOLII N.O.S.

6.1

T5

2026

PHENYLMERCURIC COMPOUND, N.O.S.

6.1

T3

2026

PHENYLMERCURIC COMPOUND, N.O.S.

-

Limited Carriage Equipment Ventila quantities ~ermitted required

6.1

T3

p

2026

PHENYLMERCURIC COMPOUND, N.O.S.

6.1

2027

SODIUM ARSENITE, SOLID

6.1

T3

T5

111

6.1

43 274 802 43 274 802 43 274 802 43 274 529 585 802 43 274 529 585 802 43 274 529 585 802 43 274 802 43 274 802 43 274 802 43 802

LQO

PP, EP, TOX, A

VEO

LQ17

PP, EP, TOX, A

VEC

LQ7

PP, EP, TOX, A

WC

LQO

PP, EP

LQ18

PP, EP

PP, EP

PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX, A PP, EP

Provisions concerning ,oading,unloading and carriage

Number of cones, blue lights

Remarks

Name and description

3.1.2 (2) BOMBS, SMOKE, NONEXPLOSIVE with corrosive liquid. without initiating device HYDRAZINE, ANHYDROUS

Class

Iassifi cation Code

2.2

2.2

00 8

8

C1 1

Labels

Special provisions

Limited Carriage Equipment quantities permitted required Ventilation

3i;Ci

LQO

1 1 3;

POTASSIUM MONOXIDE HYDROGEN AND METHANE MIXTURE. COMPKESSED 1.1.1-TRIFLUOROETHANE (REFRIGERANT GAS R 143a) XENON RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable

PP, EP

PP, EP, EX TOX, A PP, EP, TOX, A

CFT P

HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass, having a flashpoint above 60 "C HYDRAZINE AQUEOUS SOLUTION, with more than 37% hvdrazine bv mass having" a flashpoint of not more than 60 "C HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass HYDRAZINE AOUEOUS SOLUTION, withmore than 37% hydrazine by mass NITRIC ACID, other than red fuming, with more than 70% nitric acid NITRIC ACID, other than red fuming, with not more than 70% nitric acid NITRIC ACID, RED FUMING

Si;;

CTl

CFT TOX, A

CTl

TOX, A CT 1 TOX, A

CO 1

C01

COT

LQO

I

T

I

C6 lF

PP, EP. TOX, A PP, EP PP, EX, A

2F

PP, EX, A

-

2A 5A

LQ2

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

3.2.1 ( 1 3 ) .

UN No. or ID No.

Name and description

3.1.2 (2) RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 1 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release (1) 2037

Classification Packing Code

Class

2.2 (323) 2

2.2 (3b) 5F

2

50

2.1.1.3 (4)

I I I I

Labels

5.2.2 (5) 2.1

Special provisions

Limited Carriage Equipment quantities ~ermitted required Ventilation

3.3 3.4.6 3.2.1 (6) (7) (8) 191 LQ2 303

2.2+5.1

8.1.5 (9) PP, EX, A

7.1.6

0 VEOl

PP

I

CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release I device, non-refillable 2037 1 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable

1

CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refiilable RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable DINITROTOLUENES, LIQUID

2037

2038 I

2044 2045

2

I 2,2-DIMETHYLPROPANE l ISOBUTYRALDEHYDE

I (ISOBUTYL. ALDEHYDE)

2

/

5TFC

2

5TOC

6.1

T1 I

I

1

5TF

2

2.3+2.1

I

I1 I

1 2 F (

6.1 I

1

1 3 1 F l- l T -I. I -

2.1 3

T

Provisions concerning Loading, unloading and carriage

PP, EP, TOX, A

W02

PP, EP, TOX, A

W02

PP, EP, EX TOX, A

VEOl, VE02

PP, EP, EX TOX, A

VEOI, W02

PP, EP, TOX, A

VE 02

PP, EP, TOX, A

W02

PP, EP, TOX, A PP, EX, A PP, EX, A

W02 VEOl WO1

blue lights

UN No. or ID No.

Name and description

Class

2.2

-

Limited quantities

3.4.6

LQ22

T

F1 F1

111 I11

LQ7 LQ7

8

CF 1

I

LQO

3

F1

nI

F1 F1 F1 F1 D

D

8

1 3 1 3

CF 1

I11 I1 IU 111 IU 11

STYRENE MONOMER.

2057 2057 2058 2059

2059

2059

FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose (vapour pressure at 50 'C more thar 110 kPa) NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose (vapour pressure at 50 'C not more than 110 kPa)

1

D

8.1.5

7.1.6

VEOl VEO l VEOl VEOl VEOl VEOl

'P, EP, EX A PP, EX, A PP, EX, A

VEOl

VEO l

LQ7

'P, EP, EX A PP, EX, A

I1 I1 111 I1 I

LQ4 LQ4 LQ7 LQ4 LQ3

PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A

VEOl VEOl VEOl VEOl VEO l

I1

LQ4

PP, EX, A

VEO l

LQ4

PP, EX, A

VEOl

-

I1

T T T

T

Provisions concerning loading, unloading and camage

0 0 PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A

I

2056

3.2.1

0 (8)

I1

2049 2050

2055

:arriage Equipment Ventilation ermittec required

T

2048 COMPOUNDS 2-DIMETHYLAMINO-ETHANOL

Special provisions

LQ7 LQ4 LQ7 LQ7 LQ7 LQ4

F1 F1 F1 F1 F1 F1

2047 2047

2052 - DIPENTENE 2053 METHYL ISOBUTYL - CARBINOL 2054 MORPHOLINE

2.1.1.3

0 0

0 2046

2051

lassif Packing :ation Code group

VEO l VEO l

VEO l

Number of cones, blue lights

Remarks

Name and description

3.1.2

Class

lassiti :ation Code

2.2

2.2

E L 0 FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose AMMONIUM NITRATE BASED FERTILIZER

AMMONIUM NITRATE BASED FERTILIZERS, uniform mixtures of the nitrogedphosphate, nitrogedpotash or nitrogedphosphate/potash type, containing not more than 70% an~moniumnitrate and not more than 0.4% total combustible/organic material calculated as carbon or with not more than 45% ammonium nitrate and unrestricted combustible material AMMONIA SOLUTION, relative density less than 0.880 at 15 'C in water, with more than 35% but not more than 50% ammonia ACRYLAMIDE, SOLID CHLORAL, ANHYDROUS, STABILIZED CRESOLS, LlQUID

Special provisions

Limited quantities

:arriagl ermitte

lqnipment required

3.2.1

8.1.5

00

02

B

3002. STOI, L004

9

M1 1

B

3002 ST02

4A

6.1 6.1

T2 T1

6.1

TC 1

T1 C7

-

T

PP, EP PP, EP, TOX, A PP, EP PP, EP, TOX, A PP, EP, TOX, A PP, EP

Remarks

(10)

5.1

2

Number of cones, due lights

7.1.6

D

-

'P, EX, A

Provisions concerning loading, unloading and carriage

3

T2 T1 TOLUENE DIISOCYANATE (2,4TOLUENE DIISOCYANATE) DIETHYLENETlUAMINE

Labels

VEOl

C002, L004 and HA09 apply only when this substance is caniec in bulk or without packaging Dangerous only in bulk or without packaging. C002, ST02 and HA09 apply only when this substance is carried in bulk or without packaging

I

UN No. Or ID No.

I

Name and description

3.1.2 (2) HYDROGEN CHLORIDE. REFRIGERATED LIQUID 2187 1 CARBON DIOXIDE, ( REFRIGERATED LIQUID 2188 ARSINE

(1) 2186

2189

I

I

class

1 cation

2.2 (34 2

2.2 (3b) 3TC

Pac*ing Code group

Labels

1

3

A

2.2

1

1

2

1

2TF

l

1

2TFC

/ DICHLOROSILANE

1

2

)

Limited Carriage Equip.ment Ventilation quantities permitted requwed

593

LQ1

PP

2.3+2.1

LQO

2.3+2.1+8

LQo

2.3+5.1+8

LQo

2.3

LQo

PP, EP, EX, TOX, A PP, EP, EX, TOX, A PP, EP, TOX, A PP, EP, TOX, A PP, EP, EX, TOX, A PP

COMPRESSED I

2192

GERMANE

2

2TF

2.3+2.1

2193

HEXAFLUOROETHANE (REFRIGERANT GAS R 116) SELENrOM HEXAFLUORIDE

2

2A

2.2

LQ1

2TC

2.3+8

LQO

2TC

2.3+8

LQO

2TC

2.3+8

LQO

2194

2

2195

TELLURIUM HEXAFLUORIDE

2 l96

TUNGSTEN HEXAFLUORIDE I

2197 2198 2199 2200 2201

2 l

I

1 HYDROGEN IODIDE, ( ANHYDROUS 1 PHOSPHORUS PENTAFLUORIDE PHOSPHINE

PROPADIENE, STABILIZED NITROUS OXIDE, I REFRIGERATED LIQUID 2202 1 HYDROGEN SELENIDE. ANHYDROUS 2203 SILANE 2204 CARBONYL SULPHIDE

632

LQo

l

l

l

2

I

1

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

CARRIAGE PROHIBITED

2

I

provisions

1

2

1

2TC

2.3+8

LQO

1

2

1

2TC

2.3+8

LQo

2

2TF

2.3+2.1

2 2

2F 30

2.1 2.2+5.1

LQo LQO

1 2

1 2TF

2.3+2.1

LQO

2 2

2F 2TF

2.1 2.3+2.1

632

632

LQO

LQo LQO

PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX, A PP,EP, TOX, A PP, EP, EX, TOX, A PP, EX, A PP PP, EP, EX. TOX. A PP, EX, A PP, EP, EX, TOX, A

0 VEO1, VE02 VEO1, W02 VE02

2

W02

2

VEO1, VE02

2

2 2

0 W02

2

VE02

2

VE02

2

W02

2

VE02

2

VEO1, VE02 VEOl

2

VEO1, VE02 VEOl VEO1, VE02

2

l 0

1 2

Remarks

LP4 No

or ID No.

111 2205 2206

2206

2208

2209 2210

221 1

Name and description

3.1.2 (2) ADIPONITRILE

Class

cation Code

2.2

2.2

Labels

Limited quantities

Zarriage Equipment ermitted required

2213 2214

2215

2215

BLUE ASBESTOS (crocidolite) or BROWN ASBESTOS (amosite, mysorite) PARAFORMALDEHYDE PHTHALIC ANHYDRIDE with more than 0.05% of maleic anhydride MALEIC ANHYDRIDE, MOLTEN MALEIC ANHYDRIDE

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

0 T

T

TOX, A PP, EP, TOX, A PP, EP, TOX, A

PP. EP PP, EX, A

none

P, EX, El A

P

2212

Ventilation

3.2.1

m m T1 6.1

ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. ISOCYANATES. TOXIC. N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 10% but not more than 39% available chlorine FORMAI.IXHYDE SOI.U'T1ON with not less than 25% formaldehyde MANEB or MANEB PREPARATION with not less than 60% maneb

POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour

Special provisions

PP PP, EP PP, EP PP. EP

VEO l, VE03

VE03, M01 and IN03 apply only when this substance is canie in bulk or without packaging W 0 3 and IN01 apply only when this substance is carried in bulk or without packaging

UN No. or ID No.

Name and description

3.1.2 (2) FISH MEAL, STABILISED or FISH SCRAP, STABILISED SEED CAKE with not more than 1.5% oil and not more than 11% moisture

Class

ALLYL GLYCIDYL ETHER ANTSOLE . - BENZONITRILE - --

BENZENESULPHONYL CHLORIDE BENZOTRICHLORIDE n-BUTYL METHACRYLATE, STABILIZED 2-CHLOROETHANAL

2.2 2.1.1.3 (4) (3b) M11

2.2

(3a) 9

1

I

4.2

I

ACRYLIC ACID, STABILIZED

ClassifiPacking cation Code

1

1

1

S2

I

8

(

I

1

111

I

CF1

(

1

1

Labels

Special provisions

5.2.2 (5)

3.3 (6)

4.2

142 800

Limited Carriage Equipmen1 Ventilation quantities permitted required

1

WO1

8+3 PP, EX, A PP, EX, A PP, EP, TOX, A PP, EP

F1 F1 T1

111 I11 I1

3 3 6.1

8

C3

I11

8

8 3

C9 F1

I1 I11

8 3

6.1

T1

I

6.1

LQO

6.1 3

LQ9 LQ7

1 1

T2 I 111 F1 1 1 1 1

1

I

Remarks

when this substance is carrie in bulk or without

3 3 6.1

CHLOROANISIDINES 1 6.1 1 3 CHLOROBENZOTRIFLUORIDES CHLOROBENZYLCHLORIDES, 1 6.1 LIQUID 3-CJXORO-4-METHYLPHENYL 1 6.1

Number of cones, blue lights

7.1.6 (10)

I

I1

Provisions concerning loading, unloading and carriage

.%F$T+&G

WO1 VEO l W02

PP, EP

PP, EP, TOX, A PP, EP PP, EX, P l

m02 VEO l

I

1

T1

I

I11

1

6.1

LQ7

PP, EP

1

T1

I

I1

1

6.1

LQ17

PP, EP

LQ9 LQ7 LQ9 LQO LQ4 LQ4 LQ7 LQ7 LQ7 LQ4

VEOl

T T

PP, EP PP, EX, P PP, EP PP, EP PP, EX, P PP, EX, P PP, EX, P PP, EX, P PP, EX, P PP, EX, P

VEOl

VEOl VEOl VEOl VEOl VEO l VEOl

UN No. or ID No.

Special provisions

111 2247 n-DECANE

3.1.2 (2)

2248

DI-n-BUTYLAMINE

2249

-

DICHLORODIMETHYL ETHER, SYMMETRICAL DICHLOROPHENYL ISOCYANATES

2251

BICYCLO[2.2.1]HEPTA-2,5-

2252 2253

DIENE, STABILIZED (2,5NORBORNADIENE, STABILIZED) 1,2-DIMETHOXYETHANE N,N-DIMETHYLANILINE MATCHES, FUSEE CYCLOHEXENE POTASSIUM 1,2-PROPYLENEDIAMINE

2.2 (34 3 8 I

2250

2254 2256 2257 2258

1

1

TF1

5.2.2 (5) 3 8+3

3.3 (6)

(7) LQ7 L022

I

I

1

(8) T T

2262

2263 2264 2265 2266

2267

2269 2270

P

-

(11)

LQ4

PP, EX, A

VEOl

1

LQ4 LQ17

PP, EX, A PP,EP, TOX, A PP PP, EX,A PP, EX, A PP, EP, EX, A PP,EP PP, EP, EX, A PP, EP PP, EP

VEOl VE02

l 2

VEOl VEOl VEOl

0 1 0 1

PP,EX, A PP, EP,EX, A PP, EX, A PP, EP, EX, A PP, EP, TOX, A PP, EP PP, EP, EX, A

VEOl VEOl

1 l

VEOl VEOl

0 1

W02

2

VEOl

0 1

6.1

3

F1

I1

3

3 6.1

F1 T1

I1 I1

3 6.1

4.1 3 4.3 8

F1 F1 W2 CFI

I11 I1 I I1

4.1 3 4.3 8+3

8 3

C7 FC

I1 111

8 3+8

XYLENOLS, SOLID DIMETHYLCARBAMOYL CHLORIDE DIMETHYLCYCLOHEXANES N,N-DIMETHYLCYCLOHEXYLAMINE N,N-DIMETHYL-FORMAMIDE DIMETHYL-N-PROPYLAMINE

6.1 8

T2 C3

I1 I1

6.1 8

3 8

F1 CFl

I1 I1

3 8+3

LQ4 LQ22

T T

3 3

F1 FC

111 I1

3 3+8

LQ7 LQ4

T T

DIMETHYL THIOPHOSPHORYL CHLORIDE 3,3'-IMINODIPROPYLAMINE ETHYLAMINE, AQUEOUS SOLUTION with not less than 50% but not more than 70% ethylamhe

6.1

TCl

I1

6.1+8

8 3

C7 FC

111

8 3+8

802

802 293

LQ9 LQ4 LQO LQ22 LQ22 LQ7

Il

802

802

2

PP, EP

11

T

P

2261 -

(9) (10) PP,EX,A VEOl PP.. EP.. EX., VEOl ] A ]

Number of cones, blue lights

LQ17

T2

TRIPROPYLAMINE

Provisions concerning loading, unloading and carriage

CARRIAGE PROHIBITED

6.1

2259 TRIETHYLENETETRAMINE 2260

I

I

6.1

2.1.1.3 (4) 111 I1

2.2 (3b) F1 CFl

Limited Carriage Equipment Ventilation quantities permitted required

LQl8 LQ22

LQ17 LQ7 LQ4

VEOl

HA08

0 0 2 0

Remarks

YN No. or ID No.

( I )

2271 2272

Name and description

3.1.2 (2)

ETHYL AMYL KETONE N-ETHYLANILINE

Class

Classifi, Packing cation Code ~r'"'P

2.1.1.3

0 111 I11

111

2273 2274

111

2275 2276

I11 I11

2277 2278 2279 2280 2281

ETHYL METHACRYLATE, STABILlZED n-HEPTENE HEXACHLOROBUTADIENE HEXAMETHYLENE-DIAMINE, SOLID HEXAMETHYLENE DIISOCYANATE

2282 2283

2285

I1 111 111

rI

111 111

- STABILIZED 2284

I1

ISOBUTYRONITRILE ISOCYANATOBENZOTRIFLUORIDES PENTAMETHYLHEPTANE ISOHEPTENES ISOHEXENES ISOPHORONEDIAMINE ISOPHORONE DIISOCYANATE

LEAD COMPOUND, SOLUBLE, N.O.S.

I1

Labels

Special provisions

Limited Carriag~ Equipment Ventilation quantities permitte required

8.1.5

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.6

0 (10) PP, EX, A PP, EP, TOX, A PP, EP,

VEOl W02

VEOl WO1 A PP, EX, A PP, EX, A PP, EP, TOX. A PP, EP PP, EP, TOX, A PP, EX, A PP, EX, A

VEOl VEOl VE02

VEOl VEO l

'P, EP, EX

I1

I11 I1 I1 111 I11 111

TOX; A PP, EX, A PP, EX, A PP, EX, A PP, EP PP, EP, TOX, A PP. EP

VEO~ VEO l VEOl VEO l

if'

Remarks

IN No. or CD No.

Name and description

Class

2.2 (3a) 3

METHYL CHLOROACETATE

ClassifiPac~ng cation Labels Code

2.2 (3b) F1

2.1.1.3

(4) U1

5.2.2 (5)

3

Special provisions

Limited Carriage Equipment Ventilation quantities permittet required

l

Provisions concerning loading, unloading and carriage

7.1.6

0 PP, EX, A PP, EP, TOX, A 'P, EP, EX TOX, A PP. EX. A

METHY IXYCLOHEXANONE IETHY LCYCLOPENTANE METHYL DICHLOROACETATE

7.1.6

VEOl

m02 VEOl VEOl VEOl m02

TOX, A PP, EP, 2-METHYLFURAN S-METHYLHEXAN-2-ONE [SOPROPENYLBENZENE NAPHTHALENE, MOLTEN NITROBENZENE-SULPHONIC ACID

NITROBENZO-TRIFLUORIDES. LIQUID 3-NITRO-4-CHLOROBENZOTRIFLUORIDE NITROSYLSULPIIURIC ACID. LIQUID OCTADIENE PENTANE-2,CDIONE

PP PP, EP PP, EP, TOX, A PP, EP, TOX, A PP, EP PP, EX, A 'P, EP, EX

PHENETIDINES PHENOL, MOLTEN PICOLINES POLYCHLORMATED RIPHENYLS, LlQUlD SODIUM CUPROCYANIDE. SOLID

TOX, A PP, EP, TOX, A PP, EX, A PP, EP PP, EP

VEOl

I

I

1

I

I

l

I

Number of cones, blue lights

Remarks

jn No

or ID No.

0 2317

23 18 2319

2320

Name and description

3.1.2 (2) SODIUM CUPROCYANIDE SOLUTION SODIUM HYDROSULPHIDE wi less than 25% water of xystallization TERPENE HYDROCARBONS, V.O.S.

2321 2322

LIQUID TRICHLOROBUTENE

2323

TRIETHYL PHOSPHITE TRIISOBUTYLENE 2325 1,3,5-TRIMETHYLBENZENE 2326 FRIMETHYLCYCLOHEXYLAMINE 2327 HUMETHYLHEXAMETHYLENEDIAMINES 2328 HUMETHYLHEXAMETHYLENE DIISOCYANATE 2329 rRIMETHYL PHOSPHITE 2324

2330 233 1 2332 2333 2334

ALLYLAMME

2335

ALLYL ETHYL ETHER

2336

ALLYL FORMATE

2337

PHENYL MERCAPTAN

2338

BENZOTRIFLUORIDE

Class

2.2

4%. 6.1

4.2

lassifi. cation Code group

2.2

0 T4

Labels

Special provisions

Limited Carriage Equipment Ventilation quantities permittec required

8.1.5

0 PP, EP

S4

3

F1

PP, EX, A

8 6.1

C7 T1

6.1

T1

3 3 3 8 8

Fl F1 F1 C7

PP, EP PP. EP. TOX, A PP, EP, TOX, A PP, EX, A PP, EX, A PP. EX, A PP, EP

C7

PP, EP

6.1 3 3 8 3 3

T1

TF1

FT1 FT I

TF1 F1

VEOl VEO l VEOl

PP. EP. TOX, A

F1 F1 C2 F1 FT1

VEOl

m01 VEOl PP. EP TOX, A =P, EP, EX TOX, A ?P, EP, EX TOX, A PP, EP, EX TOX, A 'P, EP, EX TOX, A PP, EX, A

VEOl VEOl. VE02 VEo1, WO2 VEo1, VE02 VEo1, VE02 VEo1, m02 VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

Name and description

Class

ClassifiPacking cation Code

Labels

Speeial provisions

Limited Carriag~ Equipment quantities permitte~ required Ventilation

7.1.6

(10) 0

X-,

2-BROMOBUTANE 2-BROMOETHYL ETHYL ETHER

PP, EX, A PP, EX, A

BROMOPROPANtS RROMOPROPAKES 3-BROMOPROPYNE BUTANEDIONE B u m MERCAPTAN BUTYL ACRYLATES, STABILIZED BUTYL METHYL ETHER BUTYL NITRITES BUTYL NITRITES BUTYL VINYL ETHER, STABILIZED BUTYRYL CHLORIDE CHLOROMETHYL ETHYL ETHER 2-CHLOROPROPANE CYCLOHEXYLAMINE

VEOl VEOl

VEO l VEOl VEOl VEOl

-

3 8

F1 CFl

I I1

3 8+3

3 3

F1 FTC

I1 I1

3 3+6.1+8

PP, EP, EX A EP, EX TOX, A PP, EX, A PP, EP. EX

VEOl E02 VEOl VEOl

A

CYCLOOCTATETRAENE DIALLYLAMINE DIALLYL ETHER

T O X ~A PP, EP, EX

VEOl VEo1, VE02 VEOI,

DIISOBUTYLAMINE VEOl VEOl VEOl VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

-

3.1.2 (2)

0 2367

alpha-

2368 2370 2371 ISOPENTENES 2372

1.2-DI-(DIMETHYLAMINO)

Class

Classifi cation Packing group 1 Code

Labels

Special provisions

Provisions concerning loading, unloading and carriage

Limited Carriag~ Equipment Ventilation quantities permitte required

3.2.1 (8)

Number of cones, blue lights

; PP,EX, A

VEOl

- ETHANE 2373 DIETHOXYMETHANE 2374 3,3-DIETHOXYPROPENE 2375 DlETHYL SULPHIDE 2376

2.3-DIHY DROPYRAN

2377 2378

2379

ACETONITRILE I ,3-DIMETHYLBUTYLAMINE

I

VE02 VEOl

'P, EP, EX,

VEOl,

'P, EP, EX,

VEOl

TOX, A 'P, EP,

EXA

I 1

I

2380

2381 2382

- SYMMETRICAL 2383

DIPROPYLAMINE

2384 2385 2386

2387 FLUOROBENZENE 2388 FLUOROTOLUENES 2389 FURAN 2390 2-IODOBUTANE 2391 IODOMETHYLPROPANES 2392 IODOPROPANES 2393 ISOBUTYL FORMATE 2394 ISOBUTYL PROPIONATE 2395 ISOBUTYRYL CHLORIDE

Remarks

2 'P, EP, EX,

JN No. or Ul No.

111 2396

2397

Name and description

2400

METHYL ISOVALERATE PIPERIDINE PROPANETHIOLS ISOPROPENYL ACETATE PROPIONITRILE

2403 2404 2405

2406 2407

ISOPROPYL PROPIONATE BUTYRONITRILE

2412

TETKAHYDROTHIOPHENE I ETRAPROPY L ORTHOTITANATE THIOPHENE TRIMETHYL BORATE CARBONYL FLUORIDE

2414 2416 2417

Remarks

7.1.6 (1 1)

7.1.5 (12)

3.2.1 (13)

I1 I

PP, EX, A PP, EP, E3

VEOl VEOl

1 1

3 3 3

F1 F1 FT1

I1 I1 I1

PP, EX, A PP, EX, A PP, EP, E3 TOX, A PP, EX, A PP, EX, A PP, EP, E3 TOX, A PP, EX, A PP, EX, A PP, EP, E3 TOX, A PP, EX, A PP, EX, A

VEOl VEOl VEo1, VE02 VEOl VEOl -01, VE02 VEOl VEOl VEo1, VE02 VEOl WO1

1

LQ7 LQ4 LQO

TFC

3

3

F1 F1 FT1

I1 I1 I1

LQ4 LQ4 LQO

3 3

F1 F1

I1 I11

LQ7

2TC

LOO l

I

2

2TC

LQO

2419

BROMOTRIFLUOROETHYLENE HEXAFLUOROACETONE

2

2F

LQo

2

2TC

LQO

1 I

1 2

1

1 1 1

F1 CF1

1,2,3,6-TETRAHYDROPYRIDINE 3

NITROGEN TRIOXIDE OCTAFLUOROBUT-2-ENE (REFRIGERANT GAS R 1318)

VEOI. VE02 VEOl VEOl VEOl

2

TOX, A PP,EX, A PP, EX, A PP, EP, E3

3 8

SULPHUR TETRAFLUORIDE

2421 2422

T T

LQ4 LQ4 LQ4

2418

2420

Number of cones, blue lights

I1

I

-

Provisions concerning loading, unloading and carriage

FC

ISOPROPYL BUTYRATE ISOPROPYL ISOBUlYRATE ISOPROPYL. CHLOROFORMATE 6.1

2409 2410 2411 2413

Special Limited Carriage Equipmeni ~rovisions quantities permitted required Ventilation

Labels

METHACRYLALDEHYDE, STABILIZED METHYL tert-BUTYL ETHER l-METHYLPIPERIDINE

2402

ClassifiPacking cation Code

7.1.6 (10)

2398 2399 2401

Class

2

) 2TOC [ ( 2 A 1

I

I

1

2.2

1

I

L01

1

I

PP, EX, A PP, EP, TOX,A ( PP, EP, TOX, A PP, EX, A

I

1 2 0 1 2 1 1 2 1 0

VEOl VEOl VE02

1 1 2

I

I

I

I

l

VEOl

1

I

I

PP, EP, TOX, A I CARRIAG PROHIBITED 1 PP

I

I

l

l

0

JN No. or ID No.

Name and description

I (REFRIGERANT GAS R 218) 2426

1 AMMONIUM NITRATE, LIQUII: hot concentrated solution, in a concentration of more than 80% bu not more than 93% 1 POTASSIUM CHLORATE. AQUEOUS SOLUTION POTASSIUM CHLORATE, AQUEOUS SOLUTION SODIUM CHLORATE, AQUEOUS SOLUTION SODIUM CHLORATE, AQUEOUS SOLUTION CALCIUM CHLORATE, AQUEOUS SOLUTION CALCIUM CHLORATE, AQUEOUS SOLUTION ALKYLPHENOLS, SOLID, N.0.I (including CZ-C12homologues) ALKYLPHENOLS, SOLID, N.0.I (including C& 12 homologues) ALKYLPHENOLS, SOLID, N.0.h (including C Z - Chomologues) ~~ ANISIDINES

Class

Classifi 'acking cation Code group

2.2 (3a) 2

2.2 (3b) 2A

5.1

01

5.1

01

5.1

01

5.1

01

5.1

01

5.1

Labels

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

7.1.6 (10)

I 2427 2427 2428 2428 2429 2429 2430 2430 2430 243 1

2433 2434 2435 2436 2437

CHLORONITROTOLUENES, LIQUID DIBENZYLDICHLORO-SILANE ETHYLPHENYLDICHLOROSILANE THIOACETIC ACID METHYLPHENYLDICHLOROSILANE

LQlO

PP

01

LQlO

PP

5.1

01

LQ13

PP

8

C4

274

LQO

PP, EP

8

C4

274

LQ23

8

C4

274

LQ24

6.1

T1

6.1

T1

6.1

T1

8 8

C3 C3

3 8

F1 C3

PP, EP

T

PP, EP PP, EP, TOX, A

802 802

TOX, A PP, EP, TOX, A PP, EP PP, EP I

I I

I

LQ4 LQ22

I I

I

I PP, EX, A I

PP, EP

VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.5 (12) 0

Remarks

UN No. or ID No.

(1) 2438 2439 2440 244 1

2442 2443

Name and description

3.1.2 (2) TRIMETHYLACETYL CHLORIDE l SODIUM l HYDROGENDIFLUORIDE 1 STANNIC CHLORIDE PENTAHYDRATE 1 TITANIUM TRICHLORIDE. PYROPHORIC or T I T A N I U ~ TRICHLORIDE MIXTURE, l PYROPHORIC l TRICHLOROACETYL CHLORIDE l VANADIUM

l

l

~

2111 2446 2447

2448 245 1 2452 2453 2454

ClassifiPacking cation Code

2.2 (3a) 6.1

2.2 2.1.1.3 (4) (3b) TFC I ) C 2 1 I1

(5)

6.1+3+8

I

8

I

8

1

4.2+8

8

1

8

1

4.2

1

8

1 C 3 I I I I

8

1

8

( C l I I I I

8

1 1

C2

I

1 SC4 I

1 VANADIUM TETRACHLORIDE 1 8 1 16.1 1 I NITROCRESOLS, SOLID -

MOLTEN SULPHUR, MOLTEN NITROGEN TRIFLUORIDE ETHYLACETYLENE, STABILIZED ETHYL FLUORIDE (REFRIGERANT GAS R 161) METHYL FLUORIDE

5.2.2

1

.

1 PHOSPHORUS, WHITE,

Special provisions

111 I

1

/ I Il l

l

- .. . ..~ .-..-

Class

1

4.2 4.1 2 2

1

1 I T2 1 1 1 1 ST3 I I l

F3 20 2F

111

I 1 1

8 6.1 4.2+6.1

4.1 2.2+5.1 2.1

1

Limited Carriage Equipment Ventilation quantities permitted required

3.3 (6) 802 TOX, A PP, EP

I

2F

2.1

2

2F

2.1

7.1.6 (10) VEOl, VE02

1

I

0

537

802 802 538

7.1.5 (12) 2

0

PP, EP

1 1

Number of cones, blue lights

0

PP, EP

LQo LQ9 LQO LQO LOO LQO

I

I

j

T

PP, EP PP, EP PP, EP, I TOX,A I PP l PP PP, EX, A

VEOl

+ I

2

Provisions concerning loading, unloading and carriage

LQo

1

I

I PP, EX, A PP, EX, A

VEOl VEOl

I

PROHIBITED

Remarks

-

Class

Classifi cation Code

2.2

2.2

F N No.

or D No.

Name and description

3.1.2 (2) 0 IICHLOROISOCYANURIC !465 K I D , DRY or XCHLOROISOCYANURIC \CID SALTS !466 'OTASSIUM SUPEROXIDE l468 rRICHLOROISOCYANURIC \CID. DRY 2469

1470

y 7 J 2473

LIQUID OSMIUM TETROXIDE SODIUM ARSANILATE

2475 2477

5.1 5.1 5.1 6.1 6.1 6.1

VANADIUM TRICHLORIDE METHYL ISOTHIOCYANATE

8 6.1 3

LQll

02

5.1

02 02

02 T1

TOX. A PP, EP PP, EP, TOX, A PP, EP, TOX, A PP, EP

T5 T3

-

L017

T1

C2 I

LY

PP, EP, E)

2480 2481

ETHYL ISOCYANATE

802

2482

n-PROPYL ISOCYANATE

802

LQO

2483

ISOPROPYL ISOCYANATE

802

LQO

2484

tert-BUTYL ISOCYANATE

802

LQO

2478

PP

+ . LQll

[SOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION. FLAMMABLE. TOXIC, N.O.S. ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. METHYL ISOCYANATE

2478

Provisions concerning loading, unloading and carriage

Limited Carriage Equipment Ventilation quantities permitted required

Special ,revisions

00

6.1

2474

Labels

PP, EP, E> TOX, A I

802

LQO

1

LQO

I

PP, EP, E><.I 1 TOX,A IPP, EP, EX,^ TOX, A PP, EP, EX, TOX, A PP, EP, EX, TOX, A PP, EP, EX,

I

I

VEOI. VE02 VEO1, VE02 VEO1, VE02 VEO1, VE02 VEOI,

I

1 I

I

Number of cones, h e lights

Remarks

I

UN No. or ID No.

Name and description

Class

3.1.2 (2) n-BUTYL ISOCYANATE

2485

..

Limited Carriage Eauiament quantities permitted required

p$f:ns

Labels 80UP

ISOBUTYL ISOCYANATE

2487

PHENYL ISOCYANATE

2488

CYCLOHEXYL ISOCYANATE

1

6.1

TFl

I

I

I

6.1+3

802

I

6.1 I

2491

DICHLOROISOPROPYL ETHER

6.1 I

ETHANOLAMINE or ETHANOLAMINE SOLUTION

I

8

2493 I

2495

Number of cones, blue Lights

Remarks

3 l

2490

Provisions concerning loading,carriage unloading and

l

2486

-

Ventilation

2.2 (34 6.1

0 -

Ilassification Code

IODINE PENTAFLUORIDE

5.1

2496 2498

1 8 PROPIONIC ANHYDRIDE 1 3 1.2.3.6-TETRAHYDROBENZALDEHYDE 2501 TRIS-(1-AZIRIDINYL) 6.1 PHOSPHINE OXIDE SOLUTION 2501 TRIS-(1-AZIRIDINYL) 6.1 - PHOSPHINE OXIDE SOLUTION 2502 VALERYL CHLORIDE 8

OTC

1

5.1+6.1+8

802

TOX, A 'P, EP, EX TOX, A 'P, EP, EX TOX, A PP, EP, TOX, A PP, EP 'P, EP, EX A PP, EP, TOX, A PP, EP PP, EX, A

VEOl

PP, EP, TOX, A PP, EP, TOX, A 'P, EP, EX

W02

VE02 VEOl

W02 VEOl

A

.-

2503 2504

ZIRCONIUM TETRACHLORIDE TETRABROMOETHANE

2505 2506

AMMONIUM FLUORIDE AMMONIUM HYDROGEN SULPHATE

2507

CHLOROPLATINIC ACID, SOLID

6.1 8

PP, EP PP, EP, TOX, A PP, EP PP, EP

8

PP, EP

8 6.1

1 1

I

I

C003 applies only when this substance is carriec in bulk or without packaging

JN No. or ID No.

-

Class

Name and description

3.1.2 (2) MOLYBDENUM PENTACHLORIDE POTASSIUM HYDROGEN SULPHATE

2.2

m 8

0 2508

2509

8

AMINOPlIENOI~S(o-, m-,p-)

6.1

-

-

2513 2514 2515

2516 2517 2518

2520 2521

CARBON TETRABROMLDE I-CHI.ORO-I.1DIFLUOROETHANE (REFRIGERAN'I' GAS R I12b)

Labels

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

2.2

-

C2

LQ24

C2

C3 T2

8 3 6.1

C3 F1 T1

6.1 2

T2 2F

"C' III

LQ23

T1

LQ17

2525 2526

FURFURYLAMINE

FC

2527

ISOBUTYL ACRYLATE,

F1

2531

METHACRYLIC ACID, STABILIZED

F1 T1

F1 FC

C3

111

6.1

I

B

I

PP, EP

C003 applies only when this substance is carried in bulk or without

PP, EP PP, EP PP, EP PP, EX, A PP. EP. TOX, A PP, EP PP, EX, A

LQ7

Loo

METHACRYLATE ETHYL ORTHOFORMATE ETHYL OXALATE

I

LQ9

F1 TF1

ISOBUTYL ISOBUTYRATE ISOBUTYRIC ACID

Remarks

PP, EP

6.1

CYCLOOCTADIENES DIKETENE, STABILIZED

2528 2529

Number of cones, blue lights

3.2.1

T1

- STABILIZED

Provisions concerning loading, unloading and carriage

0

1,5,9-CYCLODODECATRIENE-

2522

2524

lacking

W"'P

I

8 2511 2-CHLOKOPROPIONICACID~ 2512

Iassifi cation Code

I I

TOX, A PP, EX, A PP, EP. EX ( TOX, A I PP, EP, TOX, A PP, EX, A PP, EP, TOX, A PP, EP, EX

VEOl W02 VEOl

VEO l VEOl,

VEOl m02 VEOl VEOl

PP, EP, EX

VEOl WO1

JN No. or U) No.

Name and description

Class

2.2

0 2533

2534

2535 2536

(2)

METHYL I'RICHLOROACETATE METHYLCHLOROSILANE

$-METHYLMORPHOLINE (NMETHYLMORPHOLINE) METHYLrETRAHYDKOFURAN NITRONAPHTHALENE

2542

2545

lassiti- 'acking cation Code group

6.1

T1

2

2TFC

2546 -

2547 2552

HEXAFLUOROACETONE

2554

F1 F1 T1

T1

WATER (not less than 25% water,

- by mass) 2556

2557

NITROCELLULOSE WITH ALCOHOL (not less than 25% alcohol, by mass, and not more tha 12.6% nitrogen, by dry mass) NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH or WITHOUT PLASTICIZER, WIT1 or WITHOUT PIGMENT

8.1.5

PP. EP. TOX, A 'P, EP, EX TOX, A 'P, EP, EX A PP, EX, A

802

Fl

F1 D

2555

6.1

FC

-

2546

3.2.1

111

D

D

Provisions concerning Loading, unloading and carriage

yarnage Equipment srmitted required

CS) 0

-

-

POWDER. DRY 2546 TITANIIJM

Limited quantities

2.2

2548

2545

Special provisions

0(3b)

S4 S4 S4 S4 S4 S4 02 2TOC

2545

Labels

VEO l VE02 LQO LOO

TOX, A PP PP

LQO LQO LQO LOO PP, EP, TOX, A PP, EP, TOX, A PP, EX, A PP

E02 m02 VEOl

Number of cones, blue lights

Remarks

UN No or ID No.

Name and description

-

3.1.2

(2) a 2558 EPIBROMOHYDRIN 2560 2561 2564

2-METHYLPENTAN-2-OL 3-METHYL- 1-BUTENE TRICHLOROACETIC ACID

-

2570

-

2.2 -

3assification PacWug Code

2.2

6.1

TFl

3 3 8

F1 F1 c3

SOLUTION DICYCLOHEXYLAMINE SODILJM PENTACHLOROPIIENATE CADMIIJM COMPOUND

2570

CADMIUM COMPOUND

2570

CADMIUM COMPOUND

Special provisions

2.1.1.3 (4) I

0 (3b)

5.2.2

I

8

C3

8 -

C7 T2

I11

II

8 6.1

T5

I

6.1

6.1

6.1

3.2.1 (8)

LQ7 LQ3 LQ22 I

I

111

3.4.6 (7) LQo

3 3 8

n

I

Limited Carriage Equipment quantities permitted required

3.3 (6) 802

(5) 6.1+3

111 I I

2564

2565 2567

Class

l

ILQ7

8

802 274 596

T I

I

8.1.5 (9) PP, EP, EX TOX, A PP, EX, A PP, EX, A PP,EP l

T

I

PP, EP

LQ7 LQ18

PP, EP PP, EP

LQo

PP, EP

6.1

PP, EP

6.1

LQ9

PP, EP

596 2571 2572

2573 2574

2576

ALKYI.SULP1-1URIC ACIDS PI IENYLHYDRAZINE THALLlUhl Cl1LORATE TRICRESYL PHOSPHATE nil11 more than 3% ortho isomer PHOSPHORUS OXYBROMIDE, MOLTEN PHENnACETYL CHLORIDE

SOLUTION ALUMINIUM CHLORIDE SOLUTION FERRIC CHLORIDE SOLUTION

-

I

I

5.1 6.1

0T2 T1

I1 I1

5.1+6.1 6.1

8

C1

II

8

LQO

C3 C2 C8 C1

I1 111 111 111

8 8 8 8

LQ22 LQ24 LQ24 LQ7

PP, EP PP, EP PP,EP PP, EP

C1

111

8

LQ7

PP, EP

C1

111

8

LQ7

PP, EP

1

802 802 802

1

LQ22 L017

I

PP,EP PP. EP. TOX, A PP PP, EP, TOX, A PP, EP

1

8 6.1

I

C3 T1

I

I1 I1

I

8 6.1

LQll LQ17

I

I T

T

Ventilation

VE02 VEOl VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

JN NO.

Name and description

or ID No.

Class

3.1.2 2.2 (2) (3a) (L) 2583 ALKYLSULPHONIC ACIDS, 8 SOLID or ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid 8 2584 ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid 1 8 2585 ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid 2586 ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with not more - than 5% free sulphuric acid 2587 BENZOQUINONE 2588 PESTICIDE, SOLID, TOXIC, N.O.S. 2588 N.O.S. 2588

PESTICIDE, SOLID, TOXIC, N.O.S.

2589

VINYL CHLOROACETATE

2590

WHITE ASBESTOS (chrysotile, actinolite, anthophyllite, tremolite)

6.1 l

2591

-

XENON, REFRIGERATED LIQUID

6.1

1

I

9

I

2

lassifiPacking :ation Code

Labels

Special provisions

Limited quantities

2.2 2.1.1.3 (4) (3b) I1 C2

5.2.2 (5) 8

3.3

3.4.6

(7) 0 274

LQ23

C1

I1

8

274

LQ22

C4

111

8

274

LQ24

C3

I11

8

274

LQ7

T2 T7

II

6.1 6.1

802 61 648 802 61 648 802 61 648 802 802

LQ18 LQO

168 542 802 593

LQ27

I

LQ18

LQ9 LQ17

LQ1

Remarks

UN No or ID No.

Name and description

3.1.2 ( 1 ) (2) 2599 ZHLOROTRIFLUOROMETHANE AND rRIFLUOROMETHANE 4ZEOTROPIC MIXTURE with approximately 60%

Class

:lassi& cation Code

2.2

2.2

Labels

Special provisions

Limited Carriagc quantities permittet

Provisions concerning Equipment Ventilation loading, unloading and required carriage

00 2

2A

2 2

2F 2A

PP, EX, A PP

VEO l

'P, EP, EX TOX, A 'P, EP, EX A 'P. EP. EX TOX, A 'P, EP, EX TOX, A PP, EX, A

VEo1, VE02 VEOl

:hlorotrifluoromethane

2601 2602

,REFRIGERANT GAS R 503) CYCLOBU'I'ANE DICHLORODIFLUOROMETHANEAND 1.1DIFLUOROETHANE 4ZEOTROPIC MIXTURE with approximately 74% ~ichlorodifluoromethane

2603

[REFRIGERANT GAS R 500) CYCLOHEPTATRIENE

3

FT1

2604

BORON TRIFLUORIDE

8

CFl

3

FT1

6.1

TFl

3

F1

2605 2606

2607

2608 2609

[SOCYANATE METHYL ORTHOSILICATE ACROLEIN DIMER. STABILIZED NITROPROPANES TRIALLYL BORATE

3

2610 261 1

PROPYLENE CHLOROHYDRIN

2612

2614 2615 2616 2616

3 6.1

I'RIISOPROPYL BORATE

6.1 3 3 3 3 3

F1 Tl

FC

TFl

F1 F1 F1 F1 F1

VEOl. VE02 VEOl VEOl VE02

TOX, A 'P, EP, EX A 'P, EP, EX TOX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A PP, EX, A

VEOl VEOl.

VEO l VEO l VEOl

Number of cones, blue lights

Remarks

Name and description

Class

2.2

8a)

-

METHYLCYCLOHEXANOLS.

3

3 8 AMYL BUTYRA'I'FS -. ACETYL METHYL CARIiINOI. GLYCIDALDEHYDE

3 3 3

FIRELIGHTERS, SOLID with flammable liquid MAGNESIUM SLICIDE CHLORIC ACID. AOUEOUS SOLUTION with notkore than 10% chloric acid NITRITES, INORGANIC, N.O.S.

4.1

--

--

-

-

4.3 5.1

5.1

POTASSIUM FLUOROACETAT - . ~ - - . . -- -~ ----SODIUM FLUOROACETATE SELENATES or SELENITES -

- -

~

FI,UOROACETIC ACID METHYL BROMOACETATE METHYL IODIDE PHENACYL BROMIDE HEXACJTLOROCYCLOPENTADIENE MALONONITWE 1,2-DIBROMOBUTAN-3-ONE

-

-

6.1 6.1 6.1

6.1 6.1

6.1

6.1 6.1

6.1 6.1

6.1 6.1

lassifi. 'acking cation Code W"-P

6.1

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

2.2

m F1

LQ7

PP, EX, A

F1 F1 F1 FT 1

A PP, EX, A PP, EX, A PP, EP, EX TOX, A PP

LQ7 LQ7 LQO

Fl

W2 01

LQ9

zFf=fFPP, EX, A

02

T2 T2 T5

LQo LQO LQO

PP, EP PP, EP PP, EP

T2 T1

LQ17

T1

LQO

T2 T1 T2 T1

T2 T1 T2

7.1.6 (10) VEO l VEO l VEOl

CFl

-METHANE

Labels

I

I I

PP, EP PP, EP, T0X.A PP, EP, TOX, A PP, EP PP, EP, TOX, A PP, EP PP, EP, TOX, A PP, EP PP. EP,

Provisions concerning loading, unloading and carriage

7.1.6 (11)

Number of cones, blue lights

Remarks

m No. or ID No.

Class

Name and description

;a 3.1.2

111 BENZYL IODIDE

6.1

2655 POTASSIUM FLUOROSILICATE -

6.1 6.1

2653

2656

cation Packing goup

QUINOLINE

(

Labels

Special provisions

3.4.6 (7)

3.2.1 (8)

8.1.5

LQ17 LQ9 LQ7

LQ9 LQ7 I

DIBROMOMETHANE

6.1

LQ7

l

BUTYLTOLUENES

6.1

LQ7

6.1

LQ17

6.1

LQ17

6.1

L07

1

CHLOROACETONITRILE I

CHLOROCRESOLS, SOLUTION I

CHLOROCRESOLS, SOLUTION

I

CYANURIC CHLORIDE AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 'C in water, with more than 10Y0

7.1.6 (10)

(9) PP, EP, TOX, A PP, EP PP, EP, TOX, A PP, EP PP, EP PP, EP

7.1.6 (11)

W02

VE02

TOX, A PP, EP, TOX, A PP, EP, TOX, A PP, EP, EX, TOX, A PP, EP, I TOX,A l I PP, EP, I TOX, A PP, EP PP, EP PP, EP

W02 VE02 VEO1, VE02 VE02 VE02

1 I

1

I

I

PP, EP PP, EP TOX, A PP, EP

I

RUBIDIUM HYDROXIDE SOLUTION RUBIDIUM HYDROXIDE SOLUTION RUBIDIUM HYDROXIDE LITHIUM HYDROXIDE SOLUTION

1

8

LQ22

1

8

LQ7

PP, EP

8 8

LQ23 LQ22

PP, EP PP, EP

I

I

W02 I

Number of cones, blue Lights

Provisions concerning loading, unloading and carriage

Limited Carriage Equipment Ventilation quantities permitted required

I

Remarks

JN No. or [D No.

a 2679 2680 268 1 2681

Name and description

3.1.2 (2) LITHIUM HYDROXIDE SOLUTION LITHIUM HYDROXIDE CAESIUM HYDROXIDE SOLUTION CAESIUM HYDROXIDE

2682 2683 2684 2685 2686

2687 2688 2689 2690

SOLUTION 3-DIETHYLAMMOPROPYLAMINE N,N-DIETHYLETHYLENEDIAMINE 2-DIETHYLAMINO-ETHANOL DICYCLOHEXYL-AMMONIUM NITRITE 1-BROMO-3-CHLOROPROPAM GLYCEROL alphaMONOCHLOROHYDRIN N,n-BUTYLIMIDAZOLE

2691 PHOSPHORUS PENTABROMID 2692 BORON TRIBROMIDE 2693 BISULPHITES, AQUEOUS - SOLUTION, N.O.S. 2698 TETRAHYDROPHTHALIC ANHYDRIDES with more than of maleic anhydride 0.05% 2699 TRIFLUOROACETIC ACID 2705 1-PENTOL 2707 DIMETHYLDIOXANES 2707 DIMETHYLDIOXANES 2709 BUTYLBENZENES 2710 DIPROPYL KETONE -

Packing group

2.1.1.3 0 111

Labels

Special provisions

Limited Carriag~ Equipment Ventilation required quantities permitte

8.1.5 (9) PP, EP PP, EP PP, EP PP, EP PP, EP 'P, EP, EX TOX, A 'P, EP, EX A 'P, EP, EX A 'P, EP, E3

PP, EP, TOX, A PP, EP, TOX, A PP, EP PP, EP PP, EP PP, EP

PP, EX, A PP, EX, A r

,

PP, EX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

JN No. or [DNo.

Classili cation Code

acking PUP

Labels

Special provisions

Limited quantities

-

1.1.1.3

5.2.2

3.3

2713 2714 2715 2716 1,4-BUTYNEDIOL 2717 CAMPHOR, synthetic 2719 - BARIUM BROMATE 2720 CHROMIUM NITRATE

6.1 111 111 4.1 4.1 111 111 6.1 4.1 I11 5.1+6.1 I1 111 5.1

3.4.6 (7) LQ9 LQ9 LQ9 LQ9 LQ9 LQll LQ12

Name and description

111

2721 2722

Class

00 (6) 802

I1 ILI

5.1 5.1

LQl l LQ12

I1 111

5.1 5.1

LQll LQ12

Provisions concerning Equipment Ventilation loading, unloading and required carriage

8.1.5

0 PP, EP PP PP PP, EP PP PP PP

Number of cones, blue lights

Remarks

7.1.5

(12) 0 0 0 0 0 2 0

C002 and L004 apply only when this substance is carried in bulk or without packaging C002 and L004 apply only when this substance is carried in bulk or without packaging

2723 2724

MAGNESIUM CHLORATE MANGANESE NITRATE

2725

NICKEL NITRATE

LQ12

2726 2727 2728

NICKEL NITRITE THALLIUM NITRATE ZIRCONIUM NITRATE

LQ12 LQ18 LQl2

PP PP, EP PP

2729

HEXACHLOROBENZENE

LQ9

PP, EP

C002 and L004 apply only when this substance is carried in bulk or without packaging C002 and L004 apply only when this substance is carried in bulk or without packaging

C002 and L004 apply only when this substance is carried in bulk or without packaging

m No. Name and description

or D No.

1 I Class

0 1730

NITROANISOLES, LIQUID

Classifilacking cation group

6.1 l

I

NITROBROMOBENZENES, 1 6 . 1 1 T1 LIQUID 1 3 1FC !733 AMINES, FLAMMABLE, CORROSNE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 3 ,733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 3 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, - CORROSIVE, N.O.S. 2734 AMINES, LIQUID, CORROSIVE, 1 8 1 CF1 FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE. FLAMMABLE. 1732

I /

1 1

2734

FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSNE. FLAMMABLE. N.O.S. 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, - LIQUID, CORROSIVE, N.O.S. I 2735 AMINES. LIQUID. CORROSIVE, 1

- LIQUID, CORROSNE. N.O.S. 2735

2738

I

AMINES, LIQUID, CORROSIVE, 1 N.O.S. or POLYAMINES, N-BUTYLAMLINJ!

8 8

8

1

1 1

Labels

Special arovisions

Provisions concerning loading, unloading and carriage

Limited quantities

Number of cones, blue lights

Remarks

3.4.6 3.3 (6) 0 279 LQ7 802 802 LQ7

274 544

LQ3

274 544

LQ4

274 544

LQ7

274

LQO

274

LQ22

-l--r PP, EP, EX,

I

C7

LQO

C7

LQ22

C7

LQ7

VEOl

1

IPP, EP,

EX,^

-l---lPP, EP, EX,

LQ17 TOX, A

VEOl

VEOl

U N No or 1D No.

Name and description

1

Class

I

Classifi cation Code

( I ) 2739 BUTYRIC ANHYDRlDE 2740

I I

Limited Carriage Equipmenl Ventilation quantities permitted required

LQ7 LQO

-

LQl l

2741

11

gi;;

PP, EP PP, EP, E3 TOX, A PP

- more than 22% available chlorine 2742 2743 2744 2745 2746

TOX, A

CORROSIVE, FLAMMABLE, N.O.S. n-BUTYL CHLOROFORMATE CYCLOBUTYL CHLOROFORMATE CHLOROMETHYL CHLOROFORMATE PHENYL CHLOROFORMATE

L017

PP, EP, E3 TOX, A PP, EP, E3 TOX, A I PP,EP, TOX, A PP, EP, TOX, A PP, EP,

I

I

TC l

2747 2748 2749 2750

2751 2752

2753

2754

-

CHLOROFORMATE 2-ETHYLHEXYL CHLOROFORMATE TETRAMETHYLSILANE 1,3-DICHLOROPROPANOL-2

1 6.1 / TCl 3 6.1

I

I

2757

CARBAMATE PESTICIDE. SOLID, TOXIC

16.1

1 T7

2757

CARBAMATE PESTICIDE, SOLID, TOXIC

6.1

T7

I

I

VEo1, VE02 VEOl, W02 VEo1, W02 VEOl, VE02 W02 m02 W02 W02 VEOl W02

F1 T1

DIETHYLTHIOPHOSPHORYL ( 8 ( C3 CHLORIDE 1.2-EPOXY-31 3 I F 1 ETHOXYPROPANE 1 6.1 1 T1 N-ETHYLBENZYLTOLUIDINES, LIQUID T1 N-ETHYLTOLUIDINES 6.1

7.1.6 (1'4

PP, EP LQ7 LQ7

I

I

I

l

I

I

I

PP, EX, A

VEOl

PP, EP, TOX, A PP, EP, TOX, A PP. EP

W02

+ LQ17 LQO

T

PP, EP

m02

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

Class

-

Classifi cation Code

Labels

2.2

5.2.2

0

2757 SOLID, TOXIC

I

(-5)

2758

CARBAMATE PESTICIDE, 3 LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C CARBAMATE PESTICIDE. 1 3 LIQUID, FLAMMABLE, TOXIC,

FT2

3+6.1

FT2

3+6.1

61 802

6.1

61 648

-

-

-

2759

T7

2759

6.1

T7

6.1

Number of cones, blue lights

7.1.6 (10)

LQ3

PP, EP, EX, TOX,A

VEO1, VE02

2

LQ4

PP, EP, EX, TOX, A

VEOl, VE02

2

3.2.1 (8)

I

I

T7

Provisions concerning loading, unloading and carriage

8.1.5 (9) PP, EP

3.4.6 (7) LQ9

6.1

-

Limited Carriage Equipment Ventilation quantities permitted required

3.3 (6) 61 648 802 61 802

T7

I

2758

Special provisions

LQO

I

7.1.5

0 0

I

PP, EP

2

PP, EP

2

LQ9

PP, EP

0

LQ3

PP, EP, EX, TOX,A

VEO1, VE02

2

LQ4

PP, EP, EX, TOX, A

VEO1, VE02

2

LQO

PP, EP

TOXIC 2759 TOXIC 2760 2760 2761

ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 'C ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C ORGANOCHLORINE PESTICIDE, SOLID, TOXIC

2761

ORGANOCHLORINE PESTICIDE, SOLID, TOXIC

2761

ORGANOCHLORINE PESTICIDE, SOLID, TOXIC

3

FT2

-

3+6.1

648 802 61 802

I

FT2

3+6.1

61 802

6.1

T7

6.1

61 648

6.1

T7

6.1

3

l

PP, EP 802

2762

ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-

T7

1 648

FT2

LQ9

PP, EP

PP, EP, EX,

VEO1.

Remarks

3.2.1 (13)

JN No. or ID No.

Name and description

l l

Limited Carriage Equipment Ventilation quantities permitted required

Provisions concerning loading, unloading and carriage

7.1.6

(2) ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 'C TRIAZINE PESTICIDE, SOLID, TOXIC TRIAZINE PESTICIDE, SOLID, TOXIC TRIAZINE PESTICIDE, SOLID, TOXIC

0 LQ4

PP, EP, EX TOX, A PP, EP

+-+ PP, EP

TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 "C TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 "C THIOCARBAMATE PESTICIDE. SOLID, TOXIC

THIOCARBAMATE PESTICIDE. SOLID, TOXIC THIOCARBAMATE PESTICIDE. LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C THIOCARBAMATE PESTICIDE. LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C COPPER BASED PESTICIDE, SOLID, TOXIC

TOX, A

VEOI, VE02

TOX, A

VEOI, VE02

PP, EP

+ I

THIOCARBAMATE PESTICIDE. SOLID, TOXIC

VEOI, VE 02

I

LQ18

PP, EP PP, EP

I

LQO

PP, EP, EX TOX, A

VEOI, m02

TOX, A

VEo1, m02

I

PP, EP

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

(2) COPPER BASED PESTICIDE, SOLID, TOXIC COPPER BASED PESTICIDE, SOLID, TOXIC

Class

Classifi cation pacfing Code group

Provisions concerning loading, unloading and camage

Labels

2.2 (3a) 6.1

2.2 (3b) T7

6.1

T7

3

FT2

P PP, EP, EX, TOX, A

VEOI, W02

3

FT2

PP, EP, EX,

VEO1,

PP, EP

I

COPPER BASED PESTICIDE, LIQUID, FLAMMABLE. TOXIC. flash-point less than 23 "C COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC. flash-point less than 23 "C MERCURY BASED PESTICIDE. SOLID, TOXIC

l

I

LQ3

PP, EP

MERCURY BASED PESTICIDE. SOLID, TOXIC

LQl8

PP, EP

MERCURY BASED PESTICIDE, SOLID, TOXIC

LQ9

PP, EP

MERCURY BASED PESTICIDF. LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC

LQ3

PP, EP, EX, TOX, A

LQ4 LQo

PP, EP

SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC

LQ18

PP, EP

LQ9

PP, EP

SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC

111

1

1 6.1

1

802 61

VEOl, W02

I

I

I

!PP, EP, EX,( VEO1, I TOX, A I VE02

I

f

Number of cones, blue lights

Remarks

UN No.

Name and description

or ID No.

3.1.2 (2) SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC. flashpoint less than 23 "C SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 "C BIPYRIDILIUM PESTICIDE. SOLID, TOXIC

0 2780

2780

2781

Class

Classifi cation Code

2.2

2.2

00 3

FT2

3

FT2

T7

Special provisions

Limited quantities

3.3 (6) 61 802

03;;

3.4.6

LQ3

61 802

LQ4

61 648 802 61 648 802 61 648 802 61 802

LQO LQl8

2781

BIPYRIDILIUM PESTICIDE, SOLID, TOXIC

T7

2781

BIPYRIDILIUM PESTICIDE, SOLID, TOXIC

T7

2782

BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 'C BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC

FT2

T7

LQO

2783

ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC

T7

LQl8

2783

ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC

T7

LQ9

ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 "C

FT2

LQ3

2782 2783

FT2

:arriage Equipment Ventilation ermitted required

LQ9 LQ3

1

PP, EP, EX TOX, A

l I PP, EP, EX TOX, A PP, EP

t -r PP, EP

PP, EP

TOX, A LQ4 TOX, A

I PP, EP

3PP, EP

TOX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No or ID No.

111 2784

2785

Name and description

3.1.2 (2) ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 "C 4-THIAPENTANAL

P

Class

2.2

m 3

Xassifi cation Code

ackin BrouP

2.2

!.1.1.;

0 0 FT2

I1

Special provisions

Limited quantities

Equipment Ventilation required

8.1.5

0 P, EP, EX TOX, A

6.1 6.1

PP, EP,

2786

ORGANOTIN PESTICIDE, SOLID, TOXIC

2786

ORGANOTIN PESTICIDE, SOLID. TOXIC

6.1

PP, EP

2786

ORGANOTIN PESTICIDE, SOLID, TOXIC

6.1

PP, EP

2787

ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C ORGANOTIN COMPOUND, LIQUID, N.O.S.

P, EP, EX TOX, A

ORGANOTIN COMPOUND, LIQUID, N.O.S.

PP, EP, TOX, A

2788

ORGANOTIN COMPOUND, LIQUID, N.O.S.

PP, EP, TOX, A

2789

ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, more than 80% acid, by mass ACETIC ACID SOLUTION, not less than 50% but not more than 80% acid, by mass

P, EP, EX A

P

2787

2788 2788

-

2790

P, EP, EX TOX, A PP, EP, TOX, A

VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

JN No.

or ID No.

Classifipacking cation Code

Special provisions

Name and description

Class

3.1.2 (2) ACETIC ACID SOLUTION, more than 10% and less than 50% acid, by mass FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to selfheating

2.2 (3a) 8

2.2 (3b) C3

2.1.1.3 (4) 111

5.2.2 (5) 8

3.3 (6) 597 647

4.2

S4

I11

4.2

592

295 598 295 598

I

BATTERIES, WET, FILLED WITH ACID, electric storage BATTERIES, WET. FILLED WITH ALKALI, electric storage SULPHURIC ACID with not more than 51% acid or BATTERY

I

Labels

8.1.5 PP, EP

Provisions concerning loading, unloading and carriage

7.1.6

8

1

C11

I

8

1

8

1

C11

I

8

Cl

I1

8

PP, EP

8 8 DICHLORIDE PHENYLPHOSPHORUS THIODICHLORIDE

8

i ' T PP, EP PP, EP

SPILLABLE, electric storage DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. DYE, LIQUID, CORROSIVE, LIQUID, CORROSIVE, N.O.S. DYE, LIQUID, CORROSIVE, N.O.S. O ~ D Y E INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. COPPER CHLORIDE GALLIUM LITHIUM HYDRIDE, FUSED SOLID LITHIUM NITRIDE

C9

8

I

I

1

PP, EP

T PP, EP

1

I I

8

I

I I

8 8 4.3

1

4.3

C9

1111

I

111 111 I1

C2 C10 W2

1

W2

I

I PP, EP

PP, EP PP, EP

I

I

Number of cones, blue lights

Remarks

7.1.5 (12) 0 >002applies only vhen this ubstance is carriec n bulk or without lackaging

I

1

8

+-

Limited Carriage Equipment Ventilation quantities permittec required

PP. EX. A l

VEOl

Name and description

3.1.2 (2) Magnetized material MERCURY rOXICLIQUID,ORGANIC, N.O.S.

Class

1

Classifi Packing cation Code gronp

Provisions concerning loading, unloading and carriage

Special provisions

2.1.1.3

0 NOT ! I11 I

N.O.S. TOXIC LIQUID, ORGANIC, N.O.S. TOXIC SOLID, ORGANIC, N.0.S

I

TOXIC SOLID. ORGANIC, N.0.S

I1

TOXIC SOLID, ORGANIC, N.0.S

111

NOT ! I N.O.S. WATER-REACTNE SOLID, N.O.S. WATER-REACTIVE SOLID, N.O.S. [NFECTIOUS SUBSTANCE. AFFECTING IWMANS INFECTIOUS SUBSTANCE, AFFECTING HUMANS, in refrigerated liquid nitrogen INFECTIOIJS SUBSTANCE, AFFECTING HUMANS (animal carcasses only)

Labels

PP,EP PP, EP, TOX, A

315 614 802 274 614 802 274 614 802 274 614 802 274 614 802 274 614 802 1 ADN 274

LQ17

I11

274

I

VE02

T

LQ7 LQO

T

LQ9

LQO I

LQl l

PP, EP, TOX, A

PP, EP

LQ18

I

X TOX, A

I

I1

T

I

VE02

Number of cones, blue lights

Remarks

UN No or ID No,

Name and description

2820 2821

3.1.2 (2) N-AMINOETHYL-PIPERAZINE AMMONIUM HYDROGENDIFLUORIDE SOLUTION AMMONIUM HYDROGENDIFLUORIDE SOLUTION AMMONlUM POLYSULPHIDE SOLUTION AMMONIUM POLYSULPHIDE SOLUTION AMYL ACID PHOSPHATE BUTYRIC ACID PHENOL SOLUTION

2821

PHENOL SOLUTION

-

ILL

2815 2817 2817 2818

2818

2819 -

2822

2823 2826

2829 2830 283 1 2834 2835 2837

2837

2838 2839

CROTONIC ACID, SOLID ETHYL CHLOROTHIOFORMATE CAPROIC ACID LITHIUM FERROSILICON 1,1,1-TRICHLOROETHANE PHOSPHOROUS ACID SODIUM ALUMINIUM HYDRIDE BISULPHATES, AQUEOUS SOLUTION BISULPHATES, AQUEOUS SOLUTION VINYL BUTYRATE, STABILIZED ALDOL

Class

:lassifi cation Code

2.2 -

2.2

8 8

C7 CT1

00

Labels

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

3.4.6 (7) LQ7 LQ22

8.1.5 (9) PP,EP PP. EP

3.2.1 (8) T

-8

CT1

8

CT1

--

4 m-p-tPP, EP

8

CT1

8 8 6.1

C3 C3 T1

.

,

LQ7 L017

I 1

6.1

T1

L07

1

6.1

T1

LQ17

I

PP, EP

-8 C4 8

CF1

T

I

PP,EP PP. EP. TOX, A I PP., EP., TOX,A I PP, EP, TOX, A PP, EP PP, EP, EX

I

I I

C3 W2 T1 C2 W2 C1

VEOl W02 TOX, A PP, EP PP, EX, A

+

VEOl

PP, EP

C1 F1

T1

LQ4

I

I PP, EX, A

VEOl

PP, EP, TOX, A

W02

F'rovisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

JN No. or [D No.

Name and description

Class

ClassifiPacking cation Code

Labels

Special provisions

1 1

Limited Carriage Equipment Ventilation quantities permittec required

8.1.S

111 2840 2841

2842 2844 2845

2846

2849

2850 2851 2852 2853

2854 2855 2856 2857

2858

(2) BUTYRALDOXIME DI-n-AMYLAMINE

FT1

111 111

3+6.1

YITROETHANE EALCIUM MANGANESE SILICON PYROPHORIC LIQUID, 3RGANIC. N.O.S. PYROPHORIC SOLID, ORGANIC, N.O.S. 3-CHLOROPROPANOL-l

2859 2861 2862 fused form

PP, EX, A 'P, EP, EX TOX, A PP, EX, A PP, EX, A

VEOl VEo1, VE02 VEOl VEOl

PP PP PP, EP, TOX, A PP, EX, A PP, EP

PROPYLENE TETRAMER BORON TRIFLUORIDE DIHYDRATE DIPICRYL SULPHIDE, WETTED with not less than 10% water, by mass MAGNESIUM FLUOROSILICATE AMMONIUM FLUOROSILICATI ZINC FLUOROSILICATE FLUOROSILICATES, N.O.S. REFRIGERATING MACHINES zontaining non-flammable, nontoxic gases or ammonia solutions [UN 2672) ZIRCONIUM. DRY. coiled wire. finished metal'sheets; strip (thinner than 254 microns but not thinner

7.1.6

0 (10)

PP PP, EP PP, EP PP, EP PP, EP 2

6A

4.1

F3

6.1 6.1 6.1

T5 T5 T5

2.2

PP

III

4.1

PP

I1 I1 111

6.1 6.1 6.1

PP, EP PP, EP PP, EP

m02 VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

Class

3.1.2 (2)

SODIUM AMMONIUM VANADATE POTASSIUM ME'I'AVANADATE HYDROXYLAMINE SULPHATE llTANIUM TRICHLORIDE MIXTURE UTANIUM TRICHLORIDE MIXTURE 4LUMINIUM BOROHYDRIDE 4LUMINIUM BOROHYDRIDE .- - .- 4NTIMONY POWDER DIBROMOCHLORO-PROPANES

Classifi. cation Code group

Labels

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

3.3 (6) 802

3.4.6 (7)

PP, EP

7.1.6

0

Number of cones, blue lights

7.1.5 (12)

2 2 0

I

I

LQ24

PP, EP

LQO LQO

PP, EX, A PP, EX, A

L

802 802

1 1

LQ7

DIBUTYLAMINOETHANOL

802

LQ7

FURFURYL ALCOHOL

802

1

1

I

LQ9 LQ17

802

L07

p p

CALCIUM HYPOCHLORITE, HYDRATED, or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, with not less than 5.5% 3ut not more than 16% water ZALCIUM HYPOCHLORITE, HYDRATED or CALCIUM HYPOCHLORITE HYDRATED MIXTURE, with not less than 5.5% ~ unot t more than 16% water

8.1.5 (9)

LQ18

DIBROMOCHLORO-PROPANES

HEXACHLOROPHERE RESORCINOL HTANIUM SPONGE 3RANULES or TITANIUM SPONGE POWDERS SELENIUM OXYCHLORIDE

3.2.1 (8)

Provisions concerning loading, unloading and carriage

I I

I

I I

T

I

I

PP,EP PP, EP, TOX. A PP, EP, TOX, A PP, EP, TOX, A PP,EP. TOX, A PP, EP PP, EP

LQ9 802

LQO

313 3l 4 322

LQl l

PP, EP, TOX, A PP

223 3l 3 3l 4

LQ12

PP

W01 VEOl

Remarks

JN No. or D No.

Name and description

Class

Classification Code

Labels

Special provisions

Provisions concerning Limited Carriage Equipment Ventilation loading, unloading and quantities permittec required carriage

Number of cones, blue lights

Remarks

1

3.1.2

(2) a 2881 METAL CATALYST. DRY

2881 2881 2900

- 4FFECTING ANIMALS only 2900

2900 2901

-

MFECTIOUS SUBSTANCE. AFFECTING ANIMALS only, in refrigerated liquid nitrogen INFECTIOUS SUBSTANCE. AFFECTING ANIMALS only (animal carcasses and wastes only) BROMINE CHLORIDE

PP, EP, TOX, A PP, EP, TOX, A

2902

PESTICIDE, LIQUID, TOXIC, N.O.S.

2902

PESTICIDE, LIQUID, TOXIC, N.O.S.

PP. EP.

2902

PESTICIDE, LIQUID, TOXIC, N.O.S.

PP, EP, TOX, A

2903

PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-poir not less than 23 "C PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-poir not less than 23 "C PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-poir not less than 23 'C CHLOROPHENOLATES, LIQUI or PHENOLATES, LIQUID

PP, EP, EX TOX, A

CHLOROPHENOLATES, SOLIC or PHENOLATES, SOLID

PP, EP

2903 2903 2904 2905

PP, EP, EX TOX, A PP. EP. EX PP, EP

P

* applies only to )henolates but not o chloro henolates

orNo' ID No.

2908 2909

2910

l

Name and description

MIXTURE with not less than 60% lactose, mannose, starch or calcium hydrogen phosphate RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING RADIOACTIVE MATERIAL, EXCEPTED PACKAGE ARTICLES MANUFACTURED FROM NATURAL URANNM or DEPLETED URANlUM or NATURAL THORIUM 1 RADIOACTIVE MATERIAL, 1 EXCEPTED PACKAGE LIMITED QUANTITY OF MATERIAL 1 RADIOACTIVE MATERIAL. 1 I EXCEPTED PACKAGE - ' 1 INSTRUMENTS or ARTICLES 1 RADIOACTIVE MATERIAL, 1

I

I 2912

1 RADIOACTIVEMATERIAL,

I1

Classifi Packing cation Code group

7

7

1

7

1

7

1 1

7

1

7

1 1

7

1

I /

SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-11). non fissile or fissile-excepted 2915 1 RADIOACTIVEMATERIAL, 1 I TYPE A PACKAGE, non-special I fonn, non fissile or fissile-excepted I 2916 1 RADIOACTIVE MATERIAL. 1 TYPE B(U) PACKAGE, non fissile

I

1

7

I

I I), non fissile or fissile-excepted 2913

Class

1 1

l 2911

1

I

TYPE B(M) PACKAGE, non fissile

Special provisions

Limited quantities

:arriage Equipment Ventilation ermitted required

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

3.1.2 (2) RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted CORROSIVE LIOUID. FLAMMABLE, K0.s. CORROSIVE LIQUID, FLAMMABLE, N.O.S. CORROSIVE SOLID. FLAMMABLE, N.O.S. CORROSIVE SOLID, FLAMMABLE, N.O.S. CORROSIVE LIQUID, TOXIC, N.O.S. CORROSNE LIOUID. . , TOXIC. N.O.S. CORROSIVE LIQUID, TOXIC, N.O.S. CORROSIVE SOLID. TOXIC. N.O.S. CORROSNE SOLID, TOXIC. N.O.S. CORROSNE SOLID, TOXIC, N.O.S. FLAMMABLE LIQUID. CORROSIVE, N.O:S. FLAMMABLE LIQUID, CORROSIVE, N.O.S. FLAMMABLE LIQUID, CORROSIVE, N.O.S. FLAMMABLE SOLID. CORROSIVE, ORGANIC, N.O.S. FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.

Class

ClassifiPacking cation Code

Labels

Special provisions

3.3 (6) 172 317 274 274 274 274 274 802 274 802 274 802 274 802 274 802 274 802 274 274 274 274 274 274 802

Limited Carriage Equipment Ventilation quantities permitted required

3.4.6 (7) LQO

3.2.1 (8)

8.1.5 (9) PP

7.1.6 (10)

PP, EP, EX,

VEOl

Provisions concerning loading, unloading and carriage

7.1.6 (11)

Number of cones, blue lights

Remarks

JN No. or [D No.

Name and description Code

3.1.2 (2) ( I ) 2926 FLAMMABLE SOLD, TOXIC, ORGANIC, N.O.S. 2927 ORGANIC, N.O.S.

2.2 (3a) 4.1

-

1

6.1

l

TCl

1

6.1

1

TC2

2929

1

6.1

1

6.1

1

6.1

TOXIC LIQUID. FLAMMABLE. ORGANIC;N.O:S. 2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 2931 VANADYL SULPHATE 2933 METHYL 2- CHLOROPROPIONATE 2934 ISOPROPYL 2- CHLOROPROPIONATE 2935 ETHYL 2CHLOROPROPIONATE 2936 THIOLACTIC ACID

1

TFl

1

TF3

1

TF3

1

274 802 274 3 L5 802 274 802 274 802 274 802 274 315 802 274 802 274 802 274 802 802

8.1.5

7.1.5

(12) 0

PP

PP, EP, TOX, A

VE02

PP, EP, TOX, A PP, EP

VE02

PP, EP 'P, EP, EX TOX, A 'P, EP, EX TOX, A PP, EP PP, EP

PP, EX, A

VEOl

T1

PP, EP, TOX, A PP, EP, TOX, A PP

VE02

6.1

2940

T1

I

3

Number of cones, blue lights

7.1.6

F1

3

111

Provisions concerning loading, unloading and carriage

0 (10)

VEOl

F1

6.1

3.3

0

PP, EX, A

3

FLUOROANILINES

Limited Carriage Equipment Ventilation quantities permitted required

VEOl

T5 F1

2937

294 1

Special provisions

PP, EP PP, EX, A

6.1 3

-

- PHOSPHINES)

group

2.2 (3b) FT1

TOXIC LIQUID, CORROSIVE, ORGANIC:N.O.S. 2928 TOXIC SOLID, CORROSIVE, - ORGANIC, N.O.S. 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.

2927

Labels

PP, EP, TOX, A

VE02

Remarks

Name and description

3.1.2 (2) 2-TRIFLUOROMETHYLANILINE TETRAHYDROFURFURYLAMINE N-METHYLBUTYLAMINE

Class

Classifi cation Code

2.2

2.2 -

00 6.1

3

T1 F1

Special

Limited quantities

Iarriage Equipment Ventilation ermitted required

3i2f

l l 8; PP, EP, TOX, A PP, EX, A

P

3

2-AMINO-5-DIETHYLAMINOPENTANE

FC

IPP, EP,

EX.^

7.1.6 (lo) VE02 VEOl VEOl

T1 F1

TOX, A PP, EX, A

T1

ANILINE SODIUM HYDROSULPHIDE. HYDRATED with not less than 25% water ot'crystallization MAGNESIUM GRANUI.FS. COATED, particle size not less t h a ~ 149 microns

5-tert-BUTYL-2.4.6-TRINITRO-m. XYLENE (MUSK XYLENE) BORON TRIFLUORIDE DIMETHYL ETHERATE THIOGLYCOL SULPllAMlC ACID MANEB. S'I'ABILIZED or STABILIZED against self-heating CASTOR BEANS or CASTOR MEAL or CASTOR POMACE or CASTOR FLAKE RADIOACTIVE MATERIAL. URANIUM HEXAFLUORIDE. FISSILE RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non fissile or fissile-excepted

C6 W2 SRI WFC

\PP, EP,

EX,^

TOX, A PP, EP

VEOl

Provisions concerning loading, unloading and carriage

UN No. or m NO.

Name and description

1

aass

XassiE, cation Packing Code group

2.2

( 1 ) 2983 2984

2985

0

2988

Special provisions

Limited Carriage Equipment Ventilation quantities permitted required

3.3

FT l

(6) 802

01

65

FC

274 548

PP, EP, EX

CF1

274 548

PP, EP, EX

C3

274 548 274 549

PP, EP

i PROPYLENE OXIDE MIXTURE, not more than 30% eth lene oxide HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary) CHLOROSILANES. I FLAMMABLE. C O ~ O S I V E . I

3

2986 2987

Labels

CORROSIVE, FLAMMABLE, N.O.S. CHLOROSILANES. CORROSIVE, N.O.S. CHLOROSILANES, WATERREACTIVE, FLAMMABLE,

1

8 4.3

WFC

PP, EP, EX TOX, A

PP, EP, EX

-

2989 2989 2990

F3 F3 M5 SELF-INFLATING CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE,

PP, EP, EX TOX, A

2991

CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE,

PP, EP, EX TOX, A

2991

CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C CARBAMATE PESTICIDE, LIQUID, TOXIC

2991

-

2992

TOX, A

1

l

6.1

TOX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.5 (12) 2

Remarks

JN No. or LD No.

-

111 2992

2992

Name and description

3.1.2 (2) ZARBAMATE PESTICIDE, LIQUID, TOXIC

ZARBAMATE PESTICIDE, LIQUID, TOXIC

Class

2.2

m 6.1 6.1

Iassifi, cation Code

Labels

2.2

5.2.2

0

(5)

T6

6.1

T6

6.1

P

2993 2993 2993 2994

2994 2994 2995

2995

2995

4RSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C 4RSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, Bash-point not less than 23 "C 4RSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, [ash-point not less than 23 "C 4RSENICAL PESTICIDE. LIQUID, TOXIC 4RSENICAL PESTICIDE, LIQUID, TOXIC

6.1 6.1

TF2

TF2

6.1+3

Special provisions

I l

Limited Carriage Equipment Ventilation quantities permitted required

3.3 (6) 61 648 802 61 648 802 61 802

TOX, A TOX, A

6.1+3

61 802

PP, EP, EX TOX, A

6.1+3

61 802

PP, EP, EX TOX, A

P

TF2 p

T6 TOX, A

T6

TOX, A

4RSENICAL PESTICIDE, LIQUID, TOXIC

T6

3RGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less :han 23 "C DRGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less :han 23 'C DRGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less :han 23 "C

TF2

TOX, A LQO

I

/PP, EP, EX TOX, A

P

TF2

TF2

LQ17

PP, EP, EX TOX, A PP, EP, EX TOX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

JN No. or [D No.

-

Name and description

3.1.2 (2) ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC

I I

0 2996

2996

I

Class

Classifi Packing cation Code group

Labels

2.2 (34 6.1

2.2 2.1.1.3 (3b) (4) I T6

5.2.2 (5) 6.1

I

ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC

I1

2996

ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC

6.1

T6

2997

TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 'C TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 "C TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 "C TRIAZINE PESTICIDE, LIQUID, TOXIC

6.1

TF2

6.1

TF2

6.1 6.1

TRIAZINE PESTICIDE, LIQUID, TOXIC

6.1

TRIAZINE PESTICIDE, LIQUID, TOXIC

6.1

2997 2997 2998 2998 2998 3005

1 1 3;:

8; PP, EP,

Number of cones, blue lights

7.1.5 (12) 2

2 TOX, A

PP, EP, EX TOX, A

2

61 802

PP, EP, EX TOX, A

2

TF2

61 802

PP, EP, EX TOX, A

0

T6

61 648 802 61 648 802 61 648 802 61 802

T6 T6

3005

1

3;; LQO

Provisions concerning loading, unloading and carriage

0

3005

3.3 (6) 61 648 802 61 648 802 61 648 802 61 802

Limited Carriage Equipment Ventilation quantities permitted required

PP, EP, TOX, A

THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, LIQUID, TOXIC, FLAMMABLE, flasll-point not less than 23 "C THIOCARBAMATE PESTICIDE, 1 6.1 LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

I11

Special provisions

TF2

I

2

TOX, A TOX, A TOX, A TOX, A

61 802

TOX, A

61 802

TOX, A

Remarks

Name and description

Class

:lassifi. cation Code

Labels

Special provisions

Limited Carriage Equipment quantities permitted required Ventilation

1 I

Provisions concerning loading, unloading and carriage

2.2

0

THIOCARBAMATE PESTICIDE, LIQUID, TOXIC

6.1

T6

I

T6

LQ17

T6

LQ7

1

I

I

1

1

PP, EP,

VE02

LIQUID, TOXIC Il5IOCARBAMATE PESTICIDE, LIQUID, TOXIC

6.1

TF2 LIQUID, TOXIC, FLAMMABLE, flash- oint not less than 23 "C COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C COPPER BASED PESI'ICIDE. LIQUID, TOXIC, FLAMMABLE,

TF2

1 6.1

TF2

PP, EP, EX,

VE01,

PP, EP, EX, TOX, A

VEO1, W02

PP, EP, EX,

-01,

1 LQ17

1 LQO

PP, EP, TOX, A

VE02

LQ17

PP, EP, TOX, A

W02

COPPER BASED PESTICIDE, LIQUID, TOXIC

6.1

T6

COPPER BASED PESTICIDE, LIQUID, TOXIC

6.1

T6

MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE,

VE02

T6 LIQUID, TOXIC

MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C MERCURY BASED PESTICIDE. LIQUID, TOXIC, FLAMMABLE,

PP,EP, TOX, A

TOX, A 6.1

l

6.1

TF2

TF2 TF2

I

LQo

I

I

PP, EP, EX, TOX, A

VEOl, VE02

PP, EP, EX,

VEOl,

PP, EP, EX, TOX, A

VEOl, VE02

1 LQ7

Number of cones, blue lights

I

ID No.

Class

I

Classifi. cation Code

Special provisions

Limited Carriage quantities permitted required

3.3

0 LIQUID, TOXIC

61 648 802 61 648 802 61 648 802 61 802

3012

MERCURY BASED PESTICIDE, LIQUID, TOXIC

6.1

T6

3012

MERCURY BASED PESTICIDE, LIQUID, TOXIC

6.1

T6

3013

StlSSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 'C SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE. flash--ooint not less than 23 'C SUBSTITUTEDNITROPHENOL PESTICIDE, LIQUID, TOXIC

6.1

TF2

6.1

TF2

61 802

6.1

TF2

61 802

6.1

T6

3014

SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC

6.1

T6

3014

SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC

6.1

T6

61 648 802 61 648 802 61 638 802 61 802

3013

3013

3014 I

I

3015

BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, I flash-point not less than 23 'C 3015 I BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

1

1

6.1

TF2

1 6.1 1 TF2

61 802

Ventilation

Provisions concerning u&oading and carriage

Number of cones, blue lights

Remarks

UN No.

or ID No.

Name and description

Class

'lassifiPackin1 cation Code pOup

3

2.2 2.1.1.2 (3b) (4) TF2 111

BIPYRIDILIUM PESTICIDE,

LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC

I

1 6.1

l

T6 T6

I 11

LIQUID, TOXIC

Labels

5.2.2 (-5)

6.1+3

Special provisions

33 3.4.6 (6) 0 61 LQ7 802

61 648 802 61 648 802 61 648 802 61 802

LQO LQ17

TOX, A

6.1

T6

I11

DRGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, tlash-point not less .han 23 "C DRGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C 3RGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less .han 23 "C ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC

6.1

TF2

I

6.1

TF2

11

61 802

LQ17

6.1

TF2

111

61 802

LQ7

6.1

T6

I

LQO

T6

I1

61 648 802 61 648 802 61 648 802 61 802

DRGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC

LQ7

PP, EP, TOX, A

LQO

PP, EP, EX, TOX, A

VEOI, W02

PP, EP, EX,

VEOl,

* I

6.1

T6 TF2

LIQUID, TOXIC, FLAMMABLE,

X TOX, A

BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC

PESTICIDE, LIQUID, TOXIC 111 I

Provisions concerning Loading, unloading and carriage

Limited Carriage Equipment Ventilation quantities permitted required

LQ17

I

/PP, EP, EX,^

I

VEO1,

I

TOX, A

TOX, A

LQ7 TOX, A

LQO

IOX* PP, EP, EX,

VEO1,

Number of cones, blue lights

Remarks

JN No. or [D No.

m 3019 3019 3020

-

Name and description

3.1.2

(2) 3RGANOTM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, 7ash-point not less than 23 "C 3RGANOTM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, Bash-point not less than 23 "C 3RGANOTIN PESTICIDE, LIQUID, TOXIC

3020

3RGANOTIN PESTICIDE, LIQUID, TOXIC

3020

3RGANOTIN PESTICIDE, LIQUID, TOXIC

3021

3021 3022

PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash-point less than 23 'C PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash-point less than 23 'C 1.2-BUTYLENE OXIDE.

Class

cation Code

2.2 2.2 f3a) W

6.1

TF2

'aeking group

Labels

Special provisions

!.1.1.3

5.2.2

3.3

a 0 (6) I1 6.1+3 61

Limited Carriage Equipment Ventilation quantities permitted required

7.1.6

(W LQ17

PP, EP, EX

802 6.1

TF2

T6

T6 T6

FT2

111

6.1+3

61 802 61 648 802 61 648 802 61 648 802 61 802

TOX, A LQO

I

I

I

I

1

F1

61 802

1

TF l

3024

3024

3025

COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 "C COUMARIN DERIVATlVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 "C COUMARIN DERIVATIVE PESIICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not les! than 23 "C

VE02

PP, EP, TOX, A

VE02

PP, EP, TOX, A

VE02

I

I

IPP,

EP, EX TOX, A

VEOl, VE02

PP, EX, A

VEOl

LQO

I

IPP, EP, EX

VEo1, VE02 VEOI,

TOX, A

VE02

I I

FT2

-'t I

FT2

TF2

VEo1, m02

+ LQ4

I

3023

VEOI, VE02

PP, EP, TOX, A

TOX, A l

FT2

I

VEO1, VE02

LQ4

I

I

IPP, EP, EX TOX, A

VEo1, VE02

PP, EP, EX TOX, A

VEo1, VE02

Provisions concerning loading, unloading and camage

Number of cones, blue lights

7.1.5 (12) 2

Remarks

UN No. or U]No.

Name and description

Class

:iassifi cation Code

2.2 (2) I (3a) 1 6.1 C'OUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE. flash-~ointnot less 11an 23 "C COUMARIN DERIVATIVE 1 6.1 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less :han 23 'C COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC

II

'ackin; group

Labels

Special provisions

Limited quantities

!.l.l.?

3.2.1

11

TF2

U1

1 I

0

0 TF2

,

Carriage Equipment ~ermittec required Ventilation

m;

PP. EP. EX,

T6

LQO

T6

LQ17

PESTICIDE, LIQUID, TOXIC

TOX, A -

T6

LQ7

T7

LQO

T7

LQl8

T7

LQ9

C11

LQO

PESTICIDE, LIQUID, TOXIC COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC

6.1

PESTICIDE, SOLID, TOXIC COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC

6.1

X

BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE SOLID, electric atora e ALUMINIUM PHOSPHIDE PESTICIDE

1 CYCLOIIEXYL MERCAPTAN 1 3 2-(2-A~OETHOXYIE'THANOLI 8

T7

I

F1 C7 F1 -

111 111 111 -

PP, EP, TOX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No.

or

Name and description

m NO.

(1) 3057

3.1.2 (2)

I

I TRIFLUOROACETYL

Packing BOUP

2.1.1.3

-@L

NITROGLYCERIN, SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerirl BEVERAGES. wit11

Limited Carriage Equipment quantities ~ermitte~ required

3.4.6

8.1.5

I1

LQ0

PP, EP, TOX, A PP, EX, A

II

LQ5

PP, EX, A

111

LQ7

PP, EX, A

I1

LQ22

PP, EP

LQ7

PP, EP

LQ1

PP

LQ17

'P, EP, E3 TOX, A

LQO

PP

LQ17

'P, EP, E3 TOX, A

more than 24% but not more than 70% alcohol by volume 3066 / PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATEI MATERIAL (including paint thinning and reducing compound) PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATEI MATERIAL (including paint thinning and reducing compound) ETHYLENE OXIDE AND DICHLORODIFLUOROMETHANE MIXTURE with not more than 12.5% ethylene oxide MERCAPTANS, LIQUID, TOXIC FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment VINYLPYIUDINES, STABILIZE1

3.2.1

1

nI

Provisions concerning Jentilation toading, unloading and carriage

0 00 LQ0

l CHLORIDE

3064

Special provisions

Number of cones, blue lights

Remarks

lNor

Class

Name and demription

OD No.

y 3077

ENVIRONMENTALLY

I HAZARDOUS SUBSTANCE, l STABILIZED

1 ISOCYANATES. TOXIC. FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION, HAZARDOUS SUBSTANCE, LIQUID, N.O.S. PERCHLORVL FLUORIDE

3083 3084 3084 3085 3085 3085 3086 3086 3087 3087

CORROSIVE SOLID, OXIDIZING, N.O.S. CORROSIVE SOLID, OXIDIZING, N.O.S. OXIDIZING SOLID, CORROSIVE, N.O.S. OXIDIZING SOLID, CORROSIVE. N.O.S. OXIDIZING SOLID, CORROSIVE, N.O.S. TOXIC SOLID, OXIDIZING, N.O.S. TOXIC SOLID. OXIDIZING. N.0.S. 1 OXIDIZING SOLID, TOXIC, N.O.S. 1 OXIDIZING SOLID. TOXIC.

I

I

Limited Carriage Equipment Ventilation quantities permitted required

0

9

3

6.1

Provisions concerning loading, unloading and carriage

7.1.6

2.2

4.3 3080

Special provisions

S50 802

LQll LQo

274 551 802

LQ17

274 601

LQ7

T

PP, EX, A PP, EP, EX TOX, A PP, EP, EX TOX, A PP

T

LQo 274

LQO

I

l

274

1

LQ23

I

274

PP, EP, TOX, A PP, EP

1

LQll

I

f

I

I

l

I

I

PP, EP

PP

I

274 802 2 74 802 2 74 802 274 802 274 802 274

LQO

PP, EP

LQ18

PP, EP

LQO

PP

LQll

PP

LQ12

PP

LQO

PP

VEOl VEo1, W02 VEOI, VEO2

Number of cones, blue lights

Remarks

UN No or UD No.

Name and description

Class

3.1.2

2.2 (3a) 4.2

(2) a 3088 SELF-HEATING SOLID, 3089 3089 3090

3091

3092 3093

3093

3094 3094

3095

3095

3096

3096

P

3097

3098

3098

ORGANIC, N.O.S. METAL POWDER FLAMMABLE, N.O.S. METAL POWDER, FLAMMABLE, N.O.S. LITHIUM BATTERIES

LITHIUM BATTERIES CONTAINED IN EQUIPMENT or LITHIUM BATTERIES PACKED WITH EQUIPMENT l -METHOXY-2-PROPANOL CORROSIVE LIQUID, OXIDIZING, N.O.S. CORROSIVE LIQUID, OXIDIZING, N.O.S. CORROSIVE LIQUID, WATERREACTIVE, N.O.S. CORROSIVE LIQUID, WATERIEACTIVE, N.O.S. CORROSIVE SOLID, SELFHEATING, N.O.S. CORROSIVE SOLID, SELFHEATING, N.O.S. CORROSIVE SOLID, WATERREACTIVE, N.O.S. CORROSIVE SOLID, WATERREACTIVE, N.O.S. FLAMMABLE SOLID, OXIDIZING, N.O.S. OXIDIZING LIQUID, CORROSIVE, N.O.S. OXIDIZING LIQUID, CORROSIVE, N.O.S.

4.1 -

:lassi& cation Code %ro"P

Limited quantities

Provisions concerning loading, unloading and carriage

Equipment Ventilation required

Number of cones, blue lights

Remarks

2.2 0

S2

F3

4.1

F3

9

M4

9

Special provisions

Labels

M4

P

3 F1 8 8

8

VEOl

CO1

PP, EP

C01

CWl

PP, EP

8

CWl

PP, EP

8

CS2

PP, EP

CS2

PP, EP

8 8

8

CW2

PP, EP

-

PP, EP

CW2

P

4.1

F0

5.1

OC l

I

5.118

5.1

-

OC 1

11

1

274

I

I

5.1+8

1

LQO

I

274

LQlO

I I

CARRIAGE PROHIBITED

PP, EP I

0 I

PP, EP

I

I

l

I

0

I

UN No or ID No,

-

111 3098

3099

3099

3099 3100 3101

-

Name and description

3.1.2 (2) OXIDIZING IJQUID, CORROSIVE, N.O.S. OXIDIZING LIQUID, TOXIC, N.O.S. OXIDIZING LIQUID, TOXIC, N.O.S. OXIDIZING LIQUID, TOXIC, N.O.S. OXIDIZING SOLID, SELFHEATING, N.O.S. ORGANIC PEROXIDE TYPE B, LIQUID

Class

Special provisions

tabeh

Limited quantities

3.2;

2.2

&

1

Number of cones, blue lights

asi;

I

5.11.6.1

1

274

1

LOO

I

PP, EP,

I

TOX, A

5.1

5.1 5.1

CARRIAGE PROHIBITED

5.2

PP,EX, A

VEO1

HAOI, HA10 HAOl, HA10

3 l

3

3 102

ORGANIC PEROXIDE TYPE B, SOLID

5.2

PP, EX, A

VEOl

3103

ORGANlC PEROXIDE TYPE C, LIQUID ORGANIC PEROXIDE TYPE C, SOLID ORGANIC PEROXIDE TYPE D. LIQUID ORGANIC PEROXIDE TYPE D, SOLID ORGANIC PEROXIDE TYPE E, LIQUID ORGAMC PEROXIDE TYPE E, SOLID ORGANIC PEROXIDE TYPE F, LIQUID ORGANIC PEROXIDE TYPE F, SOLID ORGANIC PEROXIDE TYPE B, LIQUID, TEWERATURE CONTROLLED

5.2

PP,EX, A

VEOl

0

5.2

PP,EX, A

VEOl

0

3 104

Remarks

PP, EP

5.1

5.1

Provisions concerning loading, unloading and carriage

Zarriage Equipment ermitted required

5.2 5.2

1 5.2

1

274 122

1

1

1

LQll

1

PP, EX, A

5.2 5.2

5.2

5.2

5.2

5.2

5.2

5.2

5.2+1

274 122 274 122 274 122 274 122

LQll

PP, EX,A

VEOl I

LQ16

PP,EX, A

LQll

PP,EX, A

LQO

PP,EX,A

0 I

I

I

I

VEOl I

I

I

I

I

VEOl

I

VEOl

I

0 I

I

I

0

I

I

I

I HAOI, I

l

l

3

UN No or ID No.

Special provisions

Name and description

Limited Carriage Equipment Ventilation quantities permitted required

-

,-, a 3112 ORGANIC PEROXIDE TYPE B,

3113

3114 3115

3116

3117

122

LOO

SOLID. TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE C. SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE D. SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE

- CONTROLLED 3 118 3119 3120 3121 3122

3 122

3 123

ORGANIC PEROXIDE TYPE E. SOLID. TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED OXIDIZING SOLID, WATERREACTTVE, N.O.S. TOXIC LIQUID, OXIDIZING, N.O.S. TOXIC LIQUID, OXIDIZING, N.O.S. TOXIC LIOUID. WATER-

8.1.5

7.1.6

PP, EX, A

VEOl

PP, EX, A

VEO l

PP, EX, A

VEOl

PP, EX, A

m01

PP, EX, A

VEOl

PP, EX, A

VEOl

PP, EX, A

VEO l

PP, EX, A

VEOl

PP, EX, A

VEO l

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

0 0

CARRIAGE PROHIBITED 6.1

TO1

I

6.1+5.1

6.1

TO1

I1

6.14-5.1

6.1

TW1

I

6.14-4.3

274 315 802 274 802 274 315 802

LQO

PP, EP, TOX, A

VE02

2

LQ17

PP, EP, TOX, A PP, EP, TOX, A

VE02

2

VEO2

2

LQO

Remarks

UN No or [D No.

Name and description

Class

ClassifiPacking cation Code

-

3.1.2

2.2 (3a) 6.1

2.2 2.1.1.3 (3b) (4) TW1 I1

(2) 0 3 123 TOXIC LIQUID, WATERREACTIVE, N.O.S. 3 124

TOXIC SOLID, SELF-HEATING, 1 6.1

- N.O.S. 3 l24

TOXIC SOLID, SELF-HEATING,

- N.O.S. 3125

3 125

3126 3 l26

3127

3128

3128

3129

3 129

3129

3130

3130

3130

3131 3131

TOXIC SOLID. WATERREACTIVE, N.O.S. TOXIC SOLID, WATERREACTIVE, N.O.S. SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. SELF-HEATING SOLID. OXIDIZING, N.0.S SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. WATER-EACTI~QUID, CORROSIVE, N.O.S. WATER-REACTIVE LIQUID, TOXIC, N.O.S. WA'ER-REACTIVE LIQUID, TOXIC, N.O.S. WATER-REACTIVE LIQUID, TOXIC, N.O.S. WATER-REACTIVE SOLID, CORROSIVE, N.O.S. WATER-REACTIVE SOLID, CORROSIVE, N.O.S.

1

TS

I

Special provisions

Limited Carriage Eqnipment Ventilation quantities permitted required

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

7.1.6 LQ17

PP, EP, TOX, A PP, EP

802 I

6.1

TS

II

6.1

TW2

I

6.1

TW2

IS

4.2

SC2

I1

4.2

SC2

US

4.2

SO

4.2

ST2

11

4.2+6.1

4.2

ST2

I11

4.2+6.1

4.3

WC1

1

4.3

WC1

11

1 6,1+4.3

1

802 274

f I

LQO

I

I

0 W02

PP, EP

1

CARRIAGE PROHIBITED

LQO

PP

2

LQO

PP

0

4.3+8

274 802 274 802 274

LQo

4.3+8

274

LQlO

PP, EP, EX, A PP, EP, EX, A PP, EP, EX, A PP, EP, EX, TOX,A PP, EP, EX, TOX,A PP, EP, EX, TOX, A PP, EP, EX, A PP, EP, EX, A

-

4.3

WCI

III

4.3+8

274

LQ13

4.3

WTl

1

4.3+6.1

LQO

4.3

WTl

I1

4.3+6.1

4.3

WT1

111

4.3+6.1

4.3

WC2

1

4.3+8

274 802 274 802 274 802 274

4.3

WC2

I1

4.3+8

274

LQlO LQ13 LQo LQll

VEOl

HA08

0

VE01

HA08

0

VEOl

HA08

0

VEOI, W02 VEOl, VE02 VEOI, W02 VEOl

HA08

2

HA08

2

HA08

0

HA08

0

HA08

0

WO1

UN No. or ID No.

Name and description

3.1.2 (2) 3131 WATER-REACTIVE SOLID. CORROSIVE, N.O.S. 3 132 WATER-REACTIVE SOLID, - FLAMMABLE, N.O.S. 3133 WATER-REACTIVE SOLID. OXIDIZING, N.O.S. 3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 3134 WATER-REACTWE SOLID. TOXIC, N.O.S. 3 134 WATER-REACTIVE SOLID, - TOXIC, N.O.S. 3135 WATER-REACTIVE SOLID. SELF-HEATING, N.O.S. 3 l36 TRIFLUOROMETKANE, - REFRIGERATED LIQUID 3137 OXIDIZING SOLID, - FLAMMABLE, N.O.S. 3138 ETHYLENE, ACETYLENE AND PROPYLENE MIXTURE, REFRIGEKATED LIQUID containing at least 71.5% ethylene with not more than 22.5% acetyIen and not yore than 6% propylene 3139 OXIDIZING LlOIJlD. N.O.S. 3139 3139 3140 ALKALOID SALTS, LIQUID, N.O.S. 3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, - N.O.S. 3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S.

-

0

Class

'lassifiPacking cation Code group

Special provisions

2.2

3.3 (6) 274

0 4.3

Provisions concerning Limited Carriage Equipment Ventilation loading, unloading and quantities permitted required carriage

3.4.6 (7) LQ12

4.3 4.3

-

WO 4.3+6.1

WT2

I1

4.3+6.1

4.3

WT2

111

4.3+6.1

4.3

WS

4.3

-

2

3A

274 802 274 802 274 802

LQo LQll LQ12

5.1 5. l 5.1 6.1

6.1

6.1

7.1.6

7.1.6

VEO l

HA08

PP, EP, EX, A PP, EP, EX, A PP, EP, EX, A

VEOl

HA08

2

VEOl

HA08

2

WO1

HA08

0

CARRIAGE PROHIBITED 2.2

593

LQ1

5.1 2

8.1.5 (9) ]PP, EP, EX,

CARRIAGE PROHIBITED

I

-

1 1

CARRIAGE PROHIBITED

WT2

4.3

3.2.1 (8)

Number of cones, blue lights

PP

0

CARRIAGE PROHIBITED

l PP, EX, A

274 6.1 6.1 6.1

274 802 43 274 802 43 274

LQ13 LQO

PP, EP, TOX, A

LQ17

PP, EP, TOX. A

LQ7

PP, EP, TOX, A

VEOl

Remarks

JN No or ID No.

Name and description

-

3.1.2 ( 1 ) (2) 3141 ANTIMONY COMPOWD, INORGANIC, LIQUID, N.O.S. 3142

3 142

3 l42 3l43 3143 3143

3 l44

3 l44 3 144 3 l45 3145

3 145

DISINFECTANT, LIQUID, TOXIC, N.O.S. DISINFECTANT, LIQUID, TOXIC, N.O.S. DISINFECTANT. LIOUID. TOXIC, N.O.S. DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. NICOTINE COMPOUND. LIOUID. N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) ALKYLPHENOLS., LIOUID. . N.O.S. (including CICIZ homologues) ALKYLPHENOLS, LIQUID, N.O.S. (including CpC12 homologues)

Special provisions

3.3

Limited Carriage Equipment Ventilation quantities 3ermitted required

3.4.6

3.2.1

8.1.5

Provisions concerning loading, unloading and carriage

7.1.6

Number of cones, blue lights

LQ7

PP, EP, TOX, A

VE02

7.1.5 (12) 0

LQO

VE02

2

VE02

2

LQO

PP, EP, TOX, A PP, EP, 'FOX, A PP, EP, TOX, A PP, EP

274 802

LQl8

PP, EP

274 802

LQ9

PP, EP

43 274 802 43 274 802 43 274 802 274

LQO

PP, EP, TOX, A

LQ17

PP, EP, TOX, A

LQ7

PP, EP, TOX. A

LQO

PP, EP

274

LQ22

PP, EP

274

LQ7

PP, EP

-.@. 0 L (8) 0 0 45 274 5 12 802 274 802 274 802 274 802 274 802

LQ17 LQ7

VE02

Remarks

UN No. or ZD No.

Name and description

3.1.2 (2) ( 1 ) 3146 ORGANOTIN COMPOUND. SOLID, N.O.S.

-

3 l46

3 l46

ORGANOTIN COMPOUND, SOLID, N.O.S. ORGANOTIN COMPOUND, SOLID, N.O.S.

3 147

DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, - SOLID. CORROSIVE, N.O.S. 3 147 DYE, SOLID. CORROSIVE, p

SOLID, CORROSIVE, N.O.S. -3 147

DYE, SOLID, CORROSIVE. N.O.S. or DYE INTERMEDIATE, - SOLID, CORROSIVE, N.O.S. 3148 WATER-REACTIVE LIQUID, - N.O.S. 3148 WATER-REACTIVE LIQUID, - N.O.S. 3148 WATER-REACTIVE LIQUID, - N.O.S. 3 149 HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE with acid(s), water and not more than 5% peroxyacetic acid, STABILIZED 3150 DEVICES, SMALL, HYDROCARBON GAS POWERED or HYDROCARBON GAS REFILLS FOR SMALL DEVICES with release device P

Class

2.2

:lassifi cation Code

2.2

6.1

T3

PP, EP

T3

-8

C10

-8

8

4.3 4.3

4.3

5.1

2

Limited Carriagt Equipment Ventilation quantities permitte' required

T3

-6.1

Special provisions

8.1.5 (9) PP, EP

(313) 6.1

Labels

PP, EP PP, EP

C10

PP, EP

Cl0

PP, EP

W1

PP, EX, A

W1

PP, EX, A

W1

PP, EX, A

P

OC l

PP, EP

6F

PP, EX, A

Provisions concerning loading, ualoading and carriage

Number of cones, bfne lights

Remarks

.AY No.

or a)No.

Name and description

3.1.2

(2) n 3151 POLYHALOGENATED

3152

3 153 3154 3155 3156

BIPHENYLS, LIQUID or POLYHALOGENATED TERPIOENYLS, LIQUID POLYHALOGENATED BIPHENYLS, SOLID or POLYHALOGENATED TERPHENYLS, SOLID PERFLUORO(METHYL VINYL ETHER) PERFLUORO(ETHYL VINYL ETHER) PENTACHLOROPHENOL COMPRESSED GAS,

- OXIDIZING, N.O.S. 3157 3158

3159 3160

3 161

P

3162

3163 3164

3 l65

LIQUEFED GAS, OXIDIZING, N.O.S. GAS, REFRIGERATED LIQUID, N.O.S.

Class

Classifi. cation Code

Special provisions

Number of cones, blue lights

2.2

2.2

3.3

7.1.5 (12) 0

(3b) m M2 9

P

9

2 2 6.1 2 2 P

2

1,1,1,2*TETRAnUOROETWANE 2 [REFRIGERANTGAS R 134a) LIQUEFIED GAS, TOXIC. FLAMMABLE,N.O.S. LIQUEFIED GAS, FLAMMABLE N.O.S. LIQUEFIED GAS, TOXIC, N.O.S. LIQUEFIED GAS, N.O.S. ARTICLES, PRESSURIZED, PNEUMATIC or HYDRAULIC [containing non-flammable gas) AIRCRAFT HYDRAULIC POWER UNIT FUEL TANK [containing a mixture of anhydrous hydrazine and methylhydrazine) :M86 fuel)

M2

(6)

203 305 802 203 305 802

2F

2F

T2

10

20

3A

2A

I

2 2 2

2TF

2F

2T

2 2A 2

3

6A

FTC

LQo

I

I

IPP, EP, EXA I TOX,A PP,EX,A

I

I

I

I

I

VEO1, VE02 VEOl

I I I

I

I

Remarks

UN No. or

Name and description

Class

Zlassifi cation Code

3.1.2

2.2 (3a) 9

0

ID No.

(2) Zngine, internal combustion or iehicle, flatnmable gas powered or iehicle, flammable liquid powered

2

>AS SAMPLE, NON'RESSURIZED, FLAMMABLE, V.O.S., not refrigerated liquid >AS SAMPLE, NON3RESSURIZED, TOXIC, XAMMABLE, N.O.S., not

2

2.2 M1 1

Limited Carriage Equipment quantities permittec required Ventilation

3.4.6

7.1.6 0 00 ( O ADN 10) NOT IUBJECT

lot refrigerated liquid

4LUMINIUM SMELTING BYPRODUCTS or ALUMINIUM KEMELTING BY-PRODUCTS 4LUMINIUM SMELTING BYPRODUCTS or ALUMINIUM WMELTCNG BY-PRODUCTS

7F

LQO

-

Remarks

7.1.5

3.2.1

(12)

(13)

' 7

7TF

LQO

2

7T

LQO

1 I

4.3

W2

LQll

PP, EX, A

VEOl

I

4.3

W2

LQ12

PP, EX, A

VEOl,

PP, EP, EX,

VEO1,

I

I

I PP. EP. I VE02

1 1

Battery-powered vehicle or Battery,owered equipment

TOXINS, EXTRACTED FROM JVING SOURCES, LIQUID, V.O.S. TOXINS, EXTRACTED FROM JVING SOURCES, LIQUID, V.O.S. TOXINS, EXTRACTED FROM ,WING SOURCES, LIQUID, V.O.S. rITANlUM DISULPHIDE

8.1.5

Number of cones, blue lights

-

.efiigerated liquid

>AS SAMPLE, NON?RESSURIZED. TOXIC, N.O.S..

3.2.1

Provisions concerning loading, unloading and carriage

9

M11

6.1

T1

6.1

T1

1 NOT SUBJECT TO ADN

TOX, A 6.1

1

4.2

Tl

PP, EP, TOX, A

VE03, L003, HA07, INOI, IN02 and IN03 apply only when this substance is carrie' in bulk or without packaging

UN No. or U)No.

(1) 3 175

3175

3 176 3 176

3 178 3 178 3 179 3 179 3180 3180

Name and description

Labels

3.1.2 (2) SOLIDS or mixtures of solids (such as preparations and wastes) CONTAINING FLAMMABLE LIQUID, N.O.S. having a flashpoint up to 60°C

5.2.2

SOLIDS CONTAINING FLAMMABLE LIQUID, MOLTEN, having a flash-point up to 60°C (DIALKYL-(Cj2-Ci8)DIMETHYLAMMONWM and 2-PROPANOL) FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. FLAMMABLE SOLID, INORGANIC, N.O.S. FLAMMABLE SOLID, I INORGANIC, N.O.S. [ FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. COMPOUNDS, FLAMMABLE, COMPOUNDS, FLAMMABLE, N.O.S.

Special provisions

Limited quantities

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

(5)

4.1 1 ~ 0 apply 2 only when this substance is carriec in bulk or without ackaging

-b IN02 apply only when this substance is carriec in bulk or without packaging

0

I

274

1

LOO

UN No. or ID No.

(1) 3 182 3182 3 183 3 183

3 184

3 184 3 185 3185

3 186

3 186 3 l87 3 187

3 188

Name and description

Class

3.1.2 (2) METAL HYDRIDES, I FLAMMABLE, N.O.S. f METAL lCYDRIDES, 1 FLAMMABLE, N.O.S. 1 SELF-HEATING LIQUID, 1 ORGANIC, N.O.S. SELF-HEATING LIQUID, ORGANIC, N.O.S. SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. SELF-HEATING LIQUID, I CORROSIVE, ORGANIC, N.O.S. I 1 SELF-HEATING LlOlllD. 1 CORROSIVE, ORG.~NIC(N.O.S. SELF-HEATING LIQUID, INORGANIC, N.O.S. SELF-HEATING LIQUID, INORGANIC, N.O.S. SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. SELF-HEATING LIOUID. TOXIC. INORGANIC, N.O.S: ' 1 SELF-HEATING LIQUID, 1

2.2 (3a) 4.1

I

I

1

Classiflcation Code group

Labels

2.2 12.1.1.3 (3b) 1 (4) F3 I I1

5.2.2

4.1

1

F3

1

111

4.1

4.2

1

S1

1

I1

4.2

3.3 (6) 274 554 274 554 274

(5) 4.1

4.2

S1

111

4.2

274

4.2

ST1

I1

4.2+6.1

4.2

ST1

I11

4.2t-6.1

SCl

I1

4.2+8

274 802 274 802 274

III

4.2+8

274

3 190

1 SELF-HEATING SOLID,

I INORGANIC, N.O.S.

4.2 4.2

I

1

SC1

I

4.2

S3

11

4.2

274

4.2

S3

111

4.2

274

4.2

ST3

I1

4.2+6.1

4.2

ST3

111

4.2+6.1

I1

4.2+8

274 802 274 802 274

4.2+8

274

4.2

274 555 274 555 274

4.2

1

SC3

I

4.2

1

1

Ventilation

4.2

1

S4

1

11

4.2

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

, , i;

I

HEATING, N.O.S.

I HEATING, N.O.S.

Special provisions

L00

1

LQ0

I

1

1

I

1

PP. EP. TOX, A PP, EP, TOX, A PP, EP

7 PP, EP

Remarks

,,

3.2.1

,

UN No. or O) No.

Classifi

Packing Code w".P

Name and descriation

(2) SELF-HEATING SOLID, INORGANIC, N.O.S. SELF-HEATING SOLID, TOXIC, [NORGANIC, N.O.S.

1 1

Special provisions

Provisions concerning loading, unloading and carriage

Limited Carriage Equipment quantities permitted required

2.1.1.3 (3a) I (3b) (4) 4.2 [ S4 I11 P

I1

111

[NORGANIC, N.O.S. SELF-mATING SOLID.

1

4.2

I SC4

I1

I11

CORROSIVE, INORGANIC, N.O.S. PYROPHORIC LIQUID, [NORGANIC, N.O.S. PYROPHORIC SOLID. INORGANIC, N.O.S. ALKALINE EARTH METAL ALCOHOLATES, N.O.S. ALKALINE EARTH METAL ALCOHOLATES, N.O.S. ALKALI METAL ALCOHOLATES, SELFHEATING, CORROSIVE, N.O.S. ALKALI METAL ALCOHOLATES, SELFHEATING, CORROSIVE, N.O.S. METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. METALLIC SUBSTANCE, WATER-REACTIVE, SELFHEATING, N.O.S.

I

I 4.2

S4

4.2

S4

4.2

SC4

4.2

SC4

4.3

W2

4.3

W2

4.3 4.3

W2 WS

LQll

PP, EX, A I

I

I

l

LQ12 LQO

VEOl I

PP,EX,A

VEOl I

PP, EX, A

VEOl

No. or ID No.

I

Classifi, eation Code

Name and deacriotion

2.2

(1) f (2) I 3209 1 METALLIC SUBSTANCE, 1 I WATER-REACTIVE, SELFI HEATING, N.O.S. 3209 1 METALLIC SUBSTANCE, 1 I WATER-REACTIVE, SELF- I I HEATING, N.O.S. 3210 1 CHLORATES, INORGANIC, 1 AQUEOUS SOLUTION, N.O.S. 3210 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 321 1 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 32 1l PERCHLORATES, INORGANIC, I AQUEOUS SOLUTION, N.O.S. I 3212 1 HYPOCHLORITES, INORGANIC.I N.O.S.

(3a) 4.3

I

I

4.3 5.1

5.1

(3P) WS

WS

01

01

5.1

01

5.1

01

5.1

02

01 AQUEOUS SOLUTION, N.O.S. 01 AQUEOUS SOLUTION, N.O.S. 01

INORGANIC. AQUEOUS SOLUTION, N.OS. 3215 1 PERSULPHATES, INORGANIC, I N.O.S. 3216 1 PERSULPHAES. INORGANIC. AQUEOUS SOLUTION, N.O.S. ' 3218 1 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

I

I

I

3218

NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

I

5.1

02

1

5.1

01

1

5.1

01

5.1

01

I

I

01

01

AQUEOUS SOLUTION, N.O.S.

Number of cones, blue lights

Remarks

UN No. or ID No.

Classifi. Name and description

Labels

Special provisions

5.2.2

3.3

Code

3.1.2 (2) PENTAFLUOKOETHANE 'REFRIGERANT GAS R 125 SELF-REACTIVE LIQUID rYPE B SELF-REACTIVE SOLID TYPE BI

2.2 Qa)

2

1 1 I

2.2 (3b) 2A

I

4.1

1

SR1

SELF-REACTIVE LIQUID

4.1+1 4.1 4.1

SELF-REACTIVE LIQUID

4.1

SELF-REACTIVE SOLID TYPE D

4.1

1 4.1 SELF-REACTIVE LIQUID rYPE E SELF-REACTIVE SOLID TYPE E 4.1

1

l

SELF-REACTTVE LIQUID

1

4.1

4.1

1

SRI

4.1

1

SKI

4.1

SRI

4.1

I

1

I

SELF-REACTIVE LIQUID rYPE B, TEhPEMTURE CONTROLLED SELF-REACTIVE SOLID rYPE B, TEMPEMTURE CONTROLLED SELF-REACTIVE LIQUID rYPE C, TEMPERATURE CONTROLLED SELF-REACTIW SOLID rYPE C, TEMPERATURE CONTROLLED

4.1

SR2

4.1

SR2

4.1

SR2

4.1

SW

Number of cones, blue lights

0

2.2

181 194 274 181 194 274 194 274 194 274 194 274 194 274 194 2 74 194 274 194 274 194 274 181 194 274 181 194 274 194 274

Provisions concerning loading, unloading and carriage

7.1.5

00 4.1+1

I

Limited Carriage Equipment Ventilation quantities permitted required

0

3

LQ16

PP

LQl1

PP

LQ16

PP

LQll

PP

LQ16

PP

LQll

PP

LQO

PP

Remarks

UN No. or ID No.

Name and description

3.1.2

(2) SELF-REACTIVE LIOUID

0 3235

- CONTROLLED 3236

SELF-REACTIVE SOLID rYPE D, TEMPERATURE - CONTROLLED 3237 SELF-REACTIVE LIOUID IYPE E, TEMPERATURE - CONTROLLED 3238 SELF-REACTIVE SOLID rYPE E, TEMPERATURE - CONTROLLED 3239 SELF-REACTIVE LIQUID IYPE F, TEMPERATURE - CONTROLLED 3240 SELF-REACTIVE SOLID TYPE E

3241 3242 3243

3244

2.2

2.2

00 4.1 P

4.1

4.1

4.1

SR2

Special provisions

!.1.1.3 (4)

Limited quantities

Equipment Ventilation required

5.2.2 (S)

4.1

SR2

sR2 SR2 SR2 SR2

AZODICARBONAMIDE

SRI

SOLIDS CONTAINING TOXIC LIQUID, N.O.S.

T9

PP, EP, TOX, A

SOLIDS CONTAMING

C10

PP, EP

- CORROSrVE LIQUID, N.O.S. GENETICALLY MODIFIED MICROORGANISMS or GENETICALLY MODIFIED - ORGANISMS 3245 GENETICALLY MODIFIED MICRO-ORGANISMS or GENETICALLY MODIFED ORGANISMS. hrefrigerated - liquid nitrogen 3246 METHANESULPHONYI. CHLORIDE 3245

:lassit7 cation Code

SR1

- 1,3-DIOL -

Class

M8

M8

TC 1

PP, EP, TOX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Special provisions

< 3247

3248

Name and description

SODIUM PEROXOBORATE.

8.1.5

3.2.1

3.4.6

l ANHYDROUS

7.1.6

LQl l

PP

LQo

PP, EP, EX, TOX,A

VEO1, VE02

LQ7

PP, EP, EX, TOX,A

VEOl, VE02

I

1 MEDICINE, LIQUID,

I

Limited Carriage Equipment Ventilation quantities permitted required

FLAMMABLE, TOXIC, N.O.S.

FLAMMABLE, TOXIC, N.O.S.

. LQ18

PP, EP

LQ9

PP, EP

LQO

VE02

LQO

PP, EP, TOX, A PP

LQO

PP, EX, A

VEOl

N.O.S.

N.O.S.

I

3250

1 CIILOROACETIC ACID.

MOLTEN ISOSORBIDE-5-MONONITRATE

325 1

l

3252

I DIFLUOROMETHANE

3255 1 tert-BUTYL IIYPOCHLORITE 3256 1 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flash-point above 60 "C, a! or above its flash- oint

8 4.2 4.2 3

C6 S1 SCl F2

LQ24 LQo

I11 I

I11

3

274 560

LQO

I I

I 1

T

PP,EP PP CARRIAGE PROHIBI PP,EX,A VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remark.,

UN No. or ID No.

0

Name and description

3.1.2 (2)

3257

ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 "C and below its flash-point :including molten metals, molten - salts, etc.j 3258 ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 "C

3259

\MINES. SO1.ID. CORROSIVE, V.O.S. or POLYAMINES, SOLID, - CORROSIVE, N.O.S. 3259 4MTNES, SOLID, CORROSNE, V.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. 3259 4MJNES, SOLID, CORROSIVE, V.O.S. or POLYAMINES, SOLID, - CORROSIVE, N.O.S. 3260 CORROSIVE SOLID, ACIDIC, - MORGANIC, N.O.S. 3260 CORROSIVE SOLID, ACIDIC, - [NORGANIC, N.O.S. 3260 CORROSNE SOLID, ACIDIC, [NORGANIC, N.O.S. 3261 CORROSIVE SOLID, ACIDIC, - DRGANIC, N.O.S. 3261 CORROSIVE SOLID, ACIDIC, - DRGANIC, N.O.S. 3261 CORROSNE SOLID, ACIDIC, - DRGANIC, N.O.S. 3262 CORROSIVE SOLID, BASIC, MORGANIC, N.O.S. 3262 CORROSIVE SOLID, BASIC, - MORGANIC, N.O.S. 3262 CORROSNE SOLID, BASIC, [NORGANIC, N.O.S. 3263 CORROSIVE SOLID, BASIC, 3RGANIC. N.O.S.

Class

Classifi, cation Code

Special provisions

Limited Carriage Equipment Ventilation quantities permittec required

3.3

0 274 580 643

8.1.5

7.1.6

0 (10) PP

274 580 643 274

PP, EP

274

PP, EP

274

PP, EP

274

PP, EP

274

PP, EP

274

PP, EP

274

PP, EP

274

PP, EP

274

PP, EP

274

PP, EP

274

PP, EP

274

PP, EP

274

PP, EP

PP

Provisions concerning loading, unloading and carriage

Number of cones, blue tights

Remarks

JN No. or

Name and description

U) No.

Class

ClassifiPacking cation Code

Labels

5.2.2

(2) CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. CORROSIVE LIOUID. ACIDIC. INORGANIC, N.O.S. CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. CORROSIVE LIO'IJID. ACIDIC. ORGANIC, N.O.S. CORROSlVE LIQUID, ACIDIC, ORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. CORROSIVE LIOUID. BASIC. INORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. CORROSIVE LIOUID. BASIC. ORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT

NITROCELLULOSE MEMBRANE FILTERS, with not more than 12.6% nitrogen, by dry mass

Special provisions

Provisions concerning Limited Carriage Equipment Ventilation loading, unloading and quantities permitted required carriage

8

3.3 (6) 274

LQ23

PP, EP

8

274

LQ24

PP, EP

8

274

8

274

8

274

8

2 74

8

274

8

274

(5)

PP, EP LQ7

PP, EP

274 274 PP, EP

274 274 274 274 280 289 236 236 237 286

LQo

PP, EP

Number of cones, blue Lights

Remarks

UN No. or ID No.

Name and description

3.1.2 (2) 3271 ETHERS, N.O.S. 3271 ETHERS, N.O.S. 3272 ESTERS, N.O.S.

-

0

3272 3273

ESTERS, N.O.S. NITRILES, FLAMMABLE,

- TOXIC, N.O.S. 3273

3274 3275

NITRILES, FLAMMABLE, TOXIC, N.O.S. ALCOHOLATES SOLUTION, N.O.S., in alcohol NITRlLES, TOXIC, FLAMMABLE, N.O.S.

NITRILES, TOXIC, - FLAMMABLE, N.O.S. 3276 NITRILES, TOXIC,. LIOUlD. N.O.S. 3275

3276

NITRILES, TOXIC, LIQUID,

Class

:lassifi cation Code

2.2

2.2

3 3

F1 F1

3

F1

PP, EX, A

VEOl

FT 1

'P, EP, EX

VEOl,

m m Fl 3 P

3 3 P

3 6.1

6.1

-

3277

CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S.

6.1 6.1

6.1

ORGANOPHOSPHOKUS COMPOUND, TOXIC, LIQUID, - N.O.S. 3278 OKGANOPWOSPHORUS COMPOUND, TOXIC, LIQIJID, - N.O.S.

6.1

3278

Equipment required

6.1

Ventilation

3.3 (a) 274

VEOl

TOX, A 'P, EP, EX

Tl

VEOI, W02 'P, EP, EX

PP, EP, TOX, A PP. EP.

TC 1 TOX, A

ORGANOPHOSPHOKUS COMPOUND, TOXIC, LIQUID, N.O.S.

3278

TF1

T1

-

NITRILES, TOXIC, LIQUID,

Limited quantities

TF1

6.1

- N.O.S.

3276

FC

T1

-

Special provisions

FT1

-

6. l

- N.O.S.

Labels

Tl

-

PP, EP, TOX, A

T1

PP, EP, TOX, A

T1

PP, EP, TOX, A

VEOl,

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

Class

2.2

(2) ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S.

2.2

-TF1

T3

METAL CARBONYLS. LIQUID. N.O.S. ORGANOMETALLIC COMPOUND, TOXIC, LIQUID, N.O.S. ORGANOMETALLIC COMPOUND, TOXIC, LIQUID, N.O.S. ORGANOMETALLIC COMPOUND, TOXIC, LIQUID, N.O.S. SELENIUM COMPOUM), SOLID, N.O.S.

Special provisions

Limited quantities

5.2.2

3.3

3.4.6

I1

6.1+3

I

6.1

-T3

I1

6.1

T3

nr

6.1

I

6.1

p p

METAL CARBONYLS, LIQUID, N.O.S.

2.1.1.3

Labels

(3b) 00 m (6) 0 I TF1 6.1+3 43 6.1 LQO

ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. ORGANOARSENIC COMPOUND, LIQUID, N.O.S. ORGANOARSENIC COMPOUND, LIQUID. N.O.S. p.p ORGANOARSENlC COMPOUND, LIQUID, N.O.S. METAL CARBONYLS. LIQUID. N.O.S.

Iassifi Packing cation Code group

T3

-T3

I1

6.1

T3

111

6.1

I

6.1

T3

T3

I1

T3

111

T5

I

--

6.1

274 315 802 43 274 802 274 315 802 274 802 274 802 274 315 562 802 274 562 802 274 562 802 274 562 802 274 562 802 274 562 802 274 563 802

Equipment Ventilation required

8.1.5

7.1.6

0 0 P, EP, EX VEOl, TOX, A

W02

LQ17

P, EP, EX TOX, A

VE01, VE02

LQO

PP, EP, TOX, A

VE02

LQ17

PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX, A

m02

LQ7 LQO

Provisions concerning loading, unloading and carriage

W02 a 0 2

LQ17

PP, EP, TOX, A

m02

LQ7

PP, EP, TOX, A

W02

LQO

PP, EP, TOX, A

VE02

LQ17

PP, EP, TOX, A

W02

LQ7

PP, EP, TOX, A

W02

LQO

PP, EP

Number of cones, blue lights

7.1.5

(12) 2

Remarks

-

JN No.

or CD No.

Name and description

Class

2.2

(2) SELENIUM C O M P O W , SOLID, N.O.S. SELENIUM COMPOUND, SOLID, N.O.S. TELLURIUM COMPOUND, N.O.S. TELLURIUM COMPOUND, N.O.S. TELLURIUM COMPOUND, N.O.S. VANADIUM COMPOUND, N.O.S. VANADIUM COMPOUND, N.O.S. VANADIUM COMPOUND, N.O.S.

'lassifiacking cation Code FOUP

2.2

:.1.1.3

&!.!L 0 0 6.1

6.1

6.1

Special provisions

Limited Uarriagt quantities lermittec

3.2.1

Equipment Ventilation required

8.1.5 (9)

T5

n

PP, EP

T5

III

PP, EP

P

T5

-6.1

Labels

PP, EP

T5

PP, EP

T5

PP, EP

T5

PP, EP

T5

PP, EP

T5

PP, EP

P

FTC CORKOSIVF.. N.O.S. FLAMMABLE L.IOIJII). 'fOXlC. CORROSIVE, N.O:S. TOXIC LIQUIII. INORGANIC. N.O.S. TOXIC LIQUID, INORGANIC, N.O.S. TOXIC LIQUID, INORGANIC, N.O.S. TOXIC SOLID, INORGANIC, N.O.S. TOXIC SOLID, INORGANIC, N.O.S.

FTC T4 T4

'P, EP, EX TOX, A 'P, EP, EX TOX, A PP, EP, TOX, A

PP,EP,

T4 T5

T5

-

TOX, A PP, EP PP, EP

Provisions concerning loading, unloading and carriage

Number of cones, blue ligbts

Remarks

UN No or ID No.

Name and description

3.1.2 (2) _(II 3288 TOXIC SOLID. INORGANIC. - N.O.S. 3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S.

3289 3290 3290

3291

3291

3292

3293

3294

3295 3295

TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. TOXIC SOLID, CORROSNE, INORGANIC, N.O.S. CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S. CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S., in refrigerated liquid nitrogen BATTERIES, CONTAINING SODIUM, or CELLS, CONTAINING SODIUM HYDRAZINE, AQUEOUS SOLUTION with not more than 37% hydrazine, by mass HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45% hydrogen cyanide HYDROCARBONS, LIQUID, N.O.S. HYDROCARBONS, LIQUID, N.O.S. (vapour pressure at 50 'C more than l l0 kPa)

Class

31assifi cation Code

2.2

2.2

00

Labels

Special provisions

5.2.2

3.3

T5

6.1

TC3

6.1+8

6.1

TC3

6.1+8

6.1

TC4

6.1+8

6. I

6.2

6.2

4.3 6.1

TC4

I3

-

6.1

6.1+8 6.2

565 802

W3

4.3

239 295

T4

6.1

566 802

-

TF1

F1

F1

6.1+3

Number of cones, blue lights

7.1.5

274 802 274 315 802 274 802 274 802 274 802 565 802

6.2 +2.2

I3

Bovisions concerning loading, unloading and carriage

(12)

0 (6)

6.1

--

limited Carriagc Equipment Ventilation quantities permitte~ required

0 2 2

'XPP, EX, A

VEOl

PP, EX, A

VEOl

Remarks

Name and description

3.1.2

(2) HYDROCARBONS. LIOUID. . , N.O.S. (vapour pressure at 50 'C not more than l l 0 kPa) HYDROCARBONS. LIOUID. N.O.S. HEPTAFLUOROPROPANE (REFRIGERANT GAS R 227) ETHYLENE OXIDE AND CHLOROTETRAFLUOROETHANE MIXTURE with not more than 8.8% ethylene oxide ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than 7.9% ethylene oxide ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more than 5.6% ethylene oxide ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxidc CORROSIVE LIOUID. SELFHEATING, N.O.S. CORROSIVE LIQUID, SELFHEA'TING. N.O.S. 2-DIME'THYLAMINOE.I'IIYl. ACRYLATE COMPRESSED GAS, TOXIC, OXIDIZING. N.O.S. COMPRESSED GAS. TOXIC. CORROSIVE, N.O.S. COMPRtSSEL) GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S.

Special provisions

Limited quantities

Equipment Ventilation required

8.1.5

7.1.6

0 (10) PP, EX, A

VEOl

PP, EX, A

VEOl

PP PP

'P, EP, EX TOX, A PP, EP

PP, EP PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX, A 'P, EP, EX TOX, A

VEOl, m02

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

3.1.2 (2) COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC. N.O.S. LIQUEFIED GAS. I'OXIC. CORROSIVE, S.O.S. LIQIJEFIEL) GAS, TOXIC'. FLAMMABLE, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. ORGANIC PIGMENTS, SELFHEATING ORGANIC PIGMENTS, SELFHEATING PLASTICS MOULDING COMPOUND in dough, sheet or

Class

Special provisions

2.2 2.2 -

extruded rope form evolving flammable vapour

CHEMICAL SAMPLE, TOXIC CHEMICAL KIT or FIRST AID KIT CHEMICAL KIT or FIRST AID KIT

2-AMINO-4,6-DINITROPHENOI

2

2 2 2

Limited Carriage Equipment Ventilation quantities permitted required

8.1.5

00

OXIDIZING.

WETTED with not less than 20% water. bv mass

Jlassifi cation Code

0 PP, EP, TOX, A

l TOC

PP. EP.

2T0

2TC

-

TOX, A 'P, EP, EX TOX, A

2TOC

PP, EP, TOX, A

2TFC

30

-

PP, EX, A

3F

S2

S2

M3

T8

M1 1

M11

D

none

1

207

'P, EP, EX A PP, EP, TOX, A PP

VEO l

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

LlN No.

or ID No.

Class

Name and description

-

a 3318 3319

3320

3320

3321 3322

1

density less than 0.880 at 15 'C in water, with more than 50% ammonia NITROGLYCERIN MIXTURE, 1 4.1 DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin, by mass SODIUM BOROHYDRIDE AND 8 SODIUM HYDROXIDE SOLUTION, with not more than 12% sodium borohydride and not more than 40% sodium hydroxide by mass SODIUM BOROHYDRIDE AND ] 8 SODIUM HYDROXIDE SOLUTION, with not more than 12% sodium borohydride and not more than 40% sodium hydroxide by mass RADIOACTIVE MATERIAL, 1 7

U), non fissile or fissile-excepted I RADIOACTIVE MATERIAL, 1 LOW SPECIFIC ACTIVITY (LSA-

7

Special provisions

Limited quantities

3.3 (6) 23

3.4.6 LQO

PP, EP, TOX, A

272 274

LQO

PP

LQ22

PP, EP

LQ7

PP, EP

LQO

PP

LQO

PP

(7)

LQO

3323

TYPE C PACKAGE, non fissile or LQO

3324

3325

LOW SPECIFIC ACTIVITY (LSAIl), FISSILE 1 RADIOACTIVEMATERIAL. LOW SPECIFIC ACTIVITY, (LSA-III), FISSILE

7

LQO

:arriage Equipment ermitted required

3.2.1

/

Provisions concerning Jentilation loading, unloading and carriage

8.1.5

00

Number of cones, blue lights

Remarks

UN No, or ID No.

Name and description

3.1.2 (2) RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-11), FISSILE RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non-special form RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE RADIOACTIVE MATERIAL, W P E C PACKAGE, FISSILE RADIOACTIVE MATERIAL, rRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE RADIOACTIVE MATERIAL, I ' V E A PACKAGE, SPECIAL FORM, non fissile or fissile:xcepted RADIOACTIVE MATERIAL. IYPE A PACKAGE, SPECIAL FORM, FISSILE 4viation regulated liquid, n.0.s.

0 3326

3327

3328

3329

3330 3331

3332

3333

3334

3335

4viation regulated solid, n.0.s.

3336

MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE. LIQUID, FLAMMABLE, N.O.S.

Class

lassif cation Code

2.2

2.2

Labels

Special provisions

Limited quantities

Provisions concerning loading, unloading and carriage

3arriage Equipment ermitted required

00 7

7 7 7 7 7

7

7 9

I NOT SUBJECT '

) ADN

NOT SUBJECT TO ADN

Number of cones, blue lights

Remarks

UN No.

or ZD No.

Name and description

Class

3.1.2

0 3336

3336

3336

3337

3338

3339

MERCAPTANS. LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIOUID. . , FLAMMABLE. N.O.S. (vavour vressure at 50 T ' m o r e than1 116 k ~ a ) MERCAPTANS, LIQUID, 1 3 FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (vapour pressure at 50 "C not more than 110 kPa) MERCAPTANS, LIQUID, 3 FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, F L A W B L E , N.O.S. ( REFRIGERANT GAS R 404A 1 2 (Pentafluoroethane, 1,1,1trifluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 44% pentafluoroethane and 52% 1,1,1trifluoroethane) REFRIGERANT GAS R 407A 1 2 (Difluoromethane, pentafluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 20% difluoromethane and 40% pentafluoroethane) REFRIGERANT GAS R 407B 1 2 (Difluoromethane, pentafluoroethane, and 1,1,1,2tetratluoroethane zeotropic mixture with approximately 10% difluoromethane and 70%

Classifi cation Code

'ackin W"-P

2.2

0 L ! A F1 I1

F1

F1

Labels

Special wovisions

Limited quantities

:arriage ermittec

Squipmen required

Jentilation

5.2.2

3.3

3.4.6

3.2.1

8.1.5

7.1.6

Provisions concerning loadine. unioadine and

0(6) 0000 3

274 640C

LQ4

'P, EX, P

VEOl

I1

3

274 640D

LQ4

'P, EX, P

VEOl

111

3

274

LQ7

'P, EX, P

VEOl

2A

2.2

LQ I

PP

2A

2.2

LQ 1

PP

2A

2.2

LQ 1

PP

Number of cones, blue lights

Remarks

Name and description

(2) REFRIGERANT GAS R 407C [Difluoromethane, pentafluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 23%difluoromethane and 25% pentaflnoroethane) THIOUREA DIOXIDE THIOUREA DIOXIDE XANTHATES XANTHATES NITROGLYCERIN MIXTURE. DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass PENTAERYTHRITE TETRANITRATE MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN, by mass PHENOXYACETlC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 'C

Class

Classifi cation Code

2.2

2.2

Special provisions

Limited quantities

Provisions concerning loading, unloading and carriage

Iarriage Equipmenl ermitted required

0(3b) 2

2A

4.2 4.2 4.2 4.2 3

S2 S2 -

P

S2 S2 D

P

4.1

D

6.1

T7

=l

PP, EX, A

VEOl

PP, EP

T7 T7 FT2

1 PP, EP

TOX, A

Number of cones, blue lights

Remarks

UN No.

or ID No.

Name and description

Class

Classifi, Packing cation Code group

ll

3i;; PHENOXYACETIC ACID ):.2 DERIVATIVE PESTICIDE, LIQUID. FLAMMABLE, TOXIC. flash-point less than 23 "C P1IENOXYACETIC ACID 1 6.1 DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID. TOXIC. FLAMMABLE. f l ~ h - ~ o not h t less than 23 "C PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE,

'

PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE. LIQUID, TOXIC PYRETHROID PESTICIDE, SOLID, TOXIC

1

Labels

52;

FT2 12.\i.31 3+6.1

TF2

3.3 (6) 61 802 61 802 61 802

1

6.1

1

TF2

I

III

1

6.1+3

16.1

1

T6

I

I1

1

6.1

1

6.1

T6

I11

1 6 . 1 1 T 7 I

1

/

I

1,

I I1

6.1 )

1

,

6.1

PYRETHROID PESTICIDE, SOLID, TOXIC

6.1

T7

PYRETHROID PESTICIDE, SOLID, TOXIC

6.1

T7

111

6.1

3

FT2

I

3+6.1

PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C

Special provisions

6.1

61 802

Limited Carriage Equipment Ventilation quantities permitted required

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

I

UN No. or m NO.

Name and description

Class

3.1.2

2.2

( 1 ) (2) (3a) 3350 'YRETHROID PESTICIDE, 3 JOUID. FLAMMABLE. TOXIC. lash-pokt less than 23 'C 3351 'YRETHROID PESTICIDE, 16.1 JQUID, TOXIC, FLAMMABLE, lash-point not less than 23 "C 6.1 3351 'YRETHROID PESTICIDE, JOUID. . , TOXIC. FLAMMABLE. lash-point not less than 23 "C 3351 'YRETHROID PESTICIDE, 1 6.1 AQUID, TOXIC, FLAMMABLE, I 3352

?YRETHROID PESTICIDE,

3352

PYRETKROID PESTICIDE, LIQUID, TOXIC ?YRETHROID PESTICIDE, LIQUID, TOXIC 'NSECTICIDE GAS, FLAMMABLE, N.O.S. NSECTICIDE GAS, TOXIC, ?LAMMABLE, N.O.S. 3XYGEN GENERATOR, ZHEMICAL VITROGLYCERINMIXTURE, IESENSITIZED, LIQUZD, N.O.S. with not more than 30% litroglycerin, by mass REFRIGERATINGMACHINES :ontaining flammable, non-toxic, iquefied gas FUMIGATED UNIT Fibres, vegetable, dry

Classification pacWug Code

1

1

I

Special pro*idms

Limited Carriage Equipment Ventilation quantities permitted required

2.2 (3b)

2.1.1.3 (4)

5.2.2 (S)

3.3 (6)

7.1.6 (10)

FT2

I1

3+6.1

61 802

VEo1, W02

TF2

I

TF2

1

Labels

I

1

I1

6.1+3

1

6.1+3

61 802

TOX, A

VEOl, VE02

61 802

TOX, A

VEo1, W02

61 802

TOX, A

vEo1, W02

~

TF2

I I

111

1

I

6.1+3

1

1

-

PP, EP, TOX, A

VE02 W02

16.1

1

1 1

2

T6 1 1 1 1 [

1

1

2F

6.1

1 1 1

2.1

648 802 61 648 802 274

TOX, A VE02 TOX, A

* -wj-t-I

2

2TF

2.3+2.1

274

1

5.1

1

03

1

I1

1

5.1

1

284

1

3

1

D

I

I1

I

3

1

274

1

2.1

1

291

1 2 1 6F 1 9 4.1

M11 F1

302 NOT

LQO

I

PP, EX, A

VEOl

]PP, EP, EX TOX, A

VEo1, W02

I

Tq-t-PP, EX, A

4 PP, EX, A

m01

m01

Provisions concerning loading, unloading and carriage

I

Number of cones, blue lights

Remarks

UN No.

or ID No.

Name and description

Class

:lassifi Packing cation Code group

Special provisions

Limited Carriage Equipment Ventilation quantities permittec required

2.2

3.1.2

8.1.5

0 CHLOROSILANES, TOXIC,

6.1

PP, EP, TOX, A PP, EP, EX TOX, A

TC 1 TFC

CORROSIVE, FLAMMABLE, Dangerous goods in machinery or 1 9 iangerous goods in apparatus rRINITROPHENOL (PICRIC [ 4.1 4CID) WETTED with not less than

M1 1 D

rRINITROCHLOROBENZENE ZPICRYL CHLORIDE) WETTED with not less tl~an10% water, by

D

rRMITROTOLUENE (TNT), WETTED with not less than 10%

D

D with not less than 10% water, by mass I'RINITROBENZOIC ACID, WETTED with not less than 10% water, by mass SODIUM DMITRO-oCRESOLATE, WETTED with not

1 1

4.1

1 4.1

D DT D

less than 10% water. by mass 2-METHYLBIJT'ANAL not

F1 1

BIOLOGICAL SUBSTANCE, - .- -

- - - .-

ACETYLENE, SOLVENT FREE AMMONIUM NITRATE EMULSION, or SUSPENSION or GEL, intermediate for blasting

1

6.2

I4

1

2

2F 01

1 5.1

7.1.6

0 (10)

I

I

I

I

NOT SUBJECT TO ADN [see also 1 .3.l (b)]

VE02

m01 m02

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

7.1.5

0 2

2

Remarks

UN No or ILI No.

Name and description

-

(2) a 3375 AMMONIUM NITRATE

3376 3377

EMULSION, or SUSPENSION or GEL, intermediate for blasting explosives, solid 4-NITROPHENYLHYDRAZME, with not less than 30% water, by mass SODNM PERBORATE MONOHYDRATE

Class

'lassifi Packing :ation Code @-".P

Labels

Special provisions

2.2 2.2 2.1.1.3 5.2.2 @!L. 0 00 5.1

02

4.1

D

5.1

02

I1

-

5.1

3.3 (6) 309

Limited quantities

larriage Equipment Ventilation ermitted required

3.4.6

Provisions concerning loading. -, unloading and carriage

7.1.6

-

Number of cones, blue lights

LQO

7.1.5 (12) 0

0

0

I

4.1

LQO

1

111

5.1

LQ12

0

3378

;ODIUM CARBONATE 'EROXYHYDRATE

5.1

02

5.1

LQll

0

3378

;ODIUM CARBONATE 'EROXYHYDRATE

5.1

02

5.1

LQ12

0

3379

3380 3381

3382

-

DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. DESENSITIZED EXPLOSIVE, SOLID, N.O.S. TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 200 mum3 and saturated vapour concentration greater than or equal to 500 LCso TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LCso

3

D

LQO

-t-

PP, EX, A

VEO l

LQO W02

LQO TOX. A

W02

LQO TOX, A

Remarks

UN No or ID No.

Class

Name and description

2.2 -

'lassif cation Code

2.2

00

-

TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 mum3 and saturated vapour concentration greater than or equal to 500 LCso TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an inhalation toxicit lower than or equal to 200 mum and saturated vapour concentration greater than or equal to 500 LCso TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LCSO TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to 200 mum3 and saturated vapour concentration greater than ol equal to 500 LCSO TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/n13 and saturated vapour concentration greater than equal to 10 LC5o

6.1

TFI

6.1

TFl

Labels

Special provisions

Limited quantities

5.2.2

Zarriage Equipment emitted required

Ventilation

PP, EP, E3 TOX, A

7.1.6 (10) VEo1, W02

PP, EP, E3 TOX, A

VEo1, m02

PP, EP, TOX, A

m02

+ 1

0 6.1 +3

6.1 +3

6.1 +4.3

Y

08

I

6.1 +4.3

274

1

LQO

m02

TOX, A

VE02

6.1 +5.1

TOX, A

6.1 +5.1

PP, EP, TOX, A

m02

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No.

or LD No.

Name and description

Class

2.2

0

-

TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 mum3 and saturated vapour concentration - greater than or equal to 500 LCSO 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vamur concentration greater than or equal to 10 1.c~" 3391 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC 3392 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC 3393 ORGANOMETALLIC SUBSTANCE, SOLlD, PYROPHORIC, WATER - REACTIVE 3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER REACTIVE 3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATER REACTIVE 3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATER REACTIVE 3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATER REACTIVE 3389

6.1

6.1

4.2

'lassifi cation Code

2.2

Q!&

K 1 01 TC3

acking PUP

Labels

Special provisions

Limited quantities

1.1.1.3 (4) I

Equipment Ventilation required

8.1.5

0 PP, EP, TOX, A

rc10 TC3

I

PP, EP, TOX, A

S5

I

PP

S5

I

PP

SW

I

PP, EX, A

VEOl

SW

I

PP, EX, A

VEO l

W2

I

LQO

PP, EX, A

VEOl

W2

I1

LQll

PP, EX, A

VEOl

W2

111

LQ12

PP, EX, A

VEOl

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

Class

c 3396

ORGANOMETALLIC SUBSTANCE, SOLID, WATER

SUBSTANCE. SOLID. WATER REACTIVE, SELF-HEATING 3397 l ORGANOMETALLIC I SUBSTANCE, SOLID, WATER I REACTIVE, SELF-HEATING 3398 1 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER

provisions

2.2 (3a) 4.3

2.2 2.1.1.3 (3b) (4) WF2 I

5.2.2 (5) 4.3 +4.1

4.3

WF2

I1

4.3 +4.1

4.3

WF2

I11

4.3

3.3

l

-

l.

l

Limited imlted Carriage Equipmenl Ventilation quantities permitted required

3.4.6

3.2.1 (8)

8.1.5

7.1.6

PP, EX, A

VEOl

PP, EX, A

VEOl

PP, EX, A

VEOl

WS

PP, EX, A

VEOl

4.3

WS

PP, EX, A

VEOl

4.3

WS

PP, EX, A

VEOl

4.3

W1

PP, EX, A

VEOl

4.3

W1

PP, EX, A

VEOl

4.3

W1

PP, EX, A

VEO l

4.3

WF1

PP, EX, A

VEOl

4.3

WFl

PP, EX, A

VEOl

4.3

WFl

PP, EX, A

VEOl

SUBSTANCE, SOLID, WATER SUBSTANCE, SOLID, WATER ( REACTIVE, FLAMMABLE 3397 I ORGANOMETALLIC SUBSTANCE, SOLID, WATER

l .Special~

Classifi Packing cation Code group

(7) 274 274

LQll

0 0

I

SUBSTANCE, LIQUID, WATER REACTIVE l ORGANOMETALLIC 1 SUBSTANCE.,LIOUID. . , WATER REACTIVE ( ORGANOMETALLIC I SUBSTANCE, LIQUID, WATER REACTIVE, FLAMMABLE l ORGANOMETALLIC I SUBSTANCE. LIOUID. WATER REACTIVE, FLAMMABLE l ORGANOMETALLIC SUBSTANCE, LIQUID, WATER REACTIVE, FLAMMABLE

l 3398

l 3399

I 3399

1 3399

Provisions concerning loading,carriage unloading and

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

Class

Labels

Special provisions

Limited Carriage Equipment quantities permitted required Ventilation

5.2.2 (5)

SUBSTANCE. SOLID. SELFI HEATING 1 4.2 DRGANOMETALLIC I SUBSTANCE, SOLID, SELFHEATING ALKALI METAL AMALGAM. 1 4.3 SOLID ( 4.3 ALKALLNE EARTH METAL AMALGAM, SOLID POTASSIUM METAL ALLOYS, 1 4.3 SOLID

4.2 4.2

274

4.3

182 274 183 274

LQll

I

LOO

I

1

LQO

I

LQO

I

1

4.3

1 5.1

SOLUTION CHLORATE AND MAGNESIUM 1 5.1 I CHLORIDE MIXTURE SOLUTION CHLORATE AND MAGNESIUM 1 5.1 CHLORIDE MIXTURE SOLUTION LEAD PERCHLORATE SOLUTION 1 5.1 LEAD PERCHLORATE SOLUTION CHLORONITROBENZENES, LIQUID 4-CHLORO-0-TOLUIDINE HYDROCHLORIDE SOLUTION

l

I

4.3 BARIUM CHLORATE SOLUTION BARIUM CHLORATE

I

1

4.3

5.1 +6.1 5.1 +6.1 5.1 +6.1 5.1 +6.1 5.1

PP 1

l

I PP.. EX. A I

VEOl

I PP, EX, A I

VEOl

PP, EX, A

VEOl

,

I

I

LQO

PP, EX, A

VEOl

802

LQlO

VE02

802

LQ13

PP, EP, TOX, A PP, EP, TOX, A PP. EP, TOX, A

802

1

LQlO

I

I I

l

I

VE02 VE02

TOX, A

5.1 5.1 +6.1 5.1 +6.1 6.1 6.1

279 802 802

LQ17 LQ7

PP, EP

1

PP, EP, TOX, A

1

VE02

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No or ID No.

Name and description

3414

3.1.2 (2) beta-NAPHTHYLAMINE SOLUTION beta-NAPHTHYLAMINE SOLUTION FORMIC ACID with not less than 10Y0but not more than 85% acid by mass FORMIC ACID with not less than 5% but less than 10% acid by Inass POTASSIUM CYANIDE SOLUTION POTASSIUM CYANIDE SOLUTION POTASSIUM CYANIDE SOLUTION SODIUM CYANIDE SOLUTION

3414 3414

0 3411

341 1 3412 3412

3413 3413 3413

-

Limited Carriage Equipment Ventilation quantities permitted required

Special provisions

:G

802

1

3.4;

1

LQ7

I

1

LQ17

1

I

802

1

LQ7

I

I

802

LQ17

SODIUM CYANIDE SOLUTION

802

1

LQ7

I

3415

SODIUM FLUORIDE SOLUTION

802

1

LQ7

I

3416

CHLOROACETOPHENONE, LIQUID x n Y L BROMIDE, SOLID 2,4-TOLUYLENEDIAMINE SOLUTION BORON TRIFLUORIDE ACETIC ACID COMPLEX, SOLID BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, SOLID POTASSIUM HYDROGENDIFLUORIDE SOLUTION POTASSIUM HYDROGENDIFLUORIDE SOLUTION

802

1

LQ17

1

3420 3421 3421

I

802

SODIUM CYANIDE SOLUTION

3419

I

y LQO

3417 3418

I

PP. EP. T&,A PP, EP, TOX, A

-piqq-m 802

802

-

%S;"

3i2:

L017

I

/

I

I

1 1

I

LQ18 LQ7

802 802

LQ23

I

LQ23

I

PP, EP, TOX, A PP, EP, TOX,A PP, EP, TOX, A PP, EP, TOX, A PP, EP, TOX,A PP. EP, TOX,A PP, EP, TOX,A PP, EP, TOX, A PP, EP PP, EP, TOX, A PP, EP

I

PP, EP

I

PP, EP, TOX, A PP, EP, TOX, A

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

UN No. or ID No.

Name and description

3.1.2 (2)

0 3422

3424

POTASSIUM FLUORIDE SOLUTION rETRAMETHYLAMMONIUM HYDROXIDE, SOLID LMMONIUMDINITRO .o-CRESOLATE SOLUTION iMMONIUM DINITRO

3425 3426

BROMOACETIC ACID, SOLID ACRYLAMIDE SOLUTION

3423 3424

P

l l Class

Classifi cation Code

2.2 (34

2.2 (3W

3.4.6 (7)

6.1

T4

LQ7

Labels

Special provisions

Provisions concerning loading, unloading and carriage

Limited Carriage Equipment quantities permitted required

3.2.1 (8)

LQ24 I

L017

1

8.1.5 (9)

7.1.6 (10)

7.1.5 (12)

PP, EP, TOX, A PP, EP

VE02

0 0

I

I

1 PP. EP. I VE02

I

TOX,A PP, EP,

[

2 LQ7

3427

I

I

I

ISOCYANATE, SOLID

W02

l

I

PP, EP

LQ18

3428

I

PP, EP, TOX, A PP, EP

LQ9

-

I

I

I

LQ7

I

I PP. EP. I VE02

T1

LQ17

I

I

NITROBENZOTRI-FLUORIDES, 1 6.1 1 T2 SOLID POLYCHLORINATED 1 9 1 M 2 BIPHENYLS, SOLID

LQ18

3429 l

XYLENOLS, LIQUID

6.1 I

I

1

NITROCRESOLS, LIQUID

6.1

- --

LQ7

I

I

1

T2

LQ18

6.1 6.1

1

T2

LQl8 LQ9

PP, EP PP, EP

T2

LQ18

PP, EP

T2

LQ9

PP, EP

I

1 T2

6.1

T2 I

6.1 I

l

6.1

VE02

PP, EP

6.1

I

JITRILES, TOXIC, SOLID, N.O.S.

T1

( 1 I

I

LQ25

l

7

UTRILES, TOXIC, SOLID, N.O.S.

I

T&,A PP, EP, TOX, A PP, EP

PP, EP, TOX, A PP, EP

l

HEXAFLUOROACETONE 1 HYDRATE. I . -- . SOLID - ---CHLOROCRESOLS, SOLID ( alaha-METHYLBENZYL ( ALCOHOL, SOLID TITRILES, TOXIC, SOLID, N.O.S.

I

Number of cones, blue lights

I

W02

2

Remarks

3.2.1 (13)

UN No. Name and description

Class

Classification Packing Code

t 3440

3440

3442

LIQUID, N.O.S. SELENIUM COMPOUND, LIQUID, N.O.S. SELENIUM COMPOUND,

SOLID DICHLOROANILINES, SOLID

SOLID

Labels

Special provisions

3.3

3.4.6

(6)

(7)

274 802 274 802 274 802 279 802 279 802 802 43 802 802 802 802 274

LOO

3.2.1 (8)

8.1.5 (9)

7.1.6 VE02

LQ18

PP. EP. TOX, A PP, EP, TOX, A PP, EP, TOX, A PP, EP

LQl8

PP, EP

LQ18 LQ18

PP, EP PP, EP

LQ17 LQ7

1

LQ18 LQl8 LQl8 LOO

T

I

I

3451

l DIPHENYLCHLOROARSINE. SOLID TOLUIDINES, SOLID

PP, EP 279 802 802 802 802

1 SOLID 3457 3458

PP, EP PP,EP PP, EP PP.EP

PP, EP

l SOLID 3450

LQ18 LQ18 LQ24 LQ18 LQl8 LQ23

T

PP,EP

T T3

PP, EP PP, EP PP, EP PP,EP PP,EP

l CHLORONITROTOLUENES. SOLID NITROANISOLES, SOLID

279 802

Provisions concerning loading, unloading and carriage

Limited Carriage Equipment quantities permitted required

LQ9

PP, EP

(10)

VE02 VE02

I

JN No. Name and description

or [D No.

-

3.1.2

0 3459 3460

(2)

NITROBROMOBENZENES. SOLID N-ETHYLBENZYLTOLUIDINES, SOLID TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID. N.O.S. PROPIONIC ACID with not less than 90% acid by mass ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S. ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S. ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S. ORGANOARSENIC COMPOUND, SOLID. N.O.S. OKGANOARSENIC COMPOUND, SOLID, N.O.S. ORGANOARSENIC COMPOUND, SOLID, N.O.S. METAL CARBONYLS, SOLID, METAL CARBONYLS, SOLID, N.0.S

Class

Classification 'ackbZ Code group

Special Limited Carriage Equipment Ventilation pro~sions quantities permitted required

2.1.1.3 (4) 111

5.2.2 (5) 6.1

3.3 (6) 802 I

I

3.4.6 (7) LQ9 I

3.2.1 (8)

7.1.5 ( U ) 0

0

I

6.1

802

LQ9

PP, EP

I

6.1

210 274

LQO

PP, EP PP, EP

I1

8

LQ9 LQ22

+3 1

6.1

I1

6.1

111

6.1

I

6.1

n

6.1

43 274 802 43 274 802 43 274

802 274 562 802 274 562

Number of cones, blue lights

8.1.5 (9) PP, EP

111

210 274 802

Provisions concerning loading, unloading and carriage

PP, EP T

PP, EP, EX A

LQo

PP, EP

LQ18

PP, EP

LQ9

PP, EP

LQO

PP, EP

LQIS

PP, EP

Remarks

l

Name and description

(2) METAL CARBONYLS, SOLID, V.0.S

3RGANOMETALLIC ZOMPOUND, TOXIC, SOLID, N.O.S. DRGANOMETALLIC COMPOUND, TOXIC, SOLID, V.O.S. 3RGANOMETALLIC COMPOUND, TOXIC, SOLID, N.0.S HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PAINT. FLAMMABLE. CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSNE :including paint thinning or aeducing compound) PAINT. FLAMMABLE. CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSNE :including paint thinning or reducing compound)

Class

Xassifi cation Code

2.2

2.2

0 0 6.1

T3 T3 T3 T3 2F

Special provisions

3.3 (6) 274 562 802 274 562 802 274 562 802 274 562 802 321

Limited Carriag~ Equipment Ventilation quantities permittem required

8.1.5

Provisions concerning loading,carriage unloading and

7.1.6

0 0 PP, EP

Number of cones, blue lights

7.1.5

0 0

2

PP, EP PP, EP PP. EP PP, EX, A

VEOl

FC

PP, EX, A

VEOl

FC

PP, EX, A

VEOl

Remarks

Name and description

,-, PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, wnish. polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE [includingpaint thinning or reducing compound) PAINT, CORROSIVE, FLAMMABLE (including paint, lacquer, enamel, stain, shellac, riarnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL CORROSIVE, FLAMMABLE :including paint thinning or reducing compound) HYDROGENDIFLUORIDES SOLUTION, N.O.S.

Class

Iassifi cation Code

2.2

2.2

Labels

HYDROGENDIFLUORIDES SOLUTION, N.O.S.

8

CROTONIC ACID, LIQUID

8

FUEL CELL CARTRIDGES :ontaining flammable liquids 4MMONIA, DEEPLY REFRIGERATED

3

SUBSTANCES WITH A FLASHPOINT ABOVE 60 "C which are :arried heated within a limiting w g e of 15K below their flash3oint

3

2

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

7.1.6

0 0

FC

CF1 8

8

Equipment Ventilation required

8.1.5

00 3

Special provisions

CT1

PP, EX, A

VEO l

'P, EP, EX A

VEOl

PP, EP

CT1

PP. EP

C3

PP, EP

F1

3TC F3

none

kdtnitted only for :arriage in tank vessel Dangerous only when carried in !ank vessel

or ID No.

Name and description

3.1.2 (2) SUBSTANCES WITH A SELFIGNITION TEMPERATURE OF 200 "C AND BELOW, n.0.s. 9003 SUBSTANCES WITH A FLASHPOINT ABOVE 60 'C AND NOT MORE THAN 100 "C, which do not belong to I another Class 9004 1 DIPHENYLMETHANE-4 4'(1) 9002

Class

Classification Code

Labels

Special provisions

5.2.2

0 none

none

none

Limited quantities

Zarriage Equipment Ventilation ermitted required

Provisions concerning loading, unloading and carriage

Number of cones, blue lights

Remarks

*

Dangerous only when carried in tank vessel Dangerous only when carried in tank vessel

-A

1

I

Dangerous only when carried in tank vessel

This page intentionally left blank

Table B: List of dangerous goods in alphabetical order This index is an alphabetical list of the substances and articles which are listed in the UN numerical order in Table A of 3.2.1. It does not form an integral part of ADN. It has been prepared, with all necessary care by the Secretariat of the United Nations Economic Commission for Europe, in order to facilitate the consultation of Annexes A and B, but it cannot be relied upon as a substitute for the careful study and observance of the actual provisions of those annexed Regulations which, in case of conflict, are deemed to be authoritative. NOTE l : For the pwpose of determining the alphabetical order the following information has been ignored, even when it forms part of the proper shipping name: numbers; Greek letters; the abbreviations "sec" and "tert"; and the letters "Nu (nitrogen), "nff(normal), "o" (ortho) "m" (nzeta), 'bp'@ara)and "N.O.S. " (not otherwise speczjied). NOTE 2: The name of a substance or article in block capital letters indicates a proper shipping name (see 3.1.2). NOTE 3: The name of a substance or article in block capital letters followed by the word "see" indicates an alternative proper shipping name or part of a proper shipping name (exceptfor PCBs) (see 3.1.2.1). NOTE 4: An entry in lower case letters followed by the word "ee" indicates that the entry is not a proper shipping name; it is a synonym. NOTE 5: Where an entry is partly in block capital letters and partly in lower case letters, the latter part is considered not to be part of the proper shipping name (see 3.1.2.1). NOTE 6: A proper shipping name may be used in the singular or plural, as appropriate,for the purposes of documentation and package marking (see 3.1.2.3). NOTE 7: For the exact determination of a proper shipping name, see 3.1.2.

Name and description Accumulators, electric, see

UN Class Remarks Name and description No. ACETYL METHYL CARBINOL Acid butyl phosphate, see

ACETAL

Acid mixture, hydrofluoric and sulphuric, see

ACETALDEHYDE

Acid mixture, nitrating acid, see

ACETALDEHYDE AMMONIA ACETALDEHYDE OXIME

Acid mixture, spent, nitrating acid, see

ACETIC ACID, GLACIAL

Acraldehyde, inhibited, see

ACETIC ACID SOLUTION, more than 10% but not more than 80% acid, by mass

ACFUDINE ACROLEIN DIMER, STABILIZED

ACETIC ACID SOLUTION, more than 80% acid, by mass

ACROLEIN. STABILIZED

ACETIC ANHYDRIDE

ACRYLAMIDE, SOLID

Acetoin, see

ACRYLAMIDE, SOLUTION ACRYLIC ACID, STABILIZED

ACETONE ACETONE CYANOHYDRIN, STABILIZED

ACRYLONITRILE, STABILIZED Actinolite, see

ACETONE OILS Activated carbon, see ACETONITRILE Activated charcoal, see ACETYL BROMIDE ACETYL CHLORIDE

ADHESIVES containing flammable liquid

ACETYLENE, DISSOLVED

ADIPONITRILE

ACETYLENE,SOLVENT FREE

Aeroplane flares, see

Acetylene tetrabromide, see Acetylene tetrachloride, see AEROSOLS ACETYL IODIDE AGENT, BLASTING, TYPE B

UN Class Remarks

No.

Name and description AGENT, BLASTING, TYPE E

UN Class Remarks Name and description No.

UN Class Remarks

No.

ALDEHYDES, FLAMMABLE, TOXIC, N.O.S.

1988

3

ALDOL

2839 6.1

ALKALI METAL ALCOHOLATES, SELFHEATING, CORROSIVE, N.O.S.

3206 4.2

ALKALI METAL ALLOY, LIQUID, N.O.S.

1421 4.3

ALKALI METAL AMALGAM, LIQUID

1389 4.3

ALKALI METAL AMALGAM, SOLID

3401 4.3

ALKALI METAL AMIDES

1390 4.3

ALKALI METAL DISPERSION

1391 4.3

Alkaline corrosive battery fluid, see

2797

AIR BAG INFLATORS

AIR BAG MODULES

AIR, COMPRESSED Aircraft evacuation slides, see AIRCRAFT HYDRAULIC POWER UNIT FUEL TANK (containing a mixture of anhydrous hydrazine and methylhydrazine) (M86 fuel) Aircraft survival kits, see AIR, REFRIGERATED LIQUID ALCOHOLATES SOLUTION, N.O.S., in alcohol

8

Alcohol, denaturated, see

ALKALINE EARTH METAL 3205 4.2 ALCOHOLATES, N.O.S.

Alcohol, industrial, see

ALKALINE EARTH METAL 1393 4.3 ALLOY, N.O.S.

ALCOHOLS, N.O.S.

ALKALINE EARTH METAL 1392 4.3 AMALGAM, LIQUID

ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. ALCOHOLIC BEVERAGES, with more than 24% but not more than 70% alcohol by volume ALCOHOLIC BEVERAGES, with more than 70% alcohol by volume

ALKALINE EARTH METAL 3402 4.3 AMALGAM, SOLID ALKALINE EARTH METAL 1391 4.3 DISPERSION ALKALOIDS, LIQUID, N.O.S.

3140 6.1

ALKALOIDS, SOLID, N.O.S.

1544 6.1

ALKALOID SALTS, LIQUID, N.O.S.

3140 6.1

Aldehyde, see ALDEHYDES, N.O.S.

Name and description

UN Class Remarks Name and description No.

ALKALOID SALTS, SOLID, 1544 6.1 N.O.S. Alkyl aluminium halides, see

ALLYL GLYCIDYL ETHER 2219

3

ALLYL IODIDE

1723

3

ALLYL ISOTHIOCYANATE, STABILIZED

1545 6.1

ALLYLTRICHLOROSILANE, STABILIZED

1724

Aluminium alkyls, see Aluminium alkyl halides, liquid, see Aluminium alkyl halides, solid, see Aluminium alkyl hydrides, see ALUMINIUM BOROHYDRIDE

3394 4.2 3394 4.2

3394 4.2

ALKYLPHENOLS, LIQUID, 3 145 N.O.S. (including C2-CI2 homologues)

8

ALKYLPHENOLS, SOLID, N.O.S. (including C?-CI2 homologues)

2430

8

ALKYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid

2584

ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid

2586

ALKYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid

2583

8

8

8

ALUMINIUM BOROHYDRIDE IN DEVICES ALUMINIUM BROMIDE, ANHYDROUS

ALKYLSULPHONIC 2585 ACIDS, SOLID with not more than 5% free sulphuric acid

8

ALKYLSULPHURIC ACIDS 2571

8

Allene, see

ALUMINIUM BROMIDE SOLUTION ALUMINIUM CARBIDE ALUMINIUM CHLORIDE, ANHYDROUS

ALLYL ACETATE ALLYL ALCOHOL

ALUMINIUM CHLORIDE SOLUTION

ALLYLAMINE

Aluminium dross, see

ALLYL BROMIDE

ALUMINIUM FERROSILICON POWDER

ALLYL CHLORIDE ALUMINIUM HYDRIDE Ally1 chlorocarbonate, see ALUMINIUM NITRATE ALLYL CHLOROFORMATE ALLYL ETHYL ETHER ALLYL FORMATE

UN Class Remarks No.

ALUMINIUM PHOSPHIDE ALUMINIUM PHOSPHIDE PESTICIDE

8

3393 4.2 3394 4.2

Name and description

UN Class Remarks Name and description No.

ALUMINIUM POWDER, COATED

2-(2-AMINOETHOXY) ETHANOL

ALUMINIUM POWDER, UNCOATED

N-AMmOETHYLPIPERAZINE

ALUMINIUM REMELTING BY-PRODUCTS

l -Amino-2-nitrobenzene, see

UN Class Remarks No.

l -Amino-3-nitrobenzene. see

ALUMINIUM RESINATE 1-Amino-4-nitrobenzene, see ALUMINIUM SILICON POWDER, UNCOATED ALUMINIUM SMELTING BY-PRODUCTS

AMINOPHENOLS (0-9 m-, P-) AMINOPYRIDINES (0-, m-, P-)

Amatols, see AMMONIA, ANHYDROUS AMINES, FLAMMABLE, CORROSIVE, N.O.S.

9000

2

AMMONIA SOLUTION 2672 relative density between 0.880 and 0.957 at 15 "C in water, with more than 10% but not more than 35% ammonia

8

AMMONIA, DEEPLY REFRIGERATED

AMINES, LIQUID, CORROSIVE, N.O.S. AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. AMINES, SOLID, CORROSIVE, N.O.S. Aminobenzene, see 2-Aminobenzotrifluoruride, see 3-Aminobenzotrifluoruride, see

AMMONIA SOLUTION, relative density less than 0.880 at 15 "C in water, with more than 35% but not more than 50% ammonia AMMONIA SOLUTION, relative density less than 0.880 at 15 "C in water, with more than 50% ammonia

Aminobutane, see AMMONIUM ARSENATE 2-AMINO-4CHLOROPHENOL

Ammonium bichromate, see

2-AMINO-5DIETHYLAMINOPENTANE

Ammonium bifluoride solid, see

2-AMINO-4,6DINITROPHENOL, WETTED with not less than 20% water, by mass

Ammonium bifluoride solution, see Ammonium bisulphate, see

Admitted only for carriage in tank vessel

Name and description

UN Class Remarks Name and description No.

Ammonium bisulphite solution, see AMMONIUM DICHROMATE AMMONIUM DINITRO-0CRESOLATE, SOLID AMMONIUM DINITRO-0CRESOLATE, SOLUTION AMMONIUM FLUORIDE AMMOMUM FLUOROSILICATE

AMMONIUM NITRATE EMULSION, intermediate for blasting explosives, liquid AMMONIUM NITRATE EMULSION, intermediate for blasting explosives, solid Ammonium nitrate explosive, see AMMONIUM NITRATE BASED FERTILIZER

AMMONIUM HYDROGEN SULPHATE

AMMONIUM NITRATE BASED FERTILIZER, uniform mixtures of the nitrogedphosphate, nitrogenlpotash or nitrogedphosphate/potash type, containing not more than 70% ammonium nitrate and not more than 0.4% total combustible/organic material calculated as carbon or with not more than 45% ammonium nitrate and unrestricted combustible material

Ammonium hydrosulphide solution (treat as ammonium sulphide solution), see

AMMONIUM NITRATE GEL, intermediate for blasting explosives, liquid

AMMONIUM METAVANADATE

AMMONIUM NITRATE GEL, intermediate for blasting explosives, solid

Ammonium hexafluorosilicate, see AMMOMUM HYDROGENDIFLUORIDE, SOLID AMMONIUM HYDROGENDIFLUORIDE SOLUTION

AMMONIUM NITRATE with more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance AMMONIUM NITRATE 1942 5.1 with not more than 0.2% total combustible material, including any organic substance calculated as carbon, to the exclusion of any other added substance

AMMONIUM NITRATE, LIQUID hot concentrated solution, in a concentration of more than 80% but not more than 93% AMMONIUM NITRATE SUSPENSION, intermediate for blasting explosives, liquid AMMONIUM NITRATE SUSPENSION, intermediate for blasting explosives, solid AMMOMUM PERCHLORATE

UN Class Remarks No.

Name and description

Ammonium permanganate, see AMMONIUM PERSULPHATE

UN Class Remarks Name and description No. Ammunition, incendiary (water-activated contrivances) with burster, expelling charge or propelling charge, see

AMMONIUM PICRATE dry or wetted with less than 10% water, by mass

AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge

AMMONIUM PICRATE, WETTED with not less than 10% water, by mass

Ammunition, industrial, see

AMMONIUM POLYSULPHIDE SOLUTION AMMONIUM POLYVANADATE

Ammunition, lachrymatory, see

Ammonium silicofluoride, see AMMONIUM SULPHIDE SOLUTION

AMMUNITION, PRACTICE

Ammunition, blank, see

AMMUNITION, PROOF AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge

Ammunition, fixed Ammunition, semi-fixed Ammunition, separate loading, see

AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge AMMUNITION, INCENDIARY with or without bwster, expelling charge or propelling charge

Ammunition, smoke (wateractivated contrivances), white phosphorus with burster, expelling charge or propelling charge, see Ammunition, smoke (wateractivated contrivances), without white phosphorus or phosphides with burster, expelling charge or propelling charge, see AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge

UN Class Remarks No.

Name and description Ammunition, sporting, see

UN Class Remarks Name and description No. 0012 0328 0339 0417

AMMUNITION, TEAR201 7 PRODUCING, NONEXPLOSIVE without burster or expelling charge, non-fuzed AMMUNITION, TEAR0018 PRODUCING with burster, 0019 expelling charge or propelling 0301 charge AMMUNITION, TOXIC with 0020 burster, expelling charge or propelling charge AMMUNITION, TOXIC with 002 1 burster, expelling charge or propelling charge Ammunition, toxic (wateractivated contrivances) with burster, expelling charge or propelling charge, see

0248 0249

AMMUNITION, TOXIC, NON-EXPLOSIVE without burster or expelling charge, non-fuzed

2016

UN Class Remarks No.

AMYL MERCAPTAN

1111

3

n-AMYL METHYL KETONE

1110

3

AMYL NITRATE

1112

3

AMYL NITRITE

1113

3

AMYLTRICHLOROSILANE 1728

8

Anaesthetic ether, see ANILINE Carriage Aniline chloride, see prohibited ANILINE HYDROCHLORIDE Carriage prohi- Aniline oil, see bited Aniline salt, see ANISIDINES ANISOLE ANISOYL CHLORIDE Anthophyllite, see Antimonous chloride, see

Amosite, see AMYL ACETATES

1104

AMYL ACID PHOSPHATE

2819

Amyl aldehyde, see

2058

ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. Antimony hydride, see

2676

2

n-Amylamine, see

1106

ANTIMONY LACTATE

1550 6.1

AMYL BUTYRATES

2620

Antimony (111) lactate, see

1550 6.1

AMYL CHLORIDE

1107

ANTIMONY 1730 PENTACHLORIDE, LIQUID

8

n-AMYLENE. see

1108 1109

ANTIMONY PENTACHLORIDE SOLUTION

8

AMYL FORMATES

1731

Name and description ANTIMONY PENTAFLUORIDE

UN No. Class Remarks Name and description 1732

8

Antinlony perchloride, liquid, 1730 see

8

ANTIMONY POTASSIUM TARTRATE

1551 6.1

ANTIMONY POWDER

2871 6.1

ANTIMONY TRICHLORIDE 1733

8

A.n.t.u., see

1651 6.1

ARGON, COMPRESSED

1006

UN Class Remarks No.

Arsenic chloride, see

1560 6.1

ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.0.s.; and Arsenic sulphides, n.0.s.

1556 6.1

ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.0.s.; Arsenites, n.0.s.; and Arsenic sulphides, n.0.s.

1557 6.1

Arsenic (111) oxide, see

1561 6.1

Arsenic (V) oxide, see

1559 6.1

ARSENIC PENTOXIDE

1559 6.1

2

ARGON, REFRIGERATED LIQUID

1951

Arsenates, n.o.s., see

1554 6.1 1557 6.1

Arsenic sulphides, see

1556 6.1 1557 6.1

ARSENIC

1558 6.1

ARSENIC TRICHLORIDE

1560 6.1

ARSENIC ACID, LIQUID

1553 6.1

ARSENIC TRIOXIDE

1561 6.1

ARSENIC ACID, SOLID

1554 6.1

Arsenious chloride, see

1560 6.1

ARSENICAL DUST

1562 6.1

Arsenites, n.o.s., see

1556 6.1 1557 6.1

Arsenical flue dust, see

1562 6.1 Arsenous chloride, see

1560 6.1

ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 O C

2760

ARSINE

2188

2

ARTICLES, EEI, see

0486

1

ARSENICAL PESTICIDE, LIQUID, TOXIC

2994 6.1

ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 'C

2993 6.1

ARSENICAL PESTICIDE, SOLID, TOXIC ARSENIC BROMIDE Arsenic (111) bromide, see

2

3

ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE ARTICLES, EXPLOSIVE, N.O.S.

Name and description

UN No. Class Remarks Name and description Aviation regulated liquid, n.0.s.

ARTICLES, PRESSURIZED, 3 l64 HYDRAULIC (containing non-flammable gas)

UN Class Remarks No. 3334

9

Not subject to ADN

Aviation regulated solid, n.0.s. 3335

9

Not subject to ADN

AZODICARBONAMIDE

3242 4.1

Bag charges, see

0242 0279 0414

1 1 1

1 1 1 1

ARTICLES, PRESSURIZED, 3 l64 PNEUMATIC (containing non-flammable gas)

Ballistite, see

ARTICLES, PYROPHORIC

Bangalore torpedoes, see

0136 0137 0138 0294

BARIUM

1400 4.3

0380

ARTICLES, PYROTECHNIC 0428 for technical purposes 0429 0430 043 1 0432 ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid

2584

BARIUM ALLOYS, PYROPHORIC

1854 4.2

0224

ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid

2586

BARIUM AZIDE, dry or wetted with less than 50% water, by mass

1571 4.1

ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid

2583

BARIUM AZIDE, WETTED with not less than 50% water, by mass Barium binoxide, see

1449 5.1

BARIUM BROMATE

2719 5.1

BARIUM CHLORATE, SOLID

1445 5.1

BARIUM CHLORATE, SOLUTION

3405 5.1

Asphalt, with a flash-point not 1999 greater than 60 "C, see

BARIUM COMPOUND, N.O.S.

1564 6.1

Asphalt, with flash-point above 60 "C, at or above its flash-point, see Asphalt, at or above 100 "C and below its flashpoint, see

BARIUM CYANIDE

1565 6.1

Barium dioxide, see

1449 5.1

ARYLSULPHONIC ACIDS, 2585 SOLID with not more than 5% free sulphuric acid Asbestos, blue or brown, see

22 12

Asbestos, white, see

2590

3256

3257

1

Name and description

UN

No.

Class Remarks Name and description

UN Class Remarks

No.

BARIUM HYPOCHLORITE 2741 5.1 with more than 22% available chlorine

BENZENESULPHONYL CHLORIDE

2225

BARIUM NITRATE

1446 5.1

Benzenethiol, see

2337 6.1

BARIUM OXIDE

1884 6.1

BENZIDINE

1885 6.1

BARIUM PERCHLORATE, SOLID

1447 5.1

Benzol, see

1114

3

Benzolene, see

1268

3

BARIUM PERCHLORATE, SOLUTION

3406 5.1 BENZONITRILE

2224 6.1

BARIUM PERMANGANATE

1448 5.1

BENZOQUINONE

2587 6.1

Benzosulphochloride, see

2225

8

BENZOTRICHLORIDE

2226

8

BENZOTRIFLUORIDE

2338

3

BENZOYL CHLORIDE

1736

8

BENZYL BROMIDE

1737 6.1

BENZYL CHLORIDE

1738 6.1

Benzyl chlorocarbonate, see

1739

8

BENZYL CHLOROFORMATE

1739

8

BARIUM PEROXIDE

1449 5.1

Barium selenate, see

2630 6.1

Barium selenite, see

2630 6.1

Barium superoxide, see

1449 5.1

BATTERIES, CONTAINING 3292 4.3 SODIUM

8

BATTERIES, DRY, 3028 CONTAINING POTASSIUM HYDROXIDE SOLID, electric storage

8

BATTERIES, WET, FILLED 2794 WITH ACID, electric storage

8

Benzyl cyanide, see

2470 6.1 2619

BATTERIES, WET, FILLED 2795 WITH ALKALI, electric storage

8

BENZYLDIMETHYLAMINE

BATTERIES, WET, NONSPILLABLE, electric storage

8

BENZYL IODIDE

2796

8

BERYLLIUM COMPOUND, 1566 6.1 N.O.S.

BATTERY FLUID, ALKALI 2797

8

BERYLLIUM NITRATE

2464 5.1

Battery-powered vehicle or Battery-powered equipment

9

Not BERYLLIUM POWDER subject tOADN Bhusa

1567 6.1

BATTERY FLUID, ACID

2800

3 171

8

BENZYLIDENE CHLORIDE 1886 6.1

BENZALDEHYDE

1990

9

BENZENE

1114

3

2653 6.1

1327 4.1

Not subject to ADN

Name and description

UN No. Class Remarks Name and description

BICYCL0[2.2.1]HEPTA-2,52251

3

Blasting cap assemblies, see

8

Blasting caps, electric, see

DIENE, STABILIZED Bifluorides, n.o.s., see

1740

BIOLOGICAL SUBSTANCE, CATEGORY B (BIO) MEDICAL WASTE, N.O.S.

3373 6.2 Bleaching powder, see 3291 6.2 BLUE ASBESTOS (crocidolite)

BIPYRIDILIUM PESTICIDE, 2782 LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C

3 BOMBS with bursting charge

BIPYRIDILIUM PESTICIDE, 3016 6.1 LIQUID, TOXIC

Bombs, illuminating, see

BIPYRIDILIUM PESTICIDE, 301 5 6.1 LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

BOMBS, PHOTO-FLASH

BIPYRIDILIUM PESTICIDE, 2781 6.1 SOLID, TOXIC 8

BOMBS, SMOKE, NONEXPLOSIVE with corrosive liquid, without initiating device Bombs, target identification, see

BISULPHATES, AQUEOUS 283 7 SOLUTION BISULPHITES, AQUEOUS SOLUTION, N.O.S.

2693

8

Bitumen, with a flash-point not greater than 60 "C,see

1999

3

Bitumen, with a flash-point not greater than 60 "C, see Bitumen, with flash-point above 60 "C, at or above its flash-point, see Bitumen, at or above 100 "C and below its flashpoint, see BLACK POWDER, COMPRESSED

1999

3

3256

9

BOOSTERS WITH DETONATOR

3257

9

BOOSTERS without detonator

0028

1

Borate and chlorate mixture, see

BOMBS WITH FLAMMABLE LIQUID with bursting charge

BORNEOL BLACK POWDER, granular or as a meal

0027

BLACK POWDER, IN PELLETS

0028

1 BORON TRIBROMIDE 1

BORON TRICHLORIDE

UN Class Remarks No.

Name and description BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID BORON TRIFLUORIDE ACETIC ACID COMPLEX, SOLID

UN No.

Class Remarks Name and description omega-Bromoacetone, see BROMOACETYL BROMIDE BROMOBENZENE

BORON TRIFLUORIDE

BROMOBENZYL CYANIDES, LIQUID

BORON TRIFLUORIDE DIETHYL ETHERATE

BROMOBENZYL CYANIDES, SOLID

BORON TRIFLUORIDE DIHYDRATE

l -BROMOBUTANE

2-BROMOBUTANE BORON TRIFLUORIDE DIMETHYL ETHERATE BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, SOLID

BROMOCHLOROMETHANE 1-BROMO-3CHLOROPROPANE l -Bromo-2,3-epoxypropane,

see Bromoethane, see

BROMATES, INORGANIC, N.O.S. BROMATES, INORGANIC, AQUEOUS SOLUTION, N.0.S

2-BROMOETHYL ETHYL ETHER BROMOFORM Bromomethane, see

BROMINE BROMINE CHLORIDE

l -BROMO-3METHYLBUTANE

BROMINE PENTAFLUORIDE

BROMOMETHYLPROPANES

BROMINE SOLUTION

2-BROMO-2NITROPROPANE- 1,3-DIOL

BROMINE TRIFLUORIDE 2-BROMOPENTANE BROMOACETIC ACID, SOLID BROMOACETIC ACID, SOLUTION BROMOACETONE

BROMOPROPANES 3-BROMOPROPYNE BROMOTRIFLUOROETHYLENE

UN Class Remarks

No.

Name and description

UN Class Remarks Name and description No.

BROMOTRIFLUOROMETHANE

1009

2

BROWN ASBESTOS (amosite, mysorite)

2212

9

BRUCINE

1570 6.1

BURSTERS, explosive

0043

1

BUTADIENES AND 1010 HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 "C not exceeding 1.l MPa (1 1 bar) and a density at 50 "C not lower than 0.525 kg11

2

UN Class Remarks No.

BUTYL ACETATES Butyl acetate, secondary, see BUTYL ACID PHOSPHATE BUTYL ACRYLATES, STABILIZED n-Butyl alcohol, see Butyl alcohols, see

N-BUTYLANILINE sec-Butyl benzene, see

BUTADIENES , STABILIZED, having a vapour pressure at 70 "C not exceeding 1.l MPa ( l l bar) and a density at 50 "C not lower than 0.525 kg/] BUTANE

BUTYLBENZENES n-Butyl bromide, see n-Butyl chloride, see n-BUTYL CHLOROFORMATE

BUTANEDIONE Butane-l -thiol, see BUTANOLS l -Butanol, see

tert-BUTYLCYCLOHEXYL CHLOROFORMATE BUTYLENES MIXTURE or 1-BUTYLENE or CIS-2-BUTYLENE or TRANS-2-BUTYLENE

Butan-2-01, see Butanol, secondary, see

l ,2-BUTYLENE OXIDE, STABILIZED

Butanol, tertiary, see

Butyl ethers, see

Butanone, see

Butyl ethyl ether, see

2-Butenal, see

n-BUTYL FORMATE

Butene, see

tert-BUTYL HYPOCHLORITE

Bute-l -ene-3-one, see 1,2-Buteneoxide,see 2-Buten- 1-01, see

N,n-Butyliminazole, see n-BUTYL ISOCYANATE

3255 4.2

Carriage prohibited

Name and description

UN Class Remarks Name and description No.

tert-BUTYL ISOCYANATE

Butyroyl chloride, see

Butyl lithium, see

BUTYRYL CHLORIDE

BUTYL MERCAPTAN

Cable cutters, explosive, see

n-BUTYL METHACRYLATE, STABILIZED

CACODYLIC ACID

BUTYL METHYL ETHER

CAESIUM

BUTYL NITRITES

CAESIUM HYDROXIDE

Butylphenols, liquid, see

CAESIUM HYDROXIDE SOLUTION

CADMIUM COMPOUND

Butylphenols, solid, see CAESIUM NITRATE BUTYL PROPIONATES Caffeine, see p-tert-Butyltoluene, see Cajeputene, see BUTYLTOLUENES CALCIUM BUTYLTRICHLOROSILANE

CALCIUM ALLOYS, PYROPHORIC

5-tert-BUTYL-2,4,6TRINITRO-m-XYLENE

CALCIUM ARSENATE

BUTYL VINYL ETHER, STABILIZED

CALCIUM ARSENATE AND CALCIUM ARSEMTE MIXTURE, SOLID

But- l -yne, see l ,4-BUTYNEDIOL

Calcium bisulphite solution, see

2-Butyne- 1,4-diol, see

CALCIUM CARBIDE

BUTYRALDEHYDE

CALCIUM CHLORATE

n-Butyraldehyde, see

CALCIUM CHLORATE, AQUEOUS SOLUTION

BUTYRALDOXIME CALCIUM CHLORITE BUTYRIC ACID BUTYRIC ANHYDRIDE

CALCIUM CYANAMIDE with more than 0.1% calcium carbide

Butyrone, see CALCIUM CYANIDE BUTYRONITRILE CALCIUM DITHIONITE

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

CALCIUM HYDRIDE

1404 4.3

CALCIUM HYDROSULPHITE, see

1923 4.2

CALCIUM HYPOCHLORITE, DRY

1748 5.1

UN Class Remarks No.

CALCIUM RESINATE, FUSED

1314 4.1

Calcium selenate, see

2630 6.1

CALCIUM SILICIDE Calcium silicon, see

CALCIUM HYPOCHLORITE, HYDRATED with not less than 5.5% but not more than 16% water

2880 5.1 Calcium superoxide, see Camphanone, see CAMPHOR OIL

CALCIUM 2880 5.1 HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16% water

CAMPHOR, synthetic CAPROIC ACID CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C

CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 10% but not more than 39% available chlorine

2208 5.1

CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen)

1748 5.1

CALCIUM MANGANESE SILICON

2844 4.3

CARBAMATE PESTICIDE, SOLID, TOXIC

2757 6.1

CALCIUM NITRATE

1454 5.1

Carbolic acid, see

Calcium oxide

1910

1671 6.1 2312 6.1 2821 6.1

CARBON, animal or vegetable origin

1361 4.2

CARBON, ACTIVATED

1362 4.2

Carbon bisulphide, see

1131

Carbon black (animal or vegetable origin), see

1361 4.2

CARBON DIOXIDE

1013

CARBAMATE PESTICIDE, LIQUID, TOXIC CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

8

CALCIUM PERCHLORATE 1455 5.1 CALCIUM PERMANGANATE CALCIUM PEROXIDE

1457 5.1

CALCIUM PHOSPHIDE

1360 4.3

CALCIUM, PYROPHORIC

1855 4.2

CALCIUM RESINATE

1313 4.1

Not subject

3

2

Name and description

UN Class Remarks Name and description No. CARTRIDGES FOR WEAPONS. BLANK

Carbon dioxide and ethylene oxide mixture, see

104 1 1952 3300

2 2 2

CARBON DIOXIDE, REFRIGERATED LIQUID

2187

2

Carbon dioxide, solid

1845

9

CARBON DISULPHIDE

1131

3

Cartridges, illuminating, see

Carbonic anhydride, see

1013 1845 2187

2 9 2

CARTRIDGES, OIL WELL

CARBON MONOXIDE, COMPRESSED

1016

2

Carbon oxysulphide, see

2204 2.3

Carbon sulphide, see

1131

CARTRIDGES FOR Not WEAPONS, INERT subject PROJECTILE to ADN

CARTRIDGES, POWER DEVICE

3

CARBON TETRABROMIDE 25 l 6 6.1

CARTRIDGES, SIGNAL

CARBON TETRACHLORIDE

1846 6.1

Carbonyl chloride, see

1076

2

CARBONYL FLUORIDE

24 17

2

CARBONYL SULPHIDE

2204

2

Cartridge cases, empty, primed, see

0055 0379

1 1

Cartridges, starter, jet engine, see

Cartridges, actuating, for fire extinguisher or apparatus valve, see

0275 0276 0323 0381

1 1 1 1

CASES, CARTRIDGE, EMPTY, WITH PRIMER

Cartridges, explosive, see

0048

1

CARTRIDGES, FLASH

0049 0050

1 1

CARTRIDGES FOR WEAPONS with bursting charge

0005 0006 0007 0321 0348 0412

1 1 1 1 1 1

CARTRIDGES, SMALL ARMS

CARTRIDGES, SMALL ARMS, BLANK

CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER Casinghead gasoline, see CASTOR BEANS CASTOR FLAKE

UN Class Remarks No.

Name and description CASTOR MEAL

UN Class Remarks Name and description No.

0271 0272 0415 0491

1 1 1 1

CHARGES, PROPELLING, FOR CANNON

0242 0279 0414

1 1

CHARGES, SHAPED, FLEXIBLE, LINEAR

0237 0288

1 1

CHARGES, SHAPED, without detonator

0059 0439 0440 0441

1 1 1 1

CHARGES, SUPPLEMENTARY, EXPLOSIVE

0060

1

CHEMICAL KIT

3316

9

CHEMICAL SAMPLE, TOXIC

3315 6.1

Chile saltpetre, see

1498 5.1

CHLORAL, ANHYDROUS, STABILIZED

2075 6.1

Caustic potash, see Caustic soda, see

Class Remarks

CHARGES, PROPELLING

CASTOR POMACE CAUSTIC ALKALI LIQUID, N.O.S.

No.

1

Caustic soda liquor, see CELLS, CONTAINING SODIUM CELLULOID in block, rods, rolls, sheets, tubes, etc., except scrap CELLULOID, SCRAP Cement, see CERIUM, slabs, ingots or rods CERIUM, turnings or gritty powder Cer mishrnetall, see Charcoal, activated, see

CHLORATE AND BORATE 1458 5.1 MIXTURE

Charcoal, non-activated, see CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID

1459 5.1

CHARGES, BURSTING, PLASTICS BONDED

3407 5.1

CHARGES, DEMOLITION

CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLUTION

CHARGES, DEPTH Charges, expelling, explosive, for fire extinguishers, see

CHARGES, EXPLOSIVE, COMMERCIAL without detonator

CHLORATES, INORGANIC, 1461 5.1 N.O.S. CHLORATES, INORGANIC, 3210 5.1 AQUEOUS SOLUTION, N.O.S. CHLORIC ACID, AQUEOUS 2626 5.1 SOLUTION with not more than 10% chloric acid

Name and description

UN Class Remarks Name and description No. CHLOROBENZYL CHLORIDES, SOLID

CHLORINE

1017

CHLORINE PENTAFLUORIDE

2548

CHLORINE TRIFLUORIDE

1749

l -Chlorobutane, see

CHLORITES, INORGANIC, N.O.S.

l462

2-Chlorobutane, see

CHLORITE SOLUTION

1908

Chloroacetaldehyde, see

2232

CHLOROCRESOLS, SOLUTION

CHLOROACETIC ACID, MOLTEN

3250

CHLOROCRESOLS, SOLID

CHLOROACETIC ACID, SOLID

1751

CHLORODIFLUOROBROMOMETHANE

CHLOROACETIC ACID SOLUTION

1750

1-CHLORO- l , l -DIFLUOROETHANE

CHLOROACETONE, STABILIZED

1695

CHLORODIFLUOROMETHANE

CHLOROACETONITRILE

2668

l -Chloro-3-bromopropane, see

CHLOROBUTANES

CHLOROACETOPHENONE, 3416 LIQUID CHLOROACETOPHENONE, 1697 SOLID CHLOROACETYL CHLORIDE

1752

CHLOROANILINES, LIQUID

2019

CHLORODIFLUOROMETHANE AND CHLOROPENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane 3-Chloro-1,2dihydroxypropane, see Chlorodirnethyl ether, see

CHLOROANILINES, SOLID 201 8 CHLOROANISIDINES

2233

CHLOROBENZENE

1134

1Chloro-2,2-dimethylpropane, see CHLORODINITROBENZENES, LIQUID CHLORODINITROBENZENES, SOLID

CHLOROBENZOTRIFLUO- 2234 RIDES Chloroethane, see CHLOROBENZYL CHLORIDES, LIQUID

2235 Chloroethane nitrile, see 2-Chloroethanol, see

UN Class Remarks

No.

Name and description

UN Class Remarks Name and description No.

CHLOROFORM

1888 6.1

CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S.

3277 6.1

CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S.

2742 6.1

Chloromethane, see

1063

l-Chloro-3-methylbutane, see

UN Class Remarks No.

CHLORONITROBENZENES 1578 6.1 SOLID CHLORONITROTOLUENES, LIQUID

2433 6.1

CHLORONITROTOLUENES, SOLID

3457 6.1

CHLOROPENTAFLUOROETHANE

1020

2

2

1107

3

l -Chloropentane

1107

3

2-Chloro-2-methylbutane, see 1107

3

CHLOROPHENOLATES, LIQUID

2904

8

CHLOROPHENOLATES, SOLID

2905

8

CHLOROPHENOLS, LIQUID

2021 6.1

CHLOROMETHYL CHLOROFORMATE

2745 6.1

Chloromethyl cyanide, see

2668 6.1

CHLOROMETHYL ETHYL ETHER

2354

3

l-Chloro-3-methylbutane, see

1107

3

l -Chloro-3-methylbutane, see 1107

3

CHLOROPHENOLS. SOLID 2020 6.1 CHLOROPHENYLTRICHLOROSILANE

1753

8

CHLOROPICRIN

1580 6.1

CHLOROPICRIN AND METHYL BROMIDE MIXTURE, with more than 2% chloropicrin

1581

2

2

Chloromethyl methyl ether, see

1239 6.1

3-CHLORO-4-METHYLPHENYL ISOCYANATE, LIQUID

2236 6.1

3-CHLORO-4-METHYLPHENYL ISOCYANATE, SOLID

3428 6.1

CHLOROPICRIN AND METHYL CHLORIDE MIXTURE

1582

l -Chloro-2-methylpropane, see

1127

3

CHLOROPICRIN MIXTURE, N.O.S.

1583 6.1

2-Chloro-2-methylpropane, see

1127

3

CHLOROPLATMIC ACID, SOLID

2507

8

3-Chloro-2-methylprop- l -ene, 2554 see

3

CHLOROPRENE, STABILIZED

1991

3

CHLORONITROANILINES 2237 6.1

1-CHLOROPROPANE

1278

3

CHLORONITROBENZENES 3409 6.1 LIQUID

2-CHLOROPROPANE

2356

3

3-Chloro-propanediol-1,2, see 2689 6.1

Name and description

UN

No.

Class Remarks Name and description

UN Class Remarks No.

CHLOROTOLUIDINES LIQUID CHLOROTOLUIDINES SOLID

3-Chloropropene, see

1100

3

3-Chloroprop- l-ene, see

1100

3

1-CHLORO-2,2,2TRIFLUOROETHANE

2-CHLOROPROPIONIC ACID

2511

8

Chlorotrifluoroethylene, see

CHLOROTRIFLUOROMETHANE CHLOROSILANES, CORROSIVE, N.O.S.

2987

8

CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S.

2986

8

CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S.

2985

3

CHLOROTRIFLUOROMETHANE AND TRIFLUOROMETHANE AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane Chromic acid, solid, see CHROMIC ACID SOLUTION

CHLOROSILANES, TOXIC, 3361 6.1 CORROSIVE, N.O.S. CHLOROSILANES, TOXIC, 3362 6.1 CORROSIVE, FLAMMABLE. N.O.S. CHLOROSILANES, WATER-REACTIVE, FLAMMABLE, CORROSIVE, N.O.S.

2988 4.3

CHLOROSULPHONIC ACID (with or without sulphur trioxide)

1754

1-CHLORO-1,2,2,2TETRAFLUOROETHANE

1021

CHLOROTOLUENES

2238

Chromic anhydride, solid, see CHROMIC FLUORIDE, SOLID CHROMIC FLUORIDE SOLUTION Chromic nitrate, see

8

Chromium (VI) dichloride dioxide. see Chromium (111) fluoride, solid, l756 see

2 CHROMIUM NITRATE 3

Chromium (111) nitrate, see

4-CHLORO-0-TOLUIDINE 1579 6.1 HYDROCHLORIDE, SOLID

CHROMIUM OXYCHLORIDE

4-CHLORO-0-TOLUIDINE HYDROCHLORIDE, SOLUTION

CHROMIUM TRIOXIDE, ANHYDROUS

3410 6.1

8

Name and description

UN Class Remarks Name and description No.

CHROMOSULPHURIC ACID

2240

8

COMPRESSED GAS, N.O.S.

Chryosotile, see

2590

9

COMPRESSED GAS, FLAMMABLE. N.O.S.

Cinene, see

2052

3

Cinnamene, see

2055

3

Cinnamol, see

2055

3

CLINICAL WASTE, UNSPECIFIED, N.O.S.

3291 6.2

COAL GAS, COMPRESSED 1023

2

COAL TAR DISTILLATES, FLAMMABLE

1l36

3

Coal tar naphtha, see

1268

3

Coal tar oil, see

1136

3

COATING SOLUTION 1139 (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining)

3

COMPRESSED GAS, TOXIC, N.O.S. COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S.

COBALT NAPHTHENATES, 2001 4.1 POWDER COBALT RESINATE, PRECIPITATED

1318 4.1

Cocculus, see

3172 3462 0340 0341 0342 2059 2555 2556 2557

6.1 6.1 1 1 1 3 4.1 4.1 4.1

COMPONENTS, EXPLOSIVE TRAIN, N.O.S.

0382 0383 0384 0461

1 1 1 1

Composition B, see

0118

1

Collodion cottons, see

COMPRESSED GAS, OXIDIZING, N.O.S.

CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge COPPER ACETOARSENITE COPPER ARSENITE Copper (11) arsenite, see COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C COPPER BASED PESTICIDE, LIQUID, TOXIC

UN Class Remarks

No.

Name and description

UN Class Remarks Name and description No.

COPPER BASED 3009 6.1 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

UN Class Remarks

No.

CORROSIVE LIQUID, FLAMMABLE, N.O.S.

2920

8

CORROSIVE LIQUID, OXIDIZING, N.O.S.

3093

8

CORROSIVE LIQUID, SELF-HEATING, N.O.S.

3301

8

CORROSIVE LIQUID, TOXIC, N.O.S.

2922

8

CORROSIVE LIQUID, 3094 WATER-REACTIVE, N.O. S.

8

CORROSIVE SOLID, N.O.S.

1759

8

CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.

3260

8

CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.

3261

8

CORROSIVE SOLID, 3262 BASIC, INORGANIC, N.O.S.

8

CORROSIVE SOLID, BASIC, ORGANIC, N.O.S.

3263

8

CORROSIVE SOLID, FLAMMABLE, N.O.S.

2921

8

Cordite, see

CORROSIVE SOLID, OXIDIZING, N.O.S.

3084

8

CORROSIVE LIQUID, N.O.S.

CORROSIVE SOLID, SELF- 3095 HEATING, N.O.S.

8

CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

CORROSIVE SOLID, TOXIC, N.O.S.

2923

8

CORROSIVE SOLID, 3096 WATER-REACTIVE, N.O. S.

8

COPPER BASED 2775 6.1 PESTICIDE, SOLID, TOXIC COPPER CHLORATE Copper (11) chlorate, see COPPER CHLORIDE COPPER CYANIDE Copper selenate, see Copper selenite, see COPRA CORD, DETONATING, flexible CORD, DETONATING, metal clad CORD, DETONATING, MILD EFFECT, metal clad CORD, IGNITER

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.

3267

8

COTTON WASTE, OILY

1364 4.2

COTTON, WET

1365 4.2

COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C

3024

3

Name and description

UN Class Remarks Name and description No.

UN Class Remarks

No.

Cut backs, at or above l00 "C and below its flashpoint, see CUTTERS, CABLE, EXPLOSIVE

3257

9

0070

1

CYANIDE SOLUTION, N.O.S.

1935 6.1

COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC

CYANIDES, INORGANIC, SOLID, N.O.S.

l588 6.1

Creosote, see

Cyanides, organic, flammable, 3273 toxic, n.o.s., see

COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

3

Creosote salts, see CRESOLS, LIQUID CRESOLS, SOLID

Cyanides, organic, toxic, n.o.s., see Cyanides, organic, toxic, flammable, n.o.s., see

CRESYLIC ACID Cyanoacetonitrile, see Crocidolite, see CYANOGEN CROTONALDEHYDE CYANOGEN BROMIDE CROTONALDEHYDE, STABILIZED

CYANOGEN CHLORIDE, STABILIZED

CROTONIC ACID, LIQUID CYANURIC CHLORIDE CROTONIC ACID, SOLID CYCLOBUTANE Crotonic aldehyde / Crotonic aldehyde, stabilized, see

CYCLOBUTYL CHLOROFORMATE

CROTONYLENE Crude naphtha, see

l ,5,9-CYCLODODECATRIENE

Cumene, see

CYCLOHEPTANE

Cupric chlorate, see

CYCLOHEPTATRIENE

CUPRIETHYLENEDIAMINE SOLUTION

1,3,5-Cycloheptatriene, see CYCLOHEPTENE

Cut backs, with a flash-point not greater than 60 "C, see Cut backs, with flash-point above 60 'C, at or above its flash-point, see

1,4-Cyclohexadienedione,see 2587 6.1 CYCLOHEXANE

1145

3

Cyclehexanethiol, see

3054

3

Name and description

UN Class Remarks Name and description No. CYCLOTETRAMETHYLENETETRANITRAMINE, DESENSITIZED

CYCLOHEXANONE CYCLOHEXENE CYCLOHEXENYLTRICHLOROSILANE

CYCLOTETRAMETHYLENETETRANITRAMINE, WETTED with not less than 15% water, by mass

CYCLOHEXYL ACETATE CYCLOHEXYLAMINE

CYCLOTFUMETHYLENETRINITRAMINE AND CYCLOTETRAMETHYLENETETRANITRAMINE MIXTURE, DESENSITIZED with not less than 10% phlegmatiser by mass

CYCLOHEXYL ISOCYANATE CYCLOHEXYL MERCAPTAN CYCLOHEXYLTRICHLOROSILANE CYCLONITE AND CYCLOTETRAMETHYLENETETRANITRAMME MIXTURE, WETTED with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegmatiser by mass, see CYCLONITE, DESENSITIZED, see

UN Class Remarks No.

CYCLOTRIMETHYLENETRINITRAMINE AND CYCLOTETRAMETHYLENETETRANITRAMINE MIXTURE, WETTED with not less than 15% water, by mass

0483

CYCLONITE, WETTED with 0072 not less than 15% water, by mass, see

CYCLOTRIMETHYLENETRINITRAMINE, DESENSITIZED CYCLOTRIMETHYLENETRINITRAMINE, WETTED with not less than 15% water, by mass

CYCLOOCTADIENES

2520

CYCLOOCTADIENE PHOSPHINES, see

2940

CYCLOOCTATETRAENE

2358

Deanol, see

CYCLOPENTANE

1146

Dangerous goods in 3363 machinery or dangerous goods in apparatus

CYMENES Cymol, see

CYCLOPENTANOL

2244

CYCLOPENTANONE

2245

CYCLOPENTENE

2246

CYCLOPROPANE

1027

9

Not

subject to ADN

[see also 1.1.3.1

@)l DECABORANE DECAHYDRONAPHTHALENE

1868 4.1

Name and description

UN Class Remarks Name and description No.

Decalin, see

1147

DIALKYL-(CIZ-CI8)DIMETHYL-AMMONIUM and 2-PROPANOL

DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES, N.O.S.

0 132

DIALLYLAMINE

Depth charge, see

0056

4,4'-DIAMINODIPHENYLMETHANE

DESENSITIZED EXPLOSIVE, LIQUID, N.O.S.

3379

1,ZDiaminoethane, see

DIALLYL ETHER

Diaminopropylamine, see

DESENSITIZED 3380 EXPLOSIVE, SOLID, N.O.S. Detonating relays, see

0029 0267 0360 0361 0455 0500

DETONATOR ASSEMBLIES, NONELECTRIC for blasting

0360 0361 0500

DETONATORS FOR AMMUNITION

0073 0364 0365 0366

DI-n-AMYLAMINE DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass Dibenzopyridine, see DIBENZYLDICHLOROSILANE DIBORANE 1,2-DIBROMOBUTAN-3ONE DIBROMOCHLOROPROPANES

DETONATORS, ELECTRIC 0030 for blasting see DETONATORS, NONELECTRIC for blasting

DIBROMODIFLUOROMETHANE DIBROMOMETHANE

DEUTERIUM, COMPRESSED

DI-n-BUTYLAMINE

DEVICES, SMALL, HYDROCARBONGAS POWERED with release device

DIBUTYLAMINOETHANOL

DIACETONE ALCOHOL

N,N-Di-n-butylaminoethanol,

2-Dibutylaminoethanol, see

see

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

DIBUTYL ETHERS

UN Class Remarks No.

DICHLOROISOCYANURIC 2465 ACID SALTS

DICHLOROACETIC ACID l ,3-DICHLOROACETONE DICHLOROACETYL CHLORIDE DICHLOROANILINES, LIQUID DICHLOROANILMES, SOLID

DICHLOROISOPROPYL ETHER

2490

DICHLOROMETHANE

1593

1,l -DICHLORO- l NITROETHANE

2650

DICHLOROPENTANES

1152

Dichlorophenol, see

2020 202 1

DICHLOROPHENYL ISOCYANATES

2250

DICHLOROPHENYLTRICHLOROSILANE

1766

1,2-DICHLOROPROPANE

1279

I ,3-DICHLOROPROPANOL-2

2750

0-DICHLOROBENZENE 2,2'-DICHLORODIETHYL ETHER DICHLORODIFLUOROMETHANE DICHLORODIFLUOROMETHANE AND 1,lDIFLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane

1,3-Dichloro-2-propanone,see 2649

Dichlorodifluoromethane and ethylene oxide mixture, see DICHLORODIMETHYL ETHER, SYMMETRICAL 1,l -DICHLOROETHANE

2249 6.1

DICHLOROPROPENES

2047

DICHLOROSILANE

2189

Carriage l ,2-DICHLORO- 1,1,2,2prohi- TETRAFLUOROETHANE bited

1958

Dichloro-S-triazine-2,4,6trione, see

2465

1,4-Dicyanobutane, see

2205

Dicycloheptadiene, see

225 1

DICYCLOHEXYLAMINE

2565

1,2-Dichloroethane, see l ,2-DICHLOROETHYLENE Di(2-chloroethyl) ether, see DICHLOROFLUOROMETHANE alpha-Dichlorohydrin, see DICHLOROISOCYANURIC ACID. DRY

Dicyclohexylamine nitrite, see 2687 DICYCLOHEXYLAMMONIUM NITRITE

2687

DICYCLOPENTADIENE

2048

Name and description

UN

No.

Class Remarks Name and description

ETHANE

Di-(2-ethylhexyl) phosphoric acid, see

DIDYMIUM NITRATE

DIETHYL KETONE

DIESEL FUEL

DIETHYL SULPHATE

l , l -Diethoxyethane, see

DIETHYL SULPHIDE

1,2-Diethoxyethane,see

DIETHYLTHIOPHOSPHORYL CHLORIDE

DIETHOXYMETHANE Diethylzinc, see 3,3-DIETHOXYPROPENE 2,4-Difluoroaniline, see DIETHYLAMINE Difluorochloroethane, see 2-DIETHYLAMINOETHANOL 3-DIETHYLAMINOPROPYLAMINE DIFLUOROMETHANE N,N-DIETHYLANILINE Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 10% difluoromethane and 70% pentafluoroethane, see

DIETHYLBENZENE Diethylcarbinol, see DIETHYL CARBONATE DIETHYLDICHLOROSILANE

Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 20% difluoromethane and 40% pentafluoroethane, see

Diethylenediamine, see DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile, waterinsoluble phlegmatizer, by mass DIETHYLENETRIAMINE

2079

8

N,N-Diethylethanolamine, see 2686

3

DIETHYL ETHER

1155

3

N,N-DIETHYLETHYLENEDIAMINE

2685

8

Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 23%difluoromethane and 25% pentafluoroethane, see DIFLUOROPHOSPHORIC ACID, ANHYDROUS

UN Class Remarks No.

Name and description

UN

DIISOBUTYLAMINE

2361

3

D11SOBUTYLENE, ISOMERIC COMPOUNDS

2050

3

alpha-Diisobutylene, see

2050

3

beta-Diisobutylene, see

2050

3

DIISOBUTYL KETONE

1157

3

DIISOOCTYL ACID PHOSPHATE

1902

8

N,N-DIMETHYLCYCLOHEXYLAMINE

DIISOPROPYLAMINE

1158

3

DIMETHYLDICHLOROSILANE

DIISOPROPYL ETHER

1159

3

DIKETENE, STABILIZED

252 1 6.1

DIMETHYLDIETHOXYSILANE

1,l-DIMETHOXYETHANE

2377

3

DIMETHYLDIOXANES

l ,2-DIMETHOXYETHANE

2252

3

DIMETHYL DISULPHIDE

Dimethoxystrychnine, see

1570 6.1

Dimethylethanolamine, see

DIMETHYLAMINE, ANHYDROUS

1032

2

DIMETHYL ETHER

No.

Class Remarks Name and description 1,3-DIMETHYLBUTYLAMlNE DIMETHYLCARBAMOYL CHLORIDE DIMETHYL CARBONATE DIMETHYLCYCLOHEXANES

DIMETHYLAMTNE AQUEOUS SOLUTION

1160

3

N,N-DIMETHYLFORMAMIDE

2-DIMETHYLAMINOACETONITRILE

2378

3

DIMETHYLHYDRAZINE, SYMMETRICAL

8

DIMETHYLHYDRAZINE, UNSYMMETRICAL

2-DIMETHYLAMINOETHANOL

2051

l , l -Dimethylhydrazine, see 2-DIMETHYL3302 6.1 AMINOETHYL ACRYLATE 2-DIMETHYLArnOETHYL METHACRYLATE

N,N-Dimethyl-4nitrosoaniline. see

2522 6.1

DIMETHYL-NPROPYLAMINE Dimethylarsenic acid, see

1572 6.1

N,N-Dimethylbenzylamine, see

26 19

8

DIMETHYL SULPHATE DIMETHYL SULPHIDE

UN Class Remarks No.

Name and description DIMETHYL THIOPHOSPHORYL CHLORIDE Dimethylzinc, see DINGU, see

UN Class Remarks Name and description No.

UN Class Remarks No.

Dinitrotoluene mixed with sodium chlorate, see DINITROTOLUENES, LIQUID

DINITROANILINES

DINITROTOLUENES, MOLTEN

DINITROBENZENES, LIQUID

DINITROTOLUENES, SOLID

DINITROBENZENES, SOLID

DIOXANE DIOXOLANE

Dinitrochlorobenzene, see DIPENTENE

DINITROGEN TETROXIDE DINITROGLYCOLURIL

DIPHENYLAMINE CHLOROARSINE DIPHENYLCHLOROARSINE, LIQUID

DINITROPHENOL, dry or wetted with less than 15% water, by mass

DIPHENYLCHLOROARSINE, SOLID

DINITROPHENOL SOLUTION

DIPHENYLDICHLOROSILANE

DINITROPHENOL, WETTED with not less than 15% water, by mass

DIPHENYLMETHANE-4,4'- 9004 DIISOCYANATE

9

DIPHENYLMETHYL BROMIDE

8

DINITROPHENOLATES, alkali metals, dry or wetted with less than 15% water, by mass DINITROPHENOLATES, WETTED with not less than 15% water, by mass DINITRORESORCINOL, dry or wetted with less than 15% water, by mass

DIPICRYLAMINE, see DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass DIPICRYL SULPHIDE, WETTED with not less than 10% water, by mass DIPROPYLAMINE

DINITRORESORCINOL, WETTED with not less than 15% water, by mass

Dipropylene triamine, see DI-n-PROPYL ETHER

DINITROSOBENZENE DIPROPYL KETONE

1770

Dmgerous in tank vessels only

Name and description DISINFECTANT, LIQUID, CORROSIVE, N.O.S.

UN Class Remarks Name and description No. 1903

8

DISINFECTANT, LIQUID, TOXIC, N.O.S. DISINFECTANT, SOLID, TOXIC, N.O.S. DISODIUM TRIOXOSILICATE DIVINYL ETHER, STABILIZED DODECYLTRICHLOROSILANE Dry ice, see

1845

9

Not

UN Class Remarks No.

Electrolyte (acid or alkaline) for batteries, see

2796 2797

8 8

ELEVATED TEMPERATURE LIQUID, N.O.S., at or above l00 "C and below its flash-point (including molten metals, molten salts, etc.)

3257

9

ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flash-point above 60 "C, at or above its flash-point

3256

3

ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 "C

3258

9

subject to ADN Empty battery-vehicle,

uncleaned

DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S.

of ADR, 5.1.3 and 5.4.1.1.6

1602 6.1

DYE INTERMEDIATE, 3147 SOLID, CORROSIVE, N.O.S. DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. DYE, LIQUID, CORROSIVE, N.O.S.

See 4.3.2.4

Empty IBC, uncleaned

8

3143 6.1

See 4.1.1.11 of ADR, 5.1.3 and 5.4.1.1.6

Empty large packaging, uncleaned

See 4.1.1.11

of ADR,

2801

5.1.3 and 5.4.1.1.6

8

Empty MEGC, uncleaned

DYE, LIQUID, TOXIC, N.O.S.

1602 6.1

DYE, SOLID, CORROSIVE, N.O.S.

3 147

8

See 4.3.2.4

of ADR, 5.1.3 and 5.4.1.1.6

Empty packaging, uncleaned

See 4.1.1.11

of ADR, 5.1.3 and 5.4.1.1.6

DYE, SOLID, TOXIC, N.O.S. 3 143 6.1 Dynamite, see

0081

1

Electric storage batteries, see

2794 2795 2800 3028

8 8 8 8

Empty receptacle, uncleaned

See 5.1.3 and 5.4.1.1.6

Name and description

UN Class Remarks Name and description No.

Empty tank, uncleaned

Empty vehicle, uncleaned

Enamel, see

Engines, internal combustion

1263 3066 3469 3470 3 166

3 8 3 8 9

UN Class Remarks

No.

See ETHANE, REFRIGERATED 1961 4-3.2.4 LIQUID of ADR, 5.1.3 and Ethanethiol, see 5.4.1.1.6

2

ETHANOL See 5.1.3 and 5.4.1.1.6 ETHANOL SOLUTION

1170

3

1170

3

ETHANOLAMINE

2491

8

ETHANOLAMINE SOLUTION

2491

8

1155

3

ETHERS, N.O.S.

3271

3

2-Ethoxyethanol, see

1171

3

2-Ethoxyethyl acetate, see

1172

3

Ethoxy propane- l , see

2615

3

ETHYL ACETATE

1173

3

ETHYLACETYLENE, STABILIZED

2452

2

ETHYL ACRYLATE, STABILIZED

1917

3

ETHYL ALCOHOL, see

1170

3

ETHYL ALCOHOL SOLUTION, see

1170

3

ETHYLAMINE

1036

2

ETHYLAMINE, AQUEOUS 2270 SOLUTION with not less than 50% but not more than 70% ethylamine

3

ETHYL AMYL KETONE

2271

3

Not

subject Ether, see to ADN

Engines, rocket, see

0250 0322

1 1

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

3082

9

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

3077

EPIBROMOHYDRIN

2558 6.1

EPICHLOROHYDRIN

2023 6.1

1,2-Epoxybutane, stabilized, see

3022

Epoxyethane, see

1040

2

1,2-EPOXY-3ETHOXYPROPANE

2752

3

2,3-Epoxy-1-propanal, see

2622

3

2,3-Epoxypropyl ethyl ether, see

2752

3

ESTERS, N.O.S.

3272

3

N-ETHYLANILINE

2272 6.1

Ethanal, see

l089

3

2-ETHYLANILINE

2273 6.1

ETHANE

1035

2

ETHYLBENZENE

1175

9

3

3

Name and description N-ETHYL-NBENZYLANILINE N-ETHYLBENZYLTOLUIDINES, LIQUID N-ETHYLBENZYLTOLUIDMES, SOLID ETHYL BORATE

UN Class Remarks Name and description No.

ETHYLENE, ACETYLENE 3 138 AND PROPYLENE MIXTURE, REFRIGERATED LIQUID containing at least 71S % ethylene with not more than 22.5% acetylene and not more than 6% propylene ETHYLENE CHLOROHYDRIN

ETHYL BROMIDE ETHYLENE ETHYL BROMOACETATE ETHYLENEDIAMINE 2-ETHYLBUTANOL ETHYLENE DIBROMIDE 2-ETHYLBUTYL ACETATE ETHYL BUTYL ETHER 2ETHYLBUTYRALDEHYDE ETHYL BUTYRATE

Ethylene dibromide and methyl bromide, liquid mixture, see

ETHYLENE DICHLORIDE ETHYLENE GLYCOL DIETHYL ETHER

ETHYL CHLORIDE ETHYL CHLOROACETATE Ethyl chlorocarbonate, see

ETHYL CHLOROFORMATE ETHYL 2-CHLOROPROPIONATE

ETHYLENE GLYCOL MONOETHYL ETHER ETHYLENE GLYCOL MONOETHYL ETHER ACETATE ETHYLENE GLYCOL MONOMETHYL ETHER

Ethyl-alpha-chloropropionate, see

ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE

ETHYL CHLOROTHIOFORMATE

ETHYLENEIMINE, STABILIZED

ETHYL CROTONATE

ETHYLENE OXIDE

ETHYLDICHLOROARSINE

ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxide

ETHYLDICHLOROSILANE

UN Class Remarks No. 2

Name and description ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide

UN

No. 104 1

Class Remarks Name and description 2

2-ETHYLHEXYL CHLOROFORMATE

Ethylidene chloride, see ETHYL ISOBUTYRATE

ETHYLENE OXIDE AND 1952 CARBON DIOXIDE MlXTURE with not more than 9% ethylene oxide

2

ETHYLENE OXIDE AND 3297 CHLOROTETRAFLUOROETHANE MIXTURE with not more than 8.8% ethylene oxide

2

ETHYL ISOCYANATE ETHYL LACTATE ETHYL MERCAPTAN ETHYL METHACRYLATE, STABILIZED ETHYL METHYL ETHER

ETHYLENE OXIDE AND 3070 DICHLORODIFLUOROMETHANE MIXTURE with not more than 12.5% ethylene oxide

2

ETHYLENE OXIDE AND 3298 PENTAFLUOROETHANE MIXTURE with not more than 7.9% ethylene oxide

2

ETHYLENE OXIDE AND PROPYLENE OXIDE MIXTURE, not more than 30% ethylene oxide

3

2983

ETHYLMETHYLKETONE ETHYL NITRITE SOLUTION ETHYL ORTHOFORMATE ETHYL OXALATE ETHYLPHENYLDICHLOROSILANE 1-ETHYLPIPERIDINE ETHYL PROPIONATE

ETHYLENE OXIDE AND 3299 TETRAFLUOROETHANE MIXTURE with not more than 5.6% ethylene oxide ETHYLENE OXIDE WITH NITROGEN up to a total pressure of I MPa (l 0 bar) at 50 "C ETHYLENE, REFRIGERATED LIQUID ETHYL ETHER, see ETHYL FLUORIDE

2 ETHYL PROPYL ETHER Ethyl silicate, see

Ethyl sulphate, see N-ETHYLTOLUIDINES ETHYLTRICHLOROSILANE EXPLOSIVE, BLASTING, TYPE A EXPLOSIVE, BLASTING, TYPE B

ETHYL FORMATE 2-ETHYLHEXYLAMINE

EXPLOSIVE, BLASTING, TYPE C

UN Class Remarks

No.

Name and description

UN Class Remarks Name and description No.

UN Class Remarks No.

EXPLOSIVE, BLASTING, TYPE D

FERROSILICON with 30% or 1408 more but less than 90% silicon

EXPLOSIVE, BLASTING, TYPE E

FERROUS ARSENATE

1608

FERROUS METAL BORINGS in a form liable to self-heating

2793

Explosives, emulsion, see

Explosive, seismic, see

FERROUS METAL 2793 CUTTINGS in a form liable to self-heating FERROUS METAL SHAVINGS in a form liable to self-heating

2793

FERROUS METAL TURNINGS in a form liable to self-heating

2793

1043

EXTRACTS, FLAVOURING, LIQUID

FERTILIZER AMMONIATING SOLUTION with free ammonia

FABRICS, ANIMAL, N.O.S. with oil

Fertilizer with ammonium nitrate, n.o.s., see

2067

FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S.

Fibres, animal, burnt wet or damp

1372

FIBRES, ANIMAL, N.O.S. with oil

1373

FIBRES IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S.

1353

FIBRES, SYNTHETIC, N.O.S. with oil

1373

Explosive, slurry, see

Explosive, water gel, see

EXTRACTS, AROMATIC, LIQUID

FABRICS, SYNTHETIC, N.O.S. with oil FABRICS, VEGETABLE, N.O.S. with oil FERRIC ARSENATE FERRIC ARSENITE FERRIC CHLORIDE, ANHYDROUS FERRIC CHLORIDE SOLUTION FERRIC NITRATE FERROCERIUM

Fibres, vegetable, burnt wet or 1372 damp Fibres, vegetable, dry

3360

FIBRES, VEGETABLE, N.O.S. with oil

1373

Not subject to ADN

Not subject to ADN Not subject to ADN

Name and description Filler, liquid, see

Films, nitrocellulose base, from which gelatin has been removed; film scrap, see

UN No.

Class Remarks Name and description

1263 3 3066 8 3469 3 3470 8 2002 4.2

FILMS, NITROCELLULOSE 1324 4.1 BASE, gelatin coated, except scrap FIRE EXTINGUISHER CHARGES, corrosive liquid

1774

8

Fire extinguisher charges, expelling, explosive, see

0275 0276 0323 0381

1 1 1 1

FIRE EXTINGUISHERS with 1044 compressed or liquefied gas

2

FIRELIGHTERS, SOLID with flammable liquid

2623 4.1

FIREWORKS

0333 0334 0335 0336 0337

1 1 1 1 1

FIRST AID KIT

3316

9

FISH MEAL, STABILIZED FISH MEAL, UNSTABILIZED

2216 9 1374 4.2

FISH SCRAP, STABILIZED, 2216 9 see FISH SCRAP, 1374 4.2 UNSTABILIZED, see Flammable gas in lighters, see 1057

2

FLAMMABLE LIQUID, N.0.S

1993

3

FLAMMABLE LIQUID, CORROSIVE, N.O.S.

2924

3

UN Class Remarks No.

FLAMMABLE LIQUID, TOXIC, N.O.S.

1992

3

FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S.

3286

3

FLAMMABLE SOLID, 3180 4.1 CORROSIVE, INORGANIC, N.O.S. FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S.

2925 4.1

FLAMMABLE SOLID, INORGANIC, N.O.S.

3178 4.1

FLAMMABLE SOLID, ORGANIC, N.O.S.

1325 4.1

FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S.

3176 4.1

FLAMMABLE SOLID, See OXIDIZING, N.O.S. 2.2.1.1.7 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S.

3097 4.1

Carriage prohibited

3179 4.1

FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.

2926 4.1

FLARES, AERIAL

0093 0403 0404 0420 0421

1 1 1 1 1

Flares, aeroplane, see

0093 0403 0404 0420 0421

1 1 1 1 1

Flares, highway, Flares, distress, small, Flares, railway or highway, see

0191 0373

1 1

Name and description

UN

No.

Class Remarks Name and description

FLARES, SURFACE

FORMALDEHYDE SOLUTION, FLAMMABLE Formalin, see

Flares, water-activated, see Formamidine sulphinic acid, see

FLASH POWDER

FORMIC ACID with more than Flue dusts, toxic, see

85% acid by mass FORMIC ACID with not more than 85% acid by mass

Fluoric acid, see

Formic aldehyde, see FLUORINE, COMPRESSED

2-Formyl-3,4-dihydro-2Hpyran, see

FLUOROACETIC ACID FLUOROANILINES

FRACTURING DEVICES, EXPLOSIVE without detonator. for oil wells

2-Fluoroaniline, see 4-Fluoroaniline, see o-Fluoroaniline, see

FUEL, AVIATION, TURBINE ENGINE

p-Fluoroaniline, see

FUEL CELL CARTRIDGES

FLUOROBENZENE

Fumaroyl dichloride, see

FLUOROBORIC ACID

FUMARYL CHLORIDE

Fluoroethane, see

FUMIGATED UNIT

Fluoroform, see

FURALDEHYDES

Fluoromethane, see

FURAN

FLUOROPHOSPHORIC ACID, ANHYDROUS

FURFURYL ALCOHOL FURFURYLAMINE

FLUOROSILICATES, N.O.S. Fury1 carbinol, see FLUOROSILICIC ACID FUSE, DETONATING, metal clad

FLUOROSULPHONIC ACID

FUSE, DETONATING, MILD EFFECT, metal clad

FLUOROTOLUENES FORMALDEHYDE 2209 SOLUTION with not less than 25% formaldehyde

8

FUSE, IGNITER, tubular, metal clad

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

UN Class Remarks No.

FUSE, NON-DETONATING

0 10 1

3167

FUSEL OIL

1201

FUSE, SAFETY

0105

GAS SAMPLE, NONPRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid

GAS SAMPLE, NON3169 PRESSURIZED, TOXIC, N.O.S., not refrigerated liquid

Fuze, combination, percussion 0106 or time, see 0107 0257 03 16 03 17 0367 0368

GAS SAMPLE, NONPRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid

3168

FUZES, DETONATING

Gelatin, blasting, see

0081

Gelatin, dynamites, see

008 1

0106 0107 0257 0367

FUZES, DETONATING with 0408 protective features 0409 0410 FUZES, IGNITING

GALLIUM

0316 0317 0368

GENETICALLY MODIFIED 3245 MICRO-ORGANISMS GENETICALLY MODIFIED 3245 ORGANISMS GERMANE

2192

Germanium hydride, see

2192

2803 Glycer- l ,3-dichlorohydrin, see 2750

GAS CARTRIDGES without a release device, nonrefillable, see

2037

Gas drips, hydrocarbon, see

3295

GAS OIL

1202

GASOLINE

1203

Gasoline, casinghead, see

1203

GAS, REFRIGERATED LIQUID, N.O.S.

3158

GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S.

3312

GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S.

331 1

GLYCEROL alphaMONOCHLOROHYDRIN

2689

Glyceryl trinitrate, see

0143 0144 1204 3064

GLYCIDALDEHYDE

2622

GRENADES, hand or rifle, with bursting charge

0284 0285 0292 0293

Grenades, illuminating, see

0171 0254 0297

GRENADES, PRACTICE, hand or rifle

01 10 0318 0372 0452

Name and description

UN Class Remarks Name and description No.

Grenades, smoke, see

0015 0016 0245 0246 0303

1 1 1 1 1

n-Heptanal, see HEPTANES 4-Heptanone, see

GUANIDINE NITRATE

1467 5.1

n-HEPTENE

GUANYLNITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass

0 1 13

HEXACHLOROACETONE

GUANYLNITROSAMINOGUANYLTETRAZENE, WETTED with not less than 30% water, or mixture of alcohol and water, by mass

0 114

GUNPOWDER, COMPRESSED, see

0028

1

GUNPOWDER, granular or as 0027 a meal, see

1

GUNPOWDER, IN PELLETS, see

0028

1

Gutta percha solution, see

1287

HAFNIUM POWDER, DRY

2545 4.2

HAFNIUM POWDER, WETTED with not less than 25% water

1326 4.1

1

HEXACHLOROBENZENE HEXACHLOROBUTADIENE 1 Hexachloro-l ,3-butadiene, see HEXACHLOROCYCLOPENTADIENE HEXACHLOROPHENE Hexachloro-2-propanone,see HEXADECYLTRJCHLOROSILANE HEXADIENES 3

1327 4.1

HEXAETHYL TETRAPHOSPHATE HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE Not HEXAFLUOROACETONE subject to ADN HEXAFLUOROACETONE HYDRATE, LIQUID

HEATING OIL, LIGHT

1202

3

Heavy hydrogen, see

1957

2

HEXAFLUOROACETONE HYDRATE, SOLID

HELIUM, COMPRESSED

1046

2

HEXAFLUOROETHANE

HELIUM, REFRIGERATED LIQUID

1963

2

HEXAFLUOROPHOSPHORIC ACID

HEPTAFLUOROPROPANE

3296

2

HEXAFLUOROPROPYLENE

UN Class Remarks

No.

Name and description

UN Class Remarks Name and description No.

Hexahydrocresol, see

2617

3

Hexahydromethyl phenol, see 26 17

3

UN Class Remarks No.

HEXOLITE, dry or wetted with less than 15% water, by mass

01 18

1

HEXOTOL, dry or wetted with less than 15% water, by mass, see

0 118

1

HEXOTONAL

0393

1

HEXOTONAL, cast, see

0393

1

HEXYL, see

0079

1

HEXYLTRICHLOROSILANE

1784

8

HMX, see

0391

1

HMX, DESENSITIZED, see

0484

1

HMX, WETTED with not less 0226 than 15% water, by mass, see

1

HEXANES HEXANITRODIPHENYLAMINE

HYDRAZINE, ANHYDROUS

2029

8

HEXANITROSTILBENE

HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass

2030

8

HEXANOLS

HYDRAZINE, AQUEOUS SOLUTION with not more than 37% hydrazine, by mass

3293 6.1

HEXOGEN AND CYCLOTETRAMETHYLENETETRANITRAMINE MIXTURE, WETTED with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegmatiser by mass, see

Hydrides, metal, waterreactive, n.o.s., see

1409 4.3

Hydriodic acid, anhydrous, see

2197

2

HYDRIODIC ACID

1787

8

HYDROBROMIC ACID

1788

8

HYDROCARBONGAS MIXTURE, COMPRESSED, N.O.S.

1964

2

HEXALDEHYDE HEXAMETHYLENEDIAMINE, SOLID HEXAMETHYLENEDIAMINE SOLUTION HEXAMETHYLENE DIISOCYANATE HEXAMETHYLENEIMINE HEXAMETHYLENETETRAMINE Hexamine, see

Hexanoic acid. see

HEXOGEN, DESENSITIZED, see

0483

1

HEXOGEN, WETTED with not less than 15% water, by mass, see

0072

1

Name and description HYDROCARBONGAS MIXTURE, LIQUEFIED, N.O.S. such as mixtures A, AOl,A02,AO,Al, B1, B2,B or C

UN Class Remarks Name and description No. 1965

2

HYDROCARBONGAS 3150 REFILLS FOR SMALL DEVICES with release device

2

HYDROCARBONS, LIQUID, N.O.S.

3295

3

HYDROCHLORIC ACID

1789

8

HYDROCYANIC ACID, 1613 6.1 AQUEOUS SOLUTION with not inore than 20% hydrogen cyanide HYDROFLUORIC ACID with more than 60% but not more than 85% hydrogen fluoride HYDROFLUORIC ACID with more than 85% hydrogen fluoride

UN Class Remarks No.

HYDROGEN CHLORIDE, ANHYDROUS

1050

2

HYDROGEN CHLORIDE, REFRIGERATED LIQUID

2 186

2

HYDROGEN, COMPRESSED

1049

prohi-

bited 2

HYDROGEN CYANIDE, 1613 6.1 AQUEOUS SOLUTION with not more than 20% hydrogen cyanide, see HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45% hydrogen cyanide

3294 6.1

HYDROGEN CYANIDE, 10.51 6.1 STABILIZED containing less than 3% water HYDROGEN CYANIDE, 1614 6.1 STABILIZED, containing less than 3% water and absorbed in a porous inert material 1740

8

HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE

HYDROGEN3471 DIFLUORIDES SOLUTION, N.O.S.

8

Hydrofluoroboric acid, see

HYDROGEN FLUORIDE, ANHYDROUS

1052

8

Hydrogen fluoride solution, see

1790

8

2

3468

Hydrogen arsenide, see

HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM

HYDROGEN BROMIDE, ANHYDROUS

HYDROGEN IODIDE, ANHYDROUS

2197

2

Hydrogen bromide solution, see

Hydrogen iodide solution, see 1787

8

HYDROFLUORIC ACID with not more than 60% hydrogen fluoride

HYDROGENDIFLUORIDES, SOLID, N.O.S.

Hydrofluorosilicic acid, see HYDROGEN AND METHANE MIXTURE, COMPRESSED

Carriage

Name and description

UN Class Remarks Name and description No.

HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE with acid(s), water and not more than 5% peroxyacetic acid, STABILIZED

3 149 5.1

HYDROGEN PEROXIDE, 2984 5.1 AQUEOUS SOLUTION with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary) HYDROGEN PEROXIDE, 20 14 5.1 AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) HYDROGEN PEROXIDE, 20 15 5.1 AQUEOUS SOLUTION, STABILIZED with more than 60% hydrogen peroxide and not more than 70% hydrogen peroxide HYDROGEN PEROXIDE, 201 5 5.1 AQUEOUS SOLUTION, STABILIZED with more than 70% hydrogen peroxide HYDROGEN, REFRIGERATED LIQUID HYDROGEN SELENIDE, ANHYDROUS

3-Hydroxyphenol, see HYPOCHLORITES, INORGANIC, N.O.S. HYPOCHLORITE SOLUTION IGNITERS

3,3'-IMINODIPROPYLAMINE Indiarubber, see

INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only

INFECTIOUS SUBSTANCE, AFFECTING HUMANS Ink, printer's, flammable, see INSECTICIDE GAS, N.O.S. INSECTICIDE GAS, FLAMMABLE, N.O.S. INSECTICIDE GAS, TOXIC, N.O.S.

Hydrogen silicide, see

INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S.

HYDROGEN SULPHIDE

IODINE MONOCHLORIDE

Hydroselenic acid, see

IODINE PENTAFLUORIDE

Hydrosilicofluoric acid, see 3-Hydroxybutan-2-one, see

Iodomethane, see

HYDROXYLAMINE SULPHATE

IODOMETHYLPROPANES IODOPROPANES

l -Hydroxy-3-methyl-2penten-4-yne, see

alpha-Iodotoluene, see

UN Class Remarks

No.

Name and description

UN Class Remarks Name and description No.

I.p.d.i., see

ISOBUTYL ISOCYANATE

Iron chloride, anhydrous, see

ISOBUTYL METHACRYLATE, STABILIZED

Iron (111) chloride, anhydrous, see

ISOBUTYL PROPIONATE Iron chloride solution, see ISOBUTYRALDEHYDE IRON OXIDE, SPENT obtained from coal gas purification

ISOBUTYRIC ACID ISOBUTYRONITRILE

IRON PENTACARBONYL ISOBUTYRYL CHLORIDE Iron perchloride, anhydrous, see Iron powder, pyrophoric, see

ISOCYANATES, FLAMMABLE, TOXIC, N.O.S.

Iron sesquichloride, anhydrous, see

ISOCYANATES, TOXIC, N.O.S.

IRON SPONGE, SPENT obtained from coal gas purification

ISOCYANATES, TOXIC, FLAMMABLE, N.O.S.

Iron swarf, see

ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S.

ISOBUTANE ISOBUTANOL

ISOCYANATE SOLUTION, TOXIC, N.O.S.

ISOBUTYLACETATE

ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S.

ISOBUTYL ACRYLATE, STABILIZED

ISOCYANATOBENZOTRIFLUORIDES

ISOBUTYL ALCOHOL, see

3-Isocyanatomethyl-3,5,5-trimethy Icy clohexyl isocyanate, see

Isobutene, see

ISOBUTYL ALDEHYDE, see

Isododecane, see ISOBUTYLAMINE I SOHEPTENE ISOBUTYLENE

I SOHEXENE ISOBUTYL FORMATE Isooctane, see ISOBUTYL ISOBUTYRATE ISOOCTENE

UN Class Remarks

No.

Name and description Isopentane, see

UN Class Remarks Name and description No. ISOPROPYL ISOBUTYRATE

ISOPENTENES ISOPROPYL ISOCYANATE Isopentylamine, see Isopropyl mercaptan, see Isopentyl nitrite, see ISOPROPYL NITRATE ISOPHORONEDIAMINE ISOPROPYL PROPIONATE ISOPHORONE DIISOCYANATE

Isolpropyltoluene, see

ISOPRENE, STABILIZED

Isopropyltoluol, see

ISOPROPANOL

ISOSORBIDE DINITRATE MIXTURE with not less than 60% lactose, mannose, starch or calcium hydrogen phosphate

ISOPROPENYL ACETATE ISOPROPENYLBENZENE ISOPROPYL ACETATE ISOPROPYL ACID PHOSPHATE ISOPROPYL ALCOHOL, see ISOPROPYLAMINE ISOPROPYLBENZENE

ISOSORBIDE-5MONONITRATE Isovaleraldehyde, see JET PERFORATING GUNS, CHARGED, oil well, without detonator Jet tappers, without detonator, see

ISOPROPYL BUTYRATE KEROSENE Isopropyl chloride, see KETONES, LIQUID, N.O.S. ISOPROPYL CHLOROACETATE

KRYPTON, COMPRESSED

ISOPROPYL CHLOROFORMATE

KRYPTON, REFRIGERATED LIQUID

ISOPROPYL 2-CHLOROPROPIONATE

Lacquer, see

Isopropyl-alphachloropropionate, see

Lacquer base, liquid, see

Isopropyl ether, see Isopropylethylene, see Isopropyl formate, see

Lacquer base or lacquer chips, nitrocellulose, dry, see

UN Class Remarks No.

Name and description

UN

No.

Lacquer base or lacquer chips, 1263 plasiic, wet with alcohol or solvent, see

Class Remarks Name and description 3

Lead tetraethyl, see Lead tetramethyl, see LEAD TRINITRORESORCINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass, see

LEAD ACETATE Lead (11) acetate, see LEAD ARSENATES

LIFE-SAVING APPLIANCES NOT SELFINFLATING containing dangerous goods as equipment

LEAD ARSENITES LEAD AZIDE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass

LIFE-SAVING APPLIANCES, SELFINFLATING

Lead chloride, solid, see LIGHTER REFILLS containing flammable gas

LEAD COMPOUND, SOLUBLE, N.O.S. LEAD CYANIDE

LIGHTERS containing flammable gas

Lead (11) cyanide

LIGHTERS, FUSE

LEAD DIOXIDE

Limonene, inactive, see

LEAD NITRATE

LIQUEFIED GAS, N.O.S.

Lead (11) nitrate

LIQUEFIED GAS, FLAMMABLE, N.O.S.

LEAD PERCHLORATE, SOLID

LIQUEFIED GASES, nonflammable, charged with nitrogen, carbon dioxide or air

LEAD PERCHLORATE, SOLUTION

LIQUEFIED GAS, OXIDIZING, N.O.S.

Lead (11) perchlorate Lead peroxide, see

LIQUEFIED GAS, TOXIC, N.O.S.

LEAD PHOSPHITE, DIBASIC

LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S.

LEAD STYPHNATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass LEAD SULPHATE with more 1794 than 3% free acid

LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S.

8

LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S.

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

UN Class Remarks No.

LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S.

LITHIUM HYPOCHLORITE, 1471 5.1 DRY

LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S.

LITHIUM HYPOCHLORITE 1471 5.1 MIXTURE Lithium in cartouches, see

1415 4.3

LITHIUM NITRATE

2722

LITHIUM NITRIDE

2806 4.3

LITHIUM PEROXIDE

1472 5.1

Lithium silicide, see

1417 4.3

LITHIUM SILICON

1417 4.3

L.n.g., see

1972

LONDON PURPLE

1621 6.1

L.p.g., see

1075

2

Lye, see

1823

8

Lythene, see

1268

3

MAGNESIUM in pellets, turnings or ribbons

1869 4.1

Magnesium akyls, see

3394 4.2

Liquefied petroleum gas, see 5.1

Liquid filler, see

Liquid lacquer base, see

LITHIUM 2

Lithium alkyls, liquid, see Lithium alkyls, solid, see LITHIUM ALUMINIUM HYDRIDE LITHIUM ALUMINIUM HYDRIDE, ETHEREAL LITHIUM BATTERIES LITHIUM BATTERIES CONTAINED IN EQUIPMENT LITHIUM BATTERIES PACKED WITH EQUIPMENT

MAGNESIUM ALLOYS with l869 4.1 more than 50% magnesium in pellets, turnings or ribbons MAGNESIUM ALLOYS POWDER

1418 4.3

LITHIUM BOROHYDRIDE LITHIUM FERROSILICON

MAGNESIUM ALUMINIUM 1419 4.3 PHOSPHIDE

LITHIUM HYDRIDE

MAGNESIUM ARSENATE

l622 6.1

LITHIUM HYDRIDE, FUSED SOLID

Magnesium bisulphite solution, see

2693

LITHIUM HYDROXIDE

MAGNESIUM BROMATE

1473 5.1

LITHIUM HYDROXIDE SOLUTION

MAGNESIUM CHLORATE

2723 5.1

8

Name and description

UN

No.

Class Remarks Name and description MANEB PREPARATION, STABILIZED against selfheating

Magnesium chloride and chlorate mixture. see MAGNESIUM DIAMIDE Magnesium diphenyl, see

MANEB, STABILIZED against self-heating

MAGNESIUM FLUOROSILICATE

Manganese ethylene-didithiocarbamate, see

MAGNESIUM GRANULES, COATED, particle size not less than 149 microns

Manganese ethylene- 1,2dithiocarbamate, see MANGANESE NITRATE

MAGNESIUM HYDRIDE Manganese (11) nitrate, see MAGNESIUM NITRATE MANGANESE RESINATE MAGNESIUM PERCHLORATE

Manganous nitrate, see

MAGNESIUM POWDER

MANNITOL HEXANITRATE, WETTED with not less than 40% water, or mixture of alcohol and water, by mass

Magnesium scrap, see

MATCHES, FUSEE

MAGNESIUM SILICIDE

MATCHES, SAFETY (book, card or strike on box)

MAGNESIUM PEROXIDE MAGNESIUM PHOSPHIDE

Magnesium silicofluoride, see Magnetized material

2807

9

Not subject to ADN

MATCHES, "STRIKE ANYWHERE" MATCHES, WAX "VESTA"

MALEIC ANHYDRIDE

MEDICAL WASTE, N.O.S.

MALEIC ANHYDRIDE, MOLTEN

MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S.

Malonic dinitrile, see Malonodinitrile, see MALONONITRILE MANEB MANEB PREPARATION with not less than 60% maneb

MEDICINE, LIQUID, TOXIC, N.O.S. MEDICINE, SOLID, TOXIC, N.O.S. p-Mentha- l ,8-diene, see MERCAPTANS, LIQUID, FLAMMABLE, N.O.S.

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S.

MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C

2778

MERCURY BASED PESTICIDE, LIQUID, TOXIC

3012 6.1

MERCURY BASED PESTICIDE, SOLID, TOXIC MERCURY BENZOATE Mercury bichloride, see MERCURY BROMIDES

2-Mercaptopropionic acid, see 2936 6.1 MERCURY COMPOUND, LIQUID, N.O.S.

MERCURIC ARSENATE

MERCURY COMPOUND, SOLID, N.O.S.

MERCURIC CHLORIDE

MERCURY CYANIDE

MERCURIC NITRATE MERCURIC POTASSIUM CYANIDE

MERCURY FULMINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass

Mercuric sulphate, see

MERCURY GLUCONATE

Mercurol, see

MERCURY IODIDE

Mercurous bisulphate, see

MERCURY NUCLEATE

MERCUROUS NITRATE

MERCURY OLEATE

Mercurous sulphate, see

MERCURY OXIDE

MERCURY

MERCURY OXYCYANIDE, DESENSITIZED

MERCURY ACETATE MERCURY AMMONIUM CHLORIDE

3

MERCURY BASED 3011 6.1 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

2-Mercaptoethanol, see

5-MERCAPTOTETRAZOL1-ACETIC ACID

UN Class Remarks No.

MERCURY POTASSIUM IODIDE MERCURY SALICYLATE

Name and description MERCURY SULPHATE

UN Class Remarks Name and description No. 1645 6.1

MERCURY THIOCYANATE 1646 6.1 Metal alkyl halides, waterreactive, n.0.s. / Metal aryl halides, water-reactive, n.o.s., see Metal alkyl hydrides, waterreactive, n.0.s. 1 Metal aryl hydrides, water-reactive, n.o.s., see Metal alkyls, water-reactive, n.0.s. / Metal aryls, waterreactive, n.o.s., see Mesitylene, see

3394 4.2

2325

3

MESITYL OXIDE

1229

3

METAL CARBONYLS, LIQUID, N.O.S.

3281 6.1

3394 4.2

METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.

UN Class Remarks

No.

3181 4.1

METHACRYLALDEHYDE, STABILIZED METHACRYLIC ACID, STABILIZED METHACRYLONITRILE, STABILIZED

3393 4.2 METHALLYL ALCOHOL Methanal, see

Methane and hydrogen mixture, see METHANE. COMPRESSED

METAL CARBONYLS, SOLID, N.O.S.

3466 6.1

METAL CATALYST, DRY

2881 4.2

METAL CATALYST, WETTED with a visible excess of liquid

1378 4.2

METALDEHYDE

1332 4.1

2-Methoxyethyl acetate, see

1 189

3

METAL HYDRIDES, FLAMMABLE, N.O.S.

3182 4.1

METHOXYMETHYL ISOCYANATE

2605

3

METAL HYDRIDES, 1409 4.3 WATER-REACTIVE, N.O.S.

4-METHOXY-4METHYLPENTAN-2-ONE

2293

3

METALLIC SUBSTANCE, 3208 4.3 WATER-REACTIVE, N.O.S.

l -Methoxy-2-nitrobenzene, see

2730 6.1 3458 6.1

METALLIC SUBSTANCE, 3209 4.3 WATER-REACTIVE, SELFHEATING, N.O.S.

l -Methoxy-3-nitrobenzene, see

2730 6.1 3458 6.1

l -Methoxy-4-nitrobenzene, see

2730 6.1 3458 6.1

METHANE, REFRIGERATED LIQUID METHANESULPHONYL CHLORIDE METHANOL

METAL POWDER, FLAMMABLE, N.O.S.

3089 4.1

METAL POWDER, SELFHEATING, N.O.S.

3 l89 4.2

1-METHOXY-2-PROPANOL 3092

3

METHYL ACETATE

3

1231

Name and description

UN Class Remarks Name and description No.

METHYLACETYLENE 1060 AND PROPADIENE MIXTURE, STABILIZED such as mixture P1 or mixture P2

2

UN Class Remarks No.

METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID

1647 6.1

METHYL BROMOACETATE

2643 6.1

2-METHYLBUTANAL

3371

3

3-METHYLBUTAN-2-ONE

2397

3

beta-Methyl acrolein, see

1143 6.1

METHYL ACRYLATE, STABILIZED

1919

METHYLAL

1234

3

2-METHYL-l -BUTENE

2459

3

Methyl alcohol, see

1230

3

2-METHYL-2-BUTENE

2460

3

Methyl ally1 alcohol, see

2614

3

3-METHYL- l -BUTENE

2561

3

METHYLALLYL CHLORIDE

2554

3

N-METHYLBUTYLAMINE

2945

3 3

1061

2

METHYL tert-BUTYL ETHER

2398

METHYLAMINE, ANHYDROUS

METHYL BUTYRATE

1237

3

METHYL CHLORIDE

1063

2

Methyl chloride and chloropicrin mixture, see

1582

2

METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE

1912

2

METHYL CHLOROACETATE

2295 6.1

Methyl chlorocarbonate, see

1238 6.1

Methyl chloroform, see

2831 6.1

METHYL CHLOROFORMATE

1238 6.1

3

METHYLAMINE, AQUEOUS SOLUTION

1235

3

METHYLAMYL ACETATE

1233

3

Methyl amyl alcohol, see

2053

3

Methyl amyl ketone, see

1110

3

N-METHYLANILINE

2294 6.1

Methylated spirit, see

1986 1987

alpha-METHYLBENZYL ALCOHOL, LIQUID

293 7 6.1

alpha-METHYLBENZYL ALCOHOL. SOLID

3438 6.1

3 3

METHYL BROMIDE with 1062 not more than 2% chloropicrin

2

METHYL CHLOROMETHYL ETHER

1239 6.1

Methyl bromide and chloropicrin mixture, with more than 2% chloropicrin, see

2

METHYL 2-CHLOROPROPIONATE

2933

3

Methyl alphachloropropionate, see

2933

3

METHYLCHLOROSILANE

2534

2

1581

Name and description Methyl cyanide, see

No.

Class Remarks Name and description

UN Class Remarks No.

2-METHYL-2HEPTANETHIOL

METHYLCYCLOHEXANE METHYLCYCLOHEXANOLS, flammable METHYLCYCLOHEXANONE

METHYLHYDRAZINE METHYL IODIDE

METHYLCYCLOPENTANE

METHYL ISOBUTYL CARBINOL

METHYL DICHLOROACETATE

METHYL ISOBUTYL KETONE

METHYLDICHLOROSILANE

METHYL ISOCYANATE

Methylene bromide, see Methylene chloride, see Methylene chloride and methyl chloride mixture, see

METHYL ISOPROPENYL KETONE, STABILIZED METHYL ISOTHIOCYANATE METHYL ISOVALERATE

p,pl-Methylenedianiline, see

METHYL MAGNESIUM BROMIDE M ETHYL ETHER

Methylene dibromide, see

METHYL MERCAPTAN

2,2'-Methylene-di-(3,4,6trichlorophenol), see

Methyl mercaptopropionaldehyde, see

Methyl ethyl ether, see

METHYL METHACRYLATE MONOMER, STABILIZED

Methylene cyanide, see

METHYL ETHYL, KETONE, see 2-METHYL-5ETHYLPYRIDINE

N-METHYLMORPHOLINE, see

METHYL FLUOFUDE METHYL NITRITE METHYL FORMATE 2-METHYLFURAN Methyl glycol, see Methyl glycol acetate, see

METHYL ORTHOSILICATE METHYLPENTADIENE Methylpentanes, see

2455

2

Carriage prohibited

Name and description

4-Methylpentan-2-01, see

UN Class Remarks Name and description No.

MINES with bursting charge

3-Methyl-2-penten-4yno1, see METHYLPHENYLDICHLOROSILANE

2-Methyl-2-phenylpropane, see

Mirbane oil, see Missiles, guided, see

1-METHYLPIPERIDINE METHYL PROPIONATE Methylpropylbenzene, see METHYL PROPYL ETHER METHYL PROPYL KETONE

Mixtures A, A01 , A02, AO, A l , B1, B2, B or C, see

Methyl pyridines, see

Mixture F 1, mixture F2 or mixture F3, see

Methylstyrene, inhibited, see alpha-Methylstyrene, see Methyl sulphate, see Methyl sulphide, see METHYLTETRAHYDROFURAN

MIXTURES OF 1,3-BUTADIENE AND HYDROCARBONS, STABILIZED, having a vapour pressure at 70 'C not exceeding 1.1 MPa ( l l bar) and a density at 50 'C not lower than 0.525 kg11 Mixture P1 or mixture P2. see

METHYL TRICHLOROACETATE

MOLYBDENUM PENTACHLORIDE

METHYLTRICHLOROSILANE

Monochloroacetic acid, see

alpha-METHYLVALERALDEHYDE

Monochlorobenzene, see

Methyl vinyl benzene, inhibited, see

Monochlorodifluoromethane, see

METHYL VINYL KETONE, STABILIZED

Monochlorodifluoromethane and monochloropentafluoroethane mixture, see

M.i.b.c., see Monochlorodifluoromonobromomethane, see

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

UN Class Remarks No.

Monochloropentafluoroethane 1973 and monochlorodifluoromethane mixture, see

NATURAL GAS, REFRIGERATED LIQUID with high methane content

1972

2

Monoethylamine, see

Natural gasoline, see

1203

3

Neohexane, see

1208

3

NEON, COMPRESSED

1065

2

1036

MONONITROTOLUIDINES, 2660 see Monopropylamine, see

1277 2

2054

NEON, REFRIGERATED LIQUID

1913

MORPHOLINE MOTOR FUEL ANTIKNOCK MIXTURE

1649

Neothyl, see

2612

3

NICKEL CARBONYL

1259 6.1

MOTOR SPIRIT

1203 NICKEL CYANIDE

1653 6.1

Nickel (11) cyanide, see

1653 6.1

NICKEL NITRATE

2725 5.1

Nickel (11) nitrate, see

2725 5.1

NICKEL NITRITE

2726 5.1

Nickel (11) nitrite, see

2726 5.1

Nickelous nitrate, see

2725 5.1

Nickelous nitrite, see

2726 5.1

Nickel tetracarbonyl, see

1259 6.1

NICOTINE

1654 6.1

Muriatic acid, see

1789

MUSK XYLENE, see

2956

Mysorite, see

2212

Naphta, see

1268

Naphta, petroleum, see

1268

Naphta, solvent, see

1268

NAPHTHALENE, CRUDE

1334

NAPHTHALENE, MOLTEN 2304 NAPHTHALENE, REFINED 1334 alpha-NAPHTHYLAMINE

2077 1650

NICOTINE COMPOUND, LIQUID, N.0.S

3 144 6.1

beta-NAPHTHYLAMINE, SOLID

341 1

NICOTINE COMPOUND, SOLID, N.0.S

1655 6.1

beta-NAPHTHYLAMINE, SOLUTION

1651

NICOTINE HYDROCHLORIDE, LIQUID

1656 6.1

NAPHTHYLTHIOUREA l -Naphthylthiourea see

1651

NAPHTHYLUREA

1652

NATURAL GAS, COMPRESSED with high methane content

1971

NICOTINE 3444 6.1 HYDROCHLORIDE, SOLID NICOTINE HYDROCHLORIDE SOLUTION

1656 6.1

Name and description

UN Class Remarks Name and description No.

NICOTINE PREPARATION, 3 144 6.1 LIQUID, N.O.S. NICOTINE PREPARATION, 1655 6.1 SOLID, N.O.S.

UN Class Remarks No.

NITRIC OXIDE AND 1975 DINITROGEN TETROXIDE MIXTURE

2

NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE, see

1975

2

3273

3

NICOTINE SALICYLATE

1657 6.1

NICOTINE SULPHATE, SOLID

3445 6.1

NITRILES, FLAMMABLE, TOXIC, N.O.S.

NICOTINE SULPHATE, SOLUTION

1658 6.1

NITRILES, TOXIC, LIQUID, 3276 6.1 N.O.S.

NICOTINE TARTRATE

1659 6.1

NITRILES, TOXIC, SOLID, N.O.S.

3439 6.1

NITRATES, INORGANIC, N.O.S.

1477 5.1 NITRILES, TOXIC, FLAMMABLE, N.O.S.

3275 6.1

NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

3218 5.1 NITRITES, INORGANIC, N.O.S.

2627 5.1

NITRATING ACID MIXTURE with more than 50% nitric acid

1796

8

NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

32 19 5.1

NITRATING ACID 1796 MIXTURE with not more than 50% nitric acid

8

NITROANILINES (0-7 m-, P-)

1661 6.1

NITROANISOLES, LIQUID

2730 6.1

NITRATING ACID MIXTURE, SPENT, with more than 50% nitric acid

8 NITROANISOLES, SOLID

3458 6.1

NITROBENZENE

1662 6.1

Nitrobenzene bromide, see

2732 6.1

NITROBENZENESULPHONIC ACID

2305

Nitrobenzol, see

1662 6.1

5-NITROBENZOTRIAZOL

0385

NITROBENZOTRIFLUORIDES, LIQUID

2306 6.1

NITROBENZOTRIFLUORIDES, SOLID

343 1 6.1

NITRATING ACID MIXTURE, SPENT, with not more than 50% nitric acid

1826

1826

8

NITRIC ACID, other than red 203 1 fuming, with more than 70% nitric acid

8

NITRIC ACID, other than red 203 1 fuming, with not more than 70% nitric acid

8

NITRIC ACID, RED FUMING

2032

8

NITRIC OXIDE, COMPRESSED

1660

8

1

2 NITROBROMOBENZENES, 2732 6.1 LIQUID

Name and description

UN Class Remarks Name and description No.

NITROBROMOBENZENES, 3459 SOLID NITROCELLULOSE, dry or wetted with less than 25% water (or alcohol), by mass

0342

1

0340

NITROCELLULOSE, 0341 unmodified or plasticized with less than 18% plasticizing substance, by mass NITROCELLULOSE 3270 MEMBRANE FILTERS, with not more than 12.6% nitrogen, by dry mass NITROCELLULOSE, with 2557 not more than 12.6% nitrogen, by dry mass, MIXTURE WITH PLASTICIZER, WITH PIGMENT NITROCELLULOSE, with 2557 not more than 12.6% nitrogen, by dry mass, MIXTURE WITH PLASTICIZER, WITHOUT PIGMENT NITROCELLULOSE, with 2557 not more than 12.6% nitrogen, by dry mass, MIXTURE WITHOUT PLASTICIZER, WITH PIGMENT NITROCELLULOSE, with 2557 not more than 12.6% nitrogen, by dry mass, MIXTURE WITHOUT PLASTICIZER, WITHOUT PIGMENT NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance, by mass

NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass

UN Class Remarks No.

0343

NITROCELLULOSE 2059 SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose

NITROCELLULOSE WITH 2556 4.1 ALCOHOL (not less than 25% alcohol, by mass, and not more than 12.6% nitrogen, by dry mass) NITROCELLULOSE WITH WATER (not less than 25% water, by mass)

2555 4.1

Nitrochlorobenzenes, see

1578 6.1 3409 6.1 2307 6.1

3-NITRO-4CHLOROBENZOTRIFLUORIDE NITROCRESOLS, LIQUID

3434 6.1

NITROCRESOLS, SOLID

2446 6.1

NITROETHANE

2842

3

NITROGEN. COMPRESSED 1066

2

NITROGEN DIOXIDE, see

1067

2

NITROGEN, REFRIGERATED LIQUID

1977

2

NITROGEN TRIFLUORIDE 245 1

2

NITROGEN TRIOXIDE

2

2421

Carriage prohi-

bited NITROGLYCERIN, 0143 DESENSITIZED with not less than 40% non-volatile waterinsoluble phlegmatizer, by mass

1

NITROGLYCEFUN 3357 MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin, by mass

3

Name and description

No. Class Remarks Name and description

UN

NITROGLYCERIN 3343 MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass

3

NITROGLYCERIN 3319 4.1 MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin, by mass NITROGLYCERIN, SOLUTION M ALCOHOL with more than 1% but not more than 5% nitroglycerin

3064

NITROGLYCERIN SOLUTION M ALCOHOL with more than 1% but not more than 10% nitroglycerin

0144

NITROGLYCERIN SOLUTION M ALCOHOL with not more than 1% nitroglycerin

1204

NITROGUANIDINE, dry or wetted with less than 20% water, by mass

0282

NITROGUANIDINE, WETTED with not less than 20% water, by mass

1336 4.1

NITROHYDROCHLORIC ACID

1798

8

NITROMANNITE, WETTED, see

0133

1

NITROMETHANE

1261

UN Class Remarks No.

NITROPROPANES

2608

3

p-NITROSODIMETHYLANILINE

1369 4.2

NITROSTARCH, dry or wetted with less than 20% water, by mass

0146

NITROSTARCH, WETTED with not less than 20% water, by mass

1337 4.1

NITROSYL CHLORIDE

1069

2

NITROSYLSULPHURIC ACID, LIQUID

2308

8

NITROSYLSULPHURIC ACID, SOLID

3456

8

1

3

1

NITROTOLUENES, LIQUID 1664 6.1 3 NITROTOLUENES, SOLID NITROTOLUIDINES 1

NITROTRIAZOLONE NITRO UREA NITROUS OXIDE NITROUS OXIDE, REFRIGERATED LIQUID Carriage prohi- NITROXYLENES, LIQUID bited

NITROXYLENES, SOLID Non-activated carbon, see

3

Nitromuriatic acid, see

Non-activated charcoal, see NONANES

NITRONAPHTHALENE

2538 4.1

NITROPHENOLS (0-, m-, P-)

1663 6.1

4-NITROPHENYLHYDRAZINE, with not less than 30% water, by mass

3376 4.1

NONYLTRICHLOROSILANE 2,5-NORBORNADIENE, STABILIZED, see Normal propyl alcohol, see

Name and description NTO, see OCTADECYLTRICHLOROSILANE OCTADIENE

OCTAFLUOROCYCLOBUTANE

UN Class Remarks Name and description No.

ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE C, LIQUID ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED

OCTAFLUOROPROPANE OCTANES OCTOGEN, see

OCTOL, dry or wetted with less than 15% water, by mass, see OCTOLITE, dry or wetted with less than 15% water, by mass

ORGANIC PEROXIDE TYPE C, SOLID ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE D, LIQUID ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

OCTONAL OCTYL ALDEHYDES tert-Octyl mercaptan, see OCTYLTRICHLOROSILANE Oenanthol, see

ORGANIC PEROXIDE TYPE D, SOLID ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE E, LIQUID

OIL GAS, COMPRESSED Oleum, see ORGANIC PEROXIDE TYPE B, LIQUID ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE B, SOLID

ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE E, SOLID ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED

UN Class Remarks No.

Name and description ORGANIC PEROXIDE TYPE F, LIQUID ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE F, SOLID ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED Organic peroxides, see 2.2.52.4 for an alphabetic list of currently assigned organic peroxides and see ORGANIC PIGMENTS, SELF-HEATING ORGANOARSENIC COMPOUND, LIQUID, N.O.S. ORGANOARSENIC COMPOUND, SOLID, N.O.S. ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C ORGANOCHLORINE PESTICIDE, SOLID, TOXIC ORGANOMETALLIC COMPOUND, TOXIC, LIQUID, N.O.S.

UN

No. Class Remarks Name and description

UN Class Remarks No.

ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S.

3467 6.1

Organometallic compound, solid, water-reactive, flammable, n.o.s., see

3396 4.3

Organometallic compound or 3399 4.3 Organometallic compound solution or Organometallic compound dispersion, waterreactive, flammable, n.o.s., see ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC

3392 4.2

ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC

3391 4.2

ORGANOMETALLIC SUBSTANCE, SOLID, SELF-HEATING

3400 4.2

ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATERREACTIVE

3394 4.2

ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATERREACTIVE

3393 4.2

ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE

3398 4.3

ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE

3395 4.3

ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE

3399 4.3

ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE

3396 4.3

Name and description

UN Class Remarks Name and description No.

UN Class Remarks No.

ORGANOMETALLIC 3397 4.3 SUBSTANCE, SOLID, WATER-REACTIVE, SELFHEATING

ORGANOTIN PESTICIDE, SOLID, TOXIC

2786 6.1

Orthophospohoric acid, see

1805

ORGANOPHOSPHORUS COMPOUND, TOXIC, LIQUID, N.O.S.

OSMIUM TETROXIDE

2471 6.1

8

OXIDIZING LIQUID, N.O.S. 3 139 5.1

ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S. ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC

OXIDIZING LIQUID, CORROSIVE, N.O.S.

3098 5.1

OXIDIZING LIQUID, TOXIC, N.O.S.

3099 5.1

OXIDIZING SOLID, N.O.S.

1479 5.1

OXIDIZING SOLID, CORROSIVE, N.O.S.

3085 5.1

OXIDIZING SOLID, FLAMMABLE, N.O.S.

3137 5.1

OXIDIZING SOLID, SELFHEATING, N.O.S.

3 100 5.1

OXIDIZING SOLID, TOXIC, 3087 5.1 N.O.S.

ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

OXIDIZING SOLID, 3 121 5.1 WATER-REACTIVE, N.O.S.

ORGANOPHOSPHORUS 2783 6.1 PESTICIDE, SOLID, TOXIC

Oxirane, see

1040

2

ORGANOTIN COMPOUND, 2788 6.1 LIQUID, N.O.S.

OXYGEN, COMPRESSED

1072

2

ORGANOTIN COMPOUND, 3 146 6.1 SOLID, N.O.S.

OXYGEN DIFLUORIDE, COMPRESSED

2190

2

ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C

2787

OXYGEN GENERATOR, CHEMICAL

3356 5.1

ORGANOTIN PESTICIDE, LIQUID, TOXIC

3020 6.1

ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

Carriage prohibited Carriage prohibited

3

OXYGEN, REFRIGERATED 1073 LIQUID

2

l -0xy-4-nitrobenzene, see

l663 6.1

PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base)

1263 3066 3469 3470

3019 6.1 3 8 3 8

Carriage prohibited

Name and description

UN No. Class Remarks Name and description

PAINT RELATED MATERIAL (including paint thinning and reducing compound) Paint thinning and reducing compound, see

PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper) 3

UN Class Remarks

No.

Pentafluoroethane, 1,1,13337 trifluoroethane, and 1,l, 1,2tetrafluoroethane zeotropic mixture with approximately 44% pentafluoroethane and 52% l, l, l -trifluoroethane, see

2

PENTAMETHYLHEPTANE 2286

3

Pentanal, see

2058

3

PENTANES, liquid

1265

3

Paraffin, see

1223

PARAFORMALDEHYDE

2213 4.1

n-Pentane, see

1265

3

PARALDEHYDE

1264

PENTANOLS

1105

3

PCBs, see

n-Pentanol, see

1105

3

PENTABORANE

2315 9 3432 9 1380 4.2

3-Pentanol, see

1105

3

PENTACHLOROETHANE

1669 6.1

l -PENTENE

1108

3

PENTACHLOROPHENOL

3 155 6.1

1-PENTOL

2705

8

PENTAERYTHRITE TETRANITRATE with not less than 7% wax, by mass

0411

1

PENTOLITE, dry or wetted with less than 15% water, by mass

015 1

1

PENTAERYTHRITE 0150 TETRANITRATE, DESENSITIZED with not less than 15% phlegmatizer, by mass

1

Pentyl nitrite, see

1113

3

PERCHLORATES, INORGANIC, N.O.S.

1481 5.1

PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

3211 5.1

PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass

1873 5.1

PERCHLORIC ACID with not more than 50% acid, by mass

1802

Perchlorobenzene, see

2729 6.1

3

PENTAERYTHRITE 3344 4.1 TETRANITRATE MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN, by mass PENTAERYTHRITE 0150 TETRANITRATE, WETTED with not less than 25% water, by mass

1

8

PENTAERYTHRITOL TETRANITRATE, see

0150 0411

1 1

Perchlorocyclopentadiene, see 2646 6.1

PENTAFLUOROETHANE

3220

2

Perchloroethylene, see

1897 6.1

Name and description

UN Class Remarks Name and description No.

PERCHLOROMETHYL MERCAPTAN

PETN, see

PERCHLORYL FLUORIDE

PETNITNT, see

Perfluoroacetylchloride, see

PETROL

PERFLUORO(ETHYL VINYL ETHER)

PETROLEUM CRUDE OIL

PERFLUORO(h4ETHYL VINYL ETHER)

PETROLEUM DISTILLATES, N.O.S. Petroleum ether, see

Perfluoropropane, see PERFUMERY PRODUCTS with flammable solvents

PETROLEUM GASES, LIQUEFIED Petroleum naphtha, see

PERMANGANATES, INORGANIC, N.O.S. PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

Petroleum oil, see PETROLEUM PRODUCTS, N.O.S. Petroleum raffinate, see

PEROXIDES, INORGANIC, N.O.S. PERSULPHATES, INORGANIC, N.O.S.

Petroleum spirit, see PHENACYL BROMIDE PHENETIDINES

PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

PHENOLATES, LIQUID PHENOLATES, SOLID

PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash-point less than 23 "C PESTICIDE, LIQUID, TOXIC, N.O.S. PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-point not less than 23 "C PESTICIDE, SOLID, TOXIC, N.O.S. Pesticide, toxic, under compressed gas, n.o.s, see

PHENOL, MOLTEN PHENOL, SOLID PHENOL SOLUTION PHENOLSULPHONIC ACID, LIQUID PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC

3348 6.1

PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

3347 6.1

PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC

3345 6.1

PHENYLACETONITRILE, LIQUID

UN Class Remarks

No.

PHENYLMERCURIC HYDROXIDE

1894 6.1

PHENYLMERCURIC NITRATE

1895 6.1

PHENYLPHOSPHORUS DICHLORIDE

2798

8

PHENYLPHOSPHORUS THIODICHLORIDE

2799

8

2-Phenylpropene, see

2303

3

2470 6.1

PHENYLTRICHLOROSILANE

1804

8

PHENYLACETYL CHLORIDE

2577

PHOSGENE

1076

2

1547 6.1

9-PHOSPHABICYCLONONANES

2940 4.2

Phenylamine, see l -Phenylbutane, see

2709

3

PHOSPHINE

2199

2

2-Phenylbutane, see

2709

3

Phosphoretted hydrogen, see

2 199

2

PHENYLCARBYLAMINE CHLORIDE

1672 6.1

PHOSPHORIC ACID, SOLUTION

1805

8

PHENYL CHLOROFORMATE

2746 6.1

PHOSPHORIC ACID, SOLID 3453

8 8

2224 6.1

Phosphoric acid, anhydrous, see

1807

Phenyl cyanide, see PHENYLENEDIAMINES (0-, m-, P-)

1673 6.1

PHOSPHOROUS ACID

2834

8

2055

PHOSPHORUS, AMORPHOUS

1338 4.1

Phenylethylene, see PHENYLHYDRAZINE

2572 6.1

Phosphorus bromide, see

1808

PHENYL ISOCYANATE

2487 6.1

Phosphorus chloride, see

1809 6.1

8

3

Phenylisocyanodichloride, see 1672 6.1

8

PHOSPHORUS 1339 4.1 HEPTASULPHIDE, free from yellow and white phosphorus

PHENYL MERCAPTAN

2337 6.1

PHENYLMERCURIC ACETATE

1674 6.1

PHOSPHORUS OXYBROMIDE

1939

8

PHENYLMERCURIC COMPOUND, N.O.S.

2026 6.1

PHOSPHORUS OXYBROMIDE, MOLTEN

2576

8

Name and description

UN Class Remarks Name and description No.

PHOSPHORUS OXYCHLORIDE

PHOSPHORUS, YELLOW, DRY

PHOSPHORUS PENTABROMIDE

PHOSPHORUS, YELLOW, IN SOLUTION

PHOSPHORUS PENTACHLORIDE

PHOSPHORUS, YELLOW, UNDER WATER

PHOSPHORUS PENTAFLUORIDE

Phosphoryl chloride, see

PHOSPHORUS PENTASULPHIDE, free from yellow and white phosphorus

PHTHALIC ANHYDRIDE with more than 0.05% of maleic anhydride PICOLINES

PHOSPHORUS PENTOXIDE PICRAMIDE, see PHOSPHORUS SESQUISULPHIDE, free from yellow and white phosphorus Phosphorus (V) sulphide, free from yellow and white phosphorus, see Phosphorus sulphochloride, see PHOSPHORUS TRIBROMIDE PHOSPHORUS TRICHLOIUDE

PICFUC ACID WETTED, see PICRITE, see PICRITE, WETTED, see Picrotoxin, see PICRYL CHLORIDE, see PICRYL CHLORIDE, WETTED, see alpha-PINENE PINE OIL PIPERAZINE

PHOSPHORUS TRIOXIDE PIPERIDINE PHOSPHORUS TRISULPHIDE, free from yellow and white phosphorus

Pivaloyl chloride, see Plastic explosives ,see

PHOSPHORUS, WHITE, DRY PHOSPHORUS, WHITE IN SOLUTION PHOSPHORUS, WHITE, MOLTEN PHOSPHORUS, WHITE, UNDER WATER

PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour PLASTICS, NITROCELLULOSEBASED, SELF-HEATING, N.O.S.

UN Class Remarks No.

Name and description

Polish, see

UN Class Remarks Name and description No. Potassium bisulphate, see Potassium bisulphite solution, see

POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. POLYAMINES, LIQUID, CORROSIVE, N.O.S.

POTASSIUM BOROHYDRIDE POTASSIUM BROMATE POTASSIUM CHLORATE

POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.

POTASSIUM CHLORATE, AQUEOUS SOLUTION

POLYAMINES, SOLID, CORROSIVE, N.O.S.

Potassium chlorate mixed with mineral oil, see

POLYCHLORINATED BIPHENYLS, LIQUID

POTASSIUM CUPROCYANIDE

POLYCHLORINATED BIPHENYLS, SOLID

POTASSIUM CYANIDE, SOLID

POLYESTER RESIN KIT

POTASSIUM CYANIDE, SOLUTION

POLYHALOGENATED BIPHENYLS, LIQUID

Potassium dicyanocuprate (I), see

POLYHALOGENATED BIPHENYLS, SOLID

POTASSIUM DITHIONITE

POLYHALOGENATED TERPHENYLS, LIQUID

POTASSIUM FLUORIDE, SOLID

POLYHALOGENATED TERPHENYLS, SOLID

POTASSIUM FLUORIDE, SOLUTION

POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour

POTASSIUM FLUOROACETATE

Polystyrene beads, expandable, see

POTASSIUM FLUOROSILICATE

POTASSIUM

Potassium hexafluorosilicate, see

POTASSIUM ARSENATE

Potassium hydrate, see

POTASSIUM ARSENITE

POTASSIUM HYDROGENDIFLUORIDE, SOLID

Potassium bifluoride, see

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

POTASSIUM 3421 HYDROGENDIFLUORIDE, SOLUTION

8

POTASSIUM HYDROGEN SULPHATE

2509

8

POTASSIUM HYDROSULPHITE, see

1929 4.2

POTASSIUM SODIUM ALLOYS, LIQUID

Potassium hydroxide, liquid, see

1814

8

POTASSIUM SODIUM ALLOYS. SOLID

POTASSIUM HYDROXIDE, 18 13 SOLID

8

Potassium selenate, see Potassium selenite, see Potassium silicofluoride, see

POTASSIUM SULPHIDE with less than 30% water of crystallization

POTASSIUM HYDROXIDE SOLUTION

POTASSIUM SULPHIDE, ANHYDROUS

POTASSIUM METAL ALLOYS, LIQUID

POTASSIUM SULPHIDE, HYDRATED with not less than 30% water of crystallization

POTASSIUM METAL ALLOYS, SOLID

POTASSIUM SUPEROXIDE POTASSIUM METAVANADATE

Potassium tetracyanomercurate (11), see

POTASSIUM MONOXIDE POTASSIUM NITRATE Potassium nitrate and sodium nitrate mixture, see POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE

POWDER CAKE, WETTED with not less than 17% alcohol, by mass POWDER CAKE, WETTED with not less than 25% water, by mass POWDER PASTE, see

POTASSIUM NITRITE POWDER, SMOKELESS POTASSIUM PERCHLORATE Power devices, explosive, see POTASSIUM PERMANGANATE POTASSIUM PEROXIDE PRIMERS, CAP TYPE POTASSIUM PERSULPHATE POTASSIUM PHOSPHIDE

Primers, small arms, see

UN Class Remarks No.

Name and description

PRIMERS. TUBULAR

PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable Projectiles, illuminating, see

UN Class Remarks Name and description No.

Propellant with a single base, 0160 Propellant with a double base, 0161 Propellant with a triple base, see Propene, see PROPIONALDEHYDE PROPIONIC ACID with not less than 10% and less than 90% acid by mass PROPIONIC ACID with not less than 90% acid by mass

PROJECTILES, inert with tracer

PROPIONIC ANHYDRIDE PROPIONITRILE

PROJECTILES with burster or expelling charge

PROPIONYL CHLORIDE n-PROPYL ACETATE PROPYL ALCOHOL, NORMAL, see

PROJECTILES with bursting charge

PROPYLAMINE n-PROPYLBENZENE Propyl chloride, see

PROPADIENE, STABILIZED Propadiene and methyl acetylene mixture, stabilized, see

UN Class Remarks No.

n-PROPYL CHLOROFORMATE PROPYLENE

PROPANE

PROPYLENE CHLOROHYDRIN

PROPANETHIOLS

l ,2-PROPYLENEDIAMINE

n-PROPANOL

Propylene dichloride, see

PROPELLANT, LIQUID

PROPYLENEIMINE, STABILIZED

PROPELLANT, SOLID

PROPYLENE OXIDE PROPYLENE TETRAMER Propylene trimer, see

1 1

Name and description

UN Class Remarks Name and description No.

PROPYL FORMATES

1281

3

n-PROPYL ISOCYANATE

2482 6.1

PYROPHORIC SOLID, ORGANIC, N.O.S.

Propyl mercaptan, see

2402

3

PYROSULPHURYL CHLORIDE

n-PROPYL NITRATE

1865

3

Pyroxylin solution, see

PROPYLTRICHLOROSILA NE

1816

8

PYRROLIDINE

Pyrazine hexahydride, see

2579

8

QUINOLINE

PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 'C

3350

3

Quinone, see

PYRETHROID PESTICIDE, LIQUID, TOXIC

3352 6.1

PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C

335 1 6.1

RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM

PYRETHROID PESTICIDE, SOLID, TOXIC

3349 6.1

RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING

PYRIDINE Pyrophoric organometallic compound, water-reactive, n.o.s., liquid, see Pyrophoric organometallic compound, water-reactive, n.o.s., solid, see PYROPHORIC ALLOY, N.O.S. PYROPHORIC LIQUID, INORGANIC, N.O.S. PYROPHORIC LIQUID, ORGANIC, N.O.S. PYROPHORIC METAL, N.O.S. PYROPHORIC SOLID, INORGANIC, N.O.S.

UN Class Remarks No.

RADIOACTIVE MATERIAL, EXCEPTED PACKAGE INSTRUMENTS or ARTICLES RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I), non fissile or fissileexcepted

2912

7

RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-11), FISSILE

3324

7

Name and description RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-11), non fissile or fissileexcepted RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (LSAIII), FISSILE RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-III), non fissile or fissile-excepted RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-11), FISSILE RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-11), non fissile or fissile-excepted RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, nonspecial form RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissile-excepted

UN Class Remarks Name and description No.

UN Class Remarks No.

RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE

3333

7

RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, non fissile or fissileexcepted

3332

7

RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE

3329

7

RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, non fissile or fissile-excepted

2917

7

RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE

3328

7

RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile or fissile-excepted

2916

7

RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE

3330

7

RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissile-excepted

3323

7

RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE

2977

7

RADIOACTIVE 2978 MATERIAL, URANIUM HEXAFLUORIDE, non fissile or fissile-excepted

7

Rags, oily

1856 4.2

RDX,see

0072 0391 0483

1 1 1

Not subject to ADN

Name and description

UN

No.

RECEPTACLES, SMALL, 2037 CONTAINING GAS without a release device, non-refillable

Class Remarks Name and description 2

Red phosphorus, see

1338 4.1

REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture P2

1078

2

REFRIGERANT GAS R 124, see REFRIGERANT GAS R 125, see REFRIGERANT GAS R 133a, see

REFRIGERANT GAS R 12, see

1028

2

REFRIGERANT GAS R 134a, see

REFRIGERANT GAS R 12B1, see

1974

2

REFRIGERANT GAS R 142b, see

REFRIGERANT GAS R 13, see

1022

2

REFRIGERANT GAS R 143a, see

REFRIGERANT GAS R 13B1, see

1009

2

REFRIGERANT GASR 152a, see

REFRIGERANT GAS R 14, see

1982

2

REFRIGERANT GAS R 161, see

REFRIGERANT GAS R 2 1, see

1029

2

REFRIGERANT GAS R 2 18, see

REFRIGERANT GAS R 22, see

10 18

2

REFRIGERANT GAS R 227, see

REFRIGERANT GAS R 23, see

1984

2

REFRIGERANT GAS R 404A

REFRIGERANT GAS R 32, see

3252

2

REFRIGERANT GAS R 407A

REFRIGERANT GAS R 40, see

1063

2

REFRIGERANT GAS R 407B

REFRIGERANT GAS R 41, see

2454

2

REFRIGERANT GAS R 407C

REFRIGERANT GAS R 1 14, 1958 see

2

REFRIGERANT GAS R 500, see

REFRIGERANT GAS R 115, 1020 see

2

REFRIGERANT GAS R 502, see

REFRIGERANT GAS R 1 16, 2 193 see

2

REFRIGERANT GAS R 503, see REFRIGERANT GAS R 1l32a, see

UN Class Remarks

No.

Name and description

UN Class Remarks Name and description No.

REFRIGERANT GAS R 1216, see

1858

2

REFRIGERANT GAS R l 3 18, see

2422

2

REFRIGERANT GAS RC 3 18, see

1976

REFRIGERATING MACHINES containing flammable, non-toxic, liquefied gas

3358

ROCKETS with expelling charge

ROCKETS with inert head 2 ROCKETS, LINETHROWING 2 ROCKETS, LIQUID FUELLED with bursting charge

REFRIGERATING 2857 MACHINES containing nonflammable, non-toxic, gases or ammonia solutions (UN 2672)

2 ROSIN OIL RUBBER SCRAP, powdered or granulated

REGULATED MEDICAL WASTE, N.O.S.

RUBBER SHODDY, powdered or granulated

RELEASE DEVICES, EXPLOSIVE

RUBBER SOLUTION RUBIDIUM

RESIN SOLUTION, flammable

RUBIDIUM HYDROXIDE Resorcin, see RESORCINOL

RUBIDIUM HYDROXIDE SOLUTION

RIVETS, EXPLOSIVE

Saltpetre, see

ROCKET MOTORS

SAMPLES, EXPLOSIVE, other than initiating explosive Sand acid, see

ROCKET MOTORS, LIQUID 0395 FUELLED 0396

1 1

ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge

0250 0322

1 1

ROCKETS with bursting charge

0180 0181 0182 0295

1 1 1 1

SEAT-BELT PRETENSIONERS SEED CAKE with more than 1.5% oil and not more than l l % moisture SEED CAKE with not more than 1.5% oil and not more than 11% moisture Seed expellers, see

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

SELENATES

2630 6.1

SELENIC ACID

1905

SELENITES

UN Class Remarks

No.

SELF-HEATING SOLID, ORGANIC, N.O.S.

8

2630 6.1

SELF-HEATING SOLID, OXIDIZING,N.O.S

3127 4.2

Carriage prohibited

SELENIUM COMPOUND, LIQUID, N.O.S.

3440 6.1

SELENIUM COMPOUND, SOLID, N.O.S.

3283 6.1

SELENIUM DISULPHIDE

2657 6.1

SELENIUM HEXAFLUORIDE

2194

SELENIUM OXYCHLORIDE

SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S.

2879

2

8

SELF-HEATING LIQUID, 3188 4.2 CORROSIVE, INORGANIC, N.O.S. SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S.

3185 4.2

SELF-HEATING LIQUID, INORGANIC, N.O.S.

3186 4.2

SELF-HEATING LIQUID, ORGANIC, N.O.S.

3183 4.2

SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S.

3187 4.2

SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S.

3184 4.2

3192 4.2 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S.

SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S.

3126 4.2

SELF-HEATING SOLID, INORGANIC, N.O.S.

3190 4.2

SELF-REACTIVE LIQUID TYPE B SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE C SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE D SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE E SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE F SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE B

3191 4.2

Name and description

UN

No.

Class Remarks Name and description

UN Class Remarks No.

SIGNALS, RAILWAY TRACK, EXPLOSIVE

0192 0193 0492 0493

1 1 1 1

SIGNALS, SMOKE

0196 0197 03 13 0487

1 1 1 1

SILANE

2203

2

Silicofluoric acid, see

1778

8

SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED

Silicofluorides, n.o.s., see

2856 6.1

Silicon chloride, see

1818

SELF-REACTIVE SOLID TYPE E

SILICON POWDER, AMORPHOUS

1346 4.1

SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED

SILICON TETRACHLORIDE

1818

8

SILICON TETRAFLUORIDE 1859

2

SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE C SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE D

SELF-REACTIVE SOLID TYPE F

8

SILVER ARSENITE

1683 6.1

SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED

SILVER CYANIDE

1684 6.1

SILVER NITRATE

1493 5.1

SHALE OIL

SILVER PICRATE, WETTED with not less than 30% water, by mass

1347 4.1

SLUDGE ACID

1906

8

SODA LIME with more than 4% sodium hydroxide

1907

8

SODIUM

1428 4.3

Sodium aluminate, solid

2812

Shaped charges, see

Shellac, see

SIGNAL DEVICES. HAND

8

Not subject to ADN

SIGNALS, DISTRESS, ship

Signals, distress, ship, wateractivated. see

SODIUM ALUMINATE SOLUTION

1819

SODIUM ALUMINIUM HYDRIDE

2835 4.3

8

Name and description

UN

No. Class Remarks Name and description

SODIUM AMMONIUM VANADATE

SODIUM CUPROCYANIDE, SOLID

SODIUM ARSANILATE

SODIUM CUPROCYANIDE SOLUTION

SODIUM ARSENATE SODIUM CYANIDE, SOLID SODIUM ARSENITE, AQUEOUS SOLUTION SODIUM ARSENITE, SOLID

SODIUM CYANIDE, SOLUTION Sodium dicyanocuprate (I), solid, see

SODIUM AZIDE Sodium bifluoride, see

Sodium dicyanocuprate (I) solution, see

Sodium binoxide, see

Sodium dimethylarsenate, see

Sodium bisulphite solution, see

SODIUM DINITRO-0CRESOLATE, dry or wetted with less than 15% water, by mass

SODIUM BOROHYDRIDE SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION, with not more than 12% sodium borohydride and not more than 40% sodium hydroxide by mass

SODIUM DINITRO-0CRESOLATE, WETTED with not less than 10% water, by mass

SODIUM BROMATE

SODIUM DINITRO-0CRESOLATE, WETTED with not less than 15% water, by mass

SODIUM CACODYLATE

Sodium dioxide, see

SODIUM CARBONATE PEROXYHYDRATE

SODIUM DITHIONITE

SODIUM CHLORATE

SODIUM FLUORIDE, SOLID

SODIUM CHLORATE, AQUEOUS SOLUTION

SODIUM FLUORIDE, SOLUTION

Sodium chlorate mixed with dinitrotoluene, see

SODIUM FLUOROACETATE

SODIUM CHLORITE

SODIUM FLUOROSILICATE

SODIUM CHLOROACETATE

Sodium hexafluorosilicate, see Sodium hydrate, see

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

SODIUM HYDRIDE

1427 4.3

Sodium hydrogen 4-aminophenylarsenate, see

2473 6.1

SODIUM HYDROGENDIFLUORIDE

2439

SODIUM PERCHLORATE 8

SODIUM 2318 4.2 HYDROSULPHIDE with less than 25% water of crystallization SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization SODIUM HYDROSULPHITE, see SODIUM HYDROXIDE, SOLID SODIUM HYDROXIDE SOLUTION

SODIUM PERBORATE MONOHYDRATE

SODIUM PERMANGANATE SODIUM PEROXIDE SODIUM PEROXOBORATE, ANHYDROUS SODIUM PERSULPHATE SODIUM PHOSPHIDE SODIUM PICRAMATE, dry or wetted with less than 20% water, by mass SODIUM PICRAMATE, WETTED with not less than 20% water, by mass Sodium potassium alloys, liquid, see

Sodium metasilicate pentahydrate, see

Sodium selenate, see

SODIUM METHYLATE

Sodium selenite, see

SODIUM METHYLATE SOLUTION in alcohol

Sodium silicofluoride, see

SODIUM MONOXIDE SODIUM NITRATE SODIUM NITRATE AND POTASSIUM NITRATE MIXTURE SODIUM NITRITE Sodium nitrite and potassium nitrate mixture, see SODIUM PENTACHLOROPHENATE

SODIUM SULPHIDE, ANHYDROUS SODIUM SULPHIDE with less than 30% water of crystallization SODIUM SULPHIDE, HYDRATED with not less than 30% water SODIUM SUPEROXIDE SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S.

UN Class Remarks

No.

Name and description

No.

Class Remarks Name and description

UN Class Remarks No.

STRONTIUM PERCHLORATE

SOLIDS or mixtures of solids 3 175 4.1 (such as preparations and wastes) CONTAINING FLAMMABLE LIQUID, N.O.S. having a flash-point up

STRONTIUM PEROXIDE STRONTIUM PHOSPHIDE STRYCHNINE

SOLIDS CONTAINING TOXIC LIQUID, N.O.S.

STRYCHNINE SALTS Solvents, flammable, n.o.s., see

STYPHNIC ACID, see

Solvents, flammable, toxic, n.o.s., see

STYRENE MONOMER, STABILIZED

SOUNDING DEVICES, EXPLOSIVE

SUBSTANCES, EVI, N.O.S., see SUBSTANCES, EXPLOSIVE, N.O.S.

Squibs, see

Stain, see

STANNIC CHLORIDE, ANHYDROUS STANNIC CHLORIDE PENTAHYDRATE SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE, N.O.S.

STANNIC PHOSPHIDES Steel swarf, see

Substances liable to spontaneous combustion, n.o.s., see

STIBINE Straw

1327 4.1 Not subject to ADN

Strontium alloys, pyrophoric, see STRONTIUM ARSENITE STRONTIUM CHLORATE Strontium dioxide, see STRONTIUM NITRATE

SUBSTANCES WITH A FLASH-POINT ABOVE 60 'C which are carried heated within a limiting range of 15K below their flash-point SUBSTANCES WITH A FLASH-POINT ABOVE 60 "C AND NOT MORE THAN l00 "C, which do not belong to another Class

2845 2846 3194 3200 9001

9003

4.2 4.2 4.2 4.2 3 DWFrous in tank vessels only

9

Dmgerous in tank vessels only

Name and description

UN

No.

SUBSTANCES WITH AN AUTO-IGNITION TEMPERATURE OF 200 "C AND BELOW, n.0.s.

9002

SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C

2780

Class Remarks Name and description 3

Dangerous in tank vessels only

SULPHUR, MOLTEN

2448 4.1

Sulphur monochloride, see

1828

8

SULPHUROUS ACID

1833

8

SULPHUR TETRAFLUORIDE

2418

2

SULPHUR TRIOXIDE, STABILIZED

1829

8

SULPHURYL CHLORIDE

1834

8

SULPHURYL FLUORIDE

2 191

2

Talcum with tremolite andlor actinolite, see

2590

9

TARS, LIQUID, including 1999 road asphalt and oils, bitumen and cut backs, with a flashpoint not greater than 60 "C

3

3

SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC SUBSTITUTED 3013 6.1 NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 'C SUBSTITUTED 2779 6.1 NITROPHENOL PESTICIDE, SOLID, TOXIC

Sulphur dichloride, see

Tars, liquid, with flash-point above 60 "C, at or above its flash-point, see Tars, liquid, at or above 100 "C and below its flashpoint, see Tartar emetic, see

SULPHUR DIOXIDE

TEAR GAS CANDLES

Sulphuretted hydrogen, see

TEAR GAS SUBSTANCE, LIQUID, N.O.S.

SULPHAMIC ACID SULPHUR SULPHUR CHLORIDES

SULPHUR HEXAFLUORIDE SULPHURIC ACID with more than 5 1% acid SULPHURIC ACID with not more than 5 1% acid SULPHURIC ACID, FUMING

UN Class Remarks No.

TEAR GAS SUBSTANCE, SOLID, N.O.S. TELLURIUM COMPOUND, 3284 6.1 N.O.S. TELLURIUM HEXAFLUORIDE

2195

2

TERPENE HYDROCARBONS, N.O.S.

2319

3

TERPINOLENE

2541

3

TETRABROMOETHANE

2504 6.1

SULPHURIC ACID, SPENT Sulphuric and hydrofluoric acid mixture, see

Name and description

UN Class Remarks Name and description No.

1,1,2,2-TETRACHLOROETHANE

1702 6.1

TETRACHLOROETHYLENE

1897 6.1

TETRAETHYL DITHIOPYROPHOSPHATE

1704 6.1

TETRAETHYLENEPENTAMINE

2320

Tetraethyl lead, see

1649 6.1

TETRANITROANILINE

TETRAETHYL SILICATE

1292

3

TETRANITROMETHANE

Tetraethyoxysilane, see

1292

3

TETRAPROPYL ORTHOTITANATE

Tetrafluorodichloroethane,see 1958

2

l , 1,1,2-TETRAFLUOROETHANE

3159

2

TETRAFLUOROETHYLENE, STABILIZED

l081

2

UN Class Remarks No.

TETRAMETHYLAMMONIUM HYDROXIDE, SOLUTION Tetramethylene, see Tetramethylene cyanide, see Tetramethyl lead, see

8

TETRAMETHYLSILANE

TETRAZENE, WETTED with not less than 30% water, or mixture of alcohol and water, by mass, see TETRAZOL-1 -ACETIC ACID

TETRAFLUOROMETHANE 1982

2

l ,2,3,6-TETRAHYDROBENZALDEHYDE

2498

3

TETRAHYDROFURAN

2056

3

TETRAHYDROFURFURYLAMINE

2943

3

Tetrahydro-l ,4-oxazine, see

2054

3

Thallium (I) chlorate, see

TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% of maleic anhydride

2698

8

THALLIUM COMPOUND, N.O.S.

1,2,3,6-TETRAHYDROPYRIDINE

2410

TETRYL, see 1857 4.2 Not subject

THALLIUM CHLORATE

2573 5.1

to ADN

THALLIUM NITRATE 3

Thallium (I) nitrate, see Thallous chlorate, see

TETRAHYDROTHIOPHENE 2412 Tetramethoxysilane, see

Textile waste, wet

3

2606 6.1

TETRAMETHYL3423 AMMONIUM HYDROXIDE, SOLID

8

Thia-4-pentanal, see THIOACETIC ACID

Name and description THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C THIOCARBAMATE PESTICIDE, LIQUID, TOXIC THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C THIOCARBAMATE PESTICIDE, SOLID, TOXIC THIOGLYCOL THIOGLYCOLIC ACID

UN Class Remarks Name and description No.

UN Class Remarks

No.

TITANIUM POWDER, WETTED with not less than 25% water

1352 4.1

TITANIUM SPONGE GRANULES

2878 4.1

TITANIUM SPONGE POWDERS

2878 4.1

TITANIUM TETRACHLORIDE

1838

8

TITANIUM TRICHLORIDE MIXTURE

2869

8

TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC

244 1 4.2

TITANIUM TRICHLORIDE, 2441 4.2 PYROPHORIC

THIOLACTIC ACID TNT, see

0209 0388 0389

1 1 1

TNT mixed with aluminium, see

0390

1

TNT, WETTED with not less than 30% water, by mass, see

1356 4.1

TNT, WETTED with not less than 10% water, by mass, see

3366 4.1

Toe puffs, nitrocellulose base, see

1353 4.1

TOLUENE

1294

THIONYL CHLORIDE THIOPHENE Thiophenol, see THIOPHOSGENE THIOPHOSPHORYL CHLORIDE THlOUREA DIOXIDE Tin (IV) chloride, anhydrous, see

3

Tin (IV) chloride pentahydrate, see

TOLUENE DIISOCYANATE 2078 6.1

TINCTURES, MEDICINAL

TOLUIDINES, LIQUID

1708 6.1

Tin tetrachloride, see

TOLUIDINES, SOLID

3451 6.1

TITANIUM DISULPHIDE

Toluol, see

1294

TITANIUM HYDRIDE

2,4-TOLUYLENEDIAMINE, 1709 6.1 SOLID

3

TITANIUM POWDER, DRY 2,4-TOLUYLENEDIAMINE, 3418 6.1 SOLUTION

Name and description

UN Class Remarks Name and description No.

TOXIC BY INHALATION 3383 6.1 LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC5o

Toluylene diisocyanate, see Tolylene diisocyanate, see Tolylethylene, inhibited, see TORPEDOES with bursting charge

TOXIC BY INHALATION 3384 6.1 LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to l000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50

TORPEDOES, LIQUID FUELLED with inert head TORPEDOES, LIQUID FUELLED with or without bursting charge

TOXIC BY INHALATION 3387 6.1 LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LCso

TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LCso TOXIC BY INHALATION 3382 6.1 LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LCSO

UN Class Remarks No.

3389 6.1

3390 6.1

TOXIC BY INHALATION 3387 6.1 LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to l000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 TOXIC BY INHALATION 3388 6.1 LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to l000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 TOXIC BY INHALATION 3385 6.1 LIQUID, WATERREACTIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50

Name and description TOXIC BY INHALATION LIQUID, WATERREACTIVE, N.O.S. with an inhalation toxicity lower than or equal to l000 m1/m3 and saturated vapour concentration greater than or equal to 10 LCso TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S.

UN

No.

Class Remarks Name and description TOXIC SOLID, SELFHEATING. N.O.S. TOXIC SOLID, WATERREACTIVE, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. TRACERS FOR AMMUNITION

TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.

Tremolite. see

TOXIC LIQUID, INORGANIC. N.O.S.

TRIALLYL BORATE

TOXIC LIQUID, ORGANIC, N.O.S. TOXIC LIQUID, OXIDIZING, N.O.S. TOXIC LIQUID, WATERREACTIVE, N.O.S. TOXIC SOLID, CORROSIVE, INORGAMC, N.O.S. TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S.

TRIALLYLAMTNE

TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 "C TRIAZINE PESTICIDE, LIQUID, TOXIC T W I N E PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 "C TRIAZINE PESTICIDE, SOLID. TOXIC

Tribromoborane, see

TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S.

TRIBUTYLAMINE

TOXIC SOLID, INORGANIC. N.O.S.

Trichloroacetaldehyde, see

TRIBUTYLPHOSPHANE

TRICHLOROACETIC ACID TOXIC SOLID, ORGANIC, N.O.S. TOXIC SOLID, OXIDIZING, N.O.S.

TRICHLOROACETIC ACID SOLUTION

Trichlororaceticaldehyde, see

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

TRICHLOROACETYL CHLORIDE

2442

TRICHLOROBENZENES, LIQUID

2321 6.1

TRICHLOROBUTENE

2322 6.1

8 TRIFLUOROMETHANE TRIFLUOROMETHANE, REFRIGERATED LIQUID 2-TRIFLUOROMETHYLANILINE

TRICHLOROETHYLENE

1710 6.1

3-TRIFLUOROMETHYLANILINE

TRICHLOROISOCYANURIC ACID, DRY

2468 5.1

Trichloronitromethane, see

1580 6.1

TRIISOPROPYL BORATE

TRICHLOROSILANE

1295 4.3

TRIMETHYLACETYL CHLORIDE

1,3,5-Trichloro-S-triazine2,4,6-trione, see

2468 5.1

TRIISOBUTYLENE

TRIMETHYLAMINE, ANHYDROUS

2,4,6-Trichloro-1,3,5- triazine, 2670 see

8 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass

TRICRESYL PHOSPHATE with more than 3% ortho isomer

2574 6.1

TRIETHYLAMINE

1296

3

l ,3,5-TRIMETHYLBENZENE

Triethyl borate, see

1176

3

TRIMETHYL BORATE

TRIETHYLENETETRAMINE

2259

8

TRIMETHYLCHLOROSILANE

Triethyl orthoformate, see

2524

3

TRIMETHYLCYCLOHEXYLAMINE

TRIETHYL PHOSPHITE

2323

3

TRIFLUOROACETIC ACID 2699

8

TRIFLUOROACETYL CHLORIDE

3057

2

TRIMETHYLHEXAMETHYLENEDIAMINES

Trifluorobromomethane, see

1009

2

Trifluorochloroethane, see

1983

2

TRIMETHYLHEXAMETHYLENE DIISOCYANATE

TRIFLUOROCHLOROETHYLENE, STABILIZED

1082

2

2,4,4-Trimethylpentene- 1, see

Trifluorochloromethane,see

1022

2

Trimethylene chlorobromide, see

2,4,4-Trirnethylpentene-2,see

UN Class Remarks No.

Name and description

UN Class Remarks Name and description No.

UN Class Remarks No.

TRINITROPHENOL, WETTED with not less than 30% water, by mass

1344 4.1

TRINITROPHENOL WETTED with not less than 10% water, by mass

3364 4.1

TRINITROPHENYLMETHYLNITRAMINE

0208

1

TRINITRORESORCINOL, dry or wetted with less than 20% water, or mixture of alcohol and water, by mass

02 19

1

0394

1

TRINITROBENZENESULPHONIC ACID

TRINITRORESORCINOL, WETTED with not less than 20% water, or mixture of alcohol and water, by mass

TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass

TRINITROTOLUENE (TNT), 0209 dry or wetted with less than 30% water, by mass

1

TRINITROBENZOIC ACID, WETTED with not less than 10% water, by mass

TRINITROTOLUENE AND HEXANITROSTILBENE MIXTURE

0388

1

TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass

TRINITROTOLUENE MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE

0389

1

TRINITROTOLUENE AND TRINITROBENZENE MIXTURE

0388

1

TRINITROTOLUENE, WETTED with not less than 10% water, by mass

3366 4.1

1356 4.1

TRINITRONAPHTHALENE

TRINITROTOLUENE, WETTED with not less than 30% water, by mass

TRINITROPHENETOLE

TRIPROPYLAMINE

2260

3

TRINITROPHENOL, dry or wetted with less than 30% water, by mass

TRIPROPYLENE

2057

3

TRIS-( l -AZIRIDINYL) PHOSPHINE OXIDE SOLUTION

2501 6.1

TRIMETHYL PHOSPHITE TRINITROANILINE TRINITROANISOLE TRINITROBENZENE, dry or wetted with less than 30% water, by mass TRINITROBENZENE, WETTED with not less than 10% water, by mass TRINITROBENZENE, WETTED with not less than 30% water, by mass

TRINITROCHLOROBENZENE TRINITROCHLOROBENZE NE WETTED with not less than 10% water, by mass

TRINITROFLUORENONE

Name and description TRITONAL

UN Class Remarks Name and description No.

UN Class Remarks No.

VANADIUM TETRACHLORIDE

Tropilidene, see TUNGSTEN HEXAFLUORIDE

VANADIUM TRICHLORIDE VANADYL SULPHATE

TURPENTINE Varnish, see TURPENTINE SUBSTITUTE UNDECANE UREA HYDROGEN PEROXIDE

Vehicle, flammable gas powered or vehicle, flammable liquid powered Villiaumite, see

UREA NITRATE, dry or wetted with less than 20% water, by mass UREA NITRATE, WETTED with not less than 10% water, by mass UREA NITRATE, WETTED with not less than 20% water, by mass Valeral, see

VINYL ACETATE, STABILIZED Vinylbenzene, see VINYL BROMIDE, STABILIZED VINYL BUTYRATE, STABILIZED VINYL CHLORIDE, STABILIZED

VALERALDEHYDE VINYL CHLOROACETATE n-Valeraldehyde, see Valeric aldehyde, see VALERYL CHLORIDE VANADIUM COMPOUND, N.O.S. Vanadium (IV) oxide sulphate, see

VINYL ETHYL ETHER, STABILIZED VINYL FLUORIDE, STABILIZED VINYLIDENE CHLORIDE, STABILIZED VINYL ISOBUTYL ETHER, STABILIZED

Vanadium oxysulphate, see VANADIUM OXYTRICHLORIDE VANADIUM PENTOXIDE, non-fused form

VINYL METHYL ETHER, STABILIZED VINYLPYRIDINES, STABILIZED

1263 3066 3469 3470 3166

3 8 3 8 9

Not subject to ADN

Name and description

UN Class Remarks Name and description No.

No.

VINYLTOLUENES, STABILIZED

2618

3

WHITE ASBESTOS (chrysotile, actinolite, anthophyllite, tremolite)

2590

9

VINYLTRICHLOROSILANE

1305

3 White spirit, see

1300

3

WOOD PRESERVATIVES, LIQUID

1306

3

Wool waste, wet

1387 4.2

XANTHATES

3342 4.2

XENON

2036

2

UN Class Remarks

Warheads for guided missiles, 0286 see 0287 0369 0370 0371

1 1 1 1 1

WARHEADS, ROCKET with 0370 burster or expelling charge 037 1

1 1

WARHEADS, ROCKET with 0286 bursting charge 0287 0369

1 1 1

XENON,REFRIGERATED LIQUID

2591

2

WARHEADS, TORPEDO with bursting charge

0221

1

XYLENES

1307

3

XYLENOLS, LIQUID

3430 6.1

WATER-REACTIVE LIQUID, N.O.S.

3148 4.3

XYLENOLS, SOLID

2261 6.1

XYLIDINES, LIQUID

1711 6.1

WATER-REACTIVE LIQUID, CORROSIVE, N.O.S.

3129 4.3 XYLIDINES, SOLID

3452 6.1

Xylols, see

1307

WATER-REACTIVE LIQUID, TOXIC, N.O.S.

3130 4.3

WATER-REACTIVE SOLID, 2813 4.3 N.O.S. WATER-REACTIVE SOLID, 3 131 4.3 CORROSIVE, N.O.S. WATER-REACTIVE SOLID, 3 132 4.3 FLAMMABLE, N.O.S. WATER-REACTIVE SOLID, 3 133 4.3 OXIDIZING, N.O.S. WATER-REACTIVE SOLID, 3 135 4.3 SELF-HEATING, N.O.S.

3

XYLYL BROMIDE, LIQUID 1701 6.1 XYLYL BROMIDE. SOLID

3417 6.1

ZINC AMMONIUM NITRITE

1512 5.1

ZINC ARSENATE

1712 6.1

Carriage prohi- ZINC ARSENATE AND bited ZINC ARSENITE MIXTURE Carriage prohi- ZINC ARSENITE bited Carriage ZINC ASHES prohibited Zinc bisulphite solution, see

WATER-REACTIVE SOLID, 3 134 4.3 TOXIC, N.O.S.

ZINC BROMATE

White arsenic, see

ZINC CHLORATE

1712 6.1

1712 6.1 1435 4.3 2693

8

2469 5.1

Not subject to ADN

Name and description ZINC CHLORIDE, ANHYDROUS ZINC CHLORIDE SOLUTION ZINC CYANIDE

UN Class Remarks Name and description No.

UN Class Remarks No.

ZIRCONIUM, DRY, coiled 2858 wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns) ZIRCONIUM, DRY, fmished 2009 sheets, strip or coiled wire

ZINC DITHIONITE ZIRCONIUM HYDRIDE

1437

ZIRCONIUM NITRATE

2728

ZINC DUST ZINC FLUOROSILICATE Zinc hexafluorosilicate, see ZINC HYDROSULPHITE, see ZINC NITRATE ZINC PERMANGANATE

ZIRCONIUM PICRAMATE, 0236 dry or wetted with less than 20% water, by mass ZIRCONIUM PICRAMATE, WETTED with not less than 20% water, by mass

1517

ZIRCONIUM POWDER, DRY

2008

ZIRCONIUM POWDER, WETTED with not less than 25% water

1358

ZIRCONIUM SCRAP

1932

ZINC PEROXIDE ZINC PHOSPHIDE ZINC POWDER ZINC RESINATE Zinc selenate, see Zinc selenite, see Zinc silicofluoride, see

ZIRCONIUM SUSPENDED 1308 INA FLAMMABLE LIQUID ZIRCONIUM TETRACHLORIDE

2503

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CHAPTER 3.3 SPECIAL PROVISIONS APPLICABLE TO CERTAIN ARTICLES OR SUBSTANCES

3.3.1

When Column (6) of Table A of Chapter 3.2 indicates that a special provision is relevant to a substance or article, the meaning and requirements of that special provision are as set forth below. Samples of new or existing explosive substances or articles may be carried as directed by the competent authorities (see 2.2.1 .l .3) for purposes including: testing, classification, research and development, quality control, or as a commercial sample. Explosive samples which are not wetted or desensitised shall be limited to 10 kg in small packages as specified by the competent authorities. Explosive samples which are wetted or desensitised shall be limited to 25 kg. Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. This substance is not subject to the requirements of ADN when in any other form. This substance is not subject to the requirements of ADN when coated. This substance is not subject to the requirements of ADN when it contains not more than 0.1 % calcium carbide. This substance is not subject to the requirements of ADN when it contains less than 30% or not less than 90% silicon. When offered for carriage as pesticides, these substances shall be carried under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see 2.2.61.1.10 to 2.2.61.1.11.2). Antimony sulphides and oxides which contain not more than 0.5% of arsenic calculated on the total mass are not subject to the requirements of ADN. Ferricyanides and ferrocyanides are not subject to the requirements of ADN. The carriage of this substance, when it contains more than 20% hydrocyanic acid, is prohibited. These substances are not subject to the requirements of ADN when they contain not more than 50% magnesium. If the concentration is more than 72%, the carriage of this substance is prohibited. The technical name which shall supplement the proper shipping name shall be the I S 0 common name (see also I S 0 1750:1981 "Pesticides and other agrochemicals common names", as amended), other name listed in the WHO "Recommended Classification of Pesticides by Hazard and Guidelines to Classification" or the name of the active substance (see also 3.1.2.8.1 and 3.1.2.8.1.1). This substance is not subject to the requirements of ADN when it contains not more than 4% sodium hydroxide.

Hydrogen peroxide aqueous solutions with less than 8% hydrogen peroxide are not subject to the requirements of ADN. The carriage of ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt is prohibited. Nitrocellulose meeting the descriptions of UN No. 2556 or UN No. 2557 may be classified in Class 4.1. The carriage of chemically unstable mixtures is prohibited. Refrigerating machines include machines or other appliances which have been designed for the specific purpose of keeping food or other items at a low temperature in an internal compartment, and air conditioning units. Refrigerating machines and refrigerating machine components are not subject to the provisions of ADN if they contain less than 12 kg of gas in Class 2, group A or 0 according to 2.2.2.1.3, or if they contain less than 12 litres ammonia solution (UN No. 2672). The subsidiary risks, control and emergency temperatures if any, and the UN number (generic entry) for each of the currently assigned organic peroxide formulations are given in 2.2.52.4. Other inert material or inert material mixture may be used, provided this inert material has identical phlegmatizing properties. The phlegmatized substance shall be significantly less sensitive than dry PETN. The dihydrated sodium salt of dichloroisocyanuric acid is not subject to the requirements of ADN. p-Bromobenzyl cyanide is not subject to the requirements of ADN. Products which have undergone sufficient heat treatment so that they present no hazard during carriage are not subject to the requirements of ADN. Solvent extracted soya bean meal containing not more than 1.5% oil and 11% moisture, which is substantially free of flammable solvent, is not subject to the requirements of ADN. An aqueous solution containing not more than 24% alcohol by volume is not subject to the requirements of ADN.

Alcoholic beverages of packing group 111, when carried in receptacles of 250 litres or less, are not subject to the requirements of ADN. The classification of this substance will vary with particle size and packaging, but borderlines have not been experimentally determined. Appropriate classifications shall be made in accordance with 2.2.1. This entry applies only if it is demonstrated, on the basis of tests, that the substances when in contact with water are not combustible nor show a tendency to auto-ignition and that the mixture of gases evolved is not flammable. A substance mentioned by name in Table A of Chapter 3.2 shall not be carried under this entry. Substances carried under this entry may contain 20% or less nitrocellulose provided the nitrocellulose contains not more than 12.6% nitrogen (by dry mass).

Asbestos which is immersed or fixed in a natural or artificial binder (such as cement, plastics, asphalt, resins or mineral ore) in such a way that no escape of hazardous quantities of respirable asbestos fibres can occur during carriage is not subject to the requirements of ADN. Manufactured articles containing asbestos and not meeting this provision are nevertheless not subject to the requirements of ADN when packed so that no escape of hazardous quantities of respirable asbestos fibres can occur during carriage. Phthalic anhydride in the solid state and tetrahydrophthalic anhydrides, with not more than 0.05% maleic anhydride, are not subject to the requirements of ADN. Phthalic anhydride molten at a temperature above its flash-point, with not more than 0.05% maleic anhydride, shall be classified under UN No. 3256. For radioactive material with a subsidiary risk: (a)

The packages shall be labelled with a label corresponding to each subsidiary risk exhibited by the material; corresponding placards shall be affixed to vehicles or containers in accordance with the relevant provisions of 5.3.1 ;

(b)

The radioactive material shall be allocated to packing groups I, I1 or 111, as and if appropriate, by application of the grouping criteria provided in Part 2 corresponding to the nature of the predominant subsidiary risk.

The description required in 5.4.1.2.5.1 (b) shall include a description of these subsidiary risks (e.g. "Subsidiary risk: 3, 6.1"), the name of the constituents which most predominantly contribute to this (these) subsidiary risk(s), and where applicable, the packing group. Barium sulphate is not subject to the requirements of ADN. This designation shall be used only when no other appropriate designation exists in Table A of Chapter 3.2, and only with the approval of the competent authority of the country of origin (see 2.2.1.1.3). Packages containing this type of substance shall bear a label conforming to model No. l (see 5.2.2.2.2) unless the competent authority of the country of origin has permitted this label to be dispensed with for the specific packaging employed because test data have proved that the substance in this packaging does not exhibit explosive behaviour (see 5.2.2.1.9). The group of alkali metals includes lithium, sodium, potassium, rubidium and caesium. The group of alkaline earth metals includes magnesium, calcium, strontium and barium. In determining the ammonium nitrate content, all nitrate ions for which a molecular equivalent of ammonium ions is present in the mixture shall be calculated as ammonium nitrate.

188

Lithium cells and batteries offered for carriage are not subject to other provisions of ADN if they meet the following: For a lithium metal or lithium alloy cell, the lithium content is not more than 1 g, and for a lithium-ion cell, the lithium-equivalent content is not more than 1.5 g; For a lithium metal or lithium alloy battery the aggregate lithium content is not more than 2 g, and for a lithium-ion battery, the aggregate lithium-equivalent content is not more than 8 g; Each cell or battery is of the type proved to meet the requirements of each test in the Manual of Tests and Criteria, Part 111, sub-section 38.3; Cells and batteries are separated so as to prevent short circuits and are packed in strong packagings, except when installed in equipment; and Except when installed in equipment, each package containing more than 24 lithium cells or 12 lithium batteries shall in addition meet the following requirements: Each package shall be marked indicating that it contains lithium batteries and that special procedures should be followed in the event that the package is damaged; Each shipment shall be accompanied with a document indicating that packages contain lithium batteries and that special procedures should be followed in the event a package is damaged; Each package is capable of withstanding a 1.2 m drop test in any orientation without damage to cells or batteries contained therein, without shifting of the contents so as to allow battery to battery (or cell to cell) contact and without release of contents; and Except in the case of lithium batteries packed with equipment, packages may not exceed 30 kg gross mass. As used above and elsewhere in ADN, "lithium content" means the mass of lithium in the anode of a lithium metal or lithium alloy cell, except in the case of a lithium-ion cell the "lithium-equivalent content" in grams is calculated to be 0.3 times the rated capacity in ampere-hours.

190 Aerosol dispensers shall be provided with protection against inadvertent discharge. Aerosols with a capacity not exceeding 50 m1 containing only non-toxic constituents are not subject to the requirements of ADN. 191

Receptacles, small, with a capacity not exceeding 50 ml, containing only non-toxic constituents are not subject to the requirements of ADN.

This entry may only be used for uniform ammonium nitrate based fertilizer mixtures of the nitrogen, phosphate or potash type, containing not more than 70% ammonium nitrate and not more than 0.4% total combustible/organic material calculated as carbon or with not more than 45% ammonium nitrate and unrestricted combustible material. Fertilizers within these composition limits are not subject to the requirements of ADN if shown by a Trough Test (see Manual of Tests and Criteria, Part 111, sub-section 38.2) not to be liable to self-sustaining decomposition. The control and emergency temperatures, if any, and the UN number (generic entry) for each of the currently assigned self-reactive substances are given in 2.2.41.4. Formulations which in laboratory testing neither detonate in the cavitated state nor deflagrate, which show no effect when heated under confinement and which exhibit no explosive power may be carried under this entry. The formulation must also be thermally stable (i.e. the SADT is 60 "C or higher for a 50 kg package). Formulations not meeting these criteria shall be carried under the provisions of Class 5.2, (see 2.2.52.4). Nitrocellulose solutions containing not more than 20 % nitrocellulose may be carried as paint or printing ink, as applicable (see UN Nos. 1210, 1263 and 3066). Lead compounds which, when mixed in a ratio of 1:1000 with 0.07M hydrochloric acid and stirred for one hour at a temperature of 23 "C 2 "C, exhibit a solubility of 5 % or less are considered insoluble. See I S 0 37 11:1990 "Lead chromate pigments and lead chromate - molybdate pigments - Specijications and methods of test".

*

Lighters and lighter refills shall comply with the provisions of the country in which they were filled. They shall be provided with protection against inadvertent discharge. The liquid portion of the gas shall not exceed 85% of the capacity of the receptacle at 15 "C. The receptacles, including the closures, shall be capable of withstanding an internal pressure of twice the pressure of the liquefied petroleum gas at 55 "C. The valve mechanisms and ignition devices shall be securely sealed, taped or otherwise fastened or designed to prevent operation or leakage of the contents during carriage. Lighters shall not contain more than 10 g of liquefied petroleum gas. Lighter refills shall not contain more than 65 g of liquefied petroleum gas. This entry shall not be used for polychlorinated biphenyls, liquid, UN No. 23 15 and polychlorinated biphenyls, solid, UN No. 3432. This entry shall not be used for UN No. 3 155 PENTACHLOROPHENOL. Polymeric beads and moulding compounds may be made from polystyrene, poly(methy1 methacrylate) or other polymeric material. The commercial grade of calcium nitrate fertilizer, when consisting mainly of a double salt (calcium nitrate and ammonium nitrate) containing not more than 10% ammonium nitrate and at least 12% water of crystallization, is not subject to the requirements of ADN. Toxins from plant, animal or bacterial sources which contain infectious substances, or toxins that are contained in infectious substances, shall be classified in Class 6.2. This entry only applies to the technically pure substance or to formulations derived from it having an SADT higher than 75 "C and therefore does not apply to formulations which are self-reactive substances (for self-reactive substances, see 2.2.41.4). Homogeneous mixtures containing not more than 35 % by mass of

azodicarbonamide and at least 65 % of inert substance are not subject to the requirements of ADN unless criteria of other classes are met. Mixtures of solids which are not subject to the requirements of ADN and flammable liquids may be carried under this entry without first applying the classification criteria of Class 4.1, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, vehicle or container is closed. Sealed packets and articles containing less than 10 m1 of a packing group I1 or 111 flammable liquid absorbed into a solid material are not subject to ADN provided there is no free liquid in the packet or article. Mixtures of solids which are not subject to the requirements of ADN and toxic liquids may be carried under this entry without first applying the classification criteria of Class 6.1, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, vehicle or container is closed. This entry shall not be used for solids containing a packing group I liquid. Mixtures of solids which are not subject to the requirements of ADN and corrosive liquids may be carried under this entry without first applying the classification criteria of Class 8, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, vehicle or container is closed. Genetically modified micro-organisms and genetically modified organisms which meet the definition of an infectious substance and the criteria for inclusion in Class 6.2 in accordance with section 2.2.62 shall be carried as UN No. 2814, UN No. 2900 or UN No. 3373, as appropriate. Only the technical name of the flammable liquid component of this solution or mixture shall be shown in parentheses immediately following the proper shipping name. Substances included under this entry shall not be of packing group I. Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is no greater than in its liquid state, the substance shall remain liquid during normal transport conditions. It shall not freeze at temperatures above -15 "C. Fire extinguishers under this entry may include installed actuating cartridges (cartridges, power device of classification code 1.4C or 1.4S), without changing the classification of Class 2, group A or 0 according to 2.2.2.1.3 provided the total quantity of deflagrating (propellant) explosives does not exceed 3.2 g per extinguishing unit. Formulations of this substance containing not less than 30% non-volatile, nonflammable phlegmatizer are not subject to the requirements of ADN. When phlegmatized with water and inorganic inert material the content of urea nitrate may not exceed 75% by mass and the mixture shall not be capable of being detonated by the Series 1, type (a), test in the Manual of Tests and Criteria, Part 1. Mixtures not meeting the criteria for flammable gases (see 2.2.2.1.5) shall be carried under UN No. 3 163.

230

This entry applies to cells and batteries containing lithium in any form, including lithium polymer and lithium ion cells and batteries. Lithium cells and batteries may be carried under this entry if they meet the following provisions: (a)

Each cell or battery is of the type proved to meet the requirements of each test of the Manual of Tests and Criteria, Part 111, sub-section 38.3;

(b)

Each cell and battery incorporates a safety venting device or is designed to preclude a violent rupture under normal conditions of carriage;

(c)

Each cell and battery is equipped with an effective means of preventing external short circuits;

(d)

Each battery containing cells or series of cells connected in parallel is equipped with effective means as necessary to prevent dangerous reverse current flow (e.g. diodes, fuses, etc.).

235

This entry applies to articles which contain Class 1 explosive substances and which may also contain dangerous goods of other classes. These articles are used as lifesaving vehicle air bag inflators or air bag modules or seat-belt pretensioners.

236

Polyester resin kits consist of two components: a base material (Class 3, packing group 11 or 111) and an activator (organic peroxide). The organic peroxide shall be type D, E or F, not requiring temperature control. Packing group shall be I1 or 111, according to the criteria for Class 3, applied to the base material. The quantity limit referred to in Column (7) of Table A of Chapter 3.2 applies to the base material.

237

The membrane filters, including paper separators, coating or backing materials, etc., that are present in carriage, shall not be liable to propagate a detonation as tested by one of the tests described in the Manual of Tests and Criteria, Part I, Test series 1 (a). In addition the competent authority may detennine, on the basis of the results of suitable burning rate tests taking account of the standard tests in the Manual of Tests and Criteria, Part 111, sub-section 33.2.1, that nitrocellulose membrane filters in the form in which they are to be carried are not subject to the requirements applicable to flammable solids in Class 4.1.

238

(a)

Batteries can be considered as non-spillable provided that they are capable of withstanding the vibration and pressure differential tests given below, without leakage of battery fluid. Vibration test: The battery is rigidly clamped to the platform of a vibration machine and a simple harmonic motion having an amplitude of 0.8 mm (1.6 mm maximum total excursion) is applied. The frequency is varied at the rate of l Hdmin between the limits of 10 Hz and 55 Hz. The entire range of frequencies and return is traversed in 95 5 minutes for each mounting position (direction of vibration) of the battery. The battery is tested in three mutually perpendicular positions (to include testing with fill openings and vents, if any, in an inverted position) for equal time periods.

*

Pressure differential test: Following the vibration test, the battery is stored for 4 'C while subjected to a pressure differential of at six hours at 24 'C least 88 kPa. The battery is tested in three mutually perpendicular positions (to

*

include testing with fill openings and vents, if any, in an inverted position) for at least six hours in each position. (b)

239

Non-spillable batteries are not subject to the requirements of ADN if, at a temperature of 55 "C, the electrolyte will not flow from a ruptured or cracked case and there is no free liquid to flow and if, as packaged for carriage, the terminals are protected from short circuit.

Batteries or cells shall not contain dangerous substances other than sodium, sulphur andlor polysulphides. Batteries or cells shall not be offered for carriage at a temperature such that liquid elemental sodium is present in the battery or cell unless approved and under the conditions established by the competent authority of the country of origin. If the country of origin is not a Contracting Party to ADN, the approval and conditions of carriage shall be recognized by the competent authority of the frst country Contracting Party to ADN reached by the consignment. Cells shall consist of hermetically sealed metal casings which fully enclose the dangerous substances and which are so constructed and closed as to prevent the release of the dangerous substances under normal conditions of carriage. Batteries shall consist of cells secured within and fully enclosed by a metal casing so constructed and closed as to prevent the release of the dangerous substances under normal conditions of carriage.

241

The formulation shall be prepared so that it remains homogeneous and does not separate during carriage. Formulations with low nitrocellulose contents and not showing dangerous properties when tested for their liability to detonate, deflagrate or explode when heated under defined confinement by tests of Test series 1 (a), 2 (b) and 2 (c) respectively in the Manual of Tests and Criteria, Part I and not being a flammable solid when tested in accordance with test No. 1 in the Manual of Tests and Criteria, Part 111, sub-section 33.2.1.4 (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm) are not subject to the requirements of ADN.

242

Sulphur is not subject to the requirements of ADN when it has been formed to a specific shape (e.g. prills, granules, pellets, pastilles or flakes).

243

Gasoline, motor spirit and petrol for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) shall be assigned to this entry regardless of variations in volatility.

244

This entry includes e.g. aluminium dross, aluminium skimmings, spent cathodes, spent potliner, and aluminium salt slags.

247

Alcoholic beverages containing more than 24% alcohol but not more than 70% by volume, when carried as part of the manufacturing process, may be carried in wooden barrels with a capacity of more than 250 litres and not more than 500 litres meeting the general requirements of 4.1 .l of ADR, as appropriate, on the following conditions: (a)

The wooden barrels shall be checked and tightened before filling;

(b)

Sufficient ullage (not less than 3%) shall be left to allow for the expansion of the liquid;

(c)

The wooden barrels shall be carried with the bungholes pointing upwards;

(d)

The wooden barrels shall be carried in containers meeting the requirements of the CSC. Each wooden barrel shall be secured in custom-made cradles and be wedged by appropriate means to prevent it from being displaced in any way during carriage.

249

Ferrocerium, stabilized against corrosion, with a minimum iron content of 10% is not subject to the requirements of ADN.

250

This entry may only be used for samples of chemicals taken for analysis in connection with the implementation of the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction. The carriage of substances under this entry shall be in accordance with the chain of custody and security procedures specified by the Organisation for the Prohibition of Chemical Weapons. The chemical sample may only be carried providing prior approval has been granted by the competent authority or the Director General of the Organisation for the Prohibition of Chemical Weapons and providing the sample complies with the following provisions:

251

(a)

It shall be packed according to packing instruction 623 in the ICAO Technical Instructions (see S-3-8 of the Supplement); and

(b)

During carriage, a copy of the document of approval for transport, showing the quantity limitations and the packing provisions shall be attached to the transport document.

The entry CHEMICAL KIT or FIRST AID KIT is intended to apply to boxes, cases etc. containing small quantities of various dangerous goods which are used for example for medical, analytical or testing or repair purposes. Such kits may not contain dangerous goods for which the code "LQO" has been indicated in Column (7) of Table A of Chapter 3.2. Components shall not react dangerously (see "dangerous reaction" in 1.2.1). The total quantity of dangerous goods in any one kit shall not exceed either 1 I or 1 kg. The packing group assigned to the kit as a whole shall be the most stringent packing group assigned to any individual substance in the kit. Kits which are carried on board vessels for first-aid or operating purposes are not subject to the requirements of ADN. Chemical kits and first aid kits containing dangerous goods in inner packagings which do not exceed the quantity limits applicable to individual substances as specified in Column (7) of Table A of Chapter 3.2 in accordance with the LQ code defined in 3.4.6 may be carried in accordance with Chapter 3.4.

252

Provided the ammonium nitrate remains in solution under all conditions of carriage, aqueous solutions of ammonium nitrate, with not more than 0.2% combustible material, in a concentration not exceeding 80%, are not subject to the requirements of ADN.

266

This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be carried unless specifically authorized by the competent authority (see 2.2.1 .l).

267

Any explosives, blasting, type C containing chlorates shall be segregated from explosives containing ammonium nitrate or other ammonium salts.

270

Aqueous solutions of Class 5.1 inorganic solid nitrate substances are considered as not meeting the criteria of Class 5.1 if the concentration of the substances in solution at the minimum temperature encountered during carriage is not greater than 80% of the saturation limit.

271

Lactose or glucose or similar materials, may be used as a phlegmatizer provided that the substance contains not less than 90%, by mass, of phlegmatizer. The competent authority may authorize these mixtures to be classified in Class 4.1 on the basis of a test Series 6 (c) of Section 16 of Part I of the Manual of Tests and Criteria on at least three packages as prepared for carriage. Mixtures containing at least 98%, by mass, of phlegmatizer are not subject to the requirements of ADN. Packages containing mixtures with not less than 90%, by mass, of phlegmatizer need not bear a label conforming to model No. 6.1.

272

This substance shall not be carried under the provisions of Class 4.1 unless specifically authorized by the competent authority (see UN No. 0143).

273

Maneb and maneb preparations stabilized against self-heating need not be classified in Class 4.2 when it can be demonstrated by testing that a cubic volume of 1 m3 of substance does not self-ignite and that the temperature at the centre of the sample does not exceed 200 "C, when the sample is maintained at a temperature of not less than 75 "C 2 "C for a period of 24 hours.

*

274

The provisions of 3.1.2.8 apply.

278

These substances shall not be classified and carried unless authorized by the competent authority on the basis of results from Series 2 tests and a Series 6(c) test of Part I of the Manual of Tests and Criteria on packages as prepared for carriage (see 2.2.1 .l). The competent authority shall assign the packing group on the basis of 2.2.3 criteria and the package type used for the Series 6(c) test.

279

The substance is assigned to this classification or packing group based on human experience rather than the strict application of classification criteria set out in ADN.

280

This entry applies to articles which are used as life-saving vehicle air bag inflators, or air bag modules or seat-belt pretensioners and which contain dangerous goods of Class 1 or dangerous goods of other classes and when carried as component parts and when these articles as presented for carriage have been tested in accordance with Test series 6 (c) of Part I of the Manual of Tests and Criteria, with no explosion of the device, no fragmentation of device casing or pressure vessel, and no projection hazard nor thermal effect which would significantly hinder fire-fighting or other emergency response efforts in the immediate vicinity.

283

Articles, containing gas, intended to function as shock absorbers, including impact energy-absorbing devices, or pneumatic springs are not subject to the requirements of ADN provided: (a)

Each article has a gas space capacity not exceeding 1.6 litres and a charge pressure not exceeding 280 bar where the product of the capacity (litres) and charge pressure (bars) does not exceed 80 (i.e. 0.5 litres gas space and 160 bar charge pressure, 1 litre gas space and 80 bar charge pressure, 1.6 litres gas space and 50 bar charge pressure, 0.28 litres gas space and 280 bar charge pressure);

Each article has a minimum burst pressure of 4 times the charge pressure at 20 "C for products not exceeding 0.5 litres gas space capacity and 5 times charge pressure for products greater than 0.5 litres gas space capacity; Each article is manufactured from material which will not fragment upon rupture; Each article is manufactured in accordance with a quality assurance standard acceptable to the competent authority; and The design type has been subjected to a fire test demonstrating that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, such that the article will not fragment and that the article does not rocket. See also 1.1.3.2 (d) of ADR for equipment used for the operation of the vehicle. An oxygen generator, chemical, containing oxidizing substances shall meet the following conditions: (a)

The generator when containing an explosive actuating device shall only be carried under this entry when excluded from Class 1 in accordance with the NOTE under paragraph 2.2.1.1.1 (b);

(b)

The generator, without its packaging, shall be capable of withstanding a 1.8 m drop test onto a rigid, non-resilient, flat and horizontal surface, in the position most likely to cause damage, without loss of its contents and without actuation;

(c)

When a generator is equipped with an actuating device, it shall have at least two positive means of preventing unintentional actuation.

Nitrocellulose membrane filters covered by this entry, each with a mass not exceeding 0.5 g, are not subject to the requirements of ADN when contained individually in an article or a sealed packet. These substances shall not be classified and carried unless authorized by the competent authority on the basis of results from Series 2 tests and a Series 6 (c) test of Part I of the Manual of tests and Criteria on packages as prepared for carriage (see 2.2.1 .l). Air bags or seat-belts installed in conveyances or in completed conveyance components such as steering columns, door panels, seats, etc. are not subject to the requirements of ADN. When this material meets the definitions and criteria of other classes as defined in Part 2, it shall be classified in accordance with the predominant subsidiary risk. Such material shall be declared under the proper shipping name and UN number appropriate for the material in that predominant Class, with the addition of the name applicable to this material according to Column (2) of Table A of Chapter 3.2, and shall be carried in accordance with the provisions applicable to that UN number. In addition, all other requirements specified in 2.2.7.9.1 shall apply, except 5.2.1.7.2. Flammable liquefied gases shall be contained within refrigerating machine components. These components shall be designed and tested to at least three times the working pressure of the machinery. The refrigerating machines shall be designed and constructed to contain the liquefied gas and preclude the risk of bursting or cracking of

the pressure retaining components during normal conditions of carriage. Refrigerating machines and refrigerating-machine components are not subject to the requirements of ADN if they contain less than 12 kg of gas. 292

Mixtures containing not more than 23.5% oxygen by volume may be carried under this entry when no other oxidizing gases are present. A label conforming to model 5.1 is not required for any concentrations within this limit.

293

The following definitions apply to matches: (a)

Fusee matches are matches the heads of which are prepared with a frictionsensitive igniter composition and a pyrotechnic composition which burns with little or no flame, but with intense heat;

(b)

Safety matches are matches which are combined with or attached to the box, book or card that can be ignited by friction only on a prepared surface;

(c)

Strike anywhere matches are matches that can be ignited by friction on a solid surface;

(d)

Wax Vesta matches are matches that can be ignited by friction either on a prepared surface or on a solid surface.

295

Batteries need not be individually marked and labelled if the pallet bears the appropriate mark and label.

296

These entries apply for life-saving appliances such as life rafts, personal flotation devices and self-inflating slides. UN No. 2990 applies to self-inflating appliances and UN No. 3072 applies to life-saving appliances that are not self-inflating. Life-saving appliances may contain: (a)

Signal devices (Class 1) which may include smoke and illumination signal flares packed in packagings that prevent them from being inadvertently activated;

(b)

For UN No. 2990 only, cartridges, power device of Division 1.4, compatibility group S, may be contained for purposes of the self-inflating mechanism and provided that the quantity of explosives per appliance does not exceed 3.2 g;

(c)

Class 2 compressed gases, group A or 0, according to 2.2.2.1.3;

(d)

Electric storage batteries (Class 8) and lithium batteries (Class 9);

(e)

First aid kits or repair kits containing small quantities of dangerous goods (e.g.: substances of Class 3,4.1, 5.2, 8 or 9); or

(f)

"Strike anywhere" matches packed in packagings that prevent them from being inadvertently activated.

300

Fish meal or fish scrap shall not be loaded if the temperature at the time of loading exceeds 35 "C or 5 "C above the ambient temperature whichever is higher.

302

In the proper shipping name, the word "UNIT" means: a vehicle, a wagon, a container or a tank. Fumigated vehicles, containers and tanks are only subject to the provisions of 5.5.2.

303

Receptacles shall be assigned to the classification code of the gas or mixture of gases contained therein determined in accordance with the provisions of section 2.2.2.

304

Batteries, dry, containing corrosive electrolyte which will not flow out of the battery if the battery case is cracked are not subject to the requirements of ADN provided the batteries are securely packed and protected against short-circuits. Examples of such batteries are: alkali-manganese, zinc-carbon, nickel-metal hydride and nickelcadmium batteries.

305

These substances are not subject to the requirements of ADN when in concentrations of not more than 50 mglkg.

306

This entry may only be used for substances that do not exhibit explosive properties of Class 1 when tested in accordance to Test Series 1 and 2 of Class 1 (see Manual of Tests and Criteria, Part I).

307

This entry may only be used for uniform mixtures containing ammonium nitrate as the main ingredient within the following composition limits:

309

(a)

Not less than 90% ammonium nitrate with not more than 0.2% total combustiblelorganic material calculated as carbon and with added matter, if any, which is inorganic and inert towards ammonium nitrate; or

(b)

Less than 90% but more than 70% ammonium nitrate with other inorganic materials or more than 80% but less than 90% ammonium nitrate mixed with calcium carbonate andor dolomite and not more than 0.4% total combustible/organic material calculated as carbon; or

(c)

Nitrogen type ammonium nitrate based fertilizers containing mixtures of ammonium nitrate and ammonium sulphate with more than 45% but less than 70% ammonium nitrate and not more than 0.4% total combustible/organic material calculated as carbon such that the sum of the percentage compositions of ammonium nitrate and ammonium sulphate exceeds 70%.

This entry applies to non sensitized emulsions, suspensions and gels consisting primarily of a mixture of ammonium nitrate and fuel, intended to produce a Type E blasting explosive only after further processing prior to use. The mixture for emulsions typically has the following composition: 6045% ammonium nitrate, 5-30% water, 2-8% fuel, 0.5-4% emulsifier agent, 0-10% soluble flame suppressants, and trace additives. Other inorganic nitrate salts may replace part of the ammonium nitrate. The mixture for suspensions and gels typically has the following composition: 60-85% ammonium nitrate, 0 4 % sodium or potassium perchlorate, 0-17% hexamine nitrate or monomethylamine nitrate, 5-30% water, 2-15% fuel, 0.5-4% thickening agent, 0-10% soluble flame suppressants, and trace additives. Other inorganic nitrate salts may replace part of the ammonium nitrate. Substances shall satisfactorily pass Test Series 8 of the Manual of Tests and Criteria, Part I, Section 18 and be approved by the competent authority.

310

The testing requirements in sub-section 38.3 of the Manual of Tests and Criteria do not apply to production runs consisting of not more than 100 lithium cells and

batteries, or to pre-production prototypes of lithium cells and batteries when these prototypes are carried for testing, if: (a)

the cells and batteries are carried in an outer packaging that is a metal, plastics or plywood drum or a metal, plastics or wooden box and that meets the criteria for packing group I; and

(b)

each cell and battery is individually packed in an inner packaging inside an outer packaging and is surrounded by cushioning material that is noncombustible, and non-conductive.

Substances shall not be carried under this entry unless approved by the competent authority on the basis of the results of appropriate tests according to Part I of the Manual of Tests and Criteria. Packaging shall ensure that the percentage of diluent does not fall below that stated in the competent authority approval, at any time during carriage. (Reserved).

Substances and mixtures meeting the criteria for Class 8 shall bear a subsidiary risk label conforming to model No. 8 (see 5.2.2.2.2). (a)

These substances are liable to exothermic decomposition at elevated temperatures. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds);

(b)

During the course of carriage, these substances shall be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas.

This entry shall not be used for Class 6.1 substances which meet the inhalation toxicity criteria for packing group I described in 2.2.61.1 .S. This entry applies only to calcium hypochlorite, dry, when carried in non friable tablet form. "Fissile-excepted" applies only to those packages complying with 6.4.1 1.2 of ADR. For the purposes of documentation, the proper shipping name shall be supplemented with the technical name (see 3.1.2.8). When the infectious substances to be carried are unknown, but suspected of meeting the criteria for inclusion in category A and assignment to UN No. 2814 or 2900, the words "suspected category A infectious substance" shall be shown, in parentheses, following the proper shipping name on the transport document. Substances packed and packages marked in accordance with packing instruction P650 are not subject to any other requirements of ADN. These storage systems shall always be considered as containing hydrogen. When carried in non-friable tablet form, these goods are assigned to packing group 111. (Reserved).

This substance needs to be stabilized when in concentrations of not more than 99%.

In the case of non-fissile or fissile excepted uranium hexafluoride, the material shall be classified under UN No 2978. In the case of fissile uranium hexafluoride, the material shall be classified under UN No 2977. Waste aerosols consigned in accordance with 5.4.1.1.3 may be carried under this entry for the purposes of reprocessing or disposal. They need not be protected against inadvertent discharge provided that measures to prevent dangerous build up of pressure and dangerous atmospheres are addressed. Waste aerosols, other than those leaking or severely deformed, shall be packed in accordance with packing instruction P003 of ADR and special provision PP87 of ADR, or packing instruction LP02 of ADR and special packing provision L2 of ADR. Leaking or severely deformed aerosols shall be carried in salvage packagings provided appropriate measures are taken to ensure there is no dangerous build up of pressure.

NOTE: For maritime carriage, waste aerosols shall not be carried in closed containers. This entry applies to fuel cell cartridges containing flammable liquids including methanol or methanollwater solutions. Fuel cell cartridge means a container that stores fuel for discharge into fuel cell powered equipment through a valve(s) that controls the discharge of fuel into such equipment and is free of electric charge generating components. The cartridge shall be designed and constructed to prevent the fuel from leaking during normal conditions of carriage. This entry applies to fuel cell cartridge design types shown without their packaging to pass an internal pressure test at a pressure of 100 kPa (gauge). (Reserved).

Alcohols containing petroleum products (e.g. gasoline) up to 5% shall be carried under the entry UN 1987 ALCOHOLS, N.O.S.

33 1-499 (Reserved).

UN No. 3064 nitroglycerin, solution in alcohol with more than 1% but not more than 5% nitroglycerin, packed in accordance with packing instruction P300 of 4.1.4.1 of ADR, is a substance of Class 3. For naphthalene, molten, see UN No. 2304. UN No. 2006 plastics, nitrocellulose-based, self-heating, n.o.s., and 2002 celluloid scrap are substances of Class 4.2.

For phosphorus, white or yellow, molten, see UN No. 2447.

UN No. 1847 potassium sulphide, hydrated with not less than 30% water of crystallization, UN No. 1849 sodium sulphide, hydrated with not less than 30% water of crystallization and UN No. 2949 sodium hydrosulphide with not less than 25% water of crystallization are substances of Class 8. UN No. 2004 magnesium diamide is a substance of Class 4.2.

Alkaline earth metals and alkaline earth metal alloys in pyrophoric form are substances of Class 4.2. UN No. 1869 magnesium or magnesium alloys containing more than 50% magnesium as pellets, turnings or ribbons, are substances of Class 4.1.

UN No. 3048 aluminium phosphide pesticides, with additives inhibiting the emission of toxic flammable gases are substances of Class 6.1. UN No. 1871 titanium hydride and UN No. 1437 zirconium hydride are substances of Class 4.1. UN No. 2870 aluminium borohydride is a substance of Class 4.2. UN No. 1908 chlorite solution is a substance of Class 8. UN No. 1755 chromic acid solution is a substance of Class 8.

UN No. 1625 mercuric nitrate, UN No. 1627 mercurous nitrate and UN No. 2727 thallium nitrate are substances of Class 6.1. Thorium nitrate, solid, uranyl nitrate hexahydrate solution and uranyl nitrate, solid are substances of Class 7.

UN No. 1730 antimony pentachloride, liquid, UN No. 1731 antimony pentachloride solution, UN No. 1732 antimony pentafluoride and UN No. 1733 antimony trichloride are substances of Class 8. UN No. 0224 barium azide, dry or wetted with less than 50% water, by mass, is a substance of Class 1. UN No. 1571 barium azide, wetted with not less than 50% water, by mass, is a substance of Class 4.1. UN No. 1854 barium alloys, pyrophoric, are substances of Class 4.2. UN No. 1445 barium chlorate, solid, UN No. 1446 barium nitrate, UN No. 1447 barium perchlorate, solid, UN No. 1448 barium permanganate, UN No. 1449 barium peroxide, UN No. 2719 barium bromate, UN No. 2741 barium hypochlorite with more than 22% available chlorine, UN No. 3405 barium chlorate, solution and UN No. 3406 barium perchlorate, solution, are substances of Class 5.1. UN No. 1565 barium cyanide and UN No. 1884 barium oxide are substances of Class 6.1. UN No. 2464 beryllium nitrate is a substance of Class 5.1.

UN No. 1581 chloropicrin and methyl bromide mixture and UN No. 1582 chloropicrin and methyl chloride mixture are substances of Class 2.

UN No. 1912 methyl chloride and methylene chloride mixture is a substance of Class 2. UN No. 1690 sodium fluoride, solid, UN No. 1812 potassium fluoride, solid, UN No. 2505 ammonium fluoride, UN No. 2674 sodium fluorosilicate, UN No. 2856 fluorosilicates, n.o.s., UN No. 3415 sodium fluoride, solution and UN No. 3422

potassium fluoride, solution, are substances of Class 6.1. UN No. 1463 chromium trioxide, anhydrous (chromic acid, solid) is a substance of Class 5.1.

UN No. 1048 hydrogen bromide, anhydrous, is a substance of Class 2.

UN No. 1050 hydrogen chloride, anhydrous, is a substance of Class 2. Solid chlorites and hypochlorites are substances of Class 5.1.

UN No. 1873 perchloric acid aqueous solution with more than 50% but not more than 72% pure acid, by mass are substances of Class 5.1. Perchloric acid solutions containing more than 72% pure acid, by mass, or mixtures of perchloric acid with any liquid other than water, are not to be accepted for carriage. UN No. 1382 anhydrous potassium sulphide and UN No. 1385 anhydrous sodium sulphide and their hydrates with less than 30% water of crystallization, and UN No. 2318 sodium hydrosulphide with less than 25% water of crystallization are substances of Class 4.2. UNNo. 2858 finished zirconium products of a thickness of 18 pm or more are substances of Class 4.1. Solutions of inorganic cyanides with a total cyanide ion content of more than 30% shall be classified in packing group I, solutions with a total cyanide ion content of more than 3% and not more than 30% in packing group II and solutions with a cyanide ion content of more than 0.3% and not more than 3% in packing group 111. UN No. 2000 celluloid is assigned to Class 4. l.

UNNo. 1353 fibres or fabrics impregnated with weakly nitrated cellulose, non-self heating are articles of Class 4.1.

UN No. 0135 mercury fulminate, wetted with not less than 20% water, or mixture of alcohol and water, by mass, is a substance of Class 1. Mercurous chloride (calomel) is a substance of Class 9 (UN No. 3077). UN No. 3293 hydrazine, aqueous solution with not more than 37% hydrazine, by mass, is a substance of Class 6.1. Mixtures having a flash-point below 23 "C and containing more than 55% nitrocellulose, whatever its nitrogen content or containing not more than 55% nitrocellulose with a nitrogen content above 12.6% (by dry mass), are substances of Class 1 (see UN Nos. 0340 or 0342) or of Class 4.1. UN No. 2672 ammonia solution containing not less than 10% but not more than 35% ammonia is a substance of Class 8. UN No. 1198 formaldehyde solutions, flammable are substances of Class 3. Formaldehyde solutions, non-flammable, with less than 25% formaldehyde are not subject to the requirements of ADN.

While in some climatic conditions, petrol (gasoline) may have a vapour pressure at 50 "C of more than l l 0 kPa (1.10 bar) but not more than 150 kPa (1S 0 bar) it is to continue to be considered as a substance having a vapour pressure at 50 OC of not more than 110 kPa (1.10 bar). UN No. 1469 lead nitrate, UN No. 1470 lead perchlorate, solid and UN No. 3408 lead perchlorate, solution are substances of Class 5.1. For naphthalene, solid, see UN No. 1334. UN No. 2869 titanium trichloride mixture, not pyrophoric, is a substance of Class 8.

For sulphur (in the solid state), see UN No. 1350.

- 505 -

Solutions of isocyanates having a flash-point of not less than 23 OC are substances of Class 6.1. UNNo. 1326 hafnium powder, wetted, UNNo. 1352 titanium powder, wetted or UN No. 1358 zirconium powder, wetted, with not less than 25% water, are substances of Class 4.1. Nitrocellulose mixtures with a water content, alcohol content or plasticizer content lower than the stated limits are substances of Class 1. Talc containing tremolite andfor actinolite is covered by this entry UN No. 1005 ammonia, anhydrous, UN No. 3318 ammonia solution with more than 50% ammonia and UN No. 2073 ammonia solution, with more than 35% but not more than 50% ammonia, are substances of Class 2. Ammonia solutions with not more than 10% ammonia are not subject to the requirements of ADN. UN No. 1032 dimethylamine, anhydrous, UN No. 1036 ethylamine, UN No. 1061 methylamine, anhydrous and UN No. 1083 trirnethylamine, anhydrous, are substances of Class 2.

UN No. 0401 dipicryl sulphide, wetted with less than 10% water by mass is a substance of Class 1. UN No. 2009 zirconium, dry, finished sheets, strip or coiled wire, in thicknesses of less than 18 pm, is a substance of Class 4.2. Zirconium, dry, finished sheets, strip or coiled wire, in thicknesses of 254 pm or more, is not subject to the requirements of ADN. UN No. 2210 maneb or UN No. 2210 maneb preparations in self-heating form are substances of Class 4.2.

Chlorosilanes which, in contact with water, emit flammable gases, are substances of Class 4.3. Chlorosilanes having a flash-point of less than 23 "C and which, in contact with water, do not emit flammable gases are substances of Class 3. Chlorosilanes having a flash-point equal to or greater than 23 "C and which, in contact with water, do not emit flammable gases are substances of Class 8. UN No. 1333 cerium in slabs, rods or ingots is a substance of Class 4.1. Solutions of these isocyanates having a flash-point below 23 OC are substances of Class 3. Metals and metal alloys in powdered or other flammable form, liable to spontaneous combustion, are substances of Class 4.2. Metals and metal alloys in powdered or other flammable form which, in contact with water, emit flammable gases are substances of Class 4.3. This mixture of hydrogen peroxide and peroxyacetic acid shall, in laboratory testing (see Manual of Tests and Criteria, Part 11, section 20), neither detonate in the cavitated state nor deflagrate at all and shall show no effect when heated under confinement nor any explosive power. The formulation shall be thermally stable (self-accelerating decomposition temperature 60 'C or higher for a 50 kg package), and a liquid

- 506 -

compatible with peroxyacetic acid shall be used for desensitization. Formulations not meeting these criteria are to be regarded as substances of Class 5.2 (see Manual of Tests and Criteria, Part 11, paragraph 20.4.3 (g)). Metal hydrides which, in contact with water, emit flammable gases are substances of Class 4.3. UN No. 2870 aluminium borohydride or UN No. 2870 aluminium borohydride in devices is a substance of Class 4.2. Dust and powder of metals in non-spontaneously combustible form, non-toxic which nevertheless, in contact with water, emit flammable gases, are substances of Class 4.3. Organometallic compounds and their solutions which ignite spontaneously are substances of Class 4.2. Flammable solutions with organometallic compounds in concentrations which, in contact with water, neither emit flammable gases in dangerous quantities nor ignite spontaneously are substances of Class 3. Dust and powder of metals in pyrophoric form are substances of Class 4.2. Metals and metal alloys in pyrophoric form are substances of Class 4.2. Metals and metal alloys which, in contact with water, do not emit flammable gases and are not pyrophoric or self-heating, but which are easily ignited, are substances of Class 4.1. Mixtures of a hypochlorite with an ammonium salt are not to be accepted for carriage. UN No. 1791 hypochlorite solution is a substance of Class 8. UNNo. 3257 elevated temperature liquid, n.o.s., at or above 100 'C and, for a substance with a flash-point, below its flash-point (including molten metals and molten salts) is a substance of Class 9. Chloroformates having predominantly corrosive properties are substances of Class 8. Spontaneously combustible organometallic compounds are substances of Class 4.2. Water-reactive organometallic compounds, flammable, are substances of Class 4.3. UN No. 1905 selenic acid is a substance of Class 8.

UN No. 2443 vanadium oxytrichloride, UN No. 2444 vanadium tetrachloride and UN No. 2475 vanadium trichloride are substances of Class 8. Unspecified wastes resulting from medical/veterinary treatment of humans/animals or from biological research, and which are unlikely to contain substances of Class 6.2 shall be assigned to this entry. Decontaminated clinical wastes or wastes resulting from biological research which previously contained infectious substances are not subject to the requirements of Class 6.2.

UN No. 2030 hydrazine aqueous solution, with more than 37% hydrazine, by mass, is a substance of Class 8. Mixtures containing more than 21% oxygen by volume shall be classified as oxidizing. Barium azide with a water content lower than the stated limit is a substance of Class 1, UN No. 0224. 569-579 (Reserved).

580

Tank-vehicles, specialized vehicles and specially equipped vehicles for carriage in bulk shall bear on both sides and at the rear the mark referred to in 5.3.3. Tank-containers, portable tanks, special containers and specially equipped containers for carriage in bulk shall bear this mark on both sides and at each end.

581

This entry covers mixtures of methylacetylene and propadiene with hydrocarbons, which as: Mixture PI, contain not more than 63% methylacetylene and propadiene by volume and not more than 24% propane and propylene by volume, the percentage of C4-saturatedhydrocarbons being not less than 14% by volume; and as Mixture P2, contain not more than 48% methylacetylene and propadiene by volume and not more than 50% propane and propylene by volume, the percentage of C4-saturatedhydrocarbons being not less than 5% by volume, as well as mixtures of propadiene with 1 to 4% methylacetylene. When relevant, in order to meet the requirements for the transport document (5.4.1. l), the term "Mixture P1" or "Mixture P2" may be used as technical name.

582

This entry covers, inter alia, mixtures of gases indicated by the letter R ..., which as Mixture F1, have a vapour pressure at 70° C not exceeding 1.3 MPa (13 bar) and a density at 50 "C not lower than that of dichlorofluoromethane (1.30 kgll); Mixture F2, have a vapour pressure at 70 "C not exceeding 1.9 MPa (19 bar) and a density at 50 'C not lower than that of dichloridifluoromethane (1.21 kgll); Mixture F3, have a vapour pressure at 70 "C not exceeding 3 MPa (30 bar) and a density at 50 "C not lower than that of chlorodifluoromethane (1.09 kg/l). Trichlorojluoron~ethane (refrigerant R I I), 1,1,2-trichloro-1,2,2NOTE: trzjluoroethane (refrigerant R 1 13), 1,I , I -trichloro-2,2,2-trzjluoroethane (refrigerant R 113a), I-chloro-1,2,2-trzjluoroethane (reJi.igerant R 133) and l -chloro-I,1,2trijluoroethane (refrigerant R 133 b) are not substances of Class 2. The-v may, however, enter into the conzposition of mixtures F1 to F3.

When relevant, in order to meet the requirements for the transport document (5.4.1.l), the term "Mixture F1 ","Mixture F2" or "Mixture F3" may be used as technical name.

583

This entry covers, inter alia, mixtures which as: Mixture A, have a vapour pressure at 70 "C not exceeding 1.1 MPa (1 1 bar) and a density at 50 "C not lower than 0.525 kgll; Mixture A01, have a vapour pressure at 70 'C not exceeding 1.6 MPa (16 bar) and a density at 50 'C not lower than 0.5 16 kgll; Mixture A02, have a vapour pressure at 70 'C not exceeding 1.6 MPa (16 bar) and a density at 50 "C not lower than 0.505 kgll; Mixture AO, have a vapour pressure at 70 'C not exceeding 1.6 MPa (16 bar) and a density at 50 'C not lower than 0.495 kgll;

Mixture A l , have a vapour pressure at 70 "C not exceeding 2.1 MPa (21 bar) and a density at 50 "C not lower than 0.485 kg/l; Mixture B1, have a vapour pressure at 70 "C not exceeding 2.6 MPa (26 bar) and a density at 50 "C not lower than 0.474 kgll; Mixture B2, have a vapour pressure at 70 OC not exceeding 2.6 MPa (26 bar) and a density at 50 "C not lower than 0.463 kg/l; Mixture B, have a vapour pressure at 70 "C not exceeding 2.6 MPa (26 bar) and a density at 50 'C not lower than 0.450 kg/l; Mixture C, have a vapour pressure at 70 "C not exceeding 3.1 MPa (31 bar) and a density at 50 OC not lower than 0.440 kgll; When relevant, in order to meet the requirements for the transport document (5.4.1. l), the following terms may be used as technical name: -

"Mixture A" or "Butanet'; "Mixture A01" or "Butane"; "Mixture A02" or "Butane";

-

"Mixture AO" or "Butane";

-

"Mixture A l ";

-

"Mixture B 1";

-

"Mixture B2";

-

"Mixture B";

-

"Mixture C" or "Propane"

For carriage in tanks, the trade names "butane" or "propane" may be used only as a complement. 584

585

This gas is not subject to the requirements of ADN when: -

it is in the gaseous state;

-

it contains not more than 0.5% air;

-

it is contained in metal capsules (sodors, sparklets) free from defects which may impair their strength;

-

the leakproofness of the closure of the capsule is ensured;

-

a capsule contains not more than 25 g of this gas;

-

a capsule contains not more than 0.75 g of this gas per cm3 of capacity.

Cinnabar is not subject to the requirements of ADN.

Hafnium, titanium and zirconium powders shall contain a visible excess of water. Hafnium, titanium and zirconium powders, wetted, mechanically produced, of a particle size of 53 pm and over, or chemically produced, of a particle size of 840 pm and over, are not subject to the requirements of ADN. Barium stearate and barium titanate are not subject to the requirements of ADN. Solid hydrated forms of aluminium bromide and aluminium chloride are not subject to the requirements of ADN. Calcium hypochlorite mixtures, dry, containing not more than 10% available chlorine are not subject to the requirements of ADN. Ferric chloride hexahydrate is not subject to the requirements of ADN. Lead sulphate with not more than 3% free acid is not subject to the requirements of ADN. Uncleaned empty packagings (including empty IBCs and large packagings), empty tank-vehicles, empty demountable tanks, empty portable tanks, empty tank-containers and empty small containers which have contained this substance are not subject to the requirements of ADN. This gas, intended for the cooling of e.g. medical or biological specimens, if contained in double wall receptacles which comply with the provisions of packing instruction P203 (1 2) of 4.1.4.1 of ADR is not subject to the requirements of ADN. The following articles, manufactured and filled according to the regulations of the manufacturing State and packaged in strong outer packagings, are not subject to the requirements of ADN: -

UN No. 1044 fire extinguishers provided with protection against inadvertent discharge;

-

UN No. 3 164 articles, pressurized pneumatic or hydraulic, designed to withstand stresses greater than the internal gas pressure by virtue of transmission of force, intrinsic strength or construction.

Cadmium pigments, such as cadmium sulphides, cadmium sulphoselenides and cadmium salts of higher fatty acids (e.g. cadmium stearate), are not subject to the requirements of ADN. Acetic acid solutions with not more than 10%pure acid by mass, are not subject to the requirements of ADN. The following are not subject to the requirements of ADN: (a)

New storage batteries when: -

they are secured in such a way that they cannot slip, fall or be damaged;

-

they are provided with carrying devices, unless they are suitably stacked, e.g. on pallets;

-

there are no dangerous traces of alkalis or acids on the outside;

-

(b)

they are protected against short circuits;

Used storage batteries when: -

their cases are undamaged;

-

they are secured in such a way that they cannot leak, slip, fall or be damaged, e.g. by stacking on pallets;

-

there are no dangerous traces of alkalis or acids on the outside of the articles;

-

they are protected against short circuits.

"Used storage batteries" means storage batteries carried for recycling at the end of their normal service life. Manufactured articles or instruments containing not more than 1 kg of mercury are not subject to the requirements of ADN. Vanadium pentoxide, fused and solidified, is not subject to the requirements of ADN. Pharmaceutical products (medicines) ready for use, which are substances manufactured and packaged for retail sale or distribution for personal or household consumption are not subject to the requirements of ADN. Phosphorus sulphides which are not free from yellow and white phosphorus are not to be accepted for carriage. Anhydrous hydrogen cyanide not meeting the description for UN No. 1051 or UN No. 1614 is not to be accepted for carriage. Hydrogen cyanide (hydrocyanic acid) containing less than 3% water is stable, if the pH-value is 2.5 + 0.5 and the liquid is clear and colourless. Ammonium bromate and its aqueous solutions and mixtures of a bromate with an ammonium salt are not to be accepted for carriage. Ammonium chlorate and its aqueous solutions and mixtures of a chlorate with an ammonium salt are not to be accepted for carriage. Ammonium chlorite and its aqueous solutions and mixtures of a chlorite with an ammonium salt are not to be accepted for carriage. Mixtures of potassium nitrate and sodium nitrite with an ammonium salt are not to be accepted for carriage. Ammonium permanganate and its aqueous solutions and mixtures of a permanganate with an ammonium salt are not to be accepted for carriage. Tetranitromethane not free from combustible impurities is not to be accepted for carriage. The carriage of this substance, when it contains more than 45% hydrogen cyanide is prohibited.

Ammonium nitrate containing more than 0.2% combustible substances (including any organic substance calculated as carbon) is not to be accepted for carriage unless it is a constituent of a substance or article of Class 1. (Reserved). Chloric acid solution containing more than 10% chloric acid and mixtures of chloric acid with any liquid other than water is not to be accepted for carriage. 2,3,7,8-tetrachlorodibenzo-p-dioxin(TCDD) in concentrations considered highly toxic according to the criteria in 2.2.61.1 is not to be accepted for carriage. (Reserved). Substances containing more than 40% liquid nitric esters shall satisfy the exudation test specified in 2.3.1. In addition to the type of explosive, the commercial name of the particular explosive shall be marked on the package. In receptacles containing 1,2-butadiene, the oxygen concentration in the gaseous phase shall not exceed 50 ml/m3. 619-622 (Reserved). 623

UN No. 1829 sulphur trioxide shall be inhibited. Sulphur trioxide, 99.95% pure or above, may be carried without inhibitor in tanks provided that its temperature is maintained at or above 32.5 "C. For the carriage of this substance without inhibitor in tanks at a minimum temperature of 32.5 OC, the specification "Transport under minimum temperature of the product of 32.5 OC" shall appear in the transport document.

625

Packages containing these articles shall be clearly marked as follows: "UN 1950 AEROSOLS"

626-627 (Resewed). 632

Considered to be spontaneously flammable (pyrophoric).

633

Packages and small containers containing this substance shall bear the following marking: "Keep away from any source of ignition". This marking shall be in an official language of the forwarding country, and also, if that language is not English, French or German, in English, French or German, unless any agreements concluded between the countries concerned in the transport operation provide otherwise.

635

Packages containing these articles need not bear a label conforming to model No. 9 unless the article is fully enclosed by packaging, crates or other means that prevent the ready identification of the article.

636

(a)

Used lithium cells and batteries collected and presented for carriage for disposal between the consumer collecting point and the intermediate processing facility, together with other non-lithium cells or batteries or alone, are not subject to the other provisions of ADN if they meet the following conditions: (i)

The gross mass of each lithium cell or battery does not exceed 250 g;

(ii)

The provisions of packing instruction P903b (2) of ADR are complied with.

(b)

Cells contained in equipment shall not be capable of being discharged during carriage to the extent that the open circuit voltage falls below 2 volts or two thirds of the voltage of the undischarged cell, whichever is the lower.

(c)

Packages containing used cells or batteries in unmarked packagings shall bear the inscription: "Used lithium cells".

Genetically modified micro-organisms are those which are not dangerous for humans and animals, but which could alter animals, plants, microbiological substances and ecosystems in such a way as cannot occur naturally. Genetically modified microorganisms which have received a consent for deliberate release into the environment1 are not subject to the requirements of Class 9. Live vertebrate or invertebrate animals shall not be used to carry these substances classified under this UN number unless the substance can be carried in no other way. For the carriage of easily perishable substances under this UN number appropriate information shall be given, e.g.: "Coolat +2 O/+4 OC" or "Carryin frozen state" or "Do not freeze". Substances related to self-reactive substances (see 2.2.41.1.19). See 2.2.2.3, classification code 2F, UN No. 1965, Note 2. The physical and technical characteristics mentioned in column (2) of Table A of Chapter 3.2 determine different tank codes for the carriage of substances of the same packing group in tanks conforming to Chapter 6.8 of RID or ADR. In order to identify these physical and technical characteristics of the product carried in the tank, the following shall be added, to the particulars required in the transport document/consignrnent note, only in case of carriage in tanks conforming to Chapter 6.8 of ADR or RID:

"Special provision 640X" where "X" is the applicable capital letter appearing after the reference to special provision 640 in column (6) of Table A of Chapter 3.2. These particulars may, however, be dispensed with in the case of carriage in the type of tank which, for substances of a specific packing group of a specific UN number, meets at least the most stringent requirements. Stone or aggregate asphalt mixture is not subject to the requirements for Class 9. This substance is admitted for carriage provided that:

1

-

The pH is between 5 and 7 measured in an aqueous solution of 10% of the substance carried;

-

The solution does not contain more than 0.2% combustible material or chlorine compounds in quantities such that the chlorine level exceeds 0.02%.

See in particular Part C of Directive 2001/18/EC of the European Parliament and of the Council on the deliberate release into the environment of genetically modiJied organisms and repealing Council Directive 90/220/EEC (Oflcial Journal of the European Communities, No. L 106, of 17 April 2001, pp. 814), which sets out the authorizationprocedures for the European Community.

The classification code as mentioned in Column (3b) of Table A of Chapter 3.2 shall be used only with the approval of the competent authority of a Contracting Party to ADN prior to carriage. When assignment to a division is made in accordance with the procedure in 2.2.1.1.7.2, the competent authority may require the default classification to be verified on the basis of test data derived from Test Series 6 of the Manual of Tests and Criteria. Carbon made by steam activation process is not subject to the requirements of ADN. Except for carriage in tank vessels, the carriage of vinegar and acetic acid with not more than 25 % pure acid by mass is subject only to the following requirements: Packagings, including IBCs and large packagings, and tanks shall be manufactured from stainless steel or plastic material which is permanently resistant to corrosion of vinegarlacetic acid food grade; Packagings, including IBCs and large packagings, and tanks shall be subjected to a visual inspection by the owner at least once a year. The results of the inspections shall be recorded and the records kept for at least one year. Damaged packagings, including IBCs and large packagings, and tanks shall not be filled; Packagings, including IBCs and large packagings, and tanks shall be filled in a way that no product is spilled or adheres to the outer surface; Seals and closures shall be resistant to vinegarlacetic acid food grade. Packagings, including IBCs and large packagings, and tanks shall be hermetically sealed by the person in charge of packaging andor filling so that under normal conditions of carriage there will be no leakage; Combination packagings with inner packaging made of glass or plastic (see packing instruction PO01 in 4.1.4.1 of ADR) which fulfil the general packing requirements of 4.1.1.1, 4.1.1.2, 4.1.1.4, 4.1.1.5, 4.1.1.6, 4.1.1.7 and 4.1.1.8 of ADR may be used; The other provisions of ADN do not apply. Articles impregnated with this pesticide, such as fibreboard plates, paper strips, cotton-wool balls, sheets of plastics material, in hermetically closed wrappings, are not subject to the provisions of ADN. To determine the initial boiling point, as mentioned under 2.2.3.1.3, packing group I, the test method according to standard ASTM ~ 8 6 - 0 1 is ' suitable. Substances which have an initial boiling point above 35 "C determined with this method are substances of packing group II and shall be classified in accordance with the applicable entry of this packing group. Waste consisting of packaging residues, solidified residues and liquid residues of paint may be carried under the conditions of packing group 11. In addition to the provisions of UN No. 1263, packing group 11, the waste may also be packed and carried as follows:

"tandard Test Method for Distillation of Petroleum Products at Atmospheric Pressure, published September 2001 by ASTM International. - 514 -

The waste may be packed in accordance with packing instruction P002 of 4.1.4.1 of ADR or to packing instruction IBC006 of 4.1.4.2 of ADR; The waste may be packed in flexible IBCs of types 13H3, 13H4 and 13H5 in overpacks with complete walls; Testing of packagings and IBCs indicated under (a) or (b) may be carried out in accordance with the requirements of Chapters 6.1 or 6.5 of ADR, as appropriate, in relation to solids, at the packing group I1 performance level. The tests shall be carried out on packagings and IBCs, filled with a representative sample of the waste, as prepared for carriage; Carriage in bulk in sheeted wagons, movable roof wagonslsheeted vehicles, closed containers or sheeted large containers, all with complete walls is allowed. The wagons, containers or body of vehicles shall be leakproof or rendered leakproof, for example by means of a suitable and sufficiently stout inner lining; If the waste is carried under the conditions of this special provision, the goods shall be declared in accordance with 5.4.1.1.3 in the transport document, as follows: "WASTE, UN 1263 PAINT, 3,II. Special provision V2 (1) of ADR is only applicable for a net explosive content of more than 3,000 kg (4,000 kg with trailer). The carriage of this gas in cylinders with a maximum capacity of 0.5 litres, is not subject to the other provisions of ADN if the following conditions are met:

-

The provisions for construction and testing of cylinders are observed;

-

The cylinders are contained in outer packagings which at least meet the requirements of Part 4 for combination packagings. The general provisions of packing of 4.1.1.1, 4.1.1.2 and 4.1.1.5 to 4.1.1.7 of ADR shall be observed;

-

The cylinders are not packed together with other dangerous goods;

-

The total gross mass of a package does not exceed 30 kg; and

Each package is clearly and durably marked with "UN 1013". This marking is displayed within a diamond-shaped area surrounded by a line that measures at least l00 mm by l00 mm. Oil seeds, crushed seeds and seedcake containing vegetable oil, treated with solvents, not subject to spontaneous combustion, are allocated to UNNo. 3175. These substances are not subject to ADN when they have been prepared or treated to ensure that they cannot give off dangerous gases in dangerous quantities (no risk of explosion) during carriage and when this is mentioned in the transport document. Ferrosilicon with between 25 and 30% or more than 90% silicon content by mass is a dangerous substance of Class 4.3 for carriage in bulk or without packaging by inland navigation vessel. See 7.1.4.10.

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CHAPTER 3.4 EXEMPTIONS RELATED TO DANGEROUS GOODS PACKED IN LIMITED QUANTITIES 3.4.1

General requirements

3.4.1.1

Packagings used in accordance with 3.4.3 to 3.4.6 below, need only to conform to the general provisions of 4.1.1. l , 4.1.1.2 and 4.1.1.4 to 4.1.1.8 of ADR.

3.4.1.2

The maximum gross mass of a combination packaging shall not exceed 30 kg and for shrink and stretched wrapped trays shall not exceed 20 kg.

NOTE:

The limitfor combination packagings does not apply when LQ5 is issued.

Subject to the maximum limits in 3.4.1.2 and individual limits in table 3.4.6, dangerous goods may be packed together with other articles or substances, provided they will not react dangerously in the event of leakage. When the code "LQO" is shown in Column (7) of Table A in Chapter 3.2 for a given substance or article, that substance or article is not exempted from any of the applicable provisions of ADN when it is packed in limited quantities, unless otherwise specified in these annexed Regulations. Unless otherwise provided in this Chapter, when one of the codes "LQI" or "LQ2" is shown in Column (7) of Table A in Chapter 3.2 for a given substance or article, the provisions of other Chapters of ADN do not apply to the carriage of that substance or article, provided: (a)

the provisions of 3.4.5 (a) to (c) are observed; with respect to these provisions, articles are considered to be inner packagings;

(b)

inner packagings meet the conditions of 6.2.1.2,6.2.4.1, 6.2.4.3 of ADR.

Unless otherwise provided in this Chapter, when the code "LQ3" is shown in Column (7) of Table A in Chapter 3.2 for a given substance, the provisions of other Chapters of ADN do not apply to the carriage of that substance, provided: (a)

The substance is carried in combination packagings, the following outer packagings being allowed: -

steel or aluminium drums with removable head;

-

steel or aluminium jerricans with removable head;

-

plywood or fibre drums;

-

plastics drums or jerricans with removable head;

-

boxes of natural wood, plywood, reconstituted wood, fibreboard, plastics, steel or aluminium;

and be so designed that they meet the relevant construction requirements of 6.1.4 of ADR; (b)

The maximum net quantities per inner packaging shown in columns (2) or (4) and per package in columns (3) or (5), where indicated, of table 3.4.6 are not exceeded;

(c)

Each package is clearly and durably marked with : (i)

the UN number of the goods contained therein, as given in Column (1) of Table A in Chapter 3.2, preceded by the letters "UN";

(ii)

in the case of different goods with different UN numbers within a single package: -

-

the UN numbers of the goods contained therein, preceded by the letters WN", or the letters "LQ"'.

These markings shall be displayed within a diamond-shaped area surrounded by a line that measures at least 100 mm X 100 mm. The width of line forming the diamond shall be at least 2 mm; the number shall be at least 6 mm high. Where more than one substance assigned to different UN numbers are included in the package, the diamond shall be large enough to include each relevant UN number. If the size of the package so requires, the dimension may be reduced, provided the markings remain clearly visible. Unless otherwise provided in this Chapter, when one of the codes "LQ4" to "LQ19" and "LQ22" to "LQ28" is shown in Column (7) of Table A in Chapter 3.2 for a given substance, the provisions of other Chapters of ADN do not apply to the carriage of that substance, provided: (a)

l

The substance is carried: -

in combination packagings, corresponding to the prescriptions of 3.4.4 (a), or

-

in metal or plastics inner packagings which are not liable to break or be easily punctured, placed in shrink-wrapped or stretch-wrapped trays;

(b)

The maximum net quantities per inner packaging shown in columns (2) or (4) and per package in columns (3) or (5), where indicated, of table 3.4.6 are not exceeded;

(c)

Each package is clearly and durably marked as indicated in 3.4.4 (c).

The letters "Q" are an abbreviation of the English words "Limited Quantities': The letters "LQ" are not permitted by the IMDG Code or the ICAO Technical Instructions.

Code

Combination packagingsa Maximum net quantity per inner packaging

,

per packageb

Inner packagings placed in shrink-wrapped or stretch-wrapped traysa Maximum net quantity per inner packaging

per packageb

(1) LQo LQ 1 LQ2 LQ3 ' LQ4 ' LQ5 ' LQ6 ' LQ7 '

(2) (3) (4) (5) No exemption under the conditions of 3.4.2. 120 m1 120 m1 ll lI ll 500 m1 Not allowed Not allowed 3l ll ll 5l Unlimited 5l 11 5l 51 500 g LQ8 3 kg LQ9 6 kg 3 kg LQlO 500 m1 500 m1 500 g LQl l 500 g LQ12 1 kg 1 kg ll LQ13 ll 25 ml LQ14 25 m1 100 g LQl5 l00 g 125 m1 LQ16 125 m1 2l 500 m1 LQ17 100 m1 2l LQl8 500 g 1 kg 4kg 4 kg LQ19 5 kg 5 kg LQ20 Reserved Reserved Reserved Reserved Reserved LQ2 1 Reserved Reserved Reserved LQ22 11 500 m1 LQ23 3 kg 1 kg LQ24 6 kg 2 kg ~ ~ 2 5 1 kg ~ 1 kg 21 ~ ~ 2 6 500~m1 500 ml 2l LQ27 6 kg 6 kg 3l LQ28 31 " See 3.4.1.2. See3.4.1.3. ' In the case of homogenous mixtures of Class 3 containing water, the quantities speciJ;edrelate only to the substance of Class 3 contained in those mixtures. For W N O S 2315, . 3151, 3152 and 3432 when carried in apparatus, the inner packaging quantities shall not be exceededperpiece of apparatus. The apparatus shall be carried in a leakproofpackaging and the complete package shall conform to 3.4.4 (c). Shrink-wrapped and stretch-wrapped trays shall not be used for apparatus.

Overpacks containing packages conforming to 3.4.3, 3.4.4 or 3.4.5 shall be marked, as required by 3.4.4 (c) for each item of dangerous goods contained in the overpack, unless markings representative of all dangerous goods contained in the overpack are visible.