PREFACE In this sixth edition of the Atlas of Zeolite Framework Types, data are presented for each of the 176 unique zeolite Framework Types that had been approved and assigned a 3-letter code by the Structure Commission of the IZA (IZA-SC) by February 2007.
Six years ago, this number was 133.
The
number of new verified Framework Types reflects the vibrant activity that persists within the zeolite community. In 1970, the paper that can be considered to be the forerunner of the first edition of the
Atlas was published ~) and it described the 27 zeolite framework structures known at the time. With each edition of the Atlas, this number has grown and the exponential trend continues. In that initial paper, the foundation for a systematic description of zeolite framework structures was laid, and we are still using these basic concepts. It is with pleasure and gratitude for this pioneering work that we dedicate this edition of the Atlas to Walter M. Meier, co-author of that first Atlas and co-founder of the Structure Commission of the IZA, on the occasion of his 80th birthday. Each of the zeolite Framework Types included in this book has been examined by the members of the IZA-SC to verify that it conforms to the IZA-SC definition of a zeolite, that it is unique, and that the structure has been satisfactorily proven. The three-letter code that is then assigned is officially recognized by IUPAC, and is used in the nomenclature recommended by IUPAC for these materials. ~2) The rules used by the IZA-SC are given in Appendix B. As a frequently quoted work of reference, the Atlas must be updated on a regular basis to be of full use. Not only must new Framework Types be added, but corrections and new information on existing entries must also be disseminated.
To do this, the IZA-SC maintains a freely available searchable
database on the internet at http://www.iza-structure.org/databases/.
Although all the information in
this book (and more) is available at that website, even the most technologically-minded individuals will admit that it is sometimes easier to access the desired information in a book. This is why we continue to publish a hard copy of the most used data on a periodic basis. In this edition we have prepared new stereo drawings of all Framework Types, added over 250 references, and for the first time, included some composite building units that are common to more than one Framework Type. To make room for the latter, we have removed the loop configurations (still available on the web), reasoning that the vertex symbols provide very similar information. To minimize errors, the data sheets have all been generated directly from the zeolite database that is used for the online version of the Atlas. We wish to acknowledge the assistance and collaboration of many fellow scientists, who have provided us with information and suggested improvements. We are particularly indebted to Henk van Koningsveld, who determined the secondary building units for all the new frameworks, and the members of the IZA Structure Commission, who provided additional information and proofread tirelessly.
It does not seem to be possible to assemble such a compilation without mistakes or
oversights, so we will be grateful for any corrections and/or additions that you communicate to us.
February 2007
Christian Baerlocher
Lynne B. McCusker
David H. Olson
Structure Commission of the International Zeolite Association
Christian Baerlocher
Lynne B. McCusker
Allen W. Burton
Walter M. Meier***
Werner H. Baur
Russell E. Morris
Robert W. Broach
Wilfried J. Mortier
Douglas L. Dorset
Michael O'Keeffe
Reinhard X. Fischer
David H. Olson***
Hermann Gies
Michael M.J. Treacy*
Richard M. Kirchner
Henk van Koningsveld**
Raul F. Lobo
Osamu Terasaki
*
Chairperson
** Co-Chairperson *** Honorary Life Member
Previous IZA Special Publications:
W.M. Meier and D.H. Olson, Atlas of Zeolite Structure Types (1978) W.M. Meier and D.H. Olson, Atlas of Zeolite Structure Types, 2nd ed. (1987) W.M. Meier and D.H. Olson, Atlas of Zeolite Structure Types, 3rd ed. (1992) W.M. Meier, D.H. Olson and Ch. Baerlocher, Atlas of Zeolite Structure Types, 4th ed. (1996) Ch. Baerlocher, W.M. Meier and D.H. Olson, Atlas of Zeolite Framework Types, 5th ed. (2001) W.J. Mortier, Compilation of Extra Framework Sites in Zeolites (1982) R. yon Ballmoos, Collection of Simulated XRD Powder Patterns for Zeolites (1984) R. yon Ballmoos and J.B. Higgins, Collection of Simulated XRD Powder Patterns for Zeolites, 2nd ed. (1990) M.M.J. Treacy, J.B. Higgins and R. yon Ballmoos, Collection of Simulated XRD Powder Patterns for Zeolites, 3rd ed. (1996) M.M.J. Treacy and J.B. Higgins, Collection of Simulated XRD Powder Patterns for Zeolites, 4th ed. (2001 ) H. Robson and K.P. Lillerud, Verified Synthesis of Zeolitic Materials (1998)
INTRODUCTION AND EXPLANATORY NOTES Zeolites and zeolite-like materials do not comprise an easily definable family of crystalline solids. A simple criterion for distinguishing zeolites and zeolite-like materials from denser tectosilicates is based on the framework density (FD), the number of tetrahedrally coordinated framework atoms (T-atoms) per 1000 A3. Figure 1 shows the distribution of these values for porous and dense frameworks, whose structures are well established (3~. A gap is clearly recognizable between zeolitetype and dense tetrahedral framework structures. The maximum FD for a zeolite ranges from 19 to over 21 T-atoms per 1000 A3, depending on the type of smallest ring present, whereas the minimum for denser structures ranges from 20 to 22. Strictly speaking the boundaries defined in Figure 1 for the framework densities only apply to fully crosslinked frameworks, so interrupted frameworks have not been included. For each Framework Type Code (see below), two pages of data are included in this Atlas. The first page lists the information that characterizes the Framework Type. This includes crystallographic data (highest possible space group, cell constants of the idealized framework), coordination sequences, vertex symbols and composite building units. Taken together, the coordination sequences and the vertex symbols define the Framework Type. On the second page, data for the Type Material (i.e. the real material on which the idealized Framework Type is based) can be found. Although the channel dimensionality is a property of the Framework Type, the channel description also includes the observed ring dimensions, and must therefore refer to the Type Material. For each Framework Type, a list of isotypic materials with the corresponding references is also given. The different entries in the data sheets are described in more detail below.
Framework Type Page Framework Type Code Following the roles set up by an IUPAC Commission on Zeolite Nomenclature in 1979 ~4),designations consisting of three capital letters (in boldface type) have been used throughout. The codes are generally derived from the names of the Type Materials (see Appendix G) and do not include numbers and characters other than capital Roman letters. The assignment of Framework Type Codes is subject to review and clearance by the IZA Structure Commission according to a decision of the IZA Council (taken at the time of the 7th IZC in Tokyo, 1986). Codes are only assigned to established structures that satisfy the rules of the IZA Structure Commission (see Appendix B for a listing of these rules). For interrupted frameworks, the 3-letter code is preceded by a hyphen. These mnemonic codes should not be confused or equated with actual materials. They only describe and define the network of the corner sharing tetrahedrally coordinated framework atoms. Thus, designations such as NaFAU are untenable.
However, a material can be described using the IUPAC crystal chemical formula ~2), as
INa~l [A158Si134O384]-FAU or INa-I [A1-Si-O]-FAU.
Note that the chemical elements must be enclosed within the appropriate (boldface) brackets (i.e. I I for guest species and [ ] for the framework host)
FD
quartz moganite
26-
albite
24-
cristobalite
cordierite milaritc
tridymite
banalsite
22
scapolite
-
,
i[''''~ ~,~,~ ~,~,~~
parace.lsi~n
,~
".
| •
-
16-
E
1
I
I l ,!iiii~iir
p
18g
i
......,~i't;TF)
O
•
,
iiiliiiiiill~i l ii~i ~ ~i ~il'!i ii! ~qiiiiil
!
n~,
,
~
S
O
"#
|
.~,o - -~
".4-" .-'" " 08. ~ -"
0 0 0
0
•
•
.
..-
.." ""
.'"
• (UTL).O"
-
•
14-
(r~'~., """
I
|
0 •
o
..
p
p
-
•
° p
12-
.-
P p
10-
." d.
p P P "
o
(RWY~o
""
p p
I
3
Fig. l.
'
I
4
'
I
'
I
5 6 Average Size of Smallest Ring
F r a m e w o r k density calculated for the idealized SiO 2 framework vs. average size of the smallest ring in the structure.
and that the stoichiometry may, but does not have to be specified. Framework Types do not depend on composition, distribution of the T-atoms (Si, A1, P, Ga, Ge, B, Be, etc.), cell dimensions or symmetry. The Framework Types have been arranged in alphabetical order according to the Framework Type Code, because structural criteria alone do not provide an unambiguous classification scheme. This also facilitates later insertion of new codes and allows simple indexing. The Framework Type Code is given at the top of each page. On the first page this is supplemented with the maximum space group symmetry for the framework, and on the second page with the full name of the Type Material. In this edition, the new designation "e" in space groups with double-glide planes has been used (e.g. Cmma is now Cmme).
Framework drawing A stereographic drawing of the framework, generated using the program CrystalMaker (5~ is presented for each Framework Type. Although the depth fading helps in viewing the drawings, the use of a stereo viewer is recommended (can be obtained from any electron microscopy supply house). The coordinates of the idealized, highest symmetry structures have been used for these drawings. Only the positions of the T-atoms are shown. The T-O-T bridges are represented by straight lines. This idealization makes it easier to visualize the topology and the basic features of these (often complex) framework structures. The unit cell is outlined and the orientation of the axes indicated. For most frameworks, more than a unit cell is shown, but for cases where the figures would have been too complex, only a part of the unit cell is depicted.
In these cases a projection along a major axis is
shown to help in visualizing the build-up of the complete framework.
Idealized cell parameters The idealized cell parameters were obtained from a DLS-refinement
using the given (highest
possible) symmetry of the Framework Type. The refinement was carried out assuming a (sometimes h y p o t h e t i c a l ) SiO 2 composition and with the following prescribed interatomic distances: ds~_o- 1.61A,
do_o - 2.629A and Ds~_s~- 3.07A using the weights of 2.0, 0.61 and 0.23, respectively.
Coordination sequences (CS) and vertex symbols The concept of coordination sequences was originally introduced by Brunner and L a v e s (7~ and first applied to zeolite frameworks by Meier and Moeck ~8~. In a typical zeolite framework, each T-atom is connected to N ~ - 4 neighboring T-atoms through oxygen bridges. These neighboring T-atoms are then linked in the same manner to N 2 T-atoms in the next shell. The latter are connected to N 3 T-atoms etc. Each T-atom is counted only once. In this way, a coordination sequence can be determined for each T-atom of the 4-connected net of T-atoms. It follows that N O- 1
Nj < 4
N 2 _< 12
N 3 _< 36...
Nk
_< 4 • 3 k-1
CS's are listed from N~ up to N~0 for each topologically distinct T-atom in the framework structure along with the site multiplicity and the site symmetry (both in parenthesis). The vertex symbol was first used in connection with zeolite-type networks by M. O' Keefe and S.T. Hyde (9~. This symbol indicates the size of the smallest ring associated with each of the 6 angles of a
tetrahedron (T-atom). The symbols for opposite pairs of angles are grouped together. For FAU the vertex symbol reads 4 . 4 . 4 . 6 - 6 . 1 2 , indicating that one pair of opposing angles contains 4-rings, a second pair a 4-ring and a 6-ring, and the final pair a 6-ring and a 12-ring. It is useful for determining the smallest rings in a framework. In the case of DOH, for example, the vertex symbols for the four T-atoms are 5.5.5.5.5.6, 4.5.5-6- 5.6, 5- 5.5.5.5.6 and 5.5.5- 5.5.5, so the smallest rings are 4- and 5-rings, (4.75 in Figure 1). Sometimes more than one ring of the same size is found for a single angle. This is indicated with a subscript like
6 2 o r 8 2.
An asterisk in the vertex symbol indicates that no ring is
formed for that angle. The coordination sequence and the vertex symbol together appear to be unique for a particular framework topology.
That is, they can be used to distinguish different zeolite Framework Types
unambiguously. In this way, isotypic frameworks can be recognized easily.
Secondary building units (SBU's) Zeolite frameworks can be thought to consist of finite or infinite (i.e. chain- or layer-like) component units. The finite units which have been found to occur in at least two tetrahedral frameworks are shown in Appendix C. TO 4
These secondary building units (primary building units are
tetrahedra), which contain up to 16 T-atoms, are derived assuming that the entire framework is
made up of one type of SBU only. It should be noted that SBU's are invariably non-chiral (neither left- nor right-handed) and a unit cell always contains an integral number of them.
As far as
practicable, all possible SBU's have been listed. The number of observed SBU's has increased from 20 in 2001 to 23.
For Framework Types with an SBU that only occurs once or for which
combinations of SBU's are necessary, the reader is referred to the Compendium of Zeolite Framework
Types. Building Schemes and Type Characteristics by H. van Koningsve 1.s(10) u , where all SBU's are listed in detail. The symbols given below the drawings in Appendix C are used in the data sheets. If more than one SBU is possible for a given Framework Type, all are listed. The number given in parenthesis in Appendix C indicates the frequency of the occurrence of that SBU. The SBU's are only theoretical topological building units and should not be considered to be or equated with species that may be in the solution/gel during the crystallization of a zeolitic material.
Framework description For all 19 Framework Types belonging to the so-called ABC-6-family, the ABC stacking sequence is given. Some other structural relationships which are thought to be helpful are also listed.
Composite Building Units (CBU's) Some units (e.g. double 6-ring, cancrinite cage, alpha cavity, double crankshaft chain) appear in several different framework structures, and can be useful in identifying relationships between Framework Types. Smith has compiled an exhaustive list of such units, not only for zeolite structures but also for hypothetical 3-dimensional 4-connected nets (~). In his Compendium(~0), van Koningsveld has also included an extensive list of them. Here we have arbitrarily selected just 47 Composite Building Units and five chains (Appendix D) that are found in at least two different Framework Types. These are different from secondary building units in that they are not required to be achiral, and cannot
necessarily be used to build the entire framework. To facilitate communication, each unit has been assigned a lower case italic three-character designation. With the exception of the double 4-, 6- and 8rings (d4r, d6r and d8r, respectively), a code corresponding to one of the Framework Types containing the CBU has been used for this purpose. A comparison of the notation used by Smith, van Koningsveld and here is also given in Appendix D.
Materials with this Framework Type Under this heading, as-synthesized materials that have the same Framework Type but different chemical composition or have a different laboratory designation are listed.
Materials obtained by
post-synthesis treatment (e.g. ion exchange, dealumination, etc.) are generally not included. The Type Material (defined on the second page) is given first and marked with an asterisk. These materials are also listed in the Isotypic Material Index at the end of the book.
References The list of references cited is far from complete.
As a general rule, references for the Type
Material are to the work that first established the Framework Type and to subsequent work adding significant information regarding the framework topology.
Thus papers on non-framework species
have not been included. References for other materials with a specific framework type are limited to work in which sufficient data are provided to establish the framework type. For most of the codes from ABW to RHO, complete references, cell constant data, space groups, site symmetries, symmetry relationships, structural diagrams, positional coordinates and chemical compositions for all crystal structure determinations published up to April 2000 can be found in the Landolt-B6rnstein Series on Microporous and other framework materials with zeolite-type structures edited by W.H. Baur and R.X. Fischer ~j2,.
Type Material Page The Type Material is the species first used to establish the Framework Type. Detailed information about the material is given on this page.
Crystal chemical data The chemical composition, expressed in terms of unit cell contents, has been idealized where necessary for simplicity. The chemical formula is given according to IUPAC recommendations ~2~. For each Type Material, the space group and cell parameters listed are taken from the reference cited. In many instances, further refinement of the structure taking into account ordering etc. would yield a lower symmetry. It should also be noted that the space group and other crystallographic data related to the Type Material structure do not necessarily apply to isotypes. In some cases, the space group setting of the Type Material differs from that of the Framework Type.
In these cases, the relationship between the two unit cells is given.
This relationship is
important when comparing the orientation of the channel direction and the viewing direction of ring
drawings (both are given for the axis orientation of the Type Material) with that of the framework drawing.
Framework density (FD) The framework density is defined as the number of T-atoms per 1000 ~3. The number given refers to the Type Material. For non-zeolitic framework structures, these values tend to be at least 20 to 21 T/1000
/k 3,
while for zeolites with fully crosslinked frameworks, the observed values range from
-12.1, for structures with the largest pore volume, to --20.6. To date, FD's of less than 12 have only been encountered for the interrupted framework cloverite (-CLO) (~3~, for the sulfide UCR-20 (~4~ --
(RWY), and for hypothetical networks
(15)
. The FD is obviously related to the pore volume but does
not reflect the size of the pore openings.
For some of the more flexible zeolite structures, the FD
values can vary appreciably. In these cases (e.g. gismondine) values are given for the Type Material and for the framework in its most expanded state. The flexibility of a framework structure is, to some extent, revealed by the possible variation in FD.
FD values may also depend on chemical
composition.
Channels A shorthand notation has been adopted for the description of the channels in the various frameworks. Each system of equivalent channels has been characterized by •
the channel direction (relative to the axes of the Type Material structure),
•
the number of T-atoms (in bold type) forming the rings controlling diffusion through the channels, and
•
the crystallographic free diameters of the channels in Angstrom units.
The number of asterisks in the notation indicates whether the channel system is one-, two- or threedimensional.
In most cases, the smaller openings simply form windows (rather than channels)
connecting larger cavities. Interconnecting channel systems are separated by a double arrow ( ~ ) . A vertical bar (I) means that there is no direct access from one channel system to the other. The examples below have been selected to illustrate the use of this notation. Cancrinite Offretite
[001] 12 5.9 x 5.9* [001] 12 6.7 x 6.8* ~
2_ [001] 8 3.6 x 4.9**
Mordenite
[001] 12 6.5 x 7.0* ~
{ [010] 8 3.4 x 4.8 +-+ [001] 8 2.6 x 5.7 }*
Zeolite Rho
<100> 8 3.6 x 3.6*** I <100> 8 3.6 x 3.6***
Gismondine
{[100] 8 3 . 1 x 4 . 5 ~
[010] 8 2.8x4.8}***
Cancrinite is characterized by a 1-dimensional system of channels parallel to [001] (or c) with circular 12-ring apertures. In offretite, the main channels are similar but they are interconnected at right angles by a 2-dimensional system of 8-ring channels, and thus form a 3-dimensional channel system. The channel system in mordenite is essentially 2-dimensional with somewhat elliptical 12-ring apertures. The 8-ring limiting diffusion in the [001] direction is an example of a highly puckered aperture. Zeolite rho is an example of a Framework Type containing two non-interconnecting 3-dimensional channel systems which are displaced with respect to one another (<100> means there are channels
parallel to all crystallographically equivalent axes of the cubic structure, i.e., along [100], [010] and [001 ]). In gismondine, the channels parallel to [100] together with those parallel to [010] give rise to a 3-dimensional channel system which can be pictured as an array of partially overlapping tubes. A summary of the channel systems, ordered by decreasing number of T-atoms in the largest ring, is given in Appendix E. The free diameter values (effective pore width) given in the channel description and on the ring drawings are based upon the atomic coordinates of the Type Material and an oxygen radius of 1.35,~. Both minimum and maximum values are given for non-circular apertures. In some instances, the corresponding interatomic distance vectors are only approximately coplanar, in other cases the plane of the ring is not normal to the direction of the channel. Close inspection of the framework and ring drawings should provide qualitative evidence of these factors. Some ring openings are defined by a very complex arrangement of oxygen atoms, so in these cases other short interatomic distances that are not listed may also be observed. It should be noted that crystallographic free diameters may depend upon the hydration state of the zeolite, particularly for the more flexible frameworks.
It should also be borne in mind that effective free diameters can be affected by non-
framework cations and may also be temperature dependent. Note that the channel direction is given for the axis orientation of the Type Material. This orientation may be different from the orientation given in the framework drawing (see the cell relationship given under "crystal chemical data" for these cases).
Stability In some cases, the Type Material is not stable to heating and/or removal of the template. This has been indicated, if the information was available.
Ring drawings Stereographic drawings of the limiting channel windows are presented for all Framework Types. In contrast to the framework drawings, all atoms are shown in the ring drawings. Their positions are based on the crystal structure of the Type Material, and therefore the ring dimensions and the viewing direction are also those of the Type Material. As explained in the crystal chemical data section, for a few Type Materials, the orientation of the crystallographic axes is different from that given for the Framework Type. In these cases, the relationship given in the "crystal chemical data" section must be applied when comparing the viewing direction of the ring drawings with that of the framework drawing.
10
Supplementary Information Topological densities The coordination sequences (CS) can be used to calculate a topological density (TD). As might be expected, the CS is a periodic function.
This has been established for all observed framework
topologies by Grosse-Kunstleve, Brunner and Sloane ~6~. They showed that the CS of any T - a t o m can be described exactly by a set of p quadratic equations N k - aik2 + bik +
Ci
for k - i + np,
n - 0,1,2 .... and
i - 1,2,3 .... p
For example, the CS of ABW (NI= 4 N2= 10 N3= 21 N4=36 Ns= 54 N6= 78 NT= 106, etc.) is exactly described by a set of three quadratic equations (p=3), namely Nk-
19/9k 2 + 1 / 9 k + 1 6 / 9
for k - l + 3 n ,
n =0,1,2 ....
Nk-
19/9k 2 - 1 / 9 k + 1 6 / 9
for k - 2 + 3 n ,
n = 0,1,2 ....
Nk-
19/9k 2 - 0 k + 2
for k - 3 + 3 n ,
n = 0,1,2 ....
The number of equations p necessary to calculate all members of a particular coordination sequence varies from p=l for SOD and p=42 for FAU to p=140,900,760 for EUO. With growing index k (the shell number of the CS), the linear and constant coefficients, bi and ci, respectively, become less and less important. Therefore we can define the exact topological density TD as the mean of all ai divided by the dimensionality of the topology (i.e. 3 for zeolites) 1 TD - < ai-------~>= ~ 3p i---1
This TD is the same for all T atoms in a given structure. For some frameworks, this calculation can take quite a long time, so an approximation valid to _+0.001 has been used to calculate the values given in Appendix F for each of the Framework Types. The value for
has been approximated as the mean of ai for the last 100 terms of a CS with 1000 terms (TD1000:100), weighted with the multiplicity of the atom position, and divided by three (dimensionality). The value for TD~0 (sum of the CS values for N o to N10), which was listed in the first four editions of the Atlas, is also given for comparison. There is a simple relationship between TD and TD10:TD~0 - TD * 1155. Since TD~0 is an approximation, i.e. it is 'arbitarily' terminated at N~0, the values obtained by this formula deviate by 11% f o r - C L O and 5% for FAU but the differences are generally below 3%. It seems that for very open structures, 10 steps are not sufficient for a satifactory convergence. The correlation factor between the exact topological density TD and the framework density FD is 0.82.
Origin of 3-letter codes and Type Material names The derivation of the 3-letter codes for the zeolite minerals is fairly obvious, because the code generally consists of the first 3 letters of the mineral name.
For the synthetic materials this is
sometimes more obscure. One reason for this is that numbers are frequently included to distinguish different products from a particular lab, and these numbers cannot be transferred directly to the
11 framework code. To help the reader better understand the origin of the codes, a table that includes all Framework Type codes derived from synthetic Type Materials is given in Appendix G. In this table, the letters taken for the code are written in bold.
Also, an attempt has been made to decipher the
origin of the mnemonic sometimes used in the designations of these materials.
lsotypic material index All materials are listed in alphabetical order in this index. To make the index as informative as possible, all reported materials and designations have been included in this section, provided the Framework Type assignment appears to be reasonably well established.
Even a number of
occasionally used, but discredited, names of mineral species have been included for the same reason. A full list of obsolete and discredited zeolite mineral names can be found in a report of the subcommittee on zeolites of the International Mineralogical Association ~7~. Moreover, the inclusion of a synthetic material's designation in this index must not be interpreted to mean that the designation has been formally recognized or generally accepted.
References are to be found on the respective
Framework Type data sheets.
References (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11)
(12)
(13) (14) (15) (16) (17)
W.M. Meier and D.H. Olson, Adv. Chem. Ser. 101, 155 (1970) L.B. McCusker, F. Liebau and G. Engelhardt, Pure Appl. Chem. 73, 381 (2001) G.O. Brunner and W.M. Meier, Nature 337, 146 (1989) R.M. Barrer, Pure Appl. Chem. 51, 1091 (1979) CrystalMaker, a Crystal Structure Program for MacOS Computers. CrystalMaker Software, P.O. Box 183, Bicester, Oxfordshire, OX6 7BS, UK (http://www.crystalmaker.co.uk) Ch. Baerlocher, A. Hepp. and W.M Meier, "DLS-76, a program for the simulation of crystal structures by geometric refinement". (1978). Lab. f. Kristallographie, ETH, Zt~rich. G.O. Brunner and F. Laves, Wiss. Z. Techn. Univers. Dresden 20, 387 (1971) H.2 W.M,. Meier and H.J. Moeck, J. Solid State Chem. 27, 349 (1979) M. O'Keefe and S.T. Hyde, Zeolites 19, 370 (997) H. van Koningsveld, Compendium of Zeolite Framework Types. Building Schemes and Type Characteristics, Elsevier, Amsterdam, 2007 J.V. Smith, Tetrahedral frameworks of zeolites, clathrates and related materials. Subvolume A in Landolt-B6rnstein, Numerical Data and Functional Relationships in Science and Technology, New Series, Group IV: Physical Chemistry, Volume 14, Microporous and other Framework Materials with ZeoliteType Structures, eds. W.H. Baur, R.X. Fischer, Springer, Berlin, 2000 W.H. Baur and R.X. Fischer, Zeolite Structure Codes A B W to RHO. Subvolumes B-D in LandoltB6rnstein, Numerical Data and Functional Relationships in Science and Technology, New Series, Group IV: Physical Chemistry, Volume 14, Microporous and other Framework Materials with Zeolite-Type Structures, eds. W.H. Baur, R.X. Fischer, Springer, Berlin, 2000 M. Estermann, L.B. McCusker, Ch. Baerlocher, A. Merrouche and H. Kessler, Nature 352, 320 (199!) N. Zheng, X. Bu, B. Wang and P. Feng, Science 298, 2366 (2002) W.M. Meier, Proc. 7th IZC Tokyo, Kodansha-Elsevier, 1986, p. 13 R.W. Grosse-Kunstleve, G.O. Brunner and N.J.A. Sloane, Acta Crystallogr. A52, 879 (1996) D.S. Coombs, A. Alberti, T. Armbruster, G. Artioli, C. Colella, E. Galli, J.D. Grice, F. Liebau, J.A. Mandarino, H. Minato, E.H. Nickel, E. Passaglia, D.R. Peacor, S. Quartieri, R. Rinaldi, M. Ross, R.A. Sheppard, E. Tillmanns, G. Vezzalini, Can. Mineral. 35, 1571 (1997) or Mineral. Mag. 64, 533 (1998) or Eur. J. Mineral. 10, 1037 (1998)
14
ABW
Framework Type Data
Imma
t
/ X Z
framework viewed along [01 O]
Idealized cell data:
orthorhombic, Imma, a - 9.9/k, b - 5.3A,, c - 8.8A
Coordination sequences and vertex symbols: T, (8,m)
4
10
Secondary building units:
21
36
54
78
106
136
173
4.6.4.6.6.8~
214
8or4
Composite building units: dzc
abw
double zigzag chain
Materials with this framework type" *Li-A (Barrer and White) ~1-3) [ B e - A s - O ] - A B W (4'5) [ B e - P - O ] - A B W (4'6'7) [ G a - S i - O ] - A B W (8) [ Z n - A s - O ] - A B W (4'9) [ Z n - P - O ] - A B W (4) I(NH4)-I[Co-P-O]-ABW(1°) [(NH4)-I[Zn-As-O]-ABW (1~)
](NH4)-I[Zn-P-OI-ABW
(12)
ICs-I[Mg-P-OI-ABW(13) ]Cs-][A1-Si-O]-ABW (~4'~5) ICs-I[A1-Ti-O]-ABW (~6~ [Li-[[Zn-As-O]-ABW (~7~ ILi-I[A1-Si-O]-ABW~8) ILi-I[Zn-P-O]-ABW(19) [Li-I[A1-Ge-O]-ABW (2°)
[Na-I[Zn-P-O]-ABW (2~) INa-I[Co-P-O]-ABW (22~ IRb-I[Cu-P-OI-ABW ~23) IRb-I[Ni-P-OI-ABW (24)
IRb-I[Co-P-O]-ABW~13) IRb-I[A1-Si-OI-ABW ~14'15)
ITI-[[A1-Si-O]-ABW~5) UCSB-3 (26)
15
Li-A (Barrer and White)
Type Material Data
ABW
Crystal chemical data:
ILi4 (H20)41 [A14Si40,6]-ABW orthorhombic, Pna2~, a - 10.3 l/k, b - 8.18/k, c - 5.00A ~2) (Relationship to unit cell of Framework Type: a ' = a, b ' = c, c ' = b)
Framework density:
19 T/1000A 3
Channels:
[001] 8 3.4 x 3.8*
8-ring viewed along [001]
References: (1) Barrer, R.M. and White, E.A.D.J. Chem. Soc., 1267-278 (1951) (2) Kerr, I.S.Z. Kristallogr., 139, 186-195 (1974) (3) Krogh Andersen, E. and Ploug-SOrensen, (3. Z. Kristallogr., 176, 67-73 (1986) (4) Gier, T.E. and Stucky, G.D. Nature, 349, 508-5 l0 (1991) (5) Harrison, W.T.A., Gier, T.E. and Stucky, G.D. Acta Crystallogr., C51, 181-183 (1995) (6) Robl, C. and Gobner, V. J. Chem. Soc., Dalton Trans., 1911-1912 (1993) (7) Zhang, H., Chen, M., Shi, Z., Bu, X., Zhou, Y., Xu, X. and Zhao, D. Chem. Mater., 13, 2042-2048 (2001) (8) Newsam, J.M.J. Phys. Chem., 92, 445-452 (1988) (9) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001) (10) Feng, P., Bu, X., Tolbert, S.H. and Stucky, G.D.J. Am. Chem. Soc., 119, 2497-2504 (1997) (11) Johnson, C.D., Macphee, D.E. and Feldmann, J. lnorg. Chem., 41, 3588-3589 (2002) (12) Bu, X., Feng, P., Gier, T.E. and Stucky, G.D. Zeolites, 19, 200-208 (1997) (13) Rakotomahanina Ralaisoa, E.L. Ph.D. Thesis, Univ. Grenoble (1972) (14) Klaska, R. and Jarchow, O. Naturwiss., 60, 299 (1973) (15) Klaska, R. and Jarchow, O. Z. Kristallogr., 142, 225-238 (1975) (16) Gatehouse, B.M. Acta Crystallogr., C45, 1674-1677 (1989) (17) Jensen, T.R., Norby, P., Christensen, A.N. and Hanson, J.C. Microporous Mesoporous Mat., 26, 77-87 (1998) (18) Ghobarkar, H. Cryst. Res. Technol., 27, 1071-1075 (1992) (19) Harrison, W.T.A., Gier, T.E., Nicol, J.M. and Stucky, G.D.J. Solid State Chem., 114, 249-257 (1995) (20) Tripathi, A., Kim, S.J., Johnson, G.M. and Parise, J.B. Microporous Mesoporous Mat., 34, 273-279 (2000) (21) Ng, H.Y. and Harrison, W.T.A. Microporous Mesoporous Mat., 23, 197-202 (1998) (22) Chippindale, A.M., Cowley, A.R., Chen, J.S., Gao, Q. and Xu, R. Acta Crystallogr., C55, 845-847 (1999) (23) Henry, P.F., Hughes, R.W., Ward, S.C. and Weller, M.T. Chem. Commun., 1959-1960 (2000) (24) Henry, P.F., Weller, M.T. and Hughes, R.W. Inorg. Chem., 39, 5420-5421 (2000) (25) Krogh Andersen, I.G., Krogh Andersen, E., Norby, P., Colella, C. and Degennaro, M. Zeolites, 11, 149-154 (1991) (26) Bu, X., Feng, P., Gier, T.E. and Stucky, G.D.J. Solid State Chem., 136, 210-215 (1998)
16
ACO
m
Framework Type Data
Im3m
1 ~
y
X
framework viewed along [001] m
Idealized cell data:
o
cubic, I m 3 m , a - 9.9A
Coordination sequences and vertex symbols: T 1(16,3m) 4 9 19 35 52 72 Secondary building units:
8 or 4-4 or 4
Composite building units" d4r
Materials with this framework type: • ACP_I ~)
100
131
163
201
4.82-4-8~.4.8 ~
17
ACP-1
ACO
Type Material Data
Crystal chemical data:
I(C2H,oN2)4 (H20)21 [Alo.ssCo7.,2PsO32]-ACO C2H~oN2 = ethylenediammonium tetragonal, 1-42m, a - 10.240A, c - 9 . 6 5 2 A ¢l)
F r a m e w o r k density:
15.8 T/1000A 3
Channels
<100> 8 2.8 x 3.5** +--+ [001] 8 3.5 x 3.5*
8-ring viewed along <100>
References(l) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997)
8-ring viewed along [001]
18
AEI
Framework Type Data ..................
~ , ~ : ~
Cmcm
.......
Y
L. framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 13.7A,, b - 12.6/~, c -
18.5A,
Coordination sequences and vertex symbols: (16,1)
4
9
17
29
45
64
85
111
143
177
4-4.4.8.6.8
T 2(16,1)
4
9
17
29
45
65
88
113
143
178
4.4-4-8-6.8
T 3(16,1)
4
9
17
29
45
65
87
113
143
176
4.4.4.8.6.8
T l
Secondary building units:
6-6 or 4-2 or 6 or 4
Composite building units: d6r
Materials with this framework type" • A1PO_18 <1) [Co-A1-P-O]-AEI <2) SAPO- 18 (3) SIZ_8 (4) SSZ_39 ~5
19
AIPO-18
AEI
Type Material Data
Crystal chemical data:
[A124P24096]-AEI monoclinic, C2/c a - 13.71 1A, b - 12.732A, c - 18.571A, 3 - 9 0.01°~1)
Framework density: Channels:
14.8 T/1000A 3 {[100183.8x3.8o
[110183.8x3.8o
8-ring viewed along [100]
[001183.8x3.8}***
8-ring viewed along [11 O]
8-ring viewed along [001]
References: (1) Simmen, A., McCusker, L.B., Baerlocher, Ch. and Meier, W.M. Zeolites, 11,654-661 (1991) (2) Marchese, L., Chen, J.S., Thomas, J.M., Coluccia, S. and Zecchina, A. J. Phys. Chem., 98, 13350-13356 (1994) (3) Chen, J.S., Thomas, J.M., Wright, P.A. and Townsend, R.P. Catalysis Letters, 28, 241-248 (1994) (4) Parnham, E.R. and Morris, R.E.J. Am. Chem. Soc., 128, 2204-2205 (2006) (5) Wagner, P., Nakagawa, Y., Lee, G.S., Davis, M.E., Elomari, S., Medrud, R.C. and Zones, S.I.J. Am. Chem. Soc., 122, 263-273 (2000)
20
AEL
Framework Type Data
Imma
z
frameworkviewedalong[100] I d e a l i z e d cell d a t a :
orthorhombic,
Imma,a -
8.3/k, b - 18.7/k, c - 13.4/k
Coordination sequences a n d v e r t e x symbols" T 1 (16,1)
4
11
21
37
59
85
114
150
189
232
4.62.6.63.62.63
T 2(16,1)
4
11
22
38
58
85
115
148
188
234
4.62.6.63.62.63
T~(8,m)
4
12
24
40
59
84
115
150
186
230
6.62.62.62.62-62
Secondary building units: Composite building units"
nsc
narSch:Ukite
4-1
afi t~
bog ~ ~
Materials with this framework type: *A1PO- 11 ~,2) G e A P O - 11 ~3) M n A P O - 11 ~4~ (5 6)
SAPO-11 plus n u m e r o u s compositional variants '
21
AIPO-11
Type Material Data
AEL
Crystal chemical data:
[A12oP2oO80]-AEL orthorhombic, Ibm2, a - 13.534/~,, b - 18.482/k, c - 8.370A (2) (Relationship to unit cell of Framework Type: a ' - ¢, b ' - b, c ' - a)
Framework density"
19.1 T/1000A 3
Channels"
[001] 10 4.0 x 6.5*
1O-ring viewed along [001 ]
References: (1) Bennett, J.M., Richardson Jr., J.W., Pluth, J.J. and Smith, J.V. Zeolites, 7, 160-162 (1987) (2) Richardson Jr., J.W., Pluth, J.J. and Smith, J.V. Acta Crystallogr., B44, 367-373 (1988) (3) Meriaudeau, P., Tuan, V.A., Hung, L.N. and Szabo, G. Zeolites, 19, 449-451 (1997) (4) Pluth, J.J., Smith, J.V. and Richardson Jr., J.W.J. Phys. Chem., 92, 2734-2738 (1988) (5) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure Appl. Chem., 58, 1351-1358 (1986) (6) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986)
22
AEN
Framework Type Data
Cmce
! t
~
y
framework viewed along [001] Idealized cell data:
orthorhombic,
Cmce, a - 18.5/k, b - 13.4A, c - 9.6/k
Coordination sequences and vertex symbols: T 1 (16,1)
4
11
24
41
60
86
123
162
199
248
4"63"62"82"63"8
T 2(16,1)
4
11
22
39
64
90
119
155
201
250
4"6"6"62"62"64
T 3(16,1)
4
11
22
38
63
90
116
155
204
250
4"63"62"63"62"8
Secondary building units:
6or4
Materials with this framework type" • A1PO_EN3 ~ [ G a - P - O ] - A E N ~2~ A 1 P O - 5 3 ( A ) ~3~ A 1 P O - 5 3 ( B ) ~3~
C o l S T _ 2 ~5~ IST_2 (6~ JDF_2 ~7~ M C S _ I ~8~
C F S A P O _ I A (4~
M n A P O - 14 (9~
Mu_IO °°) U i 0 _ 1 2 - 5 0 0 ~11~ UiO_12_as ~1~
23
AIPO-EN3 Crystal chemical data:
Type Material Data
AEN
[(C2HsN2)4 (H20),6l [Alz4P24096]-AEN CzHsN 2 = ethylenediamine orthorhombic, P2~2~2,, a - 10.292 A,, b - 13.636A,, c - 17.344 A~~1) (Relationship to unit cell of Framework Type: a ' = c, b'= b, c'= a)
Framework density:
19.7 T/1000A 3
Channels:
[100] 8 3.1 x 4.3* ~ [010] 8 2.7 x 5.0*
4
8-ring viewed along [100]
~,
8-ring viewed along [010]
References: (1) Parise, J.B. Stud. Surf. Sci. Catal., 24, 271-278 (1985) (2) Glasser, F.P., Howie, R.A. and Kan, Q.B. Acta Crystallogr., C50, 848-850 (1994) (3) Kirchner, R.M., Grosse-Kunstleve, R.W., Pluth, J.J., Wilson, S.T., Broach, R.W. and Smith, J.V. Microporous Mesoporous Mat., 39, 319-332 (2000) (4) He, H. and Long, Y. J. Incl. Phenom., 5, 591-599 (1987) (5) Borges, C., Ribeiro, M.F., Henriques, C., Lourenco, J.P., Murphy, D.M., Louati, A. and Gabelica, Z. J. Phys. Chem. B, 108, 8344-8354 (2004) (6) Fernandes, A., Ribeiro, M.F., Borges, C., Lourenco, J.P., Rocha, J. and Gabelica, Z. Microporous Mesoporous Mat., 90, 112-128 (2006) (7) Chippindale, A.M., Powell, A.V., Jones, R.H., Thomas, J.M., Cheetham, A.K., Huo, Q.S. and Xu, R.R. Acta Crystallogr., C50, 1537-1540 (1994) (8) Simmen, A. Ph.D. Thesis, ETH, Ziirich, Switzerland (1992) (9) Shi, L., Li, J.Y., Yu, J.H., Li, Y., Ding, H. and Xu, R. Inorg. Chem., 43, 2703-2707 (2004) (10) Soulard, M., Patarin, J. and Marler, B. Solid State Sci., 1, 37-53 (1999) (11) Kongshaug, K.O., Fjellv~g, H., Klewe, B. and Lillerud, K. P. Microporous Mesoporous Mat., 39, 333-339 (2000)
24
AET
Framework Type Data
Cmcm
Y
framework viewed along [001] Idealized cell data:
orthorhombic, Cmcm, a - 32.8A, b - 14.4A, c - 8.4/k
Coordination sequences and vertex symbols" T l (16,1)
4
11
21
35
53
78
108
140
172
208
4-62"6-63.62.63
T 2(16,1)
4
11
21
35
52
74
102
136
172
212
4-62"62"63"62"63
T 3(16,1)
4
11
22
38
55
74
98
132
173
216
4"62-6.63-62.63
T 4(16,1)
4
12
23
36
52
75
103
135
172
215
6"62"62"62"62"62
T 5(8,m)
4
10
18
32
52
76
105
140
171
202
4.63.4.63.6.64
Secondary building units: Composite building units"
nsc narsarsukite chain
dnc double narsarsukite chain
Materials with this framework type: • A1PO_8 ~1,2) MCM_37 ~3~
aft ~
bog
25
Type Material Data
AIPO-8
AET
Crystal chemical data:
[A136P360144]-AET orthorhombic, Cmc2~, a - 33.29A, b - 14.76A, c - 8.257A (~)
Framework density:
17.7 T/1000A 3
Channels:
[001] 14 7.9 x 8.7*
8.7
i
14-ring viewed along [001]
References: (1) Dessau, R.M., Schlenker, J.L. and Higgins, J.B. Zeolites, 10, 522-524 (1990) (2) Richardson Jr., J.W. and Vogt, E.T.C. Zeolites, 12, 13-19 (1992) (3) Chu, C.T.W., Schlenker, J.L., Lutner, J.D. and Chang, C.D.U.S. Patent 5,091,073 (1992)
26
AFG
P6Jmmc
Framework Type Data
z
J.y f r a m e w o r k viewed normal to [001]
Idealized cell data:
hexagonal, P63/mmc, a - 12.5/k, c - 20.8/k
Coordination sequences and vertex symbols" T~(24,1)
4
10
20
34
53
76
103
135
170
208
4.6.4.6.6.6
T 2(12,m)
4
10
20
34
54
78
104
134
168
210
4.6.4.6.6.6
T 3(12,2)
4
10
20
34
54
78
104
134
168
210
4.4.6.6.6.6
Secondary building units"
6or4
Framework description:
A B A B A C A C sequence of 6-rings
Composite building unitscar/
lio
J Materials with this framework type: *Afghanite ~1"4~
27
Afghanite
Type Material Data
Crystal chemical data:
ICag.sNae: (HeO)4 C1e(SO4)5.3CO~1 [Ale4Sie4096]oA F G hexagonal, P63mc, a = 12.761A, c = 21.416A (3~
Framework density"
15.9 T/1000A 3
Channels:
apertures formed by 6-rings only
AFG
References: (1) Bariand, P., Cesbron, F. and Giraud, R. Bull. Soc.fr. Mindral. Cristallogr., 91, 34-42 (1968) (2) Merlino, S. and Mellini, M. Zeolite 1976, Program and Abstracts, Tucson (1976) (3) Pobedimskaya, E.A., Rastsvetaeva, R.K., Terent'eva, L.E. and Sapozhnikov, A.N. Dokl. Akad. Nauk SSSR, 320, 882-886 (1991 ) (4) Ballirano, P., Bonaccorsi, E., Maras, A. and Merlino, S., Eur. J. Mineral., 9, 21-30 (1997)
28
AFI
P61mcc
Framework Type Data
?/
~ : ? ~ 2 2 2 2 L ............12221':~./
X
F
y
framework viewed along [001] (upper right: projection down [001 ])
Idealized cell data:
h e x a g o n a l , P6/mcc, a - 13.8,~, c - 8.6/k
Coordination sequences and vertex symbols: T 1 (24,1)
4
11
Secondary building units: Composite building units" nsc
21
35
53
77
105
137
172
212
4"62"6"63"62"63
12 or 6 or 4
aft
bog
narsarsukite chain
Materials with this framework type: • A1PO_5 (1~ [ S n - A 1 - P - O ] - A F I (2~ [(Ni(deta)2)-I [ A 1 - P - O - F - ] - A F I ~ I T P A F - I [ A I - P - O ] - A F I (4~ C o A P O _ 5 (5,6~ CrAPO_5 (7~ F A P O _ 5 (8~
M A P O - 5 , M - Cd, Cu, M o , V / M o , Z r (9~ M A P O - 5 , M = M g , M n (~°~ S A P O - 5 and n u m e r o u s c o m p o s i t i o n a l variants (~'12~ SSZ_24 (13~ VAPO_5 (14~ ZnAPO_5 (~5~
29
Type Material Data
AIPO-5
AFI
I(C,2H2~N)(H20) ~ (OH)I
Crystal chemical data:
[Al~2P~2O4J-AFI C~2H28N = tetrapropylammonium hexagonal, P6cc, a - 13.726/k, c - 8.484/k (~)
Framework density:
17.3 T/1000,~ 3
Channels:
[001 ] 12 7.3 x 7.3" :7.
7.3
":~
.........................
7.3
.,
7.3
12-ring viewed along [001 ]
References: (1) Bennett, J.M., Cohen, J.P., Flanigen, E.M., Pluth, J.J. andSmith, J.V. ACSSym. Set.,218, 109-118 (1983) (2) Flavell, W.R., Nicholson, D.G., Nilsen, M.H. and St~hl, K. J. Mater. Chem., 11,620-627 (2001) (3) Garcia, R., Shannon, I.J., Slawin, A.M.Z., Zhou, W., Cox, P.A. and Wright, P.A. Microporous Mesoporous Mat., 58, 91-104 (2003) (4) Qiu, S., Pang, W., Kessler, H. and Guth, J.L. Zeolites, 9, 440-444 (1989) (5) Montes, C., Davis, M.E., Murray, B. and Narayana, M. J. Phys. Chem., 94, 6425-6430 (1990) (6) Chao, K.J., Sheu, S.P. and Sheu, H.S.J. Chem. Soc., Faraday Trans., 88, 2949-2954 (1992) (7) Radaev, S., Joswig, W. and Baur, W.H.J. Mater. Chem., 6, 1413-1418 (1996) (8) Zenonos, C., Sankar, G., Cora, F., Lewis, D.W., Pankhurst, Q.A., Catlow, C.R.A. and Thomas, J.M. Phys Chem Chem Phys, 4, 5421-5429 (2002) (9) Kornatowski, J., Sychev, M., Finger, G., Baur W.H., Rozwadowski, M. and Zibrowius, B. Proc. PolishGerman Zeolite Colloquium, 20-26 (1992) (10) Parrillo, D.J., Pereira, C., Kokotailo, G.T. and Gorte, R.J.J. Catal., 138, 377-385 (1992) (11) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure Appl. Chem., 58, 1351-1358 (1986) (12) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986) (13) Bialek, R., Meier, W.M., Davis, M. and Annen, M.J. Zeolites, 11,438-442 (1991) (14) Bedioui, F., Briot, E., Devynck, J. and Balkus, K.J. Inorganica Chimica Acta, 254, 151-155 (1997) (15) Christensen, A.N. and Hazell, R.G. Acta Chemica Scand., 53, 403-409 (1999)
30
AFN
Framework Type Data
C21m
y
framework viewed normal to [010]
Idealized cell data:
monoclinic, C2/m, a - 14A, b - 13.5/k, c - 10.2A, ~ = 107.2 °
Coordination sequences and vertex symbols: T 1 (8,1)
4
9
19
33
51
76
98
123
162
203
4.4.4.82.6.84
T 2(8,1)
4
9
18
31
49
72
99
130
160
198
4.4-4.82.6-62
T 3(8,1)
4
9
17
30
49
75
102
125
157
202
4.6.4.8.4.87
T 4(8,1)
4
10
21
35
50
71
100
132
164
198
4.4.6.8.8.82
Secondary building units:
8or4
Composite building units" mei
Materials with this framework type" *A1PO- 14 ~'2)
I(c~N~H0 I[Mn-A1-P-O]-AFN ~ GaPO_14 ~4~
31
AIPO-14
Type Material Data
Crystal chemical data:
AFN
[A18PsO32]-AFN triclinic, P]-, a - 9.704A, b -
9.736A, c - 10.202A
oL - 77.81 °, ~3- 77.50 °, ~ - 87.69 ° ~ F r a m e w o r k density:
17.4 T/1000A 3
Channels:
[100] 8 1.9 x 4.6* <-->[010] 8 2.1 x 4.9* <'-> [001] 8 3.3 x 4.0*
8-ring viewed along [100]
8-ring viewed along [010]
8-ring viewed along [001]
References: (1) Broach, R.W., Wilson, S.T. and Kirchner, R.M. Proc. 12th Int. Zeolite Conf., III, pp. 1715-1722 (1999) (2) Broach, R.W., Wilson, S.T. and Kirchner, R.M. Microporous Mesoporous Mat., 57, 211-214 (2003) (3) Shi, L., Li, J., Duan, F., Yu, J., Li, Y. and Xu, R. Microporous Mesoporous Mat., 85, 252-259 (2005) (4) Parise, J.B. Acta Crystallogr., C42, 670-673 (1986)
32
AFO
Framework Type Data
Cmcm
y
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 9.8A, b - 25.6A, c - 8.3A
Coordination sequences and vertex symbols: T 1(16,1)
4
11
22
38
58
85
115
149
190
235
4"62"6"63"62"63
T 2(8,m)
4
11
22
41
65
88
111
145
186
231
4"62-6"63-6-63
T 3 (8,m)
4
11
21
36
56
82
115
156
195
231
4"62"62"63"62"63
T 4 (8,m)
4
12
23
37
55
82
118
155
189
232
6.62.62.62.62.62
Secondary building units:
2-6-2 or 4-1
Composite building units: nsc
aft
bog
narsarsukite chain
Materials with this framework type: * A1PO-41 (1)
M n A P S O-41 ~2~
M n A P O - 4 1 <2)
SAPO-41 (2)
33
AIPO-41 Crystal chemical data:
Type Material Data
AFO
[All0P1004o]-AFO monoclinic, P2 1 a - 9.718A, b - 13.792A, c - 8.359A, 7 - 110.6 °(~ (Relationship to unit cell of Framework Type:
a'= a, b ' - b/(2sinT'), c'= c or, as vectors, a ' = a, b ' = (b - a)/2, c ' = c) Framework density"
19.1 T/1000A 3
Channels:
[001] 10 4.3 x 7.0*
lO-ring viewed along [001]
References: (1) Kirchner, R.M. and Bennett, J.M. Zeolites, 14, 523-528 (1994) (2) Hartmann, M., Prakash, A.M. and Kevan, L. J. Chem. Soc., Faraday Trans., 94, 723-727 (1998)
34
AFR
Framework Type Data
Pmmn
=
~
-~
y
X
framework viewed along [001]
Idealized cell data:
o r t h o r h o m b i c , Pmmn (origin choice 2), a - 22.3A, b - 13.6/k, c - 7 A
Coordination sequences and vertex symbols" T 1 (8,1)
4
9
16
27
43
63
88
115
141
171
4-6.4.62.4-8
T 2(8,1)
4
9
18
30
43
64
90
111
140
181
4.4.4.8.63-8
T 3(8,1)
4
9
18
29
42
66
93
112
139
177
4.4.4.12-6-63
T 4(8,1)
4
10
17
28
47
65
86
117
144
169
4"6-4"6"6" 12
Secondary building units:
6-2 or 4-4- or 4
Composite building units: sti
Materials with this framework type" • S A P O _ 4 0 ~v3~ A1PO_40 ~4,s)
C o A P S O - 4 0 ~6~ Z n A P O _ 4 0 ~4~
C o A P O _ 4 0 ~4~
Z n A P S O - 4 0 ~6)
35
SAPO-40
Type Material Data
AFR
Crystal chemical data:
I(C,2H28N)4 (OH)4I [SisA12sP28 O,28]-AFR C~2H28N = tetrapropylammonium orthorhombic, Pccn, a - 21.944,~, b - 13.691A, c - 14.249A (3~ (Relationship to unit cell of Framework Type: a'= a, b'= b, c'= 2c)
Framework density: Channels:
15 T/1000A 3 [001] 12 6.7 x 6.9* <-->[010] 8 3.7 x 3.7* ~:.
6.7
i
6.7
..
....
!6.9
12-ring viewed along [001]
8-ring viewed along [01 O]
References: Estermann, M.A., McCusker, L.B. and Baerlocher, Ch. J. Appl. Crystallogr., 25, 539-543 (1992) Dumont, N., Gabelica, Z., Derouane, E.G. and McCusker, L.B. Microporous Materials, 1, 149-160 (1993) McCusker, L.B. and Baerlocher, Ch. Microporous Materials, 6, 51-54 (1996) Lourenco, J.P., Ribeiro, M.F., Ribeiro, F.R., Rocha, J., Onida, B., Garrone, E. and Gabelica, Z. Zeolites, 18, 398-407 (1997) (5) Ramaswamy, V., McCusker, L.B. and Baerlocher, Ch. Microporous Mesoporous Mat., 31, 1-8 (1999) (6) Lourenco, J.P., Ribeiro, M.F., Borges, C., Rocha, J., Onida, B., Garrone, E. and Gabelica, Z. Microporous Mesoporous Mat., 38, 267-278 (2000) (1) (2) (3) (4)
36
AFS
P6almcm
Framework Type Data ........:!..........................................ii15 ... ::~......
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
h e x a g o n a l , P63/mcm, a - 13.1A, c - 25.9/k
Coordination sequences and vertex symbols: T 1(24,1)
4
9
17
28
42
60
83
111
138
166
4.4-4-82.62.8
T 2(24,1)
4
9
16
25
39
61
86
109
134
163
4.4.4"6- 6" 12
T 3(8,3)
4
9
18
30
43
62
85
105
135
180
4.8-4.8"4"8
Secondary building units:
6"1
Composite building units:
afs
bph
Materials with this framework type" • M A P S O - 4 6 ~1~ M A P O _ 4 6 ~2~
37
MAPSO-46 Crystal chemical data:
Type Material Data
I(C~H,~N)a(H20),41 [Mg6A122P26Si20~21-AFS CoH16N : dipropylammonium trigonal, P 3 c l , a - 13.225A, c - 26.892A (~)
Framework density:
13.7 T/1000.~ 3
Channels:
[001] 12 7.0 x 7.0* <-->l [001] 8 4.0 x 4.0**
...
12-ring viewed along [001 ]
:.::
8-ring viewed normal to [001]
References: (1) Bennett, J.M. and Marcus, B.K. Stud. Surf Sci. Catal., 37, 269-279 (1988) (2) Akolekar, D.B. and Kaliaguine, S. J. Chem. Soc., Faraday Trans., 89, 4141-4147 (1993)
AFS
38
AFT
P6almmc
Framework Type Data
z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data"
hexagonal, P63/mmc, a = 13.7A, c - 29.4/k
Coordination sequences and vertex symbols: T, (24,1)
4
9
17
29
45
64
85
110
140
173
4-4.4-8.6.8
T 2(24,1)
4
9
17
29
45
64
86
113
144
178
4.4-4.8.6-8
(24,1)
4
9
17
29
45
65
88
113
141
175
4.4.4.8.6-8
T3
Secondary building units:
6-6 or 4-2 or 6 or 4
Framework description:
A A B B C C A A C C B B sequence of 6-rings
Composite building units: d6r
gme
cha . . . . . . . . . . . . . . . . ~ ........
Materials w i t h this framework type" • A1PO_52 <1,2)
aft .,
39
AIPO-52 Crystal chemical data:
AFT
Type Material Data [A136P360144]-AFT trigonal, P-31c, a - 13.715A, c -
Framework density:
14.9 T/1000A 3
Channels:
l [001] 8 3.2 x 3.8***
gme cage 8-ring viewed normal to [001 ]
29.676/k ~2~
cha cage 8-ring viewed normal to [001]
References: (1) Bennett, J.M., Kirchner, R.M. and Wilson, S.T. Stud. Surf Sci. Catal., 49, 731-739 (1989) (2) McGuire, N.K., Bateman, C.A., Blackwell, C.S., Wilson, S.T. and Kirchner, R.M. Zeolites, 15, 460-469 (1995)
40
AFX
P6Jmmc
Framework Type Data
7.
framework viewed normal to [001] (upper right: projection down [001 ])
Idealized cell data:
hexagonal, P63/mmc, a - 13.7/k, c - 19.7/k
C o o r d i n a t i o n sequences a n d vertex symbols: T 1(24,1)
4
9
17
29
45
65
89
116
144
175
4.4-4.8-6-8
T 2(24,1)
4
9
17
29
45
64
85
110
141
178
4-4.4-8.6.8
Secondary building units:
6-6 or 4-2 or 6 or 4
F r a m e w o r k description:
AABBCCBB sequence of 6-rings
C o m p o s i t e building units: d6r
gme
M a t e r i a l s with this f r a m e w o r k type: • SAPO_56 (1,2~ MAPSO-56, M=Co, Mn, Zr ~3~ SSZ_16 (4~
aft
41
SAPO-56
Type Material Data
AFX
IH I [SisAlz3P20096]-AFX
Crystal chemical data:
trigonal, P-31c, a - 13.762A, c - 19.949A (2~ Framework density:
14.7 T/1000A. 3
Channels:
2_ [001] 8 3.4 x 3.6***
3.6 •
3.4
....
8-ring viewed normal to [OOl]
References: (1) McGuire, N.K., Blackwell, C.S., Bateman, C.A., Wilson, S.T. and Kirchner, R.M. private communication (2) Wilson, S.T., Broach, R.W., Blackwell, C.S., Bateman, C.A., McGuire, N.K. and Kirchner, R.M. Microporous Mesoporous Mat., 28, 125-137 (1999) (3) Tian, P., Liu, Z., Xu, L. and Sun, C. Stud. Surf. Sci. Catal., 135, 248 (05-P-18) (2001) (4) Lobo, R.F., Zones, S.I. and Medrud, R.C. Chem. Mater., 8, 2409-2411 (1996)
42
AFY
Framework Type Data
P31m
F ~:<::S!;;;;;, ...................:>J ........................
y
X
framework viewed along [001] (upper right: projection down [001]) n
Idealized cell data:
trigonal, P31m, a -
12.3/k, c - 8.6/k
Coordination sequences and vertex symbols: T, (12,1)
4
8
14
25
39
53
71
96
124
152
4.4.4.8.4.12
T 2(4,3)
4
9
16
23
34
57
82
98
115
141
4-8-4.8.4-8
Secondary building units:
4-4 or 4
Composite building units:
d4r
Materials with this framework type: • CoAPO_50 <~,2~ M g A P O - 5 0 ~3~ M n A P O _ 5 0 <4~ ZnAPO_50 ~5~
43
Type Material Data
CoAPO-50 Crystal chemical data:
I(C6H,6N)3 (H20)71 [Co3A15PaO32]-AFY C6H16N = dipropylammonium trigonal, P-3, a - 12.747A, c - 9.015A (2~
Stability"
Unstable to removal of template (~
Framework density:
12.6 T/1000,~ 3
Channels:
[001] 12 6.1 x 6.1" ~ A_ [001] 8 4.0 x 4.3**
":"..
12-ring viewed along [001 ]
AFY
3
8-ring viewed normal to [001]
References: (1) (2) (3) (4) (5)
Wilson, S.T. private communication Bennett, J.M. and Marcus, B.K. Stud. Surf. Sci. Catal., 37, 269-279 (1988) Akolekar, D.B. Zeolites, 15, 583-590 (1995) Tusar, N.N., Ristic, A., Meden, A. and Kaucic, V. Microporous Mesoporous Mat., 37, 303-311 (2000) Arcon, I., Tusar, N.N., Ristic, A., Kaucic, V., Kodre, A. and Helliwell, M. J. Synch. Rad., 8, 590-592 (2001)
44
AHT
Framework Type Data ........................ ~
~
....
Cmcm
¸:,ij!~'~'~'i~'!ii¸i¸ii~
U
Y
x
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 15.8/k, b - 9.2/k, c - 8.6A
Coordination sequences and vertex symbols" T, (16,1)
4
11
21
36
56
81
109
142
179
221
4.62.6.63-6.63
T 2(8,m)
4
10
18
32
53
78
105
140
179
218
4.63.4.63.6.64
Secondary building units:
4-2 or 6
Composite building units: dnc
bog
double narsarsukite chain
Materials with this framework type: • A1PO_H2 ~-3~
45
AIPO-H2 Crystal chemical data:
Type Material Data
AHT
I(H:O) I [A16P6Oz4]-AHT monoclinic, P2~, a - 9.486*, b - 9 . 9 1 4 ' , c - 8 . 1 2 6 ' , ~ - 121.49 °(~) (Relationship to unit cell of Framework Type: a ' = a/(2sin~'), b ' = b, c ' = c or, as vectors, a ' = (a - b)/2, b ' = b, c ' = c)
Stability:
Transforms to A1PO4-tridymite on heating (3)
Framework density:
18.4 T/1000A 3
Channels:
[OO1] 10 3.3 x 6.8*
1O-ring viewed along [001]
References: (1) (2) (3)
Higgins, J.B. private communication Li, H.X., Davis, M.E., Higgins, J.B. and Dessau, R.M. Chem. Commun., 403-405 (1993) Kennedy, G.J., Higgins, J.B., Ridenour, C.F., Li, H.X. and Davis, M.E. Solid State Nucl. Mag. Res., 4, 173-178 (~995)
46 !
ANA
Framework Type Data
/a3d
¢
i ii i
k(~..............................................................~/
x
framework viewed along [001]
Idealized cell data:
cubic, Ia-3d , a - 13.6~,
Coordination sequences and vertex symbols: T 1(48,2)
4
10
Secondary building units:
22
39
60
87
118
154
196
242
4"4"6"6"84"84
6-2 or 6 or 4-[1,1] or 1-4-1 or 4
Materials with this framework type: • Analcime (1-3) ICs_Na_(H20) [[Ga-Si-O]-ANA - -(~3) [A1-Co-P-O]-ANA (4) Ifs 1 6 [ [ C u 8 S i a o O 9 6 ] - A N A (14) [A1-Si-P-O]-ANA (5) IK-I[Be-B-P-O]-ANA (~5~ IK-I[B-Si-O]-ANA [Ga-Ge-O]-ANA (6) ]Li-l[Li-Zn- Si-O]-ANA - --(17) [Zn-As-O]-ANA (7) ]Li-NaI[A1-Si-O]-ANA (18) I(NH4)-I[Be-B-P-O]-ANA~8~ INa-I[B e-B-P-O]-ANA I(NH4)-I[Zn-Ga-P-O]ANA (9) A1PO_24 (2°) A1PO4-pollucite(21) [Cs-[[A1-Ge-O]-ANA (1°) 1" (22) [Cs-[[Be-Si-O]-ANA (11) Ammonioleuc'te Ca_D (23) ICs-FeI[Si-O]-ANA (12) -
-(16)
-
--(19)
Hsianghualite(24) Leucite (25) Na_B (26) Pollucite (27) Synthetic analcime(28) Synthetic hsinghualite(29) (30) Synthetic wairakite Wairakite, compositional variants °~)
References" (1) Taylor, W.H. Z Kristallogr., 74, 1-19 (1930) (2) Knowles, C.R., Rinaldi, F.F. and Smith, J.V. Indian Mineral., 6, 127- (1965) (3) Ferraris, G., Jones, D.W. and Yerkess, J. Z. Kristallogr., 135, 240-252 (1972) (4) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997) (5) Artioli, G., Pluth, J.J. and Smith, J.V. Acta Crystallogr., C40, 214-217 (1984) (6) Bu, X., Feng, P., Gier, T.E., Zhao, D. and Stucky, G.D.J. Am. Chem. Soc., 120, 13389-13397 (1998) (7) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001) (8) Zhang, H.Y., Chen, Z.X., Weng, L.H., Zhou, Y.M. and Zhao, D.Y. Microporous Mesoporous Mat., 57, 309-316 (2003)
47
Analcime
Type Material Data
Crystal chemical data:
[Na,6 (H20),6l [A1,6Si32096]-ANA cubic, Ia-3d, a - 13.73A ~3)
Framework density:
18.5 T/1000A 3
Channels"
irregular channels formed by highly distorted 8-rings
ANA
distorted 8-ring viewed along [110]
References (cont.): (9) Logar, N.Z., Mrak, M., Kaucic, V. and Golobic, A. J. Solid State Chem., 156, 480-486 (2001) (10) Tripathi, A. and Parise, J.B. Microporous Mesoporous Mat., 52, 65-78 (2002) (11) Torres-Martines, L.M., Gard, J.A., Howie, R.A. and West, A.R.J. Solid State Chem., 51, 100-103 (1984) (12) Kopp, O.C., Harris, L.A., Clark, G.W. and Yakel, H.L. Am. Mineral., 48, 100-109 (1963) (13) Yelon, W.B., Xie, D., Newsam, J.M. and Dunn, J. Zeolites, 10, 553-558 (1990) (14) Heinrich, A.R. and Baerlocher, Ch. Acta Crystallogr., C47, 237-241 (1991) (15) Zhang, H.Y., Chen, Z.X., Weng, L.H., Zhou, Y.M. and Zhao, D.Y. Microporous Mesoporous Mat., 57, 309-316 (2003) (16) Millini, R., Montanari, L. and Bellussi, G. Microporous Materials, 1, 9-15 (1993) (17) Park, S.H., Gies, H., Toby, B.H. and Parise, J.B. Chem. Mater., 14, 3187-3196 (2002) (18) Seretkin, Y.V., Bakakin, V.V. and Bazhan, I.S.J. Struct. Chem., 46, 659-671 (2005) (19) Zhang, H.Y., Chen, Z.X., Weng, L.H., Zhou, Y.M. and Zhao, D.Y. Microporous Mesoporous Mat., 57, 309-316 (2003) (20) Wilson, S.T., Lok, B.M., Messina, C.A., Cannan, T.R. and Flanigen, E.M.J. Am. Chem. Soc., 104, 11461147 (1982) (21) Keller, E.B. Ph.D. Thesis, ETH, Ziirich, Switzerland (1987) (22) Hori, H., Nagashima, K., Yamada, M., Miyawaki, R. and Marubashi, T. Am. Mineral., 71, 1022-1027 (1986) (23) Ames, L.L. and Sand, L.B. Am. Mineral., 43, 476-480 (1958) (24) Wen-Hui, H., Saho-Hua, T., Kung-Hai, W., Chun-Lin, C. and Cheng Chi, Y. Am. Mineral., 44, 1327-1328 (1959) (25) Peacor, D.R.Z. Kristallogr., 127, 213-224 (1968) (26) Barrer, R.M. and White, E.A.D.J. Chem. Soc., 1561-1571 (1952) (27) Nel, H.J. Am. Mineral., 29, 443-451 (1944) (28) Ghobarkar, H. and Franke, W. Cryst. Res. Technol., 1071-1075 (1986) (29) Ghobarkar, H., Schaef, O. and Knauth, Pl Annal. Chimie, Science Mat~riaux, 24, 209-215 (1999) (30) Ghobarkar, H. Cryst. Res. Technol., K90-92 (1985) (31) Takeuchi, Y., Mazzi, F., Haga, N. and Galli, E. Am. Mineral., 64, 993-1001 (1979)
48
APC
Framework Type Data
Cmce ":::iiiiii~ii~.
"
i
i
Z
framework viewed along [100]
Idealized cell data:
o r t h o r h o m b i c , Cmce, a - 9.0/k, b - 19.4A, c - 10.4/k
Coordination sequences and vertex symbols: T 1 (16,1)
4
9
19
35
53
75
102
132
168
208
T 2 (16,1)
4
10
20
35
54
76
104
136
171
211
Secondary building units:
8or4
Composite building units: dcc double crankshaft chain
Materials with this framework type: • A1PO_C °,2~ A1PO_H3 ~3~ C o A P O _ H 3 ~4~
4.4.4.82-8.82 4.6.4.6.6.82
49
Type Material Data
AIPO-C
APC
Crystal chemical data:
[Alj6PI6064]-APC orthorhombic, Pbca, a - 19.821A, b - 10.028A, c - 8.936A ~2) (Relationship to unit cell of Framework Type: a ' = b, b ' = c, c ' = a)
Stability:
Transforms to A1PO-D at ca 250°C (2)
Framework density:
18 T/1000A 3
Channels:
[001] 8 3.4 x 3.7* ~ [100] 8 2.0 x 4.7*
8-ring viewed along [001]
distorted 8-ring viewed along [100]
References: (1) Bennett, J.M., Dytrych, W.J., Pluth, J.J., Richardson Jr., J.W. and Smith, J.V. Zeolites, 6, 349-359 (1986) (2) Keller, E.B., Meier, W.M. and Kirchner, R.M. Solid State Ionics, 43, 93-102 (1990) (3) Pluth, J.J. andSmith, J.V. Acta Crystallogr., C42, 1118-1120(1986) (4) Canesson, L., Arcon, I., Caldarelli, S. and Tuel, A. Microporous Mesoporous Mat., 26, 117-131 (1998)
50
APD
Framework Type Data
Cmce
)
!
z
framework viewed along [100]
Idealized cell data:
orthorhombic, Cmce, a - 8.7/k, b - 20. l/k, c - 10.2A
Coordination sequences and vertex symbols: T 1 (16,1)
4
10
21
37
57
82
112
145
184
228
4.4-62.83.63.83
T 2(16,1)
4
11
22
38
59
83
113
147
186
230
4.62.6.62.6-63
Secondary building units:
8 or 6-2 or 4
Composite building units: RSC
narsarsukite chain
Materials with this framework type: • A1PO_D ~ APO_CJ3 ~2~
51
AIPO-D Crystal chemical data"
Type Material Data
APD
[Al16P16064]-APD (forms irreversibly from A1PO-C at around 200°C) orthorhombic, Pca2~, a - 19.187A, b - 8.576A, c - 9.804A ~1~ (Relationship to unit cell of Framework Type: a ' = b, b ' = a, c'= c)
F r a m e w o r k density: Channels:
19.8 T/1000A 3 [010] 8 2.3 x 6.0* ~ [201] 8 1.3 x 5.8*
distorted 8-ring viewed along [010]
distorted 8-ring along [201]
References: (1) Keller, E.B., Meier, W.M. and Kirchner, R.M. Solid State Ionics, 43, 93-102 (1990) (2) Wang, K.X., Yu, J.H., Zhu, G.S., Zou, Y.C. and Xu, R.R. Microporous Mesoporous Mat., 39, 281-289 (2000)
52
AST
m
Framework Type Data
Fm3m
Z
framework viewed along [100] Idealized cell data:
cubic,
Fm-3m, a - 13.6/k
Coordination sequences and vertex symbols" 4
9
19
34
48
66
96
127
151
183
4.6.4-6.4.6
T 2(8,43m) 4
12
18
28
52
78
88
112
162
204
6.6.6.6.6.6
T l (32,3m)
Secondary building units"
4-1
Composite building units: d4r
Materials with this framework type: • A1PO_16 ~ Octadecasil ~2~ [SinGe4o_nO8o]-AST, 0 < n >_ 40 ~3)
53
AIPO-16
Type Material Data
Crystal chemical data:
I(C~H,3N)4 (H20),61 [A12oP2oOj-AST CTH~3N = quinuclidine cubic, F23, a - 13.383,,~ i~)
Framework density"
16.7 T/1000A 3
Channels:
apertures formed by 6-rings only
AST
References: (1) Bennett, J.M. and Kirchner, R.M. Zeolites, 11,502-506 (1991) (2) Caullet, P., Guth, J.L., Hazm, J., Lamblin, J.M. and Gies, H. Eur. J. Solid State Inorg. Chem., 28, 345-361 (1991) (3) Wang, Y.X., Song, J.Q. and Gies, H. Solid State Sci., 5, 1421-1433 (2003)
54
ASV
Framework Type Data •
~,.,~
P41mcc
:..:..:..
PY
x
framework viewed along [001]
Idealized cell data:
tetragonal, P4/mcc, a - 8.7/k, c - 13.9/k
Coordination sequences and vertex symbols: T 1 (16,1)
4
9
19
35
52
72
100
131
163
201
4.6.4.6.4.6
T 2(4,222)
4
12
18
26
52
84
100
118
162
210
6.6.62.62-128.128
Secondary building units:
4-1
Composite building units: d4r
lau
Materials with this framework type" • ASU_7 0)
55
ASU-7
Type Material Data
Crystal chemical data:
I(C2HTN)2 (H20)2[ [Ge2oO4o]-ASV C2HTN = dimethylamine tetragonal, P4/mcc, a - 8.780A, c - 14.470A ~)
Framework density:
17.9 T/1000,~ 3
Channels:
[001] 12 4.1x 4.1"
4.1
i i4.1
12-ring along [001]
References: (1) Li, H. and Yaghi, O.M.J. Am. Chem. Soc., 120, 10569-10570 (1998)
ASV
56
ATN
Framework Type Data
141mmm
-~Y
x
framework viewed along [001]
Idealized cell data:
tetragonal, I 4 / m m m , a - 13. l f~, c - 5.3/k
Coordination sequences and vertex symbols" T~ (16,m)
4
10
21
Secondary building units:
36 8or4
Composite building units: &c
atn
double zigzag chain
Materials with this framework type" • MAPO_39 <~,2~ [Mg-Si-A1-P-O]-ATN ~3) S A P O - 3 9 (4~ ZnAPO_39 (5~
54
78
106
136
173
214
4.6.4.6.6.8
57
MAPO-39
Type Material Data
ATN
IHol [MgoAls_nPsO32]-ATN
Crystal chemical data:
tetragonal, I4/m, a - 13.209,~, c - 5.277,~ (2)
Framework density:
17.4 T/1000.& 3
Channels:
[001] 8 4.0 x 4.0* > .......
•
.\
4.0
..
,
.........4.0 .... '..
8-ring viewed along [OOl]
References: (1) McCusker, L.B., Brunner, G.O. and Ojo, A.F. Acta Crystallogr., A46, C59 (1990) (2) Baur, W.H., Joswig, W., Kassner, D., Bieniok, A., Finger, G. and Kornatowski, J. Z. Kristallogr., 214, 154-159 (1999) (3) Akporiaye, D.E., Andersen, A., Dahl, I.M., Mostad, H.B. and Wendelbo, R. J. Phys. Chem., 99, 1414214148 (1995) (4) Sinha, A.K., Hegde, S.G., Jacob, N.E. and Sivasanker, S. Zeolites, 18, 350-355 (1997) (5) Christensen, A.N., Jensen, T.R., Norby, P. and Hanson, J.C. Chem. Mater., 10, 1688-1693 (1998)
58
ATO
Framework Type Data ..........
R3m
"~"~",..,.....
m Z Z
z
:.
X
framework viewed along [001]
Idealized cell data:
trigonal, R-3m, a - 20.9A, c - 5.1/k
Coordination sequences and vertex symbols: T~ (36,1)
4
11
Secondary building units"
22
37
59
85
114
147
184
230
12 or 6 or 4
Composite building units: lau
Materials with this framework type: *A1PO-31 (1,2) MAPO-31, M - Mn, Ni, Zn ~3) MAPO-31, M - Zn, Mg, Mn, Co, Cr, Cu, C d (4)
SAPO-31 ¢5-7) VAPO-31~8)
4-6~.6.6~.6.63
59
AIPO-31
Type Material Data
Crystal chemical data:
[A118PlsOTz]-ATO trigonal, R3, a - 20.827A, c - 5.003A (~)
Framework density:
19.2 T/1000A 3
Channels:
[001] 12 5.4 x 5.4*
ATO
12-ring viewed along [001 ]
References: (1) Bennett, J.M. and Kirchner, R.M. Zeolites, 12, 338-342 (1992) (2) Baur, W.H., Joswig, W., Kassner, D. and Kornatowski, J. Acta Crystallogr., B50, 290-294 (1994) (3) Umamaheswari, V., Kanna, C., Arabindoo, B., Palanichamy, M. and Murugesan, V. Proc. Indian Acad. Sci. (Chem. Sci.), 112, 439-448 (2000) (4) Finger, G., Kornatowski, J., Jancke, K., Matschat, R. and Baur, W.H. Microporous Mesoporous Mat., 33, 127-136 (1999) (5) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure Appl. Chem., 58, 1351-1358 (1986) (6) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986) (7) Baur, W.H., Joswig, W., Kassner, D. and Kornatowski, J. Acta Crystallogr., B50, 290-294 (1994) (8) Venkatathri, N., Gegde, S.G. and Sivasanker, S. Chem. Commun., 151-152 (1995)
60
ATS
Framework Type Data
Cmcm
z•Y x
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 13.2/k, b - 21.6A, c - 5.3A
Coordination sequences and vertex symbols: T 1 (8,m)
4
10
19
30
46
67
93
124
154
189
4.6.4.6.6.62
T 2(8,m)
4
10
20
32
49
73
97
124
157
193
4.62.4.62.6.122
T 3(8,m)
4
10
19
32
51
72
96
124
155
196
4.62.4.62.6-122
Secondary building units:
12 or 6 or 4
Composite building units" dzc
ats
double zigzag chain
Materials with this framework type: • MAPO_36 ~1~ A1PO_36 ~2) FAPO_36 ~3~
SSZ_55 ~4~ ZnAPO_36 ~5~
61
MAPO-36
Crystal chemical data:
Type Material Data
ATS
IHI [MgAI,,P,2Oj-ATS monoclinic, C2/c a - 13.148A, b - 21.577A, c - 5.164A, ~ - 91.84 °~l~
Framework density:
16.4 T/1000,~ 3
Channels:
[001 ] 12 6.5 x 7.5"
"
7.5j
12-ring viewed along [001]
References: (1) Smith, J.V., Pluth, J.J. and Andries, K.J. Zeolites, 13, 166-169 (1993) (2) Zahedi-Niaki, M.H., Xu, G.Y., Meyer, H., Fyfe, C.A. and Kaliaguine, S. Microporous Mesoporous Mat., 32, 241-250 (1999) (3) Ristic, A., Tusar, N.N., Arcon, I., Logar, N.Z., Thibault-Starzyk, F., Czyzniewska, J. and Kaucic, V. Chem. Mater., 15, 3643-3649 (2003) (4) Wu, M.G., Deem, M.W., Elomari, S.A., Medrud, R.C., Zones, S.I., Maesen, T., Kibby, C., Chen, C.-Y. and Chen, I.Y.J. Phys. Chem. B, 106, 264-270 (2002) (5) Christensen, A.N., Norby, P. and Hanson, J.C. Microporous Mesoporous Mat., 20, 349-354 (1998)
62
ATT
Framework Type Data
Pmma
Z
framework viewed along [010]
Idealized cell data:
orthorhombic, Pmma, a - 10.0/k, b - 7.5/k, c - 9.4A
Coordination sequences and vertex symbols: T 1(8,1)
4
9
18
33
52
73
96
123
158
199
4.4.4.6.8.8
T 2(4,m)
4
10
21
34
48
70
100
130
159
194
4.82.4.82.6.82
Secondary building units:
4-2 or 6
Composite building units: dcc
dsc
double crankshaft chain
double sawtooth chain
Materials with this framework type" *A1PO- 1 2 - T A M U ~1~ A1PO_33 ~2~ A1PO_33 <3~ RMA_3 <4~
abw
gis
63
Crystal chemical data:
ATT
Type Material Data
AIPO-12-TAMU
I(C4H~2N)4(OH)41[Al12P12048]-ATT C4H~2N = tetramethylammonium orthorhombic, P2~2~2, a - 10.332/~,, b - 14.640A,, c - 9.511/~, ~ (Relationship to unit cell of Framework Type: a'= a, b'= 2b, c'= c)
Framework density:
16.7 T/1000A 3
Channels:
[100] 8 4.2 x 4.6* <-->[010] 8 3.8 x 3.8*
.,,.
3.8
8-ring viewed along [100]
-,.
f
~
3.8
j
complex 8-ring viewed along [01 O]
References: (1) Rudolf, P.R., Saldarriaga-Molina, C. and Clearfield, A. J. Phys. Chem., 90, 6122-6125 (1986) (2) Smith, J.V., Pluth, J.J. and Bennett, J.M. private communication (3) Patton, R.L. and Gajek, R.T.U.S. Patent 4,473,663 (1984) (4) Ikeda, T. and Itabashi, K. Chem. Commun., 2753-2755 (2005)
.....
64
ATV
Framework Type Data .........
....
Creme
, ..............•
...
~.,,
....
z
frameworkviewedalong[100] Idealized cell data:
orthorhombic,
Cmme,a -
8.6A, b - 15.3/k, c - 9.7A
Coordination sequences and vertex symbols: T 1 (16,1)
4
11
22
40
64
92
121
157
200
248
4"62"6"63"62"63
T 2(8,m)
4
12
25
42
61
88
122
160
200
246
6.62-6.62.62"62
Secondary building units: Composite building units:
nsc
narScahrffkite
6 or 4-[1,1]
afi l~
Materials with this framework type: *A1PO_25 °~ [ G a - P - O ] - A T V a~
bog ~ D
65
Type Material Data
AIPO-25
ATV
Crystal chemical data:
[Al12P1204s]-ATV orthorhombic, Aemm, a - 9.449A, b - 15.203A, c - 8.408A ~ (Relationship to unit cell of Framework Type: a'= c, b'= b, c'= a)
Framework density:
19.9 T/1000A 3
Channels:
[001] 8 3.0 x 4.9* ~-~.............
4.9
~,
..........
8-ring viewed along [001]
References: (1) (2)
Richardson Jr., J.W., Smith, J.V. and Pluth, J.J.J. Phys. Chem., 94, 3365-3367 (1990) Parise, J.B. Chem. Commun., 606-607 (1985)
66
AWO
Framework Type Data
a.
.................~!¢ .... . . . . . . . . . . . . . . . . . . . . . .
•........
.......
.... ~:i: . ..............
~,.-
,,
Cmce
'................. ~, j .................i..~..iaa~.............." ...:.,.""
~'~
.
Z
framework viewed along [100]
Idealized cell data:
o r t h o r h o m b i c , Cmce, a - 9 . 1 A , b - 15.0/k, c - 1 9 . 2 A
Coordination sequences and vertex symbols: T,(16,1)
4
10
20
35
55
78
103
133
173
217
4.62.4.8~.6.82
T 2(16,1)
4
10
21
'36
53
76
108
142
173
210
4.6.4.82.6.8
Y 3(16,1)
4
9
19
35
54
76
102
134
172
214
4.4.4.6.8.83
Secondary building units:
6 or 4-2 or 4
Composite building units" dcc double crankshaft chain
Materials with this framework type: * A 1 P O - 21 (1,2) [Ga-P-O]-AWO
~3~
67
AIPO-21 Crystal chemical data:
Type Material Data
AWO
IH4 (C2H7N),o.66(C3Hs)5.33 (OH)4I [Al,zP,zO48]-AWO CzHTN = dimethylamine, C3H s = propane monoclinic, P2~/a a - 10.330A, b - 17.524A, c - 8.676A, ~ - 123.37 °~'~ (Relationship to unit cell of Framework Type: a ' = a, b ' = c, c'= b/(2sin~') or, as vectors, a ' = a, b ' = c, c ' = (b - a)/2 )
Stability:
Transforms to A1PO-25 (ATV) upon calcination (2~
Framework density:
18.3 T/1000A 3
Channels:
[100] 8 2.7 x 5.5*
8-ring viewed along [100]
References: (1) Bennett, J.M., Cohen, J.M., Artioli, G., Pluth, J.J. and Smith, J.V. Inorg. Chem., 24, 188-193 (1985) (2) Parise, J.B. and Day, C.S. Acta Crystallogr., C41, 515-520 (1985) (3) Parise, J.B. Chem. Commun., 606-607 (1985)
68
AWW
Framework Type Data
P41nmm
1
i
Z
~x
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
tetragonal, P4/nmm (origin choice 2), a - 13.6A, c - 7.6A
Coordination sequences and vertex symbols" T~ (16,1)
4
10
20
33
50
72
98
128
162
200
4.4.6-6.6.8
T 2(8,2)
4
9
17
30
50
74
97
123
158
198
4-4.4.6.6.6
Secondary building units:
6or4
Composite building units: aww
clo
Materials with this framework type" *A1PO_22 ~ A1PO-CJB 1 (additional phosphate group prese n t).(2)
69
AIPO-22
Type Material Data
AWW
Crystal chemical data:
I(CTH14N)4 (HPO4)2I [A|z4P24096]-AWW C7H~4N = quinuclidinium tetragonal, P4/ncc, a - 13.628A, c - 15.463A (j) (Relationship to unit cell of Framework Type: a'= a, c'= 2c)
Framework density:
16.7 T/1000A 3
Channels:
[001] 8 3.9 x 3.9*
8-ring viewed along [001]
References: (1) Richardson Jr., J.W., Pluth, J.J. and Smith, J.V. Naturwiss., 76, 467-469 (1989) (2) Yah, W.F., Yu, J.H., Xu, R.R., Zhu, G.S, Xiao, F.S., Han, Y., Sugiyama, K. and Terasaki, O. Chem. Mater., 12, 2517-2519 (2000)
70
BCT
Framework Type Data
141mmm
~
pz~l~ y
X
framework viewed along [001]
Idealized cell data:
tetragonal, I 4 / m m m , a - 9.0A, c - 5.3/k
Coordination sequences and vertex symbols:
Tl(8,m.2m ) 4
11
Secondary building units:
24
41
62
90
122
157
200
247
8or4
Composite building units: lau
Q Materials with this framework type: • M g _ B C T T <1~
ICa-lrAI-Si-O]-BCTa) F e ( I I I ) - B C T T ~)
Metavariscite(3~ Svyatoslavite(4) Zn_BCTT (1~
4.6~.6.6.6.6
71
Mg-BCTT
Type Material Data
Crystal chemical data:
IK4.s6l[M g2.28S i5.72016] - B C T tetragonal, I4mm, a - 8.957A, c - 5.281/k ~)
Framework density:
18.9 T/1000.A 3
Channels:
[001] 8 2.4 x 2.4*
BCT
8-ring viewd along [001]
References: (1) Dollase, W.A. and Ross, C.R. Am. Mineral., 78, 627-632 (1993) (2) Takeuchi, Y., Haga, N. and Ito, J. Z. Kristallogr., 137, 380-398 (1973) (3) Kniep, R. and Mootz, D. Acta Crystallogr., B29, 2292-2294 (1973) (4) Chesnokov, B.V., Lotova, E.V., Pavlyuchenko, V.S., Usova, L.V., Bushmakin, A.F. and Nishanbayev, T.P. Zap. Vses. Mineral. Obshch. (Am. Mineral. 76, 299-301 (1991)), 118, 111-114 (1989)
72
*BEA
Framework Type Data
P4122
z
framework viewed along [010]
Idealized cell data:
tetragonal, P4122, a - 12.6/~., c - 26.2A
Coordination sequences and vertex symbols: T 1 (8,1) T 2(8,1) T 3(8,1) T 4(8,1) T 5(8,1) T 6(8,1) T 7(8,1) T 8(4,2) T 9(4,2)
4 4 4 4 4 4 4 4 4
10 10 10 10 11 11 12 12 12
Secondary building units: Composite building units: mor
19 19 21 21 18 18 18 19 17
32 32 32 32 29 29 31 32 30
51 51 49 49 48 48 51 48 54
77 75 76 74 80 77 76 75 77
105 102 109 105 107 106 109 112 106
133 133 137 139 133 134 133 134 134
167 170 170 173 160 160 164 164 160
207 208 207 204 203 204 210 206 212
see Compendium
bea
mtw
Materials with this framework type: , B e t a (1,2~ [ B - S i - O ] - * B E A (3'4~ [ G a - S i - O ] - * B E A (4~ [ T i - S i - O ] - * B E A (5~
Al-rich beta ~6~ CIT_6 ~7~ Tschernichite ~8~ pure silica beta ~9~
4-5-4.123.5.5 4.5.4.126.5.5 4.6.4.123.5.5 4.6.4.126.5.5 4-52.5.5.5.6 4.52.5-5.5.6 5.5.5.6.52"125 5.5.52.127.6"6 5-5.5.5.52.123
73
Beta polymorph A
*BEA
Type Material Data
Crystal chemical data:
INa, I [AlySi57O12s]-*BEA tetragonal, P4122, a - 12.661A, c - 26.406A ~2)
F r a m e w o r k density:
15.1 T/1000ek 3
Channels:
< 100> 12 6.6 x 6.7** +--+ [001 ] 12 5.6 x 5.6*
7.1 ........i.::~ ...:/i..........
.
.
.
5.6
i
... 5.6
.
12-ring viewed along <100>
12-ring viewed along [001 ]
References: (1) Higgins, J.B., LaPierre, R.B., Schlenker, J.L., Rohrman, A.C., Wood, J.D., Kerr, G.T. and Rohrbaugh, W.J. Zeolites, 8, 446-452 (1988) (2) Newsam, J.M., Treacy, M.M.J., Koetsier, W.T. and de Gruyter, C.B. Proc. R. Soc. Lond. A, 420, 375-405 (1988) (3) Marler, B., B6hme, R. and Gies, H. Proc. 9th Int. Zeolite Conf., pp. 425-432 (1993) (4) Reddy, K.S.N., Eapen, M.J., Joshi, P.N., Mirajkar, S.P. and Shiralkar, V.P.J. Incl. Phenom. Mol. Recogn. Chem., 20, 197-210 (1994) (5) Blasco, T., Camblor, M.A., Corma, A., Esteve, P., Martinez, A., Prieto, C. and Valencia, S. Chem. Commun., 2367-2368 (1996) (6) Borade, R.B. and Clearfield, A. Microporous Materials, 5, 289-297 (1996) (7) Takewaki, T., Beck, L.W. and Davis, M.E. Topics in Catalysis, 9, 35-42 (1999) (8) Boggs, R.C., Howard, D.G., Smith, J.V. and Klein, G.L. Am. Mineral., 78, 822-826 (1993) (9) Camblor, M.A., Corma, A. and Valencia, S. Chem. Commun., 2365-2366 (1996)
74
BEC
P4Jmmc
Framework Type Data
if
y
framework viewed along [001] Idealized cell data:
tetragonal, P42/mmc, a - 1 2 . 8 ' , c - 13.0*
Coordination sequences and vertex symbols: Tl(16,1 )
4
9
18
32
50
71
96
129
167
199
4.5.4.6.4-126
T2(8,2 )
4
12
17
30
48
71
98
126
156
198
5.5.52-125.6.6
T3(8,m)
4
11
20
28
41
70
103
127
150
188
4.52.5.6-5.6
Secondary building units:
6-2
Composite building units: d4r
mor
Materials with this framework type: *FOS-5 (Beta polymorph C) (~) ITQ- 14 overgrowth a) ITQ_17 ~3~
mtw
75
(Beta polymorph C)
Type Material Data
BEC
Crystal chemical data:
[(C3HgN)48 (H20)361 [Gez56Os,21-BEC tetragonal, N / a m & a - 25.990A, c - 27.271A (1~ (Relationship to unit cell of Framework Type: a ' = 2a, c'= 2c)
Framework density:
13.9 T/1000A 3
Channels:
[001] 12 6.3 x 7.5* ~
12-ring viewed along [001]
<100> 12 6.0 x 6.9**
12-ring viewed along [100]
References: (1) Conradsson, T., Dadachov, M.S. and Zou, X.D. Microporous Mesoporous Mat., 41, 183-191 (2000) (2) Liu, Z., Ohsuna, T., Terasaki, O., Camblor, M.A., Diaz-Cabafias, M.-J. and Hiraga, K. J. Am. Chem. Soc., 123, 5370-5371 (2001) (3) Corma, A., Navarro, M.T., Rey, F., Rius, j. and Valencia, S. Angew. Chem., Int. Ed., 40,2277-2280(2001)
76
BIK
Framework Type Data
Cmcm
x
framework viewed along [001]
Idealized cell data:
orthorhombic, C m c m , a - 7.5/k, b - 16.2/~, c - 5.3,~
Coordination sequences and vertex symbols: T~(8,m) 4 T 2(4,m2m) 4
12 12
Secondary building units:
23 26
43 42
5-1
Composite building units: bik
Materials with this framework type: • Bikitaite ~1,2~
ICs-I[A1-Si-O]-BIK~3~ Triclinic bikitaite ~4~
71 66
97 102
128 140
179 164
226 216
264 288
5.5.5.5.6.82 52.6~.6.6.6.6
77
Bikitaite
Crystal chemical data:
Type Material Data
ILi: (H O) I
[AlzSi40,zl-BIK triclinic, P1, a - 8.607A, b - 4.954A, c - 7.597A c~ - 89.90 °, 3 - 114.44 °, ~ - 89.99 ° ~2~ (Relationship to unit cell of F r a m e w o r k Type: a ' = b/(2sin3'), b ' = c, c ' = a or, as vectors, a ' = (b - a)/2, b ' = c, c ' = a)
Framework density"
20.3 T/1000A 3
Channels:
[010] 8 2.8 x 3.7*
8-ring viewed along [010]
References: (1) (2) (3) (4)
Kocman, V., Gait, R.I. and Rucklidge, J. Am. Mineral., 59, 71-78 (1974) Stfihl, K., Kvick, A. and Ghose, S. Zeolites, 9, 303-311 (1989) Annehed, H. and F~ilth, L. Z. Kristallogr., 166, 301-306 (1984) Bissert, G. and Liebau, L. N. Jb. Miner. Mh., 241-252 (1986)
BIK
78
BOG
Framework Type Data
/mma
y
U z ii:!' ...................................i~ ..... :~i y
framework viewed along [100] (upper right: projection down [100])
Idealized cell data:
orthorhombic, Imma, a - 20.O/k, b = 2 3 . 6 ' , c - 1 2 . 7 '
Coordination sequences and vertex symbols: T 1 (16,1) T 2(16,1) T 3(16,1) T 4(16,1) T 5(16,1) T 6(16,1)
4 4 4 4 4 4
10 10 11 11 11 11
Secondary building units:
19 20 19 21 20 18
32 32 34 32 31 31
51 48 50 49 53 52
74 74 71 74 76 75
101 104 98 101 97 100
6 or 5-1 or 4
Composite building units" bre
bog
Materials with this framework type: *Boggsite ~) Dehyd. boggsite <2~
cas
129 131 133 128 126 126
158 159 162 162 168 158
199 195 195 200 199 206
4-5.4-6.5.122 4-5.4.62.10-12 4.52-5.6.5-103 4-105.5-63.5"63 4-5"5"6~'5" 10 4.5.5.6-5.62
79
Type Material Data
Boggsite
BOG
Crystal chemical data:
ICa7Na4 (H20)741 [A1,8Si780,92]-BOG orthorhombic, Imma, a - 20.236,~, b - 23.798,~, c - 12.798A ~)
F r a m e w o r k density:
15.6 T/1000/~ 3
Channels:
[100] 12 7.0 x 7.0* ~ [010] 10 5.5 x 5.8*
12-ring viewed along [100]
1O-ring viewed along [01 O]
References: (1) Pluth, J.J. and Smith, J.V. Am. Mineral., 75, 501-507 (1990) (2) Zanardi, S., Cruciani, (3., Alberti, A. and Galli, E. Am. Mineral., 89, 1033-1042 (2004)
80
B PH
P62m
Framework Type Data
"" i ~
~
" ~i+"....~,..i.i.~.~...
'"
..
//i
i!:
........
/
................-y
framework viewed normal to [001] (upper right: projection down [001]) m
Idealized cell data:
hexagonal, P 6 2 m , a -
13.l/k, c - 13.0A
Coordination sequences and vertex symbols: T, (12,1) T 2(12,1) T 3 (4,3)
4 4 4
9 9 9
17 16 18
Secondary building units:
28 25 30
6* 1
Composite building units:
@h
afs
Materials with this f r a m e w o r k type" (12)
*Beryllophosphate-H '
Linde Q(3) STA_5 ~4~ UZM_4 ~5~
42 39 43
60 61 62
84 86 85
113 111 105
140 141 135
169 173 180
4-4.4.82.62.8 4"4-4"6"6.12 4"8"4"8"4"8
81
Beryl Iophosphate-H Crystal chemical data:
Type Material Data
BPH
IK~Na~(H20)201 [Be,4P,4056]oBPH trigonal, P321, a - 12.582A, c - 12.451A (2~
Framework density:
16.4 T/1000A 3
Channels:
[001] 12 6.3 x 6.3* +-+ I [001] 8 2.7 x 3.5**
12-ring viewed along [OO1]
8-ring viewed normal to [001]
References: (1) Harvey, G. Z. Kristallogr., 182, 123-124 (1988) (2) Harvey, G., Baerlocher, Ch. and Wroblewski, T. Z. Kristallogr., 201, 113-123 (1992) (3) Andries, K.J., Bosmans, H.J. and Grobet, P.J. Zeolites, 11, 124-131 (1991) (4) Patinec, V., Wright, P.A., Aitken, R.A., Lightfoot, P., Purdie, S.D.J., Cox, P.A., Kvick, A. and Vaughan, G. Chem. Mater., 11, 2456-2462 (1999)
(5) Blackwell, C.S., Broach, R.W., Gatter, M.G., Holmgren, J.S., Jan, D.-Y., Lewis, G.J., Mezza, B.J., Mezza, T.M., Miller, M.A., Moscoso, J.G., Patton, R.L., Rohde, L.M., Schoonover, M.W., Sinkler, W., Wilson, B.A. and Wilson, S.T. Angew. Chem., Int. Ed., 42, 1737-1740 (2003)
82
BRE
P2 lm
Framework Type Data
i]i
..... .......i
~
-.t~ L Z
y
.............•"
framework viewed along [100]
Idealized cell data:
monoclinic, P211m, a - 6.8/k, b - 17.1,a,, c - 7.6A, fi - 95.8 °~2)
Coordination sequences and vertex symbols: T 1(4,1) T 2(4,1) T 3(4,1)
4 4 4 4
T 4 (4,1)
10 10 11 11
20 20 23 18
Secondary building units"
37 36 37 37
61 61 54 62
83 85 82 85
110 107 119 110
144 147 152 147
192 191 184 195
238 234 233 236
4
Composite building units: bre
Materials with this framework type: •
(12)
*Brewsterite ' B a - d o m i n a n t brewsterite¢3) CIT_4 ¢4)
Dehyd. brewsterite ~5~ Synthetic brewsterite ~6~
4.5-4.6.5.8 4.5-4.8.5-6 4.8.5.8.5.82 4.52.5.6.5.8
83
Type Material Data
Brewsterite
Crystal chemical data:
BRE
I(Ba,Sr)2 (n20)~ol [A14Si~2032]-BRE monoclinic, P21/m a - 6.793A, b - 17.573A,, c - 7.759A,, [3 - 94.54 °~2~
Framework density:
17.3 T/1000A 3
Channels:
[100] 8 2.3 x 5.0* +-+ [001] 8 2.8 x 4.1"
8-ring viewed along [100]
8-ring viewed along [001]
References: (1) Perrotta, A.J. and Smith, J.V. Acta Crystallogr., 17, 857-862 (1964) (2) Schlenker, J.L., Pluth, J.J. and Smith, J.V. Acta Crystallogr., B33, 2907-2910 (1977) (3) Cabella, R., Lucchetti, G., Palenzona, A., Quartieri, S. and Vezzalini, G. Eur. J. Mineral., 5, 353-360 (1993) (4) Khodabandeh, S., Lee, G. and Davis, M.E. Microporous Mesoporous Mat., 11, 87-95 (1997) (5) St~hl, K. and Hanson, J.C. Microporous Mesoporous Mat., 32, 147-158 (1999) (6) Ghobarkar, H. and Schaef, O. German Patent AZ 198 24 184.4-41 (1999)
84
CAN
P6Jmmc
Framework Type Data
)
" "! X
framework viewed along [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/mmc, a - 12.5/k, c - 5.3A
Coordination sequences and vertex symbols: T 1 (12,m)
4
10
20
34
54
78
104
Secondary building units"
12 or 6 or 4
Framework description:
AB sequence of 6-rings
134
168
210
4.6.4.6.6.6
Composite building units: dzc
can
double zigzag chain
Materials with this framework type: *Cancrinite (~'2) [A1-Ge-O]-CAN (3) [ C o - P - O ] - C A N (4) [ G a - G e - O ] - C A N (5) [ G a - S i - O ] - C A N (6) [ Z n - P - O ] - C A N (7)
]Li-Csl[A1-Si-O]-CAN (8) ILi-TII[A]-Si-O]-CAN (8) Basic cancrinite(9'~°) Cancrinite hydrate (~) D a v y n e (~2) ECR_5 (13)
Microsommite (~4) Synthetic cancrlmte Tiptopite (~6) Vishnevite (~7) •
•
(15)
85
Cancrinite
Type Material Data
Crystal chemical data:
INa6Ca (H20)2 CO3l [A16Si6oO24]-CAN hexagonal, P63, a - 12.75A, c - 5.14A (2~
Framework density:
16.6 T/1000A 3
Channels:
[001] 12 5.9 x 5.9*
CAN
12-ring viewed along [001]
References: (1) Pauling, L. Proc. Natl. Acad. Sci., 16, 453-459 (1930) (2) Jarchow, O. Z. Kristallogr., 122, 407-422 (1965) (3) Belokoneva, E.L., Uvarova, T.G. and Dem'yanets, L.N. Soy. Phys. Crystallogr., 31,516-519 (1986) (4) Bieniok, A., Brendel, U., Paulus, E.F. and Amthauer, G. Eur. J. Mineral., 17, 813-818 (2005) (5) Lee, Y., Parise, J.B., Tripathi, A., Kim, S.J. and Vogt, T. Microporous Mesoporous Mat., 39, 445-455 (2000) (6) Newsam, J.M. and Jorgensen, J.D. Zeolites, 7, 569-573 (1987) (7) Yakubovich, O.V., Karimova, O.V. and Mel'nikov, O.K. Crystallogr. Reports, 39, 564-568 (1994) (8) Norby, P., Krogh Andersen, I.G., Krogh Andersen, E., Colella, C. and de'Gennaro, M. Zeolites, 11,248253 (1991) (9) Barrer, R.M. and White, E.A.D.J. Chem. Soc., 1561-1571 (1952) (10) Bresciana Pahor, N., Calligaris, M., Nardin, G. and Randaccio, L. Acta Crystallogr., B38, 893-895 (1982) (11) Wyart, J. and Michel-Levy, M. Compt. Rend., 229, 131- (1949) (12) Hassan, I. and Grundy, H.D. Can. Mineral., 28, 341-349 (1990) (13) Vaughan, D.E.W.E. Patent A-190, 90 (1986) (14) Bonaccorsi, E., Comodi, P. and Merlino, S. Phys. Chem. Mineral., 22, 367-374 (1995) (15) Smolin, Y.I., Shepelev, Y.F., Butikova, I.K. and Kobyakov, I.B. Kristallografiya, 26, 63-66 (1981) (16) Peacor, D.R., Rouse, R.C. and Ahn, J.-H. Am. Mineral., 72, 816-820 (1987) (17) Hassan, I. and Grundy, H.D. Can. Mineral., 22, 333-340 (1984)
86
CAS
Framework Type Data
Cmcm
<
z
Y
framework viewed along [100]
Idealized cell data:
orthorhombic, Cmcm, a - 5.3A, b = 14.l/k, c - 17.2A
Coordination sequences and vertex symbols" T~ (8,m) T 2(8,m)
4 4 4
T 3 (8,m)
12 12 12
Secondary building units:
23 26 23
41 43 43
70 64 72
97 101 95
125 138 128
5-1
Composite building unitscas
bik
Materials with this framework type: *Cesium Aluminosilicate ~1'2~ EU-20b (CAS-NSI structural intermediate) <3~
174 165 177
224 215 225
264 284 259
5.5.5.5-6-82 5"6"5"6"6~-8~ 5.6.5-6.52-6
87
Cesium Aluminosilicate
Type Material Data
CAS
Crystal chemical data:
ICs4l [A14Si20048]-CAS orthorhombic, Ama2, a = 16.776A, b - 13.828/k, c - 5.021A (1) (Relationship to unit cell of Framework Type: a ' = -c, b ' = b, c'= a)
Framework density:
20.6 T/1000A 3
Channels:
[001] 8 2.4 x 4.7*
8-ring viewed along [001]
References: (1) Araki, T. Z. Kristallogr., 152, 207-213 (1980) (2) Hughes, R.W. and Weller, M.T. Microporous Mesoporous Mat., 51, 189-196 (2002) (3) Marler, B., Camblor, M.A. and Gies, H. Microporous Mesoporous Mat., 90, 87-101 (2006)
88
CDO
Framework Type Data
Cmcm
y
framework viewed along [001]
Idealized cell data"
orthorhombic, Cmcm, a - 7.6/k, b - 18.7/k, c - 14.1A
Coordination sequences and vertex symbols: T, (16,1) T 2(8,..m)
4 4 T 3 (8,m..) 4 T 4 (4,m2m) 4
12 12 12 12
Secondary building units:
21 20 28 24
39 35 44 42
5-1
Composite building units:
fer
Materials with this framework type: • CDS_I (~ MCM_65 ~2) UZM_25 ~3~
67 69 64 66
99 105 100 98
129 125 144 130
172 168 178 172
228 231 215 228
275 282 277 278
319 320 347 334
391 381 402 398
5.5.5.52.5.8 5.52.5.52.8.* 5-82.5.82.52.82 5.5.5.5-52.82
89
Type Material Data
CDS-1
CDO
Crystal chemical data:
[Si3~O72]-CDO orthorhombic, Pnma, a - 18.355A, b - 13.779A, c - 7.3674A. ~l~ (Relationship to unit cell of Framework Type: a ' = b, b ' = c, c ' = a)
Framework density:
19.3 T/1000* 3
Channels:
[010] 8 3.1 x 4.7* ~ [001] 8 2.5 x 4.2*
4.7
8-ring viewed along [010]
!
~.
~"
8-ring viewed along [001]
References: (1) Ikeda, T., Akiyama, Y., Oumi, Y., Kawai, A. and Mizukami, F. Angew. Chem., Int. Ed., 43, 4892-4896 (2004) (2) Dorset, D.L. and Kennedy, G.J.J. Phys. Chem. B, 108, 15216-15222 (2004) (3) Broach, R.W. private communication
90
CFI
Framework Type Data
Imma
i Z
framework viewed along [01 O]
Idealized cell data"
orthorhombic, Imma, a - 14.0/k, b - 5.3A, c - 26.0/k
Coordination sequences and vertex symbols: T 1(8,m) 4 10 21 36 56 84 T 2(8,m) T 3(8,m) T 4 (4,mm2) T 5(4,mm2)
4 4 4 4
12 12 12 12
Secondary building units:
23 22 24 20
37 37 36 34
55 57 54 56
83 84 79 81
114 114 114 118 116
143 153 156 153 151
182 195 184 190 186
4.6.4.6.5-6 5.6.5.6.52.6 5.6.5.6.5.62 5.5.5.5.1414.* 5.5.5.5.5.62
231 222 222 234 220
see Compendium
Composite building units" dzc
mtt
double zigzag chain
Materials with this framework type" • CIT_5 ~,2~
cas
ton
91
CIT-5
Type Material Data
CFI
Crystal chemical data:
[Si32064]-CFI orthorhombic, Pmn2~, a - 13.674', b - 5.022A, c - 25.488* (2>
Framework density:
18.3 T/1000A 3
Channels:
[010] 14 7.2 x 7.5*
14-ring viewed along [010]
References: (1) Wagner, P., Yoshikawa, M., Lovallo, M., Tsuji, K., Taspatsis, M. and Davis, M.E. Chem. Commun., 21792180 (1997) (2) Yoshikawa, M., Wagner, P., Lovallo, M., Tsuji, K., Takewaki, T., Chen, C.Y., Beck, L.W., Jones, C., Tsapatsis, M., Zones, S.I. and Davis, M.E.J. Phys. Chem. B, 102, 7139-7147 (1998)
92
CGF
Framework Type Data
C21m
X
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 15.5/k, b - 16.9A, c - 7.3/k, 3= 96.1 °
Coordination sequences and vertex symbols: T 1 (8,1) T 2(8,1) T 3(8,1) T 4(8,1) T 5(4,2)
4 4 4 4 4
11 10 9 9 10
22 19 18 18 18
Secondary building units:
34 33 34 34 32
bog
Materials with this framework type: * Co- Ga- Phosphate- 5 ~1) [ Z n - G a - P - O ] - C G F ~2~
76 79 76 75 80
see Compendium
Composite building units: mei
50 55 55 55 58
111 100 97 98 96
142 129 131 133 124
165 172 177 177 176
199 216 217 216 228
.4.8.63.8.63.8 4.6.4.62.6.6 4.4-4.6-6.62 4.63.4.63.4-8 4-4.62"62" 10" 10
93
Type Material Data
Co-Ga-Phosphate-5 C r y s t a l chemical data:
CGF
I(C6H,4N2):[ [Co4Ga5P9036]-CGF C6HlzN 2 = D A B C O monoclinic, I2/a a - 15.002A, b - 17.688tk, c - 15.751A, ~3- 97.24 (') (Relationship to unit cell of Framework Type: a ' = 2c, b ' = b, c ' = a)
Framework density:
17.4 T/1000A 3
Channels:
{[100] 10 2.5 x 9.2* + 8 2.1 x 6.7*} ~ [001] 8 2.4 x 4.8*
! 9.2
1O-ring viewed along [100]
8-ring viewed along [100]
8-ring viewed along [001]
References: (1) Chippindale, A.M. and Cowley, A.R. Zeolites, 18, 176-181 (1997) (2) Cowley, A.R., Jones, R.H., Teat, S.J. and Chippindale, A.M. Microporous Mesoporous Mat., 51, 51-64
(2002)
94
CGS
Framework Type Data
Prima
Z
framework viewed along [100]
Idealized cell data:
orthorhombic, P n m a , a - 8.4,~, b - 14.1/k, c - 15.9A
Coordination sequences and vertex symbols" T 1 (8,1) T 2(8,1) T 3(8,1) T 4(8,1)
4 4 4 4
9 9 9 9
Secondary building units:
16 18 17 18
26 32 28 32
4
Materials with this framework type: *Co-Ga-Phosphate-6 ~) [Zn-Ga-P-O]-CGS
43 48 45 48
67 66 66 67
91 91 91 91
116 121 119 119
148 150 148 151
188 184 186 185
4.4.4.6.6.8 4.4.4.102.8.86 4.4.4.82.6.10 4.4.4.8.84.10
95
Co-Ga-Phosphate-6 Crystal chemical data:
Type Material Data
CGS
I(CH,4N)4I [Co4Ga,2P16064]-CGS CTH~4N = quinuclidinium monoclinic, P2~/c a - 14.365A, b - 16.305A, c - 8.734A, ~= 90.24 (~) (Relationship to unit cell of Framework Type: a ' = b, b ' = c, ¢'= a)
Framework density:
15.6 T/1000A 3
Channels:
{[001] 10 3.5 x 8.1 +-+ [100] 8 2.5 x 4.6}***
1O-ring viewed along [001]
8-ring viewed along [100]
References: (1) (2) (3) (4)
Cowley, A.R. and Chippindale, A.M. Microporous Mesoporous Mat., 28, 163-172 (1999) Lin, C.-H. and Wang, S.-L. Chem. Mater., 12, 3617-3623 (2000) Hong, S.B., Kim, S.H., Kim, Y.G., Kim, Y.C., Barrett, P.A. and Camblor, M.A.J. Mater. Chem., 9, 22872289 (1999) Lee, Y.J., Kim, S.J., Wu, G. and Parise, J.B. Chem. Mater., 11, 879-880 (1999)
96
CHA
m
Framework Type Data
R3m
z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, R 3 m , a - 13.7A, c - 14.8A
Coordination sequences and vertex symbols: T, (36,1)
4
9
17
29
45
64
85
110
140
Secondary building units:
6-6 or 6 or 4-2 or 4
Framework description"
A A B B C C sequence of 6-rings
Composite building units: d6r
cha
173
4.4-4.8.6.8
Materials with this framework type: • Chabazite (1,2) [ A 1 - A s - O ] - C H A (3) [ C o - A 1 - P - O ] - C H A (4'5) [ M g - A 1 - P - O ] - C H A ~5~ [ S i - O ] - C H A ~6~ [ Z n - A 1 - P - O ] - C H A ~7~ [ Z n - A s - O ] - C H A ~3~ [CoI[Be-P-O]-CHA~8~ ILi-NaI[AI-Si-O]-CHA <9) A1PO_34 <~°)
CoAPO_44 ~ CoAPO_47 ~) DAF_5 (12)
M e A P S O _ 4 7 (11,2°,21)
Dehyd. Na-Chabazite ~3~ GaPO_34 (~4) K-Chabazite, Iran~5~ LZ-218 ~6~ Linde D ~17'~8~ Linde R (19) MeAPO_47 ~11'2°'21~
SAPO_34 ~25~ SAPO_47 ~26~ UiO_21 ~27~ Willhendersonite(28) ZK- 14 (29) ZYT_6 (3°)
m
.-(22)
Ni(deta)~-UT-o Phi(18,23,24) -
97
Chabazite
Crystal chemical data:
Type Material Data
CHA
lea6 (HO)401 [Al12Si24072]-CHA rhombohedral, R - 3 m , a - 9.42A, c~- 94.47 ° ~2~
Framework density:
14.5 T/1000A 3
Channels:
_L [001] 8 3.8 x 3.8*** (variable due to considerable flexibility of framework) see Appendix A for 8-ring viewed normal to [001]
References: (1) Dent, L.S. and Smith, J.V. Nature, 181, 1794-1796 (1958) (2) Smith, J.V., Rinaldi, F. and Dent Glasser, L.S. Acta Crystallogr., 16, 45-53 (1963) (3) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001) (4) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997) (5) Feng, P., Bu, X., Gier, T.E. and Stucky, G.D. Microporous Mesoporous Mat., 23, 221-229 (1998) (6) Dfaz-Cabafias, M.-J., Barrett, P.A. and Camblor, M.A. Chem. Commun., 1881-1882 (1998) (7) Tusar, N.N., Kaucic, V., Geremia, S. and Vlaic, G. Zeolites, 15, 708-713 (1995) (8) Zhang, H.Y., Weng, L.H., Zhou, Y.M., Chen, Z.X., Sun, J.Y. and Zhao, D.Y.J. Mater. Chem., 12, 658-662 (2O02) (9) Smith, L.J., Eckert, H. and Cheetham, A.K.J. Am. Chem. Soc., 122, 1700-1708 (2000) (10) Harding, M.M. and Kariuki, B.M. Acta Cmstallogr., C50, 852-854 (1994) (11) Bennett, J.M. and Marcus, B.K. Stud. Surf Sci. Catal., 37, 269-279 (1988) (12) Sankar, G., Wyles, J.K., Jones, R.H., Thomas, J.M., Catlow, C.R.A., Lewis, D.W., Clegg, W., Coles, S.J. and Teat, S.J. Chem. Commun., 117-118 (1998) (13) Mortier, W.J., Pluth, J.J. and Smith, J.V. Mater. Res. Bull., 12, 241-250 (1977) (14) Schott-Darie, C., Kessler, H., Soulard, M., Gramlich, V. and Benazzi, E. Stud. Surf Sci. Catal., 84, 101108 (1994) (15) Calligaris, M., Nardin, G. and Randaccio, L. Zeolites, 3, 205-208 (1983) (16) Breck, D.W. and Skeels, G.W.U.S. Patent 4,333,859 (1982) (17) Breck, D.W. and Acara, N.A.U.S. Patent 2,950,952 (1960) (18) Lillerud, K.P., Szostak, R. and Long, A. J. Chem. Soc., Faraday Trans., 90, 1547-1551 (1994) (19) Milton, R.M. Brit. Patent 841,812 (1960) (20) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure App1. Chem., 58, 1351-1358 (1986) (21) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986) (22) Garcia, R., Shannon, I.J., Slawin, A.M.Z., Zhou, W., Cox, P.A. and Wright, P.A. Microporous Mesoporous Mat., 58, 91-104 (2003) (23) Grose, R.W. and Flanigen, E.M.U.S. Patent 4,124,686 (1978) (24) Lobo, R.F., Annen, M.J. and Davis, M.E. 21. Chem. Soc., Faraday Trans., 88, 2791-2795 (1992) (25) Lok, B.M., Messina, C.A., Patton, R.L., Gajek, R.T., Cannan, T.R. and Flanigen, E.M.J. Am. Chem. Soc., 106, 6092-6093 (1984) (26) Pluth, J.J. and Smith, J.V.J. Phys. Chem., 93, 6516-6520 (1989) (27) Kongshaug, K.O., Fjellvfig, H. and Lillerud, K.P. Microporous Mesoporous Mat., 39, 341-350 (2000) (28) Tillmanns, E., Fischer, R.X. and Baur, W.H.N. Jb. Miner. Mh., 547-558 (1984) (29) Kuehl, G.H. Molecular Sieves, pp. 85-91 (1968) (30) Ito, M., Shimoyama, Y., Saito, Y., Tsurita, Y. and Otake, M. Acta Crystallogr., C41, 1698-1700 (1985)
98
-CHI
Framework Type Data
Pbcn
~
z
Y
framework viewed along [100]
Idealized cell data:
orthorhombic, Pbcn, a - 5.0/k, b - 31.2A, c - 9.0A
Coordination sequences and vertex symbols: T 1 (8,1) T2(8,1) T 3(8,1) T 4(4,2)
4 4 3 4
11 10 8 6
Secondary building units:
22 20 13 14
40 36 29 28 5-[1,1]
Materials with this framework type: *Chiavennite ~
64 60 53 56
89 86 80 80
120 115 113 114
160 157 147 152
203 196 193 190
248 238 231 236
4.63-6.6.62-62 4.5.6.9-63.102 4.5-9 4.4.5.9-10"10
99
Chiavennite
Type Material Data
-CHI
Crystal chemical data:
ICa4 Mn4(H~O)81[Be8Si20052 (OH)8I-CHI orthorhombic, Pnab, a - 8.729A, b - 3 1 . 3 2 6 ' , c - 4.903A (~ (Relationship to unit cell of Framework Type: a ' - -c, b ' - b, c ' - a)
Framework density:
20.9 T/1000A 3
Channels:
[001] 9 3.9 x 4.3*
9-ring viewed along [001]
References: (1) Tazzoli, V., Domeneghetti, M.C., Mazzi, F. and Cannillo, E. Eur. J. Mineral., 7, 1339-1344 (1995)
100
-CLO
Framework Type Data
•
~ :
" .. s2
Pm3m
...... :~:', °~'~*'~
~
.~:~4i ~ ....................~iiiiiiiii~+
/ z
framework viewed along [001] (upper right: projection down [001])
Idealized cell data"
cubic, P m - 3 m , a - 25.8A
Coordination sequences and vertex symbols: T1(48,1) 4 9 16 23 31 44 T 2 (48,1) T 3 (48,1) T 4 (24,m) T 5 (24,m)
4 4 4 3
9 8 9 5
17 13 16 10
Secondary building units:
27 22 23 18
37 34 32 29
47 44 45 45
59 56 55 58 56
4-4 or 4
Composite building units: d4r
clo
~,!~: ......
Materials with this framework type: *Cloverite ~ [ M n - G a - P - O ] - - C L O ~2~ [ Z n - G a - P - O ] - - C L O ~2~
lta
74 66 72 76 65
91 80 94 98 86
109 99 117 118 110
.4.6.4.6.4.12 4-6.4-6-4-8 4.6.4.6.4.208 4-6.4.6.4.8 4.4.4
101
Cloverite
Crystal chemical data:
Type Material Data
-CLO
I(CvH14N)2418[F24Ga96P960372(OH)2418-CLO CvHl4N - quinuclidinium cubic, Fm-3c, a - 51.712A ~1~ (Relationship to unit cell of Framework Type: a ' - 2a)
Framework density:
11.1 T/1000A 3
Channels"
<100> 20 4.0 x 13.2"** I <100> 8 3.8 x 3.8***
20-ring viewed along <100>
8-ring viewed along <100>
References: (1) Estermann, M., McCusker, L.B., Baerlocher, Ch., Merrouche, A. and Kessler, H. Nature, 352, 320-323 (1991) (2) Yoshino, M., Matsuda, M. and Miyake, M. Solid State Ionics, 151,269-274 (2002)
102
CON
Framework Type Data
"
~
C21m
~r'~....,,:~ ........
x
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 22.7/k, b - 13.4A, c - 12.6/k, 3= 69.5 °
Coordination sequences and vertex symbols: T,(8,1) T 2(8,1)
4 4 4 4 4 4 4
T 3 (8,1) T 4 (8,1)
T 5(8,1) T 6(8,1) T 7(8,1)
10 11 10 10 10 11 11
Secondary building units:
19 18 21 19 19 18 19
32 31 32 32 32 28 32
50 52 47 51 51 49 49
73 77 74 74 74 77 75
101 98 105 100 101 103 105
132 126 134 130 130 126 131
164 164 159 165 164 155 159
199 205 196 203 203 201 196
4.5.4.104.5.62 4.5-5.6.5.102 4.6.4.104.5.62 4"4"5-62"5" 127 4.4.5.62-5.124 4.52.5.62.6.62 4.62.5.6.5.102
1-5-1
Composite building units" bea
bre
lau
mel
Materials with this framework type" *CIT-1(1)
SSZ-26 (related to C O N ) (1'2)
SSZ-33 (related to C O N ) (1'2)
103
CIT-1
Type Material Data
Crystal chemical data:
CON
IH~I[BeSi540,,el-CON monoclinic, C2/m a - 22.624A, b - 13.350A, c - 12.364A,, ~= 68.91 °~1)
F r a m e w o r k density"
16.1 T/1000.~ 3
Channels:
[001] 12 6.4 x 7.0* ~ [ 100] 12 7.0 x 5.9* +--> [010] 10 5.1 x 4.5"
12-ring viewed along [001 ]
12-ring viewed along [100]
1O-ring viewed along [01 O]
References: (1) Lobo, R.F. and Davis, M.E.J. Am. Chem. Soc., 117, 3764-3779 (1995) (2) Lobo, R.F., Pan, M., Chan, I., Li, H.X., Medrud, R.C., Zones, S.I., Crozier, P.A. and Davis, M.E. Science, 262, 1543-1546 (1993)
104
CZP
Framework Type Data
P6122
iI
? °
° °
Z
1
x
L.
Y
framework viewed normal to [001] (upper right: projection down [001]) Idealized cell data"
hexagonal, P6~22, a - 9.4/k, c - 15.3A
Coordination sequences and vertex symbols" T, (12,1) 4 9 18 32 54 83 T 2(6,2) 4 10 20 33 56 85 T 3(6,2) 4 8 16 33 52 73 Secondary building units:
4-[1,1] or 4
Materials with this f r a m e w o r k type: (12) *Chiral Zincophosphate ' I(H3DETA)2 (H20)d [Mn6Ga6P 12O48]-CZP (3) [Na-I[Co-Zn-P-O]-CZP ~4~ [Zn-B-P-O]-CZP ~5~
113 114 112
149 144 160
191 192 190
234 242 214
4-4.4.86-8.8 4"4"83"83"86"86 4"4"4"4"8"8
105
Chiral Zincophosphate Crystal chemical data"
Type Material Data
CZP
INa,~ (H~O),J [Zn,2P,2048]-CZP hexagonal, P6t22, a - 10.480A, c - 15.089A ~2~
Framework density:
16.7 T/1000* 3
Channels:
[001] 12 3.8 x 7.2* (highly distorted 12-ring)
7.2 /
distorted 12-ring viewed along [001 ]
References: (1) Rajic, N., Logar, N.Z. and Kaucic, V. Zeolites, 15, 672-678 (1995) (2) Harrison, W.T.A., Gier, T.E., Stucky, G.D., Broach, R.W. and Bedard, R.A. Chem. Mater., 8, 145-151 (1996) (3) Lin, C.H. and Wang, S.L. Chem. Mater., 14, 96-102 (2002) (4) Helliwell, M., Helliwell, J.R., Kaucic, V., Logar, N.Z., Barba, L., Busetto, E. and Lausi, A. Acta Crystallogr., B55, 327-332 (1999) (5~ Wiebcke, M., Bogershausen and A., Koller, H. Microporous Mesoporous Mat., 78, 97-102 (2005)
106
DAC
Framework Type Data
C21m
x
framework viewed along [001]
Idealized cell data"
monoclinic, C2/m, a - 18.6/~, b - 7.5/k, c - 10.4A, 3 = 108.9 °
Coordination sequences and vertex symbols: 4 4 4 4
T 1(8,1)
T 2(8,1) T 3 (4,m) T 4(4,m)
12 12 11 11
Secondary building units:
22 20 24 24
39 37 41 39
65 63 59 63
91 91 99 95
121 118 130 132
163 164 155 156
5-1
Composite building units" mot"
Materials with this framework type*D achiardite(l'2) Svetlozarite (disordered variant, since discredited) ~3~
208 212 202 199
250 245 262 266
5.5-5.52.8.102 5"5-5-5~-5-8 4-52.5.8.5.8 4-52.5.8.5.8
107
Dachiardite
Crystal chemical data:
Type Material Data
](Cao.~,K,Na) ~ (H~O)J monoclinic, C2/m
[A15Si19048]-DAC
a - 18.676A, b - 7.518A, c - 10.246A, ~3 - 107.87 ° (2~ F r a m e w o r k density:
17.5 T/1000A 3
Channels:
[010] 10 3.4 x 5.3* <--> [001] 8 3.7 x 4.8*
1O-ring viewed along [01 O]
8-ring viewed along [001]
References: (1) (2) (3)
Gottardi, (3. and Meier, W.M.Z. Kristallogr., 119, 53-64 (1963) Vezzalini, G. Z. Kristallogr., 166, 63-71 (1984) Gellens, L.R., Price, G.D. and Smith, J.V. Mineral. Mag., 45, 157-161 (1982)
DAC
108
DDR
Framework Type Data
R3m
Z
framework viewed normal to [001] (upper right: projection down [001]) trigonal, R-3m, a = 13.8/k, c - 40.8/k
Idealized cell data"
Coordination sequences and vertex symbols" T1(36,1 ) T2(18,m ) T3(18,m ) T4(18,m ) T5(18,2 ) T6(6,3m ) T7(6,3m )
4 4 4 4 4 4 4
11 12 12 12 10 12 12
Secondary building units"
23 22 25 24 21 24 24
39 37 40 40 37 39 33
62 59 61 63 62 57 60
91 93 86 87 94 93 97
124 127 119 121 124 121 136
159 158 164 165 158 157 150
203 193 212 208 196 210 192
251 251 253 255 252 240 264
4.5-5-5.5.8 5.5-5.5.5.5 5.5.5.5.5.6 5.5.5.5.5.8 4.4.5.5-6.8 5.5.5.5.5.5 5 . 5 . 5.~- 5 . 5
see Compendium
Composite building units: mtn
.
•
..
.., k
)-
Materials with this framework type: *Deca-dodecasil 3R ~1) [B-Si-O]-DDR ~2~
Sigma_l ~3) ZSM_58 ~4,5~
....
109
Type Material Data
Deca-dodecasil 3R
Crystal chemical data:
](C,oH,TN)6 (N2)91 [Si~2oO24o]-DDR CjoH~TN - 1-aminoadamantane trigonal, R 3 m , a - 13.860A, c - 40.891A, ~1)
Framework density:
17.6 T/1000A 3
Channels:
2_ [001] 8 3.6 x 4.4**
DDR
:..
8-ring viewed normal to [001]
References: (1) Gies, H. Z. Kristallogr., 175, 93-104 (1986) (2) Grfinewald-Luke, A., Marler, B., Hochgrafe, M. and Gies, H. J. Mater. Chem., 9, 2529-2536 (1999) (3) Stewart, A., Johnson, D.W. and Shannon, M.D. Stud. Surf. Sci. Catal., 37, 57-64 (1988) (4) Valyocsik, E.W.U.S. Patent 4,698,217 (1987) (5) Ernst, S., Chen, C.Y., Lindner, D. and Weitkamp, J. Zeolites for the Nineties, Recent Progress Reports Abstracts, pp. 55-56 (1989)
110
DFO
Framework Type Data
P61mmm f
z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P6/mmm, a - 22.0/k, c - 21.2A
Coordination sequences and vertex symbols" T 1(24,1) T 2(24,1) T 3 (24,1) T 4(24,1) T 5(24,1) T 6 (12,m)
4 4 4 4 4 4
9 10 10 9 9 10
Secondary building units:
16 18 18 17 17 18
26 27 28 29 29 28
41 42 45 45 44 45
60 62 65 63 62 66
82 84 84 82 85 89
sti
Materials with this framework type: • DAF_I ~,2~
135 135 134 136 139 141
4-63.4.63.4.12 4.62.4.8.6.62 4.4.6.63.63.10 4.6.4.62.4-8 4.4.4.6.6.62 4.62.4.62.10.12
167 167 173 168 169 171
see Compendium
Composite building units: d4r
107 109 106 106 112 115
bog
/au
111
DAF-1
Type Material Data
DFO
I(C,6H38N2)7(H:O)40l [Mg,4A152P660264]-DFO
Crystal chemical data:
C~6H3sN2 = decamethonium hexagonal, P6/mmm, a - 2 2 . 3 5 1 ' , c - 21.693/~, (1)
Stability:
Transforms to A1PO-5 and A1PO-tridymite on heating to 500°C ~1~
Framework density:
14.1 T/1000A 3
Channels:
{[001] 12 7.3 x 7.3 <-->2_ [001] 8 3.4 x 5.6}*** <-->{[001] 12 6.2 x 6.2 ± [001 ] 10 5.4 x 6.4 }***
7.3
'\\
7.3
.....".,,/
12-ring viewed along [001]
8-ring viewed normal to [001]
2nd 12-ring viewed along [001]
1O-ring viewed normal to [001 ]
References: (1) (2)
Wright, P.A., Jones, R.H., Natarajan, S., Bell, R.G., Chen, J.S., Hursthouse, M.B. and Thomas, J.M. Chem. Commun., 633-635 (1993) Muncaster, G., Sankar, G., Catlow, C.R.A., Thomas, J.M., Bell, R.G., Wright, P.A., Coles, S., Teat, S.J., Clegg, W. and Reeve, W. Chem. Mater., 11, 158-163 (1999)
112
DFT
P4Jmmc
Framework Type Data
> ,> >
~
Y
x
framework viewed along [001]
Idealized cell data"
tetragonal, P42/mmc, a - 7.1A, c - 9.0/k
Coordination sequences and vertex symbols: T, (8,m)
4
10
Secondary building units"
21
36
55
79
106
138
175
215
4
Composite building units: llsc
narsarsukite chain
Materials with this framework type: *DAF_2 °) ACP-3 ([Co-A1-P-O]-DFT) ~2~ U C S B - 3 G a G e ~3~ U C S B - 3 Z n A s ~2~
U i O - 2 0 ( [ M g - P - O ] - D F T ) <4~ [ F e - Z n - P - O ] - D F T ~5) [ Z n - C o - P - O ] - D F T ~6~
4.4.62.83.62-83
113
Type Material Data
DAF-2 Crystal chemical data:
DFT
I(C2H~oN2)2[ [C04P40~6I-DFT CaHloN 2 = ethylenediammonium monoclinic, I2/b a - 14.719A, b - 14.734A, c - 17.891A,, ~ - 90.02 ° ('~ (Relationship to unit cell of Framework Type: a ' = 2a, b ' = 2a, c ' = 2c)
Framework density" Channels:
16.5 T/1000A 3 [001] 84.1 x 4.1" o [100] 8 1.8 x 4.7* <--) [010] 8 1.8 x 4.7*
8-ring viewed along [001]
8-ring viewed along [100]
8-ring viewed along[OlO]
References: (1)
(2) (3) (4) (5) (6)
Chen, J., Jones, R.H., Natarajan, S., Hursthouse, M.B. and Thomas, J.M. Angew. Chem., Int. Ed., 33, 639640 (1994) Bu, X., Feng, P., Gier, T.E. and Stucky, G.D.J. Solid State Chem., 136, 210-215 (1998) Bu, X., Feng, P., Gier, T.E., Zhao, D. and Stucky, G.D.J. Am. Chem. Soc., 120, 13389-13397 (1998) Kongshaug, K.O., Fjellvag, H. and Lillerud, K.P. Chem. Mater., 12, 1095-1099 (2000) Zhao, Y.N., Jin, J. and Kwon, Y.U. Bull. Korean Chem. Soc., 26, 1277-1280 (2005) Ke, Y., He, G., Li, J., Zhang, Y., Lu, S. and Lei, Z. Cryst. Res. Technol., 37, 803-811 (2002)
114
DOH
Framework Type Data
P61mmm
Z
22122
............. ::~:~....
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P6/mmm, a - 14.2/k, c - 11.5/k
Coordination sequences and vertex symbols: T~(12,m) T 2(12,m) T 3(6,mm2) T 4(4,3m)
4 4 4 4
12 11 12 12
Secondary building units:
23 24 25 24
41 41 42 36
mtn
Materials with this framework type: *Dodecasil 1H ~1~
92 91 90 101
see Compendium
Composite building units:
[ B - S i - O ] - D O H ~2~
64 63 68 61
128 128 122 133
167 171 167 156
207 214 210 204
259 259 268 256
5.5-5.5.5.6 4.5.5.6-5.6 5.5.5.5.5.6 5-5.5-5.5.5
115
Dodecasil 1 H
Crystal chemical data:
Type Material Data
DOH
ICsH1,N (N:)~I [Si34068]-DOH CsH~N = piperidine hexagonal, P6/mmm, a - 13.783A,, c - 11.190A (~)
Framework density:
18.5 T/1000A 3
Channels:
apertures formed by 6-rings only
References: (1) (2)
Gerke, H. and Gies, H. Z. Kristallogr., 166, 11-22 (1984) Grtinewald-Luke, A., Marler, B., Hochgrafe, M. and Gies, H. J. Mater. Chem., 9, 2529-2536 (1999)
116
DON
Framework Type Data
Cmcm
X
framework viewed along [001] orthorhombic, Cmcm, a - 18.9A, b - 23.4A, c - 8.5A
Idealized cell data:
Coordination sequences and vertex symbols: T 1 (16,1) T 2(16,1) T 3(16,1) T 4(8,m) T 5(8,m)
4 4 4 4 4
10 10 12 12 12
Secondary building units: Composite building units: clcc
20 20 24 22 23
34 35 38 33 37
aft"
double
Materials with this framework type" * U T D - 1F (1)
77 77 76 80 74
107 106 105 109 107
5-3
crankshaft chain
UTD_I (2~
54 54 55 53 52
mel
140 138 143 143 143
175 177 184 179 183
218 221 223 217 223
4.6.4.62.5.6 4.6.4.62.5.6 5.62.6.62.6.62 5.6.5.6.6.62 5.62.5.62.62-62
117
Type Material Data
UTD-1F
DON
I((Cp*)~Co)~ F, ~(OH)0~l[Si64012sl-DON
Crystal chemical data:
Cp* = pentamethylcyclopentadiene monoclinic, Pc a - 14.970A, b - 8.476A, c - 30.028A, ~ - 102.65 ° (1) (Relationship to unit cell of Framework Type: a ' - a/(2sin~3'), b ' - c, c ' - v/(a2+c 2) or, as vectors, a ' = (a - b)/2, b ' = c, c ' = a + b) Framework density:
17.2 T/1000A 3
Channels:
[010] 14 8.1 x 8.2*
•
8.1
.................i ........................................
~•
14-ring viewed along [01 O]
References: (1) Wessels, T., Baerlocher, C., McCusker, L.B. and Creyghton, E.J.J. Am. Chem. Soc., 121, 6242-6247 (1999) (2) Lobo, R.F., Tsapatsis, M., Freyhardt, C.C., Khodabandeh, S., Wagner, P., Chen, C.Y., Balkus, K.J., Zones, S.I. and Davis, M.E.J. Am. Chem. Soc., 119, 8474-8484 (1997)
118
EAB
P6Jmmc
Framework Type Data
z
framework viewed normal to [001] (upper right: projection down [001 ]) o
Idealized cell data:
o
hexagonal, P63/mmc, a - 13.2A, c - 15.0A
Coordination sequences and v e r t e x s y m b o l s : T~(24,1) T 2(12,2)
4 4
9 10
17 20
30 32
49 46
71 66
92 94
115 128
147 162
Secondary building units:
6or4
Framework description:
A B B A C C sequence of 6-rings
Composite building units: d6r
gme
Materials with this framework type: * T M A - E (Aiello and Barrer) ~'2~ 1 (3) Bellberg'te
190 192
4-4.4.6.6.8 4.4-6-6.8.8
119
TMA-E (Aiello and Barrer)
Type Material Data
Crystal chemical data:
[(C4H~2N)2Na7 (H20)26l [A19Si27072]-EAB C4H~2N - tetramethylammonium hexagonal, P63/mmc, a - 13.28A, c - 15.21A (2~
Framework density"
15.5 T/1000A 3
Channels:
2_ [001] 8 3.7 x 5.1"*
8-ring viewed normal to [001]
References: (1) Aiello, R. and Barrer, R.M.J. Chem. Soc. (A), 1470-1475 (1970) (2) Meier, W.M. and Groner, M. J. Solid State Chem., 37, 204-218 (1981) (3) Rtidinger, B., Tillmanns, E. and Hentschel, G. Miner. Petrol., 48, 147-152 (1993)
EAB
•
120
ED
Framework Type Data
P4m2
Z
framework viewed normal to [001]
Idealized cell data:
tetragonal,
P-4m2,
a -
6.9/k, c - 6.4/k
Coordination sequences and vertex symbols: T 1 (4,m) 4 T 2(1, 4 m 2 ) 4
9 8
Secondary building units"
19 18
35 32
52 52
72 74
100 100
131 128
163 162
201 204
4=1
Composite building units: nat
Materials with this framework type: *Edingtonite(1-3) [Co-A1-P-O]-EDI (4) [Co-Ga-P-O]-EDI (4~ [Zn-As-O]-EDI ~5~ [(C3H12N2)2.sl[Zn5P502o]-EDI(6)
ILi-I[A1-Si-O]-EDI ~7~ IRb7 Na (H20)3I[GasSil2040]-EDI ~8~
K_F(9,10)
Linde F ~l~ Orthorhombic edingtonite(12) Synthetic edingtonite ~13~ Tetragonal edingtonite ~14) Zeolite N ~15~
4"83"4"83"42"84 42"42"84"84"84"84
121
Edingtonite Crystal chemical data:
Type Material Data IBa2 (H20)sl [A14Si6020I-EDI orthorhombic, P2~2~2, a - 9.550A, b - 9.665A, c - 6.523.3, ~2) (Relationship to unit cell of Framework Type: a ' - av/2, b ' - by/2, c' - c or, as vectors, a ' = a + b, b ' = b - a, e ' = e)
F r a m e w o r k density:
16.6 T/1000A 3
Channels:
<110> 8 2.8 x 3.8** ~ [001] 8 2.0 x 3.1" (variable due to considerable flexibility of framework)
References: (1) Taylor, W.H. and Jackson, R. Z. Kristallogr., 86, 53-64 (1933) (2) Galli, E. Acta Crystallogr., B32, 1623-1627 (1976) (3) Kvick, A. and Smith J.V.J. Chem. Phys., 79, 2356-2362 (1983) (4) Bu, X., Gier, T.E., Feng, P. and Stucky, G.D. Chem. Mater., 10, 2546-2551 (1998) (5) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001) (6) Harrison, W.T.A. Acta Crystallogr., E57, m248-m250 (2001) (7) Matsumoto, T., Miyazaki, I. and Goto, Y. J. Eur. Ceramic Soc., 26, 455-458 (2006) (8) Lee, Y.J., Kim, S.J. and Parise, J.B. Microporous Mesoporous Mat., 34, 255-271 (2000) (9) Barrer, R.M. and Baynham, J.W.J. Chem. Soc., 2882-2891 (1956) (10) Baerlocher, Ch. and Barrer, R.M.Z. Kristallogr., 140, 10-26 (1974) (ll) Sherman, J.D. ACS Sym. Set., 40, 30-42 (1977) (12) Gatta, G.D. and Ballaran, T.B. Mineral. Mag., 68, 167-175 (2004) (13) Ghobarkar, H. and Schaef, O. C~st. Res. Technol., 32, 653-657 (1997) (14) Mazzi, F., Galli, E. and Gottardi, G. N. Jb. Miner. Mh., 373-382 (1984) (15) Christensen, A.N. and Fjellvfig, H. Acta Chemica Scand., 51,969-973 (1997)
EDI
122
EMT
P6Jmmc
Framework Type Data
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data"
hexagonal, P63/mmc, a - 17.2A, c - 28.1/k
Coordination sequences and vertex symbols: T 1 (24,1) T 2(24,1) T 3 (24,1) T 4 (24,1)
4 4 4 4
9 9 9 9
Secondary building units: Composite building units: d6r
16 16 16 16
25 25 25 25
37 37 37 37
53 53 53 53
73 73 73 73
96 96 97 96
121 121 124 120
148 148 152 145
178 179 180 174
212 214 210 210
4-4.4.6.6-12 4.4-4.6.6.12 4-4-4-6.6.12 4.4-4.6.6.12
6-6 or 6-2 or 6 or 4-2 or 1-4-1 or 4
sod
Materials with this framework type: • EMC_2 (1,2) CSZ- 1 ( E M T - F A U structural intermediate) (3) E C R - 3 0 ( E M T - F A U structural intermediate) (4)
Z S M - 2 0 ( E M T - F A U structural intermediate) (5~ Z S M - 3 ( E M T - F A U structural intermediate) (6~
123
EMC-2
EMT
Type Material Data
Crystal chemical data"
INa2, (C12H2406)41[Ale,Si750,9el-EMT C12H240
6 =
18-crown-6
hexagonal, P6]mmc, a - 17.374A, c - 28.365A ~2~
Framework density:
12.9 T/1000A ~
Channels:
[001] 12 7.3 x 7.3* +-+ I [001] 12 6.5 x 7.5**
7.3
7.s
...'......./
i
i
...........
•
.~
12-ring viewed along [001]
12-ring viewed normal to [001]
References: (1) Delprato, F., Delmotte, L., Guth, J.L. and Huve, L. Zeolites, 10, 546-552 (1990) (2) Baerlocher, Ch., McCusker, L.B. and Chiappetta, R. Microporous Materials, 2, 269-280 (1994) (3) Barrett, M.G. and Vaughan, D.E.W. UK Patent GB 2,076, 793 A (1981) (4) Vaughan, D.E.W.E. Patent 0,351,461 (1989) (5) Newsam, J.M., Treacy, M.M.J., Vaughan, D.E.W., Strohmaier, K.G. and Mortier, W.J. Chem. Commun., 493-495 (1989) (6) Kokotailo, G.T. and Ciric, J. Adv. Chem. Ser., 101, 109-121 (1971)
124
EON
Framework Type Data
Pmmn
z
y
framework viewed along [100]
Idealized cell data:
orthorhomic, Pmmn (origin choice 2), a - 7.6/k, b - 18.1A, c - 25.9A
Coordination sequences and vertex symbols" T 1 (8,1)
T 2(8,1) T 3(8,1) T 4(8,1) T 5(8,1) T 6(4,m..) T 7(4,m..) T 8(4,m..) T 9(4,m..) T10(4,m..)
4 4 4 4 4 4 4 4 4 4
10 10 10 12 12 10 10 10 11 11
Secondary building units:
20 20 21 21 20 21 21 21 24 24
35 36 37 36 36 36 36 37 38 39
55 56 55 59 62 53 54 55 52 57
80 79 80 85 84 77 76 76 82 87
108 106 111 108 112 109 108 103 124 118
137 140 137 150 151 142 142 149 146 149
5-1
Composite building units" dsc
mor
double sawtooth chain
Materials with this framework type" • ECR_I ~1-3) TNU_7 ~4~
gme
Q
170 177 183 192 193 175 181 191 182 187
214 222 232 231 229 217 226 218 238 235
272 267 274 277 272 266 258 266 283 282
330 317 316 331 340 315 309 326 325 327
4.5.4.5.8-12 4.5.4.5.8.12 4.5.4.5-8.12 5.5.5.52.8.12 5.5.5.52.5.8 4.82.4.82.5.6 4.82.4.82.5.6 4.82.4.82.5.6 4.52.5.82.5.82 4.52.5.8.5.8
125
ECR-1
EON
Type Material Data
Crystal chemical data:
INa~(H20)yl [AlxSi6~xO,20l-EON, x - 3.6 ... 11.4 orthorhombic, Pmmn, a - 7.579/~, b - 18.089/k, c - 25.853/k (4)
Framework density:
16.9 T/1000A 3
Channels:
{[1001 12 6.7 x 6.8* ~ [010] 8 {[001] 3.4 x 4.9 [100] 8 2.9 x 2.9}*}** (Two independent, 2-dimensional channel systems, each consisting of a 12-ring in the [100] direction and a series of 8-rings with effective diffusion in the [010] direction) ,i.
4.9
..... ....
12-ring viewed along [lO0]
..:
:,~
i3.8
:!~
"
.....
8-ring viewed along [001]
References: (1) Leonowicz, M.E. and Vaughan, D.E.W. Nature, 329, 819-821 (1987) (2) Chen, C.S.H., Schlenker, J.L. and Wentzek, S.E. Zeolites, 17, 393-400 (1996) (3) Gualtieri, A.F., Ferrari, S., Galli, E., Di Renzo, F. and van Beek, W. Chem. Mater., 18, 76-84 (2006) (4) Warrender, S.J., Wright, P.A. Zhou, W.Z., Lightfoot, P., Camblor, M.A., Shin, C.H., Kim, D.J. and Hong, S.B. Chem. Mater., 17, 1272-1274 (2005)
126
EPI
<
Framework Type Data
C21m
l ,JI
t y
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 9.1A, b - 17.5A, c - 10.4A, 3 - 124.9°
Coordination sequences and vertex symbols" T 1 (8,1) 4 11 24 42 63 93 T 2(8,1) T 3(8,1)
4 4
12 12
Secondary building units:
22 20
37 39
5-1
Composite building units: roof
Materials with this framework type" (14)
*Epistilbite Synthetic epistilbite (5)
64 66
94 90
127 119 118
160 161 164
206 204 214
262 252 245
4.52.5.8.5-8 5.5-5.52-8.102 5"5"5"5~'5"8
127
Epistilbite Crystal chemical data:
Type Material Data
EPI
ICa~ (n:o),6l [A16SiIsO48]-EPI monoclinic, C2/m a - 9.08,~, b - 17.74A, c - 10.25,~, 3 - 124.54°(2)
Framework density:
17.6 T/1000.A 3
Channels:
{[001] 8 3.7 x 4.5 +-+ [100] 8 3.6 x 3.6}** (The 8-ring along [100] is tilted and has its normal along [101 ].
4.5
4.5
3.7
8-ring viewed along [001]
::
8-ring viewed along [101]
References: (1) Kerr, I.S. Nature, 202, 589 (1964) (2) Perrotta, A.J. Mineral. Mag., 36, 480-490 (1967) (3) Alberti, A., Galli, E. and Vezzalini, G. Z. Kristallogr., 173, 257-265 (1985) (4) Yang, P. and Armbruster, T. Eur. J. Mineral., 8, 263-271 (1996) (5) Ghobarkar, H. C~st. Res. Technol., 151-1573 (1984)
128
ERI
P6 flmmc
Framework Type Data
z
X
Y
framework viewed normal to [001 ] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/mmc, a - 13.1 A, c - 15.2A
Coordination sequences and vertex symbols: T, (24,1)
4
9
17
30
50
75
98
118
144
185
4.4.4.6.6.8
T 2(12,m)
4
10
20
32
46
64
90
126
164
196
4.8.4.8.6.6
Secondary building units:
6or4
Framework description"
AABAAC sequence of 6-rings
Composite building units: d6r
can
Materials with this framework type" • Erionite ~-4~ A1PO- 17 plus compositional variants ~5-7~
Linde T (ERI-OFF structural intermediate) ~8~ LZ_220 ~9)
129
Erionite
Crystal chemical data:
Type Material Data
ERI
I(Ca,Na2)~. ~ K 2 (H~O)2~I [AI~Si~vO~I-ERI hexagonal, P63/mmc, a - 13.27A, c - 15.05A ~3)
Framework density:
15.7 T/1000A 3
Channels:
2_ [001] 8 3.6 x 5.1"**
3.6
i
3.6
8-ring viewed normal to [001]
References: (1) Staples, L.W. and Gard, J.A. Mineral. Mag., 32, 261-281 (1959) (2~ Kawahara, A. and Curien, H. Bull. Soc. fr. Mindral. Cristallogr., 92, 250-256 (1969) (3) Gard, J.A. and Tait, J.M. Proc. 3rd Int. Conf. Molecular Sieves, pp. 94-99 (1973) (4) Schlenker, J.L., Pluth, J.J. and Smith, J.V. Acta Crystallogr. B33, 3265-3268 (1977) (5) Pluth, J.J., Smith, J.V. and Bennett, J.M. Acta C~stallogr., C42, 283-286 (1986) (6) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure Appl. Chem., 58, 1351-1358 (1986) (7) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986) (8) Breck, D.W. Zeolite Molecular Sieves, p. 173 (1974) (9) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
130
ESV
Framework Type Data
Pnma
z
framework viewed along [01 O]
Idealized cell data:
orthorhombic, Pnma, a - 9.7/k, b - 12.2/k, c - 22.8/k
Coordination sequences and vertex symbols: T 1(8,1) T 2(8,1) T 3(8,1) T 4(8,1) T 5(8,1) T 6(8,1)
4 4 4 4 4 4
10 10 10 10 11 11
Secondary building units:
20 20 21 21 22 20
35 36 36 36 36 37
5-1
Materials with this framework type: • ERS_7 o-3~
56 58 57 56 56 54
82 82 82 82 78 82
111 109 111 113 110 112
143 144 145 145 148 142
180 186 183 180 184 182
228 230 231 224 225 226
4.5.4.5.6-8 4-4.5.6-6.8 4-4.5.8-6.6 4.4-5-6.6.8 4.6.5.6.5-6 4.5-5.5.6.6
131
ERS-7
Type Material Data
ESV
Crystal chemical data:
IH~.o6Nao.o~l[A15.13Si42.aTO96]-ESV orthorhombic, Pnma, a - 9.800 ~,, b - 12.412A, c - 22.861A ~2)
Framework density"
17.3 T/1000A 3
Channels:
[010] 8 3.5 x 4.7*
8-ring viewed along [010]
References: (1) Campbell, B.J., Bellussi, G., Carluccio, L., Perego, (3., Cheetham, A.K., Cox, D.E. and Millini, R. Chem. Commun., 1725-1726 (1998) (2) Millini, R., Perego, (3., Carluccio, L., Bellussi, (3., Cox, D.E., Campbell, B.J. and Cheetham, A.K. Proc. 12th Int. Zeolite Conf., I, pp. 541-548 (1999) (3) Campbell, B.J., Cheetham, A.K., Vogt, T., Carluccio, L., Parker, W.O., Flego, C. and Millini, R. J. Phys. Chem. B, 105, 1947-1955 (2001)
132
ETR
,, ......~..
framework
Idealized cell data:
P6amc
Framework Type Data
hexagonal,
P63mc,
a -
4
M a t e r i a l s with this f r a m e w o r k type: • ECR_34 ~
J
viewed along [001]
20.6A, c - 8.4A
C o o r d i n a t i o n sequences a n d vertex symbols: T, (12,1) 4 9 18 31 45 63 T 2(12,1) 4 9 17 28 41 57 T 3(12,1) 4 9 17 28 43 62 T 4(12,1) 4 9 16 25 39 58
Secondary building units:
F%
86 80 83 80
111 113 109 107
140 151 138 143
172 189 170 185
210 226 214 220
253 260 255 254
4.4-4.8.84.103 4.4.4.6-8.86
4"4"4"82"6"104 4-4.4-6-6.8
133
ECR-34
Type Material Data
Crystal chemical data:
IHI.2K6.3Na4.4I [Ga,l.6Alo.3Si36.1096]o-ETR hexagonal, P63mc, a - 21.030 A, c - 8.530 A ('~
F r a m e w o r k density:
14.7 T/1000.,~ ~
Channels:
[001 ] 18 10.1 * +-+ _L [001 ] 8 2.5 x6.0**
...........
18-ring viewed along [001 ]
..............
8-ring viewed normal to [001]
References:
(1) Strohmaier, K. G. and Vaughan, D.E.W.J. Am. Chem. Soc., 125, 16035-16039 (2003)
ETR
134
EUO
Framework Type Data
Creme
\
Z
k-y f r a m e w o r k viewed along [100]
Idealized cell data"
orthorhombic, C m m e , a - 13.9/k, b - 22.9A, c - 20.6A
Coordination sequences and vertex symbols: T~(16,1) T 2(16,1) T 3(16,1) T 4(16,1) T 5(8,m) T 6(8,m) T 7(8,m) T 8(8,m) T 9(8,m) T10(8,m)
4 4 4 4 4 4 4 4 4 4
11 12 12 12 12 12 12 12 11 11
Secondary building units:
21 25 23 22 20 20 24 24 23 24
36 41 38 39 31 34 39 36 45 39
59 64 60 59 61 57 60 56 67 68
92 88 89 91 88 92 91 90 88 92
129 122 124 124 120 131 126 127 115 118
167 160 159 160 159 164 161 157 162 156
197 202 194 206 197 202 195 197 218 213
246 256 248 257 248 236 243 236 261 268
1-5-1
Composite building units: cas
non
Materials with this framework type: * EU- 1<~,2) [ B - S i - O ] - E U O (3'4) TPZ_3 (5~
ZSM_50 (6) o - F D B D M - Z S M - 5 0 (7)
4.6.5.5.52.10 5.6.5.6.5-6 5.52.5.6.5.6 5.5.5.62.5.10 5.5.5.5.5.62 5.52.5.52.122.* 5.6.5.6.5.62 5.5.5.5.124.,* 4-6.5.5.5.5 4.10.5.5.5.5
135
EU-1
Type Material Data
EUO
Crystal chemical data:
INan (H20)261 [AlnSil,2_nO224]-EUO ,on < 19, typically n-~ 3.6 orthorhombic, Cmme, a - 13.695A, b - 22.326A, c - 2 0 . 1 7 8 ' (2)
F r a m e w o r k density:
18.2 T/IOOOA 3
Channels:
[100] 10 4.1 x 5.4* with large side pockets
1O-ring viewed along [100]
References:
(1) Casci, J.L., Lowe, B.M. and Whittam, T.V.U.S. Patent 4,537, 754 (1985) (2) Briscoe, N.A., Johnson, D.W., Shannon, M.D., Kokotailo, G.T. and McCusker, L.B. Zeolites, 8, 74-76 (1988) (3) Grtinewald-Luke, A., Marler, B., Hochgrafe, M. and Gies, H. J. Mater. Chem., 9, 2529-2536 (1999) (4) Millini, R., Carluccio, L.C., Carati, A. and Parker, W.O. Microporous Mesoporous Mat., 46, 191-201 (2001) (5) Sumitani, K., Sakai, T., Yamasaki, Y. and Onodera, T. E. Patent EP 51318 (1982) (6) Rohrbaugh, W.J. private communication (7) Arranz, M., Perez-Pariente, J., Wright, P.A., Slawin, A.M.Z., Blasco, T., Gomez-Hortiguela, L. and Cora, F. Chem. Mater., 17, 4374-4385 (2005)
136
EZT
Framework Type Data
,.
"..........
............ '....
•................ ~ ' , ~ " ..
.d~
Imma
:~. ....... -~! "
~
q~
z
Y
framework viewed along [100]
Idealized cell data"
orthorhombic, Imma, a - 1 0 . 2 ' , b - 12.6A, c - 21.7A
Coordination sequences and vertex symbols: T 1 (16,1)
T 2(8,m..) T 3(8,m..) T 4(8,m..) T 5(8,2..)
4 4 4 4 4
10 10 10 9 9
Secondary building units:
19 19 20 17 18
31 31 32 30 29
bph
Q Materials with this framework type: • EMM_3 °)
72 73 71 73 72
see Compendium
Composite building units: lau
49 51 48 49 48
97 93 98 97 94
124 123 126 120 124
155 157 155 154 156
194 195 192 199 192
236 236 237 237 236
278 274 280 273 278
4.4.6.6.62.8 4.62.4.62.62.1218 4.6.4.6.62.8 4.6.4-6-4.1226 4.4.4.8.62.62
137
EMM-3
Crystal chemical data:
EZT
Type Material Data
[A124P24096]-EZT monoclinic, I2/m a - 10.3132 A, b - 12.6975 * , c - 21.8660 A, oL- 89.656 °(j)
F r a m e w o r k density:
16.8 T/1000A ~
Channels:
[ 100] 12 6.5 x 7.4" :
:.~
.
~
:
12-ring viewed along [100]
References: (1)
Afeworki, M., Dorset, D.L., Kennedy, G.J. and Strohmaier, K.G. Chem. Mater., 18, 1697-1704 (2006)
138
FAR
i
P6Jmmc
Framework Type Data
'i
! z
xJ
............ vL y
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
o
o
hexagonal, P63/mmc, a - 12.6A, c - 35.7A
Coordination sequences and vertex symbolsT 1 (24,1)
T 2(24,1) T 3(24,1) T 4(12,m..)
4 4 4 4
10 10 10 10
20 20 20 20
34 34 34 34
52 53 53 54
74 76 76 78
101 102 102 104
133 132 132 134
169 166 166 168
208 206 205 208
251 251 248 252
Secondary building units:
6
Framework description:
A B C A B A B A C B A C A C sequence of 6-rings
Composite building units: Cat/
lio
sod
~
Materials with this framework type: *Farneseite <~
J
299 299 294 298
.4.4.6.6-6.6 4-4-6.6.6.6 4.6.4.6-6.6 4.6.4.6.6.6
139
Farneseite
FAR
Type Material Data
Crystal chemical data:
[(Na, K)46Ca,o (H20)6 (SO4),21 [Si~2A1420,j-FAR hexagonal, P 6 J m , a - 12.8784A, c - 37.0078A (~
Framework density:
15.8 T/1000,~ 3
Channels:
apertures formed by 6-rings only
References: (1) C~.mara,F., Bellatreccia, F., Della Ventura, G. and Mottana, A. Eur.
J. Mineral.,
17, 839-846 (2005)
140
FAU
m
Framework Type Data
Fd3m ~ !
z
!
iiiii. . . . . . .
i
......
"!,,i
.......:j
..........;:
.-'S+~,///'/"'"
"<"
,.d/<<+e/<'+'>''+ z
framework viewed along [111] (upper right: projection down [110])
Idealized cell data:
cubic, Fd-3m (origin choice 2), a - 24.3/k
Coordination sequences and vertex symbols: T~ (192,1)
4
9
16
Secondary building units: Composite building units: d6r
25
37
53
73
96
120
145
4.4.4.6-6.12
6-6 or 6-2 or 6 or 4-2 or 1-4-1 or 4
sod
Materials with this framework type: ,
(12)
Faujasite ' [A1-Ge-O]-FAU ~3'4) [Co-A1-P-O]-FAU ~5~ [Ga-A1-Si-O]-FAU ~6~ [ G a - G e - O ] - F A U ~3~ [ G a - S i - O ] - F A U ~7~ Beryllophosphate X ~8'9~
D e h y d r a t e d N a - X ~°~ D e h y d r a t e d U S - Y ~ll~ LZ_210 ~12~ Li_LSX °3~ SAPO_37 ~14~ Siliceous Na-Y ~s Zeolite X (Linde X) ~6'~7~
Zeolite Y (Linde y)~18,19) Zincophosphate X (9) E M T - F A U structural intermediates: CSZ- 1 (20) ECR_30 (21) ZSM_20 ~22~
ZSM_3 (23~
141
Faujasite
Type Material Data
Crystal chemical data:
I(Ca,MgNa2)29(H O 4ol [A1585i~340384]-FAU cubic, Fd-3m , a - 24.74A ~2~
Framework density:
12.7 T/1000A 3
Channels:
<1 1 1> 12 7.4 x 7.4***
FAU
12-ring viewed along <111>
References: (1) Bergerhoff, G., Baur, W.H. and Nowacki, W. N. Jb. Miner. Mh., 193-200 (1958) (2) Baur, W.H. Am. Mineral., 49, 697-704 (1964) (3) Barrer, R.M., Baynham, J.W., Bultitude, F.W. and Meier, W.M.J. Chem. Soc., 195-208 (1959) (4) Johnson, G.M., Lee, Y.J., Tripathi, A. and Parise, J.B. Microporous Mesoporous Mat., 31, 195-204 (1999) (5) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997) (6) Occelli, M.L., Schweizer, A.E., Fild, C., Schwering, G., Eckert, H. and Auroux, A. J. Catal., 192, 119-127 (2000) (7) Occelli, M.L., Schwering, G., Fild, C., Eckert, H., Auroux, A. and Iyer, P.S. Microporous Mesoporous Mat., 34, 15-22 (2000) (8) Harrison, W.T.A., Gier, T.E., Moran, K.L., Nicol, J.M., Eckert, H. and Stucky, G.D. Chem. Mater., 3, 2729 (1991) (9) Gier, T.E. and Stucky, G.D. Zeolites, 12, 770-775 (1992) (10) Olson, D.H. Zeolites, 15, 439-443 (1995) (11) Parise, J.B., Corbin, D.R., Abrams, L. and Cox, D.E. Acta Crystallogr., C40, 1493-1497 (1984) (12) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985) (13) Feuerstein, M. and Lobo, R.F. Chem. Mater., 2197-2204 (1998) (14) Lok, B.M., Messina, C.A., Patton, R.L., Gajek, R.T., Cannan, T.R. and Flanigen, E.M.J. Am. Chem. Soc., 106, 6092-6093 (1984) (15) Hriljac, J.J., Eddy, M.M., Cheetham, A.K., Donohue, J.A. and Ray, G.J.J. Solid State Chem., 106, 66-72 (1993) (16) Milton, R.M.U.S. Patent 2,882,244 (1959) (17) Olson, D.H.J. Phys. Chem., 74, 2758-2764 (1970) (18) Breck, D.W.U.S. Patent 3,130,007 (1964) (19) Costenoble, M.L., Mortier, W.J. and Uytterhoeven, J.B.J. Chem. Soc., Faraday Trans. I, 72, 1877-1883 (1976) (20) Barrett, M.G. and Vaughan, D.E.W. UK Patent GB 2,076,793 (1981) (21) Vaughan, D.E.W.E. Patent 0,351,461 (1989) (22) Newsam, J.M., Treacy, M.M.J., Vaughan, D.E.W., Strohmaier, K.G. and Mortier, W.J. Chem. Commun., 493-495 (1989) (23) Kokotailo, G.T. and Ciric, J. Adv. Chem. Set., 101, 109-121 (1971)
142
FER
Framework Type Data
Immm
,,
iif
U
Y
x
framework viewed along [001]
Idealized cell data:
orthorhombic, Immm, a - 19.0J,, b - 14.3Ji, c - 7.5it
Coordination sequences and vertex symbols: T~(16,1) T 2(8,m) T 3(8,m) T 4(4,2mm)
4 4 4 4
12 12 12 12
Secondary building units:
21 27 20 23
39 43 35 40
66 62 67 66
95 97 104 96
126 139 121 131
169 172 157 164
221 206 223 214
5.5.5-52.5.8 5.8.5.8.52.6 5-52.5.52.102.122 5.5.5.5.52.6
265 264 276 272
5-1
Composite building units: yer
Materials with this framework type: *Ferrierite <~) [ B - S i - O ] - F E R ~2) [ G a - S i - O ] - F E R ~3) [ S i - O ] - F E R ~4'5~
FU_9 ~6) ISI_6 °~ Monoclinic ferrierite <8~ NU_23 ~9)
Sr_D ~m~ ZSM_35 ~11)
143
Type Material Data
Ferrierite Crystal chemical data:
FER
[Mg Na (n o),81 [A16Si30072]-FER orthorhombic, Immm, a - 19.156A, b - 14.127A, c - 7.489A (~)
F r a m e w o r k density:
17.8 T / 1 0 0 0 A 3
Channels:
[001] 10 4.2 x 5.4* +-+ [010] 8 3.5 x 4.8*
-...
o
' 3.5
1O-ring viewed along [001 ]
8-ring viewed along [010]
References:
(1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11)
Vaughan, P.A. Acta Crystallogr., 21,983-990 (1966) Perego, G., Bellussi, G., Millini, R., Alberti, A. and Zanardi, S. Microporous Mesoporous Mat., 56, 193202 (2002) Jacob, N.E., Joshi, P.N., Shaikh, A.A. and Shiralkar, V.P. Zeolites, 13, 430-434 (1993) Gies, H. and Gunawardane, R.P. Zeolites, 7, 442-445 (1987) Morris, R.E., Weigel, S.J., Henson, N.J., Bull, L.M., Janicke, M.T., Chmelka, B.F. and Cheetham, A.K.J. Am. Chem. Soc., 116, 11849-11855 (1994) Seddon, D. and Whittam, T.V.E. Patent B-55,529 (1985) Morimoto, N., Takatsu, K. and Sugimoto, M. U.S. Patent 4,578,259 (1986) Gramlich-Meier, R., Gramlich, V. and Meier, W.M. Am. Mineral., 70, 619-623 (1985) Whittam, T.V.E. Patent A-103,981 (1984) Barrer, R.M. and Marshall, D.J.J. Chem. Soc., 2296-2305 (1964) Plank, C.J., Rosinski, E.J. and Rubin, M.K.U.S. Patent 4,016,245 (1977)
144
FRA
m
Framework Type Data
P3ml
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, P - 3 m l , a - 12.7A, c - 25.3A
Coordination sequences and vertex symbols: T 1 (12,1) T 2(12,1) T 3(12,1) T4(12,1) T 5(6,2) T 6(6,2)
4 4 4 4 4 4
10 10 10 10 10 10
20 20 20 20 20 20
34 34 34 34 34 34
52 52 52 53 52 54
74 74 74 76 74 78
100 101 101 102 100 104
130 133 133 132 130 134
165 168 168 166 164 168
205 206 206 206 202 208
Secondary building units:
6or4
Framework description:
A B C A B A C A B C sequence of 6-rings
Composite building units: sod
call
los ................. . ....
Materials with this framework type: • . ,
(12)
*Franzlnlte '
4.4.6.6.6.6 4.4.6.6.6.6 4-6-4.6.6-6 4.4.6.6.6.6 4.4-6.6-6.6 4.4-6.6-6.6
145
Type Material Data
Franzinite
Crystal chemical data:
I(Na,K)3o Calo (H20)2 (S04)~ol [A13oSi3oO,2o]-FRA trigonal, P321, a = 12.916A, c - 26.543A ~)
Framework density:
15.6
Channels:
apertures formed by 6-rings only
T/1000A 3
References: (1) Ballirano, P., Bonaccorsi, E., Maras, A. and Merlino, S. Can. Mineral., 38, 657-668 (2000) (2) Ballirano, P. and Maras, A. Powder Diffraction, 16, 216-219 (2001)
FRA
146
GIS
14lamd
Framework Type Data
z
framework viewed along [100]
Idealized cell data:
tetragonal, I41/amd (origin choice 2), a - 9.8/k, c - 10.2A
Coordination sequences and vertex symbols: T, (16,2)
4
9
18
32
Secondary building units:
8or4
Composite building units: dcc
gis
double crankshaft chain
48
67
92
120
150
185
4.4.4.82.8.8
t
Materials with this framework type: *Gismondine ~ [A1-Co-P-O]-GIS ~2~ [A1-Ge-O]-GIS (3'4) [A1-P-O]-GIS ~5) [Be-P-O]-GIS (6) [Co-A1-P-O]-GIS (7~ [Co-Ga-P-O]-GIS (8~ [Co-P-O]-GIS (9~ [Ga-Si-O]-GIS (1°~ [Mg-A1-P-O]-GIS (7~ [Zn-A1-As-O]-GIS (1~ [Zn-Co-B-P-O]-GIS (~2~
[Zn-Ga-As-O]-GIS (~1~ [Zn-Ga-P-O]-GIS (~3~ [(C3H~2N2)4[[BesP8032]-GIS (~4) I(C3H12N2)4[[Zn8PsO32] -GIS(~5~ [(NH4)4[[Zn4B4P8032]-GIS (16) [Cs41[Zn4B4P8032]-GIS (16) IRb4l[zn4B4p8 O32]-G IS~6' Amicite (~7) (17 19) Garronite ' Gobbinsite ~2°) High-silica Na-P ~2~ Low-silica Na-P (MAP) ~22~
MAPO_43 (23) MAPSO_43 (24,25) Na-P 1(26) Na_P2 (27) SAPO_43 (28) Synthetic Ca-garronite(29) Synthetic amicite(3°~ Synthetic garronite(3°~ Synthetic gobbinsite ~3°~ TMA-gismondine(3~
147
Gismondine
Crystal chemical data"
Type Material Data
GIS
ICa4(H:O),3 [AlsSisO32]-GIS monoclinic, P2,/a a - 9.843A, b - 10.023,~, c - 10.616.A, ~ - 92.417 °¢~) (Relationship to unit cell of Framework Type: a ' = a, b ' = b, c'= c)
Framework density"
15.3 T/1000A 3
Channels:
{[100] 8 3.1 x 4.5 +-+ [010] 8 2.8 x 4.8}*** (variable due to considerable flexibility of framework) see Appendix A for 8-rings viewed along [100] and [010]
References: (1) Fischer, K. and Schramm, V. Adv. Chem. Ser., 101, 250-258 (1971) (2) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997) (3) Johnson, G.M., Tripathi, A. and Parise, J.B. Chem. Mater., 11, 10+ (1999) (4) Tripathi, A., Parise, J.B., Kim, S.J., Lee, Y., Johnson, G.M. and Uh, Y.S. Chem. Mater., 12, 3760-3769 (2000) (5) Paillaud, J.L., Marler, B. and Kessler, H. Chem. Commun., 1293-1294 (1996) (6) Zhang, H., Chen, M., Shi, Z., Bu, X., Zhou, Y., Xu, X. and Zhao, D. Chem. Mater., 13, 2042-2048 (2001) (7) Feng, P., Bu, X., Gier, T.E. and Stucky, G.D. Microporous Mesoporous Mat., 23, 221-229 (1998) (8) Cowley, A.R. and Chippindale, A.M. Chem. Commun., 673-674 (1996) (9) Yuan, H.M., Chen, J.S., Zhu, G.S.,Li, J.Y., Yu, J.H., Yang, G.D. and Xu, R. Inorg. Chem., 39, 1476-1479 (2000) (10) Cho, H.H., Kim, S.H., Kim, Y.G., Kim, Y.C., Koller, H., Camblor, M.A. and Hong, S.B. Chem. Mater., 12, 2292-2300 (2000) (11) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001) (12) Schafer, G., Borrmann, H. and Kniep, R. Microporous Mesoporous Mat., 41, 161-167 (2000) (13) Chippindale, A.M., Cowley, A.R. and Peacock, K.J. Microporous Mesoporous Mat., 24, 133-141 (1998) (14) Harrison, W.T.A. Acta Crystallogr., C57, 891-892 (2001) (15) Harrison, W.T.A. International Journal of Inorganic Materials, 3, 179-182 (2001) (16) Kniep, R., Sch~ifer, G., Engelhardt, H. and Boy, I. Angew. Chem. Int. Ed., 38, 3642-3644 (1999) (17) Alberti, A. and Vezzalini, G. Acta C~stallogr., B35, 2866-2869 (1979) (18) Artioli, G. Am. Mineral., 77, 189-196 (1992) (19) Artioli, G. and Marchi, M. Powder Diffraction, 14, 190-194 (1999) (20) McCusker, L.B., Baerlocher, Ch. and Nawaz, R. Z. Kristallogr., 171, 281-289 (1985) (21) H~tkansson, U., F~ilth, L. and Hansen, S. Acta Crystallogr., C46, 1363-1364 (1990) (22) Albert, B.R., Cheetham, A.K., Stuart, J.A. and Adams, C.J." Microporous Mesoporous Mat., 21, 133-142 (1998) (23) Pluth, J.J., Smith, J.V. and Bennett, J.M.J. Am. Chem. Soc., 111, 1692-1698 (1989) (24) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure Appl. Chem., 58, 1351-1358 (1986) (25) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986) (26) Baerlocher, Ch. and Meier, W.M.Z. Kristallogr., 135, 339-354 (1972) (27) Hansen, S., Hfikansson, U. and F~ilth, L. Acta Crystallogr., C46, 1361-1362 (1990) (28) Helliwell, M., Kaucic, V., Cheetham, G.M.T., Harding, M.M., Kariuki, B.M. and Rizkallah, P.J. Acta Crystallogr., B49, 413-420 (1993) (29) Schropfer, L and Joswig, W. Eur. J. Mineral., 9, 53-65 (1997) (30) Ghobarkar, H. and Schaef, O. Mater. Res. Bull., 34, 517-525 (1999) (31) Baerlocher, Ch. and Meier, W.M. Helv. Chim. Acta, 53, 1285-1293 (1970)
148
GIU
P6Jmmc
Framework Type Data
)
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/mmc, a - 12.6A, c - 4 1 . 0 '
Coordination sequences and vertex symbols" T 1(24,1) T 2(24,1) T 3(24,1) T 4(12,m..) T 5(12,.2.)
4 4 4 4 4
10 10 10 10 10
20 20 20 20 20
34 34 34 34 34
53 53 54 54 52
76 76 78 78 74
102 102 104 104 102
132 132 134 134 136
167 166 168 168 172
209 206 209 208 208
255 251 254 252 248
301 299 300 298 298
Secondary building units"
6or4
Framework description:
A B A B A B A C B A B A B A B C sequence of 6-rings
Composite building units: can
sod
Materials with this framework type: *Giuseppettite ~
4.4.6.6.6.6 4.6.4.6.6.6 4.6.4.6.6.6 4.6.4.6.6.6 4-4.6.6.6-6
149
Giuseppettite Crystal chemical data:
Type Material Data lNa42K,~Ca~ (SO4),0C12) (H~O)sI [Si48A1480~92]-GIU trigonal, P31 c, a 12.856A, c = 42.256A (~) -
Framework density:
15.9 T/1000A 3
Channels:
apertures formed by 6-rings only
References: (1) Bonaccorsi, E. Microporous Mesoporous Mat., 73, 129-136 (2004)
GIU
150
GME
P6Jmmc
Framework Type Data
!
z
L.y framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/mmc, a - 13.7/k, c - 9.9A
Coordination sequences and vertex symbols: T~ (24,1)
4
9
17
29
45
65
89
116
144
175
Secondary building units:
12 or 6-6 or 8 or 6 or 4-2 or 4
Framework description:
A A B B sequence of 6-rings
Composite building units: dcc
d6r
double crankshaft chain
Materials with this framework type: *Gmelinite <1~ [ B e - P - O ] - G M E ~2~ K-rich gmelinite <3~ Synthetic fault-free gmelinite <4~
gme
4.4.4.8.6.8
151
Crystal chemical data:
GME
Type Material Data
Gmelinite
I(Ca,Na~)4 (H:O)~4I[A18Si,6048]-GME hexagonal, P63/mmc, a - 13.75,~, c - 10.05A (~
F r a m e w o r k density"
14.6 T/1000A 3
Channels:
[001] 12 7.0 x 7.0* +-+ A_ [001 ] 8 3.6 x 3.9**
~..
.~
3.9
12-ring viewed along [001]
8-ring viewed normal to [001]
References: (1) Fischer, K. N. Jb. Miner. Mh., 1-13 (1966) (2) Zhang, H., Chen, M., Shi, Z., Bu, X., Zhou, Y., Xu, X. and Zhao, D. Chem. Mater., 13, 2042-2048 (2001) (3) Vezzalini, G., Quartieri, S. and Passaglia, E. N. Jb. Miner. Mh., 504-516 (1990) (4) Daniels, R.H., Kerr, G.T. and Rollmann, L.D.J. Am. Chem. Soc., 100, 3097-3100 (1978)
152
GON
Framework Type Data
Cmmm
..........ZIZ
X
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmmm, a - 16.9A, b - 20.4A, c - 5.3/k
Coordination sequences and vertex symbols: T, (8,m) T 2(8,m)
4 4 4 4
T 3 (8,m)
T 4(8,m)
12 12 11 11
Secondary building units:
21 25 22 22
39 38 38 38
5-3
Composite building units: mtw
cas
Materials with this framework type: • GUS_I °)
63 57 58 63
85 86 86 91
117 119 121 115
154 158 156 147
192 194 191 195
242 233 229 244
5.6.5.6.52.6 5.6.5.6.6.126 4.62.5.6.5.6 4.62.5.6.5.6
153
Type Material Data
GUS-1
GON
Crystal chemical data:
[Si32064]-GON orthorhombic, C222, a - 16.421A, b - 20.054A, c - 5.046A ~
F r a m e w o r k density"
19.3 T/1000A 3
Channels:
[001] 12 5.4 x 6.8*
•
6.8
12-ring viewed along [001]
i
8-ring viewed along [001]
References: (1) P16vert, J., Kubota, Y., Honda, T., Okubo, T. and Sugi, Y. Chem. Commun., 2363-2364 (2000)
154
GOO
Framework Type Data
C222.,
z
x~~--~ y Idealized cell data:
orthorhombic, C2221, a - 8.7/i,, b -
11.O/k, c - 17.5/k
Coordination sequences and vertex symbols" T,(8,1) T 2 (8,1)
T 3(8,1) T 4(4,2) T 5 (4,2)
4 4 4 4 4
9 10 9 10 10
Secondary building units:
19 20 19 20 20
36 36 36 34 34 see
56 55 56 58 52
Compendium
Materials with this framework type: *Goosecreekite(1)
80 77 76 82 78
102 108 106 102 110
132 140 142 136 140
180 174 172 176 176
220 219 217 220 212
4"4"4"85"62"82 4"4"6"83"63"82 4"4"4"82"6-82 4"4"64"84"82"82 4.4.82.106"83"83
155
Goosecreekite
Crystal chemical data"
GO0
Type Material Data
ICa~ (H20)10l [A14Si12032]-GOO monoclinic, P21 a - 7 . 4 0 1 ' , b - 17.439A, c - 7.293A, ~3- 105.44 °~ (Relationship to unit cell of Framework Type: a' = a/(2cos(3'/2)), b' = c, c' = a/(2cos(~'/2)) or, as vectors, a ' = (a + b)/2, b ' = e, e ' = (a - b)/2
F r a m e w o r k density:
17.6 T/1000.~ 3
Channels:
[100] 8 2.8 x 4.0* +-+ [010] 8 2.7 x 4.1" ~ [001] 8 2.9 x 4.7* ....
9.
8-ring viewed along [ 1001
8-ring viewed along [010]
i
8-ring viewed along [001]
References: (1) Rouse, R.C. and Peacor, D.R. Am. Mineral., 71, 1494-1501 (1986)
7
156
HEU
Framework Type Data
C21m
:~,..
•
~
a~
y
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 17.5/k, b - 17.6A, c - 7.4A, 3 - 116.1 o
Coordination sequences and vertex symbols: T, (8,1) T 2(8,1) T 3(8,1) T 4(8,1) T 5(4,2)
4 4 4 4 4
10 11 10 11 12
Secondary building units:
20 23 19 21 18
34 39 37 35 34
62 55 58 61 62
85 82 84 89 88
104 127 109 111 110
148 158 149 146 132
201 178 201 194 196
241 221 236 243 254
4-4=1
Composite building units: bre
Materials with this framework type: *Heulandite ~'2~ Clinoptilolite(3) Dehyd. Ca,NH4-Heulandite ~4)
Heulandite-Ba ~5~ LZ_219 ~6)
4.5.4.5.5.8 4.8.5.8-5.8 4.5.4.8.5.5 4.5.5.5.5.8 5.5.52.52.10.10
157
Type Material Data
Heulandite Crystal chemical data:
HEU
ICa4 (H20)241 [AlaSi28072]-HEU monoclinic, Cm a - 17.718A, b - 17.897A, c - 7.428A, ~3- 116.42 ° (2~
Framework density:
17.1 T/1000A 3
Channels:
{[001] 10 3.1 x 7.5* + 8 3.6 x 4.6*} ~ [100] 8 2.8x 4.7* (variable due to considerable flexibility of framework)
8-ring, also along [001]
lO-ring viewed along [001]
8-ring viewed along [100]
References: (1) Merkle, A.B. and Slaughter, M. Am. Mineral., 52, 273-276 (1967) (2) Alberti, A. Tschermaks Min. Petr. Mitt., 18, 129-146 (1972) (3) Koyama, K. and Takeuchi, Y. Z. Kristallogr., 145, 216-239 (1977) (4) Mortier, W.J. and Pearce, J.R. Am. Mineral., 66, 309-314 (1981) (5) Larsen, A.O., Nordrum, F.S., Dobelin, N., Armbruster, T., Petersen, O.V. and Erambert, M. Eur. J. Mineral., 17, 143-153 (2005) (6) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
158
IFR
Framework Type Data
C21m
i~'~ i iiii~
1
't~~~~~I
X
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 18.6/k, b - 13.4/k, c - 7.6/k, 3 - 102-3°
Coordination sequences and vertex symbols: T, (8,1) T 2(8,1) T 3(8,1)
4 4 4 4
T 4 (8,1)
11 10 10 10
Secondary building units:
20 18 19 21
32 31 32 35
6-2
Composite building units: bea
lau
Materials with this framework type: • ITQ_4 <1,2) M C M _ 5 8 (3) SSZ_42 ~4'5)
53 52 53 50
77 77 78 74
100 103 102 105
135 127 126 133
166 159 162 165
199 210 209 206
4.62. 5.6.6-12 3 4.5.4.6.5-62 4-6.4-6.5.62 4-4"5" 125.6.62
159
ITQ-4
Type Material Data
Crystal chemical data:
IFR
[Si32064]-IFR monoclinic, I2/m a - 18.652A, b - 13.496A, c - 7.631A, 3 - 101.98 ° ~1) (Relationship to unit cell of Framework Type: as vectors, a' = a + e, b ' = b, e ' = -e)
Framework density:
17 T/1000.~ 3
Channels:
[001] 12 6.2 x 7.2*
•
//7.2
12-ring viewed along [001 ]
References: (1) Barrett, P.A., Camblor, M.A., Corma, A., Jones, R.H. and Villaescusa, L.A. Chem. Mater., 9, 1713-1715 (1997) (2) Barrett, P.A., Camblor, M.A., Corma, A., Jones, R.H. and Villaescusa, L.A.J. Phys. Chem. B, 102, 41474155 (1998) (3) Valyocsik, E.W. WOP 9511196 (1995) (4) Chen, C.Y., Finger, L.W., Medrud, R.C., Crozier, P.A., Chan, I.Y., Harris, T.V. and Zones, S.I. Chem. Commun., 1775-1776 (1997) (5) Chen, C.Y., Finger, L.W., Medrud, R.C., Kibby, C.L., Crozier, P.A., Chan, I.Y., Harris, T.V., Beck, L.W. and Zones, S.I. Chem. Eur. Journal, 4, 1312-1323 (1998)
160
IHW
Framework Type Data
........................
.
..,,.
.
Cmce
.........................
X Z
y
f r a m e w o r k viewed along [100]
Idealized cell data:
orthorhombic, C m c e , a - 13.7A, b - 24.1A, c - 18.3A
Coordination sequences and vertex symbols: Tl(16,1 ) T2(16,1) T3(16,1 ) T4(16,1 ) T5(16,1) T6(8,m.. ) T7(8,m.. ) Ts(8,m.. ) T9(8,m.. )
4 4 4 4 4 4 4 4 4
11 12 12 12 12 12 12 12 12
Secondary building units:
24 23 22 24 25 22 24 22 24
41 40 40 41 40 37 38 37 36
69 67 62 65 63 65 62 65 62
95 96 96 94 94 95 97 99 95
122 130 127 129 134 129 137 128 132
see C o m p e n d i u m
Composite building units: cas
non
Materials with this framework type: • ITQ_32 ~)
ton
165 161 166 171 177 170 168 164 169
221 208 213 216 208 212 211 210 204
276 273 258 264 258 259 260 262 251
323 329 320 322 324 310 312 319 326
374 373 381 382 393 397 389 383 399
4.8-5.5.5.5 5.5.5.5.5.8 5.5.5.5.5.6 5.5.5.62.5.8 5.6.52.8.6.62 5.5.5.5.5.62 5.5.5.5.12.* 5.5.5.5.5.62 5.5.5.5.126.*
161
ITQ-32
IHW
Type Material Data
Crystal chemical data"
[Si1120224]-IHW orthorhombic, Cmce, a - 13.6988A, b - 24.0665A, c - 18.1968A ~
F r a m e w o r k density:
18.7 T/1000A 3
Channels:
[100] 8 3.5 x 4.3** (There are 12-ring connections between the channels along [ 100] but there is no continuous 12-ring channel.)
~
,.~ ~
..~:
.::
..~ 3 . 5
.
:,
.~
8-ring viewed along [100]
References: (1) Cantin, A.,Corma, A.,Leiva, S.,Rey, F.,Rius, J. andValencia, S.J. Am. Chem. Soc.,127, 11560-11561 (2005)
162
IMF
Framework Type Data
Cmcm
Y
f r a m e w o r k viewed along [100]
Idealized cell data"
orthorhombic, C m c m , a - 14.3/k, b - 56.8A, c - 20.3A
Coordination sequences and vertex symbols: see Appendix A for a list of the coordination sequences and vertex symbols for the 24 T-atoms
Secondary building units"
5-1
Composite building units: mor
mtt
Materials with this framework type" • IM_5 (~)
ats
stf
feE
163
Type Material Data
IM-5
IMF
Crystal chemical data:
[Si2880576]-IMF orthorhombic, Cmcm, a - 14.2088A, b - 57.2368A, c - 19.9940A ~
Framework density:
17.7 T/1000A 3
Channels:
{[001] 10 5.5 x 5.6 ~ [100] 10 5.3 x 5.4}** +-+ {[010] 10 5.3 x 5.9} {[001] 10 4.8 x 5.4 +--+[100] 10 5.1 x 5.3}** (There is central 2D channel system (above: left) connected through 10-rings along [010] (above: after second ~ ) to another 2D channel system (above: after third +-+) on either side. There is no further connection along [010].)
5.4 . . . . . . . . ."\. . .
1O-ring (center) viewed along [001 ]
1O-ring (center) viewed along [100]
1O-ring viewed along [01 O]
1O-ring (side) viewed along [001]
1O-ring (side) viewed along [100]
References: (1) Baerlocher, Ch., Gramm, F., Masstiger, L., McCusker, L.B., He, Z., Hovm611er, S. and Zou, X. Science, 315, 1113-1116 (2007)
164
ISV
P4Jmmc
Framework Type Data
Z
framework viewed along [100]
Idealized cell data:
tetragonal, P42/mmc, a - 12.9A, c - 25.7A
Coordination sequences and vertex symbols: T, (16,1) T 2(16,1) T 3(16,1) T 4(8,m) T 5(8,m)
4 4 4 4 4
12 9 9 11 11
Secondary building units:
17 18 18 20 20
30 32 32 28 28
48 50 50 42 41
72 71 72 74 70
99 96 97 110 105
6-2
Composite building units" d4r
mo r
Materials with this framework type: *ITQ_7 ~ [ G e - S i - O ] - I S Y 2~
](C 15H29N)4F41[ S i640 128]- I S V (3) [BCHPI[SixAlyGezO128]-ISV ~4)
mtw
128 129 128 132 131
160 167 167 150 154
199 200 203 195 188
5.5.52.125.6-6 4"5"4.6.4" 127 4"5"4"6"4" 124 4.52.5.6.5-6 4.52.5.6.5.6
165
ITQ-7
ISV
Type Material Data
Crystal chemical data:
[Si64O12J-ISV tetragonal, P4Jmmc, a - 12.85 3 A, c - 25.214A (~
Framework density:
15.4 T/1000A 3
Channels:
<100> 12 6.1 x 6.5** ~ [001] 12 5.9 x 6.6* "5
6.5
12-ring viewed along
5.9
"~
i
12-ring viewed along [001]
References: (1) (2) (3) (4)
Villaescusa, L.A., Barrett, P.A. and Camblor, M.A. Angew. Chem., Int. Ed., 38, 1997-2000 (1999) Blasco, T., Corma, A., DiazCabanas, M.J., Rey, F., VidalMoya, J.A. and ZicovichWilson, C.M.J. Phys. Chem. B, 106, 2634-2642 (2002) Song, J.Q., Marler, B. and Gies, H. Compt. Rend. Chimie, 8, 341-352 (2005) Leiva, S., Sabater, M.J., Valencia, S., Sastre, G., Fornes, V., Rey, F. and Corma, A. Compt. Rend. Chimie, 8, 369-378 (2005)
166
ITE
Framework Type Data
Cmcm
~
Y
x
framework viewed along [001]
Idealized cell data"
orthorhombic, C m c m , a - 20.8A, b - 9.8A, c - 20.0A
Coordination sequences and vertex symbols: T~ (16,1) T~(16,1) T 3(16,1) T 4(16,1)
4 4 4 4
11 10 10 10
Secondary building units:
21 21 19 18
34 36 31 31
53 54 50 55
78 77 82 77
108 102 107 105
4
Composite building units: rth
Materials with this framework type: • ITQ_3 <1~ Mu_14 ~2~ SSZ-36 ( I T E - R T H structural intermediate) ~3~
138 135 132 136
168 181 168 166
211 217 209 216
4-6-5.6-5-8 4.4.5.8-5.8 4.5.4.6.5-5 4.5.4.8.5.5
167
ITE
Type Material Data
ITQ-3
Crystal chemical data:
[Si64012s]-ITE orthorhombic, Cmcm, a - 20.622A, b - 9.724A, c - 19.623A ~)
Framework density:
16.3 T/1000A 3
Channels:
[010] 8 3.8 x 4.3* ~ [001] 8 2.7 x 5.8*
2.7,
8-ring viewed along [010]
8-ring viewed along [001]
References: (1) Camblor, M.A., Corma, A., Lighffoot, P., Villaescusa, L.A. and Wright, P.A. Angew. Chem., Int. Ed., 36, 2659-2661 (1997) (2) Valtchev, V., Paillaud, J.L., Lefebvre, T., LeNouen, D. and Kessler, H. Microporous Mesoporous Mat., 38, 177-185 (2000) (3) Wagner, P., Nakagawa, Y., Lee, G.S., Davis, M.E., Elomari, S., Medrud, R.C. and Zones, S.I.J. Am. Chem. Soc., 122, 263-273 (2000)
168
ITH
Framework Type Data
'
....
Atom2
'.......... " - 4
Z
framework viewed along [01 O]
Idealized cell data:
orthorhombic, Amm2, a - 12.6A, b - 11.7A., c - 21.9A
Coordination sequences and vertex symbols: T~(8,1) T2(8,1) T3(8,1) T4(8,1) T5(8,1) T6(4,m..) TT(4,m..) Ts(4,.m.) T9(4,.m.)
4 4 4 4 4 4 4 4 4
9 12 9 12 11 11 11 11 11
Secondary building units:
18 22 19 21 22 22 20 22 20
35 37 37 36 39 32 32 36 34
61 56 60 56 57 51 55 53 57
90 84 86 83 80 87 85 83 81
116 116 117 112 114 116 112 119 117
146 154 151 155 156 139 141 155 155
190 193 189 196 202 183 185 186 192
244 233 238 237 239 241 243 236 234
296 288 296 283 283 296 294 299 297
338 351 349 349 343 343 339 359 357
see Compendium
Composite building units: cl4r
lau
mel
Materials with this framework type: *ITQ- 13 ~1'2)
AI-ITQ-13 (3~
IM_7 (4~
4"62"4"6~-4"10~ 5.6.5.6.6~.92 4.6.4.62.4.102 5"6"5"6~-5"9 4.92-5.5.5-62 4.52.6.6~.6.6 ~ 4"52"62"6~'62"62 4"9~'5"6~'5"6: 4"5"5"6~'5"6~
169
ITH
Type Material Data
ITQ-13 Crystal chemical data:
I((CH3)3N(CH=)6N(CH3)3)=F41 [Si560,,=]-ITIt orthorhombic, Amm2, a - 12.525A, b - 11.391A, c - 22.053A (2~
Framework density:
17.8 T/1000A, 3
Channels:
[001] 10 4.8 x 5.3* ~
[010] 10 4.8 x 5.1" +--+[100] 9 4.0 x 4.8*
:~i ....
4.8
.i:::~ :: i:~~ :-'*'7~::
......,~,.: ..,,~ 4.8
1O-ring viewed along [01 O]
lO-ring viewed along [001]
~
.:.~
~iI.. ": ::.::~..~
.....
4
d
9-ring viewed along [100]
References: (1) Boix, T., Puche, M., Camblor, M.A. and Corma, A. U.S. Patent 6,471,941 B1 (2002) (2) Corma, A., Puche, M., Rey, F., Sankar, G. and Teat, S.J. Angew. Chem., Int. Ed., 42, 1156-1159 (2003) (3) Castaneda, R., Corma, A., Fornes, V., Martinez-Triguero, J. and Valencia, S. J. Catal., 238, 79-87 (2006) (4) Bats, N., Rouleau, L., Paillaud, J.-L., Caullet, P., Mathieu, Y. and Lacombe, S. Stud. Surf Sci. Catal., 154, 283-288 (2004)
170
ITW
Framework Type Data
C21m
i ° iiiiii:!i{ i ...........
Y
Z ~
......-"~X ....
framework viewed along [100]
Idealized cell data:
monoclinic, C2/m, a = 10.4, b = 15.0, c = 9.0, ~ = 105.6
Coordination sequences and vertex symbols: T 1 (8,1)
T 2(8,1) T 3(8,1)
4 4 4
12 9 9
Secondary building units:
23 19 19
36 38 38
87 83 82
1-4-1 or 4-[1,1]
Composite building units: d4r
Materials with this framework type: *ITQ- 12 0'2)
56 61 62
121 110 108
149 149 152
181 194 197
231 234 229
288 274 269
337 329 338
5.5.5.6.8.8 4.5.4.6.4.82 4.5.4.6.4.82
171
ITW
Type Material Data
ITQ-12
Crystal chemical data:
[Si24048]-ITW monoclinic, Cm a - 10.3304', b - 15.010A, c - 8.860A., 3 - 105.34°~1)
Framework density:
18.1 T/1000/~k 3
Channels:
[100] 8 2.4 x 5.4* +-+ [001] 8 3.9 x 4.2* :~::
8-ring viewed along [100]
:,5.
':
8-ring viewed along [001]
References: (1) Barrett, P.A., Boix, T., Puche, M., Olson, D.H., Jordan, E., Koller, H. and Camblor, M.A Chem. Commun., 2114-2115 (2003) (2) Yang, X.B., Camblor, M.A., Lee, Y., Liu, H.M. and Olson, D.H.J. Am. Chem. Soc., 126, 10403-10409 (2004)
172
IWR
Framework Type Data
Cmmm
~
Y
x
framework viewed along [001]
Idealized cell data:
orthorhombic, C m m m , a - 21.2A, b - 13.3A, c - 12.7A
Coordination sequences and vertex symbolsT, (16,1) T 2(16,1) T 3(16,1) T 4(8,..m)
4 4 4 4
9 11 10 11
Secondary building units:
18 18 19 20
32 31 32 27
50 49 49 43
72 72 69 73
98 96 98 99
128 125 132 117
158 159 161 147
192 194 190 198
240 237 233 246
1-5-1
Composite building units: d4r
bre
Materials with this framework type" • ITQ_24 <1~
lau
mel
291 285 289 281
4.6.4.62.4.104 4.62.5.6.5.102 4.4.5.62. 5.127 4-52.6.6~.6.62
173
IWR
Type Material Data
ITQ-24 Crystal chemical data:
[A12.6GeS.1Si48.30224]-IWR orthorhombic, C m m m , a - 21.2549A, b - 13.5210A, c - 12.6095A ~
Framework density:
15.5 T/1000A 3
Channels:
[001] 125.8 x6.8" +-+ Ill0] 104.6 x5.3" ~ [010] 1 0 4 . 6 x 5.3" (The 10-ring shown below (viewed along [010]) limits the channel dimensions of both 10-ring channels.)
5.8
i6.8
.......
~.8
12-ring viewed along [OO1]
i':~
5.3i
lO-ring viewed along [010]
References(1) Castaneda, R., Corma, A., Fornes, V., Rey, F. and Rius, J. J. Am. Chem. Soc., 125, 7820-7821 (2003)
174
[WV
Framework Type Data
Fmmm
ii.............i~.~
y
f r a m e w o r k viewed along [001]
Idealized cell data:
orthorhombic, F m m m , a - 27.8/k, b - 26.1A, c - 13.9,~
Coordination sequences and vertex symbols: T~ (32,1) T 2(32,1) T 3(32,1) T 4 (16,..m) T 5(16,..m) T 6(16,.m.) T 7 (8,2mm)
4 4 4 4 4 4 4
12 9 11 12 12 12 12
Secondary building units:
20 18 21 20 20 22 24
32 32 34 34 28 32 32
50 52 49 50 49 45 40
74 78 72 67 69 69 66
101 105 101 100 100 101 108
135 130 138 141 136 137 136
167 164 177 178 166 167 168
203 213 204 214 201 199 196
254 264 243 232 245 244 240
see C o m p e n d i u m
Composite building units" d4r
cas
Materials with this framework type: • ITQ_27 ~1)
non
ton
307 310 292 278 292 303 298
5.5.5.62.5.12 4.5.4.5.4.12 4.6.5.5.52.12 5.52.5.52.14:.* 5.5.5.5-5.62 5.52.5.6.5.6 5.5.5.5-146.,*
175
ITQ-27
Type Material Data
IWV
Crystal chemical data:
[A15Si 147° 304]-IWV orthorhombic, Fmmm, a - 27.7508A, b - 25.2969A, c - 13.7923A ~l)
Framework density:
15.7 T/1000A 3
Channels:
{ [001] 12 6.2 x 6.9 ~ [011] 12 6.2 x 6.9 }** (The channel dimensions are limited by the same 12-ring in both directions.)
12-ring viewed along [001 ]
References: (1) Dorset, D.L., Kennedy, G.J., Strohmaier, K.G., Diaz-Cabanas, M.J., Rey, F. and Corma, A. J. Am. Chem. Soc., 128, 8862-8867 (2006)
176
IWW
Framework Type Data
Pbam
~
y
X
framework viewed along [001]
Idealized cell data:
orthorhombic, Pbam, a - 41.7/k, b - 12.7,~, c - 12.7A
Coordination sequences and vertex symbols: see A p p e n d i x A for a list of the coordination sequences and vertex symbols for the 16 T - a t o m s
Secondary building units:
1-5-1
Composite building units: d4r
mor
Materials with this framework type: *ITQ_22 ~)
bre
lau
stf
mel
177
IWW
Type Material Data
ITQ-22
Crystal chemical data:
[Gez: 2S isg.sOzz4]-IWW orthorhombic, Pbam, a - 4 2 . 1 3 2 6 ' , b - 12.9885A, c - 12.6814A ~1)
Framework density:
16.1 T/1000A ~
Channels:
[001] 12 6.0 x 6.7* +-+ 2_ [001] 10 4.9 x 4.9** +-+ [001] 8 3.3 x 4.6*
1
!4.9
.....>< ...... ~.~ 4 . 9
12-ring viewed along [001 ]
i
:
, .................. 4.9
lO-ring viewed normal to [001]
8-ring viewed allong [001]
References: (1)
Corma, A., Rey, F., Valencia, S., Jorda, J.L. and Rius, J. Nature Materials, 2, 493-497 (2003)
......
178
JBW
Framework Type Data
Pmma
z
framework viewed along [100]
Idealized cell data"
orthorhombic, Pmma, a - 5.3/k, b - 7.5/k, c - 8.2/k
Coordination sequences and vertex symbols: T 1(4,m) 4 T 2(2,mm2) 4
10 12
Secondary building units"
21 24
39 36
61 56
81 86
107 118
148 146
192 176
228 228
6
Composite building units: &c
jbw
abw
double zigzag chain
Materials with this framework type: *Na-J (Barrer and White )~) [Na 2 Rb H2OI[A13Ge3012]-JBW ~2) INa3 (H20)2l [A13Ge3012I-JBW (3~
Nepheline hydrate ~4~ [Na-I[A1-Si-OI-JBW ~5~
4.6~.4-62.6.82 6.6-6-6.62-62
179
Type Material Data
Na-J (Barrer and White)
JBW
Crystal chemical data:
[Na 3 (H~O),.~l [A13Si30,2I-JBW orthorhombic, Pna2j, a - 16.426A, b - 15.014A, c - 5.224A (1) (Relationship to unit cell of Framework Type: a ' = 2c, b ' = 2b, c ' = a)
Framework density:
18.6 T/1000A 3
Channels:
[001] 8 3.7 x 4.8* ,. . . . . .
...-.
8-ring along [001]
References: (1) Hansen, S. and Faith, L. Zeolites, 2, 162-166 (1982) (2) Healey, A.M., Henry, P.F., Johnson, G.M., Weller, M.T., Webster, M. and Genge, A.J. Microporous Mesoporous Mat., 37, 165-174 (2000) (3) Tripathi, A. and Parise, J.B. Microporous Mesoporous Mat., 52, 65-78 (2002) (4) Rheinhardt, A., Hellner, E. and Ahsbahs, H. Fortsch. Mineral., 60, 175-176 (1982) (5) Ragimov, K.G., Chiragove, M.I., Mustafaev, N.M. and Mamedov, Kh.S. Sov. Phys. Dokl., 23, 697-698 (1978)
180
KFI
m
Framework Type Data
Im3m
! U
y
X
framework viewed along [001] Idealized cell data:
cubic,
Im-3m, a - 18.6A
Coordination sequences and vertex s y m b o l s : T, (96,1)
4
9
Secondary building units:
17
29
45
64
86
112
141
173
6-6 or 6-2 or 8 or 6 or 4-2 or 4
Composite building units"
cl6r
pau
lla
Materials with this framework type: • ZK_5 (~)
(Cs,K)-ZK-5 (2'3) [ Z n - G a - A s - O ] - K F I (4~
l18-crown-61[A1- S i-O ] - K F I (5~
p(6) Q(6)
4.4.4.8.6-8
181
ZK-5
Crystal chemical data:
Type Material Data
INa~o(H20)gs[ [A13oSi~O,92]-KFI cubic, Im3-m, a - 18.75,,~ ~
Framework density"
14.6 T/1000A 3
Channels:
<100> 8 3.9 x 3.9*** I <100> 8 3.9 x 3.9***
3.9 '
i i 3.9
8-ring viewed along < 100>
References: (1) Meier, W.M. and Kokotailo, G.T.Z. Krismllogr., 121, 211-219 (1965) (2) Robson, H.E.U.S. Patent3,720,753 (1973) (3) Parise, J.B., Shannon, R.D., Prince, E. and Cox, D.E.Z. Kristallogr., 165, 175-190 (1983) (4) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Sot., 123, 8608-8609 (2001) (5) Chatelain, T., Patarin, J., Farre, R., Petigny, O. and Schulz, P. Zeolites, 17, 328-333 (1996) (6) Barrer, R.M. and Robinson, D. Z. Kristallogr., 135, 374-390 (1972)
KFI
182
LAU
Framework Type Data
C21m
U
Y
x
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 14.6/k, b - 12.9/k, c - 7.6/k, ~= 111.2 °
Coordination sequences and vertex symbols: T 1(8,1) T 2(8,1)
4 4 4
T 3 (8,1)
10 10 10
Secondary building units:
20 19 19
33 32 33
51 52 53
74 74 74
99 99 96
128 126 127
161 162 166
199 203 201
6 or 1-4-1
Composite building units: bog
lau
Q Materials with this framework type" *Laumontite (1-4) [ C o - G a - P - O ] - L A U (5'6) [ F e - G a - P - O ] - L A U (6) [ M n - G a - P - O ] - L A U ¢6) [Zn-A1-As-O]-LAU ¢7)
[ Z n - G a - P - O I - L A U ~8~ (9 10) Leonhardite ' Na,K-rich laumontite ~1> -1 (12) Primary leonhard'te Synthetic laumontite ¢~3)
4.4.6.62.6.104 4.4.6-62.6-102 4.4.6.63.6.63
183
Laumontite
Crystal chemical data:
Type Material Data
LAU
lea4 (H20),61 [A18Si,6048]-LAU monoclinic, Am, a - 7.549~,, b - 14.740]k, c - 13.072A, ~ - 111.9 °(3~ (Relationship to unit cell of Framework Type: a'=c,b'=a,c'=b,~'
=~3)
Framework density"
17.8 T/1000/~, 3
Channels:
[100] 10 4.0 x 5.3* (contracts upon dehydration)
lO-ring viewed along [100]
References: (1) Bartl, H. and Fischer, K. N. Jb. Miner. Mh., 33-42 (1967) (2) Amirov, S.T., Ilyukhin, V.V. and Belov, N.V. Dokl. Akad. Nauk SSSR, 174, 667- (1967) (3) Schramm, V. and Fischer Adv. Chem. Ser., 101,259-265 (1971) (4) Artioli, G. and St~hl, K. Zeolites, 17, 249-255 (1993) (5) Chippindale, A.M. and Walton, R.I. Chem. Commun., 2453-2454 (1994) (6) Bond, A.D., Chippindale, A., Cowley, A.R., Readman, J.E. and Powell, A.V. Zeolites, 19, 326-333 (1997) (7) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001) (8) Cowley, A.R., Jones, R.H., Teat, S.J. and Chippindale, A.M. Microporous Mesoporous Mat., 51, 51-64 (2002) (9) Lapham, D.L. Am. Mineral., 48, 683-689 (1963) (10) Artioli, G., Smith, J.V. and Kvick, A Zeolites, 9, 377-391 (1989) (11) Stolz, J. and Armbruster, T. N. Jb. Miner. Mh., 131-144 (1997) (12) Baur, W.H., Joswig, W., Fursenko, B.A. AND Belitsky, I.A. Eur. J. Mineral., 9, 1173-1182 (1997) (13) Ghobarkar, H. and Schaef, O. Microporous Mesoporous Mat., 23, 55-60 (1998)
184
LEV
D
Framework Type Data
R3m
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, R-3m, a - 13.2A, c - 22.6/k
Coordination sequences and vertex symbols: T~ (36,1) T~(18,2)
4 4
9 10
17 20
30 32
49 46
71 64
92 90
114 124
143 156
Secondary building units:
6
Framework description:
A A B C C A B B C sequence of 6-rings
183 184
4.4.4-6-6-8 4.4.6.6-8.8
Composite building units: d6r
Materials with this framework type: • L e v y n e ~,2~ A1PO_35 ~3) CoDAF_4 ~4~
LZ_132 ~5~ NU_3 ~6) RUB- 1 ( [ B - S i - O ] - L E V ) ~7~
SAPO_35 ~8~ ZK_20 O) ZnAPO_35 ~°~
185
Levyne Crystal chemical data:
LEV
Type Material Data ICa (H20) ol [A1,sSi36Olosl-LEV trigonal, R - 3 m , a - 13.338A, c - 23.014A ~2)
Framework density:
15.2 T/1000A 3
Channels:
2_ [001] 8 3.6 x 4.8**
3.6
~ 3~6
48
"
8-ring viewed normal to [0011
References: (1) Barrer, R.M. and Kerr, I.S. Trans. Faraday Soc., 55, 1915-1923 (1959) (2) Merlino, S., Galli, E. and Alberti, A. Tschermaks Min. Petr. Mitt., 22, 117-129 (1975) (3) Zhu, G.S., Xiao, F.S., Qiu, S.L., Hun, P.C., Xu, R.R., Ma, S.J. and Terasaki, O." Microporous Materials, 11,269-273 (1997) (4) Barrett, P.A. and Jones, R.H. Phys. Chem. Chem. Phys., 2, 407-412 (2000) (5) Tvaruzkova, Z., Tupa, M., Kiru, P., Nastro, A., Giordano, G. and Trifiro, F. Int. Zeolite Sym., Wurzburg, Extended Abstracts (1988) (6) McCusker, L.B. Mater. Sci. Forum, 133-136, 423-433 (1993) (7) Grtinewald-Luke, A., Marler, B., Hochgrafe, M. and Gies, H. J. Mater. Chem., 9, 2529-2536 (1999) (8) Lok, B.M., Messina, C.A., Patton, R.L., Gajek, R.T., Cannan, T.R. and Flanigen, E.M.J. Am. Chem. Soc., 106, 6092-6093 (1984) (9) Kerr, G.T.U.S. Patent 3,459,676 (1969) (10) Christensen, A.N. and Hazell, R.G. Acta Chemica Stand., 53, 403-409 (1999)
186
LIO
Framework Type Data
P6m2
~i
i Z
x
A
--='~ Y
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
D
o
hexagonal, P 6 m 2 , a -
Coordination sequences and vertex symbols: T 1(12,1) 4 10 20 34 53 76 T 2(12,1) T 3(6,m) T 4(6,m)
4 4' 4
10 10 10
20 20 20
34 34 34
54 52 54
78 74 78
12.3A, c -
103 104 102 104
135 134 136 134
15.6/k
170 168 172 168
Secondary building units:
6or4
Framework description:
A B A B A C sequence of 6-rings
Composite building units" can
los
Materials with this framework type" *Liottite °'2)
lio
209 210 208 210
4.6-4.6.6.6 4.4.6-6.6-6 4.6.4-6.6-6 4.6.4.6.6.6
187
Liottite Crystal chemical data:
Type Material Data
ICas(K,Na)~6(SO.)~Cl.l [Al,sSi~8072]-LIO hexagonal, P 6 , a - 12.870A, c - 16.096A(2~
F r a m e w o r k density:
15.6 T/1000A 3
Channels:
apertures formed by 6-rings only
References: (1) (2)
Merlino, S. and Orlandi, P. Am. Mineral., 62, 321-326 (1977) Ballirano, P., Merlino, S. and Bonaccorsi, E. Can. Mineral., 34, 1021-1030 (1996)
LIO
188
-LIT
Framework Type Data
Pnma
~
t~
X
Z
framework viewed along [01O] Idealized cell data:
orthorhombic,
Pnma, a - 14.8A, b - 8.6A, c - 9.8/k
Coordination sequences and vertex symbols" T,(8,1) T 2(8,1) T 3(8,1)
3 4 4
7 9 10
Secondary building units:
16 19 19
31 34 31
68 72 76
93 100 98
6 or 4-[1,1] or 4-2
Materials w i t h this framework type" • Lithosite ~)
50 50 51
128 128 124
161 160 161
196 197 201
237 239 239
283 287 284
4-6-6 4.8.4.82.6.6 4.6.6.83.8.8
189
Lithosite
Crystal chemical data:
Type Material Data
-LIT
IKl21 [A18Si,6048(OH)4]-LIT monoclinic, P2~ a - 15.197.~, b - 10.233.~, c - 8.435A, f3 - 90.31 °~1) (Relationship to unit cell of Framework Type: a'= a, b'= c, c'= b)
F r a m e w o r k density:
18.3 T/1000A 3
Channels:
References: (1) Pudovkina, Z.V., Solov'eva, L.P. and Pyatenko, Yu.A. Sov. Phys. Dokl., 31,941-942 (1986)
190
LOS
Framework Type Data
P6 ff m m c
z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/mmc, a - 12.6A, c = 10.3/k
Coordination sequences and vertex symbols" T 1 (12,m)
T 2 (12,2)
4 4
10 10
20 20
34 34
52 54
74 78
102 104
136 134
Secondary building units:
6-2 or 6 or 4
Framework description:
A B A C sequence of 6-rings
Composite building units: carl
los
Materials with this framework type: • Losod ~1,2~ [A1-Ge-O]-LOS (3) ILi-I[Be-P-O]-LOS (4) Bystrite (5)
172 168
210 210
4.6.4.6.6.6 4.4.6.6.6.6
191
Losod
Type Material Data
Crystal chemical data:
INa,~ (H20)18l [A1,2Si12048]-LOS hexagonal, P63mc, a - 12.906A, c - 10.541A ~2)
Framework density:
15.8 T/1000A 3
Channels:
apertures formed by 6-rings only
LOS
References: (1) (2) (3) (4) (5)
Sieber, W. and Meier, W.M. Helv. Chim. Acta, 57, 1533-1549 (1974) Schicker, P. Ph.D. Thesis, ETH, Ziirich, Switzerland (1988) Sokolov, Yu.A., Maksimov, B.A., Ilyukhin, V.V. and Belov, N.V. Soy. Phys. Dokl., 23, 789-791 (1978) Harrison, W.T.A., Gier, T.E. and Stucky, G.D. Zeolites, 13, 242-248 (1993) Pobedimskaya, E.A., Terent'eva, L.F., Sapozhnikov, A.N., Kashaev, A.A. and Dorokhova, G.I. Soy. Phys. Dokl., 36, 553-555 ( 1991 )
192
LOV
P4Jmmc
Framework Type Data
Z
framework viewed normal [001 ]
Idealized cell data:
tetragonal, P42/mmc, a - 7.2A, c - 20.9/k
Coordination sequences and vertex symbols: T 1 (8,m)
4 T 2(8,m) 4 T3(2,42m)4
10 9 8
Secondary building units:
21 19 20
37 39 40
VSV
Materials with this framework type" *Lovdarite ~'2) Synthetic lovdarite ~3~
87 79 76
see Compendium
Composite building units" lov
58 55 54
111 113 116
138 149 144
187 177 200
232 229 210
4.4.62-8.62-8 3"4"83"94"83"94 3"3"94"94"94"94
193
LOV
Type Material Data
Lovdarite
Crystal chemical data:
IK4Na,2(HeO),~l [BesSi280721-LOV orthorhombic, P m a 2 , a - 3 9 . 5 7 6 ' , b - 6 . 9 3 1 ' , c - 7.153A ~2~ (Relationship to unit cell of Framework Type: a ' = 2c, b ' = c ' = a)
Framework density:
18.3 T/1000A 3
Channels:
[010] 9 3.2 x 4.5* ~ [001] 9 3.0 x 4.2* ~ [100] 8 3.6 x 3.7* ':~
....
"
: ..
::~
4.2
°0
......................
9-ring viewed along [001]
9-ring viewed along [010]
8-ring viewed along [100]
References: (1) Merlino, S. Acta Crystallogr. (Suppl.), A37, C189 (1981) (2) Merlino, S. Eur. J. Mineral., 2, 809-817 (1990) (3) Ueda, S., Koizumi, M., Baerlocher, Ch., McCusker, L.B. and Meier, W.M. Preprints of Poster Papers, 7th Int. Zeolite Conf., pp. 23-24 (1986)
194
LTA
Framework Type Data
Pm3m
~
y
X
framework viewed along [001] m
Idealized cell data"
cubic, P m 3 m , a - 1 1 . 9 A
Coordination sequences and vertex symbols: T 1 (24,m)
4
9
Secondary building units:
17
28
42
60
81
105
132
162
8 or 4-4 or 6-2 or 6 or 1-4-1 or 4
Composite building units" d4r
sod
lta
Materials with this framework type: *Linde Type A (zeolite A ) <1'2) [A1-Ge-O]-LTA <3) [ G a - P - O ] - L T A (4) Alpha (5) Dehyd. Linde Type A (dehyd. zeolite A) (6) ITQ_29 (7)
LZ_215 (8) N_A (9) SAPO_42 (~°) ZK_21 (1~) ZK_22 (~) ZK_4 (12)
4.6.4.6.4.8
195
Linde Type A
Type Material Data
Crystal chemical data:
INa,~ (H20)27[8 [A1,2Si,2 O4Js-LTA cubic, Fm-3c , a - 24.61,~ ~2) (Relationship to unit cell of Framework Type: a ' = 2a)
Framework density:
12.9 T/1000,~ 3
Channels:
<100> 8 4.1 x 4.1"**
LTA
8-ring viewed along <100>
References: (1) Reed, T.B. and Breck, D.W.J. Am. Chem. Soc., 78, 5972-5977 (1956) (2) Gramlich, V. and Meier, W.M.Z. Kristallogr., 133, 134-149 (1971) (3) Barter, R.M., Baynham, J.W., Bultitude, F.W. and Meier, W.M.J. Chem. Soc., 195-208 (1959) (4) Simmen, A., Patarin, J. and Baerlocher, Ch. Proc. 9th Int. Zeolite Conf., pp. 433-440 (1993) (5) Wadlinger, R.L., Rosinski, E.J. and Plank, C.J.U.S. Patent 3,375,205 (1968) (6) Pluth, J.J. and Smith, J.V.J. Am. Chem. Soc., 102, 4704-4708 (1980) (7) Corma, A., Rey, F., Rius, J., Sabater, M.J. and Valencia, S. Nature, 431,287-290 (2004) (8) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985) (9) Barrer, R.M. and Denny, P.J.J. Chem. Sot., 971-982 (1961) (10) Lok, B.M., Messina, C.A., Patton, R.L., Gajek, R.T., Carman, T.R. and Flanigen, E.M.J. Am. Chem. Soc., 106, 6092-6093 (1984) (11) Kuehl, G.H. lnorg. Chem., 10, 2488-2495 (1971 ) (12) Kerr, G.T. Inorg. Chem., 5, 1537-1539 (1966)
196
LTL
Framework Type Data
P61mmm
t. Z
framework viewed normal to [001] (upper right: projection down [001]) Idealized cell data:
hexagonal,
P6/mmm, a
- 18.1A, c - 7.6A
Coordination sequences and vertex symbols: T, (24,1) T 2(12,m)
4 4
9 10
17 21
Secondary building units:
29 35
46 49
69 66
98 89
131 117
162 150
4.4.4.6-6.8
187 190
4.83.4.83.6.12
6 or 4-2
Composite building units"
dsc doublechainSaWtooth
d6r
can
ltl
.~...........::,~:,.:.~,.-. . . . . . . . . . . . . .,..
~
Materials with this framework type" (K,Ba)-G,L ~ *Linde Type L (zeolite L) ~2~ Gallosilicate L (3'4)
LZ-212 ~5~ (6 7) Perlialite ' [A1-P-O]-LTU 8~
197
Linde Type L
LTL
Type Material Data
Crystal chemical data:
IK6Na3 (H20)2,1 [A19Si27072]-LTL hexagonal, P6/mmm, a - 18.40A, c - 7.52A ~2~
Framework density:
16.3 T/1000fi~ 3
Channels:
[001] 12 7.1 x 7.1"
"
7 . 1 .....................
i
.
"
12-ring viewed along [001]
References: (1) Baerlocher, Ch. and Barter, R.M.Z. Kristallogr., 136, 245-254 (1972) (2) Barrer, R.M. and Villiger, H. Z. Kristallogr., 128, 352-370 (1969) (3) Wright, P.A., Thomas, J.M., Cheetham, A.K. and Nowak, A.K. Nature, 318, 611-614 (1985) (4) Newsam, J.M. Mater. Res. Bull., 21, 661-672 (1986) (5) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985) (6) Menshikov, Y.P. Zap. Vses. Mineral. O-va, 113, 607-612 (1984) (7) Artioli, G. and Kvick, A. Eur. J. Mineral., 2, 749-759 (1990) (8) Venkatathri, N. Indian J Chem Sect A, 41, 2223-2230 (2002)
198
LTN
m
Framework Type Data
Fd3m y
x
i
?
i I
:
i(
:
: i i z
¢.y framework viewed normal to [001] (upper right: projection down [001]) m
Idealized cell data:
o
cubic, F d 3 m (origin choice 2), a - 35.6A
Coordination sequences and vertex symbols: T,(192,1) T 2(192,1) T 3(192,1) T 4(192,1)
4 4 4 4
10 10 10 9
Secondary building units:
20 20 20 17
34 34 33 30
53 51 50 49
76 71 71 72
102 96 97 97
132 126 129 125
166 162 163 158
205 202 200 197
4.4-6.6.6.6 4.6-4.6.6.6 4.4.6.6.6.8 4-4-4-8-6-6
6 or 4-2
Composite building units" d6r
can
Materials with this framework type: *Linde Type N (1) NaZ-21 ~2~
sod
Ita
199
Linde Type N
Crystal chemical data:
LTN
Type Material Data
1Na384(H~O)~,8I[A1384Si3840,,361-LTN cubic,
Fcl-3 , a -
36.93A ~'~
Framework density"
15.2 T/1000A 3
Channels"
apertures formed by 6-rings only
References: (1) F~ilth,L. and Andersson, S. Z. Kristallogr., 160, 313-316 (1982) (2) Shepelev, Yu.F., Smolin, Yu.I., Butikova, I.K. and Tarasov, V.I. Dokl. (1983)
Akad. N a u k S S S R ,
272, 1133-1137
200
MAR
P6Jmmc
Framework Type Data
o
°
Z
z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal,
P63/mmc,
a -
Coordination sequences and vertex symbols: T, (24,1) 4 10 20 34 53 76 T2(24,1) 4 10 20 34 53 76 T3(12,m..) 4 10 20 34 54 78 T 4 (12,.2.) 4 10 20 34 52 74
12.4/k, c - 30.7A
102
132
102 104 102
132 134 136
167 166 168 172
209 205 208 208
Secondary building units:
8or4
Framework description:
ABCBCBACBCBC sequence of 6-rings
Composite building units: can
sod
Materials with this framework type: Marinellite (1)
lio
255 249 252 248
301
297 298 298
4.4-6.6.6.6 4.6.4.6.6.6 4.6.4.6.6.6 4-4.6.6-6.6
201
Marinellite
Type Material Data
Crystal chemical data:
INa3,K,,Ca6 (H20)3.4(SO4)8C121 [A136Si360,44]-MAR trigonal, P31 c, a - 12.880A, c - 31.761A (~
F r a m e w o r k density:
15.8 T/1000A 3
Channels:
apertures formed by 6-rings only
References: (1)
Bonaccorsi, E. and Orlandi, P. Eur. J. Mineral., 15, 1019-1027 (2003)
MAR
202
MAZ
P6Jmmc
Framework Type Data
i
...... i ~ l oo
....... ~
Z
framework viewed normal to [001] (upper right: projection down [001]) Idealized cell data"
hexagonal, P63/mmc , a - 18.l/k, c - 7.6/k
Coordination sequences and vertex symbols: T 1 (24,1)
4
10
20
35
54
78
104
134
171
210
4.5-4.5.8-12
T 2(12,m)
4
10
21
36
53
74
104
138
174
212
4.82.4.82.5.6
Secondary building units: Composite building units: dsc
5-1 or 4-2
gme
double sawtooth
chain
Materials with this framework type: • Mazzite
(1,2)
[ G a - S i - O ] - M A Z ~3~
Mazzite-Na, Boron, CA ~5~ Omega (6,7)
LZ_202 (4~
ZSM_4 (8~
203
Mazzite
Type Material Data
Crystal chemical data:
[(Na2,K2,Ca,Mg)5 (H20)281 [Al10Siz6Ovz]-MAZ hexagonal, P6Jmmc, a - 18.392A, c - 7.646A (2~
Framework density:
16.1 T/1000A 3
Channels:
[001] 12 7.4 x 7.4" I [001 ] 8 3.1 x 3.1"**
MAZ
"2
7.4
""',.. ,"(
:
12-ring viewed along [001]
limiting 8-ring along [001]
References: Galli, E. Cryst. Struct. Comm., 3, 339-344 (1974) Galli, E. Rend. Soc. Ital. Mineral. Petrol., 31,599-612 (|975) Newsam, J.M., Jarman, R.H. and Jacobson, A.J. Mater. Res. Bull., 20, 125-136 (1985) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985) Arletti, R., Galli, E., Vezzalini, G. and Wise, W.S. Am. Mineral., 90, 1186-1191 (2005) Galli, E. Cryst. Struct. Comm., 3, 339-344 (1974) Martucci, A., Alberti, A., Guzman-Castillo, M.D., Di Renzo, F. and Fajula, F. Microporous Mesoporous Mat., 63, 33-42 (2003) (8) Rubin, M.K., Plank, C.J. and Rosinski, E.J.U.S. Patent 4,021,447 (1977) (1) (2) (3) (4) (5) (6) (7)
204
M El
Framework Type Data
~
P6alm
framework viewed normal to [001 ] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/m, a - 13.1A, c - 15.6A
Coordination sequences and vertex symbols: 4 4 4 4
T 1(12,1)
T 2 (12,1) T 3 (6,m) T 4 (4,3)
9 10 10 9
Secondary building units:
18 17 16 18
30 30 26 30
63 67 66 67
see Compendium
Composite building units: mei
Materials w i t h this framework type: • ZSM_18 <1) ECR_40 ~2~
46 46 46 39
94 91 94 98
125 123 114 121
152 153 158 147
183 190 194 189
4.4.4.12.5.7 4.5.4.7.5.12 3.7.5.5-5.5 4.7.4.7-4-7
205
Type Material Data
ZSM-18
C r y s t a l chemical data:
INao(H20):J [AlnSi34_nO6s]-MEI, n - 2.1 - 5.7 hexagonal, P 6 / m , a - 13.175A, c - 15.848A ~
F r a m e w o r k density:
14.3 T/1000A 3
Channels:
[001] 12 6.9 x 6.9* +-+ I [001] 7 3.2 x 3.5**
6.9
..........,....
~
6,9
" ..........~
12-ring viewed along [001]
MEI
:
7-ring viewed normal to [001]
References: (1) Lawton, S.L. and Rohrbaugh, W.J. Science, 247, 1319-1321 (1990) (2) Afeworki, M., Dorset, D.L., Kennedy, G.J and Strohmaier, K.G. Stud. Surf. Sci. Catal., 154, 1274-1281
(2004)
206
MEL
D
Framework Type Data
14m2
~e
Z
framework viewed along [100]
Idealized cell data:
tetragonal, I-4m2, a - 20.3/k, c - 1 3 . 5 '
Coordination sequences and vertex symbols: T 1(16,1) T 2(16,1) T 3(16,1) T 4 (16,1) T 5(16,1) T 6 (8,2) T 7(8,2)
4 4 4 4 4 4 4
12 11 12 12 11 11 12
Secondary building units:
21 23 23 23 22 23 21
36 38 38 38 36 38 40
63 61 62 59 57 57 63
88 93 91 87 90 88 83
121 121 116 122 127 126 124
153 153 155 158 157 158 155
192 198 203 198 194 191 197
249 246 244 243 244 236 244
5-1
Composite building units: mor
mel
mfi
Materials with this framework type: • ZSM_I 1<1-3>
IDEOTAI[Si-B-O]-MEL <4' Bor-D ( M F I / M E L i n t e r g r o w t h ) <5~ Boralite D (6)
SSZ_46 (7,8~ Silicalite 2 (9) TS_2(10~
5.5-5.5.5.6 4.5.5.62.5.102 5.5.5.52.5.103 5.62.5-102.52.6 4.5.5.6.5.82 4-52.62.62.10.10 5.5.5.5.52.102
207
ZSM-11
Crystal chemical data:
Type Material Data
MEL
INa n (H~O),~l [AlnSi96_nO,92]-MEL, n < 16 tetragonal, f 4 m 2 , a - 20.12A, c - 13.44A (~)
Framework density:
17.6 T/1000A 3
Channels:
<100> 10 5.3 x 5.4*** ~..
>
lO-ring viewed along <100>
References: (1) Kokotailo, G.T., Chu, P., Lawton, S.L. and Meier, W.M. Nature, 275, 119-120 (1978) (2) Fyfe, C.A., Gies, H., Kokotailo, G.T., Pasztor, C., Strobl, H. and Cox, D.E.J. Am. Chem. Soc., 111, 24702474 (1989) (3) van Koningsveld, H., den Exter, M.J., Koegler, J.H., Laman, C.D., Njo, S.L. and Graafsma, H. Proc. 12th Int. Zeolite Conf., IV, pp. 2419-2424 (1999) (4) Piccione, P.M. and Davis, M.E. Microporous Mesoporous Mat., 49, 163-169 (2001) (5) Perego, G. and Cesari, M. J. Appl. Crystallogr., 17, 403-410 (1984) (6) Taramasso, M., Manara, G., Fattore, V. and Notari, B. GB Patent 2,024,790 (1980) (7) Terasaki, O., Ohsuna, T., Sakuma, H., Watanabe, D., Nakagawa, Y. and Medrud, R.C. Chem. Mater., 8, 463-468 (1996) (8) Nakagawa, Y. and Dartt, C. U.S. Patent 5,968,474 (1999) (9) Bibby, D.M., Milestone, N.B. and Aldridge, L.P. Nature, 280, 664-665 (1979) (10) Reddy, J.S. and Kumar, R. Zeolites, 12, 95-100 (1992)
208
MEP
Framework Type Data
Pm3n ~
Y
y
framework viewed along [001] (upper right: projection down [001]) o
Idealized cell data:
cubic, P m 3 n , a - 13.7A
Coordination sequences and vertex symbols" T~ (24,m) 4 T 2(16,3) 4 T3 ( 6 , 4 2 m ) 4 m
12 12 12
Secondary building units:
25 24 26
42 42 44
69 67 64
100 95 98
see Compendium
Composite building units: mtn
Materials with this framework type: * Melanophlogite <~ Synthetic melanophlogite <2~ low melanophlogite ~3~
129 133 144
176 177 172
229 219 222
277 277 272
5.5.5.5.5.6 5.5.5.5.5.5 5.5.5.5.6.6
209
Melanophlogite Crystal chemical data:
Type Material Data I (CH4,N2,CO2)~[ [Si46Og2]-MEP cubic, Pm-3n, a - 13.436A~1) (Data refer to structure at 200°; tetragonal at 25°C)
Framework density:
19 T/1000A 3
Channels"
apertures formed by 6-rings only
References: (1) Gies, H. Z. Kristallogr., 164, 247-257 (1983) (2) Gies, H., Gerke, H. and Liebau, F. N. Jb. Miner. Mh., 119-124 (1982) (3) Nakagawa, T., Kihara, K. and Harada, K. Am. Mineral., 86, 1506-1512 (2001)
MEP
210
MER
Framework Type Data
•.
....~,... . . . . . . . . d'.~,,,~.,.,
141mmm
,!;%..... .
y
Y
X
framework
Idealized cell data-
tetragonal, I 4 / m m m ,
viewed along [001]
a - 14.0/k, c - 10.0/k
Coordination sequences and vertex s y m b o l s T~ (32,1)
4
9
18
Secondary building units:
32
49
69
93
121
153
189
8-8 or 8 or 4
Composite building units: dcc
d8r
pau
double crankshaft chain
Materials with this framework type" •
(12)
*Merlinoite ' [ A 1 - C o - P - O ] - M E R (3~ [ G a - A 1 - S i - O ] - M E R (4~
IBa-I[A1-Si-OI-MER(5) IBa-CI-][A1-Si-O]-MER(6) I K - I [ A I - S i - O ] - M E R (7)
]NH4-I[Be-P-O]-MER (8~ K_M(5,9) Linde W (5'~°~ (1 Synthetic merlinoite ~ Zeolite W (~2~
4.4.4.82.8.8
211
Type Material Data
Merlinoite
MER
Crystal chemical data:
IKsCa2 (H20)241 [A19Si23064]-MER orthorhombic, Imrnm, a - 14.116A, b - 14.229A, c - 9.946/k (2) (Relationship to unit cell of Framework Type: a ' = b ' = a, c ' = c)
F r a m e w o r k density:
16 T/1000A 3
Channels:
[lO0] 8 3.1 x 3.5* +-+ [010] 8 2.7 x 3.6*
[001] {8 3.4 x 5.1" + 8 3.3 x 3.3*}
8-ring viewed along [100]
8-ring viewed along [010]
8-ring viewed along [001]
2nd 8-ring viewed along [001]
References: (1) Passaglia, E., Pongiluppi, D. and Rinaldi, R. N. Jb. Miner. Mh., 355-364 (1977) (2) Galli, E., Gottardi, G. and Pongiluppi, D. N. Jb. Miner. Mh., 1-9 (1979) (3) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997) (4) Kim, S.H., Kim, S.D., Kim, Y.C., Kim, C.S. and Hong, S.B. Microporous Mesoporous Mat., 42, 121-129 (2001) (5) Gottardi, G. and Galli, E. Natural Zeolites, p. 157 (1985) (6) Solov'eva, L.P., Borisov, S.V. and Bakakin, V.V. Sov. Phys. Crystallogr., 16, 1035-1038 (1972) (7) Skofteland, B.M., Ellestad, O.H. and Lillerud, K.P. Microporous Mesoporous Mat., 43, 61-71 (2001) (8) Bu, X., Gier, T.E. and Stucky, G.D. Microporous Mesoporous Mat., 26, 61-66 (1998) (9) Barrer, R.M. and Baynham, J.W.J. Chem. Soc., 2882-2891 (1956) (10) Sherman, J.D. A CS Sym. Set., 40, 30-42 (1977) (11) Barrett, P.A., Valencia, S. and Camblor, M.A.J. Mater. Chem., 8, 2263-2268 (1998) (12) Bieniok, A., Bornholdt, K., Brendel, U. and Baur, W.H.J. Mater. Chem., 6, 271-275 (1996)
212
MFI
Framework Type Data • :.:(.~:,:~!~£:~5
Pnma .
x
framework viewed along [01 O]
Idealized cell data:
o r t h o r h o m b i c , P n m a , a - 20.1A, b - 19.7A, c - 13.1A
Coordination sequences and vertex symbols: see A p p e n d i x A for a list of the c o o r d i n a t i o n s e q u e n c e s and vertex s y m b o l s for the 12 T - a t o m s
Secondary building units:
5-1
Composite building units: mor
cas
mel
mfi
Materials with this framework type: • ZSM_5 (1-3)
F Z _ I {12)
[ A s - S i - O ] - M F I (4) [ F e - S i - O ] - M F I (5~ [ G a - S i - O ] - M F I (6~ A M S- 1B ~7~ A Z - 1~8~ Bor_C (9~ Boralite C ~l°~ Encilite (ll~
L Z _ 1 0 5 (13)
M o n o c l i n i c H - Z S M - 5 {14) M u t i n a i t e (~5~ N U _ 4 (16) N U _ 5 (17)
Silicalite (~8~ TS_I (19~ T S Z (2°)
TSZ_III (21) TZ-01 (22) U S C _ 4 (23~
USI_108 (24~ Z B H (25) Z K Q - 1B (26) Z M Q _ T B ~27~ o r g a n i c - f r e e Z S M - 5 ~28~
213
Type Material Data
ZSM-5
Crystal chemical data:
INao (H20),J [AloSi96_oO,gzl-MFI, n < 27 orthorhombic, Prima, a - 20.07A, b - 19.92A, c - 13.42A (2)
F r a m e w o r k density:
17.9 T/1000A ~
Channels:
{ [ 100] 10 5.1 x 5.5 +-+ [010] 10 5.3 x 5.6 }***
1O-ring viewed along [100]
MFI
lO-ring viewed along [010]
References: (1) Kokotailo, G.T., Lawton, S.L., Olson, D.H. and Meier, W.M. Nature, 272, 437-438 (1978) (2) Olson, D.H., Kokotailo, G.T., Lawton, S.L. and Meier, W.M.J. Phys. Chem., 85, 2238-2243 (1981) (3) van Koningsveld, H., van Bekkum, H. and Jansen, J.C. Acta Crystallogr., B43, 127-132 (1987) (4) Bhaumik, A. and Kumar, R. Chem. Commun., 869-870 (1995) (5) Patarin, J., Kessler, H. and Guth, J.L. Zeolites, 10, 674-679 (1990) (6) Awate, S.V., Joshi, P.N., Shiralkar, V.P. and Kotasthane, A.N.J. Incl. Phenom., 13, 207-218 (1992) (7) Klotz, M.R.U.S. Patent 4,269,813 (1981) (8) Chono, M. andIshida, H.E. PatentB-ll3,116 (1984) (9) Taramasso, M., Perego, G. and Notari, B. Proc. 5th Int. Zeolite Conf., pp. 40-48 (1980) (10) Taramasso, M., Manara, G., Fattore, V. and Notari, B. GB Patent 2,024,790 (1980) (11) Ratnasamy, P. and Borade, M.B.E. Patent A- 160,136 (1985) (12) Suzuki, T., Hashimoto, S. and Nakano, R. E. Patent B-31,255 (1981) (13) Grose, R.W. and Flanigen, E.M.U.S. Patent 4,257,885 (1981) (14) van Koningsveld, H., Jansen, J.C. and van Bekkum, H. Zeolites, 10, 235-242 (1990) (15) Vezzalini, G., Quartieri, S., Galli, E., Alberti, A., Cruciani, G. and Kvick, A. Zeolites, 19, 323-325 (1997) (16) Whittam, T.V.E. Patent B-65,401 (1986) (17) Whittam, T.V.E. Patent B-54,386 (1982) (18) Flanigen, E.M., Bennett, J.M., Grose, R.W., Cohen, J.P., Patton, R.L., Kirchner, R.M. and Smith, J.V. Nature, 271, 512-516 (1978) (19) Taramasso, M., Perego, G. and Notari, B. U.S. Patent 4,410,501 (1983) (20) Ashibe, K., Kobayashi, W., Maejima, T., Sakurada, S. and Tagaya, N. E. Patent A-101,232 (1984) (21) Sakurada, S., Tagaya, N., Miura, T., Maeshima, T. and Hashimoto, T. E. Patent A-170, 751 (1986) (22) Iwayama, K., Kamano, T., Tada, K. and Inoue, T. E. Patent A-57,016 (1982) (23) Young, D.A.U.S. Patent 4,325,929 (1982) (24) Hinnenkamp, J.A. and Walatka, V.V.U.S. Patent 4,423,020 (1983) (25) Holderich, W., Mross, W.D. and Schwartzmann, M. E. Patent B-77,946 (1986) (26) Kee Kwee, L.S.L.E. Patent A-148,038 (1984) (27) Kee Kwee, L.S.L.E. PatentA-104,107 (1983) (28) Kim, S.D., Noh, S.H., Seong, K.H. and Kim, W.J. Microporous Mesoporous Mat., 72, 185-192 (2004)
214
MFS
Framework Type Data
..............
~:~
:>~.
"
......
....... .-. ~
. . . .
Imm2
~.
Z
framework viewed along [010]
Idealized cell data:
orthorhombic, Imm2, a - 7.5,~, b - 14.4/k, c - 19.0/k
Coordination sequences and vertex symbols: T~(8,1) T 2(8,1) T 3(4,m) T 4(4,m) T 5(4,m) T o(4,m) T 7(2,mm2) T 8(2,mm2)
4 4 4 4 4 4 4 4
12 11 12 12 12 10 12 12
Secondary building units:
23 20 24 26 19 22 22 24
39 39 42 40 35 36 40 38
62 66 64 60 64 64 62 66
93 92 90 94 96 98 92 100
see Compendium
Composite building units: mtt
fer
Materials with this framework type: • ZSM_57 °) COK-5 (intergrowth containing M F S ) <2~
127 124 131 136 123 124 138 118
165 163 168 168 155 158 160 162
210 215 206 200 207 213 196 220
260 257 259 259 272 260 262 262
5-5.5.5.5-82 4.52.5.5.8.10 5-5-5.5.5.102 5~'5~'6-8"6-8 5.52-5.5~-6.* 4.5.4.5.82.10 5.5.5.5.62.* 5.5.5.5.52-102
215
MFS
Type Material Data
ZSM-57 Crystal chemical data:
Iu,~l [A11.58i34.50721-MFS orthorhombic, Imm2, a - 7.451A, b -
14.171,~, c -
Framework density:
18.2 T/IOOOA3
Channels:
[100] 10 5.1 x 5.4* ~ [010] 8 3.3 x 4.8*
lO-ring viewed along [100]
1 8 . 7 6 7 ' (1)
8-ring viewed along [010]
References: (1) Schlenker, J.L., Higgins, J.B. and Valyocsik, E.W. Zeolites, 10, 293-296 (1990) (2) Kirschhock, C., Bons, A.J., Mertens, M., Ravishankar, R., Mortier, W., Jacobs, P. and Martens, J. Chem. Mater., 17, 5618-5624 (2005)
216
MON
14~lamd
Framework Type Data
..
&
Z
framework viewed along [100] I d e a l i z e d cell d a t a :
tetragonal,
I4~/amd (origin
c h o i c e 2), a - 7.1A, c - 17.8A
Coordination sequences and vertex symbols: T 1 (16,m)
4
11
Secondary b u i l d i n g u n i t s "
23
44 4
Materials with this framework type: * M o n t e s o m m a i t e ~) [ A 1 - G e - O ] - M O N ~2~5
67
95
134
168
215
271
4.5~.5.82.5.8 ~
217
Montesommaite
Type Material Data
Crystal chemical data:
I(K,Na)4.~ (H20)51 [A14.sSi,,.5032]-MON tetragonal, I4~/amd, a - 7.141A, c - 17.307A (~
Framework density:
18.1 T/1000A 3
Channels:
[100] 8 3.2 x 4.4* +-+ [OO1] 8 3.6 x 3.6*
:
4.4
8-ring viewed along [100]
MON
....
8-ring viewed along [001]
References:
(1) Rouse, R.C., Dunn, P.J., Grice, J.D., Schlenker, J.L. and Higgins, J.B. Am. Mineral., 75, 1415-1420 (1990) (2) Tripathi, A. and Parise, J.B. Microporous Mesoporous Mat., 52, 65-78 (2002)
218
MOR
Framework Type Data
Cmcm
)
1
×
framework viewed along [001] Idealized cell data:
orthorhombic, Cmcm, a - 18.3A, b - 20.5/k, c - 7.5A
Coordination sequences and vertex symbols: T 1(16,1) T 2(16,1) T 3 (8,m) T 4 (8,m)
4 4 4 4
12 12 11 11
Secondary building units:
22 20 24 24
38 37 39 39
60 64 54 60
88 87 86 92
115 114 126 122
155 154 156 148
204 198 195 195
242 241 242 250
5-1
Composite building units: mor
Materials with this framework type: *Mordenite °) [ G a - S i - O ] - M O R ~2) Ca_Q ~3) LZ-211 <4)
Large port mordenite ~5) Maricopaite (interrupted framework) ~6) Mordenite, U S A O) Na_D ~8)
5.5.5.52.8.12 5.5-5-52.5.8 4-52.5-82.5.82 4.52.5-8.5.8
219
Mordenite
Type Material Data
Crystal chemical data:
INas (H~O)~4I [AlsSi4oO96]-MOR orthorhombic, Cmcm, a - 18.1,~, b - 20.5A, c - 7.5 A ¢1~
Framework density:
17.2 T/1000A 3
Channels:
[001] 12 6.5 x 7.0* ~ [001] 8 2.6 x 5.7***
7.0
MOR
i
12-ring viewed along [001]
limiting 8 ring along [001] between 12-ring channels
References" (1) Meier, W.M. Z Kristallogr., 115, 439-450 (1961 ) (2) Eapen, M.J., Reddy, K.S.N., Joshi, P.N. and Shiralkar, V.P.J. Incl. Phenom., 14, 119-129 (1992) (3) Koizumi, M. and Roy, R. J. Geol., 68, 41-53 (1960) (4) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985) (5) Sand, L.B. Molecular Sieves, pp. 71-77 (1968) (6) Rouse, R.C. andPeacor, D.R. Am. Mineral.,79, 175-184(1994) (7) Gramlich, V. Ph.D. Thesis, ETH, Ziirich, Switzerland (1971) (8) Barrer, R.M. and White, E.A.D.J. Chem. Soc., 1561-1571 (1952)
220
MOZ
Framework Type Data
P61mmm
~... (
×
y
framework viewed along [001] Idealized cell data:
hexagonal,
P6/mmm, a - 31.2/k, c - 7.6/k
Coordination sequences and vertex symbols: T 1 (24,1) T 2(24,1) T 3(24,1) T 4(12,m..) T 5(12,m..) T 6(12,m..)
4 4 4 4 4 4
9 9 9 10 10 10
Secondary building units:
17 17 17 21 21 21
29 29 31 35 34 35
46 47 53 49 46 51
70 72 78 66 64 71
100 101 100 90 92 94
130 130 122 121 127 124
155 158 151 157 169 163
179 190 190 195 211 204
215 227 237 233 245 243
271 270 287 274 272 284
4.4.4.6.6.8 4"4"4"6"6"8 4"4"4"6-6"8 4"83"4"83"6"12 4"83"4"83"6"8 4-8"4-8"6"8
6 or 4-2
Composite building units:
dsc
d6r
do ub lechainSaWtooth
Materials with this framework type: *ZSM_IO ~v3)
can
pau
Itl
221
Type Material Data
ZSM-IO C r y s t a l chemical data:
MOZ
IKz4(H~O)xI [A124Sis4Oz,6]-MOZ hexagonal, P6/mmm, a - 31.575 A, c - 7.525 A, ~3)
Framework density:
16.6 T/1000A 3
Channels:
{[001] 12 6.8 x 7.0 +-~ n[O01] 8 3.8 x 4 . 8 } * * ' 1 1 0 0 1 ] 12 6.8 x 6.8*
8-ring viewed normal to [001]
12-ring viewed along [001] .....
.7,,
.
.
.
.
.
.
.~
2nd 12-ring viewed along [001]
References: (1) (2) (3)
Higgins, J.B. and Schmitt, K.D. Zeolites, 16, 236-244 (1996) Foster, M.D., Treacy, M.M.J., Higgins, J.B., Rivin, I., Balkovsky, E. and Randall, K.H.J. Appl. Crystallogr., 38, 1028-1030 (2005) Dorset, D.L. Z Kristallogr., 221,260-265 (2006)
222
MSE
P4Jmnm
Framework Type Data i] I:~.......................... '~1+-.................
z
framework viewed normal to [001]
Idealized cell data:
tetragonal, P42/mnm, a - 18.2A, c - 20.6A
Coordination sequences and vertex symbols: T, (16,1) T 2(16,1) T 3(16,1) T 4(16,1) T 5(16,1) T 6(16,1) T 7(8,..m) T 8(8,..m)
4 4 4 4 4 4 4 4
10 10 12 11 12 10 11 11
Secondary building units:
19 21 22 20 18 20 21 20
33 34 33 36 35 34 32 31
53 57 50 54 58 56 47 55
83 84 75 78 81 83 75 85
114 112 114 106 110 109 114 115
see Compendium
Composite building units" mor
bea
Materials with this framework type" • M C M _ 6 8 ~1)
mtw
141 139 152 148 143 140 156 141
174 181 183 193 177 181 189 1'79
227 230 220 225 230 226 215 223
283 274 267 254 271 282 262 275
329 317 324 317 328 337 329 331
4.5.4.6.5.6 4.5.4-10.5.6 5.6.52.6.6.10 4.52.5.5.5.10 5.5.5.6.52.10 4.5.4.10-5-6 4.5.5.6.5.6 4.52.5.6.5.6
223
MSE
Type Material Data
MCM-68
C r y s t a l c h e m i c a l data:
[Allj.4Siloo.60224]-MSE t e t r a g o n a l , P42/mnm, a - 1 8 . 2 8 6 A , c - 2 0 . 2 0 8 * (1)
Framework density:
16.6 T/1000A 3
Channels:
{ [ 0 0 1 ] 12 6.4 x 6.8 ~
[100] 10 5.2 x 5.8 ~
::
5.8 .....................!
12-ring viewed along [001]
:.
[110] 10 5.2 x 5.2 } * * *
:
5.8 .................i......
1O-ring viewed along [100]
I O-ring viewed along [11 O]
References: (1)
Dorset, D.L., Weston, S.C. and Dhingra, S . S . J .
Phys. Chem. B, 110, 2 0 4 5 - 2 0 5 0 (2006)
..
224
MSO
m
Framework Type Data
R3m
3
z
¢-y framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, R-3m, a - 17.2A, c - 19.8/k
Coordination sequences and vertex symbols: T 1 (36,1)
T 2 (36,1) T 3(18,2)
4 4 4
10 10 12
Secondary building units: Composite building units" d6r
21 20 21
37 34 32
(1,2)
75 77 80
101 106 110
2-6-2 or 4-1
lau
Materials with this framework type" *MCM-61 Mu_13 ~3~
55 53 51
mso
136 138 132
175 170 164
211 206 212
4-6.4.62.6.6 4.62-4.62.6.6 6.6.6-62.62.62
225
MCM-61
Crystal chemical data:
Type Material Data
MSO
[K2.1 C12H24061 [A12.15i27.9060]-MSO C12H2406 - 18-crown-6 rhombohedral, R-3m, a - 11.841~,, c~ - 93.29 ° (2) (hexagonal setting: a - 17.220A, c - 19.296A)
F r a m e w o r k density:
18.2 T/1000A 3
Channels:
apertures formed by 6-rings only
References: (1) Valyosik, E.W.U.S. Patent 5,670,131 (1997) (2) Shantz, D.F., Burton, A. and Lobo, R.F. Microporous Mesoporous Mat., 31, 61-73 (1999) (3) Paillaud, J.-L., Caullet, P., Schreyeck, L. and Marler, B. Microporous Mesoporous Mat., 42, 177-189
(2001 )
226
MTF
Framework Type Data
C21m
Y
framework viewed along [001]
Idealized cell data"
monoclinic, C2/m, a - 9.6,~, b - 30.4/k, c - 7.2A, 3 - 90-5°
Coordination sequences and vertex symbols: T~(8,1) T 2(8,1) T 3(8,1) T 4(8,1) T 5(8,1) T 6(4,2)
4 4 4 4 4 4
11 12 12 12 12 12
Secondary building units:
24 24 27 26 24 21
45 42 47 45 42 44
109 95 99 96 93 106
see Compendium
Composite building units:
Materials with this framework type: • MCM_35 ~) UTM_I ~2)
77 70 69 64 64 74
137 136 142 134 133 138
174 184 184 186 179 172
224 227 227 230 234 226
280 277 281 290 290 284
4.5.5.6.5.8 5.52.5.6.5.8 5.6.5-7.5.8 5-6.5.6-5.6 5.6.5.62.5.7 5.5.5.5.52.6
227
MCM-35 Crystal chemical data:
Type Material Data
[Si44Oj-MTF monoclinic, C2/m a - 9.500 A, b - 30.710A, c - 7.313A, ~ - 91.71 °~1)
Framework density:
20.6 T/1000A)
Channels:
[001] 8 3.6 x 3.9*
8-ring viewed along [001]
References: (1) (2)
Barrett, P.A., Diaz-Cabanas, M.-J. and Camblor, M.A. Chem. Mater., 11, 2919-2927 (1999) P16vert, J., Yamamoto, K. Chiari, G. and Tatsumi, T. J. Phys. Chem. B, 103, 8647-8649 (1999)
MTF
228
MTN
Framework Type Data
Fd3m Z
×
.ii
:ii ~i '
i
y
~ ~~....../:~ il ....i! . .....................
,j
.:/:,.
.;...;;
i
Z
;;
"............. :......... o ........ ~.. ?.
,
framework viewed along [111] (upper right: projection down [110]) Idealized cell data:
cubic, Fd-3m (origin choice 2), a - 19.9A
C o o r d i n a t i o n s e q u e n c e s and vertex symbols: T, (96,m) 4 12 25 43 68 95 T 2(32,3m) 4 12 24 39 66 103 T 3 (8, 43m) 4 12 24 36 64 112 m
S e c o n d a r y building units:
see Compendium
C o m p o s i t e building units" mtn
M a t e r i a l s with this f r a m e w o r k type: • ZSM_39 ~ CF_4 (2~ Dodecasil-3C ~3~ Holdstite ~4~
133 130 132
177 168 156
223 216 222
274 274 264
5.5.5-5.5.6 5.5.5.5.5.5 5-5.5.5.5.5
229
ZSM-39
Type Material Data
Crystal chemical data:
I(CsH2oN)q (OH)q[ [Sij36027el-MTN CsH2oN- tetraethylammonium cubic, Fd-3m, a - 19.36A (j)
Framework density:
18.7 T/1000.A, 3
Channels:
apertures formed by 6-rings only
MTN
References: (1) Schlenker, J.L., Dwyer, F.G., Jenkins, E.E., Rohrbaugh, W.J., Kokotailo G.T. and Meier, W.M. Nature, 294, 340-342 (1981 ) (2) Long, Y., He, H., Zheng, P., Guang, W. and Wang, B. J. Incl. Phenom., 5, 355-362 (1987) (3) Gies, H. Z. Kristallogr., 167, 73-82 (1984) (4) Smith, J.V. and Blackwell, C.S. Nature, 303, 223-225 (1983)
230
MTT
Framework Type Data
Pmmn
:%'2:::
i!
"
U z y
framework viewed along [100]
Idealized cell data:
o r t h o r h o m b i c , Pmmn (origin c h o i c e 1), a - 5.3A, b - 2 2 . 0 A , c - 1 1 . 4 '
Coordination sequences and vertex symbols: T 1 (4,m) 4 12 23 43 66 92 T 2 (4,m) T 3 (4,m) T 4 (4,m) T 5 (4,m) T 6 (2,mm2) T 7 (2,mm2)
4 4 4 4 4 4
12 12 12 12 12 12
Secondary building units:
24 22 22 24 22 24
40 40 40 41 42 44
64 67 65 62 66 66
96 97 98 97 94 88
130 136 124 132 129 126 132
170 167 165 159 170 164 174
213 207 219 206 212 220 214
261 258 265 278 262 270 258
5-5.5.5.6-102 52"62"6.62-6.62 5.5.5.5.62-102 5.5.5-5.62.* 5~'62.6.6~.6.62 5"5"5"5-6~" 10~ 5"5"5"5.10~.*
5-1
Composite building units: jbw
mtt
bik
Materials with this framework type: • Z S M _ 2 3 °-4)
ISI_4 ~6)
EU_13 ~5)
KZ_I °)
ton
231
ZSM-23
Type Material Data
Crystal chemical data:
INa. (H:O)41 [AlnSiz, nO4s]-MTT, n < 2 orthorhombic, Pmn21, a - 21.5A, b - 11.1A, c - 5.0 A, ¢1)
Framework density:
20.1 T/1000A. 3
Channels:
[001] 10 4.5 x 5.2*
MTT
1O-ring viewed along [001 ]
References: (1) Schlenker, J.L., Higgins, J.B. and Cox, D.E. private communication (2) Rohrman Jr., A.C., LaPierre, R.B., Schlenker, J.L., Wood, J.D., Valyocsik, E.W., Rubin, M.K., Higgins, J.B. and Rohrbaugh, W.J. Zeolites, 5, 352-354 (1985) (3) Marler, B., Deroche, C., Gies, H., Fyfe, C.A., Grondey, H., Kokotailo, G.T., Feng, Y., Ernst, S., Weitkamp, J. and Cox, D.E.J. Appl. Crystallogr., 26, 636-644 (1993) (4) Zones, S.I., Dalton, R.J., Morris, R. and Hwang, S.-J. J. Phys. Chem. B, 109, 652-661 (2005) (5) Araya, A. and Lowe, B.M.U.S. Patent 4,581,211 (1986) (6) Kakatsu, K. and Kawata, N. Eur. Pat. Appl. EPA 102,497 (1984) (7) Parker, L.M. and Bibby, D.M. Zeolites, 3, 8-11 (1983)
232
MTW
Framework Type Data
C21m
x
z
framework viewed along [01 O]
Idealized cell d a t a :
monoclinic, C2/m, a - 25.6A, b - 5.3A, c - 12.l/k, 3 - 109.3°
Coordination sequences and vertex symbols: T 1(4,m) T 2(4,m) T 3(4,m) T 4(4,m) T 5(4,m) T 6(4,m) T 7(4,m)
4 4 4 4 4 4 4
11 11 12 12 12 12 12
Secondary building units:
22 22 21 23 21 24 23
38 38 37 37 37 39 38
60 60 62 59 58 55 59
88 86 84 85 87 85 83
113 115 119 120 119 122 115
147 147 147 154 154 156 155
190 191 188 184 182 188 192
243 238 239 231 227 225 233
4.62.5.6.5.6 4.62.5.6.5.6 5.6.5.6.52.6 5.6.5.6.6.62 5.62.5.62.52.6 5.62.5.62.62.126 5.5.5.5.6.126
5-[1,1]
Composite building units: jbw
cas
bik
mtw
Materials with this framework type: *ZSM- 12 ~1'2~ [ B - S i - O ] - M T W ~3~ [ G a - S i - O ] - M T W ~4~
CZH_5 ~5~ NU_13 ~6) TPZ- 12~7~
Theta_3 ~8~ VS_12 ~9~
233
ZSM-12
Crystal chemical data:
MTW
Type Material Data
INao (H~O)~l[A1,Si56_nO,12]-MTW, n < 5 monoclinic, C2/c a - 24.863A, b - 5.012A, c -
Framework density:
19.4 T/1000A 3
Channels:
[010] 12 5.6 x 6.0*
,/5.6
24.328A, ~ - 107.72 °~2)
......
12-ring viewed along [01 O]
References: (1) LaPierre, R.B., Rohrman Jr., A.C., Schlenker, J.L., Wood, J.D., Rubin, M.K. and Rohrbaugh, W.J. Zeolites, 5, 346-348 (1985) (2) Fyfe, C.A., Gies, H., Kokotailo, G.T., Marler, B. and Cox, D.E.J. Phys. Chem., 94, 3718-3721 (1990) (3) Bandyopadhyay, R., Kubota, Y., Sugimoto, N., Fukushima, Y. and Sugi, Y. Microporous Mesoporous Mat., 32, 81-91 (1999) (4) Zhi, Y.X., Tuel, A., Ben Taarit, Y. and Naccache, C. Zeolites, 12, 138-141 (1992) (5) Hickson, D.A. UK Pat. Appl. GB 2079735A (1981) (6) Whittam, T.V. Eur. Pat. Appl. EPA 0059059 (1982) (7) Sumitani, K., Sakai, T., Yamasaki, Y. and Onodera, T. U.S. Patent 4,557,919 (1985) (8) Barlow, T.M.E. PatentA-162,719 (1985) (9) Reddy, K.M., Moudrakovski, I. and Sayari, A. Chem. Commun., 1491-1492 (1994)
234
MWW
Framework Type Data
P61mmm
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data"
hexagonal, P6/mmm, a - 14.4/k, c - 25.2/k
Coordination sequences and vertex symbols: see Appendix A for a list of the coordination sequences and vertex symbols for the 8 T-atoms
Secondary building units" Composite building units: d6r
see Compendium
mel
Materials with this framework type: * M C M - 22 ~ [ G a - S i - O ] - M W W ~2~
[Ti-S i- O ] - M W W (3) ERB- 1(4)
ITQ- 1(5,6) PSH_3 (7)
552_25(8.9)
235
MCM-22
MWW
Type Material Data
Crystal chemical data:
IH2.4Na3.,I [Alo.4Bs.,Si66.50,441-MWW hexagonal, P6/mmm, a - 14.208,,~, c - 24.945A ~6~
Framework density-
16.5 T/1000A 3
Channels:
2_ [001] 10 4.0 x 5.5"* I ± [001] 10 4.1 x 5.1"*
!
lO-ring viewed normal to [001] between 'layers'
5.1
l O-ring viewed normal to [001] within 'layers'
References: (1) Leonowicz, M.E., Lawton, J.A., Lawton, S.L. and Rubin, M.K. Science, 264, 1910-1913 (1994) (2) Kim, S.J., Jung, K.D. and Joo, O.S.J. Porous Mater., 11, 211-218 (2004) (3) Peng, W., Liu, Y.M., He, M.Y. and Tatsumi, T. J. Catal., 228, 183-191 (2004) (4) Belussi, G., Perego, G., Clerici, M.G. and Giusti, A. Eur. Pat. Appl. EPA 293032 (1988) (5) Camblor, M.A., Corell, C., Corma, A., Diaz-Cabanas, M.-J., Nicolopoulos, S., Gonzalez-Calbet, J.M. and Vallet-Regi, M. Chem. Mater., 8, 2415-2417 (1996) (6) Camblor, M.A., Corma, A., Diaz-Cabanas, M.-J. and Baerlocher, Ch. J. Phys. Chem. B, 102, 44-51 (1998) (7) Puppe, L. and Weisser, J. U.S. Patent 4,439,409 (1984) (8) Zones, S.I.E. Patent 231,860 (1987) (9) Zones, S.I., Hwang, S.J. and Davis, M.E. Chemistry-A European Journal, 7, 1990-2001 (2001)
236
NAB
m
Framework Type Data
~i i!i!,~
°
14m2
....".......,,
j
Z
framework viewed along [100]
Idealized cell data:
tetragonal, I - 4 m 2 , a - 7.2/k, c - 12.0A.
Coordination sequences and vertex symbols: T~ (8,.m.) 4 T~(2,4m2)4
9 8
Secondary building units"
19 20
40 40
4-1
Composite building units: lov
"PSI:
Materials with this framework type: • Nabesite ~
55 52
80 82
115 116
138 132
183 184
229 236
260 252
328 322
3.4.8.94.8.94 3-3.94.94.94.94
237
Type Material Data
Nabesite
Crystal chemical data:
NAB
INas (H2O),J [Be4Si,6040I-NAB orthorhombic, P2~2~2~, a - 9.748A, b - 10.133,~, c - 11.954,~ ~) (Relationship to unit cell of Framework Type: a ' = av/2, b ' = by/2, c' = c or, as vectors, a ' = a + b, b ' = b - a, e ' = e)
Stability:
reversable dehydration ~
Framework density:
16.9 T/1000A 3
Channels:
[110192.7x4.1"~
9-ring viewed along [110]
[110193.0x4.6"
9-ring viewed along [ 110 ]
References" (1)
Petersen, O.V., Giester, G., Brandst~itter, F. and Niedermayr, G. Can. Mineral., 40, 173-181 (2002)
238
NAT
1411amd
Framework Type Data
',~i/NI
zx|z~\
ii\
.............................. ii ,
i ¢
<.'.'~?. •%::....
Z
framework viewed normal to [001] Idealized cell data:
tetragonal, I41/amd (origin choice 2), a - 13.9, c - 6.4
Coordination sequences and vertex symbols: T, (16,m) 4 T2 ( 4 , 4 m 2 ) 4
9 8
19 18
Secondary building units:
35 36
52 56
78 66
106 116
139 140
179 154
213 232
4.82.4.82.42-84 42"42"84"84"84-84
4=1
Composite building units" nat
Materials with this framework type" *Natrolite ~1'2) [A1-Ge-O]-NAT °) [ G a - S i - O ] - N A T ~4) IRb-I[Ga-Ge-O]-NAT ~5) Gonnardite ~6)
High natrolite ~7~ Mesolite ~8'9~ Metanatrolite~°) Paranatrolite ~ Scolecite(8'12-14)
Synthetic gonnardite ~15~ Synthetic mesolite ~16~ Synthetic natrolite ~6~ Synthetic scolecite ~16~ Tetranatrolite~7)
239
Type Material Data
Natrolite
Crystal chemical data:
NAT
INa,~ (H20)~61 [A1,6Siz4080]-NAT orthorhombic, Fdd2, a - 18.30,~, b - 18.63,~, c - 6.60A ~2) (Relationship to unit cell of Framework Type: a ' = b ' = av/2, c ' = c or, as vectors, a ' = a + b, b ' = b - a, c ' = c)
Framework density"
17.8 T/1000A 3
Channels:
<100> 8 2.6 x 3.9** ~ [001] 9 2.5 x 4.1" (variable due to considerable flexibility of framework)
8-ring viewed along <100>
9-ring viewed along [001]
References: (1) Pauling, L. Proc. Natl. Acad. Sci., 16, 453-459 (1930) (2) Meier, W.M.Z. Kristallogr., 113, 430-444 (1960) (3) Tripathi, A., Johnson, G.M., Kim, S.J. and Parise, J.B.J. Mater. Chem., 10, 451-455 (2000) (4) Xie, D., Newsam, J.M., Yang, J. and Yelong, W.B. MRS Sym. Proc., 111, pp. 147-154 (1988) (5) Klaska, K.H. and Jarchow, O. Z. Kristallogr., 172, 167-174 (1985) (6) Mazzi, F., Larsen, A.O., Gottardi, G. and Galli, E. N. Jb. Miner. Mh., 219-228 (1986) (7) Baur, W.H. and Joswig, W. N. Jb. Miner. Mh., 171-187 (1996) (8) Taylor, W.H., Meek, C.A. and Jackson, W.W.Z. Kristallogr., 84, 373-398 (1933) (9) Artioli, G., Smith, J.V. and Pluth, J.J. Acta Crystallogr., C42, 937-942 (1986) (10) Joswig, W. and Baur, W.H.N. Jb. Miner. Mh., 26-38 (1995) (11) Seryotkin, Y.V., Bakakin, V.V. and Belitsky, I.A. Eur. J. Mineral., 16, 545-550 (2004) (12) F~ilth, L. and Hansen, S. Acta Crystallogr., B35, 1877-1880 (1979) (13) Smith, J.V., Pluth, J.J., Artioli, Co. and Ross, F.K. Proc. 6th Int. Zeolite Conf., pp. 842-850 (1984) (14) Stuckenschmidt, E., Joswig, W., Baur, W.H. and Hofmeister, W. Phys. Chem. Mineral., 24, 403-410 (1997) (15) Ghobarkar, H. and Schaef, O. Zeolites, 19, 259-261 (1997) (16) Ghobarkar, H. and Schaef, O. Cryst. Res. Technol., 31, K67-69 (1996) (17) Evans, H.T., Konnert, J.A., Ross, M. Am. Mineral., 85, 1808-1815 (2000)
240
NES
Fmmm
Framework Type Data
x
framework viewed along [01 O]
Idealized cell data"
orthorhombic, F m m m , a - 26.1A, b - 13.9A, c - 22.9A
Coordination sequences and vertex symbols: T 1(32,1) T 2(32,1)
4 4 T 3 (16,m) 4 T 4(16,m) 4 T 5(16,m) 4 T 6(16,m) 4 T 7(8,mm2) 4
11 12 12 12 11 12 12
Secondary building units:
21 22 20 20 24 22 24
36 38 34 31 40 35 32
58 57 57 57 63 55 50
89 86 88 84 86 83 88
123 118 125 118 114 119 120
see C o m p e n d i u m
Composite building units: cas
non
Materials with this framework type" • NU_87 (~ Gottardiite ~2~
ton
157 152 158 150 158 151 152
187 196 192 187 208 184 180
237 245 224 237 255 237 226
4.6.5.52.10 5.5.5.62.5.10 5.52.5.52.122"* 5.5-5.5.5.62 4.10"5"5"5"5 5.52.5.6.5.6 5.5.5.5.126-*
241
Type Material Data
Type Material- NU-87 Crystal chemical data:
IH4 (H~O).I [A14Si640136]-NES monoclinic, P2/c a - 14.324.~, b - 22.376A, c - 25.092A, ~3- 151.51 ° ~ (Relationship to unit cell of Framework Type: a ' = b/(2sin~3'), b ' = c, c ' = a or, as vectors, a ' = (b - a)/2, b ' = c, c ' = a)
Framework density:
17.7 T/1000A 3
Channels:
[100] 10 4.8 x 5.7** .- .
.
.
.
:.
1O-ring along [100]
References: (1) Shannon, M.D., Casci, J.L., Cox, P.A. and Andrews, S.J. Nature, 353, 417-420 (199 l) (2) Alberti, A., Vezzalini, G., Galli, E. and Quartieri, S. Eur. J. Mineral., 8, 69-75 (1996)
NES
242
NON
Framework Type Data
Fmmm
z
x& framework viewed along [001]
Idealized cell data:
orthorhombic, Fmmm, a - 22.9A, b - 15.7/k, c - 13.9A
Coordination sequences and vertex symbols: r 1 (32,1)
4 T~ (16,m) 4 T 3 (16,m) 4 T 4 (16,m) 4 T 5 (8,2mm) 4
12 12 11 12 12
Secondary building units"
25 24 23 24 24
42 39 44 41 40
95 99 95 97 92
see Compendium
Composite building units: t/Or/
Materials with this framework type: • Nonasil (~ [ B - S i - O ] - N O N (2) I(Co(CsH5)z)4 F4l[si880176] -sOs(3~ CF_3 (4~ ZSM_51 (5~
67 64 72 65 62
133 130 124 133 142
174 174 170 173 166
219 217 229 212 214
273 262 279 267 262
5.6.5.6.5-6 5.6.5.6.5.62 4-6.5.5.5-5 5.52.5.6.5.6 5.5.5.5.122.*
243
Nonasil
Type Material Data
NON
Crystal chemical data:
I (CsH,3N)4I [SissO,76]-NON CsH13N = 2-aminopentane orthorhombic, F m m m , a - 22.232.&, b - 15.058A, c - 13.627~. ¢~)
Framework density"
19.3 T/1000A 3
Channels:
apertures formed by 6-rings only
References: (1) Marler, B., Dehnbostel, N., Eulert, H.-H., Gies, H. and Liebau, F. J. Incl. Phenom., 4, 339-349 (1986) (2) Marler, B. and Gies, H. Zeolites, 15, 517-525 (1995) (3) Vandegoor, G., Freyhardt, C.C. and Behrens, P. Z. anorg, allg. Chemie, 621, 311-322 (1999) (4) Long,Y.-C., Zhong, W. and Shen, X. J. Incl. Phenom., 4, 121-127 (1986) (5) Rohrbaugh, W.J. private communication
244
NPO
P6Jmmc
Framework Type Data
X
F
Y
framework viewed along [001]
Idealized cell data:
hexagonal, P63/mmc, a - 9.1A, c - 5.3/k
Coordination sequences and vertex symbols: T~ (6,mm2) 4
10
Secondary building units"
20
34
3
Materials with this framework type: *Nitridophosphate- 1~
58
82
108
144
186
222
268
330
3"62"6"6"6"6
245
N itridop h osp hate- 1
Crystal chemical data:
Type Material Data
NPO
ILi~H,2+y+~Clxl [P,2OyN24y]-NPO with 6 < x < 9, 2 < y < 4 a n d 2 < z < 3 orthorhombic, P n a 2 , , a - 4.753~., b - 14.208A, c - 8.203A, ¢~) (Relationship to unit cell of Framework Type: a' = c, b' = a x / 3 , c' = b
or, as vectors, a ' = c, b ' = 2a + b, c ' = b)
Framework density:
21.7 T/1000/~ 3
Channels:
[100] 12 3.3 x 4.4*
12-ring viewed along [100]
References: (1)
Correll, S., Oeckler, O., Stock, N. and Schnick, W. Angew. Chem., Int. Ed., 42, 3549-3552 (2003)
246
NS!
Fr__aarneworkType ata
C21m
X
framework viewed along [01 O]
Idealized cell data:
monoclinic, C2/m, a - 14.l/k, b - 5.3A, c - 8.9/k, ~ - 105.4 °
Coordination sequences and vertex symbols: T 1(4,m) T 2(4,m) T 3(4,m)
4 4 4
12 12 12
Secondary building units:
23 26 23
42 43 40
70 64 68
93 99 95
126 133 123
5-1
Composite building units" cas
bik
Materials with this framework type: *Nu-6(2) ~ EU-20b ( C A S - N S I structural intermediate) a~
172 161 169
216 210 217
255 274 256
314 318 310
385 364 383
5.6.5.6.52.6 5.6.5.6.62.8 ~ 5.5.5.5.6.82
247
Nu-6(2)
Type Material Data
Crystal chemical data:
NSI
[Si24048]-NSI monoclinic, P2/a a - 17.257A, b - 4.988A, c - 13.848A, ~ - 106.1 ° ~ (Relationship to unit cell of Framework Type: a ' = 2c, b ' = b, c ' = a)
Framework density:
21 T/1000A 3
Channels:
[010] 8 2.6 x
8-ring viewed along [010]
4.5"1 [01o] 8
2.4 x 4.8,
2nd 8-ring viewed along [010]
References: (1) Zanardi, S., Alberti, A., Cruciani, G., Corma, A., Forn6s, V. and Brunelli, M. Angew. Chem., Int. Ed., 43, 4933-4937 (2004) (2) Marler, B., Camblor, M.A. and Gies, H. Microporous Mesoporous Mat., 90, 87-101 (2006)
248
OBW
Framework Type Data
141mmm
z
framework viewed normal to [001]
Idealized cell data:
tetragonal, I4/mmm, a - 13.9A, c - 30.8/k
Coordination sequences and vertex symbols: T~ (32,1) T 2(16,.m.) T 3(16,..m) T 4 (8,m.2m) T 5(4,4m2) m
4 4 4 4 4
8 8 8 9 8
Secondary building units:
16 16 17 18 16
30 30 30 32 32
VSV
Materials with this framework type: • OSB_2 ¢~,2)
69 67 69 64 72
see Compendium
Composite building units" lov
45 50 43 46 52
95 93 97 93 90
126 122 124 130 120
162 154 174 170 160
194 204 195 214 208
242 256 229 247 264
295 292 305 260 320
3.3.8.8.8.10 3.3.8.10-8-10 3.3.8.8-8.8 3.4-8-8-8.8 3.3.10.10.10.10
249
OBW
Type Material Data
OSB-2
Crystal chemical data:
IK44(n:o)~ol [Bez:Si5401j-OBW tetragonal, I4/mmm, a - 13.7452A, c - 30.654A (2)
Stability:
NH4-exchanged form not stable to heating (2)
Framework density:
13.1 T/1000/k 3
Channels:
{<110> 10 5.0 x 5.0** ~ ([001] 8 3.4 x 3.4* + <101> 8 2.8 x 4.0**) +-+ <100> 8 3.3 x 3.4**}***
.....
.~ 3.4
lO-ring viewed along [l lO] :: i
~i~
i
':~: ~:i~
.~
8-ring viewed along [001] ~!~
.-:: :
::%
~..,~............... .
~:%
. . . . . . . . . . . . . . . .
8-ring viewed along [101]
8-ring viewed along [100]
References: (1) (2)
Cheetham, A.K., Fjellvfig, H., Gier, T.E., Kongshaug, K.O., Lillerud, K.P. and Stucky, G.D. Stud. Surf. Sci. Catal., 135, 158 (2001) Lillerud, K.P. private communication
250
OFF
m
Framework Type Data
P6m2
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P - 6 m 2 , a - 13.1,~, c - 7.6/k
Coordination sequences and vertex symbols" T~ (12,1) T 2(6,m)
4 4
9 10
17 20
30 32
50 46
75 66
98 94
118 128
Secondary building units:
6 or 4-2
Framework description"
AAB sequence of 6-rings
144 162
4.4.4.6.6.8 4.8.4.8.6.6
185 192
Composite building units: dsc
d6r
can
gme
o esawoo Materials with this framework type: • Offretite ~'4~ LZ_217 ~5~ Linde T ( E R I - O F F structural intermediate) ~6~
Synthetic offretite ~7~ TMA_O ~8~
251
Offretite
Type Material Data
Crystal chemical data:
I (Ca,Mg),.sK (H20),41 [A14Si,403J-OFF hexagonal, P 6 m 2 , a - 13.291A, c - 7.582A ~2~
Framework density:
15.5 T/1000A 3
Channels:
[001] 12 6.7 x 6.8* ~-~ 3_ [001] 8 3.6 x 4.9**
6.7
i
12-ring viewed along [OOl]
8-ring viewed normal to [001]
References: Bennett, J.M. and Gard, J.A. Nature, 214, 1005-1006 (1967) (2) Gard, J.A. and Tait, J.M. Acta C~stallogr., B28, 825-834 (1972) Mortier, W.J., Pluth, J.J. and Smith, J.V.Z. Kristallogr. 143, 319-332 (1976) (4) Alberti, A., Cruciani, G., Galli, E. and Vezzalini, G. Zeolites, 17, 457-461 (1996) (5) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985) (6) Breck, D.W. Zeolite Molecular Sieves, p. 173 (1974) (7) Ghobarkar, H. and Schaef, O. Cryst. Res. Technol., 31, K29-31 (1996) (8) Aiello, R., Barrer, R.M., Davies, J.A. and Kerr, I.S. Trans. Faraday Soc., 66, 1610-1617 (1970)
OFF
253
UiO-6
Type Material Data
OSI
Crystal chemical data:
[Al16P16064]-OSI orthorhombic, Imm2, a - 18.355A, b - 18.321A, c - 5.053A (l~
F r a m e w o r k density:
18.8 T/1000A 3
Channels:
[001] 12 5.2 x 6.0*
12-ring viewed along [001]
References: (1) Akporiaye, D.E., Fjellvag, H., Halvorsen, E.N., Haug, T., Karlsson, A. and Lillerud, K.P. Chem. Commun., 1553-1554 (1996)
254
OSO
Framework Type Data
P6222
x
F
y
framework viewed along [001] Idealized cell data:
hexagonal, P6222, a - 10.l/k, c - 7.6/k
Coordination sequences and vertex symbols: T 1(6,2) T 2(3,222)
4 4
8 8
Secondary building units:
16 16
29 30 see
46 44
Compendium
Composite building units: lov
Y Materials with this framework type: * O S B - 1o,2)
70 76
101 92
118 130
162 148
190 202
3.3.8.8.8-141o 3-3-8-8.147-147
255
OSB-1
Type Material Data
Crystal chemical data:
OSO
IK~(H~O)91[Be3Si60~s]-OSO trigonal, P32, a - 10.093A, c - 7.626A (~)
Framework density:
13.4 T/1000/~ 3
Channels:
[001] 14 5.4 x 7.3* ~ l [001] 8 2.8 x 3.3**
•
i5.4
puckered 14-ring viewed along [OO1]
8-ring viewed normal to [001]
References: (1) (2)
Kongshaug, K.O., Fjellv~g, H., Lillerud, K.P., Gier, T.E., Stucky, G.D. and Cheetham, A.K. private communication Cheetham, A.K., Fjellvfig, H., Gier, T.E., Kongshaug, K.O., Lillerud, K.P. and Stucky, G.D. Stud. Surf Sci. Catal., 135, 158 (2001 )
256
OWE
Framework Type Data
Pmma
Z
framework viewed along [01O] Idealized cell data:
orthorhombic,
Pmma,
a - 14.4A, b - 7.2A, c - 9.1/k
Coordination sequences and vertex symbols" T~(8,1) T 2(4,.m.) T~(4,.m.)
4 4 4
9 9 11
Secondary building units:
18 19 22
35 34 32
4 or 4-4-
Composite building units:
dsc
sti
doublechainSaWtooth
Materials with this framework type: • U i 0 _ 2 8 (1) ACP_2 (2)
57 52 49
76 75 77
96 99 109
128 129 139
172 172 163
216 215 197
252 250 250
290 288 310
4.4.4.83.62.82 4.62.4.62.4.82 4.82.62.82.62.82
258
-PAR
Framework Type Data
C21c
x
framework viewed along [001]
Idealized cell data:
monoclinic, C2/c, a - 20.9/k, b - 9.2/k, c - 8.6/k, 3 - 89.7°
C o o r d i n a t i o n s e q u e n c e s a n d vertex symbols: T~ (8,1) 4 9 18 31 48 71 T:(8,1) 4 9 19 33 51 77 T 3(8,1) 4 10 19 33 52 72 T 4 (8,1) 3 8 16 29 49 68
Secondary building units:
4
M a t e r i a l s with this f r a m e w o r k type" *Partheite ~)
99 96 102 94
132 126 126 123
162 162 161 162
197 203 204 203
4-6.6.6.6.102 4.6-4-82.6-62 4.62.4.82.82-10 4.6-62
260
PAU
Framework Type Data
Im3m
x
framework viewed along [001]
Idealized cell data:
cubic, Im-3m, a - 34.8/k
Coordination sequences and vertex symbols" see Appendix A for a list of the coordination sequences and vertex symbols for the 8 T-atoms
Secondary building units:
4or8
Composite building units" pau
d8r
Materials with this framework type: •
(12)
*Paulingite ' [Ga-Si-O]-PAU ~3~ ECR- 18 ~4'5~ Paulingite, Vinaricka Hora ~6)
lta
261
Paulingite
PAU
Type Material Data
Crystal chemical data:
I (Ca,K~_,Na2)~6(H20)7oo1 [A1,52Si52oO,344]-PAU cubic, Im-3m, a - 35.093A, ~
Framework density:
15.5 T/1000,~ 3
Channels"
<100> 8 3.6x3.6"** I <100> 8 3.6 x 3.6***
3.6
!
....
3.6
8-ring viewed along <100>
References: (1) Gordon, E.K., Samson, S. and Kamb, W.K. Science, 154, 1004-1007 (1966) (2) Bieniok, A. Natural Zeolites for the Third Millennium, 53-60 (2000) (3) Kim, D.J., Shin, C.H. and Hong, S.B. Microporous Mesoporous Mat., 83, 319-325 (2005) (4) Vaughan, D.E.W. and Strohmaier, G. U.S. Patent 4,661,332 (1987) (5) Vaughan, D.E.W. and Strohmaier, K.G. Microporous Mesoporous Mat., 28, 233-239 (1999) (6) Lengauer, C.L., Giester, G. and Tillmanns, E. Mineral. Mag., 61,591-606 (1997)
262
PHI
Framework Type Data
~
~Y
z~
........... ?
~
...........
~
'
~ '~/7~ ~
A:;¢~
JJ
.,.y
........S
i
~ii
,:¢Y
Cmcm
,:
"'
...."
x
framework viewed along [001]
Idealized cell data:
o r t h o r h o m b i c , Cmcm, a - 9.9/k, b - 14. l/k, c - 14.0/k
Coordination sequences and vertex symbols" T 1(16,1) T 2(16,1)
4 4
9 9
Secondary building units:
18 18
32 32
50 48
71 68
94 96
122 126
157 155
195 191
8or4
Composite building units: dec double crankshaft chain
Materials with this framework type: *Phillipsite(l'2) [ A 1 - C o - P - O ] - P H I <3~ D A F _ 8 ~4)
H a r m o t o m e (2,5) Wellsite ~6~ ZK_19 °~
4.4-4-82-8.8 4-4.4.82.8.8
263
Type Material Data
Phillipsite C r y s t a l c h e m i c a l data:
PHI
IK~ (Ca,Na2)2 (H20),2[ [A16SiI0032]-PHI monoclinic, P2/m a - 9.865.A,, b - 14.300.A,, c - 8.668.~, ~3- 124.20 °~2) (Relationship to unit cell of Framework Type: a ' = a, b ' = c, c ' = b/(2sin(3')) or, as vectors, a ' = a, b ' = c, c ' = (b - a)/2)
F r a m e w o r k density:
15.8 T / 1 0 0 0 A 3
Channels:
[100] 8 3.8 x 3.8* +-+ [010] 8 3.0 x 4.3* +-+ [001] 8 3.2 x 3.3*
....3.8 ......... 3.8
' ........
8-ring viewed along [100]
8-ring viewed along [010]
8-ring viewed along [001]
References:
(1) (2) (3) (4) (5) (6) (7)
Steinfink, H. Acta Crystallogr., 15, 644-651 (1962) Rinaldi, R., Pluth, J.J. and Smith, J.V. Acta Crystallogr., B30, 2426-2433 (1974) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997) Barrett, P.A., Sankar, G., Stephenson, R., Catlow, C.R.A., Thomas, J.M., Jones, R.H. and Teat, S.J. Solid State Sci., 8, 337-341 (2006) Sadanaga, R., Marumo, F. and Yak6uchi, Y. Acta Crystallogr., 14, 1153-1163 (1961) Cerny, P., Rinaldi, R. and Surdam, R.C.N. Jb. Miner. Abh., 128, 312-330 (1977) Kuehl, G.H. Am. Mineral., 54, 1607-1612 (1969)
264
PON
Pca2.,
Framework Type Data
. . . . . .
2222;22J
y
framework viewed along [100]
Idealized cell data:
orthorhombic, Pca21, a - 8.9/k, b - 9.2A, c - 16.1A
Coordination sequences and vertex symbols: Tl(4,1 ) T2(4,1 ) T3(4,1 ) T,(4,1) T5(4,1 ) T6(4,1 )
4 4 4 4 4 4
10 10 10 11 9 10
Secondary building units"
20 20 19 20 18 21
36 34 34 34 34 38
4-2
Materials with this framework type: • IST_I (1~
56 54 56 55 54 57
76 82 78 83 75 76
105 108 106 110 104 105
144 134 144 136 142 146
180 175 179 176 176 182
215 224 211 227 211 212
260 264 262 264 260 262
323 304 321 304 319 325
4.6.4.6.6.8 4.6.4-6-62.107 4.6.4.62.63.64 4.6.6-62-64.107 4.4.4.6.6.63 4.6.4.6.62.8
265
IST-1
Type Material Data
PON
Crystal chemical data"
I(CH3NH3)4 (CH3NH2) 4 (OH)4I [A1jePleO48]-PON orthorhombic, Pca2j, a - 9.6152A, b - 8.6702A, c - 16.2196A (1)
Framework density:
17.7 T/1000A 3
Channels:
[100] 10 5.0 x 5.3*
lO-ring viewed along [100]
References: (1) Jorda, J.L., McCusker, L.B., Baerlocher, Ch., Morais, C.M., Rocha, J., Fernandez, C., Borges, C., Lourenco, J.P., Ribeiro, M.F. and Gabelica, Z. Microporous Mesoporous Mat., 65, 43-57 (2003)
266
RHO
D
Framework Type Data
Im3m
i
Z
~.Y framework viewed along [100]
Idealized cell data:
cubic, I m - 3 m , a - 14.9/k
Coordination sequences and vertex symbols: T, (48,2)
4
9
Secondary building units:
17
28
42
60
81
105
132
162
8-8 or 8 or 6 or 4
Composite building units: dSr
lta
i Materials with this framework type:
,Rho (1,2)
[Mn-A1-P-O]-RHO (5~
[ B e - A s - O ] - R H O (3) [ B e - P - O ] - R H O (4) [Co-A1-P-O]-RHO (5~ [Mg-A1-P-O]-RHO (5~
Gallosilicate ECR- 10 (7~ LZ_214 (8~ Pahasapaite(9'~°~
[Nal6 Cs8[[A124Ge24096]-RHO(6)
4.4.4.6.8.8
267
Rho
Type Material Data
Crystal chemical data:
I(Na,Cs),2 (H~O)~I [A1,2Si~Oj-RHO cubic, lm-3m, a - 15.031A (2)
Framework density:
14.1 T/1000A 3
Channels:
<100> 8 3.6 x 3.6*** [ <100> 8 3.6 x 3.6*** • :..
RHO
>
3.6
8-ring viewed along < 100>
References: (1) Robson, H.E., Shoemaker, D.P., Ogilvie, R.A. and Manor, P.C. Adv. Chem. Set., 121, 106-115 (1973) (2) McCusker, L.B. and Baerlocher, Ch. Proc. 6th Int. Zeolite Conf., pp. 812-822 (1984) (3) Gier, T.E. and Stucky, G.D. Nature, 349, 508-510 (1991) (4) Harvey, G. and Meier, W.M. Stud. Surf. Sci. Catal., 49, 411-420 (1989) (5) Feng, P., Bu, X. and Stucky, G.D. Microporous Mesoporous Mat., 23, 315-322 (1998) (6) Johnson, G.M., Tripathi, A. and Parise, J.B. Microporous Mesoporous Mat., 28, 139-154 (1999) (7) Newsam, J.M., Vaughan, D.E.W. and Strohmaier, K.G.J. Phys. Chem., 99, 9924-9932 (1995) (8) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985) (9) Rouse, R.C., Peacor, D.R., Dunn, P.J., Campbell, T.J., Roberts, W.L., Wicks, F.J. and Newbury, D. N. Jb. Miner. Mh., 433-440 (1987) (10) Rouse, R.C., Peacor, D.R. and Merlino, S. Am. Mineral., 74, 1195-1202 (1989)
268
-RON
Framework Type Data
141mcm
U
Y
x
framework viewed along [001]
Idealized cell data:
tetragonal, I4/mcm, a - 18.l/k, c - 9.0/k
Coordination sequences and vertex symbols: T~ (16,m) 4 T 2(16,m) 4 T 3(16,2) 4 T 4(8,m.2m)2
7 10 10 4
Secondary building units: Composite building units: vsv
17 20 16 10
31 31 31 24
76 78 67 58
see Compendium
lau
Materials with this framework type: *Roggianite ~1)
49 47 56 38
98 109 94 91
125 127 146 110
170 162 164 138
208 212 188 194
3.4.104.*.104.* 4.4.6.6.6.6 4.4.62.104.102.102 3
269
Roggianite
Type Material Data
Crystal chemical data:
[Cal6 (H20),91 [A1,6BesSi32 O,04 (oOH)16]--RON tetragonal, I4/mcm, a - 18.33A, c - 9.16.& (~)
F r a m e w o r k density:
18.2 T/1000,& 3
Channels:
[001 ] 12 4.3 x 4.3"
12-ring viewed along [OOl]
References: (1) Giuseppetti, G., Mazzi, F., Tadini, C. and Galli, E. N. Jb. Miner. Mh., 7, 307-314 (1991)
-RON
270
RRO
P21c
Framework Type Data
I<......................
..~, .,
x~__~ y
Z
framework viewed along [100]
Idealized cell data:
monoclinic, P2/c, a - 7.4A,, b - 8.6*, c - 17.2/k, ~ - 113.7 °
Coordination sequences and vertex symbols: 4 4 4 4 4
T 1 (4,1)
T 2(4,1) T 3 (4,1) T 4 (4,1) T 5(2,2)
11 10 11 10 12
Secondary building units:
23 19 21 20 18
40 37 36 34 34 4-4= 1
Composite building units" bre
Materials with this framework type: *RUB-41 m
56 59 62 62 62
83 86 90 86 90
130 111 111 108 112
163 149 148 150 136
182 201 203 201 198
226 241 252 242 264
300 281 285 285 286
371 340 331 329 314
4.8-5-8.5.104 4.5.4-8-5.5 4.5-5.5-5-103 4.5-4.5.5-8 5.5.52.52.10.103
271
RUB-41
Type Material Data
Crystal chemical data"
[Si18036]-RRO monoclinic, P2/c a-
7.345 A, b - 8.724 A, c - 17.152 A, 3 - 114.2°¢')
Framework density:
18 T/1000,~ 3
Channels:
[100] 10 4.0 x 6.5* +-+ [001] 8 2.7 x 5.0*
1O-ring viewed along [100]
8-ring viewed along [001]
References: (1) Wang, Y., Marler, B., Gies, H. and Mtiller, U. Chem. Mater., 17, 43-49 (2005)
RRO
272
RSN
Framework Type Data
Cmmm
Y
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmmm, a - 7.2/k, b - 41.9/k, c - 7.2A
Coordination sequences and vertex symbols: 4 T~ (8,m..) 4 T 3 (8,m..) 4 T 4 (8,..m) 4 T 5 (4,m2m) 4 T 1 (8,..m)
9 10 9 11 8
Secondary building units:
19 21 21 21 20
39 37 42 40 44
VSV
Materials with this framework type: • RUB_17 ~)
78 91 82 89 80
see Compendium
Composite building units: lov
59 58 57 61 55
117 117 119 116 118
155 144 151 145 152
189 194 188 191 204
235 241 239 239 228
288 287 277 294 272
330 343 345 339 354
3"4"83"94"83"94 4.4.62"8-62"8 3"4"82"94"82"94 4"5~'5"8"5"8 3"3"94"94"94"94
273
Type Material Data
RUB-17
Crystal chemical data:
RSN
IK4Na,2 (H20)lsl [ZnsSi28072]-RSN monoclinic, Cm, a - 7.238/k, b - 40.56/k, c - 7.308/k, ~ - 91.8 ° ~)
Stability"
Complete dehydration leads to destruction of the framework (~
Framework density"
16.8 T/1000A 3
Channels:
[100] 9 3.3 x 4.4* +-+ [001] 9 3.1 x 4.3* +-+[010] 8 3.4 x 4.1"
9-ring viewed along [001]
9-ring viewed along [100]
8-ring viewed along [010]
References: (1) R6hrig, C. and Gies, H. Angew. Chem., Int. Ed., 34, 63-65 (1995)
274
RTE
/
i
/
/
/
C21m
Framework Type Data
/
/ z
x
framework viewed normal to [001 ] (upper right: projection down [001 ])
Idealized cell data:
monoclinic, C2/m, a - 14.1A, b - 13.7A, c - 7.4,~, ~ - 102.4 °
Coordination sequences and vertex symbols" T, (8,1) T 2(8,1) T 3(8,1)
4 4 4
10 10 11
Secondary building units:
19 22 21
33 37 35
6 or 5-1
Composite building units" rte
Materials with this framework type: • RUB_3 ~,2)
56 54 57
81 79 80
105 108 106
136 140 139
175 176 176
219 215 218
4-5.4-6-5.6 4-4.5-8.6.6 4.5.5.6-6.8
275
RUB-3
Crystal chemical data:
RTE
Type Material Data
[ (C8H,~N)2[ [Si24048]-RTE CsH~sN = exo-2-aminobicyclo[2.2.1.]heptane monoclinic, C2/m a - 14.039A, b - 13.602A, c - 7 . 4 2 8 * , ~3 -
Framework density:
17.3 T/1000A 3
Channels:
[001] 8 3.7 x 4.4* ~
102.22 ° (1~
.~.
4.4
8-ring viewed along [001]
References: (1) (2)
Marler, B., Grtinewald-Luke, A. and Gies, H. Zeolites, 15, 388-399 (1995) Marler, B., Grfinewald-Ltike, A. and Gies, H. Microporous Mesoporous Mat., 26, 49-59 (1998)
276
RTH
Framework Type Data
C21m
y
framework viewed along [001]
Idealized cell data"
m o n o c l i n i c , C2/m, a - 9.8/k, b - 20.5/~,, c - 10.0A., ~3 - 96.9 °
Coordination sequences and vertex symbols: T 1 (8,1) T 2(8,1) T 3(8,1) T 4 (8,1)
4 4 4 4
11 10 10 10
Secondary building units:
21 21 19 18
34 36 31 31
53 54 50 55
78 75 82 77
108 100 106 103
4
Composite building units: rth
Materials with this framework type" • RUB_13 ~ S S Z - 3 6 ( I T E - R T H structural intermediate) ~2~ S S Z - 5 0 ( [ A 1 - S i - O ] - R T H ) ~3~
137 136 130 134
165 181 168 165
207 214 203 214
4.6.5-6-5.8 4.4.5.8.5.8 4.5-4.6.5.5 4.5.4.8.5.5
277
RTH
Type Material Data
RUB-13
Crystal chemical data:
I (C,oH~_,N)2[ [B2Si3oOj-RTH CjoH2,N = pentamethylpiperidinium monoclinic, C2/m a-
9.659A, b -
20.461A, c -
9.831A, 3 -
F r a m e w o r k density:
16.6 T/1000A 3
Channels:
[ 100] 8 3.8 x 4.1 * +--+ [001 ] 8 2.5 x 5.6* '::
8-ring viewed along [ 100]
96.58°(')
2:
8-ring viewed along [001]
References:
(1) Vortmann, S., Marler, B., Gies, H. and Daniels, P. Microporous Materials, 4, 111-121 (1995) (2) Wagner, P., Nakagawa, Y., Lee, G.S., Davis, M.E., Elomari, S., Medrud, R.C. and Zones, S.I.J. Am. Chem. Soc., 122, 263-273 (2000) (3) Lee, G.S. and Zones, S.I.J. Solid State Chem., 167, 289-298 (2002)
278
RUT
Framework Type Data
C21m
x
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 13.2/k, b -
13.3/k, c -
12.5,~, 3 -
114.8°
Coordination sequences and vertex symbols: T 1(8,1) T 2(8,1) T 3(8,1) T 4(8,1) T 5(4,2)
4 4 4 4 4
10 10 11 11 12
21 21 23 21 22
37 38 38 37 40
58 60 58 62 58
87 84 86 85 82
116 113 114 114 116
146 148 148 148 154
185 192 189 185 186
Secondary building units: Composite building units: rte
Materials with this framework type: • RUB_10 (1)
ITMA-ItSi-O]-RUT AI_Nu_I ~3~ B_Nu_I ~3)
Fe_Nu_ 1(3) Ga_Nu_ 1(3) Nu_l (4)
232 232 234 232 232
4.4.5.6.5-8 4.5.4-6.5.6 4.5-5-6-6.6 4.5.5.5.6-8 5.5-6.6-6.6
279
RUB-IO Crystal chemical data:
Type Material Data
RUT
I (C4H12N)4I [B4Si32OTzl-RUT C4HlzN = tetramethylammonium monoclinic, P2/a a - 13.112A, b - 12.903A, c - 12.407A, [3 - 113.50 °~
F r a m e w o r k density:
18.7 T/1000A 3
Channels:
apertures formed by 6-rings only
References: (1) Gies, H. and Rius, J. Z. Kristallogr., 210, 475-480 (1995) (2) Broach, R.W., McGuire, N.K., Chao, C.C. and Kirchner, R.M.J. Phys. Chem. Solids, 56, 1363-1368 (1995) (3) Bellussi, G., Millini, R., Carati, A., Maddinelli, G. and Gervasini, A. Zeolites, 10, 642-649 (1990) (4) Whittam, T.V. and Youll, B. U.S. Patent 4,060,590 (1977)
280
RWR
1411amd
Framework Type Data
U Z
X
framework viewed along [01O] Idealized cell data:
tetragonal, I4~/amd (origin choice 2), a - 7.8A, c - 27.3/k
Coordination sequences and vertex symbols: T~ (16,.m.) T~(16,..2)
4 4
12 11
Secondary building units:
24 23
42 42
6-2
Composite building units: mot"
Materials with this framework type: • RUB_24 ~,2~
68 66
97 94
133 133
180 173
221 218
277 280
334 328
394 393
5-6.5.6.5.62 4.52-6~.62-8-8
281
RUB-24
Crystal chemical data:
RWR
Type Material Data
[Si32064]-RWR tetragonal, I 4 / a m d ,
a -
7.6677A, c - 27.0625/k ~2)
Stability:
stable at 900°C ~
Framework density:
20.1 T/1000.~ 3
Channels:
[~00] 8 2.8 x 5.0, II [0~0] 8 2.8 x 5.0* (nonintersecting 1-d 8-ring channels)
..... S . O
,~,
~28~' 8-ring viewed along <100>
References: (1) Marler, B., Str6ter, N. and Gies, H. Recent Research Reports, 14th IZC, Cape Town, South Africa, 15-16 (2004) (2) Marler, B., Str6ter, N. and Gies, H. Microporous Mesoporous Mat., 83, 201-211 (2005)
282
RWY
Im3m
Framework Type Data
z
framework viewed along [100] Idealized cell data:
cubic,
Im-3m, a - 18.5/k
Coordination sequences and vertex symbols: T~ (48,m)
4
6
Secondary building units:
12
17
28
8 or 3"1
M a t e r i a l s w i t h this f r a m e w o r k type: • UCR_20 <~)
38
52
64
84
104
124
143
3-8.3.12.3-12
283
UCR-20
Crystal chemical data:
Type Material Data
RWY
I(C~H,~N.~,J [Ga32Ge,6S96]-RWY C6H~sN4 - T A E A - tris(2-aminoethyl)amine cubic, I 4 3 m , a - 20.9352A ~j~
Stability:
Stable when heated in air at 300°C for lh (ca 20% weight loss) or at 380°C in argon
F r a m e w o r k density:
5.2 T/1000A 3
Channels:
<111> 12 6.9 x 6.9***
1 2 - r i n g v i e w e d a l o n g < 111 >
References: (1) Zheng, N., Bu, X., Wang, B. and Feng, P. S c i e n c e , 298, 2366-2369 (2002)
284
SAO
Framework Type Data
14m2
......
Z
frameworkviewedalong[100] o
Idealized cell data:
o
tetragonal, I 4 m 2 , a - 13.4A, c - 21.9A
Coordination sequences and vertex symbols: T~ (16,1) T 2(16,1) T 3(16,1) T 4(8,2)
4 4 4 4
9 9 9 10
Secondary building units: Composite building units:
dsc
16 17 16 16
25 27 25 25
61 61 58 61
84 85 79 82
102 106 104 108
124 132 130 132
4.4.4"62"63" 124 4.4.4.125.6.63 4.6.4.6-4.126 4.4-6-6.62.125
158 167 158 156
4
sti
doublesawtooth~chain
Materials with this framework type: • STA_I ~
39 40 39 42
lau ~~)
aww
285
STA-1
SAO
Type Material Data
I(C=,H4oN=)=~(H20)61
C r y s t a l c h e m i c a l data:
[MgsAlz3PzsO,12I-SAO C21H4oN2 = CvH13N - (CH:) 7 - CvH,3N C7H~3N = quinuclidine
tetragonal, P-4n2, a - 13.810A, c - 21.969A (~)
Framework density:
13.4 T/1000A 3
Channels:
<100> 12 6.5 x 7.2** +-+ [001] 12 7.0 x 7.0* ,.-.
7.0
•
£2
,.
i
7.0
j
..........................
....,..
12-ring viewed along <100>
12-ring viewed along [001]
References: (1)
Noble, G.W., Wright, P.A., Lighffoot, P., Morris, R.E., Hudson, K.J., Kvick, A. and Graafsma, H. Angew. Chem., Int. Ed., 36, 81-83 (1997)
286
SAS
Framework Type Data
141mmm
X
framework viewed along [001] o
Idealized cell data:
tetragonal,
o
I4/mmm, a - 14.3A, c - 10.4A
Coordination sequences and vertex symbols: T, (16,m)
4
10
19
30
45
65
90
118
145
175
4.6.4-6-6.8
T 2(16,2)
4
9
17
30
48
68
87
109
142
184
4-4.4.6.6.6
Secondary building units:
6-2 or 4
Composite building units: d6r
Materials with this framework type" • STA_6 °) SSZ_73 ~2~
287
STA-6
Type Material Data
SAS
Crystal chemical data:
l(C14H34N4),.5 (H20)2.51 [MggA1,3P,60641-SAS C j4H32N4- 1,4,8,11 -tetrameth~yl- 1,4,8,11-tetraazatetradecane tetragonal, P4/mnc, a - 14.282A, c - 10.249A (~)
F r a m e w o r k density:
15.3 T/1000A 3
Channels:
[001] 8 4.2 x 4.2*
8-ring viewed along [001]
References: (1) Patinec, V., Wright, P.A., Lighffoot, P., Aitken, R.A. and Cox, P.A.J. Chem. Soc., Dalton Trans., 39093911 (1999) (2) Zones, S., Burton, A. and Ong, K. U.S. Patent 7,138,099 (2006)
288
SAT
m
Framework Type Data
R3m
z
x~----~ y framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, R-3m, a - 12.9A, c - 30.6/k
Coordination sequences and vertex symbols: T, (36,1) T2(36,1)
4 4
10 9
20 17
33 30
50 50
71 75
95 100
124 126
158 157
197 194
Secondary building units:
6or4
Framework description:
A B B C B C C A C A A B sequence of 6-rings
Composite building units: d6r
can
Materials with this framework type" • STA_2 ~
4.6.4-8-6.6 4.4-4.6.6-8
289
STA-2
Crystal chemical data:
Type Material Data
I(C,sH34N2)3(I4~O)~.~l [Mgs.4A13o.6P3601441-NAT CtsH34N2 = C7H13N - (CH:) 4 - CTH13N CTH~3N = quinuclidine trigonal, R-3, a - 12.726 A, c - 30.939A (~
F r a m e w o r k density:
16.6 T/1000.~ 3
Channels:
_1_ [001] 8 3.0 x 5.5***
8-ring viewed normal to [001]
References: (1) Noble, G.W., Wright, P.A. and Kvick, A. J. Chem. Soc., Dalton Trans., 4485-4490 (1997)
SAT
290
SAV
Framework Type Data
P41nmm
Iv
~
y
X
framework viewed along [001]
Idealized cell data"
tetragonal, P4/nmm (origin choice 2), a - 18.7A, c - 9.4A
Coordination sequences and vertex symbols: T 1 (16,1) T 2(16,1) T 3(16,1)
4 4 4
9 9 9
Secondary building units:
17 17 17
29 29 29
65 65 63
88 88 84
6-6 or 6 or 4-2 or 4
Composite building units: d6r
Materials with this framework type: • Mg_STA_7 ~ Co_STA_7 ~ Zn_STA_7 ~
45 45 45
113 114 112
143 144 144
179 177 177
4.4.4.8.6.8 4-4.4.8.6.8 4-4.4-8-6.8
291
Mg-STA-7
Type Material Data
Crystal chemical data:
I(C,aH42N6),.96 (H20)71 [Mg4.sA1,9.2P24096]-SAV CIsH42N6 = 1,4,7,10,13,16-hexamethyl1,4,7,10,13,16-hexaazacyclooctadecane tetragonal, P4/n, a - 18.773,4,, c - 9.454A ~)
F r a m e w o r k density:
14.4 T/1000A 3
Channels:
<100> 8 3.8 x 3.8** +-+ [001] 8 3.9 x 3.9*
8-ring viewed along < 100>
SAV
8-ring viewed along [001]
References: (1) Wright, P.A., Maple, M.J., Slawin, A.M.Z., Patinec, V., Aitken, R.A., Welsh, S. and Cox, P.A.J. Chem. Soc., Dalton Trans., 1243-1248 (2000)
292
SBE
Framework Type Data
141mmm
Z
-,..
".... !
:
framework viewed along [100] (upper right: projection down [100])
Idealized cell data"
tetragonal, I4/mmm, a - 18.5A, c - 27.1A
Coordination sequences and vertex symbols: T,(32,1) T 2(32,1) T 3(32,1) T 4(32,1)
4 4 4 4
9 9 9 9
Secondary building units"
17 17 17 17
27 28 27 27
38 41 39 40
55 57 56 59
78 77 77 79
8or4
Composite building units: d8r
sti
Materials with this framework type: • UCSB_SCo
(1)
U C S B - 8 M g (1) UCSB_8Mn ~ U C S B _ 8 Z n ~1~
atn
102 101 100 99
129 130 126 126
157 162 157 158
4.6.4.8-4-87 4"4"4"6"8"12 4.4.4.8.6.62 4.4-4-82-62-84
293
SBE
Type Material Data
UCSB-8Co
Crystal chemical data:
I (C~H:4N2),J [A132Co32P640256]-SBE CgH2:N ~ = 1,9 d i a m i n o n o n a n e tetragonal, P4/nnc, a - 19.065,~, c - 27.594 A (1)
Framework density:
12.8 T/1000A 3
Channels:
< 1 0 0 > 12 7.2 x 7.4** +-+ [001] 8 4.0 x 4.0*
4.o ...7.2 .
".~.....
!
4.0
•
12-ring viewed along < 100>
8-ring viewed along [001]
3.~ .......,i...........................
second 8-ring along [001]
References: (1)
Bu, X., Feng, P. and Stucky, G.D. Science, 278, 2080-2085 (1997)
i
294
SBS
P6almmc
Framework Type Data
....................
z
"
,
i
:i!
i ~............. ...........,~
....
,i~ Z
framework viewed normal to [001] (upper right: projection down [001]) hexagonal, P63/mmc, a - 17.2/k, c - 27.3A
Idealized cell data:
Coordination sequences and vertex symbols: T, (24,1) T 2(24,1) T 3(24,1) T 4(24,1)
4 4 4 4
9 9 9 9
Secondary building units"
17 17 16 16
28 27 25 24
41 39 38 35
56 55 58 53
75 75 84 77
100 100 111 104
127 127 135 130
8or4
Composite building units" sti
d6r
can
Materials with this framework type: • U C S B - 6 G a C o <~ U C S B _ 6 C o ~l~ U C S B - 6 G a M g ~l) U C S B - 6 G a Z n ~l)
UCSB-6Mg ~ UCSB_6Mn ~ UCSB_6Zn ~1)
157 156 157 153
195 192 182 178
233 230 215 213
4.4.4.126.62-84 4.4.4.8.6.62 4-4.4.6"6-12 4-6.4.6.4.87
295
Crystal chemical data:
SBS
Type Material Data
UCSB-6GaCo
I(C9H24N2)121[Gaz4C°24P48° 192]-SBS CgH22N2 = 1,9-diaminononane trigonal, P-31c, a - 17.836A, c - 27.182.31 ~)
Framework density:
12.8 T/1000/k 3
Channels:
[001] 12 6.8 x 6.8* ~ 2_ [001] 12 6.9 x 7.0** "7
12-ring viewed along [001 ]
12-ring viewed normal to [001]
8-ring along [001 ]
References: (1)
"
Bu, X., Feng, P. and Stucky, G.D. Science, 278, 2080-2085 (1997)
296
SBT
Framework Type Data
.........; ......................................... <
R3m
i
i
i'
)
,
~'
i
,//="
~.
Z
/,,
....
x ~1 ,~ y ,,a,., .....
-....,
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data"
trigonal, R-3m, a - 17.2A, c - 41.0A
Coordination sequences and vertex symbols: T~ (36,1) T 2(36,1) T 3 (36,1)
4 4 4 4
T 4 (36,1)
9 9 9 9
Secondary building units"
16 17 17 16
25 28 27 24
38 41 39 35
58 56 55 53
84 75 75 77
4
Composite building units: sti
d6r
Materials with this framework type: *UCSB-10GaZn ~ U C S B - 1 0 C o a~ UCSB-10Mg ~ U C S B - 1 0 Z n °~
can
111 100 100 104
135 127 127 130
157 157 156 153
182 195 192 178
215 232 228 213
4-4.4.6.6.12 4.4.4.126.62.84 4.4.4.8.6.62 4.6.4.6.4.87
297
UCSB-IOGaZn
Type Material Data I (C,oH26N203),81 [Ga36Zn36P7202j-SBT
Crystal chemical data:
C~oH26N203 = 4,7,10-trioxa- 1, 13-tridecanediammonium trigonal, R-3,, a - 18.080A, c - 41.951A, (~
Framework density"
12.1 T / 1 0 0 0 * 3
Channels:
[001] 12 6.4 x 7.4 * ~ _1_ [001] 12 7.3 x 7.8**
7.4
i
7.4
12-ring viewed along [001]
12-ring viewed normal to [001]
8-ring viewed along [102]
References: (1)
Bu, X., Feng, P. and Stucky, G.D. Science, 278, 2080-2085 (1997)
SBT
298
SFE
P211m
Framework Type Data
l < .................. ~.....
~,,,............... t~
y
framework viewed normal to [01 O] (upper right: projection down [010])
Idealized cell data:
monoclinic, P21/m, a - 11.5/k, b - 5.3/k, c - 14.0/k, ~ - 101 °
Coordination sequences and vertex symbols: T~(2,m) T2(2,m ) T3(2,m )
T4(2,m ) Ts(2,m )
T6(2,m ) TT(2,m )
4 4 4 4 4 4 4
12 10 10 12 12 12 12
Secondary building units: Composite building units" dzc
20 19 20 22 22 24 23
37 35 35 36 37 37 41
82 86 83 86 83 80 78
114 108 116 114 120 117 111
142 144 141 150 149 158 154
192 183 181 179 177 184 198
238 233 230 232 227 219 235
278 287 284 283 288 281 261
316 322 342 337 347 338 318
5.5.5.5.62.122 4.5-4.5.6.122 4.5.4.5.122.* 5.5.5.5.62.* 52-62.6-62-6.62 52.62.6.62.6-62 5.5.5.5.6.122
see Compendium
jbw
double zigzag chain
Materials with this framework type: • 58Z_48 (1)
62 58 57 56 55 54 58
mtt
bik
ton
299
SSZ-48
Crystal chemical data:
Type Material Data
SFE
[Si140:8]-SFE monoclinic, P2 1 a - 11.153A, b - 5.002A, c - 13.667A, 3 - 100.63 °~1)
F r a m e w o r k density:
18.7 T/1000A 3
Channels:
[010] 12 5.4 x 7.6*
7.6
7.6
12-ring viewed along [010]
References" (1) Wagner, P., Terasaki, O., Ritsch, S., Nery, J.G., Zones, S.I., Davis, M.E. and Hiraga, K. J. Phys. Chem. B, 103, 8245-8250 (1999)
300
SFF
P2 lm
Framework Type Data
z
×
framework viewed normal to [001] (upper right: projection down [001]) I d e a l i z e d cell d a t a :
monoclinic, P21/m, a - 11.5/k, b - 21.7A, c - 7.2/k, ~3 - 93.2 °
Coordination sequences and vertex symbols: 4 4 4 4 4 4 4 4
T 1 (4,1)
T 2(4,1) T 3 (4,1) T 4 (4,1) T 5(4,1) T 6 (4,1)
T 7(4,1) T 8(4,1)
12 12 11 11 11 11 11 11
Secondary building units"
20 20 22 22 23 20 19 23
34 34 38 39 37 31 36 36
56 56 57 54 57 58 55 59
5-3
Composite building units: cas
sOe
Materials with this framework type: • SSZ_44 (1) S T F - S F F structural intermediates ~2)
87 88 80 84 82 86 82 79
115 115 111 110 113 115 113 114
143 142 148 145 150 142 148 147
176 177 189 189 184 174 181 183
224 225 228 234 228 225 220 229
5.52.5.6.5.6 5.52.5.6.5.6 4.5.5.6.5.10 4.5.5.6.5.10 4.5.5-6.5.10 4.62.5.5.5.5 4.6.5.5.5.5 4.5.5.6.5.10
301
Type Material Data
SSZ-44 C r y s t a l chemical data:
SFF
[Si32Oj-SFF monoclinic, P21/m a - 1 1.485 A, b - 21.946A, c - 7.388A, ~ - 94.70 ° ~
Framework density:
17.2 T/1000A 3
Channels:
[001] 10 5.4 x 5.7*
5.4
\
1O-ring viewed along [001]
References: (1) (2)
Wagner, P., Zones, S.I., Davis, M.E. and Medrud, R.C. Angew. Chem., Int. Ed., 38, 1269-1272 (1999) Villaescusa, L.A., Zhou, W., Morris, R.E. and Barrett, P.A.J. Mater. Chem., 14, 1982-1987 (2004)
302
SFG
Framework Type Data
Pmma
x
Y
framework viewed along [001]
Idealized cell data:
orthorhombic, Pmma, a - 25.5/k, b - 12.6A, c - 13.1A
Coordination sequences and vertex symbols" T 1 (8,1)
T 2(8,1) T 3(8,1) T 4(8,1) T 5(4,.m.) T 6(4,.m.) T 7(8,1) T 8(8,1) T 9 (4,m..) T,o(2,mm2) T~I (8,1)
T~2(4,m..)
4 4 4 4 4 4 4 4 4 4 4 4
12 11 12 10 12 12 11 10 12 12 10 10
Secondary building units:
24 22 22 20 24 22 21 21 24 22 20 20
38 38 35 37 36 35 37 40 36 36 36 38
83 79 86 90 85 88 85 88 80 78 83 86
see Compendium
Composite building units" reel
Materials with this framework type: • SSZ_58 (1)
61 55 61 62 53 52 56 63 56 52 58 61
117 114 121 120 120 118 122 118 116 122 112 117
159 158 155 155 150 148 161 156 156 148 152 152
205 201 199 193 192 182 192 200 193 180 206 196
246 242 248 241 241 244 240 247 235 236 250 246
293 298 306 304 294 307 305 299 303 306 288 304
359 355 360 374 371 363 364 361 367 364 344 360
5-6.5.7.6.62 4.72.5.6.5.62 5.6-5.6.6.62 4.62.4.6~.5.10 5.52.6-62.6.62 5-5~-62"6~-6~'6~ 4.6.5.62.5.62 4-6-4"62"5" 102 5.6.5.6-62-72 5"5~'6~-62"6~'62 4.6.4.62-5.6 4.62.4.62-5" 102
303
SSZ-58
SFG
Type Material Data
Crystal chemical data:
[B 2.25Si71.750j - S F G orthorhombic, Pmma, a - 25.1118A, b - 12.4976A, c - 12.8598A (l~
Framework density"
18.3 T/1000A. 3
Channels:
[001] 10 5.2 x 5.7* +--+ [100] 10 4.8 x 5.7*
......
....
lO-ring viewed along [OO1]
~
~
>
:2.
1O-ring viewed along [100]
References: (1) Burton, A., Elomari, S., Medrud, R.C., Chan, I.Y., Chen, C.-Y., Bull, L.M. and Vittoratos, E.S.J. Am. Chem. Soc., 125, 1633-1642 (2003)
304
SFH
Framework Type Data
Cmcm
z
framework viewed along [100]
Idealized cell data:
orthorhombic, Cmcm, a - 5.3/k, b - 34.3A, c - 21.5/k
Coordination sequences and vertex symbols: T,(8,m..) T2(8,m.. ) T3(8,m.. )
T4(8,m.. ) Ts(8,m.. )
T6(8,m.. ) T7(8,m.. ) T8(8,m.. )
4 4 4 4 4 4 4 4
11 10 12 10 11 12 12 12
Secondary building units:
22 20 22 19 22 19 22 23
35 31 35 34 38 35 34 36
57 54 49 47 52 54 50 53
75 71 80 76 78 79 72 75
107 106 109 100 103 103 108 108
135 132 144 140 140 145 147 143
178 174 178 172 178 167 179 178
221 212 205 213 220 216 208 212
269 258 244 249 262 273 248 258
5-3
Composite building units: dzc double zigzag chain
Materials with this framework type: • 5SZ_53 (1)
cas
mtw
315 307 321 299 312 315 303 314
4.62.5.6.5.6 4.5.4.5.146.* 5.62.5.62.52.6 4.5.4.5.6.146 4.62.5.6.5.6 5.6.5.6.52.6 5.62.5.62-62-146 5.6.5.6.6.62
305
SSZ-53 Crystal chemical data:
Type Material Data
SFH
[B 1.6Si62.4012J-SFH monoclinic, C2/c a - 5.0192A, b - 33.7437A, c - 21.1653A, ~3- 90.485 °(I~
Framework density"
17.9 T/1000A 3
Channels:
[001] 14 6.4 x 8.7*
8.7
"
6.4
14-ring viewed along [001]
References: (1) Burton, A., Elomari, S., Chen, C.Y., Medrud, R.C., Chan, I.Y., Bull, L.M., Kibby, C., Harris, T.V., Zones, S.I. and Vittoratos, E.S. Chem. Eur. Journal, 9, 5737-5748 (2003)
306
SFN
Framework Type Data
.....................
C21m
.~:.~.....................
Z
framework viewed along [01 O]
Idealized cell data:
monoclinic, C2/m, a - 25.2A, b - 5.3A, c - 15.0A, ~3- 103.9 °
Coordination sequences and vertex symbols: T, (4,m) T 2(4,m) T 3 (4,m)
4 4 4 4 4 4 4 4
T 4 (4,m)
T 5(4,m) T 6 (4,m)
T 7(4,m) T 8(4,m)
11 11 12 12 12 12 10 10
Secondary building units:
22 22 22 19 23 21 20 19
35 38 35 34 35 34 31 34
56 51 51 55 52 49 53 48
73 76 74 79 73 78 73 76
103 99 108 101 106 109 106 102
131 135 146 139 142 138 130 139
173 176 171 163 176 176 169 166
217 220 199 209 205 196 206 205
265 251 242 263 246 238 252 242
5-3
Composite building units" dzc
jbw
double zigzag chain
Materials with this framework type: • SSZ_59 ~
cas
mtw
297 296 302 306 295 310 297 299
4.62.5.6.5-6 4-62.5.6.5.6 5"62-5"62"62"146 5.6.5.6.52.6 5.6.5.6-6.62 5-62.5.62"52"6 4.5-4.5.146.* 4.5.4.5.6.146
307
SSZ-59
C r y s t a l chemical d a t a :
SFN
Type Material Data
[B o.35Si 15.65032]-SFN triclinic, P]-, a - 5.023A, b - 12.735A, c -
14.722A
oc - 103.44 °, ~3 - 90.51 °, ~ - 100.88 ° (~) F r a m e w o r k density:
17.8 T/1000A 3
Channels:
[001] 14 6.2 x 8.5*
14-ring viewed along [001]
References: (1)
Burton, A., Elomari, S., Chen, C.Y., Medrud, R.C., Chan, I.Y., Bull, L.M., Kibby, C., Harris, T.V., Zones, S.I. and Vittoratos, E.S. Chem. Eur. Journal, 9, 5737-5748 (2003)
308
SFO
Framework Type Data
C21m
i
l~!.~.i
.i!:ii
?
X
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 22.6/k, b - 13.6A, c - 7.0A, ~ - 99 °
Coordination sequences and vertex symbols: T~(8,1) T 2(8,1) T 3(8,1) T 4(8,1)
4 4 4 4
10 9 9 9
Secondary building units:
17 18 18 16
28 30 29 27
63 64 65 65
6-2 or 4-4- or 4
Composite building units: sti
Materials with this framework type: ,SSZ_51 (1)
46 43 42 44
86 90 91 87
117 111 111 110
142 139 138 138
168 178 176 171
211 212 210 211
256 248 248 257
4.6-4-6.6.12 4.4.4.8.63.8 4.4.4.12.6.63 4.6.4.62.4.8
309
SFO
Type Material Data
SSZ-51 Crystal chemical data:
I(C7NzH,1)s(H:O)4I [FsA132P3:O12s]-SFO C7N2H~ = 4-dimethylaminopyridinium monoclinic, C2/c a - 21.759,&, b - 13.821A, c - 14.224 A, ~ - 98.849 °(') (Relationship to unit cell of Framework Type: a ' = a, b ' = b, c ' = 2c)
Framework density:
15.1 T/1000A 3
Channels:
[0011126.9x7.1"+-+
[01018 3.1x3.9"
•
12-ring viewed along [001]
.1
8-ring viewed along [010]
References: (1) Morris, R.E., Burton, A., Bull, L.M. and Zones, S.I. Chem. Mater., 16, 2844-2851 (2004)
...................
310
SGT
1411amd
Framework Type Data
:
).
i
!
t
t, t,
i!
Z
*£) .............. :
framework viewed along [100] (upper right: projection down [100]) tetragonal, I 4 / a m d (origin choice 2), a - lO.3/k, c - 34.4*
Idealized cell data:
Coordination sequences and vertex symbols: T, (16,m) T 2(16,m) T 3(16,2) T 4 (16,m)
4 4 4 4
11 11 11 12
Secondary building units:
22 21 23 24
37 37 38 42
5-3
Materials with this framework type: • Sigma_2 ~ [B-Si-O]-SGT ~2~
62 63 62 61
89 86 92 87
120 121 113 128
155 152 159 168
202 196 210 205
257 258 244 250
4.6-5.5.5.5 4.6.5.5.5.5 4.6.5.5.5.5 5.6.5.6.5.6
311
Sigma-2 Crystal chemical data:
Type Material Data
SGT
I(C,oH,~N)41[Si64012s]-SGT C10H17N = 1-aminoadamantane tetragonal, N / a m & a - 10.239A, c - 34.383A ~
F r a m e w o r k density:
17.8 T/1000A 3
Channels:
apertures formed by 6-rings only
References: (1) (2)
McCusker, L.B.J. Appl. Crystallogr., 21, 305-310 (1988) Grtinewald-Luke, A., Marler, B., Hochgrafe, M. and Gies, H. J. Mater. Chem., 9, 2529-2536 (1999)
312
SIV
Framework Type Data
Cmcm
;":~ - y
x•I z
framework viewed along [100]
Idealized cell data:
orthorhombic, Cmcm,
a -
9 . 9 ' , b - 14.1A, c - 28.1/k
Coordination sequences and vertex symbols" 4 4 4 4
T 1 (16,1)
T 2(16,1) T 3(16,1) T 4(16,1)
9 9 9 9
Secondary building units"
18 18 18 18
32 32 32 32
49 48 48 49
4or8
Composite building units: dcc
double crankshaft chain
gis
i
Materials with this framework type: • SIZ_7 ~)
69 67 68 69
93 92 96 93
122 120 126 121
156 150 155 155
191 187 191 193
229 231 234 230
275 275 277 272
4-4-4.82.8.8 4.4.4.82.8.8 4.4-4.82.8.8 4.4.4.82.8.8
313
SlV
Type Material Data
SIZ-7
Crystal chemical data:
[ C o 12.sA119.2P32O 128]-S I V m o n o c l i n i c , C2/c a - 10.2959~,, b - 14.3715~,, c - 2 8 . 5 9 9 A , ~ - 9 1 . 0 9 4 ° ~
Framework density:
15.1 T/1000/k 3
Channels:
{ [100] 8 (3.5 x 3.9+ 8 3.7 x 3.8 +-+ [110] 8 3.7 x 3.8 +-+ [001] 8 3.8 x 3.9 ° } ***
8-ring viewed along [100] • .>
2nd 8-ring viewed along [100]
..:.
3.8
&ring viewed along [110]
8-ring viewed along [001]
References: (1)
Parnham, E.R. and Morris, R.E.J. Am. Chem. Soc., 128, 2204-2205 (2006)
i
314
SOD
m
Framework Type Data
Im3m
Z
framework viewed along [100]
Idealized cell data:
cubic, Im-3m, a - 9.0/k
Coordination sequences and vertex symbols: T l (12, 42m )
4
10
20
34
52
74
100
Secondary building units"
6
Framework description:
A B C sequence of 6-rings
130
164
4.4.6.6.6.6
202
sod
Composite building units:
Materials with this framework type: • Sodalite (1,2) [A1-Co-P-O]-SOD (3) [A1-Ga-Si-Ge-O]-SOD(4) (5 6) [AI-Ge-O]-SOD ' [Be-A1-Si-O]-SOD (7) [ B e - A s - O ] - S O D (8~ [ B e - G e - O ] - S O W 9~ [ B e - P - O ] - S O D (8~ [Be-Si-O]-SOD °'l°) [ C o - G a - P - O ] - S O D (3'1~ [ G a - G e - O ] - S O W 6~
[Ga-Si-O]-SOD ~2) [Zn-A1-As-O]-SOD (13) [ Z n - A s - O ] - S O D (14~ [ Z n - G a - A s - O ] - S O D (11'13~ [ Z n - G a - P - O I - S O D (11~ [ Z n - P - O l - S O O (14) [ Z n - S i - O l - S O D (15)
Danalite ~22)
lea 8 (WO4)2111112024]-SOO(16)
SIZ_9 ~28~ Silica sodalite(29) T M A sodalite ~3°~ (31 32) Tugtupite '
A1PO-20 plus variants (19 20) Basic sodalite ' Bicchulite (21~
6 (23)
Genthelvite ~24~ H a u y n ~25) Helvin ~22) H y d r o x o sodalite ~26) Nosean
(17 18)
'
(27)
315
Sodalite Crystal chemical data:
Type Material Data
SOD
INa C] l [A16Si6024]-SOD cubic, P-43n , a - 8.870,~ ~2~
Framework density:
17.2 T/1000A 3
Channels:
apertures formed by 6-rings only
References: (1) Pauling, L. Z. Kristallogr., 74, 213-225 (1930) (2) Loens, J. and Schulz, H. Acta Crystallogr., 23, 434-436 (1967) (3) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997) (4) Johnson, G.M., Mead, P.J. and Weller, M.T. Microporous Mesoporous Mat., 38, 445-460 (2000) (5) Wiebcke, M., Sieger, P., Felsche, J., Engelhardt, Co.,Behrens, P. and Schefer, J. Z. anorg, allg. Chemie, 619, 1321-1329 (1993) (6) Bu, X., Feng, P., Gier, T.E., Zhao, D. and Stucky, G.D.J. Am. Chem. Soc., 120, 13389-13397 (1998) (7) Armstrong, J.A. and Weller, M.T.J. Chem. Soc., Dalton Trans., 2998-3005 (2006) (8) Gier, T.E., Harrison, W.T.A. and Stucky, G.D. Angew. Chem., Int. Ed., 30, 1169-1171 (1991) (9) Dann, S.E., Weller, M.T., Rainford, B.D. and Adroja, D.T. Inorg. Chem., 36, 5278-5283 (1997) (10) Dann, S.E. and Weller, M.T. Inorg. Chem., 35, 555-558 (1996) (11) Bu, X., Gier, T.E., Feng, P. and Stucky, G.D. Microporous Mesoporous Mat., 20, 371-379 (1998) (12) McCusker, L.B., Meier, W.M., Suzuki, K. and Shin, S. Zeolites, 6, 388-391 (1986) (13) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001) (14) Nenoff, T.M., Harrison, W.T.A., Gier, T.E. and Stucky, G.D.J. Am. Chem. Soc., 113, 378-379 (1991) (15) Camblor, M.A., Lobo, R.F., Koller, H. and Davis, M.E. Chem. Mater., 6, 2193-2199 (1994) (16) Depmeier, W. Acta Crystallogr., C40, 226-231 (1984) (17) Wilson, S.T., Lok, B.M., Messina, C.A., Cannan, T.R. and Flanigen, E.M.J. Am. Chem. Soc., 104, 11461147 (1982) (18) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986) (19) Barrer, R.M. and White, E.A.D.J. Chem. Soc., 1267-1278 (1951) (20) Hassan, I. and Grundy, H.D. Acta Crystallogr., C39, 3-5 (1983) (21) Sahl, K. and Chatterjee, N.D.Z. Kristallogr., 146, 35-41 (1977) (22) Glass, J.J., Jahns, R.H. and Stevens, R.E. Am. Mineral., 29, 163-191 (1944) (23) Shishakova, T.N. and Dubinin, M.M. Izv. Akad. Nauk SSSR, 1303- (1965) (24) Merlino, S. Feldspars and Feldspathoids, pp. 435-470 (1983) (25) Loehn, J. and Schulz, H. N. Jb. Miner. Abh., 109, 201-210 (1968) (26) Felsche, J., Luger, S. and Baerlocher, Ch. Zeolites, 6, 367-372 (1986) (27) Schulz, H. and Saalfeld, H. Tschermaks Min. Petr. Mitt., 10, 225-232 (1965) (28) Parnham, E.R. and Morris, R.E.J. Am. Chem. Soc., 128, 2204-2205 (2006) (29) Bibby, D.M. and Dale, M.P. Nature, 317, 157-158 (1985) (30) Baerlocher, Ch. and Meier, W.M. Helv. Chim. Acta, 52, 1853-1860 (1969) (31) Sorensen, H. Am. Mineral., 48, 1178 (1963) (32) Hassan, I. and Grundy, H.D. Can. Mineral., 29, 385-390 (1991)
316
SOS
Framework Type Data
Pmna
.......... " "~......
(
~s~.~,w~
ft.
................
Z
framework viewed along [010]
Idealized cell data:
orthorhombic, P m n a , a - 20.4/k, b - 7.1A, c - 9.7/k
Coordination sequences and vertex symbols: T~(8,1) T 2(8,1) T 3(8,1)
4 4 4
10 8 7
Secondary building units"
19 15 15
31 27 27
4-2
Materials with this framework type: *SU_16 ~1~ FJ_17 ~2)
47 46 41
71 70 68
97 93 93
124 116 119
153 151 146
187 197 192
231 235 230
278 265 268
4.8.4.8-84.12 3"87"4"62"62"8 3.4.3.82-62.*
317
SU-16
Type Material Data
Crystal chemical data:
[(C4H,sN3)4[ [BsGe~6048]-SOS C4Ht3N 3 = diethylenetriamine monoclinic, P2l/C a - 6.936A, b - 10.493A, c - 20.448,~, ~3- 90.09 °~1~
Stability:
Unstable to removal of template ~)
Framework density:
16.1 T/1000/k 3
Channels:
{[100] 12 3.9 x 9.1 +-+ [010] 8 3.3 x 3.3}**
12-ring viewed along [100]
8-ring viewed along [010]
References: (1) (2)
Li, Y. and Zou, X. Angew. Chem., Int. Ed., 44, 2012-2015 (2005) Zhang, H.-X., Zhang, J., Zheng, S.-T. and Yang, G.-Y. Inorg. Chem., 44, 1166-1168 (2005)
SOS
318
SSY
Framework Type Data
Pmmn
z
framework viewed along [100] I d e a l i z e d cell d a t a :
orthorhombic, Pmmn (origin choice 2), a - 5.3/k, b - 22.6/k, c - 14.0/k
Coordination sequences and vertex symbols: T 1 (4,m..) T 2(4,m..) T 3 (4,m..)
4 4 4 T 4 (4,m..) 4 T 5(4,m..) 4 T 6 (4,m..) 4 T 7(2,mm2) 4 T 8(2,mm2) 4
12 10 12 10 12 12 12 12
Secondary building units:
20 19 24 20 22 22 24 22
36 35 38 35 37 37 44 38
59 57 57 57 57 55 56 60
84 84 79 83 87 87 78 78
115 113 116 115 117 120 110 114
152 147 156 146 152 148 158 150
183 179 193 183 185 180 206 200
236 229 233 227 234 234 234 232
286 289 280 282 286 294 262 280
see Compendium
Composite building units: &c
jbw
double zigzag chain
Materials with this framework type: *SSZ_60 ")
mtt
ton
344 337 330 348 345 344 336 332
5.5.5.5.62 •122 4.5.4.5-6-122 52.62.6.62-6-62 4.5-4.5.122.* 52.62.6.62.6.62 5-5.5.5.62..* 5.5.5.5.122..* 5.5.5-5.62 •122
320
STF
Framework Type Data
C21m
z
x
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
monoclinic, C2/m, a - 14.1A,, b - 18.2/k, c - 7.5/k, 3 - 99°
Coordination sequences and vertex symbols: 4 4 4 4 4
T 1(8,1)
T 2(8,1) T 3(8,1) T 4 (4,m) T 5(4,m)
12 11 11 11 11
Secondary building units:
20 22 23 19 20
34 39 36 36 31
56 55 59 54 58
88 82 80 84 84
114 111 113 110 117
143 149 147 146 137
173 188 183 179 174
224 223 227 226 229
5.52.5.6.5.6 4"5-5-6"5"10 4"5"5"6-5"10 4.6.5-5"5"5 4.62-5.5.5.5
5-3
Composite building units: cas
stf
Materials with this framework type: , 5 5 2 _ 3 5 ~1) ITQ_9 ~2~ Mu_26 ~3~
SSZ-35, as synthesized ~4~ S T F - S F F structural intermediates ~5)
321
SSZ-35 Crystal chemical data"
Type Material Data
STF
[Si16032]-STF triclinic, P]-, a - 11.411A, b - 11.527A, c - 7.377A oL - 94.66o, f3 - 96.21, ~ - 104.89 ° (l~ (Relationship to unit cell of Framework Type" V' - V/2)
Framework density"
17.3 T/1000A 3
Channels:
[001] 10 5.4 x 5.7*
1O-ring viewed along [001]
References: (1) Wagner, P., Zones, S.I., Davis, M.E. and Medrud, R.C. Angew. Chem., Int. Ed., 38, 1269-1272 (1999) (2) Villaescusa, L.A., Barrett, P.A. and Camblor, M.A. Chem. Commun., 21, 2329-2330 (1998) (3) Harbuzaru, B., Roux, M., Paillaud, J.L., Porcher, F., Marichal, C., Chezeau, J.M. and Patarin, J. Chemistry Letters, 616-617 (2002) (4) Fyfe, C.A., Brouwer, D.H., Lewis, A.R., Villaescusa, L.A. and Morris, R.E.J. Am. Chem. Soc., 124, 77707778 (2002) (5) Villaescusa, L.A., Zhou, W., Morris, R.E. and Barrett, P.A.J. Mater. Chem., 14, 1982-1987 (2004)
322
STI
Framework Type Data
Fmmm
~,~:...... i,~......."~'~: ....... .......... ,2121 ~
\ i
\ ....
•..........
x•
Z
y
framework viewed along [100]
Idealized cell data:
o r t h o r h o m b i c , Fmmm, a - 13.5/k, b - 17.8/k, c - 17.9,~
Coordination sequences and vertex symbols: T 1 (32,1) T 2(16,m) T 3(16,m) T 4 (8,222)
4 4 4 4
10 11 9 12
Secondary building units:
20 20 17 18
34 36 35 34
57 57 57 58
82 78 77 82
103 109 103 112
138 140 138 130
181 176 188 172
220 222 225 228
4-4=1
Composite building units: sti
bre
Materials with this framework type: • Stilbite ~-3~ Barrerite ~4~ Stellerite <5~ Synthetic barrerite~6~
Synthetic stellerite(6) Synthetic stilbite ~7~ T N U _ 1 0 ~8~
4.5.4-6.5.62 4.8.5.82.5.82 4.5.4-5"4"8 52.52-6-6-10.10
323
STI
Type Material Data
Stilbite
Crystal chemical data:
INa4Ca8 (H20)561 [Alz0Si520~44]-STI monoclinic, C2/m a - 13.64A, b - 18.24A, c - 11.27,~, ~ - 128.0 °~3) (Relationship to unit cell of Framework Type: a ' = a, b ' = b, c'= c/(2sin~') or, as vectors, a' = a, b' = b, e' = (e - a)/2)
Framework density:
16.3 T/1000/k 3
Channels:
[ 100] 10 4.7 x 5.0* +--+ [001 ] 8 2.7 x 5.6*
5.O
lO-ring viewed along [100]
i
•
8-ring along [001]
References: (1) Galli, E. and Gottardi, G. Miner. Petrogr. Acta, 12, 1-10 (1966) (2) Slaughter, M. Am. Mineral., 55, 387-397 (1970) (3) Galli, E. Acta Crystallogr., B27, 833-841 (1971) (4) Galli, E. and Alberti, A. Bull. Soc. fr. Mineral. Cristallogr., 98, 331-340 (1975) (5) Galli, E. and Alberti, A. Bull. Soc. fr. Mindral. Cristallogr., 98, 11-18 (1975) (6) Ghobarkar, H., Schaef, O. and Guth, U. J. Solid State Chem., 142, 451-454 (1999) (7) Ghobarkar, H. and Schaef, O. J. Phys. D: Appl. Phys., 31, 3172-3176 (1998) (8) Hong, S.B., Lear, E.G., Wright, P.A., Zhou, W., Cox, P.A., Shin, C.-H., Park, J.-H. and Nam. I.-S. J. Am. Chem. Soc., 126, 5817-5826 (2004)
324
STT
P2.,In
Framework Type Data
A ................................
'
~ .............
~
/
x
z
f r a m e w o r k viewed normal to [100]
Idealized cell data:
monoclinic, P21/n, a - 13.l/k, b - 21.9/k, c - 13.6/k, 3 - 102-9°
Coordination sequences and vertex symbols: T~ (4,1) T 2 (4,1) T 3 (4,1) T 4 (4,1) T 5 (4,1) T 6 (4,1) T 7 (4,1) T 8 (4,1) T 9 (4,1) Tlo (4,1) T1, (4,1) T,2 (4,1) T13 (4,1) T~4 (4,1) T15 (4,1) T16 (4,1)
4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4
11 10 11 10 9 10 10 10 11 10 12 10 10 12 11 11
Secondary building units:
22 23 20 19 21 20 20 19 19 21 20 18 20 21 21 20
36 37 35 32 38 40 35 35 34 31 31 35 38 33 33 32
5-3
Composite building units: bea
cas
Materials with this framework type: • SSZ_23 ~1)
55 57 54 55 57 57 57 54 53 51 50 59 55 58 55 54
84 78 84 81 78 78 77 77 81 83 88 77 75 86 78 89
111 108 108 109 104 105 108 108 115 115 117 107 104 112 111 115
142 146 142 141 144 143 139 146 140 134 137 150 149 141 145 138
179 187 178 174 195 191 184 174 173 172 167 179 185 174 175 172
233 225 225 223 220 226 230 215 219 216 221 221 218 226 217 221
4.5.5.7.6-9 4.4.5.9.6.7 4.6.5-6.5.7 4.5.4.6.5.5 4.4.4.9.5.7 4.5-4.7.5.9 4.6.4.6.5.7 4.5.4-9-5-6 4.6.5.5.5.5 4.6.4-6.5.5 5.52.5.6.6.6 4.5.4.9.5.5 4.4.5.6.5.9 5.5.5.6.5.7 4.5.5.6.5-9 4.62.5.5.5.5
325
SSZ-23
Type Material Data
Crystal chemical data"
STT
I(C,~H~N)~,F~(OH)0J [Si640,2s]-STT C ~3H2~N = N , N , N - t r i m e t h y l - 1 - a d a m a n t a m m o n i u m monoclinic, P2~/n a - 12.959A, b - 21.792A,, c - 13.598A, ~3 - 101.85 ° ~)
Framework density:
17 T/1000A, ~
Channels:
[101] 9 3.7 x 5.3* ~
9-ring viewed along [101]
[001] 7 2.4 x 3.5*
7-ring viewed along [001]
References: (1)
Camblor, M.A., Diaz-Cabanas, M.-J., Perez-Pariente, J., Teat, S.J., Clegg, W., Shannon, I.J., Lightfoot, P., Wright, P.A. and Morris, R.E. Angew. Chem., Int. Ed., 37, 2122-2126 (1998)
326
SZR
Framework Type Data
..........................
...
'>.>,,.,..:-.
Cmmm
, , . - .....
y
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmmm, a - 18.9/k, b - 14.4/k, c - 7.5/k
Coordination sequences and vertex symbols: T 1(16,1) T 2(8,..m) T 3 (8,.m.) T 4(4,2mm)
4 4 4 4
10 12 10 12
Secondary building units"
21 23 19 24
38 38 34 38
61 59 60 52
88 82 89 88
116 119 118 118
6
Composite building units: mtt
d6r
Materials with this framework type: • SUZ_4 (1,2)
mso
149 155 144 150
190 191 179 192
237 231 238 232
289 283 296 278
340 338 342 340
4.5.4.6.6.82 5.8.5.8.52.6 4.5.4.5.6.82 5.5.5.5.102.104
327
Type Material Data
SUZ-4
Crystal chemical data:
SZR
IK41[A14Si32072]-SZR orthorhombic, Cmmm, a - 18.8064A, b - 14.2298A, c - 7.4548,~ ~2)
F r a m e w o r k density:
18 T/IOOOA 3
Channels:
{ [001] 104.1 x 5.2 ~
5.2
i
5.2
[010] 8 3.2 x 4.8 ~ [110] 8 3.0 x 4.8 }***
!
lO-ring viewed along [001]
4.8
8-ring viewed along [010]
•
4,8
i3.0 8-ring viewed along [110]
References: (1) Lawton, S.L., Bennett, J.M., Schlenker, J.L. and Rubin, M.K. Chem. Commun., 894-896 (1993) (2) Strohmaier, K.G., Afeworki, M. and Dorset, D.L.Z. Kristallogr., 221,689-698 (2006)
328
TER
Framework Type Data
Cmcm
Vy
y
k-x framework viewed along [001 ]
Idealized cell data:
orthorhombic, Cmcm, a - 9.8A, b - 23.6A, c - 20.2/~.
Coordination sequences and vertex symbols: T 1 (16,1) T 2(16,1) T 3 (8,m) T 4 (8,m) T 5(8,m) T 6(8,m) T 7(8,m) T 8(8,m)
4 4 4 4 4 4 4 4
11 11 11 11 11 11 12 12
Secondary building units:
19 21 22 21 19 21 20 23
35 35 39 41 34 33 35 32
57 58 62 61 56 53 55 49
83 87 82 77 78 80 81 86
113 103 104 107 116 112 119 124
2-6-2 or 4-1
Composite building units: bre
bog
d3 Materials with this framework type" *Terranovaite °~
cas
137 144 142 134 152 155 142 147
184 188 178 186 184 187 182 167
231 227 225 232 208 214 216 219
4.5.5.6.5.62 4.5.5.62-5.103 4"106"5"63"5"63 4"52"5"104"5"104 4.52.5.6.5.6 4.102-5-63-5"63 5.6.5.6.52.102 5.62.5-62.10-104
329
Type Material Data
Terranovaite
TER
Crystal chemical data:
INa4.2Ko.2Mgo.2Ca3.7 (H20)291 [A1 ~2.3S i67.70,6o]-TER orthorhombic, Cmcm, a - 9.747A, b - 23.880A, c - 20.068A (1~
Framework density:
17.1 T/1000,~ 3
Channels:
[ 100] 10 5.0 x 5.0* +-+ [001 ] 10 4.1 x 7.0*
7.0
/::: 5.0
1O-ring viewed along [100]
......
1O-ring viewed along [001]
References: (1) Galli, E., Quartieri, S., Vezzalini, G., Alberti, A. and Franzini, M. Am. Mineral., 82, 423-429 (1997)
330
THO
Framework Type Data
......~
i~!~i'~
Pmma
.....~....: ~
Z
xJ-~
-y
f r a m e w o r k viewed normal to [001]
Idealized cell data:
orthorhombic, P m m a , a - 14.0/k, b - 7.0A, c - 6.5/k
Coordination sequences and vertex symbols: T 1 (4,m)
4 T 2(4,m) 4 T 3 (2,mm2) 4
9 9 8
Secondary building units:
19 19 18
35 33 34
52 50 50
72 74 68
100 100 100
131 129 130
163 165 160
201 201 204
4"83"4"83"42"84 4"83"4"83"42"84 42"42"84"84"84"84
4=1
Composite building units" nat
Materials with this framework type: • Thomsonite (1-3~ [A1-Co-P-O]-THO (4~ [ G a - C o - P - O ] - T H O (4) [Zn-A1-As-O]-THO (5~ [ Z n - P - O ] - T H O (6~
[ Z n - P - O ] - T H O (7)
IRb201[
Ga20Ge20° 80]-THO(8~ Na-V ([Ga-Si-O]-THO) (9) Synthetic thomsonite (l°~ Z C P - T H O ( [ Z n - C o - P - O ] - T H O ) (ll)
331
Thomsonite
Crystal chemical data"
Type Material Data
THO
INa4Ca (H20)41 [Alz0Siz0Os0]-THO orthorhombic, Pncn, a - 13.088A, b - 13.052A, c - 13.229A ¢3) (Relationship to unit cell of Framework Type: a ' = a, b'= 2b, c'= 2c)
F r a m e w o r k density:
17.7 T/1000A 3
Channels:
[100] 8 2.3 x 3.9* ~ [010] 8 2.2 x 4.0* +-+ [001] 8 2.2 x 3.0* (variable due to considerable flexibility of framework)
22i
8-ring viewed along [100]
8-ring viewed along [010]
8-ring along [001], variable
References:
(1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11)
Taylor, W.H., Meek, C.A. and Jackson, W.W.Z. Kristallogr., 84, 373-398 (1933) Alberti, A., Vezzalini, (3. and Tazzoli, V. Zeolites, 1, 91-97 (1981) Pluth, J.J., Smith, J.V. and Kvick, A. Zeolites, 5, 74-80 (1985) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001) Neeraj, S. and Natarajan, S. J. Phys. Chem. Solids, 62, 1499-1505 (2001) Ng, H.Y. and Harrison, W.T.A. Microporous Mesoporous Mat., 50, 187-194 (2001) Lee, Y.J., Kim, S.J. and Parise, J.B. Microporous Mesoporous Mat., 34, 255-271 (2000) Barrer, R.M., Baynham, J.W., Bultitude, F.W. and Meier, W.M.J. Chem. Soc., 195-208 (1959) Ghobarkar, H. and Schaef, O. Cryst. Res. Technol., 32, 653-657 (1997) Ke, Y.X., He, G.F., Li, J.M., Zhang, Y.G. and Lu, S.M. New J. Chem., 25, 1627-1630 (2001)
332
TOL
Framework Type Data
P3ml
! )__y framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, P-3ml, a - 12.3/k, c - 30.9/k
Coordination sequences and vertex symbols: T1(12,1 ) T2(12,1 ) T3(12,1 ) T4(12,1 ) T5(12,1 ) T6(6,.2. ) T7(6,.2. )
4 4 4 4 4 4 4
10 10 10 10 10 10 10
20 20 20 20 20 20 20
34 34 34 34 34 34 34
54 53 54 53 52 54 54
78 76 78 76 74 78 78
104 103 104 103 102 104 104
134 135 134 135 136 134 134
168 170 168 170 172 168 168
210 209 210 208 209 210 210
Secondary building units"
4or6
Framework description:
C A C A C B C B C A C B sequence of 6-rings
Composite building units: can
los
Materials with this framework type: *Tounkite-like mineral ~)
lio
256 252 256 250 250 256 256
302 300 302 299 299 302 302
4.4-6.6.6.6 4.6.4.6.6.6 4.6-4.6.6.6 4.6.4.6.6.6 4.6.4.6-6.6 4.4.6.6.6-6 4.4.6.6.6-6
333
Tounkite-like mineral
Type Material Data
Crystal chemical data:
INa3~,Ca,5 94Ko96C18(504)~ 3(503)0.71 [AI3~Si360~44]-TOL trigonal, P3, a = 12.757A, c - 32.211A (~
Framework density:
15.9 T/1000A 3
Channels:
apertures formed by 6-rings only
TOL
References: (1) Rozenberg, K.A., Sapozhnikov, A.N., Rastsvetaeva, R.K., Bolotina, N.B. and Kashaev, A.A. Crystallogr. Reports, 4, 635-642 (2004)
334
TON
Framework Type Data
Cmcm
~
y
X
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 14.l/k, b - 17.8/k, c - 5.3A
Coordination sequences and vertex symbols: 4 T 2(8,m) 4 T 3(4,m2m) 4 T 4 (4,m2m) 4
T 1(8,m)
12 12 12 12
Secondary building units:
24 23 22 22
40 43 41 39
61 66 68 66
96 91 97 95
133 128 118 130
163 169 166 158
204 214 224 208
52.6~'6"6~'6-62 5.5.5.5.6.102 5-5.5.5.62.102 5-5"5"5"6~'*
262 258 258 270
5-1
Composite building units: jbw
mtt
bik
Materials with this framework type" *Theta-l<~3) ISI_I ~4~ KZ_2 ~5)
NU_10 (6) ZSM_22 ~7'8~
ton
335
Theta-1
Crystal chemical data"
Type Material Data
INa. (H20)41 [AlnSi24_nO48]-TON, n < 2 orthorhombic, Cmc2~, a - 13.859A, b - 17.420A, c -
Framework density:
19.7 T/1000,~ 3
Channels:
[001 ] 10 4.6 x 5.7*
TON 5.038A (8)
1 O-ring viewed along [001 ]
References: (1) Barri, S.A.I., Smith, G.W., White, D. and Young, D. Nature, 312, 533-534 (1984) (2) Highcock, R.M., Smith, G.W. and Wood, D. Acta Crystallogr., C41, 1391-1394 (1985) (3) Papiz, Z., Andrews, S.J., Damas, A.M., Harding, M.M. and Highcock, R.M. Acta Crystallogr., C46, 172173 (1990) (4) Kozo, T. and Noboru, K. E. Patent A-170,003 (1986) (5) Parker, L.M. and Bibby, D.M. Zeolites, 3, 8-11 (1983) (6) Araya, A. and Lowe, B.M. Zeolites, 4, 280-286 (1984) (7) Kokotailo, G.T., Schlenker, J.L., Dwyer, F.G. and Valyocsik, E.W. Zeolites, 5, 349-351 (1985) (8) Marler, B. Zeolites, 7, 393-397 (1987)
336
TSC
m
Framework Type Data
i
.... :l.......~........
J
Fm3m
'\
framework viewed along [001] o
Idealized cell data:
cubic, F m 3 m , a - 30.7A
Coordination sequences and vertex symbols: T 1(192,1) 4 9 16 25 37 53 T 2 (192,1)
4
9
Secondary building units:
17
28
41
56
74 73
99 93
125 117
4.4.4.6.6.8 4.4.4-8.6.8
151 146
8-8 or 8 or 6-6 or 6 or 4-2 or 4
Composite building units: d6r
d8r
Materials with this framework type: *Tsch6rtnerite(1)
sod
lta
337
Tsch6rtnerite
Type Material Data
Crystal chemical data"
ICa64(K2,Ca,Sr,Ba)48Cu48 (HzO)x (OH)1281 [A1,92Si192Ov68]-TSC cubic, Fm-3m, a - 31.62A ~)
F r a m e w o r k density:
12.1 T/1000/~ 3
Channels"
< 1 0 0 > 8 4.2 x 4.2***
8-ring viewed along <100>
~
< 1 1 0 > 8 3.1 x 5.6***
8-ring viewed along <110>
References:
(1) Effenberger, H., Giester, G., Krause, W. and Bernhardt, H.J. Am. Mineral., 83, 607-617 (1998)
TSC
338
TUN
Framework Type Data
C21m
V
X
Z f r a m e w o r k viewed along [01 O]
Idealized cell data:
monoclinic, C 2 / m , a - 27.8/k, b - 20.0/k, c - 19.6A, 3 - 93-2°
Coordination sequences and vertex symbols: see Appendix A for a list of the coordination sequences and vertex symbols for the 24 T-atoms
Secondary building units:
5-1
Composite building units: mor
mtt
Materials w i t h this framework type: • TNU_9 ~1~
cas
lau
stf
339
TNU-9
TUN
Type Material Data
Crystal chemical data:
IHJ [A19.3Si,82.70384]-TUN monoclinic, C2/m a - 28.2219 A, b - 20.0123 A, c - 19.4926 A, ~ - 92.33 ° ~
Framework density:
17.5 T/1000.~ 3
Channels:
{[010] 10 5.6 x 5.5 +-+ [101 ] 10 5.4 x 5.5}*** (There are 2 different channels along [010]; the smaller is 5.1 x 5.5 A)
m
.+.
5.5
1O-ring viewed along [01 O]
/
m
1O-ring viewed along [ 101 ]
References: (1)
Gramm, F., Baerlocher, Ch., McCusker, L.B., Warrender, S.J., Wright, P.A., Han, B., Hong, S.B., Liu, Z., Ohsuna, T. and Terasaki, O. Nature, 444, 79-81 (2006)
340
UEI
Framework Type Data
From2
F I
z
framework viewed along [010]
Idealized cell data:
orthorhombic, Fmm2, a - 19.5 A, b - 9.4A, c - 15.1/k
Coordination sequences and vertex symbols: T~(16,1) T 2(16,1) T 3(16,1)
4 4 4
10 9 10
Secondary building units:
20 19 21
35 35 36
80 77 76
6 or 4-2 or 4
Composite building units: dcc double crankshaft chain
Materials with this framework type" • Mu_18 (l)
56 55 53
105 102 108
135 135 142
174 173 173
217 214 210
259 259 259
306 307 310
4-62.4.83.6.82 4.4.4.6.8.83 4.6.4.82.6.8
341
Mu-18
UEI
Type Material Data
Crystal chemical data"
I(CsHHN2)4 (H20)41 [Ga24P24096 (OH)j-UEI CsH,2N 2 = 1-methylpiperazine orthorhombic, Aea2, a - 18.035A, b - 10.S13A, c - 14.293A "~
Stability:
reversibly adsorbs water below 350°C ~j~
F r a m e w o r k density:
17.7 T/1000A 3
Channels:
{ [010] 8 3.5 x 4.6 +-+ [001] 8 2.5 x 3.6}**
~
8-ring viewed along [010]
i!
~.~
!'~~,
8-ring viewed along [001]
References:
(1) Josien, L., Simon, A., Gramlich, V. and Patarin, J. Chem. Mater., 13, 1305-1311 (2001)
342
UFI
Framework Type Data
E
~
141mmm
iiiiiii...i.~17: .... '¸
I Z
m
framework viewed along [100]
Idealized cell data:
tetragonal, I 4 / m m m , a - 12.1A, c - 28.6A
Coordination sequences and vertex symbols: T 1 (16,.m.)
T 2(32,1) T 3(16,.m.)
4 4 4
9 10 10
Secondary building units:
18 19 19
33 31 30
51 46 50
71 64 70
97 91 93
8
Composite building units: d4r
rth
Materials with this f r a m e w o r k type: • UZM_5 (1)
lta
124 123 124
153 156 155
195 194 196
241 231 230
283 271 280
4.6.4.6.4.8 4.4.5-6.5.8 4.6.4.6.5-8
343
UZM-5
Type Material Data
U FI
Crystal chemical data"
IK81 [A18Si560,zs]-UFI tetragonal, I4/mmm, a - 12.1507~,, c - 28.172A ~
Framework density"
15.4 T/1000A 3
Channels:
<100> 8 3.6 x 4.4** ~ [001] 8 3.2 x 3.2 (cage) (i.e. ends in a cage with this window to the cage)
4.4
~i
4.4
i
8-ring viewed along [100]
References: (1)
Blackwell, C.S., Broach, R.W., Gatter, M.G., Holmgren, J.S., Jan, D.-Y., Lewis, G.J., Mezza, B.J., Mezza, T.M., Miller, M.A., Moscoso, J.G., Patton, R.L., Rohde, L.M., Schoonover, M.W., Sinkler, W., Wilson, B.A. and Wilson, S.T. Angew. Chem., Int. Ed., 42, 1737-1740 (2003)
344
UOZ
P41nnc
Framework Type Data
X
framework viewed along [01 O]
Idealized cell data:
tetragonal, P4/nnc (origin choice 2), a - 8.6/k, c - 27.5A
Coordination sequences and vertex symbols: T 1 (16,1)
T 2(16,1) T 3 (4, 4) T 4(4,222)
4 4 4 4
9 9 12 12
Secondary building units: Composite building units: d4r
19 19 18 18
34 35 28 26
4-1
lau
O Materials with this framework type: * IM- 10 °~
49 51 52 52
69 69 82 80
100 97 100 88
133 131 120 110
162 164 162 162
195 197 208 214
238 236 244 244
288 287 274 268
4.6.4.6.4.6 4-6.4.6.4.6 6-6.6.6.6.6 6.6.62-62.128.128
345
IM-IO
Type Material Data
UOZ
Crystal chemical data:
I(CI:N:H~o): F41 [Ge40Oso]-UOZ C12N2H3o = hexamethonium = (1,6-bis(trimethylamino)hexane) tetragonal, P-4n2, a - 9.1596/~,, c - 28.5614/~, ~)
Framework density:
16.7 T/1000A 3
Channels:
apertures formed by 6-rings only
References: (1) Mathieu, Y., Paillaud, J.-L., Caullet, P. and Bats, N. MicroporousMesoporous Mat., 75, 13-22 (2004)
346
USI
Framework Type Data
C21m
....
i
.....
U
y
x
frameworkviewedalong[001] Idealized cell data:
monoclinic,
C2/m, a -
21.l/k, b - 13.0A, c - 9.7/k, 3 - 108.4°
Coordination sequences and vertex symbols: T 1 (8,1) T 2(8,1)
4 4 4 4 4
T 3 (8,1)
T 4(8,1) T 5(8,1)
10 9 9 10 9
Secondary building units:
17 15 17 19 18
27 26 26 32 29
46 43 41 47 44
70 61 65 60 68
94 86 85 84 92
112 114 108 122 116
4-1
Composite building units:
dzc doublezigzag chain
mei ~
Materials with this framework type: • IM_6 ~
bog ~ ~
134 139 145 153 144
181 174 181 177 173
230 217 213 209 214
259 260 252 255 267
4.62.4"62" 10" 122 4-63.4.63.4.122 4.4.4-6-6.62 4-4.63.10.63.10 4.4"4"6"6"6
347
IM-6
USI
Type Material Data
Crystal chemical data:
I(CsH,3N2)2 (H30)21 [Co4Ga6P,oO4o]-USI CsH~3N2 - 1-methylpiperazinium triclinic, P]-, a - 9.848A, b - 12.470A, c - 12.603A oL- 63.47 °, ~3- 74.56 °, 7 - 76.03 °(~
Framework density:
15.1 T/1000A 3
Channels:
[100] 12 6.1 x 6.2 * ~
[001] 10 3.9 x 6.4* ..
12-ring viewed along [100]
1O-ring viewed along [001 ]
References:
(1) Josien, L., Simon Masseron, A., Gramlich, V., Patarin, J. and Rouleau, L. Chem. Eur. Journal, 9, 856-861 (2003)
348
UTL
C21m
Framework Type Data
X
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 29.0/k, b - 14.O/k, c - 12.4/k, 3 - 104.9°
Coordination sequences and vertex symbols: see Appendix A for a list of the coordination sequences and vertex symbols for the 12 T-atoms
Secondary building units:
see C o m p e n d i u m
Composite building units: d4r
cas
Materials with this framework type: • IM_12 ~ ITQ_15 ~2~
fer
non
ton
349
IM-12
Type Material Data
Crystal chemical data:
UTL
[Ge 13.8Si62.20152]-UTL monoclinic, C2/m a - 29.8004A, b - 13.9926A, c - 12.3926A, 3 - 105.185°~'~
F r a m e w o r k density:
15.2 T/1000.,~ 3
Channels:
[001 ] 14 7.1 x 9.5" +--+ [010] 12 5.5 x 8.5"
14-ring viewed along [001]
12-ring viewed along [01 O]
References: (1) Paillaud, J.-L., Harbuzaru, B., Patarin, J. and Bats, N. Science, 304, 990-992 (2004) (2) Corma, A., DSaz-Cabafias, M.J., Rey, F., Nicolopoulus, S. and Boulahya, K. Chem. Commun., 1356-1357 (2004)
350 m
VET
Framework Type Data
P4
Y
~
Y
x
framework viewed along [001] (upper right: projection down [001]) m
Idealized cell data:
o
o
tetragonal, P 4 , a - 13.0A, c - 4.9A
Coordination sequences and vertex symbols: T 1(4,1) T2(4,1) T 3(4,1) T 4(4,1) T5(1,4 )
4 4 4 4 4
12 12 12 12 12
Secondary building units"
24 26 24 23 28
39 41 41 43 38
93 94 95 94 98
see Compendium
Composite building units: cas
Materials with this framework type: • VPi_8 (1)
61 65 65 68 60
133 130 128 125 152
179 169 169 172 182
209 218 218 226 200
246 269 270 269 246
5.5.5.62.5-7 5.5.5-6.7.126 5.6.5.6-5.62 5.6.5.6-52.6 5.5.5.5.82.82
351
VPI-8
Type Material Data
Crystal chemical data:
[SilTO34]-VET tetragonal, P 4 , a - 13.045A, c - 5.034A ~)
Framework density:
19.8 T/1000A 3
Channels:
[001] 12 5.9 x 5.9*
VET
12-ring viewed along [001]
References: (1) Freyhardt, C.C., Lobo, R.F., Khodabandeh, S., Lewis, J.E., Tsapatsis, M., Yoshikawa, M., Camblor, M.A., Pan, M., Helmkamp, M.M., Zones, S.I. and Davis, M.E.J. Am. Chem. Soc., 118, 7299-7310 (1996)
352
VFI
P 6 flmcm
Framework Type Data
~"'<~:.................2 5 2 2 2 2 L 2 ; , 2 2 > , ~ .
// ...:i
~
y
X
framework viewed along [001] (upper right: projection down [001]) Idealized cell data:
hexagonal,
P63/mcm, a - 18.3/k, c - 8.6/k
Coordination sequences and vertex symbols: T~(24,1) T 2(12,m)
4 4
11 10
Secondary building units: Composite building units" dnc
20 18
31 30
44 44
61 60
82 80
108 106
18 or 6 or 4-2
aft
bog
double narsarsukite chain
Materials with this framework type: • VPi_5 (v3) A1PO_54 (2~ C o V P I _ 5 (4~ F A P O _ H 1 (5)
H1 (6~ M C M _ 9 (7~ T i V P I - 5 (8~
139 135
174 168
4..62"6"63"62"63 4-63-4-63.6.64
353
VPI-5
Crystal chemical data:
Type Material Data
VFI
1(H2O)421[A1,8P,8072]-VFI hexagonal, P63, a - 18.975A, c - 8.104A (3~
Framework density:
14.2 T/1000A 3
Channels:
[001] 18 12.7 x 12.7"
18-ring viewed along [001]
References: (1) Davis, M.E., Saldarriaga, C., Mantes, C., Garces, J. and Crowder, C. Nature, 331,698-699 (1988) (2) Richardson Jr., J.W., Smith, J.V. and Pluth, J.J.J. Phys. Chem., 93, 8212-8219 (1989) (3) McCusker, L.B., Baerlocher, Ch., Jahn, E. and Btilow, M. Zeolites, 11,308-313 (1991) (4) Singh, P.S., Shaikh, R.A., Bandyopadhyay, R. and Rao, B.S. Chem. Commun., 2255-2256 (1995) (5) Prasad, S. and Yang, T.C. Catalysis Letters, 28, 269-275 (1994) (6) d'Yvoire, F. Bull. Soc. Chim. France, 1762-1776 (1961) (7) Derouane, E.G., Maistreiau, L., Gabelica, Z., Tuel, A., Nagy, J.B. and van Ballmoos, R. Appl. Catal., 51, L13-L20 (1989) (8) Tusar, N.N., Logar, N.Z., Arcon, I., ThibaultStarzyk, F. and Kaucic, V. Croatica Chemica Acta, 74, 837849 (2001)
354
VNI
P4Jncm
Framework Type Data
z
framework viewedalong [110] Idealized cell data:
tetragonal,
P42/ncm (origin
choice 2), a - 10.0A, c - 34.1/k
Coordination sequences and vertex symbols: T 1 (16,1) T 2 (8,m) T 3(8,m) T 4(8,m) T 5(8,m) T 6(8,m) T 7 (4,2mm)
4 4 4 4 4 4 4
11 11 9 9 9 10 10
Secondary building units:
23 19 20 20 21 18 18
39 39 37 37 41 39 36 see
63 59 61 62 59 65 64
Compendium
Composite building units: l:sv
Materials with this framework type" • VPI_9 <~)
93 89 92 87 85 83 82
126 130 117 119 133 119 118
170 166 152 158 155 169 176
210 207 201 195 195 218 202
255 274 246 248 261 236 264
4.8-5.82.52.82 4.52.5.8.5.8 3"4"8"82"8"82
3.4.82" 83"82"83 3.4.8.83.8.83 3"83"5"52"5"52 3.82"5"5"5"5
355
Type Material Data
VPI-9
VNI
Crystal chemical data:
IRb44K~ (H20)J [Zn24Si960240]-VNI tetragonal, P4~2~2, a - 9.884A, c - 73.650A ~ (Relationship to unit cell of Framework Type: a ' = a, b' = b, c ' = 2c)
Framework density:
16.7 T/1000A 3
Channels:
{<110> 8 3.1 x 4.0 +--+[001] 8 3.5 x .3.6}***
8-ring along <110>
8-ring viewed along [001]
2nd 8-ring along <110>
References: (1) McCusker, L.B., Grosse-Kunstleve, R.W., Baerlocher, Ch., Yoshikawa, M. and Davis, M.E. Microporous Materials, 6, 295-309 (1996)
356
VSV
14~lamd
Framework Type Data
Z
framework viewed along [100]
Idealized cell data"
tetragonal, I4~/amd, a - 7.2A., c - 41.8/k
Coordination sequences and vertex symbols: T 1(16,m) T 2(16,m)
4 4 T 3 (4,4m2) 4 m
9 11 8
Secondary building units:
21 21 20
42 40 48
VSV
Materials with this framework type" • VPi_7 ~1,2) Gaultite ~3~ V S V _ 7 # (4)
81 93 84
see Compendium
Composite building units: lov
61 61 56
123 122 120
159 151 160
198 195 212
246 251 240
3"4"82"94"82"94 4.52.5.8.5-8 3"3"94"94"94"94
357
VSV
Type Material Data
VPI-7
lNa26H6 (H~O)~l [Zn16Si560,44]-VSV
Crystal chemical data:
orthorhombic, Fdd2, a - 39.88A, b - 10.326A, c - 10.219A (2) (Relationship to unit cell of Framework Type: a ' - c, b ' - av/2, c ' - by/2 or, as vectors, a ' - c , b ' - b - a, c ' - a + b) F r a m e w o r k density:
17.1 T/1000A 3
Channels:
[01 1 ] 9 3.3 x 4.3* ~ [011] 9 2.9 x 4.2*+--+ [011] 8 2.1 x 2.7*
I
4.2 'i m
9-ring along [ O11 ]
9-ring along [011]
8-ring along [011 ]
8-ring viewed along [100]
References: (1) Annen, M.J., Davis, M.E., Higgins, J.B. and Schlenker, J.L. Chem. Commun., 1175-1176 (1991) (2) R6hrig, C., Gies, H. and Marler, B. Zeolites, 14, 498-503 (1994) (3) Ercit, T.S. and van Velthuizen, J. Can. Mineral., 32, 855-863 (1994) (4) R6hrig, C., Dierdorf, I. and Gies, H. J. Phys. Chem. Solids, 56, 1369-1376 (1995)
358
WEI
Cccm
Framework Type Data
C .........
}
U
Y
X
framework viewed along [001]
Idealized cell data:
orthorhombic, Cccm, a - 11.8/k, b - 10.3/k, c - 10.0A
Coordination sequences and vertex symbols: T, (16,1) T 2(4,222)
4 4
9 8
Secondary building units:
18 18
32 32 spiro-5
Composite building units: lov
VSV
Materials with this framework type: *Weinebeneite ~)
51 52
74 70
98 98
126 132
163 152
199 200
3-4.6.8.8.10 3.3.6.6.10.10
359
Weinebeneite Crystal chemical data"
Type Material Data
[Ca 4 (H20),61 [Be~2Pa 032 ( O H ) a ] - W E I m o n o c l i n i c , Cc a - 11.897A, b - 9.707A, c - 9.633A, ~ - 95.76 ° ~'~
Framework density:
18.1 T/1000A 3
Channels:
[001] 10 3.1 x 5.4* ~
[100] 8 3.3 x 5.0*
".,.\
1O-ring viewed along [001 ]
References: (1)
Walter, F. Eur. J. Mineral., 4, 1275-1283 (1992)
8-ring viewed along [100]
WEI
360
-WEN
Framework Type Data .~.~
•.... :
,
..~:~.,
.¢;J'~ j.,.
P62m
i:z.......................... ~:
/ ~ Y
framework viewed along [001]
Idealized cell data:
hexagonal, P-62m, a - 13.6A, c - 7.6A
Coordination sequences and vertex symbols" T, (12,1) T 2(6,m) T 3(2,-6)
4 4 3
9 9 9
Secondary building units: Composite building units" dsc
16 19 21
27 34 36
73 67 69
102 94 90
see Compendium
d6r
doublechainSaWtooth
Materials with this framework type: • Wenkite <~,2)
46 49 53
can
129 125 119
157 157 156
191 195 201
4.4.4.6-6-102 4.8.4.8.6-82 82"82"82
361
Wenkite
-WEN
Type Material Data
C r y s t a l chemical d a t a :
[Ba 4 (Ca,Na2) 3 H20 (SO4)3[ [A18Si~2039(OH)2]- -WEN hexagonal, P-62m, a - 13.511A, c - 7.462A (2)
F r a m e w o r k density:
17 T/1000A 3
Channels:
<100> 10 2.5 x 4.8** +--+ [001] 8 2.3 x 2.7*
Z% ¢
1O-ring viewed along <100>
References: (1) (2)
Wenk, H.-R. Z. Kristallogr., 137, 113-126 (1973) Merlino, S. Acta Crystallogr., B30, 1262-1266 (1974)
8-ring viewed along [001]
362
YUG
Framework Type Data
C21m
I
~
y
X
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 10.2/k, b - 13.8A, c - 6.8A, 3 - 111.5 °
Coordination sequences and vertex symbols: T, (8,1) T 2(8,1)
4 4
11 10
Secondary building units:
22 22
39 39
61 61
8or4
Materials with this framework type: -
*Yugawaralite Sr_Q ~4)
(1-3)
Yugawaralite, Hvalfj6rdur, Iceland ~5~
88 89
120 118
155 153
192 198
241 241
4.5.5-5.8.8 4.4.5.82.5.82
363
Type Material Data
Yugawaralite Crystal chemical data:
YUG
ICa (H O)J [A14Si~2032]-YUG monoclinic, Pc, a - 6.73/k, b - 13.95A, c - 10.03A, ~ - 111.5 °~2~ (Relationship to unit cell of Framework Type: a ' = c, b ' = b, c ' = a)
Framework density:
18.3 T/1000A 3
Channels:
[100] 8 2.8 x 3.6* ~ [001] 8 3.1 x 5.0*
8-ring viewed along [100]
8-ring viewed along [001]
References: (1) Kerr, I.S. and Williams, D.J.Z. Kristallogr., 125, 220-225 (1967) (2) Kerr, I.S. and Williams, D.J. Acta Crystallogr., B25, 1183-1190(1969) (3) Leimer, H.W. and Slaughter, M. Z. Kristallogr., 130, 88-111 (1969) (4) Hawkins, D.B. Mater. Res. Bull., 2, 951-958 (1967) (5) Kvick, A., Artioli, G. and Smith, J.V.Z. Kristallogr., 174, 265-281 (1986)
364
ZON
Framework Type Data
Pbcm
Z
framework viewed along [100]
Idealized cell data"
orthorhombic, P b c m , a - 6.9A, b - 14.9A, c - 17.2A,
Coordination sequences and vertex symbols: 4 4 4 4
T 1 (8,1)
T 2(8,1) T 3(8,1) T 4(8,1)
10 9 10 9
Secondary building units:
21 19 18 17
34 33 33 32
72 78 77 74
6-2 or 4-4- or 4
Composite building units: sti
Materials with this framework type: • ZAPO_M1 ~ GaPO_DAB_2 ~z3~ UiO_7 (4'5~
47 53 57 53
108 100 95 98
136 126 129 128
162 166 172 165
200 213 209 208
4.8.4.82.63.8 4.4.4.8.6.63 4.6.4"6-6"8 4-6.4.62.4.8
365
Type Material Data
ZAPO-M1
ZON
Crystal chemical data:
I(C4H,2N)sI [Zn8A124P32O,28]-ZON C4H~zN = tetramethylammonium orthorhombic, Pbca, a - 14.226.~, b - 15.117A, c - 17.557.A ~ (Relationship to unit cell of Framework Type: a ' = 2a, b'= b, c'= c)
Framework density:
17 T/1000A, 3
Channels:
[100] 8 2.5 x 5.1" ~ [010] 8 3.7 x 4.4*
8-ring viewed along [100]
8-ring viewed along [01 O]
References:
(1) Marler, B., Patarin, J. and Sierra, L. Microporous Materials, 5, 151-159 (1995) (2) Schott-Darie, C., Kessler, H., Soulard, M., Gramlich, V. and Benazzi, E. Stud. Surf. Sci. Catal., 84, 101108 (1994) (3) Meden, A., Grosse-Kunstleve, R.W., Baerlocher, Ch. and McCusker, L.B.Z. Kristallogr., 212, 801-807 (1997) (4) Akporiaye, D.E., Fjellvag, H., Halvorsen, E.N., Hustveit, J., Karlsson, A. and Lillerud, K.P. Chem. Commun., 601-602 (1996) (5) Akporiaye, D.E., Fjellvag, H., Halvorsen, E.N., Hustveit, J., Karlsson, A. and Lillerud, K.P.J. Phys. Chem., 100, ! 6641-16646 (1996)
367
APPENDIX A
CHA
8-ring viewed normal to [001]
GIS
8-ring viewed along [100]
8-ring viewed along [010]
368
IMF Coordination sequences and vertex symbols: T, (8,1) T~ (16,1) T 2(16,1) T 3(16,1) T 4(16,1) T 5(16,1) T 6(16,1) T 7(16,1) T 8(16,1) T 9(16,1) T~o(16,1) TI~ (16,1) T12(16,1) T,3(8,m..) T14(8,m..) T~5(8,m..) T~6(8,m..) TI7 (8,m..) T18(8,m..) T,9(8,m..) T~o(8,m..) T2, (8,m..) T22(8,m..) T23(8,m..) T~4(8,m..)
4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4
9 12 12 12 12 12 12 12 12 12 12 11 11 12 12 12 12 12 12 10 11 11 11 11 10
18 21 22 21 23 24 24 21 23 25 21 21 23 20 22 19 21 22 21 21 21 20 20 22 22
33 39 37 40 39 39 40 38 38 39 41 37 39 38 34 39 35 35 33 37 35 33 36 37 37
56 65 58 60 61 62 60 60 60 57 64 61 62 63 63 62 62 57 55 61 61 59 62 66 61
84 92 94 88 87 92 91 89 90 88 89 87 93 94 92 88 90 90 94 94 97 93 92 97 89
108 119 129 121 122 126 126 123 126 128 125 121 131 118 119 123 123 126 136 126 123 124 119 120 112
135 157 161 159 162 159 167 161 162 160 161 159 167 150 160 156 161 159 157 162 153 150 152 153 156
179 208 196 202 201 207 204 202 205 195 209 201 201 206 201 199 202 197 185 200 205 189 199 208 215
227 256 248 249 242 251 250 249 256 246 253 251 248 262 243 256 252 241 244 249 260 252 251 267 257
276 290 317 296 301 305 307 305 309 309 303 303 312 291 300 302 306 301 315 312 313 312 305 297 294
326 357 374 358 364 362 368 362 367 369 360 362 377 347 360 358 360 370 384 368 363 366 355 354 348
4.5.4.6.4.10 5-5.5-52-5.103 5.5.5-6-5.62 5.5-5.52.5-102 5.52.5.6.5.103 5.52.5.6.5.103 5.5.5.103.52.6 5.5.5.5-5.6 5.62.5.102.52.6 5.6.5-62.5.102 5.5.5-5.52.102 4-52-5.62.10.10 4.5.5-62.6.102 5-52-5-52-102.0 5.5-5.5-52.102 5.52.5-52.6-* 5.5.5.5.52-6 52-62.52.62.10.122 52.62.52-62.6.* 4-5.4.5-6.102 4.6.5.5.5.5 4-62.5.5.5.5 4-62.5-5.5.5 4.103.5.5.5.5 4.5.4.5.10-102
135 144 142 138 143 138 138 146 143 143 145 156 129 134 126 131
179 177 174 177 179 178 176 180 181 172 190 191 180 165 174 163
227 220 216 219 224 226 219 219 211 216 225 216 220 232 217 225
276 276 275 267 271 265 265 272 271 275 265 261 277 282 268 267
326 330 324 320 325 317 327 323 342 319 320 331 321 312 326 313
4.5.4.6.4.10 4.6.4-62-4.104 4.6-4-62.4.102 4.5.4.6.4.10 5.6.5.62.5.8 5.5.5.6.52.10 5.5-52.8-6-82 4-62.5.6.5.102 4.82.5.5.5.82 4.52.5.5.5.82 4.5.5-62.5.127 4.4.5.62.5-127 4.52.5.6.5.6 4.5~.6.62.6.62 4-52.6.62.6.62 4.52.5.6.5.6
IWW Coordination sequences and vertex symbols: T 1 (8,1)
T 2(8,1) T 3(8,1) T~(8,1) T 5(8,1) T 6(8,1) T 7(8,1) T 8(8,1) T 9(8,1) T,o(8,1) TI~ (8,1) T~2(8,1) T~(4,..m) T,4(4,..m) T,5(4,..m) T,6(4,..m)
4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4
9 9 9 9 12 12 12 11 11 11 11 10 11 11 11 11
18 18 19 18 21 18 20 18 24 20 21 20 20 20 22 20
33 33 35 34 36 33 36 33 38 35 34 34 29 29 28 31
56 55 55 56 53 55 55 53 52 54 56 52 50 48 50 46
84 84 80 79 76 77 75 78 77 75 76 78 82 85 80 79
108 114 110 104 106 105 106 116 108 107 106 110 104 111 110 105
369
MFI Coordination sequences and vertex symbols: Z l (8,1)
T 2(8,1) T 3(8,1) T 4 (8,1) T 5 (8,1) T 6(8,1) T 7(8,1) T~(8,1) T 9(8,1) Tlo(8,1) T,, (8,1) TI2 ( 8 , 1 )
4 4 4 4 4 4 4 4 4 4 4 4
12 12 12 12 12 12 12 12 11 11 12 12
22 22 23 21 24 22 24 21 23 22 22 23
41 39 37 36 38 40 38 37 39 36 38 38
61 64 62 61 63 61 56 63 62 61 59 59
88 91 91 90 93 88 90 90 93 93 92 89
125 117 120 122 123 124 132 121 119 120 125 126
159 158 157 159 157 156 164 155 153 154 159 161
198 209 206 196 206 197 193 201 204 200 202 196
250 247 250 251 247 253 241 253 254 255 250 246
5"5"5"102"52"6 5"5"5"52"5"103 5"5"5"52"5"103 5"5"5"52-5"6 5"5"5"62"5"103 5"5"5"5"52"103 5"62"52"62"10"10 5"5"5"5"5"6 4"5"5"62"5"103 4"5"5"62"5"102 5-5"5"6"5"62 5"62"5"102"52"62
146 137 128 147 144 139 138 142
185 175 177 187 176 188 181 166
225 218 228 215 220 244 214 204
42.6.5.5.5.5 5.5.5.5.6.102 4-5.4.5-6.102 4.102-52.62.52.62 4.5.5.62.5.62 4.104.4.104.4.104 4.62.4.62.4.62 5.62.5.62.5.62
117 122 123 121 119 117 113 123
151 154 153 152 152 149 144 152
188 191 186 185 188 185 183 188
4-4.4.82.8-8 4.4-4.82.8.8 4.4.4.82.8.8 4-4.4-82.8-8 4-4.4.82.8.8 4"4"4"6"8"8 4"4"4"6"8"8 4.4.4.82.8.8
MWW Coordination sequences and vertex symbols: T, (12,.m.) T 2 (12,.m.) T 3 (12,.m.) T 4 (12,..m) T 5 (12,..m) T 6 (4,3m) T 7 (4,3m) T 8 (4,3m)
4 4 4 4 4 4 4 4
10 12 10 11 11 10 10 12
20 22 21 18 22 20 16 22
32 35 40 32 32 34 30 31
52 51 62 52 53 54 49 52
76 81 78 78 79 87 77 74
lll 109 95 107 113 114
100 ll2
PAU Coordination sequences and vertex symbols" T, (96,1) T 2 (96,1)
T 3 (96,1) T 4(96,1) T 5(96,1) T 6 (96,1) T 7 (48,2) T 8 (48,2)
4 4 4 4 4 4 4 4
9 9 9 9 9 9 9 9
18 18 18 18 18 17 17 18
31 32 32 32 31 29 30 32
47 49 49 48 47 45 47 49
68 70 69 67 68 65 66 69
91 95 94 92 92 89 88 95
370
TUN Coordination sequences and vertex symbols: T 1 (8,1) T 2(8,1) T 3(8,1) T 4(8,1) T 5(8,1) T 6(8,1) T 7(8,1) T 8(8,1) T 9(8,1) T1o(8,1) T,~(8,1) T12(8,1) T~3(8,1) T14(8,1) T15(8,1) T16(8,1) T17(8,1) T18(8,1) T~9(8,1) T2o(8,1) T21(8,1) T22(8,1) T23(8,1) T24(8,1)
4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4
12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 11 11 11 11 11 11 11 11 10
22 20 21 22 24 23 21 22 22 20 19 20 24 22 21 21 24 22 21 21 23 21 23 22
34 37 39 37 38 38 37 36 33 36 37 41 38 37 36 34 39 36 35 36 37 38 38 39
59 60 62 58 59 59 56 55 55 60 62 61 61 57 66 57 58 55 58 60 60 60 56 62
88 88 84 89 88 83 90 87 88 87 87 84 91 86 92 90 86 87 86 87 88 86 87 83
116 117 115 124 119 118 121 129 124 113 115 119 121 121 112 123 122 123 117 113 121 116 122 109
157 147 155 158 156 159 154 158 153 154 153 146 154 160 151 150 158 159 150 150 155 152 152 156
198 192 201 190 195 197 198 186 187 196 194 197 194 194 202 187 190 188 198 199 200 197 193 201
235 246 242 234 240 239 234 233 238 244 243 250 244 236 250 238 237 237 241 244 235 247 241 241
285 299 284 298 292 285 292 291 292 289 291 285 297 288 283 296 301 295 288 289 292 291 296 293
347 347 338 363 353 346 350 355 350 336 345 338 346 351 334 361 359 353 352 344 352 339 351 348
5.5.5.5.52-10 5.5.5-52.5.6 5-5.5.5.52.103 5.5.5.6-5-62 5.5-5-103.52.6 5.6.5.102-52.62 5.5.5.5-5.6 52.62.52.62-10.* 5.62.5.122-52-6 5-5.5.52-5-10 5-5-5.5.5~.6 5-52.5.52.102.* 5.52-5.6.5.103 5.5.5-6.52.10 5.5.5-52.5.103 4.52.5-62-6.122 4.5.5.62.6.102 4.62-5-5.5-82 4.5.5.5.5.82 4.52.5.6-10.10 4.62-5-5.5.10 4.52.5-5.5.10 4.5.5-6.10-10 4.5.4.5.10.102
129 130 144 139 140 144 140 147 141 144 145 145
171 166 181 183 176 173 170 176 178 172 178 179
217 220 213 215 208 208 212 215 211 208 223 199
264 263 246 251 255 259 255 249 242 256 252 250
308 311 306 298 310 311 315 300 298 287 284 315
4.5.4.5.4.12 4.5.4.5.4.12 5"5"5"6"52"12 5"5"5"52"5"12 5-5-5"5-5~'6 5"5"5"62"5"12 5"5"5"52"5"12 5"5"5"5"146"* 5"52"5"52"14~'* 5-5.5.5.5.52 5-52.5.5~.14~.* 5.5-5.5-5.62
UTL Coordination sequences and vertex symbols: T~ (8,1) T 2(8,1) T 3 (8,1)
T 4(8,1) T 5(8,1) T 6(8,1) T 7(8,1) T 8(4,m) T 9(4,m) T~o(4,m) T~(4,m) Tl2(4,m)
4 4 4 4 4 4 4 4 4 4 4 4
9 9 12 12 12 12 12 12 12 12 12 12
18 18 22 21 21 22 20 24 20 20 20 22
32 32 34 34 34 33 31 34 34 28 36 30
53 53 49 49 48 52 53 46 48 51 50 49
80 79 73 71 73 76 76 71 68 73 67 73
104 105 102 102 106 107 104 107 107 100 102 106
371
APPENDIX B Rules for F r a m e w o r k Type A s s i g n m e n t The following is a set of rules to be applied by the Structure Commission of the IZA in assigning a three-letter code to a new framework type.
The materials of interest are generally defined as open
4-connected 3D nets which have the general (approximate) composition
AB2, where
A is a
tetrahedrally connected atom and B is any 2-connected atom, which may or may not be shared, between two neighboring A atoms. Inclusion of other microporous materials is left to the discretion of the IZA Structure Commission, depending on the interest of the molecular sieve science community at large.
RULES (i)
The IZA Structure Commission is the only body that can coordinate the assignment of a code to such frameworks.
The framework types are idealized, with no reference to actual materials,
symmetry, composition, etc. and, therefore, ONLY refer to the connectivity. (ii) The code for a 4-connected 3D framework type shall consist of three capital letters.
Other
frameworks of interest shall be indicated by a (-) in front of the code. (iii) The three letters of the code shall be mnemonic and must refer to an actual material (i.e. the type material). These materials are chosen to be:
- mineral names (rules of the International Mineralogical Association followed). - commonly accepted synthetic material types. - in the absence of the above, the workers who first determined the structure have priority in assigning the name. (iv) No mnemonic code can be assigned without the structure being determined with the following exception: For "polytypic" materials, codes can be assigned as useful. Such codes shall be marked with an asterisk. (v) Codes of framework types which turn out to be in error are discredited. Later use of the code is not permitted. (vi) For all cases where a decision of the Structure Commission is required, a two thirds majority vote of the full commission shall be required.
Such votes are taken verbally at a meeting of the
Structure Commission or are done in writing on the initiative of the Chairperson and Cochairperson. All evidence substantiating a new framework type must accompany the ballot. The members are obliged to respond to this request within one month and the Chairperson and Cochairperson will make all possible effort to solicit replies from all members.
373
APPENDIX C Secondary Building Units and their Symbols a
a
3 (5)
4 (71)
6
8
12
(51)
(24)
(5)
Spiro-5 (2)
4-4 (4)
6-6 (10)
8-8 (3)
4-1 (13)
4-[1,1]
1-4-1 (7)
4-2 (23)
4=1 (3)
4-4(4)
4-4=1
5-1 (25)
5-[1,1] (2)
1-5-1 (4)
6-2 (16)
2-6-2 (16)
6"1
(5)
Number in parenthesis = frequency of occurrence
(3)
(4)
5-3 (10)
375 APPENDIX D
Selected Composite Building Units ordered by number of T-atoms in the unit Each unit is identified with a lower-case three-character code in italics and the number of T-atoms in the unit. Framework types containing the unit are listed below each unit. Iov
5T
nat
6T
vsv
6T
mei
7T
y LOV, NAB, OBW, OSO, RSN, VSV, WEI
EDI, NAT, THO
LOV, NAB, OBW, -RON, RSN, VNI, VSV, WEI
AFN, CGF, MEI, USI (see also d4r- 8T, sti - 8T and bph - 147")
d4r
8T
ACO, AFY, AST, ASV, BEC,-CLO, DFO, ISV, ITH, ITW, IWR, IWV, IWW, LTA, UFI, UOZ, UTL
mor
8T
*BEA, BEC, DAC, EON, EPI, IMF, ISV, IWW, MEL, MFI, MOR, MSE, RWR, TUN
sti
8T
bea
AFR, DFO, OWE, SAO, SBE, SBS, SBT, SFO, STI, ZON
lOT
*BEA, CON, IFR, MSE, STT
(see also d4r- 8T)
(see also fer- 137") bre
lOT
jbw
lOT
mtt
11T
aft
12T
( BOG, BRE, CON, HEU, IWR, IWW, RRO, STI, TER
JBW, MTT, MTW, SFE, SFN, SSY, TON
CFI, IMF, MFS, MTT, SFE, SSY, SZR, TON, TUN (see also non - 15T)
AEL, AET, AFI, AFO, ATV, DON, SFH, VFI (see also b p h - 14T)
376
afs
12T
ats
AFS, BPH
12T
ATS, IMF, OSI
(see also aww- 167)
d6r
12T
lau
12T
AEI, AFT, AFX, CHA, EAB, EMT, ERI, FAU, GME, KFI, LEV, LTL, LTN, MOZ, MSO, MWW, OFF, SAS, SAT, SAV, SBS, SBT, SZR, TSC,-WEN
ASV, ATO, BCT, CON, DFO, EZT, IFR, ITH, IWR, IWW, LAU, MSO, OSI,-RON, SAO, TUN, UOZ
bik
fer
13T
14T
12T
cas
12T
AEL, AET, AFI, AFO, BOG, CAS, CFI, EUO, AHT, ATV, BOG, GON, IHW, IWV, MFI, CGF, DFO, LAU, TER, MTW, NES, NSI, SFF, USI, VFI SFH, SFN, STF, STT, TER, TUN, UTL, VET rth
12T
ITE, RTH, UFI
stf
12T
SFF, STF, TUN, IMF, IWW
(see also mtw - 14 T) 13T
BIK, CAS, MTT, MTW, CDO, FER, IMF, MFS, NSI, SFE, TON UTL me/
bog
mfi
14T
abw
14T
ABW, ATT, JBW mtw
14T
bph
14T
AFS, BPH, EZT non
15T
q CON, DON, ITH, IWR, IWW, MEL, MFI, MWW, SFG
MEL, MFI, MTF
*BEA, BEC, GON, ISV, MSE, MTW, SFH, SFN
EUO, IHW, IWV, NES, NON, UTL
377
ton
15T
aww
16T
d8r
16T
~
CFI, IHW, IWV, MTT, NES, SFE, SSY, TON, UTL can
18T
AWW, SAO
AFG, CAN, ERI, FAR, FRA, GIU, LIO, LOS, LTL, LTN, MAR, MOZ, OFF, SAT, SBS, SBT, TOL, -WEN atn
24T
ATN, SBE
clo
MSO, SZR
gme
20T
pau
RTE, RUT
mtn
ATT, GIS, SIV
24T
sod
24T
AFT, AFX, EAB, EON, EMT, FAR, FAU, FRA, GME, MAZ, OFF GIU, LTA, LTN, MAR, SOD, TSC 32T
AWW, -CLO
g~
32T
KFI, MER, MOZ, PAU
cha
36T
AFT, CHA
16T
l
.~i#i~¸¸
MER, PAU, RHO, SBE, TSC 18T
mso
rte
20T
DDR, DOH, MEP, MTN
/os
30T
FRA, LIO, LOS, TOL
lio
42T
AFG, FAR, LIO, MAR, TOL
378
48T
aft
48T
Ita
48T
Itl
J LTL, MOZ
-CLO, KFI, LTA, LTN, PAU, RHO, TSC, UFI
AFT, AFX
Selected Chains
double zigzag chain
double crankshaft chain
double sawtooth chain
narsarsukite chain
double narsarsukite chain
dzc
dcc
dsc
nsc
dnc
JN¢
,!
ABW, ATN, ATS, CAN, JBW, OSI, SFE, SFH, SFN, SSY, USI
APC, ATT, AWO, DON, GIS, GME, MER, PHI, SIV, UEI
ATT, EON, LTL, MAZ, MOZ, OFF, OWE, SAO,WEN
AEL, AET, AFI, AFO, APD, ATV, DFT
AET, AHT, VFI
379 Composite Building Unit Nomenclature Comparison Atlas abw aft afs aft atn ats aww bea bog bph bre can cas cha clo d4r d6r d8r gis gme jbw lau lio los lov lta ltl mei mel mfi mor mso mtn
mtw nat non pau rte rth sod
stf sti
T-atoms 14 12 12 48 24 12 16 10 12 14 10 18
Compendium a {2 [4'56289]} { 1 [486482]} [4264]-c [4664] [4354] [4264]-b [4663] [4254] [4665]
12
[5462]
36 32 8 12 16 20 24 10 12 42 30 5 48 48 7 14 14 8 18 20 14 6 15 32 16 12 24 12 8
{3 [4126286]} { 1 [486882] } [46] [4662] {2 [4684] } {2 [496283] } [64] [4264]-a [466 ~7] [466 ~] {3 [4~26886]} {3 [4 ~886122]} [4 ~5264] [58] [54] [68]-b [5 ~2] [425462] [44] [4158] {3 [41286]} [445462] [4454] [4668] [4156] [446 l]
J.V. Smith b
kdq aft afs aft ocn oth aww wwt bog afo bru can eun cha rpa cub hpr opr gsm gme hes lau lio los sfi grc lil iet reel pen tes ber red mtw des non pau
tte cle toc huh sti
42628 2-b 6362 4242628~ 464643628683 486482 426262 444264 424 ~5261 4264-b 4663 4254 466362
5462 46466286
486882 46 4662 4882 444284-a
46436283 64 4264-a 4666666362 46666362 32 4~26886 4 ~24686122-b 436 ~ 415262 5454 54-a 6262-a 5 ~2 425462 44 4 ~545252 48448482 445462 4454 4668 4 ~525252 42426~
Occurence mm2
3
6-2m
8
mm2
2
6-2m
2
4/mmm mm2
2 2
4-2m
2
mm2 mmm
5 13
62m
3
mmm mm2 2/m
9 18
-32 82m 4 / m-3m 6/mmm 8/mmm
20 2 2 17
25 5
4-2m 6-2m 43m
3 7 7
4/mmm
17
62m 6-2m 42m 4 / m-3m
5 4 7
6/mmm
8 2
3ml
4
mm2
9
42m 42m
3 14
6/mmm
2
53m
4
mmm
8
42m
3
ram2 4/mmm mmm
6 4 2
4-2m 4 / m-3m ram2 mm2
3 10 4 10
no equivalents for bik (13T, 7 occurences),fer (13T 5 occurences), mtt (14T, 9 occurences), ton (15T, 9 occurences) or vsv (6T, 8 occurences)
" H. van Koningsveld, Compendium of Zeolite Framework Types. Building Schemes and Type Characteristics, Elsevier, Amsterdam, 2007 b J.V. Smith, Tetrahedralframeworks ofzeolites, clathrates and related materials, Landolt-B6rnstein, Vol. 14A, Springer, Berlin, 2000
381 APPENDIX
E
Channel System Dimensions o r d e r e d by largest ring
20-, 18- & 14-Ring Structures -CLO
Cloverite
<100> 20 4.0 x 13.2"** I <100> 8 3.8 x 3.8***
ETR
ECR-34
[001] 18 10.1" L _L [001] 8 2.5 x6.0**
VFI
VPI-5
[001] 18 12.7 x 12.7"
AET
A1PO-8
[001] 14 7.9 x 8.7*
CFI
CIT-5
[010] 14 7.2 x 7.5*
DON
UTD-1F
[010] 14 8.1 x 8.2*
OSO
OSB-1
[001] 14 5.4 x 7.3* / _1_ [001] 8 2.8 x 3.3**
SFH
SSZ-53
[001] 14 6.4 x 8.7*
SFN
SSZ-59
[001 ] 14 6.2 x 8.5"
UTL
IM-12
[001] 14 7.1 x 9.5* _1_ [010] 12 5.5 x 8.5*
12-Ring Structures AFI
A1PO-5
[001] 12 7.3 x 7.3*
AFR
SAPO-40
[001] 12 6.7 x 6.9* _1_ [010] 8 3.7 x 3.7*
AFS
MAPSO-46
[001 ] 12 7.0 x 7.0* L _L [001 ] 8 4.0 x 4.0**
AFY
CoAPO-50
[001] 126.1 x 6.1" L _L [001] 8 4.0 x 4.3"*
ASV
ASU-7
[001] 12 4.1x 4.1"
ATO
A1PO- 31
[001] 12 5.4 x 5.4*
ATS
MAPO-36
[001 ] 12 6.5 x 7.5"
*BEA
Beta polymorph A
<100> 12 6.6 x 6.7** A [001] 12 5.6 x 5.6*
BEC
FOS-5 (Beta pol. C)
[001] 12 6.3 x 7.5* _1_<100> 12 6.0 x 6.9**
BOG
Boggsite
[100] 12 7.0 x 7.0* _1_ [010] 10 5.5 x 5.8*
BPH
Beryllophosphate-H
[001] 12 6.3 x 6.3* A_ _L [001] 8 2.7 x 3.5**
CAN
Cancrinite
[001] 12 5.9 x 5.9*
CON
CIT-1
[001] 12 6.4 x 7.0* ± [100] 12 7.0 x 5.9* _1_ [010] 10 5.1 x 4.5*
CZP
Chiral ZnPO4
[001] 12 3.8 x 7.2* (highly distorted 12-ring)
DFO
DAF-1
{ [001 ] 12 7.3 x 7.3 _1_ A [001 ] 8 3.4 x 5.6 }*** _1_ {[001] 12 6.2 x 6.2 l A [001] 10 5.4 x 6.4}***
EMT
EMC-2
[001] 12 7.3 x 7.3* _1_ 2_ [001] 12 6.5 x 7.5**
382
12-Ring Structures (cont.) EON
ECR-1
{[100] 12 6.7 x 6.8* 2_ [010] 8 {[001] 3.4 x 4.9 _1_
[100] 8 2.9 x 2.9}*}** EZT
EMM-3
[ 100] 12 6.5 x 7.4"
FAU
Faujasite
<111> 12 7.4 x 7.4***
GME
Gmelinite
[001] 12 7.0 x 7.0* L _L [001] 8 3.6 x 3.9**
GON
GUS-1
[001] 12 5.4 x 6.8*
IFR
ITQ-4
[001 ] 12 6.2 x 7.2"
ISV
ITQ-7
<100> 12 6.1 x 6.5** ± [001] 12 5.9 x 6.6*
IWR
ITQ-24
[001] 12 5.8 x 6.8* I [110] 10 4.6 x 5.3* I [010] 10 4.6 x 5.3*
IWV
ITQ-27
{[001] 12 6.2 x 6.9 _1_ [011] 12 6.2 x 6.9}**
IWW
ITQ-22
[001] 12 6.0 x 6.7* I n[001] 10 4.9 x 4.9** _1_ [001] 8 3.3 x 4.6*
LTL
Linde Type L
[001] 12 7.1 x 7.1"
MAZ
Mazzite
[001] 12 7.4 x 7.4" I [001] 8 3.1 x 3.1"**
MEI
ZSM-18
[001] 12 6.9 x 6.9* 3_ _1_ [001] 7 3.2 x 3.5**
MOR
Mordenite
[001] 12 6.5 x 7.0* _L [001] 8 2.6 x 5.7***
MOZ
ZSM-10
{[001] 12 6.8 x 7.0 _1_n[001] 8 3.8 x 4.8}*** I [001] 12 6.8 x 6.8*
MSE
MCM-68
{ [001] 12 6.4 x 6.8 ± [100] 10 5.2 x 5.8 l [110] 10 5.2 x 5.2 }***
MTW
ZSM-12
[010] 12 5.6 x 6.0*
NPO
Nitridophosphate- 1
[100] 12 3.3 x 4.4*
OFF
Offretite
[001] 12 6.7 x 6.8* I _1_ [001] 8 3.6 x 4.9**
OSI
UiO-6
[001] 12 5.2 x 6.0*
-RON
Roggianite
[001 ] 12 4.3 x 4.3"
RWY
UCR-20
<111> 12 6.9 x 6.9***
SAO
STA-1
<100> 12 6.5 x 7.2** 2_ [001] 12 7.0 x 7.0*
SBE
UCSB-8Co
<100> 12 7.2 x 7.4** _1_ [001] 8 4.0 x 4.0*
SBS
UCSB-6GaCo
[001] 12 6.8 x 6.8* I I [001] 12 6.9 x 7.0**
SBT
UCSB- 10GaZn
[001] 12 6.4 x 7.4 * _1_1 [001] 12 7.3 x 7.8**
SFE
SSZ-48
[010] 12 5.4 x 7.6*
SFO
SSZ-51
[001] 12 6.9 x 7.1" ± [010] 8 3.1 x 3.9*
SOS
SU-16
{[100] 12 3.9 x 9.1 I [010] 8 3.3 x 3.3}**
SSY
SSZ-60
[001] 12 5.0 x 7.6*
383
12-Ring Structures (cont.) USI
IM-6
[100] 12 6.1 x 6.2 * ± [001] 10 3.9 x 6.4*
VET
VPI-8
[001] 12 5.9 x 5.9*
10-Ring Structures AEL
A1PO- 11
[001] 10 4.0 x 6.5*
AFO
A1PO-41
[001] 10 4.3 x 7.0*
AHT
A1PO-H2
[001 ] 10 3.3 x 6.8*
CGF
Co-Ga-Phosphate-5
{[100] 10 2.5 x 9.2* + 8 2.1 x 6.7*} 2_ [001] 8 2.4 x 4.8*
CGS
Co-Ga-Phosphate-6
{[001] 10 3.5 x 8.1 ± [100] 8 2.5 x4.6}***
DAC
Dachiardite
[010] 10 3.4 x 5.3* _1_ [001] 8 3.7 x 4.8*
EUO
EU-1
[100] 10 4.1 x 5.4* with large side pockets
FER
Ferrierite
[001] 10 4.2 x 5.4* _1_ [010] 8 3.5 x 4.8*
HEU
Heulandite
{[001] 10 3.1 x 7.5* + 8 3.6 x 4.6*} 2_ [100] 8 2.8x 4.7*
IMF
IM-5
{[001] 10 5.5 x 5.6 _1_ [100] 10 5.3 x 5.4}** 2_ {[010] 10 5.3 x 5.9} _1_ {[001] 10 4.8 x 5.4 _1_ [100] 10 5.1 x 5.3}**
ITH
ITQ-13
[001] 10 4.8 x 5.3* _1_ [010] 10 4.8 x 5.1" _1_ [100] 9 4.0 x 4.8*
LAU
Laumontite
[100] 10 4.0 x 5.3* (contracts upon dehydration)
MEL
ZSM-11
<100> 10 5.3 x 5.4***
MFI
ZSM-5
{[100] 10 5.1 x 5.5 _2_ [010] 10 5.3 x 5.6}***
MFS
ZSM-57
[100] 10 5.1 x 5.4* _1_ [010] 8 3.3 x 4.8*
MTT
ZSM-23
[001 ] 10 4.5 x 5.2"
MWW
MCM-22
_1_ [001] 104.0 x 5.5** 12_ [001] 104.1 x 5.1"*
NES
NU-87
[100] 10 4.8 x 5.7**
OBW
OSB-2
{<110> 10 5.0 x 5.0** _1_ ([001] 8 3.4 x 3.4* +
-PAR
Partheite
[001] 10 3.5 x 6.9*
PON
IST-1
[100] 10 5.0 x 5.3*
RRO
RUB-41
[ 100] 10 4.0 x 6.5" _1_ [001 ] 8 2.7 x 5.0*
SFF
SSZ-44
[001] 10 5.4 x 5.7*
SFG
SSZ-58
[001] 10 5.2 x 5.7* 2_ [100] 10 4.8 x 5.7*
STF
SSZ-35
[001] 10 5.4 x 5.7*
STI
Stilbite
[100] 10 4.7 x 5.0* 2_ [001] 8 2.7 x 5.6*
SZR
SUZ-4
{[001] 10 4.1 x 5.2 2_ [010] 8 3.2 x 4.8 _1_ [110] 8 3.0 x 4.8}***
<101> 8 2.8 x 4.0**) _1_ <100> 3.3 x 3.4**}***
384 10-Ring Structures (cont.)
TER
Terranovaite
[ 100] 10 5.0 x 5.0* I [001 ] 10 4.1 x 7.0*
TON
Theta- 1
[001] 10 4.6 x 5.7*
TUN
TNU-9
{[010] 10 5.6 x 5.5 _1_ [101 ] 10 5.4 x 5.5}***
WEI
Weinebeneite
[001] 10 3.1 x 5.4* _1_ [100] 8 3.3 x 5.0*
-WEN
Wenkite
<100> 10 2.5 x 4.8** _1_ [001] 8 2.3 x 2.7* 9-Ring Structures
-CHI
Chiavennite
[001] 9 3.9 x 4.3*
LOV
Lovdarite
[010] 9 3.2 x 4.5* _1_ [001] 9 3.0 x 4.2* _1_ [100] 8 3.6 x 3.7*
NAB
Nabesite
[110] 9 2.7 x 4.1" _t_ [ 1 10 ] 9 3.0 x 4.6*
NAT
Natrolite
<100> 8 2.6 x 3.9** _1_ [001] 9 2.5 x 4.1"
RSN
RUB-17
[100] 9 3.3 x 4.4* _1_ [001] 9 3.1 x 4.3* 2_ [010] 8 3.4 x 4.1"
STT
SSZ-23
[101] 9 3.7 x 5.3* _1_ [001] 7 2.4 x 3.5*
VSV
VPI-7
[01-1] 9 3.3 x 4.3* _1_ [011] 9 2.9 x 4.2* _L [011] 8 2.1 x 2.7* 8-Ring Structures
ABW
Li-A
[001] 8 3.4 x 3.8*
ACO
ACP-1
<100> 8 2.8 x 3.5** _1_ [001] 8 3.5 x 3.5*
AEI
A1PO- 18
{[100] 8 3.8 x 3.8 _1_ [110] 8 3.8 x 3.8 _1_ [001] 8 3.8 x 3.8}***
AEN
A1PO-EN3
[100] 8 3.1 x 4.3* _[_ [010] 8 2.7 x 5.0*
AFN
A1PO-14
[100] 81.9 x 4.6* 2_ [010] 8 2.1 x 4.9* _1_ [001] 8 3.3 x 4.0*
AFT
A1PO-52
_1_ [001] 8 3.2 x 3.8***
AFX
SAPO-56
3_ [001] 8 3.4 x 3.6***
ANA
Analcime
irregular channels formed by highly distorted 8-rings
APC
A1PO-C
[001] 8 3.4 x 3.7* 2_ [100] 8 2.0 x 4.7*
APD
A1PO-D
[010] 8 2.3 x 6.0* _1_ [201] 8 1.3 x 5.8*
ATN
MAPO-39
[001 ] 8 4.0 x 4.0*
ATT
A1PO- 12-TAMU
[100] 8 4.2 x 4.6* _1_ [010] 8 3.8 x 3,8*
ATV
A1PO-25
[001] 8 3.0 x 4.9*
AWO
A1PO-21
[ 100] 8 2.7 x 5.5"
AWW
A1PO-22
[001] 8 3.9 x 3.9*
BCT
Mg-BCTT
[001 ] 8 2.4 x 2.4"
385 8-Ring Structures (cont.) BIK
Bikitaite
[010] 8 2.8 × 3.7*
BRE
Brewsterite
[100] 8 2.3 x 5.0* _1_ [001] 8 2.8 x 4.1"
CAS
Cs Aluminosilicate
[001] 8 2.4 x 4.7*
CDO
CDS-1
[010] 8 3.1 x 4.7* 2_ [001] 8 2.5 x 4.2*
CHA
Chabazite
_1_ [001] 8 3.8 x 3.8***
DDR
Deca-dodecasil 3R
2_ [001] 8 3.6 x 4.4**
DFT
DAF-2
[001] 8 4.1 x 4.1" 2_ [100] 8 1.8 x 4.7* _1_ [010] 8 1.8 x 4.7*
EAB
TMA-E
_L [001] 8 3.7 x 5.1"*
EDI
Edingtonite
<110> 8 2.8 x 3.8"* 2_ [001] 8 2.0 x 3.1"
EPI
Epistilbite
{[0011 8 3.7 x 4.5 / [100] 8 3.6 x 3.6}**
ERI
Erionite
2_ [001] 8 3.6 x 5.1"**
ESV
ERS-7
[010] 8 3.5 x 4.7*
GIS
Gismondine
{[100] 8 3.1 x 4.5 2_ [010] 8 2.8 x 4.8}***
GOO
Goosecreekite
[100] 8 2.8 x 4.0* ± [010] 8 2.7 x 4.1" _1_ [001] 8 2.9 x 4.7*
IHW
ITQ-32
[100] 8 3.5 x 4.3**
ITE
ITQ-3
[010] 8 3.8 x 4.3* 2_ [001] 8 2.7 x 5.8*
ITW
ITQ-12
[100] 8 2.4 x 5.4* _1_ [001] 8 3.9 x 4.2*
JBW
Na-J
[001] 8 3.7 x 4.8*
KFI
ZK-5
<100> 8 3.9 x 3.9*** [ <100> 8 3.9 x 3.9***
LEV
Levyne
± [001] 8 3.6 x 4.8**
LTA
Linde Type A
<100> 8 4.1 x 4.1"**
MER
Merlinoite
[100] 8 3.1 x 3.5* 2_ [010] 8 2.7 x 3.6* _1_ [001] {8 3.4 x 5.1" + 8 3.3 x 3.3*}
MON
Montesommaite
[100] 8 3.2 x 4.4* _1_ [001] 8 3.6 x 3.6*
MTF
MCM-35
[001] 8 3.6 x 3.9*
NSI
Nu-6(2)
[010] 8 2.6 x 4.5* [ [010] 8 2.4 x 4.8*
OWE
UIO-28
[010] 8 3.5 x 4.0* _1_ [001] 8 3.2 x 4.8*
PAU
Paulingite
<100> 8 3.6 x 3.6*** I <100> 8 3.6 x 3.6***
PHI
Phillipsite
[100] 8 3.8 x 3.8* 2_ [010] 8 3.0 x 4.3* I [001] 8 3.2 x 3.3*
RHO
Rho
<100> 8 3.6 x 3.6*** [ <100> 8 3.6 x 3.6***
RTE
RUB-3
[001] 8 3.7 x 4.4*
RTH
RUB-13
[100] 8 3.8 x 4.1" 2_ [001] 8 2.5 x 5.6*
386 8-Ring Structures (cont.) RWR
RUB-24
[100] 8 2.8 x 5.0" I [010] 8 2.8 x 5.0*
SAS
STA-6
[001] 8 4.2 x 4.2*
SAT
STA-2
_1_ [001] 8 3.0 x 5.5***
SAV
Mg-STA-7
<100> 8 3.8 x 3.8** 2_ [001] 8 3.9 x 3.9*
SIV
SIZ-7
{[100] 8 (3.5 x 3.9 + 8 3.7 x 3.8 _1_ [110] 8 3.7 x 3.8 _1_ [001] 8 3.8 x 3.9} ***
THO
Thomsonite
[100] 8 2.3 x 3.9* _1_ [010] 8 2.2 x 4.0* _1_ [001] 8 2.2 x 3.0*
TSC
Tsch6rtnerite
<100> 8 4.2 x 4.2*** 3_ <110> 8 3.1 x 5.6***
UEI
Mu-18
{[010] 8 3.5 x 4.6 _1_ [001] 8 2.5 x 3.6}**
UFI
UZM-5
<100> 8 3.6 x 4.4** _1_ [001] 8 3.2 x 3.2(cage) i.e. ends in a cage
VNI
VPI-9
{<110> 8 3.1 x 4.0 _1_ [001] 8 3.5 x .3.6}***
YUG
Yugawaralite
[100] 8 2.8 x 3.6* _1_ [001] 8 3.1 x 5.0*
ZON
ZAPO-M1
[100] 8 2.5 x 5.1" _1_ [010] 8 3.7 x 4.4*
387
APPENDIX F Topological Densities
Code ABW ACO AEI AEL AEN AET AFG AFI AFN AFO AFR AFS AFT AFX AFY AHT ANA APC APD AST ASV ATN ATO ATS ATT ATV AWO AWW BCT
*BEA BEC
BIK BOG BPH BRE CAN CAS CDO CFI CGF CGS CHA
TD10a 833 787 689 904 956 824 816 828 777 907 687 656 685 689 585 853 933 814 888 742 787 833 894 752 768 960 828 772 959 805 764 1052 781 667 901 817 1042 1053 892 819 718 677
TD b 0.703 0.666 0.583 0.766 0.857 0.697 0.693 0.700 0.661 0.769 0.579 0.568 0.585 0.585 0.488 0.729 0.800 0.696 0.759 0.625 0.666 0.703 0.760 0.640 0.647 0.816 0.708 0.656 0.814 0.704 0.656 0.907 0.659 0.568 0.778 0.693 0.895 0.930 0.765 0.695 0.613 0.566
Code -CHI -CLO CON CZP DAC DDR DFO DFT DOH DON EAB EDI EMT EON EPI ERI ESV ETR EUO EZT FAR FAU FER FRA GIS GIU GME GON GOO HEU IFR IHW IMF ISV ITE ITH ITW IWR IWV IWW JBW KFI
TDlo ~ 913 456 784 885 977 968 664 840 1002 851 735 786 584 873 979 738 875 675 965 754 806 579 1021 802 726 811 694 926 840 909 798 1013 964 772 824 910 901 759 802 849 890 681
TD b 0.833 0.443 0.670 0.800 0.841 0.850 0.576 0.711 0.882 0.728 0.628 0.666 0.493 0.769 0.845 0.628 0.754 0.576 0.872 0.639 0.693 0.476 0.887 0.683 0.611 0.693 0.585 0.787 0.716 0.778 0.678 0.898 0.846 0.694 0.711 0.799 0.769 0.651 O.700 0.756 0.753 0.571
Code LAU LEV LIO -LIT LOS LOV LTA LTL LTN MAR
MAZ MEI MEL MEP MER MFI MFS MON MOR MOZ MSE MSO MTF MTN MTT MTW
MWW NAB NAT NES
NON NPO NSI OBW OFF OSI OSO OWE -PAR PAU PHI PON
TD10a 782 719 816 768 816 879 641 746 779 808 823 728 944 1059 738 960 995 1033 938 757 867 822 1083 1049 1015 912 851 873 834 922 1038 869 1016 756 739 892 747 809 773 728 751 845
TD b 0.658 0.605 0.693 0.655 0.693 0.754 0.533 0.619 0.698 0.693 0.697 0.630 0.808 0.955 0.622 0.825 0.866 0.885 0.802 0.642 0.753 0.694 0.942 0.927 0.883 0.776 0.752 0.740 0.740 0.818 0.915 0.750 0.869 0.689 0.628 0.777 0.645 0.685 0.664 0.623 0.635 0.725
388
Code
TDlo a
RHO -RON RRO RSN RTE RTH RUT RWR RWY SAO SAS SAT SAV SBE SBS SBT SFE
641 771 924 914 844 817 902 1052 410 632 701 763 690 619 617 617 892
TW
Code
TDlo a
0.533 0.688 0.801 0.786 0.715 0.695 0.767 0.919 0.333 0.545 0.586 0.644 0.587 0.514 0.534 0.522 0.767
SFF SFG SFH SFN SFO SGT SIV SOD SOS SSY STF STI STT SZR TER THO TOL
880 932 835 819 681 962 741 791 728 900 877 852 859 910 872 784 816
TW 0.765 0.850 0.724 0.692 0.575 0.862 0.636 0.666 0.631 0.784 0.748 0.720 0.760 0.780 0.739 0.666 0.693
sum of all values of the coordination sequence from N Oto N m. b topological density TD 1000:100 as defined in the Explanatory Notes.
a
Code
TDlo a
TON TSC TUN UEI UFI UOZ USI UTL VET VFI VNI VSV WEI -WEN YUG ZON
1006 590 929 832 747 776 691 826 1023 669 971 948 773 755 935 798
TW 0.867 0.482 0.803 0.708 0.641 0.658 0.590 0.713 0.913 0.562 0.896 0.818 0.655 0.640 0.797 0.679
389
APPENDIX G Origin of 3-Letter Codes and Material Names Code ABW ACO AEI AEL AEN AET AFI AFN AFO AFR AFS AFT AFX AFY AHT APC APD AST ASV ATN ATO ATS ATT ATV AWO AWW *BEA BPH CAS CDO CFI CGF CGS -CLO CON CZP DDR DFO DFT DOH DON EAB EMT
Abbreviated Name ACP- 1 (one) A1PO4-18 (eighteen) A1PO4-11 (eleven) A1PO-EN3 A1PO4-8 (eight) A1PO4-5 (five) A1PO4-14 (forteen) A1PO4-41 (forty-one) SAPO-40 (forty) MAPSO-46 (forty-six) A1PO4-52 (fifty-two) SAPO-56 (fifty-six) CoAPO-50 (fifty) A1PO4-H2 (two) A1PO4-C A1PO4-D A1PO4-16 (sixteen) ASU-7 (seven) MAPO-39 (thirty-nine) A1PO4-31 (thirty-one) MAPO-36 (thirty-six) A1PO4-12 (twelve)-TAMU A1PO4-25 (twenty-five) A1PO4-21 (twenty-one) A1PO4-22 (twenty-two) Zeolite Beta Beryllophosphate-H Cesium Aluminsilicate CDS- 1 (one) CIT-5 (five) CoGaPO-5 (five) CoGaPO-6 (six) Cloverite CIT- 1 (one) Deca-dodecasil 3R DAF- 1 (one) DAF-2 (two) Dodecasil 1H UTD- 1 (one) EMC-2 (two)
Full Name Li-A (Barrer and White) Aluminium Cobalt Phosphate - one Aluminophosphate-eighteen Aluminophosphate-eleven Aluminophosphate ethylenediamine (en) - three Aluminophosphate-eight Aluminophosphate-five Aluminophosphate-forteen Aluminophosphate-forty-one Silico-Aluminophosphate-forty MgAl(P,Si)O4-46 Silico-Aluminophosphate-fifty-six
Arizona State University- seven MgA1PO 4- thirty-nine
A1PO4-12-Texas A&M University
Beryllophosphate-Harvey (or hexagonal) Cylindrically Double Saw-edged structure - one California Institute of Technology - five Cobalt-Gallium-Phosphate-five Cobalt-Gallium-Phosphate-six Four-leafed dover shaped pore opening California Institute of Technology - one Chiral Zincophosphate Deea- & dodecahedra, 3 layers, rhombohedral Davy Faraday Research Laboratory - one Davy Faraday Research Laboratory - two Dodecahedra, 1 layer, hexagonally stacked University of Texas at Dallas-one TMA-E (Aiello and Barrer) Elf (or Ecole Sup6rieure) Mulhouse Chimie - two
390 EON ESV ETR EUO EZT GIU GON IFR IMF
ISV ITE ITH ITW IWR IWV IWW JBW KFI LOS LTA LTL LTN MEI MEL MFI MFS MSE MSO MTF MTN MTT MTW MWW NES NON NPO NSI OBW OSI OSO PON -RON RRO RSN RTE
RTH RUT
ECR- 1 (one) ERS-7 (seven) ECR-34 (thirty-four) EU- 1 (one) EMM-3 (three) (Z for zeolite) Giuseppettite GUS-1 (one) ITQ-4 (four) IM-5 (five) ITQ-7 (seven) ITQ-3 (three) ITQ-13 (thirteen) ITQ-12 (twelve) ITQ-24 (twenty-four) ITQ-27 (twenty-seven) ITQ-22 (twenty-two) ZK-5 (five) Losod Linde Type A Linde Type L Linde Type N ZSM- 18 (eighteen) ZSM- 11 (eleven) ZSM-5 (five) ZSM-57 (fifty-seven) MCM-68 (sixty-eight) MCM-61 (sixty-one) MCM-35 (thirty-five) ZSM-39 (thirty-nine) ZSM-23 (twenty-three) ZSM-12 (twelve) MCM-22 (twenty-two) NU-87 (eighty-seven) Nonasil Oxonitridophosphate- 1 (one) Nu-6(2) (six) OSB-2 (two) UiO-6 (six) OSB-1 (one) IST-1, Portugal Number One Roggianite RUB-41 (forty-one) RUB- 17 (seventeen) RUB- 3 (three) RUB- 13 (thirteen) RUB- 10 (ten)
Exxon Cooperate Research- one Eniricerche-molecular-sieve-seven Exxon Cooperate Research- thirty-four Edinburgh Univerisity - one Exxon-Mobil Material - three
Gifu University Molecular Sieve - one Instituto de Tecnologia Quimica Valencia- four Institut Franqais du P6trole and University of Mulhouse five Instituto de Tecnologia Quimica Valencia - seven Instituto de Tecnologia Quimica Valencia- three Instituto de Tecnologia Quimica Valencia - thirteen Instituto de Tecnologia Quimica Valencia- twelve Instituto de Tecnologia Quimica Valencia- twenty-four Instituto de Tecnologia Quimica Valencia- twenty-seven Instituto de Tecnologia Quimica Valencia- twenty-two Na-J (Barrer and White) Zeolite Kerr- five Low sodium aluminosilicate Zeolite A (Linde Division, Union Carbide) Zeolite L (Linde Division, Union Carbide) Zeolite N (Linde Division, Union Carbide) Zeolite Socony Mobil - eighteen Zeolite Socony Mobil - eleven Zeolite Socony Mobil - five Zeolite Socony Mobil - fifty-seven Mobil Composition of Matter- sixty-eight Mobil Composition of Matter- sixty-one Mobil Composition of Matter- thirty-five Zeolite Socony Mobil - thirty-nine Zeolite Socony Mobil - twenty-three Zeolite Socony Mobil - twelve Mobil Composition of Matter-twenty-two New (ICI) - eighty-seven Nonahedra, all silica composition N e w (ICI) - six
Universities of Oslo and Calif., Santa Barbara - two University of Oslo- six Universities of Oslo and Calif., Santa Barbara - one Instituto Superior T6cnico, Lisboa, - one Ruhr Ruhr Ruhr Ruhr Ruhr
University University University University University
Bochum - forty-one Bochum- seventeen Bochum - three Bochum- thirteen Bochum- ten
391 RWR RWY SAO SAS SAT SAV SBE SBS SBT SFE SFF SFG SFH SFN SFO SGT SIV SOS STF STT SSY SZR TOL TON TUN UEI UFI UOZ
RUB-24 (twenty-four) UCR-20 (twenty) STA- 1 (one) STA-6 (six) STA-2 (two) Mg-STA-7 (seven) UCSB-8 (eight) UCSB-6 (six) UCSB- 10 (ten) SSZ-48 (forty-eight) SSZ-44 (forty-four) SSZ-58 (fifty-eight) SSZ-53 (fifty-three) SSZ-59 (fifty-nine) SSZ-51 (fifty-one) Sigma-2 (two) SIZ-7 (seven) SU- 16 (one-six) SSZ-35 (thirty-five) SSZ-23 (twenty-three) SSZ-60 (sixty) SUZ-4 (four) Tounkite-like mineral Theta- 1 (one) TNU-9 (nine) MU- 18 (eighteen) UZM-5 (five) IM- 10, Mulhouse (one-zero)
USI
IM-6, Mulhouse (six)
UTL
IM- 12, Mulhouse (twelve)
UWE VET VFI VNI VSV ZON
UIO-28 (twenty-eight) VPI-8 (eight) VPI-5 (five) VPI-9 (nine) VPI-7 (seven) ZAPO-M 1 (one)
Ruhr University Bochum - twenty-four University of California, Riverside -twenty University of Saint Andrews - one University of Saint Andrews - six University of Saint Andrews - two University of Saint Andrews- seven University of California, Santa Barbara - eight University of California, Santa Barbara - six University of California, Santa Barbara - ten Standard Oil Synthetic Zeolite - fourty-eight Standard Oil Synthetic Zeolite- fourty-four Standard Oil Synthetic Zeolite- fifty-eight Standard Oil Synthetic Zeolite- fifty-three Standard Oil Synthetic Zeolite - fifty-nine Standard Oil Synthetic Zeolite - fifty-one St. Andrews Ionothermal Zeolite - seven Stockholm University- sixteen Standard Oil Synthetic Zeolite - thirty-five Standard Oil Synthetic Zeolite- twenty-three Standard Oil Synthetic Zeolite- sixty Sunbury Zeolite- four
Taejon National University - nine Mulhouse - eighteen UOP Zeolitic Material - five Institut Franqais du P6trole and University of Mulhouse ten lnstitut Franqais du P6trole and University of Mulhouse six lnstitut Franqais du P6trole and University of Mulhouse twelve University of O s l o - twenty-eight Virgina Polytechnic Institute - eight Virgina Polytechnic Institute - five Virgina Polytechnic Institute - nine Virgina Polytechnic Institute- seven (Zn,A1)PO4 -Mulhouse - one
393
Isotypic Material Index
*ACP-1 ACP-2 ACP-3 *Afghanite AI-ITQ-13 A1-Nu- 1 Al-rich beta Alpha A1PO-pollucite *A1PO- 11 *A1PO- 12-TAMU *A1PO-14 *A1PO-16 A1PO-17 *A1PO- 18 A1PO-20 *A1PO-21 *A1PO-21 *A1PO-22 A1PO-24 *A1PO-25 *A1PO-31 *A1PO- 31 A1PO-33 A1PO-33 A1PO-34 A1PO-35 A1PO-36 A1PO-40 A1PO-40 *A1PO-41 *A1PO-5 *A1PO-52 *A1PO-52 A1PO-53(A) A1PO-53(B) A1PO-54 *A1PO-8 *A1PO-8 *A1PO-C *A1PO-C A1PO-CJB 1 *A1PO-D *A1PO-EN3 *A1PO-H2
ACO OWE DFT AFG ITH RUT *BEA LTA ANA AEL ATT AFN AST ERI AEI SOD AWO AWO AWW ANA ATV ATO ATO ATT ATT CHA LEV ATS AFR AFR AFO AFI AFT AFT AEN AEN VFI AET AET APC APC AWW APD AEN AHT
*A1PO-H2 *A1PO-H2 A1PO-H3 Amicite Ammonioleucite AMS-1B *Analcime *Analcime *Analcime APO-CJ3 *ASU-7 AZ-1 B-Nu-1 Barrerite Basic cancrinite Basic sodalite Bellbergite Beryllophosphate X *Beryllophosphate-H *Beta Bicchulite *Bikitaite *Boggsite Bor-C Bor-D Boralite C Boralite D *Brewsterite Bystrite Ca-D Ca-Q *Cancrinite Cancrinite hydrate *CDS-1 *Cesium Aluminosilicate CF-3 CF-4 CFSAPO-1A *Chabazite *Chiavennite *Chiral Zincophosphate *CIT-1 CIT-4 *CIT-5 CIT-6
AHT AHT APC GIS ANA MFI ANA ANA ANA APD ASV MFI RUT STI CAN SOD EAB FAU BPH *BEA SOD BIK BOG MFI MEL/MFI MFI MEL BRE LOS ANA MOR CAN CAN CDO CAS NON MTN AEN CHA -CHI CZP CON BRE CFI *BEA
394 Clinoptilolite *Cloverite *Co-Ga-Phosphate-5 *Co-Ga-Phosphate-6 Co-STA-7 CoAPO-40 CoAPO-44 CoAPO-47 CoAPO-5 *CoAPO-50 CoAPO-H3 CoAPSO-40 CoDAF-4 CoIST-2 COK-5 CoVPI-5 CrAPO-5 CSZ-1 CZH-5 *Dachiardite *DAF-1 *DAF-2 DAF-5 DAF-8 Danalite Davyne *Deca-dodecasil 3R Dehyd. boggsite Dehyd. brewsterite Dehyd. Ca,NH4-Heulandite Dehyd. Linde Type A Dehyd. Na-Chabazite Dehyd. Na-X Dehyd. US-Y Deuterated Rho *Dodecasil 1H Dodecasil-3C *ECR-1 ECR-18 ECR-30 *ECR-34 ECR-40 ECR-5 *Edingtonite *EMC-2 *EMM-3 Encilite *Epistilbite ERB-1
HEU -CLO CGF CGS SAV AFR CHA CHA AFI AFY APC AFR LEV AEN MFS VFI AFI EMT/FAU MTW DAC DFO DFT CHA PHI SOD CAN DDR BOG BRE HEU LTA CHA FAU FAU RHO DOH MTN EON PAU EMT/FAU ETR MEI CAN EDI EMT EZT MFI EPI MWW
*Erionite *ERS-7 *EU-1 EU-13 EU-20 EU-20b FAPO-36 FAPO-5 FAPO-H1 *Farneseite *Faujasite Fe(III)-BCTT Fe-Nu-1 *Ferrierite FJ-17 *FOS-5 *Franzinite FU-9 FZ-1 G Ga-Nu-1 Gallosilicate ECR- 10 Gallosilicate L GaPO-14 GaPO-34 GaPO-DAB-2 Garronite Gaultite GeAPO- 11 Genthelvite *Gismondine *Giuseppettite *Gmelinite Gobbinsite Gonnardite *Goosecreekite Gottardiite *GUS-1 H1 Harmotome Hauyn Helvin *Heulandite Heulandite-Ba High natrolite High-silica Na-P Holdstite Hsianghualite Hydroxo sodalite
ERI ESV EUO MTT CAS/NSI CAS/NSI ATS AFI VFI FAR FAU BCT RUT FER SOS BEC FRA FER MFI SOD RUT RHO LTL AFN CHA ZON GIS VSV AEL SOD GIS GIU GME GIS NAT GOO NES GON VFI PHI SOD SOD HEU HEU NAT GIS MTN ANA SOD
395 *IM-10 *IM-12 *IM-5 *IM-6 IM-7 ISI-1 ISI-4 ISI-6 *IST-1 IST-2 ITQ-1 *ITQ-12 *ITQ-13 ITQ-14 ITQ-15 ITQ-17 *ITQ-22 *ITQ-24 *ITQ-27 ITQ-29 *ITQ-3 *ITQ-32 *ITQ-4 *ITQ-4 *ITQ-7 ITQ-9 JDF-2 (K,Ba)-G,L K-F K-M K-rich gmelinite KZ-1 KZ-2 Large port mordenite *Laumontite Leonhardite Leucite *Levyne *Li-A Li-LSX Linde D Linde F Linde Q Linde R Linde T *Linde Type A (zeolite A) *Linde Type L (zeolite L) *Linde Type N Linde W
UOZ UTL IMF USI ITH TON MTT FER PON AEN MWW ITW ITH BEC UTL BEC IWW IWR IWV LTA ITE IHW IFR IFR ISV STF AEN LTL EDI MER GME MTT TON MOR LAU LAU ANA LEV ABW FAU CHA EDI BPH CHA ERUOFF LTA LTL LTN MER
*Liottite *Lithosite *Losod *Lovdarite low melanophlogite Low-silica Na-P (MAP) LZ-105 LZ-132 LZ-202 LZ-210 LZ-211 LZ-212 LZ-214 LZ-215 LZ-217 LZ-218 LZ-219 LZ-220 MAP MAPO-31 *MAPO-36 *MAPO-39 MAPO-43 MAPO-46 MAPO-5 MAPSO-43 *MAPSO-46 MAPSO-56 Maricopaite *Marinellite *Mazzite *MCM-22 *MCM-35 MCM-37 MCM-58 *MCM-61 MCM-65 *MCM-68 MCM-9 MCS-1 MeAPO-47 MeAPSO-47 *Melanophlogite *Merlinoite Mesolite Metanatrolite Metavariscite *Mg-BCTT *Mg-STA-7
LIO -LIT LOS LOV MEP GIS MFI LEV MAZ FAU MOR LTL RHO LTA OFF CHA HEU ERI GIS ATO ATS ATN GIS AFS AFI GIS AFS AFX MOR MAR MAZ MWW MTF AET IFR MSO CDO MSE VFI AEN CHA CHA MEP MER NAT NAT BCT BCT SAV
396 MgAPO-50 Microsommite MnAPO- 11 MnAPO- 14 MnAPO-41 MnAPO-50 MnAPSO-41 *Montesommaite *Mordenite Mu-10 Mu-13 Mu-14 *Mu-18 Mu-26 Mutinaite N-A Na-B Na-D *Na-J Na-P1 Na-P2 Na-V *Nabesite *Natrolite NaZ-21 Nepheline hydrate (Ni(deta)2)-UT-6 *Nitridophosphate- 1 *Nonasil Nosean Nu-1 NU-10 NU-13 NU-23 NU-3 NU-4 NU-5 *Nu-6(2) *NU-87 o-FDBDM-ZSM-50 Octadecasil *Offretite Omega *OSB-1 *OSB-2 P Pahasapaite Paranatrolite *Partheite
AFY CAN AEL AEN AFO AFY AFO MON MOR AEN MSO ITE UEI STF MFI LTA ANA MOR JBW GIS GIS THO NAB NAT LTN JBW CHA NPO NON SOD RUT TON MTW FER LEV MFI MFI NSI NES EUO AST OFF MAZ OSO OBW KFI RHO NAT -PAR
*Paulingite Perlialite Phi *Phillipsite Pollucite Primary leonhardite PSH-3
Q *Rho RMA-3 *Roggianite RUB-1 *RUB-10 *RUB-13 *RUB-17 *RUB-24 *RUB-24 *RUB-3 *RUB-3 *RUB-41 SAPO- 11 SAPO-18 SAPO-31 SAPO-31 SAPO-34 SAPO-35 SAPO-37 SAPO-39 *SAPO-40 SAPO-41 SAPO-42 SAPO-43 SAPO-47 SAPO-5 *SAPO-56 Scolecite Sigma-1 *Sigma-2 Silicalite Silicalite 2 Siliceous Na-Y *SIZ-7 SIZ-8 SIZ-9 *Sodalite Sr-D Sr-Q SSZ-16 *SSZ-23
PAU LTL CHA PHI ANA LAU MWW KFI RHO ATT -RON LEV RUT RTH RSN RWR RWR RTE RTE RRO AEL AEI ATO ATO CHA LEV FAU ATN AFR AFO LTA GIS CHA AFI AFX NAT DDR SGT MFI MEL FAU SIV AEI SOD SOD FER YUG AFX STT
397 SSZ-24 SSZ-25 SSZ-26 SSZ-33 *SSZ-35 SSZ-36 SSZ-39 SSZ-42 *SSZ-44 SSZ-46 *SSZ-48 SSZ-50 *SSZ-51 *SSZ-53 SSZ-55 *SSZ-58 *SSZ-59 *SSZ-60 SSZ-73 *STA-1 *STA-2 STA-5 *STA-6 Stellerite *Stilbite *SU-16 *SUZ-4 Svetlozarite Svyatoslavite Synthetic amicite Synthetic analcime Synthetic barrerite Synthetic brewsterite Synthetic Ca-garronite Synthetic cancrinite Synthetic edingtonite Synthetic epistilbite Synthetic garronite Synthetic gobbinsite Synthetic gonnardite Synthetic hsinghualite Synthetic laumontite Synthetic lovdarite Synthetic melanophlogite Synthetic merlinoite Synthetic mesolite Synthetic natrolite Synthetic offretite Synthetic scolecite
AFI MWW
CON CON STF ITE/RTH
AEI IFR SFF MEL SFE RTH SFO SFH ATS SFG SFN SSY SAS
SAO SAT BPH SAS STI STI SOS SZR
DAC BCT
GIS ANA STI BRE
GIS CAN EDI EPI
GIS GIS NAT ANA LAU LOV MEP MER
NAT NAT OFF
NAT
Synthetic stellerite Synthetic stilbite Synthetic thomsonite Synthetic wairakite *Terranovaite Tetragonal edingtonite Tetranatrolite *Theta-1 Theta-3 *Thomsonite Tiptopite TiVPI-5 TMA sodalite *TMA-E TMA-gismondine TMA-O TNU-1 TNU-10 TNU-7 *TNU-9 *Tounkite-like mineral TPZ- 12 TPZ-3 Triclinic bikitaite TS-1 TS-2 *Tsch6rtnerite Tschernichite TsG-1 TSZ TSZ-III Tugtupite TZ-01 *UCR-20 UCSB- 10Co *UCSB-10GaZn UCSB-10Mg UCSB-10Zn UCSB-3 UCSB-3GaGe UCSB-3ZnAs UCSB-6Co *UCSB-6GaCo UCSB-6GaMg UCSB-6GaZn UCSB-6Mg UCSB-6Mn UCSB-6Zn *UCSB-8Co
STI STI THO ANA TER EDI
NAT TON MTW THO
CAN VFI SOD EAB GIS OFF CGS STI EON
TUN TOL MTW EUO BIK MFI MEL TSC *BEA CGS MFI MFI SOD MFI RWY SBT SBT SBT SBT ABW DFT DFT SBS SBS SBS SBS SBS SBS SBS SBE
398 UCSB-8Mg UCSB-8Mn UCSB-8Zn UIO-12-500 UiO-12-as UiO-20 UiO-21 *UIO-28 *UiO-6 UiO-7 UiO-7 USC-4 USI-108 UTD-1 *UTD-1F UTM- 1 UZM-25 UZM-4 *UZM-5 VAPO-31 VAPO-5 Vishnevite *VPI-5 *VPI-7 *VPI-8 *VPI-9 VS-12 VSV-7# Wairakite *Weinebeneite Wellsite *Wenkite Willhendersonite *Yugawaralite *ZAPO-M1 ZBH ZCP-THO Zeolite N Zeolite W
SBE SBE SBE AEN AEN DFT CHA OWE OSI ZON ZON MFI MFI DON DON MTF CDO BPH UFI ATO AFI CAN VFI VSV VET VNI MTW VSV ANA WEI PHI -WEN CHA YUG ZON MFI THO EDI MER
Zeolite X (Linde X) Zeolite Y (Linde Y) Zincophosphate X ZK-14 ZK-19 ZK-20 ZK-21 ZK-22 ZK-4 *ZK-5 ZKQ-1B ZMQ-TB Zn-BCTT Zn-STA-7 ZnAPO-35 ZnAPO-36 ZnAPO-39 ZnAPO-40 ZnAPO-5 ZnAPO-50 ZnAPSO-40 *ZSM-10 *ZSM-11 *ZSM-12 *ZSM-18 ZSM-20 ZSM-22 *ZSM-23 ZSM-3 ZSM-35 *ZSM-39 ZSM-4 *ZSM-5 ZSM-50 ZSM-51 *ZSM-57 ZSM-58 ZYT-6
FAU FAU FAU CHA PHI LEV LTA LTA LTA KFI MFI MFI BCT SAV LEV ATS ATN AFR AFI AFY AFR MOZ MEL MTW MEI EMT/FAU TON MTT EMT/FAU FER MTN MAZ MFI EUO NON MFS DDR CHA
