ADVANCED CLEANING PRODUCT FORMULATIONS
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ADVANCED CLEANING PRODUCT
FORMULATIONS V...
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ADVANCED CLEANING PRODUCT FORMULATIONS
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ADVANCED CLEANING PRODUCT
FORMULATIONS Volume 3
by
Ernest W. Flick
NOYES PUBLICATIONS Park Ridge, New Jersuy, U S A .
Copyright 8 1995 by Ernest W.Rick No part of this book may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying. recording or by any information storage and retrieval system, without permission in writing from the Publisher. Library of Congress Catalog Card Number: 89-30274 ISBN: 0-8155-1382-8 Printed in the United States Published in the United States of America by Noyes Publications Mill Road, Park Ridge, New Jersey 07656 10 9 8 7 6 5 4 3 2 1
Library of Congress Cataloging-in-Publication Data (Revised for vol. 3) Flick, Ernest W. Advanced cleaning produd formulations. Includes bibliographical references and index. 1. Cleaning compounds. I. Title. TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-8 (v. 3)
To Charlotte Morgan
V
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Preface This book (Volume 3) presents more than 630 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1 and 2 published earlier. Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria. The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ):
I. Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (14) 2. Dairy, Food and General Industrial Cleaners (52) 3. Degreasers (25) 4. Dishwashing Detergents (70) 5. General Purpose Cleaners (29) 6. Glass CLeanersPolishes (18) 7. Hard Surface Cleaners (59) 8. Laundry Products (100) 9. Metal Cleaners and Polishes (52) 10. Oven, Grill and Hot Plate Cleaners (11) 11. Polishes, Coatings and Finishes (19) 12. Rinse Aids (5) 13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (41) 14. Miscellaneous (49) vii
Preface
viii
11. Transportation Cleaners and Polishes 15. Auto Cleaners and Polishes (32) 16. Car and Truck Wash Compounds (34) 17. Whitewall Tire Cleaners (11) 18. Miscellaneous (12)
Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader. 111. Achemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the supplier's name. The specifications which each raw material meets are included, if applicable.
IV. Main office addresses of the suppliers of trademarked raw materials. Each formulation in the book lists the following information, as available, in the manufacturer's own words: 0
Description of end use and most outstanding properties.
0
The percent by weight or volume of each raw material included in the formula, rounded to a decimal figure.
0
Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type.
0
The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publication title, or both. A formula number is included, if applicable.
The table of contents is organized in such a way as to serve as a subject index. My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials. Newburyport, Massachusetts September 1994
Ernest W. Flick
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NOTICE To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. Final determination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We recommend that anyone intending to rely on any recommendation of materials or procedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards.
X
Contents and Subject Index SECTION I HOUSEHOLD AND INDUSTRIAL CLEANERS AND POLISHES 1. BATHROOM CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Clear Liquid Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Thick Toilet Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Disinfectant Bowl Cleaner Formulation Name: TB-A23 . . . . . . . 4 4 Viscous PhosphoridHCI Acid Cleaner .................... Gentle Abrasive Lotion Cleanser for Bathroom and Kitchen . . . . 5 Cream Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Mixed Acid Bath Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Liquid Scouring Cleanser I . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 HCI Acid Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Solid Automatic Toilet Bowl Cleaner Formulation . . . . . . . . . . . 7 Acid Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 Viscous Organic Acid Cleaner4 ........................ 8 Viscous Organic Acid Cleaner41 . . . . . . . . . . . . . . . . . . . . . . . . 8 Viscous Organic Acid Cleaner411 . . . . . . . . . . . . . . . . . . . . . . . 8
.
2 DAIRY. FOOD AND GENERAL INDUSTRIAL CLEANERS . . . . 9 Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Alkaline All-Purpose Industrial Cleaner Phosphated. Powder Type . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Acid Cleaners. Foamy Acid Dairy Cleaner . . . . . . . . . . . . . . . . 11 11 Aluminum Brightener A103 . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum Brightener A102 . . . . . . . . . . . . . . . . . . . . . . . . . . 11 Built Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 Aluminum Soak Tank CleanerDrightener . . . . . . . . . . . . . . . . . 12 12 Heavy Duty Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . d-Limonene . Microemulsion Cleaner/Degreaser . . . . . . . . . . . . . 13 Heavy Duty Industrial Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . 13 Electrocleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 14 Low Foam Tanktruck Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . Food Plant Cleaners Foamy Acid Dairy Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 15 xi
xii
Contents and Subject Index Low Foam-Self Demulsifying Cleaner . . . . . . . . . . . . . . . . 15 Low Foam Moderate pH. Self Demulsifying . . . . . . . . . . . . 15 Graffiti Remover 1 ................................. 16 Graffiti Remover 2 ................................. 16 Heavy Duty Cleaners (Industrial) Steam Cleaners-Liquids ......................... 17 Steam Cleaners-Powders ......................... 17 Heavy Duty Industrial Spray Cleaner Concentrate F-543 . . . . . . 18 Heavy Duty Industrial Spray Metal Cleaner Concentrate F-544 ............................... 18 High Solids Alkaline Cleaner F-555 . . . . . . . . . . . . . . . . . . . . 18 High Foaming Smokehouse Cleaner-I . . . . . . . . . . . . . . . . . . . 19 High Foaming Smokehouse Cleaner-II . . . . . . . . . . . . . . . . . . . 19 Industrial Cleaners Acid Based AluminurdSS Cleaner . . . . . . . . . . . . . . . . . . . 20 20 Acid Based Metal Cleaner ........................ Light Duty Neutral Cleaner ........................ 20 Anionic/Nonionic Glycol Ether HSC . . . . . . . . . . . . . . . . . 21 21 Anionic/Nonionic HD HSC ........................ Low VOC Cleaners 22 Non-Caustic Industrial Cleaner ..................... 22 Low VOC Heavy Duty Presoak ..................... Non-Solvent Medium Duty Degreaser . . . . . . . . . . . . . . . . 23 Non-Solvent Heavy Duty Steam Cleaner . . . . . . . . . . . . . . 23 Low VOC Solvent Cleaner-Isopar G . . . . . . . . . . . . . . . . 24 Low VOC Solvent Cleaner-Isopar M . . . . . . . . . . . . . . . . 24 Sanitizers and Food Plant Cleaners 25 Detergent for Blood Removal ...................... Food Plant and Dairy Detergent Sanitizer . . . . . . . . . . . . . . 25 General Purpose Sanitizers 25 Alkaline .................................. Acidic .................................... 25 Mildly Acidic .............................. 25 General Purpose Equipment Detergent4 . . . . . . . . . . . . . . 26 General Purpose Equipment Detergent41 . . . . . . . . . . . . . . 26 26 Milk Can Cleaners4 ............................ Milk Can Cleaner-II ............................ 26 26 Soak Bottle Cleaner-I ........................... Soak Bottle Cleaner-I1 ........................... 26 27 Heavy Duty Chlorinated Cleaner .................... Heavy Duty Liquid Chlorinated Cleaner-I . . . . . . . . . . . . . 27 Heavy Duty Liquid Chlorinated Cleaner-II . . . . . . . . . . . . 27 Heavy Duty Liquid Chlorinated Cleaner411 . . . . . . . . . . . . 27
Contents and Subject Index
.
2 DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Alkaline Degreaser-A . . . . . . . . . . . . . . . . . . . . . . All Purpose Alkaline Degreaser-B . . . . . . . . . . . . . . . . . . . . . . All Purpose Alkaline Degreaser-C . . . . . . . . . . . . . . . . . . . . . . All Purpose Alkaline Degreaser-D . . . . . . . . . . . . . . . . . . . . . . Industrial Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Spray Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Engine Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . Cosmoline Remover (Heavy oil or greasy-wax remover) . . . . . . Degreaser Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Metal Cleaner Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-Limonene Degreaser-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-Limonene Degreaser-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Metal Degreaser Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Micro-Emulsions with Aloe Vera and d-Limonene . . . . . . . . . . Phosphate Free Cleaners Glycol Ether Degreaser-I . . . . . . . . . . . . . . . . . . . . . . . . . Glycol Ether Degreaser-I1 . . . . . . . . . . . . . . . . . . . . . . . . Solvent Cleaners Glycol Ether Cleaner 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . Water Rinseable Degreaser I . . . . . . . . . . . . . . . . . . . . . . . Isopar M Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Kerosene Emulsion Cleaner . . . . . . . . . . . . . . . . . . . . . . . . Acid/Solvent Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.
4 DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . Automatic Dishwash I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Automatic Dishwash I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rinse Aid-Commercial Machine . . . . . . . . . . . . . . . . . . . . . . . Automatic Dishwash Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . Automatic Dishwashing Gel-I . . . . . . . . . . . . . . . . . . . . . . . . . Automatic Dishwashing Gel-I1 . . . . . . . . . . . . . . . . . . . . . . . . Automatic Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . Crystal Clear Hand Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . Clear Hand Dishwashing Liquid (25% actives)-A . . . . . . . . . . Clear Hand Dishwashing Liquid (25% actives)-B . . . . . . . . . . . Clear Hand Dishwashing Liquid (25% actives)-(= . . . . . . . . . . . Clear Hand Dishwashing Liquid (25% actives)-D . . . . . . . . . . Clear Hand Dishwashing Liquid (25% actives)-D . . . . . . . . . . Clear Hand Dishwashing Liquid (30% actives)-A . . . . . . . . . . Clear Hand Dishwashing Liquid (30% actives)-B . . . . . . . . . . . Clear Hand Dishwashing Liquid (30% actives)-C . . . . . . . . . . . Clear Hand Dishwashing Liquid (30% actives)-D . . . . . . . . . .
xiii 28 29 29 30 30 31 31 31 31 32 32 33 33 34 34 35
36 36 37 37 38 38 38 39 40 40 40 41 42 42 43 43 44
44 45 45 46 46 47 47 48
xiv
Contents and Subject Index Clear Hand Dishwashing Liquid (30% actives)-E . . . . . . . . . . . 48 Commercial Machine Dishwashing Compound4 . . . . . . . . . . . . 49 Commercial Machine Dishwashing Compound41 . . . . . . . . . . . 49 Liquid Machine Dishwashing Detergent4 . . . . . . . . . . . . . . . . 49 Liquid Machine Dishwashing Detergent4 . . . . . . . . . . . . . . . . 49 Non-DDBSA Dishwashing Liquid ...................... 49 Dishwash Products Pearlescent Premium I1 ........................... 50 Low Cost Formula .............................. 50 Low Cost Formula I1 ............................ 50 Hand Dishwash-Premium ........................... 51 Hand Dishwash-Intermediate ......................... 51 Hand Dishwash-Economy ........................... 51 Hand Dishwashing-Solid-I1 .......................... 52 Hand Dishwashing-Solid-I1 .......................... 52 Hand Dishwashing--Li quid ........................... 52 Automatic Dishwashing Detergent Soft Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Hard Water ................................... 52 High Performance Dishwash .......................... 53 Dish Washing Agents (Manual Use) ..................... 53 High-Performance Hand Dish Detergent . . . . . . . . . . . . . . . . . 54 Mild Liquid Hand Dish Detergent ...................... 54 Liquid Dishwasher Detergent .......................... 55 Liquid Hand Dish Detergent .......................... 56 Liquid Hand Dish Detergent .......................... 56 Liquid Hand Dish Detergent .......................... 56 Liquid Manual Dishwashing Detergents Premium Performance Glucopon & AES ............................ 57 Glucopon & LAS ............................ 57 Economy Performance Glucopon & AES ............................ 57 Glucopon & LAS ............................ 57 Liquid Manual Dishwashing Detergents (Based on Added Value Surfactant Concentrates) 58 Premium Perfarmance ............................ Economy Performance ........................... 58 Premium Performance with h i d e . . . . . . . . . . . . . . . . . . 58 Premium Performance with Betaine . . . . . . . . . . . . . . . . . . 58 Liquid Manual Dishwashing Detergents Intermediate Performance Lauryl Sulfate & AES ........................ 59 Premium Performance
Contents and Subject Index
.
5
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LAS & A E S . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Glucopon & AOS . . . . . . . . . . . . . . . . . . . . . . . . . . . . Economy Performance Glucopon & AOS . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Cost Liquid Dishwasher Detergent . . . . . . . . . . . . . . . . . . Machine Dishwash Detergents (Institutional) Liquids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Powders . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Machine Dishwashing Formulation . . . . . . . . . . . . . . . . . . . . . . Mechanical Dishwashing Detergent Liquid . . . . . . . . . . . . . . . . Mechanical Dishwashing Detergent Chlorinated . . . . . . . . . . . . Premium Dishwash 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Premium Dishwash 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Premium Dishwash 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Premium Dishwash 4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Premium Hand Dishwash Formula-1 . . . . . . . . . . . . . . . . . . . . Premium Hand Dishwash Formula-2 . . . . . . . . . . . . . . . . . . . . Premium Hand Dishwash FOrmda-3 .................... Premium Hand Dishwash Formula-4 . . . . . . . . . . . . . . . . . . . .
59 59
GENERAL PURPOSE CLEANERS . . . . . . . . . . . . . . . . . . . . . . . All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . Alkaline Powder Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Ammoniated General Purpose Household Detergent . . . . . . . . . Butyl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Ammoniated Liquid General Purpose Detergent-I . . . . . . . . . . . Ammoniated Liquid General Purpose Detergent-I1 . . . . . . . . . . Ammoniated Liquid General Purpose Detergent-I11 . . . . . . . . . . Scouring Powder-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Scouring Powder-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Bleach Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Vegetable Oil Soap . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty All Purpose Cleaner-A . . . . . . . . . . . . . . . . . . . . . Heavy Duty All Purpose Cleaner-B . . . . . . . . . . . . . . . . . . . . . Heavy Duty All Purpose Cleaner-C . . . . . . . . . . . . . . . . . . . . . Heavy Duty All Purpose Cleaner-D . . . . . . . . . . . . . . . . . . . . . Heavy Duty All Purpose Cleaner-E . . . . . . . . . . . . . . . . . . . . . Heavy Duty All Purpose Cleaner-F . . . . . . . . . . . . . . . . . . . . . Heavy Duty Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . General Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Neutral Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Caustic All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . .
67 68 68 68 69 69 70 70 70 70 70 71 71 71 72 72 73 73 74 74 75 75 75 76
59 60 61 61 62 63 63 64 64 65 65 66 66 66 66
mi
Contents and Subject Index Non-Caustic Powder ............................... 76 Non-Caustic Steam Cleaner .......................... 76 Non-Phosphate All Purpose Cleaner .................... 77 Oil Splitting General Purpose Cleaner . . . . . . . . . . . . . . . . . . . 77
. GLASS CLEANERSPOLISHES
6
.
.........................
Ammoniated Glass Cleaner ........................... Glass Cleaner I .................................... Low VOC/Non-Acid Glass Cleaner ..................... CleanerPolish for Glass ............................. Dry Powder Cleaning Compound. Low Aggressive Type . . . . . . Glass Cleaner Ammonia Economical . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty ................................... Glass Cleaner Vinegar Economical ................................... Heavy Duty ................. .................. Glass Cleaner & Polish .............................. Glass Cleaner-Polish ............................... Glass Cleaners All-Purpose Glass Cleaner ........................ All-Purpose Glass Cleaner. Liquid Spray . . . . . . . . . . . . . . Industrial Glass Cleaner ............................. Multi-Feature Glass Cleaner .......................... Glass Cleaner .....................................
78 79 79 79 80 80 81 81 82 82 83 83 84
84 85 85 85
86 7 HARD SURFACE CLEANERS .......................... 87 Abrasive Hard Surface Cleaner-A ...................... Abrasive Hard Surface Cleaner-B ...................... 87 87 Abrasive Hard Surface Cleaner-C ...................... D-Limonene Based Cleaner-I ......................... 88 D-Limonene Based Cleaner-I1 ........................ 88 D-Limonene Based Cleaner-I11 ........................ 89 Low Foaming Liquid Cleaner with Abrasive . . . . . . . . . . . . . . . 89 D-Limonene Hard Surface Cleaner 90 D-Limonene Concentrate ......................... All-Purpose Spray Cleaner Type (1:9 Dilution) . . . . . . . . . 90 Heavy-Duty Degreaser Type (1:3 Dilution) . . . . . . . . . . . . 91 D-Limonene All-Purpose Cleaner . . . . . . . . . . . . . . . . . . . 91 Economical Pine Oil Hard-surface Cleaner . . . . . . . . . . . . . . . 92 92 Heavy-Duty Cleaner Powder .......................... D-Limonene Emulsifiable Concentrate . . . . . . . . . . . . . . . . . . . 92 General Purpose Hard-surface Cleaners Solvent-Free Non-Phosphate Type . . . . . . . . . . . . . . . . . . 93
Contents and Subject Index
xvii
Solvent-Free Phosphate Type . . . . . . . . . . . . . . . . . . . . . . 93 93 Heavy-Duty Solvent Type . . . . . . . . . . . . . . . . . . . . . . . . General Purpose Spray-and-Wipe Cleaner . . . . . . . . . . . . . . . . 94 Mold and Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . 94 95 Glycol Ether Cleaner 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 Glycol Ether Cleaner 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaners All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 All Purpose Cleaner with Solvent . . . . . . . . . . . . . . . . . . . 96 96 Pine Oil Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 Heavy Duty Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . All Surface Bathroom Acid Type . . . . . . . . . . . . . . . . . . . . 97 All Surface Bathroom Type . . . . . . . . . . . . . . . . . . . . . . . . 97 98 Hard Surface Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 Hard Surface Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 Hard Surface Cleaner-C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 Hard Surface Cleaner-D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 Heavy Duty HSC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Powder-Heavy Duty HSC . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 High.Foaming. Clear. Light-Duty Liquid Cleaner . . . . . . . . . 101 High.Foaming. Light-Duty Cleaner . . . . . . . . . . . . . . . . . . . . 101 Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 Pine Oil Detergent-Cleaner-Sanitizer . . . . . . . . . . . . . . . . . . 101 Heavy-Duty Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 101 High.Performance. Hard Surface Cleaners Solvent-Free Non-Phosphate Type . . . . . . . . . . . . . . . . . 102 102 Solvent-Free Phosphate Type . . . . . . . . . . . . . . . . . . . . . 102 Heavy-Duty Solvent Type . . . . . . . . . . . . . . . . . . . . . . . High Pressure Spray Concentrate (Liquid. Low Foam) . . . . . . . 103 Spray and Wipe Household Hardsurface (Liquid) . . . . . . . . . . 103 Destainer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103 HSC/Food Service Degreaser I . . . . . . . . . . . . . . . . . . . . . . . 104 104 HSC/Food Service Degreaser I1 . . . . . . . . . . . . . . . . . . . . . . . 105 Liquid Abrasive Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . 105 Liquid Abrasive Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . Low Foam Cleaners Self Demulsifying Hard Surface Cleaner . . . . . . . . . . . . . 106 HSC. Moderate pH. Self Demulsifying . . . . . . . . . . . . . . . 106 Phosphate Free Cleaners Heavy Duty Non-Solvent Degreaser . . . . . . . . . . . . . . . . 107 107 AnionicDIonionic HSC . . . . . . . . . . . . . . . . . . . . . . . . . . Thickened D-Limonene Cleaner . . . . . . . . . . . . . . . . . . . . . . 108 108 D-Limonene HSCDegreaser . . . . . . . . . . . . . . . . . . . . . . . . . Unbuilt. High-Sudsing. Hard-surface Cleaner . . . . . . . . . . . . 109
xviii
Contents and Subject Ifidex High-Performance General Purpose Cleaner Concentrate . . . . . Viscous Phosphoric Acid Cleaner ...................... Viscous HCI Acid Cleaner .......................... Viscous Mixed Acid Cleaner .........................
.
109 110 110 110
8 LAUNDRY PRODUCTS .............................. 111 Alkaline Laundry Formulation-Emulsion Type . . . . . . . . . . . 112 Alkaline Laundry Fomulation-Slurry Type . . . . . . . . . . . . . 112 AnionidNonionic Heavy-Duty Laundry Detergent . . . . . . . . . 113 AnionidNonionic Heavy-Duty Laundry Detergent . . . . . . . . . 113 114 Chlorine Dry Bleach-I ............................. 114 Chlorine Dry Bleach-I1 ............................. SOW-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 SOW-I1 ........................................ 114 Oxygen Safety Dry Bleach4 ......................... 114 114 Oxygen Safety Dry Bleach-I1 ........................ Cold Water Detergent (for Wool and Delicate Fabrics) . . . . . . 115 Fine Fabric Detergent .............................. 115 Commercial Laundry Formulations Phosphated Alkali or Builder ...................... 116 Tallow Soap Detergent Light Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116 Heavy Duty ............................... 116 Built Detergent (Light Duty) ...................... 116 Built Detergent (Heavy Duty) ..................... 116 Commercial Low-Built Laundry Detergent One-Shot Liquid .............................. 117 Multi-Component System Detergent Break . . . . . . . . . . . 117 Enzymatic Heavy Duty Laundry Detergent . . . . . . . . . . . . . . . 118 Nonionidhphoteric Heavy Duty Laundry Liquid . . . . . . . . . 118 Fine Fabric Handwash .............................. 119 Low Temperature Powder Detergent . . . . . . . . . . . . . . . . . . . 119 Heavy Duty Laundry Detergent High Sudsing ................................. 120 120 Low Sudsing ................................. 120 Cold Water Wool Detergent ......................... Heavy Duty Liquid Laundry Detergent . . . . . . . . . . . . . . . . . . 120 Heavy Duty Laundry. Liquid ......................... 121 Light Duty Liquid Detergent ......................... 121 Heavy Duty Liquid Laundry Detergent . . . . . . . . . . . . . . . . . . 122 Heavy Duty Powdered Laundry Detergent . . . . . . . . . . . . . . . 122 Heavy Duty Liquid Laundry Formulad . . . . . . . . . . . . . . . . . 123 Heavy Duty Liquid Laundry Formula-6 . . . . . . . . . . . . . . . . . 123 Heavy Duty Liquid Laundry Formula-7 . . . . . . . . . . . . . . . . . 123
Contents and Subject Index Heavy Duty Liquid Laundry Formula-8 . . . . . . . . . . . . . . . . . Heavy Duty Phosphate Free Laundry Powder-A . . . . . . . . . . . Heavy Duty Phosphate Free Laundry Powder-B . . . . . . . . . . . Concentrated Liquid Laundry Detergent . . . . . . . . . . . . . . . . . Industrial and Institutional Detergent Concentrate Formulation A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Formulation B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Formulation C ................................ Industrial Laundry Powder Uniforms . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hotel Linen Supply ............................ Industrial Laundry Two-Part Systems-Uniforms (Petroleum Greases and Oils) ............................... Hoteminen Supply (Animal and Vegetable Grease) . . . . . . . . Industrial Laundry One-Shot Liquid . . . . . . . . . . . . . . . . . . . Laundry Alkali Builders Powders-Industrial Supply. Moderate Alkalinity . . . . . . . Liquids Linen Supply .............. . . . . . . . . . . . . . . . . Industrial Supply ........................... Laundry Detergent. I and I-Unbuilt (Liquid) . . . . . . . . . . . . . Laundry Detergent-Linen Supply (Powder. Low Alkalinity) . . Laundry Detergents (Consumer) Dry Blended . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Phosphorous-Free . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Agglomerated . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Phosphorous (Economy) . . . . . . . . . . . . . . . . . . Premium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Phosphorous-Free (Economy) ..................... Premium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Formulas RestauranVHotel Laundry I ....................... RestauranVHotel Laundry I1 ...................... Concentrated Prespotter . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Powder Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Phosphate Laundry Powder ...................... Liquid Commercial Laundry .Detergents . . . . . . . . . . . . . . . . . Industrial and Institutional Detergent Concentrates Formulation A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Formulation B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Formulation C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Laundry/Anionic Phosphate-Free . . . . . . . . . . . . . . . . Liquid LaundryJNonionic Phosphate-Free . . . . . . . . . . . . . . .
xix
123 124 124 124 125 125 125 126 126 127 127 127 128 128 128 129 129 130 130 130 130 131 131 131 132 132 132 133 133 134 134 134 134 135 135
XT
Contents and Subject Index Liquid Laundry Detergents Anionic & Nonionic ............................ All Nonionic ................................. Anionic & Nonionic with Builder .................. Nonionic with Builder .......................... Liquid Laundry Detergents (Based on Added Value Surfactant Concentrates) Premium HDL ................................ Economy HDL ................................ Concentrate with Nonionics ....................... Ultra High Active .............................. Liquid LaundryDJonionic Phosphate .................... Liquid Laundry/Anionic Phosphate .................... Oxygen Safety Dry Bleach-I ......................... Oxygen Safety Dry Bleach-I1 ........................ Detergent Sanitizer-I .............................. Detergent Sanitizer-I1 .............................. Super Concentrate Laundry Liquid ..................... Laundry Detergents Industrial and Institutional Liquid (Dispersion) ............................. Liquid (Solution) .............................. Unbuilt Laundry Detergent-A ........................ Unbuilt Laundry Detergent-B ........................ Unbuilt Laundry Detergent-C ........................ Unbuilt Laundry Detergent-D ........................ Unbuilt Laundry Liquid-A .......................... Unbuilt Laundry Liquid-B .......................... Unbuilt Laundry Liquid-C .......................... Unbuilt Laundry Liquid-D ..........................
136 136 136 136
137 137 137 137 138 138 139 139 139 139 140 140 140 141 141 142 142 143 143 144 144
. METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . 145
9
Acid Cleaner .................................... High-Foaming Acid Scrubber ........................ Acid Metal Cleaner No . 392 ......................... Acid Cleaner No . 288 .............................. Aluminum Brightener-I ............................ Aluminum Brightener41 ............................ Aluminum Brightener-111 ........................... Aluminum Cleaner ................................ Aluminum Cleaner ................................ Aluminum Cleaner Concentrate F-498 .................. Aluminum Wash F-499 ............................ Aluminum CleanerPolish. Soft Paste . . . . . . . . . . . . . . . . . . . Silver Polish. Soft Paste ............................
146 146 147 147 148 148 148 149 150 151 151 152 152
Contents and Subject Index
xxi
Aluminum Cleaner/Polish. Soft Paste . . . . . . . . . . . . . . . . . . . 153 Tarnish-Retardant Silver Polish. Soft Paste . . . . . . . . . . . . . . 153 Fine Brass Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154 Emulsion Metal Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154 Iron Phosphating and Cleaning Formulations Liquid Products . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Steam Cleaners Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Acid Cleaners 156 Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156 Liquid-I1 ............................. 156 Industrial Soak Tank Aluminum Cleaner . . . . . . . 156 Rust Remover for Steel . . . . . . . . . . . . . . . . . . . 156 Degreaser (for Engine Blocks and Automotive Machine Parts) . . . . . . . . . . . . . . . . . . . . . . . . 156 Solid Products . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157 Low Foam Heavy Duty Alkaline Cleaner-A . . . . . . . . . . . . . . 158 Low Foam Heavy Duty Alkaline Cleaner-B . . . . . . . . . . . . . . 158 Moderate Alkalinity. Soil Splitting Soak Cleaner . . . . . . . . . . . 158 Metal Cleaner Formulas 159 Liquid A-14 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid A-15 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 Powder A-16 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 Metal Cleaning (Industrial) Ferrous Metals-Immersion 160 Liquid-Light Duty . . . . . . . . . . . . . . . . . . . . . . . . . Powder-Heavy Duty . . . . . . . . . . . . . . . . . . . . . . . . 160 Powder-Medium Duty . . . . . . . . . . . . . . . . . . . . . . 160 Powder-Light Duty . . . . . . . . . . . . . . . . . . . . . . . . 160 Ferrous Metals-Spray Liquid-Light Duty . . . . . . . . . . . . . . . . . . . . . . . . . 160 Powder-Light Duty . . . . . . . . . . . . . . . . . . . . . . . . 160 Non-Acid Aluminum Brightener-I .................... 161 Non-Acid Aluminum Brightener-I1 .................... 161 Soak-Tank Metal Cleaner (Powder. for Magnesium) . . . . . . . . 162 High Temperature Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . 162 Viscous Phosphoric/Oxalic Acid Cleaner-I . . . . . . . . . . . . . . . 163 Viscous Phosphoric/Oxalic Acid Cleaner-I1 Viscous Phosphoric/Oxalic Acid Cleaner-I11 . . . . . . . . . . . . . . 163
.
10 OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . . 164 Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165
xxii
Contents and Subject Index Grill Cleaner .................................... Oven Cleaner .................................... Caustic Oven. Grill and Drain Cleaners . . . . . . . . . . . . . . . . . Formulation A ................................ Formulation B ................................ Formulation C ................................ Hot Plate/Grill Cleaner ............................. Oven Cleaner .................................... Industrial Cleaners ................................ Oven Cleaner ................................. Thickened Alkaline Cleaner .........................
165 165 166 166 166 166 167 167 168 168 168
11 POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . . Aerosol Appliance Polish ........................... Aerosol Furniture Polish ............................ Aerosol Furniture Polish ............................ Furniture Polish .................................. Furniture Polish (Cationic Emulsion) . . . . . . . . . . . . . . . . . . . Detergent/Corrosion-Resistant Polish . . . . . . . . . . . . . . . . . . . Detergent-Resistant Paste Polish ...................... Furniture Polish .................................. Spray and Wipe Furniture Polish ...................... Furniture Polish No . 337 ............................ Scratched Wood Polish No . 210 ....................... Industrial Floor Finish-Formula B (24% Solids) . . . . . . . . . . . Industrial Floor Finish-Formula A (22% Solids) . . . . . . . . . . . Industrial Floor Finish-Formula B (25% Solids) . . . . . . . . . . . Industrial Floor Finish-Formula C (18% Solids) . . . . . . . . . . . Industrial Floor Finish-Formula A (20% Solids) . . . . . . . . . . . Industrial Floor Finish-Formula B (16% Solids) . . . . . . . . . . . Industrial Floor Finish-Fomula C (20% Solids) . . . . . . . . . . . Industrial Floor Finish-Formula D (25% Solids) . . . . . . . . . . .
169 170 170 171 171 171 172 172 173 173 174 174 175 175 176 176 177 177 178 178
.
.
12 RINSE AIDS ....................................... Automatic Dishwasher Rinse Aid-I .................... Automatic Dishwasher Rinse Aid-I1 . . . . . . . . . . . . . . . . . . . Automatic Dishwasher Rinse Aid-111 . . . . . . . . . . . . . . . . . . . Rinse Aid ......................................
.
179 180 180 180 181
12 RUG. FLOOR, CARPET UPHOLSTERY SHAMPOOS AND CLEANERS ......................... 182 Carpet Shampoo for Automatic Carpet Shampooer (may also be used for cleaning vinyl and upholstery) . . . . . . . . . . 183 Aerosol Rug Shampoo ............................. 183
Contents and Subject Index Carpet Shampoo with Grease-Cutting Solvent . . . . . . . . . . . . Liquid Steam Cleaner for Carpets (for use in hard water systems) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Floor and Carpet Care Products . . . . . . . . . . . . . . . . . . . . . . . Floor and Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wax Stripper (Solvent) . . . . . . . . . . . . . . . . . . . . . . . . . . Machine Floor Scrubber . . . . . . . . . . . . . . . . . . . . . . . . . Floor Care Products . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Floor Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Waxed Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Floor Cleanerwax Stripper (Liquid) . . . . . . . . . . . . . . . . . . . Floor Cleanerwax Stripper B . . . . . . . . . . . . . . . . . . . . . . . . Floor Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . No Rinse Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . General Purpose Floor and Wall Cleaner Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Floor Wax Remover Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concrete Garage Floor Cleaner4 ...................... Concrete Garage Floor Cleaner4 ..................... Ceramic Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Concrete Cleaner ........................ Evaporative (No Rinse) Wax Stripper . . . . . . . . . . . . . . . . . . . Liquid Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet Stain Remover-Liquid . . . . . . . . . . . . . . . . . . . . . . . . Carpet Cleaner/Booster-Dry Destainer . . . . . . . . . . . . . . . . . . Low Foam Cleaners Machine Floor Cleaner I . . . . . . . . . . . . . . . . . . . . . . . . . Machine Floor Cleaner I1 . . . . . . . . . . . . . . . . . . . . . . . . Carpet Stain Remover/Prespotter . . . . . . . . . . . . . . . . . . . Pumpsprays for Removal of Odors ..................... Deodorant Rug Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rug Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rug and Upholstery Shampoo . . . . . . . . . . . . . . . . . . . . . . . .
.................................. . MISCELLANEOUS Aerosol Bathroom Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . .
14
Aerosol Oven Release
..............................
xriii
184 184 185 185 185 185 185 186 186 186 187 187 188 188 189 189 189 190 190 190 190 190 190 190 191 191 192 192 192 193 193 193 194 194 195 195 196 197 197
xxiv
Contents and Subject Index Aerosol Water-Repellent Fabric Treatment . . . . . . . . . . . . . . 198 Liquid. Vinyl Surface Protectant ...................... 198 Asphalt Emulsion ................................. 199 199 Road Tar Emulsion ................................ 200 Cationic Oil-in-Water Emulsifier ..................... 200 Cationic Water-in-Oil Emulsion ...................... Concrete Cleaner ................................. 200 Rust Remover ................................... 200 Chain Belt Lube 1 ................................ 201 Chain Belt Lube 2 ................................ 201 Concrete Cleaner (Dry Type) ......................... 202 202 Polishing Cloth ................................... 203 Detergent Sanitizer ................................ Steam-Cleaning Compound .......................... 203 d-Limonene Microemulsion Cleaner F-478 . . . . . . . . . . . . . . 204 d-Limonene Alkaline Cleaner F-524 . . . . . . . . . . . . . . . . . . . 204 d-Limonene Microemulsions that Give Clear Dilutions . . . . . . 205 Water Spot and Soap Film Remover . . . . . . . . . . . . . . . . . . . 205 Dry Cleaning Formula ............................. 206 Dry Cleaning Formula ............................. 206 Egg Cleaner (Powder) .............................. 207 Grill Cleaner (Liquid) .............................. 207 Printing Plant Cleaner (Powder) ....................... 207 208 Graffiti Cleaner .................................. Penetrating Lubricant .............................. 208 208 Bottle Wash Cleaner F-542 .......................... 209 Heavy Duty Presoak ............................... Underbody Rust Inhibitor ........................... 209 Railcar Cleaner .................................. 209 210 Leather Preservative ............................... "Liquid Sandpaper" (Water Base) ..................... 211 "Marble Polish" (Water Base) ........................ 211 212 Paint Stripper .................................... Paint Strippers Liquid ...................................... 213 213 Powders ..................................... Wax Strippers Liquids ..................................... 213 213 Powder ..................................... 214 Paraffin Wax Emulsion ............................. 214 Liquid Drain Opener ............................... Low VOC Heavy Duty Presoak ....................... 214 215 Penetrating Gel Base ............................... 215 Water-in-Oil Emulsion Base ........................
Contents and Subject Index Solvent Cleaners Blood Stain Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . Paint Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~ n ,
216 216
SECIlON II TRANSPORTATION CLEANERS AND POLISHES
. AUTO CLEANERS AND POLISHES
15
....................
Auto CleanerPolish. Aerosol Packed . . . . . . . . . . . . . . . . . . . Detergent-Resistant Auto CleanerPolish (Thick. Liquid. Oil-External) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Auto CleanerPolish. Hard Paste . . . . . . . . . . . . . . . . . . . . . . Cream Cleanser-Non-Wax Type ...................... Auto CleanerPolish. Hard Paste ...................... Detergent-Resistant Auto CleanerPolish (Thick. Liquid. Oil-External) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Auto CleanerPolish. High Gloss . . . . . . . . . . . . . . . . . . . . . . Pre-Wax Cleaner. Automotive. Liquid . . . . . . . . . . . . . . . . . . Auto CleanerPolish. Low-Temperature Compounded (Thick Liquid. Water-External) ..................... Auto CleanerPolish. for Machine Buffing . . . . . . . . . . . . . . . Auto CleanerPolish. Soft Paste. Emulsion . . . . . . . . . . . . . . . "Luster-Powder" Auto Polish . . . . . . . . . . . . . . . . . . . . . . . . Auto CleanerPolish. Thick Liquid. Oil External . . . . . . . . . . . Detergent-Resistant AutoKleaner Polish. Thin Liquid . . . . . . . Cream Car Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rubbing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent-Resistant Auto Cleaner Polish . . . . . . . . . . . . . . . . Detergent-Resistant Auto Cleaner Polish . . . . . . . . . . . . . . . . PolishA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Polish B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Auto Cleaner-Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Silicone Car Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . Auto Rinse-Wax Concentrate . . . . . . . . . . . . . . . . . . . . . . . . Auto Vinyl-Top Protector . . . . . . . . . . . . . . . . . . . . . . . . . . . Spraywax I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Hydrocarbon Spraywax-N-3 . . . . . . . . . . . . . . . . . . . . . Non-Hydrocarbon Spraywax-N-4 . . . . . . . . . . . . . . . . . . . . . Transportation Cleaners Wash and Wax 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wash and Wax 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Polish or "Hot Wax" . . . . . . . . . . . . . . . . . . . . . . . . . . . . Waxless. Presoftened. Detergent-Resistant. Cleaner. Paste Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
218 219 219 220 220 221 221 222 222 223 223 224 224 225 225 236 226 227 228 228 228 228 229 229 229 230 230 230 231 231 231 232
m i
Contents and Subject Index
Auto-Rinse Polish
................................
232
.
16 CAR AND TRUCK WASH COMPOUNDS . . . . . . . . . . . . . . . . 233 Auto and Truck Care Products Concentrated Car Wash ......................... 234 Car Wash (Automatic) .......................... 234 Power Car Wash (Self Service) .................... 234 Hand Wash and Upholstery ....................... 234 235 Car Wash Liquid ................................. Car Wash Powder ................................. 235 Carwash Shampoo-I ............................... 236 Carwash Shampoo-I1 .............................. 236 Spraywax-Drying Agent ............................ 236 High Oil Splitting Vehicle Wash-A .................... 237 High Oil Splitting Vehicle Wash-B .................... 237 Non-Phosphate Truck Wash ......................... 237 Liquid Car Wash-Formula A ........................ 238 Liquid Car Wash-Formula B ......................... 238 Spray-On Car Wash Concentrate "Grease and Grime" 238 Remover ..................................... Liquid Truck Wash ................................ 239 Non-Phosphate Truckwash .......................... 240 Self Demulsifying Truckwash ........................ 240 Transportation Cleaners. Car Wash Solids Manual ..................................... 241 Spray ...................................... 241 Commercial High Performance .................... 241 Car Wash-Liquid I ............................. 241 'Car Wash-Liquid I1 ............................ 241 Traffic Film Remover ........................... 242 Viscous Wire Wheel Cleaner ...................... 242 Glass Cleaner ................................. 242 Truck Wash Detergent Formulation-I . . . . . . . . . . . . . . . . . . 243 Truck Wash Detergent Formulation-I1 . . . . . . . . . . . . . . . . . . 243 Aluminum Truck Body CleanerBrightener-I . . . . . . . . . . . . . 243 Aluminum Truck Body CleanerBrightener-I1 . . . . . . . . . . . . . 243 Aluminum Truck Body CleanerBrightener-111 . . . . . . . . . . . . 243 Truck Wash Liquid ................................ 244 Economy Truck Wash High-Pressure Spray . . . . . . . . . . . . . . 244
.
17 WHITEWALL TIRE CLEANERS ....................... Whitewall Tire Cleaner-I ........................... Whitewall Tire Cleaner-I1 ........................... Whitewall Tire Cleaner-I . . . . . . . . . . . . . . . . . . . . . . . . . . .
245 246 246 247
Contents and Subject Index
Whitewall Tire Cleaner-I1 ........................... Liquid Whitewall Tire Cleaner-Type I . . . . . . . . . . . . . . . . . . Liquid Whitewall Tire Cleaner-Type I1 . . . . . . . . . . . . . . . . . Whitewall Tire Cleaner Liquid ....................... Whitewall Tire Cleaner Concentrate .................... Whitewall Tire Cleaner 1 ........................... Whitewall Tire Cleaner 2 won-Caustic) . . . . . . . . . . . . . . . . Whitewall Tire Cleaner 3 ...........................
xxvii
247 247 247 248 248 249 249 249
.
18 MISCELLANEOUS .................................. 250 Brake Cleaner ................................... 251 Mag Wheel Cleaner ............................... 251 Concrete Floor Cleaner ............................. 251 Liquid Aluminum Engine Block Cleaner . . . . . . . . . . . . . . . . 252 Foaming Engine Cleaner ............................ 252 Liquid Boat Polish ................................ 253 Paste Boat Polish ................................. 253 Locomotive Cleaner I .............................. 254 Locomotive Cleaner I1 ............................. 254 Locomotive Cleaner 111 ............................. 254 Polishing Cleaner for Plastic Windows . . . . . . . . . . . . . . . . . . 255 Hard-surface CleanerNax (May be Aerosol Loaded) . . . . . . . 255
..........
256
...................
276
SECTION Ilk TRADEMARKED RAW MATERIALS SECTION IV: SUPPLIERS' ADDRESSES
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Section I Household and Industrial Cleaners and Polishes
1
Bathroom Cleaners
2
Bathroom Cleaners
3
C l e a r L i q u i d Bowl C l e a n e r
WL% 3.0 20.0 77.0
M i r a n o l FBS H y d r o c h l o r i c A c i d (20Be) Water Procedure: Add t h e w a t e r . S l o w l y add t h e h y d r o c h l o r i c a c i d , Add t h e M i r a n o l FBS. M i x u n t i l u n i f o r m .
w i t h mixing.
Physical Properties: Appearance: C l e a r , l i g h t y e l l o w V i s c o s i t y : <10 c p s S p e c i f i c G r a v i t y : 1.03 pH ( a s i s ) : t l . 0 F o r m u l a t i o n BC-0001
T h i c k T o i l e t Bowl C l e a n e r M i r a t a i ne TM H y d r o c h l o r i c A c i d (20Be) Water
Procedure: Add t h e h y d r o c h l o r i c a c i d t o t h e w a t e r , w i t h s t i r r i n g . add t h e M i r a t a i n e TM and m i x u n t i l u n i f o r m . Physical Properties: Appearance: C1 e a r , ye1 l o w 1 iq u i d V i s c o s i t y : 1 . 0 3 5 cps S p e c i f i c G r a v i t y : 1.037 pH ( a s i s ) : t l . 0 Formula BC-0002
SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
uLL%
5.0 32.0 Q.S. Slowly
4
Advanced Cleaning Product Formulations
D i s i n f e c t a n t Bowl C 1 eaner F o r m u l a t i o n Name: TB-A23
Wt%
Inaredi ent : Dei o n i zed Water Tomah A c i d T h i c k e n e r * Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Tomah A m p h o t e r i c L Add, m i x w e l l Ethylene G ly c ol Add, m i x w e l l FMB-210-15 Quat (50%)* Add, m i x w e l l HCL A c i d (31.5%) Add s l o w l y , m i x w e l l , c o o l
58.19 5.00 3.00
2.00 3.00 2.88 25.93
Recommended D i l u t i o n s : 1-4 oz/bowl ( 3 / 4 g a l l o n w a t e r ) Applications: Registered d i s i n f e c t a n t formula N o t e s : M i x A c i d T h i c k e n e r p r i o r t o use i n o r d e r t o a s s u r e homogeneity *EPA R e g i s t r a t i o n No. 47371-86 and FMB-210-15 q u a t f r o m H u n t i n g t o n Chemicals Formul a A-1 00 V i s c o u s Phosphori c/HCl
A c i d C 1 eaner W B 70.00 2.00
InQredient: Water Phosphori c A c i d (75%) Add, mix. c o o l A cid Thickener* Add, m i x w e l l HC1 (37%) Add, m i x w e l l
3.00 24.40
pH: 1 . 3 0 Recommended D i 1u t i ons : 0-30 : 1 A p p l i c a t i o n s : T o i l e t bowl c l e a n i n g , v e r t i c a l s u r f a c e c l e a n i n g N o t e s : Easy m i x f o r m u l a M i x A c i d T h i c k e n e r p r i o r t o use i n o r d e r t o a s s u r e homogenei t y Formula A-1 06 SOURCE: Tomah P r o d u c t s ,
I n c . : Suggested F o r m u l a t i o n s
Bathroom Cleaners
G e n t l e A b r a s i v e L o t i o n C l e a n s e r f o r Bathroom and K i t c h e n In g r e d i en t s :
% b y Weiqht
(1) D e i o n i z e d Water
60.8
(2) Korthix H 0.2 ( 3 ) Sodium C a r b o n a t e , anhydrous 1 .o ( 4 ) T e t r a s o d i u m Pyrophosphate, anhydrous 1 .o (5).Sodium M e t a s i l i c a t e , pentahydrate 1 .o (6) K a o p o l i t e SF o r 1168 24.0 ( 7 ) CMS-7M8S ( 5 % S o l u t i o n i n W a t e r ) 10.0 (8) S y n t h r a p o l N 2.0 Procedure: D i s p e r s e i n g r e d i e n t s ( 2 ) t h r o u g h ( 7 ) , i n t h a t sequence, i n t o (l), w i t h v i g o r o u s a g i t a t i o n , a l l o w i n g t i m e f o r each t o d i s s o l v e o r d i s p e r s e t h o r o u g h l y . Reduce a g i t a t i o n t o a v o i d e x c e s s i v e f o a m i n g , s l o w l y add (8). F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Comments : I f a more v i s c o u s p r o d u c t i s d e s i r e d , i n c r e a s e ( 2 ) and ( 7 1 , k e e p i n g same r a t i o . These can be a d j u s t e d t o g i v e t h e d e s i r e d viscosity charaacteristics. Use o f K a o p o l i t e 1168 g i v e s more a g g r e s s i v e c l e a n i n g and polishing action t o the formulation. Cream C l e a n s e r % by Weiqht Ingredients: 5.0 ( 1 ) Odor1 e s s Kerosene 20.0 ( 2 ) VM&P Naphtha 9.0 ( 3 ) Oleic Acid 3.0 (4) Triethanolamine 3.0 ( 5 ) P r o p y l ene G1 y c o l 4.0 (6) T e r g i t o l N P - 1 0 40.0 ( 7 ) D e i o n i z e d Water 1.o ( 8 ) Sodium Hexametaphosphate 10.0 ( 9 ) K a o p o l i t e SF o r 1168 (10)Korthix H 5.0 Procedure: Combine ( 1 ) t h r o u g h ( 4 ) , w i t h v i g o r o u s a g i t a t i o n , c o n t i n u i n g u n t i l w e l l d i s p e r s e d . I n a n o t h e r v e s s e l , d i s p e r s e ( 5 ) , (61, ( 7 ) ’ and (8). Then d i s p e r s e (9) and (10) i n t h e m i x t u r e w i t h maximum a g i t a t i o n . Reduce a g i t a t i o n i n t h e o i l m i x t u r e t o moderate, add t h e w a t e r m i x t u r e s l o w l y , and s t i r u n t i l w e l l b l ended. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t u s e d . Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g flammable i n g r e d i e n t s . Comments : A d j u s t (1) t o g i v e c o n s i s t e n c y d e r i r e d . Use o f K a o p o l i t e 1168 g i v e s more a g g r e s s i v e c l e a n i n g and polishing action t o the formulation.
SOURCE: K a o p o l i t e ,
Inc.:
Suggested F o r m u l a t i o n s
5
6
Advanced Cleaning Product Formulations
Mixed A c i d Bath Cleaner Inoredient: Water Hydroxyacetic a c i d Add, mix Sulfamic a c i d Add, mix Tomah AO-728 Special Add, mix pH: 1.00 Recommended D i l u t i o n s : As necessary A p p l i c a t i o n s : T u b / t i l e c l e a n e r , good d e s c a l i n g Formula 8-102
W B 80.00 5.00
5.00 10.00
L i a u i d Scourina Cleanser I W B I n q r e d ie n t : 35.60 S o f t Water 0.40 Tomah OAT 1000 Add t o v o r t e x and mix w e l l u n t i l s o l u b i l i z e d 7.00 Tomah A0-728 Special Add, mix w e l l 5.00 DDBSA. Na S a l t (60%) Add, mix w e l l 2.00 Sodi um o r Potassi um C i t r a t e Add, mix w e l l 50.00 Calcium carbonate (100 mesh) Add, mix w e l l pH: 9.90 Recommended D i 1u t i ons : a s - i s A p p l i c a t i o n s : Rub and r i n s e from s u r f a c e . Notes: Creamy, v i s c o u s l i q u i d good f o r c l e a n i n g t u b / t i l e / s i n k s . W i l l s e t t l e , shake b e f o r e use. Pack i n opaque b o t t l e . Formula 8-1 04 H C l A c i d Bowl Cleaner E % I n q r e d ie n t : Water 71.40 Tomah A c i d Thickener 3.00 Add, mix w e l l H C l A c i d (37%) 25.60 Add s l o w l y , mix w e l l , cool pH: 1.30 Recommended D i l u t i o n s : a s - i s A p p l i c a t i o n s : T o i l e t bowl c l e a n i n g , v e r t i c a l s u r f a c e c l e a n i n g . Notes: Mix A c i d Thickener p r i o r t o use i n o r d e r t o assure homogenei t y Formula B-105
SOURCE: Tomah
Products,
Irte.: Suggested Formulations
Bathroom Cleaners
S o l i d A u t o m a t i c T o i l e t Bowl C l e a n e r F o r m u l a t i o n
%y&yy
Inqredi ent: Macol DNP 150 I n c r o m i de L90 Carbowax PEG 8000 Macol 27 V e r s a f l e x 207 ( d r y ) Water
25.0 25.0 20.0 20.0 5.0 5.0
Procedure: 1 . M e l t t h e Macol 27, Macol DNP 150, and Carbowax PEG 8000, and m i x t o g e t h e r . 2 . M a i n t a i n a t e m p e r a t u r e o f a b o u t 70C, and add t h e I n c r o m i d e L90 w h i l e m i x i n g . 3 . Add w a t e r and V e r s a f l e x 207 ( d r y ) and m i x . 4 . Pour f o r m u l a t i o n i n t o a mold, and a l l o w t o c o o l .
SOURCE:
N a t i o n a l S t a r c h and Chemical C o . :
R e f e r e n c e #8069:49
A c i d Bowl C l e a n e r Mackam 2CSF (Cocoamphodipropionate) H y d r o c h l o r i c A c i d (30%) Rodine 213 Water Procedure: 1 . Add components t o w a t e r . 2 . Blend u n t i l c l e a r .
SOURCE: M c I n t y r e Group L t d . :
I n d u s t r i a l Formulary
Weiqht,% 3.5 18.5 0.4 77.6
7
8
Advanced Cleaning Product Formulations
Viscous Orqanic A c i d C l e a n e r - I
Wt%
Inqredient: Water C i t r i c Acid Add, d i s s o l v e w i t h m i x i n g Tomah A c i d Thickener Add. mix w e l l Alcohol E t h o x y l a t e ( 8 mole) Add, mix w e l l S a l t (NaC1) Dissolve w i t h mixing P e r f ume* Add, mix w e l l V i s c o s i t y ( c p s ) : 816
88. DO 2.50 3.00
0.30 6.00 0.20
Viscous Oraanic A c i d C l e a n e r - I 1 W B 88.00 1.25
Inaredi ent : Water C i t r i c Acid Add, d i s s o l v e w i t h m i x i n g Tomah A c i d Thickener Add, mix w e l l Formic A c i d Add, mix w e l l Alcohol E t h o x y l a t e ( 8 mole) Add, mix w e l l S a l t (NaC1) D i s s o l v e w i t h m i x i ng P e r f ume* Add, mix w e l l V i scosi t y (cps) : 784
3.00 1.25 0.30
6.00
0.20
Viscous Organic A c i d Cleaner-I11 Wt% 88.00 3.00
Ingredient: Water Tomah A c i d Thickener Add, mix w e l l Formic A c i d Add, m 3 x w e l l Alcohol E t h o x y l a t e ( 8 mole) Add, mix w e l l S a l t (NaC1) D i s s o l v e w i t h m i x i ng Perfume* Add, mix w e l l V i s c o s i t y ( c p s ) : 556
2.50
0.30 6.00 0.20
Recommnded D i 1u t i o n s : As-i s Appl ic a t i ons : Toi 1e t bowl c l e a n e r s w i t h good c l ing t i me Notes: *Quest I n t ' l C i t r u s X004.950
SOURCE: Tomah Products,
lnc.:
Suggested Formulations
2. Dairy, Food and General Industrial Cleaners
9
I0
Advanced Cleaning Product Fotmulatiom
A c i d Cleaner
Wt.% M i r a t a i ne CBS H y d r o f l o u r i c A c i d (70%) P h o s p h o r i c A c i d (85%) Butoxyethanol Water
3.0
3.0 30.0 3.0 61 .O
Procedure: Add t h e w a t e r and M i r a t a i n e CBS. S l o w l y add t h e h y d r o f l u o r i c and p h o s p h o r i c a c i d s . Add t h e b u t o x y e t h a n o l and m i x u n t i l uniform. Physical Properties: Appearance: C l e a r s o l u t i o n pH: 3 . 1 V i s c o s i t y : t 1 0 cps S p e c i f i c G r a v i t y : 1 .17 Formula MS-0073 A 1 k a l in e A 1 1-Purpose I n d u s t r i a1 C1eaner PhosDhated. Powder TVDe
.
Sodi um T r i p o l yphosphate ( L t D e n s i t y ) Sodium Carbonate ( L t . D e n s i t y ) Sodium M e t a s i l i c a t e P e n t a h y d r a t e Rhodafac RA-600
Wt.% 52.5 20.0 22.5 5.0
Procedure: 1 . M i x Rhodafac RA-600 w i t h Sodium T r i p o l y p h o s p h a t e t o o b t a i n a u n i f o r m , powdered m i x t u r e . 2. Add Sodium M e t a s i l i c a t e and Sodium Carbonate. Physical Properties: pH ( 1 % ) : 1 1 . 4 Specific Gravity:
0.82
Formula MS-0074
SOURCE: Rhone-Poulenc: Suggested F o r m u l a t i o n s
11
Daity, Food and General Industrial Cleaners
A c i d Cleaners Foamy A c i d Dai r y C l e a n e r Inaredi ent: Water P h o s p h o r i c A c i d (75%) Add, m i x , c o o l Monosodium phosphate, monohydrate Add, d i s s o l v e , mix w e l l A m p h o t e r i c SC, A1 k a l i S u r f a c t a n t Add, m i x w e l l
W
S
32.40 17.60 45.00 5.00
SpG 20/20C: 1.47 pH: 1.67 Recommended D i l u t i o n s : 10-3O:l Applications: Dairy p l a n t cleaning Formula A-101
A l u m i n u m B r i g h t e n e r A103 W
Inaredi ent : Water A c i d Foamer Add, mix w e l l * S u l f u r i c A c i d (95%) Add, m i x w e l l H y d r o f l u o r i c A c i d (70%) Add, m i x w e l l
B
70.00 3.00 10.00 17.00
A1 u m i num B r i s h t e n e r A1 02 W B
Ingredient : Water A c i d Foamer Add, m i x w e l l * S u l f u r i c A c i d (95%) Add, m i x , t h e n c o o l Ammoni um B i f 1u o r i de Add, m i x w e l l
64.00 3.00 20.00 13.00
pH: 3 . 5 0 Recommended D i 1u t i ons : 10-30 : 1 A p p l i c a t i o n s : Truckwash, v e r t i c a l aluminum s u r f a c e c l e a n i n g N o t e s : *A p r e p a r a t i o n and u s e o f a s t o c k s o l u t i o n o f 3% g l y c o l e t h e r / 9 7 % A c i d Foamer w i l l a i d i n s o l u b i l i z a t i o n and homogeniety
SOURCE: Tomah P r o d u c t s ,
Inc.:
Suggested F o r m u l a t i o n s
12
Advanced Cleaning Product Formulations
Bui 1t Steam Cleaner I n q r e d ie n t : Water STPP D i s s o l v e , mix w e l l Na M e t a s i l i c a t e Pentahydrate Dissolve, m i x w e l l Nonionic Surfactant-HLB 13 Add, mix w e l l Tomah A l k a l i S u r f a c t a n t Add, mix u n t i l c l e a r SpG 20/20F: 1.10 pH: 10.40 Recommended D i l u t i o n s : 1 o z / g a l A p p l i c a t i o n s : I n d u s t r i a l degreasing and c l e a n i n g Formula 1-105
W B 79.00
10.00 2.00 5.00
5.00
A1 umi num Soak Tank C l eaner/Bri ahtener
I n s r e d ient: Water EDTA (39%) Add, mix w e l l KOH (45%) Add, mix w e l l 42 Sodium S i l i c a t e 3.22/1 Add, mix w e l l Nonionic Surfactant-HLB 13 Add, mix w e l l Tomah A l k a l i S u r f a c t a n t Add. mix w e l l pH: 13.50 Recommended D i l u t i o n s : 10-3O:l A p p l i c a t i o n s : p a r t s soak Formula 1-102
Wt% 51 .OO 2.00 20.00 20.00 3.00
2.00
Heavy Duty Steam Cleaner
Wt% I n q r e d ie n t : 45.00 Water 30.00 Na M e t a s i l i c a t e Pentahydrate Dissolve u n t i l c l e a r 10.00 KOH (45%) Add, mix w e l l 15.00 Tomah A1 k a l i S u r f a c t a n t Add, mix w e l l pH: 14.00 Recommended D i l u t i o n s : 20-5O:l A p p l i c a t i o n s : I n d u s t r i a l c l e a n i n g and degreasing Notes: Long term s t o r a g e should be i n p l a s t i c c o n t a i n e r s , as w i l l e t c h g l a s s Formula 1-109
SOURCE:
Tomah Products,
Inc.:
Suggested Formulations
Dairy, Food and General Industrial Cleaners
13
d - L i monene M i croernul s i on C1 e a n e r / D e a r e a s e r B u r c o TME Burco F A € D-Limonene Water
11 11 16 62
parts parts parts parts
M i x i n o r d e r l i s t e d , add w a t e r s l o w l y . P r o d u c t w i l l t h i c k e n , t h e n b r e a k as w a t e r i s added. No c o - s o l v e n t i s r e q u i r e d when m i x e d i n p r o p o r t i o n s g i v e n above. Produces a c l e a r p r o d u c t . Burco FAE i m p a r t s c o r r o s i o n r e s i s t a n c e i n a d d i t i o n t o emulsion c h a r a c t e r i s t i c s . To make a more c o n c e n t r a t e d p r o d u c t , l e s s w a t e r can be used, b u t r a t i o s o f t h e o t h e r a c t i v e s must r e m a i n s i m i l a r t o t h e above Exampl e : TME FAE d - L i monene Water
22 22 32 24
H i g h a c t i v e p r o d u c t s can r e a c h a g e l - l i k e v i s c o s i t y , be t h i n n e d w i t h I s o p r o p a n o l o r B u t y l P r o p y l s o l v .
parts parts parts parts b u t can
Heavy D u t y I n d u s t r i a l C l e a n e r Components: Water Burco NPS-225 Burco LAA-38 B u r c o TME 45% KOH K a s i l #1 TKPP
% b y Weiqht 6.5 10.0 0.75
0.75 24.0 48.0 10.0
Procedure: 1 ) D i s s o l v e B u r c o NPS-225, B u r c o LAA-38 and B u r c o TME i n w a t e r . 2 ) Add 45% KOH and b l e n d u n t i l u n i f o r m t h e n add K a s i l # 1 and blend u n t i l uniform. 3 ) Add TKPP and s t i r u n t i l f u l l y d i s s o l v e d . T h i s c o n c e n t r a t e d f o r m u l a t i o n can be used f o r a v a r i e t y o f a p p l i c a t i o n s . The b u i l d e r systam i s d e s i g n e d t o be s a f e f o r use on a v a r i e t y o f s u r f a c e s a t use d i l u t i o n s . P o s s i b l e a p p l i c a t i o n s in c l ude : I n d u s t r i a1 1 a u n d r y Equipment c l e a n i n g Vehicle cleaning O t h e r i n d u s t r i a l a p p l i c a t i o n s r e q u i r i n g a v e r y heavy d u t y detergent.
*
* * *
SOURCE:
B u r l i n g t o n Chemical Co.,
I n c . : Suggested F o r m u l a t i o n s
14
Advanced Cleaning Product Formulations
E lectrocleaner % by Weight 2-8 1-4 0.75-3 0.25-1 To 100% T o t a l
Components: Water Burco BSGH-400 Burco NPS-225 Burco TME 50% NaOH
Basic Formulating Guidelines: 1) R a t i o o f B u r c o NPS-225/Burco TME s h o u l d be 3 / 1 . 2 ) The l e v e l o f Burco BSGH-400 i s p r e f e r a b l y e q u a l t o t h e sum o f Burco NPS-225 and Burco TME. 3 ) The w a t e r c h a r g e s h o u l d be e q u a l t o t h e sum o f Burco BSGH-400, Burco NPS-225 and Burco TME. 4) Premix a l l components b u t NaOH, t h e n add NaOH w i t h s t i r r i n g . T h i s f o r m u l a t i o n w i l l p r o v i d e moderate foam l e v e l s and i s s u i t a b l e f o r use as an e l e c t r o c l e a n e r , f o o d p l a n t c l e a n e r o r o t h e r a p p l i c a t i o n s where h i g h c a u s t i c c o n c e n t r a t e s a r e used. For reduced foam l e v e l s as i n an a l k a l i n e s p r a y c l e a n e r , r e p l a c e Burco NPS-225 w i t h Burco HCS-SONF.
L o w Foam T a n k t r u c k C l e a n e r S a f e on aluminum s u r f a c e s f o r e x t e r i o r and i n t e r i o r c l e a n i n g . Stable i n hard water. % by Weiaht 26.5 19.5 39.0
Water KOH-45% K a s i l #1 STPP Burco HCS-5ONF % Solids:
8.0 7.0
31.0
Add components i n o r d e r l i s t e d . B l e n d between a d d i t i o n s . To f o r m u l a t e a l o w e r a c t i v i t y p r o d u c t , keep t h e r a t i o s o f t h e components t h e same. so t h a t t h e b a l a n c e o f t h e f o r m u l a t i o n i s n o t d e s t r o y e d . End use c o n c e n t r a t i o n s w i l l depend on d e g r e e o f s o i l t o be removed. A s l i g h t s i l i c a t e p r e c i p i t a t e may o c c u r upon l o n g s t a n d i n g .
SOURCE:
B u r l i n g t o n Chemical Co.
,
I n c . : SUQQeSted F o r m u l a t i o n s
Dairy, Food and General Industrial Cleaners
Food P l a n t C ? e a n e r s Foamy A c i d Dai r y C1 eaner Inaredi ent: Water P h o s p h o r i c A c i d (85%) Add, m i x , c o o l Monosodium phosphate, monohydrate Add, d i s s o l v e , mix w e l l Tomah A m p h o t e r i c SC Add, m i x w e l l SpG 20/20C: 1 . 4 7 pH: 1.67 Recommended D i l u t i o n s : 10-2O:l Appl ic a t i ons : Dai r y p l a n t c l e a n i ng Formula A-101
Wt% 32.40 17.60 45.00 5.00
Low Foam-Sel f Demul s i f v i na C1eaner W B I n a r e d ient : 92.20 Water 1.30 T r i s o d i um Phosphate D i ssolve 2.00 EDTA (39-40%) Mix w e l l 3.50 Tomah A m p h o t e r i c 400 Mix w e l l 1 .oo T r i t o n CF-10 Mix w e l l pH: 11.50 Recommended D i l u t i o n s : 10-2O:l A p p l i c a t i o n s : Low foam f l o o r , CIP N o t e s : D e m u l s i f i e s f o o d o i l s r a p i d l y w i t h no t r e a t m e n t Formula LF-101 Low Foam Moderate DH. S e l f D e m u l s i f y i n q Wt% Inaredient : Water 86.90 C i t r i c acid 1 .oo D i s s o l ve T r i sodium phosphate 1.30 Dissolve EDTA (39-40%) 2.00 Mix w e l l Tomah A m p h o t e r i c 400 7.80 Mix w e l l T r i t o n CF-10 1 .oo Mix w e l l pH: 8.50 Recommended D i l u t i o n s : 10-2O:l A p p l i c a t i o n s : Low foam f l o o r , C I P N o t e s : D e m u l s i f i e s f o o d o i l s r a p i d l y w i t h no t r e a t m e n t Good d e t e r g e n c y even a t l o w e r pH Formula LF-102
SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
15
I6
Advanced Cleaning Product Formulations
G r a f f i t i Remover 1
Wt%
Inaredi ent : Dei oni zed Water KOH (45%) Add, mix w e l l Sodi um g l uconate Add, mix w e l l Methanol Add, mix w e l l Ethylene g l y c o l b u t y l e t h e r Add, mix w e l l Tomah A l k a l i S u r f a c t a n t Add, mix w e l l
20.00 50.00
5.00
5.00 5.00 15.00
SpG 20/20C: 1.225 pH: 13.9 Recommended D i l u t i o n s : 1-1O:l A p p l i c a t i o n s : Removes most p a i n t , markers, e t c Formula S-103 G r a f f i t i Remover 2 Inaredi ent : S o f t Water KOH (45%) Mix w e l l Sodi um G1uconate Mix w e l l Tomah A1 k a l i S u r f a c t a n t Mix w e l l Methanol Mix w e l l Dipropylene g l y c o l methyl e t h e r Mix w e l l SpG 20/20C: 1.22 pH: 13.70 Recommended D i l u t i o n s : 10-2O:l Notes: E f f e c t i v e on most p a i n t s and i n k s Formula S-104
SOURCE: Tomah Products,
Inc.:
Suggested Formulations
Wt% 28.00 50.00
2.00 10.00
5.00 5.00
Dairy, Food and General Industrial Cleaners
I7
Heavy D u t y C l e a n e r s ( I n d u s t r i a l 1 Steam_Cle_ners-Liquids
P o t a s s i u m H y d r o x i d e (45%) S t a r s o s o d i um s i 1 ic a t e Phosphate e s t e r O c t y l p h e n o l , 7-8 moles EO
18.8% 17.2% 31 .3% 30.0% 2.3% 0.4%
Water TKPP P o t a s s i u m h y d r o x i d e (45%) S t a r s o s o d i urn s i 1 i c a t e Phosphate e s t e r C9-Cll l i n e a r a l c o h o l , 6 moles EO
34.1% 17.2% 31.1% 15.2% 2.0% 0.4%
Water TKPP
Steam
Cleaners-Powders -__-
STPP
Sodi um c a r b o n a t e C9-C10 l i n e a r a l c o h o l , 12 moles EO Metso Beads 2048 s o d i um m e t a s i 1 i c a t e STPP
C9-C10 1 in e a r a l c o h o l , 12 moles EO Sodi um g l u c o n a t e Metso Pentabead 20 sodium m e t a s i l i c a t e
SOURCE:
PQ C o r p . :
Detergent Formulary:
35% 20% 10% 3 5%
50% 3% 2% 45% Suggested F o r m u l a t i o n s
18
Advanced Cleaning Product Formulations
Heavy D u t y I n d u s t r i a l S w a y C l e a n e r C o n c e n t r a t e F-543
‘k BY. Wei s h t
40 50 10
Water Sodium H y d r o x i d e (50%) Mona NF-25 Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n Typical Properties: Cloud P o i n t : t75C K r a f f t P o i n t : (5C Recommended Use D i l u t i o n :
1 t o 4 oz./gal.
Heavy D u t y I n d u s t r i a l Spray M e t a l C l e a n e r C o n c e n t r a t e F-544 % By Weight 65 10 10 5 10
Water P o t a s s i um H y d r o x i d e Sodi um M e t a s i 1i c a t e (Anhydrous) Sodium Carbonate Mona NF-25
Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . T y p i c a l P r o p e r t i8s : Cloud P o i n t : 43C K r a f f t Point: tOC Recommended Use D i l u t i o n :
6 t o 8 oz./gal.
H i ah S o l i d s A1 k a l in e Cl-eaner F-555 Water P o t a s s i um H y d r o x i d e Sodium M e t a s i l i c a t e (Anhydrous) T e t r a p o t a s s i u m Pyrophosphate Mona NF-25
% By Weiaht 45.0 10.0 10.0 25.0 10.0
Procedure: Mix i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . SOURCE: Mona I n d u s t r i e s , I n c . :
Suggested F o r m u l a t i o n s
Dairy, Food and General Industrial Cleaners
H i g h Foamina Smokehouse C l e a n e r - I Inqredi ent : S o f t Water NaOH (50%) Add, m i x , c o o l Tomah A0-728 Speci a1 Add, m i x w e l l Tomah A m p h o t e r i c SC Add, mix w e l l N o n i o n i c Surfactant-HLB Add, mix w e l l
W B
60.70 30.00
3.00 5.30 1 .oo
13
pH: 14.50 Recommended D i 1u t ions : 5-1 0 : 1 A p p l i c a t i o n s : Food p l a n t c l e a n i n g , foam Formula 1-116-1
good e m u l s i f i c a t i o n and
H i g h Foaminq Smokehouse C l e a n e r - I 1 Inqredi ent : S o f t Water NaOH (50%) Add, mix, c o o l Tomah A0-728 S p e c i a l Add, m i x w e l l Tomah Ampohoteric N Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l
Wt%
60.40 30.00 3.00 5.60 1 .oo
pH: 14.50 Recommended D i 1u t ions : 5-1 0 : 1 A p p l i c a t i o n s : Food p l a n t c l e a n i n g , foam Formula 1-116-11
SOURCE: Tomah P r o d u c t s ,
Inc.:
good e m u l s i f i c a t i o n and
Suggested F o r m u l a t i o n s
19
20
Advanced Cleaning Product Formulations
I n d u s t r i a l Cleaners A c i d Based A 1 u m i nurn/SS C1e a n e r Inqredi ent: Water P h o s p h o r i c A c i d (85%) Add, m i x w e l l C i t r i c Acid Add, m i x w e l l A m p h o t e r i c SC o r A l k a l i S u r f a c t a n t Add, mix w e l l M e t h y l E t h y l Ketone Add, m i x w e l l SpG 20/20C: 1 . 0 3 pH: 1.2-1.4 Recommended D i 1u t i ons: 1-2 o z / g a l 1on A p p l i c a t i o n s : metal c l e a n i n g Formula 1-100
Wt% 88.00
3.00 4.00 2.00 3.00
A c i d Based M e t a l C l e a n e r W S Inaredient : 61 . O O Water 35.00 P h o s p h o r i c A c i d (85%) Add, c o o l 1 .oo Glycolic Acid Add, c o o l 3.00 Tomah A l k a l i S u r f a c t a n t Add, m i x w e l l SDG 20/20C: 1 . 1 9 pH: 0.90 Recommended D i l u t i o n s : 1-2 o z / g a l l o n A p p l i c a t i o n s : Metal cleaner N o t e s : R i n s e w e l l a f t e r wash. N e u t r a l i z e i f n e c e s s a r y Formula 1-101
L i g h t Duty N e u t r a l Cleaner Ingredient: Water Tomah AO-14-2 Add, mix w e l l Tomah P-17-2 Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l SpG 20/20F: 1 . 0 0 pH: 7 . 6 Recommended D i l u t i o n s : as i s o r 1O:l A p p l i c a t i o n s : W a l l , f l o o r , t i l e wash Notes: Good on l i g h t h y d r o c a r b o n and f o o d s o i l s Formula 1-110 SOURCE: Tomah P r o d u c t s ,
Inc.:
Suggested F o r m u l a t i o n s
W B 95.00 1 .oo
1 .oo 3.00
Dairy, Food and General Industrial Cleaners
I n d u s t r i a l Cleaners A n i o n i c/Noni o n i c G1v c o l E t h e r HSC Inaredi ent: S o f t Water TKPP Dissolve KOH (45%) Add, m i x w e l l D i p r o p y l ene g l y c o l m e t h y l e t h e r Add, mix w e l l DDBSA, Na s a l t (60%) Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Tomah A m p h o t e r i c 400 Add, m i x w e l l
W B 76.50 5.00 5.00 5.00 3.50
2.00 3.00
pH: 14.06 Recommended D i l u t i o n s : 10-3O:l A p p l i c a t i o n s : HSC N o t e s : Good foam and d e g r e a s i n g Formula 1-103 A n i o n i c / N o n i o n i c HD HSC W B 80.00 0.50
Innredi ent : S o f t Water EDTA D i s s o l ve KDH (45%) Add, m i x w e l l TKPP D i s s o l ve P o t a s s i um S i 1 i c a t e Add, m i x w e l l DDBSA, Na s a l t (60%) Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Tomah A l k a l i S u r f a c t a n t Add, m i x w e l l
5.00 3.00 3.00 3.50
2.00 3.00
pH: 13.86 Recommended D i l u t i o n s : 10-3O:l Appl ic a t ions : HSC Notes: E x c e l l e n t b u i l t c l e a n e r Formula 1-104
SOURCE: Tomah P r o d u c t s ,
Inc.:
Suggested F o r m u l a t i o n s
21
22
Advanced Cleaning Product Formulations
Low VOC Cleaners Non-Caustic I n d u s t r i a l Cleaner Inaredient: Water Na M e t a s i l i c a t e Pentahydrate D i s s o l v e completely w i t h m i x i ng EDTA 100% D i s s o l v e completely w i t h m i x i n g TKPP D i s s o l v e completely w i t h m i x i n g Tomah AO-14-2 Add w i t h m i x i n g Tomah P-14-2 Add w i t h m i x i n g Nonionic Surfactant-HLB 13 Add w i t h m i x i n g
Wt% 90.40 2.00
I .60 2.00
1 .oo 1 .oo
2.00
SpG 20/20F: 1.03 pH: 12.95 Recommended D i l u t i o n s : 10-2O:l A p p l i c a t i o n s : I n d u s t r i a1 Formula LV-I 02 Low VOC Heavy Duty Presoak I n a r e d ie n t : Water Na M e t a s i l i c a t e Pentahydrate D i s s o l v e completely w i t h m i x i n g NTA (40%) Dissolve completely w i t h mixing TKPP D i s s o l v e completley w i t h m i x i n g Tomah AO-14-2 Add w i t h m i x i n g Tomah Q-14-2 Add w i t h m i x i n g Nonionic Surfactant-HLB13 Add w i t h m i x i n g
Wt% 77.00
SpG 20/20F: 1.00 pH: 12.50 Recommended D i l u t i o n s : 10-5O:l depending on c o n d i t i o n s A p p l i c a t i o n s : Carwash presoak, soak t a n k c l e a n e r Formula LV-105
SOURCE: Tornah Products,
Inc.:
Suggested Formulations
2.00 4.00 6.00 1 .oo 3.00 3.00
23
Dairy, Food and General Industrial Cleaners Low VOC Cleaners Non S o l v e n t Medium Dutv Deareaser
3
I n q r e d ient : Water Na M e t a s i l i c a t e Pentahydrate Dissolve completely w i t h mixing TKPP D i s s o l v e completely w i t h m i x i n g NaOH (50%) Add s l o w l y w i t h m i x i n g EDTA (40%) Add s l o w l y w i t h m i x i n g Tomah AO-14-2 Add w i t h m i x i n g Tomah 9-14-2 Add w i t h m i x i n g Nonionic Surfactant-HLB 13 Add w i t h m i x i n g SpG 20/20F: 1 . 0 8 pH: 1 2 . 5 0 Recommended D i 1u t i on : 10-20 : 1 Applications: I n d u s t r i a l cleaning, Formula LV-100 Non-Solvent
86.50 2.50 1 .oo 4.50 1.50 1 .oo 1 .oo 2.00
metal, concrete,
Heavv Duty Steam Cleaner
I n n r e d ie n t : Water Na Metasi 1i c a t e Pentahydrate D i s s o l v e c o m p l e t e l y w i t h m i x i ng NaOH (50%) Add s l o w l y w i t h m i x i n g NTA ( 4 0 % ) Add s l o w l y w i t h m i x i n g Tomah AO-14-2 Add w i t h m i x i n g Tomah 9-14-2 Add w i t h m i x i n g Nonionic Surfactant-HLB 1 3 Add w i t h m i x i n g SpG 20/20F: 1 . 0 3 pH: 12.60 Recommended D i 1u t ions : 10-20 : 1 A p p l i c a t i o n s : I n d u s t r i a l steam c l e a n i n g , concrete, Formula LV-101
SOURCE:
Tomah Products,
etc
Inc.:
Suggested Formulations
Wt%
81.50 2.00 9.50 1 .oo 1 .50 1.50 3.00
metal.
etc
24
Advanced Cleaning Product Formulations
Low VOC S o l v e n t Cleaner-Isopar G I n q r e d ie n t : Exxon I s o p a r G Tomah (2-17-2 Mix w e l l Nonionic Surfactant-HLB 13 Mix w e l l Tomah E-14-2 Mix w e l l Water Add v e r y s l o w l y w i t h m i x i n g Tomah AO-14-2 Add w i t h m i x i n g Water Add v e r y s l o w l y w i t h m i x i n g Tomah A l k a l i S u r f a c t a n t Add w i t h m i x i n g
W B
7.00 3.00 2.00 3.00 65.00 2.00 18.00 q.s.
pH: n e u t r a l Recommended D i l u t i o n s : 10-3O:l A p p l i c a t i o n s : G r a f f i t i Remover, Degreaser, Cosmoline Remover Notes: F a s t e r d r y i n g than I s o p a r M formula, b u t lower f l a s h point Formula LV-104 Low VOC S o l v e n t Cleaner-Isopar M
Wt% 7.00 1 .oo
I n a r e d ie n t : Exxon I s o p a r M Tomah 0-17-2 Mix w e l l Nonionic Surfactant-HLB 13 Mix w e l l Tomah E-14-2 Mix w e l l Water Add v e r y s l o w l y w i t h m i x i n g Tomah AO-14 2 Add w i t h m i x i ng Water Add v e r y s l o w l y w i t h m i x i n g Tomah A l k a l Surfactant Add w i t h m i x i ng pH: N e u t r a l Recommended D i l u t i o n s : 10-3O:l A p p l i c a t i o n s : G r a f f i t i Remover, Degreaser. Notes: High f l a s h formula Formula LV-103
SOURCE: Tomah Products, I n c . :
2.00 4.00 66.00 2.00 17.50 0.50
Cosmoline Remover
Suggested Formulations
Dairy, Food and General Industrial Cleaners
25
S a n i t i z e r s and Food P l a n t C l e a n e r s D e t e r g e n t f o r B l o o d Removal 45-60% 35-40 3- 5 0- 3
STPP o r TSPP Sesqui c a r b o n a t e Anionic Foam s t a b i 1 iz e r To be used i n c o o l w a t e r . Food P1a n t and D a i r y D e t e r a e n t S a n i t i z e r *
5.6% 35
CDB C l e a r o n STPP Sodium m e t a s i l i c a t e anhydrous LAS (85% a c t i v e ) Sodi urn s u l f a t e EPA r e g i s t e r e d s a n i t i z e r
5
5 49.4
*
G e n e r a l Purpose S a n i t i z e r s * * A1 k a l in e 2 5% 10 65
CDB C l e a r o n STPP Sodium s u l f a t e Acidic
28% 42 30
CDB C l e a r o n Sodium s u l f a t e Monosodium p h o s p h a t e M i l d l y Acidic CDB C l e a r o n Sodi um s u l f a t e **EPA r e g i s t e r e d s a n i t i z e r s
SOURCE:
FMC Corp. : D e t e r g e n t A p p l i c a t i o n s B u l l e t i n No. 4 : Suggested F o r m u l a t i o n s
3 4% 66
26
Advanced Cleaning Product Formulations
Sani t i z e r g and Food P1a n t Cleaners General Purpose Eauipment Detergent-1 STPP Sodium m e t a s i l i c a t e anhydrous NaOH A n i o n i c or Nonionic* Soda ash
30-50% 10-20 10-20 0- 2 balance
General Purpose E q u i p m e n t - w r a e n t - I 1 STPP Sodi um metasi 1ic a t e anhydrous Ani o n i c or Noni o n i c * Soda ash *Omit a l l surfactants f o r C I P applications.
30-50% 10-15 5- 6 balance
M i l k Can Cleaners-I
30-50%
STPP Sodi um metasi 1ic a t e A n i o n i c or Nonionic CDB Clearon Soda ash
20-40 2 2- 3 balance M i 1k Can C l e a n e r - I 1
50%
STPP TSP C r y s t a l s Sesquicarbonate A n i o n i c or Nonionic
20 25 5
Soak
B o t t l e Cleaner-I 20% 0-2 1-3 10 balance
STPP or TSPP A n i o n i c or Nonionic** Sodium gluconate Soda ash NaOH
Soak B o t t l e C l e a n e r - I 1 5% 0-2 balance
TSP A n i o n i c or Nonionic** NaOH
**For spray cleaners, low foam s u r f a c t a n t r e q u i r e d . Must be compati b l e w i t h NaOH
.
SOURCE:
FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4: Suggested Formulations
Dairy, Food and General Industrial Cleaners
27
S a n i t i z e r s and Food P l a n t Cleaners Heavy Duty C h l o r i n a t e d Cleaner CDB Clearon STPP
Sodium m e t a s i l i c a t e anhydrous NaOH Soda ash o r sodium s u l f a t e
2 - 5% 30-45 10-20 5-20
balance
Heavy Duty L i q u i d C h l o r i n a t e d C l e a n e r - I Water STPP Kasi 1 #1 ( P o t a s s i um s i 1i c a t e ) KOH ( 1 0 0 % b a s i s ) Sodium h y p o c h l o r i t e ( 1 5 % s o l u t i o n )
50.1% 10.0 14.4 15.5 10.0
Heavy Duty L i q u i d C h l o r i n a t e d C l e a n e r - I 1 Water TKPP STPP
Kasi 1 #1 ( P o t a s s i um s i 1i c a t e ) KOH ( 1 00% basi s ) Sodium h y p o c h l o r i t e ( 1 5 % s o l u t i o n )
3 5% 5.0 10.5 24.0 15.5 10.0
Heavy Duty L i q u i d C h l o r i n a t e d Cleaner-I11 Water
25.0
TKPP STPP
20.0 5.5 24.0 15.5 10
K a s i l #1 (Potassium s i l i c a t e ) KOH ( 1 0 0 % b a s i s ) Sodium h y p o c h l o r i t e ( 1 5 % s o l u t i o n )
SOURCE:
FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No.4: Suggested Formulations
3. Degreasers
28
Degreasers
29
A l l Purpose A l k a l i n e Degreaser-A
Components: Water T e t r a s o d i u m EOTA ( l o o % ) * L i q u i d potassium s i l i c a t e (2.1Si02/K20)** Potassium h y d r o x i d e (50%) Sodium x y l e n e s u l f o n a t e ( 4 0 % ) * * * N o n i o n i c s u r f a c t a n t : Genapol UO 079
Wt.
%
72 4 7 2 5 10
Physical Properties: Appearance (25C): c l e a r pH ( l % , 25C): 10.8 Ross M i l e s (49C, 1%, cm): 1 min.: 3.0 5 min.: 1.0 C l o u d P o i n t ( l % / a s i s , C ) : 40/65 S u r f a c e t e n s i o n (0.25%, dynes/cm): 27.42 Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : ( 0 A1 1 Purpose A1 k a l in e Degreaser-B Components: Water T e t r a s o d i um EOTA ( 100%) L i q u i d potassium s i l i c a t e (2.1Si02/K20)** P o t a s s i um h y d r o x i d e (50%) Sodium x y l e n e s u l f o n a t e ( 4 0 % ) * * * Nonionic s u r f a c t a n t : Genapol UD 030 Genapol UO 079
*
Wt.
%
73 5 7 2 5
P h y s i c a l P r o p e r t i es : Appearance (25C): c l e a r pH ( l % , 25C): 1 0 . 8 Ross M i l e s (49C, 1%, cm): 1 m i n . : 4.0 5 m i n . : 0.5 C l o u d P o i n t ( l % / a s i s , C ) : 35/52 S u r f a c e t e n s i o n (0.25%, dynes/cm): 26.85 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C): < O Procedure: B l e n d t h e components one a t a t i m e i n t h e g i v e n o r d e r w i t h c o n t i n u o u s s t i r r i n g . Be s u r e t h e t e t r a s o d i u m EDTA i s t o t a l l y dissolved before adding t h e l i q u i d s i l i c a t e .
* ** ***
Versene 220 c r y s t a l K a s i l #6 W i t c o n a t e 1260
SOURCE: Hoechst Celanese C o r p . :
Suggested F o r m u l a t i o n s
2 6
30
Advanced Cleaning Product Formulatiom
A1 1 Purpose A1 k a l in e Desreaser-C ComDonents: Water T e t r a s o d i um EDTA ( 100%) L i q u i d p o t a s s i u m s i l i c a t e (2.1Si02/K20)** P o t a s s i um h y d r o x i d e (50%) Sodium x y l e n e s u l f o n a t e (40%)*** Nonionic s u r f a c t a n t : Genapol 26-L-2 Genapol 26-L-60
Wt.
*
Physical Properties: Appearance ( 2 5 C ) : c l e a r pH (1%’ 25C): 1 0 . 8 Ross M i l e s (49C, 1%. cm): 1 m i n . : 4.0 5 min.: 1.0 Cloud P o i n t ( l % / a s i s , C ) : 37/75 S u r f a c e t e n s i o n (0.25%. dynes/cm): 26.85 Freeze thaw s t a b l e : f r e e z i ng p o i n t (C) : f r o z e n ,
% 74 4 7 2 5
2 6
but stable
A1 1 Purpose A 1 k a l in e Depreaser-D ComDonents: Water T e t r a s o d i um EDTA ( 1 O O % ) * L i q u i d potassium s i l i c a t e (2.1Si02/K20)** P o t a s s i um h y d r o x i d e (50%) Sodium x y l e n e s u l f o n a t e (40%)*** Nonionic s u r f a c t a n t : H o s t a p a l N 040 H o s t a p a l N 090
Wt.
% 75 4 7 2 5
Physical Properties: Appearance ( 2 5 C ) : c l e a r pH (l%, 25C): 1 0 . 8 Ross M i l e s (49C, 1%. cm): 1 min.: 4.0 5 m i n . : 2.0 Cloud P o i n t ( l % / a s i s , C ) : 32/25 S u r f a c e t e n s i o n (0.25%, dynes/cm): 29.98 Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : t O Procedure: B l e n d t h e components one a t a t i m e i n t h e g i v e n o r d e r w i t h c o n t i n u o u s s t i r r i n g . Be s u r e t h e t e t r a s o d i u m EDTA i s t o t a l l y dissolved before adding t h e l i q u i d s i l i c a t e .
* ** ***
Versene 220 C r y s t a l K a s i l #6 W i t c o n a t e 1260
SOURCE:
Hoechst Celanese C o r p . :
SuOOested F o r m u l a t i o n s
2 5
Degreasers
3I
Deareasers I n d u s t r i a1 Degreaser Formulation: Kerosene Oowanol DPM ( o r 1:l PnB:DPM) g l y c o l e t h e r S i p o n i c SK condensate
Wt.%
60.0 15.0 25.0
Soray Degreaser Formulation: M i r a n o l C2M a m p h o t e r i c Sodium t r i p o l y p h o s p h a t e Sodi um m e t a s i 1ic a t e T r i s o d i um phosphate Tall o i l f a t t y acid P o t a s s i u m h y d r o x i d e (45%) Dowanol PM ( o r 1 : 1 PM:PnB) g l y c o l e t h e r Water
Wt.% 3.3 1.4
2.7 1.4 1.7 1 .o 8.5 80.0
E n g i n e C l e a n e r and Deoreaser Formulation: Monoi s o p r o p a n o l ami ne Water A t 1 as (53300 s u r f a c t a n t Dowanol OPM ( o r PnB) g l y c o l e t h e r Versene 100 c h e l a t i n g agont
Wt.% 20.0 58.0 5.0 15.0 2.0
Cosmoline Remover (Heavy o i l o r greasy-wax remover) Formu 1a t ion : Xyl ene Perchloroethylene I g e p a l CO-530 s u r f a c t a n t Dowanol DPM ( o r PnB) g l y c o l e t h e r
SOURCE: Dow Chemical Co. : Suggested F o r m u l a t i o n s
Wt.% 30.0 30.0 20.0 20.0
32
Advanced Cleaning Product Formulations
Deareaser F o r m u l a t i o n
Wt.%
Kerosene A l c o d e t MC-2000 Rhodacal 330 Butyl Cellosolve
70 10 10 10
Procedure: Add a l l i n g r e d i e n t s and mix w i t h a g i t a t i o n u n t i l homogeneous. Physi c a l P r o p e r t i es : Appearance: C l e a r , y e l l o w l i q u i d pH, 1% S o l u t i o n : 6 . 5 S p e c i f i c G r a v i t y : 0.83 V i s c o s i t y : t10 c p s Formula MC-0066
Metal Cleaner Spray W t -3
Butoxyethanol I g e p a l CO-630 Kerosene Procedure: M i x B u t o x y e t h a n o l and Kerosene t o g e t h e r . Mix t h o r o u g h l y .
20.0 20.0 60.0
Add I g e p a l CO-630.
Physical Properties: pH ( a s i s ) : 7 . 5 pH ( 1 % ) : 6 . 4 S p e c i f i c G r a v i t y : 0.96 V i s c o s i t y : 10 c p s Formula MC-0067
SOURCE: Rhone-Poulenc: Suggested F o r m u l a t i o n s
Degreasers
D-Limonene D e q r e a s e r - I
Wt%
Inqredient: Ethylene g l y c o l b u t y l ether Part A D-1 imonene P a r t A-Mix we1 1 Tomah E-14-5 P a r t A-Mix w e l l Tomah A1 k a l i S u r f a c t a n t P a r t A-Mix w e l l N o n i o n i c S u r f a c t a n t - H L B 13 P a r t A-Mix w e l l S o f t Water S l o w l y mix i n t o P a r t A EDTA (40%) Add s l o w l y w i t h m i x i n g KOH (45%) Add s l o w l y w i t h m i x i n g
15.00 3.50 3.50 5.00 2.00 69.00 1 .oo 1 .oo
SpG 20/20C: 1 . O O pH: 12.60 Recommended D i 1u t i ons : 5-20 : 1 Applications: I n d u s t r i a l cleaning,
HSC
D-Limonene D e a r e a s e r - I 1 Inqredi ent : Ethylene g l y c o l b u t y l ether Part A D-1 imonene P a r t A-Mix w e l l Tomah E-14-5 P a r t A-Mix w e l l Tomah A l k a l i S u r f a c t a n t P a r t A-Mix w e l l N o n i o n i c S u r f a c t a n t - H L B 13 P a r t A-Mix w e l l S o f t Water S l o w l y m i x i n t o Par EDTA (40%) Add s l o w l y w i t h m i x KOH (45%) Add s l o w l y w i t h mix Monoethanol ami ne Add s l o w l y w i t h m i x
15.00 3.50 3.50 5.00 2.00 68.00 1 .oo 1 .oo 1 .oo
SpG 20/20C: 1 . 0 0 p H : 12.60 Recommended D i 1u t i ons : 5-20 : 1 Applications: I n d u s t r i a l cleaning,
SOURCE: Tomah P r o d u c t s ,
Inc.:
HSC
Formula S-109
33
34
Advanced Cleaning Product Formulotiom
Heavy D u t y Deareaser Butoxy Ethanol Mackam 2CSF Sodi um Metasi 1ic a t e Pentahydrate Sodium Tripolyphosphate Trisodium Phosphate T a l l O i l F a t t y Acid KOH (45%) EDTA (40%) Deionized Water
Weiqht .% 0.0 3.5 3.0 1.5 2.5 2.0 2.1 0.3 79.0
Procedure: 1. Add components t o water and heat t o 40C. 2 . Blend u n t i l c l e a r . Heavy D u t y Deareaser Mackam 2CSF (Cocoamphodipropionate) Mackamide LLM (Laurami de DEA) TKPP Trisodium NTA (40%) C a u s t i c Potash (45%) T r i t o n X-100 Water qs t o
WeiQht.% 4.0 4.5 2.4 3.5 1.6 4.0 100.0
Procedures: Add components i n o r d e r . Heat t o 40 degrees u n t i l c l e a r . Cool and f i 11. Metal Deareaser Cleaner Mackamide CDM (Cocamide DEA (and) DEA Oleate High F l a s h Naphtha
Wei a h t .% 5.0 95.0
Procedure: Add Mackamide CDM t o Naphtha and b l e n d u n t i l c l e a r . Remarks : T h i s product can be r e a d i l y mixed w i t h water when used f o r c l e a n i n g engine b l o c k s , garage f l o o r , e t c . The r e s i d u a l Mackamide CDM a c t s as a c o r r o s i o n i n h i b i t o r .
SOURCE: M c I n t y r e Group L t d . :
I n d u s t r i a l Formulary
Degreasers
35
M i cro-Emu1 s i ons w i t h A1 oe V e r a and d-Li monene
The f o l l o w i n g f o r m u l a s a r e c l e a r , m i c r o e m u l s i o n s o f d-Limonene and A l o e V e r a . They r e p r e s e n t t h e r a n g e o f d-Limonene and A l o e Vera c o n c e n t r a t i o n s commonly used as d e g r e a s i n g s o l v e n t c l e a n e r s . These f o r m u l a s a r e g e n e r a l l y used b y d i l u t i n g i n w a t e r ( 1 - > 1 6 o z . / g a l l o n d e p e n d i n g on t h e use r e q u i r e m e n t s ) . The f o r m u l a s a r e c l e a r and e x h i b i t a bloom e f f e c t upon d i l u t i o n . & %
d - L i monene Monamul s e DL-1273 Isopropanol Water A l o e Vera Gel ( T e r r y AG002)
10.0 18.0 10.0 42.0 20.0
d - L i monene Monamul s e DL-1273 Isopropanol Water A l o e Vera Gel ( T e r r y AG002)
&% 35.0 28.0 5.0 12.0 20.0
d - L i monene Monamul s e DL-1273 A l o e Vera Gel ( T e r r y AG002)
65.0 23.0 12.0
Procedure: I n a l l cases, m i x Monamulse DL-1273 w i t h d-Limonene u n t i l c o m p l e t e l y d i s s o l v e d and o f u n i f o r m c o n s i s t e n c y . Add t h e Isop r o p a n o l , m i x i n g u n t i l homogeneous. Pre-mix A l o e Vera Gel w i t h w a t e r . S l o w l y add t o b a t c h w i t h s t i r r i n g u n t i l u n i f o r m .
SOURCE: T e r r y L a b o r a t o r i e s , I n c . : Suggested F o r m u l a t i o n s
36
Advanced Cleaning Product Formulations
Phosphate Free Cleaners G l y c o l E t h e r Deareaser-I I n n r e d ie n t : S o f t Water NaOH (50%) Add, mix w e l l Na M e t a s i l i c a t e Pentahydrate D i s s o l ve EDTA (39%) Add, mix w e l l D i p r o p y l ene g l y c o l methyl e t h e r Add, mix w e l l Tomah Amphoteric 400 Add, mix w e l l Nonionic Surfactant-HLB 13 Add, m i x w e l l
Wt% 72.00
5.00 3.00 2.00 10.00 6.00 2.00
SDG 20/20C: 1.06 pH: 12’.80 Recommended D i l u t i o n : 10-5O:l A p p l i c a t i o n s : High performance degreaser
G l y c o l Ether Deqreaser-I1
Wt%
Inqredi ent : S o f t Water NaOH (50%) Add, mix w e l l Na M e t a s i l i c a t e Pentahydrate D i s s o l ve EDTA (39%) Add, mix w e l l Ethylene g l y c o l b u t y l e t h e r Add, mix w e l l Tomah Amphoteric 400 Add, m i x w e l l Nonionic Surfactant-HLB 13 Add, mix w e l l
72.00 5.00 3.00 2.00 10.00 6.00 2.00
SpG 20/20C: 1.06 pH: 12.80 Recommended D i l u t i o n : 10-5O:l A p p l i c a t i o n s : High performance degreaser
SOURCE:
Tomah Products,
Inc.:
Formula NP-100
Degreasers
37
Solvent Cleaners G l v c o l E t h e r Cleaner 3 Inqredient: S o f t Water Sodium m e t a s i l i c a t e p e n t a h y d r a t e Dissolve EDTA (40%) Add, m i x w e l l Ethylene g l y c o l b u t y l ether Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Tomah A l k a l i S u r f a c t a n t Add, m i x w e l l
W S
83.00 5.00 2.00
5.00
3.00 2.00
SpG 20/20C: 1.04 pH: 12.50 Recommended D i l u t i o n s : 10-3O:l Appl ic a t i ons: HSC Notes: B u i l t degreaser Formula S-102 Water R i n s e a b l e D e q r e a s e r I W S 75.00 2.00
I n n r e d ie n t : Mineral S p i r i t s Tomah Q-14-2 Mix w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Mix w e l l Tomah E - 1 7 - 2 Mix w e l l Dei o n i zed w a t e r S l o w l y add and m i x w e l l
6.00
7.00 10.00
SpG 20/20C: 0.03 pH: 8.60 Recommended D i l u t i o n s : as n e c e s s a r y f o r a p p l i c a t i o n A p p l i c a t i o n s : C l e a n i n g o f heavy g r e a s e s / p a i n t / v a r n i s h Notes: Viscous cleaner f o r b e t t e r c l i n g Formula S-105 SOURCE: Tomah P r o d u c t s ,
Inc.:
Suggested A p p l i c a t i o n s
stripper
38
Advanced Cleaning Product Formulations
S o l v e n t Cleaners I s o p a r M Emulsion I n a r e d ie n t : Exxon I s o p a r M Part A Tomah Emu1s i f ie r Four P a r t A-Mix w e l l Alcohol Ethoxylate-7E0 P a r t A-Mix w e l l Ethylene g l y c o l b u t y l e t h e r P a r t A-Mix w e l l Water Add s l o w l y w i t h good m i x i n g pH: 7.00 Recommended D i l u t i o n s : 10-3O:l Appl ic a t ions : HSC Notes: U n b u i l t degreaser, e x c e l l e n t f o r heavy o i l s Formula S-115 Kerosene Emu1s i on Cleaner Inaredient : Kerosene Tomah E-14-2 Mix w e l l Tomah Q-14-2 Mix w e l l Nonionic Surfactant-HLB 13 Mix w e l l S o f t Water Add v e r y s l o w l y , mix w e l l SpG 20/20C: 0.92 pH: 9.30 Recommended D i l u t i o n s : As necessary Appl ic a t i ons: Degreaser Formul a S-112 Aci d/Sol vent C1eaner I n a r e d ie n t : Water Tomah A l k a l i Sur a c t a n t Mix w e l l Propyl ene G1y c o l Ether Mix w e l l Phosphoric A c i d 85%) Mix w e l l G1uconi c Aci d M i x we1 1 SpG 20/20C: 1.18 pH: 1.05 Recommended D i 1u t i ons : 1-1 0 : 1 A p p l i c a t i o n s : Metal b r i g h t e n e r / c l e a n e r / d e g r e a s e r Formula S-114
SOURCE: Tomah Products,
Inc.:
Suggested Formulations
Wt% 20.00 14.90 1.10
3.00 61 . O O
Wt% 35.00 14.00
3.00
3.00 45.00
W X 37.00 10.00
15.00
30.00 8.00
4. Dishwashing Detergents
39
40
Advanced Cleaning Product Formulations
A u t o m a t i c Dishwash I Inaredi ent: Water TKPP D i ssolve Na M e t a s i 1 i c a t e D i s s o l ve Na Benzoate D i ssolve Tomah A m p h o t e r i c 400 Add, m i x w e l l T r i t o n CF-10 ( o r equivalent) Add, m i x w e l l pH: 13.80 Recommended D i l u t i o n s : t y p i c a l l o a d i n g A p p l i c a t i o n s : machine dishwash. l o w foam f o r m u l a Formula D-107
Wt% 56.60 20.70 9.40 1 .oo 10.40 1.90
A u t o m a t i c Dishwash I1 Inaredient : Water TKPP Dissolve Na M e t a s i l i c a t e P e n t a h y d r a t e D i s s o l ve Na Benzoate D i s s o l ve Tomah A m p h o t e r i c 400 Add, m i x w e l l T r i t o n CF-54 ( o r e q u i v a l e n t ) Add, m i x w e l l pH: 13.40 Recommended D i 1u t i ons: T y p i c a l 1o a d i ng A p p l i c a t i o n s : A u t o m a t i c dishwash, l o w foam f o r m u l a Formula D-108
Wt% 57.10 21 .oo 9.50 1 .oo 9.50 1.90
R i n s e A i d-Commerci a1 Machine >W Inaredient : 42.50 Water 47.50 T r i t o n CF-10 Add, m i x w e l l 10.00 Tomah A m p h o t e r i c 400 Add, m i x w e l l pH: 7.00 Recommended D i l u t i o n s : 100 ppm i n f i n a l r i n s e Appl ic a t i ons: R i nse a i d in commerci a1 warewash A i d s i n w a t e r s p o t p r e v e n t i o n , Low foam Formula D-109
SOURCE: Tomah P r o d u c t s ,
Inc.:
Suggested F o r m u l a t i o n s
Dishwashing Detergents
41
A u t o m a t i c Dishwash L i q u i d Water-dei o n i zed L a p o n i t e RDS H i g h Mono S t e a r y l A c i d Phosphate C a u s t i c Soda 50% Rayon Grade L i g h t D e n s i t y Soda Ash Sodi um T r i p o l y p h o s p h a t e ( L i g h t D e n s i t y grade 0 6 7 ) Metso 2048, Sodium M e t a s i l i c a t e Anhydrous Avanel S-74 Sodi um H y p o c h o r i t e 1 2 . 5 %
Wei q h t / % 48.8% 1.6% 0.6% 2.0% 5.0% 20.0% 11 .O%
1 .O% 10.0%
Procedure: 1 . Charge t h e w a t e r and t h e L a p o n i t e RDS t o t h e m i x i n g v e s s e l and a l l o w t o s i t f o r f i v e m i n u t e s t o s t a r t t h e h y d r a t i o n t o o f the clay. 2 . S t a r t a g i t a t i o n and s l o w l y add t h e M o n o s t e a r y l Phosphate and t h e C a u s t i c Soda. M i x t h o r o u g h l y t o r e d u c e lumps. M i x t u r e w i l l be v i s c o u s . 3 . S l o w l y add t h e Soda Ash, Sodium T r i p o l y p h o s p h a t e and t h e Sodium M e t a s i l l c a t e b l e n d i n g w e l l a f t e r each a d d i t i o n . Adding t h e s e i n g r e d i e n t s w i l l p r o d u c e an e x o t h e r m i c r e a c t i o n , h e a t i n g t h e m i x t u r e t o 125-14OF. 4. A p p l y e x t e r n a l c o o l i n g and c o o l t h e m i x t u r e t o l e s s t h a n 9OF. 5 . Reduce a g i t a t i o n and add t h e Avanel S-74 and t h e Sodium Hypochlorite solution. 6. Finished f o r m u l a t i o n w i l l continue t o t h i c k e n f o r several days a f t e r t h e b l e n d i n g o p e r a t i o n i s c o m p l e t e . Packaging i n f i n a l c o n t a i n e r s s h o u l d be c o m p l e t e d as soon as p o s s i b l e .
SOURCE:
PPG I n d u s t r i e s ,
Inc.:
Suggested F o r m u l a t i o n
42
Advanced Cleaning Product Formulations A u t o m a t i c D i s h w a s h i n g Gel-I
I _nqredient.1
Weis!&
D I water Carbopol 672 r e s i n NaOH (50%) KTPP K2C03 RU Sodium S i l i c a t e (52%) Oowfax 2A-1 (45%) NaOCL (12%) pH: 12+-0.2 V i s c o s i t y : 2,500-3,500
.%-L?cLiivd 74.3 1.2 2.0 15.0 1 .o 5.0 0.5 1. o
CP ( B r o o k f i e l d RVT @ 20rpm)
A u t o m a t i c D i shwashi nQ Gel -11 Ingredient: D I water Carbopol 672 r e s i n NaOH (50%) KTPP STPP ( 1 ig h t d e n s i t y , a n h y d r o u s ) STPP ( h e x a h y d r a t e ) K2C03 RU Sodium S i l i c a t e (52%) Oowfax 2A-1 (45%) NaOCl (12%) pH: 12.0+-0.2 V i s c o s i t y : 2,500-35OOcP
Weight % ( a c t i v e ) 72.3 1.2 2.0 7.0 4.0 4.0 3.0 5.0 0.5 1 .o
( B r o o k f i e l d RVT @ 20 r p m )
Order o f A d d i t i o n : 1. U s i n g a L i g h t n i n ' M i x e r o r s i m i l a r u n i t . and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g , s c r e e n t h e Carbopol r e s i n i n t o the vortex o f t h e r a p i d l y a g i t a t i n g water (approximately 800 r p m ) . A l l o w t o m i x u n t i l homogeneous. 2 . Add NaOH and m i x u n t i l homogeneous. 3 . Add KTPP and STPP and m i x u n t i l s y s t e m i s c l e a r . 4. Add t h e r e m a i n i n g i n g r e d i e n t s i n o r d e r l i s t e d above and m i x u n t i l homogeneous.
SOURCE: B.F. G o o d r i c h Co.: CARBOPOL H i g h Performance P o l y m e r s : Suggested F o r m u l a t i o n s
Dishwashing Detergents
43
Automatic Dishwashins L i q u i d % B y Weiqht 44.5 3.0 3.0 15.0 6.0 18.0 8.5 2.0
Water G e l w h i t e GP Sodi um H y d r o x i d e (50%) Sodium M e t a s i l i c a t e Anhydrous Sodium C a r b o n a t e Sodi um T r i p o l y p h o s p h a t e Sodium H y p o c h l o r i t e (12%) Mona NF-15
Procedure: B l e n d G e l w h i t e GP i n 60C w a t e r . Add sodium h y d r o x i d e , sodium m e t a s i 1 i c a t e , s o d i um c a r b o n a t e and s o d i urn t r i p o l y p h o s p h a t e w i t h r a p i d a g i t a t i o n . Cool t o room t e m p e r a t u r e , add sodium hypoc h l o r i t e and Mona NF-15. A g i t a t e u n t i l u n i f o r m . C r y s t a l C l e a r Hand D i shwash Water Ammoni um L a u r y l S u l f a t e 28% Ammonium L a u r e t h ( 4 ) S u l f a t e (60%) M o n a t e r i c CAB-LC Mona1ux CAO-LC Nonoxynol 10
% By Weiqht 13.0 18.0 17.0 14.0 33.0 5.0
Procedure: B l e n d w a t e r , ALS, ALES-4, M o n a t e r i c CAB-LC, Monalux CAO-LC, Nonoxynol 10 and h e a t t o 40-60C. S t i r c o o l t o 35-40C and a d j u s t pH t o 6-6.5 w i t h 50% c i t r i c a c i d .
SOURCE:
Mona I n d u s t r i e s ,
Inc.:
Suggested F o r m u l a t i o n s
44
Advanced Cleaning Product Formulotions
C l e a r Hand Dishwashinn L i a u i d (25% a c t i v e s ) - A Wt.
Components: Part A: Hostapur SAS 60 Genapol ZRO L i q u i d P a r t B: Water Preservat ive Dye Perfume
%
33.3
17.9 40.6 0.1 q.s.
0.1
Physical P r o p e r t i es : V i s c o s i t y (25C. mPas): 75 Cloud P o i n t (l%, C): (-5 Procedure: Blend t h e s u r f a c t a n t components i n P a r t A . Add t h e compone n t s o f P a r t B one a t a t i m e t o P a r t A w i t h continuous s t i r r i ng. Clear Hand Dishwashinn L i a u i d (25% a c t i v e s ) - 8 ComDonents: Part A: Hostapur SAS 60 Genapol ZRO L i q u i d P a r t B: Water Preservative Dye Perfume Genagen LAB
Wt.
%
33.3 17.9 47.6 0.1 q.s.
0.1 1 .o
Physical P r o p e r t i e s : V i s c o s i t y (25C, mPas): 100 Cloud P o i n t (1%. C ) : <-5 Procedure: Blend t h e s u r f a c t a n t components i n P a r t A . Add t h e components o f P a r t B one a t a t i m e t o P a r t A w i t h continuous s t i r r i n g .
SOURCE: Hoechst Celanese Corp.: by Hoechst AG
Suggested Formulations Provided
Dishwashing Detergents
45
C l e a r Hand D i s h w a s h i n q L i q u i d (25% a c t i v e s ) - C Wt.
Components: P a r t A: H o s t a p u r SAS 60 Genapol Z R O L i q u i d P a r t B: Water Preservative Dye Perfume Genagen LAB
%
33.3 17.9 44.6 0.1 q.s. 0.1 4.0
Physical Properties: V i s c o s i t y (25C, mPas): 230 C l o u d P o i n t ( I % , C ) : (-5 Procedure: B l e n d t h e s u r f a c t a n t components i n P a r t A . Add t h e components o f P a r t B one a t a t i m e t o P a r t A w i t h c o n t i n u o u s s t i r r i n g . C l e a r Hand D i s h w a s h i n n L i q u i d (25% a c t i v e s ) - D Components: Part A: H o s t a p u r SAS 60 Genapol ZRO L i q u i d P a r t 0: Water Preservative b e Perfume Genapol 26-L-3
Wt.
%
33.3 17.9 47.6 0.1 q.s. 0.1 1.o
P h y s i c a l P r o p e r t i8s: V i s c o s i t y (25C, mPas): 90 C l o u d P o i n t ( l % , C ) : (-5 Procedure: B l e n d t h e s u r f a c t a n t components i n P a r t A . Add t h e components o f P a r t B one a t a t i m e t o P a r t A w i t h c o n t i n u o u s s t i r r i n g .
SOURCE:
Hoechst Celanese C o r p . : by Hoechst AG
SugQested F o r m u l a t i o n s Provided
46
Advanced Cleaning Product Formulations
C l e a r Hand Dishwashins L i q u i d (25% Actives)-D Wt.
Components: P a r t A: Hostapur SAS 60 Genapol ZRO L i q u i d P a r t B: Water Preservative Dye Perfume Genapol 26-L-3
%
33.3 17.9 44.6 0.1 q.s 0.1 4.0
Physical P r o p e r t i e s : V i s c o s i t y (25C, mPas): 410 Cloud P o i n t ( l % , C ) : (-5 Procedure: Blend t h e s u r f a c t a n t components i n P a r t A. Add t h e components o f P a r t B one a t a t i m e t o P a r t A w i t h continuous s t i r r i n g . C l e a r Hand Dishwashina L i q u i d (30% Actives)-A Components : P a r t A: Hostapur SAS 60 Genapol ZRO L i q u i d P a r t B: Water Preservative Dye Perfume
Wt.
%
40 21.4 30.4 0.1 q.s. 0.1
Physical P r o p e r t i 8s: V i s c o s i t y (25C. mPas): 330 Cloud P o i n t ( l % , C ) : (-5 Procedure: Blend t h e s u r f a c t a n t components i n P a r t A. Add t h e components o f P a r t B one a t a t i m e t o P a r t A w i t h continuous s t i r r i n g .
SOURCE: Hoechst Celanese Corp.: by Hoechst AG
Suggested Formulations Provided
Dishwashing Detergents
47
C l e a r Hand Dishwashinq L i q u i d (30% A c t i v e s ) - 8 Wt.
Components: P a r t A: Hostapur SAS 60 Genapol ZRO L i q u i d P a r t 0: Water Preservative Dye Perfume Genagen LAB
%
40 21.4 37.4 0.1 q.s. 0.1 1 .o
P h y s i c a l P r o p e r t i 8s: V i s c o s i t y (25C, mPas): 380 Cloud P o i n t (l%, C ) : <-5 Procedure: Blend t h e s u r f a c t a n t components i n P a r t A. Add t h e components o f P a r t B one a t a t i m e t o P a r t A w i t h continuous s t i r r i n g . C l e a r Hand Dishwashinq L i q u i d (30% Actives)-C Components: Part A: Hostapur SAS 60 Genapol ZRO L i q u i d P a r t B: Water Preservat ive Dye Perfume Genagen LAB
Wt.
%
40 21.4 34.4 0.1 q.s. 0.1 4.0
P h y s i c a l P r o p e r t ies : V i s c o s i t y (25C, mPas): 630 Cloud P o i n t (l%, C): (-5 Procedure: Blend t h e s u r f a c t a n t components i n P a r t A. Add t h e components o f P a r t B one a t a t i m e t o P a r t A w i t h continuous s t i r r i n g .
SOURCE: Hoechst Celenese Corp.: by Hoechst AG
Suggested Formulations Provided
48
Advanced Cleaning Product Formulations
C l e a r Hand D i s h w a s h i n g L i a u i d (30% A c t i v e s ) - D Wt.
Components: P a r t A: Hostapur SAS 60 Genapol ZRO L i q u i d P a r t B: Water Preservative Dy e Perfume Genapol 26-L-3
%
40 21.4 37.4 0.1 q.s. 0.1 1. o
Physical Properties: V i s c o s i t y (25C, mPas): 420 C l o u d P o i n t (l%, C ) : <-5 Procedure: B l e n d t h e s u r f a c t a n t components i n P a r t A . Add t h e components o f P a r t B one a t a t i m e t o P a r t A w i t h c o n t i n u o u s s t i r r i n g . C l e a r Hand D i s h w a s h i n g L i q u i d (30% A c t i v e s ) - E Components: P a r t A: Hostapur SAS 60 Genapol ZRO L i q u i d P a r t B: Water P r e s e r v a t iv e Dye Perfume Genapol 26-L-3
Wt.
%
40 21.4 34.4 0.1 q.s. 0.1 4.0
Physical Properties: V i s c o s i t y (25C. mPas): 610 C l o u d P o i n t ( l % , C ) : (-5 Procedure: B l e n d t h e s u r f a c t a n t components i n P a r t A. Add t h e components o f P a r t B one a t a t i m e t o P a r t A w i t h c o n t i n u o u s s t i r r i n g .
SOURCE: Hoechst Celanese C o r p . : b y Hoechst AG
Suggested F o r m u l a t i o n s P r o v i d e d
Dishwashing Detergents
49
Commercial Machine D i shwashi n g Compound-I STPP Sodi um m e t a s i 1 i c a t e anhydrous NaOH CDB C l e a r o n Soda ash
30-50% 10-20 10-20 3- 5 balance
Commercial Machine D i shwashi na Compound-I1 STPP Sodium o r t h o s i l i c a t e CDB C l e a r o n Soda ash
30-50% 40 3- 5 balance
L i u i d Machine D i shwashi n g D e t e r q e n t - I TKPP (60% solu
15-25% 35-45 0- 8 5-1 0 balance
L i q u i d Machine D i s h w a s h i n q D e t e r g e n t - I 1 STPP KOH (45% s o l u t i o n ) Potassium s i l i c a t e (Si02/K20=2:1) Sodi um h y p o c h l o r i t e ( 1 5% s o l n . ) Water SOURCE: FMC C o r p . : Suggested F o r m u l a t i o n s
10% 10-25 0- 8 5-1 0 balance
Non-DDBSA D i shwashi n a L i q u i d W% .t 60.0 Rhodacal A-246/L 10.0 Rhodapex MA-360 5.0 A1 kami de DC-212/S 4.0 Sodium X y l e n e S u l f o n a t e (40%) 1. o Opaci f ie r 20.0 Water Q.S. C i t r i c A c i d t o pH 6 . 5 - 7 . 5 Q.S. Prefume and C o l o r Procedure: 1 . Charge w a t e r and sodium x y l e n e s u l f o n a t e t o v e s s e l e q u i p p e d with agitation. 2 . Add Rhodacal A-246/L and Rhodapex MA-360 t o v e s s e l and m i x u n t i 1 uniform. 3 . Add A l k a m i d e DC-212/S and m i x as above. 4. A d j u s t pH 6 . 5 - 7 . 5 w i t h c i t r i c a c i d . 5. Add o p a c i f i e r ( o p t i o n a l ) , p e r f u m e and c o o r a n t . a s d e s i r e d . Physical ProDerties: - A p p e a r a n c e : C l e a r g o l d l i q u i d , dye and o p a c i f y t o p r e f e r e n c e . p H , as i s : 6 . 5 - 7 . 5 S p e c i f i c G r a v i t y : 1.02-1.04 V i s c o s i t y : 200-300 cps
SOURCE: Rhone-Poulenc:
Formula OW-0008
50
Advanced Cleaning product Formulations
‘Dishwash Products P e a r l e s c e n t Premi urn I 1
R % Insredient: 44.70 Water DDBSA. Na s a l t (60%) 23.50 Add, mix w e l l L a u r y l e t h e r s u l f a t e , ammonium s a l t (60%) 16.50 Add, mix w e l l L y t r o n 295 (Morton) opaci f ie r 0.10 Add, mix w e l l Euperlan PK-771 p e a r l i z e r 2.20 Add, mix w e l l 3.00 Tomah AO-728 S p e c i a l Add, mix w e l l Tomah Amphoteric N 10.00 Add, mix w e l l pH: 7.85 Recommended D i 1u t i ons: 1 o z / g a l A p p l i c a t i o n s : hand dishwash Notes: High foaming, degreasi ng, opaque premium d i shwash V i s c o s i t y 3220 cps ( B r o o k f i e l d 100 rpm s p i n d l e #5) A d j u s t v i s c o s i t y w i t h Ethanol Formula D-103A
.
Low Cost Formula I n a r e d ie n t : Water DDBSA. Na s a l t (40%) Add, mix w e l l Tomah A0-728 Speci a1 Add, mix w e l l NaCl as necessary t o t h i c k e n pH: 7.80 Recommended D i 1u t i ons : 1 oz. / g a l A p p l i c a t i o n s : Hand d i shwash Notes: Simple, lower c o s t f o r m u l a Formul a D-105 Low Cost Formula I 1 Inaredient: Water DDBSA, Na S a l t (60%) Add, mix w e l l Tomah A0-728 S p e c i a l Add, mix w e l l Tomah Amphoteric L Add, mix w e l l pH: 8.00 Recommended D i l u t i o n s : 1 o z . / g a l A p p l i c a t i o n s : hand dishwash Notes: Good, low c o s t product Formula D-106
SOURCE: Tomah Products,
Inc.:
Suggested Formulations
Wt% 25.00 65.00 10.00
Wt% 71 .OO 19.00 5.00 5.00
Dishwashing Detergents
Hand Dishwash-Premium
wt%
I n q r ed i e n t s : G1 ucopon LD-15 S u l f o t e x SXS Water
42.0 5.0 53.0
T y p i c a l P r o p e r t i es : S o l i d s , %: 26 pH, as i s : 6 . 5 - 7 . 0 V i s c o s i t y , c p s ( 2 5 C ) : 300-400 Clear Point, C: 8 Hand D i s h w a s h - I n t e r m e d i a t e Wt% 28.0 3.0 69.0
Inqredients: G1 ucopon LD-15 S u l f o t e x SXS Water T y p i c a l P r o p e r t i es : S o l i d s , %: 17 pH, a s i s : 6 . 5 - 7 . 0 V i s c o s i t y , cps (25C): Clear P o i n t , C: 8
300-400
Hand Dishwash-Economy
Wt%
InQredients: G1 ucopon LD-15 Sodium C h l o r i d e Water
15.0 0.2 04.8
Typical Properties: S o l i d s , %: 9 pH, as i s : 6 . 5 - 7 . 0 V i s c o s i t y , cps (25C) : 300-400 Clear Point, C: 8
SOURCE: Henkel C o r p . :
Glucopon S u r f a c t a n t s : Suggested Formulas
51
52
Advanced Cleaning Product Formulations
Hand D i shwashi na-Sol id - I
0-10%
STPP Ani on ic * Sesqui c a r b . Foam s t a b i 1 iz e r S a l t cake
20-40 10 J
balance Hand D i shwashi ng-Sol i d - I 1 5-10%
STPP Soap Sesqui c a r b .
balance
Anionic* Foam s t a b i 1iz e r Water
30-40% 3 balance
50-75
*Choice o f s u r f a c t a n t s h o u l d t a k e i n t o a c c o u n t s k i n s e n s i t i v i t y Automatic Dishwashina Deteraent S o f t Water STPP STPP h e x a h y d r a t e Sodi um m e t a s i 1i c a t e anhydrous N o n i o n i c (low foam) CDB C l e a r o n Soda ash, sodium s u l f a t e , s e s q u i c a r b
1520% 5-1 0 25 2.0 2.5 balance
A u t o m a t i c D i shwashi na D e t e r g e n t Hard Water STPP STPP h e x a h y d r a t e Sodium m e t a s i l i c a t e anhydrous N o n i o n i c ( l o w foam) CDB C l e a r o n Soda ash, sodium s u l f a t e , s e s q u i c a r b
SOURCE:
FMC Corp.: D e t e r g e n t A p p l i c a t i o n s B u l l e t i n Suggested F o r m u l a t i o n s
30-35% 10-1 5 25 2.0 2.5 balance
No. 4 :
Dishwashing Detergents
53
H i qh P e r f o r m a n c e D i shwash Weiqht,% 21.5 5.4 4.0 5.5 8.0 100.0
Dodecyl benzene S u l f o n i c A c i d C a u s t i c Soda (50%) Sodium L a u r e t h S u l f a t e (60%) Mackam 3 5 (Cocamidopropyl B e t a i n e ) Sodium X y l e n e S u l f o n a t e (40%) Water, Dye, F r a g r a n c e qs t o S o l i d s , %: 3 0 + - 1 . 0 pH: 6 . 5 - 7 . 0 V i s c o s i t y ( c p s , 25 d e g r e e s C . ) : Cloud P o i n t : 5 degrees C .
250-350
Procedure: 1 . Add c a u s t i c soda t o w a t e r and a d j u s t pH t o 7 . 0 - 8 . 0 w i t h DDBSA. 2. Add r e m a i n i n g components and a d j u s t pH t o 6 . 5 - 7 . 0 w i t h c i t r i c acid. 3 . I f n e c e s s a r y , l o w e r v i s c o s i t y w i t h SXS, o r r a i s e v i s c o s i t y w i t h s o d i urn- c h l o r i d e .
SOURCE: M c I n t y r e Group L t d . :
I n d u s t r i a l Formulary
Washi nn A n e n t s (Manual Use) D 41/31: Z e t e s o l 2056 Amphotensid 0 4 Z u s o l a t 1008/85 P u r t o n CFD Perfume Sodium c h l o r i d e Water, p r e s e r v a t i v e
q.s.
D 41/33: Lumorol RK Sodium c h l o r i d e Water, perfume, p r e s e r v a t i v e
50.0% a p p r o x . 1.0% q . s . t o make 100.0%
SOURCE: Zschimmer & Schwarz GmbH & C o . :
20.0% 2.0% 1 .O% 0.5% 0.1% 1.5% t o make 100.0%
Suggested F o r m u l a t i o n s
54
Advanced Cleaning Product Formulations
High-Performance Hand D i s h D e t e r s e n t
Yt&%
Wa e r 1 100 SXS, 40 3.0 C a u s t i c Soda, 50% 6.6 Dodecylbenzene S u l f o n i c A c i d 25.0 Rhodapex NA-61 8.0 A1 kamide DC-212/S 3.0 Rhodacal A-246/L 10.0 Rhodasurf 25-9 6.0 C i t r i c A c i d (50%), t o pH 8 Q.S E t h a n o l SD3A 2.0 Preservative 0.1 --Fragrance --Dve Procedure : Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h m i x i n g . M i x u n t i l u n i f o r m a f t e r each a d d i t i o n . C i t r i c A c i d and C a u s t i c Soda a r e used f o r pH a d j u s t m e n t . Physical Properties: Appearance: C l e a r g o l d l i q u i d , dyed t o p r e f e r e n c e pH, as i s : 8 V i s c o s i t y : 400 cps S p e c i f i c G r a v i t y : 1 .05 Formula DW-0013
M i l d L i s u i d Hand D i s h D e t e r g e n t W% .t
T o 100 Water C a u s t i c Soda (50%) 3 Dodecylbenzene S u l f o n i c A c i d 12 M i r a n o l CS Conc. 15 A1 kami de DC-212/S 3 Rhodasurf 25-9 3 Cheelox BF-13 0.2 C i t r i c A c i d (SO%), t o pH 8 Q.S. Fragrance Dye Procedure: Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h m i x i n g . M i x u n t i l u n i f o r m a f t e r each a d d i t i o n . C i t r i c A c i d and C a u s t i c Soda a r e used f o r pH a d j u s t m e n t . D i s s o l v e t h e dye i n w a t e r b e f o r e addition. Physical Properties: Appearance: C l e a r g o l d l i q u i d , dyed t o p r e f e r e n c e pH, as i s : 8 S p e c i f i c G r a v i t y : 1.04 V i s c o s i t y : 150 cps Formula DW-0014
-----
SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
Dishwashing Detergents
Liquid
55
D i shwasher D e t e r q e n t
~Inaredients:.
D e i o n i z e d Water Korthix H H i g h Mono S t e a r y l A c i d Phosphate C a u s t i c Soda 50% (Rayon Grade) L i g h t D e n s i t y , F i n e P a r t i c l e S i z e Soda Ash Sodi um T r i p o l y Phosphate ( L i g h t D e n s i t y Grade 067) Metso 2040 Sodium Meta S i l i c a t e Anhydrous Avanel S-74 Sodium H y p o c h l o r i t e ( 1 2 . 5 % a c t i v e )
(1) (2) (3) (4) (5) (6) (7) (8) (9)
3.0 0.6 2.0 10.0 20.0 11 . o 1. o 10.0
Procedure: S l o w l y m i x ( 1 ) and ( 2 ) under h i g h s h e a r f o r 15-20 m i n u t e s . Reduce speed o f a g i t a t i o n and s l o w l y add ( 3 ) and ( 4 ) . M i x t u r e w i l l become v e r y v i s c o u s . S l o w l y add ( 5 ) , ( 6 1 , and (7). b l e n d i n g w e l l a f t e r each a d d i t i o n . Temperature w i l l i n c r e a s e t o 125-14OF. A p p l y e x t e r n a l c o o l i n g t o r e d u c e t e m p e r a t u r e t o 9OF o r l e s s . Add ( 8 ) and ( 9 ) , b l e n d i n g w e l l a f t e r each a d d i t i o n . C o l o r a n t and f r a g r a n c e can a l s o be added as d e s i r e d . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Comments : I t i s a b s o l u t e l y n e c e s s a r y t o add i n g r e d i e n t s i n o r d e r l i s t e d , and p a r t i c u l a r l y i m p o r t a n t t o use h i g h shear a g i t a t i o n t o disperse Korthix H properly before other i n g r e d i e n t s a r e added, o t h e r w i s e l o w v i s c o s i t y , phase s e p a r a t i o n and s e v e r e s e t t l i n g o c c u r s . Use o f t h e p r o p e r g r a d e o f soda ash, sodium m e t a s i l i c a t e and sodium t r i - p o l y p h o s p h a t e i s i m p o r t a n t . Use o f t h e wrong g r a d e can cause s e p a r a t i o n , s e t t l i n g , and l o s s o f v i scosi t y
*
*
.
SOURCE:
Kaopolite,
Inc.:
Suggested F o r m u l a t i o n
56
Advanced Cleaning Product Formulations
L i a u i d Hand D i s h Deteraent
Wt.% Water C a u s t i c Soda (50%) Dodecyl benzene Sul f o n i c A c i d Rhodapex NA-61 Alkamide DC 212/S Cheel ox BF-13 C i t r i c A c i d (50%), t o pH 8 Sodium C h l o r i d e Fragrance Dye Dpaci f ie r L i a u i d Hand D i s h Deteraent
T o 100 2.5 10 4.5 1 0.5
Q.S. 1
--Wt.%
Water Caustic Soda (50%) Dodecyl benzene Sul f o n i c A c i d Rhodapex NA-61 Alkamide DC 2 1 2 / S Cheel ox BF-13 C i t r i c A c i d (50%), t o pH 8 Sodium C h l o r i d e Fragrance DY e Opaci f ie r L i a u i d Hand D i s h Deteraent
To 100 3.3 13 4.5 2 0.5
Q.S. 1
--Wt.%
To 100 Water 4.1 C a u s t i c Soda (50%) 16 Dodecylbenzene S u l f o n i c A c i d 5 Rhodapex NA-61 3 A1 kamide DC 2 1 2 / S 0.5 Cheel ox BF-13 Q.S. C i t r i c A c i d (50%). t o pH 8 1 Sodium C h l o r i d e Fragrance --Dye ODaci f ie r Procedure: Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d , w i t h m i x i n g . Mix u n t i l u n i f o r m a f t e r each a d d i t i o n . C i t r i c A c i d and C a u s t i c Soda a r e used f o r pH adjustment. Sodium C h l o r i d e b u i l d s v i s c o s i t y . D i s s o l v e i t i n water b e f o r e a d d i t i o n . D i s s o l v e t h e dye i n water b e f o r e a d d i t i o n . I f o p a c i f i e r i s used, i t should be d i l u t e d w i t h water b e f o r e a d d i t i o n . A l l pH adjustments must be completed b e f o r e t h e o p a c i f i e r i s added. P h y s i c a l P r o p e r t i 8s: Appearance: L i q u i d , c o l o r e d and o p a c i f i e d t o p r e f e r e n c e pH, as i s : 8 pH. 1%: 7.2 V i s c o s i t y : 200-4OOcps S p e c i f i c G r a v i t y : 1.02-1.05 Formula DW-0016 SOURCE: Rhone-Poulenc: Suggested Formulations
---
Dishwashing Detergents
57
L i q u i d Manual D i shwashi ne Deteraents Premi um Performance Glucopon h AES W t %
Water S u l f o t e x SXS 40 Standamid LD Standamid SD Glucopon 600 CSUP S u l f o t e x 6040s S o l i d s : 35% A c t i v e s : 29%
37 15
2 3 18 25
Glucopon
I
LAS W
Water S u l f o t e x SXS 40 Sodium LAS (60%) Standamid SD Glucopon 600 CSUP Ethanol S o l i d s : 33.5% A c t i v e s : 31 .O%
U
41
6 30
4 16 3
Economy Performance GlucoDon & AES
k %
Water S u l f o t e x SXS 40 Standamid LD Standamid SD Glucopon 600 CSUP Sul f o t e x 6040s S o l i d s : 24% A c t i v e s : 20%
57
10 1 2 10 20
Glucopon h LAS -W
Water S u l f o t e x SXS 40 Sodium LAS (60%) Standamid SD Glucopon 600 CSUP Ethanol S o l i d s : 23% A c t i v e s : 21%
58 5
20 3 12 2
Procedure: Add i n t h e o r d e r l i s t e d , d i s s o l v i n g each i n g r e d i e n t complete l y u s i n g moderate a g i t a t i o n . A d j u s t t o n e u t r a l pH w i t h c i t r i c a c i d . I n c o r p o r a t e c o l o r and f r a g r a n c e as needed.
SOURCE:
Henkel Corp.:
Suggested Formulations
58
Advanced Cleaning Product Formulations
L i q u i d Manual Dishwashina Deteraents (Based on Added Value S u r f a c t a n t Concentrates)
-_ Premium
Performance W
Water G1ucopon LD-15 S u l f o t e x SXS 40
U
53 42 5
S o l i d s : 26% A c t i v e s : 21%
____ Economy
Performance WE-%
Water G1ucopon LD-15 Sodium C h l o r i d e
84.8 15.0 0.2
Solids: 8 . 0 % A c t i v e s : 7.5% Premium Performance w i t h Amide W
Water G1ucopon AV-110 S u l f o t e x SXS 40 Standamid LD
U
37 46 12 5
S o l i d s : 34% A c t i v e s : 28% Premi urn Performance w i t h B e t a i ne Water Glucopon AV-110 S u l f o t e x SXS 40 Vel vetex BK-35
31.9 51 .o 10.0 7.1
S o l i d s : 36% A c t i v e s : 28% Procedure: Add i n t h e o r d e r 1isted, d i s s o l v i n g each ingredi e n t completely u s i n g moderate a g i t a t i o n . A d j u s t t o n e u t r a l pH w i t h c i t r i c a c i d . I n c o r p o r a t e c o l o r and f r a g r a n c e as needed.
SOURCE: Henkel Corp. : Suggested Formulations
Dishwashing Detergents
59
L i a u i d Manual D i shwashi ng D e t e r a e n t s I n t e r m e d i a t e Performance L a u r v l S u l f a t e IAES W t % 40.7 2.0
Water S u l f o t e x SXS 40 Standapol T Standapol ES-3 Standamid SD V e l v e t e x BA-35 Sodi um Chl o r i de S o l i d s : 24% A c t i v e s : 22%
20.0 25.0 4.0 7.0 1.3
Premium Performance LAS & AES Water S u l f o t e x SXS 40 Sodium LAS (60%) S u l f o t e x 6040s Standamid SD S o l i d s : 34% A c t i v e s : 32%
44 5 32 15 4
Premium Performance Glucopon IAOS W t % 22 5 3 20
Water S u l f o t e x SXS 40 Standamid SD Glucopon 600 CSUP Sodium AOS (40%) S o l i d s : 35% A c t i v e s : 33%
50
Economv Performance Glucopon & AOS Water S u l f o t e x SXS 40 Standamid SD Glucopon 600 CSUP Sodium AOS (40%) S o l i d s : 24.5% A c t i v e s : 22.5%
W
3 47 5 3 15 30
Procedure: Add i n t h e o r d e r l i s t e d , d i s s o l v i n g each i n g r e d i e n t c o m p l e t e l y u s i n g moderate a g i t a t i o n . A d j u s t t o n e u t r a l pH w i t h c i t r i c a c i d . I n c o r p o r a t e c o l o r and f r a g r a n c e as needed.
SOURCE: Henkel Corp. : Suggested F o r m u l a t i o n s
60 Advanced Cleaning Product Formulations
Low C o s t L i a u i d Dishwasher D e t e r g e n t
~~
__ I nq r ed ien t s :-
% by Wei&t 41 . 4 D e i o n i z e d Water 4.0 K a o p o l i t e AB 0.6 H i g h Mono S t e a r y l A c i d Phosphate 2.0 C a u s t i c Soda 50% (Rayon Grade) 10.0 L i g h t D e n s i t y , F i n e P a r t i c l e S i z e Soda Ash 20.0 Sodi um T r i p o l y Phosphate ( L i g h t D e n s i t y Grade 067) 11 . o Metso 2048 Sodium Meta S i l i c a t e Anhydrous 1.o Avanel S-74 10.0 Sodium H y p o c h l o r i t e ( 1 2 . 5 % a c t i v e )
(1) (2) (3) (4) (5) (6) (7) (8) (9)
Procedure: S l o w l y m i x ( 1 ) and ( 2 ) u n d e r h i g h s h e a r f o r 10-15 m i n u t e s . Reduce speed o f a g i t a t i o n and s l o w l y add ( 3 ) and ( 4 ) . M i x t u r e w i l l become v e r y v i s c o u s . S l o w l y add ( 5 ) , ( 6 1 , and ( 7 ) , b l e n d i n g w e l l a f t e r each a d d i t i o n . T e m p e r a t u r e w i l l i n c r e a s e t o 125-14OF. A p p l y e x t e r n a l c o o l i n g t o r e d u c e t e m p e r a t u r e t o 9OF o r l e s s . Add ( 8 ) and (.9), b l e n d i n g w e l l a f t e r each a d d i t i o n . C o l o r a n t and f r a g r a n c e can a l s o be added a s d e s i r e d . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Comments: I t i s a b s o l u t e l y n e c e s s a r y t o add i n g r e d i e n t s i n o r d e r l i s t e d , and p a r t i c u l a r l y i m p o r t a n t t o use h i g h shear a g i t a t i o n t o d i s p e r s e K a o p o l i t e AB p r o p e r l y b e f o r e o t h e r i n g r e d i e n t s a r e added, o t h e r w i s e l o w v i s c o s i t y , phase s e p a r a t i o n and s e v e r e s e t t l i n g o c c u r s . Use o f t h e p r o p e r g r a d e o f soda ash, sodium m e t a s i l i c a t e and sodium t r i - p o l y p h o s p h a t e i s i m p o r t a n t . Use o f t h e wrong g r a d e can cause s e p a r a t i o n , s e t t l i n g , and l o s s o f viscosity.
*
*
SOURCE: K a o p o l i t e ,
Inc.:
Suggested F o r m u l a t i o n
Dishwashing Detergents
Machine D i shwash D e t e r q e n t _ s _ L I n s t i t u t i o _ n l > L i .qujds 50.9% 6.9% 3.0% 1.2% 25.0% 13.0%
Water A c r y s o l ASE-108 T r i t o n DF-16 P o t a s s i um h y d r o x i d e (45%) TKPP (60%) N C l e a r sodium s i l i c a t e
10%
Water P o t a s s i u m h y d r o x i d e (45%) Kasi 1 # 1 p o t a s s i um s i 1 ic a t e TKPP (60%) Sodium h y p o c h l o r i t e (15%)
35% 30% 20% 5% Powders __
STPP Metso Beads 2048 sodium m e t a s i l i c a t e Sodium c a r b o n a t e Sodi um h y d r o x i d e beads ("PELS") C h l o r i n a t e d TSP
40% 20% 15% 20%
STPP Sodium c a r b o n a t e C12-Cl3 1 in e a r a l c o h o l , 5 moles EO Metso Pentabead 20 sodium m e t a s i l i c a t e
40% 2 4% 6%
SOURCE:
PQ Corp.:
Detergent Formulary:
5%
30% Suggested F o r m u l a t i o n s
61
62
Advanced Cleaning Product Formulations
Machine D i shwashi na Foraul a t i on Mazer Macol 40 Tetrasodium Pyrophosphate Sodi um T r i p o l yphosphate Sodi um Metasi 1i c a t e , Pentahydrate C h l o r i n a t e d Cyanurate Sodium Carbonate Water*
Wei s h t / % 3.0% 35.0% 25.0% 10.0% 2.0% 18.0% 12.0%
Procedure: 1. Spray a m i x t u r e o f t h e Macol 40 and water* o n t o t h e T e t r a sodium Pyrophosphate ( a l o n e o r mixed w i t h t h e o t h e r anhydrous i n o r g a n i c s a l t s ) w h i l e c o n t i n u a l l y mixing, whereby h y d r a t i o n and simultaneous a b s o r p t i o n o f t h e s u r f a c t a n t occur. 2. Add t h e hydrated Sodium M e t a s i l i c a t e t o t h e hydrated phosphates, s t i l l m i x i n g . 3. Add t h e C h l o r i n a t e d Cyanurate t o t h e m i x t u r e and c o n t i n u e m i x i n g u n t i l homogenized and a d r y , f r e e - f l o w i n g , g r a n u l a r product is o b t a i ned. C h l o r i ne-contai n i ng compounds which may a l s o be used i n t h i s process i n c l u d e t r i s o d i u m phosphate ( c h l o r i n a t e d ) , t r i c h l o r o c y a n u r i c a c i d , s a l t s o f d i c h l orocyan u r i c a c i d , dichlorodimethylhydantoin (Halane) and o t h e r o r g a n i c - a c t i v e compounds. Maximum c h l o r i n e s t a b i l i t y i s o b t a i n e d when t h e Macol 40, d i l u t e d w i t h water, i s completely absorbed by t h e phosphate m i x t u r e . Step 1 a v o i d s temperature c o n t r o l problems and e l i m i n a t e s t h e need f o r an a g i n g p e r i o d . I n s t e p 2, h y d r a t e d M e t a s i l i c a t e does n o t promote agglomera t i o n . I t i s e s s e n t i a l t h a t t h e M e t a s i l i c a t e be added a f t e r t h e phosphate m i x t u r e has hydrated and absorbed t h e s u r f a c t a n t . t o a v o i d d i s c o l o r a t i o n and degradation.
*
The amount o f water used should n o t exceed t h a t shown i n the formulation.
SOURCE:
PPG I n d u s t r i e s ,
Inc.:
Suggested Formulation
Dishwashing Detergents
63
M e c h a n i c a l D i shwashi na D e t e r g e n t L i q u i d W% .t
I g e p a l CO-730 G a n t r e z AN-149 P o t a s s i um H y d r o x i de (45% a c t iv e ) Sodium S i l i c a t e (46% a c t i v e ) A n t a r o x BL-330 T e t r a p o t a s s i u m Pyrophosphate (60% a c t i v e ) Water
0.5 1.o 3.0 17.0 3.0 63.3 12.2
Procedure: 1 . Add G a n t r e z AN-149 t o I g e p a l CO-730/Water m i x t u r e and s t i r a t room t e m p e r a t u r e u n t i l d i s s o l v e d . Heat t o 45-50C i f n o t t o t a l l y i n solution. 2 . M a i n t a i n h e a t a t 45C and add r e s t o f i n g r e d i e n t s i n d i v i d u a l l y . Physi c a l P r o p e r t ies : pH ( a s i s ) : 1 3 . 2 pH ( 1 % ) : 1 0 . 4 V i s c o s i t y : 1060 cps S p e c i f i c G r a v i t y : 1 .14 Formula DW-0010 M e c h a n i c a l D i shwashi ng D e t e r g e n t Ch 1o r in a t d
Wt.% 41 .O
Sodium Carbonate ( L t . D e n s i t y ) A n t a r o x BL-330 Sodium T r i p o o l y p h o s p h a t e , Powder Sodium M e t a s i l i c a t e P e n t a h y d r a t e C l e a r o n CDB
2.0 34.0 20.0 3.0
Procedure: Add t h e sodium c a r b o n a t e t o t h e m i x e r . Spray on t h e A n t a r o x BL 330. Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d . M i x u n t i l uniform. Physi c a l P r o p e r t i es : Appearance: W h i t e , f r e e - f l o w i n g pH ( 1 % ) : 1 1 . 2 Speci f ic G r a v i t y : 0 . 7 0
powder
Formula DW-0009
SOURCE:
Rhone-Poluenc:
Suggested F o r m u l a t i o n s
64
Advanced Cleaning Product Formulations
Premium Dishwash 1 Inaredi ent: Water SXS (40%) Add, m i x w e l l C12 D i e t h a n o l a m i d e (100%) Add, m i x w e l l COCO d i e t h a n o l ami de (80%) Add, m i x w e l l Tomah A m p h o t e r i c N Add, mix w e l l NaCl* D i s s o l ve
W X 37.00 15.00 2.00 3.00 18.00 q.s.
SpG 20/20C: 1 . 0 4 pH: 9 . 1 8 A d j u s t t o 7.0 w i t h c i t r i c a c i d Recommended D i l u t i o n s : 1 0 2 . g a l Appl ic a t i ons: V i scous h i g h qua1 it y d i shwash Notes: V i s c o s i t y 45 cps ( B r o o k f i e l d RVT 100 rpm s p i n d l e # 3 ) *Add more NaCl t o i n c r e a s e v i s c o s i t y Formula D-100 Premium Dishwash 2 Ingredient : Water Neodol 91-8 Add, m i x w e l l Tomah AO-728 S p e c i a l Add, m i x w e l l Ethanol Add, m i x w e l l Tomah A m p h o t e r i c L Add, m i x w e l l Na L a u r y l E t h e r S u l f a t e (60%) Add, m i x w e l l
W B 58.50 27.00
1.50 4.00 1 .oo
8.00
pH: 7.00 Recommended D i l u t i o n s : 1 o z . / g a l l o n A p p l i c a t i o n s : N o n i o n i c based " l o w i r r i t a t i o n " premium wash Formula D-101
SOURCE:
Tomah P r o d u c t s ,
Inc.:
Suggested F o r m u l a t i o n s
Dishwashing Detergents
65
Premium Dishwash 3 I n a r e d ie n t : Water DDBSA, Na s a l t (60%) Add, m i x w e l l L a u r y l E t h e r S u l f a t e , Na s a l t (60%) Add, m i x w e l l - w i l l g e l and t h e n t h i n Tomah A0-728 S p e c i a l Add, m i x w e l l Tomah A m p h o t e r i c SC Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Dye, Perfume
W S 61 . O O 3.00 29.00
2.00 4.00 1 .oo q.s.
SpG 20/20C: 1 . 0 2 pH: 8 . 4 0 Adjust t o 7.0 w i t h c i t r i c a c i d Recommended D i 1u t i ons: 1 o z . / g a l A p p l i c a t i o n s : Hand dishwash N o t e s : C l e a r f o r m u l a , e x c e l l e n t d e g r e a s i n g power V i s c o s i t y 40 c p s ( B r o o k f i e l d RVT 100 rpm S p i n d l e # 3 ) Formula D-102 Premium Dishwash 4 Inpredient: Water DDBSA, Na S a l t (90%) D i ssolve Lauryl ether s u l f a t e , Add, m i x w e l l C i t r i c acid D i ssolve SXS (40%) Add, m i x w e l l Ethanol Add, m i x w e l l Tomah A0-728 Speci a1 Add, m i x w e l l
% & q.s. 16.00 Na s a l t (60%)
1.oo 3.00 5.00
3.00
8.00 Recommended D i 1u t ions : 1 o z / g a l A p p l i c a t i o n s : H i g h f o a m i n g premium d i s h Formula D-104 pH:
SOURCE: Tomah P r o d u c t s ,
8.00
.
Inc.:
Suggested F o r m u l a t i o n s
66 Advanced Cleaning Product Formulatiom Prerni urn Hand D i shwash Formula-1 Inqredients: Glucopon AV-110 S u l f o t e x SXS Standamid LM Water Typical Properties: S o l i d s , %: 36 A c t i v e s , %: 28 pH, as i s : 6 . 5 - 7 . 0 V i s c o s i t y , cps (25C): 100-200 C l e a r P o i n t , C: 12 Prerni urn Hand D i shwash Forrnul a-2 Inaredients: G1 ucopon AV- 110 S u l f o t e x SXS Standamid LD Water T y p i c a l P r o p e r t i 8s : S o l i d s , %: 34 A c t i v e s , %: 28 pH, as i s : 6 . 5 - 7 . 0 V i s c o s i t y , cps (25C): 150-250 Clear P o i n t , C: 5 Prerni urn Hand D i shwash Forrnul a-3 Inqredi ents : G1ucopon AV-110 S u l f o t e x SXS V e l v e t e x BK35 Water Typical Properties: S o l i d s , %: 38 A c t i v e s , %: 28 pH, as i s : 6 . 5 - 7 . 0 V i s c o s i t y , c p s (25C): 100-200 C l e a r P o i n t , C: 8 Prerni urn Hand D i shwash Formul a-4 Inqredients: Glucopon AV-110 S u l f o t e x SXS Standami d LAO Water T y p i c a l P r o p e r t i 8s: S o l i d s , %: 34 A c t i v e s , %: 28 pH, a s i s : 6.5-7.0 V i s c o s i t y , cps (25C): 200-300 C l e a r P o i n t , C: 5 SOURCE:
Henkel Corp.:
Glucopon S u r f a c t a n t s :
W B 51 .O 15.0 2.5 31.5
Wt% 46.0 12.0 5.0 37.0
K% 51 .O 10.0 7.1 31.9
Q 51 .O 10.0 8.3 30.7
Suggested Formulas
5. General Purpose Cleaners
67
68
Advanced Cleaning Product Formulations
A l l Purpose C l e a n e r
Wei a h t / % 5% 5% 1% 10% 7 9%
Mazer Maphos 91 Mazer Mazon 60T Mazer Mazamide 70 Sodi um T r i p o l yphosphate Water A l l Purpose C l e a n e r
Wei s h t / % 25.0% 5.0% 1 .O% 1 .O% 1 .O% 67.0%
Mazer Macon 41 Mazer Macol 48 P i n e O i l (steam d i s t i l l e d ) Mazer Mazon 7 1 A Versene Water Heavv D u t y A 1 k a l in e C l e a n e r
Wei Q h t / % 59.0% 10.0% 20.0% 1 .O% 4.0% 4.0% 2.0%
Water Sodi urn M e t a s i 1 i c a t e Sodium Carbonate Sodium Benzoate Mazer Macol 25 Mazer Maphos 66H Mazer Macol 48 A1 k a l in e Powder C1eaner Sodi um T r i p o l y p h o s p h a t e Sodium M e t a s i l i c a t e (Anhydrous) Sodium Carbonate Sodi um H y d r o x i d e Mazer Macol LF-110 Procedure: For h i g h p r e s s u r e spray,
SOURCE:
Wei q h t / % 24.0% 24.0% 24.0% 24.0% 4.0%
use l e v e l i s 1-4 ounces p e r g a l l o n .
PPG I n d u s t r i e s , Lnc.:
Suggested F o r m u l a t i o n s
General Purpose Cleaners
Ammoniated G e n e r a l Purpose H o u s e h o l d Detercaent
Mackami de CO-8 (Cocami de OEA) Sodium T r i p o l y p h o s p h a t e 60 Dense Mackadet 40K ( P o t a s s i u m Coconut Soap) TSPP Ammonia (29%) Water qs t o
Weiqht,% 8.0 5.0 4.3
3.0 0.5 100.0
Procedure: 1 . Add components ( e x c e p t ammonia) t o w a t e r . 2. B l e n d u n t i l c l e a r . 3 . Cool t o room t e m p e r a t u r e and add ammonia. Remarks : Use a p p r o x i m a t e l y 1 / 4 cup t o 1 / 2 p a i l w a t e r . Butyl Cleans Mackam 2CSF ( C o c o a m p h o d i p r o p i o n a t e ) Butyl Cellosolve Sodium C a r b o n a t e Water
Wei g h t .% 5.0 10.0 2.0 83.0
Procedure: 1 . Add components i n o r d e r . 2 . Heat t o 40 d e g r e e s C . and b l e n d u n t i l c l e a r . B u t y l C1e a n e r Mackam 2CSF ( C o c o a m p h o d i p r o p i o n a t e ) B u t y l C e l l o s o l ve Nonoxvnol 9 . 5 Sodium M e t a s i 1 ic a t e 5H20 TKPP Water Procedure: 1 . Add components t o w a t e r . 2 . Heat t o 50 d e g r e e s C . and b l e n d u n t i l c l e a r . 3 . Cool and f i l l . SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a l F o r m u l a r y
Weiqht .% 5.5 3.8 1.5
3.8 3.8 81.6
69
70
Advanced Cleaning Product Formulations
Ammoni a t e d L i q u i d General Purpose D e t e r g e n t - I 5-10% 1 .o 8.0 3.0 balance
TKPP
NH4C1 Anionic Hydrotrope Water
Ammoniated L i a u i d General PurDose D e t e r q e n t - I 1 5-10% 1.o 8.0 balance
TKPP
NH4C1 Noni oni c Water
Ammoniated L i q u i d General Purpose Deterclent-I11 10-15% 4.0 5.0 1. o balance
TKPP
Anionic Ammoni um hydroxide Foam s t a b i 1iz e r Water Scourinn Powder-I
0.6 10.0 4.0 3.5 balance
CDB 90 Soda ash STPP* A n i o n i c (40% a c t i v e ) Silica flour
Scourina Powder-I1 CDB Clearon Soda ash STPP* A n i o n i c (40% a c t i v e ) Silica flour *STPP enhances c h l o r i n e s t a b i l i t y .
1. o 10.0 4.0 3.5 balance May be e l i m i n a t e d i n
phosphate r e s t r i c t e d areas.
SOURCE: FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4 : Suggested Formulations
General Purpose Cleaners
A l l Puroose B l e a c h C l e a n e r Wei a h t
6.0 5.0 3.0 100.0
Sodium H y p o c h l o r i t e (35%) Mackamine CO (Cocamine O x i d e ) TKPP Water, q s t o Procedure: Add components t o w a t e r and b l e n d u n t i l c l e a r . A l l Puroose C l e a n e r W&i Mackam 2CSF ( C o c o a m p h o d i p r o p i o n a t e ) TKPP TSPP KOH (45%) Low R o s i n T a l l O i l F a t t y A c i d Water
g h t ,% 10.0 5.0 5.0 4.0 10.0 66.0
Procedure: 1 . D i s s o l v e TKPP and TSPP a t 70 degrees C . 2. Add KOH. 3. D i s p e r s e T a l l O i l F a t t y A c i d . 4. Cool t o 50 degrees C . and s l o w l y add Mackam PCSF Remarks : The f i n a l p r o d u c t w i l l be a c l e a r v i s c o u s l i q u i d w i t h a pH between 9 . 5 and 1 0 . 5 . A l l Purpose V e q e t a b l e O i l SoaD Mackadet 40K ( P o t a s s i u m Coconut Soap) Mackamide S (Soyamide OEA) T e t r a s o d i um EOTA (40%) M a c k s t a t DM (OMDM H y d a n t o i n ) Sodium C h l o r i d e q s t o 200 c p s D e i o n i z e d Water, Dye, F r a g r a n c e qs t o Procedure:
1 . Add Mackadet 40K and Mackamide S t o w a t e r . 2. 3. 4. 5.
Heat t o 50 d e g r e e s C . w i t h a g i t a t i o n . Blend u n t i l c l e a r . Cool t o 40 d e g r e e s C . and add r e m a i n i n g components A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e .
SOURCE: M c I n t y r e Group L t d . :
I n d u s t r i a l Formulary
Wei g h t .% 35.0
8.0 5.0 qs
100.0
71
72 Advanced Cleaning Product Formulations Heavy D u t y A l l Purpose Cleaner-A Components: Water Sodium x y l e n e s u l f o n a t e (40%) E t h y l e n e g l y c o l monobutyl e t h e r Nonionic Surfactant: H o s t a p a l N 090 Soda ash ( g r a d e 100) T e t r a s o d i u m EDTA (40%)
Wt.
% 73 8 5
8 2 4
Physical Properties: Appearance (25C): c l e a r D e n s i t y ( l b / g a l ) : 8.73 pH ( l % , 25C): 1 0 . 7 Ross M i l e s (49C, 1%, cm): 1 min.: 7 5 min.: 2 C ) : 55 C l o u d P o i n t (l%, S u r f a c e t e n s i o n (0.25%, dynes/cm): 32.14 V i s c o s i t y , B r o o k f i e l d (25C, L V # l , 100rpm, c p s ) : 5.1 Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : D i d n o t f r e e z e Procedure: B l e n d t h e components i n t h e g i v e n o r d e r w i t h c o n t i n u o u s stirring. Heavy D u t y A l l Purpose Cleaner-B Components: Water Sodium x y l e n e s u l f o n a t e (40%) E t h y l e n e g l y c o l monobutyl e t h e r Nonionic S u r f a c t a n t : Genapol UD 079 Soda ash ( g r a d e 100) T e t r a s o d i u m EDTA (40%)
Wt.
Physical Properties: Appearance (25C): c l e a r D e n s i t y ( 1b / g a l ) : 8 . 7 0 pH ( l % , 25C): 1 0 . 2 Ross M i l e s (49C, 1%, cm): 1 m i n . : 11 5 min.: 2 Cloud P o i n t ( l % , C ) : 53 S u r f a c e t e n s i o n (0.25% dynes/cm): 28.17 V i s c o s i t y , B r o o k f i e l d (25C. LV#1, lOOrprn, c p s ) : 5 . 8 Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : D i d n o t f r e e z e Procedure: B l e n d t h e components i n t h e g i v e n o r d e r w i t h c o n t i n u o u s stirring.
SOURCE: Hoechst Celanese C o r p . :
Suggested F o r m u l a t i o n s
% 72
General Purpose Cleaners
73
Heavy D u t y A l l Purpose Cleaner-C Components: Water Sodi um x y l e n e s u l f o n a t e (40%) E t h y l e n e g l y c o l monobutyl e t h e r Nonionic Surfactant: Genapol 26-L-75 Soda ash ( g r a d e 100) T e t r a s o d i u m EDTA (40%)
Wt.
%
73 8 5 8 2 4
Physical Properties: Appearance ( 2 5 C ) : c l e a r D e n s i t y ( 1b / g a l ) : 8 . 6 6 pH ( l % , 25C): 1 0 . 7 Ross M i l e s (49C, 1%, cm 1 m i n . : 11 5 min.: 8 C l o u d P o i n t ( l % , C ) : 60 S u r f a c e t e n s i o n (0.25%, dynes/cm): 27.80 V i s c o s i t y , B r o o k f i e l d ( 5C, L V # l , 100 r p m , c p s ) : 5 . 1 F r e e z e thaw s t a b l e : f r e e z i n g p o i n t ( C ) : D i d n o t f r e e z e Procedure: B l e n d t h e components i n t h e g i v e n o r d e r w i t h c o n t i n u o u s
Heavy D u t y A l l Purpose Cleaner-D Components : Water Sodium x y l e n e s u l f o n a t e ( 4 0 % ) E t h y l e n e a l v c o l monobutvl e t h e r Non; o n i c S u i f a c t a n t : Genapol 26-L-60 Soda ash ( g r a d e 1 0 0 ) T e t r a s o d i um EDTA (40%)
Wt.
Physical Properties: Appearance ( 2 5 C ) : c l e a r D e n s i t y ( 1b / g a l ) : 8.71 pH ( l % , 25C): 1 0 . 7 Ross M i l e s (49C, 1%, cm 1 min.: 9 5 min.: 4 C l o u d P o i n t ( l % , C ) : 60 S u r f a c e t e n s i o n (0.2596, dynes/cm): 29.42 V i s c o s i t y , B r o o k f i e l d ( 5C, L V # l , 100rpm, c p s ) : 6 . 4 F r e e z e t h a w s t a b l e : f r e e z i n g p o i n t (C ) : D i d n o t f r e e z e Procedure: B l e n d t h e components i n t h e g i v e n o r d e r w i t h c o n t i n u o u s s t i rring.
SOURCE:
Hoechst Cel anese Corp. : Suggested F o r m u l a t i o n s
% 73 8 5 8
2 4
74
Advanced Cleaning Product Formulations Heavy Duty A l l PurDose Cleaner-€
Wt. % Components: 73 Water Sodium xylene s u l f o n a t e (40%) Ethylene g l y c o l monobutyl e t h e r Nonionic S u r f a c t a n t : Genapol 26-L-5 Genapol 26-L-75 Soda ash (grade 100) Tetrasodium EDTA (40%) Physical P r o p e r t i e s : Appearance (25C): c l e a r D e n s i t y (1b / g a l ) : 8.71 pH (l%, 25C): 10.7 Ross M i l e s (49C, 1%, cm): 1 min.: 9 5 min.: 6 Cloud P o i n t ( l % , C ) : 60 Surface t e n s i o n (0.25%, dynes/cm): 29.49 V i s c o s i t y , B r o o k f i e l d (25C, LV#1, 100rpm, cps): 5.1 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C): D d n o t f r e e z e Procedure: Blend t h e components i n t h e g i v e n o r d e r w t h continuous stirring.
Heavy Duty A l l PurDose Cleaner-F Wt. % ComDonents: 72 Water Sodium xylene s u l f o n a t e (40%) Ethylene g l y c o l monobutyl e t h e r Nonionic S u r f a c t a n t : Genapol UD 050 Genapol UD 079 Soda ash (grade 100) Tetrasodium EDTA (40%) Physi c a l P r o p e r t i es : Appearance (2%): c l e a r D e n s i t y ( l b / g a l ) : 8.67 pH (l%, 25C): 10.7 Ross M i l e s (49C, 1%, cm): 1 min.: 7 5 min.: 2 Cloud P o i n t ( l % , C ) : 50 Surface t e n s i o n (0.25%, dynes/cm): 27.62 V i s c o s i t y , B r o o k f i e l d (25C. LV#l, 10Drpm. c p s ) : 5 . 8 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C): D i d n o t f r e e z e Procedure: Blend t h e components i n t h e g i v e n o r d e r w i t h continuous stirring.
SOURCE: Hoechst Celanese Corp.:
Suggested Formulations
General Purpose Cleaners
Heavy D u t y C l e a n e r Mackamide CDM (Cocamide DEA ( a n d ) DEA O l e a t e ) TSP TKPP Sodium M e t a s i l i c a t e Sodium LAS (60% S l u r r y ) Sodi um X y l ene S u l f o n a t e (40%) Water
Weiqht,% 8.0
5.0 3.0 2.0 2.0 2.0 78.0
Procedure: 1 . B l e n d components and h e a t t o 50 d e g r e e s C . 2 . Blend u n t i l c l e a r . Remarks: T h i s f o r m u l a was d e s i g n e d f o r heavy d u t y c l e a n i n g on f l o o r wax s t r i p p i n g . I t can b e m o d i f i e d f o r s t r i p p i n g c r o s s l i n k e d p o l y m e r s b y a d d i n g 5 p e r c e n t b u t y l c e l l o s o l v e and 2 p e r c e n t ammonia. G e n e r a l Purpose C l e a n e r Wei s h t ,%
3.0
TSP TKPP Mackamide CDM (Cocamide DEA ( a n d ) DEA O l e a t e ) Water
2.0
8.0 87.0
Procedure: 1 . Add components t o w a t e r and h e a t t o 50 degrees C . 2. Blend u n t i l c l e a r . Neutral Cleaner Wei a h t .% 8.0
T a l l O i l F a t t y Acid P o t a s s i u m H y d r o x i d e (45%) Mackam 2CSF D i e t h y l e n e G1 y c o l EDTA (40%) Pine O i l Water
3.3 2.0 2.5
2.0 0.6 82.6
Procedure: 1 . Add components t o w a t e r and b l e n d . 2 . A d j u s t p H t o 7.0-8.0 w i t h KOH o r T a l l O i l F a t t y A c i d .
SOURCE: M c I n t y r e Group L t d . :
I n d u s t r i a l Formulary
75
76
Advanced Cleaning Product Formulations
Non C a u s t i c A l l PurDose C l e a n e r Inaredi ent : Water
W B 81 . O O 10.00
TKPP D i s s o l ve
Na M e t a s i l i c a t e Anhydrous D i s s o l ve Tomah A l k a l i S u r f a c t a n t Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l SpG 20/20F: 1 . 1 2 pH: 12.50 Recommended D i l u t i o n s : 10-3O:l Applications: hard surface cleaning Formula 1-111 Non-Caustic
2.00
>W 80.00 10.00
8.00 2.00
Steam C l e a n e r
Inaredi ent : Water Na M e t a s i l i c a t e P e n t a h v d r a t e D i s s o l ve STPP D i s s o l ve N o n i o n i c S u r f a c t a n t - H L B 13 Mix w e l l Tomah A l k a l i S u r f a c t a n t Mix w e l l SpG 20/20F: 1.10 pH: 10.40 Recommended D i l u t i o n s : 10-5O:l A p p l i c a t i o n s : Hard s u r f a c e c l e a n i n g and d e g e a s i n g Formula 1-114
SOURCE: Tomah P r o d u c t s ,
2.00
Powder
Inaredient: Soda Ash STPP B l e n d w e l l i n powder b l e n d e r N o n i o n i c S u r f a c t a n t - H L B 13 Spray a p p l y o r b l e n d w e l l Tomah A l k a l i S u r f a c t a n t Spray a p p l y o r b l e n d w e l l Recommended D i l u t i o n s : 1 oz/5 g a l A p p l i c a t i o n s : I n d u s t r i a l d e g r e a s i n g and c l e a n i n g Notes: O p t i c a l b r i g h t e n e r s u s e f u l a t 0.01% Dye a t 0.02%, i f d e s i r e d Formula 1-112 Non-Caustic
5.00
I n c . : Suggested F o r m u l a t i o n s
W B 79.00 1 .oo
10.00
5.00 5.00
General Purpose Cleaners
77
Non-Phosphate A l l Purpose C l e a n e r Components: Water 45% KOH B u r c o s p e r s e AP L i q u i d Sodium X y l e n e S u l f o n a t e s 40% Sodi um C i t r a t e Dodecylbenzene S u l f o n i c A c i d B u r c o TME B u t y l Propasol Varsol o r Mineral S p i r i t s
% by Weiqht
77.15 0.75 3.00 3.40
1 .oo
1.75 6.00 6.00 0.95
Procedure: Add components i n t h e o r d e r l i s t e d . B l e n d u n t i l u n i f o r m between each a d d i t i o n . O i 1 S p l it t i n q G e n e r a l Purpose C l e a n e r Components: Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e B u r c o ADS-40 B u r c o TME B u r c o LAA-38 B u r c o EHS
%-by
Weight 82.5 5 2.5 5 2.5 2.5
Procedure: Add components i n t h e o r d e r l i s t e d . B l e n d u n t i l f u l l y d i s s o l v e d between each a d d i t i o n . T h i s i s a use as i s f o r m u l a t i o n f o r heavy d u t y c l e a n i n g . For l i g h t e r d u t y a p p l i c a t i o n s , d i l u t i o n w i t h w a t e r may be p o s s i b l e . T h i s f o r m u l a t i o n w i l l suspend o i l t o a s s i s t w i t h r e m o v a l . The suspended o i l w i l l t h e n f l o a t f o r easy r e m o v a l . S o u r c e : B u r l i n g t o n Chemical Co.,
Inc.:
Suggested F o r m u l a t i o n s
6. Glass Cleaners/Polishes
78
Glass CleanerslPolkhes
Ammoni a t e d G l a s s C1e a n e r Inaredient: Water EDTA (40%) Add, m i x w e l l Tomah AO-14-2 Add, m i x w e l l N o n i o n i c S u r f a c t a n t (NP-6 t y p e ) Add, m i x w e l l Aqua ammonia ( 2 6 ) Add, b o t t l e , cap
W B
93.00 1 .oo
3.00 1.oo 2.00
SpG 20/20C: 1 . O O pH: 11.20 Recommended D i 1u t i ons : a s - i s A p p l i c a t i o n s : Spray g l a s s c l e a n e r N o t e s : Good foam, good c l e a n i n g Formula G-1 00 Glass Cleaner I
Wt%
Inaredient : Water Acetic Acid (Glacial) Add, m i x w e l l Tomah AO-14-2 Add, m i x w e l l
95.50 2.50 2.00
p H : 4.30 Recommended D i l u t i o n s : a s - i s A p p l i c a t i o n s : Spray g l a s s c l e a n e r N o t e s : good foam, good c l e a n i n g Formula G-101 L o w VOC/Non A c i d G l a s s C l e a n e r Insredient: Water Tomah 9-17-2 (PG) Add, m i x w e l l Tomah AO-14-2 Add, m i x w e l l Nonionic Surfactant-HLB
Wt% 99.80 0.05 0.05 0.10
13
pH: N e u t r a l Recommended D i 1u t i ons: a s - i s A p p l i c a t i o n s : Spray g l a s s c l e a n e r , N o t e s : Good foam, good c l e a n i n g F o r m u l a G-102 SOURCE: Tomah P r o d u c t s ,
Inc.:
c a r o r home
Suggested F o r m u l a t i o n s
79
80
Advanced Cleaning Product Formulations
Cleaner/Polish for Glass % by Wei g h t 4.75 0.25 73.9 10.0 10.0 1.o 0.1 q s.
Ingredients: ( 1 ) D e i o n i z e d Water ( 2 ) Carbopol 934 ( 3 ) D e i o n i z e d Water ( 4 ) K a o p o l i t e SF o r 1168 ( 5 ) Odorless M i n e r a l S p i r i t s ( 6 ) Kessco PEG-600 M o n o l a u r a t e ( 7 ) Dowicide A ( 8 ) Ammonium H y d r o x i d e
Procedure: S l u r r y ( 2 ) i n ( 1 ) w i t h i n t e n s i v e a g i t a t i o n , s t i r t h e mix u r e i n t o (3). Add ( 4 ) w i t h good a g i t a t i o n , c o n t i n u a l l y u n t i l smoothly d i s p e r s e d . Add ( 5 ) . ( 6 ) and ( 7 ) w i t h c o n t i n u i n g a g i t a t i o n . Add ( 8 ) t o a d j u s t pH t o 7.2-7.5. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s of each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g f 1ammable in g r e d i e n t s . Comments: Use o f K a o p o l i t e 1168 g i v e s more a g g r e s s i v e c l e a n i n g and polishing action t o t h e formulation. D r v Powder C l e a n i n g Conmound. Low A q q r e s s i v e Type Insredients: ( 1 ) K a o p o l i t e 1168 ( 2 ) A e r o s i l 200 ( 3 ) Avanel-S 74 ( 4 ) Sodium D i c h l o r o - s - T r i a z i n e
T r i o n e Dyhydrote
% bv Weight 91 . o 5.0 2.0 2.0
Procedure: Dry b l e n d ( 1 ) and ( 2 ) . Add (3) and ( 4 ) . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used.
SOURCE:
Kaopol it e ,
I n c . : Suggested F o r m u l a t i o n s
Glass CleanersIPolishes
81
G l a s s C1e a n e r -~ Ammonia Economical.
Wt.% 94.60 0.15 5.00 0.25
Water Rhodacal DSB Butoxyethanol Ammonium H y d r o x i d e (28%) Dye
----
Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and m i x u n t i l u n i f o r m . P h y s i c a l P r o p e r t i es : Appearance: C l e a r l i q u i d , dye t o p r e f e r e n c e pH ( a s i s ) : 1 0 . 5 pH ( 1 % ) : 9 . 0 Specific Gravity: 0.99 V i s c o s i t y : t10 cps Formula GC-0017
-_ Glass
Cleaner Ammon ia Heavy-Duty
Htv% Water Rhodacal DSB Butoxyet hanol Ammonium H y d r o x i d e (28%) Dye
88.70 0.30 10.00 1.oo
Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m Physical Properties: Appearance: C l e a r l i q u i d , dye t o p r e f e r e n c e pH ( a s i s ) : 1 0 . 8 pH ( 1 % ) : 9 . 7 Specific Gravity: 0.99 V i s c o s i t y : >10 c p s Formula GC-0017
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
----
82
Advanced Cleaning Product Formulations
G l ass Cleaner V i neaar Economical Wt% . 94.85 0.15 5.00 To pH=4
Water Rhodacal DSB Butoxyethanol Acetic Acid Dye
----
Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r l i q u i d , dye t o p r e f e r e n c e pH ( a s i s ) : 4 . 0 pH ( 1 % ) : 3.5 S p e c i f i c G r a v i t y : 0.99 V i s c o s i t y : < I 0 cps Formula GC-0018 G1 a s s C l e a n e r V i nesar Heavy-Duty
Wt.% 89.70 0.30 10.00 To pH=4
Water Rhodacal DSB Butoxyethanol Acetic Acid Dye
----
Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r l i q u i d , dye t o p r e f e r e n c e pH ( a s is): 4.0 pH ( 1 % ) : 3 . 5 Speci f ic G r a v i t y : 0 . 9 9 V i s c o s i t y : t10 cps Formula GC-0018
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
Glass CleanerslPolishes
G l a s s C l e a n e r (L P o l i s h E x c e l l e n t f o r c l e a n i n g a u t o m o b i l e w i n d s h i e l d s , household windows, r e f r i g e r a t o r s , s t o v e t o p s , and k i t c h e n c o u n t e r s u r f a c e s . I t removes g r e a s e and d i r t and i s easy t o wipe o f f because o f t h e l u b r i c i t y p r o v i d e d by t h e s i l i c o n e f l u i d . T h i s formulation also provides a n t i - f o g properties. P e r c e n t by Weiaht 0.5 4.0 10.0
Incjredi e n ts : Dow C o r n i n g 193 S u r f a c t a n t Dowanol EB G l y c o l E t h e r I s o p r o p a n o l (91%) Water ( d e i o n i z e d )
85.5
Preparation: 1 . D i s s o l v e Dow C o r n i n g 193 S u r f a c t a n t i n t h e i s o p r o p a n o l and glycol ether. 2 . Add t h i s s o l u t i o n t o t h e w a t e r . Use I n s t r u c t i o n s : T h i s p r o d u c t s h o u l d be a c l e a r l i q u i d . I t s grease-removing and c l e a n i n g power can be s l i g h t l y improved by a d d i n g a s m a l l amount o f o r g a n i c s u r f a c t a n t such as T r i t o n W-30. The p r o d u c t can be s p r a y e d o n t o s u r f a c e s w i t h a mechanical s p r a y a p p l i c a t o r d e v i c e o r f r o m a p l a s t i c squeeze b o t t l e . I t s h o u l d be wiped o f f i m m e d i a t e l y w i t h a d r y , l i n t - f r e e c l o t h . F o r m u l a t i o n E2-7247 G l a s s C l eaner-Pol is h Part: A B C D
E
Ingredient: 200 F l u i d - 2 0 c s Oleic Acid Isopar H Morphol ine Water Water Snowf 1oss Water Carbopol 934, 2%
P e r c e n t by Weisht 1.5 2.5 10.0 1.5 10.0
22.0 10.0 35.0
5.0
Method : When b l e n d i n g p a r t " A " on a h i g h - s h e a r m i x e r such as an Eppenbach, s l o w l y add p a r t "€3." Add p a r t s "C," and "D" and "E" i n t h a t order w i t h continued a g i t a t i o n .
SOURCE:
Dow C o r n i n g Corp.:
Suggested F o r m u l a t i o n s
83
84
Advanced Cleaning Product Formulations
Glass Cleaners A1 1-PurDose Glass C1 eaner
Wt.%
Formulation: Water Ammonium hydroxide (28%) P l u r o n i c L-10 polymer Dowanol PnB g l y c o l e t h e r
92.4 2.5 0.1 5.0
Notes : Mix components n t h e o r d e r l i s t e d . Cleaners should be c l e a r and c o l o r l e s s . All-Purpose Glass Cleaner
Wt.% 91.85
Formulation: Water Duponol C s u r f a c e a c t i v e agent Dowanol PnB g l y c o l e t h e r Dowanol DPnB g l y c o l e t h e r P l u r o n i c L-10 polymer Colloidal S i l i c a
0.05 3.0 2.0 0.1 3.0
Notes : Combine f i r s t two components and s t i r t o d i s s o l v e s o l i d s . Add remaining components i n o r d e r l i s t e d . Cleaner should be c l e a r and c o l o r l e s s . All-Purpose Glass Cleaner.
L i a u i d Spray
Wt.%
Formulation: Dowanol PM ( o r DPM o r PnB) g l y c o l e t h e r Propylene g l y c o l Isopropanol Water A1 1-PurDose G1ass C1eaner Formulati on: Dowanol PM ( o r 1:l PM:PnB) Ammonium hydroxide P l u r o n i c F 108 polymer Water
SOURCE: Dow Chemical Co.:
.
5.0 5.0 35.0 55.0 L i a u i d SDrav
Wt.% glycol ether
Suggested Formulations
8.0 1.5 0.1 90.4
Glass CleanersIPolishes
85
I n d u s t r i a l Glass Cleaner Wei Q h t / % 75% 3% 5% 5% 3% 4% 3%
Water Mazer Macol NP 9 . 5 Sodi urn D i hydrogen Phosphate Mazer Macol 212 Mazer Mazon DDBSA Mazer Mazawet DF I s o p r o p y l Alcohol Procedure: Mix i n o r d e r o f l i s t i n g . M u l t i - F e a t u r e Glass Cleaner
Wei s h t / % 10-15% 85% 1.75% 0.25%
I s o p r o p y l Alcohol Water Mazer Macol 19 Mazer M a s i l 1066C G1ass C1eaner
Weight/% 89.1% 0.2% 0.2% 0.5% 10.0%
Water Mazer M a s i l 1066C Mazer Mazawet DF Mazer Macol 212 Isopropyl Alcohol
SOURCE: PPG I n d u s t r i e s , I n c . :
Suggested F o r m u l a t i o n s
7. Hard Surface Cleaners
86
Hard Surface Cleaners
A b r a s i v e H a r d S u r f a c e Cleaner-A % 59.9 4.5 5.4 0.1 0.1 30
Wt.
Components: Water (40-5OC) Hostapur SAS 60 Genapol UD 030 Preservative Perfume Calcium carbonate Physical Properties: V i s c o s i t y ( s p i n d l e RVT, p H : 10.0
mPas):
1700
A b r a s i v e Hard S u r f a c e Cleaner-B Wt. % 49.9 4.5 5.4 0.1 0.1 40
Components: Water (40-5OC) H o s t a p u r SAS 60 Genapol UD 030 Preservative Perfume Cal c i um c a r b o n a t e P h y s i c a l P r o p e r t ies : V i s c o s i t y ( s p i n d l e RVT, pH: 1 0 . 0
mPas): 2800
A b r a s i v e Hard S u r f a c e Cleaner-C % 39.9 4.5 5.4 0.1 0.1
Components: Water (40-5OC) Hostapur SAS 60 Genapol UD 030 Preservative Perfume Calcium carbonate P h y s i c a l P r o p e r t i 8s: V i s c o s i t y ( s p i n d l e RVT, pH: 1 0 . 0
Wt.
50 mPas) : 6400
Procedure: Add a m i x t u r e o f t h e t w o s u r f a c t a n t s t o w a t e r . A l l o w t h e w a t e r t o c o o l t o 30C and c o n t i n u e t o add t h e o t h e r components i n t h e given order.
SOURCE: Hoechst Celanese C o r p . :
Suggested F o r m u l a t i o n s
87
88
Advanced Cleaning Product Formulations
D-Limonene Based C l e a n e r - I Ingredient : 01 Water d - L i monene Carbopol ETD-2001 r e s i n P r o p y l ene G1 y c o l Glycerine Neodol 25-7 Germaben I I E NaOH (18%)
Wt.%
(active1 67.5 25.0 0.5 2.0 3.0 0.5 0.8 0.7
V i s c o s i t y ( c P s , RVT @ 20rpm, 25C): 56,000 Appearance: Opaque 1o t i on S t a b i l i t y : Pass 4+ weeks @ 50C, 5 c y c l e s o f f r e e z e / t h a w D-Limonene Based C l e a n e r - I 1 Inqredi ent: D I Water d-Limonene Pemulen T R - I r e s i n P r o p y l ene G l y c o l Glycerine Neodol 25-7 Germaben I I E NaOH (18%)
Wt.%
(active) 68.2 25.0 0.2 2.0 3.0 0.1 0.8 0.7
V i s c o s i t y (CPs, RVT @ 20rpm, 25C): 8,600 Appearance: Opaque l o t i o n S t a b i l i t y : Pass 4+ weeks @ 50C. 5 c y c l e s o f f r e e z e / t h a w Procedure: 1 . P l a c e t h e d - l i m o n e n e i n a beaker and add t h e Carbopol o r Pemulen r e s i n t o t h e s o l v e n t . ( S i f t i n g t h e r e s i n i n t o t h e s o l v e n t i s recommended b u t n o t r e q u i r e d . ) 2 . U s i n g moderate a g i t a t i o n p r o v i d e d b y a L i g h t n i n ' M i x e r ( o r s i m i l a r t y p e ) and a m a r i n e - t y p e i m p e l l e r , add t h e w a t e r t o t h e s o l v e n t phase and m i x f o r a p p r o x i m a t e l y 10 m i n u t e s . 3. Mix t h e propylene g l y c o l , g l y c e r i n e . nonionic s u r f a c t a n t and p r e s e r v a t i v e . Add t o t h e s o l v e n t / w a t e r m i x t u r e . 4 . Add t h e 18% NaOH u n t i l t h e f o r m u l a t i o n r e a c h e s pH 6 . 0 . The q u a n t i t y o f NaOH l i s t e d i n t h e f o r m u l a t i o n s i s a p p r o x i m a t e and may r e q u i r e s l i g h t a d j u s t m e n t t o a c h i e v e t h e d e s i r e d pH. Characteristics: Pemul en r e s i n s p r o v i d e e f f ic i e n t and s t a b 1 e emu1 s i f ic a t i on o f d - l i m o n e n e s o l v e n t i n w a t e r l e s s hand c l e a n e r s and h a r d surface cleaners A b r a s i v e s , such as pumice, can be suspended i f d e s i r e d .
* *
SOURCE: B.F. G o o d r i c h Co.: CARBOPOL H i g h Performance Polymers: Suggested F o r m u l a t i o n s
Hard Surface Cleaners
89
D-Li monene Based C1 e a n e r - I I 1 W t .% ( a c t i v e ) I n s r e d i en= D I Water 68.2 25.0 d - L i monene Pemulen T R - 2 r e s i n 0.2 2.0 P r o p y l ene G1 y c o l 3.0 Glycerine 0.1 Neodol 25-7 0.8 Germaben I I E 0.7 NaOH (18%) V i s c o s i t y (cPs, 2 5 C ) : 3,400 Appearance: Opaque l o t i o n S t a b i l i t y : Pass 4 t weeks @ 50C, 5 c y c l e s o f f r e e z e / t h a w Procedure: 1 . P l a c e t h e d - l i m o n e n e i n a b e a k e r and add t h e Carbopol o r Pemulen r e s i n t o t h e s o l v e n t . ( S i f t i n g t h e r e s i n i n t o t h e s o l v e n t i s recommended b u t n o t r e q u i r e d . ) 2. U s i n g moderate a g i t a t i o n p r o v i d e d b y a L i g h t n i n ' M i x e r ( o r s i m i l a r t y p e ) and a m a r i n e - t y p e i m p e l l e r , add t h e w a t e r t o t h e s o l v e n t phase and m i x f o r a p p r o x i m a t e l y 1 0 m i n u t e s . 3. M i x t h e p r o p y l e n e g l y c o l , g l y c e r i n e , n o n i o n i c s u r f a c t a n t and p r e s e r v a t i v e . Add t o t h e s o l v e n t / w a t e r m i x t u r e . 3. Add t h e 18% NaOH u n t i l t h e f o r m u l a t i o n r e a c h e s pH 6 . 0 . The q u a n t i t y o f NaOH l i s t e d i n t h e f o r m u l a t i o n i s a p p r o x i m a t e and may r e q u i r e s l i g h t a d j u s t m e n t t o a c h i e v e t h e d e s i r e d pH. Characteristics: Pemulen r e s i n s p r o v i d e e f f i c i e n t and s t a b l e e m u l s i f i c a t i o n o f d - l i m o n e n e s o l v e n t i n w a t e r l e s s hand c l e a n e r s and h a r d surface cleaners. A b r a s i v e s , such as pumice, can be suspended i f d e s i r e d . Low Foaming L i q u i d C l e a n e r w i t h A b r a s i v e Wt.% las is) Innredient: DM Water 62.1 Ethanol 2.0 0.6 Carbopol 6 7 4 r e s i n NaOH (50%) 1 .o NaHC03 1.2 G e o r g i a M a r b l e W h i t e #8 30.0 Neodol 2 5 - 3 2.5 N i n o l GR (80%) 0.6 Fragrance q.s. Procedure: 1 . Add t h e e t h a n o l t o t h e w a t e r . ( H o l d o u t a p o r t i o n o f t h e w a t e r f o r S t e p 3.) 2 . U s i n g moderate ( 8 0 0 rpm) a g i t a t i o n p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , s c r e e n t h e Carbopol r e s i n i n t o t h e e t h a n o l / w a t e r s o l u t i o n . M i x t h e s o l u t i o n f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i 1 t h e d i s p e r s i o n is homogeneous. 3. P r e p a r e a n e u t r a l i z i n g s o l u t i o n o f water/NaOH/NaHCOB. Add i t t o t h e Carbopol r e s i n d i s p e r s i o n and m i x u n t i l homogeneous. 4. Add t h e a b r a s i v e and s u r f a c t a n t t o t h e s o l u t i o n and mix u n t i l homogeneous. Add f r a g r a n c e a s d e s i r e d . SOURCE: B . F . G o o d r i c h Co.: CARBOPOL P o l y m e r s : Suggested Formulas
* *
90
Advanced Cleaning Product Formulations
D-Limonene H a r d - s u r f a c e C l e a n e r ___________. D-Limonene C o n c e n t r a t e Component: D-Li monene A l c o d e t HSC-1000 I g e p a l CO-720 M i r a n o l FBS T r i e t h a n o l ami ne Water
20.0 30.0 30.0 19.0 1 .o
---
Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r , g o l d l i q u i d S p e c i f i c G r a v i t y : 1.02 V i s c o s i t y : 110 cps pH, as i s : 1 0 . 0 Formula HS-0093 D-Lirnonene H a r d - s u r f a c e C l e a n e r A1 1-Purpose Spray C1eaner Type ( 1 :9 D i 1u t i on) ComDonent: D-Limonene A l c o d e t HSC-1000 I g e p a l CO-720 M i r a n o l FBS T r i e t h a n o l a m i ne Water
W
a 2.0 3.0 3.0 1.9 0.1 90.0
Procedure: D i l u t e c o n c e n t r a t e 1 : 9 w i t h w a t e r o r c h a r g e "Vessel A" w i t h D-Limonene, A l c o d e t HSC-1000, and t h e n I g e p a l CO-720. M i x u n t i l u n i f o r m . Charge a s e p a r a t e "Vessel B" w i t h w a t e r , t r i e t h a n o l a m i n e and M i r a n o l FBS. M i x u n t i l u n i f o r m . F i n a l l y , add t h e c o n t e n t s o f "Vessel A " t o "Vessel 8'' and mix u n t i l u n i f o r m . Physi cal P r o p e r t ies : Appearance: C1 e a r , 1ig h t ye1 1ow 1iq u i d Speci f ic G r a v i t y : 1 .OO V i s c o s i t y : <10 cps pH, as i s : 9 . 5 Formula HS-0093
SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
Hard Surface Cleaners
91
D-Limonene H a r d - s u r f a c e C l e a n e r s Heavy-Duty D e q r e a s e r Type [1:3 D i l u t i o n 1 W% .t
Component: D - L i monene A l c o d e t HSC-1000 I g e p a l CO-720 M i r a n o l FBS T r i e t h a n o l ami ne Water
5.0 7.5 7.5 4.75 0.25 75.0
Procedure: D i l u t e c o n c entrate 1:3 w i t h water o r b l e n d i n g r e d i e n t s i n t h e same manner a s s p e c i f i e d i n t h e s p r a y c l e a n e r p r o c e d u r e . Physi c a l P r o p e r t i es : Appearance: C l e a r , y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1 .OO V i s c o s i t y : 110 cps pH: 9 . 5 Formula HS-0093 D-Limonene A 1 1-Purpose C l e a n e r Component: Water Sodium Metasilicate-Pentahydrate M i r a n o l FBS R h o d a s u r f 91-6 Cheel ox BF-13 A1 kami de DC-212/M D-Limonene
W % .t 73.5 2.0 10.0 3.5 5.0 3.0 2.0
Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and m i x u n t i l u n i f o r m . P h y s i c a l P r o p e r t i es : Appearance: S l i g h t l y hazy, pH, as i s : 1 2 . 5 S p e c i f i c G r a v i t y : 1.02 V i s c o s i t y : <10 cps
yellow 1 quid
Formula HS-0033
SOURCE:
Rhone-Poulenc:
Suggested Formu a t i ons
92
Advanced Cleaning Product Formulations
Economi c a l P i ne O i 1 Hard-Surf ace C 1 eaner W% .t Component: Pine O i l 5.0 Rhodasurf BC-840 10.0 Water 85.0 Procedure: 1 . Add Rhodasurf BC-840 t o Pine O i l . Mix w e l l . Heat t o approxi m a t e l y 35-40C t o o b t a i n homogeneous s o l u t i o n . 2 . Add water and mix t h o r o u g h l y . Physical P r o p e r t i 8s: Appearance: C l e a r , water-white l i q u i d pH, as i s : 3.08 S p e c i f i c G r a v i t y : 0.99 V i s c o s i t y : 110 cps Formula HS-0037
Heavy-Duty
Cleaner Powder
Wt.% Trisodium Phosphate o r Sodium Carbonate 40 10 Sodi um S i 1ic a t e Rhodacal DS-10 20 Sodium S u l f a t e 30 Q.S. Fragrance Procedure: Add i n g r e d i e n t s i n o r d e r l i s t e d t o powder b l e n d e r . Mix u n t i l uniform. Physical P r o p e r t i es : Appearance: White, f r e e - f l o w i n g powder pH, 1% s o l u t i o n : 10.8 Formula HS-0039 D-Limonene E m u l s i f i a b l e Concentrate
Wt.% Comoonent: D-Li monene 80.0 Rhodacal IPAM 15.0 4.0 I g e p a l CO-720 Triethanolami ne 1 .o Procedure: Blend i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m . Physical P r o p e r t i 8s: Appearance: Clear, y e l l o w l i q u i d S p e c i f i c G r a v i t y : 0.9 V i s c o s i t y : t 1 0 cps pH, as i s : 10.0 Note: Product forms m i l k y w h i t e emulsions when d i l u t e d w i t h water Formula HS-0094 SOURCE:
Rhone-Poul enc: Suggested Formulation
Hard Surface Cleaners
93
G e n e r a l PurDose H a r d - s u r f a c e C l e a n e r s S o l v e n t - F r e e Non-Phosphate Type Component: wt-% Water 83.5 Sodium M e t a s i l i c a t e P e n t a h y d r a t e 2.0 R h o d a s u r f 91-6 7.5 Cheel ox BF-13 3.0 M i r a n o l FBS 4.0 Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and m i x u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r , I t . y e l l o w S p e c i f i c G r a v i t y : 1.035 V i s c o s i t y : t 1 0 cps pH, as i s : 1 2 . 3 Solvent-Free
Phosphate Type
Componm W % .t Water 85.5 Sodium M e t a s i l i c a t e P e n t a h y d r a t e 2.0 Rhodasurf 91 -6 7.5 Cheelox BF-13 3.0 Rhodafac RA-600 2.0 Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r , w a t e r - w h i t e Speci f ic G r a v i t y : 1 .012 V i s c o s i t y : t10 cps pH, as i s : 11.85 Heavy-Duty S o l v e n t Type Component: Wt.% Water 8 _3 _ . 0. Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1. o R h o d a s u r f 91-6 6.0 Cheel ox BF-13 2.0 M i r a n o l FBS 2.0 Butoxyethanol 6.0 Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and m i x u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r , w a t e r - w h i t e Speci f ic G r a v i t y : 0.994 V i s c o s i t y : t10 c p s pH, as i s : 12.20
SOURCE:
Rhone-Poulenc:
Formula HS-0034
94 Advanced Cleaning Product Formulations General Purpose SDrav-and-WiDe
Cleaner Wt.%(as
I n a r e d i en:t 01 Water Carbopol ETO-2691 T e t r a s o d i um EOTA Sodium M e t a s i l i c a t e ( a n h y d r o u s ) Dowanol PM Neodol 25-7
90.7 0.2 2.0 2.3 3.0 1.5
V i s c o s i t y : 120 CP pH: 1 2 . 3 C1 e a r - t o - h a z y v i scous 1iq u i d Procedure: 1 . Combine Carbopol ETO-2691 w i t h t h e d e i o n i z e d w a t e r . 2. M i x u n t i l a homogeneous d i s p e r s i o n i s o b t a i n e d . 3. Combine t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d t a k i n g c a r e t o mix t h o r o u g h l y a f t e r each a d d i t i o n . Characteristics: Leaves s u r f a c e s c l e a n and b r i g h t P r o v i d e s v e r t i c a l c l ing--doesn ' t r u n down Reduces m i s t i n a i r
*
* *
M o l d and M i l d e w Remover Wt.%(as i s ) 84.5 1. o 2.0 0.5 5.0 7.0
Inaredie n c
DI Water Carbopol 672 NaOH (50%) Sodium M e t a s i l i c a t e P e n t a h y d r a t e B i o t e r g e PAS-8S Sodium H y p o c h l o r i t e ( 1 5 % ) V i s c o s i t y : 120 CP pH ( a s i s ) : 12.5 Opaque, v i s c o u s l i q u i d
Procedure: 1 . Combine Carbopol 672 w i t h t h e d e i o n i z e d w a t e r . M i x u n t i l a homogeneous d i s p e r s i on is o b t a i ned. 2. N e u t r a l i z e t h e d i s p e r s i o n w i t h NaOH. M i x w i t h moderate (800-1 200rpm) a g i t a t i o n . 3 . Add sodium m e t a s i l i c a t e p e n t a h y d r a t e and m i x u n t i l d i s s o l v e d . 4 . Add B i o t e r g e PAS-8S t o t h e m i x t u r e . 5. Add sodium h y p o c h l o r i t e t o t h e m i x t u r e . Reduce t h e m i x i n g speed t o p r e v e n t s p l a s h i n g as a sudden d r o p i n v i s c o s i t y w i l l occur. Characteristics: P r o v i d e s v e r t i c a l c l in g - - d o e s n ' t r u n down Removes m i l d e w s t a i n s and soap scum e f f e c t i v e l y by p r o l o n g ing contact time Prevents splashing Reduces m i s t i n a i r SOURCE: B.F. G o o d r i c h Co.: CARBOPOL Polymers: Suggested Formulas
* *
*
*
Hard Surface Cleaners
Glycol Ether Cleaner 1 >W
Inqredient: Water EDTA (39.0%) Add, m i x w e l l Sodi um G1 u c o n a t e Add, m i x w e l l 42 Sodium S i l i c a t e 3.22/1 Add, m i x w e l l KOH (45%) Add, m i x w e l l Ethylene g l y c o l b u t y l ether Add, m i x w e l l Tomah A l k a l i S u r f a c t a n t Add, m i x w e l l Nonionic-HLB 13 Add, m i x w e l l
66.00
1 .oo
1
10.00 10.00
5.00 5.00 2.00
SpG 20C/20C: 1 .17 pH: 12.90 Recommended D i l u t i o n s : 12-3O:l A p p l i c a t i o n s : HSC, g r i l l c l e a n e r , Formula S-1 00
etC
G l y c o l E t h e r Cleaner
2 Wt% 60.00 3.00
Inqredient : S o f t Water Sodi um G1 u c o n a t e Add, m i x w e l l Ethylene g l y c o l b u t y l ether Add, m i x w e l l Noni o n i c-HLB 13 Add, m i x w e l l Tomah A l k a l i S u r f a c t a n t Add, m i x w e l l KOH (45%) Add, m i x w e l l
8.00 1
Tomah P r o d u c t s ,
Inc.:
.oo
8.00
20.00
SpG 20/20C: 1.095 pH: 13.5 Recommended D i 1u t i ons : 10-30 : 1 A p p l i c a t i o n s : HSC Formula S-1 01
SOURCE:
.oo
Suggested F o r m u l a t i o n s
95
96 Advanced Cleaning Product Formulations
Hard Surface Cleaners A l l Purpose Cleaner W t % 93 3 2 2
Water Sodi urn Metasi 1ic a t e T r i sodi urn Phosphate Glucopon 425 CS A l l Purpose Cleaner w i t h Solvent
Water Sodium Metasi 1i c a t e T r i sodi urn Phosphate Propylene G l y c o l n B u t y l Ether Glucopon 425 CS
WE_% 91.5 2.0
1. o 3.5 2.0
P i n e O i l Cleaner % &
15 5 5 4
Pine O i l T r y c o l 5963 Sul f o t e x 6040s Glucopon 425 CS I s o p r o p y l Alcohol T r i ethanol ami ne Water
8 3 60 Heavy Dutv Deareaser W
Water TKPP Sodi urn Metasi 1ic a t e Potassi urn Hydroxide (45%) Glucopon 425 CS Propylene G l y c o l n B u t y l Ether
U 72 4 3 10 8 3
Procedure: Add i n t h e o r d e r 1isted, d i s s o l v i n g each i n g r e d i e n t completely u s i n g moderate a g i t a t i o n . I n c o r p o r a t e c o l o r and f r a g r a n c e as needed.
SOURCE: Henkel Corp. : SugQested Formul a t 1 ons
Hard Surface Cleaners
97
Hard-surface Cleaner A l l - S u r f a c e Bathroom A c i d Type
W_L% 4.0 1.o 0.2 9.5 85.3
M-Pyrol, N - M e t h y l - 2 - P y r r o l i d o n e I g e p a l CO-630 Hydroxyethylcellulose Phosphoric A c i d Water Perfume and c o l o r a n t s may be added.
Procedure: 1 D i sperse h y d r o x y e t h y l c e l l ulose i n water. 2 . I n a s e p a r a t e v e s s e l , m i x M - P y r o l , I g e p a l CO-630 t o g e t h e r . Add hydroxyethylcellulose/water m i x t u r e . 3 . Add a c i d and m i x t h o r o u g h l y .
.
P h y s i c a l P r o p e r t i es : pH ( a s i s ) : 2 . 0 pH ( 1 % ) : 2 . 4 V i s c o s i t y : 30 c p s Speci f ic G r a v i t y : 1 . 0 2 Formula BC-0005 Hard-surface Cleaner Type A1 1-Surface_&throom Water I g e p a l CO-630 Cheel ox NTA-Na3 Sodium X y l e n e S u l f o n a t e Sodi um H y d r o x i d e Perfume and c o l o r a n t s added,
W% .t 70.5 2.5 20.0 5.5 1.5 as d e s i r e d ,
r e p l a c i n g water
Procedure: 1 . D i s s o l v e I g e p a l CO-630 i n w a t e r . Add Cheelox NTA-Na3. 2 . Add sodium x y l e n e s u l f o n a t e and sodium h y d r o x i d e , m i x i n g w e l l a f t e r each a d d i t i o n . Physi c a l P r o p e r t i es : pH, as i s : 1 2 . 9 pH ( 1 % ) : 1 1 . 4 V i s c o s i t y : 10 c p s S p e c i f i c G r a v i t y : 1.05 Formula BC-0006
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
98
Advanced Cleaning Product Formulations
Hard Surface Cleaner-A Components: Water Tetrasodi um EDTA (40% s o l n) Tetrapotassium Pyrophosphate (TKPP 60%) Dowanol PNB Sodium xylene s u l f o n a t e (96%) Nonionic s u r f a c t a n t : Hostapal N 090
Wt.
% 70 1 6 6 8
9
Physical P r o p e r t i e s : Appearance (25C): c l e a r D e n s i t y ( l b / g a l ) : 9.0 pH (l%, 25C): 10.1 Ross M i l e s (49C, 1%, cm): 1 m i n . : 10 5 min.: 4 Cloud P o i n t ( l % , C ) : 54.5 Surface Tension (0.25%, Dynes/cm): 31.84 V i s c o s i t y , B r o o k f i e l d (25C, 50 rpm, L V # l ) : 24.3 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C): D i d n o t f r e e z e Procedure: Blend t h e components i n t h e g i v e n o r d e r w i t h continuous stirring. Hard S u r f a c e Cleaner-8 Components: Water Tetrasodium EDTA (40% s o l n ) Tetrapotassium Pyrophosphate (TKPP 60%) Dowanol PNB Sodium xylene s u l f o n a t e (96%) Nonionic s u r f a c t a n t : Genapol UD 079
Wt.
Physical p r o p e r t i e s : Appearance (25C): c l e a r D e n s i t y ( l b / g a l ) : 9.1 pH ( l % , 25C): 10.8 Ross M i l e s (49C. 196, cm 1 m i n . : 14 5 min.: 3 Cloud P o i n t ( l % , C): 63 Surface Tension (0.25%, Dynes/cm): 27.92 V i s c o s i t y , B r o o k f i e l d (-5C, 50 rpm, LV#1): 25.4 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C): D i d n o t f r e e z e Procedure: Blend t h e components i n t h e g i v e n o r d e r w i t h continuous s t ir r i ng
.
Source: Hoechst Celanese Corp.:
Suggested Formulatlons
% 69 1 6 6
8 10
Hard Surface Cleaners
99
H a r d S u r f a c e Cleaner-C Components: Water T e t r a s o d i u m EDTA (40% s o l n ) T e t r a p o t a s s i u m Pyrophosphate (TKPP 60%) Dowanol PNB Sodium x y l e n e s u l f o n a t e (96%) Nonionic s u r f a c t a n t : Genapol 26-L-75
Wt.
% 70 1 6 6 8
9
Physical Properties: Appearance ( 2 5 C ) : c l e a r D e n s i t y ( l b / g a l ) : 9.00 pH ( l % , 25C): 1 0 . 6 Ross M i l e s (49C, 1%, cm): 1 m i n . : 16 5 m i n . : 10 Cloud P o i n t ( l % , C ) : 76 S u r f a c e T e n s i o n (0.25%, Dynes/cm): 31.69 V i s c o s i t y , B r o o k f i e l d (25C. 50 rpm, LV#1): 2 0 . 4 Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : D i d n o t f r e e z e Procedure: B l e n d t h e components i n t h e g i v e n o r d e r w i t h c o n t i n u o u s stirring. H a r d S u r f a c e Cleaner-D Components: Water T e t r a s o d i u m EDTA (40% s o l n ) T e t r a p o t a s s i u m Pyrophosphate (TKPP 60%) Dowanol PNB Sodium x y l e n e s u l f o n a t e (96%) Nonionic s u r f a c t a n t : Genapol 26-L-60
Wt.
Physical Properties: Appearance ( 2 5 C ) : c l e a r pH ( l % , 25C): 10.17 Ross M i l e s (49C, 196, cm): 1 m i n . : 13 5 min.: 5 C l o u d P o i n t ( l % , C ) : 59 S u r f a c e T e n s i o n (0.25%, Dynes/cm): 29.44 V i s c o s i t y , B r o o k f i e l d (25C, 50 rpm, L V # l ) : 1 9 . 2 Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : D i d n o t f r e e z e Procedure: B l e n d t h e components i n t h e g i v e n o r d e r w i t h c o n t i n u o u s s t ir r i ng
.
SOURCE: Hoechst Celanese C o r p . :
Suggested F o r m u l a t i o n s
% 70 1 6 6 8
9
100
Advanced Cleaning Product Formulations
Heavy D u t y HSC
Wt%
I n q r e d ie n t : Water NTA (39%) D i s s o l ve Sodi um G1 uconate Add, mix w e l l KOH (45%) Add, mix w e l l Tomah A l k a l i S u r f a c t a n t Add, mix w e l l Nonionic Surfactant-HLB 13 Add, mix w e l l
65.00 1 .oo 4.00 25.00 3.00 2.00
pH: 14.20 Recommended D i l u t i o n s : 5-2O:l A p p l i c a t i o n s : Soak tank, heavy d u t y HSC Formula NP-103 Powder-Heavy Duty HSC I n g r e d i e n t: Soda Ash Nonionic Surfactant-HLB 13 Blend i n powder blender o r spray over Tomah A l k a l i S u r f a c t a n t Blend i n powder blender or spray over Sodium M e t a s i l i c a t e Pentahydrate Blend i n powder b l e n d e r NTA o r EDTA (100%) Blend i n powder b l e n d e r Sodium Gluconate Blend i n powder blender NaOH ( f l a k e ) Blend i n powder blender SpG 2 0 / 2 0 C : 0.97 Recommended D i l u t i o n s : 1-4 oz/gal A p p l i c a t i o n s : Soak t a n k , heavy d u t y HSC Formula NP-104
SOURCE:
Tomah Products,
Inc.:
Suggested Formulations
Wt% 65.00 2.00 2.00
15.00 2.00 4.00 10.00
Hard Surface Cleaners
H i Qh-Foaming.
Clear.
Liaht-Duty
101
L i q u i d Cleaner P a r t s b y Weinht 20-40 80-60 Q.S.
Rhodaterge SMC Water Perfume, Dye, P r e s e r v a t i v e H i gh-Foami n e L i q h t - D u t y
C1eaner P a r t s by W e i g h t 20-30 70-60 1
A.
Rhodaterge SMC Water 8. O p a c i f i e r * Water C . Perfume, Dye, P r e s e r v a t i v e
9 Q.S.
Add Rhodaterge SMC t o Water i n " A " u n t i l c l e a r . D i l u t e o p a c i f i e r i n Water i n " B " . Add "B" t o "A" s l o w l y w i t h g e n t l e s t i r r i n g . A f t e r t h e o p a c i f i e r i s uniformly dispersed, continue s t i r r i n g d u r i n g dye and perfume a d d i t i o n . *Opaci f ie r E295, M o r t o n Chemi c a l C o . Spray C l e a n e r P a r t s by Weight 88.0 1.o 8.0 3.0 Q.S.
Water C a u s t i c Soda Glycol Ether Rhodaterge SMC Perfume, Dye, P r e s e r v a t i v e
P i ne O i 1 D e t e r a e n t - C l e a n e r - S a n i ti z e r
P a r t s by Weinht 20.0 0.5 79.5
Rhodaterge SMC Pine O i l Water Heavy-Duty
Steam C l e a n e r
Gafac RE-610 Rhodaterge SMC Sodium M e t a s i l i c a t e P e n t a h y d r a t e Sodi um S i 1i c a t e Water
SOURCE:
Rhone-Poulenc:
SugQested F o r m u l a t i o n s
P a r t s by Weiqht 4.0 3.0 10.0 5.0 78
102
Advanced Cleaning Product Formulations
Hiah-Performance. H a r d - s u r f a c e C l e a n e r s S o l v e n t - F r e e Non-Phosphate Type Component: W % .t Water 88.0 Sodium M e t a s i l i c a t e P e n t a h y d r a t e 2.0 M i r a n o l FBS 3.0 A l c o d e t HSC-1000 4.0 Cheelox BF-13 3.0 Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r , l i g h t y e l l o w l i q u i d pH, as i s : 1 2 . 6 V i s c o s i t y : t 1 0 cps Speci f ic G r a v i t y : 0.978 Solvent-Free
Phosphate TYDe
Component: W % .t 87.0 Water Sodium Metas l i c a t e P e n t a h y d r a t e 2.0 1.o M i r a n o l FBS 4 .0 A l c o d e t HSC- 000 3.0 Cheelox BF-1 3.0 Rhodafac RA-600 Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r , l i g h t y e l l o w l l q u i d pH: 1 1 . 5 V i s c o s i t y : <10 cps S p e c i f i c G r a v i t y : 1.013 Heavy-Duty
S o l v e n t Type
W% .t Component: 85.0 Water 2.0 Sodium M e t a s i l i c a t e P e n t a h y d r a t e 2.0 M i r a n o l FBS 3.0 A l c o d e t HSC-1000 2.0 Cheelox BF-13 6.0 Butoxyethanol Procedure: i s t e d and mix u n t i l u n i f o r m . B1end in g r e d i e n t s n o r d e r P h y s i c a l P r o p e r t i es : Appearance: C l e a r , l i g h t y e l o w l i q u i d pH, as i s : 12.55 V i s c o s i t y : t 1 0 cps .016 Specific Gravity:
SOURCE:
Rhone-Poulenc
Formula HS-0035
Hard Surface Cleaners
103
H i n h P r e s s u r e Spray C o n c e n t r a t e ( L i q u i d , low foam) S o i l - Grease, o i l Surface - P a i n t , polymeric, metal A p p l i c a t i o n Method - Spray Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r Composi t i on : Water Metso Beads 2048 EDTA, T e t r a s o d i u m (37%) Sodium X y l e n e S u l f o n a t e (40%) C 9 - C l l L i n e a r A l c o h o l , 6 Moles EO C 9 - C l l L i n e a r A l c o h o l , 2 . 5 Moles EO Use D i l u t i o n : 10% bw ( 1 3 o z / g a l l o n )
%!t 76.0 2.0
8.0 8.0 3.0 3.0
Spray and Wipe H o u s e h o l d H a r d s u r f a c e ( L i q u i d) S o i l - Food g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l Surface - Metal, ceramic, polymeric, g l a s s A p p l i c a t i o n Method - Spray and w i p e Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r Composi t i on : Water Metso Beads 2048 STPP EDTA, T e t r a s o d i u m (37%) Ethylene Glycol n-Butyl Ether C9-C11 L i n e a r A l c o h o l , 6 Moles EO Use D i l u t i o n : As i s
% A 88.2 2.4
2.0 1.4
3.0 3.0
Destainer S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s S u r f a c e - Cement, wood, p a i n t , p o l y m e r i c A p p l i c a t i o n Method - Brush M a n u f a c t u r e - Ribbon o r p a d d l e b l e n d e r Composi t i on : STPP Metso Beads 2048 Sodium S u l f a t e PQ Epsom S a l t O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 9-10 Moles € 0 Sodium P e r b o r a t e , Monohydrate Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 o z / g a l l o n ) Source:
The PQ C o r p . :
Suggested F o r m u l a t i o n s
25.0 25.0 8.0 2.0
2.0 38.0
104
Advanced Cleaning Product Formulations
HSC/Food S e r v i c e Deareaser I
Wt%
I n a r e d ie n t : Water EDTA (55%) Add, mix w e l l Na O r t h o s i l c a t e D i s s o l ve Dowanol PM Add Dowanol DPM Add L i n . alcoho e t h o x y l a t e (3-6 mole) Add, mix s l ig h t l y L i n . alcoho e t h o x y l a t e (6-9 mole) Add, mix s l i g h t l y Tomah A l k a l Surfactant Add, mix u n t i l c l e a r pH: 13.00 Recommended D i l u t i o n s : 2 o z / g a l l o n A p p l i c a t i o n s : Food s e r v i c e degreasing,
71 . 5 D 6.00 6.00 6.00 4.00
1
.oo
3.00 3.50
HSC
HSC/Food S e r v i c e DeQreaSer I1
Wt%
Ingredient: Water EDTA (55%) Add, mix we1 1 Na O r t h o s i l c a t e D i s s o l ve B u t y l Carbi t o 1 Add L i n . a l c o h o l e t h o x y l a t e (3-6 mole) Add, mix s l i g h t l y L i n. a l c o h o l e t h o x y l a t e (6-9 mole) Add, mix s l i g h t l y Tomah A l k a l i S u r f a c t a n t Add, mix u n t i l c l e a r pH: 13.00 Recommended D i l u t i o n s : 2 o z / g a l l o n A p p l i c a t i o n s : Food s e r v i c e degreasing,
66.50 6.00 6.00 10.00 1 .OD
3.00 8.50
HSC
SOURCE: Tomah Products, I n c . : Formula S-116
Hard Surfnce Cleaners
L i q u i d Abrasive
105
Cl eaner-A
E f f e c t i v e c l e a n e r t h a t shows no i n d i c a t i o n o f s e p a r a t i n g a f t e r 30 days a t room t e m p e r a t u r e . % as S u p p l i e d 45.4
I n q r e d ie n t s Water C a l c i um C a r b o n a t e * A c u s o l 820 S t a b i l i z e r (30%) B e n t o n i t e C1 a y * * * NPE10 NaOH (10%) Brookfield Viscosity,
50 1.o 2.5 0.5 0.6
cps @ 0 . 5 r p m : @ 12 r p m :
18,000 5,500
M i x i ng P r o c e d u r e : Add t h e i n g r e d i e n t s i n t h e s t a t e d o r d e r w i t h moderate agitation.
*Q-3: C a l c i u m C a r b o n a t e C o .
***a%
dispersion L i q u i d A b r a s i v e C1 eaner-B
E f f e c t i v e c l e a n e r t h a t shows no i n d i c a t i o n o f s e p a r a t i n g a f t e r 30 days a t room t e m p e r a t u r e . Ingredients: Water S i 1 ic a * * A c u s o l 820 S t a b i l i z e r TKPP (60%) NPElO NaOH (10%)
% as S u p p l i e d
44.4 50 1.5 3 0.25 0.85
(30%)
Brookfield Viscosity,
cps @ 0 . 5 rpm: @ 12 rpm:
53,000 12,400
M i x i ng P r o c e d u r e : Add t h e i n g r e d i e n t s i n t h e s t a t e d o r d e r w i t h moderate agitation. **Sil-Co.
SOURCE:
S i l 53: U . S .
Rohm and Haas Co.: Formulations
S i l i c o n Co. A c u s o l 820 S t a b i l i z e r :
Suggested
106
Advanced Cleaning Product Formulations
Low Foam Cleaners S e l f D e m u l s i f y i n a Hard S u r f a c e Cleaner
Wt%
Inaredi ent: Water T r i sodi um phosphate D i s s o l ve EDTA (39-40%) Mix w e l l Tomah Amphoteri c 400 Mix w e l l T r i t o n CF-10 Mix w e l l
92.20 1.30 2.00 3.50
1 .oo
pH: 11.50 Recommended D i l u t i o n s : 10-2O:l A p p l i c a t i o n s : Low foam f l o o r , C I P Notes: D e m u l s i f i e s food o i l s r a p i d l y w i t h no t r e a t m e n t Formula LF-101 HSC. Moderate pH.
S e l f Demulsifving
Wt%
I n g r e d i e n t: Water C i t r i c acid D i s s o l ve T r i sodi um phosphate D i s s o l ve EDTA (39-40%) Mix w e l l Tomah Amphoteric 400 Mix w e l l T r i t o n CF-10 Mix w e l l
86.90 1 .oo
1.30 2.00
7.80 1 .oo
pH: 8.50 Recommended D i l u t i o n s : 10-2O:l A p p l i c a t i o n s : Low foam f l o o r , CIP Notes: D e m u l s i f i e s food o i l s r a p i d l y w i t h no t r e a t m e n t Good detergency even a t lower pH Formula LF-102
SOURCE: Tomah Pr6ducts, I n c . :
Suggested Formulations
Hard Surface Cleaners
107
Phosphate F r e e C l e a n e r s Heavy D u t y Non S o l v e n t D e g r e a s e r W B 81.50 2.00
Inqredient: S o f t Water Na m e t a s i l i c a t e p e n t a h y d r a t e D i s s o l ve NTA (40%) D i s s o l ve NaOH ( 5 0 % ) Add, m i x w e l l Tomah AO-14-2 Add, m i x w e l l Tomah (2-17-2 Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l
1 .oo
9.50 1.50 1.50
3.00
pH: 1 4 . 5 0 Recommended D i 1u t i ons: 5-30 : A p p l i c a t i o n s : HSC N o t e s : F o r e x t r e m e l y h a r d wa e r , Formula NP-101
add 1-2% EDTA (40%
A n i o n i c / N o n i o n i c HSC
9
I n q r e d ie n t : S o f t Water Na M e t a s i l i c a t e P e n t a h y d r a t e Dissolve EDTA (39%) Add, m i x w e l l DDBSA, Na S a l t (60%) Add, m i x w e l l Tomah A m p h o t e r i c 400 Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l
82.50 5.00 3.00 3.50
4.00 2.00
SpG 20/20C: 1 . 0 5 pH: 12.90 Recommended D i 1u t i o n s : 5-20 : 1 A p p l i c a t i o n s : Medium D u t y HSC Formula NP-102
SOURCE:
Tomah P r o d u c t s ,
Inc.:
Suggested F o r m u l a t i o n s
108
Advanced Cleaning Product Formulations
T h i c k e n e d D-Limonene C l e a n e r W X 7.20
Inqredient: D-1 imonene P a r t A-Add, m i x Ethylene g l y c o l b u t y l ether P a r t A-Add, m i x Tomah E-14-5 P a r t A-Add, m i x Stepan N i n o l l l C M P a r t A-Add, m i x N o n i o n i c S u r f a c t a n t - H L B 13 P a r t A-Add, m i x S o f t Water Add s l o w l y w i t h good m i x i n g DDDBSA, Na S a l t , (60%) Add t o A, m i x w e l l TEA Add t o A, mix w e l l Water Add s l o w l y w i t h good m i x i n g pH: 5.60 Recommended D i l u t i o n s : 0-1O:l A p p l i c a t i o n s : Cleaner/degreaser Notes: T h i s p r o d u c t i s a s o f t g e l , time i s desirable Formula S-107
7.20 4.50 2.00 1 .oo
50.00 6.50 1.oo 20.60
e x c e l l e n t where c l i n g
D-Limonene HSC/Degreaser Inqredient : D-1 imonene Part A Tomah E-14-5 P a r t A-Mix we1 Tomah AO-14-2 P a r t A-Mix we1 Tomah 9-17-2 P a r t A-Mix w e l l N o n i o n i c S u r f a c t a n t - H L B 13 P a r t A-mix w e l l S o f t Water Mix slowly i n t o Part A EDTA (40%) Add, m i x Tomah A l k a l i S u r f a c t a n t Add, m i x SpG 20/20C: 1.01 pH: 10.60 Recommended D i l u t i o n s : 10-5O:l A p p l i c a t i o n s : HSC Formula S-1 11 SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
W X 7.00
3.00 2.00 2.00 3.00 77.00
5.00 1 .oo
Hard Surface Cleaners
U n b u i l t . Hiah-Sudsinq.
109
Hard-surface Cleaner
Component: Water C a l s o f t F-90 M i r a n o l FBS Sodi um S i 1 ic a t e I g e p a l CO-710 A1 kami de DC-212/S M - P y r o l , N - M e t h y l - . P - P y r r o l idone
Wt.% 79.7 5.3 3.0 5.5 1 .o 2.0 3.5
Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and m i x u n t i l u n i f o r m . T y p i c a l P r o p e r t i es : Appearance: C l e a r , y e l l o w l i q u i d V i s c o s i t y : <10 c p s pH, as i s : 9 . 8 5 S p e c i f i c G r a v i t y : 1.07 Formula HS-0036 H i q h - P e r f o r m a n c e G e n e r a l Purpose C l e a n e r C o n c e n t r a t e
Wt.% Water STPP (Anhydrous G r a n u l a r ) Rhodapon UB Rhodapon BOS A l c o d e t HSC-1000 Butoxyethanol M i r a n o l FBS
65.0 6.0 13.0 5.0 5.0 4.0 2.0
Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r , l i g h t y e l l o w l i q u i d pH, a s i s : 9 . 4 S p e c i f i c G r a v i t y : 1 .06 V i s c o s i t y : <10 c p s Formula HS-0038
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
I10 Advanced Cleaning Product Formulations
Viscous PhosDhoric A c i d Cleaner W X Inaredi ent : Water 77.70 Phosphoric A c i d (75%) 12.70 Add. mix, c o o l A c i d Thickener 4.00 Add, d i s s o l v e , mix w e l l S a l t (NaC1) 5.00 D i ssolve Noni oni c S u r f a c t a n t (HLB 13) 0.50 Add, mix w e l l 0.10 Perfume Add, mix w e l l Recommended D i l u t i o n s : 5-1O:l A p p l i c a t i o n s : Good c l e a n i n g and d e s c a l i n g , good c l i n g t i m e Formul a A-1 05
Viscous H C l A c i d Cleaner W X Ingredient: 71.40 Water 3.00 Tomah A c i d Thickener* Add, mix w e l l 25.60 HC1 A c i d (37%) Add, s l o w l y , mix w e l l , c o o l pH: 1.30 Recommended D i 1u t i ons : 0-30 : 1 A p p l i c a t i o n s : T o i l e t bowl c l e a n i n g , v e r t i c a l s u r f a c e c l e a n i n g Notes: *Mix A c i d Thickener p r i o r t o use i n o r d e r t o assure homogenei t y Formul a A-1 09
Viscous Mixed A c i d Cleaner
Wt% Inaredi ent : 71 .oo Water 22.00 Phosphoric A c i d (75%) Add, mix, c o o l 1 .oo Oxalic Acid D i s s o l ve 3.00 Tomah A c i d Thickener* Add, mix w e l l 3.00 S a l t (NaC1) Add, d i s s o l v e w i t h m i x i n g V i s c o s i t y ( c p s ) : 693 Recommended Di 1u t ions: 10-20: 1 A p p l i c a t i o n s : Metal c l e a n i n g , v e r t i c a l s u r f a c e c l e a n i n g , descal ing Notes: *Mix A c i d Thickener p r i o r t o use i n o r d e r t o assure homogenei t y Formula A-108
SOURCE: Tomah Products,
Inc.:
Suggested Formulations
8. Laundry Products
111
112
Advanced Cleaning Product Formulations
A1 k a l i n e Laundry F o r m u l a t i o n - E m u l s i o n TYDe % as SupDl i e d 42 2 4 2 10 40
Inqredi ents: Water* Acusol 820 S t a b i 1iz e r (30%) Acusol 81 0 S t a b i 1iz e r (18%) Acusol 445 D i s p e r s a n t (48%) NPElO NaOH (50%) T o t a l S o l i d s ( % ) : 32.28 Appearance: Opaque V i s c o s i t y (cp. 12 rpm, #3 sp n d l e ) :
1700
M i x i ng I n s t r u c t ions : Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h s u b s u r f a c e a g i t a t i o n . A l l o w s u f f i c i e n t t i m e f o r h y d r a i o n o f t h e STPP b e f o r e a d d i t i o n o f t h e NaOH. Make s u r e t o h e a t w a t e r t o a p p r o x i mate1 y 86F (30C) t o in s u r e easy d i s p o s i t i o n o f t h e s u r f a c t a n t and r a p i d h y d r a t i o n o f t h e phosphate.
*
A 1 k a l in e Laundry Formul a t i on-Sl u r r y Type
Ingredients: Water* Acusol 820 S t a b i 1iz e r (30%) Acusol 81 0 S t a b i 1iz e r (18%) Acusol 445 D i s p e r s a n t (48%) NPElO STPP NaOH (50%)
% as SuDPl i e d 32 2 4 2 10 10 40
T o t a l S o l i d s ( % ) : 42.28 Appearance: Opaque V i s c o s i t y (cp, 12 rpm, #3 s p i n d l e ) : 5500
M i x i ng I n s t r u c t i o n s : Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h s u b s u r f a c e a g i t a t i o n . A l l o w s u f f i c i e n t t i m e f o r h y d r a t i o n o f t h e STPP b e f o r e a d d i t i o n o f t h e NaOH. Make s u r e t o h e a t w a t e r t o a p p r o x i m a t e l y 86F (30C) t o i n s u r e easy d i s p o s i t i o n o f t h e s u r f a c t a n t and r a p i d h y d r a t i o n o f t h e phosphate. Excel 1e n t s t a b i 1 it y and suspendabi 1 it y a r e p r o v i d e d t o t h e h i g h l y - a l k a l i n e f o r m u l a t i o n s b y a c o m b i n a t i o n o f Acusol 810 and Acusol 820 s t a b i l i z e r s . B o t h f o r m u l a t i o n s can be pumped w i t h a p e r i s t a l ic pump. Acusol 445 low-mol e c u l a r - w e i g h t p o l y a c y l i c a c i d improves o v e r a l l c l e a n i n g , p r e v e n t s s o i l r e d e p o s i t i o n and, i n t h e s l u r r y f o r m u l a t i o n s , a i d i n t h e p r e c i p i t a t i o n and d i s p e r s i o n o f t h e h y d r a t e d STPP.
*
SOURCE:
Rohm and Haas Co.: F o r m u l a t i on8
ACUSOL 820 S t a b i l i z e r : Suggested
Laundry Products
Anionic/Nonionic
Heavy-Duty
113
Laundry D e t e r q e n t
Ktft P a r t A: Water Na C i t r a t e C a l s o f t F-90 P a r t B: Rhodasurf 25-7
30.0 8.0 17.0
8.0 2.0
MEA
sxs
6.0
Part C : Colorant Perfume Water
0.02-1 0.1 - 0 . 5
Q.S.
Procedure: D i s s o l v e Sodium C i t r a t e i n Water b y s t i r r i n g a t 45-50C and add C a l s o f t F-90. M i x P a r t "B" i n t h e o r d e r l i s t e d . Add "A" t o " B " . Add c o l o r a n t , p e r f u m e and w a t e r . A d j u s t pH t o 1 1 . 0 . Physical Properties: pH: 11.0 pH (1% S o l u t i o n ) : 9 . 5 0 S p e c i f i c G r a v i t y : 1.120 V i s c o s i t y : 75 c p s Formula LY-0043 A n i o n i c / N o n i o n i c Heavy-Duty
Laundry D e t e r g e n t W % .t
P a r t A: Water Na C i t r a t e C a l s o f t F-90 P a r t B: Rhodasurf 25- 7
30.0 8.0 17.0
8.0 2.0 6.0
MEA
sxs
Part C: Colorant Perfume Water
0.02-1 0.1- 0.5 Q.S.
Procedure: D i s s o l v e Sodium C i t r a t e i n w a t e r b y s t i r r i n g a t 45-50C, add C a l s o f t F-90. M i x P a r t "B" i n t h e o r d e r l i s t e d . Add " A " t o " B " . Add c o l o r a n t , p e r f u m e and w a t e r . A d j u s t pH t o 1 1 . 0 . Formula LY-0044
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
114
Advanced Cleaning Product Formulations
Chlorine D r y Bleach-I
28% 5-20 balance
CDB C l e a r o n STPP Sodi urn s u l f a t e
Chlorine D r y Bleach-I1 CDB 90 STPP Sodi urn m e t a s i 1 i c a t e , anhydrous Sodi urn s u l f a t e
18% 5-20 5 balance
N o t e : These a r e f o r 16% a v a i l a b l e c h l o r i n e b l e a c h e s . Sour-I 2 5% 75
Sodi urn o r ammoni urn b i f 1u o r i de Sodi urn o r ammoni urn s i 1 ic o f 1u o r i de Sour-I1
50% 50
Sodi urn o r ammoni urn b i f 1 u o r i de Sodium o r ammonium s i l i c o f l u o r i d e Oxvnen S a f e t y D r y B l e a c h - I Sodi urn p e r b o r a t e - H 2 0 STPP Soda ash
35% 0-40 balance
Oxyaen S a f e t y D r y B l e a c h - I 1 Sodi urn p e r b o r a t e t e t r a h y d r a t e STPP Soda ash
50% 0-40 balance
N o t e : These a r e f o r 5.5% a c t i v e oxygen b l e a c h e s .
SOURCE:
FMC Corp.: D e t e r g e n t A p p l i c a t i o n s B u l l e t i n No. 4 : Suggested F o r m u l a t i o n s
Laundry Products
115
C o l d Water D e t e r g e n t ( F o r Wool and D e l i c a t e F a b r i c s ) W% .t
Water M i r a n o l CS Conc. Rhodapex ES-2 A1 kami de DC-212 F l u o r e s c e n t W h i t e n i n g Agent
55.9 10.0 30.0 4.0 0.1
Procedure: Add i n g r e d i e n t s i n o r d e r l i s t e d . Heat t o 50C and m i x u n t i l clear. Physical Properties: Appearance: C l e a r , y e l l o w l i q u i d pH, as i s : 8 . 1 6 S p e c i f i c G r a v i t y : 1.02 V i s c o s i t y : 7 0 0 cps Formula LY-0040 Fine F a b r i c Deterqent W % .t
Rhodacal OS- 10 Sodium Hexametaphosphate Sodi um B i c a r b o n a t e O p t i c a l B r i ghtener
32.0 30.0 38.0 Q.S.
Procedure: Add t h e sodium b i c a r b o n a t e and t h e sodium hexametaphosphate t o t h e b l e n d e r . M i x f i v e m i n u t e s . Add t h e Rhodacal DS-10 w i t h m i x i n g . Add t h e o p t i c a l b r i g h t e n e r w i t h m i x i n g . M i x u n t i l uniform. Physical Properties: Appearance: W h i t e , f r e e - f l o w i n g powder pH, 1% S o l u t i o n : 8 . 5 Formula LY-0041
SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
116
Advanced Cleaning Product Formulations
Commerci a1 Laundry Formulations Phosphated a1 k a l i o r b u i 1der
20-30% 15 10 0- 2 4
Caustic soda, f l a k e STPP
Sodium m e t a s i l i c a t e anhydrous CMC A l i p h a t i c solvent (dedusting) Soda ash
balance
T a l l o w Soap Detergent L i s h t Duty
35% 59 5
Tallow soap (Hi t i t e r ) Soda ash Sodium m e t a s i l i c a t e , anhydrous O p t i c a l b r i ghtener A l i p h a t i c solvent (dedusting)
0-1 1
Heavy Duty
20%
T a l l o w soap ( H i t i t e r ) Sodi urn metasi 1icate, anhydrous C a u s t i c soda, f l a k e
40 40
B u i l t Deterqent ( L i g h t D u t a
20% 1 1 15 0.1 3
Anionic CMC
Foam S t a b i 1izer STPP
Optical brightener Noni oni c Soda ash
balance Bui 1t Detersent (Heavy Duty)
Soda ash Nonionic ( h i g h foam) Anionic Sodi urn metasi 1icate. Anhydrous Caustic soda, f l a k e Optical brightener CMC STPP
SOURCE:
FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4: Suggested Formulations
39.9% 6 3 20 15 0.1 1 15
Dairy, Food and General Industrial Cleaners
17
Heavy D u t y C l e a n e r s ( I n d u s t r i a l 1 Steam C l e a n e r s - L i a u i d s Water TKPP P o t a s s i um H y d r o x i d e (45%) S t a r s o s o d i um s i 1i c a t e Phosphate e s t e r O c t y l p h e n o l , 7-8 moles EO
18.8% 17.2% 31.3% 30.0% 2.3% 0.4%
Water TKPP P o t a s s i um h y d r o x i d e (45%) S t a r s o sodium s i l i c a t e Phosphate e s t e r C9-C11 1i n e a r a l c o h o l , 6 moles €0
34.1% 17.2% 31 .l% 15.2% 2.0% 0.4%
Steam Cleaners-Powders STPP Sodium c a r b o n a t e C9-C10 l i n e a r a l c o h o l , 12 moles EO Metso Beads 2040 s o d i um m e t a s i 1 ic a t e
35% 20% 10% 35%
STPP
50% 3% 2% 45%
CQ-ClO l i n e a r a l c o h o l ,
12 moles EO
Sodi urn g l u c o n a t e Metso Pentabead 20 sodium m e t a s i l i c a t e
SOURCE:
PQ Corp.:
D e t e r g e n t F o r m u l a r y : Suggested F o r m u l a t i o n s
118
Advanced Cleaning Product Formulations
Enzymatic Heavy-Duty
Laundry D e t e r g e n t
Ett% P a r t A: Water Citrate C a l s o f t F-90 P a r t B: Rhodasurf 25-7 MEA TEA
10.0 5.0 8.0 6.0 2.0 2.0 3.0 8.0
sxs
Rhodapex NA-61 P a r t C: Na Formate Calcium C h l o r i d e Enzymes Colorant Perfume Water
1.2 0.2 0.4 0.02-1 0.1- 0 . 8 Q.S.
Procedure: D i s s o l v e Sodium C i t r a t e i n Water by s t i r r i n g a t 45-50C, add C a l s o f t F-90. M i x P a r t "B" i n t h e o r d e r l i s t e d . Add "A" t o "B". Add Sodium Formate and C a l c i u m C h l o r i d e . Cool t o room temperaa t u r e . Add t h e enzymes. Add c o l o r a n t , perfume and w a t e r . A d j u s t pH t o 1 0 . 0 . Physical Properties: pH: 1 0 . 0 pH (1% S o l u t i o n ) : 8.8 Speci f ic G r a v i t y : 1 . I 0 0 V i s c o s i t y : 100 cps Formula LY-0046 N o n i o n i c / A m p h o t e r i c Heavy-Duty
Laundry L i a u i d
wt.% Water Glycosides M i r a n o l FBS MEA Colorant Perfume
Q.S. 20.0 7.0 2.0 0.02-1 0.1- 0 . 5
Procedure: Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d . M i x w e l l a f t e r each a d d i t i o n . A d j u s t pH t o 1 1 . 0 . P h y s i c a l P r o p e r t i 8s: pH: 11.0 pH (1% S o l u t i o n ) : 9.50 S p e c i f i c G r a v i t y : 1.100 V i s c o s i t y : 300 cps Formula LY-0045 SOURCE: Rhone-Poulenc: Suggested F o r m u l a t i o n s
Laundry Products
119
F i n e F a b r i c Handwash Inqredi ent: Water SXS ( 4 0 % ) Add, m i x w e l l C-12 D i e t h a n o l ami de ( 100%) Add, m i x w e l l COCO D i e t h a n o l ami de (80%) Add, m i x w e l l Tomah A m p h o t e r i c N Add, m i x w e l l C i t r i c Acid D i s s o l v e , a d j u s t t o p H 7.00 NaCl* D i s s o l ve
W B 37.00 15.00 2.00 3.00
18.00 q.s. Q . S .
SpG 20/20C: 1 . 0 4 pH: A d j u s t t o 7 . 0 w i t h c i t r i c a c i d Recommended D i l u t i o n s : 1 oz. g a l A p p l i c a t i o n s : V i s c o u s h i g h q u a l i t y handwash N o t e s : V i s c o s i t y 45 c p s ( B r o o k f i e l d RVT 100 rpm s p i n d l e # 3 ) *Add more NaCl t o i n c r e a s e v i s c o s i t y Formula L-108
Low T e m p e r a t u r e Powder D e t e r g e n t Inqredient: Na M e t a s i l i c a t e Anhydrous Soda Ash M i x i n powder b l e n d e r TKPP M i x i n powder b l e n d e r NaOH M i x i n powder b l e n d e r T r i t o n DF-12 Add i n conven e n t manner Tomah A m p h o t e r i c 400 Add i n conven e n t manner Recommended D i l u t i o n s : 2-4 o z / g a l l o n Appl ic a t i ons: HSC, Degreaser N o t e s : Good d e t e r g e n t even a t temps <35C Formula LF-100
SOURCE: Tomah P r o d u c t s ,
I n c . : Suggested F o r m u l a t i o n s
Wt% 35.00 25.00 20.00 15.00 2.50 2.50
120
Advanced Cleaning Product Formulations
Heavy D u t y Laundry D e t e r g e n t High Sudsing 35-50% 10-15 15-20 2- 5 0.5- 1.0 0.2- 0.8 balance
STPP Hydrous Sodium S i l i c a t e * Ani o n i c Foam s t a b i 1iz e r CMC Optical brightener S a l t cake
Low S u d s i n g STPP Hydrous Sodi um S i 1i c a t e * Nonionic CMC Optical brightener S a l t cake
*
35-50% 10-15 8-10
0.5-1.0 0.2-0.8 balance
S i l i c a t e s l e s s a l k a l i n e than m e t a s i l i c a t e . C o l d Water Wool Detersient
Hexaphos STPP A n i o n i c (40% a c t i v e ) CMC S a l t cake
30% 10 35
0.5 balance
Heavy D u t y L i sui d L a u n d r y D e t e r a e n t Water CMC 50% KOH 39.4% Potassium s i l i c a t e s o l u t i o n 1 Water S t a b i l i z e r AS€-108 ) preblend 60% TKPP s o l u t i o n Noni o n i c Optical brightener Add i n o r d e r l i s t e d w i t h v i g o r o u s a g i t a t i o n
SOURCE: FMC Corp.: D e t e r g e n t A p p l i c a t i o n s B u l l e t i n No. 4 : Suggested F o r m u l a t i o n s
19.8% 0.5 2.2 12.7 6.5 6.5 41 .7 10.0 0.2
Laundry Products
121
Heavy D u t y L a u n d r y , L i q u i d
Pct. I n n r e d i en& Water 30.10 50% Sodi urn H y d r o x i d e 4.60 D i e t h a n o l ami ne 5.00 P i l o t SXS-40 25.00 Cal s o f t LAS-99 30.00 5.00 C a l o x y l a t e N-9 Procedure: 1 . Combine t h e w a t e r , 50% NaOH, and DEA i n t h e r e a c t o r . 2 . T u r n on t h e s t i r r e r , and m i x t h e i n g r e d i e n t s . 3 . S t a r t t h e LAS-99 a d d i t i o n . Add o n l y 50% o f t h e S u l f o n i c A c i d . 4. Add t h e C a l o x y l a t e N-9 t o a i d i n f l u i d i z i n g t h e n e u t r a l i z a t i o n reactants. 5 . F i n a l pH s h o u l d be 8.0. A d j u s t w i t h 50% NaOH o r LAS-99. Formula No. HDL-005-01 L i q h t Duty L i q u i d D e t e r g e n t
Pet. Ingredient: 26.26 Water . ~P i l o t SXS-40 12.53 C a l s o f t L-40 44.93 Cal foam EA-603 10.00 5.99 Calamide C C i t r i c Acid 0.19 Dye & Perfume 0.10 Procedure: 1 . Charge t h e w a t e r and SXS-40 t o t h e r e a c t o r . T u r n on t h e stirrer. 2 . Add t h e C a l s o f t L-40 t o t h e w a t e r and SXS-40 w h i l e m i x i n g . 3 . Add t h e Calfoam EA-603 t o t h e r e a c t o r and c o n t i n u e m i x i n g . 4 . Add t h e Calamide C t o t h e f i r s t f o u r ( 4 ) i n g r e d i e n t s . 5 . C i t r i c A c i d i s added t o make m i n o r a d j u s t m e n t s i n l o w e r i n g t h e pH. 6 . F i n a l pH=6.6-7.2 Formula No.: LDL-005-1 Heavy D u t y Laundry.
Liquid
Pet. Inaredient: 71.43 Calsuds A 21.43 C a l o x y l a t e N-9 7.14 P i l o t SXS-40 Procedure: W i t h m i x i n a . add t h e C a l o x v l a t e N-9 and SXS-40 t o t h e Calsuds A . Warming t h e i n g r e d i e n t s t o 80-1OOF w i l l a i d i n b l e n d i n g . Formula No. HDL-003-1
-.
SOURCE:
P i 1o t Chemical Co. : Suggested F o r m u l a t i o n s
122
Advanced Cleaning Product Formulations
Heavy-Duty
L i a u i d Laundry D e t e r a e n t
Mazer Macol 25 Carboxymethyl C e l l u l o s e Potassium H y d r o x i d e (50% s o l u t i o n ) T e t r a p o t a s s i u m Pyrophosphate (60% s o l u t i o n ) V i n y l E t h y l - M a l e i c A n h y d r i d e Copolymer* Sodi um M e t a s i 1 ic a t e Water
*
G a n t r e z AN-149
Wei n h t / % 10.0% 0.6% 4.0% 36.0% 0.6%
5.8% 43.0%
(GAF) o r e q u i v a l e n t
Procedure: M i x t h e w a t e r , 0.01% o f t h e Macol 25 s u r f a c t a n t and t h e G a n t r e z AN-149 ( i n t h a t o r d e r ) w i t h g e n t l e a g i t a t i o n . Heat t h i s m i x t u r e t o 176F and m a i n t a i n f o r 20-30 m i n u t e s , u n t i l i t becomes v e r y f l u i d . W i t h g e n t l e a g i t a t i o n , s l o w l y add t h e p o t a s s i u m h y d r o x i d e s o l u t i o n . When t h i s m i x t u r e i s homogeneous, c o n t i n u e s t i r r i n g and d i s s o l v e t h e Carboxymethyl C e l l u l o s e . Next add t h e sodium m e t a s i l i c a t e . Cool t h e m i x t u r e t o 140F and w i t h v i g o r o u s a g i t a t i o n , add t h e b a l a n c e o f t h e s u r f a c t a n t . C o n t i n u i n g t h e v i g o r o u s a g i t a t i o n , r a p i d l y add t h e t e t r a p o t a s s i um s o l u t i o n ( p r e - h e a t e d t o 140F). O p t i c a l b r i g h t e n e r s , perfumes and dyes may be added i m m e d i a t e l y and t h e v i g o r o u s a g i t a t i o n c o n t i n u e d f o r f i v e (5) m i n u t e s . The f i n a l p r o d u c t may be c o o l e d and w i t h d r a w n i n t o s u i t a b l e c o n t a i n e r s . Heavy-Duty Powdered L a u n d r y D e t e r a e n t Mazer Macol 25 Carboxymethyl C e l l u l o s e Sodi um T r i p o l y p h o s p h a t e Sodium M e t a s i l i c a t e , Anhydrous Powder* Sodium S u l f a t e , B r i g h t e n e r s , E t c .
*
Na20:Si02 r a t i o 1:2-1:2:4,
SOURCE:
PPG I n d u s t r i e s ,
Inc.:
80-85% s o l i d s Suggested F o r m u l a t i o n s
Wei n h t / % 12% 2% 3 4%
8% 4 4%
Laundry Products
Heavy D u t y L i q u i d Laundry Formula-5 Ingredi ents: G1 ucopon AV-110 S u l f o t e x SXS Monoethanol ami ne Water T y p i c a l P r o p e r t i es : S o l i d s , %: 33 A c t i v e s , %: 25 pH, as i s : 11-12 V i s c o s i t y , cps (2.32): 150-250 Heavy D u t y L i q u i d Laundry Formula-6 Ingredients: G I ucoDon AV-110 S u l f o t e x sxs Nonionic Surfactant* Monoethanol ami ne Water T y p i c a l P r o p e r t i es : S o l i d s , %: 32 A c t i v e s , %: 25 pH, as i s : 11-12 V i s c o s i t y , cps (25C) : 150-250
123
W S 50.0
8.0 3.0 39.0
W S 40.0 6.0 5.0 3.0 46.0
Heavy D u t y L i q u i d Laundry Formul a-7
Wt%
Ingredi ent s : G1 ucopon A V - 1 1 0 S u l f o t e x SXS Nonionic S u r fa ctant* Monoethanol ami ne Water Typical Properties: S o l i d s , %: 32 A c t i v e s , %: 25 pH, as i s : 11-12 V i s c o s i t y , cps ( 2 5 C ) :
30.0
7.0 10.0 3.0
50.0
150-250
Heavy D u t y L i qui d Laundry Formul a-8 Ingredients: Glucooon AV-110 S u l f o t e x sxs Nonionic Surfactant* Monoethanol ami ne Water T y p i c a l P r o p e r t i es : S o l i d s , %: 32 A c t i v e s , %: 25 pH, as i s : 11-12 V i s c o s i t y , cps (25C): 150-250 * T r y c o l 5963, T r y c o l 6964
SOURCE:
Henkel C o r p . :
Glucopon S u r f a c t a n t s :
Wt% 25.0
8.0 12.5 3.0 61.5
Suggested Formulas
124
Advanced Cleaning product Formulations
Heavy-Duty
Phosohate F r e e Laundry Powder-A
Mazer Macol 25 Soda Ash, L i g h t , Anhydrous Sodium M e t a s i l i c a t e , L i q u i d Carboxymethyl C e l l u l o s e Sodi um S u l f a t e , B r i g h t e n e r , E t c . Heavy-Duty
Wei Q h f t % 12%
65% 2 0%
2% 1%
Phosphate F r e e Laundry Powder-B
Mazer Macol 25 Soda Ash, L i g h t , Anhydrous Sodium M e t a s i l i c a t e , Anhydrous Powder Carboxymethyl C e l l u l o s e Sodium S u l f a t e , B r i g h t e n e r , E t c .
Wei s h t / % 12% 50% 16% 2% 2 0%
N o t e : A l l f o r m u l a t i o n s s h o u l d be s u b j e c t e d t o s t o r a g e t e s t s under v a r i o u s t e m p e r a t u r e and h u m i d i t y c o n d i t i o n s . C o n c e n t r a t e d L i q u i d Laundry D e t e r a e n t Avanel S-70 Mazer Macol Mazer Macol Mazer Macol Mazer Macol Dye Fragrance
SOURCE:
25 45 48 41
PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Wei a h t / % 50.0% 25.0% 10.0%
7.0% 8.0% q.s. q.s.
Laundry Products
I n d u s t r i a l and I n s t i t u t i o n a l D e t e r q e n t C o n c e n t r a t e - F o r m u l a t i o n Ingredients: water Acusol 8 2 0 S t a b i l i z e r ( 3 0 % ) NPElO Sodium H y d r o x i d e , ( 5 0 % ) Brookfield Viscosity, Appearance: C l o u d y
c p fj 12 rpm:
2.5 5 10 300
I n g r e d ien t s : water Acusol 820 S t a b i l i z e r (30%) NPElO Sodi urn H y d r o x i d e , ( 5 0 % )
%
as
c p @ 12 rpm: 900
InQredients: Water Acusol 8 2 0 S t a b i l i z e r (30%) NPElO Sodi um H y d r o x i d e , ( 5 0 % )
% as S u p p l i e d
66.7
3.3 10 20
c p fj 12 rpm: 600
Mixing Instructions: Add Acusol 8 2 0 s t a b i l i z e r f i r s t t o t h e w a t e r , t h e n add t h e s u r f a c t a n t w i t h adequate m i x i n g . S l o w l y add c a u s t i c s o l u t i o n w i t h adequate m i x i n g .
SOURCE: Rohm and Haas C o . : ACUSOL 8 2 0 S t a b i l i z e r : Suggested Formulations
B
S y p p l ied 76.7 3.3 10 10
I n d u s t r i a l and I n s t i t u t i o n a l D e t e r a e n t C o n c e n t r a t e - F o r m u l a t i o n
Brookfield Viscosity, Appearance: Opaque
A
%- as supp 1 ie d 82.5
I n d u s t r i a l and I n s t i t u t i o n a l D e t e r a e n t C o n c e n t r a t e - F o r m u l a t i o n
Brookfield Viscosity, Appearance: C l o u d y
125
C
126
Advanced Cleaning Product Formulations
I n d u s t r i a l Laundry Powder Uniforms W% .t
52.5 15 20 12 0.5
Sodi um Carbonate I g e p a l CO-660 Sodium T r i p o l y p h o s p h a t e Sodium M e t a s i l i c a t e Optical Brightener
Procedure: Add t h e Sodium Carbonate t o t h e m i x e r . Spray on t h e I g e p a l CO-660. Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d . M i x u n t i 1 uniform. Physical Properties: Appearance: White, f r e e - f l o w i n g pH, 1% S o l u t i o n : 11.4
powder
Formula LY-0050 I n d u s t r i a l Laundry Powder Hotel Linen S u m l y
Wt.% 46.5 3 3 30
Sodi um Carbonate I g e p a l CO-630 I g e p a l CO-710 Sodium T r i p o l y p h o s p h a t e C a l s o f t F-90 Sodi um H y d r o x i d e Optical Brightener
2 15 0.5
Procedure: Add t h e Sodium Carbonate t o t h e m i x e r . Spray on t h e I g e p a l CO-630 and CO-710. Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d . Mix u n t i l uniform. Physi c a l P r o p e r t i8 s : Appearance: W h i t e , f r e e - f l o w i n g pH. 1% S o l u t i o n : 13.0
powder
Formula LY-0051 SOURCE: Rhone-Poul enc: Suggested F o r m u l a t i o n s
Laundry Products
127
I n d u s t r i a l L a u n d r y Two-Part S v s t e n s U n i f o r m s ( P e t r o l e u m Greases and O i l s ) W% .t
Part A: I g e p a l CO-660 C a l s o f t F-90 Water P a r t 0: Sodium S i l i c a t e ( S i 0 2 / N a 2 0 1 . 6 - 2 . 5 )
8 2 90 100
H o t e l / L i nen S u p p l y ( A n i m a l and V e a e t a b l e Grease) Wt% .
Part A: I g e p a l CO-660 C a l s o f t F-90 Water Part 0: P o t a s s i u m H y d r o x i d e (45%) STPP, TKPP o r KTPP
10 2 88 85 15
Formula LY-0052 I n d u s t r i a l L a u n d r y One-Shot
Liquid W% .t
Water I g e p a l CO-630 I g e p a l CO-710 Cheel ox BF-13 P o t a s s i u m H y d r o x i d e (45%) M i r a n o l FBS
69 3 3 10 10 5
Procedure: Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d . M i x u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r l i q u i d pH, a s i s : 1 3 . 0 pH, 1% S o l u t i o n : 1 1 . 8 S p e c i f i c G r a v i t y : 1 .06 V i s c o s i t y : t 1 0 cps F o r m u l a LY-0049
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
128
Advanced Cleaning Product Formulations
___L a u n d r y A1 k a l i B u i l d e r s P o w d e r s - - 1 n d u s t r i i l S U Py ~ ~ M o d e r a t e A1 k a l in i t y Sodium c a r b o n a t e STPP N o n y l p h e n o l , 9-10 moles EO Sodi um s u l f a t e Polyvinylpyrrolidone CMC Metso Beads 2048 sodium m e t a s i l i c a t e
20% 15% 12% 16% 1% 1% 35%
Liquids
__L i n e n SueeLy N C l e a r sodium s i l i c a t e P o t a s s i u m h y d r o x i d e (45%)
62% 38%
N C l e a r sodium s i l i c a t e P o t a s s i um h y d r o x i d e ( f 1 ake) Water
52% 37% 11%
N C l e a r sodium s i l i c a t e Sodi um h y d r o x i d e beads ("PELS") P o t a s s i um h y d r o x i d e ( f 1 ake) Water
52% 14% 28% 6%
I n d u s t r i a l SuDPly
D sodium s i l i c a t e Water
90% 10%
N C l e a r sodium s i l i c a t e Sodium h y d r o x i d e (50%)
88% 12%
SOURCE: PQ Corp.: D e t e r g e n t F o r m u l a r y : Suggested F o r m u l a t i o n s
Laundry Products
L a u n d r y D e t e r q e n t , I and I ( L i Quid)
-
129
Unbuilt
S o i l - A c i d i c f o o d f a t , o i l and g r e a s e Surface - Cotton, c o t t o n / p o l y e s t e r , p o l y e s t e r A p p l i c a t i o n Method - I n d u s t r i a l washing machine Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r ComDosi t i on A : &% Water Balance F1 u o r e s c e n t B r i g h t e n e r 0.2 Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles EO 20-30 A l k y l a r y l S u l f o n i c A c i d (98%) 5-10 Sodium H y d r o x i d e (50%) (Add t o pH) 6-8 Composi t i o m Water Fluorescent Brightener Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles EO Coconut D i e t h a n o l ami de
% A Balance 0.2 20-30 5-1 0
Use D i l u t i o n : L i g h t Soi 1 : 0.06% by w e i g h t o r 4 oz p e r 100 l b s l a u n d r y Medium S o i l : 0.06% - 0 . 1 2 % b y w e i g h t o r 4-0 o z s p e r 100 l b s 1a u n d r y Heavy S o i l : 0.12% - 0 . 2 5 % by w e i g h t o r 8-16 oz p e r 100 l b s 1a u n d r y N o t e : Use l a u n d r y d e t e r g e n t , u n b u i l t i n c o n j u n c t i o n w i t h l a u n d r y b u i l d e r , s i l i c a t e d ( b o t h l i n e n and i n d u s t r i a l ) a t 1 p a r t bw d e t e r g e n t t o 2-4 p a r t s b u i l d e r s o l u t i o n . Laundry D e t e r g e n t - L i n e n Supply (Powder, Low A1 k a l in i ty) Soil
-
A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n Method - I n d u s t r i a l washing machine Manufacture - Ribbon o r paddle b l e n d e r Composition: B r i t e s i l H20 STPP Sodium C a r b o n a t e Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles EO Sodi um S u l f a t e C a r b o x y m e t h y l c e l l u l o s e (CMC) Sodi um A1 k y l a r y l S u l f o n a t e Powder (90%)
20.0 26.0
28.0 10.0 10.0 2.0
4.0
Use D i l u t i o n : L i g h t S o i l : 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l : 0.50% b y w e i g h t o r 2 l b s p e r 100 l b s l a u n d r y Heavy S o i l : 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s l a u n d r y
SOURCE: The PQ C o r p . :
Suggested F o r m u l a t i o n s
130
Advanced Cleaning Product Formulations
Laundry D e t e r q e n t s (Consumer) Dry B l e n d e d B r i t e s i l C24 h y d r o u s p o l y s i l i c a t e STPP Sodium c a r b o n a t e C 1 2 - C l 5 l i n e a r a l c o h o l , 7 moles €0 Sodi um s u l f a t e CMC LAS O p t i c a l b r i g h t e n e r , Perfume
2 0% 30% 10.5% 4% 2 4% 1% 10% 0.5%
PhosDhorous-Free V a l f o r 100 Z e o l i t e A B r i t e s i l C24 h y d r o u s p o l y s i l i c a t e Sodium c a r b o n a t e P o l y a c r y l a t e (MW 4 5 0 0 - 5 5 0 0 ) C 1 2 - C l 5 1i n e a r a l c o h o l , 7 moles €0 LAS CMC Optical brightener Sodi um s u l f a t e
30% 7% 15% 1% 4% 10% 1% 0.5% 31.5%
A g ~omerated l
STPP Sodi um c a r b o n a t e E r i t e s i 1 C24 h y d r o u s p o l y s i 1ic a t e Sodium s u l f a t e LAS A 2447 sodium s i l i c a t e
30% 15% 10% 31%
7% 7%
Low Phosphorous (Economy) Valfor Sodi um STPP Sodium LAS A 2447
100 Z e o l i t e A carbonate sulfate sodium s i l i c a t e
20% 2 5%
5% 36% 7% 7%
SOURCE: PQ Corp.: D e t e r g e n t F o r m u l a r y : Suggested F o r m u l a t i o n s
Laundry Products
. L-a u n d r ~
131
D e t e r q e L t s (Consumer) [ C o n t i n u e d ) Aqqlomerated (Continued) .(Premium)
V a l f o r 100 Z e o l i t e A STPP Sodium c a r b o n a t e CMC Sodium s u l f a t e LAS C12-Cl5 l i n e a r a l c o h o l , A 2447 sodium s i l i c a t e
7 moles
EO
Phosphorous-Free .fEconomy) V a l f o r 100 z e o l i t e ASodi um c a r b o n a t e Sodium s u l f a t e LAS P o l y a c r y l a t e (MW 4 5 0 0 ) C12-C15 1 in e a r a l c o h o l , 7 moles EO A 2447 sodium s i l i c a t e
2 7% 5% 10% 1% 2 9% 12% 6% 10%
2 5% 2 5% 35.5% 5%
0.5% 2% 7%
(Premi um) V a l f o r 100 z e o l i t e A Sodi um c a r b o n a t e CMC
Sodi um s u l f a t e P o l y a c r y l a t e (MW 4 5 0 0 ) LAS C12-Cl5 l i n e a r a l c o h o l , A 2447 sodium s i l i c a t e
7 moles EO
30% 15% 1% 22.5% 0.5% 10% 11% 10%
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a r y : Suggested F o r m u l a t i o n s
132
Advanced Cleaning Product Formulations
Laundry Formulas Restaurant/Hotel Laundry I Inqredi ent : Water STPP D i s s o l v e , mix w e l l KOH (45%) Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Tomah A m p h o t e r i c 400 Add, m i x u n t i l c l e a r pH: 13.50 Recommended D i l u t i o n s : 1/4-1/2 Applications: Restaurant/hotel Formula L-1 00
W B 45.00 5.00
30.00 10.00 10.00 cup laundry
R e s t a u r a n t / H o t e l Laundry I1 Inaredient : Water STPP D i s s o l ve P o t a s s i um s i 1ic a t e Add, m i x w e l l KOH (45%) Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Tomah A m p h o t e r i c 400 Add, m i x w e l l pH: 13.50 Recommended D i l u t i o n s : 1/4-1/2 cup Applications: Restaurant/hotel laundry Formula L-101
W B
40.50 5.00 4.50 30.00 10.00 10.00
Concentrated PresDotter Wt% Innredient: C12-15 a l c o h o l e t h o x y l a t e (3EO) 10.00 C12-15 a l c o h o l e t h o x y l a t e (7EO) 10.00 Mix w e l l Tomah (2-17-2 3.00 Mix w e l l Exxon I s o p a r G 20.00 Mix w e l l Water 10.00 Add s l o w l y , m i x i n g w e l l pH: n e u t r a l Recommended D i l u t i o n s : as n e c e s s a r y A p p l i c a t i o n s : pump s p r a y p r e s p o t t e r N o t e s : Use o f d e t e r g e n t q u a t e r n a r y g r e a t l y i m p r o v e s p e r formance o i l y s o i 1s Formula L-102 SOURCE: Tomah P r o d u c t s ,
Inc.:
SUQQeSted F o r m u l a t i o n s
Laundry Products
133
L a u n d r y Powder D e t e r g e n t
Wt.% Sodi um C a r b o n a t e C a l s o f t F-90 Rhodapex NA-61 Rhodasurf 25-7 Sodi um M e t a s i 1 i c a t e P e n t a h y d r a t e Sodium S u l f a t e Zeol it e Sodi um P e r b o r a t e Enzymes can be added Dye Perfume
44.0 14.0 6.0 2.0 4.0 10.0 18.0 2.0
Procedure: Add t h e Sodium C a r b o n a t e t o t h e m i x e r . Spray on t h e Rhodapex NA-61 and t h e R h o d a s u r f 25-7. Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d and m i x u n t i l u n i f o r m . Physical Properties: Appearance: W h i t e , f r e e - f l o w i n g powder, dyed t o p r e f e r e n c e pH, 1% S o l u t i o n : 11 Formula LY-0047 Non-Phosphate L a u n d r y Powder
Wt.% 50.0 12.0 12.0 24.5 1. o 0.5
Sodium C a r b o n a t e I g e p a l CO-630 Sodi um S i 1 i c a t e Sodium S u l f a t e Carboxymethylcel l u l o s e Optical Brightener
Procedure: Add t h e Sodium C a r b o n a t e t o t h e m i x e r . Spray t h e I g e p a l CO-630 o n t o t h e Sodium C a r b o n a t e . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d . M i x u n t i l a homogeneous, f r e e - f l o w i n g product r e s u l t s . Physical Properties: Appearance: W h i t e , f r e e - f l o w i n g powder pH, 1% S o l u t i o n : 1 1 . 0 Formula LY-0048
SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
134
Advanced Cleaning Product Formulations
L i q u i d Commercial Laundry Deteraents Acusol 820 s t a b i l i z e r i s u s e f u l i n p r e p a r i n g l i q u i d d e t e r gent systems on s u r f a c t a n t / b u i l d e r m i x t u r e s . I n these formu l a t i o n s i t can f u n c t i o n i n e i t h e r o f two ways:
* *
T o p r o v i d e s t a b i l i z a t i o n or suspension o f n o n i o n i c s u r f a c t a n t s i n b u i l t l i q u i d systems o f low v i s c o s i t y . or To p r o v i d e t h i c k e n i n g t o g i v e h i g h l y v i s c o u s o r g e l l e d formulations.
I n d u s t r i a l and I n s t i t u t i o n a l Deteraent Concentrates Formul a t i on A
I ngredi e n t s : Water Acusol 820 S t a b i l i z e r (30%) NPElO Sodium Hydroxide,
(50%)
Brookfield Viscosity, Appearance: c l o u d y
% as s u p p l i e d
82.5 2.5 5 10
cp @ 12 rpm: 300
Formulation B Ingredients: Water Acusol 820 S t a b i l i z e r (30%)
NPElO Sodium Hydroxide,
(50%)
% as s u p p l i e d 76.7
3.3 10 10
B r o o k f i e l d V i s c o s i t y , cp @ 12 rpm: 900 Appearance: cloudy Formulation C I n q r e d ie n t s : Water Acusol 820 S t a b i l i z e r
% as s u p p l i e d 66.7
(30%)
N P E 10 Sodium Hydroxide,
(50%)
3.3 10 20
B r o o k f i e l d V i s c o s i t y , cp I3 12 rpm: 600 Appearance: opaque MiXing I n s t r u c t i o n s : Add Acusol 820 s t a b i l i z e r f i r s t t o t h e water, then add t h e s u r f a c t a n t w i t h adequate m i x i n g . Slowly add c a u s t i c s o l u t i o n w i t h adequate m i x i n g .
SOURCE: Rohm
and Haas G o. : Acusol 820 S t a b i l i z e r : Formulations
Suggested
Laundry Products
L i o u i d Laundry/Ani o n i c Phosphate F r e e Inqredient: Water EDTA (40%) Add, m i x w e l l Na c i t r a t e (87%) Dissolve Ethanol Add, m i x w e l l P r o p y l ene g l y c o l Add, m i x w e l l ODBSA, Na s a l t (60%) Add, m i x w e l l A l c o h o l e t h e r s u l f a t e 4E0 (60%) Add, m i x w e l l FWA (CBS-X, Ciba-Geigy) 5% s t o c k s o l ' n P r e d i s s o l v e i n w a t e r t o make s t o c k s o l ' n N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Tomah A m p h o t e r i c N Add, m i x w e l l Protease-Novo N o r d i s k ( o p t i o n a l ) Add, m i x w e l l pH: 8 . 0 0 A d j u s t t o pH 8 . 0 Recommended D i l u t i o n s : 1 / 2 cup A p p l i c a t i o n s : Household l a u n d r y Formula L-105
L i q u i d Laundry/Nonionic
SOURCE:
Tomah P r o d u c t s ,
Inc.:
K% 26.60 7.50 8.00 5.00 5.00 13.30
9.60 10.00 4.00
5.00 6.00
Phosphate F r e e
Insredient: Dei o n i zed w a t e r EDTA (40%) Mix w e l l Sodi um c i t r a t e Add, mix w e l l Ethanol Add, m i x w e l l N o n i o n i c Surfactant-HLB13 Add, m i x w e l l Tomah A m p h o t e r i c N Add, m i x w e l l FWA (CBS-X, Ciba-Geigy) 5% s t o c k s o l ' n P r e d i s s o l v e i n w a t e r t o make s t o c k s o l ' n Propylene g l y c o l Add, m i x w e l l P r o t e a s e . Novo N o r d i s k ( o p t i o n a l ) Add, m i x w e l l pH: 8 . 0 0 a d j u s t t o pH 8 . 0 Recommended D i l u t i o n s : 1 / 2 c u p Appl ic a t i ons: Household Formula L-106 Suggested F o r m u l a t i o n s
135
Wt%
43.50 5.00 3.50 7.00 15.00
5.00 10.00 5.00
6.00
136
Advanced Cleaning Product Formulations
L i a u i d Laundry Detergents A n i o n i c & Nonionic W
Water Glucopon 600 CSUP Ethanol Sul f o t e x 6040s
a 62 10 3 25
A l l Nonionic
Water Glucopon 600 CSUP Ethanol T r y c o l 5963
72 10 3 15
Anionic
(L
Nonionic w i t h B u i l d e r
!tL%
Water Sodi urn C i t r a t e S u l f o t e x SXS 40 Glucopon 600 CSUP Ethanol S u l f o t e x 6040s
32 5 5 15 5
38 Nonionic w i t h B u i l d e r
Water Sodium C i t r a t e S u l f o t e x SXS 40 Glucopon 600 CSUP Ethanol T r y c o l 5963
42.5 5.0 10.0 15.0 5.0 22.5
Procedure: Add i n t h e o r d e r 1 isted, d i s s o l v i ng each ingredi e n t completely u s i n g moderate a g i t a t i o n . I n c o r p o r a t e c o l o r and f r a g r a n c e as needed.
SOURCE: Henkel Corp.:
Sugqested Formulations
Laundry Products
137
L i q u i d Laundry Deterqents (Based on Added Value S u r f a c t a n t Concentrates) Premium HDL W
U
1 16
Water S u l f o t e x SXS 40 G l ucopon AV-110 Monoethanolamine
80 3
Economv HDL W
Water S u l f o t e x SXS 40 G1 ucopon AV-110 Monoethanol ami ne
U 55 2 40
3 Concentrate w i t h Noni o n i c s W
U
50 7 30
Water S u l f o t e x SXS 40 G1ucopon AV-110 T r y c o l 5963 Monoethanol ami ne
10
3 U l t r a Hiqh A c t i v e 80 2 15 3
G1ucopon AV-110 S u l f o t e x SXS 40 T r y c o l 5963 Monoethanol ami ne
Procedure: Add in t h e o r d e r 1 is t e d , d i s s o l v i ng each ingredi e n t completely u s i n g moderate a g i t a t i o n . I n c o r p o r a t e c o l o r and f r a g r a n c e as needed.
SOURCE: Henkel Corp.:
Suggested Formulations
138
Advanced Cleaning Product Formulations
L i q u i d Laundrv/Noni o n i c PhosDhate g I n a r e d ie n t : Ethanol 10.00 0.50 FWA ( T i n o p a l CBS-X) Add, mix w e l l 45.00 Dei o n i zed Water Add, mix w e l l 15.00 Nonionic Surfactant-HLB 13 Add, mix w e l l TKPP 4.00 D i s s o l ve Tomah Amphoteric N 5.00 Add, mix w e l l 5.00 Propyl ene G1y c o l Add, mix w e l l 1 .oo Tomah Q-17-2 Add, mix w e l l 6.00 Protease ( O p t i o n a l ) Add, i f d e s i r e d , mix w e l l q.s. Water Add, m i x w e l l pH: 8 . 0 0 A d j u s t t o pH 8 Recommended D i l u t i o n s : 1/2 cup A p p l i c a t i o n s : Household l a u n d r y Notes: Use o f d e t e r g e n t quaternary g r e a t l y improves performance on o i l y s o i l s Formula L-103 L i q u i d Laundrv/Anionic Phosohate Inaredi ent : %Deionized Water 31.60 10.00 TKPP Dissolve Ethanol 5.00 Add, mix w e l l 5.00 Propyl ene g l y c o l Add, mix w e l l 13.30 DDBSA. Na S a l t (60%) Add, mix w e l l Alcohol Ether S u l f a t e 4E0 (60%) 9.60 Add, mix w e l l - a d j u s t t o pH 8 . 0 FWA (CBS-X, Ciba-Geigy) 5% s t o c k s o l ' n 10.00 P r e d i s s o l v e i n water t o make s t o c k s o l ' n Nonionic Surfactant-HLB 13 4.00 Add, mix w e l l Tornah Amphoteric N 5.00 Add, mix w e l l 6.00 Protease, Novo N o r d i s k ( o p t i o n a l ) Add, mix w e l l q.s. Water Add, mix w e l l pH: 8 . 0 0 Recommended D i l u t i o n s : 1/2 cup A p p l i c a t i o n s : Household Formula L-107 SOURCE: Tomah Products, I n c . : Suggested Formulations
Laundry Products
139
Oxygen S a f e t y D r y B l e a c h - I Sodium p e r b o r a t e t e t r a h y d r a t e Sodium t r i p o l y p h o s p h a t e Anionic o r nonionic Optical brightener F i l l e r ( s o d a ash, sodium s u l f a t e ,
sesquicarb.,
etc.)
20-35% 0-35 0- 3 0- 0 . 3 balance
etc.)
1525% 0-35 0- 3 0- 0 . 3 balance
Oxygen S a f e t y D r y B l e a c h - I 1 Sodium p e r b o r a t e monohydrate Sodium t r i p o l y p h o s p h a t e Anionic o r nonionic Optical brightener F i l l e r (soda ash, sodium s u l f a t e ,
sesquicarb.,
Deterqent S a n i t i z e r - I * CDB C l e a r o n STPP Sodium m e t a s i l i c a t e ( a n h y d r o u s ) A n i o n i c (85% a c t i v e ) S a l t cake
5.6% 35 5
5 49.4
Detergent Sanitizer-11* CDB C l e a r o n STPP A n i o n i c (85% a c t i v e ) S a l t cake Soda ash *EPA
SOURCE:
R e g i s t ered sani t i zers FMC C o r p . : D e t e r g e n t A p p l i c a t i o n s B u l l e t i n No. 4 : Suggested F o r m u l a t i o n s
18% 25 3 29 25
140
Advanced Cleaning R&ct
Formulations
Super C o n c e n t r a t e Laundry L i q u i d W t . % (as i s ) Ingredient: 37.5 01 Water 5.00 B i o - S o f t S-100 0.12 T r i e t h a n o l a m i n e (99%) 3.50 Carbopol 2201 (30% a c t i v e ) 5.00 P r o p y l ene G1y c o l 20.00 Makon 10 7.88 T r i e t h a n o l a m i n e (99%) 16.00 Standapol ES-3 1 .oo Sodi um C i t r a t e 4.00 Opaci f ie r O i s p e r s i on (25%) q.s. Dye (FO&C B l u e #1, Red #33) V i s c o s i t y : 600-800 cPs pH: 8.3-8.8 Procedure: 1 . Combine B i o - S o f t S-100 (Na-LAS) w i t h 01 w a t e r . N e u t r a l i z e s l i g h t l y w i t h TEA. M i x u n t i l homogeneous. 2. Add Carbopol 2201 w h i l e m i x i n g . 3. A d d p r o p y l e n e g l y c o l t o t h e m i x t u r e . 4. Add Makon 10 ( n o n y l phenol e t h o x y l a t e , 10 €0) t o t h e m i x t u r e under a g i t a t i o n . 5. F u l l y n e u t r a l i z e t h e s o l u t i o n w i t h t h e r e m a i n i n g TEA. 6 . Warm t h e m i x t u r e t o 50C. S l o w l y add t h e Standapol ES-3 w h i l e mixing. Continue m i x i n g u n t i l uniform. 7 . Add sodium c i t r a t e and mix u n t i l d i s s o l v e d . 8 . Combine one p a r t o p a c i f i e r w i t h t h r e e p a r t s w a t e r . Add t h i s d i s p e r s i o n t o t h e m i x t u r e . S l o w l y c o o l m i x t u r e t o room temperature. 9. Add dye and f r a g r a n c e as d e s i r e d . Characteristics: Carbopol r e s i n p r o v i d e s s t a b i l i t y w i t h o u t a f f e c t i n g p e r f o r m ance o f t h i s c o n c e n t r a t e d f o r m u l a Easy-f 1owi ng rheol ogy Carbopol r e s i n s a r e a l s o s u i t a b l e f o r h i g h l y - b u i l t systems SOURCE: B.F. G o o d r i c h Co.: CARBOPOL H i g h Performance Polymers: Suggested F o r m u l a t i o n s
*
* *
Laundry D e t e r a e n t s I n d u s t r i a l and I n s t i t u t i o n a l L i aui d- ( D i s p e r s i on 1 Water STPP P o t a s s i um h y d r o x i d e (45%) Kasi 1 #6 p o t a s s i um s i 1ic a t e LAS L i a u i d - ( S o l u t i on) Water Potassium h y d r o x i d e (45%) STPP Kasi 1 #6 p o t a s s i um s i 1ic a t e LAS SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a r y : Suggested Formulas
69% 17% 1.6% 7.4% 5% 69.0% 1.6% 17.0% 7.4%
5.0%
Laundry Products
141
U n b u i l t Laundry Deternent-A ComDonents: Water Sodium c a r b o n a t e Sodium x y l e n e s u l f o n a t e (40%) Ethanol Nonionic s u r f a c t a n t : H o s t a p a l N 090 Anionic Sufactant: L i n e a r a1 k y l s u l f o n a t e (60%)
Wt.
% 45 2 15 2
28 8
P h y s i c a l P r o p e r t ies : Appearance ( 2 5 C ) : c l e a r D e n s i t y ( 1b / g a l ) : 8 . 9 pH (l%, 25C): 10.6 Ross M i l e s (49C, 1%, cm): 1 m i n . : 19 5 min.: 19 Cloud p o i n t ( l % , C ) : > l o 0 S u r f a c e t e n s i o n (0.25%, dynes/cm): 32.8 V i s c o s i t y , B r o o k f i e l d (25C, L V # l , 100 rpm, c p s ) : 118 F r e e z e thaw s t a b l e f r e e z i n g p o i n t ( C ) : D i d n o t f r e e z e U n b u i l t Laundry Detergent-B ComDonents: Water Sodium c a r b o n a t e Sodium x y l e n e c a r b o n a t e (40%) Ethanol Nonionic s u r f a c t a n t : Genapol UD 079 Anionic surfactant: L i n e a r a1 k y l s u l f o n a t e (60%)
Wt.
Physical Properties: Appearance ( 2 5 C ) : c l e a r Density ( l b / g a l ) : 8.8 pH ( l % , 25C): 10.3 Ross M i l e s (49C, 1%’ cm): 1 m i n . : 12 5 min.: 5 Cloud p o i n t ( l % , C ) : > l o 0 S u r f a c e t e n s i o n (0.25%, dynes/cm): 2 9 . 2 V i s c o s i t y , B r o o k f i e l d (25C, L V #1, 100 rpm. c p s ) : 68 F r e e z e thaw s t a b l e f r e e z i n g p o i n t ( C ) : D i d n o t f r e e z e Procedure: D i s s o l v e sodium c a r b o n a t e i n w a t e r and add t h e r e m a i n i n g components i n t h e g i v e n o r d e r w i t h c o n t i n u o u s s t i r r i n g . SOURCE: Hoechst Celanese C o r p . :
Suggested F o r m u l a t i o n s
%
40 2 14 2
33 9
142
Advanced Cleaning Product Formulations
U n b u i l t Laundry Detergent-C Components: Water Sodium carbonate Sodium xylene s u l f o n a t e (40%) Ethanol Nonionic s u r f a c t a n t : Genapol UD 030 Genapol UD 079
Wt.
%
47 2 15 2 6 28
Physical P r o p e r t i e s : Appearance (25C): c l e a r D e n s i t y ( 1b / g a l ) : 8.7 pH (l%, 2%): 10.6 Ross M i l e s (49C, 1%, cm): 1 m i n . : 14 5 min.: 3 Cloud p o i n t ( l % , C ) : 53 Surface t e n s i o n (0.25%, dynes/cm): 27.3 V i s c o s i t y , B r o o k f i e l d (25C. L V # l , 100 rpm. cps): 44 Freeze thaw s t a b l e f r e e z i n g p o i n t ( C ) : D i d n o t f r e e z e U n b u i l t Laundry Deterpent-D Components: Water Sodium carbonate Sodi um x y l ene s u l f o n a t e (40%) Ethanol Nonionic s u r f a c t a n t : Hostapal N 090 Hostapal N 040
Wt.
27 7
Physical Properties: Appearance (25C): c l e a r D e n s i t y ( l b / g a l ) : 8.9 pH (l%, 25C): 10.3 Ross M i l e s (49C, 1%. cm): 1 min.: 3 5 min.: 3 Cloud p o i n t ( l % , C ) : 21 Surface t e n s i o n (0.25%, dynes/cm): 29.9 V i s c o s i t y , B r o o k f i e l d (25C, L V # l , 100 rpm. cps): 194 Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : D i d n o t f r e e z e Procedure: D i s s o l v e sodium carbonate i n water and add t h e remaining components i n t h e g i v e n o r d e r w i t h continuous s t i r r i n g .
SOURCE: Hoechst Celanese Corp.:
%
48 2 14 2
Suggested Formulations
Laundry Products
143
Unbui 1t L a u n d r y L i q u i d - A Components: Water Ethanol P o t a s s ium c h 1o r ide T r i e t h a n o l ami ne Noni o n i c s u r f a c t a n t : H o s t a p a l N 090 Anionic surfactant: L i n e a r a1 k y l s u l f o n a t e (60%)
,W t
41 5 1 3 35 15
Physical Properties: Appearance ( 2 5 C ) : c l e a r D e n s i t y ( 1b / g a l ) : 8 . 8 pH (l%, 25C): 9 . 5 Ross M i l e s (49C, 1%, c m ) : 1 m i n . : 19 5 m i n . : 11 Cloud p o i n t ( l % , C ) : > l o 0 S u r f a c e t e n s i o n (0.25%, dynes/cm): 33.51 V i s c o s i t y , B r o o k f i e l d (25C, L V # l , 100 rpm, c p s ) : F r e e z e thaw s t a b l e : f r e e z i n g p o i n t ( C ) : t O
343
Unbui 1t L a u n d r y L i qui d-B Wt.
ComDQnents: Water Ethanol Potassium c h l o r i d e Triethanolamine Nonionic s u r f a c t a n t : Genapol UD 079 Anionic surfactant: L i n e a r a1 k y l s u l f o n a t e (60%)
%
37 5 1 3 39 15
Physical Properties: Appearance ( 2 5 C ) : c l e a r D e n s i t y ( 1b / g a l ) : 8 . 6 pH (l%, 25C): 9 . 5 Ross M i l e s (49C, 1%. cm): 1 m i n . : 12 5 min.: 4 C l o u d p o i n t (l%, C): > l o 0 S u r f a c e t e n s i o n (0.25%. dynes/crn): 29.85 V i s c o s i t y , B r o o k f i e l d (25C, LV#1, 100rpm. c p s : 9 4 . 7 F r e e z e thaw s t a b l e : f r e e z i n g p o i n t ( C ) : t O Procedure: B l e n d t h e components one a t a t i m e i n t h e g i v e n o r d e r w i t h c o n t i n u o u s s t i r r i n g , a t 75-8OF. SOURCE: Hoechst Celanese C o r p . :
Suggested F o r m u l a t i o n s
144
Advanced Cleaning Product Formulations
Unbui 1t Laundry L i a u i d-C Components : Water Ethanol P o t a s s i um c h l o r i d e T r i e t h a n o l ami ne Nonionic s u r f a c t a n t : Genapol 26-L-60 Anionic- s u r f a c t a n t : L i n e a r a l k y l s u l o n a t e (60%)
Wt.
% 44 5 1
3 28 19
Physical Properties Appearance (2%) c l e a r gel Densi t v ( 1 b / a a l ) 14.8 PH (1%; 2 5 c j T 9;2 Ross M i l e s (49C, 1%, cm): 1 m i n . : 20 5 m i n . : 15 Cloud p o i n t (l%, C): >lo0 S u r f a c e t e n s i o n (0.25%. dynes/cm): 32.90 V i s c o s i t y , B r o o k f i e l d (25C. LV#1, 100 rpm, c p s ) : 272 Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : 13 Unbui It Laundry L i a u i d - 0 Components: Water Ethanol Potassium c h l o r i d e Triethanolamine Nonionic s u r f a c t a n t : Genapol 26-L-60 Anionic surfactant: L i n e a r a l k y l s u l f o n a t e (60%) Physical Properties: Appearance (25C): c l e a r D e n s i t y ( 1 b / g a l ) : 14.8 pH (l%, 25C): 9 . 2 Ross M i l e s (49C, 1%, cm): 1 m i n . : 19 5 m i n . : 17 Cloud p o i n t (l%, C): >lo0 S u r f a c e t e n s i o n (0.25%, dynes/cm): 33.47 V i s c o s i t y , B r o o k f i e l d (25C, LV#1, 100 rpm, c p s ) : Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : 12
Wt.
% 40 5 1 3
30 21
403
Procedure: B l e n d t h e components one a t a t i m e i n t h e g i v e n o r d e r w i t h c o n t i n u o u s s t i r r i n g , a t 75-8OF. F o r m u l a t i o n D r e m a i n s a f r e e f l o w i n g l i q u i d a t 51% t o t a l s u r f a c t a n t c o n c e n t r a t i o n . SOURCE:
Hoechst Cel anese Corp. : Suggested F o r m u l a t i o n s
9. Metal Cleaners and Polishes
145
146
Advanced Cleaning Product Formulations
A c i d Cleaner Rhodafac RE-610 I g e p a l CO-630 Phosphoric Acid, Water
3.0 4.0 10.0 83.0
75%
Procedure: Add P h o s p h o r i c A c i d t o Water and h e a t w i t h a g i t a t i o n t o 50C. w i t h r a p i d b u t smooth a g i t a t i o n , s l o w l y b l e n d i n Rhodafac RE-610 and I g e p a l GO-630. Once system i s c o m p l e t e l y u n i f o r m , c o o l w i t h s t i r r i n g t o 40-45C, and package. Physical P r o p erties: Appearance: S l i g h t l y hazy l i q u i d pH, as i s : 1 . 6 S p e c i f i c G r a v i t y : 1.03 V i s c o s i t y : 20 c p s Formula BC-0004 Hiqh-Foaminq A c i d S c r u b b e r *
Wt% . 5.0 2.0 4.0 4.0 3.0 82.0
M i r a n o l FBS I g e p a l CO 630 Sulfamic A c id G l y c o l i c ( H y d r o x y a c e t i c ) A c i d (70%) Butoxyethanol Water
Procedure: Add t h e w a t e r , s u l f a m i c and g l y c o l i c a c i d s . M i x u n t i l d i s s o l v e d . Add t h e r e m a i n i n g i n g r e d i e n t s , w i t h m i x i n g . M i x u n t i 1 uniform. Physical Properties: Appearance: C1 e a r 1 iq u i d pH, as i s : 1 . 5 Speci f ic G r a v i t y : 1 .027 V i s c o s i t y : < l o cps *Suitable f o r applications w i t h a trigger-type Formula BC-0003
SOURCE: Rhone-Poulenc: Suggested F o r m u l a t i o n s
sprayer.
Metal Cleaners and Polishes
147
A c i d M e t a l C l e a n e r No. 392* 0.8 Veegum Rhodopol 23 0.4 72.1 Water Hamp-ene 100 0.9 0.8 Monazol ine CY B Phosphoric a c i d 15.0 Super F l o s s 10.0 Procedure: B l e n d Veegum and Rhodopol. S l o w l y add t o t h e w a t e r w h i l e a g i t a t i ng a t maxi mum a v a i 1 a b l e s h e a r . C o n t i nue m i x i ng u n t i 1 smooth. Add €3 i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each a d d i t i o n u n t i l smooth and u n i f o r m ( a v o i d i n c o r p o r a t i o n o f air). C o n s i s t e n c y : W h i t e p o u r a b l e 1i q u i d . Suggested Packaging: P l a s t i c squeeze b o t t l e w i t h p r e c a u t i o n a r y labelling f o r acid. D i r e c t i o n s For Use: Pour s m a l l amount on damp c l o t h or sponge and c l e a n a r t i c l e w i t h moderate r u b b i n g . R i n s e w i t h w a t e r and d r y . T h i s f o r m u l a may be used on most n o n f e r r o u s m e t a l s i n c l u d i n g copper, b r a s s , s t a i n l e s s s t e e l and aluminum. Comments: The c o m b i n a t i o n o f Veegum and Rhodopol suspends t h e a b r a s i v e and p r o v i d e s a s t a b l e , f r e e f l o w i n g c l e a n e r w i t h good c l i n g t o v e r t i c a l s u r f a c e . Veegum i s p r o t e c t e d a g a i n s t f l o c c u l a t i o n i n t h i s pH 1 c o m p o s i t i o n t h r o u g h base exchange w i t h t h e i m i d a z o l i n e Hamp-Ene 100 f a c i l i t a t e s t h i s exchange. The t r e a t e d Veegum and Rhodopol p r o v i d e s y n e r g i s t i c t h i c k e n i n g w i t h b e t t e r v i s c o s i t y s t a b i l i t y and i n h i b i t i o n o f s y n e r e s i s t h a n i s p o s s i b l e w i t h e i t h e r t h i c k e n e r a l o n e . Super F l o s s d i a t o m i t e a l l o w s good c l e a n s i ng and p o l is h i ng. U . S. P a t e n t No. 4,302,253
A
*
A c i d C l e a n e r No. 288 1. o Van Gel ES Rhodopol 23 0.5 86.5 Water B Phosphoric a c i d 10.0 C T r i t o n X-100 2.0 Procedure: B l e n d Van Gel ES and Rhodopol. S l o w l y add t o t h e w a t e r w h i l e a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e m i x i n g u n t i l smooth. Add B t o A w h i l e m i x i n g . Add C t o A/B and m i x u n t i l smooth and u n i f o r m . Consi s t e n c y : P o u r a b l e 1iq u i d . Suggested Packaging: P l a s t i c squeeze b o t t l e w i t h p r e c a u t i o n a r y l a b e l l i n g f o r acid. Comments: The Van Gel ES/Rhodopol c o m b i n a t i o n a d j u s t s t h e v i s c o s i t y and p r o v i d e s good v e r t i c a l s u r f a c e c l ing. T h i s b a s i c f o r m u l a can be used as a s t a r t i n g p o i n t f o r a bowl c l e a n e r o r metal c leaner. SOURCE: R . T . V a n d e r b i l t Co.: Suggested F o r m u l a t i o n s
A
148
Advanced Cleaning Product Formulations
Aluminum B r i a h t e n e r - I Wt% InQrede i nt : 83.00 Water Phosphoric A c i d (85%) 3.00 Add s l o w l y , mix w e l l C i t r i c Acid, Anhydrous 4.00 D i s s o l ve Ethylene g l y c o l b u t y l e t h e r 5.00 Mix w e l l , u n t i l c l e a r Nonionic Surfactant-HLB 13 3.00 Mix w e l l , u n t i l c l e a r Tomah Q-17-2 2.00 Mix w e l l , u n t i l c l e a r SpG 2 0 / 2 0 C : 1.03 pH: 1.27 Recommended D i l u t i o n s : 5-1O:l A p p l i c a t i o n s : Spray a p p l i c a t i o n s f o r t r u c k s and equipment Soak t a n k a p p l i c a t i o n f o r equipment/parts Aluminum B r i a h t e n e r - I 1 I n a r e d ient : W B 80.50 Water Hydroxyacetic A c i d (70%) 10.00 Add s l o w l y , mix w e l l Ethylene g l y c o l b u t y l e t h e r 5.00 Mix we1 1, u n t i 1 c l e a r Nonionic Surfactant-HLB 13 2.50 Mix w e l l , u n t i 1 c l e a r Tomah Q-17-2 2.00 Mix w e l l , u n t i l c l e a r SpG 20/20C: 1.02 pH: 1.60 Recommended D i l u t i o n s : 5-1O:l A p p l i c a t i o n s : Spray a p p l i c a t i o n s f o r t r u c k s and equipment Soak t a n k a p p l i c a t i o n f o r equipment/parts A1 umi num B r i ahtener-111 I n n r e d ie n t : Wt% 82.50 Water Hydroxyacetic A c i d (70%) 5.00 Add s l o w l y , mix w e l l C i t r i c A c i d , Anhydrous 3.50 D i s s o l ve Ethylene g l y c o l b u t y l e t h e r 5.00 Mix w e l l , u n t i 1 c l e a r Nonionic Surfactant-HLB 13 2.00 Mix w e l l , u n t i l c l e a r Tomah Q-17-2 2.00 Mix w e l l , u n t i 1 c l e a r SpG 20/20C: 1.02 pH: 1.67 Recommended D i l u t i o n s : 5-1O:l A p p l i c a t i o n s : Spray a p p l i c a t i o n s f o r t r u c k s and equipment Soak t a n k a p p l i c a t i o n f o r equipment/parts SOURCE: Tomah Products, I n c . : Formula S-113
Metal Cleaners and Polishes
149
A1 umi n u m C1e a n x W% .t
27.0 10.0 10.0 50.0 3.0
Water Butoxyethanol M i r a n o l CS Conc. P h o s p h o r i c A c i d , 75% Ammoni um B i f 1 u o r i de
Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and m i x u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r , y e l l o w l i q u i d pH, as i s : 1 . 0 S p e c i f i c G r a v i t y : 1.24 V i s c o s i t y : <10 cps Formula MC-0102 A1 uni n u n C1e a n e r Wt.%
M i r a n o l FBS Cheel ox BF-Aci d Butoxyethanol P h o s p h o r i c A c i d (85%) H y d r o f 1u o r i c A c i d (70%) Water
5.0 1 .o
6.0 38.0 8.0 42.0
Procedure: Add t h e w a t e r , s t a r t t h e m i x e r . Add t h e r e m a i n i n g i n g r e d i e n t s w i t h a g i t a t i o n . Mix u n t i l uniform. Physical Properties: Appearance: Hazy 1 iq u i d pH, as i s : 3 . 6 0 S p e c i f i c G r a v i t y : 1 .22 Viscosity: t20 Formula MC-0063
SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
150
Advanced Cleaning Product Formulations
A 1 u m i num C1 e a n e r
M i r a n o l FBS Sodium M e t a s i l i c a t e , Water
Pentahydrate
Wt.% 10.0 5.0 85.0
Procedure: Add w a t e r , s t a r t t h e m i x e r . Add t h e sodium m e t a s i l i c a t e and m i x u n t i l d i s s o l v e d . Add t h e M i r a n o l FBS and m i x u n t i l uniform. Physical Properties: Appearance: C l e a r , y e l l o w l i q u i d pH, as i s : 12.75 Specific Gravity: 1.02 V i s c o s i t y : t 1 0 cps Formula MC-0064
,
A1 umi num C1 e a n e r
Wt.% M i r a n o l FBS I g e p a l CA-630 T e t r a p o t a s s i u m Pyrophosphate Sodium M e t a s i l i c a t e P e n t a h y d r a t e Carbi t o 1 Water
3.5 1.5 5.0 1 .o
3.0 86.0
Procedure: Add t h e w a t e r , s t a r t t h e m i x e r . Add t h e sodium m e t a s i l i c a t e and TKPP and m i x u n t i l d i s s o l v e d . Add t h e r e m a i n i n g i n g r e d i e n t s and mix u n t i l u n i f o r m . P h y s i c a l P r o p e r t i 8s: Appearance: C l e a r , l i g h t y e l l o w l i q u i d pH, as i s : 1 2 . 5 5 S p e c i f i c G r a v i t y : 1.05 V i s c o s i t y : < l o cps Formula MC-0065
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
Metal Cleaners and Polishes
151
Aluminum C l e a n e r C o n c e n t r a t e F-498 %By
Water Sodium M e t a s i l i c a t e ( A n h y d r o u s ) T e t r a P o t a s s i u m P y r o p h o s p h a t e (Powder) Mona NF-10
Wei s h t 75 10 5 10
Procedure: D i s s o l v e sodium m e t a s i 1 i c a t e and t e t r a p o t a s s i u m p y r o p h o s p h a t e i n w a t e r w i t h m i x i n g , t h e n add Mona NF-10. T y p i c a l P r o p e r t i es : Appearance: C 1 e a r 1 iq u i d Cloud P o i n t : 88C Recommended Use D i l u t i o n :
1 t o 4 oz/gal.
Aluminum Wash F-499
Water Sodium M e t a s i l i c a t e ( A n h y d r o u s ) T e t r a Sodium P y r o p h o s p h a t e (Powder) B u t y l Carbi t o 1 Mona NF-10
% By Weight 88 2 3 2 5
Procedure: D i s s o l v e s o d i um m e t a s i 1 i c a t e and t e t r a s o d i um p y r o p h o s p h a t e i n w a t e r , t h e n add B u t y l C a r b i t o l and Mona NF-10. Typical Properties: Appearance: C l e a r l i q u i d pH: 1 2 . 8 Recommended Use D i 1u t io n :
SOURCE: Mona I n d u s t r i e s ,
1 :10 w i t h water
Inc.:
Suggested F o r m u l a t i o n s
152
Advanced Cleaning Product Formulations
Aluminum Cleaner/Polish.
S o f t Paste
Inqredients: ( 1 ) Odor1 ess Kerosene ( 2 ) Duomeen TDO ( 3 ) K a o p o l i t e SF o r 1168 ( 4 ) Bentone 34 ( 5 ) T e r g i t o l NP-10 ( 6 ) Methanol
% bv Weisht 57.5 1. o 26.5 10.3 1.3 3.4
Procedure: Combine f i r s t f i v e i n g r e d i e n t s w i t h i n t e n s i v e a g i t a t i o n u n t i l t h o r o u g h l y dispersed. When ( 6 ) i s added, t h e f l u i d system w i l l change i n a few minutes t o a s o f t paste. Follow recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each product used. Good i n d u s t r i a l p r a c t i c e s should be used when h a n d l i n g flammable ingredients. Comments: A f t e r r u b b i n g t o s u f f i c i e n t l u s t e r , f l u s h o f f w i t h water, o r wipe w i t h a damp c l o t h . Product may be used w i t h f i n e s t e e l wool i f t h e aluminum i s h e a v i l y weathered. Consistency o f t h i s product i s r a t h e r s t a b l e over wide tempe r a t u r e range. For more f l u i d p r o d u c t , omit ( 4 ) and ( 6 ) , o r use l e s s e r q u a n t i t i e s , keeping 3 : l r a t i o , t o g i v e d e s i r e d consi stency Use o f K a o p o l i t e 1168 g i v e s more aggressive c l e a n i n g and polishing action t o t h e formulation.
.
S i l v e r Polish,
S o f t Paste
I n a r e d ie n t s : ( 1 ) Miranol DM ( 2 ) K a o p o l i t e SF
% by Wei q h t
50 50
Procedure: Charge 40 p a r t s o f ( 1 ) t o s u i t a b l e p a s t e m i x e r . Run mixer c o n t i n u o u s l y w h i l e adding ( 2 ) . w i t h f u r t h e r small increments o f ( 1 ) i f necessary, t o a v o i d o v e r l o a d i n g t h e mixer d r i v e ; t h e o b j e c t i s t o blend a t heaviest p r a c t i c a b l e consistency t o p r o v i d e thorough d i s p e r s i o n . Continue m i x i n g u n t i l f u l l y d i spersed and smooth. Follow recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each product used.
SOURCE:
Kaopolite,
I n c . : Suggested Formulations
Metal Cleaners and Polishes
153
A1 umi num C l e a n e r / P o l ish, S o f t P a s t e % by Weiqht 58.5 26.5
Ingredients: ( 1 ) Odor1 e s s Kerosene ( 2 ) K a o p o l i t e SFO-NP ( 3 ) Bentone 34 ( 4 ) T e r g i t o l NP-10 ( 5 ) Methanol
10.3 1.3 3.4
Procedure: Combine f i r s t f o u r i n g r e d i e n t s w i t h i n t e n s i v e a g i t a t i o n u n t i l t h o r o u g h l y d i s p e r s e d . When ( 5 ) i s added, t h e f l u i d system w i l l change i n a few m i n u t e s t o a s o f t p a s t e . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d b e used when h a n d l i n g flammable i n g r e d i e n t s . Comments : A f t e r rubbing t o s u f f i c i e n t l u s t e r , f l u s h o f f w i t h water, o r w i p e w i t h a damp c l o t h . P r o d u c t may be used w i t h f i n e s t e e l wool i f t h e aluminum i s h e a v i l y weathered. Consistency o f t h i s p r o d u c t i s r a t h e r s t a b l e over wide t e m p e r a t u r e r a n g e . F o r more f l u i d p r o d u c t , o m i t ( 3 ) and ( 5 ) , o r use l e s s e r q u a n t i t i e s , k e e p i n g 3 : l r a t i o . T a r n i s h - R e t a r d a n t S i l v e r P o l ish. S o f t P a s t e I n s r e d ien t s :
(1) (2) (3) (4)
D e i o n i z e d Water N a t r o s o l 250-LR Tarnish Retardant B r i j 30 (5) K a o p o l i t e SF (6) Korthix ( 7 ) Methyl p-hydroxybenzoate
% by W e i s h t 69.4 1. o 5.0 5.0 14.5 5.0 0.1
Procedure: Mix ( 2 ) i n t o ( 1 ) . Separately, d i s s o l v e ( 3 ) i n ( 4 ) , w i t h s l i g h t warming i f n e c e s s a r y , t h e n add t o p r e v i o u s m i x t u r e . W i t h i n t e n s i v e a g i t a t i o n , add ( 5 ) , t h e n (S), c o n t i n u i n g a g i t a t i o n u n t i l w e l l d i s p e r s e d and smooth. Add ( 7 ) a s p r e s e r v a t i v e . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t u s e d .
SOURCE: K a o p o l i t e ,
Inc.:
Sugegsted F o r m u l a t i o n s
154
Advanced Cleaning Product Formulations
F i n e Brass P o l i s h Inaredients: ( 1 ) D e i o n i z e d Water ( 2 ) Sodium Hexametaphosphate, anhydrous (3) Korthix ( 4 ) K a o p o l i t e SF ( 5 ) B i o - S o f t S-100 ( 6 ) A m i n o a c e t i c A c i d , t e c h n i c a l grade ( 7 ) P r o p y l ene G1 y c o l ( 8 ) Ammonia Water, 26 Be' ( 9 ) C o l l o i d 60
% by Weiqht 39.9 0.1
2.0 25.0
3.0 5.0 25.0 q.s. q.s.
Procedure: D i s s o l v e ( 2 ) i n ( l ) , add (3) and ( 4 ) s l o w l y , w i t h v i g o r o u s a g i t a t i o n u n t i l w e l l - d i s p e r s e d and smooth. Reduce a g i t a t i o n t o moderate, add (5), ( 6 ) , and ( 7 ) , b l e n d t h o r o u g h l y . C o n t i n u i n g moderate a g i t a t i o n , add ( 8 ) t o pH 8 . 5 . About 0.2% o f ( 9 ) i s e f f e c t i v e , i f needed, t o c o n t r o l foam d u r i n g m i x i n g and p a c k a g i ng. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Emu1s i on M e t a l P o l ish Inqredients: ( 1 ) Odor1 ess Kerosene ( 2 ) VM&P Naphtha (3) Oleic Acid (4) D e i o n i z e d Water (5) Sodium Hexametaphosphate ( 6 ) K a o p o l i t e SF o r 1168 ( 7 ) Ammonia Water, 26 Be' (8) Triethanolamine
% b y Weiaht
12.0 24.0
2.5 43.0 1 .o 15.0 1.9 0.6
Procedure: D i s p e r s e ( 4 ) , ( 5 ) , ( 6 ) , ( 7 ) , and ( 8 ) . Then add t h i s s o l u t i o n t o t h e o i l phase ( 1 1 , ( 2 ) . and (3), a g i t a t i n g w e l l u n t i l smooth. F o l l o w recommended h a n d l i n a _ p. r a c t i c e s o f t h e s u.p.p l i e r s o f each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when hand i n g flammable ingredients. Comments : Use o f K a o p o l i t e 1168 g i v e s more a g g r e s s i v e c l e a n ng and polishing action t o t h i s formulation.
SOURCE:
Kaopol it e ,
I n c . : Suggested Formul a t i on8
Metal Cleaners and Polishes
155
I r o n PhosDhatins and C l e a n i n g F o r m u l a t i o n s - L i q u i d P r o d u c t s 1 . H3P04, 75% Sodi um molybdate-2H20 Surfactants Water
18.3% 1% 2.7% 78.3%
Comment: Blue a c i d cleaner-phosphating systems. pH o f 3% s o l u t i o n : 2 . 1 .
system f o r use i n immersion
12.5% 3% 3% 2.5% 79%
2. Monosodium o r t h o p h o s p h a t e (MSP) H3P04, 75% Sodi um molybdate-2H20 Surfactants Water Comment: L i q u i d a c i d p r o d u c t used i n steam p h o s p h a t o r s and steam i n j e c t i o n equipment t o remove heavy s o i l s and d e p o s i t i r o n phosphate c o a t i n g . pH o f 1% s o l u t i o n : 3 . 5 5 . 3 . TKPP, 60% s o l u t i o n Monosodium o r t h o p h o s p h a t e (MSP) H3P04, 75% Sodi um n i t r a t e Surfactants Water
10% 10.4% 9.7% 1.2% 3.8% Balance
Comment : L i q u i d a c i d product, s l i g h t l y viscous, f o r i r o n phosphating pH as i s : 3 . 3 5 . Soak o r s p r a y p r o c e s s , d e p o s i t s 40 M g / f t 2 i n one m i n u t e . Steam C1e a n e r s Powder 5 0% 45 2 3
STPP Sodium m e t a s i l i c a t e p e n t a h y d r a t e Nonionic Sodi um g l u c o n a t e
L iaui d Noni o n i c P o t a s s i u m s a l t o f a n o n i o n i c phosphate e s t e r KOH (45%) P o t a s s i um s i 1 ic a t e TKPP Water
2% 6 25 12 12 balance
SOURCE: FMC C o r p . : D e t e r g e n t A p p l i c a t i o n s B u l l e t i n No. 4: Suggested F o r m u l a t i o n s
1
156
Advanced Cleaning Product Formulations
I r o n PhosDhati nu and Cleani na F o r m u l a t i ons-Li a u i d Products
A c i d C1eaners Powder
60% 38 2
SAPP Sodium b i s u l f a t e Anionic
Liquid-I
20% 15 2
Phosphori c A c i d (85%) S u l f u r i c A c i d (96%) Noni oni c Water
balance Liauid-I1
35% 10-20 0- 2
Phosphoric A c i d (85%) B u t y l C e l l osol ve Noni oni c Water
balance
I n d u s t r i a l Soak Tank Aluminum Cleaner
30% 40-45 20 2- 3 1- 2
STPP Sodi um metasi 1ic a t e anhydrous Sodium sesquicarbonate Anionic Nonionic
Rust Remover f o r S t e e l
15-20% 3- 5
Phosphoric a c i d (85%) O x a l i c a c i d or c i t r i c a c i d Water Deareaser ( f o r enaine b l o c k s
balance
a
automotive machine D a r t s )
Anionic TKPP Sodium x y l e n e s u l f o n a t e Sodium m e t a s i l i c a t e anhydrous Butyl C e l l osolve Water
SOURCE:
FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4: Suggested Formulations
7%
5 3 7 1 77
Metal Cleaners and Polishes
157
I r o n P h o s p h a t i n a and C l e a n i n q F o r m u l a t i o n s - S o l i d P r o d u c t s Monosorb MSP SAPP Sodium molybdate-2H20 Nonionic s u r f a c t a n t
7 7% 6% 2.5% 14.5%
Comments: Med. t e m p e r a t u r e (120-14OF); g i v e s s l i g h t l y d a r k e r c o a t i n g t h a n t h e u s u a l l i g h t b l u e phosphate f i l m ; pH o f 2 o z / g a l s o l u t i o n : 3.5. Use a t 1 1/2-2 o z / g a l i n 3 s t a g e s p r a y system f o r p h o s p h a t i n g cold rolled steel.
Monosorb MSP SAPP Sodi um mol ybdate-2H20 Sodi um s i 1ic a t e H y d r o f l u o r i c a c i d , 70% Nonionic s u r f a c t a n t Use b l e n d o f h i g h and l o w t e m p e r a t u r e n o n i o n i c s .
71% 7% 1.5% 1% 7% 13%
Comments: Use t e m p e r a t u r e 130-15OF; f o r m u l a t i o n a v o i d s s t r e a k i n g , d u s t i n g , removes s o i l , l i g h t o i l , d r a w i n g compounds and o t h e r common c o n t a m i n a n t s ; pH o f 2 o z / g a l s o l u t i o n : 3 . 0 Use a t 1 1/4-2 o z / g a l . i n 3 s t a g e s p r a y system, m a i n t a i n o p e r a t i n g pH w i t h i n 3 . 2 - 4 . 5 ; f o r s t e e l , aluminum and g a l v a n i z e d metal phosphating. Monosorb MSP H3P04, 75% SAPP Sodi um Mol ybdate-2H20 Sodi um N i t r a t e Nonionic S u r fa ctant Comments: Use t e m p e r a t u r e 130-15OF; p r o d u c e s dense, h a r d c o a t e x c e l l e n t f o r p a i n t adhesion; f o r m u l a i s pH s t a b l e and 1 onger s e r v i c e . Use a t 1 1/4-2 o z / g a l i n 3 s t a g e s p r a y system, main pH i n 3 . 5 - 4 . 0 range. Phosphate f i l m i s formed i n 46-60
55% 10% 9% 1% 11% 14%
ng I offers a i n i ng seconds.
Some n o n i o n i c s u r f a c t a n t s t h a t can be used i n t h e s e formu l a t i ons : T r i t o n X102 I g e p a l CA620 P l u r o n i c F68 P l u r a f a c D25
SOURCE:
FMC C o r p . : D e t e r g e n t A p p l i c a t i o n s B u l l e t i n No. 4: Suggested F o r m u l a t i o n s
158
Advanced Cleaning Product Formulations
L o w Foam Heavy D u t y A1 k a l i n e C l e a n e r - A
Component: Water Sodium M e t a s i l i c a t e , Burcene 100 B u r c o s o l v TM Burco TME Burcowet TM-LF
% bv Weight
58 5 2 10 20 5
Pentahydrate
Low Foam Heavy D u t y A1 k a l ine C l e a n e r - B Component: Water Sodium M e t a s i l i c a t e , P e n t a h y d r a t e Sodium X y l e n e S u l f o n a t e s 40% B u r c o s o l v TM Burco TME Burco LAF-125
% b v Weinh_t
55 5 8.5 10 20 5
Procedure: Add a l l components i n t h e o r d e r l i s t e d . S t i r u n t i l homogeneous between each a d d i t i o n . F o r m u l a t i o n A i s l o w f o a m i n g a t t e m p e r a t u r e s above 1 6 0 F . F o r m u l a t i o n B i s l o w f o a m i n g above 1OOF. M o d e r a t e A1 k a l in i t y ,
S o i 1 S p l itti no Soak C l e a n e r
Components: Water Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) T r i s o d i u m Phosphate ( C r y s t a l s ) B u r c o ADS-40 Burco EHS B u r c o TME
% b y Weight
70 5 10 5 5 5
Procedure: Add components i n t h e o r d e r l i s t e d . S t i r u n t i l homogeneous between each a d d i t i o n . SOURCE: B u r l i n g t o n Chemical Co.,
I n c . : Suggested F o r m u l a t i o n s
Metal Cleaners and Polishes
159
M e t a l C1e a n e r F o r m u l a s L i q u i d A-14 P a r t s by Weiaht 38 18 10 2 32
M a t e r i a1 s : Yarmor o r Herco p i n e o i l Dresinate XX Pamak 4 o r 4A C a u s t i c soda (NaOH) Water L i q u i d A-15 Materials:Yarmor o r Herco p i n e o i l D r e s i n a t e TX Water
P a r t s by Weiqht 38 30 32 Powder A - 1 6
M a t e r i a1 s : Yarmor o r Herco p i n e o i l Dresinate XX Soda ash (Na2C03) Sodium o r t h o p h o s p h a t e (Na3P04-12H20) Water
P a r t s b y Weiqht 10 10 45 30 5
Method o f P r e p a r a t i o n : Formula A-14: B l e n d t h e p i n e o i l and Pamak and h e a t t o 50-60C. W h i l e s t i r r i n g , d i s s o l v e t h e powdered soap i n t h i s m i x t u r e ; t h e n add t h e c a u s t i c soda d i s s o l v e d i n a l l t h e w a t e r . C o n t i n u e s t i r r i n g u n t i l p r o d u c t i s homogeneous. Formula A - I S : Heat w a t e r t o 50-60C and s l o w l y add t h e D r e s i n a t e T X w i t h a g i t a t i o n . Then s l o w l y add a p o r t i o n o f t h e p i n e o i l . M i x t h o r o u g h l y f o r a few m i n u t e s and add t h e r e m a i n i n g p i n e o i l . S t i r u n t i l p r o d u c t appears u n i f o r m . Formula A - 1 6 : I n a powder m i l l , t h o r o u g h l y m i x t h e powdered i n g r e d i e n t s . S l o w l y add f i r s t t h e p i n e o i l and t h e n t h e w a t e r . C o n t i n u e m i 11 ing u n t i 1 a f r e e - f 1owi ng powder is o b t a i ned.
SOURCE:
Hercules,
I n c . : P i n e Oil F o r m u l a r y
140 Advanced Cleaning Product Formulations Metal Cleanina ( I n d u s t r i a l Ferrous Metals--Immersion L i q u i d-Li g h t Duty
49% 12% 12% 12% 12% 3%
Water Potassi um hydroxide (45%) Metso Beads 2048 sodium m e t a s i l i c a t e TKPP (60%) Sodi um x y l ene s u l f o n a t e (40%) Nonylphenol , 11-1 3 moles EO Powder--Heavy
1
Duty
22% 10% 3% 5% 2 0% 40%
Sodium carbonate TSPP Nonylphenol , 11 -1 3 moles €0 Sodi um g l uconate Metso Beads 2048 sodium m e t a s i l i c a t e Sodi um hydroxide beads ("PELS") Powder--Medi urn Duty
40% 16%
Sodium carbonate TSP Nonylphenol, 11-13 moles EO Metso Beads 2048 sodium m e t a s i l i c a t e Sodium l i g n o s u l f o n a t e Sodi um h y d r o x i d e beads ("PELS") Powder--Light
4%
14% 4% 22% Duty
Sodium carbonate STPP Nonylphenol , 11 -1 3 moles EO Metso Beads 2048 sodi um metasi 1i c a t e
4 5% 2 5% 5% 25%
Ferrous Metals--SPray L i a u i d - - L i g h t Duty Water Phosphate e s t e r , p o t e s s i um s a l t Nonylphenol, 9-11 moles EO Potassi um hydroxide (45%) S t a r sodi urn s i 1ic a t e Gluconic a c i d (50%)
10.0% 4.5% 1 .O%
38.0% 45.0% 1.5%
Powder--Li a h t Duty
55.0% Sodi um carbonate 11 .O% TSPP C12-Cl3 l i n e a r a l c o h o l , 1 mole EO 2.0% C12-Cl3 l i n e a r a l c o h o l , 3 moles EO 2.0% Metso Pentabead 20 sodium m e t a s i l i c a t e 2 5% Sodium gluconate 5.0% SOURCE: PQ Corp.: Detergent Formulary: Suggested Formulations
Metal Cleaners and Polishes
161
Non-Aci d A 1 u m i n u m B r i a h t e n e r - I Inqredient: Water
Wt%
58.00 10.00
NTA
Dissolve KOH (45%) Add, m i x , coo NaOH (50%) Add, m i x , coo N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Tomah A l k a l i S u r f a c t a n t Add, m i x w e l l
4.00 20.00 2.00 6.00
pH: 13.80 Recommended D i l u t i o n s : 5-2O:l A p p l i c a t i o n s : Truckwash, p a r t s wash N o t e s : R i n s e w e l l i m m e d i a t e l y a f t e r wash Formula 1-113-1 Non-Aci d A 1 umi num B r i q h t e n e r - I I Ingredient: Water EDTA D i s s o l ve KOH (45%) Add, m i x , c o o l NaOH (50%) Add, m i x , c o o l Noni o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Tomah A l k a l i S u r f a c t a n t Add, m i x w e l l
Wt% 58.00 10.00
4.00
20.00 2.00 6.00
pH: 13.80 Recommended D i l u t i o n s : 5-2O:l A p p l i c a t i o n s : Truckwash, p a r t s wash N o t e s : R i n s e w e l l i m m e d i a t e l y a f t e r wash Formula 1-113-11
SOURCE: Tomah P r o d u c t s ,
Inc.:
Suggested F o r r n u l a t l o n s
162
Advanced Cleaning Product Formulations
Soak-Tank M e t a l C l e a n e r (Powder, F o r Maanesi u m l W% .t 5.0 2.0
Rhodafac RA-600 I g e p a l CO-710 T a l l O i 1 F a t t y A c i d Soap Sodi um T r i p o l y p h o s p h a t e Sodium Carbonate ( L t . D e n s i t y ) Sodium H y d r o x i d e , F l a k e d Sodi um M e t a s i 1ic a t e , Anhydrous
5.0 20.0
18.0 20.0 30.0
Procedure: 1 . M i x Sodium Carbonate, Rhodafac RA-600, I g e p a l CO-710 and T a l l O i l F a t t y A c i d Soap t o g e t h e r u n t i l a u n i f o r m powdered m i x t u r e is o b t a i ned. 2. Add r e s t o f i n g r e d i e n t s . M i x t h o r o u g h l y . P h y s i c a l P r o p e r t i 8s: 12.8 pH ( 7 % ) : Speci f ic G r a v i t y : 0 . 9 8 Formula MC-0068 HiQh-Temperature
Spray Cleaner
w l y Water Sodi um M e t a s i 1 ic a t e , Anh. T e t r a p o t a s s i u m Pyrophosphate, M i r a t a i ne JC-HA A n t a r o x L61 A l c o d e t MC 2000
60%
73 5 10 5 2 5
Procedure: Add t h e Sodium M e t a s i l i c a t e t o t h e w a t e r , w i h m i x i n g . M i x u n t i l d i s s o l v e d . Add t h e r e m a i n i n g i n g r e d i e n t s , w i t h m i x i n g i n t h e o r d e r l i s t e d , and c o n t i n u e m i x i n g u n t i l a c e a r , homogeneous solution results. Physical Properties: Appearance: C l e a r , p a l e y e l l o w s o l u t i o n pH, as i s : 12.6 V i s c o s i t y : <20 cps S p e c i f i c G r a v i t y : 1.08 Formula MC-0104
SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
Metal Cleaners and Polishes
163
V i scous PhosDhori c/Oxal ic A c i d C1 e a n e r - I
w
Inqredi ent: Water Phosphoric A c i d (75%) Add, m i x , cool Oxal i c A c i d D i s s o l ve A c i d Thickener Add, mix w e l l S a l t (NaC1) D i s s o l ve w i t h m i x i ng V i s c o s i t y ( c p s ) : 693
71 .OO 22.00 1
.oo
3.00 3.00
Viscous Phosphoric/Oxalic A c i d C l e a n e r - I 1 Ingredient: Water Phosphoric A c i d (75%) Add, mix, cool Oxalic Acid D i s s o l ve Aci d Thickener Add, mix w e l l S a l t (NaCl) D i s s o l v e w i t h m i x i ng V i s c o s i t y ( c p s ) : ll?
72.00 22.00 1
.oo
2.00 3.00
Viscous Phosphoric/Oxalic A c i d Cleaner-XI1
w
Inaredient: Water Phosphoric A c i d (75%) Abd, mix, cool Oxalic Acid D i s s o l ve A c i d Thickener Add, m i x w e l l S a l t (NaCl) D i s s o l v e w i t h m i x i ng V i s c o s i t y ( c p s ) : 2275
71 .OO 21 .oo 1
.oo
2.00 5.00
Recommended D i l u t i o n s : 0-1O:l A p p l i c a t i o n s : Metal c l e a n i n g , r u s t removal, d e s c a l i n g Notes: Mix A c i d Thickener p r i o r t o use i n order t o assure homogenei t y
SOURCE:
Tomah Products,
Inc.:
Formula A-107
10. Oven, Grill and Hot Plate Cleaners
364
Metal Cleaners and Polishes
165
A1 urni n u m C l e a n e r Wei q h t ,% 7.5 4.5
Mackam 2CSF ( C o c o a m p h o d i p r o p i o n a t e ) Sodium M e t a s i l i c a t e 5H20 Water
88.0
Procedure: 1 . Add components t o w a t e r . 2 . Heat t o 50 d e g r e e s C . and b l e n d u n t i l c l e a r . 3. Cool and f i l l .
G r i 11 Cleaner WeiQht,% 22.0
Sodium M e t a s i l i c a t e P e n t a h y d r a t e Mackami ne LO (Laurami ne O x i d e ) C a u s t i c Soda (50%) Sodium X y l e n e S u l f o n a t e (40%) T e t r a s o d i um EDTA (40%) D e i o n i z e d Water, qs t o
9.0 2.0 4.0 1 .o
100.0
Procedure: 1 . Add Sodium M e t a s i l i c a t e and T e t r a s o d i u m EDTA t o w a t e r and h e a t t o 60 degrees C . 2 . Add Mackamine LO and C a u s t i c Soda ( 5 0 % ) . 3. Add Sodium X y l e n e S u l f o n a t e u n t i l c l e a r . Oven C l e a n e r Mackam TM ( D i h y d r o x y e t h y l T a l l o w G l y c i n a t e ) C a u s t i c Soda (50%) Water
Wei g h t ,% 5.0 15.0
00.0
Procedure: 1 . Add c a u s t i c soda t o w a t e r . 2 . Add Mackam TM and b l e n d u n t i l c o m p l e t e l y d i s p e r s e d . Remark: The v i s c o s i t y can b e c o n t r o l l e d b y i n c r e a s i n g o r d e c r e a s i n g t h e Mackam TM. SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a l
Formulary
166
Advanced Cleaning Product Formulatiom
C a u s t i c Oven, G r i l l and D r a i n C l e a n e r s T h i c k e n e d s o l u t i o n s o f c a u s t i c a r e used as oven and g r i l l cleaners. Most o f t h e s e f o r m u l a t i o n s can be a p p l i e d e a s i l y by b r u s h i n g o r pump-spraying and do n o t r u n on a v e r t i c a l s u r f a c e . Formul a t i on A Inqredients: Water Acusol 820 S t a b i NPElO NaOH (50%) V i s c o s i t y (cp
% as s u p p l i e d
85.75 3.75
z e r (30%)
0.5 10 #3 s p i n d l e @ 12 rpm):
4300
Formulation B % as s u p p l i e d
Inaredients: Water Acusol 820 S t a b i l i z e r (30%) NPElO NaOH (50%) V i s c o s i t y (cp;
#3 s p i n d l e @ 12 rpm):
75.25 4.25
0.5 20 4000
Formulation C % as s u p p l i e d
Inaredi ents: Water Acusol 820 S t a b i l i z e r (30%) NPElO NaOH (50%) V i s c o s i t y (cp;
#3 s p i n d l e I3 12 rpm):
87.4 2.5 0.1 10 675
MiXing I n s t r u c t i o n s : Add i n g r e d i e n t s i n t h e o r d e r l i s t e d . Add Acusol 820 t h i c k e n e r t o t h e w a t e r and t h e n t h e s u r f a c t a n t w i t h adequate a g i t a t i o n . Add c a u s t i c s o l u t i o n s l o w l y w i t h adequate m i x i n g . I n c r e a s i n g t h e s u r f a c t a n t l e v e l may l e a d t o p r o d u c t separation. Note: A f l o c c u l a n t p r e c i p i t a t e may f o r m upon a d d i n g t h e c a u s t i c s o l u t i o n . The p r e c i p i t a t e i s caused b y h i g h l o c a l c o n c e n t r a t i o n s o f c a u s t i c and d i s a p p e a r s a f t e r a few m i n u t e s o f a g i t a t i o n . SOURCE:
Rohm and Haas Co.: Formulations
Acusol 820 S t a b i l i z e r : Suggested
Metal Cleaners and Polishes
167
H o t P1a t e / G r i 11 C1e a n e r
Wt.% Sodium M e t a s i l i c a t e , Anhydrous Cheel ox NTA-Na3 Rhodafac RA-600 A l k a m i d e DC-212/S Sodium X y l e n e S u l f o n a t e (40% a c t i v e ) Sodium H y d r o x i d e Water
22.0 1.o 7.0 2.0 10.0 1.o 57.0
Procedure: 1 . D i s s o l v e Sodium M e t a s i l i c a t e , Anhydrous i n w a t e r . 2 . Add Cheelox NTA-Na3 and Sodium X y l e n e S u l f o n a t e . M i x t h o r oughl y . 3 . Add Rhodafac RA-600, A1 kami de DC-212/5 and Sodi um H y d r o x i d e , m i x i n g a f t e r each a d d i t i o n . 4. F i l t e r product. P h y s i c a l P r o p e r t i es : pH, as i s : 1 3 . 0 pH ( 1 % ) : 1 1 . 6 V i s c o s i t y : 40 cps S p e c i f i c G r a v i t y : 1 .08 Formula MS-0076
Oven C l e a n e r
Wt.% Rhodapol Veegum Water Sodium H y d r o x i d e (50% a c t i v e ) Rhodafac RA-600
1.2 0.4 80.4 8.0 10.0
Procedure: 1 . Heat w a t e r t o 85-9OC. Add Veegum and Rhodapol. S t i r f o r one hour. 2 . B r i n g t e m p e r a t u r e s t o 55C. Add Sodium H y d r o x i d e and Rhodafac RA-600. M i x t h o r o u g h l y . Physical Properties: pH ( a s i s ) : 1 2 . 8 pH ( 1 % ) : 1 0 . 9 V i s c o s i t y : 830 c p s S p e c i f i c G r a v i t y : 1.02 Formula MS-0075
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
168
Advanced Cleaning Product Formulatiom
I n d u s t r i a l Cleaners Oven C l e a n e r
Wt% Innredi ent : 57.00 Water 2.00 Sodi um G1 u c o n a t e Add, mix w e l l 20.00 NaOH ( f l a k e ) Dissolve, cool 10.00 Tomah A 1 k a l i S u r f a c t a n t Add, m i x w e l l 6.00 P r o p y l ene G1y c o l Add, m i x w e l l 4.00 E t h y l e n e G l y c o l Monobutyl E t h e r Add, m i x w e l l 1 .oo N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l pH: 13.10 Recommended D i l u t i o n s : As n e c e s s a r y A p p l i c a t i o n s : Oven, g r i l l c l e a n e r Notes: E x c e l l e n t on g r e a s y r e s i d u e s . R i n s e a f t e r a p p l i c a t i o n . Formula 1-115 T h i c k e n e d A 1 k a l in e C l e a n e r Inaredi ent: Water NaOH ( f l a k e ) Add s l o w l y , d i s s o l v e , c o o l Tomah A l k a l i S u r f a c t a n t Add. m i x w e l l Tomah A m p h o t e r i c L Add, m i x w e l l pH: 14.00 Recommended D i 1u t i ons: a s - i s A p p l i c a t i o n s : B r u s h on g r i l l / o v e n c l e a n e r Notes: #1 V i s c o s i t y @ 20C: 400 c p s R i n s e w e l l a f t e r use Formula 1-117 T h i c k e n e d A 1 k a l in e C1eaner Inaredient: Water NaOH ( f l a k e ) Add s l o w l y , d i s s o l v e , c o o l Tomah A1 k a l i S u r f a c t a n t Add, m i x w e l l Tomah A m p h o t e r i c L Add, m i x w e l l pH: 14.00 Recommended D i l u t i o n s : a s - i s A p p l i c a t i o n s : B r u s h on g r i l l / o v e n c l e a n e r Notes: #2 V i s c o s i t y @ 2 0 C : 1900 cps Rinse w e l l a f t e r use Formula 1-118
SOURCE: Tomah P r o d u c t s ,
Inc.:
Suggested F o r m u l a t i o n s
W B 71.50 24.00
3.00 1.50
Wt% 72.00 20.00
5.00 3.00
11
Polishes, Coatings and Finishes
169
170
Advanced Cleaning Product Formulations
Aerosol
ADD^ iance P o l i s h
A w a t e r - i n - o i l emulsion p o l i s h which produces a h i g h g l o s s , no smear, h a r d f i l m when a p p l i e d t o F o r m i c a , as w e l l as most k i t c h e n a p p l iances . The c o n c e n t r a t e f o r m u l a t i o n can be a p p l i e d as a l i q u i d p o l ish. Aerosol Concentrate: P e r c e n t bv Wei q h t -_ Part: Inaredients: A 200 S i l i c o n e F l u i d , 350 c s . 4.0 W i t c a m i de 51 1 1.o Carnauba Wax #3 1.o Isopar K 34.0 0 Water 60.0 Suggested A e r o s o l F o r m u l a t i o n : _ Pe _r c e n t by Wei g h t Inqredient : 80 C o n c e n t r a t e CP7-0227 P r o p e l 1a n t o f c h o i c e 20 P r e p a r a t i on : 1 . Heat m i x t u r e o f P a r t A i n g r e d i e n t s t o 8OC ( 1 7 6 F ) - - m e l t wax. 2. Heat w a t e r t o 8OC ( 1 7 6 F ) . 3 . Add w a t e r s l o w l y t o P a r t A m i x t u r e w i t h h i g h speed a g i t a t i o n . 4. C o n t i n u e s t i r r i n g w h i l e c o o l i n g t o room t e m p e r a t u r e . 5 . Package a e r o s o l . F o r m u l a t i o n CP2-0227
Aerosol F u r n i t u r e P o l i s h Uses a u n i q u e b l e n d o f s i l i c o n e f l u i d s w h i c h g i v e s t h i s p o l ish e x c e l 1e n t g l o s s w i t h m i n i ma1 smear. The c o n c e n t r a t e may be used as a l i q u i d f u r n i t u r e p o l i s h o r t o f o r m u l a t e an a e r o s o l p r o d u c t . Aerosol Concentrate: Part: Inaredients: P e r c e n t by Wei q h t A 200 S i l o c o n e F l u i d by Dow C o r n i n g , 10,000 c s . 1. o 200 S i l i c o n e F l u i d b y Dow C o r n i n g . 350 c s . 4.0 W i t c a m i de 51 1 1.4 L-140 S o l v e n t 14.0 Lemon F r a g r a n c e 0.5 0 C-340 Carnauba Wax E m u l s i o n 16.0 Water 63.1 Suggested A e r o s o l F o r m u l a t i o n : Inqredient : E2-7300 C o n c e n t r a t e A e r o s o l P r o p e l 1a n t
P e r c e n t b v Wei s h t 80.0 20.0
Preparation : 1 . Add a l l i n g r e d i e n t s i n P a r t A i n t o v e s s e l w i t h good a g i t a t i o n 2. When P a r t A i s mixed t h o r o u g h l y , add P a r t B w i t h good a g i t a tion. F o r m u l a t i o n E2-7300 SOURCE:
Dow C o r n i n g C o r p . :
Suggested F o r m u l a t i o n s
Polishes, Coatings and Finishes
I71
Aerosol F u r n i t u r e P o l i s h Part: A
B
C
Inqredi ent : 200 F l u i d - 60,000 c s 200 F l u i d - 350 c s W i t c a m i de 51 1 Stoddard Solvent Lemon F r a g r a n c e Stoddard S o l v e n t C-340 Carnauba Wax Emulsion Water P r o p e l 1a n t o f Choi c e
P e r c e n t by WeiRht 1.5 4.5 0.8 11.2 0.4 18.0 12.8 50.8 20.0
Method M i x p a r t "A" u n t i l u n i f o r m . Add P a r t "B" and mix w i t h good a g i t a t on. Package. N o t e : For co-wax d i l u t i o n , h e a t 10 p a r t s wax t o 9OC (194F) and h e a t 90 p a r t s w a t e r t o 9OC ( 1 9 4 F ) . M i x w i t h good a g i t a t i o n . F u r n i t u r e P o l ish Part : A
8
Inqredi ent : 200 F l u i d - 500 c s Linseed O i 1 I g e p a l CO-520 Stoddard S o l v e n t Water
Method: Add p a r t "B"
t o p a r t "A"
P e r c e n t by Weight
3 9 5 35 48 u s i n g a high-shear mixer.
F u r n i t u r e P o l i s h ( C a t i o n i c Emulsion) Part: A
B
Insredient: 200 F l u i d - 350 c s Carnauba Wax, #1 Y e l l o w Be Square Wax, W h i t e 190/195 Armac-HT M i n e r a l S p i r it s Water
P e r c e n t by Wei s h t 3.00 1.25 0.25 1.25 26.00 65.50
Method: Heat p a r t " A " t o 8OC ( 1 76F) and "B" t o 85C (185F). Whi l e b l e n d i n g "A" on a high-speed, h i g h - s h e a r m i x e r , s l o w l y add "B". F o r c e - c o o l t o 35C (95F) i n i c e . CAUTION: Check cans f o r p o s s i b l e c o r r o s i o n s i n c e t h i s i s a c a t i o n i c emulsion. SOURCE: Dow C o r n i n g Corp. : Suggested F o r m u l a t i o n
172
Advanced Cleaning Product Formulations
D e t e r a e n t - / C o r r o s i on-Resi s t a n t P o l is h T h i s p o l i s h has e x c e l l e n t d e t e r g e n t r e s i s t a n c e and a l s o a h i g h degree o f c o r r o s i o n r e s i s t a n c e . Ingredients: Part A: Isosteari c Acid Dow C o r n i n g 531 F l u i d Dow C o r n i n g 536 F l u i d Kerosene Stoddard S o l v e n t W i t c a m i de 51 1 P a r t €3: Water K a o p o l i t e SF Part C: Bentone 38 P a r t D: I s o p r o p y l A l c o h o l (Anhydrous)
Percent bv Weight 0.60 6.00 2.00 10.00 16.40 1 .oo 53.25 10.00 0.50 0.25
Add i s o s t e a r i c a c i d t o t h e c o m b i n a t i o n o f Dow C o r n i n g 531 and 536 f l u i d s , and a l l o w f i v e m i n u t e s t o r e a c t . Add t h e r e m a i n i n g i n g r e d i e n t s i n p a r t " A " and t h o r o u g h l y m i x t o i n s u r e u n i f o r m i t y . Add p a r t "8" s l o w l y w i t h good a g i t a t i o n . Add p a r t "6" s l o w l y w i t h good a g i t a t i o n . S i f t p a r t " C " i f l o w s h e a r m i x i n g equipment i s used. Load p a r t I'D. Detergent-Resistant
Paste P o l i s h
T h i s creamy p a s t e p o l i s h i s a w a t e r - i n - o i l e m u l s i o n w i t h e x c e l l e n t p o l ish p r o p e r t i e s . Dow C o r n i ng 536 f 1u i d g i ves d e t e r g e n t r e s i s t a n c e , w h i l e Dow C o r n i n g 200 f l u i d p r o v i d e s easy r u b - o u t and e x c e l l e n t d e p t h o f g l o s s . The r a t i o o f t h e s e f l u i d s can be v a r i e d d e p e n d i n g on d e s i r e d p r o p e r t i e s . Ingredients: Emcol 14 Dow C o r n i n g 200 F l u i d , Carnauba Wax #3 Morphol ine Isopar L Oow C o r n i n g 536 F1u i d K a o p o l i t e SF Water
1000 c S t .
P e r c e n t by Wei a h t 1.5 4.0 10.0 0.4 25.0 2.0 10.0 47.1
Combine Emcol 14, Dow C o r n i n g 200 f l u i d , Carnauba Wax and h a l f o f t h e I s o p a r L i n a c o n t a i n e r and h e a t a t 195F (9OC) w i t h a g i t a t i o n t o m e l t t h e wax. Add t h e m o r p h o l i n e w i t h a g i t a t i o n t o n e u t r a l i z e t h e wax. Add Dow C o r n i n g 536 f l u i d t o t h e r e m a i n i n g I s o p a r L, k e e p i n g t h e t e m p e r a t u r e a t 176F (8OC). When t h e m i x t u r e i s u n i f o r m , s l o w l y add t h e w a t e r and t h e K a o p o l i t e SF. H o l d a t 176F (8OC). Remove t h e h e a t and m i x u n t i l t h e s o l u t i o n r e a c h e s 131F ( 5 5 C ) . Pour i n t o c o n t a i n e r s . SOURCE: Dow C o r n i n g C o r p . : Suggested F o r m u l a t i o n s
Polishes, Coatings and Finishes
I73
F u r n i t u r e P o l ish Wei a h t /% Part A: Mazer M a s i l EM lOOP Mazer M a s i l EM l O O O P Wax E m u l s i o n P a r t B: Carbopol 934 T r i e t h a n o l ami ne Water
3.0% 1 .O%
2.0% 3% 3% 07%
Procedure: 1 . B l e n d P a r t A and B s e p a r a t e l y . 2 . Add P a r t B s l o w l y t o P a r t A w i t h m i l d a g i t a t i o n . C o n t i n u e t o m i x u n t i l a homogeneous m i x t u r e i s o b t a i n e d . Product s h o u l d be mixed p r i o r t o use. Apply t o s u r f a c e e v e n l y allow t o dry. i n a t h i n f i l m w i t h a d r y , s o f t c l o t h . Do T u r n c l o t h as o f t e n as n e c e s s a r y t o o b t a i n a b r i g h t , d r y s u r f a c e . S p r a y and Wipe F u r n i t u r e P o l i s h Wei e h t / % Part A: Isopar E Concord CO Wax Mazer S-Maz 03R Mazer Masi 1 SF 100 Mazer Masi 1 SF 10,000 P a r t 8: Water
27.5%
2.0% 1 .O% 2.3% 0.5% 66.7%
Procedure: 1. Heat P a r t A t o 9OC w i t h a q i t a t i o n t o t h o r o u g h l y m i x a l l ingredients. 2 . Add P a r t B p r e h e a t e d t o 60C w i t h h i g h speed. 3. Continue m i x i n g u n t i l c o o l .
SOURCE:
PPG I n d u s t r i e s ,
Inc.:
Suggested F o r m u l a t i o n s
174
Advanced Cleaning Product Formulations
F u r n i t u r e P o l i s h No. 337 1.5 Veegum 45.5 A Water 35.0 M i neral s p i r i t s 4.0 B Dow Corning 200 F l u i d W i tcami de 51 1 4.0 C Carnauba Emulsion C-340 10.0 Preservative q.s Procedure: Slowly add Veegum t o t h e water wh l e a g i t a t i n g a t max mum avai l a b 1e shear. Conti nue m i x i na u n t 1 smooth. Add abras ve where r e q u i r e d and mix u n t i l smooth. Mix B w e l l and add C t o B m i x i n g u n t i l smooth. Add A and Mix u n t i l smooth and u n i f o r m . Add desired preservative. Consistency: Pourable l o t i o n Suggested Packaging : P1a s t i c squeeze b o t t l e D i r e c t i o n s For Use: Apply a t h i n even c o a t w i t h a s o f t c l o t h . A l l o w t o d r y t o a haze. Wipe t o a h i g h g l o s s w i t h a c l e a n s o f t c l o t h . Comments: Veegum s t a b i 1izes these w a t e r - i n - o i 1 emulsions a g a i n s t s e p a r a t i o n or s o l v e n t phase b l e e d . I n t h e a u t o p o l i s h , Veegum a l s o keeps t h e m i l d a b r a s i v e u n i f o r m l y suspended w i t h i n t h e i n t e r n a l phase. Both compositions a p p l y e a s i l y , d r y q u i c k l y t o a haze, and r e a d i l y b u f f t o a h i g h g l o s s . Scratched Wood P o l i s h No. 210 Veegum T 1 .so A Water 25.50 Stearic acid 4.50 B Carnauba wax 16.50 Beeswax, ye1 1ow 16.50 C T r i ethanol ami ne 2.75 D Mineral s p i r i t s 27.00 0.50 Dye E Water 5.25 Preservative q.s. Procedure: Slowly add Veegum T t o t h e water w h i l e a g i t a t i n g a t maximum a v a i l a b l e shear. Continue m i x i n g u n t i l smooth. Heat B t o 9OC. Add C w h i l e m a i n t a i n i n g temperature. Add D and m a i n t a i n tempe r a t u r e . Heat A t o 9OC and add t o B/C/D m i x i n g u n t i l u n i f o r m . Prepare E u s i n g h o t water and add t o m i x t u r e . Continue m i x i n g u n t i l . Add p r e s e r v a t i v e . Consi stency: High v i scosi t y cream. Suggested Packaging: Tube D i r e c t l o n s For Use: Work i n t o damaged area w i t h s o f t c l o t h . A l l o w t o d r y . B u f f t o d e s i r e d sheen. Comments : Veegum T s t a b i l i z e s t h e t r i e t h a n o l a m i n e s t e a r a t e emulsion. T h i s h i g h v i s c o s i t y cream n o t o n l y r e s t a i n s wood s c r a t c h e s b u t a l s o f i l l s depressed areas r e s t o r i n g o r i g i n a l s u r f a c e appearance. As t h e m i n e r a l s p i r i t s evaporate, t h e carnauba wax/beeswax combination p r o v i d e s a r i g i d , non-cracking f i l l e r . Dye c o l o r and l e v e l may be a d j u s t e d as r e q u i r e d . SOURCE: R.T. V a n d e r b l l t Co.: Suggested Formulations
Polishes, Coatings and Finishes
~Indus
t r i a l Floor Finish-Formula
175
B (24% S o l i d s 1
Water F1 u o r a d FC-120 f 1 uorochemi c a l s u r f a c t a n t (1%) SWS-211 s i 1 i c o n e a n t i foam a g e n t E k t a s o l v e DE g l y c o l e t h e r E k t a s o l v e DM g l y c o l e t h e r Texanol e s t e r a l c o h o l T r i b u t o x y e t h y l phosphate p l a s t i c i z e r K a t h o n CG/ICP p r e s e r v a t i v e ( 1 . 5 % ) D u r a p l u s 2 p o l y m e r (38%) R e s i n a l l 802 l e v e l i n g r e s i n (25%) E p o l e n e E-43 wax n o n i o n i c e m u l s i o n (40%) E p o l e n e E-43 wax 40 I g e p a l CO-630 s u r f a c t a n t 12 P o t a s s i um h y d r o x i d e (86%) 4 Water 84 E p o l e n e E-20 n o n i o n i c e m u l s i o n ( 4 0 % ) : E p o l e n e E-20 wax 40 I g e p a l CO-710 s u r f a c t a n t 12 P o t a s s i um h y d r o x i d e (86%) 1 Sodi um m e t a b i s u l f i t e 0.4 Water 80.1
P a r t s by Wejnht 29.00 0.90 0.02 4.75 2.25 1.12 1.43 0.03 50.00 4.50 2.78
2.78
I n d u s t r i a l F l o o r F i n i s h - F o r m u l a A (22% S o l i d s ) Water T r i b u t o x y e t h y l phosphate p l a s t i c i z e r E k t a s o l v e DE g l y c o l e t h e r D ibutyl phthalate F l u o r a d FC-129 f l u o r o c h e m i c a l s u r f a c t a n t (1%) E s i - C r y 1 Respond I p o l y m e r (38%) A c r y s o l 644 l e v e l i n g r e s i n E p o l e n e E-43 wax n o n i o n i c e m u l s i o n (40%) E p o l e n e E-43 wax 40 I g e p a l CO-630 s u r f a c t a n t 12 P o t a s s i um h y d r o x i d e (86%) 4 Water 84 Epol ene E-20 wax n o n i o n i c emu1 s i on (35%) : E p o l e n e E-20 wax 40 I g e p a l CO-710 s u r f a c t a n t 12 P o t a s s i u m h y d r o x i d e (86%) 1 Sodium m e t a b i s u l f i t e 0.4 Water 99.2 SWS-211 s i l i c o n e a n t i f o a m a g e n t Preservative
P a r t s b v Wei q h t 39.44 1 .62 7.32 1.21 0.02 43.45 2.28 1.86
2.73
0.02 0.05
M i x i ng Procedure: 1 . Add a l l i n g r e d i e n t s , i n o r d e r l i s t e d , w i t h a g i t a t i o n . 2 . C o n t i n u e a d e q u a t e ag t a t i o n f o r 30 m i n u t e s . 3. A l l o w t o e q u i l i b r a t e f o r 16 hours b e f o r e t e s t i n g o r u s i n g . SOURCE: Eastman Chemica Co.: S u g g e s t e d F o r m u l a t i o n s
176
Advanced Cleaning Product Formulations
I n d u s t r i a l F l o o r Finish-Formula
B (25% S o l i d s )
P a r t s b y Weiqht 32.00 Water 2.19 T r i b u t o x y e t h y l phosphate p l a s t i c i z e r 6.25 E k t a s o l v e DE g l y c o l e t h e r 0.03 F1 u o r a d FC-129 f 1uorochemi c a l s u r f a c t a n t (1%) 48.81 E s i c r y l 20/20 polymer ( z i n c - f r e e ) ( 4 0 % ) 4.55 Esi -F1 ex 802 1e v e l ing r e s i n 2.86 Epolene E-43 wax n o n i o n i c e m u l s i o n (40%) 40 Epolene E-43 wax 12 I g e p a l CO-630 s u r f a c t a n t 4 Potassium h y d r o x i d e (86%) 84 Water 3.24 Epolene E-20 wax n o n i o n i c e m u l s i o n (35%) 40 Epolene E-20 wax 12 I g e p a l CO-710 s u r f a c t a n t 1 Potassium h y d r o x i d e (86%) 0.4 Sodi um metabi s u l f it e 99.2 Water 0.02 SWS-211 s i 1 i c o n e a n t i foam agent 0.05 Preservative I n d u s t r i a l F l o o r F i n i s h - F o r m u l a C (18% S o l i d s ) Water T r i b u t o x y e t h y l phosphate p l a s t i c i z e r E k t a s o l v e DE g l y c o l e t h e r E s i - C r y 1 20/20 polymer ( z i n c - f r e e ) (40%) E s i -F1 ex 802 1e v e l ing r e s i n Epolene E-43 wax n o n i o n i c e m u l s i o n (40%) Epolene E-43 wax I g e p a l CO-630 s u r f a c t a n t P o t a s s i um h y d r o x i d e (86%) Water Epolene E-20 wax n o n i o n i c e m u l s i o n (35%) Epolene E-20 wax I g e p a l CO-710 s u r f a c t a n t Potass um h y d r o x i d e (86%) Sodi um m e t a b i s u l f i t e Water sws-211 s 1 i c o n e a n t i foam agent Preservat ve
P a r t s by Weiqht 49.87 1.62 4.63 35.89 3.38 2.12 40 12 4 84 2.40 40 12 1 0.4 99.2 0.02 0.05
M i x i ng P r o c e d u r e : 1 . Add a l l i n g r e d i e n t s , i n o r d e r l i s t e d , w i t h a g i t a t i o n . 2. C o n t i n u e adequate a g i t a t i o n f o r 30 m i n u t e s . 3. A l l o w t o e q u i l i b r a t e f o r 16 h o u r s b e f o r e t e s t i n g o r u s i n g . SOURCE:
Eastman Chemical Co.:
Suggested F o r m u l a t i o n s
Polishes, Coatings and Finishes
I n d u s t r i a l _ F l o o r F i n i s h - F o r m u l a A (20% S o l i d s ) Water T r i b u t o x y e t h y l phosphate p l a s t i c i z e r E k t a s o l v e DE g l y c o l e t h e r D i butyl phthalate SWS-211 s i l i c o n e a n t i f o a m a g e n t F l u o r a d FC-129 f l u o r o c h e m i c a l s u r f a c t a n t P r o x e l GXL p r e s e r v a t i v e NM 90 p o l y m e r ( z i n c - f r e e ) (38%) M o r t o n Conrez 500 l e v e l i n g r e s i n (25%) E p o l e n e E-43 wax n o n i o n i c e m u l s i o n (40%) E p o l e n e E-43 wax I g e p a l CO-630 s u r f a c t a n t P o t a s s i urn h y d r o x i d e (86%) Water E p o l e n e E-20 wax n o n i o n i c e m u l s i o n (35%) E p o l e n e E-20 wax I g e p a l CO-710 s u r f a c t a n t P o t a s s i um h y d r o x i d e (86%) Sodi um m e t a b i s u l f it e Water I n d u s t r i a l Floor Finish-Formula
~~
_ L_h t P a r t s b r~Wei 430.0 14.0 41 .O 4.8 0.2 6.0 1.o
353.0 75.0 35.0 40 12 4 84 40.0 40 12 1 0.4 99.2
B (16% s o l i d s )
Water T r i b u t o x y e t h y l phosphate p l a s t i c i z e r E k t a s o l v e DE g l y c o l e t h e r D ibutyl phthalate SWS-211 s i 1 i c o n e a n t i foam a g e n t F l u o r a d FC-129 f l u o r o c h e m i c a l s u r f a c t a n t (1%) P r o x e l GXL p r e s e r v a t i v e Mor-Glo 2 l a t e x p o l y m e r (38%) M o r t o n Conrez 500 l e v e l i n g r e s i n (25%) E p o l e n e E-43 wax n o n i o n i c e m u l s i o n (40%) 40 E p o l e n e E-43 wax 12 I g e p a l CO-630 s u r f a c t a n t 4 P o t a s s i urn h y d r o x i d e (86%) 84 Water E p o l e n e E-20 wax n o n i o n i c e m u l s i o n (35%) 40 E p o l e n e E-20 wax 12 I g e p a l CO-710 s u r f a c t a n t 1 P o t a s s i u m h y d r o x i d e (86%) 0.4 Sodi urn m e t a b i s u l f it e 99.2 Water
P a r t s b y Weiqht 546.5 10.7 42.9 5.6 0.2 4.5 1.0 321.2 28.7 18.0
20.7
M i x i n g Procedure: 1 . Add a l l i n g r e d i e n t s , i n o r d e r l i s t e d , w i t h a g i t a t i o n . 2 . C o n t i n u e a d e q u a t e a g i t a t i o n f o r 30 m i n u t e s . 3 . A l l o w t o e q u i l i b r a t e f o r 16 hours b e f o r e t e s t i n g o r u s i n g . SOURCE: Eastman Chemical Co. : S u g g e s t e d Formul a t i ons
177
178
Advanced Cleaning Product Formulations
I n d u s t r i a l F l o o r F i n i s h - F o r m u l a C (20% S o l i d s 1 Water T r i b u t o x y e t h y l phosphate p l a s t i c i z e r E k t a s o l v e DE g l y c o l e t h e r D ib u t y l phthal ate SWS-211 s i l i c o n e a n t i f o a m agent I g e p a l CO-977 s u r f a c t a n t F l u o r a d FC-129 f l u o r o c h e m i c a l s u r f a c t a n t (1%) . . P r o x e l GXL p r e s e r v a t i v e Mor-Glo 2 l a t e x polymer (38%) M o r t o n Conrez 500 l e v e l i n g r e s i n (25%) Epolene E-43 wax n o n i o n i c e m u l s i o n (40%) Epolene E-43 wax 40 I g e p a l CO-630 s u r f a c t a n t 12 4 Potassium h y d r o x i d e (86%) Water 84 Epolene E-20 wax n o n i o n i c e m u l s i o n (35%) Epolene E-20 wax 40 12 I g e p a l CO-710 s u r f a c t a n t 1 P o t a s s i um h y d r o x i d e (86%) Sodi um m e t a b i s u l f it e 0.4 99.2 Water
P a r t s by Wei a h t 437.5 13.1 52.9 7.0 0.2 4.5 5.5 1.o 395.4 35.3 22.2
25.4
I n d u s t r i a l F l o o r F i n i s h - F o r m u l a D (25% S o l i d s ) P a r t s b y Weiqht 297.3 Water 16.4 T r i b u t o x y e t h y l phosphate p l a s t i c i z e r E k t a s o l v e DE g l y c o l e t h e r 66.1 Dibutyl phthalate 8.7 SWS-211 s i l i c o n e a n t i f o a m agent 0.2 5.5 I g e p a l CO-977 p r e s e r v a t i v e F l u o r a d FC-129 f l u o r o c h e m i c a l s u r f a c t a n t (1%) 7.0 P r o x e l GXL p r e s e r v a t i v e 1 .o 494.2 Mor-Glo 2 l a t e x p o l y m e r (38%) 44.1 M o r t o n Conrez 500 l e v e l i n g r e s i n (25%) 27.7 Epolene E-43 wax n o n i o n i c e m u l s i o n (40%) Epolene E-43 wax 40 I g e p a l CO-630 s u r f a c t a n t 12 Potassium h y d r o x i d e (86%) 4 Water 84 31 . 8 Epolene E-20 wax n o n i o n i c e m u l s i o n (35%) Epolene E-20 wax 40 I g e p a l CO-710 s u r f a c t a n t 12 P o t a s s i um h y d r o x i d e (86%) 1 0.4 Sodi um m e t a b i s u l f it e Water 99.2 M i x i n g Procedure: 1. Add a l l i n g r e d i e n t s , i n o r d e r l i s t e d , w i t h ag t a t i on. 2. C o n t i n u e adequate a g i t a t i o n f o r 30 m i n u t e s . 3 . A l l o w t o e q u i l i b r a t e f o r 16 h o u r s b e f o r e t e s t ng o r u s i n g . SOURCE: Eastmen Chemical Co.: Suggested F o r m u l e t on
12. Rinse Aids
179
180
Advanced Cleaning Product Formulations
A u t o m a t i c Dishwasher R i n s e A i d - I Inaredi ent: Wt.% Vanseal NALS-30 (Sodi um L a u r o y l S a r c o s i n a t e ) A1 k y l a r y l Pol y e t h e r * * D e i o n i z e d Water
(As R e c ' d B a s i s ) 7.00 40.00 45.00
A u t o m a t i c Dishwasher R i n s e A i d - I 1 Insredient: Wt.% Vanseal NALS-30 (Sodium L a u r o y l S a r c o s i n a t e ) A1 k y l a r y l P o l y e t h e r * A1 k y l a r y l P o l y e t h e r * * D e i o n i z e d Water
(As R e c ' d B a s i s ) 7.00 23.00 23.00 47.00
A u t o m a t i c D i shwasher R i n s e A i d - I I I Inqredi ent : Wt.% Vanseal NALS-30 (Sodium L a u r o y l S a r c o s i n a t e ) M o d i f i e d Polyphenoxy Adduct*** Dei o n i zed Water
(As R e c ' d B a s i s 1 5.00 50.00 45.00
* T r i t o n CF-10 * * T r i t o n CF-21 * * * T r i t o n CF-54 Because t h e s a r c o s i n a t e s have t h e a b i l i t y t o r a i s e t h e c l o u d p o i n t o f n o n i o n i c s u r f a c t a n t s , t h i s f e a t u r e c a n be used t o advantage i n t h e f o r m u l a t i o n o f d i s h w a s h e r r i n s e a i d s . A t t h e c l o u d p o i n t and up t o 15C above i t , foam g e n e r a t i o n i s r e d u c e d and d e t e r g e n c y i s enhanced. By a d j u s t i n g t h e c l o u d p o i n t o f t h e f o r m u l a t o t h e u s e t e m p e r a t u r e , one can t a k e f u l l advantage o f t h i s p e r f o r m a n c e f e a t u r e .
SOURCE:
R.T.
Vanderbilt
Co.,
Inc.:
Suggested F o r m u l a t i o n s
Rinse Aids
I81
Antarox EL-240 Urea Water Dye Procedure: 1. D i s s o l v e urea i n water. 2 . Add A n t a r o x E L - 2 4 0 t o w a t e r / u r e a s o l u t i o n .
Mix t h o r o u g h l y .
Physical Properties: pH ( a s i s ) : 7 . 5 pH ( 1 % ) : 8 . 1 V i s c o s i t y : 50 c p s Specific Gravity: 1 .01 Formula DW-0011
_ R i n_ s e_A-i d Wt.%
70.0 20.0 10.0
A n t a r o x BL-225 Isopropanol Water Dye
----
Procedure: 1 . D i s s o l v e Antarox EL-225 i n w a t e r . Mix t h o r o u g h l y 2 . Add I s o p r o p a n o l
.
Physical Properties: pH ( a s i s ) : 6 . 1 pH ( 1 % ) : 8 . 3 V i s c o s i t y : 30 cps S p e c i f i c G r a v i t y : 0.99 Formula OW-0012
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
13. Rug, Floor, Carpet, Upholstery
Shampoos and Cleaners
182
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners
183
C a r p e t Shampoo f o r A u t o m a t i c C a r p e t Shampooer IMay a l s o b e used f o r c l e a n i n g v i n y l & u p h o l s t e r y )
Wt.% R h o d a t e r g e RS-25 T e t r a s o d i um EDTA (38%) F r a g r a n c e , Dye, P r e s e r v a t i v e Water
50.0 1.o Q.S. 49.0
2:
W% .t 50.0 1.0 5.0 Q.S. 44.0
Rhodaterge RS-25 T e t r a s o d i um EDTA (38%) B u t y l C e l l o s o l ve F r a g r a n c e , Dye, P r e s e r v a t i v e Water
Procedure: Charge w a t e r i n t o m i x i n g v e s s e l and add EDTA. Once system i s u n i f o r m , b l e n d in Rhodaterge RS-25. B1end in remai n i ng in g r e d i ents i n order l i s t e d . Use I n s t r u c t i o n s f o r A u t o m a t i c C a r p e t Shampooer and Vacuum: Normal Use L e v e l : M i x 1 p a r t shampoo w i t h 32 p a r t s w a t e r . S t a i n s and Heavy S o i l s : M i x 1 p a r t shampoo w i t h 15 p a r t s w a t e r P h y s i c a l P r o p e r t ies : Appearance: C l e a r , y e l l o w l i q u i d pH, a s i s : 9.95 9.95 Specific Gravity: 1.016 1.020 < l o cps t 1 0 cps Viscosity: Formula CU-0062 A e r o s o l Rug Shampoo
Wt.% Rhodacal 301-10/F Water Formal i n
10.00 89.85 0.15
Procedure: Add Rhodacal 301-10/F i n t o h o t w a t e r w i t h moderate a g i t a t i o n . When s o l u t i o n i s c l e a r , add F o r m a l i n . Fill: Shampoo C o n c e n t r a t e : 90% P r o p e l l a n t 12/114-40/60: 10% Physical P r o p e r t i e s f o r Concentrate: Appearance: C l e a r , l i g h t y e l l o w l i q u i d pH, as i s : 5 . 0 6 Speci f ic G r a v i t y : .015 V i s c o s i t y : t10 c p s Formula CU-0059
SOURCE:
Rhone-Poulenc
SUQQeSted F o r m u l a t i o n s
184
Advanced Cleaning Product Formulations
C a r p e t Shampoo w i t h G r e a s e - C u t t i n a S o l v e n t W% .t 10.0 5.0 0.2
Rhodapon SB-8208/S T e t r a s o d i u m EDTA (38% S o l u t i o n ) A1 kami de DC-212/S Fragrance, Dye, P r e s e r v a t i v e Water Butyl Cellosolve
Q.S. 79.8 5.0
Procedure: Charge w a t e r i n t o m i x i n g v e s s e l and b l e n d i n Rhodapon SB-8208/S, t e t r a s o d i u m EDTA, and A l k a m i d e DC-212/S. Once system i s u n i f o r m , b l e n d i n B u t y l C e l l o s o l v e . F r a g r a n c e , Dye and Preservative. Physical Properties: Appearance: C1 e a r , water-whi t e 1iq u i d pH, as i s : 1 2 . 0 S p e c i f i c G r a v i t y : 1.OO V i s c o s i t y : t 1 0 cps Formula CU-0061 L i a u i d Steam C l e a n e r f o r C a r p e t s (For Use i n H a r d Water Svstems)
Wt.% 7.5 12.5 4.0 1.o 75.0
Sodium M e t a s i l i c a t e , Anhydrous T e t r a p o t a s s i u m Pyrophosphate (60%) Rhodafac RA-600 I g e p a l CO-710 Water Perfume and C o l o r a n t s added,
as d e s i r e d ,
r e p l a c i n g water.
Procedure: 1 . D i s s o l v e Sodium M e t a s i l i c a t e , Anhydrous i n w a t e r . 2. Add Rhodafac RA-600 and I g e p a l CO-710, m i x i n g t h o r o u g h l y a f t e r each a d d i t i o n . 3. Add T e t r a p o t a s s i u m Pyrophosphate. P h y s i c a l P r o p e r t i es: pH ( a s i s ) : 1 3 . 2 pH (1%): 1 1 . 0 V i s c o s i t y : 10 c p s Speci f ic G r a v i t y : 1 . 0 4 Formula CU-0060
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
I85
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners
F l o o r (I C a r p e t Care P r o d u c t s F l o o r (I T i l e C l e a n e r
W!%
Water TKPP Sodi urn M e t a s i 1 ic a t e Glucopon 425 CS
81 8 3 8
Wax S t r i p o e r W t %
Water T e t r a s o d i um EDTA Sodi um M e t a s i 1i c a t e Monoethanol ami ne Glucopon 425 C S
88 1 5 3 3 Wax S t r i p p e r ( S o l v e n t )
Water T e t r a s o d i u m EDTA Ammonium H y d r o x i d e (30%) Propylene Glycol nButyl Ether Glucopon 425 CS Usage:
90 1 2 4 3
1 p a r t t o 20 p a r t s w a t e r
Machine F l o o r S c r u b b e r 84.5 8.0 2.5 2.0 3.0
Water TKPP KOH (45%) T r y c o l 5963 Glucopon 425 CS Usage:
1 p a r t t o 100 p a r t s w a t e r
SOURCE: Henkel C o r p . :
Suggested F o r m u l a t i o n s
186
Advanced Cleaning product Formulations
F l o o r Care Products F1o o r C1 eaner
Wt.%
Formulation: Dowanol PnB g l y c o l e t h e r T r i ethanol ami ne Oleic acid Water
14.0 12.0 16.0 58.0
Note: Mix i n o r d e r l i s t e d . S o l u t i o n w i l l g e l w i t h i n i t i a l a d d i t i o n o f water b u t w i l l t h i n w i t h s t i r r i n g and a d d i t i o n o f a l l w a t e r . Cleaner should be c l e a r and s l i g h t l y y e l l o w i n c o l o r . F l o o r Cleaner Formulati on: Dowanol PM ( o r PnB) g l y c o l e t h e r Water Oleic acid T r i ethanol ami ne
W% .t 14.0 58.0 16.0 12.0
F l o o r Wax S t r i p p e r Formulation: Dowanol PM ( o r PnB) g l y c o l e t h e r T r i sodi urn phosphate T r i t o n X-100 s u r f a c t a n t Water
Wt.% 8.0 2.5 8.5 81 . o
F l o o r Wax S t r i m e r Formul a t ion : Dowanol PM ( o r 1 : l PM:PnB) Ammoni um h y d r o x i d e (8%) Niaproof 08 s u r f a c t a n t Water
Wt.% g l y c o l ether
14.0 6.5 4.5 75.0
F l o o r Wax S t r i p p e r Formulation : Water T r i sodium phosphate Dowanol PnB g l y c o l e t h e r T r i t o n X-102 s u r f a c t a n t
W% .t 81 . o 2.5 8.0 8.5
Notes ; Combine f ir s t two components and s t i r t o d i s s o l ve s o l i d s . Add remaining components i n o r d e r l i s t e d . Cleaner should be c l e a r and c o l o r l e s s . SOURCE: Dow Chemical Co.: Suggested Formulations
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners
F l o o r C1e a n e r
Wt.% 5.0 Rhodafac LO-529 1. o A1 kami de DC-212/S T e t r a s o d i u m P y r o p h o s p h a t e (65% A c t i v e ) 2.0 T r i s o d i um Phosphate 1.o D i e t h y l e n e G l y c o l Monoethyl E t h e r 1.o Water 90.0 Perfume and C o l o r a n t s added, a s d e s i r e d , r e p l a c i n g w a t e r Procedure: 1 . D i s s o l v e t e t r a s o d i u m p y r o p h o s p h a t e i n w a t e r . Add t r i s o d i u m p h o s p h a t e . D i s s o l ve t h o r o u g h 1 y 2 . Add Rhodafac LO-529 and A l k a m i d e DC-212/S. 3 . Add s o l v e n t . Physical Properties: pH, as i s : 1 1 . 0 pH ( 1 % ) : 9 . 0 V i s c o s i t y : 290 c p s S p e c i f i c G r a v i t y : 1.01 Formula FC-0054
.
F1o o r C l e a n e r Rhodafac LO-529 Sodium T r i p o l y p h o s p h a t e T e t r a s o d i u m Pyrophosphate Water Procedure: 1 . D i s s o l v e s o l i d s i n t h e t o t a l amount o f w a t e r . 2. Add Rhodafac LO-529. M i x t h o r o u g h l y . P h y s i c a l P r o p e r t i es : pH, as i s : 13.9 pH ( 1 % ) : 8 . 9 V i s c o s i t y : 60 c p s S p e c i f i c G r a v i t y : 1.09 Formula FC-0053
W % .t 6.0 3.0 3.0
88.0
Waxed F l o o r C l e a n e r Rhodafac RA-600 A l k a m i d e DC 212/S T e t r a p o t a s s i u m P y r o p h o s p h a t e (60% a c t i v e ) Water Procedure: Add i n g r e d i e n t s one b y one, i n o r d e r l i s t e d above, w e l l a f t e r each a d d i t i o n . Physical Properties: pH, as i s : 8 . 6 pH ( 1 % ) : 8 . 6 V i s c o s i t y : 10 c p s S p e c i f i c G r a v i t y : 1.04 Formula FC-0055 SOURCE: Rhone-Poulenc: Suggested F o r m u l a t i o n s
W% .t 5.0 1.o 25.0 69.0 mixing
I87
188
Advanced Cleaning Product Formulations
F l o o r Cleanermax S t r i m e r (Liaui d) S o i l - F l o o r wax, o i l , grease, p a r t i c u l a t e s Surface - Polymeric f l o o r i n g A p p l i c a t i o n Method - Wipe o r mop Manufacture - M i x i n g t a n k w i t h p r o p e l l e r s t i r r e r ComDos it i on : Water Metso Beads 2040 Sodium H y d r o x i d e (50%) D i e t h a n o l ami ne (98%) EDTA, T e t r a s o d i u m (37%) O i p r o p y l e n e G l y c o l Monomethyl E t h e r Phosphate E s t e r Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 Mole EO Use D i l u t i o n :
Cleaning Stripping
-
-
75.0 5.0 1. o 1.o 6.0 4.0 3.0 5.0
6% bw ( 8 o z / g a l l o n ) 12% bw ( 1 6 o z / g a l l o n )
F l o o r Cleaner/Wax
Strivver B
S o i l - F l o o r wax, f o o d o i l and grease, p a r t i c u l a t e s Polymeric f l o o r i n g Surface A p p l i c a t i o n Method - Wipe o r mop Manufacture - M i x i n g tank w i t h p r o p e l l e r s t i r r e r
-
ComDosi t i on : Water T r i t o n DF-12 ( N o n i o n i c S u r f a c t a n t ) A c r y s o l ASE 108 ( A c r y l i c P o l y m e r ) P o t a s s i um H y d r o x i d e (45%) TKPP (60%) S t r i p Wax K a s i l #6 Use D i l u t i o n :
Cleaning Stripping
Source: The PQ Corp.:
-
-
6% bw ( 8 o z / g a l l o n ) 12% bw ( 1 6 o z / g a l l o n )
Suggested F o r m u l a t i o n s
38.6 3.0
8.3 3.4 41.7 5.0
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners
I89
Floor Stripper Inqredient: S o f t Water Na m e t a s i l i c a t e p e n t a h y d r a t e D i s s o l ve
Wt%
84.25 5.00 2.00
EDTA (39%)
Add, m i x w e l l Tomah A1 k a l i S u r f a c t a n t Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l Monoethanol ami ne Add, m i x w e l l Tomah Q-17-2 Add, m i x w e l l
1.25 2.00 5.00 0.50
pH: 13.40 Recommended D i 1u t ions : 5-1 0 : 1 A p p l i c a t i o n s : F l o o r wax s t r i p p e r
SOURCE: Tomah P r o d u c t s , I n c . : Formula 1-107 No R i n s e Wax S t r i p p e r Weiaht ,% Isopropanol Monoethanol A m i ne Butoxethoxypropanol Mackam MEJ Water
19.0 6.5 2.5 0.5 71.5
Procedure: Add components t o w a t e r and b l e n d u n t i l c l e a r .
SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a l F o r m u l a r y Wax S t r i p p e r
Wei q h t .% Mackam CSF (Cocoamphopropionate) TKPP TSP Sodium M e t a s i l i c a t e P e n t a h y d r a t e B u t y l C e l l o s o l ve Water qs t o Procedure: Add components t o w a t e r and b l e n d u n t i l c l e a r .
SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a l F o r m u l a r y
4.0 4.5 2.5 5.0 2.0 100.0
190
Advanced Cleaning Product Formulations
General PurDose F l o o r and Wall Cleaner Powder 10-35% 5 0- 1 balance
STPP
A n i o n i c o r Nonionic Ammonium c h l o r i d e Sesquicarbonate o r soda ash L ia u i d
15% 5 balance
TKPP
Soap Water Hydrotrope
5 F l o o r Wax Remover Powder 20% 15 30 35
TSP
A n i o n i c o r Nonionic Sodium m e t a s i l i c a t e pentahydrate Soda ash L isui d
5-1 0% 14-20 5-1 0 4-10 balance
TSP
O l e i c Acid A n i o n i c o r Nonionic Monoethanol ami ne Water Concrete Garage F l o o r C l e a n e r - I
60% 2-5 balance
TSP C r y s t a l s
A n i o n i c o r Nonionic Soda ash Concrete Garaae F l o o r C l e a n e r - I 1 TSP C r y s t a l s
A n i o n i c o r Nonionic Sodium m e t a s i l i c a t e pentahydrate
2 0% 5-1 0 balance
Cerami c T i 1e C1eaner STPP
80-9096
A n i o n i c o r Nonionic
3- 5 10-15
TSP
SOURCE: FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4: Suggested Formulations
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners
.~ Heavy-Duty
191
Concrete Cleaner W% .t
Water Sodi um M e t a s i 1 ic a t e , Anh. T e t r a p o t a s s i u m P y r o p h o s p h a t e , 60% Sodium H y d r o x i d e , 50% Rhodafac RA-600 I g e p a l CO-630 Butoxyethanol
70
Procedure: 1 . Add t h e w a t e r t o a m i x e r and t h e n add t h e sodium m e t a s i l i c a t e w i t h a g i t a t i o n . Mix u n t i l completely dissolved. 2 . Add t h e t e t r a p o t a s s i u m p y r o p h o s p h a t e s o l u t i o n and t h e sodium hydroxide s o l u t i o n s s l o w l y w i t h a g i t a t i o n . Mix u n t i l uniform. 3 . Add t h e Rhodafac RA-600 s l o w l y w i t h a g i t a t i o n and mix u n t i l uniform. 4. Add t h e I g e p a l CO-630 and t h e b u t o x y e t h a n o l and m i x u n t i l uniform. Physical Properties: Appearance: C l e a r , w a t e r - w h i t e t o p a l e y e l l o w l i q u i d pH, a s i s : 1 2 . 7 Speci f ic G r a v i t y : 1 .072 V i s c o s i t y : t 2 0 cps Formula FC-0105 E v a p o r a t i v e (No R i n s e ) Wax S t r i p p e r
Wt.% M i r a n o l JEM C o n c e n t r a t e Monoethanol ami ne Butoxyethoxypropanol Isopropanol Water Procedure: Add t h e i n g r e d i e n t s and m i x u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r s o l u t i o n pH, as i s : 11.4 V i s c o s i t y : t 1 0 cps S p e c i f i c G r a v i t y : 0.97 Formula FC-0056 SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
0.5 6.5 2.5 19.0 72.5
192
Advanced Cleaning Product Formulations L i a u i d Carpet Cleaner % b v Weiaht 72.5 10.0 5.0
Water SXS-40% Sodi um B i c a r b o n a t e STPP B u r c o s p e r s e AP-Liq Burco LAF-6
5.0 5.0 2.5 C a r p e t S t a i n Remover-Li o u i d % by Wei q h t T o 100 40 10
Water B u r c o t e r g e DG-40 Burcosperse AP-Li q u i d Propylene G l y c o l S o r b i t o l 70% B u r c o t a s e SL-80
20 15 0.5-1 . O
Carpet Cleaner/Booster Destainer
-
Dry % by Weiaht
2.0-6.0 40-60 40-60
Burco LAF-6 Soda Ash FB-Sodium P e r c a r b o n a t e
Above a l s o e l i m i n a t e s o d o r s such as t h o s e caused by p e t u r i n e . O x i d i z e s s t a i n s such as c o f f e e , w i n e , j u i c e . e t c . G e n e r a l l y 5 ounces o f above added t o 5 g a l l o n s o f d e t e r g e n t s o l u t i o n i s s u f f i c i e n t f o r good p e r f o r m a n c e .
SOURCE:
B u r l i n g t o n Chemical Co.,
Inc.:
Suggested F o r m u l a t i o n s
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners
193
Low Foam C l e a n e r s Machine F l o o r C l e a n e r I Inqredient: Water KOH (45%) Add s l o w l y w i t h m i x i n g TKPP Dissolve completely w i t h mixing T r i t o n X-114 Add w i t h m i x i n g Tomah A m p h o t e r i c 400 Add w i t h m i x i n g SpG 20/20F: 1 . 0 8 pH: 13.60 Recommended D i l u t i o n s : 1-2 o z / 4 g a l l o n s w a t e r A p p l i c a t i o n s : Machine c l e a n i n g Formula LF-103
W S 83.00 2.50 8.00 3.00 3.50
Machine F l o o r C l e a n e r I1 % & Ingredient: Water 78.00 TKPP 8.00 Dissolve completely w i t h mixing T r i t o n CF-10 4.00 Add w i t h m i x i n g 10.00 Tomah A m p h o t e r i c 400 Add w i t h m i x i n g SpG 20/20F: 1 . 0 8 pH: 9 . 3 0 Recommended D i l u t i o n s : 1-2 o z / 4 g a l l o n s w a t e r A p p l i c a t i o n s : Machine c l e a n i n g , l e s s a l k a l i n i t y , s a f e r t o workers Formula LF-104 Carpet S t a i n Remover/PresDotter Inqredient: Water Na O c t y l S u l f a t e (33%) Add, m i x w e l l EDTA (100%) D i s s o l v e , mix w e l l Dowanol PnB Add, m i x w e l l Tomah A m p h o t e r i c 400 Add, m i x w e l l SpG 20/20F: 1 . 0 0 pH: 9.49 Recommended D i 1u t ions : a s - i s A p p l i c a t i o n s : C a r p e t and l i n o l e u m p r e s p o t t e r / r e m o v e r o i l y stains Formula LF-105
SOURCE: Tomah P r o d u c t s I n c . :
Suggested F o r m u l a t i o n s
W B 92.80 1 .oo 0.20 3.00 3.00
for
194
Advanced Cleaning Product Formulations
PumDsDravs f o r Removal O f Odors Attributes: Can be s p r a y e d on r u g s , c l o t h i n g , a n i m a l s o r wherever a malodor e x i s t s . The o d o r w i l l be p e r m a n e n t l y removed i n seconds. 1: I n w e d i e n t s : % w/w 1 . G r i l l o c i n HY-77 2.00 2. P a t i o n i c 138C 6.60 46.20 3 . I s o p r o p y l A1 coho1 4. D i s t i l l e d Water 42.40 0.80 5 . P a t l a c LA (44%) 6. T r i e t h a n o l a m i n e (50%) 2.00 2. I n s r e d i e n t s : 1 . G r i l l o c i n HY-77 2. P a t i o n i c 138C 3. I s o p r o p y l A l c o h o l 4. D i s t i l l e d Water 5 . P a t l a c LA (44%) 6. T r i e t h a n o l ami ne (50%)
2.00 6.60 36.20 54.00 0.40
0.80
Compounding Procedure: S t i r G r i l l o c i n HY-77 and P a t i o n i c 138C t h o r o u g h l y . Add t h e o t h e r i n g r e d i e n t s i n t h e g i v e n o r d e r . B o t h f o r m u l a t i o n s , 1 and 2, a r e s u i t a b l e as t e x t i l e o r room s p r a y s . Formula H-89-G-12 Deodorant
RUQ Shampoo
Attributes: A r u g c l e a n i n g p r o d u c t w i t h G r i 1l o c i n HY-77 t o e l i m i n a t e odors. % w/w Inaredients: 1 .oo 1 . G r i 1l o c i n HY-77 4.00 2. P a t i o n i c 138C 20.00 3. Sodium C14-16 O l e f i n S u l f a t e 10.00 4. Cocami d o p r o p y l B e t a i ne 58.50 5 . D i s t i l l e d Water 1 .oo 6. Hydroxypropyl M e t h y l c e l l u l o s e 2.50 7. P o l y s o r b a t e 85 +-2.00 8 . Sodium C h l o r i d e (25% S o l u t i o n ) 1 .oo 9 . Germaben I 1 QS 10. F r a g r a n c e Compounding Procedure: Combine in g r e d i e n t s 1-4 i n o r d e r w i t h m i x i ng. D i s p e r s e in g r e d i e n t 6 i n t o 5, add t o t h e f i r s t phase. Heat t o 60C and add P o l y s o r b a t e . M i x u n t i l u n i f o r m . B e g i n c o o l i n g t o 45C. Add p e r fume and p r e s e r v a t i v e . Cool t o 35C. A d j u s t v i s c o s i t y w i t h S a l t S o l u t i o n . Package. Formula H-89-G-11 SOURCE:
R.I.T.A.
Corp.:
Suggested F o r m u l a t i o n s
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners
195
Rug Shampoo Wt.%
7.5 22.0 3.0 67.5
Rhodapon LSB Geropon TC-42 Isopropanol Water Perfume and c o l o r a n t s added,
as d e s i r e d ,
r e p l a c i n g water.
Procedure: 1 . D i s s o l v e Rhodapon LSB i n w a t e r . 2 . Add Geropon TC-42 and i s o p r o p a n o l . 3. F i l t e r product. Physical Properties: pH (as i s ) : 7.8 pH ( 1 % ) : 7 . 0 V i s c o s i t y : 10 c p s S p e c i f i c G r a v i t y : 1 .01 Formula CU-0057 Rug and U p h o l s t e r y Shampoo
Wt.% 20.00 2.00
Rhodapex ES Sodi um T r i p o l y p h o s p h a t e E t h y l Carbi t o 1 T i n o p a l 5BM Water
1 .so 0.05
76.45
Procedure: D i s s o l v e Rhodapex ES, Sodium T r i p o l y p h o s p h a t e , E t h y l C a r b i t o l and O p t i c a l B r i g h t e n e r i n w a t e r . M i x u n t i l homogeneous and c l e a r , and a g i t a t e f o r t h i r t y m i n u t e s . Physical Properties: Appearance: C l e a r , w a t e r - w h i t e pH: 1 0 . 2 S o l i d s : 9.5 S p e c i f i c G r a v i t y : 1.0 V i s c o s i t y : 100 c p s max.
liquid
Formula CU-0058
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
14. Miscellaneous
1%
Miscellaneous
197
A e r o s o l Bathroom C l e a n e r A p r o d u c t t h a t i s used on s u r f a c e s such as c e r a m i c s o r m e t a l s . When a p p l i e d , t h i s p r o d u c t p r o v i d e s t h e c o a t e d s u r f a c e w i t h e x c e l l e n t water-shedding c h a r a c t e r i s t i c s .
Aerosol Concentrate: Part: Insredients: A Dow C o r n i n g HV-490 Emu1 s i on Isopropanol B Renex 698 Dowanol DMP Versene Powder Water Suggested A e r o s o l F o r m u l a t i o n : Inaredients: E2-7258 C o n c e n t r a t e Isobutane
P e r c e n t by Wei q h t
1.5 2.6 4.1 4.1 6.1 81 . 6 P e r c e n t by Wei q h t
95.0 5.0
Preparation: 1. M i x P a r t A w i t h a g i t a t i o n . 2. M i x P a r t B s e p a r a t e l y . 3. Add P a r t B t o P a r t A w h i l e s t i r r i n g . 4. P r e s s u r e f i l l i n l a c q u e r - l i n e d cans w i t h Epon-coated vapor t a p v e l v e s and mechanical b r e a k - u p s p r a y heads. F o r m u l a t i o n E2-7258 A e r o s o l Oven Re1ease A w a t e r - b a s e d a e r o s o l f o r oven r e l e a s e . S i n c e t h i s p r o d u c t f o r m u l a t i o n i s water-based, i t o f f e r s advantages o v e r convent i o n a l s p r a y s i n c l u d i n g l o w e r c o s t and l e s s o d o r . Oven s u r f a c e s t r e a t e d w i t h t h i s p r o d u c t w i l l show i n c r e a s e d r e s i s t a n c e t o s t a i n penetration.
Aerosol Concentrate: Inaredi ents: Dow C o r n i n g 24 E m u l s i o n Carbopol 934 Morphol ine Water Suggested A e r o s o l F o r m u l a t i o n : Inqredi ents: C o n c e n t r a t e E2-7248 Isobutane
P e r c e n t by Weight
7.5 0.2 0.2
92.1 P e r c e n t by Wei Q h t
95.0 5.0
Preparation: 1. Premix a 2% d i s p e r s i o n o f Carbopol 934 i n w a t e r . 2. M i x 1 0 p a r t s o f t h i s d i s p e r s i o n w i t h t h e s i l i c o n e e m u l s i o n and 82.3 p a r t s o f w a t e r . 3. Add t h e M o r p h o l i n e and m i x w i t h a p r o p e l l e r - t y p e a g i t a t o r . F o r m u l a t i o n €2-7248
SOURCE:
Dow C o r n i n g Corp. : Suggested F o r m u l a t i o n s
198
Advanced Cleaning Product Formulations
Aerosol Water-Repellent
F a b r i c Treatment
An e x c e l l e n t f a b r i c water r e p e l l e n t t r e a t m e n t f o r i t e m s such as automotive u p h o l s t e r y and c a r p e t . I t may a l s o be used t o t r e a t r a i n wear, snow s u i t s , m i t t e n s , footwear, and u p h o l s t e r y m a t e r i a l s . T h i s c o n c e n t r a t e can be used t o f o r m u l a t e an aerosol product u s i ng an a p p r o p r i a t e p r o p e l l a n t
.
Aerosol Concent r a t e : Inaredients: Dow Corning C-2-0563 I s o p a r G Solvent
F a b r i c Water R e p e l l e n t
Percent by Wei q h t 5.0 95.0 Percent by Wei a h t 80 20
Suggested Aerosol Formulation: Concentrate CP7-0156D Propel 1a n t o f choi ce
Preparation: Pressure o r c o l d f i l l w i t h a p p r o p r i a t e commercial v a l v e and button. F o r m u l a t i o n CP7-0156D L i q u i d , V i n v l S u r f ace P r o t e c t a n t
Can be used on v a r i o u s s o f t s u r f a c e s such as v i n y l , eather, rubber and p l a s t i c s . T h i s f o r m u l a t i o n i m p a r t s e x c e l l e n t g l o s s t o a v i n y s u r f a c e and r e s i s t s m u l t i p l e d e t e r g e n t washings Ingredients: Dow Corning 929 C a t i o n i c Emulsion Dow Corning 347 Emulsion Water Makon o r Makon 6 50% S o l u t i o n o f Sodium C i t r a t e i n Water Acetic Acid
Percent by Wei a h t 5.4 9.9 82.7 1 .o 1.o 0.5
Preparation: 1. Load Dow Corning 929 C a t i o n i c Emulsion and Dow Corning 347 Emu1s i on in t o m i x i ng vessel 2. S t a r t low-shear m i x e r . 3. Add water. 4. When m i x t u r e i s uniform, premix Makon 4 ( o r Makon 6) and t h e sodium c i t r a t e s o l u t i o n . S l o w l y add premix t o m i x i n g v e s s e l . 5. Mix u n t i l u n i f o r m . Package.
.
Formulation E2-7234
SOURCE:
Dow
Corning Corp.:
Suggested Formulations
Miscellaneous
199
A s p h a l t Emu1 s i on Attributes: A s p h a l t e m u l s i o n u s i n g A c r i t a m e r 941 t o keep t h e a s p h a l t suspended and p r e v e n t i t f r o m s e t t l i n g o u t . Innredients: 1 . D i s t i l l e d Water 2 . A c r i t a m e r 941 3 . 10% Sodium H y d r o x i d e 4 . Ethomeen C-25 5 . S o f t A s p h a l t (180-200) Hard A s p h a l t ( 5 0 - 6 0 )
% Z 400.00 1.50 4.50 0.75 or 400.00
Compounding P r o c e d u r e s : D i s p e r s e t h e A c r i t a m e r 941 i n t h e w a t e r . Add NaOH and E t h o meen C-25 one a t a t i m e . M i x . Heat w a t e r s o l u t i o n t o 65-70C. Heat a s p h a l t t o 85C. When b o t h a r e a t t e m p e r a t u r e , s l o w l y add t h e m o l t e n a s p h a l t i n t o t h e w a t e r u s i n g m o d e r a t e l y h i g h s h e e r . The r a t e o f a d d i t i o n s h o u l d be no g r e a t e r t h a n t h e r a t e o f d i s p e r s i o n . M i x u n t i l u n i f o r m . Shock c o o l t o 30-35C u s i n g a c o l d water j a c k e t . F i n a l pH: A p p r o x i m a t e l y 6 . 5 5 , 5 0 0 cps Formula 107-190 V i scosi t y :
Road T a r E m u l s i o n Attributes: Road T a r E m u l s i o n u s i n g A c r i t a m e r 941 t o h e l p keep t h e t a r suspended and p r e v e n t i t f r o m s e t t l i n g o u t . Ingredients: 1 . D i s t i l l e d Water 2 . RT 12 3 . A c r i t a m e r 941 4 . 10% Sodium H y d r o x i d e 5 . Ethomeen C-25
%w/w 50.000 50.000 0.125 0.375 0.625
Compounding P r o c e d u r e s : D i s p e r s e t h e A c r i t a m e r 941 i n t h e w a t e r . Add NaOH and Ethomeen C-25 one a t a t i m e . M i x . S e p a r a t e l y h e a t t h e w a t e r s o l u t i o n and t a r t o 65C. When b o t h a r e a t t e m p e r a t u r e , s l o w l y add t h e m o l t e n RT 1 2 i n t o t h e w a t e r w i t h v i g o r o u s m i x i n g . The r a t e o f a d d i t i o n s h o u l d be no g r e a t e r t h a n t h e r a t e o f d i s p e r s i o n . M i x u n t i l u n i f o r m . Shock c o o l t o 30-351: u s i n g a c o l d w a t e r j a c k e t . Formula 107-1 91 SOURCE: R .
I .T.A.
Corp. : Suggested F o r m u l a t i o n s
200
Advanced Cleaning Product Formulations C a t i o n i c O i 1-i n-Water
Emul s i f i e r
Mackazoline 0 ( O l e y l Hydroxyethyl I m i d a z o l i n e ) I s o p r o p y l Alcohol Glacial Acetic Acid
Wei ght .% 69.0 10.0 21 .o
B l e n d components i n o r d e r . F o r a p p l i c a t i o n , d i s p e r s e e m u l s i f i e r i n o i l phase and add w a t e r w i t h a g i t a t i o n . C a t i o n i c Water-In-Oi 1 Emul s i o n Light Mineral O i l Mackazoline 0 ( O l e y l Hydroxyethyl I m i d a z o l i n e ) Oleic Acid Water B l e n d components e x c e p t w a t e r . agitation.
Weiaht .% 25.0 1.2 2.0 71.8
S l o w l y add w a t e r w i t h good
Concrete Cleaner Mackam 2CSF (Cocoamphodipropionate)
TKPP TSP Sodium M e t a s i l i c a t e 5H20 T r i t o n X-100 Carbi t o 1 Water
Weight ,% 4.0 5.5 1. o 2.5 2.0 2.0 83.0
Procedure: 1 . Add components t o w a t e r . 2 . Heat t o 50 degrees C. and b l e n d u n t i l c l e a r . R u s t Remover Mackam 2CYSF (Capryloamphodipropionate) KOH (45%) T r i e t h a n o l a m i ne Water Procedure: Add components t o w a t e r and b l e n d u n t i l c l e a r .
SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a l F o r m u l a r y
Wei q h t .% 2.0 70.0 12.0 16.0
Miscellaneom
201
C h a i n B e l t Lube 1 Inqredi ent : Caprylic Acid ) Oleic Acid ) Premix a c i d s and a d j u s t w i t h NaOH t o pH 1 1 . 6 Tomah A m p h o t e r i c N Add t o a d j u s t e d a c i d s , m i x w e l l Water Mix well pH: 11.60 Recommended D i l u t i o n s : 100-2OO:l Applications: I n d u s t r i a l chain l u b r i c a t i o n ; b o t t l e , container Notes: H i g h f o a m i n g system, may r e q u i r e b i o c i d e Formula M-1 00
Wt%
10.00 10.00 10.00 70.00
can,
C h a i n B e l t Lube 2 W S
Inqredient P a r t A: Water Glacial acetic acid Mix w e l l Tomah A0-728 Speci a1 Mix w e l l H e x y l ene G1 y c o l P a r t B: Tomah DA-17 Tomah TAE-RI Mix w e l l Glacial acetic acid A d j u s t pH t o 7 . 5
60.00 3.50 10.00
5.00 5.00 15.00
pH: 7.50 Recommended D i l u t i o n s : 100-3OO:l A p p l i c a t i o n s : I n d u s t r i a l c h a i n l u b r i c a t i o n ; b o t t l e , can, container N o t e s : Add P a r t B s l o w l y t o P a r t A w i t h good m i x i n g . A d j u s t pH t o 7.5 Formula M-101 SOURCE: Tomah P r o d u c t s ,
Inc.:
Suggested F o r m u l a t i o n s
202
Advanced Cleaning Product Formulations
Concrete Cleaner (Dry Tv o e l I n s r e d i ents.; ( 1 ) Sodium C a r b o n a t e ( s o d a ash) l i g h t d e n s i t y ( 2 ) Sodium M e t a s i l i c a t e , anhydrous ( 3 ) P e t r o BAF powder ( 4 ) Tetrasodium Pyrophosphate (5) Korthix H ( 6 ) FB Sodium P e r c a r b o n a t e
% by Weiqht 10.0 35.0 7.0 20.0 8.0 15.0
Procedure: Dry b l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Comments : W i t c o C o r p o r a t i o n ' s Udet 950 i s recommended i n p l a c e o f t h e i r P e t r o BAF i f i n c r e a s e d foam i s d e s i r e d . Application: T o use, wet c o n c r e t e w i t h w a t e r and s p r i n k l e c l e a n e r on g r e a s e and o i l s p o t s t o be c l e a n e d . S c r u b a r e a down w i t h b r u s h and hose o f f . P o l is h i nq C l o t h
Inpredients: ( 1 ) D e i o n i z e d Water ( 2 ) K a o p o l i t e SF ( 3 ) K a o p o l i t e AB (4) A1 r o s p e r s e (5) Isopropanol ( 6 ) C o l l o i d s 581-B Defoamer (7) Pine O i l
% by Weight
37.5 20.7 10.4 27.6 3.1 0.7 q.s.
Procedure: Charge ( 1 ) and ( 5 ) i n t o t h e m i x e r and add ( 2 ) and ( 3 ) s l o w l y , a l o n g w i t h p a r t o f ( 4 ) . Add ( 6 ) a l o n g w i t h t h e r e s t o f ( 4 ) . ( 7 ) can b e added a s needed f o r f r a g r a n c e . The above m i x t u r e c a n t h e n be used f o r i m p r e g n a t i n g b l e a c h e d c o t t o n f l a n n e l c l o t h . A f t e r t h e c l o t h i s squeezed, i t i s u s u a l l y d r i e d i n a d r y i n g oven. A f t e r d r y i n g , t h e c l o t h s h o u l d be c o o l e d before storage. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d b e used when h a n d l i n g flamma b l e in g r e d i e n t s .
SOURCE: K a o p o l i t e ,
I n c . : Suggested F o r m u l a t i o n s
Miscellaneous
203
Deteraent S a n i t i z e r W% .t
M i r a n o l FBS Quaternary Ammonium Germicide Sodium Carbonate Cheel ox BF-I 3 Water
15.0 2.0 2.0
0.5 80.5
Procedure: Add t h e water, t h e n d i s s o l v e t h e sodium carbonate. Add t h e remaining m a t e r i a l and mix u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r , y e l l o w s o l u t i o n pH: 10.6 V i s c o s i t y :
Wt.% M i r a n o l FBS Sodium M e t a s i l i c a t e Pentahydrate Potassi um Hydroxide (45%) Water
15.0 25.0 11.0 49.0
Procedure: Add t h e water. D i s s o l v e t h e sodium m e t a s i l i c a t e . Add t h e p o t a s s i urn h y d r o x i d e and M i ran0 FBS. Mix u n t i l u n i f o r m . P h y s i c a l P r o p e r t i es : Appearance: Clear, y e l l o w 1 q u i d pH: 12.0 V i s c o s i t y : 10-20 cps S p e c i f i c G r a v i t y : 1.21 Formula MS-0072
SOURCE:
Rhone-Poulenc:
SuQQeStedFormulations
204 Advanced Cleaning Product Formulations
d - L i n o n e n e M i c r o e n u l s i on C l e a n e r F-478 d - L i monene Monami ne R32-7 B u t y l Carbi t o 1 Water T e t r a sodium EDTA (40% s o l u t i o n )
% B y Weiqht 30.0 20.0 10.0 35.0
5.0
Procedure: B1 end d-Limonene, B u t y l C a r b i t o 1 and Monami ne R32-7. Pre-mi x EDTA and s l o w l y add t o o t h e r i n g r e d i e n t s w i t h good a g i t a t i o n . Formulation Properties: P h y s i c a l Appearance: C l e a r l i g h t amber l i q u i d d - L i monene A1 k a l ine C l e a n e r F-524 % B y Weigh ; 3.0 1 6.0 1
d - L i monene Nonyl Phenol 1 0 . 5 Moles EO Monafax 785 Water KOH 45%
6.00 73.09 11 .ll
Procedure: 81 end in g r e d i e n t s in o r d e r 1 is t e d . Formulation Properties: Appearance: C1 e a r 1 iq u i d C l o u d P o i n t : 51C D i l u t i o n s w i t h water: Clear l i q u i d s
SOURCE: Mona I n d u s t r i e s ,
Inc.:
Suggested F o r m u l a t i o n s
Miscellaneous
205
d-Limonene M i c r o e m u l s i o n s t h a t G i v e C l e a r D i l u t i o n s % bv Weisht 15.0 5.0-6.0 5.0-6.0 10.0-1 2 . 0 0.0- 4.0 To 100% T o t a l
Component: d - L i monene Burco TME Burco FAE NP-9 Butyl Cellosolve Water
Procedure: Add e m u l s i f i e r and B u t y l C e l l o s o l v e ( i f needed) t o d-Limonene. Add w a t e r s l o w l y , w i t h a g i t a t i o n . The f o r m u l a t i o n w i l l t h i c k e n t h e n t h e v i s c o s i t y w i l l break t o form a non-viscous p r o d u c t . F o r m u l a t i o n Adjustment: T h i s f o r m u l a t i o n can be a d j u s t e d t o compensate f o r d i f f e r e n c e s i n grades o f d-Limonene. More h i g h l y r e f i n e d grades ( f r a g r a n c e g r a d e s ) w i l l g i v e c l e a r f o r m u l a t i o n s w i t h 5% B u r c o TME, 5% B u r c o FAE and 12% NP-9. The b a s i c a d j u s t m e n t s f o r o t h e r grades a r e : 1 ) Keep l e v e l s o f B u r c o TME and B u r c o FAE e q u a l . I f t h e 5% l e v e l s do n o t g i v e a c l e a r c o n c e n t r a t e , use 6% o f each. 2 ) Keep t o t a l e m u l s i f i e r (TME, FAE, NP-9) l e v e l s a t 22%. H i g h e r 1eve1 s o f emu1 s i f ie r a r e normal 1y n o t b e n e f i c i a1 . 3 ) Add B u t y l C e l l o s o l v e as needed t o y i e l d c l e a r c o n c e n t r a t e . Water SDot and Soap F i l m Remover Components: Water 50% C i t r i c A c i d B u r c o s p e r s e LP Dequest 2000 Burco NPS 50% 45% KOH
% bv Weisht 77.5
5.0 5.0 5.0 2.5 5.0
Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d . B l e n d u n t i l u n i f o r m between each a d d i t i o n . F i n i s h e d p r o d u c t pH s h o u l d be 4.5-5.0. Appl ic a t ion : T h i s f o r m u l a t i o n may be s p r a y e d o n t o shower d o o r s , b a t h t u b s and o t h e r s u r f a c e s . F o r b e s t r e s u l t s , i t s h o u l d be w i p e d w i t h an a b s o r b e n t c l o t h o r p a p e r t o w e l . I t may a l s o be used as a d i p f o r shower heads, e t c . t o remove w a t e r d e p o s i t s . Source: B u r l i n g t o n Chemical Co.,
I n c . : SUQQeSted F o r m u l a t i o n s
206
Advanced Cleaning Product Formulations
D r y - C l e a n i ng Formula
Wt.% Rhodafac PE-510 Rhodafac RS-610 I g e p a l CO-630 Potassium H y d r o x i d e (45% a c t i v e ) Perch1o r o e t h y l ene
10.0 21 . o 15.0 4.0 50.0
Procedure: 1 . Add s u r f a c t a n t s t o g e t h e r . M i x t h o r o u g h l y . 2. Add P e r c h l o r o e t h y l e n e and Potassium H y d r o x i d e . Physical Properties: pH, as i s : 4 . 3 pH ( 1 % ) : 3 . 7 V i s c o s i t y : 50 c p s Speci f ic G r a v i t y : 1 . 0 8 Formula MS-0077 D r y - C l e a n i n a Formula
Wt.% I g e p a l RC-520 Rhodafac RS-610 Geropon WT-27 Hexylene G l y c o l S t o d d a r d Sol v e n t Potassium H y d r o x i d e (45% a c t i v e )
30.0 30.0 7.5 10.0 18.5 4.0
Procedure: 1 . Add Rhodafac RS-610 t o I g e p a l RC-520. M i x t h o r o u g h l y . 2. Add Geropon WT-27, Hexylene G l y c o l and S t o d d a r d S o l v e n t , m i x i n g w e l l a f t e r each a d d i t i o n . 3 . Add Potassium H y d r o x i d e s l o w l y t o main b a t c h . Physical Properties: pH, as i s : 4.3 pH (1%): 3 . 4 V i s c o s i t y : 150 cps Specific Gravity: 1. O Formula MS-0078
SOURCE: Rhone-Poulenc: Suggested F o r m u l a t i o n s
Miscellaneous
207
Eqq C l e a n e r IPowder) Soil - Protein S u r f a c e - Eggs and egg h a n d l i n g equipment A p p l i c a t i o n Method - Spray M a n u f a c t u r e - Ribbon o r p a d d l e b l e n d e r Composition: TSPP Sodium Carbonate Metso Beads 2048 Sodium S u l f a t e Sodium D i c h l o r o i s o c y a n u r a t e , 2H20 Sodium A l k y l a r y l S u l f o n a t e Powder,
% A
(90%)
32.0 30.0 20.0 10.0 3.0 5.0
Use D i l u t i o n : 0.75-1.5% bw ( 1 - 2 o z / g a l l o n ) G r i 11 C l e a n e r ( L i auid)
S o i l - Animal f a t and g r e a s e , c a r b o n b l a c k Surface - Metal A p p l i c a t i o n Method - Wipe o r b r u s h Manufacture - Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water Sodium P o l y a c r y l a t e , MW 4500-5500 Metso Beads 2048 TKPP (60%) Phosphate Es e r O c t y l phenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles EO
% B 78.2 0.5 7.9 3.0 5.4 5.0
Use D i l u t on: 0.80-1.5% bw ( 1 - 2 o z / g a l l o n ) P r i n t i n q P1a n t C1eaner
-
I n k p i g m e n t and o i l Soil Surface - Metal A p p l i c a t i o n Method - Wipe o r b r u s h M a n u f a c t u r e - None
% B
Composi t i on : Metso Pentabead 20
100.0
Use D i l u t i o n : 3-4.5% bw ( 4 - 6 o z / g a l l o n ) Source: The PQ C o r p . :
Suggested F o r m u l a t i o n s
208
Advanced Cleaning Product Formulations
G r a f f i t i Cleaner % By WeiQht
35.0 5.0 12.0
DuPont DBE Isopropanol Monawet MM-80 Water
48.0
Procedure: Add i n g r e d i e n t s i n o r d e r l i s t e d w i t h good a g i t a t i o n . Penetrating Lubricant % By Weiaht
50.0 40.0 2.5 2.5 5.0
Safflower O i l 2 - E t h y l hexanol Monacor TEH Monawet MO-70R Monacor 39 Procedure: Add i n g r e d i e n t s
n o r d e r l i s t e d w i t h good ag t a t i o n . B o t t l e Wash C l e a n e r F-542 % By Weiqht
58 17 5
Water P o t a s s i um H y d r o x i d e Sodium M e t a s i l i c a t e ( A n h y d r o u s ) Tetrapotassium Pyrophosphate Mona NF-25
10 10
Procedure: Add i n a r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n making s u r e each-product i s d i s s o l v e d b e f o r e adding n e x t i n g r e d i e n t . Typical Properties: C l o u d P o i n t : 50C K r a f f t Point: tOC Recommended Use D l u t i o n :
SOURCE: Mona I n d u s t r
es,
6 t o 8 oz./gal.
Inc.:
Suggested F o r m u l a t i o n s
Miscellaneous
209
Heavv Dutv Presoak Inaredient: Water Sodium M e t a s i l i c a t e Pentahydrate D i s s o l ve NTA o r EDTA (100%) Add, mix w e l l TKPP D i s s o l ve Tomah AQ-14-2 Add, mix w e l l Tomah Q-14-2 Add, mix w e l l Nonionic Surfactant-HLB 13 Add, mix w e l l SpG 20/20F: 1 . 0 8 pH: 12.50 Recommended D i 1u t i ons : 10-30 : 1 A p p l i c a t i o n s : Carwash/truckwash Notes: Presoak f o r car/truckwash Formula T-102
Wt% 77.00 2.00 6.00 1 .oo 3.00 3.00 4.00
Underbodv Rust I n h i b i t o r I n a r e d ie n t : Water Acetic Acid Mix w e l l , a d j u s t pH t o 7.5 I PA Mix w e l l Tomah DA-17 Mix u n t i l c l e a r pH: 7.50 Recommended D i l u t i o n s : 10-2O:l A p p l i c a t i o n s : Carwash-spray underbody t r e a t m e n t Formula T-108 SOURCE: Tomah Products, I n c . : Suggested Formulations
Wt% 80.00 1 .oo 4.00
15.00
R a i l c a r Cleaner Wei a h t .% Mackam 2CSF (Cocoamphodipropionate) B u t y l C e l l o s o l ve TKPP Sodium Meta S i l i c a t e 5H20 C a u s t i c Soda (50%) Water Procedure: 1 . Add component i n o r d e r t o w a t e r . 2. Heat t o 50 degrees C. and b l e n d u n t i l c l e a r . 3. Cool and f i l l . SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a1 Formulary
11.5 4.2 4.0 5.5 6.2 68.6
210
Advanced Cleaning Product Formulations
Leather P r e s e r v a t i v e Attributes: A p r o d u c t f o r p r e s e r v i n g l e a t h e r t h a t can be used as an a e r o s o l foam t y p e p r o d u c t o r packaged i n t o a squeeze t u b e container. % W/W Insredi ents: Part A O i l Phase: 1. R i t a l a n 1 .oo 2. R i t a c h o l 4.00 3 . L a n o l i n USP 1 .oo 4. C e t y l A l c o h o l 2.00 5. G l y c e r i n 5.00 2.00 6. Propylene G l y c o l 7. M e t h y l p a r a b e n 0.15 P a r t B - Water Phase: 8 . Sodium L a u r y l S u l f a t e (30% S o l u t i o n ) 1.50 9. D i s t i l l e d Water 83.15 10.Perfume 0.20 Compounding P r o c e d u r e s : Combine P a r t A and h e a t t o 65C. Combine P a r t B and h e a t t o 70C. Combine P a r t A and P a r t B w i t h s t i r r i n g . Package i n t o c o n t a i n e r s t o be used as a pump s p r a y . F o r an a e r o s o l foam t y p e p r o d u c t , p r e s s u r i z e w i t h A46 p r o p e l 1e n t o r e q u i Val e n t Formula 112-66
-
.
Leather P r e s e r v a t i v e A p r o d u c t f o r p r e s e r v i n g l e a t h e r t h a t can be used as an a e r o s o l foam t y p e p r o d u c t o r packaged i n t o a c o n t a i n e r f i t t e d w i t h a pump. I n a r e d i en t s : % w/w P a r t A - O i l Phase: 1 . L a n o l i n USP 1 .oo 2. R i t a c h o l 5.00 3. S t e a r i c A c i d 3.00 4. G l y c e r i n 5.00 5. Methylparaben 0.15 6. T r i e t h a n o l a m i n e (50%) 1 .oo P a r t B: 7. Sodium L a u r y l S u l f a t e (30% S o l u t i o n ) 1.50 8 . D i s t i l l e d Water 83.15 9. Perfume 0.20 Compounding P r o c e d u r e s : Combine P a r t A w i t h h e a t t o 6 5 C . Combine P a r t B and h e a t t o 70C. Combine P a r t A and P a r t B w i t h s t i r r i n g . Package i n t o c o n t a i n e r s t o be used as a pump s p r a y . F o r an a e r o s o l foam t y p e p r o d u c t , p r e s s u r i z e w i t h A46 propellent o r equivalent. Formula 112-67
SOURCE:
R.I.T.A.
Corp.:
Suggested F o r m u l a t i o n s
Miscellaneous
"L
211
qgcd. L a m a p e r " (Water B a s e l
% by weinhf
I n q r e d i ents;. ( 1 ) S i l t e x -50 + l o 0 Mesh ( 2 ) K a o p o l i t e AB (3) Korthix ( 4 ) D e i o n i z e d Water
42.0 4.0 4.0 50.0
Procedure: Add ( 2 ) and ( 3 ) t o ( 4 ) w i t h f a s t m i x i n g . Slow m i x e r and add ( 1 ) . Some s e t t l i n g w i l l o c c u r , b u t i s e a s i l y r e - d i s p e r s e d b y shaking c o n t a i ner. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t u s e d . Comments: For more v i s c o s i t y and even l e s s s e t t l i n g , ( 3 ) t o 5%.
i n c r e a s e ( 2 ) and
" M a r b l e Pol i sh" (Water Baser % b -y
~~. Ingredients:. ~
( 1 ) F e r r o s i l 14
( 2 ) K a o p o l i t e AB (3) Korthix ( 4 ) D e i o n i z e d Water
Wei q h t 40.0 3.0 3.0 54.0
Procedure: Add ( 2 ) and ( 3 ) t o ( 4 ) w i t h f a s t m i x i n g . Slow m i x e r and add ( 1 ) . Some s e t t l i n g w i l l o c c u r , b u t i s e a s i l y r e - d i s p e r s e d b y shaking c o n t a i n e r . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Comments : For more v i s c o s i t y and even l e s s s e t t l i n g , ( 3 ) t o 5%. SOURCE: K a o p o l i t e C o r p . :
i n c r e a s e ( 2 ) and
Suggested F o r m u l a t i o n s
212
Advanced Cleaning Product Formulations
Paint S t r i m e r 68.5 1.3 4.1 6.8 2.7 13.7 2.9
F u r f u r y l A l c o h o l (FA) Klucel H Water Tall O i l Oowfax 302 Methanol C i t r u s - d - 1 imonene ( i nd. )
parts parts parts parts parts parts parts
M i x i n g D i r e c t i o n s (With Heat): 1 . Combine f u r f u r y l a l c o h o l , w a t e r , t a l l o i l , Dowfax 382. M i x w e l l and h e a t t o 110-12OF. 2 . D i s p e r s e K l u c e l H i n above m i x t u r e . M i x u n t i l d i s s o l v e d . C o o l . 3 . Add methanol and c i t r u s - d - l i m o n e n e . M i x we1 1.
M i x i ng D i r e c t i ons ( W i t h o u t H e a t ) : 1. D i s p e r s e K l u c e l H i n t o f u r f u r y l a l c o h o l . M i x f o r 10-15 m i n u t e s u n t i1 compl e t e l y d i s s o l ved . 2 . Add r e m a i n i n g i n g r e d i e n t s . M i x t h o r o u g h l y . Developmental F o r m u l a t i o n SC-9E Pai n t S t r i m e r Tetrahydrofurfuryl Tall O i l Dei o n i zed Water Dowfax 382 Klucel H Ethanol C i t r u s - d - 1 imonene
Alcohol
65.3 p a r t s 7.2 p a r t s 4.3 p a r t s 3.85 p a r t s 1. O p a r t s 14.5 p a r t s 3.85 p a r t s
F1ash Poi n t ( S e t a f 1ash) : 118F M i x i n g D i r e c t i o n s (With Heat): 1 . Combine t e t r a h y d r o f u r f u r y l a l c o h o l , w a t e r , t a l l o i l . Dowfax 382. M i x w e l l and h e a t t o 110-12OF. 2. D i s p e r s e K l u c e l H. M i x u n t i 1 d i s s o l v e d . C o o l . 3 . Add e t h a n o l and c i t r u s - d - l i m o n e n e . M i x t h r o o u g h l y . Mixing D i r e c t i o n s (Without Heat): 1. Disperse K lucel H i n t o t e t r a h y d r o f u r f u r y l a l c o h o l . Mix u n t i 1 completely dissolved. 2. Add r e m a i n i n g i n g r e d i e n t s . M i x t h o r o u g h l y . Developmental F o r m u l a t i o n SC-20T SOURCE: G r e a t Lakes Chemical Corp. : Suggested F o r m u l a t i o n s
Miscellaneous
213
P a i n t S t r i pDers ____-
__ Li p U i d Water Metso Beads 2048 s o d i um m e t a s i 1 ic a t e B i o d e g r a d a b l e g l u c o s i de a n i o n i c Sodi um h y d r o x i d e (50%)
40% 10% 10% 40%
Powders Metso 200 s o d i um o r t h o s i 1 i c a t e Usage: 6 o z . / g a l . w a t e r
100%
Metso Pentabead 20 sodium m e t a s i l i c a t e
G sodium s i l i c a t e Sodi um r e s i n a t e
40% 50% 2%
W a x S t r ip p e r s Liauids Water
C12-Cl5 l i n e a r a l c o h o l , 3-4 m o l e s €0 A c r y s o l AS€-1 08 P o t a s s i u m h y d r o x i d e (45%) TKPP (60%) K a s i 1 #6 p o t a s s i um s i 1 i c a t e
38.6% 3.0% 8.3% 3.4% 41 .7% 5.0%
Water Metso Beads 2048 sodium m e t a s i 1 c a t e Sodium h y d r o x i d e (50%) D i e t h a n o l ami ne EDTA, t e t r a s o d i u m (37%) O i p r o p y l ene g l y c o l monomethyl e h e r Phosphate e s t e r N o n y l p h e n o l , 9-10 moles EO
75% 5% 1% 1% 6% 4% 3% 5%
Powder ____ Metso Pentabead 20 s o d i um m e t a s i 1 i c a t e Sodium c a r b o n a t e TSP Sodium a l k y l a r y l s u l f o n a t e
35% 30% 20% 15%
SOURCE: PQ C o r p . :
D e t e r g e n t F o r m u l a r y : Suggested F o r m u l a t i o n s
214
Advanced Cleaning Product Formulations
P a r a f f in Wax Emu1 s i on Inaredient : P a r a f f i n Wax 125/7 Part A PEG 660 monooleate M e l t and m i x Tomah E-18-2 M e l t and m i x - h e a t P a r t A t o 170F Hot water-170F Pump i n t o P a r t A w i t h m i x i n g - t h e n c o o l t o 140F Glacial acetic acid Add a c e t i c a c i d a t 130-140F S i l i c o n e a n t i f o a m 10% Cool t o 11OF-add and m i x Formaldehyde 37% Cool t o 11OF-add and m i x Recommended D i l u t i o n s : A p p l i c a t i o n dependent Applications: Protective coatings, l u b r i c a n t s Formula M-103
Wt% 20.00 4.00 2.00 73.50 0.30 0.05 0.15
L i p u i d D r a i n Ooener Inaredient: >W 49.00 Water 50.00 NaOH (50%) Add, c o o l Tomah A l k a l i S u r f a c t a n t 1 .oo Add, m i x w e l l pH: 14.00 Recommended D i l u t i o n s : a s - i s A p p l i c a t i o n s : Removes o r g a n i c d r a i n c l o g s Notes: A l k a l i S u r f a c t a n t added t o i m p r o v e p e n e t r a t i o n and wetting Formula 1-106 Low VOC Heavy D u t y Presoak Wt% Innredient: 77.00 Water 2.00 Na - M e t a s i 1 ic a t e P e n t a h y d r a t e Dissolve completely w i t h mixing NTA (40%) 4.00 Dissolve completely w i t h mixing TKPP 6.00 D i s s o l v e compl e t e l y w i t h m i x i ng Tomah AO-14-2 1 .oo Add w i t h m i x i n g Tomah Q-14-2 3.00 Add w i t h m i x i n g N o n i o n i c Surfactant-HL813 3.00 Add w i t h m i x i n g SpG 20/20F: 1.08 pH: 12.50 Recommended D i l u t i o n s : 10-5O:l depending on c o n d i t i o n s A p p l i c a t i o n s : Carwash p r e s o a k , soak t a n k c l e a n e r Formula LV-105 SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
Miscellaneous
215
P e n e t r a t i n g G e l Base Attributes: T h i s p r o d u c t i s an e x c e l l e n t , c l e a r , e m o l l i e n t m o i s t u r i n g g e l v e h i c l e f o r a c t i v e in g r e d i e n t s . I t c o n t a i ns p r o p y l ene g l y c o l and 2-phenoxyethanol as s o l u b i l i z e r s / p e n e t r a n t . Inaredients: % w/w Part A: 1. Propylene G l y c o l 5.00 2. R i t o l e t h - 1 0 3.00 3. 2-Phenoxyethanol 2.00 4. M e t h y l p a r a b e n 0.10 5 . P r o p y l paraben 0.05 Part 0: 6. D i s t i l l e d Water 86.55 7 . DL Panthenol 0.50 P a r t C: 8. A c r i t a m e r 940 1 .oo P a r t D: 9 . T r i e t h a n o l a m i ne 99% 0.45 10.Di s t i 1 l e d Water 1.35 Compounding Procedure: Add i t e m 3 t o i t e m 1 and m i x . Add i t e m s 2, 4 and 5, m i x i n g a f t e r each a d d i t i o n . Combine P a r t B i n main m i x i n g t a n k and mix u n t i l u n i f o r m . Add P a r t A t o P a r t B and mix u n t i l u n i f o r m . Add P a r t C and m i x u n t i l w e l l b l e n d e d and f r e e o f lumps. Add P a r t D for neutralization. Formula H-89-A-12 Water i n O i l E m u l s i o n Base Attributes: T h i s w a t e r - i n - o i l e m u l s i o n i s smooth and non-greasy. The R i t a h y d r o x produces a s t a b l e p r o d u c t , which a l l o w s f o r t h e a d d i t i o n o f o t h e r m a t e r i a l s , i f d e s i r e d . The e m u l s i o n w i l l t i g h t e n and t h e v i s c o s i t y w i l l i n c r e a s e as t h e R i t a h y d r o x l e v e l i s r a i s e d ( t o a b o u t t h e 1% l e v e l ) . % w/w Inaredients: P a r t A: 1 . M i n e r a l O i l 80/90 21 .oo 2 . P a t i o n i c CSL 7.20 3. P a t i o n i c ISL 0.80 4. R i t a h y d r o x 0.50 5. M e t h y l paraben 0.10 6. P r o p y l paraben 0.05 P a r t 0: 7. G l y c e r i n 5.00 8. D i s t i l l e d Water 65.15 P a r t C: 9. G l y d a n t (40-700) 0.20 Compounding Procedure: Combine i n g r e d i e n t s o f P a r t A and h e a t t o 72C. Combine i n g r e d i e n t s o f P a r t 0 , h e a t i n g t o 72C. Add P a r t A t o P a r t B w h i l e s t i r r i n g and c o n t i n u e t o s t i r t o room t e m p e r a t u r e . Add P a r t C. M i x . Package. V i s c o s i t y : B r o o k f i e l d RVT s p i n d l e TA @ 4 rpm @ 27 C: 24,750 c p s . Formula H-89-P-23 SOURCE: R . I . T . A . C o r p . : Suggested F o r m u l a t i o n s
216
Advanced Cleaning Product Formulations
S o l v e n t Cleaners Blood S t a i n Remover
y&
Inqredient: S o f t Water TKPP D i s s o l ve Ammoni um Hydroxide (28%) Mix w e l l Tomah Amphoteric SC Mix w e l l IPA Mix w e l l Ethylene g l y c o l b u t y l e t h e r Mix w e l l
72.00 4.00 8.00
4.00 8.00 4.00
pH: 12.07 Recommended D i l u t i o n s : 0-5:l Formula S-116 Pai n t S t r i Dver
Wt%
I n a r e d ie n t : Water Ethylene g l y c o l b u t y l e t h e r Mix w e l l Na a l k y l e t h e r s u l f a t e , (60%) Mix w e l l NaOH (50%) Add s l o w l y , mix w e l l Tomah A1 k a l i S u r f a c t a n t Mix w e l l
66.50 10.00 3.00 15.00 5.50
SpG 20/20C: 1.08 pH: 13.50 Recommended D i 1u t i ons : as is A p p l i c a t i o n s : P a i n t remover f o r wood and metal s u r f a c e s Notes: P a i n t on w i t h brush and remove w i t h p u t t y k n i f e , s t e e l wool, e t c . Formula S-108
SOURCE: Tomah Products,
Inc.:
Suggested Formulations
Section II Transportation Cleaners and Polishes
217
15. Auto Cleaners and Polishes
218
Auto Cleaners and Polishes
Auto Cleaner/Polish.
219
A e r o s o l Packed
Innredi ents: ( 1 ) Hoechst Wax LP ( 2 ) P e t r o l i t e Wax C-36 ( 3 ) D i m e t h y l S i l i c o n e , 350 c e n t i s t o k e s (4) Arlacel C ( 5 ) Odorless M i n e r a l S p i r i t s ( 6 ) K a o p o l i t e SFO-NP ( 7 ) D e i o n i z e d Water
% by Weight 4.0 3.0 3.0 1.5 38.5 10.0 40.0
Procedure: M e l t ( 1 ) and ( 2 ) a t 150F, and m a i n t a i n t h i s t e m p e r a t u r e as o t h e r i n g r e d i e n t s a r e added, r e a d j u s t i n g as n e c e s s a r y . Add ( 3 ) , ( 4 ) , and ( 5 ) w i t h moderate a g i t a t i o n , t h e n add ( 6 ) s l o w l y and c o n t i n u e good a g i t a t i o n u n t i 1 we1 1 d i s p e r s e d and smooth. P r e h e a t ( 7 ) t o 150F and add s l o w l y w i t h c o n t i n u i n g a g i t a t i o n . Shut off h e a t and c o n t i n u e a g i t a t i n g u n t i l m i x t u r e c o o l s t o 9 O F F o l l o w recommended h a n d l i n g p r a c t i c e s of t h e s u p p l i e r s of each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g f 1ammabl e in g r e d i e n t s
.
D e t e r q e n t - R e s i s t a n t Auto C l e a n e r / P o l i s h Thick Liquid, Oil-External Inqredients: (1) Isopar L (2) Isopar M ( 3 ) Dow C o r n i n g 536 F l u i d ( 4 ) Dow C o r n i n g 531 F l u i d ( 5 ) Emcol 14 ( 6 ) K a o p o l i t e SFO-NP ( 7 ) D e i o n i z e d Water
% by Weisht 14.0 10.0 1.o 6.0 1.o 10.0 58.0
Procedure: Combine ( 1 ) t h r o u g h ( 4 ) , t h e n (51, and mix t h o r o u g h l y . Add (6) slowly w i t h vigorous a g i t a t i o n , continuing u n t i l w e l l d i s p e r s e d . Add ( 7 ) s l o w l y , w h i l e a g i t a t i n g s t r o n g l y u n t i l smoot h . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s of each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g flammable i n g r e d i e n t s .
SOURCE: K a o p o l i t e ,
Inc.:
Suggested F o r m u l a t i o n s
220
Advanced Cleaning Product Formulations
Auto C 1 eaner/Pol ish. Hard Paste Inqredients: ( 1 ) V i s c a s i l 10,000 (2) Hoechst Wax E ( 3 ) Hoechst Wax F ( 4 ) Hoechst Wax S (5) Odorless M i n e r a l S p i r i t s ( 6 ) Odor1 ess Kerosene ( 7 ) K a o p o l i t e SFO-NP
% bv Weiaht
5.0 7.2 4.0
1.8 57.5 12.5 12.0
Procedure: Combine ( l ) , (2), (3), and ( 4 ) t o g e t h e r , heat t o 194F, h o l d u n t i l melted. I n separate v e s s e l , heat ( 5 ) and ( 6 ) t o 140F, add s l o w l y t o t h e m e l t w i t h g e n t l e a g i t a t i o n , c o n t i n u i n g f i v e m i nutes a f t e r complete a d d i t i o n . Shut o f f heat, b u t c o n t i nue a g i t a t i o n ; add ( 7 ) s l o w l y , c o n t i n u e a g i t a t i o n u n t i l m i x t u r e c o o l s n e a r l y t o s o l i d i f i c a t i o n , and discharge i n t o c h i l l e d containers. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each product used. Good i n d u s t r i a l p r a c t i c e s should be used when h a n d l i n g f 1ammable ingredi e n t s . Cream Cleanser-Non Wax TvDe % by Weiaht
Inaredi e n t s : ( 1 ) Odorless Kerosene (2) VM&P Naphtha (3) O l e i c Acid ( 4 ) Triethanolamine (5) K a o p o l i t e SFO-NP (6) Deionized Water (7) Propyl ene G1y c o l ( 8 ) T e r g i t o l NPX (9) K o r t h i x H
5.0 20.0 9.0
3.0 10.0 40.0 4.0 4.0
5.0
Procedure: Combine ( 1 ) t h r o u g h ( 4 ) , t h e n add (5) s l o w l y w i t h v i g o r o u s a g i t a t i o n , c o n t i n u i n g u n t i l w e l l dispersed. I n another v e s s e l , combine ( 6 ) . (7), and ( 8 ) . Then d i s p e r s e ( 9 ) i n t h e m i x t u r e w i t h good a g i t a t i o n . Reduce a g i t a t i o n i n t h e o i l m i x t u r e t o moderate, add t h e water m i x t u r e s l o w l y , and s t i r u n t i l w e l l blended. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s of each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s should be used when h a n d l i n g f 1ammabl e ingredi e n t s . SOURCE: K a o p o l i t e , I n c . :
Suggested Formulations
Auto Cleaners and Polishes
Auto Cleaner/Polish.
221
Hard Paste
Ingredients: (1) V i s c a s i l 10,000 (2) Hoechst Wax E (3) Hoechst Wax F ( 4 ) Hoechst Wax S ( 5 ) O d o r l e s s Kerosene (6) I o n a c PE 110 ( 7 ) K a o p o l i t e SF o r 1168 (8) O d o r l e s s M i n e r a l S p i r i t s
% bv Wei q h t 5.0 7.2 4.0
1.8 12.5 0.25 12.0 57.25
Procedure: Heat ( l ) , ( 2 ) , (3), and ( 4 ) t o g e t h e r t o 194F, h o l d u n t i l m e l t e d . I n s e p a r a t e v e s s e l , b l e n d ( 5 ) and (6) w i t h g e n t l e a g i t a t i o n ; add ( 7 ) s l o w l y , and i n c r e a s e f o r 5 m i n u t e s t o v i g o r o u s a g i t a t i o n . Reduce t o moderate a g i t a t i o n and add (8) When w e l l d i s p e r s e d , combine ( 5 t h r o u g h 8) w i t h t h e m e l t e d (1 t h r o u g h 4). When c o o l e d , d i s c h a r g e i n t o c o n t a i n e r s . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g flammable i n g r e d i e n t s . Comments: Use o f K a o p o l i t e 1168 g i v e s more a g g r e s s i v e c l e a n i n g and p o l i s h i n g action t o the formulation. D e t e r Q e n t - R e s i s t a n t Auto C l e a n e r / P o l i s h Thick Liquid, Oil-External % by Weiaht
Inaredients: (1) I s o p a r L (2) I s o p a r M (3) Dow C o r n i n g 536 F l u i d ( 4 ) Dow C o r n i n g 531 F l u i d ( 5 ) Emcol 14 ( 6 ) K a o p o l i t e SF ( 7 ) D e i o n i z e d Water
14.0 10.0
1 .o 6.0 1 .o 10.0 58.0
Procedure: Combine (1) t h r o u g h ( 4 ) , t h e n add (5), and mix t h o r o u g h l y . Add (6) s l o w l y w i t h v i g o r o u s a g i t a t i o n , c o n t i n u i n g u n t i l w e l l d i s p e r s e d . Add ( 7 ) s l o w l y , w h i l e a g i t a t i n g s t r o n g l y u n t i l smooth. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g flammable i n g r e d i e n t s . SOURCE: K a o p o l i t e ,
Inc.:
Suggested F o r m u l a t i o n s
222
Advanced Cleaning Product Formulations
Auto-Cl eaner/Pol ish.
H i ph Gloss % by Weight 40.4 2.0 15.0 0.2 1.4 4.0 3.0 32.0 2.0
Inqredients: ( 1 ) Deionized Water (2) Korthix ( 3 ) K a o p o l i t e SF ( 4 ) Hoechst Wax E ( 5 ) Hoechst Wax LP (6) Dimethyl S i l i c o n e , 350 c e n t i s t o k e s ( 7 ) O l e i c Acid ( 8 ) Odorless M i n e r a l S p i r i t s ( 9 ) Morphol ine
Procedure: ,i t h s t r o n g a g i t a t i o n u n t i l smooth, w h i l e Add ( 2 ) t o ( l )w h e a t i n g t o 150F. C o n t i n u i n g a g i t a t i o n and m a i n t a i n i n g temperat u r e , s l o w l y add ( 3 ) and s t i r a c t i v e l y u n t i l u n t i l f r e e from coarse agglomerates. I n another v e s s e l , heat ( 4 ) , ( 5 ) , and (6) t o 150F and b l e n d t h o r o u g h l y . Add ( 7 ) and ( 8 ) , m a i n t a i n 150F and mix we1 1. S t i r ( 9 ) i n t o t h e h o t o i l m i x t u r e , and immediately pour h o t water s l u r r y i n t o h o t o i l m i x t u r e , s t i r r i n g w e l l t o e m u l s i f y . Continue moderate a g i t a t i o n w h i l e c o o l i n g t o f i l l i n g temperature. Good i n d u s t r i a l p r a c t i c e s should be used when h a n d l i n g f 1ammabl e in g r e d i e n t s . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s of each product used. Pre-Wax Cleaner,
Automotive.
Liauid % bv Wei Qht 44.0 16.5 10.0 20.0 2.5 4.0 2.0 1 .o
Innredients: ( 1 ) Deioni zed Water ( 2 ) K a o p o l i t e SF ( 3 ) Odor1 ess Kerosene ( 4 ) VM&P Naphtha ( 5 ) T r i ethanol ami ne (6) O l e i c A c i d ( 7 ) Pine O i l ( 8 ) Bentone 38
Procedure: S l u r r y ( 2 ) i n ( 1 ) w i t h s t r o n g a g i t a t i o n . I n a separate v e s s e l , warm (3) and ( 4 ) t o 100-llOF, add ( 5 ) ’ (6). ( 7 ) . and ( 8 ) , mix t h o r o u g h l y . Pour water m i x t u r e s l o w l y , w i t h good a g i t a t i o n , i n t o warm o i l m i x t u r e , and b l e n d u n t i l smooth. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each product used. Good i n d u s t r i a l p r a c t i c e s should be used when h a n d l i n g flammable ingredi e n t s . Comments : I n use, a f t e r s u i t a b l e rubbing, product may be f l u s h e d o f f w i t h water, or i f p r e f e r r e d , may be a l l o w e d t o d r y and then wiped o f f w i t h c l e a n , d r y c l o t h . SOURCE: K a o p o l i t e ,
Inc.:
Suggested Formulations
Auto Cleaners and Polishes
223
A u t o C l e a n e r / P o l i s h . Low-Temperature Conwounded T h i c k L i q u i d , Water-External % by Weiaht Inqredients: ( 1 ) D e i o n i z e d Water 35.0 ( 2 ) K a o p o l i t e SF 17.0 ( 3 ) D e i o n i z e d Water 7.5 ( 4 ) Odorless M i n e r a l S p i r i t s 32.0 ( 5 ) D i m e t h y l S i l i c o n e , 350 c e n t i s t o k e s 4.0 (6) O l e i c A c i d 2.0 0.2 ( 7 ) Hoechst Wax E ( 8 ) Hoechst Wax LP 1.4 ( 9 ) Morphol ine 0.9 Procedure: Add ( 2 ) s l o w l y t o ( 1 ) w i t h v i g o r o u s a g i t a t i o n , w h i l e h e a t i n g t o 150F, u n t i l w e l l d i s i n t e g r a t e d and smooth, t h a n add ( 3 ) , and r e h e a t t o 150F. I n a n o t h e r v e s s e l , combine ( 4 ) t h r o u g h ( 8 ) w i t h moderate a g i t a t i o n , h e a t t o 150F and h o l d u n t i l c l e a r s o l u t i o n r e s u l t s . C o n t i n u i n g a g i t a t i o n , add 9, t h e n s l o w l y add K a o p o l i t e - W a t e r slurry. Shut o f f h e a t , c o n t i n u e g e n t l e a g i t a t i o n u n t i l e m u l s i o n c o o l s t o llOF. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Good i n d u s t r i a l h a n d l i n g p r a c t i c e s s h o u l d be used when handl i n g flammable i n g r e d i e n t s .
A u t o C1e a n e r / P o l ish , f o r Machi ne B u f f i n g % b y Weiqht Inaredients: 5.5 ( 1 ) Hoechst Wax S ( 2 ) P a r a f f i n O i l , Faxam No. 40 o r 45 5.0 ( 3 ) A c t i n o l FA-3 0.9 ( 4 ) D e i o n i z e d Water 1.5 (5) D i e t h y l a m i noethanol 0.5 (6) D e i o n i z e d Water 66.6 ( 7 ) Odorless Mineral S p i r i t s 5.0 ( 8 ) D r a k e o l 2251 5.0 ( 9 ) K a o p o l i t e SF 10.0 Procedure: M e l t ( 1 ) . ( 2 ) . and ( 3 ) t o g e t h e r a t 210F. M i x ( 4 ) and (5), add t o t h e m e l t w h i l e s t i r r i n g . P r e h e a t (6) t o 150F and add, s l o w l y a t f i r s t , w h i l e c o n t i n u a l l y s t i r r i n g . P r e h e a t ( 7 ) and ( 8 ) t o 150F. e i t h e r s e p a r a t e l y o r t o g e t h e r , and s t i r i n . Add ( 9 ) s l o w l y , c o n t i n u e s t i r r i n g a t 150F. o r h i g h e r , u n t i l t h o r o u g h l y d i s p e r s e d and b l e n d e d . Shut o f f h e a t , b u t c o n t i n u e s t i r r i n g u n t i l b a t c h c o o l s t o room t e m p e r a t u r e . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g f 1ammabl e in g r e d i e n t s .
SOURCE: K a o p o l i t e ,
Inc.:
Suggested F o r m u l a t i o n s
224
Advanced Cleaning Product Formulations
A u t o C l e a n e r / P o l ish, S o f t P a s t e ,
Emul s i on
Inqredients: ( 1 ) Odor1 ess Kerosene (2) Hoechst Wax S ( 3 ) V i s c a s i l 10,000 (4) O l e i c A c i d (5) Morphol ine ( 6 ) D e i o n i z e d Water ( 7 ) K a o p o l i t e SF ( 8 ) D e i o n i z e d Water (9) Odorless M i n e r a l S p i r i t s ( 1 O ) S i 1 i c o n e Emul s i o n SM-2035
% b y WeiphA
10.0 8.0 2.5 2.0
1.1 24.0 12.0 15.4 20.0 5.0
Procedure: Combine ( 1 ) t h r o u g h ( 5 ) and h e a t t o 210F w i t h a g i t a t i o n . Provide i n t e n s i v e a g i t a t i o n w h i l e i n t r o d u c i n g t h e remaining i n g r e d i e n t s as d e s c r i b e d b e l o w . S l u r r y t h e K a o p o l i t e SF by s l o w a d d i t i o n o f ( 7 ) i n t o ( 6 ) w i t h a g i t a t i o n . A f t e r t h o r o u g h in c o r p o r a t i on, add r e m a i n i n g w a t e r ( 8 ) t o t h e s l u r r y w i t h a g i t a t i o n . Heat s l u r r y t o 150F. S l o w l y add t h e h e a t e d s l u r r y t o t h e b a t c h w i t h i n t e n s i v e a g i t a t i o n . A l l o w t i m e f o r t h o r o u g h i n c o r p o r a t i o n . S l o w l y add (9) t o the batch w i t h intensive a g i t a t i o n allowing time f o r thorough i n c o r p o r a t i o n . Change a g i t a t i o n t o a s l o w s t i r r i n g , add (10) and c o n t i n u e s t i r r i n g u n t i 1 m i x t u r e c o o l s t o packaging temperature o f
105-1 2OF. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g f 1ammabl e in g r e d i e n t s
.
"Luster-Powder" Inqredients: (1) K a o p o l i t e SF (2) M i c r o f i n e V I ( 3 ) Dimethyl S i l i c o n e ,
A u t o P o l ish % b y Weiqht
95.0 3.0 350 c e n t i s t o k e s
2.0
Procedures: D r y b l e n d ( 1 ) and (2) t h o r o u g h l y . C o n t i n u e b l e n d i n g , w h i l e s l o w l y a d d i n g ( 3 ) u n t i l w e l l mixed. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used.
SOURCE: K a o p o l i t e ,
Inc.:
Suggested F o r m u l a t i o n s
Auto Cleaners and Polishes
Auto Cleaner/Polish,
225
Thick Liauid. Oil-External
Inaredients: ( 1 ) D e i o n i z e d Water (2) Korthix H ( 3 ) Hoechst Wax E ( 4 ) Hoechst Wax LP (5) Oleic Acid ( 6 ) D i m e t h y l S i l i c o n e , 350 c e n t i s t o k e s ( 7 ) Odorless Mineral S p i r i t s ( 8 ) K a o p o l i t e SFO-NP (9) Morpholine
% by Weiqht
40.2 2.1 0.2 1.4 2.0 4.0 32.0 17.2 0.9
Procedure: Heat ( 1 ) t o 140-150F and add ( 2 1 , w i t h good a g i t a t i o n u n t i l w e l l d i s p e r s e d . I n a s e p a r a t e v e s s e l , m e l t ( 3 ) and ( 4 ) a t 180-190F, add ( 5 ) , ( 6 ) , and ( 7 ) , r e h e a t i n g as n e c e s s a r y t o m a i n t a i n a t 140-15OF. Add ( 8 ) s l o w l y t o t h e o i l m i x t u r e , maint a i n i n g temperature, a g i t a t i n g w e l l u n t i l t h o r o u g h l y dispersed and smooth, t h e n s t i r i n ( 9 ) . Add t h e w a t e r m i x t u r e s l o w l y t o t h e o i l m i x t u r e , b l e n d i n g u n t i l smooth. Shut o f f h e a t and c o n t i n u e a g i t a t i o n u n t i l t h e p r o d u c t c o o l s t o 9OF. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d b e used when h a n d l i n g f 1ammabl e in g r e d i e n t s . D e t e r q e n t - R e s i s t a n t A u t o / C l e a n e r P o l ish, T h i n L i q u i d Inqredients: ( 1 ) S t o d d a r d Sol v e n t ( 2 ) O d o r l e s s Kerosene ( 3 ) Epolene E-10 Wax ( 4 ) Dow C o r n i n g 531 F l u i d ( 5 ) Dow C o r n i n g 536 F l u i d ( 6 ) K a o p o l i t e SFO-NP ( 7 ) Span 80 ( 8 ) D e i o n i z e d Water
% b y Weiaht 16.0 10.0 2.0 4.5 0.8 10.0 1.o 55.7
Procedure: Combine ( 1 ) t h r o u g h ( 5 ) , h e a t t o 19OF u n t i l c l e a r s o l u t i o n r e s u l t s . Add ( 6 ) s l o w l y , w i t h v i g o r o u s a g i t a t i o n u n t i l w e l l d i s p e r s e d and smooth. Add ( 7 ) and r e a d j u s t t e m p e r a t u r e t o 19OF I n a n o t h e r v e s s e l , h e a t ( 8 ) t o 19OF, t h e n add t o above m i x t u r e w i t h good a g i t a t i o n . C o n t i n u e a g i t a t i o n , m a i n t a i n i n g t e m p e r a t u r e above 180F u n t i l t h o r o u g h l y mixed, t h e n a g i t a t e s l o w l y w h i l e c o o l i n g t o room t e m p e r a t u r e . F o l l o w recommended h a n d l i n a _ D . ractices o f the suppliers o f each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g f 1ammabl e in g r e d i e n t s . SOURCE: K a o p o l i t e ,
Inc.:
Suggested F o r m u l a t ons
226
Advanced Cleaning Product Formulations
Cream Car Wax In g r e d ien t s : ( 1 ) S i l i c o n e F l u i d L45 (2) S i l i c o n e AFL 40 ( 3 ) Carnauba Wax #3 ( 4 ) Odorless M i n e r a l S p i r i t s (5) Oleic Acid ( 6 ) D e i o n i z e d Water ( 7 ) Morphol ine ( 8 ) K a o p o l i t e 1152
% by Weight 4.0
2.0 6.0
29.0 2.0 46.0
2.0 9.0
Procedure: Combine (l), (3), and ( 5 ) i n t o h a l f o f ( 4 ) . Heat w i t h a g i t a t i o n t o 19OF u n t i l wax m e l t s and a c l e a r s o l u t i o n r e s u l t s . Add ( 7 ) t o n e u t r a l i z e wax. Then add (2) and t h e r e m a i n d e r o f ( 4 3 . S l u r r y ( 8 ) i n t o t h e w a t e r w i t h h i g h a g i t a t i o n . Add h o t s o l v e n t s o l u t i o n t o t h e s l u r r y and remove h e a t w h i l e c o n t i n u i n g t o m i x u n t i l p a s t e p o l i s h r e a c h e s 130F. Pour i n t o c o n t a i n e r s . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g f 1ammabl e in g r e d i e n t s
.
Rubbing ComDound % b v Weiqht
Inqredients: ( 1 ) D e i o n i z e d Water (2) K a o p o l i t e SF (3) O d o r l e s s Kerosene (4) Glycerine (5) Triethanolamine (6) O l e i c Acid (7) Pine O i l ( 8 ) S i l t e x 44
52.0 5.6
9.9 25.0 0.5
0.8 0.5 5.7
Procedure: M i x ( 5 ) and ( 6 ) t o f o r m t e a o l e a t e . Add ( 1 ) and m i x . S l o w l y add ( 3 ) and e m u l s i f y . Add ( 4 ) w i t h c o n t i n u e d s t i r r i n g . I n c l u d e ( 2 ) and ( 8 ) w i t h a g i t a t i o n . Add ( 7 ) f o r perfume. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s of each p r o d u c t used. Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g f 1ammabl e in g r e d i e n t s
.
Comments : A f t e r s u i t a b l e r u b b i n g , p r o d u c t may be f l u s h e d o f f w i t h w a t e r ; o r i f p r e f e r r e d , may be a l l o w e d t o d r y and t h e n w i p e d o f f w i t h clean, d r y c l o t h . SOURCE:
Kaopolite,
Inc.:
Suggested F o r m u l a t i o n s
Auto Cleaners and Polishes
227
DeterQent-Resi s t a n t Auto Cleaner P o l i s h Both f o r m u l a t i o n s a r e w a t e r - i n - o i l emulsions w i t h e x c e l l e n t g l o s s and d e t e r g e n t - r e s i s t a n t p r o p e r t i e s . I n each, t h e r a t i o o f Dow Corning 536 f l u i d t o Dow Corning 200 f l u i d o r Dow Corning 531 f l u i d i s c r i t i c a l . For example, i f Dow Corning 200 f l u i d is increased in Formulation "B" , t h e d e t e r g e n t r e s i s t a n c e w i 11 decrease. Ingredients: Dow Corning 536 F l u i d Dow Corning 531 F l u i d W i tcami de 51 1 Stoddard S o l v e n t K a o p o l i t e SF Water Bentone 38 I s o p r o p y l Alcohol (Anhydrous)
Percent by Weight Polish A 1 .oo
Inqredients: Dow Corning 536 F l u i d Dow Corning 200 F l u i d , 12,500 c S t . W i tcami de 51 1 Stoddard S o l v e n t K a o p o l i t e SF Water Bentone 38 I s o p r o p y l Alcohol (Anhydrous)
6.00 1 .oo 22.00 10.00 59.25 0.50 0.25 Polish B
2.00 2.00 1 .oo 25.00 10.00 59.25 0.50 0.25
Slowly add water and K a o p o l i t e SF t o m i x t u r e o f o t h e r ingredi e n t s . S i f t i n Bentone 38 i f low shear m i x i n g equipment i s used. Solvents o t h e r t h a n Stoddard may be used depending on t h e d e s i r e d d r y i n g r a t e . Kerosene may be added t o slow t h e e v a p o r a t i o n r a t e . I s o p a r L and I s o p a r M (Exxon Company) combinations a r e a l s o excel l e n t .
SOURCE:
Dow Corning Corp.:
Suggested Formulations
228
Advanced Cleaning Product Formulations
___ D e t e r g e n t - R e s i s t a n t A u t o Cleaner- P o l i s h - P o l i s h 4 -I .nqredi
ents :
W i t c a m i de 51 1
Stoddard Solvent* K a o p o l i t e SF Water Dow C o r n i n g 929 C a t i o n i c E m u l s i o n
P e r c e n t b y Wei n h t 1.o 20.5 10.0 57.0 11.5
_ D e_ t e r q e n t - R e s i s t a n t A u t o C l e a n e r P o l ish-Pol is h B I n redi-ents: de 51 1 Stoddard S o l v e n t * K a o p o l i t e SF Dow C o r n i n g 531 f l u i d Water Dow C o r n i n g 929 C a t i o n i c E m u l s i o n
w i :cami
P e r c e n t b y Weight 1. o 19.5 10.0 2.0 59.0
8.5
Method: W i t h continuous a g i t a t i o n , mix a l l i n g r e d i e n t s t o g e t h e r except Dow C o r n i n g 929 c a t i o n i c e m u l s i o n . Add w a t e r s l o w l y . Then add Dow C o r n i n g 929 c a t i o n i c e m u l s i o n . O t h e r s o l v e n t s may be used d e p e n d i n g upon t h e d e g r e e o f d r y i n g r a t e d e s i r e d . Kerosene s l o w s t h e e v a p o r a t i o n r a t e , w h i l e c o m b i n a t i o n s o f I s o p a r L and I s o p a r M (Exxon O i l Co.) a r e a l s o e x c e l 1e n t s o l v e n t s u b s t i t u t e s .
*
A u t o C1e a n e r - P o l ish
Part: A
B
C
I n g r e d i m 200 F l u i d - 100 c s 200 F l u i d - 1,000 c s Carnaube Wax, #1 Y e l l o w Beeswax Oleic Acid Kerosene S t o d d a r d Sol v e n t Morpholine Water Snowf l o s s K a o p o l i t e SF Carbopol 934 Water
P e r c e n t b y Wei Qht 1.5 4.5 1.0 1.o 2.5 2.0 18.0 1.5 16.0 7.0 7.0 0.1 37.9
~~
Method : Heat p a r t "A" i n g r e d i e n t s t o 79C ( 1 7 5 F ) t o m e l t waxes (WARNING: FLAMMABLE). M i x p a r t s "B" and " C " s e p a r a t e l y . W h i l e b l e n d i n g "A" w i t h a h i g h - s h e a r m i x e r , add phase "B" s l o w l y . M a i n t a i n t e m p e r a t u r e between 71 and 7 9 C (160 and 1 7 5 F ) . Remove h e a t , t h e n add phase "C" w i t h s t i r r i n g .
SOURCE: Dow C o r n i n g C o r p . :
Suggested F o r m u l a t i o n s
Auto Cleaners and Polishes
229
L i a u i d S i 1i c o n e Car P o l i s h A p o l i s h des f i l m on p a i n t e d s i m p l e and easy f o r many p o s s i b
Part: A
B
C
gned t o g i v e a l u s t r o u s , h i g h - g l o s s , p r o t e c t i v e a u t o s u r f a c e s . T h i s suggested f o r m u l a t i o n i s t o p r o d u c e and can be used as a s t a r t i n g p o i n t e variations.
Inaredi ents: P e r c e n t b v Wei q h t 200 S i l i c o n e F l u i d by Dow C o r n i n g , 350 c s . 4.0 Stoddard S o l v e n t 19.0 Kerosene 2.0 Oleic Acid 2.5 Morphol ine 1.5 Water 16.0 Snow F l o s s 14.0 Water 41 .O
P r e p a r a t ion : 1 . M i x P a r t A w i t h a h i g h - s h e a r m i x e r ( C o l l o i d M i 1 or Eppenbach mixer) . 2 . S l o w l y add P a r t B t o P a r t A w h i l e c o n t i n u i n g t o m i x . 3 . C o n t i n u e t o m i x w h i l e a d d i n g P a r t C t o t h e AB c o m b i n a t i o n 4. O l e i c a c i d may be added t o P a r t B, i f d e s i r e d , and t h e n mixed as above. Formula CP-92A A u t o Rinse-Wax
Concentrate
Inaredi ents: Dow C o r n i n g 929 C a t i o n i c Emulsion Carnauba Wax Armac-HT Water
P e r c e n t bv Wei q h t 33.3 6.7 2.0 58.0
Method : M e l t wax w i t h Armac-HT and add t o 9OC (194F) w a t e r w i t h c o n t i n u o u s s t i r r i n g . Then c o o l t o room t e m p e r a t u r e and add s o l u t i o n t o Dow C o r n i n g 929 c a t i o n i c e m u l s i o n . Auto Vinyl-Top Part: A B
Protector
Inqredients: W i t c a m i de 51 1 200 F l u i d , 1,000 c S t Stoddard Solvent Dow C o r n i n g 929 C a t i o n i c E m u l s i o n Water
P e r c e n t by Wei a h t 1 .o 0.5 25.0 12.0 61.5
Method: M i x p a r t " A " and p a r t "B" i n g r e d i e n t s s e p a r a t e l y . Then, c o n t i n u o u s a g i t a t i o n , add "8" t o " A " . SOURCE: Dow C o r n i n g C o r p . :
Suggested F o r m u l a t i o n s
with
230
Advanced Cleaning Product Formulations
Soravwax I 1 I n a r e d ie n t : KerrMac 600 MSO Tomah Emu1s i f ie r 827 Add, mix w e l l Ethylene g l y c o l b u t y l e t h e r Add, mix w e l l Water (70-9OF) Add s l o w l y t o above, m x w e l l
Wt% 18.00 15.00 4.00 63.00
pH: 7.90 Recommended D i 1u t i ons : 1O:l than i n j e c t 6 oz/car Appl ic a t ions : Carwash Notes: Formulation may need s l i g h t adjustment f o r o t h e r m i n e r a l seal o i Formula T-115 Non-Hydrocarbon Soraywax-N-3 Inaredi ent: Water (70-9OF) Tomah Ecowax N-3 Blend i n t o water v e r y s l o w l y w i t h c o n s t a n t m i x i n g
Wt% 59.00 41 .OO
Recommended D i l u t i o n s : 1O:l t h e n i n j e c t 6 oz/car Applications: drying a i d "Environmentally f r i e n d l y " - e x c e l l e n t f o r r e g i o n s w i t h hydrocarbon e f f l u e n t r e s t r i c t o n s Formula T-116 Non-Hydrocarbon Sprawax-N-4 I n q r e d ie n t : Water (70-9OF) Tomah Ecowax N-7 Blend i n t o water v e r y s l o w l y w i t h c o n s t a n t m i x i n g
Wt% 61 . O O 39.00
Recommended D i l u t i o n s : 1O:l then i n j e c t 6 oz/car Applications: Drying a i d "Envi ronmental 1y f r i end1y"-excel 1e n t f o r r e g i o n s w i t h hydrocarbon e f f l u e n t r e s t r i c t i o n s Formula T-116
SOURCE: Tomah Products,
Inc.:
Suggested Formulations
Auto Cleaners and Polishes
231
T r a n s o o r t a t i on C1e a n e r s Wash and Wax 1 W S 78.50 1 .so
Inaredi ent: Water Tomah Q-17-2 Add, m i x w e l l Tomah Emu1 s i f i e r Four Add, m i x w e l l Tomah A0-728 Add, m i x w e l l Tomah A m p h o t e r i c L Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l
5.00 8.50 5.00 1.50
pH: 7.50 Recommended D i 1u t i o n s : 1 : 10 t h e use 10 z / c a r A p p l i c a t i o n s : Wash and Wax, Foam wax Notes: Good v i s c o s i t y , foaming, and b e a d i n g Formula T-109 Wash and Wax 2
Wt%
Innredi ent : Water Tomah Q-17-2 o r Q-14-2 Blend w e l l Tomah A m p h o t e r i c L Blend w e l l
76.00 8.00 16.00
SpG 2 0 / 2 0 F : 1 . 0 1 pH: 7 . 9 Recommended D i l u t i o n s : 1 : l O t h e n u s e 10 o z / c a r A p p l i c a t i o n s : Wash and Wax, Foam Wax N o t e s : More Foam, l e s s b e a d i n g t h a n Formula CW-109 Formula T-110 P o l i s h o r "Hot Wax" W S 98.00 2.00
Inaredient: Tomah E m u l s i o n C-340 U n i o n C a r b i d e S i l w e t L7600 Blend i n s l o w l y t o p r e v e n t foaming Recommended D i l u t i o n s : 1 o z / c a r A p p l i c a t i o n s : A u t o l a u n d r y h o t wax, Formula T-105
SOURCE:
Tomah P r o d u c t s ,
Inc.:
s e a l e r wax,
p o l i s h wax
Suggested F o r m u l a t i o n s
232
Advanced Cleaning Product Formulations
Waxless,
Pres0ftened.n-Resistant,
Inpredients: P a r t A: Water K a o p o l i t e SF P a r t B: L-140 S o l v e n t Dow C o r n i n g 02-3225C Part C: Dow C o r n i n g 536 F l u i d Dow C o r n i n g 531 F l u i d 50% S o l u t i o n o f Sodium C i t r a t e i n Water Tween 20
Cleaner,
Paste P o l i s h
_ Pe _r_ ce _n_t b l W e i q h t 50.0 15.0
9.5 7.5 1.o 6.0 2.0 1. o
Load p a r t " A " i n t o a m i x i n g v e s s e l . S t a r t a g i t a t i o n and m i x u n t i 1 u n i f o r m . Load p a r t "B" i n t o a g i t a t e d m i x i n g v e s s e l . M i x f o r a minimum o f 10 t o 15 m i n u t e s . Load Dow C o r n i n g 531 and 536 f l u i d s . M i x u n t i l a u n i f o r m , w a t e r - i n - o i l e m u l s i o n i s formed. A f t e r t h e e m u l s i o n i s formed, l o a d t h e s o l u t i o n o f sodium c i t r a t e and w a t e r . Load t h e Tween 20. M i x u n t i l u n i f o r m . F i n a l p r o c e s s t h r o u g h a h i g h shear m i x i n g o p e r a t i o n ( i . e . , c o l l o i d m i l l , homogenizer, h y d r o s h e a r [ G a u l i n C o r p . ] , o r Cowles M i x e r , o r r e c i r c u l a t e t h r o u g h a h i g h s h e a r auger o r c e n t r i f u g a l pump). Auto-Ri nse P o l ish Dow C o r n i n g 536 f l u i d can b e f o r m u l a t e d a s an a u t o - r i n s e p o l i s h f o r e x c e l l e n t w a t e r b e a d i n g and g l o s s . E m u l s i o n s o f t h i s f l u i d can a l s o be used as an e x c e l l e n t auto-wash p o l i s h f o r m u l a . Insredients: Dow C o r n i n g 536 F l u i d I s o p r o p y l A l c o h o l , 99 p e r c e n t Glacial Acetic Acid
P e r c e n t by Wei Q h t 44 50 6
M i x t h e a c e t i c a c i d w i t h t h e i s o p r o p y l a l c o h o l and add t h i s t o Dow C o r n i n g 536 f l u i d . T h i s c o n c e n t r a t e has good s h e l f s t a b i l i t y . To use, d i l u t e w i t h w a t e r and a p p l y . One p a r t o f t h e c o n c e n t r a t e may be added t o 2 0 p a r t s w a t e r f o r e x c e l l e n t w a t e r b e a d i n g and g l o s s p r o p e r t i e s . A p p l y w i t h a sponge o r c l o t h and r i n s e w i t h w a t e r w i t h o u t d r y i n g , o r a p p l y and w i p e d r y w i t h a cloth.
SOURCE: Dow C o r n i n g Corp. : Suggested F o r m u l a t i o n s
16. Car and Truck Wash Compounds
233
234
Advanced Cleaning Product Formulations
Auto L Truck Care Products Concentrated Car Wash
L %
Water Tetrasodi um EDTA NaOH (50%) Sodium LAS (60%) S u l f o t e x 6040s Standamid CD
44 2 4 25
20 5
Usage: 1 p a r t t o 60 p a r t s water Car Wash (Automatic)
W t % 60
Water TKPP Sodium LAS (60%) Glucopon 425 CS Standamid CD Propylene G l y c o l n B u t y l Ether Usage:
2 20 10
3 5
1 p a r t t o 30 p a r t s water Power Car Wash ( S e l f S e r v i c e ) W
Soda Ash Sodium LAS (60%) Glucopon 600 CSUP
3
88 4
8 Hand Wash
L UDholsterv W 3 64.5
Water Standapol A Glucopon 600 CSUP Standamid KD
28.0 5.0 2.5
Procedure: Add i n t h e o r d e r l i s t e d , d i s s o l v i n g each i n g r e d i e n t completely u s i n g moderate a g i t a t i o n . I n c o r p o r a t e c o l o r and f r a g r a n c e as needed.
SOURCE:
Henkel Corp.:
Sugoested Formulations
Car and Truck Wash Compounds
235
Car Wash L i q u i d Alkylbenzene S u l f o n i c Acid Sodi um X y l e n e Sul f o n a t e I g e p a l CO-710 T e t r a p o t a s s i u m P y r o p h o s p h a t e (60% A c t i v e ) P o t a s s i um H y d r o x i d e (45% A c t i v e ) Water
W % .t 6.0 11.5 3.0 25.0 2.5 52.0
Procedure: 1 . Dissolve alkylbenzene s u l f o n i c a c i d i n water. 2 . Add sodium x y l e n e s u l f o n a t e , I g e p a l CO-710, T e t r a p o t a s s i u m p y r o p h o s p h a t e and p o t a s s i u m h y d r o x i d e , m i x i n g w e l l a f t e r each a d d i t i on. 3. F i l t e r p r o d u c t . Physical Properties: pH ( a s i s ) : 9 . 5 pH ( 1 % ) : 9 . 9 V i s c o s i t y : 10 c p s S p e c i f i c G r a v i t y : 1.05 Formula TR-0023 Car Wash Powder
Wt.% Igepal Sodi um Sodi um Sodium
03-710 T r i p o l yphosphate M e t a s i 1i c a t e P e n t a h y d r a t e Carbonate ( L t . D e n s i t y )
10.0 50.0 5.0 35.0
Procedure: 1 . M i x I g e p a l CO-710 w i t h Sodium T r i p o l y p h o s p h a t e . 2 . Add Sodium M e t a s i l i c a t e P e n t a h y d r a t e and Sodium C a r b o n a t e . Physical Properties: Appearance: W h i t e , f r e e - f l o w i n g powder pH ( 1 % ) : 1 1 . 2 Speci f ic G r a v i t y : 0 . 7 3 Formula TR-0022
SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
236
Advanced Cleaning Product Formulations
Carwash Shampoo-I Inaredient: % Water 64.00 NaOH (50%) 5.40 Add c a r e f u l l y , m i x w e l l DDBSA ( f r e e a c i d ) 20.60 D i s s o l v e we1 1 Tomah A m p h o t e r i c L 10.00 Add, m i x w e l l Salt t o thicken q.s Recommended D l u t i o n s : 1-3 o z . / g a l o r as n e c e s s a r y t h r o u g h a u t o system A p p l i c a t i o n s : Foam b r u s h , shampoo, b u c k e t wash N o t e s : Very h gh f o a m i n g , good d e t e r g e n c y Formula T-117 Carwash Shampoo-I1 y& Inaredient: Water 42.00 6.20 NaOH f50%) Add c a r e f u l l y , m i x w e l l DDBSA ( f r e e a c i d ) 23.80 D i s s o l v e we1 1 L a u r y l e t h e r s u l f a t e , Na s a l t (60%) 15.00 Add, m i x w e l l Tomah A0-728 Speci a1 3.00 Add, m i x w e l l 5.00 Tomah A m p h o t e r i c L Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 5.00 Add, m i x w e l l Recommended D i l u t i o n s : 1-3 o z . / g a l o r as n e c e s s a r y t h r o u g h a u t o system A p p l i c a t i o n s : Foam b r u s h , shampoo, b u c k e t wash N o t e s : Very h i g h f o a m i n g , good d e t e r g e n c y Formula T-117 S p r a y w a x - D r v i n q Anent I n a r e d ie n t : W B M i n e r a l Seal O i l 20.00 Tomah Emu1s i f ie r Four 15.00 Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 1 .oo Add, m i x w e l l Ethylene g l y c o l b u t y l ether 3.00 Add, m i x w e l l Water (70-9OF) 61 .OO Add s l o w l y t o above, m i x w e l l SpG 20/20F: 0 . 9 6 pH: 7.90 Recommended D i l u t i o n s : 1O:l t h e n i n j e c t 6 o z / c a r Appl ic a t i ons: D r y i ng A i d-Carwash N o t e s : F o r m u l a t i o n may need s l i g h t a d j u s t m e n t f o r s p e c i f i c MSO Formula T-106
SOURCE: Tomah P r o d u c t s ,
Inc.:
Suggested F o r m u l a t i o n s
Car and Truck Wash CompoundF
237
H i g h O i l S p l i t t i n g V e h i c l e Wash-A
co!vP~nen!s: Water Sodi um M e t a s i 1 ic a t e P e n t a h y d r a t e
% by Weiqht 71 . 5 10.0
2.5 6.0 10.0
TKPP
Sodi um X y l ene Sul f o n a t e s 40% B u r c o TME H i g h O i l S p l i t t i n g - V e h i c l e Wash-B
~~
Components: Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e Burco ADS-40 Sodi um X y l e n e Sul f o n a t e s 40% B u r c o TME
% by Weiqht 73.5 10.0
5.0 1.5 10.0
Add i n t h e o r d e r l i s t e d . B l e n d u n t i l d i s s o l v e d between each addition. ~Non-Phosphate
Component: Water 45% KOH Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) Sodi um X y l ene Sul f o n a t e s 40% B u r c o s p e r s e LP B u r c o TME Dodecyl benzene Sul f o n i c A c i d B u t y l Propasol D-Li monene
T r u c k Wash % by Weiqht 63.5 4.5
5.0 10.0
5.0 4.0
3.0 4.0 1 .o
Procedure: Add components i n t h e o r d e r l i s t e d . B l e n d u n t i l u n i f o r m between each a d d i t i o n .
SOURCE: B u r l in g t o n Chemical Con, I n c . : Suggested F o r m u l a t i o n s
238
Advanced Cleaning Product Formulations
L i q u i d Car Wash-Formula
A W% .t
18.0 8.0 3.0 2.0 69.0 Q.S. Q.S.
Rhodapon SB A l c o d e t SK T e t r a p o t a s s i u m Pyrophosphate Sodi um M e t a s i 1 i c a t e Water Perfume We L i q u i d Car Was -Formu
nB W% .t
18.0 Rhodapon SB Rhodasurf 25-9 8.0 Tetrapotassium Pyrophosphate 3.0 Sodi urn M e t a s i 1 i c a t e 2.0 69.0 Water Q.S. Perfume Q.S. Dye Procedure: D i s s o l v e T e t r a p o t a s s i u m P y r o p h o s p h a t e and sodium m e t a s i l i c a t e i n w a t e r . Add Rhodapon SB. A g i t a t e u n t i l c l e a r . Add A l c o d e t SK and Rhodasurf 25-9 and m i x u n t i l u n i f o r m and c l e a r . Add p e r f u m e and dye, as d e s i r e d . P h y s i c a l P r o p e r t i 8s: Appearance: C l e a r l i q u i d , dyed t o p r e f e r e n c e pH: 12.0 S p e c i f i c G r a v i t y : 1 .03 V i s c o s i t y : <50 c p s Formula TR-0020 Spray-On Car Wash C o n c e n t r a t e "Grease and Grime" Remover
Wt.% Rhodacal A-246/L 5.0 20.0 Rhodacal 330 Rhodapon BOS 3.3 5.0 A l c o d e t SK Water 66.7 Procedure: 1. Charge w a t e r t o a v e s s e l e q u i p p e d w i t h a g i t a t i o n . 2 . Add Rhodacal A-246/L and Rhodapon 00s t o ( 1 ) above. M i x u n t i l u n i f o r m (5-10 m i n u t e s ) . 3 . Add Rhodacal 330 and A l c o d e t SK t o ( 2 ) above. M i x u n t i l u n i f o r m (15-30 m i n u t e s ) . Physical Properties: Appearance: V i scous, g e l -1 i ke 1 iq u i d pH, as i s : 9 . 0 S p e c i f i c G r a v i t y : 1.02-1 . 0 4 V i s c o s i t y : t50 c p s Formula TR-0021
SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
Car and Truck Wash Compounds
239
L iqu id T r . u c k Wash Wt.2
Water M i r a n o l FBS I g e p a l CA-630 Dowanol EB P o t a s s i um H y d r o x i d e ( 4 5 % ) Tall O i l T e t r a p o t a s s i u m Pyrophosphate Sodium M e t a s i l i c a t e , P e n t a h y d r a t e
73.6 6.0 3.0 2.0 4.0 3.4 4.0 4.0
Procedure: Premix t h e T a l l O i l and B u t y l C e l l o s o l v e . Add t h e w a t e r t o t h e m i x e r . Add t h e Sodium M e t a s i l i c a t e , t h e P o t a s s i u m H y d r o x i d e and t h e T K P P . Add t h e M i r a n o l FBS and I g e p a l CA-630. Add t h e T a l l O i l / B u t y l C e l l o s o l v e premix. Mix u n t i l u n i f o r m . Physical Properties: Appearance: C 1 e a r , amber 1 iq u i d p H , as i s : 1 2 . 7 S p e c i f i c G r a v i t y : 1 .OB V i s c o s i t y : t 5 0 cps Formula TR-0029 Liquid
T r u c k Wash
Water M i r a n o l FBS Rhodafac RA-600 I g e p a l CA-720 Cheel ox BF-13 T e t r a p o t a s s i u m Pyrophosphate P o t a s s i um H y d r o x i d e (45%) Sodium M e t a s i l i c a t e P e n t a h y d r a t e A r c o s o l v PTB
Wt.% 63.0 4.0 2.0 2.0 17.5 1.o 6.0 2.0 2.5
Procedure: Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d and m i x u n t i l u n i f o r m . Physical Properties: Appearance: C l e a r , y e l l o w l i q u i d pH, a s i s : 1 2 . 9 S p e c i f i c G r a v i t y : 1.10 V i s c o s i t y : t 5 0 cps Formula TR-0030
SOURCE: Rhone-Poulenc:
Suggested F o r m u l a t i o n s
240
Advanced Cleaning Product Formulations
Non-Phosohate Truckwash Inaredient: Water KOH (45%) Add Na M e t a s i l i c a t e Pentahydrate D i ssolve Tomah A l k a l i S u r f a c t a n t o r Amphoteric 400 Add, mix w e l l Burcosperse LP Add, mix w e l l Burco TME Add, mix w e l l DDBSA ( f 1ake) Add, mix w e l l Dowanol PNB Add, mix w e l l d-1 imonene Add, mix w e l l
Wt%
64.50 4.50 5.00 9.00
5.00 4.00 3.00 4.00 1
.oo
pH: 13.60-13.66 Recommended D i l u t i o n s : 10-2O:l A p p l i c a t i o n s : Truckwash Formula T-104 S e l f Demul s i f y i nq Truckwash Inaredi ent : Water Na M e t a s i l i c a t e Pentahydrate D i s s o l ve KOH (45%) Add, mix w e l l EDTA o r NTA Dissolve Tomah AO-14-2 Add, mix w e l l Tomah P-17-2 Add, mix w e l l Tomah Tekstim 8741 Add, mix w e l l Tomah A1 k a l i S u r f a c t a n t Add, mix w e l l
Wt%
85.70 4.20 2.60 1.80
.oo 1 .oo 1
2.00 1.70
Recommended D i l u t i o n s : 10-25:l A p p l i c a t i o n s : Pressure Wash-Trucks Notes: Useful d e t e r g e n t which a1 so performs f ir s t " s p l i t " o f o i l / g r e a s e i n separators Formula 1-101
SOURCE:
Tomah Products, I n c . : Suggested Formulations
Car and Truck Wash Compounds
241
T r a n s p o r t a t i o n C1 e a n e r s Car Wash-Sol i d s ManualSTPP Sodi um m e t a s i 1 i c a t e anhydrous A n i o n i c (40% a c t i v e ) Nonionic Sodi um S u l f a t e
35-50% 6 20 4
balance
35-50% 15 10-15 balance
STPP Sodium m e t a s i l i c a t e anhydrous Nonionic Sodium S u l f a t e
_ Commercial _ H i g h P_erformance
75-80%
STPP Sodium m e t a s i l i c a t e anhydrous Noni o n i c
10 10-15
Car W a s h - L i q u i d - I
Q.S
Water TKPP (60% s o l u t i o n ) L i q u i d sodium s i l i c a t e Sodium x y l e n e s u l f o n a t e Nonionic*
15-20 4- 5 10-15 5
*C12-15 l i n e a r , p r i m a r y a l c o h o l e t h o x y l a t e o r e q u i v a l e n t , such as Neodol 25-9 (She1 1 )
.
Car W a s h - L i q u i d - I 1 Water ( d e i o n i z e d ) TKPP (60% s o l u t i o n ) L i q u i d p o t a s s i um s i 1 ic a t e Phosphate e s t e r Nonionic**
Q.S. 10-12 2- 3 0- 1
3- 4
**Modified ethoxylated s t r a i g h t chain alcohol o r equivalent, such as P l u f a f a c D-25 ( B A S F ) .
SOURCE:
FMC C o r p . : D e t e r g e n t A p p l i c a t i o n s B u l l e t i n No. 4 : Suggested F o r m u l a t i o n s
242
Advanced Cleaning Product Formulations
T r a n s p o r t a t i o n Cleaners T r a f f i c F i l m Remover I n a r e d ient : Wt% 82.00 Water Sodium M e t a s i l i c a t e . anhydrous 1 .oo D i s s o l ve EDTA or NTA 10.00 Add, mix w e l l Tomah AO-14-2 2.00 Add, mix w e l l Tomah (2-17-2 2.00 Add, mix w e l l Nonionic Surfactant-HLB 13 3.00 Add, mix w e l l Recommended D i l u t i o n s : 10-25:l A p p l i c a t i o n s : Truckwash, t r a f f i c f i l m remover Notes: Has technology t h a t " r e l e a s e s " s o i l from s u r f a c e Formula T-107 Viscous W i r e Wheel Cleaner Wt% I n q r e d ie n t : Water 71 . O O Phosphoric Aci d (75%) 22.00 Add, mix, c o o l Oxalic Acid 1 .oo D i s s o l ve Tomah A c i d Thickener* 3.00 Add, mix w e l l S a l t (NaC1) 3.00 Add, d i s s o l v e w i t h m i x i n g V i s c o s i t y ( c p s ) : 693 Recommended D i l u t i o n s : 10-2O:l A p p l i c a t i o n s : Metal c l e a n i n g , v e r t i c a l s u r f a c e c l e a n i n g , descal ing Notes: *Mix A c i d Thickener p r i o r to use i n o r d e r t o assure homogeneity. Rinse w e l l a f t e r use. Formula T-112 G l ass Cleaner I n a r e d ie n t : Deionized Water I P A (99%) Add, mix w e l l Tomah Amphoteric N Add, mix w e l l Propylene g l y c o l n - b u t y l e t h e r Add, mix w e l l Dye/perfume o p t i o n a l Recommended D i 1u t i ons : a s - i s A p p l i c a t i o n s : a u t o / t r u c k w i n d s h i e l d wiper f l u i d Notes: D r i e s q u i c k l y , wipes c l e a n , non s t r e a k i n g Formula T-113
SOURCE: Tomah Products,
I n c . : Suggested Formulations
Wt% 69.70
25.00 0.30 5.00
Car and Truck Wash Compounds
243
T r u c k Wash D e t e r s e n t F o r m u l a t i o n - I 32% 10% 10% 8%
Sodium m e t a s i l i c a t e - 5 H 2 0 TSP c r y s t a l s 40% a c t i v e a n i o n i c s u r f a c t a n t Nonionic s u r f a c t a n t T r u c k Wash D e t e r q e n t F o r m u l a t i o n - I 1
21% 6.6% 33.5% 6.6% 5.3%
Sodium m e t a s i l i c a t e - 5 H 2 0 TSP c r y s t a l s Sodium s u l f a t e 90% a c t i v e a n i o n i c s u r f a c t a n t Noni o n i c s u r f a c t a n t A1 umi num T r u c k Body C l e a n e r / B r i g h t e n e r - I P h o s p h o r i c A c i d (85%) Nonionic NaHF2 Water
35-40% 5-10 1- 2 balance
Aluminum T r u c k Body C l e a n e r / B r i g h t e n e r - I 1 P h o s p h o r i c A c i d (85%) Noni o n i c H y d r o f l u o r i c a c i d (48%) Water
10% 4 15 balance
A l u m i n u m T r u c k Body C l e a n e r / B r i q h t e n e r - I 1 1
47.2% 2 16.0 34.0
P h o s p h o r i c A c i d (85%) Noni o n i c Butoxyethanol Water
SOURCE:
FMC C o r p . : D e t e r g e n t A p p l i c a t i o n s B u l l e t i n No Suggested F o r m u l a t i o n s
4:
244
Advanced Cleaning Product Formulations Truck Wash L i a u i d
Wt.% I g e p a l CO-630 Rhodapex CO-436 A1 kami de OC-212/S Cheel ox BF-13 Ethylene G1y c o l Monobutyl Ether Water
3.0 3.5 2.0 3.5 3.0 85.0
Procedure: 1. D i s s o l v e s u r f a c t a n t s I g e p a l CO-630, Rhodapex CO-436 and A1 kami de DC-212/S in water. 2. Add Cheelox BF-13. Mix w e l l . 3. Add Ethylene G l y c o l Monobutyl E t h e r . Physical P r o p e r t i e s : pH (as i s ) : 9 . 9 pH (1%): 9.6 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.01 Formula TR-0025 Economy Truck Wash High-pressure S w a y W% .t 3.0 1.o 1.5 84.5
I g e p a l CO-660 Cheel ox BF-13 Sodium Xylene S u l f o n a t e Water Procedure: 1. D i s s o l v e Sodium Xylene S u l f o n a t e i n water. 2 . Add I g e p a l CO-660. M i x t h o r o u g h l y . Add Cheelox BF 13. Physical P r o p e r t i 8s: pH ( a s i s ) : 10.3 pH (1%): 10.1 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1 .02 Formula TR-0024
SOURCE:
Rhone-Poulenc:
Suggested Formulations
17. Whitewall Tire Cleaners
245
246
Advanced Cleaning Product Formulations
Whitewall T i r e Cleaner I
Wt%
Inqredi ent : S o f t Water Na m e t a s i l i c a t e p e n t a h y d r a t e D i s s o l v e , mix w e l l KOH (45%) Add, m i x w e l l Diethylene glycol b u t y l ether Add, m i x w e l l Noni o n i c HLB-13 Add, m i x w e l l Tomah Q-17-2 Add, mix w e l l
81 .oo 4.00 2.00 6.00 5.00
2.00
SpG 20/20C: 1.039 pH: 1 2 . 9 Recommended D i l u t i o n s : a s - i s A p p l i c a t i o n s : Rinse t i r e f i r s t ,
app y ,
t h e n r i n s e aga n
W h i t e w a l l T i r e Cleaner-I1
Inaredient: S o f t Water Na m e t a s i l i c a t e p e n t a h y d r a t e D i s s o l v e , mix w e l l STPP D i s s o l v e , mix w e l l Diethylene glycol b u t y l ether Add, m i x w e l l N o n i o n i c HLB-13 Add, m i x w e l l Tomah Q-17-2 Add, m i x w e l l
W B 79.00 4.00
2.00 6.00 5.00 2.00
SpG 20/20C: 1.039 DH: 1 3 . 0 Recommended D i 1u t i ons : a s - i s A p p l i c a t i o n s : Rinse t i r e f i r s t ,
SOURCE: Tomah P r o d u c t s ,
Inc.:
apply, then r i n s e again
Formula S-110
Wtitewall Tire Cleaners
Wh-ewall
247
T i r e Cleaner-I
STPP TSPP
TSP c r y s t a l s L i q u i d sodium s i l i c a t e Anionic Nonionic
30 25 14 16
10 5
Whitewal-1 T i r e C l e a n e r - I 1 STPP TSPP TSP C r y s t a l s Sodium m e t a s i l i c a t e , Ani o n i c Nonionic
anhydrous
L i sui d W h i t e w a l 1 T i r e C l eaner-Tvpe I C o n c e n t r a t i o n i n Order o f A d d i t i o n : M a t e r i a1 : Dei o n i zed w a t e r TKPP (60% s o l u t i o n ) TSP C r y s t a l s Potassium s i l i c a t e ( K a s i l #6) Sodium x y l e n e s u l f o n a t e (40% s o l u t i o n ) Neodol 25-9 B u t y l c e l l o s o l v e ( E t h y l e n e G l y c o l Mono B u t y l E t h e r ) I L i q u i d W h i t e w a l 1 T i r e C l eaner-Type I C o n c e n t r a t i o n i n Order o f A d d i t i o n : M a t e r i a1 : Deionized water TKPP (60% s o l u t i o n ) TSP C r y s t a l s P o t a s s i um s i 1 ic a t e ( K a s i 1 # 6 ) P r e b l e n d and add as a u n i t : Sodium x y l e n e s u l f o n a t e (40% s o l u t i o n ) B u t y l C e l l o s o l v e ( E t h y l e n e G l y c o l Mono B u t y l E t h e r ) S u l f r a m i n 60 SOURCE: FMC Corp. : D e t e r g e n t A p p l i c a t i o n s B u l l e t i n No.4: Suggested F o r m u l a t i o n s
30 25 10 20 10 5
60.5% 8.0 7.0 4.0 11.4 4.5
4.6
58.3% 10.0 7.0 4.5 6.5 4.0 9.7
248
Advanced Cleaning Product Formulations
W h i t e w a l 1 T i r e C1e a n e r L i m d W %.t I g e p a l CA-630 Rhodaf ac RA-600 M-Pyrol N - M e t h y l - 2 - P y r r o l i d o n e Sodium M e t a s i l i c a t e , Anhydrous Sodi urn T r i p o l yphosphate P o t a s s i um H y d r o x i d e Water
2.0 6.0 2.0 3.0 5.0 1.5 80.5
Procedure: 1 . D i s s o l v e Sodium M e t a s i l i c a t e , Anhydrous, Sodium T r i p o l y p h o s p h a t e and Potassium H y d r o x i d e i n t o w a t e r . 2. Add I g e p a l CA-630, Rhodafac RA-600, and M-Pyrol s e p a r a t e l y , m i x i n g w e l l a f t e r each a d d i t i o n . P h y s i c a l P r o p e r t i es : pH ( a s i s ) : 1 3 . 3 pH ( 1 % ) : 10.7 V i s c o s i t y : 10 c p s S p e c i f i c Gravity: 1.03 Formula TR-0027 W h i t e w a l l T i r e Cleaner Concentrate
Wt.% Water M i r a n o l FBS Sodium M e t a s i l i c a t e , P e n t a h y d r a t e Potassium H y d r o x i d e (45%) Butoxyethanol Procedure: Add i n g r e d i e n t s i n o r d e r l i s t e d . M i x u n t i l u n i f o r m . Physical Properties: Appearance: C1 e a r , ye1 1ow 1 iq u i d pH, as i s : 1 2 . 7 V i s c o s i t y : (50 cps Speci f i c G r a v i t y : 1 .16 Formula TR-0031
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
48.0 22.0 25.0 3.0 2.0
Whitewall Tire Cleaners
WW l i r e C l e a n e r 1 Ineredient: Water STPP D i s s o l ve KOH (45%) Add, m i x w e l l 42 Sodium S i l i c a t e 3 . 2 2 / 1 Add, mix w e l l Tomah A l k a l i S u r f a c t a n t Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l SpG 20/20F: 1 . 1 5 pH: 13.00 Recommended D i l u t i o n s : 5 - 1 O : l A p p l i c a t i o n s : Carwash Notes: White w a l l t i r e c l e a n e r Formula T-100 W h i t e w a l l T i r e Cleaner 2 (Non-Caustic1 Innredient: Water Na M e t a s i l i c a t e P e n t a h y d r a t e D i s s o l ve N o n i o n i c S u r f a c t a n t - H L B 13 Add-Mix we1 1 Tomah A l k a l i S u r f a c t a n t Add-Mix w e l l SpG 20/20F: 1 . 1 6 pH: 12.80 Recommended D i 1u t i ons : 5-20 : 1 A p p l i c a t i o n s : Carwash WW t i r e p r e s p r a y N o t e s : Non c a u s t i c , e f f e c t i v e WW c l e a n e r Formula T - I 0 3 Whitewall l i r e Cleaner 3 Innredient: S o f t Water l r i s o d i um Phosphate Dissolve Na M e t a s i l i c a t e P e n t a h y d r a t e D i s s o l ve Tomah A l k a l i S u r f a c t a n t Add, m i x w e l l N o n i o n i c S u r f a c t a n t - H L B 13 Add, m i x w e l l pH: 1 3 . 4 4 Recommended D i l u t i o n s : 5-1O:l A p p l i c a t i o n s : Carwash Formula T-1 11
SOURCE: Tomah P r o d u c t s ,
Inc.:
Suggested F o r m u l a t i o n s
249
@ 67.40 5.00
15.60 8.00 2.00 2.00
Wt% 70.00 25.00 2.00 3.00
W S
79.60 11.60
5.00 2.50 1.30
18. Miscellaneous
250
Miscellaneous
251
B r a k e C1e a n e r 65 5 5 5 5 15
Water Burco NPS-816 Burco TME B u r c o SXS-40% B u t y l Propasol B u r c o s p e r s e AP L i q u i d
I f d e s i r e d , can be made more a l k a l i n e - add s m a l l p e r c e n t a g e o f sodium m e t a s i l i c a t e , a d j u s t l e v e l o f X S r e q u i r e d t o h y d r o trope Maq Wheel C l e a n e r % by Wei-
Water KOH 45% B u r c o f a c 9125 Burco TME Sodium M e t a s i l i c a t e , STPP Burco BSGH-270 *Dequest 2066
*
74.55 2.45 4.0 5.0 2.0 2.0 5.0 5.0
pentahydrate
From Monsanto o r use e q u i v a l e n t
Procedure: Add components i n o r d e r l i s t e d . S t i r u n t i l h mogen ous betwe n each a d d i t i o n . Note: T o t h i c k e n , add s m a l l q u a n t i t i e s o f Sodium S t e a r a t e t o o b t a i n desi red v i scosi t y . C o n c r e t e F l o o r C1 eaner % by Weiqht
ComponenWater TSP C r y s t a l sxs-40% B u r c o t e r g e DG-40 B u t y l Propasol M i n e r a l Spi r i t s
51 .O 7.5 6.5 25.0 5.0 5.0
Procedure: Add components i n t h e o r d e r l i s t e d . S t i r u n t i l homogeneous between each a d d i t i o n . T h i s f o r m u l a t i o n p r o v i d e s e x c e l l e n t removal o f o i l s t a i n s , d i r t and o t h e r s o i l s . F o r heavy d u t y a p p l i c a t i o n s a p p l y as i s Some " s c r u b b i n g " w i 11 a s s i s t o i 1 r e m o v a l . R i n s e w i t h w a t e r . L i g h t e r d u t y a p p l i c a t i o n s can use an aqueous d i l u t i o n o f t h e concentrate. Source: B u r l i n g t o n Chemical Co.,
Inc.:
Suggested F o r m u l a t i o n s
252
Advanced Cleaning Product Formulations
L i q u i d Aluminum E n a i n e B l o c k C l e a n e r
Wt.% Water Sodium M e t a s i l i c a t e , M i r a n o l FBS M i r a n o l JEM Conc. A l c o d e t HSC-1000 D-Li monene
Anh.
82.5 4.5 5.0 2.0 4.0 2.0
Procedure: C o m p l e t e l y d i s s o l v e t h e Sodium M e t a s i l i c a t e i n t h e w a t e r . Add t h e r e m a i n i n g components, w i t h a g i t a t i o n , i n t h e o r d e r l i s t e d . Premix t h e D-Limonene w i t h t h e A l c o d e t HSC-1000 and add t o g e t h e r . T y p i c a l P r o p e r t i es : Appearance: C l e a r , y e l l o w t o amber l i q u i d pH, Conc.: 12.75 pH, 10%: 12.15 S p e c i f i c G r a v i t y : 1.04 V i s c o s i t y : <50 cps Formula TR-0032 Foami ng E n g i n e C1eaner
Wt.% 2.0
A l c o d e t 260 Rhodacal 330 Water Isopar " K "
8.0 80.0 10.0
Procedure: 1 . Add A l c o d e t 260 and Rhodacal 330 t o w a t e r a t ambient tempera t u r e , s t i r u n t i l d i s s o l v e d (10-15 m i n u t e s ) . 2. Add I s o p a r K a t ambient t e m p e r a t u r e . S t i r u n t i l d i s s o l v e d (30 m i nutes) . Physical Properties: Appearance: C l e a r l i q u i d pH, as i s : 7 . 5 Speci f ic G r a v i t y : 0 . 9 9 V i s c o s i t y : 10 cps Formul a t i on TR-0019
SOURCE:
Rhone-Poulenc:
Suggested F o r m u l a t i o n s
Miscellaneous
253
L i g u i d Boat P o l i s h % b y Weight Ingredient. Part A: 3.50 ( 1 ) SF-96 ( 3 5 0 ) 1.oo ( 2 ) V i s c a s i l 10,000 1.50 (3) Oleic Acid 10.00 (4) Isopar M 1.50 ( 5 ) H o e c h s t Wax E P a r t B: 65.65 ( 6 ) D e i o n i z e d Water 7.50 ( 7 ) K a o p o l i t e 1168 2.50 ( 8 ) K a o p o l i t e SF 1 .60 ( 9 ) M o r p h o l i ne 0.25 ( 1 0 ) C a r b o p o l 934 3.00 (11)Isopar M 2.00 ( 1 2 ) SF- 1 706 Procedure: Add ( 7 ) and ( 8 ) t o 6 ) ( P a r t B ) w i t h s t r o n g a g i t a t i o n u n t i l smooth, w h i l e h e a t i n g o 150F. C o n t i n u i n g a g i t a t i o n and maint a i n i n g t e m p e r a t u r e , s o w l y add ( 9 ) and ( l o ) , and s t i r a c t i v e l y u n t i l f r e e from coarse agglomerates. I n a n o t h e r v e s s e l , h e a t ( l ) , ( 2 ) , ( 3 ) , ( 4 ) , and ( 5 ) ( P a r t A) t o 150F and b l e n d t h o r o u g h l y . Add t o P a r t B m i x t u r e , m a i n t a i n 150F and m i x w e l l . S t i r ( 1 1 ) and ( 1 2 ) , h e a t t o 150F, and add t o t h e m i x t u r e . Continue moderate a g i t a t i o n w h i l e c o o l i n g t o f i l l i n g temperature. Paste Boat P o l i s h I n g r e d i e_n=; K b r ~weisht P a r t A: ( 1 ) SF-96 ( 3 5 ) 4.50 ( 2 ) V i s c a s i l 10,000 2.00 5.00 ( 3 ) H o e c h s t Wax S ( 4 ) H o e c h s t Wax OP 1 .oo (5) Stearic Acid 1.oo (6) Isopar M 24.00 Part 0: ( 7 ) D e i o n i z e d Water 44.80 ( 8 ) M o r p h o l in e 0.70 ( 9 ) K a o p o l i t e 1168 10.00 P a r t C: (10)Isopar M 5.00 ( 1 1 )SF-1 706 2.00 Procedure: ( P a r t A ) Combine ( 1 ) t h r o u g h ( 6 ) a n d h e a t t o 210F w i t h a g i t a t i o n . Provide i n t e n s i v e a g i t a t i o n w h i l e i n t r o d u c i n g t h e remaini ng in g r e d i e n t s . ( P a r t 8) S l o w l y add ( 9 ) i n t o ( 7 ) w i t h a g i t a t i o n , t h e n add ( 8 ) and h e a t t o 150F. S l o w l y add P a r t B t o P a r t A w i t h i n t e n s i v e a g i t a t i o n . Allow t i m e f o r thorough i n c o r p o r a t i o n . ( P a r t C ) I n a s e p a r a t e c o n t a i n e r , m i x ( 1 0 ) and ( 1 1 ) and h e a t t o 1 5 0 F . S l o w a g i t a t i o n on m i x t u r e ( P a r t A + P a r t B ) , add P a r t C t o m i x t u r e , and c o n t i n u e s t i r r i n g u n t i l m i x t u r e c o o l s t o p a c k a g i n g t e m p e r a t u r e o f 105-12OF. SOURCE: K a o p o l i t e , I n c . : S u g g e s t e d F o r m u l a t i o n s
254
Advanced Cleaning Product Formulations
Locomotive Cleaner I I n q r e d ie n t : W B Water 71 . O O Phosphoric A c i d (75%) 22.00 Add, mix, cool Oxalic Acid 1 .oo Dissolve Tomah A c i d Thickener 3.00 Add, mix w e l l S a l t (NaC1) 3.00 Dissolve w i t h mixing V i s c o s i t y ( c p s ) : 693 Recommended D i l u t i o n s : 0-10: 1 A p p l i c a t i o n s : Metal c l e a n i n e , r u s t removal, d e s c a l i n pNotes: Mix A c i d Thickener p r i o r t o use i n o r d e r t o assure homogenei t y Locomoti ve Cleaner I I I n s r e d ient : W B Water 72.00 Phosphoric A c i d (75%) 22.00 Add, mix, c o o l Oxalic Acid 1 .oo D i s s o l ve Tomah A c i d Thickener 2.00 Add, mix w e l l S a l t (NaC1) 3.00 Dissolve w i t h mixing V i s c o s i t y ( c p s ) : 112 Recommended D i l u t i o n s : 0-1O:l A p p l i c a t i o n s : Metal c l e a n i n g , r u s t remova , descal ng Notes: Mix A c i d Thickener p r i o r t o use i n o r d e r t o assure homogenei t y Locomotive Cleaner I11 I n p r e d ie n t : Wt% Water 71 .OO Phosphoric A c i d (75%) 21 .oo Add, mix, cool Oxal i c A c i d 1 .oo D i s s o l ve Tomah A c i d Thickener 2.00 Add, mix w e l l S a l t (NaC1) 5.00 Dissolve w i t h mixing V i s c o s i t y (cps) : 2275 Recommended D i l u t i o n s : 0-1O:l A p p l i c a t i o n s : Metal c l e a n i n g , r u s t remova , descal ng Notes: Mix A c i d Thickener p r i o r t o use i n o r d e r t o assure hmogenei t y
SOURCE: Tomah Products, I n c . : Formula T-114
Miscellaneous
255
P o l i s h i n n C l e a n e r f o r P l a s t i c Windows Ingredients: ( 1 ) D e i o n i z e d Water ( 2 ) T e t r a s o d i u m Pyrophosphate ( 3 ) Potassium T r i p o l y p h o s p h a t e ( 4 ) K a o p o l i t e SF o r 1168 ( 5 ) Stepanate X (6) Synthrapol N
4.0 2.5 12.5 5.0 12.5
Procedure: D i s s o l v e ( 2 ) and ( 3 ) i n ( 1 ) . Add ( 4 ) s l o w l y w i t h v i g o r o u s a g i t a t i o n , c o n t i n u i n g u n t i l w e l l - d i s p e r s e d and smooth. Reduce a g i t a t i o n t o a v o i d foaming, s t i r i n ( 5 ) and ( 6 ) . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t u s e d . Comments: Use o f K a o p o l i t e 1168 g i v e s more a g g r e s s i v e c l e a n i n g and polishing action t o the formulation. H a r d - s u r f a c e Cleaner/Wax _(May Be A e r o s o l Loaded) Inqredients: ( 1 ) A r l a c e l 85 ( 2 ) Hoechst Wax E ( 3 ) Dow C o r n i n g 200 F l u i d , 350 c e n t i s t o k e s ( 4 ) Odorless M i neral S p i r i t s ( 5 ) K a o p o l i t e SF ( 6 ) D e i o n i z e d Water
% by Weight
1.o
1. o 4.0 34.0 13.0 47.0
Procedure: D i s s o l v e ( l ) , ( 2 ) , and ( 3 ) i n ( 4 ) w i t h moderate s t i r r i n g w h i l e h e a t i n g t o 175-18OF. Add ( 5 ) s l o w l y , s t i r r i n g v i g o r o u s l y u n t i l we1 1- d i s p e r s e d and smooth. Heat ( 6 ) i n s e p a r a t e v e s s e l t o 175-180F, and add s l o w l y t o above m i x t u r e w i t h moderate s t i r r i n g . Shut o f f h e a t , b u t c o n t i n u e moderate s t i r r i n g u n t i l p r o d u c t c o o l s t o 9OF o r b e l o w . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t u s e d . Good i n d u s t r i a l p r a c t i c e s s h o u l d be used when h a n d l i n g flammable i n g r e d i e n t s .
SOURCE: K a o p o l i t e ,
Inc.:
Suggested F o r m u l a t i o n s
Section 111 Trademarked Raw Materials
256
Trademarked Raw Materials
RAW MATERIAL
257
CHEMICAL DESCRIPTION Sodium s i l i c a t e
SOURCE
A 2447
A c i d Foamer
Cationic surfactant
Tomah
PQ
A c r i tamer 940 A c r i t a m e r 941 Acryso
ASE 108
A c r y l i c polymer t h i c k e n e r
Rohm&
Acryso
644
A c r y l i c polymer t h i c k e n e r
Rohm&
Actino
FA-3
Tall o i l f a t t y acid
A r i zon
Acusol 445
Detergent polymer
Rohm&
Acusol
Detergent polymer
Rohm&
Acusol 810
D e t e r g e n t polymer
Rohm&
A c u s o l 820
Detergent polymer
Rohm&
A e r o s i l 200
Silica
Deguss
A 1 c o d e t HSC-1000
E t h o x y l a t e d mercaptan
Rhone
A1 c o d e t MC-2000
E t h o x y l a t e d mercaptan
Rhone
A l c o d e t SK
E t h o x y l a t e d mercaptan
Rhone
A l c o d e t 260
E t h o x y l a t e d mercaptan
Rhone
A1 kami de DC-2 12/M
Noni o n i c ami de s u r f a c t a n t . 2 : 1 a1 k a n o l ami de
Rhone
A1 kami de DC-212/S
N o n i o n i c amide s u r f a c t a n t . 1:1 diethanolamide.
Rhone
A1 r o s p e r s e
Solvent soluble surfactant
Pai s-
Amphotensid 0 4
Amphoteric s u r f a c t a n t
Zshcim
A n t a r o x BL-225
N o n i o n i c . Capped e t h o x y l a t e .
Rhone
A n t a r o x BL-240
N o n i o n i c . Capped e t h o x y l a t e .
Rhone
A n t a r o x BL-330
N o n i o n i c . Capped e t h o x y l a t e .
Rhone
A n t a r o x L-61
Nonionic.
Rhone
505N
Poloxamer 181.
258
Advanced Cleaning Product Formulations
RAW MATERIAL Arcosolv PTB
CHEMICAL DESCRIPTION Sol v e n t
SOURCE Arco
Arlacel C
Surfactant
ICI
A r l a c e l 85
Surfactant
ICI
A r l a c e l 186
G l y c e r y l o l e a t e (and) propylene glycol surfactant
ICI
Armac-HT
A1 ip h a t i c ami ne a c e t a t e
Akzo
Avanel S-70
Sodium l i n e a r a1 k y l p o l y e t h e r
PPG
Avanel S-74
Anionic su r fa ctant
PPG
Bentone 34
Ge 1 i n g 8 suspend ng agent
Rheox
Bentone 38
Ge 1 i n g 8 suspend ng agent
Rheox
Be Square, White 190/195 Wax
Petrol
B i l t p l a t e s 156
Suspending agent
Vander
B i o - S o f t 5-100
Alkylbenrene s u l f o n i c a c i d ,
Bio-Terge PAS-8S
Sodi um 1-octane s u l f o n a t e
Stepan
B r i j 30
Surfactant
ICI
l i n e a r Stepan
B r i t e s i l C24 Hydrous Sodium P o l y s i l i c a t e
PO
B r i t e s i 1 H20 Hydrous Sodi um P o l y s i 1ic a t e
PQ
Burcene 100
Burli n
Burco ADS-40
P r o p r i e t a r y T e x t i 1e Auxi 1ia r y
Burli n
Burco BSGH-270 P r o p r i e t a r y T e x t i l e A u x i l i a r y
B u r l in
Burco BSGH-400 P r o p r i e t a r y T e x t i l e A u x i l i a r y
Burli n
Burco EHS P r o p r i e t a r y T e x t i 1e Auxi 1ia r y
Burli n
Burcofac 9125
Burli n
Trademarked Raw Materials
259
RAW MATERIALS CHEMICAL DESCRIPTION B u r c o FAE P r o p r i e t a r y T e x t i l e A u x i l i a r y
SOURCE Burl i n
B u r c o HCS-5ONF P r o p r i e t a r y T e x t i l e A u x i l i a r y
Burlin
B u r c o LAA-38 P r o p r i e t a r y T e x t i l e A u x i 1 i a r y
Burl i n
B u r c o LAF-6 P r o p r i e t a r y T e x t i l e A u x i l i a r y
Burlin
B u r c o LAF-125 P r o p r i e t a r y T e x t i l e A u x i 1 ia r y
Burlin
B u r c o NCS 50% P r o p r i e t a r y T e x t i l e A u x i l i a r y
Burl i n
B u r c o NPS-216 P r o p r i e t a r y T e x t i l e A u x i l i a r y
Burl i n
B u r c o NPS-225 P r o p r e t a r y T e x t i l e A u x i l i a r y
Burl i n
B u r c o s o l v TM
Water s o l u b l e s o l v e n t m i x t u r e
B u r l in
B u r c o s p e r s e AP L i q u d
Sodi um p o l y a c r y l a t e s o l u t i on
Burl i n
B u r c o s p e r s e LP
Sodium p o l y a c r y l a t e s o l u t i o n
Burl i n
B u r c o SXS-40% P r o p r i e t a r y T e x t i l e A u x i l i a r y
Burl i n
B u r c o t a s e SL-80
Burlin
B u r c o t e r g e DG-40
P r o p r i e t a r y D e t e r g e n t Enzyme Detergent concentrate
B u r l in
B u r c o TME P r o p r i e t a r y T e x t i l e A u x i 1 ia r y
Burl i n
B u r c o w e t TM-LF P r o p r i e t a r y T e x t i l e Auxi 1 ia r y
B u r l in
Butyl Carbi t o 1
I n d u s t r i a1 s o l v e n t
UnCarb
Butyl C e l l osol ve
E t h y l e n e g y c o l monobutyl e t h e r
UnCarb
B u t y l Propasol
Industrial solvent
UnCarb
C-340
Carnuaba wax emu1 s i o n
Tomah
Calamide C
Coconut d e r i v e d ami de
Pi l o t
C a l foam EA-603
L iqui d detergent
Pi l o t
C a l o x y l a t e N-9
Pilot
260
Advanced Cleaning product Formulations
RAW MATERIAL C a l s o f t L-40
CHEMICAL DESCRIPTION Sodi um d o d e c y l benzene s u l f o n a t e
SOURCE Pil o t
Cal s o f t LAS-99
L i n e a r a1 k y l a t e s u l f o n a t e
Pil o t
C a l s o f t F-90
Linear a l k y l a t e sulfonate
Pilot
Carbi t o 1
Solvent
UnCarb
Carbopol ETD-2001 R e s i n T h i c k e n i n g agent
BFGood
Carbopol ETD-2691 R e s i n T h i c k e n i n g agent
BFGood
Carbopol 672 R e s i n
T h i c k e n i n g agent
BFGood
Carbopol 674 R e s i n
T h i c k e n i n g agent
BFGood
Carbopol 934 R e s i n
T h i c k e n i ng a g e n t
BFGood
Carbopol 2201 R e s i n
T h i c k e n i n g agent
BFGood
Carbowax PEG 8000
Polyethylene g l y c o l
UnCarb
CDB C l e a r o n
C h l o r i n a t e d is o c y a n u r a t e
Olin
CDB 90
Chlorinated isocyanurate
01 i n
Cheelox BF-Aci d
Chel a t i ng a g e n t
Rhone
Cheelox BF-13
Chel a t i ng a g e n t
Rhone
Cheel ox NTA-Na3
Chel a t i ng a g e n t
Rhone
C i t r u s X004.950
Perfume
Quest
C1 e a r l an
Lanol i n
Henkel
CMC-7M8S
Sodium c a r b o x y m e t h y l c e l l u l o s e
Aqua1 o
C o l l o i d 60
Polymeric d i spersant
Rhone
Col 1o i d 581 -B
Polymeric d i s p e r s a n t
Rhone
Concord CO Wax
Wax. MP: 184F.
Concor
Trademarked Raw Materials
261
RAW M A T E R I A L Dowanol DPnB
CHEMICAL D E S C R I P T I O N Glycol ether
SOURCE Dow
Dowanol EB
Ethylene g l y c o l n-butyl
ether
Dow
Dowanol PM
Propylene g l y c o l methyl e t h e r
Dow
Dowanol PnB
Glycol ether
Dow
Dow C o r n i n g C-2-0563
S i 1 icone
DowCor
Dow C o r n i n g HV-490
S i 1 icone emul s i on
DowCor
Dow C o r n i n g Q2-3225C
S i 1icone
DowCor
Dow C o r n i n g 24 E m u l s i o n P o l y d i m e t h y l c y c l o s i l o x a n e
DowCor
Dow C o r n i n g 193
Silicone surfactant
DowCor
Dow C o r n i n g 200 F l u i d
A m i n o f u n c t i o n a l s i 1 icone
DowCor
Dow C o r n i n g 347
S i 1 icone emul s i on
DowCor
Dow C o r n i n g 531 F l u d
Silicone f l u i d
DowCor
Dow C o r n i n g 536 F l u d
Silicone f l u i d
DowCor
Dow C o r n i n g 929
S i l i c o n e c a t i o n i c emulsion
DowCor
A1 k y l a t e d d i p h e n y l o x i d e d i sul fonate
DowCor
Dowfax 382
Surfactant
Dow
Dowicide A
Sodi um o - p h e n y l p h e n a t e
Dow
D r a k e o l 2251
Surfactant
Penrec
Dresinate TX
R o s i n soap
Hercul
D r e s i n a t e XX
R o s i n soap
Hercul
Dowfax 2A-1
(45%)
D Sodium S i 1 i c a t e
PQ
Duomeen TDO
Akzo
Duponol C D u r a p l u s 2 Polymer
S u r f a c e a c t i v e agent
DuPont Rohm&
262
Advanced Cleaning I3.oduct Formulations
RAW MATERIALS E k t a s o l v e DE S o l v e n t
CHEMICAL DESCRIPTION
E k t a s o l v e DM S o l v e n t
SOURCE Eastma Eastma
Emcol 14
S u r f a c e - a c t i v e agent
Witco
Epolene E-10
S y n t h e t ic wax
Eastma
Epolene E-20
S y n t h e t i c wax
Eastma
Epolene E-43
S y n t h e t i c wax
Eastma
E s i -Cry1 20/20
Emulsion polymer
Emul s i
E s i - F l e x 802
L e v e l ing r e s i n
Emul s i
Ethomeen C-25
E t h o x y l a t e d a l i p h a t i c amine
Akzo
E u p e r l a n PK-771
P e a r l iz e r
Exxon I s o p a r G
I s o p a r a f f i n solvent
Faxam No.
40
Paraffin o i l
Faxam No. 45
Paraffin o i l
F e r r o s i l 14
F e r r o aluminum s u l f a t e
Kaopol
F l u o r a d FC-120
F1uorochemi c a l s u r f a c t a n t
3M
F1u o r a d FC-129
Fluorochemical s u r f a c t a n t
3M
Exxon
FMB-210-15 Quat (50%)
Huntin
G Sodi um S i 1i c a t e
PQ
Gafac RE-610
Anionic surfactant
G a n t r e z AN-149
Vinyl ethyl-maleic copolymer
G e l w h i t e GP
W h i t e montmori 1l o n i t e
ECC
Genagen LAB
C12C14 a l k y l d i m e t h y l b e t a i n e
Hoechs
Genapol UD030
C11 0x0 a l c o h o l e t h o x y l a t e w i t h 3 moles EO
Hoechs
Rhone anhydride
GAF
Trademarked Raw Materials
263
RAW MATERIALS Genapol UD 050
CHEMICAL DESCRIPTION C11 0x0 a l c o h o l e t h o x y l a t e w i t h 5 moles EO. N o n i o n i c .
SOURCE
Genapol UD 079
C11 0x0 a l c o h o l e t h o x y l a t e w i t h 7 moles EO. N o n i o n i c .
Hoechs
Genapol ZRO L i q u i d
A l k y l t r i g l y c o l ether s u l f a t e soln
Hoechs
Genapol 26-L-2
C12C16 a l c o h o l e t h o x y l a t e w i t h 2 moles EO. N o n i o n i c
Hoechs
Genapol 26-L-5
C12C16 a l c o h o l e t h o x y l a t e w i t h 5 moles EO. N o n i o n i c .
Hoechs
Genapol 26-L-60
C12C16 a l c o h o l e t h o x y l a t e w i t h c l o u d p o i n t o f 60C
Hoechs
Genapol 26-L-75
C12C16 a l c o h o l e t h o x y l a t e w i t h c l o u d p o i n t o f 75C
Hoechs
G e o r g i a M a r b l e W h i t e #8 C a l c i u m c a r b o n a t e ,
40-80 m i c r o n
Hoechs
GeoMa r
Germaben I 1
Cosmetic p r e s e r v a t i v e
Sutton
Germaben I I E
Cosmetic p r e s e r v a t i v e
Sutton
G1 ucopon AV-110
Surfactant concentrate
Henkel
G l ucopon LD-15
Surfactant concentrate
Henkel
Geropon WT-27
Glucopon 60 CSUP
Henkel
Glucopon 425 CS
A l k y l p o l y g l y c o s i d e (C8-C16),50%
Henkel
Glucopon 600 CSUP
A l k y l p o l y g l y c o s i d e (C12-C16),50%
Henkel
Glucopon 625 CSUP
A1 k y l p o l y g l y c o s i de (C12-C16), 50%
Henkel
G r i 11o c i n HY-77
Odor remover
RITA
264
Advanced Cleaning Product Formulations
RAW MATERIAL Herco P i n e O i l
CHEMICAL DESCRIPTION
SOURCE Hercul
Hoechst Wax E
Wax
Hoechs
Hoechst Wax F
Wax
Hoechs
Hoechst Wax LP
Wax
Hoechs
Hoechst Wax OP
Wax
Hoechs
Hoechst Wax S
Wax
Hoechs
H o s t a p a l N 040
Nonylphenol e t h o x y l a t e - 4 moles EO
Hoechs
H o s t a p a l N 090
Nonylphenol e t h o x y l a t e - 9 moles EO
Hoechs
Hostapur SAS 60
Secondary a l k a n e s u l f o n a t e
Hoechs
I g e p a l CA-620
Nonionic ethoxylate surfactant
Rhone
I g e p a l CA-630
Nonionic ethoxylate s u r f a c t a n t . Moles EO: 9-10
Rhone
I g e p a l CA-720
Nonionic ethoxylate surfactant. Moles EO: 1 2 . 5
Rhone
I g e p a l CO-520
Nonionic ethoxylate surfactant
Rhone
I g e p a l CO-530
Nonionic ethoxylate surfactant
Rhone
I g e p a l CO-630
Nonionic ethoxylate surfactant Moles EO: 9
Rhone
I g e p a l CO-660
Nonionic e t h o x y l a t e s u r f a c t a n t . Moles EO: 10
Rhone
I g e p a l CO-710
Nonionic ethoxylate s u r f a c t a n t . Moles EO: 10.5-11
Rhone
I g e p a l CO-720
Nonionic ethoxylate s u r f a c t a n t . Moles EO: 12
Rhone
I g e p a l RC-520
Nonionic ethoxylate s u r f a c t a n t .
Rhone
Trademarked Raw Materials
RAW MATERIALS Incromide 690
CHEMICAL DESCRIPTION
265
SOURCE
Ionac PE-110
Ion exchange resin
Sybron
Isopar E
Isoparaffin solvent
Exxon
Isopar G
Isoparaffin solvent
Exxon
Isopar K
Isoparaffin so vent
Exxon
Isopar
L
I soparaf f i n so vent
Exxon
Isopar M
Isoparaffin so vent
Exxon
Kaopolite A0
Anhydrous a1 umi num si 1 i cate
Kaopol
Kaopolite SF
Anhydrous a1 umi num si 1 i cate
Kaopol
Kaopolite SFO-NP
Anhydrous aluminum silicate
Kaopol
Kaopol i te 1 152
Anhydrous aluminum silicate
Kaopol
Kaopol i te 1 1 68
Anhydrous a1 umi num si 1 icate
Kaopol
Kasil #1
Potassi um si 1 i cate
PQ
Kasi 1 #6
Liquid potassium silicate
PQ
Kathon CG/ICP
Fungicide (biocide)
Rohm
KerMac 600 MSO
MSO
Kerr-
Kessco PEG-600
Fatty ester. Mono aurate
Stepan
Klucel
Hydroxypropyl cel ulose
Aqua1 o
Korthi x
Thickening agent
Kaopol
Korthix H
Thickening agent
Kaopol
H
266 Advanced Cleaning Product Formulations
RAW MATERIAL L-140 S o l v e n t
CHEMICAL DESCRIPTION
SOURCE
L a p o n i t e RDS L y t r o n 295 Opaci f ie r
Polystyrene emulsion
Morton
Mackadet 40K
P o t a s s i u m c o c o n u t soap
McInt
Mackam CSF
Cocoamphopropionate
McInt
Mackam MEJ
Amphoteric s u r f a c t a n t
McInt
Mackam 2CSF
Cocoamphodipropionate
McInt
Mackam 2CYSF
C a p r y l ampodi p r o p i o n a t e
McInt
Mackam TM
D i h y d r o x y e t h y l t a l low g l y c i n a t e
McInt
Mackam 35
Cocoami d o p r o p y l b e t a i ne
M c In t
Mackami de CDM
Cocamide DEA ( a n d ) DEA o l e a t e
McInt
Mackami de LLM
Laurami de DEA
McInt
Mackamide S
Soyamide DEA
McInt
Mackamine CO
Cocami n e o x i d e
McInt
Mackamine LO
Laurami n e o x i d e
McInt
Mackazol ine 0
01 e y l h y d r o x y e t h y l im i d a z o l ine
McInt
M a c k s t a t DM
DMDM h y d a n t o i n
McInt
Macol LF-110
Polyoxyethylene f a t t y ether
PPG
Macol DNP 150
Polyoxyethylene f a t t y ether
P PG
Macol NP 9 . 5
Polyoxyethylene f a t t y ether
P PG
Macol 25
Polyoxyethylene f a t t y ether
PPG
Macol 27
Polyoxyethylene f a t t y ether
PPG
Trademarked Raw Materials
RAW MATERIAL
267
CHEMICAL D E S C R I P T I O N Polyoxyethylene f a t t y ether
SOURCE
Macol 40 Macol 41
Polyoxyethylene f a t t y ether
P PG
Macol 45
Polyoxyethylene f a t t y ether
PPG
Macol 48
Polyoxyethylene f a t t y ether
PPG
Macol 212
Polyoxyethylene f a t t y ether
PPG
Makon
A l k y l phenol e t h e r
Stepan
Makon 6
A l k y l phenol e t h e r
Stepan
Makon 10
Alkyl
Stepan
Maphos 66H
Phosphate e s t e r
PPG
Maphos 91
Phosphate e s t e r
PPG
M a s i l EM 1000 P
Silicone f l u i d
P PG
M a s i l SF 100
Silicone f l u i d
PPG
M a s i l SF 10,000
S i 1 icone f 1 u i d
P PG
M a s i l 1066C
Silicone f l u i d
PPG
Mazamide 7 0
Speci a1 t y a1 k a n o l ami de
PPG
Mazawet DF
Surfactant
PPG
Mazon DDBSA
Speci a1 t y p r o p r i e t a r y
P PG
Mazon 41
Speci a1 t y p r o p r i e t a r y
P PG
Mazon 601
Specialty proprietary
PPG
Mazon 71A
Speci a1 t y p r o p r i e t a r y
PPG
Metso Beads 2048
Anhydrous s o d i um m e t a s i 1i c a t e
PQ
Metso Pentabead 2 0
Sodium m e t a s i l i c a t e p e n t a h y d r a t e
PQ
Metso 200
Sodi um o r t h o s i 1 ic a t e
PQ
Microfine V I
A i r floated bentonite
AmCol 1
phenol e t h e r
PPG
268
Advanced Cleaning Produc# Formulations
RAW MATERIALS M i r a n o l CS Conc.
CHEMICAL D E S C R I P T I O N Amphoteric s u l f o n a t e s u r f a c t a n t
SOURCE
M i r a n o l DN
Sodium stearoampho a c e t a t e
Rhone
M i r a n o l FBS
D i s o d i um cocoampho d i p r o p i o n a t e
Rhone
M i r a n o l JEM Conc.
Sodium mixed C8-amphocarboxylate
Rhone
M i r a t a i ne CBS
Cocoamidopropyl
Rhone
M i r a t a i ne JC-HA
P r o p r i e t a r y ami n o p r o p i o n a t e
Rhone
M i r a t a i n e TM
D i h y d r o x y e t h y l t a l low g l y c i n a t e
Rhone
Monacor TEH
Corrosion i n h i b i t o r
Mona
Monacor 39
Corrosion i n h i b i t o r
Mona
Monafax 785
O r g a n i c phosphate e s t e r s u r f a c t a n t Mona
Mona1ux CAO-LC
Surfactant
hydroxy s u l t a i n e
Rhone
Mona Mona
Monami ne R32-7 Monamulse DL-1273
Proprietary emulsifier/solubilizer
Mona
Mona NF-10
Surfactant
Mona
Mona NF-15
Surfactant
Mona
Mona NF-25
Surfactant
Mona
M o n a t e r i c CAB-LC
Surfactant
Mona
Monawet MM-80
Surfactant
Mona
Monawet MO-70R
Surfactant
Mona
Monazol ine CY
1-Hydroxyethylene-2-Caprylimid-
Mona
a z o l ine monobasic
FMC
Monosorb MSP
Sodium phosphate,
Mor-Glo 2 L a t e x
F l o o r p o l i s h l a t e x (38%)
Morton
M o r t o n Conrez 5 0 0
Polymer e m u l s i o n
Morton
M- P y r o l
N - m e t h y l - 2 - p y r r o l idone
ISP
N a t r o s o l 250-LR
Hydroxyethylcellulose
Aqua1 o
Trademarked Raw Materials
269
RAW MATERIAL N-C e a r
CHEMICAL DESCRIPTION Sodium m e t a s i i c a t e
Neodol 25-3
Ethoxylate
L i n e a r p r i m a r y a l c o h o l . MW:
336
Shel 1
Neodol 25-7 E t h o x y l a t e
L i n e a r p r i m a r y a l c o h o l . MW:
519
Shel 1
Neodol 25-9 E t h o x y l a t e
L i n e a r p r i m a r y a l c o h o l . MW:
610
Shel 1
Neodol 91-8 E t h o x y l a t e
L i n e a r p r i m a r y a l c o h o l . MW:
529
Shel 1
N i a p r o o f 08
Anionic surfactant
N i acet
N i n o l GR (80%)
COCO d i e t h a n o l ami de
Stepan
N i n o l 11-CM
Coconut d i e t h a n o l a m i d e , m o d i f i e d
Stepan
NM-90 L a t e x Polymer
Polymer e m u l s i o n
Morton
Opaci f ie r E295
L a t e x o p a c i f ie r
Morton
Pemulen TR-1 R e s i n
Emulsifier
BFGood
Pemulen TR-2 R e s i n
Emu1 s i f ie r
BFGood
P e t r o l i t e Wax C-36
Wax
Petrol
P i l o t SXS-40
Sodi urn x y l ene s u l f o n a t e
Pi l o t
P l u r a f a c D-25
L i n e a r a l c o h o l a l k o x y l a t e . MW:930
BASF
P l u r o n i c F68
P o l y o x y a l k y l ene g l y c o l b l o c k polymer
BASF
P1 u r o n i c F108
Polyoxyalkylene g l y c o l block polymer
BASF
SOURCE PP
P a t i o n i c CSL P a t i o n i c ISL Pat io n i c 138C P a t l a c LA
270
Advanced Cleaning Product Formulations
RAW MATERIAL P l u r o n i c L-10
CHEMICAL DESCRIPTION SOURCE P o l y o x y a l k y l e n e g r a f t b l o c k polymer BASF
PQ Epsom S a l t
PQ
Protease-Novo N o r d i s k P r o x e l GXL
Chemi c a l b i o c i de
ICI
P u r t o n CFD
F a t t y a c i d a1 k a n o l ami de
Zschi m
Q-3
Bentonite c l a y
CalCar
Renex 698
Detergent
ICI
R e s i n a l l 802
L e v e l i n g r e s i n (25%)
Resin
Rhodacal A-246/L
Sodium a l p h a o l e f i n s u l f o n a t e
Rhone
Rhodacal DS-10
Sodium dodecylbenzene ( b r a n c h e d )
Rhone
Rhodacal DSB
D i s o d i um d o d e c y l d i p h e n y l o x i d e , d i sul fonate
Rhone
Rhodacal IPAM
L i n e a r I P A DDBSA
Rhone
Rhodacal 301 -1O/F
Sodium a l p h a o l e f i n s u l f o n a t e
Rhone
Rhodacal 330
Branched is o p r o p y l ami ne d o d e c y l benzene s u l f o n a t e
Rhone
Rhodaf ac LO-529
Nonylphenol e t h o x y l a t e , sodium s a l t
Rhone
Rhodafac PE-510
Anionic surfactant
Rhone
Rhodaf ac RA-600
L i n e a r a1 coho1 e t h o x y l a t e
Rhone
Rhodafac RE-610
Nonylphenol e t h o x y l a t e
Rhone
Rhodaf ac RS-610
Branched a l c o h o l e t h o x y l a t e
Rhone
Rhodapex CO-436
Ammonium n o n o x y n o l - & s u l f a t e
Rhone
Rhodapex ES
Anionic surfactant
Rhone
partial
Trademarked Raw Materials
RAW MATERIAL
271
CHEMICAL D E S C R I P T I O N Sodium l a u r e t h ( 2 ) s u l f a t e
SOURCE
Rhodapex ES-2 Rhodapex MA-360
Anionic surfactant
Rhone
Rhodapex NA-61
Sodium l a u r e t h (3) s u l f a t e
Rhone
Rhodapol
Xanthan gum
Rhone
Rhodapol 23
Xanthan gum
Rhone
Rhodapon BOS
Sodi urn 2 - e t h y l h e x y l s u l f a t e
Rhone
Rhodapon LSB
Sodium l a u r y l s u l f a t e
Rhone
Rhodapon SB
Sodi um 1a u r y l s u l f a t e
Rhone
Rhodapon SB B208/S
Sodium l a u r y l s u l f a t e
Rhone
Rhodapon U B
Sodium l a u r y l s u l f a t e
Rhone
R h o d a s u r f BC-840
Branched c h a i n i s o t r i d e c y l alcohol ethoxylate
Rhone
R h o d a s u r f 25-7
Mixed l i n e a r a l c o h o l ethoxy a t e
Rhone
Rhodasurf 25-9
Noni o n i c s u r f a c t a n t
Rhone
Rhodasurf 91 -6
M i xed 1 in e a r a1 c o h o l e t h o x y a t e
Rhone
Rhodaterge RS-25
Cleaner concentr a t e
Rhone
Rhodaterge SMC
Cleaner c o n c e n t r a t e
Rhone
R itachol
L i q u i d a b s o r p t i o n base
RITA
R i tahydrox
Rhone
RITA
R i t a l an
Lanolin o i l
RITA
R i toleth-10
E t h o x y l a t e d o l e y l a1 c o h o l
RITA
Rodine 213
Corrosion i n h i b i t o r
Parker
RU Sodi um S i 1 i c a t e
Corrosion i n h i b i t o r
PP
272
Advanced Cleaning Product Formulations
SOURCE
RAW MATERIAL SF-96 S i l i c o n e ( 3 5 0 )
CHEMICAL DESCRIPTION Polydimethyl s i l i c o n e f l u i d
GE
SF-1 706
S i 1 icone
GE
S i 1-Co-Si 1 53
Silica
USSi 1
S i l i c o n e AFL 40
S i 1icone
UnCarb
S i 1 icone Emu1s i on SM-2035 S i l i c o n e F l u i d L45 S i 1t e x
Fused s i l i c a -50+100 mesh
Kaopol
S i l t e x 44
Fused s i l i c a
Kaopol
S i l w e t L7600
Surface a c t i v e copolymer-silicone
UnCarb
S-Maz 83R
Sorbitan f a t t y ester
PPG
Snow F l o s s
M i n e r a l f i1 l e r
JM
Sodium N S 1 ic a t e
PQ
Span 80
Surfactant
ICI
S t a b i 1 iz e r ASE-108
A c r y l i c e m u l s i o n copolymer
Rohm&
Standamid CD
Caprami de DEA
Henkel
Standamid KD
Cocamide DEA
Henkel Henk e l
Standami d LAO Standamid LD
Henkel
Laurami de DEA
Henkel
Standamid LM Standamid SD
Cocamide DEA
Henkel
S t a n d a p o l ES-3
Sodi um 1a u r e t h - 3 - s u l f a t e
Henkel
Standapol T
TEA l a u r y l s u l f a t e ,
Henkel
40%
S t a r Sodi um S i 1 ic a t e
PQ
S t a r s o Sodi um S i 1ic a t e
PQ
Trademarked Raw Materials
273
RAW MATERIAL Stepanate X
CHEMICAL DESCRIPTION Hydrot rope
SOURCE
S u l f o t e x SXS
Sodium x y l e n e s u l f o n a t e
Henkel
S u l f o t e x SXS 40
Sodium x y l e n e s u l f o n a t e , 40%
Henkel
S u l f o t e x 60405
Sodium l a u r y l e t h e r s u l f a t e ,
S u l f r a m i n 60
Detergent produc t
D i a1
Super F l o s s
Mineral f i l l e r
JM
sws-211
S i l i c o n e a n t i f o a m agent
sws
Synthrapol N
Detergent
ICI
T e r g i t o l NP-10
Nonoxynol -1 0
UnCarb
T e r g i t o l NPX
Specialty nonionic surfactant
UnCarb
T e r r y AGO02
A l o e Vera g e l
Terry
Texanol
Ester alcohol
Eastma
T e x s t i m 8741
Noni o n i c s u r f a c t a n t
Tomah
T i n o p a l CBS-X
F1 u o r e s c e n t whi t e n i ng a g e n t
C i ba-G
T i n o p a l 5BM
F1u o r e s c e n t whi t e n i ng a g e n t
C i ba-G
Tomah A c i d T h i c k e n e r
Cationic surfactant
Tomah
Stepan
59%
Henkel
Tomah A1 k a l i S u r f a c t a n t A m p h o t e r i c (35% a c t i v e )
Tomah
Tomah A m p h o t e r i c L
Mild surfactant
Tomah
Tomah A m p h o t e r i c N
Surfactant
Tomah
Tomah A m p h o t e r i c SC
Surfactant
Tomah
Tomah Amphoteri c 400
Surfactant
Tomah
Tomah AO-14-2
E t h e r amine o x i d e
Tomah
Tomah A0-728 Speci a1
P r o p r i e t a r y ami ne o x i d e
Tomah
Tomah DA-17
Tomah
274
Advanced Cleaning Product Formulations
RAW MATERIAL Tomah E-14-2
CHEMICAL DESCRIPTION E t h o x y l a t e d ami ne
SOURCE
Tomah E-14-5
E t h o x y l a t e d ami ne
Tomah
Tomah E-17-2
Ethoxyl a t e d ami ne
Tomah
Tomah E-18-2
E t h o x y l a t e d amine
Tomah
Tomah Ecowax N-3
"Hydrocarbon Free" Spraywax
Tomah
Tomah Ecowax N-7
"Hydrocarbon Free" Spraywax
Tomah
Tomah Emul s i f ie r Four
D i a1 k y l quaternary
Tomah
Tomah Emul s i f ie r 827
M i xed d i a1 k y l quaternary
Tomah
Tomah OAT 1000
Organic a c i d t h i c k e n e r
Tomah
Tomah (2-14-2
Quaternary
Tomah
Quaternary
Tomah
Tomah 9-17-2
(PG)
Tomah
Tomah
Tomah TAE-RI T r i t o n CF-10
A l k y l a r y l p o l y e t h e r nonion
C
Rohm&
T r i t o n CF-21
A l k y l a r y l p o l y e t h e r nonion
C
Rohm&
T r i t o n CF-54
Modi f ied p o l yethoxy adduct nonionic
Rohm&
T r i t o n DF-12
Modified polyethoxylated alcohol nonionic
Rohm&
T r i t o n X-100
Octoxynol-9
UnCarb
T r i t o n X-102
Octoxynol-13
UnCarb
T r i t o n X-114
O c t y l phenol
UnCarb
T r y c o l 5963
POE ( 8 )
Henk e l
T r y c o l 5964
Polyoxyethylene a1 k y l e s t e r
Henkel
Tween 20
Surfactant
ICI
l a u r y l ether s u l f a t e
Trademarked Raw Materials
275
RAW MATERIAL V a l f o r 100
CHEMICAL DESCRIPTION Zeolite A builder
SOURCE
Van Gel ES
N a t u r a l smecti t e c l a y
Vander
Varsol
Mineral spi r it s
Exxon
Veegum
Stabilizer,
suspending agent
Vander
Veegum T
S t a b i 1 iz e r ,
suspending agent
Vander
V e l v e t e x BA-35
Cocami d o p r o p y l b e t a i ne, 35%
Hen k e l
Vel v e t e x BK-35
Cocami d o p r o p y l b e t a i ne, 35%
Henkel
V e r s a f 1 ex 207
Emulsion c o a t i n g
Grace
Versene Powder
C h e l a t i n g agent
Dow
Versene 220 C r y s t a l
Chel a t i ng a g e n t
Dow
Viscasil
Silicone f l u i d
GE
W i t c a m i de 51 1
Oleamide DEA
W itco
W i t c o n a t e 1260
C-12 LAS (60%)
W i tco
Yarmor
Pine o i l
Hercul
Z e t e s o l 2056
F a t t y alcohol ether s u l f a t e
Zschim
Zusol a t 1008/85
F a t t y alcohol ether s u l f a t e
Zschim
10,000
PQ
Section IV Suppliers' Addresses
276
Suppliers' Addresses
Akzo Chemical s, I n c . 300 S. R i v e r s i d e P l a z a C h i c a g o , I L 60175
D i a l Corp. 1 1 1 W . C l a r e n d o n Ave. Phoenix, A Z 85013
(312)-906-7500/(800)-257-8292
(602)-248-5251/(800)-323-5385
American C o l l o i d Co. 1500 W . Shure D r . A r l in g t o n H e i g h t s , IL 60004
Dow Chemical Co. M i d l a n d , M I 48674
(800)-258-CHEM
(312)-392-4600 Oow C o r n i n g C o r p . Box 0994 M i d l a n d , M I 48686
Aqua1 on P . O . Box 15417 271 1 C e n t r e v i 11e Rd. W i l m i n g t o n , DE 19850
(517)-496-4000
(302)-996-2000/(800)-345-8104 A r c 0 Chemical Co. 3801 West C h e s t e r P i k e Newtown Square, PA 19073
(800)-441-7515 Eastman Chemical Co. P . 0 . Box 431 K i n g s p o r t , TN 37662
(215)-359-2000 A r i zona Chemi c a l Co. 1001 E . B u s i n e s s Hwy 98 Panama C i t y , FL 32401
(615)-229-2318/(800)-327-8626
(904)-785-6700/(800)-526-5294 BASF Corp. 100 C h e r r y H i l l Rd. P a r s i ppany, NJ 07054
ECC America 5775 P e a c h t r e e Dunwoody Rd. A t l a n t a , GA 30342
(404)-843-1551/(800)-843-3222
(201)-316-3000/(800)-526-1072 B u r l i n g t o n Chemical Co., P.O. Box 1 1 1 615 Huffman M i l l Rd. B u r l i n g t o n , NC 27215
DuPont Market S t . W i 1m i n g t o n , DE 19898
Inc.
(919)-584-0111/(800)-672-5888
E m u l s i o n Systems, P.O. Box 307 Lemont, I L 60439
Inc.
(718)-388-2653/(800)-762-7676 Exxon Chemi c a l A n e r i cas 13501 K a t y Frwy Houston, TX 77079
C i ba-Gei gy Corp. 7 Skyline Drive Hawthorne, NY 10532
FMC Corp.
(914)-347-4700/(800)-431-1900
2000 M a r k e t S t .
(713)-870-6000/(800)-231-6633
Philadelphia, Concord Chemical Co. 17th and F e d e r a l S t s . Camden, N J 08105
(609)-966-1526 Degussa Corp.
65 C h a l l e n g e r Rd. R i d g e f i e l d Park,
(201 )-641-6100
PA 19103 (215)-299-6000/(800)-526-3649
GAF C h e m i c a l s Corp. Rhone-Poul enc 1361 A l p s Rd. Wayne, NJ 07470
(201)-628-3000/(800)-848-7659 NJ 07660
277
278
Advanced Cleaning Product Formulations
GE S i l i c o n e s 260 Hudson R i v e r Rd. W a t e r f o r d , NY 12188 (518)-237-3330/(800)-255-0886
Kerr-McGee Chemical Corp. Kerr-McGee C t r . P . O . Box 25861 Oklahoma C i t y , OK 73125
(405)-270-1313/(000)-654-3911 G e o r g i a M a r b l e Co. 1201 R o b e r t s E l v d . Kennesaw, GA 30144
(404)-421-6500
M c I n t y r e Group L t d . 4851 S. S t . L o u i s Ave. Chicago, I L 60513
(312)-927-2401 E.F. G o o d r i c h Co. 9911 0 r e c k s v i l l e Rd. B r e c k s v i 11e, OH 441 41
(216)-447-5000/(800)-331-1144 W.R.
Grace & Co.
Mona I n d u s t r i e s I n c . 76 E. 24 S t . P . O . Box 425 P a t e r s o n , N J 07544
(201)-345-8220/(800)-553-6662
55 Hayden Ave. L e x i n g t o n , MA 02173
(617)-861-6600 Henkel Corp. 5325 S. N i n t h Ave. LaGrange, I 1 60525
(708)-530-7300/(800)-543-7370 Hercules, I n c . H e r c u l e s P1 aza W i 1m i n g t o n , DE 19894
(800)-247-4372 H u n t i n g t o n Labs I n c . 970 E. T i p t o n S t . H u n t i n g t o n , I N 46750
Morton I n t e r n a t i o n a l I n c . 100 N. R i v e r s i d e P l a z a Chicago, I L 60606
(312)-807-2000/(800)-367-3319 N i a c e t Corp. 47 S t . & N i a g a r a F a l l s E l v d . N i a g a r a F a l l s , NY 14304 (716)-285-1474/(800)-E28-1207 01 in Chemical s O l i n Corp. 120 Long Ridge Rd. P.O. Box 1355 S t a m f o r d , CT 06904
(203)-356-2000/(800)-243-9171
(219)-356-8100/(800)-537-5724 I C I Specialties Concord P i k e 8, New Murphy Rd. W i 1m i n g t o n , DE 19897
M.S. Paisner, I n c . 53 Beaumont St. P . O . Box 358 Canton, MA 02021
(302)-886-3000/(000)-822-8215
(617)-828-2040
Johns-Manvi 1 l e Ken-Caryl Ranch Denver, CO 80217
P a r k e r + Amchem Henkel Corp. 300 Welsh Rd. Horsham, PA 19044 (215)-E30-1200/(800)-521-6895
Kaopolite, Inc.
2444 M o r r i s Ave. Union, N J 07083 (908)-789-0609
Penreco 106 S. Main S t . B u t l e r , PA 16001
(412)-283-5600/(000)-245-3952
Suppliers' Addresses
P e t r o l it e Corp. 6910 E. 14 S t . T u l s a , OK 74112 (918)-836-1601
Rohm and Haas Co. Independence M a l l West P h i l a d e l p h i a , PA 19105 ( 2 1 5)-592-3000
P i l o t Chemical Co. 11756 B u r k e S t . Santa Fe S p r i n g s , CA 90670 (310)-723-0036
Stepan Co. 22 W . F r o n t a g e Rd. N o r t h f i e l d , I L 60093
PPG I n d u s t r i e s Chemical s Group One PPG P l a c e P i t t s b u r g h , PA 15272 (412)-434-3131/(800)-243-6774
Sutton Laboratories I n c . 116 Summit Ave. Chatham, NJ 07928 (201)-635-1551
PQ Corp. P.O. Box 840 Val l e y F o r g e , PA 19482 (215)-293-7200 Quest I n t e r n a t i o n a l F r a g r a n c e s 400 I n t e r n a t i o n a l D r i v e Mount O l i v e , NJ 07828 (201 )-691-7100 Resi n a l l Corp. P . O . Box 8149 S t a m f o r d , CT 06905 (203)-329-7100 Rheox, I n c . P . O . Box 700 H i g h t s t o w n , NJ 08520 (609)-443-2500 Rhone-Poul enc CN 7500 P r o s p e c t P1 a i n s Road C r a n b u r y , NJ 08512
(609)-860-4000/(800)-626-2613 R I T A Corp. P . O . Box 585 Woodstock, I L 60098
(815)-337-2500/(800)-426-7759
(708)-446-7500/(800)-745-7837
SWS Wacker S i l i c o n e s Corp. 3301 S u t t o n Rd. A d r i a n , M I 49221
(517)-264-8500/(800)-248-0063 Sybron Chemical s I n c . P . O . Box 66 B i r m i ngham, N J 0801 1
(609)-893-llOO/(800)-678-0020 Terry Laboratories, Inc. 3270 P i n e d a Ave. M e l b o u r n e , FL 32940
(407)-259-1630/(800)-FOR ALOE 3M 3M C e n t e r S t . P a u l , MN 55144 (612)-733-5454 Tomah P r o d u c t s , I n c . 1012 T e r r a D r i v e M i 1t o n , W I 53563 (608)-868-6811/(800)-441-0708 U . S . S i l i c a Co. P . O . Box 187 B e r k e l e y S p r i n g s , WV 25411
(304)-258-2500/(800)-243-7500
279
280
Advanced Cleaning Product Formulations
Witco Corp. 520 Madison A v e . New York. NY 10022 (212)-605-3941/(800)-634-4010
Union C a r b i d e Corp. 39 O l d Ridgebury Rd. Danbury, CT 06817 (203)-794-2000 R.T. Vanderbilt Co., P . O . Box 5150 30 W i n f i e l d S t . Norwalk, CT 06856
Inc.
(203)-853-1400/(800)-243-6064
Zschimmer & Schwarz Max-Schwarz-Strabe 3-5 D-56112 Lahnstei n/RH 0 26 21/12 0
Other Noyes Publications
COSMETIC AND TOILETRY FORMULATIONS Second Edition - Volume 3 by
Ernest W. Flick This book contains 775 cosmetic and toiletry formulations basedon information receivedfrom numerous industrial companies and other organizations. This is Volume 3 of the Second Edition of this work; Volume 1 was published in 1989.Volume 2waspublishedin1992.Thereare no duplications in any of these volumes. The data represent selections from manufacturers' desaiptions made at no cost to, nor influencefrom,themakersordistributoeof these materials. Only the most recent formulas have been included. It is believed that all of the trademarked raw materials listed are currently available, which will be of interest to readers concerned with raw material discontinuances. The cosmetic and toiletry market is projected to increase to dose to $2 billion by 1995, thus making the information in the book particularly interesting to anyone considering new products
or process variations. Each formulation in the book is identified by a description of end use. The formulations include the following as available, in the manufacturer's own words: a listing of each raw material contained; the percent by weight of each raw material; suggested formulation procedure; and the formula source, which is the company or organizationthat suppliedthe formula. The formulations in the book are divided into thirleencategories asshownbelow. Inaddition, a valuable section on Trade-Named Raw Materials is included, which liststrade-names. atnief chemical description, and the supplier's name. ThefinalsectioncontainsSuppllers' Addresses and will no doubt be a useful tool to the reader. W o n titles are listed below. Parenthetic numbers indicatethe number of formulations per topic.
1. Antiperspirants and Deodorants (28)
II. Baby Products (21) 111. Bath and Shower Productl(57)
N.
Beauty Aids (119)
V. Creams(79) Vl. Hair Care Products (118) VII. i n r d Repellents (24) VIII. Lotions (62)
IX. Shampoos (120) X. Shaving Products (4)
XI. Soaps and Hand Cleaners (57) XII. Sun Cam Products (68) XIII. Miscellaneous (18)
XN. Trade-Named Raw Materids XV. Suppliers' Addresses ISBN 0-8155-1367-4
(1995)
6' x9'
464pages
Other Noyes Publications
ADVANCED CLEANING PRODUCT FORMULATIONS Volume 2 by Ernest W. Flick
This book (Volume 2) presents more than 800 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influencefrom, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volume 1. which was published in 1989. Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost-performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents supplier's suggested formulations which might meet new performance criteria. Theformulations inthisbook aredivided into the following sections and chapters, with the number of formulations indicated in ( ): 1. Household and industrial Cleaners and Polishes (733) 1. Bathroom Cleaners (29) 2. Dairy and Food Industry Cleaners (15) 3. Degreasers (20) 4. Dishwashing Detergents (67)
12. Rug, Carpet and Upholstery Shampoos and Cleaners (21) 13. Miscellaneous Cleaners (96) 11. TransportationCleaners and Polishes (76) 14. Auto Cleaners and Polishes (9) 15. Car and Truck Wash Compounds (38) 16. Whitewall Tire Cleaners (10)
17. Miscellaneous (19)
In addition to the above, there are two other sections which will be helpful to the reader. 111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the supplier's name. The specifications which each raw material meets are included, if applicable. IV. Main office addresses of the suppliers of trademarked raw materials.
Each formulation in the book lists the following information, as available: 1. Description of end use and most
outstanding properties. 2. The percent by weight or volume of
each raw material included in the formula.
6. General Purpose Cleaners (47)
3. Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type.
7. Hard Surface Cleaners (60)
4. The formula source, which is the
5. DetergentsDisinfectants (36)
8. Laundry Products (217) 9. Metal Cleaners (87) 10. Polishes, Coatings and Sealers (32) 11. Rinse Aids (6)
ISBN 0-8155-1346-1 (1994)
company or organization that supplied the formula. The secondary source maybethe originating companyand/or the primary source's publication title, or both. A formula number is included, if applicable.
6" x9'
394 pages
Other Noyes Publications
INDUSTRIAL SURFACTANTS An Industrial Guide Second Edition by Ernest W. Flick The second Edition of this useful book describes almost 2900 surfactants which are currently availablefor industrialuse. Thebookwill be of valueto technical and managerial personnel involved in the specitition and use of these products. The information has been developed directly from information received from 46 surfactant suppliers. Industrialsurfactants find uses in almost every industry, from asphalt manufacturing to carpet fibers, from pulp and paper productionto leather processing. Examples of the types of Chemicals used as surfactants are fatty alcohol sulfates, alkanolamides, alkoxylates, sulfosuccinates, amines, quaternaries, phosphate esters, acid esters, blockcopolymers,betaines, imidazolines, alkyl sulfonates, etc. The market for these products has, and is expected to continue to have, a steady growth rate, of the order of 2% per year. Surfactants, besides their widely recognizeduse in soaps and detergents, find use as, or in, floor strippers, engine degreasers, corrosion inhibitors, hard
surface cleaners, fabric softeners, paint dispersants, cutting fluids, anti-stats,viscosily builders, rinse aids, mold release agents, foam generators, foam stabilizers, etc. The data included represent selections from manufacturers' descriptions made at no cost to, nor influence from, the makers or distributors of thematerial.Onlythemost recent informationhas beenincluded. It isbelievedthat all of the products listedhere are currently available,which will be of utmost interesttoreaders concernedwith product discontinuances. Products are presented by company. Also included is a Trade Name Index and Supplier's addresses. Thebook liststhe followingproductinformation: 1.Company name and product category 2.Trade name and product numbers 3.Product Description: a brief description of the product and its use.
Air Products and Chemicals
Lonza Inc. Mclntyre Group Ltd. Miranol Inc. Mona Industries. Inc. MTM Research Chemicals, Inc. Niacet Corp. Olin Corp. M.S. Paisner. Inc. Pilot Chemical Co. PPG/Mazer Chemicals Dr. Rhone-Poulenc Ruetgers-Nease Chemical Co., Inc. Sandoz Chemicals Scher Chemicals, Inc. Shell Chemical Co. Sherex Chemical Co., Inc. Stepan Co. 3M Industrial Chemical Products Division Texaco ChemicalCo. Union Carbide Chemicals & Plastics Co., Inc. R.T. Vanderbilt Co.. Inc. Vista Chemical Co. Witco Corp.
Akzo Chemicals, Inc. Albright &Wilson Americas Alcolac-Rhone Poulenc American Cyanamid Co. American Lecithin Co. Burlington Chemical Co., Inc. Central Soya Climax Performance Materials Costec Inc. Daniel Products Co. Dexter Chemical Corp. Dow Chemical Co. DuPont Co. Emulsion Systems Inc. Ethyl Corp. Exxon Chemical Co. GAF Chemicals Corp. Goldschmidt Chemical Corp. W.A. Grace & Co. Harcros Organics Henkel Corp. lnolex Chemical Co. ISBN 0-8155-1332-1 (1993)
The following companiesare representedinthe book.
6" x 9"
547 pages
Other Noyes Publications
ADVANCED CLEANING PRODUCT FORMULATlONS Household, Industrial, Automotive Volume 1 by Ernest W. Flick
This book presents more than 800 up-todate advanced cleaning product formulations lor household, industrial and automotive applications It is the result 01 information received lrom numerous industrial companies and other organizations The data represent selections made at no cost lo. nor inlluence lrom. the makers or distributors of these malerials Only the most recent (ormulas have been included i t is believed that all 01 the trademarked raw materials listed here are currently available The lormulalions in the book are divided as follows Parentheticnumbersindicate the number 01 lormulalions in each chapter 1. HOUSEHOLD/INDUSTRIAL CLEANERS
1. Bathroom Cleaners (16)
2. Disinfectants (11)
3. Dishwashing Detergents (57) 4. Floor Cleaners and Wax Strlppers(41)
5. General Purpose Cleaners (73) 6. Laundry Products (143) 7. Metal Cleaners (74)
8. Oven Cleaners (10) 9. Rinse Additives and Alds (97) 10. Rug, Carpet and Upholstery Cleaners and Shampoos (41) 11. Wall and Hard Surface Cleaners (52) 12. Window and Glass Cleaners (25) 13. Miscellaneous Cleaners (130) I1 A U T O M 0 TI VE CL E A NERS
14. Car and Truck Washes (48)
ISBN 0 - 8 1 5 5 - 1 1 8 6 - 8 (1989)
15. Whitewall Tlre Cleaners (8) 16. Miscellaneous Cleaners (22) Each formulation in the book liststhe lollowlng inlormation. as available. in the manufacturer's own words: Description of end use and most outstanding properties. The percent by weight or volume of each raw material included i n the formula, rounded to a decimal ligure. Key propertiesof the formula, whichare the leatures that the source considers to be more outstanding than other lormulations of the same type. The formula source, which is the company or organization that supplied the lormula. The secondary source may be the originating company andlor the primary source's publication title. or both. A formula number is included, il applicable. In addition to the sections listed above, there are two other sections which will be helpful to the reader A chemical trade name section where trade-named raw materials included in the book are listed with a briel chemical description and the supplier s name Thespecifications which each raw material meelsare included, 11 applicable
Main ollice addresses01 the suppliers 0 1 trade named raw materials
6"x9"
372 pages
